Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition

Hadimani, Ravi L.; Silva, Joao H.  B.; Pereira, Andre M.; Schlagel, Devo L.; Lograsso, Thomas A.; Ren, Yang; Zhang, Xiaoyi; Jiles, David C.; Araújo, Joao P.

doi:10.1063/1.4906056

Title: Gd₅(Si,Ge)₄ thin film displaying large magnetocaloric and strain effects due to magnetostructural transition

Abstract

Magnetic refrigeration based on the magnetocaloric effect is one of the best alternatives to compete with vapor-compression technology. Despite being already in its technology transfer stage, there is still room for optimization, namely, on the magnetic responses of the magnetocaloric material. In parallel, the demand for different magnetostrictive materials has been greatly enhanced due to the wide and innovative range of technologies that emerged in the last years (from structural evaluation to straintronics fields). In particular, the Gd₅(Si_xGe_1–x)₄ compounds are a family of well-known alloys that present both giant magnetocaloric and colossal magnetostriction effects. Despite their remarkable properties, very few reports have been dedicated to the nanostructuring of these materials: here, we report a ~800 nm Gd₅Si_2.7Ge_1.3 thin film. The magnetic and structural investigation revealed that the film undergoes a first order magnetostructural transition and as a consequence exhibits large magnetocaloric effect (–ΔS_mMAX~8.83 J kg^–1 K^–1, ΔH = 5T) and giant thermal expansion (12000 p.p.m). The thin film presents a broader magnetic response in comparison with the bulk compound, which results in a beneficial magnetic hysteresis reduction. The ΔS_mMAX exhibited by the Gd₅(Si,Ge)₄ thin film makes it a promising candidate for micro/nano magnetic refrigeration area.

Authors:

Hadimani, Ravi L. ^[1]; Silva, Joao H. B. ^[2]; Pereira, Andre M. ^[3]; Schlagel, Devo L. ^[4];

^[4]; Ren, Yang ^[5]; Zhang, Xiaoyi ^[5]; Jiles, David C. ^[1]; Araújo, Joao P. ^[2]

Iowa State Univ., Ames, IA (United States). Dept. of Electrical and Computer Engineering and Ames Lab.
Univ. do Porto, Rua do Campo Alegre (Portugal)
Imperial College, London (United Kingdom)
Iowa State Univ., Ames, IA (United States). Ames Lab.
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Tue Jan 20 00:00:00 EST 2015

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Engineering and Physical Sciences Research Council (EPSRC)

OSTI Identifier:: 1392396

Alternate Identifier(s):: OSTI ID: 1226697

Grant/Contract Number:: AC02-06CH11357; EP/G060940/1; AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Volume: 106; Journal Issue: 3; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Hadimani, Ravi L., Silva, Joao H.  B., Pereira, Andre M., Schlagel, Devo L., Lograsso, Thomas A., Ren, Yang, Zhang, Xiaoyi, Jiles, David C., and Araújo, Joao P. Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition.  United States: N. p., 2015. 
Web.  doi:10.1063/1.4906056.

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                    Hadimani, Ravi L., Silva, Joao H.  B., Pereira, Andre M., Schlagel, Devo L., Lograsso, Thomas A., Ren, Yang, Zhang, Xiaoyi, Jiles, David C., & Araújo, Joao P. Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition.  United States.  https://doi.org/10.1063/1.4906056

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                    Hadimani, Ravi L., Silva, Joao H.  B., Pereira, Andre M., Schlagel, Devo L., Lograsso, Thomas A., Ren, Yang, Zhang, Xiaoyi, Jiles, David C., and Araújo, Joao P. Tue .  
"Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition".  United States.  https://doi.org/10.1063/1.4906056.  https://www.osti.gov/servlets/purl/1392396.

