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Title: Elucidating the sole contribution from electromagnetic near-fields in plasmon-enhanced Cu2O photocathodes

Abstract

Despite many promising reports of plasmon-enhanced photocatalysis, the inability to identify the individual contributions from multiple enhancement mechanisms has delayed the development of general design rules for engineering efficient plasmonic photocatalysts. Herein, we construct a plasmonic photocathode comprised of Au@SiO2 (core@shell) nanoparticles embedded within a Cu2O nanowire network to exclusively examine the contribution from one such mechanism: electromagnetic near-field enhancement. The influence of the local electromagnetic field intensity is correlated with the overall light-harvesting efficiency of the device through variation of the SiO2 shell thickness (5—22 nm) to systematically tailor the distance between the plasmonic Au nanoparticles and the Cu2O nanowires. A three-fold increase in device photocurrent is achieved upon integrating the Au@SiO2 nanoparticles into the Cu2O nanowire network, further enabling a ~40% reduction in semiconductor film thickness while maintaining photocathode performance. Photoelectrochemical results are further correlated with photoluminescence studies and optical simulations to confirm that the near-field enhancement is the sole mechanism responsible for increased light absorption in the plasmonic photocathode.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [1];  [3];  [2];  [3];  [2];  [1]
  1. Univ. of Florida, Gainesville, FL (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Nanjing Tech Univ., Nanjing (China)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1224787
Report Number(s):
BNL-108525-2015-JA
Journal ID: ISSN 1614-6832; R&D Project: 16060/16060; KC0403020
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 115; Journal Issue: 19; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; cuprous oxide; photoelectrochemistry; solar energy conversion; surface plasmon resonance; Center for Functional Nanomaterials

Citation Formats

DuChene, Joseph S., Williams, Benjamin P., Johnston-Peck, Aaron C., Qiu, Jingjing, Gomes, Mathieu, Amilhau, Maxime, Bejleri, Donald, Weng, Jiena, Su, Dong, Huo, Fengwei, Stach, Eric A., and Wei, Wei David. Elucidating the sole contribution from electromagnetic near-fields in plasmon-enhanced Cu2O photocathodes. United States: N. p., 2015. Web. https://doi.org/10.1002/aenm.201501250.
DuChene, Joseph S., Williams, Benjamin P., Johnston-Peck, Aaron C., Qiu, Jingjing, Gomes, Mathieu, Amilhau, Maxime, Bejleri, Donald, Weng, Jiena, Su, Dong, Huo, Fengwei, Stach, Eric A., & Wei, Wei David. Elucidating the sole contribution from electromagnetic near-fields in plasmon-enhanced Cu2O photocathodes. United States. https://doi.org/10.1002/aenm.201501250
DuChene, Joseph S., Williams, Benjamin P., Johnston-Peck, Aaron C., Qiu, Jingjing, Gomes, Mathieu, Amilhau, Maxime, Bejleri, Donald, Weng, Jiena, Su, Dong, Huo, Fengwei, Stach, Eric A., and Wei, Wei David. Thu . "Elucidating the sole contribution from electromagnetic near-fields in plasmon-enhanced Cu2O photocathodes". United States. https://doi.org/10.1002/aenm.201501250. https://www.osti.gov/servlets/purl/1224787.
@article{osti_1224787,
title = {Elucidating the sole contribution from electromagnetic near-fields in plasmon-enhanced Cu2O photocathodes},
author = {DuChene, Joseph S. and Williams, Benjamin P. and Johnston-Peck, Aaron C. and Qiu, Jingjing and Gomes, Mathieu and Amilhau, Maxime and Bejleri, Donald and Weng, Jiena and Su, Dong and Huo, Fengwei and Stach, Eric A. and Wei, Wei David},
abstractNote = {Despite many promising reports of plasmon-enhanced photocatalysis, the inability to identify the individual contributions from multiple enhancement mechanisms has delayed the development of general design rules for engineering efficient plasmonic photocatalysts. Herein, we construct a plasmonic photocathode comprised of Au@SiO2 (core@shell) nanoparticles embedded within a Cu2O nanowire network to exclusively examine the contribution from one such mechanism: electromagnetic near-field enhancement. The influence of the local electromagnetic field intensity is correlated with the overall light-harvesting efficiency of the device through variation of the SiO2 shell thickness (5—22 nm) to systematically tailor the distance between the plasmonic Au nanoparticles and the Cu2O nanowires. A three-fold increase in device photocurrent is achieved upon integrating the Au@SiO2 nanoparticles into the Cu2O nanowire network, further enabling a ~40% reduction in semiconductor film thickness while maintaining photocathode performance. Photoelectrochemical results are further correlated with photoluminescence studies and optical simulations to confirm that the near-field enhancement is the sole mechanism responsible for increased light absorption in the plasmonic photocathode.},
doi = {10.1002/aenm.201501250},
journal = {Advanced Energy Materials},
number = 19,
volume = 115,
place = {United States},
year = {2015},
month = {11}
}

