In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

Siegel, D. A.; El Gabaly, F.; McCarty, K. F.; Bartelt, N. C.

doi:10.1103/PhysRevB.92.125421

Title: In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

Authors:

Siegel, D. A. ^[1]; El Gabaly, F. ^[1]; McCarty, K. F. ^[1]; Bartelt, N. C. ^[1]

Sandia National Laboratories (SNL-CA), Livermore, CA (United States). Materials Physics Dept.

Publication Date:: Tue Sep 15 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1215772

Grant/Contract Number:: AC04-94AL85000

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review. B, Condensed Matter and Materials Physics

Additional Journal Information:: Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Volume: 92 Journal Issue: 12; Journal ID: ISSN 1098-0121

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Citation Formats


                    Siegel, D. A., El Gabaly, F., McCarty, K. F., and Bartelt, N. C. In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes.  United States: N. p., 2015. 
Web.  doi:10.1103/PhysRevB.92.125421.

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                    Siegel, D. A., El Gabaly, F., McCarty, K. F., & Bartelt, N. C. In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes.  United States.  https://doi.org/10.1103/PhysRevB.92.125421

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                    Siegel, D. A., El Gabaly, F., McCarty, K. F., and Bartelt, N. C. Tue .  
"In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes".  United States.  https://doi.org/10.1103/PhysRevB.92.125421.

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@article{osti_1215772,

  title        = {In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes},

  author       = {Siegel, D. A. and El Gabaly, F. and McCarty, K. F. and Bartelt, N. C.},

  abstractNote = {},

  doi          = {10.1103/PhysRevB.92.125421},

  journal      = {Physical Review. B, Condensed Matter and Materials Physics},

  number       = 12,

  volume       = 92,

  place        = {United States},

  year         = {Tue Sep 15 00:00:00 EDT 2015},

  month        = {Tue Sep 15 00:00:00 EDT 2015}

}

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Works referenced in this record:

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Title: In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

Citation Formats

Measuring individual overpotentials in an operating solid-oxide electrochemical cell journal, January 2010

Growth mode and oxidation state analysis of individual cerium oxide islands on Ru(0001) journal, July 2013

Electronic properties of ion-implanted yttria-stabilized zirconia journal, January 1993

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Visualization of oxygen reduction sites at Pt electrodes on YSZ by means of 18O tracer incorporation: the width of the electrochemically active zone journal, January 2010

Electrochemical promotion of catalytic reactions journal, May 2010

Ion and mixed conducting oxides as catalysts journal, February 1992

Blackening in yttria stabilized zirconia due to cathodic processes at solid platinum electrodes journal, February 1974

Photoluminescence-spectra study of yttria-stabilized zirconia: Temperature dependence journal, September 1993

Measuring oxygen reduction/evolution reactions on the nanoscale journal, August 2011

Theoretical analysis of space charge layer formation at metal/ionic conductor interfaces journal, February 2011

Color-center-induced band-gap shift in yttria-stabilized zirconia journal, October 1989

In-situ Photoelectron Microspectroscopy and Imaging of Electrochemical Processes at the Electrodes of a Self-driven Cell journal, October 2013

Electrochemical blackening of yttria-stabilized zirconia â€“ morphological instability of the moving reaction front journal, January 1999

Microscopic and Nanoscopic Three-Phase-Boundaries of Platinum Thin-Film Electrodes on YSZ Electrolyte journal, December 2010

Experimental study of single triple-phase-boundary and platinum–yttria stabilized zirconia composite as cathodes for micro-solid oxide fuel cells journal, May 2012

Reduced-Temperature Solid Oxide Fuel Cell Based on YSZ Thin-Film Electrolyte journal, January 1997

Relation between solid oxide electrolyte surface properties and electrode reaction kinetics journal, December 1983

Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy journal, September 2010

Model for the Electrical Conductivity of Reduced Stabilized Zirconia journal, January 1988

In situ imaging of electrode processes on solid electrolytes by photoelectron microscopy and microspectroscopy – the role of the three-phase boundary journal, June 2007

Reducing over potential by surface mixed ionic–electronic conduction journal, October 2006

In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells journal, June 2011

Investigation of O2 reduction on Pt/YSZ by means of thin film microelectrodes: The geometry dependence of the electrode impedance journal, June 2010

Charge transfer at oxygen/zirconia interface at elevated temperatures: Part 1: Basic properties and terms journal, August 2005

Microspectroscopy at a moving reduction front in zirconia solid electrolyte journal, May 2002

Physical Chemistry of Ionic Materials: Ions and Electrons in Solids book, April 2004

Measuring individual overpotentials in an operating solid-oxide electrochemical cell
journal, January 2010

Growth mode and oxidation state analysis of individual cerium oxide islands on Ru(0001)
journal, July 2013

Electronic properties of ion-implanted yttria-stabilized zirconia
journal, January 1993

Decomposition of Nitric Oxide on Zirconia in a Solid-State Electrochemical Cell
journal, January 1979

Visualization of oxygen reduction sites at Pt electrodes on YSZ by means of 18O tracer incorporation: the width of the electrochemically active zone
journal, January 2010

Electrochemical promotion of catalytic reactions
journal, May 2010

Ion and mixed conducting oxides as catalysts
journal, February 1992

Blackening in yttria stabilized zirconia due to cathodic processes at solid platinum electrodes
journal, February 1974

Photoluminescence-spectra study of yttria-stabilized zirconia: Temperature dependence
journal, September 1993

Measuring oxygen reduction/evolution reactions on the nanoscale
journal, August 2011

Theoretical analysis of space charge layer formation at metal/ionic conductor interfaces
journal, February 2011

Color-center-induced band-gap shift in yttria-stabilized zirconia
journal, October 1989

In-situ Photoelectron Microspectroscopy and Imaging of Electrochemical Processes at the Electrodes of a Self-driven Cell
journal, October 2013

Electrochemical blackening of yttria-stabilized zirconia â€“ morphological instability of the moving reaction front
journal, January 1999

Microscopic and Nanoscopic Three-Phase-Boundaries of Platinum Thin-Film Electrodes on YSZ Electrolyte
journal, December 2010

Experimental study of single triple-phase-boundary and platinum–yttria stabilized zirconia composite as cathodes for micro-solid oxide fuel cells
journal, May 2012

Reduced-Temperature Solid Oxide Fuel Cell Based on YSZ Thin-Film Electrolyte
journal, January 1997

Relation between solid oxide electrolyte surface properties and electrode reaction kinetics
journal, December 1983

Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy
journal, September 2010

Model for the Electrical Conductivity of Reduced Stabilized Zirconia
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In situ imaging of electrode processes on solid electrolytes by photoelectron microscopy and microspectroscopy – the role of the three-phase boundary
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