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@article{osti_1392396,

  title        = {Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition},

  author       = {Hadimani, Ravi L. and Silva, Joao H.  B. and Pereira, Andre M. and Schlagel, Devo L. and Lograsso, Thomas A. and Ren, Yang and Zhang, Xiaoyi and Jiles, David C. and Araújo, Joao P.},

  abstractNote = {Magnetic refrigeration based on the magnetocaloric effect is one of the best alternatives to compete with vapor-compression technology. Despite being already in its technology transfer stage, there is still room for optimization, namely, on the magnetic responses of the magnetocaloric material. In parallel, the demand for different magnetostrictive materials has been greatly enhanced due to the wide and innovative range of technologies that emerged in the last years (from structural evaluation to straintronics fields). In particular, the Gd5(SixGe1–x)4 compounds are a family of well-known alloys that present both giant magnetocaloric and colossal magnetostriction effects. Despite their remarkable properties, very few reports have been dedicated to the nanostructuring of these materials: here, we report a ~800 nm Gd5Si2.7Ge1.3 thin film. The magnetic and structural investigation revealed that the film undergoes a first order magnetostructural transition and as a consequence exhibits large magnetocaloric effect (–ΔSmMAX~8.83 J kg–1 K–1, ΔH = 5T) and giant thermal expansion (12000 p.p.m). The thin film presents a broader magnetic response in comparison with the bulk compound, which results in a beneficial magnetic hysteresis reduction. The ΔSmMAX exhibited by the Gd5(Si,Ge)4 thin film makes it a promising candidate for micro/nano magnetic refrigeration area.},

  doi          = {10.1063/1.4906056},

  journal      = {Applied Physics Letters},

  number       = 3,

  volume       = 106,

  place        = {United States},

  year         = {Tue Jan 20 00:00:00 EST 2015},

  month        = {Tue Jan 20 00:00:00 EST 2015}

}

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We report that UV excitation of jet-cooled CH₂OO X¹A' to the excited B¹A′ electronic states results in dissociation to two spin-allowed product channels: H₂CO X¹A₁ + O ¹D and H₂CO a³A" + O ³P. In this study, the higher energy H₂CO a³A" + O ³P channel is characterized by velocity map imaging and UV action spectroscopy, in both cases utilizing 2 + 1 resonance enhanced multiphoton ionization detection of O ³P products, which complements a prior experimental study on the lower energy H₂CO X¹A₁ + O ¹D channel [Lehman et al., J. Chem. Phys. 139, 141103 (2013)]. Anisotropic angular distributionsmore »« less
Cited by 22
https://doi.org/10.1063/1.4921990

Full Text Available
Fabrication and characterization of p⁺-i-p⁺ type organic thin film transistors with electrodes of highly doped polymer

Journal Article Tadaki, Daisuke ; Ma, Teng ; Zhang, Jinyu ; ... - Journal of Applied Physics

Organic thin film transistors (OTFTs) have been explored because of their advantageous features such as light-weight, flexible, and large-area. For more practical application of organic electronic devices, it is very important to realize OTFTs that are composed only of organic materials. As such, in this paper, we have fabricated p⁺-i-p⁺ type of OTFTs in which an intrinsic (i) regioregular poly (3-hexylthiophene) (P3HT) layer is used as the active layer and highly doped p-type (p⁺) P3HT is used as the source and drain electrodes. The 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F₄-TCNQ) was used as the p-type dopant. A fabricating method of p⁺-i-p⁺ OTFTs has beenmore »« less
Cited by 5
https://doi.org/10.1063/1.4946888

Full Text Available
Laser-driven micro-Coulomb charge movement and energy conversion to relativistic electrons

Journal Article Cobble, J. A. ; Palaniyappan, S. ; Johnson, R. P. ; ... - Physics of Plasmas

Development of robust instrumentation has shown evidence for a multi-μC expulsion of relativistic electrons from a sub-μm-thick foil, laser illuminated with 60–70 J on target at 2 × 10²⁰W/cm². From previous work and with electron spectroscopy, it is seen that an exponential electron energy distribution is accurate enough to calculate the emitted electron charge and energy content. The 5–10-μC charge for the >100-TW Trident Laser represents the first active measurement of the >50% laser-light-to-electron conversion efficiency. By shorting out the TV/m electric field usually associated with accelerating multi-MeV ions from such targets, one finds that this charge is representativemore »« less
Cited by 2
https://doi.org/10.1063/1.4962518

Full Text Available
Identifying the dominant interstitial complex in dilute GaAsN alloys

Journal Article Jen, T. ; Vardar, G. ; Wang, Y. Q. ; ... - Applied Physics Letters

