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Title: Effects of ionomer morphology on oxygen reduction on Pt

In this paper, the oxygen reduction reaction (ORR) at the interface between platinum and Nafion 1100 equivalent weight was studied as a function of temperature (20–80 °C), humidity (10–100%), scan rate, the manner in which Nafion film was deposited, and the state of the Pt surface using ultramicroelectrodes employing cyclic voltammetry and chronoamperometry. ORR on smooth electrodes was strongly inhibited under specific conditions dependent on temperature, humidity, and scan rate. From the data presented, we postulate that dynamic changes in the molecular structure of the ionomer at the platinum interface result in differences in ORR voltammetry for films prepared and equilibrated under different conditions. The lack of similar changes for rough, platinized electrodes has been attributed to differences in initial ionomer structure and a higher energy barrier for ionomer restructuring. Finally, these model system studies yield insight into the ionomer-catalyst interface of particular interest for polymer electrolyte fuel cells.
 [1] ;  [2]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Report Number(s):
NREL/JA-5900-63733; LA-UR-15-22418
Journal ID: ISSN 0013-4651
Grant/Contract Number:
AC36-08GO28308; AC52-06NA25396
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 162; Journal Issue: 8; Related Information: Journal of the Electrochemical Society; Journal ID: ISSN 0013-4651
The Electrochemical Society
Research Org:
National Renewable Energy Lab. (NREL), Golden, CO (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Country of Publication:
United States
14 SOLAR ENERGY; 77 NANOSCIENCE AND NANOTECHNOLOGY; fuel cells; oxygen reduction reaction (ORR); Nafion; voltammetry; polymer electrolytes; catalysts; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; energy sciences; inorganic and physical chemistry; material science; platinum; oxygen reduction; interface; restructuring; ultramicroelectrode
OSTI Identifier:
Alternate Identifier(s):
OSTI ID: 1321757