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Title: Guided evolution of bulk metallic glass nanostructures: A platform for designing three-dimensional electrocatalytic surfaces

Abstract

Precise control over catalyst surface composition and structure is necessary to improve the function of electrochemical systems. To that end, bulk metallic glass (BMG) alloys with atomically dispersed elements provide a highly processable, nanoscale platform for electrocatalysis and surface modification. Here we report on nanostructures of Pt-based BMGs that are modified with various subtractive and additive processes to improve their electrochemical performance.

Authors:
 [1];  [2];  [3];  [3];  [4];  [3];  [3];  [3];  [5];  [6];  [3];  [3];  [3];  [7];  [3];  [3];  [8];  [3]
+ Show Author Affiliations
  1. Yale Univ., New Haven, CT (United States); Nuclear and Energy Research Inst., Sao Paulo (Brazil); Univ. of Campinas (UNICAMP) (Brazil)
  2. Yale Univ., New Haven, CT (United States); General Motors Research and Development, Warren, MI (United States)
  3. Yale Univ., New Haven, CT (United States)
  4. Yale Univ., New Haven, CT (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  5. Yale Univ., New Haven, CT (United States); Forschungszentrum Julich (Germany)
  6. Nuclear and Energy Research Inst., Sao Paulo (Brazil)
  7. Brookhaven National Lab. (BNL), Upton, NY (United States)
  8. Univ. of North Texas, Denton, TX (United States)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1227189
Report Number(s):
BNL-108561-2015-JA
Journal ID: ISSN 0935-9648; R&D Project: 16083/16083; KC0403020
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Doubek, Gustavo, Sekol, Ryan C., Li, Jinyang, Ryu, Won -Hee, Gittleson, Forrest S., Nejati, Siamak, Moy, Eric, Reid, Candy, Carmo, Marcelo, Linardi, Marcelo, Bordeenithikasem, Punnathat, Kinser, Emily, Liu, Yanhui, Tong, Xiao, Osuji, Chinedum, Schroers, Jan, Mukherjee, Sundeep, and Taylor, Andre D. Guided evolution of bulk metallic glass nanostructures: A platform for designing three-dimensional electrocatalytic surfaces. United States: N. p., 2015. Web. doi:10.1002/adma.201504504.
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Doubek, Gustavo, Sekol, Ryan C., Li, Jinyang, Ryu, Won -Hee, Gittleson, Forrest S., Nejati, Siamak, Moy, Eric, Reid, Candy, Carmo, Marcelo, Linardi, Marcelo, Bordeenithikasem, Punnathat, Kinser, Emily, Liu, Yanhui, Tong, Xiao, Osuji, Chinedum, Schroers, Jan, Mukherjee, Sundeep, & Taylor, Andre D. Guided evolution of bulk metallic glass nanostructures: A platform for designing three-dimensional electrocatalytic surfaces. United States. https://doi.org/10.1002/adma.201504504
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Doubek, Gustavo, Sekol, Ryan C., Li, Jinyang, Ryu, Won -Hee, Gittleson, Forrest S., Nejati, Siamak, Moy, Eric, Reid, Candy, Carmo, Marcelo, Linardi, Marcelo, Bordeenithikasem, Punnathat, Kinser, Emily, Liu, Yanhui, Tong, Xiao, Osuji, Chinedum, Schroers, Jan, Mukherjee, Sundeep, and Taylor, Andre D. Tue . "Guided evolution of bulk metallic glass nanostructures: A platform for designing three-dimensional electrocatalytic surfaces". United States. https://doi.org/10.1002/adma.201504504. https://www.osti.gov/servlets/purl/1227189.
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@article{osti_1227189,
title = {Guided evolution of bulk metallic glass nanostructures: A platform for designing three-dimensional electrocatalytic surfaces},
author = {Doubek, Gustavo and Sekol, Ryan C. and Li, Jinyang and Ryu, Won -Hee and Gittleson, Forrest S. and Nejati, Siamak and Moy, Eric and Reid, Candy and Carmo, Marcelo and Linardi, Marcelo and Bordeenithikasem, Punnathat and Kinser, Emily and Liu, Yanhui and Tong, Xiao and Osuji, Chinedum and Schroers, Jan and Mukherjee, Sundeep and Taylor, Andre D.},
abstractNote = {Precise control over catalyst surface composition and structure is necessary to improve the function of electrochemical systems. To that end, bulk metallic glass (BMG) alloys with atomically dispersed elements provide a highly processable, nanoscale platform for electrocatalysis and surface modification. Here we report on nanostructures of Pt-based BMGs that are modified with various subtractive and additive processes to improve their electrochemical performance.},
doi = {10.1002/adma.201504504},
journal = {Advanced Materials},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 22 00:00:00 EST 2015},
month = {Tue Dec 22 00:00:00 EST 2015}
}
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https://doi.org/10.1002/adma.201504504
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Works referenced in this record:

