Title: Ordered and disordered polymorphs of Na(Ni_2/3Sb_1/3)O₂: Honeycomb-ordered cathodes for Na-ion batteries

Abstract

Na-ion batteries are appealing alternatives to Li-ion battery systems for large-scale energy storage applications in which elemental cost and abundance are important. Although it is difficult to find Na-ion batteries which achieve substantial specific capacities at voltages above 3 V (vs Na⁺/Na), the honeycomb-layered compound Na(Ni_2/3Sb_1/3)O₂ can deliver up to 130 mAh/g of capacity at voltages above 3 V with this capacity concentrated in plateaus at 3.27 and 3.64 V. Comprehensive crystallographic studies have been carried out in order to understand the role of disorder in this system which can be prepared in both “disordered” and “ordered” forms, depending on the synthesis conditions. The average structure of Na(Ni_2/3Sb_1/3)O₂ is always found to adopt an O3-type stacking sequence, though different structures for the disordered (R3¯m, #166, a = b = 3.06253(3) Å and c = 16.05192(7) Å) and ordered variants (C2/m, #12, a = 5.30458(1) Å, b = 9.18432(1) Å, c = 5.62742(1) Å and β = 108.2797(2)°) are demonstrated through the combined Rietveld refinement of synchrotron X-ray and time-of-flight neutron powder diffraction data. However, pair distribution function studies find that the local structure of disordered Na(Ni_2/3Sb_1/3)O₂ is more correctly described using the honeycomb-ordered structural model, and solid state NMR studiesmore » confirm that the well-developed honeycomb ordering of Ni and Sb cations within the transition metal layers is indistinguishable from that of the ordered phase. The disorder is instead found to mainly occur perpendicular to the honeycomb layers with an observed coherence length of not much more than 1 nm seen in electron diffraction studies. When the Na environment is probed through ²³Na solid state NMR, no evidence is found for prismatic Na environments, and a bulk diffraction analysis finds no evidence of conventional stacking faults. The lack of long range coherence is instead attributed to disorder among the three possible choices for distributing Ni and Sb cations into a honeycomb lattice in each transition metal layer. It is observed that the full theoretical discharge capacity expected for a Ni³⁺/²⁺ redox couple (133 mAh/g) can be achieved for the ordered variant but not for the disordered variant (~110 mAh/g). The first 3.27 V plateau during charging is found to be associated with a two-phase O3 ↔ P3 structural transition, with the P3 stacking sequence persisting throughout all further stages of desodiation.« less

Authors:

Ma, Jeffrey ^[1]; Wu, Lijun ^[2]; Bo, Shou -Hang ^[1]; Khalifah, Peter G. ^[3]; Grey, Clare P. ^[4]; Zhu, Yimei ^[2]

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+ Show Author Affiliations

1. Stony Brook Univ., Stony Brook, NY (United States)
2. Brookhaven National Lab. (BNL), Upton, NY (United States)
3. Brookhaven National Lab. (BNL), Upton, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
4. Stony Brook Univ., Stony Brook, NY (United States); Cambridge Univ. (United Kingdom)

Publication Date:

2015-04-14

Research Org.:

Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:

USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:

1193224

Report Number(s):

BNL-108109-2015-JA
Journal ID: ISSN 0897-4756; R&D Project: MA015MACA; KC0201010

Grant/Contract Number:  

SC00112704

Resource Type:

Accepted Manuscript

Journal Name:

Chemistry of Materials

Additional Journal Information:

Journal Volume: 27; Journal Issue: 7; Journal ID: ISSN 0897-4756

Publisher:

American Chemical Society (ACS)

Country of Publication:

United States

Language:

English

Subject:

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Na-ion batteries; Na₃Ni₂SbO₆; α-NaFeO₂; honeycomb ordering; layered oxides; cathode