Significant composition-dependent incorporation of N into non-substitutional sites is often reported for dilute GaAsN alloys. To distinguish (N-N)_As, (N-As)_As, and (As_Ga-N_As) complexes, in this work we compare Rutherford backscattering spectrometry and nuclear reaction analysis (NRA) spectra with Monte Carlo-Molecular Dynamics simulations along the [100], [110], and [111] directions. For the Monte Carlo simulation, we assume that (N-N)_As is aligned along the [111] direction, while (N-As)_As is aligned along the [010] direction. The measured channeling NRA spectra exhibit the highest (lowest) yield in the [111] ([100]) directions. Similar trends are observed for simulations of (N-As)_As, suggesting that (N-As)_As is the dominantmore » interstitial complex in dilute GaAsN.« less
Cited by 9
https://doi.org/10.1063/1.4935857

Full Text Available
Full dimensional Franck-Condon factors for the acetylene $$\tilde{A}$$ ¹ A _u —$$\tilde{X}$$ ¹Σ$$^{+}_{g}$$ transition. I. Method for calculating polyatomic linear—bent vibrational intensity factors and evaluation of calculated intensities for the gerade vibrational modes in acetylene

Journal Article Park, G. Barratt - Journal of Chemical Physics

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Cited by 9
https://doi.org/10.1063/1.4896532

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Title: Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition

Abstract

Citation Formats

<I>A Special Issue on</I>: Advanced Materials for Nanoscience and Nanotechnology journal, January 2009

On the origin of giant magnetocaloric effect and thermal hysteresis in multifunctional α-FeRh thin films journal, December 2013

Ultrafast pulsed laser deposition as a method for the synthesis of innovative magnetic films journal, March 2009

Evaluation of silicon nitride as a diffusion barrier for Gd–Si–Ge films on silicon journal, November 2005

Multiple Metamagnetic Transitions in the Magnetic Refrigerant La ( Fe , Si ) 13 H x journal, October 2008

New trends in femtosecond pulsed laser deposition and femtosecond produced plasma diagnostics conference, May 2006

Spontaneous generation of voltage in Gd 5 ( Si x Ge 4 − x ) during a first-order phase transition induced by temperature or magnetic field journal, April 2001

Solid state magnetic refrigerator journal, May 2012

Magnetostrictive Acoustic Transducer Based Torsional Wave Generation in Pipes Using Magnetic Tapes conference, January 2007

Growth and characterization of Pt-protected Gd5Si4 thin films journal, May 2014

Size effect on the lattice parameters of nanoparticles journal, June 2002

Giant magnetic-field-induced strains in polycrystalline Ni–Mn–Ga foams journal, September 2009

Magnetostriction of Terfenol-D heat treated under compressive stress journal, January 1999

Strain-mediated phase coexistence in MnAs heteroepitaxial films on GaAs: An x-ray diffraction study journal, July 2002

Large magnetocaloric effect in La(FexSi1−x)13 itinerant-electron metamagnetic compounds journal, August 2002

Tunable thermal hysteresis in MnFe(P,Ge) compounds journal, March 2009

Transition-metal-based magnetic refrigerants for room-temperature applications journal, January 2002

“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd 5 Si 1.5 Ge 2.5 journal, April 2003

Reducing extrinsic hysteresis in first-order La(Fe,Co,Si)13 magnetocaloric systems journal, December 2009

Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain journal, October 2012

Suppression of low-temperature ferromagnetic phase in ultrathin FeRh films journal, March 2013

Effect of hydrostatic pressure upon the magnetic transitions in the Gd 5 ( Si x Ge 1 − x ) 4 giant magnetocaloric compounds: X-ray magnetic circular dichroism study journal, July 2007

Exploring La(Fe,Si)13-based magnetic refrigerants towards application journal, September 2012

Magnetocaloric piezoelectric composites for energy harvesting journal, March 2012

Magnetocaloric effect linked to the martensitic transformation in sputter-deposited Ni–Mn–Ga thin films journal, October 2009

Expanding the Repertoire of Shape Memory Alloys journal, March 2010

Femtosecond laser pulse irradiation of solid targets as a general route to nanoparticle formation in a vacuum journal, January 2005

Magnetocaloric effect in Gd/W thin film heterostructures journal, May 2010

The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models journal, August 2012

Magnetic properties and magnetocaloric effect in Pt doped Ni-Mn-Ga journal, June 2014

