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Title: Expanding iClick to group 9 metals

In this study, the iClick (inorganic click) reactions between gold-acetylides and group 9 transition metal-azide complexes are presented. Complexes [Rh(CO)(PPh 3) 2][PPh 3Au](μ-N 3C 2C 6H 4NO 2) (3), {[Rh(CO)(PPh 3)][PPh 3Au](μ-N 3C 2C 6H 4NO 2)} 2 (4), and [(CO)(PPh 3) 2IrAuPPh 3](μ-N 3C 2C 6H 4NO 2) (6) have been synthesized via M-azide/M-acetylide cycloaddition reactions between PPh 3Au(Ctriple bond; length of mdashCC 6H 4NO 2) (2) and either Rh(CO)(PPh 3) 2N 3 (1), or Ir(CO)(PPh 3) 2N 3 (5). Complexes 3, 4, and 6 have been characterized by a combination of NMR spectroscopies, crystallography and combustion analysis.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Univ. of Florida, Gainesville, FL (United States)
Publication Date:
Grant/Contract Number:
SC0010510
Type:
Accepted Manuscript
Journal Name:
Polyhedron
Additional Journal Information:
Journal Name: Polyhedron; Journal ID: ISSN 0277-5387
Publisher:
Elsevier
Research Org:
Univ. of Florida, Gainesville, FL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; iClick; azide-alkyne cycloaddition; rhodium; iridium; heterobimetallic
OSTI Identifier:
1225602
Alternate Identifier(s):
OSTI ID: 1373338

Beto, Christopher C., Yang, Xi, Powers, Andrew R., Ghiviriga, Ion, Abboud, Khalil A., and Veige, Adam S.. Expanding iClick to group 9 metals. United States: N. p., Web. doi:10.1016/j.poly.2015.08.032.
Beto, Christopher C., Yang, Xi, Powers, Andrew R., Ghiviriga, Ion, Abboud, Khalil A., & Veige, Adam S.. Expanding iClick to group 9 metals. United States. doi:10.1016/j.poly.2015.08.032.
Beto, Christopher C., Yang, Xi, Powers, Andrew R., Ghiviriga, Ion, Abboud, Khalil A., and Veige, Adam S.. 2015. "Expanding iClick to group 9 metals". United States. doi:10.1016/j.poly.2015.08.032. https://www.osti.gov/servlets/purl/1225602.
@article{osti_1225602,
title = {Expanding iClick to group 9 metals},
author = {Beto, Christopher C. and Yang, Xi and Powers, Andrew R. and Ghiviriga, Ion and Abboud, Khalil A. and Veige, Adam S.},
abstractNote = {In this study, the iClick (inorganic click) reactions between gold-acetylides and group 9 transition metal-azide complexes are presented. Complexes [Rh(CO)(PPh3)2][PPh3Au](μ-N3C2C6H4NO2) (3), {[Rh(CO)(PPh3)][PPh3Au](μ-N3C2C6H4NO2)}2 (4), and [(CO)(PPh3)2IrAuPPh3](μ-N3C2C6H4NO2) (6) have been synthesized via M-azide/M-acetylide cycloaddition reactions between PPh3Au(Ctriple bond; length of mdashCC6H4NO2) (2) and either Rh(CO)(PPh3)2N3 (1), or Ir(CO)(PPh3)2N3 (5). Complexes 3, 4, and 6 have been characterized by a combination of NMR spectroscopies, crystallography and combustion analysis.},
doi = {10.1016/j.poly.2015.08.032},
journal = {Polyhedron},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {9}
}