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Works referenced in this record:

Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Solar Water Splitting Cells
journal, November 2010

  • Walter, Michael G.; Warren, Emily L.; McKone, James R.
  • Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
  • DOI: 10.1021/cr1002326

Photoelectrochemical cells
journal, November 2001


From Water Oxidation to Reduction: Homologous Ni-Co Based Nanowires as Complementary Water Splitting Electrocatalysts
journal, February 2015

  • Peng, Zheng; Jia, Dingsi; Al-Enizi, Abdullah M.
  • Advanced Energy Materials, Vol. 5, Issue 9
  • DOI: 10.1002/aenm.201402031

Synthesis and Characterization of High-Photoactivity Electrodeposited Cu 2 O Solar Absorber by Photoelectrochemistry and Ultrafast Spectroscopy
journal, March 2012

  • Paracchino, Adriana; Brauer, Jan Cornelius; Moser, Jacques-Edouard
  • The Journal of Physical Chemistry C, Vol. 116, Issue 13
  • DOI: 10.1021/jp301176y

Cu2O: a catalyst for the photochemical decomposition of water?
journal, January 1999

  • de Jongh, Petra E.; Vanmaekelbergh, Daniel; Kelly, John J.
  • Chemical Communications, Issue 12
  • DOI: 10.1039/a901232j

820 mV open-circuit voltages from Cu2O/CH3CN junctions
journal, January 2011

  • Xiang, Chengxiang; Kimball, Gregory M.; Grimm, Ronald L.
  • Energy & Environmental Science, Vol. 4, Issue 4
  • DOI: 10.1039/c0ee00554a

A Bismuth Vanadate–Cuprous Oxide Tandem Cell for Overall Solar Water Splitting
journal, April 2014

  • Bornoz, Pauline; Abdi, Fatwa F.; Tilley, S. David
  • The Journal of Physical Chemistry C, Vol. 118, Issue 30
  • DOI: 10.1021/jp500441h

Highly active oxide photocathode for photoelectrochemical water reduction
journal, May 2011

  • Paracchino, Adriana; Laporte, Vincent; Sivula, Kevin
  • Nature Materials, Vol. 10, Issue 6
  • DOI: 10.1038/nmat3017

Ultrathin films on copper(i) oxide water splitting photocathodes: a study on performance and stability
journal, January 2012

  • Paracchino, Adriana; Mathews, Nripan; Hisatomi, Takashi
  • Energy & Environmental Science, Vol. 5, Issue 9
  • DOI: 10.1039/c2ee22063f

Ruthenium Oxide Hydrogen Evolution Catalysis on Composite Cuprous Oxide Water-Splitting Photocathodes
journal, July 2013

  • Tilley, S. David; Schreier, Marcel; Azevedo, João
  • Advanced Functional Materials, Vol. 24, Issue 3
  • DOI: 10.1002/adfm.201301106

Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst
journal, January 2014

  • Morales-Guio, Carlos G.; Tilley, S. David; Vrubel, Heron
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4059

On the stability enhancement of cuprous oxide water splitting photocathodes by low temperature steam annealing
journal, January 2014

  • Azevedo, J.; Steier, L.; Dias, P.
  • Energy Environ. Sci., Vol. 7, Issue 12
  • DOI: 10.1039/C4EE02160F

Cu2O|NiOx nanocomposite as an inexpensive photocathode in photoelectrochemical water splitting
journal, January 2012

  • Lin, Chia-Yu; Lai, Yi-Hsuan; Mersch, Dirk
  • Chemical Science, Vol. 3, Issue 12
  • DOI: 10.1039/c2sc20874a

Cu 2 O/CuO photocathode with improved stability for photoelectrochemical water reduction
journal, January 2015

