Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis

Abstract

Efficient reduction of O2 to water is a central challenge in energy conversion and many aerobic oxidation reactions. Here, we show that the electrochemical oxygen reduction reaction (ORR) can be achieved at high potentials by using soluble organic nitroxyl and nitrogen oxide (NOx) mediators. When used alone, neither organic nitroxyls, such as 2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl (TEMPO), nor NOx species, such as sodium nitrite, are effective ORR mediators. The combination of nitroxyl/NOx species, however, mediates sustained O2 reduction with overpotentials as low as 300 mV in acetonitrile containing trifluoroacetic acid. Mechanistic analysis of the coupled redox reactions supports a process in which the nitrogen oxide catalyst drives aerobic oxidation of a nitroxyl mediator to an oxoammonium species, which then is reduced back to the nitroxyl at the cathode. The electrolysis potential is dictated by the oxoammonium/nitroxyl reduction potential. The overpotentials accessible with this ORR system are significantly lower than widely studied molecular metal-macrocycle ORR catalysts and benefit from the mechanism-based specificity for four-electron reduction of oxygen to water mediated by NOx species, together with kinetically efficient reduction of oxidized NOx species by TEMPO and other organic nitroxyls.

Authors:
 [1];  [1]
+ Show Author Affiliations
  1. Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1194822
Alternate Identifier(s):
OSTI ID: 1370628
Grant/Contract Number:  
AC05-76RL01830
Resource Type:
Published Article
Journal Name:
ACS Central Science
Additional Journal Information:
Journal Name: ACS Central Science Journal Volume: 1 Journal Issue: 5; Journal ID: ISSN 2374-7943
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous); catalysis (heterogeneous); solar (fuels); bio-inspired; energy storage (including batteries and capacitors); hydrogen and fuel cells; charge transport; materials and chemistry by design; synthesis (novel materials); oxidation reactions; catalysts; redox reactions; oxidation electrodes

Citation Formats

Gerken, James B., and Stahl, Shannon S. High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis. United States: N. p., 2015. Web. doi:10.1021/acscentsci.5b00163.
Copy to clipboard
Gerken, James B., & Stahl, Shannon S. High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis. United States. https://doi.org/10.1021/acscentsci.5b00163
Copy to clipboard
Gerken, James B., and Stahl, Shannon S. Wed . "High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis". United States. https://doi.org/10.1021/acscentsci.5b00163.
Copy to clipboard
@article{osti_1194822,
title = {High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis},
author = {Gerken, James B. and Stahl, Shannon S.},
abstractNote = {Efficient reduction of O2 to water is a central challenge in energy conversion and many aerobic oxidation reactions. Here, we show that the electrochemical oxygen reduction reaction (ORR) can be achieved at high potentials by using soluble organic nitroxyl and nitrogen oxide (NOx) mediators. When used alone, neither organic nitroxyls, such as 2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl (TEMPO), nor NOx species, such as sodium nitrite, are effective ORR mediators. The combination of nitroxyl/NOx species, however, mediates sustained O2 reduction with overpotentials as low as 300 mV in acetonitrile containing trifluoroacetic acid. Mechanistic analysis of the coupled redox reactions supports a process in which the nitrogen oxide catalyst drives aerobic oxidation of a nitroxyl mediator to an oxoammonium species, which then is reduced back to the nitroxyl at the cathode. The electrolysis potential is dictated by the oxoammonium/nitroxyl reduction potential. The overpotentials accessible with this ORR system are significantly lower than widely studied molecular metal-macrocycle ORR catalysts and benefit from the mechanism-based specificity for four-electron reduction of oxygen to water mediated by NOx species, together with kinetically efficient reduction of oxidized NOx species by TEMPO and other organic nitroxyls.},
doi = {10.1021/acscentsci.5b00163},
journal = {ACS Central Science},
number = 5,
volume = 1,
place = {United States},
year = {Wed Jul 15 00:00:00 EDT 2015},
month = {Wed Jul 15 00:00:00 EDT 2015}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acscentsci.5b00163
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 76 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NO x Catalyst System
journal, October 2013

  • Lauber, Markus B.; Stahl, Shannon S.
  • ACS Catalysis, Vol. 3, Issue 11
  • DOI: 10.1021/cs400746m

Determination of Rate Constants in Second-Order Kinetics Using UV-Visible Spectroscopy
journal, January 2001

