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Title: A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control

Abstract

We report high-yield and efficient size-controlled syntheses of Chalcopyrite CuIn S 2 nanoparticles by decomposing molecular single source precursors (SSPs) via microwave irradiation in the presence of 1,2-ethanedithiol at reaction temperatures as low as 100 ° C and times as short as 30 minutes. The nanoparticles sizes were 1.8 nm to 10.8 nm as reaction temperatures were varied from 100 ° C to 200 ° C with the bandgaps from 2.71 eV to 1.28 eV with good size control and high yields (64%–95%). The resulting nanoparticles were analyzed by XRD, UV-Vis, ICP-OES, XPS, SEM, EDS, and HRTEM. Titration studies by 1 H NMR using SSP 1 with 1,2-ethanedithiol and benzyl mercaptan were conducted to elucidate the formation of Chalcopyrite CuIn S 2 nanoparticles.

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [1];  [1];  [3];  [4];  [4];  [1];  [1]
  1. Department of Chemistry, Idaho State University, Pocatello, ID 83209, USA
  2. Department of Physical Science, College of Southern Idaho, Twin Falls, ID 83303, USA
  3. W. R. Willey Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352, USA
  4. Department of Physics, Boise State University, Boise, ID 83725, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1198246
Grant/Contract Number:  
FG02-04ER46142
Resource Type:
Published Article
Journal Name:
Journal of Nanomaterials
Additional Journal Information:
Journal Name: Journal of Nanomaterials Journal Volume: 2009; Journal ID: ISSN 1687-4110
Publisher:
Hindawi Publishing Corporation
Country of Publication:
Egypt
Language:
English

Citation Formats

Sun, Chivin, Gardner, Joseph S., Shurdha, Endrit, Margulieux, Kelsey R., Westover, Richard D., Lau, Lisa, Long, Gary, Bajracharya, Cyril, Wang, Chongmin, Thurber, Aaron, Punnoose, Alex, Rodriguez, Rene G., and Pak, Joshua J. A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control. Egypt: N. p., 2009. Web. https://doi.org/10.1155/2009/748567.
Sun, Chivin, Gardner, Joseph S., Shurdha, Endrit, Margulieux, Kelsey R., Westover, Richard D., Lau, Lisa, Long, Gary, Bajracharya, Cyril, Wang, Chongmin, Thurber, Aaron, Punnoose, Alex, Rodriguez, Rene G., & Pak, Joshua J. A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control. Egypt. https://doi.org/10.1155/2009/748567
Sun, Chivin, Gardner, Joseph S., Shurdha, Endrit, Margulieux, Kelsey R., Westover, Richard D., Lau, Lisa, Long, Gary, Bajracharya, Cyril, Wang, Chongmin, Thurber, Aaron, Punnoose, Alex, Rodriguez, Rene G., and Pak, Joshua J. Thu . "A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control". Egypt. https://doi.org/10.1155/2009/748567.
@article{osti_1198246,
title = {A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control},
author = {Sun, Chivin and Gardner, Joseph S. and Shurdha, Endrit and Margulieux, Kelsey R. and Westover, Richard D. and Lau, Lisa and Long, Gary and Bajracharya, Cyril and Wang, Chongmin and Thurber, Aaron and Punnoose, Alex and Rodriguez, Rene G. and Pak, Joshua J.},
abstractNote = {We report high-yield and efficient size-controlled syntheses of Chalcopyrite CuIn S 2 nanoparticles by decomposing molecular single source precursors (SSPs) via microwave irradiation in the presence of 1,2-ethanedithiol at reaction temperatures as low as 100 ° C and times as short as 30 minutes. The nanoparticles sizes were 1.8 nm to 10.8 nm as reaction temperatures were varied from 100 ° C to 200 ° C with the bandgaps from 2.71 eV to 1.28 eV with good size control and high yields (64%–95%). The resulting nanoparticles were analyzed by XRD, UV-Vis, ICP-OES, XPS, SEM, EDS, and HRTEM. Titration studies by 1 H NMR using SSP 1 with 1,2-ethanedithiol and benzyl mercaptan were conducted to elucidate the formation of Chalcopyrite CuIn S 2 nanoparticles.},
doi = {10.1155/2009/748567},
journal = {Journal of Nanomaterials},
number = ,
volume = 2009,
place = {Egypt},
year = {2009},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1155/2009/748567

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Cited by: 15 works
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