Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process
Abstract
Lithium-rich material owns a particularly high capacity owing to the activation of electrochemical inactive Li2MnO3 phase. But at the same time, MnO2 phase formed after Li2MnO3 activation confronts a severe problem of converting to spinel phase, and resulting in voltage decay. To our knowledge, this phenomenon is inherent property of layered manganese oxide materials and can hardly be overcome. Based on this, unlike previous reports, herein we design a method for the first time to accelerate the phase transformation by tuning the charge upper-limit voltage at a high value, so the phase transformation process can be finished in a few cycles. Then material structure remains stable while cycling at a low upper-limit voltage. By this novel method voltage decay is eliminated significantly.
- Authors:
-
- Chinese Academy of Sciences (CAS), Zhejiang (China). Ningbo Inst. of Materials Technology and Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1226022
- Report Number(s):
- BNL-108189-2015-JA
Journal ID: ISSN 1521-3765; R&D Project: MA015MACA; KC0201010
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal (Online)
- Additional Journal Information:
- Journal Name: Chemistry - A European Journal (Online); Journal Volume: 21; Journal Issue: 20; Journal ID: ISSN 1521-3765
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Wei, Z., Zhu, Y., Zhang, W., Wang, F., Zhang, Q., Qiu, B., Han, S., Xia, Y., and Liu, Z. Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process. United States: N. p., 2015.
Web. doi:10.1002/chem.201406641.
Wei, Z., Zhu, Y., Zhang, W., Wang, F., Zhang, Q., Qiu, B., Han, S., Xia, Y., & Liu, Z. Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process. United States. https://doi.org/10.1002/chem.201406641
Wei, Z., Zhu, Y., Zhang, W., Wang, F., Zhang, Q., Qiu, B., Han, S., Xia, Y., and Liu, Z. Fri .
"Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process". United States. https://doi.org/10.1002/chem.201406641. https://www.osti.gov/servlets/purl/1226022.
@article{osti_1226022,
title = {Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process},
author = {Wei, Z. and Zhu, Y. and Zhang, W. and Wang, F. and Zhang, Q. and Qiu, B. and Han, S. and Xia, Y. and Liu, Z.},
abstractNote = {Lithium-rich material owns a particularly high capacity owing to the activation of electrochemical inactive Li2MnO3 phase. But at the same time, MnO2 phase formed after Li2MnO3 activation confronts a severe problem of converting to spinel phase, and resulting in voltage decay. To our knowledge, this phenomenon is inherent property of layered manganese oxide materials and can hardly be overcome. Based on this, unlike previous reports, herein we design a method for the first time to accelerate the phase transformation by tuning the charge upper-limit voltage at a high value, so the phase transformation process can be finished in a few cycles. Then material structure remains stable while cycling at a low upper-limit voltage. By this novel method voltage decay is eliminated significantly.},
doi = {10.1002/chem.201406641},
journal = {Chemistry - A European Journal (Online)},
number = 20,
volume = 21,
place = {United States},
year = {Fri Mar 27 00:00:00 EDT 2015},
month = {Fri Mar 27 00:00:00 EDT 2015}
}
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