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Title: Proposal for Universality in the Viscosity of Metallic Liquids

Abstract

The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (η o) to that at the glass transition temperature, T g. We present experimental measurements of containerlessly processed metallic liquids that suggest that log(η/η o) as a function of T A/T is a potentially universal scaled curve. In stark contrast to previous approaches, the scaling requires only two fitting parameters, which are on average predictable. The temperature T A corresponds to the onset of cooperative motion and is strongly correlated with T g, suggesting that the processes underlying the glass transition first appear in the high temperature liquid.

Authors:
 [1];  [2];  [1];  [1]
  1. Washington Univ., St. Louis, MO (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1222545
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 5; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Blodgett, M. E., Egami, Takeshi, Nussinov, Z., and Kelton, K. F. Proposal for Universality in the Viscosity of Metallic Liquids. United States: N. p., 2015. Web. doi:10.1038/srep13837.
Blodgett, M. E., Egami, Takeshi, Nussinov, Z., & Kelton, K. F. Proposal for Universality in the Viscosity of Metallic Liquids. United States. doi:10.1038/srep13837.
Blodgett, M. E., Egami, Takeshi, Nussinov, Z., and Kelton, K. F. Wed . "Proposal for Universality in the Viscosity of Metallic Liquids". United States. doi:10.1038/srep13837. https://www.osti.gov/servlets/purl/1222545.
@article{osti_1222545,
title = {Proposal for Universality in the Viscosity of Metallic Liquids},
author = {Blodgett, M. E. and Egami, Takeshi and Nussinov, Z. and Kelton, K. F.},
abstractNote = {The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (ηo) to that at the glass transition temperature, Tg. We present experimental measurements of containerlessly processed metallic liquids that suggest that log(η/ηo) as a function of TA/T is a potentially universal scaled curve. In stark contrast to previous approaches, the scaling requires only two fitting parameters, which are on average predictable. The temperature TA corresponds to the onset of cooperative motion and is strongly correlated with Tg, suggesting that the processes underlying the glass transition first appear in the high temperature liquid.},
doi = {10.1038/srep13837},
journal = {Scientific Reports},
number = ,
volume = 5,
place = {United States},
year = {2015},
month = {9}
}

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Cited by: 21 works
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