  • Bijlsma, Sabina; Boelens, Hans F. M.; Smilde, Age K.
  • Applied Spectroscopy, Vol. 55, Issue 1
  • DOI: 10.1366/0003702011951281

Aerobic oxidation catalysis with stable radicals
journal, January 2014

  • Cao, Qun; Dornan, Laura M.; Rogan, Luke
  • Chem. Commun., Vol. 50, Issue 35
  • DOI: 10.1039/C3CC47081D

Spectroscopic and Optimization Modeling Study of Nitrous Acid in Aqueous Solution
journal, February 2005

  • Riordan, Eoin; Minogue, Nicholas; Healy, David
  • The Journal of Physical Chemistry A, Vol. 109, Issue 5
  • DOI: 10.1021/jp040269v

Potent catalysis of the electroreduction of oxygen to water by dicobalt porphyrin dimers adsorbed on graphite electrodes
journal, July 1979

  • Collman, James P.; Marrocco, Matt; Denisevich, Peter
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 101, Issue 1
  • DOI: 10.1016/S0022-0728(79)80085-6

Multicopper Models for the Laccase Active Site: Effect of Nuclearity on Electrocatalytic Oxygen Reduction
journal, July 2014

  • Tse, Edmund C. M.; Schilter, David; Gray, Danielle L.
  • Inorganic Chemistry, Vol. 53, Issue 16
  • DOI: 10.1021/ic501080c

From Structural Models of Galactose Oxidase to Homogeneous Catalysis: Efficient Aerobic Oxidation of Alcohols
journal, September 1998

Electrode catalysis of the four-electron reduction of oxygen to water by dicobalt face-to-face porphyrins
journal, September 1980

  • Collman, James P.; Denisevich, Peter; Konai, Yutaka
  • Journal of the American Chemical Society, Vol. 102, Issue 19
  • DOI: 10.1021/ja00539a009

Role of Proton-Coupled Electron Transfer in O–O Bond Activation
journal, July 2007

  • Rosenthal, Joel; Nocera, Daniel G.
  • Accounts of Chemical Research, Vol. 40, Issue 7
  • DOI: 10.1021/ar7000638

Isolation of Functionalized Phenolic Monomers through Selective Oxidation and CO Bond Cleavage of the β-O-4 Linkages in Lignin
journal, November 2014

  • Lancefield, Christopher S.; Ojo, O. Stephen; Tran, Fanny
  • Angewandte Chemie International Edition, Vol. 54, Issue 1
  • DOI: 10.1002/anie.201409408

Aerobic Alcohol Oxidations Mediated by Nitric Acid
journal, October 2011

  • Aellig, Christof; Girard, Christophe; Hermans, Ive
  • Angewandte Chemie International Edition, Vol. 50, Issue 51
  • DOI: 10.1002/anie.201105620

Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant
journal, January 2009

  • Gligorich, Keith M.; Sigman, Matthew S.
  • Chemical Communications, Issue 26
  • DOI: 10.1039/b902868d

Electronic effects in transition metal porphyrins. 2. The sensitivity of redox and ligand addition reactions in para-substituted tetraphenylporphyrin complexes of cobalt(II)
journal, June 1976

  • Walker, F. Ann; Beroiz, D.; Kadish, K. M.
  • Journal of the American Chemical Society, Vol. 98, Issue 12
  • DOI: 10.1021/ja00428a016

Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs
journal, March 2005

  • Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar
  • Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35
  • DOI: 10.1016/j.apcatb.2004.06.021

Electrocatalytic O 2 Reduction by Covalently Immobilized Mononuclear Copper(I) Complexes: Evidence for a Binuclear Cu 2 O 2 Intermediate
journal, March 2011

  • McCrory, Charles C. L.; Devadoss, Anando; Ottenwaelder, Xavier
  • Journal of the American Chemical Society, Vol. 133, Issue 11
  • DOI: 10.1021/ja106338h

Analysis of Porphyrines as Catalysts for Electrochemical Reduction of O 2 and Oxidation of H 2 O
journal, January 2014

  • Baran, Jakub D.; Grönbeck, Henrik; Hellman, Anders
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja4060299

Catalytic Activity of Biscobalt Porphyrin-Corrole Dyads Toward the Reduction of Dioxygen
journal, March 2009

  • Kadish, Karl M.; Frémond, Laurent; Shen, Jing
  • Inorganic Chemistry, Vol. 48, Issue 6
  • DOI: 10.1021/ic802092n