Pressure Enhancement of the Giant Magnetocaloric Effect in T b 5 S i 2 G e 2 journal, September 2004

Voltage induced magnetostrictive switching of nanomagnets: Strain assisted strain transfer torque random access memory journal, June 2014

Giant magnetostriction in annealed Co1−xFex thin-films journal, September 2011

Innovative ideas for future research on magnetocaloric technologies journal, May 2010

Maximizing the temperature span of a solid state active magnetic regenerative refrigerator journal, January 2014

Bulk and high-energy ball-milled Gd5Si2Ge2: Comparative study of magnetic and magnetocaloric properties journal, January 2011

Pressure-induced removal of magnetostructural inhomogeneity in Ge-rich Gd 5 ( Si x Ge 1 − x ) 4 giant magnetocaloric alloys journal, December 2008

Disorder effects in giant magnetocaloric materials: Disorder effects in GMCE materials journal, February 2014

Growth and characterisation of Gd 5 (Si x Ge 1−x ) 4 thin film journal, May 2013

Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys journal, May 2005

Pressure tuning of the magnetic transition in Gd5(Si0.375Ge0.625)4 giant magnetocaloric effect material journal, April 2008

Recent developments in magnetocaloric materials journal, May 2005

Design, fabrication and thermal characterization of a magnetocaloric microcooler journal, January 2007

On the determination of the magnetic entropy change in materials with first-order transitions journal, November 2009

Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron journal, June 2004

Caloric materials near ferroic phase transitions journal, April 2014

Effects of preparation conditions on the magnetocaloric properties of Gd thin films journal, May 2013

Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ∼20 to ∼290 K journal, June 1997

Lattice contractions of a nanoparticle due to the surface tension: A model of elasticity journal, April 2007

Field and temperature induced colossal strain in Gd5(SixGe1−x)4 journal, March 2011

Strain dependent magnetocaloric effect in La 0.67 Sr 0.33 MnO 3 thin-films journal, May 2013

Nature of the first-order antiferromagnetic-ferromagnetic transition in the Ge-rich magnetocaloric compounds Gd 5 ( Si x Ge 1 − x ) 4 journal, July 2000

Magnetocaloric effect in epitaxial La 0.56 Sr 0.44 MnO 3 alloy and digital heterostructures journal, April 2012

Strain-Mediated Phase Coexistence in Heteroepitaxial Films journal, July 2000

Synthesis of nanoparticles with femtosecond laser pulses journal, April 2004

Large field-induced strains in a lead-free piezoelectric material journal, January 2011

Strain Engineering of the Magnetocaloric Effect in MnAs Epilayers journal, September 2008

Giant Magnetocaloric Effect in Gd5(Si2Ge2) journal, June 1997

Magnetocaloric effect in nanoscale thin films and heterostructures journal, July 2014

Metamagnetic transitions and magnetocaloric effect in epitaxial Ni–Co–Mn–In films journal, November 2010

Understanding the role played by Fe on the tuning of magnetocaloric effect in Tb5Si2Ge2 journal, March 2011

Magnetocaloric effect and size-effect related thermal hysteresis reduction in MnAs1-xPx compounds journal, April 2011

Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets journal, January 2012

Ultra-low-energy non-volatile straintronic computing using single multiferroic composites journal, October 2013

Giant magnetoresistance near the magnetostructural transition in Gd5(Si1.8Ge2.2) journal, December 1998

Magnetocaloric effect and improved relative cooling power in (La 0.7 Sr 0.3 MnO 3 /SrRuO 3 ) superlattices journal, January 2011

Massive Magnetic-Field-Induced Structural Transformation in G d 5 G e 4 and the Nature of the Giant Magnetocaloric Effect journal, November 2003

Magnetic-field-induced shape recovery by reverse phase transformation journal, February 2006

Caloric materials near ferroic phase transitions journalarticle, January 2014

“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd5Si1.5Ge2.5 journal, July 2003

Suppression of low-temperature ferromagnetic phase in ultrathin FeRh films text, January 2013

Suppression of low-temperature ferromagnetic phase in ultrathin FeRh films text, January 2013

Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain text, January 2012

Ultra-low-energy non-volatile straintronic computing using single multiferroic composites text, January 2015

