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Title: Effects of Dopant Metal Variation and Material Synthesis Method on the Material Properties of Mixed Metal Ferrites in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production

Abstract

Mixed metal ferrites have shown much promise in two-step solar-thermochemical fuel production. Previous work has typically focused on evaluating a particular metal ferrite produced by a particular synthesis process, which makes comparisons between studies performed by independent researchers difficult. A comparative study was undertaken to explore the effects different synthesis methods have on the performance of a particular material during redox cycling using thermogravimetry. This study revealed that materials made via wet chemistry methods and extended periods of high temperature calcination yield better redox performance. Differences in redox performance between materials made via wet chemistry methods were minimal and these demonstrated much better performance than those synthesized via the solid state method. Subsequently, various metal ferrite samples (NiFe 2 O 4 , MgFe 2 O 4 , CoFe 2 O 4 , and MnFe 2 O 4 ) in yttria stabilized zirconia (8YSZ) were synthesized via coprecipitation and tested to determine the most promising metal ferrite combination. It was determined that 10 wt.% CoFe 2 O 4 in 8YSZ produced the highest and most consistent yields of O 2 and CO. By testing the effects of synthesis methods and dopants in a consistent fashion, those aspects of ferrite preparation which aremore » most significant can be revealed. More importantly, these insights can guide future efforts in developing the next generation of thermochemical fuel production materials.« less

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [1];  [1];  [1];  [1]
  1. Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, FL 32611, USA
  2. School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, OR 97331, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1197744
Grant/Contract Number:  
AR0000184
Resource Type:
Published Article
Journal Name:
International Journal of Photoenergy
Additional Journal Information:
Journal Name: International Journal of Photoenergy Journal Volume: 2015; Journal ID: ISSN 1110-662X
Publisher:
Hindawi Publishing Corporation
Country of Publication:
Egypt
Language:
English

Citation Formats

Leonard, Jeffrey, Reyes, Nichole, Allen, Kyle M., Randhir, Kelvin, Li, Like, AuYeung, Nick, Grunewald, Jeremy, Rhodes, Nathan, Bobek, Michael, and Klausner, James F. Effects of Dopant Metal Variation and Material Synthesis Method on the Material Properties of Mixed Metal Ferrites in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production. Egypt: N. p., 2015. Web. doi:10.1155/2015/856385.
Leonard, Jeffrey, Reyes, Nichole, Allen, Kyle M., Randhir, Kelvin, Li, Like, AuYeung, Nick, Grunewald, Jeremy, Rhodes, Nathan, Bobek, Michael, & Klausner, James F. Effects of Dopant Metal Variation and Material Synthesis Method on the Material Properties of Mixed Metal Ferrites in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production. Egypt. doi:10.1155/2015/856385.
Leonard, Jeffrey, Reyes, Nichole, Allen, Kyle M., Randhir, Kelvin, Li, Like, AuYeung, Nick, Grunewald, Jeremy, Rhodes, Nathan, Bobek, Michael, and Klausner, James F. Thu . "Effects of Dopant Metal Variation and Material Synthesis Method on the Material Properties of Mixed Metal Ferrites in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production". Egypt. doi:10.1155/2015/856385.
@article{osti_1197744,
title = {Effects of Dopant Metal Variation and Material Synthesis Method on the Material Properties of Mixed Metal Ferrites in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production},
author = {Leonard, Jeffrey and Reyes, Nichole and Allen, Kyle M. and Randhir, Kelvin and Li, Like and AuYeung, Nick and Grunewald, Jeremy and Rhodes, Nathan and Bobek, Michael and Klausner, James F.},
abstractNote = {Mixed metal ferrites have shown much promise in two-step solar-thermochemical fuel production. Previous work has typically focused on evaluating a particular metal ferrite produced by a particular synthesis process, which makes comparisons between studies performed by independent researchers difficult. A comparative study was undertaken to explore the effects different synthesis methods have on the performance of a particular material during redox cycling using thermogravimetry. This study revealed that materials made via wet chemistry methods and extended periods of high temperature calcination yield better redox performance. Differences in redox performance between materials made via wet chemistry methods were minimal and these demonstrated much better performance than those synthesized via the solid state method. Subsequently, various metal ferrite samples (NiFe 2 O 4 , MgFe 2 O 4 , CoFe 2 O 4 , and MnFe 2 O 4 ) in yttria stabilized zirconia (8YSZ) were synthesized via coprecipitation and tested to determine the most promising metal ferrite combination. It was determined that 10 wt.% CoFe 2 O 4 in 8YSZ produced the highest and most consistent yields of O 2 and CO. By testing the effects of synthesis methods and dopants in a consistent fashion, those aspects of ferrite preparation which are most significant can be revealed. More importantly, these insights can guide future efforts in developing the next generation of thermochemical fuel production materials.},
doi = {10.1155/2015/856385},
journal = {International Journal of Photoenergy},
number = ,
volume = 2015,
place = {Egypt},
year = {2015},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1155/2015/856385

Citation Metrics:
Cited by: 2 works
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