Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives
Abstract
Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70× higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Div.
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Div.
- Shell Global Solutions, Houston, TX (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1212355
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 27; Journal Issue: 32; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Qu, Jun, Barnhill, William C., Luo, Huimin, Meyer, III, Harry M., Leonard, Donovan N., Landauer, Alexander K., Kheireddin, Bassem, Gao, Hong, Papke, Brian L, and Dai, Sheng. Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives. United States: N. p., 2015.
Web. doi:10.1002/adma.201502037.
Qu, Jun, Barnhill, William C., Luo, Huimin, Meyer, III, Harry M., Leonard, Donovan N., Landauer, Alexander K., Kheireddin, Bassem, Gao, Hong, Papke, Brian L, & Dai, Sheng. Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives. United States. https://doi.org/10.1002/adma.201502037
Qu, Jun, Barnhill, William C., Luo, Huimin, Meyer, III, Harry M., Leonard, Donovan N., Landauer, Alexander K., Kheireddin, Bassem, Gao, Hong, Papke, Brian L, and Dai, Sheng. Tue .
"Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives". United States. https://doi.org/10.1002/adma.201502037. https://www.osti.gov/servlets/purl/1212355.
@article{osti_1212355,
title = {Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives},
author = {Qu, Jun and Barnhill, William C. and Luo, Huimin and Meyer, III, Harry M. and Leonard, Donovan N. and Landauer, Alexander K. and Kheireddin, Bassem and Gao, Hong and Papke, Brian L and Dai, Sheng},
abstractNote = {Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70× higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.},
doi = {10.1002/adma.201502037},
journal = {Advanced Materials},
number = 32,
volume = 27,
place = {United States},
year = {Tue Jul 14 00:00:00 EDT 2015},
month = {Tue Jul 14 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 148 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ionic liquids for energy applications
journal, July 2013
- Matic, Aleksandar; Scrosati, Bruno
- MRS Bulletin, Vol. 38, Issue 7
Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009
- Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
- Nature Materials, Vol. 8, Issue 8, p. 621-629
Ionic Liquids as Advanced Lubricant Fluids
journal, August 2009
- Bermúdez, María-Dolores; Jiménez, Ana-Eva; Sanes, José
- Molecules, Vol. 14, Issue 8
Ionic liquid lubricants: designed chemistry for engineering applications
journal, January 2009
- Zhou, Feng; Liang, Yongmin; Liu, Weimin
- Chemical Society Reviews, Vol. 38, Issue 9
A Review of Ionic Liquids for Green Molecular Lubrication in Nanotechnology
journal, July 2010
- Palacio, Manuel; Bhushan, Bharat
- Tribology Letters, Vol. 40, Issue 2
A Review of Ionic Liquid Lubricants
journal, January 2013
- Somers, Anthony; Howlett, Patrick; MacFarlane, Douglas
- Lubricants, Vol. 1, Issue 1
Antiwear Performance and Mechanism of an Oil-Miscible Ionic Liquid as a Lubricant Additive
journal, February 2012
- Qu, Jun; Bansal, Dinesh G.; Yu, Bo
- ACS Applied Materials & Interfaces, Vol. 4, Issue 2, p. 997-1002
Oil-miscible and non-corrosive phosphonium-based ionic liquids as candidate lubricant additives
journal, June 2012
- Yu, Bo; Bansal, Dinesh G.; Qu, Jun
- Wear, Vol. 289, p. 58-64
Ionic Liquids as Antiwear Additives in Base Oils: Influence of Structure on Miscibility and Antiwear Performance for Steel on Aluminum
journal, November 2013
- Somers, Anthony E.; Khemchandani, Bhawna; Howlett, Patrick C.
- ACS Applied Materials & Interfaces, Vol. 5, Issue 22
Comparison of an oil-miscible ionic liquid and ZDDP as a lubricant anti-wear additive
journal, March 2014
- Qu, Jun; Luo, Huimin; Chi, Miaofang
- Tribology International, Vol. 71, p. 88-97
Ionic Liquids Based on Phosphonium Cations As Neat Lubricants or Lubricant Additives for a Steel/Steel Contact
journal, July 2014
- Otero, Inés; López, Enriqueta R.; Reichelt, Manuela
- ACS Applied Materials & Interfaces, Vol. 6, Issue 15
Comparison of the tribological behavior of steel–steel and Si3N4–steel contacts in lubricants with ZDDP or ionic liquid
journal, November 2014
- Cai, Zhen-bing; Meyer, Harry M.; Ma, Cheng
- Wear, Vol. 319, Issue 1-2
Phosphonium-Organophosphate Ionic Liquids as Lubricant Additives: Effects of Cation Structure on Physicochemical and Tribological Characteristics
journal, December 2014
- Barnhill, William C.; Qu, Jun; Luo, Huimin
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
Ionic Liquids Composed of Phosphonium Cations and Organophosphate, Carboxylate, and Sulfonate Anions as Lubricant Antiwear Additives
journal, October 2014
- Zhou, Yan; Dyck, Jeffrey; Graham, Todd W.