Mesostructured thin films as electrocatalysts with tunable composition and surface morphology
journal, November 2012

  • van der Vliet, Dennis F.; Wang, Chao; Tripkovic, Dusan
  • Nature Materials, Vol. 11, Issue 12
  • DOI: 10.1038/nmat3457

In Situ Surface-Enhanced Raman Spectroscopic Studies of CO Adsorption and Methanol Oxidation on Ru-Modified Pt Surfaces
journal, December 2007

  • Yang, Hongzhou; Yang, Yuqing; Zou, Shouzhong
  • The Journal of Physical Chemistry C, Vol. 111, Issue 51
  • DOI: 10.1021/jp075929l

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012

  • Wang, Deli; Xin, Huolin L.; Hovden, Robert
  • Nature Materials, Vol. 12, Issue 1, p. 81-87
  • DOI: 10.1038/nmat3458

Elastic strain effects on catalysis of a PdCuSi metallic glass thin film
journal, January 2015

  • Yang, Yiyi; Adit Maark, Tuhina; Peterson, Andrew
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 3
  • DOI: 10.1039/C4CP04924A

A high-performance catalyst support for methanol oxidation with graphene and vanadium carbonitride
journal, January 2015

  • Huang, Taizhong; Mao, Shun; Zhou, Guihua
  • Nanoscale, Vol. 7, Issue 4
  • DOI: 10.1039/C4NR05244G

Correction to Anomalous Pseudocapacitive Behavior of a Nanostructured, Mixed-Valent Manganese Oxide Film for Electrical Energy Storage
journal, July 2012

  • Song, Min-Kyu; Cheng, Shuang; Chen, Haiyan
  • Nano Letters, Vol. 12, Issue 8
  • DOI: 10.1021/nl3025483

Nanoporous PtRu Alloys for Electrocatalysis
journal, May 2010

  • Xu, Caixia; Wang, Lin; Mu, Xiaolei
  • Langmuir, Vol. 26, Issue 10
  • DOI: 10.1021/la9041474

Combinatorial development of bulk metallic glasses
journal, April 2014

  • Ding, Shiyan; Liu, Yanhui; Li, Yanglin
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3939

High performance bulk metallic glass/carbon nanotube composite cathodes for electron field emission
journal, November 2011

  • Hojati-Talemi, Pejman; Gibson, Mark A.; East, Daniel
  • Applied Physics Letters, Vol. 99, Issue 19
  • DOI: 10.1063/1.3659898

Metallic glasses as novel catalysts
journal, February 1983

  • Brower, W. E.; Matyjaszczyk, M. S.; Pettit, T. L.
  • Nature, Vol. 301, Issue 5900
  • DOI: 10.1038/301497a0

Methanol oxidation and direct methanol fuel cells: a selective review
journal, January 1999

Fabrication of Pd–Ni–P Metallic Glass Nanoparticles and Their Application as Highly Durable Catalysts in Methanol Electro-oxidation
journal, December 2013

  • Zhao, Ming; Abe, Katsuhiro; Yamaura, Shin-ichi
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403185h

Dealloyed Core-Shell Fuel Cell Electrocatalysts
journal, January 2009

Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014

Carbon nanofiber supercapacitors with large areal capacitances
journal, December 2009

  • McDonough, James R.; Choi, Jang Wook; Yang, Yuan
  • Applied Physics Letters, Vol. 95, Issue 24
  • DOI: 10.1063/1.3273864

Glassy Metal Alloy Nanofiber Anodes Employing Graphene Wrapping Layer: Toward Ultralong-Cycle-Life Lithium-Ion Batteries
journal, June 2015

Nanoporous graphene by quantum dots removal from graphene and its conversion to a potential oxygen reduction electrocatalyst via nitrogen doping
journal, January 2014