  • Han, Jingfeng; Zong, Xu; Zhou, Xin
  • RSC Advances, Vol. 5, Issue 14
  • DOI: 10.1039/C4RA13896A

Forming Buried Junctions to Enhance the Photovoltage Generated by Cuprous Oxide in Aqueous Solutions
journal, October 2014

  • Dai, Pengcheng; Li, Wei; Xie, Jin
  • Angewandte Chemie International Edition, Vol. 53, Issue 49
  • DOI: 10.1002/anie.201408375

Forming Buried Junctions to Enhance the Photovoltage Generated by Cuprous Oxide in Aqueous Solutions
journal, October 2014


Carbon-Layer-Protected Cuprous Oxide Nanowire Arrays for Efficient Water Reduction
journal, January 2013

  • Zhang, Zhonghai; Dua, Rubal; Zhang, Lianbin
  • ACS Nano, Vol. 7, Issue 2
  • DOI: 10.1021/nn3057092

Water photolysis with a cross-linked titanium dioxidenanowire anode
journal, January 2011

  • Liu, Mingzhao; de Leon Snapp, Nathalie; Park, Hongkun
  • Chem. Sci., Vol. 2, Issue 1
  • DOI: 10.1039/C0SC00321B

Back-illuminated Si photocathode: a combined experimental and theoretical study for photocatalytic hydrogen evolution
journal, January 2015

  • Bae, Dowon; Pedersen, Thomas; Seger, Brian
  • Energy & Environmental Science, Vol. 8, Issue 2
  • DOI: 10.1039/C4EE03723E

Plasmonics for extreme light concentration and manipulation
journal, February 2010

  • Schuller, Jon A.; Barnard, Edward S.; Cai, Wenshan
  • Nature Materials, Vol. 9, Issue 3
  • DOI: 10.1038/nmat2630

Antennas for light
journal, February 2011


Surface plasmon subwavelength optics
journal, August 2003

  • Barnes, William L.; Dereux, Alain; Ebbesen, Thomas W.
  • Nature, Vol. 424, Issue 6950, p. 824-830
  • DOI: 10.1038/nature01937

Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
journal, November 2011

  • Linic, Suljo; Christopher, Phillip; Ingram, David B.
  • Nature Materials, Vol. 10, Issue 12
  • DOI: 10.1038/nmat3151

Plasmonic solar water splitting
journal, January 2012

  • Warren, Scott C.; Thimsen, Elijah
  • Energy Environ. Sci., Vol. 5, Issue 1
  • DOI: 10.1039/C1EE02875H

A Review of Surface Plasmon Resonance-Enhanced Photocatalysis
journal, October 2012

  • Hou, Wenbo; Cronin, Stephen B.
  • Advanced Functional Materials, Vol. 23, Issue 13, p. 1612-1619
  • DOI: 10.1002/adfm.201202148

Predictive Model for the Design of Plasmonic Metal/Semiconductor Composite Photocatalysts
journal, September 2011

  • Ingram, David B.; Christopher, Phillip; Bauer, Jonathan L.
  • ACS Catalysis, Vol. 1, Issue 10
  • DOI: 10.1021/cs200320h

Metal/Semiconductor Hybrid Nanostructures for Plasmon-Enhanced Applications
journal, April 2014


Photocatalytic Activity Enhanced by Plasmonic Resonant Energy Transfer from Metal to Semiconductor
journal, August 2012

  • Cushing, Scott K.; Li, Jiangtian; Meng, Fanke
  • Journal of the American Chemical Society, Vol. 134, Issue 36
  • DOI: 10.1021/ja305603t

Plasmon Resonant Enhancement of Photocatalytic Water Splitting Under Visible Illumination
journal, March 2011

  • Liu, Zuwei; Hou, Wenbo; Pavaskar, Prathamesh
  • Nano Letters, Vol. 11, Issue 3
  • DOI: 10.1021/nl104005n

Plasmon Enhanced Solar-to-Fuel Energy Conversion
journal, August 2011

  • Thomann, Isabell; Pinaud, Blaise A.; Chen, Zhebo
  • Nano Letters, Vol. 11, Issue 8
  • DOI: 10.1021/nl201908s

Plasmon-Enhanced Photocatalytic Activity of Iron Oxide on Gold Nanopillars
journal, December 2011

  • Gao, Hanwei; Liu, Chong; Jeong, Hoon Eui
  • ACS Nano, Vol. 6, Issue 1
  • DOI: 10.1021/nn203457a