Structural, magnetic and magnetocaloric effects in epitaxial La 0.67 Ba 0.33 Ti 0.02 Mn 0.98 O 3 ferromagnetic thin films grown on 001-oriented SrTiO 3 substrates journal, January 2016

Engineered Gd-Co based multilayer stack to enhanced magneto-caloric effect and relative cooling power journal, February 2018

Magnetocaloric materials for energy efficient cooling journal, January 2017

Title: Gd₅(Si,Ge)₄ thin film displaying large magnetocaloric and strain effects due to magnetostructural transition

<I>A Special Issue on</I>: Advanced Materials for Nanoscience and Nanotechnology
journal, January 2009

On the origin of giant magnetocaloric effect and thermal hysteresis in multifunctional α-FeRh thin films
journal, December 2013

Ultrafast pulsed laser deposition as a method for the synthesis of innovative magnetic films
journal, March 2009

Evaluation of silicon nitride as a diffusion barrier for Gd–Si–Ge films on silicon
journal, November 2005

Multiple Metamagnetic Transitions in the Magnetic Refrigerant $La (Fe, Si)_{13} H_{x}$
journal, October 2008

New trends in femtosecond pulsed laser deposition and femtosecond produced plasma diagnostics
conference, May 2006

Spontaneous generation of voltage in ${Gd}_{5} ({Si}_{x} {Ge}_{4 - x})$ during a first-order phase transition induced by temperature or magnetic field
journal, April 2001

Solid state magnetic refrigerator
journal, May 2012

Magnetostrictive Acoustic Transducer Based Torsional Wave Generation in Pipes Using Magnetic Tapes
conference, January 2007

Growth and characterization of Pt-protected Gd₅Si₄ thin films
journal, May 2014

Size effect on the lattice parameters of nanoparticles
journal, June 2002

Giant magnetic-field-induced strains in polycrystalline Ni–Mn–Ga foams
journal, September 2009

Magnetostriction of Terfenol-D heat treated under compressive stress
journal, January 1999

Strain-mediated phase coexistence in MnAs heteroepitaxial films on GaAs: An x-ray diffraction study
journal, July 2002

Large magnetocaloric effect in La(FexSi1−x)13 itinerant-electron metamagnetic compounds
journal, August 2002

Tunable thermal hysteresis in MnFe(P,Ge) compounds
journal, March 2009

Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002

“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd ₅ Si _1.5 Ge _2.5
journal, April 2003

Reducing extrinsic hysteresis in first-order La(Fe,Co,Si)13 magnetocaloric systems
journal, December 2009

Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain
journal, October 2012

Suppression of low-temperature ferromagnetic phase in ultrathin FeRh films
journal, March 2013

Effect of hydrostatic pressure upon the magnetic transitions in the ${Gd}_{5} {({Si}_{x} {Ge}_{1 - x})}_{4}$ giant magnetocaloric compounds: X-ray magnetic circular dichroism study
journal, July 2007

Exploring La(Fe,Si)13-based magnetic refrigerants towards application
journal, September 2012

Magnetocaloric piezoelectric composites for energy harvesting
journal, March 2012

Magnetocaloric effect linked to the martensitic transformation in sputter-deposited Ni–Mn–Ga thin films
journal, October 2009

Expanding the Repertoire of Shape Memory Alloys
journal, March 2010

Femtosecond laser pulse irradiation of solid targets as a general route to nanoparticle formation in a vacuum
journal, January 2005

Magnetocaloric effect in Gd/W thin film heterostructures
journal, May 2010

The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012

Magnetic properties and magnetocaloric effect in Pt doped Ni-Mn-Ga
journal, June 2014

Pressure Enhancement of the Giant Magnetocaloric Effect in ${T b}_{5} {S i}_{2} {G e}_{2}$
journal, September 2004

Voltage induced magnetostrictive switching of nanomagnets: Strain assisted strain transfer torque random access memory
journal, June 2014

Giant magnetostriction in annealed Co1−xFex thin-films
journal, September 2011

Innovative ideas for future research on magnetocaloric technologies
journal, May 2010

Maximizing the temperature span of a solid state active magnetic regenerative refrigerator
journal, January 2014

Bulk and high-energy ball-milled Gd5Si2Ge2: Comparative study of magnetic and magnetocaloric properties
journal, January 2011