  • Palaniselvam, Thangavelu; Valappil, Manila Ozhukil; Illathvalappil, Rajith
  • Energy & Environmental Science, Vol. 7, Issue 3
  • DOI: 10.1039/c3ee43648a

Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012

Synthesis and Oxygen Reduction Electrocatalytic Property of Platinum Hollow and Platinum-on-Silver Nanoparticles †
journal, February 2010

  • Peng, Zhenmeng; Wu, Jianbo; Yang, Hong
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm902218j

Methanol Electro-Oxidation on Pt-Ru Alloy Nanoparticles Supported on Carbon Nanotubes
journal, September 2009

A Mesoporous Catalytic Membrane Architecture for Lithium–Oxygen Battery Systems
journal, December 2014

  • Ryu, Won-Hee; Gittleson, Forrest S.; Schwab, Mark
  • Nano Letters, Vol. 15, Issue 1
  • DOI: 10.1021/nl503760n

Catalyst and electrolyte synergy in Li–O2 batteries
journal, January 2014

  • Gittleson, Forrest S.; Sekol, Ryan C.; Doubek, Gustavo
  • Physical Chemistry Chemical Physics, Vol. 16, Issue 7
  • DOI: 10.1039/c3cp54555e

Erratum: Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries
journal, July 2011

  • Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki
  • Nature Chemistry, Vol. 3, Issue 8
  • DOI: 10.1038/nchem.1093

An ESCA study of the interaction of oxygen with the surface of ruthenium
journal, July 1991

Processing of Bulk Metallic Glass
journal, December 2009

The Impact of Ru Contamination of a Pt∕C Electrocatalyst on Its Oxygen-Reducing Activity
journal, January 2007

  • Gancs, Lajos; Hult, Brian Nicholas; Hakim, Nazih
  • Electrochemical and Solid-State Letters, Vol. 10, Issue 9
  • DOI: 10.1149/1.2754382

Tuning the Shape and Catalytic Activity of Fe Nanocrystals from Rhombic Dodecahedra and Tetragonal Bipyramids to Cubes by Electrochemistry
journal, August 2009

  • Chen, Yan-Xin; Chen, Sheng-Pei; Zhou, Zhi-You
  • Journal of the American Chemical Society, Vol. 131, Issue 31
  • DOI: 10.1021/ja904225q

Fuel Cell Membrane Electrode Assemblies Fabricated by Layer-by-Layer Electrostatic Self-Assembly Techniques
journal, October 2008

  • Taylor, André D.; Michel, Marc; Sekol, Ryan C.
  • Advanced Functional Materials, Vol. 18, Issue 19
  • DOI: 10.1002/adfm.200701516

Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
journal, April 2010

  • Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli
  • Nature Chemistry, Vol. 2, Issue 6
  • DOI: 10.1038/nchem.623

Catalytic Activity Trends of Oxygen Reduction Reaction for Nonaqueous Li-Air Batteries
journal, November 2011

  • Lu, Yi-Chun; Gasteiger, Hubert A.; Shao-Horn, Yang
  • Journal of the American Chemical Society, Vol. 133, Issue 47
  • DOI: 10.1021/ja208608s

Palladium–platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction
journal, July 2015

  • Wang, Xue; Choi, Sang-Il; Roling, Luke T.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8594

Synthesis of nanoporous copper by dealloying of Al-Cu-Mg amorphous alloys in acidic solution: The effect of nickel
journal, May 2011

Pd–Ni–Cu–P metallic glass nanowires for methanol and ethanol oxidation in alkaline media
journal, August 2013

MgZnCa glasses without clinically observable hydrogen evolution for biodegradable implants
journal, September 2009

  • Zberg, Bruno; Uggowitzer, Peter J.; Löffler, Jörg F.
  • Nature Materials, Vol. 8, Issue 11
  • DOI: 10.1038/nmat2542

Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells
journal, January 2015

  • Han, Binghong; Carlton, Christopher E.; Kongkanand, Anusorn
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE02144D

Evolution of nanoporosity in dealloying
journal, March 2001

  • Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain
  • Nature, Vol. 410, Issue 6827, p. 450-453
  • DOI: 10.1038/35068529

Characteristic features of alloy polarization curves
journal, January 1983

Operando Observation of the Gold–Electrolyte Interface in Li–O 2 Batteries
journal, October 2014