Anaerobic Nitroxide-Catalyzed Oxidation of Alcohols Using the NO + /NO· Redox Pair
journal, December 2013

  • Holan, Martin; Jahn, Ullrich
  • Organic Letters, Vol. 16, Issue 1
  • DOI: 10.1021/ol403016p

Oxygen carrier and redox properties of some neutral cobalt chelates. Axial and in-plane ligand effects
journal, January 1974

  • Carter, Mark J.; Rillema, D. Paul; Basolo, Fred
  • Journal of the American Chemical Society, Vol. 96, Issue 2, p. 392-400
  • DOI: 10.1021/ja00809a012

Mechanistic Insight into Aerobic Alcohol Oxidation Using NO x –Nitroxide Catalysis Based on Catalyst Structure–Activity Relationships
journal, October 2014

  • Shibuya, Masatoshi; Nagasawa, Shota; Osada, Yuji
  • The Journal of Organic Chemistry, Vol. 79, Issue 21
  • DOI: 10.1021/jo501862k

High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis
journal, October 2009

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach
journal, April 2008

  • Piera, Julio; Bäckvall, Jan-E.
  • Angewandte Chemie International Edition, Vol. 47, Issue 19
  • DOI: 10.1002/anie.200700604

Kinetics and mechanism of the comproportionation reaction between oxoammonium cation and hydroxylamine derived from cyclic nitroxides
journal, February 2005

Nitrogen Cycle Electrocatalysis
journal, June 2009

  • Rosca, Victor; Duca, Matteo; de Groot, Matheus T.
  • Chemical Reviews, Vol. 109, Issue 6
  • DOI: 10.1021/cr8003696

Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile
journal, June 2012

  • Roberts, John A. S.; Bullock, R. Morris
  • Inorganic Chemistry, Vol. 52, Issue 7
  • DOI: 10.1021/ic302461q

Study of the Kinetics of Vanadium Redox Reaction by Rotating Disk Electrode
journal, October 2011

  • Wu, Chun-Hsing; Liao, Hsin-Yi; Hsueh, Kan-Lin
  • ECS Transactions, Vol. 35, Issue 32
  • DOI: 10.1149/1.3655684

Organic Nitrosonium Salts. II. Stability Studies and Oxidations of Some Indole Derivatives
journal, January 1990

  • M. Bobbitt, James; M. Bobbitt, James; Cecile Flores Guttermuth, M.
  • HETEROCYCLES, Vol. 30, Issue 2
  • DOI: 10.3987/COM-89-S112

Mechanistic Study of Alcohol Oxidation by the Pd(OAc) 2 /O 2 /DMSO Catalyst System and Implications for the Development of Improved Aerobic Oxidation Catalysts
journal, February 2002

  • Steinhoff, Bradley A.; Fix, Shannon R.; Stahl, Shannon S.
  • Journal of the American Chemical Society, Vol. 124, Issue 5
  • DOI: 10.1021/ja016806w

2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)/tert-Butyl Nitrite/Oxygen: A Versatile Catalytic Oxidation System
journal, November 2011

  • Shen, Zhenlu; Dai, Jialiang; Xiong, Jie
  • Advanced Synthesis & Catalysis, Vol. 353, Issue 16
  • DOI: 10.1002/adsc.201100429

Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin
journal, April 2013

  • Rahimi, Alireza; Azarpira, Ali; Kim, Hoon
  • Journal of the American Chemical Society, Vol. 135, Issue 17, p. 6415-6418
  • DOI: 10.1021/ja401793n

Recommendations on reporting electrode potentials in nonaqueous solvents (Provisional)
journal, January 1982

Reduction Potentials of One‐Electron Couples Involving Free Radicals in Aqueous Solution
journal, October 1989

  • Wardman, Peter
  • Journal of Physical and Chemical Reference Data, Vol. 18, Issue 4
  • DOI: 10.1063/1.555843

Mechanistic aspects of the catalytic reduction of dioxygen by cofacial metalloporphyrins
journal, May 1983

  • Durand, Richard R.; Bencosme, C. Susana; Collman, James P.
  • Journal of the American Chemical Society, Vol. 105, Issue 9
  • DOI: 10.1021/ja00347a032

Molecular Oxygen To Regenerate PdII Active Species
journal, October 2006

Highly Efficient Catalytic Aerobic Oxidations of Benzylic Alcohols in Water
journal, January 2005

