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Title: Anisotropic H c 2 , thermodynamic and transport measurements, and pressure dependence of T c in K 2 Cr 3 As 3 single crystals

Abstract

We present a detailed study of single crystalline K2Cr3As3 and analyze its thermodynamic and transport properties, anisotropic Hc2(T), and initial pressure dependence of Tc. In zero field, the temperature-dependent resistivity is metallic. Deviation from a linear temperature dependence is evident below 100 K and a T3 dependence is roughly followed from just above Tc (~10K) to ~40K. Anisotropic Hc2(T) data were measured up to 140 kOe with field applied along and perpendicular to the rodlike crystals. For the applied field perpendicular to the rod, Hc2(T) is linear with a slope ~–70 kOe/K. For field applied along the rod, the slope is about –120 kOe/K below 70 kOe. Above 70 kOe, the magnitude of the slope decreases to ~–70 kOe/K. The electronic specific heat coefficient γ, just above Tc, is 73 mJ/mol K2; the Debye temperature ΘD is 220 K. As a result, the specific heat jump at the superconducting transition ΔC~2.2γTc. Finally, for hydrostatic pressures up to ~7 kbar, Tc decreases under pressure linearly at a rate of –0.034K/kbar.

Authors:
 [1];  [1];  [1]
  1. Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Lab., Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1225544
Alternate Identifier(s):
OSTI ID: 1179944
Report Number(s):
IS-J-8552
Journal ID: ISSN 1098-0121; PRBMDO
Grant/Contract Number:  
AC02–07CH11358; AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review. B, Condensed Matter and Materials Physics
Additional Journal Information:
Journal Volume: 91; Journal Issue: 2; Journal ID: ISSN 1098-0121
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Kong, Tai, Bud'ko, Sergey L., and Canfield, Paul C. Anisotropic Hc2 , thermodynamic and transport measurements, and pressure dependence of Tc in K2Cr3As3 single crystals. United States: N. p., 2015. Web. doi:10.1103/PhysRevB.91.020507.
Kong, Tai, Bud'ko, Sergey L., & Canfield, Paul C. Anisotropic Hc2 , thermodynamic and transport measurements, and pressure dependence of Tc in K2Cr3As3 single crystals. United States. doi:10.1103/PhysRevB.91.020507.
Kong, Tai, Bud'ko, Sergey L., and Canfield, Paul C. Fri . "Anisotropic Hc2 , thermodynamic and transport measurements, and pressure dependence of Tc in K2Cr3As3 single crystals". United States. doi:10.1103/PhysRevB.91.020507. https://www.osti.gov/servlets/purl/1225544.
@article{osti_1225544,
title = {Anisotropic Hc2 , thermodynamic and transport measurements, and pressure dependence of Tc in K2Cr3As3 single crystals},
author = {Kong, Tai and Bud'ko, Sergey L. and Canfield, Paul C.},
abstractNote = {We present a detailed study of single crystalline K2Cr3As3 and analyze its thermodynamic and transport properties, anisotropic Hc2(T), and initial pressure dependence of Tc. In zero field, the temperature-dependent resistivity is metallic. Deviation from a linear temperature dependence is evident below 100 K and a T3 dependence is roughly followed from just above Tc (~10K) to ~40K. Anisotropic Hc2(T) data were measured up to 140 kOe with field applied along and perpendicular to the rodlike crystals. For the applied field perpendicular to the rod, Hc2(T) is linear with a slope ~–70 kOe/K. For field applied along the rod, the slope is about –120 kOe/K below 70 kOe. Above 70 kOe, the magnitude of the slope decreases to ~–70 kOe/K. The electronic specific heat coefficient γ, just above Tc, is 73 mJ/mol K2; the Debye temperature ΘD is 220 K. As a result, the specific heat jump at the superconducting transition ΔC~2.2γTc. Finally, for hydrostatic pressures up to ~7 kbar, Tc decreases under pressure linearly at a rate of –0.034K/kbar.},
doi = {10.1103/PhysRevB.91.020507},
journal = {Physical Review. B, Condensed Matter and Materials Physics},
number = 2,
volume = 91,
place = {United States},
year = {2015},
month = {1}
}

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Works referenced in this record:

Unconventional superconductivity in quasi-one-dimensional Rb 2 Cr 3 As 3
journal, January 2015


Superconductivity in quasi-one-dimensional Cs2Cr3As3 with large interchain distance
journal, January 2015


Upper Critical Magnetic Field far above the Paramagnetic Pair-Breaking Limit of Superconducting One-Dimensional Li 0.9 Mo 6 O 17 Single Crystals
journal, May 2012


Anomalous In-Plane Anisotropy of the Onset of Superconductivity in ( TMTSF ) 2 ClO 4
journal, March 2008


Growth of single crystals from metallic fluxes
journal, June 1992


Effect of Pauli Paramagnetism on Magnetic Properties of High-Field Superconductors
journal, August 1966


Pauli-limiting effects in the upper critical fields of a clean LiFeAs single crystal
journal, September 2011


Properties of boson-exchange superconductors
journal, October 1990


Heavy-fermion systems
journal, October 1984


Magnetic measurements of the upper critical field of YBa 2 Cu 3 O 7 δ single crystals
journal, April 1989


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