O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries

Li, Xin; Wu, Di; Zhou, Yong-Ning; Liu, Lei; Yang, Xiao-Qing; Ceder, Gerbrand

doi:10.1016/j.elecom.2014.10.003

Title: O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries

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Abstract

We report a new layered Na(Mn₀.₂₅Fe₀.₂₅Co₀.₂₅Ni₀.₂₅)O₂ compound with O3 oxygen stacking. It delivers 180 mAh/g initial discharge capacity and 578 Wh/kg specific energy density with good cycling capability at high cutoff voltage. In situ X-ray diffraction (XRD) shows a reversible structure evolution of O3-P3-O3'-O3'' upon Na de-intercalation. The excellent capacity and cycling performance at high cutoff voltage make it an important model system for studying the general issue of capacity fading in layered Na cathode compounds.

Authors:: Li, Xin; Wu, Di; Zhou, Yong-Ning; Liu, Lei; Yang, Xiao-Qing; Ceder, Gerbrand

Publication Date:: Mon Dec 01 00:00:00 EST 2014

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1198372

Alternate Identifier(s):: OSTI ID: 1163942

Report Number(s):: BNL-107066-2014-JA
Journal ID: ISSN 1388-2481; S1388248114003129; PII: S1388248114003129

Grant/Contract Number:: AC02-98CH10886

Resource Type:: Published Article

Journal Name:: Electrochemistry Communications

Additional Journal Information:: Journal Name: Electrochemistry Communications Journal Volume: 49 Journal Issue: C; Journal ID: ISSN 1388-2481

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Subject:: 25 ENERGY STORAGE; Sodium battery; Na(Mn0.25Fe0.25Co0.25Ni0.25)O2; CATHODES; NSLS

Citation Formats


                    Li, Xin, Wu, Di, Zhou, Yong-Ning, Liu, Lei, Yang, Xiao-Qing, and Ceder, Gerbrand. O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries.  Netherlands: N. p., 2014. 
Web.  doi:10.1016/j.elecom.2014.10.003.

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                    Li, Xin, Wu, Di, Zhou, Yong-Ning, Liu, Lei, Yang, Xiao-Qing, & Ceder, Gerbrand. O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries.  Netherlands.  https://doi.org/10.1016/j.elecom.2014.10.003

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                    Li, Xin, Wu, Di, Zhou, Yong-Ning, Liu, Lei, Yang, Xiao-Qing, and Ceder, Gerbrand. Mon .  
"O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries".  Netherlands.  https://doi.org/10.1016/j.elecom.2014.10.003.

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@article{osti_1198372,

  title        = {O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries},

  author       = {Li, Xin and Wu, Di and Zhou, Yong-Ning and Liu, Lei and Yang, Xiao-Qing and Ceder, Gerbrand},

  abstractNote = {We report a new layered Na(Mn₀.₂₅Fe₀.₂₅Co₀.₂₅Ni₀.₂₅)O₂ compound with O3 oxygen stacking. It delivers 180 mAh/g initial discharge capacity and 578 Wh/kg specific energy density with good cycling capability at high cutoff voltage. In situ X-ray diffraction (XRD) shows a reversible structure evolution of O3-P3-O3'-O3'' upon Na de-intercalation. The excellent capacity and cycling performance at high cutoff voltage make it an important model system for studying the general issue of capacity fading in layered Na cathode compounds.},

  doi          = {10.1016/j.elecom.2014.10.003},

  journal      = {Electrochemistry Communications},

  number       = C,

  volume       = 49,

  place        = {Netherlands},

  year         = {Mon Dec 01 00:00:00 EST 2014},

  month        = {Mon Dec 01 00:00:00 EST 2014}

}

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