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Title: Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography

Abstract

Full-field transmission X-ray microscopy has been used to determine the 3D structure of a whole individual fluid catalytic cracking (FCC) particle at high spatial resolution and in a fast, noninvasive manner, maintaining the full integrity of the particle. Using X-ray absorption mosaic imaging to combine multiple fields of view, computed tomography was performed to visualize the macropore structure of the catalyst and its availability for mass transport. We mapped the relative spatial distributions of Ni and Fe using multiple-energy tomography at the respective X-ray absorption K-edges and correlated these distributions with porosity and permeability of an equilibrated catalyst (E-cat) particle. Both metals were found to accumulate in outer layers of the particle, effectively decreasing porosity by clogging of pores and eventually restricting access into the FCC particle.

Authors:
 [1];  [2];  [1];  [2];  [2];  [1]
  1. Utrecht Univ. (The Netherlands)
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1214384
Grant/Contract Number:  
AC03-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 137; Journal Issue: 1; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
02 PETROLEUM

Citation Formats

Meirer, Florian, Morris, Darius T., Kalirai, Sam, Liu, Yijin, Andrews, Joy C., and Weckhuysen, Bert M. Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography. United States: N. p., 2015. Web. doi:10.1021/ja511503d.
Meirer, Florian, Morris, Darius T., Kalirai, Sam, Liu, Yijin, Andrews, Joy C., & Weckhuysen, Bert M. Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography. United States. doi:10.1021/ja511503d.
Meirer, Florian, Morris, Darius T., Kalirai, Sam, Liu, Yijin, Andrews, Joy C., and Weckhuysen, Bert M. Fri . "Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography". United States. doi:10.1021/ja511503d. https://www.osti.gov/servlets/purl/1214384.
@article{osti_1214384,
title = {Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography},
author = {Meirer, Florian and Morris, Darius T. and Kalirai, Sam and Liu, Yijin and Andrews, Joy C. and Weckhuysen, Bert M.},
abstractNote = {Full-field transmission X-ray microscopy has been used to determine the 3D structure of a whole individual fluid catalytic cracking (FCC) particle at high spatial resolution and in a fast, noninvasive manner, maintaining the full integrity of the particle. Using X-ray absorption mosaic imaging to combine multiple fields of view, computed tomography was performed to visualize the macropore structure of the catalyst and its availability for mass transport. We mapped the relative spatial distributions of Ni and Fe using multiple-energy tomography at the respective X-ray absorption K-edges and correlated these distributions with porosity and permeability of an equilibrated catalyst (E-cat) particle. Both metals were found to accumulate in outer layers of the particle, effectively decreasing porosity by clogging of pores and eventually restricting access into the FCC particle.},
doi = {10.1021/ja511503d},
journal = {Journal of the American Chemical Society},
number = 1,
volume = 137,
place = {United States},
year = {2015},
month = {1}
}

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Cited by: 24 works
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