  • Gittleson, Forrest S.; Ryu, Won-Hee; Taylor, André D.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 21
  • DOI: 10.1021/am504900k

Electrocatalysis by ad-atoms
journal, April 1975

  • Watanabe, M.; Motoo, S.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 60, Issue 3
  • DOI: 10.1016/S0022-0728(75)80261-0

Bulk Metallic Glasses and Their Composites: A Brief History of Diverging Fields
journal, January 2013

A Reverse-Current Decay Mechanism for Fuel Cells
journal, January 2005

  • Reiser, Carl A.; Bregoli, Lawrence; Patterson, Timothy W.
  • Electrochemical and Solid-State Letters, Vol. 8, Issue 6
  • DOI: 10.1149/1.1896466

Palladium nanostructures from multi-component metallic glass
journal, July 2012

High-Quality Metal Oxide Core/Shell Nanowire Arrays on Conductive Substrates for Electrochemical Energy Storage
journal, May 2012

  • Xia, Xinhui; Tu, Jiangping; Zhang, Yongqi
  • ACS Nano, Vol. 6, Issue 6
  • DOI: 10.1021/nn301454q

Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis
journal, June 2013

  • Cui, Chunhua; Gan, Lin; Heggen, Marc
  • Nature Materials, Vol. 12, Issue 8
  • DOI: 10.1038/nmat3668

Nanomoulding with amorphous metals
journal, February 2009

  • Kumar, Golden; Tang, Hong X.; Schroers, Jan
  • Nature, Vol. 457, Issue 7231
  • DOI: 10.1038/nature07718

Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005

  • Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
  • Nature Materials, Vol. 4, Issue 5, p. 366-377
  • DOI: 10.1038/nmat1368

Spontaneous evolution of bicontinuous nanostructures in dealloyed Li-based systems
journal, August 2013

  • Chen, Qing; Sieradzki, Karl
  • Nature Materials, Vol. 12, Issue 12
  • DOI: 10.1038/nmat3741

Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
journal, February 2007

  • Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias
  • Nature Materials, Vol. 6, Issue 3, p. 241-247
  • DOI: 10.1038/nmat1840

Design and Tailoring of the Nanotubular Arrayed Architecture of Hydrous RuO 2 for Next Generation Supercapacitors
journal, December 2006

  • Hu, Chi-Chang; Chang, Kuo-Hsin; Lin, Ming-Champ
  • Nano Letters, Vol. 6, Issue 12
  • DOI: 10.1021/nl061576a

First-Principles Prediction of Oxygen Reduction Activity on Pd–Cu–Si Metallic Glasses
journal, November 2014

  • Chen, Zhengzheng; Yang, Yiyi; Kumar, Sharvan
  • The Journal of Physical Chemistry C, Vol. 118, Issue 49
  • DOI: 10.1021/jp508636y

Bulk Metallic Glass Nanowire Architecture for Electrochemical Applications
journal, March 2011

  • Carmo, Marcelo; Sekol, Ryan C.; Ding, Shiyan
  • ACS Nano, Vol. 5, Issue 4
  • DOI: 10.1021/nn200033c

Engineering Interface and Surface of Noble Metal Nanoparticle Nanotubes toward Enhanced Catalytic Activity for Fuel Cell Applications
journal, February 2013

  • Cui, Chun-Hua; Yu, Shu-Hong
  • Accounts of Chemical Research, Vol. 46, Issue 7
  • DOI: 10.1021/ar300254b

Co3O4 Nanowire@MnO2 Ultrathin Nanosheet Core/Shell Arrays: A New Class of High-Performance Pseudocapacitive Materials
journal, March 2011

  • Liu, Jinping; Jiang, Jian; Cheng, Chuanwei
  • Advanced Materials, Vol. 23, Issue 18
  • DOI: 10.1002/adma.201100058

Bulk Metallic Glass Micro Fuel Cell
journal, November 2012

A comprehensive review on PEM water electrolysis
journal, April 2013

  • Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen
  • International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934
  • DOI: 10.1016/j.ijhydene.2013.01.151

Nanoimprinted electrodes for micro-fuel cell applications
journal, September 2007

Catalytic Activity of Platinum on Ruthenium Electrodes with Modified (Electro)chemical States
journal, July 2005

  • Park, Kyung-Won; Sung, Yung-Eun
  • The Journal of Physical Chemistry B, Vol. 109, Issue 28
  • DOI: 10.1021/jp047430m

