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Title: Anion-tunable properties and electrochemical performance of functionalized ferrocene compounds

Abstract

We report a series of ionically modified ferrocene compounds for hybrid lithium-organic non-aqueous redox flow batteries, based on the ferrocene/ferrocenium redox couple as the active catholyte material. Tetraalkylammonium ionic moieties were incorporated into the ferrocene structure, in order to enhance the solubility of the otherwise relatively insoluble ferrocene. The effect of various counter anions of the tetraalkylammonium ionized species appended to the ferrocene, such as bis(trifluoromethanesulfonyl)imide, hexafluorophosphate, perchlorate, tetrafluoroborate, and dicyanamide on the solubility of the ferrocene was investigated. The solution chemistry of the ferrocene species was studied, in order to understand the mechanism of solubility enhancement. Lastly, the electrochemical performance of these ionized ferrocene species was evaluated and shown to have excellent cell efficiency and superior cycling stability.

Authors:
 [1];  [1];  [2];  [1];  [2];  [3];  [4];  [1];  [1];  [1]
  1. Energy and Environment Directorate, Richland, WA (United States)
  2. Fundamental and Computation Science Directorate, Richland, WA (United States)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  4. National Security Directorate, Richland, WA (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1226404
Report Number(s):
PNNL-SA-104406
Journal ID: ISSN 2045-2322; srep14117
Grant/Contract Number:  
AC05-76RL01830
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 5; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; redox flow; organic hybrid batteries; functionalized ferrocene; ionic liquids; Environmental Molecular Sciences Laboratory; polymer synthesis; supramolecular polymers

Citation Formats

Cosimbescu, Lelia, Wei, Xiaoliang, Vijayakumar, M., Xu, Wu, Helm, Monte L., Burton, Sarah D., Sorensen, Christina M., Liu, Jun, Sprenkle, Vincent, and Wang, Wei. Anion-tunable properties and electrochemical performance of functionalized ferrocene compounds. United States: N. p., 2015. Web. doi:10.1038/srep14117.
Cosimbescu, Lelia, Wei, Xiaoliang, Vijayakumar, M., Xu, Wu, Helm, Monte L., Burton, Sarah D., Sorensen, Christina M., Liu, Jun, Sprenkle, Vincent, & Wang, Wei. Anion-tunable properties and electrochemical performance of functionalized ferrocene compounds. United States. doi:10.1038/srep14117.
Cosimbescu, Lelia, Wei, Xiaoliang, Vijayakumar, M., Xu, Wu, Helm, Monte L., Burton, Sarah D., Sorensen, Christina M., Liu, Jun, Sprenkle, Vincent, and Wang, Wei. Wed . "Anion-tunable properties and electrochemical performance of functionalized ferrocene compounds". United States. doi:10.1038/srep14117. https://www.osti.gov/servlets/purl/1226404.
@article{osti_1226404,
title = {Anion-tunable properties and electrochemical performance of functionalized ferrocene compounds},
author = {Cosimbescu, Lelia and Wei, Xiaoliang and Vijayakumar, M. and Xu, Wu and Helm, Monte L. and Burton, Sarah D. and Sorensen, Christina M. and Liu, Jun and Sprenkle, Vincent and Wang, Wei},
abstractNote = {We report a series of ionically modified ferrocene compounds for hybrid lithium-organic non-aqueous redox flow batteries, based on the ferrocene/ferrocenium redox couple as the active catholyte material. Tetraalkylammonium ionic moieties were incorporated into the ferrocene structure, in order to enhance the solubility of the otherwise relatively insoluble ferrocene. The effect of various counter anions of the tetraalkylammonium ionized species appended to the ferrocene, such as bis(trifluoromethanesulfonyl)imide, hexafluorophosphate, perchlorate, tetrafluoroborate, and dicyanamide on the solubility of the ferrocene was investigated. The solution chemistry of the ferrocene species was studied, in order to understand the mechanism of solubility enhancement. Lastly, the electrochemical performance of these ionized ferrocene species was evaluated and shown to have excellent cell efficiency and superior cycling stability.},
doi = {10.1038/srep14117},
journal = {Scientific Reports},
number = ,
volume = 5,
place = {United States},
year = {2015},
month = {9}
}

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Cited by: 15 works
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