In-situ extended X-ray absorption fine structure study of electrostriction in Gd doped ceria
Abstract
Studying electric field-induced structural changes in ceramics is challenging due to the very small magnitude of the atomic displacements. We used differential X-ray absorption spectroscopy, an elementally specific and spatially sensitive method, to detect such changes in Gd-doped ceria, recently shown to exhibit giant electrostriction. We found that the large electrostrictive stress generation can be associated with a few percent of unusually short Ce-O chemical bonds that change their length and degree of order under an external electric field. The remainder of the lattice is reduced to the role of passive spectator. This mechanism is fundamentally different from that in electromechanically active materials currently in use.
- Authors:
-
- Weizmann Inst. of Science, Rehovot (Israel). Dept. of Materials and Interfaces
- Yeshiva Univ., New York, NY (United States). Physics Dept.
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1385134
- Alternate Identifier(s):
- OSTI ID: 1226701
- Grant/Contract Number:
- SC0001004; FG02-03ER15476; FG02-05ER15688
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 106; Journal Issue: 4; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; catalysis (homogeneous); catalysis (heterogeneous); biofuels (including algae and biomass); bio-inspired; hydrogen and fuel cells; materials and chemistry by design; synthesis (novel materials), synthesis (self-assembly); synthesis (scalable processing)
Citation Formats
Korobko, Roman, Lerner, Alyssa, Li, Yuanyuan, Wachtel, Ellen, Frenkel, Anatoly I., and Lubomirsky, Igor. In-situ extended X-ray absorption fine structure study of electrostriction in Gd doped ceria. United States: N. p., 2015.
Web. doi:10.1063/1.4906857.
Korobko, Roman, Lerner, Alyssa, Li, Yuanyuan, Wachtel, Ellen, Frenkel, Anatoly I., & Lubomirsky, Igor. In-situ extended X-ray absorption fine structure study of electrostriction in Gd doped ceria. United States. https://doi.org/10.1063/1.4906857
Korobko, Roman, Lerner, Alyssa, Li, Yuanyuan, Wachtel, Ellen, Frenkel, Anatoly I., and Lubomirsky, Igor. Mon .
"In-situ extended X-ray absorption fine structure study of electrostriction in Gd doped ceria". United States. https://doi.org/10.1063/1.4906857. https://www.osti.gov/servlets/purl/1385134.
@article{osti_1385134,
title = {In-situ extended X-ray absorption fine structure study of electrostriction in Gd doped ceria},
author = {Korobko, Roman and Lerner, Alyssa and Li, Yuanyuan and Wachtel, Ellen and Frenkel, Anatoly I. and Lubomirsky, Igor},
abstractNote = {Studying electric field-induced structural changes in ceramics is challenging due to the very small magnitude of the atomic displacements. We used differential X-ray absorption spectroscopy, an elementally specific and spatially sensitive method, to detect such changes in Gd-doped ceria, recently shown to exhibit giant electrostriction. We found that the large electrostrictive stress generation can be associated with a few percent of unusually short Ce-O chemical bonds that change their length and degree of order under an external electric field. The remainder of the lattice is reduced to the role of passive spectator. This mechanism is fundamentally different from that in electromechanically active materials currently in use.},
doi = {10.1063/1.4906857},
journal = {Applied Physics Letters},
number = 4,
volume = 106,
place = {United States},
year = {Mon Jan 26 00:00:00 EST 2015},
month = {Mon Jan 26 00:00:00 EST 2015}
}
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Works referencing / citing this record:
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