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Title: Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties

Abstract

This study highlights various design and synthesis approaches toward the construction of ZMOFs, which are metal–organic frameworks (MOFs) with topologies and, in some cases, features akin to traditional inorganic zeolites. The interest in this unique subset of MOFs is correlated with their exceptional characteristics arising from the periodic pore systems and distinctive cage-like cavities, in conjunction with modular intra- and/or extra-framework components, which ultimately allow for tailoring of the pore size, pore shape, and properties towards specific applications.

Authors:
 [1];  [2];  [3];  [4];  [4]
  1. King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia); Univ. of South Florida, Tampa, FL (United States)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States); Univ. of South Florida, Tampa, FL (United States)
  3. Univ. of South Florida, Tampa, FL (United States); Florida Southern College, Lakeland, FL (United States)
  4. King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia)
Publication Date:
Research Org.:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1214786
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Society Reviews
Additional Journal Information:
Journal Volume: 44; Journal Issue: 1; Journal ID: ISSN 0306-0012
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Eddaoudi, Mohamed, Sava, Dorina F., Eubank, Jarrod F., Adil, Karim, and Guillerm, Vincent. Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties. United States: N. p., 2015. Web. doi:10.1039/C4CS00230J.
Eddaoudi, Mohamed, Sava, Dorina F., Eubank, Jarrod F., Adil, Karim, & Guillerm, Vincent. Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties. United States. doi:10.1039/C4CS00230J.
Eddaoudi, Mohamed, Sava, Dorina F., Eubank, Jarrod F., Adil, Karim, and Guillerm, Vincent. Sat . "Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties". United States. doi:10.1039/C4CS00230J. https://www.osti.gov/servlets/purl/1214786.
@article{osti_1214786,
title = {Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties},
author = {Eddaoudi, Mohamed and Sava, Dorina F. and Eubank, Jarrod F. and Adil, Karim and Guillerm, Vincent},
abstractNote = {This study highlights various design and synthesis approaches toward the construction of ZMOFs, which are metal–organic frameworks (MOFs) with topologies and, in some cases, features akin to traditional inorganic zeolites. The interest in this unique subset of MOFs is correlated with their exceptional characteristics arising from the periodic pore systems and distinctive cage-like cavities, in conjunction with modular intra- and/or extra-framework components, which ultimately allow for tailoring of the pore size, pore shape, and properties towards specific applications.},
doi = {10.1039/C4CS00230J},
journal = {Chemical Society Reviews},
number = 1,
volume = 44,
place = {United States},
year = {2015},
month = {10}
}

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    • Liu, Yang; Feng, Yong-Lan; Fu, Wei-Wei
    • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 12
    • DOI: 10.1107/s2053229615021221

    Fluorescent heterometallic MOFs: tunable framework charges and application for explosives detection
    journal, January 2016

    • Wang, Kangcai; Liu, Tianlin; Liu, Yuji
    • CrystEngComm, Vol. 18, Issue 42
    • DOI: 10.1039/c6ce01818a

    Crystal structure of poly[bis(μ-2-amino-4,5-dicyanoimidazolato-κ 2 N 1 : N 3 )- trans -bis( N , N ′-dimethylformamide-κ O )cadmium]
    journal, August 2015

    • Zhu, Jin-Li; Jiang, Guo -Qing; Guo, Xiao-Qing
    • Acta Crystallographica Section E Crystallographic Communications, Vol. 71, Issue 9
    • DOI: 10.1107/s2056989015014516

    A Lamellar Coordination Polymer with Remarkable Catalytic Activity
    journal, August 2016

    • Mendes, Ricardo F.; Antunes, Margarida M.; Silva, Patrícia
    • Chemistry - A European Journal, Vol. 22, Issue 37
    • DOI: 10.1002/chem.201602157

    A microporous metal–organic framework with polarized trifluoromethyl groups for high methane storage
    journal, January 2015

    • Chang, Ganggang; Li, Bin; Wang, Hailong
    • Chemical Communications, Vol. 51, Issue 79
    • DOI: 10.1039/c5cc05850c

    Synthesis of homochiral zeolitic metal–organic frameworks with amino acid and tetrazolates for chiral recognition
    journal, January 2017

    • Li, Min-Yu; Wang, Fei; Gu, Zhi-Gang
    • RSC Advances, Vol. 7, Issue 9
    • DOI: 10.1039/c6ra27069g

    A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D -surface
    journal, January 2018

    • Ye, Chun-Rong; Zheng, Ji; Li, Mian
    • Chemical Communications, Vol. 54, Issue 63
    • DOI: 10.1039/c8cc03484b

    Water adsorption behaviour of CAU-10-H: a thorough investigation of its structure–property relationships
    journal, January 2016

    • Fröhlich, Dominik; Pantatosaki, Evangelia; Kolokathis, Panagiotis D.
    • Journal of Materials Chemistry A, Vol. 4, Issue 30
    • DOI: 10.1039/c6ta01757f

    An I 2 O 1 Barium Framework Derived from an In-Situ Metal-Assisted Ligand Transformation : An I
    journal, October 2018

    • Tarlas, Georgios D.; Katsenis, Athanassios D.; Papaefstathiou, Giannis S.
    • European Journal of Inorganic Chemistry, Vol. 2018, Issue 40
    • DOI: 10.1002/ejic.201800866

    A crystalline zinc( ii ) complex showing hollow hexagonal tubular morphology evolution, selective dye absorption and unique response to UV irradiation
    journal, January 2017

    • Shi, Yi-Xiang; Li, Wu-Xiang; Chen, Huan-Huan
    • Chemical Communications, Vol. 53, Issue 40
    • DOI: 10.1039/c7cc02704d

    Unveiling the Mechanism of Water-Triggered Diplex Transformation and Correlating the Changes in Structures and Separation Properties
    journal, September 2015

    • Cao, Li-Hui; Wei, Yong-Sheng; Xu, Hong
    • Advanced Functional Materials, Vol. 25, Issue 41
    • DOI: 10.1002/adfm.201503154

    Zeolite-Type Metal Oxalate Frameworks
    journal, February 2019

    • Yi, Fei-Yan; Yang, Huajun; Zhao, Xiang
    • Angewandte Chemie International Edition, Vol. 58, Issue 9
    • DOI: 10.1002/anie.201900106

    In situ large-scale construction of sulfur-functionalized metal–organic framework and its efficient removal of Hg( ii ) from water
    journal, January 2016

    • Liang, Linfeng; Chen, Qihui; Jiang, Feilong
    • Journal of Materials Chemistry A, Vol. 4, Issue 40
    • DOI: 10.1039/c6ta04927c

    Synthesis, Crystal Structures, and Supramolecular Assemblies of Two Ni(II) Coordination Polymers Containing Naphthalenedicarboxylates
    journal, May 2016

    • Chang, Hai-Ning; Liu, Yong-Guang; Hao, Zeng-Chuan
    • Journal of Inorganic and Organometallic Polymers and Materials, Vol. 26, Issue 4
    • DOI: 10.1007/s10904-016-0381-z

    Synthesis of a Zn( ii )-based 1D zigzag coordination polymer for the fabrication of optoelectronic devices with remarkably high photosensitivity
    journal, January 2019

    • Dutta, Basudeb; Das, Dhananjoy; Datta, Joydeep
    • Inorganic Chemistry Frontiers, Vol. 6, Issue 5
    • DOI: 10.1039/c9qi00162j

    Evolution from linear tetranuclear clusters into one-dimensional chains of Dy( iii ) single-molecule magnets with an enhanced energy barrier
    journal, January 2017

    • Li, Rui-Ping; Liu, Qing-Yan; Wang, Yu-Ling
    • Inorganic Chemistry Frontiers, Vol. 4, Issue 7
    • DOI: 10.1039/c7qi00178a

    A two-dimensional zinc(II) coordination polymer based on mixed dimethyl succinate and bipyridine ligands: synthesis, structure, thermostability and luminescence properties
    journal, March 2016

    • Liu, Yang; Feng, Yong-Lan; Fu, Wei-Wei
    • Acta Crystallographica Section C Structural Chemistry, Vol. 72, Issue 4
    • DOI: 10.1107/s2053229616003211

    Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework
    journal, September 2018

    • Mon, Marta; Bruno, Rosaria; Tiburcio, Estefanía
    • Chemistry - A European Journal, Vol. 24, Issue 67
    • DOI: 10.1002/chem.201803547

    Synthesis, structure, computational modeling, and biological activity of two novel bimesitylene derivatives
    journal, October 2018

    • Bahrin, Lucian G.; Clima, Lilia; Shova, Sergiu
    • Research on Chemical Intermediates, Vol. 45, Issue 2
    • DOI: 10.1007/s11164-018-3611-x

    Scalable Synthesis and Supramolecular Assembly of trans -A 2 B 2 Porphyrins with Pendant Carboxylic Functional Groups
    journal, January 2017

    • Tripuramallu, Bharat Kumar; Palakuri, Ramesh; Titi, Hatem M.
    • ChemistrySelect, Vol. 2, Issue 3
    • DOI: 10.1002/slct.201601716

    Selective and Efficient Removal of Mercury from Aqueous Media with the Highly Flexible Arms of a BioMOF
    journal, August 2016

    • Mon, Marta; Lloret, Francesc; Ferrando-Soria, Jesús
    • Angewandte Chemie International Edition, Vol. 55, Issue 37
    • DOI: 10.1002/anie.201606015

    Switchable Room-Temperature Ferroelectric Behavior, Selective Sorption and Solvent-Exchange Studies of [H 3 O][Co 2 (dat)(sdba) 2 ]⋅H 2 sdba⋅5 H 2 O
    journal, March 2016

    • Bhattacharya, Saurav; Pal, Somnath; Natarajan, Srinivasan
    • ChemPlusChem, Vol. 81, Issue 8
    • DOI: 10.1002/cplu.201500564

    A Cd( ii ) based metal organic framework: a photosensitive current conductor
    journal, January 2015

    • Halder, Shibashis; Layek, Animesh; Ghosh, Koushik
    • Dalton Transactions, Vol. 44, Issue 36
    • DOI: 10.1039/c5dt02100f