  • Liu, Renhua; Dong, Chunyan; Liang, Xinmiao
  • The Journal of Organic Chemistry, Vol. 70, Issue 2
  • DOI: 10.1021/jo048369k

Palladium-catalyzed aerobic acetoxylation of benzene using NOx-based redox mediators
journal, September 2015

Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry
journal, January 2011

  • Dogutan, Dilek K.; Stoian, Sebastian A.; McGuire, Robert
  • Journal of the American Chemical Society, Vol. 133, Issue 1
  • DOI: 10.1021/ja108904s

Combined Redox Couples for Catalytic Oxidation of Methane by Dioxygen at Low Temperatures
journal, December 2006

  • An, Zengjian; Pan, Xiulian; Liu, Xiumei
  • Journal of the American Chemical Society, Vol. 128, Issue 50
  • DOI: 10.1021/ja0647912

Cobalt(III) Corroles as Electrocatalysts for the Reduction of Dioxygen:  Reactivity of a Monocorrole, Biscorroles, and Porphyrin−Corrole Dyads
journal, April 2005

  • Kadish, Karl M.; Frémond, Laurent; Ou, Zhongping
  • Journal of the American Chemical Society, Vol. 127, Issue 15
  • DOI: 10.1021/ja0501060

Efficient reduction of dioxygen with ferrocene derivatives, catalyzed by metalloporphyrins in the presence of perchloric acid
journal, June 1989

  • Fukuzumi, Shunichi; Mochizuki, Seiji; Tanaka, Toshio
  • Inorganic Chemistry, Vol. 28, Issue 12
  • DOI: 10.1021/ic00311a042

The Aerobic Oxidation of a Pd(II) Dimethyl Complex Leads to Selective Ethane Elimination from a Pd(III) Intermediate
journal, January 2012

  • Khusnutdinova, Julia R.; Rath, Nigam P.; Mirica, Liviu M.
  • Journal of the American Chemical Society, Vol. 134, Issue 4
  • DOI: 10.1021/ja210841f

Dioxygen activation by an organometallic Pd( ii ) precursor: formation of a Pd( iv )–OH complex and its C–O bond formation reactivity
journal, January 2014

  • Qu, Fengrui; Khusnutdinova, Julia R.; Rath, Nigam P.
  • Chem. Commun., Vol. 50, Issue 23
  • DOI: 10.1039/C3CC49387C

Aerobic Palladium-Catalyzed Dioxygenation of Alkenes Enabled by Catalytic Nitrite
journal, November 2014

  • Wickens, Zachary K.; Guzmán, Pablo E.; Grubbs, Robert H.
  • Angewandte Chemie International Edition, Vol. 54, Issue 1
  • DOI: 10.1002/anie.201408650

Biochemistry of nitric oxide and its redox-activated forms
journal, December 1992

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
journal, July 2008

  • Savéant, Jean-Michel
  • Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378
  • DOI: 10.1021/cr068079z

Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion
journal, December 2013

  • Katsounaros, Ioannis; Cherevko, Serhiy; Zeradjanin, Aleksandar R.
  • Angewandte Chemie International Edition, Vol. 53, Issue 1
  • DOI: 10.1002/anie.201306588

Bimetallic Redox Synergy in Oxidative Palladium Catalysis
journal, October 2011

  • Powers, David C.; Ritter, Tobias
  • Accounts of Chemical Research, Vol. 45, Issue 6
  • DOI: 10.1021/ar2001974

Reactions of Nitric Oxide, Peroxynitrite, and Carbonate Radicals with Nitroxides and Their Corresponding Oxoammonium Cations
journal, February 2004

  • Goldstein, Sara; Samuni, Amram; Merenyi, Gabor
  • Chemical Research in Toxicology, Vol. 17, Issue 2
  • DOI: 10.1021/tx0342363

Electron transfer between azide and chlorine dioxide: the effect of solvent barrier nonadditivity
journal, May 1993

  • Awad, H. H.; Stanbury, D. M.
  • Journal of the American Chemical Society, Vol. 115, Issue 9
  • DOI: 10.1021/ja00062a030

Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals by Direct Dioxygen-Coupled Turnover
journal, June 2004

Redox equilibria of the nitrosonium cation and of its nonbonded complexes
journal, October 1990

  • Lee, K. Y.; Kuchynka, D. J.; Kochi, Jay K.
  • Inorganic Chemistry, Vol. 29, Issue 21
  • DOI: 10.1021/ic00346a008

Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays
journal, March 2012

  • Carver, Colin T.; Matson, Benjamin D.; Mayer, James M.
  • Journal of the American Chemical Society, Vol. 134, Issue 12
  • DOI: 10.1021/ja211987f

Electrocatalysis of oxygen reduction. 5. Oxygen to hydrogen peroxide conversion by cobalt(II) tetrakis(N-methyl-4-pyridyl)porphyrin
journal, November 1985

  • Chan, Ray J. H.; Su, Y. Oliver; Kuwana, Theodore
  • Inorganic Chemistry, Vol. 24, Issue 23
  • DOI: 10.1021/ic00217a017

On the Theory of Electron‐Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions
journal, July 1965

  • Marcus, R. A.
  • The Journal of Chemical Physics, Vol. 43, Issue 2
  • DOI: 10.1063/1.1696792

Novel Multinuclear Catalysts for the Electroreduction of Dioxygen Directly to Water
journal, November 1997

  • Anson, Fred C.; Shi, Chunnian; Steiger, Beat
  • Accounts of Chemical Research, Vol. 30, Issue 11
  • DOI: 10.1021/ar960264j

Functional Analogues of Cytochrome c Oxidase, Myoglobin, and Hemoglobin
journal, February 2004

  • Collman, James P.; Boulatov, Roman; Sunderland, Christopher J.
  • Chemical Reviews, Vol. 104, Issue 2
  • DOI: 10.1021/cr0206059

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
journal, February 2010

  • Lyons, Thomas W.; Sanford, Melanie S.
  • Chemical Reviews, Vol. 110, Issue 2
  • DOI: 10.1021/cr900184e

Sustainable, mild and efficient p-methoxybenzyl ether deprotections utilizing catalytic DDQ
journal, October 2014

Biphasic Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water, and Oxygen Catalyzed by Palladium Complexes with Bidentate Nitrogen Ligands
journal, March 1999

Electrocatalytic reduction of molecular oxygen using non-planar cobalt tetrakis-(4-sulfonatophenyl)-β-octabromoporphyrin
journal, April 1997

  • D'Souza, Francis; Hsieh, Yi-Ying; Deviprasad, G. R.
  • Journal of Electroanalytical Chemistry, Vol. 426, Issue 1-2
  • DOI: 10.1016/S0022-0728(97)00040-5

Efficient Two-Electron Reduction of Dioxygen to Hydrogen Peroxide with One-Electron Reductants with a Small Overpotential Catalyzed by a Cobalt Chlorin Complex
journal, February 2013

  • Mase, Kentaro; Ohkubo, Kei; Fukuzumi, Shunichi
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja312199h

Redox catalysis in organic electrosynthesis: basic principles and recent developments
journal, January 2014

  • Francke, Robert; Little, R. Daniel
  • Chemical Society Reviews, Vol. 43, Issue 8
  • DOI: 10.1039/c3cs60464k

Pulsradiolytische Beobachtungen über die Reduktion des NO 3 − -Ions und über Bildung und Zerfall der persalpetrigen Säure in wäßriger Lösung
journal, March 1970

  • Grätzel, M.; Henglein, A.; Taniguchi, S.
  • Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 74, Issue 3
  • DOI: 10.1002/bbpc.19700740322

Homogeneous catalysis of the electrochemical reduction of dioxygen by a macrocyclic cobalt(III) complex
journal, December 1981

  • Geiger, Thomas; Anson, Fred C.
  • Journal of the American Chemical Society, Vol. 103, Issue 25
  • DOI: 10.1021/ja00415a016

Dinitrogen trioxide. Part XI. The electronic spectrum of dinitrogen trioxide
journal, January 1972

  • Shaw, A. W.; Vosper, A. J.
  • Journal of the Chemical Society, Dalton Transactions, Issue 8-9
  • DOI: 10.1039/dt9720000961

The NO2 absorption spectrum. I: Absorption cross-sections at ambient temperature in the 300?500 nm region
journal, March 1995

  • M�rienne, M. F.; Jenouvrier, A.; Coquart, B.
  • Journal of Atmospheric Chemistry, Vol. 20, Issue 3
  • DOI: 10.1007/BF00694498

Accurate Rate Constants for Decomposition of Aqueous Nitrous Acid
journal, January 2012

  • Rayson, Mark S.; Mackie, John C.; Kennedy, Eric M.
  • Inorganic Chemistry, Vol. 51, Issue 4
  • DOI: 10.1021/ic202081z

