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Title: Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation

Abstract

Controlling the size, composition, and structure of bimetallic nanoparticles is of particular interest in the field of electrocatalysts for fuel cells. In the present work, structurally ordered nanoparticles with intermetallic phases of Pt3Zn and PtZn have been successfully synthesized via an impregnation reduction method, followed by post heat-treatment. The Pt3Zn and PtZn ordered intermetallic nanoparticles are well dispersed on a carbon support with ultrasmall mean particle sizes of ~5 nm and ~3 nm in diameter, respectively, which are credited to the evaporation of the zinc element at high temperature. These catalysts are less susceptible to CO poisoning relative to Pt/C and exhibited enhanced catalytic activity and stability toward formic acid electrooxidation. The mass activities of the as-prepared catalysts were approximately 2 to 3 times that of commercial Pt at 0.5 V (vs. RHE). As a result, this facile synthetic strategy is scalable for mass production of catalytic materials.

Authors:
 [1];  [1];  [1];  [1];  [2];  [2];  [3];  [1]
  1. Huazhong Univ. of Science and Technology, Wuhan (China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1222622
Report Number(s):
BNL-108453-2015-JA
Journal ID: ISSN 2050-7488; JMCAET; KC0403020
Grant/Contract Number:  
21306060
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; formic acid electrooxidation; fuel cell; Center for Functional Nanomaterials

Citation Formats

Zhu, Jing, Zheng, Xin, Wang, Jie, Wu, Zexing, Han, Lili, Lin, Ruoqian, Xin, Huolin L., and Wang, Deli. Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation. United States: N. p., 2015. Web. https://doi.org/10.1039/C5TA05699C.
Zhu, Jing, Zheng, Xin, Wang, Jie, Wu, Zexing, Han, Lili, Lin, Ruoqian, Xin, Huolin L., & Wang, Deli. Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation. United States. https://doi.org/10.1039/C5TA05699C
Zhu, Jing, Zheng, Xin, Wang, Jie, Wu, Zexing, Han, Lili, Lin, Ruoqian, Xin, Huolin L., and Wang, Deli. Tue . "Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation". United States. https://doi.org/10.1039/C5TA05699C. https://www.osti.gov/servlets/purl/1222622.
@article{osti_1222622,
title = {Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation},
author = {Zhu, Jing and Zheng, Xin and Wang, Jie and Wu, Zexing and Han, Lili and Lin, Ruoqian and Xin, Huolin L. and Wang, Deli},
abstractNote = {Controlling the size, composition, and structure of bimetallic nanoparticles is of particular interest in the field of electrocatalysts for fuel cells. In the present work, structurally ordered nanoparticles with intermetallic phases of Pt3Zn and PtZn have been successfully synthesized via an impregnation reduction method, followed by post heat-treatment. The Pt3Zn and PtZn ordered intermetallic nanoparticles are well dispersed on a carbon support with ultrasmall mean particle sizes of ~5 nm and ~3 nm in diameter, respectively, which are credited to the evaporation of the zinc element at high temperature. These catalysts are less susceptible to CO poisoning relative to Pt/C and exhibited enhanced catalytic activity and stability toward formic acid electrooxidation. The mass activities of the as-prepared catalysts were approximately 2 to 3 times that of commercial Pt at 0.5 V (vs. RHE). As a result, this facile synthetic strategy is scalable for mass production of catalytic materials.},
doi = {10.1039/C5TA05699C},
journal = {Journal of Materials Chemistry. A},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {9}
}

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Cited by: 4 works
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Works referenced in this record:

Electrochemical investigation of formic acid electro-oxidation and its crossover through a Nafion® membrane
journal, January 2004


Crossover of formic acid through Nafion® membranes
journal, May 2003


Fuel crossover in direct formic acid fuel cells
journal, May 2007


Graphene-Supported Pt–Au Alloy Nanoparticles: A Highly Efficient Anode for Direct Formic Acid Fuel Cells
journal, October 2011