Influence of Plasmonic Au Nanoparticles on the Photoactivity of Fe2O3 Electrodes for Water Splitting
journal, January 2011

  • Thimsen, Elijah; Le Formal, Florian; Grätzel, Michael
  • Nano Letters, Vol. 11, Issue 1, p. 35-43
  • DOI: 10.1021/nl1022354

Designing p-Type Semiconductor-Metal Hybrid Structures for Improved Photocatalysis
journal, April 2014


Ultrathin CdSe in Plasmonic Nanogaps for Enhanced Photocatalytic Water Splitting
journal, March 2015

  • Sigle, Daniel O.; Zhang, Liwu; Ithurria, Sandrine
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 7
  • DOI: 10.1021/acs.jpclett.5b00279

Plasmonic Enhancement in BiVO 4 Photonic Crystals for Efficient Water Splitting
journal, June 2014


Plasmon-enhanced water splitting on TiO 2 -passivated GaP photocatalysts
journal, January 2014

  • Qiu, Jing; Zeng, Guangtong; Pavaskar, Prathamesh
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 7
  • DOI: 10.1039/C3CP54674H

Plasmon-Enhanced Photoelectrochemical Water Splitting with Size-Controllable Gold Nanodot Arrays
journal, October 2014

  • Kim, Hyung Ju; Lee, Sang Ho; Upadhye, Aniruddha A.
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn504484u

Plasmon Inducing Effects for Enhanced Photoelectrochemical Water Splitting: X-ray Absorption Approach to Electronic Structures
journal, July 2012

  • Chen, Hao Ming; Chen, Chih Kai; Chen, Chih-Jung
  • ACS Nano, Vol. 6, Issue 8
  • DOI: 10.1021/nn3024877

Plasmon-induced photonic and energy-transfer enhancement of solar water splitting by a hematite nanorod array
journal, October 2013

  • Li, Jiangtian; Cushing, Scott K.; Zheng, Peng
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3651

Gold Nanorod-Enhanced Light Absorption and Photoelectrochemical Performance of α-Fe 2 O 3 Thin-Film Electrode for Solar Water Splitting
journal, October 2013

  • Wang, Jue; Pan, Shanlin; Chen, Mingyang
  • The Journal of Physical Chemistry C, Vol. 117, Issue 42
  • DOI: 10.1021/jp406733k

Efficient Ag@AgCl Cubic Cage Photocatalysts Profit from Ultrafast Plasmon-Induced Electron Transfer Processes
journal, January 2013

  • Tang, Yuxin; Jiang, Zhelong; Xing, Guichuan
  • Advanced Functional Materials, Vol. 23, Issue 23
  • DOI: 10.1002/adfm.201203379

Super-Resolution Mapping of Reactive Sites on Titania-Based Nanoparticles with Water-Soluble Fluorogenic Probes
journal, December 2012

  • Tachikawa, Takashi; Yonezawa, Tomoyuki; Majima, Tetsuro
  • ACS Nano, Vol. 7, Issue 1
  • DOI: 10.1021/nn303964v

Surface Plasmon Resonance Enhanced Real-Time Photoelectrochemical Protein Sensing by Gold Nanoparticle-Decorated TiO 2 Nanowires
journal, June 2014

  • Da, Peimei; Li, Wenjie; Lin, Xuan
  • Analytical Chemistry, Vol. 86, Issue 13
  • DOI: 10.1021/ac501406x

Plasmonics for improved photovoltaic devices
journal, February 2010

  • Atwater, Harry A.; Polman, Albert
  • Nature Materials, Vol. 9, Issue 3, p. 205-213
  • DOI: 10.1038/nmat2629

Plasmonic Dye-Sensitized Solar Cells Using Core−Shell Metal−Insulator Nanoparticles
journal, February 2011

  • Brown, Michael D.; Suteewong, Teeraporn; Kumar, R. Sai Santosh
  • Nano Letters, Vol. 11, Issue 2
  • DOI: 10.1021/nl1031106

Highly Efficient Plasmon-Enhanced Dye-Sensitized Solar Cells through Metal@Oxide Core–Shell Nanostructure
journal, August 2011

  • Qi, Jifa; Dang, Xiangnan; Hammond, Paula T.
  • ACS Nano, Vol. 5, Issue 9
  • DOI: 10.1021/nn201808g

