Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Ordonez, Carlos; Kinnibrugh, Tiffany; Xu, Hongwu; Lindline, Jennifer; Timofeeva, Tatiana; Wei, Qiang

doi:10.3390/cryst5020193

Title: Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Abstract

The solvothermal synthesis of framework isomers was carried out using the hybrid carboxylate and tetrazolate functional ligand, 4-tetrazolyl benzenecarboxylic acid (H₂TBC, TBC = 4-tetrazolyl benzenecarboxylate) and zinc. H₂TBC was also synthesized with the solvothermal approach, and is referred herein as structure 1. Using single-crystal X-ray diffraction, we found that the tetrazolate groups of TBC show an unusual “opposite-on” coordination mode with zinc. Three previously characterized metal-organic frameworks (MOFs) were obtained by systematically changing the solvents of the H₂TBC-Zn reaction, (1) ZnTBC, 2, which has a non-porous structure; (2) Zn₂(TBC)₂(H2O), 3, which has an amphiphilic pore structure and (3) Zn₂(TBC)₂{guest}, 4, which is porous and has channels containing uncoordinated N heteroatoms. Fluorescence spectra of 4 reveal a strong blue emission mainly from the TBC ligands.

Authors:: Ordonez, Carlos; Kinnibrugh, Tiffany; Xu, Hongwu; Lindline, Jennifer; Timofeeva, Tatiana; Wei, Qiang

Publication Date:: Thu Apr 02 00:00:00 EDT 2015

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1426822

Alternate Identifier(s):: OSTI ID: 1208867

Grant/Contract Number:: LDRD-DR; DMR0934212; IIA1301346

Resource Type:: Published Article

Journal Name:: Crystals

Additional Journal Information:: Journal Name: Crystals Journal Volume: 5 Journal Issue: 2; Journal ID: ISSN 2073-4352

Publisher:: MDPI AG

Country of Publication:: Germany

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; hybrid ligand; tetrazolate; opposite-on coordination; solvothermal technique

Citation Formats


                    Ordonez, Carlos, Kinnibrugh, Tiffany, Xu, Hongwu, Lindline, Jennifer, Timofeeva, Tatiana, and Wei, Qiang. Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach.  Germany: N. p., 2015. 
Web.  doi:10.3390/cryst5020193.

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                    Ordonez, Carlos, Kinnibrugh, Tiffany, Xu, Hongwu, Lindline, Jennifer, Timofeeva, Tatiana, & Wei, Qiang. Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach.  Germany.  https://doi.org/10.3390/cryst5020193

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                    Ordonez, Carlos, Kinnibrugh, Tiffany, Xu, Hongwu, Lindline, Jennifer, Timofeeva, Tatiana, and Wei, Qiang. Thu .  
"Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach".  Germany.  https://doi.org/10.3390/cryst5020193.

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@article{osti_1426822,

  title        = {Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach},

  author       = {Ordonez, Carlos and Kinnibrugh, Tiffany and Xu, Hongwu and Lindline, Jennifer and Timofeeva, Tatiana and Wei, Qiang},

  abstractNote = {The solvothermal synthesis of framework isomers was carried out using the hybrid carboxylate and tetrazolate functional ligand, 4-tetrazolyl benzenecarboxylic acid (H₂TBC, TBC = 4-tetrazolyl benzenecarboxylate) and zinc. H₂TBC was also synthesized with the solvothermal approach, and is referred herein as structure 1. Using single-crystal X-ray diffraction, we found that the tetrazolate groups of TBC show an unusual “opposite-on” coordination mode with zinc. Three previously characterized metal-organic frameworks (MOFs) were obtained by systematically changing the solvents of the H₂TBC-Zn reaction, (1) ZnTBC, 2, which has a non-porous structure; (2) Zn₂(TBC)₂(H2O), 3, which has an amphiphilic pore structure and (3) Zn₂(TBC)₂{guest}, 4, which is porous and has channels containing uncoordinated N heteroatoms. Fluorescence spectra of 4 reveal a strong blue emission mainly from the TBC ligands.},

  doi          = {10.3390/cryst5020193},

  journal      = {Crystals},

  number       = 2,

  volume       = 5,

  place        = {Germany},

  year         = {Thu Apr 02 00:00:00 EDT 2015},

  month        = {Thu Apr 02 00:00:00 EDT 2015}

}

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Works referencing / citing this record:

A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property
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Tai, Xi-Shi; You, Hai-Ying
Crystals, Vol. 5, Issue 4
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A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property
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Tai, Xi-Shi; You, Hai-Ying
Crystals, Vol. 5, Issue 4
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Liu, Botao; Vellingiri, Kowsalya; Jo, Sang-Hee
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journal, April 2018

Qu, Taoguang; Wei, Qiang; Ordonez, Carlos
Crystals, Vol. 8, Issue 4
DOI: 10.3390/cryst8040162

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Title: Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Abstract

Citation Formats

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