  • Venkateswara Rao, Chitturi; Cabrera, Carlos R.; Ishikawa, Yasuyuki
  • The Journal of Physical Chemistry C, Vol. 115, Issue 44
  • DOI: 10.1021/jp202561n

Recent advances in catalysts for direct methanol fuel cells
journal, January 2011

  • Zhao, Xiao; Yin, Min; Ma, Liang
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01307f

Recent advances in direct formic acid fuel cells (DFAFC)
journal, July 2008


Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst
journal, August 2005

  • Lović, J. D.; Tripković, A. V.; Gojković, S. Lj.
  • Journal of Electroanalytical Chemistry, Vol. 581, Issue 2, p. 294-302
  • DOI: 10.1016/j.jelechem.2005.05.002

Mechanism of the Electrocatalytic Oxidation of Formic Acid on Metals
journal, March 2012

  • Cuesta, Angel; Cabello, Gema; Osawa, Masatoshi
  • ACS Catalysis, Vol. 2, Issue 5
  • DOI: 10.1021/cs200661z

Comparisons of formic acid oxidation at supported Pt catalyst and at low-index Pt single crystal electrodes in sulfuric acid solution
journal, January 2003

  • Tripkovic, Amalija; Popovic, Ksenija; Lovic, Jelena
  • Journal of the Serbian Chemical Society, Vol. 68, Issue 11
  • DOI: 10.2298/JSC0311849T

Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
journal, March 2004

  • Casado-Rivera, Emerilis; Volpe, David J.; Alden, Laif
  • Journal of the American Chemical Society, Vol. 126, Issue 12
  • DOI: 10.1021/ja038497a

Influence of Bi Modification of Pt Anode Catalyst in Direct Formic Acid Fuel Cells
journal, April 2006

  • Kang, Sungjin; Lee, Jaeyoung; Lee, Jae Kwang
  • The Journal of Physical Chemistry B, Vol. 110, Issue 14
  • DOI: 10.1021/jp056753v

Carbon supported PtBi catalysts for direct formic acid fuel cells
journal, April 2011


Formic Acid Oxidation on Pure and Bi-Modified Pt(111):  Temperature Effects
journal, October 2000

  • Schmidt, T. J.; Behm, R. J.; Grgur, B. N.
  • Langmuir, Vol. 16, Issue 21
  • DOI: 10.1021/la000339z

The electro-oxidation of formic acid on Pt–Pd single crystal bimetallic surfaces
journal, January 2003

  • Arenz, M.; Stamenkovic, V.; Schmidt, T. J.
  • Phys. Chem. Chem. Phys., Vol. 5, Issue 19
  • DOI: 10.1039/B306307K

Carbon nanotubes supported PtPd hollow nanospheres for formic acid electrooxidation
journal, January 2009


A high dispersed Pt0.35Pd0.35Co0.30/C as superior catalyst for methanol and formic acid electro-oxidation
journal, June 2014


Shape- and Composition-Sensitive Activity of Pt and PtAu Catalysts for Formic Acid Electrooxidation
journal, August 2012

  • Kim, Youngmin; Kim, Hyung Ju; Kim, Yong Seok
  • The Journal of Physical Chemistry C, Vol. 116, Issue 34
  • DOI: 10.1021/jp3054795

Electro-oxidation of methanol and formic acid on PtRu and PtAu for direct liquid fuel cells
journal, December 2006


Highly Stable Pt–Au@Ru/C Catalyst Nanoparticles for Methanol Electro-oxidation
journal, January 2013

  • He, Qinggang; Shyam, Badri; Nishijima, Masahiko
  • The Journal of Physical Chemistry C, Vol. 117, Issue 3
  • DOI: 10.1021/jp308133q

Synthesis of Intermetallic PtZn Nanoparticles by Reaction of Pt Nanoparticles with Zn Vapor and Their Application as Fuel Cell Catalysts
journal, July 2009

  • Miura, Akira; Wang, Hongsen; Leonard, Brian M.
  • Chemistry of Materials, Vol. 21, Issue 13
  • DOI: 10.1021/cm900048e