Tunable Localized Surface Plasmon-Enabled Broadband Light-Harvesting Enhancement for High-Efficiency Panchromatic Dye-Sensitized Solar Cells
journal, January 2013

  • Dang, Xiangnan; Qi, Jifa; Klug, Matthew T.
  • Nano Letters, Vol. 13, Issue 2
  • DOI: 10.1021/nl3043823

Extreme Light Absorption by Multiple Plasmonic Layers on Upgraded Metallurgical Grade Silicon Solar Cells
journal, March 2014

  • Lee, Duck Hyun; Kwon, Jae Young; Maldonado, Stephen
  • Nano Letters, Vol. 14, Issue 4
  • DOI: 10.1021/nl4048064

Photocurrent Enhancement of HgTe Quantum Dot Photodiodes by Plasmonic Gold Nanorod Structures
journal, July 2014

  • Chen, Mengyu; Shao, Lei; Kershaw, Stephen V.
  • ACS Nano, Vol. 8, Issue 8
  • DOI: 10.1021/nn502510u

Optical Studies of Dynamics in Noble Metal Nanostructures
journal, June 2011


Photochemistry on Metal Nanoparticles
journal, October 2006

  • Watanabe, Kazuo; Menzel, Dietrich; Nilius, Niklas
  • Chemical Reviews, Vol. 106, Issue 10
  • DOI: 10.1021/cr050167g

Spectral Properties and Relaxation Dynamics of Surface Plasmon Electronic Oscillations in Gold and Silver Nanodots and Nanorods
journal, October 1999

  • Link, Stephan; El-Sayed, Mostafa A.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 40
  • DOI: 10.1021/jp9917648

Facile and mild solution synthesis of Cu 2 O nanowires and nanotubes driven by screw dislocations
journal, January 2012

  • Hacialioglu, Salih; Meng, Fei; Jin, Song
  • Chem. Commun., Vol. 48, Issue 8
  • DOI: 10.1039/C2CC16333K

Seeding Growth for Size Control of 5−40 nm Diameter Gold Nanoparticles
journal, October 2001

  • Jana, Nikhil R.; Gearheart, Latha; Murphy, Catherine J.
  • Langmuir, Vol. 17, Issue 22
  • DOI: 10.1021/la0104323

Facile synthesis of anisotropic Au@SiO2 core–shell nanostructures
journal, January 2012

  • DuChene, Joseph S.; Almeida, Renan P.; Wei, W. David
  • Dalton Transactions, Vol. 41, Issue 26
  • DOI: 10.1039/c2dt30409k

The Effect of Silica Coating on the Optical Response of Sub-micrometer Gold Spheres
journal, September 2007

  • Rodríguez-Fernández, Jessica; Pastoriza-Santos, Isabel; Pérez-Juste, Jorge
  • The Journal of Physical Chemistry C, Vol. 111, Issue 36
  • DOI: 10.1021/jp073853n

Surface Plasmonic Effects of Metallic Nanoparticles on the Performance of Polymer Bulk Heterojunction Solar Cells
journal, January 2011

  • Wu, Jyh-Lih; Chen, Fang-Chung; Hsiao, Yu-Sheng
  • ACS Nano, Vol. 5, Issue 2
  • DOI: 10.1021/nn102295p

Enhancement of Perovskite-Based Solar Cells Employing Core–Shell Metal Nanoparticles
journal, August 2013

  • Zhang, Wei; Saliba, Michael; Stranks, Samuel D.
  • Nano Letters, Vol. 13, Issue 9
  • DOI: 10.1021/nl4024287

Plasmon-Enhanced Photoluminescence and Photocatalytic Activities of Visible-Light-Responsive ZnS-AgInS 2 Solid Solution Nanoparticles
journal, November 2012

  • Takahashi, Takuya; Kudo, Akihiko; Kuwabata, Susumu
  • The Journal of Physical Chemistry C, Vol. 117, Issue 6
  • DOI: 10.1021/jp3064257

Facile synthesis of large area porous Cu2O as super hydrophobic yellow-red phosphors
journal, January 2012

  • Shinde, Satish Laxman; Nanda, Karuna Kar
  • RSC Advances, Vol. 2, Issue 9
  • DOI: 10.1039/c2ra20066j

