DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Magnetic Force Microscopy Study of Zr 2 Co 11 -Based Nanocrystalline Materials: Effect of Mo Addition

Abstract

The addition of Molybdenum was used to modify the nanostructure and enhance coercivity of rare-earth-free Zr2Co11-based nanocrystalline permanent magnets. The effect of Mo addition on magnetic domain structures of melt spun nanocrystalline Zr16Co84-xMox( x = 0 , 0.5, 1, 1.5, and 2.0) ribbons has been investigated. It was found that magnetic properties and local domain structures are strongly influenced by Mo doping. The coercivity of the samples increases with the increase in Mo content ( x 1.5 ). The maximum energy product ( B H ) max increases with increasing x from 0.5 MGOe for x = 0 to a maximum value of 4.2 MGOe for x = 1.5 . The smallest domain size with a relatively short magnetic correlation length of 128 nm and largest root-mean-square phase shift Φ rms value of 0.66° are observed for the x = 1.5 . The optimal Mo addition promotes magnetic domain structure refinement and thus leads to a significant increase in coercivity and energy product in this sample.

Authors:
ORCiD logo; ORCiD logo; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1209153
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Published Article
Journal Name:
Journal of Nanomaterials
Additional Journal Information:
Journal Name: Journal of Nanomaterials Journal Volume: 2015; Journal ID: ISSN 1687-4110
Publisher:
Hindawi Publishing Corporation
Country of Publication:
Egypt
Language:
English

Citation Formats

Yue, Lanping, Jin, Yunlong, Zhang, Wenyong, and Sellmyer, David J. Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition. Egypt: N. p., 2015. Web. doi:10.1155/2015/151740.
Yue, Lanping, Jin, Yunlong, Zhang, Wenyong, & Sellmyer, David J. Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition. Egypt. https://doi.org/10.1155/2015/151740
Yue, Lanping, Jin, Yunlong, Zhang, Wenyong, and Sellmyer, David J. Thu . "Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition". Egypt. https://doi.org/10.1155/2015/151740.
@article{osti_1209153,
title = {Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition},
author = {Yue, Lanping and Jin, Yunlong and Zhang, Wenyong and Sellmyer, David J.},
abstractNote = {The addition of Molybdenum was used to modify the nanostructure and enhance coercivity of rare-earth-free Zr2Co11-based nanocrystalline permanent magnets. The effect of Mo addition on magnetic domain structures of melt spun nanocrystalline Zr16Co84-xMox(x=0, 0.5, 1, 1.5, and 2.0) ribbons has been investigated. It was found that magnetic properties and local domain structures are strongly influenced by Mo doping. The coercivity of the samples increases with the increase in Mo content (x≤1.5). The maximum energy product(BH)maxincreases with increasingxfrom 0.5 MGOe forx=0to a maximum value of 4.2 MGOe forx=1.5. The smallest domain size with a relatively short magnetic correlation length of 128 nm and largest root-mean-square phase shiftΦrmsvalue of 0.66° are observed for thex=1.5. The optimal Mo addition promotes magnetic domain structure refinement and thus leads to a significant increase in coercivity and energy product in this sample.},
doi = {10.1155/2015/151740},
journal = {Journal of Nanomaterials},
number = ,
volume = 2015,
place = {Egypt},
year = {2015},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1155/2015/151740

Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Magnetism of rapidly quenched rhombohedral Zr 2 Co 11 -based nanocomposites
journal, March 2013


Phase composition and nanostructure of Zr 2 Co 11 -based alloys
journal, May 2014

  • Jin, Y. L.; Zhang, W. Y.; Skomski, R.
  • Journal of Applied Physics, Vol. 115, Issue 17
  • DOI: 10.1063/1.4867226

Magnetic micro-structural uniformity of die-upset Nd-Fe-B magnets
journal, April 2012

  • Fang, Yikun; Yin, Xiaolu; Zhao, Rui
  • Journal of Applied Physics, Vol. 111, Issue 7
  • DOI: 10.1063/1.3679423

Magnetic properties of ZrCo 5.1− x Fe x alloys
journal, November 1991

  • Burzo, E.; Grössinger, R.; Hundegger, P.
  • Journal of Applied Physics, Vol. 70, Issue 10
  • DOI: 10.1063/1.349904

Effects of Mo additive on structure and magnetic properties of Co82Zr18 alloy
journal, April 2009


Growth control of homogeneous pulsed electrodeposited Co thin films on n-doped Si(111) substrates
journal, January 2006


High coercivity in non‐rare‐earth containing alloys
journal, May 1990

  • Gao, C.; Wan, H.; Hadjipanayis, G. C.
  • Journal of Applied Physics, Vol. 67, Issue 9
  • DOI: 10.1063/1.344747

Hard magnetic phase in rapidly quenched Zr-Co-B alloys
journal, January 1990

  • Ishikawa, T.; Ohmori, K.
  • IEEE Transactions on Magnetics, Vol. 26, Issue 5
  • DOI: 10.1109/20.104381

Magnetic force microscopy investigation of the domain structure of nanocomposite Nd2Fe14B/Fe3B magnets
journal, January 2011


Novel Nanostructured Rare-Earth-Free Magnetic Materials with High Energy Products
journal, August 2013

  • Balasubramanian, Balamurugan; Das, Bhaskar; Skomski, Ralph
  • Advanced Materials, Vol. 25, Issue 42
  • DOI: 10.1002/adma.201302704