Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus
Abstract
As a new two-dimensional layered material, black phosphorus (BP) is a very promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to characterize and understand low-frequency (LF) interlayer breathing modes (<100 cm-1) in few-layer BP for the first time. Using laser polarization dependence study and group theory analysis the breathing modes are assigned to Ag symmetry. Compared to the high-frequency (HF) Raman modes, the LF breathing modes are considerably more sensitive to interlayer coupling and thus their frequencies show stronger dependence on the number of layers. Hence, they constitute an effective means to probe both the crystalline orientation and thickness of few-layer BP. Furthermore, the temperature dependence shows that the breathing modes have a harmonic behavior, in contrast to HF Raman modes which exhibit anharmonicity.
- Authors:
-
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS) and Computer Science and Mathematics Div.
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1185959
- Grant/Contract Number:
- AC05-00OR22725; SC0001299; FG02-09ER46577
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 15; Journal Issue: 6; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Ling, Xi, Liang, Liangbo, Huang, Shengxi, Puretzky, Alexander A., Geohegan, David B., Sumpter, Bobby G., Kong, Jing, Meunier, Vincent, and Dresselhaus, Mildred S. Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus. United States: N. p., 2015.
Web. doi:10.1021/acs.nanolett.5b01117.
Ling, Xi, Liang, Liangbo, Huang, Shengxi, Puretzky, Alexander A., Geohegan, David B., Sumpter, Bobby G., Kong, Jing, Meunier, Vincent, & Dresselhaus, Mildred S. Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus. United States. https://doi.org/10.1021/acs.nanolett.5b01117
Ling, Xi, Liang, Liangbo, Huang, Shengxi, Puretzky, Alexander A., Geohegan, David B., Sumpter, Bobby G., Kong, Jing, Meunier, Vincent, and Dresselhaus, Mildred S. Fri .
"Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus". United States. https://doi.org/10.1021/acs.nanolett.5b01117. https://www.osti.gov/servlets/purl/1185959.
@article{osti_1185959,
title = {Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus},
author = {Ling, Xi and Liang, Liangbo and Huang, Shengxi and Puretzky, Alexander A. and Geohegan, David B. and Sumpter, Bobby G. and Kong, Jing and Meunier, Vincent and Dresselhaus, Mildred S.},
abstractNote = {As a new two-dimensional layered material, black phosphorus (BP) is a very promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to characterize and understand low-frequency (LF) interlayer breathing modes (<100 cm-1) in few-layer BP for the first time. Using laser polarization dependence study and group theory analysis the breathing modes are assigned to Ag symmetry. Compared to the high-frequency (HF) Raman modes, the LF breathing modes are considerably more sensitive to interlayer coupling and thus their frequencies show stronger dependence on the number of layers. Hence, they constitute an effective means to probe both the crystalline orientation and thickness of few-layer BP. Furthermore, the temperature dependence shows that the breathing modes have a harmonic behavior, in contrast to HF Raman modes which exhibit anharmonicity.},
doi = {10.1021/acs.nanolett.5b01117},
journal = {Nano Letters},
number = 6,
volume = 15,
place = {United States},
year = {Fri May 08 00:00:00 EDT 2015},
month = {Fri May 08 00:00:00 EDT 2015}
}
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