- Langmuir, Vol. 30, Issue 44
Tribological Performance and Mechanism of Phosphate Ionic Liquids as Additives in Three Base Oils for Steel-on-aluminum Contact
journal, July 2014
- Qiao, Dan; Wang, Haizhong; Feng, Dapeng
- Tribology Letters, Vol. 55, Issue 3
Halogen-free imidazolium/ammonium-bis(salicylato)borate ionic liquids as high performance lubricant additives
journal, January 2014
- Gusain, Rashi; Singh, Raghuvir; Sivakumar, K. L. N.
- RSC Adv., Vol. 4, Issue 3
DOSS – Based QAILs: As Both Neat Lubricants and Lubricant Additives with Excellent Tribological Properties and Good Detergency
journal, November 2014
- Fan, Mingjin; Yang, Desuo; Wang, Xiaoling
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 46
The History and Mechanisms of ZDDP
journal, October 2004
- Spikes, H.
- Tribology Letters, Vol. 17, Issue 3
Review of the lubrication of metallic surfaces by zinc dialkyl-dithiophosphates
journal, January 2005
- Nicholls, Mark A.; Do, Than; Norton, Peter R.
- Tribology International, Vol. 38, Issue 1
Improving corrosion resistance of AZ31B magnesium alloy via a conversion coating produced by a protic ammonium-phosphate ionic liquid
journal, October 2014
- Elsentriecy, Hassan H.; Qu, Jun; Luo, Huimin
- Thin Solid Films, Vol. 568
A new method for analyzing data from continuous depth-sensing microindentation tests
journal, January 1990
- Joslin, D. L.; Oliver, W. C.
- Journal of Materials Research, Vol. 5, Issue 1
Synergistic extraction and separation of lanthanum (III) and cerium (III) using a mixture of 2-ethylhexylphosphonic mono-2-ethylhexyl ester and di-2-ethylhexyl phosphoric acid in the presence of two complexing agents containing lactic acid and citric acid
journal, October 2014
- Zhang, Fengyun; Wu, Wenyuan; Bian, Xue
- Hydrometallurgy, Vol. 149
Chemical properties of trihexyl(tetradecyl)phosphonium chloride and bis(2,4,4-trimethylpentyl)phosphinic acid mixtures: Interaction study by FT-IR and NMR spectroscopies
journal, November 2013
- Cholico-Gonzalez, Diana; Avila-Rodriguez, Mario; Cote, Gérard
- Journal of Molecular Liquids, Vol. 187
Effects of Temperature and Pressure on ZDDP
journal, July 2007
- Tse, John S.; Song, Yang; Liu, Zhenxian
- Tribology Letters, Vol. 28, Issue 1
New approach in the modelling of the extraction equilibrium of zinc with bis-(2-ethylhexyl) phosphoric acid
journal, August 1996
- Sainz-Diaz, C. I.; Klocker, H.; Marr, R.
- Hydrometallurgy, Vol. 42, Issue 1
A review of zinc dialkyldithiophosphates (ZDDPS): characterisation and role in the lubricating oil
journal, June 2001
- Barnes, Allyson M.; Bartle, Keith D.; Thibon, Vincent R. A.
- Tribology International, Vol. 34, Issue 6
A dual‐analysis approach in tribochemistry: application to ZDDP/calcium borate additive interactions
journal, January 1999
- Varlot, K.; Martin, J. M.; Grossiord, C.
- Tribology Letters, Vol. 6, Issue 3/4, p. 181-189
Antiwear Properties of Blends Containing Mixtures of Zinc Dialkyl Dithiophosphate and Different Detergents
journal, December 2008
- Komvopoulos, K.; Pennecot, G.; Yamaguchi, E. S.