Exploration of gas sensing possibilities with edge plane pyrolytic graphite electrodes: nitrogen dioxide detection
journal, January 2005

  • Banks, Craig E.; Goodwin, Alexander; Heald, Charles G. R.
  • The Analyst, Vol. 130, Issue 3
  • DOI: 10.1039/b416715e

Nitrate as a redox co-catalyst for the aerobic Pd-catalyzed oxidation of unactivated sp3-C–H bonds
journal, January 2012

  • Stowers, Kara J.; Kubota, Asako; Sanford, Melanie S.
  • Chemical Science, Vol. 3, Issue 11
  • DOI: 10.1039/c2sc20800h

The NO2 Absorption Spectrum. IV: The 200–400 nm Region at 220 K
journal, January 1997

  • Merienne, M. F.; Jenouvrier, A.; Coquart, B.
  • Journal of Atmospheric Chemistry, Vol. 27, Issue 3, p. 219-232
  • DOI: 10.1023/A:1005829213463

Molecular Catalysts for Multielectron Redox Reactions of Small Molecules: The“Cofacial Metallodiporphyrin” Approach
journal, September 1994

  • Collman, James P.; Wagenknecht, Paul S.; Hutchison, James E.
  • Angewandte Chemie International Edition in English, Vol. 33, Issue 1516
  • DOI: 10.1002/anie.199415371

The NO2 absorption spectrum. II. Absorption cross-sections at low temperatures in the 400?500 nm region
journal, July 1995

  • Coquart, B.; Jenouvrier, A.; Merienne, M. F.
  • Journal of Atmospheric Chemistry, Vol. 21, Issue 3
  • DOI: 10.1007/BF00696757

The use of cyclic nitroxide radicals as HNO scavengers
journal, January 2013

Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin
journal, January 2000

  • Chang, Christopher J.; Deng, Yongqi; Nocera, Daniel G.
  • Chemical Communications, Issue 15
  • DOI: 10.1039/b001620i

H 2 Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation
journal, November 2010

  • Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc
  • Inorganic Chemistry, Vol. 49, Issue 22
  • DOI: 10.1021/ic101187v

Reaction of Cyclic Nitroxides with Nitrogen Dioxide:  The Intermediacy of the Oxoammonium Cations
journal, July 2003

  • Goldstein, Sara; Samuni, Amram; Russo, Angelo
  • Journal of the American Chemical Society, Vol. 125, Issue 27
  • DOI: 10.1021/ja035286x

Highly Efficient, Organocatalytic Aerobic Alcohol Oxidation
journal, May 2011

  • Shibuya, Masatoshi; Osada, Yuji; Sasano, Yusuke
  • Journal of the American Chemical Society, Vol. 133, Issue 17
  • DOI: 10.1021/ja110940c

Nitroxide-catalyzed transition-metal-free aerobic oxidation processes
journal, January 2013

  • Wertz, Sebastian; Studer, Armido
  • Green Chemistry, Vol. 15, Issue 11
  • DOI: 10.1039/c3gc41459k

A chemically regenerative redox fuel cell. II
journal, July 1985

  • Kummer, J. T.; Oei, D. -G.
  • Journal of Applied Electrochemistry, Vol. 15, Issue 4
  • DOI: 10.1007/BF01059304

Autoxidation kinetics of aqueous nitric oxide
journal, July 1993

Electroreduction of oxygen by pillared cobalt(II) cofacial diporphyrin catalysts
journal, May 1984

  • Chang, C. K.; Liu, H. Y.; Abdalmuhdi, I.
  • Journal of the American Chemical Society, Vol. 106, Issue 9
  • DOI: 10.1021/ja00321a055

Transition-Metal-Free:  A Highly Efficient Catalytic Aerobic Alcohol Oxidation Process
journal, April 2004

  • Liu, Renhua; Liang, Xinmiao; Dong, Chunyan
  • Journal of the American Chemical Society, Vol. 126, Issue 13
  • DOI: 10.1021/ja031765k

Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation
journal, January 2013

  • Hoover, Jessica M.; Ryland, Bradford L.; Stahl, Shannon S.
  • Journal of the American Chemical Society, Vol. 135, Issue 6
  • DOI: 10.1021/ja3117203

A Redox Fuel Cell That Operates with Methane as Fuel at 120 C
journal, September 1994

    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: