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Title: Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks

Abstract

The host–guest chemistry between a series of anionic MOFs and their trapped counterions was investigated by single crystal XRD.

Authors:
 [1];  [1];  [1]
  1. Texas A & M Univ., College Station, TX (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC), Washington, D.C. (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1210424
Grant/Contract Number:  
SC0001015
Resource Type:
Accepted Manuscript
Journal Name:
CrystEngComm
Additional Journal Information:
Journal Volume: 17; Journal Issue: 5; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 1466-8033
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane; carbon capture; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)

Citation Formats

Zhang, Muwei, Bosch, Mathieu, and Zhou, Hong -Cai. Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks. United States: N. p., 2014. Web. doi:10.1039/C4CE02261K.
Zhang, Muwei, Bosch, Mathieu, & Zhou, Hong -Cai. Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks. United States. https://doi.org/10.1039/C4CE02261K
Zhang, Muwei, Bosch, Mathieu, and Zhou, Hong -Cai. Tue . "Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks". United States. https://doi.org/10.1039/C4CE02261K. https://www.osti.gov/servlets/purl/1210424.
@article{osti_1210424,
title = {Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks},
author = {Zhang, Muwei and Bosch, Mathieu and Zhou, Hong -Cai},
abstractNote = {The host–guest chemistry between a series of anionic MOFs and their trapped counterions was investigated by single crystal XRD.},
doi = {10.1039/C4CE02261K},
journal = {CrystEngComm},
number = 5,
volume = 17,
place = {United States},
year = {Tue Dec 09 00:00:00 EST 2014},
month = {Tue Dec 09 00:00:00 EST 2014}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 8 works
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Figures / Tables:

Fig. 1 Fig. 1: (a) A graphic representation of the trinuclear cadmium cluster. (b) The cage where the cadmium complex is encapsulated. (c) The crystal structure of the PCN-514 framework (the host MOF). For simplicity, the trapped Cd complexes (the guest molecules) are not shown. Color scheme: C, gray; O, red; Cd,more » green. H atoms were omitted for clarity.« less

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Works referencing / citing this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.