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Title: CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

Abstract

In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in several ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.

Authors:
 [1];  [2];  [3];  [3];  [3]
  1. Dalian Univ., Panjin (China)
  2. National Inst. of Advanced Industrial Science and Technology, Ibaraki (Japan); JST, ACT-C, Saitama (Japan)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1214520
Report Number(s):
BNL-108316-2015-JA
Journal ID: ISSN 0009-2665; R&D Project: CO026; KC0304030
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Name: Chemical Reviews; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wang, Wan -Hui, Himeda, Yuichiro, Muckerman, James T., Manbeck, Gerald F., and Fujita, Etsuko. CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction. United States: N. p., 2015. Web. https://doi.org/10.1021/acs.chemrev.5b00197.
Wang, Wan -Hui, Himeda, Yuichiro, Muckerman, James T., Manbeck, Gerald F., & Fujita, Etsuko. CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction. United States. https://doi.org/10.1021/acs.chemrev.5b00197
Wang, Wan -Hui, Himeda, Yuichiro, Muckerman, James T., Manbeck, Gerald F., and Fujita, Etsuko. Thu . "CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction". United States. https://doi.org/10.1021/acs.chemrev.5b00197. https://www.osti.gov/servlets/purl/1214520.
@article{osti_1214520,
title = {CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction},
author = {Wang, Wan -Hui and Himeda, Yuichiro and Muckerman, James T. and Manbeck, Gerald F. and Fujita, Etsuko},
abstractNote = {In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in several ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.},
doi = {10.1021/acs.chemrev.5b00197},
journal = {Chemical Reviews},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {9}
}

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    Synthesis of Carboxylic Acids and Esters from CO2
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    Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons
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    Orbital Interactions in Bi-Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO 2 Reduction toward Formate Production
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    Recent Trends, Benchmarking, and Challenges of Electrochemical Reduction of CO 2 by Molecular Catalysts
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    Ambiguous electrocatalytic CO 2 reduction behaviour of a nickel bis(aldimino)pyridine pincer complex
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    Hydroboration of carbon dioxide enabled by molecular zinc dihydrides
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    Copper catalysis: ligand-controlled selective N -methylation or N -formylation of amines with CO 2 and phenylsilane
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    Iridium Complexes with Proton-Responsive Azole-Type Ligands as Effective Catalysts for CO 2 Hydrogenation
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    Base‐Free Hydrogenation of Carbon Dioxide to Methyl Formate with a Molecular Ruthenium‐Phosphine Catalyst
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    Active Sites in Heterogeneous Catalytic Reaction on Metal and Metal Oxide: Theory and Practice
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    A new diphosphine-carbonyl complex of ruthenium: an efficient precursor for C–C and C–N bond coupling catalysis
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    A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
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    Methylformate from CO 2 : an integrated process combining catalytic hydrogenation and reactive distillation
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    Evaluating the carbon inventory, carbon fluxes and carbon cycles for a long-term sustainable world
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    Cu-Mo2C/MCM-41: An Efficient Catalyst for the Selective Synthesis of Methanol from CO2
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    Atomic Ni Anchored Covalent Triazine Framework as High Efficient Electrocatalyst for Carbon Dioxide Conversion
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    Sustainable fixation of CO 2 into epoxides to form cyclic carbonates using hollow marigold CuCo 2 O 4 spinel microspheres as a robust catalyst
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    Making a Splash in Homogeneous CO 2 Hydrogenation: Elucidating the Impact of Solvent on Catalytic Mechanisms
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    Semiconductor Quantum Dots: An Emerging Candidate for CO 2 Photoreduction
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    Formic Acid‐Based Liquid Organic Hydrogen Carrier System with Heterogeneous Catalysts
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    CO 2 Reduction: From the Electrochemical to Photochemical Approach
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    Hydrogenation of CO 2 to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water
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    Hydrogenation of CO 2 to Formate with H 2 : Transition Metal Free Catalyst Based on a Lewis Pair
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    Strategies for Designing Nanoparticles for Electro‐ and Photocatalytic CO 2 Reduction
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    Mesoporous Silica‐Encaged Ultrafine Bimetallic Nanocatalysts for CO 2 Hydrogenation to Formates
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    Catalytic CO 2 Reduction with Boron‐ and Aluminum Hydrides
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    Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO 2 Fixation Reactions
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    Homogeneous Light-Driven Catalytic Direct Carboxylation with CO 2
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    Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+
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    The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
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    Tungstate catalysis: pressure-switched 2- and 6-electron reductive functionalization of CO 2 with amines and phenylsilane
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    Selective production of aromatics from CO 2
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    Kinetics and mechanisms of catalytic water oxidation
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    Acceptorless dehydrogenative coupling reactions with alcohols over heterogeneous catalysts
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    Nanofibrous rhodium with a new morphology for the hydrogenation of CO 2 to formate
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    Acceleration of CO 2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics
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    Bio-mimetic self-assembled computationally designed catalysts of Mo and W for hydrogenation of CO 2 /dehydrogenation of HCOOH inspired by the active site of formate dehydrogenase
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    A CO 2 -induced ROCO 2 Na/ROCO 2 H buffer solution promoted the carboxylative cyclization of propargyl alcohol to synthesize cyclic carbonates
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    CO 2 activation by manganese pincer complexes through different modes of metal–ligand cooperation
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    Liquid phase hydrogenation of CO 2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide
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    A phenanthroline-based porous organic polymer for the iridium-catalyzed hydrogenation of carbon dioxide to formate
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    Pore-structure-directed CO 2 electroreduction to formate on SnO 2 /C catalysts
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    An antimonene/Cp*Rh(phen)Cl/black phosphorus hybrid nanosheet-based Z-scheme artificial photosynthesis for enhanced photo/bio-catalytic CO 2 reduction
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    Current progress in electrocatalytic carbon dioxide reduction to fuels on heterogeneous catalysts
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    On-demand hydrogen production from formic acid by light-active dinuclear iridium catalysts
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    Chemoselective and efficient catalytic hydrogenation of furfural by iridium and ruthenium half-sandwich complexes
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    Heterogeneous catalysts for hydrogenation of CO 2 and bicarbonates to formic acid and formates
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    Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups
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    Formic Acid Manufacture: Carbon Dioxide Utilization Alternatives
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    Hydrogen Production from Formic Acid over Au Catalysts Supported on Carbon: Comparison with Au Catalysts Supported on SiO2 and Al2O3
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    Emerging Applications of Plasmons in Driving CO 2 Reduction and N 2 Fixation
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    Development of Effective Catalysts for Hydrogen Storage Technology Using Formic Acid
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    Hydrogenation of CO 2 to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water
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    Catalysis of Carbon Dioxide Photoreduction on Nanosheets: Fundamentals and Challenges
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    Catalytic Disproportionation of Formic Acid to Methanol by an Iridium Complex Immobilized on Bipyridine‐Periodic Mesoporous Organosilica
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    Picolinamide‐Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability
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    Direct Synthesis of Methyl Formate from CO 2 With Phosphine‐Based Polymer‐Bound Ru Catalysts
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    Recent Advances in Palladium-Catalyzed Carboxylation with CO 2: Recent Advances in Palladium-Catalyzed Carboxylation with CO 2
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    Direct catalytic hydrogenation of CO2 to formate over a Schiff-base-mediated gold nanocatalyst
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    A copper-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide using molecular oxygen as the oxidant
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    A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons
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    Carbon dioxide hydrogenation catalysed by well-defined Mn( i ) PNP pincer hydride complexes
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    Reduction of CO 2 by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate
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    Toward ideal carbon dioxide functionalization
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    Pyrene-functionalized polymeric carbon nitride with promoted aqueous–organic biphasic photocatalytic CO 2 reduction
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    Oxygen vacancies confined in Co 3 O 4 quantum dots for promoting oxygen evolution electrocatalysis
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    Comparative Performance Evaluation of Self-Basifying Direct Formate Fuel Cells
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    A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
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    • Schieweck, Benjamin Georg; Westhues, Niklas; Klankermayer, Jürgen
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    Application of POCOP Pincer Nickel Complexes to the Catalytic Hydroboration of Carbon Dioxide
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    Techno-Economic Optimization of CO2-to-Methanol with Solid-Oxide Electrolyzer
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    3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2 Coordination and Reduction and Formic Acid Dehydrogenation
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