Synthesis, Shape Control, and Methanol Electro-oxidation Properties of Pt–Zn Alloy and Pt 3 Zn Intermetallic Nanocrystals
journal, May 2012

  • Kang, Yijin; Pyo, Jun Beom; Ye, Xingchen
  • ACS Nano, Vol. 6, Issue 6
  • DOI: 10.1021/nn301583g

Microwave-assisted polyol synthesis of Pt–Zn electrocatalysts on carbon nanotube electrodes for methanol oxidation
journal, February 2011


Enhanced electrocatalytic activity and stability of platinum, gold, and nickel oxide nanoparticles-based ternary catalyst for formic acid electro-oxidation
journal, August 2014


Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012

  • Wang, Deli; Xin, Huolin L.; Hovden, Robert
  • Nature Materials, Vol. 12, Issue 1, p. 81-87
  • DOI: 10.1038/nmat3458

Tuning Oxygen Reduction Reaction Activity via Controllable Dealloying A Model Study of Ordered Cu3Pt/C Intermetallic Nanocatalysts
journal, September 2012

  • Wang, Deli; Yu, Yingchao; Xin, Huolin L.
  • Nano Letters, Vol. 12, Issue 10, p. 5230-5238
  • DOI: 10.1021/nl302404g

Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles
journal, March 2012

  • Zhang, Sen; Guo, Shaojun; Zhu, Huiyuan
  • Journal of the American Chemical Society, Vol. 134, Issue 11
  • DOI: 10.1021/ja300708j

New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
journal, March 2015


Structurally Ordered FePt Nanoparticles and Their Enhanced Catalysis for Oxygen Reduction Reaction
journal, April 2010

  • Kim, Jaemin; Lee, Youngmin; Sun, Shouheng
  • Journal of the American Chemical Society, Vol. 132, Issue 14
  • DOI: 10.1021/ja1009629

Tuning Nanoparticle Structure and Surface Strain for Catalysis Optimization
journal, May 2014

  • Zhang, Sen; Zhang, Xu; Jiang, Guangming
  • Journal of the American Chemical Society, Vol. 136, Issue 21
  • DOI: 10.1021/ja5030172

A Surfactant-Free Strategy for Synthesizing and Processing Intermetallic Platinum-Based Nanoparticle Catalysts
journal, October 2012

  • Chen, Hao; Wang, Deli; Yu, Yingchao
  • Journal of the American Chemical Society, Vol. 134, Issue 44
  • DOI: 10.1021/ja308674b

Strained Lattice with Persistent Atomic Order in Pt 3 Fe 2 Intermetallic Core–Shell Nanocatalysts
journal, June 2013

  • Prabhudev, Sagar; Bugnet, Matthieu; Bock, Christina
  • ACS Nano, Vol. 7, Issue 7
  • DOI: 10.1021/nn4019009

Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes
journal, February 2010

  • Ji, Xiulei; Lee, Kyu Tae; Holden, Reanne
  • Nature Chemistry, Vol. 2, Issue 4, p. 286-293
  • DOI: 10.1038/nchem.553

The Impact of Geometric and Surface Electronic Properties of Pt-Catalysts on the Particle Size Effect in Electrocatalysis
journal, August 2005

  • Mayrhofer, K. J. J.; Blizanac, B. B.; Arenz, M.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 30
  • DOI: 10.1021/jp051735z

The Effect of the Particle Size on the Kinetics of CO Electrooxidation on High Surface Area Pt Catalysts
journal, May 2005

  • Arenz, Matthias; Mayrhofer, Karl J. J.; Stamenkovic, Vojislav
  • Journal of the American Chemical Society, Vol. 127, Issue 18, p. 6819-6829
  • DOI: 10.1021/ja043602h

Electrocatalysis on Platinum Nanoparticles: Particle Size Effect on Oxygen Reduction Reaction Activity
journal, September 2011

  • Shao, Minhua; Peles, Amra; Shoemaker, Krista
  • Nano Letters, Vol. 11, Issue 9
  • DOI: 10.1021/nl2017459