- Tribology Transactions, Vol. 52, Issue 1
The Antagonism between Succinimide Dispersants and a Secondary Zinc Dialkyl Dithiophosphate
journal, October 2013
- Zhang, Jie; Yamaguchi, Elaine; Spikes, Hugh
- Tribology Transactions, Vol. 57, Issue 1
Additive–additive interaction: an XPS study of the effect of ZDDP on the AW/EP characteristics of molybdenum based additives
journal, February 2002
- Unnikrishnan, R.; Jain, M. C.; Harinarayan, A. K.
- Wear, Vol. 252, Issue 3-4
Synthesis and physical property characterisation of phosphonium ionic liquids based on P(O)2(OR)2− and P(O)2(R)2− anions with potential application for corrosion mitigation of magnesium alloys
journal, December 2008
- Sun, Jiazeng; Howlett, Patrick C.; MacFarlane, Douglas R.
- Electrochimica Acta, Vol. 54, Issue 2, p. 254-260
Works referencing / citing this record:
Tribo‐Induced Structural Transformation and Lubricant Dissociation at Amorphous Carbon–Alpha Olefin Interface
journal, September 2018
- Li, Xiaowei; Wang, Aiying; Lee, Kwang‐Ryeol
- Advanced Theory and Simulations, Vol. 2, Issue 2
Synergistic effects of phosphate ionic liquids and octadecylaminen‐oleoyl sarcosinate as lubricating grease additives
journal, March 2019
- Wang, Zeyun; Chang, Jun; Wu, Wei
- Lubrication Science, Vol. 31, Issue 4
Reactivity of oil‐soluble IL with silicon surface at elevated temperature
journal, March 2019
- Al‐Sallami, Waleed; Parsaeian, Pourya; Dorgham, Abdel
- Lubrication Science, Vol. 31, Issue 4
Alkyl phosphate modified graphene oxide as friction and wear reduction additives in oil
journal, December 2018
- Zhang, Lei; He, Yi; Zhu, Lin
- Journal of Materials Science, Vol. 54, Issue 6
High-Performance Heterocyclic Friction Modifiers for Boundary Lubrication
journal, February 2018
- Desanker, Michael; He, Xingliang; Lu, Jie
- Tribology Letters, Vol. 66, Issue 1
Carbon-based tribofilms from lubricating oils
journal, August 2016
- Erdemir, Ali; Ramirez, Giovanni; Eryilmaz, Osman L.
- Nature, Vol. 536, Issue 7614
Tribotronic control of friction in oil-based lubricants with ionic liquid additives
journal, January 2016
- Cooper, P. K.; Li, H.; Rutland, M. W.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 34
Facile synthesis of photoluminescent inorganic–organic hybrid carbon dots codoped with B and N: towards an efficient lubrication additive
journal, January 2017
- Zhang, Yunxiao; Cai, Tao; Shang, Wangji
- Dalton Transactions, Vol. 46, Issue 36
Tribochemistry and thermo-oxidative stability of halogen-free ionic liquids
journal, January 2017
- Totolin, Vladimir; Pisarova, Lucia; Dörr, Nicole
- RSC Adv., Vol. 7, Issue 77
In situ fabrication of carbon dots-based lubricants using a facile ultrasonic approach
journal, January 2019
- He, Chuang; Yan, Honghao; Li, Xiaojie
- Green Chemistry, Vol. 21, Issue 9
Friction and Wear Reduction Mechanisms of the Reciprocating Contact Interfaces Using Nanolubricant Under Different Loads and Speeds
journal, April 2018
- Ahmed Ali, Mohamed Kamal; Xianjun, Hou; Essa, F. A.
- Journal of Tribology, Vol. 140, Issue 5
The Synergistic Antiwear Performances of Organic Titanium Compounds Containing Sulfur with Borate Ester Additive
journal, November 2018
- Xu, Xin; Hu, Jian-Qiang; Xie, Feng
- Journal of Spectroscopy, Vol. 2018
Non-halogenated Ionic Liquid Dramatically Enhances Tribological Performance of Biodegradable Oils
journal, February 2019
- Rohlmann, Patrick; Munavirov, Bulat; Furó, István
- Frontiers in Chemistry, Vol. 7
Understanding Tribofilm Formation Mechanisms in Ionic Liquid Lubrication
journal, August 2017
- Zhou, Yan; Leonard, Donovan N.; Guo, Wei
- Scientific Reports, Vol. 7, Issue 1