Influence of Excitation Wavelength (UV or Visible Light) on the Photocatalytic Activity of Titania Containing Gold Nanoparticles for the Generation of Hydrogen or Oxygen from Water
journal, January 2011

  • Gomes Silva, Cláudia; Juárez, Raquel; Marino, Tiziana
  • Journal of the American Chemical Society, Vol. 133, Issue 3
  • DOI: 10.1021/ja1086358

Plasmonic Photoanodes for Solar Water Splitting with Visible Light
journal, January 2012

  • Lee, Joun; Mubeen, Syed; Ji, Xiulei
  • Nano Letters, Vol. 12, Issue 9
  • DOI: 10.1021/nl302796f

An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
journal, February 2013

  • Mubeen, Syed; Lee, Joun; Singh, Nirala
  • Nature Nanotechnology, Vol. 8, Issue 4
  • DOI: 10.1038/nnano.2013.18

Engineering Interfacial Photo-Induced Charge Transfer Based on Nanobamboo Array Architecture for Efficient Solar-to-Chemical Energy Conversion
journal, February 2015

  • Wang, Xiaotian; Liow, Chihao; Bisht, Ankit
  • Advanced Materials, Vol. 27, Issue 13
  • DOI: 10.1002/adma.201405674

Prolonged Hot Electron Dynamics in Plasmonic-Metal/Semiconductor Heterostructures with Implications for Solar Photocatalysis
journal, June 2014

  • DuChene, Joseph S.; Sweeny, Brendan C.; Johnston-Peck, Aaron C.
  • Angewandte Chemie International Edition, Vol. 53, Issue 30
  • DOI: 10.1002/anie.201404259

Prolonged Hot Electron Dynamics in Plasmonic-Metal/Semiconductor Heterostructures with Implications for Solar Photocatalysis
journal, June 2014

  • DuChene, Joseph S.; Sweeny, Brendan C.; Johnston-Peck, Aaron C.
  • Angewandte Chemie, Vol. 126, Issue 30
  • DOI: 10.1002/ange.201404259

Au Nanostructure-Decorated TiO 2 Nanowires Exhibiting Photoactivity Across Entire UV-visible Region for Photoelectrochemical Water Splitting
journal, July 2013

  • Pu, Ying-Chih; Wang, Gongming; Chang, Kao-Der
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl4018385

Surface Plasmon-Driven Water Reduction: Gold Nanoparticle Size Matters
journal, July 2014

  • Qian, Kun; Sweeny, Brendan C.; Johnston-Peck, Aaron C.
  • Journal of the American Chemical Society, Vol. 136, Issue 28
  • DOI: 10.1021/ja504097v

Plasmon-Assisted Water Splitting Using Two Sides of the Same SrTiO 3 Single-Crystal Substrate: Conversion of Visible Light to Chemical Energy
journal, July 2014

  • Zhong, Yuqing; Ueno, Kosei; Mori, Yuko
  • Angewandte Chemie International Edition, Vol. 53, Issue 39
  • DOI: 10.1002/anie.201404926

Plasmon-induced hot carrier science and technology
journal, January 2015

  • Brongersma, Mark L.; Halas, Naomi J.; Nordlander, Peter
  • Nature Nanotechnology, Vol. 10, Issue 1
  • DOI: 10.1038/nnano.2014.311

Plasmon-Induced Hot Carriers in Metallic Nanoparticles
journal, July 2014

  • Manjavacas, Alejandro; Liu, Jun G.; Kulkarni, Vikram
  • ACS Nano, Vol. 8, Issue 8
  • DOI: 10.1021/nn502445f

Theoretical predictions for hot-carrier generation from surface plasmon decay
journal, December 2014

  • Sundararaman, Ravishankar; Narang, Prineha; Jermyn, Adam S.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6788

Near-Infrared Plasmon-Assisted Water Oxidation
journal, April 2012

  • Nishijima, Yoshiaki; Ueno, Kosei; Kotake, Yuki
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 10
  • DOI: 10.1021/jz3003316

Plasmonic Hot Electron Induced Structural Phase Transition in a MoS 2 Monolayer
journal, August 2014


(Gold Core)@(Ceria Shell) Nanostructures for Plasmon-Enhanced Catalytic Reactions under Visible Light
journal, July 2014


Tunable Oxygen Activation for Catalytic Organic Oxidation: Schottky Junction versus Plasmonic Effects
journal, February 2014