Synthesis of Structurally Ordered Pt 3 Ti and Pt 3 V Nanoparticles as Methanol Oxidation Catalysts
journal, July 2014

  • Cui, Zhiming; Chen, Hao; Zhao, Mengtian
  • Journal of the American Chemical Society, Vol. 136, Issue 29
  • DOI: 10.1021/ja504573a

Facile Synthesis of PtNi Intermetallic Nanoparticles: Influence of Reducing Agent and Precursors on Electrocatalytic Activity
journal, March 2011

  • Leonard, Brian M.; Zhou, Qin; Wu, Diane
  • Chemistry of Materials, Vol. 23, Issue 5
  • DOI: 10.1021/cm1024876

Partial hydrogenation of benzene to cyclohexene on a Ru–Zn/m-ZrO2 nanocomposite catalyst
journal, September 2004


Stimulation of Electro-oxidation Catalysis by Bulk-Structural Transformation in Intermetallic ZrPt 3 Nanoparticles
journal, September 2014

  • Ramesh, Gubbala V.; Kodiyath, Rajesh; Tanabe, Toyokazu
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 18
  • DOI: 10.1021/am504147q

    Works referencing / citing this record:

    Intermetallic Nanocrystals: Syntheses and Catalytic Applications
    journal, February 2017

    • Yan, Yucong; Du, Jingshan S.; Gilroy, Kyle D.
    • Advanced Materials, Vol. 29, Issue 14
    • DOI: 10.1002/adma.201605997

    Synthesis and Electrochemical Property of PtPdCu Nanoparticles with Truncated-Octahedral Morphology
    journal, September 2018


    Effects of crystal phase and composition on structurally ordered Pt–Co–Ni/C ternary intermetallic electrocatalysts for the formic acid oxidation reaction
    journal, January 2018

    • Chen, Lingxuan; Zhu, Jing; Xuan, Cuijuan
    • Journal of Materials Chemistry A, Vol. 6, Issue 14
    • DOI: 10.1039/c7ta11051k

    Optimizing PtFe intermetallics for oxygen reduction reaction: from DFT screening to in situ XAFS characterization
    journal, January 2019

    • Gong, Mingxing; Zhu, Jing; Liu, Mingjie
    • Nanoscale, Vol. 11, Issue 42
    • DOI: 10.1039/c9nr04975d

    Structurally ordered PtSn intermetallic nanoparticles supported on ATO for efficient methanol oxidation reaction
    journal, January 2019


    High-performance alcohol electrooxidation on Pt 3 Sn–SnO 2 nanocatalysts synthesized through the transformation of Pt–Sn nanoparticles
    journal, January 2020

    • Wang, Liang; Wu, Wei; Lei, Zhao
    • Journal of Materials Chemistry A, Vol. 8, Issue 2
    • DOI: 10.1039/c9ta10886f

    Improving the electrocatalytic activity for formic acid oxidation of bimetallic Ir–Zn nanoparticles decorated on graphene nanoplatelets
    journal, January 2020

    • Ahmad, Khairul Naim; Noor Azam, Adam Mohd Izhan; Isahak, Wan Nor Roslam Wan
    • Materials Research Express, Vol. 7, Issue 1
    • DOI: 10.1088/2053-1591/ab6c95

    Addressing the Stability of Bulk Electrode Materials in the Electrochemical Methanol Oxidation
    journal, January 2019

    • Zerdoumi, Ridha; Rößner, Leonard; Armbrüster, Marc
    • Journal of The Electrochemical Society, Vol. 166, Issue 14
    • DOI: 10.1149/2.0631914jes

    Zn-enriched PtZn nanoparticle electrocatalysts synthesized by solution combustion for ethanol oxidation reaction in an alkaline medium
    journal, April 2018

    • Matin, Md. Abdul; Kumar, Anand; Saad, Mohammed Ali H. Saleh
    • MRS Communications, Vol. 8, Issue 02
    • DOI: 10.1557/mrc.2018.62