Pressure-induced removal of magnetostructural inhomogeneity in Ge-rich ${Gd}_{5} {({Si}_{x} {Ge}_{1 - x})}_{4}$ giant magnetocaloric alloys
journal, December 2008

Disorder effects in giant magnetocaloric materials: Disorder effects in GMCE materials
journal, February 2014

Growth and characterisation of Gd ₅ (Si _x Ge _1−x ) ₄ thin film
journal, May 2013

Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys
journal, May 2005

Pressure tuning of the magnetic transition in Gd5(Si0.375Ge0.625)4 giant magnetocaloric effect material
journal, April 2008

Recent developments in magnetocaloric materials
journal, May 2005

Design, fabrication and thermal characterization of a magnetocaloric microcooler
journal, January 2007

On the determination of the magnetic entropy change in materials with first-order transitions
journal, November 2009

Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron
journal, June 2004

Caloric materials near ferroic phase transitions
journal, April 2014

Effects of preparation conditions on the magnetocaloric properties of Gd thin films
journal, May 2013

Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ∼20 to ∼290 K
journal, June 1997

Lattice contractions of a nanoparticle due to the surface tension: A model of elasticity
journal, April 2007

Field and temperature induced colossal strain in Gd5(SixGe1−x)4
journal, March 2011

Strain dependent magnetocaloric effect in La _0.67 Sr _0.33 MnO ₃ thin-films
journal, May 2013

Nature of the first-order antiferromagnetic-ferromagnetic transition in the Ge-rich magnetocaloric compounds ${Gd}_{5} ({Si}_{x} {Ge}_{1 - x})_{4}$
journal, July 2000

Magnetocaloric effect in epitaxial La _0.56 Sr _0.44 MnO ₃ alloy and digital heterostructures
journal, April 2012

Strain-Mediated Phase Coexistence in Heteroepitaxial Films
journal, July 2000

Synthesis of nanoparticles with femtosecond laser pulses
journal, April 2004

Large field-induced strains in a lead-free piezoelectric material
journal, January 2011

Strain Engineering of the Magnetocaloric Effect in MnAs Epilayers
journal, September 2008

Giant Magnetocaloric Effect in ${Gd}_{5} ({Si}_{2} {Ge}_{2})$
journal, June 1997

Magnetocaloric effect in nanoscale thin films and heterostructures
journal, July 2014

Metamagnetic transitions and magnetocaloric effect in epitaxial Ni–Co–Mn–In films
journal, November 2010

Understanding the role played by Fe on the tuning of magnetocaloric effect in Tb5Si2Ge2
journal, March 2011

Magnetocaloric effect and size-effect related thermal hysteresis reduction in MnAs1-xPx compounds
journal, April 2011

Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets
journal, January 2012

Ultra-low-energy non-volatile straintronic computing using single multiferroic composites
journal, October 2013

Giant magnetoresistance near the magnetostructural transition in Gd5(Si1.8Ge2.2)
journal, December 1998

Magnetocaloric effect and improved relative cooling power in (La _0.7 Sr _0.3 MnO ₃ /SrRuO ₃ ) superlattices
journal, January 2011

Massive Magnetic-Field-Induced Structural Transformation in ${G d}_{5} {G e}_{4}$ and the Nature of the Giant Magnetocaloric Effect
journal, November 2003

Magnetic-field-induced shape recovery by reverse phase transformation
journal, February 2006

Caloric materials near ferroic phase transitions
journalarticle, January 2014

“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd5Si1.5Ge2.5
journal, July 2003

Suppression of low-temperature ferromagnetic phase in ultrathin FeRh films
text, January 2013

Suppression of low-temperature ferromagnetic phase in ultrathin FeRh films
text, January 2013

Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain
text, January 2012

Ultra-low-energy non-volatile straintronic computing using single multiferroic composites
text, January 2015

Structural, magnetic and magnetocaloric effects in epitaxial La _0.67 Ba _0.33 Ti _0.02 Mn _0.98 O ₃ ferromagnetic thin films grown on 001-oriented SrTiO ₃ substrates
journal, January 2016

Engineered Gd-Co based multilayer stack to enhanced magneto-caloric effect and relative cooling power
journal, February 2018

Magnetocaloric materials for energy efficient cooling
journal, January 2017

Magnetocaloric materials: From micro- to nanoscale
journal, November 2018