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Title: Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation

Abstract

Controlling the size, composition, and structure of bimetallic nanoparticles is of particular interest in the field of electrocatalysts for fuel cells. In the present work, structurally ordered nanoparticles with intermetallic phases of Pt3Zn and PtZn have been successfully synthesized via an impregnation reduction method, followed by post heat-treatment. The Pt3Zn and PtZn ordered intermetallic nanoparticles are well dispersed on a carbon support with ultrasmall mean particle sizes of ~5 nm and ~3 nm in diameter, respectively, which are credited to the evaporation of the zinc element at high temperature. These catalysts are less susceptible to CO poisoning relative to Pt/C and exhibited enhanced catalytic activity and stability toward formic acid electrooxidation. The mass activities of the as-prepared catalysts were approximately 2 to 3 times that of commercial Pt at 0.5 V (vs. RHE). As a result, this facile synthetic strategy is scalable for mass production of catalytic materials.

Authors:
 [1];  [1];  [1];  [1];  [2];  [2];  [3];  [1]
  1. Huazhong Univ. of Science and Technology, Wuhan (China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1222622
Report Number(s):
BNL-108453-2015-JA
Journal ID: ISSN 2050-7488; JMCAET; KC0403020
Grant/Contract Number:  
21306060
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; formic acid electrooxidation; fuel cell; Center for Functional Nanomaterials

Citation Formats

Zhu, Jing, Zheng, Xin, Wang, Jie, Wu, Zexing, Han, Lili, Lin, Ruoqian, Xin, Huolin L., and Wang, Deli. Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation. United States: N. p., 2015. Web. doi:10.1039/C5TA05699C.
Zhu, Jing, Zheng, Xin, Wang, Jie, Wu, Zexing, Han, Lili, Lin, Ruoqian, Xin, Huolin L., & Wang, Deli. Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation. United States. doi:10.1039/C5TA05699C.
Zhu, Jing, Zheng, Xin, Wang, Jie, Wu, Zexing, Han, Lili, Lin, Ruoqian, Xin, Huolin L., and Wang, Deli. Tue . "Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation". United States. doi:10.1039/C5TA05699C. https://www.osti.gov/servlets/purl/1222622.
@article{osti_1222622,
title = {Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation},
author = {Zhu, Jing and Zheng, Xin and Wang, Jie and Wu, Zexing and Han, Lili and Lin, Ruoqian and Xin, Huolin L. and Wang, Deli},
abstractNote = {Controlling the size, composition, and structure of bimetallic nanoparticles is of particular interest in the field of electrocatalysts for fuel cells. In the present work, structurally ordered nanoparticles with intermetallic phases of Pt3Zn and PtZn have been successfully synthesized via an impregnation reduction method, followed by post heat-treatment. The Pt3Zn and PtZn ordered intermetallic nanoparticles are well dispersed on a carbon support with ultrasmall mean particle sizes of ~5 nm and ~3 nm in diameter, respectively, which are credited to the evaporation of the zinc element at high temperature. These catalysts are less susceptible to CO poisoning relative to Pt/C and exhibited enhanced catalytic activity and stability toward formic acid electrooxidation. The mass activities of the as-prepared catalysts were approximately 2 to 3 times that of commercial Pt at 0.5 V (vs. RHE). As a result, this facile synthetic strategy is scalable for mass production of catalytic materials.},
doi = {10.1039/C5TA05699C},
journal = {Journal of Materials Chemistry. A},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {9}
}

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Cited by: 4 works
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