  • Long, Ran; Mao, Keke; Gong, Ming
  • Angewandte Chemie International Edition, Vol. 53, Issue 12
  • DOI: 10.1002/anie.201309660

Tunable Oxygen Activation for Catalytic Organic Oxidation: Schottky Junction versus Plasmonic Effects
journal, February 2014


Au/TiO 2 Superstructure-Based Plasmonic Photocatalysts Exhibiting Efficient Charge Separation and Unprecedented Activity
journal, December 2013

  • Bian, Zhenfeng; Tachikawa, Takashi; Zhang, Peng
  • Journal of the American Chemical Society, Vol. 136, Issue 1
  • DOI: 10.1021/ja410994f

Steering charge kinetics in photocatalysis: intersection of materials syntheses, characterization techniques and theoretical simulations
journal, January 2015

  • Bai, Song; Jiang, Jun; Zhang, Qun
  • Chemical Society Reviews, Vol. 44, Issue 10
  • DOI: 10.1039/C5CS00064E

Surface Plasmon-Mediated Photothermal Chemistry
journal, July 2014

  • Qiu, Jingjing; Wei, Wei David
  • The Journal of Physical Chemistry C, Vol. 118, Issue 36
  • DOI: 10.1021/jp5042553

Understanding the Photothermal Conversion Efficiency of Gold Nanocrystals
journal, September 2010


Plasmonic Harvesting of Light Energy for Suzuki Coupling Reactions
journal, April 2013

  • Wang, Feng; Li, Chuanhao; Chen, Huanjun
  • Journal of the American Chemical Society, Vol. 135, Issue 15
  • DOI: 10.1021/ja310501y

Distance Dependence of Plasmon-Enhanced Photocurrent in Dye-Sensitized Solar Cells
journal, June 2009

  • Standridge, Stacey D.; Schatz, George C.; Hupp, Joseph T.
  • Journal of the American Chemical Society, Vol. 131, Issue 24
  • DOI: 10.1021/ja9022072

Field Effects in Plasmonic Photocatalyst by Precise SiO 2 Thickness Control Using Atomic Layer Deposition
journal, February 2011

  • Kumar, Manippady Krishna; Krishnamoorthy, Sivashankar; Tan, Lee Kheng
  • ACS Catalysis, Vol. 1, Issue 4
  • DOI: 10.1021/cs100117v

Distance and Wavelength Dependent Quenching of Molecular Fluorescence by Au@SiO 2 Core–Shell Nanoparticles
journal, June 2013

  • Reineck, Philipp; Gómez, Daniel; Ng, Soon Hock
  • ACS Nano, Vol. 7, Issue 8
  • DOI: 10.1021/nn401775e

Distance and Plasmon Wavelength Dependent Fluorescence of Molecules Bound to Silica-Coated Gold Nanorods
journal, July 2014

  • Abadeer, Nardine S.; Brennan, Marshall R.; Wilson, William L.
  • ACS Nano, Vol. 8, Issue 8
  • DOI: 10.1021/nn502887j

Distance-Engineered Plasmon-Enhanced Light Harvesting in CdSe Quantum Dots
journal, September 2013

  • Jin, Shengye; DeMarco, Erica; Pellin, Michael J.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 20
  • DOI: 10.1021/jz401801v

Scattering and Absorption of Light by Nonspherical Dielectric Grains
journal, December 1973

  • Purcell, Edward M.; Pennypacker, Carlton R.
  • The Astrophysical Journal, Vol. 186
  • DOI: 10.1086/152538

The discrete-dipole approximation and its application to interstellar graphite grains
journal, October 1988

  • Draine, B. T.
  • The Astrophysical Journal, Vol. 333
  • DOI: 10.1086/166795

    Works referencing / citing this record:

    Plasmon‐Enhanced Photoelectrochemical Water Splitting for Efficient Renewable Energy Storage
    journal, December 2018

    • Mascaretti, Luca; Dutta, Aveek; Kment, Štěpán
    • Advanced Materials, Vol. 31, Issue 31
    • DOI: 10.1002/adma.201805513

    Multi-interfacial plasmon coupling in multigap (Au/AgAu)@CdS core–shell hybrids for efficient photocatalytic hydrogen generation
    journal, January 2020

    • Ma, Liang; Chen, You-Long; Yang, Da-Jie
    • Nanoscale, Vol. 12, Issue 7
    • DOI: 10.1039/c9nr09696e