Silver palladium core–shell electrocatalyst supported on MWNTs for ORR in alkaline media
journal, July 2013

Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets
journal, July 2015

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009

  • Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S.
  • Nature Chemistry, Vol. 1, Issue 7, p. 552-556
  • DOI: 10.1038/nchem.367
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    Works referencing / citing this record:

    Determination of critical cooling rates in metallic glass forming alloy libraries through laser spike annealing
    text, January 2017

    • Vlassak, Joost J.; Singer, Jonathan P.; Schroers, Jan
    • Rutgers University
    • DOI: 10.7282/t3930x5b

    Exploring a wider range of Mg–Ca–Zn metallic glass as biocompatible alloys using combinatorial sputtering
    journal, January 2017

    • Li, Jinyang; Gittleson, Forrest S.; Liu, Yanhui
    • Chemical Communications, Vol. 53, Issue 59
    • DOI: 10.1039/c7cc02733h

    A Highly Efficient and Self-Stabilizing Metallic-Glass Catalyst for Electrochemical Hydrogen Generation
    journal, September 2016

    Excellent degradation performance of 3D hierarchical nanoporous structures of copper towards organic pollutants
    journal, January 2018

    • Yang, Chong; Zhang, Cheng; Liu, Lin
    • Journal of Materials Chemistry A, Vol. 6, Issue 42
    • DOI: 10.1039/c8ta07973k

    Recent Advances in Metallic Glass Nanostructures: Synthesis Strategies and Electrocatalytic Applications
    journal, December 2018

    • Li, Jinyang; Doubek, Gustavo; McMillon-Brown, Lyndsey
    • Advanced Materials, Vol. 31, Issue 7
    • DOI: 10.1002/adma.201802120

    Compelling Rejuvenated Catalytic Performance in Metallic Glasses
    journal, September 2018

    Low‐Iridium‐Content IrNiTa Metallic Glass Films as Intrinsically Active Catalysts for Hydrogen Evolution Reaction
    journal, December 2019

    • Wang, Zi‐Jian; Li, Ming‐Xing; Yu, Ji‐Hao
    • Advanced Materials, Vol. 32, Issue 4
    • DOI: 10.1002/adma.201906384

    A novel non-enzymatic biosensor based on Ti-metallic glass thin film: The blood glucose oxidation approach
    journal, January 2020

    • Sarafbidabad, Mohsen; Jazi, HamidrezaKaviani; Rafienia, Mohammad
    • Journal of Medical Signals & Sensors, Vol. 10, Issue 1
    • DOI: 10.4103/jmss.jmss_15_19

    Combinatorial screening of Pd-based quaternary electrocatalysts for oxygen reduction reaction in alkaline media
    journal, January 2017

    • Li, Jinyang; Stein, Helge S.; Sliozberg, Kirill
    • Journal of Materials Chemistry A, Vol. 5, Issue 1
    • DOI: 10.1039/c6ta08088j

    Multifunctional inorganic nanomaterials for energy applications
    journal, January 2020

    • Wang, Huilin; Liang, Xitong; Wang, Jiutian
    • Nanoscale, Vol. 12, Issue 1
    • DOI: 10.1039/c9nr07008g

    On the use of atomistic simulations to aid bulk metallic glasses structural elucidation with solid-state NMR
    journal, August 2017

    Recent Advancements in Bulk Metallic Glasses and Their Applications: A Review
    journal, August 2017

    • Khan, Muhammad Mudasser; Nemati, Ali; Rahman, Zia Ur
    • Critical Reviews in Solid State and Materials Sciences, Vol. 43, Issue 3
    • DOI: 10.1080/10408436.2017.1358149

    Functional Applications of Metallic Glasses in Electrocatalysis
    journal, April 2019

    Metallic glass ultrathin films with hierarchical structure and their dynamic and thermodynamic behavior
    journal, January 2019

    • Liu, Xinbang; Huang, Xinyan; Li, Jiaqi
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 27
    • DOI: 10.1039/c9cp00265k

    Determination of critical cooling rates in metallic glass forming alloy libraries through laser spike annealing
    journal, August 2017

    • Bordeenithikasem, Punnathat; Liu, Jingbei; Kube, Sebastian A.
    • Scientific Reports, Vol. 7, Issue 1
    • DOI: 10.1038/s41598-017-07719-2
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