Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping

Authors:
 [1];  [1];  [1]
+ Show Author Affiliations
  1. Radiation Laboratory, Departments of Chemistry & Biochemistry and Chemical & Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1183809
Grant/Contract Number:  
FC02-04ER15533
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry Letters
Additional Journal Information:
Journal Name: Journal of Physical Chemistry Letters Journal Volume: 6 Journal Issue: 11; Journal ID: ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Christians, Jeffrey A., Manser, Joseph S., and Kamat, Prashant V. Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping. United States: N. p., 2015. Web. doi:10.1021/acs.jpclett.5b00594.
Copy to clipboard
Christians, Jeffrey A., Manser, Joseph S., & Kamat, Prashant V. Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping. United States. https://doi.org/10.1021/acs.jpclett.5b00594
Copy to clipboard
Christians, Jeffrey A., Manser, Joseph S., and Kamat, Prashant V. Thu . "Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping". United States. https://doi.org/10.1021/acs.jpclett.5b00594.
Copy to clipboard
@article{osti_1183809,
title = {Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping},
author = {Christians, Jeffrey A. and Manser, Joseph S. and Kamat, Prashant V.},
abstractNote = {},
doi = {10.1021/acs.jpclett.5b00594},
journal = {Journal of Physical Chemistry Letters},
number = 11,
volume = 6,
place = {United States},
year = {Thu May 21 00:00:00 EDT 2015},
month = {Thu May 21 00:00:00 EDT 2015}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.jpclett.5b00594
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 108 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

The Role of Intrinsic Defects in Methylammonium Lead Iodide Perovskite
journal, March 2014

  • Kim, Jongseob; Lee, Sung-Hoon; Lee, Jung Hoon
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 8
  • DOI: 10.1021/jz500370k

Giant Photoluminescence Blinking of Perovskite Nanocrystals Reveals Single-Trap Control of Luminescence
journal, February 2015

  • Tian, Yuxi; Merdasa, Aboma; Peter, Maximilian
  • Nano Letters, Vol. 15, Issue 3
  • DOI: 10.1021/nl5041397

Reversible Hydration of CH 3 NH 3 PbI 3 in Films, Single Crystals, and Solar Cells
journal, April 2015

Trap-Assisted Non-Radiative Recombination in Organic-Inorganic Perovskite Solar Cells
journal, February 2015

  • Wetzelaer, Gert-Jan A. H.; Scheepers, Max; Sempere, Araceli Miquel
  • Advanced Materials, Vol. 27, Issue 11
  • DOI: 10.1002/adma.201405372

Preparation and characterization of layered lead halide compounds
journal, March 1991

  • Calabrese, J.; Jones, N. L.; Harlow, R. L.
  • Journal of the American Chemical Society, Vol. 113, Issue 6, p. 2328-2330
  • DOI: 10.1021/ja00006a076

Band filling with free charge carriers in organometal halide perovskites
journal, August 2014

Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility
journal, January 2014

  • You, Jingbi; Hong, Ziruo; Yang, Yang (Michael)
  • ACS Nano, Vol. 8, Issue 2
  • DOI: 10.1021/nn406020d

Enhancement of Perovskite-Based Solar Cells Employing Core–Shell Metal Nanoparticles
journal, August 2013

  • Zhang, Wei; Saliba, Michael; Stranks, Samuel D.
  • Nano Letters, Vol. 13, Issue 9
  • DOI: 10.1021/nl4024287

Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
journal, January 2015

Über die Cäsium- und Kalium-Bleihalogenide
journal, January 1893

Organometal Halide Perovskite Solar Cell Materials Rationalized: Ultrafast Charge Generation, High and Microsecond-Long Balanced Mobilities, and Slow Recombination
journal, February 2014

  • Ponseca, Carlito S.; Savenije, Tom J.; Abdellah, Mohamed
  • Journal of the American Chemical Society, Vol. 136, Issue 14
  • DOI: 10.1021/ja412583t

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Interface engineering of highly efficient perovskite solar cells
journal, July 2014

Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells
journal, January 2014

  • Marchioro, Arianna; Teuscher, Joël; Friedrich, Dennis
  • Nature Photonics, Vol. 8, Issue 3
  • DOI: 10.1038/nphoton.2013.374

Electronic structures of lead iodide based low-dimensional crystals
journal, April 2003

Role of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films
journal, October 2014

  • Williams, Spencer T.; Zuo, Fan; Chueh, Chu-Chen
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn5041922

Electro-optics of perovskite solar cells
journal, December 2014

  • Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju
  • Nature Photonics, Vol. 9, Issue 2
  • DOI: 10.1038/nphoton.2014.284

Charge Trapping in Photovoltaically Active Perovskites and Related Halogenoplumbate Compounds
journal, March 2014

  • Shkrob, Ilya A.; Marin, Timothy W.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 7
  • DOI: 10.1021/jz5004022

Organohalide lead perovskites for photovoltaic applications
journal, January 2014

  • Gao, Peng; Grätzel, Michael; Nazeeruddin, Mohammad K.
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE00942H

Optical properties of PbI-based perovskite structures
journal, April 1994

Solar cell efficiency tables (Version 45): Solar cell efficiency tables
journal, December 2014

  • Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro
  • Progress in Photovoltaics: Research and Applications, Vol. 23, Issue 1
  • DOI: 10.1002/pip.2573

Crystal Structure and Photoconductivity of Cæsium Plumbohalides
journal, November 1958

Anomalous Hysteresis in Perovskite Solar Cells
journal, April 2014

  • Snaith, Henry J.; Abate, Antonio; Ball, James M.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
  • DOI: 10.1021/jz500113x

Investigation of CH 3 NH 3 PbI 3 Degradation Rates and Mechanisms in Controlled Humidity Environments Using in Situ Techniques
journal, January 2015

  • Yang, Jinli; Siempelkamp, Braden D.; Liu, Dianyi
  • ACS Nano, Vol. 9, Issue 2
  • DOI: 10.1021/nn506864k

Effect of Carrier Thermalization Dynamics on Light Emission and Amplification in Organometal Halide Perovskites
journal, December 2014

  • Chen, Kai; Barker, Alex J.; Morgan, Francis L. C.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 1
  • DOI: 10.1021/jz502528c

Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells
journal, April 2014

  • Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico
  • Nano Letters, Vol. 14, Issue 5
  • DOI: 10.1021/nl500390f

Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013

  • Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
  • Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
  • DOI: 10.1021/ic401215x

Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015

Materials Processing Routes to Trap-Free Halide Perovskites
journal, October 2014

  • Buin, Andrei; Pietsch, Patrick; Xu, Jixian
  • Nano Letters, Vol. 14, Issue 11
  • DOI: 10.1021/nl502612m

Influence of moisture on the preparation, crystal structure, and photophysical properties of organohalide perovskites
journal, January 2014

  • Bass, Kelsey K.; McAnally, R. Eric; Zhou, Shiliang
  • Chem. Commun., Vol. 50, Issue 99
  • DOI: 10.1039/C4CC05231E

Transformation of the Excited State and Photovoltaic Efficiency of CH 3 NH 3 PbI 3 Perovskite upon Controlled Exposure to Humidified Air
journal, January 2015

  • Christians, Jeffrey A.; Miranda Herrera, Pierre A.; Kamat, Prashant V.
  • Journal of the American Chemical Society, Vol. 137, Issue 4
  • DOI: 10.1021/ja511132a

Defect density and dielectric constant in perovskite solar cells
journal, October 2014

  • Samiee, Mehran; Konduri, Siva; Ganapathy, Balaji
  • Applied Physics Letters, Vol. 105, Issue 15
  • DOI: 10.1063/1.4897329

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015

Best Practices in Perovskite Solar Cell Efficiency Measurements. Avoiding the Error of Making Bad Cells Look Good
journal, February 2015

  • Christians, Jeffrey A.; Manser, Joseph S.; Kamat, Prashant V.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
  • DOI: 10.1021/acs.jpclett.5b00289

Ultrasmooth organic–inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells
journal, January 2015

  • Zhang, Wei; Saliba, Michael; Moore, David T.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7142

Low-temperature solution-processed wavelength-tunable perovskites for lasing
journal, March 2014

  • Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3911

Photocarrier Recombination Dynamics in Perovskite CH 3 NH 3 PbI 3 for Solar Cell Applications
journal, August 2014

  • Yamada, Yasuhiro; Nakamura, Toru; Endo, Masaru
  • Journal of the American Chemical Society, Vol. 136, Issue 33
  • DOI: 10.1021/ja506624n

High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors
journal, March 2014

  • Deschler, Felix; Price, Michael; Pathak, Sandeep
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 8
  • DOI: 10.1021/jz5005285

Structural and electronic properties of the natural quantum-well system (C6H5CH2CH2NH3)2SnI4
journal, September 1994

Electronic Properties of Meso-Superstructured and Planar Organometal Halide Perovskite Films: Charge Trapping, Photodoping, and Carrier Mobility
journal, June 2014

  • Leijtens, Tomas; Stranks, Samuel D.; Eperon, Giles E.
  • ACS Nano, Vol. 8, Issue 7
  • DOI: 10.1021/nn502115k

Thermally Activated Exciton Dissociation and Recombination Control the Carrier Dynamics in Organometal Halide Perovskite
journal, June 2014

  • Savenije, Tom J.; Ponseca, Carlito S.; Kunneman, Lucas
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
  • DOI: 10.1021/jz500858a

Extremely Slow Photoconductivity Response of CH 3 NH 3 PbI 3 Perovskites Suggesting Structural Changes under Working Conditions
journal, July 2014

  • Gottesman, Ronen; Haltzi, Eynav; Gouda, Laxman
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 15
  • DOI: 10.1021/jz501373f

Unusual defect physics in CH 3 NH 3 PbI 3 perovskite solar cell absorber
journal, February 2014

  • Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa
  • Applied Physics Letters, Vol. 104, Issue 6
  • DOI: 10.1063/1.4864778

Trap States in Lead Iodide Perovskites
journal, January 2015

  • Wu, Xiaoxi; Trinh, M. Tuan; Niesner, Daniel
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja512833n

A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014

  • Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
  • Angewandte Chemie, Vol. 126, Issue 42
  • DOI: 10.1002/ange.201406466

Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
journal, September 2014

Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell
journal, July 2013

  • Park, Nam-Gyu
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 15, p. 2423-2429
  • DOI: 10.1021/jz400892a

Comparative study on the excitons in lead-halide-based perovskite-type crystals CH3NH3PbBr3 CH3NH3PbI3
journal, September 2003

  • Tanaka, Kenichiro; Takahashi, Takayuki; Ban, Takuma
  • Solid State Communications, Vol. 127, Issue 9-10, p. 619-623
  • DOI: 10.1016/S0038-1098(03)00566-0

Excitonic bands in the spectra of some organic-inorganic hybrid compounds based on metal halide units
journal, March 2001

All Solution-Processed Lead Halide Perovskite-BiVO 4 Tandem Assembly for Photolytic Solar Fuels Production
journal, January 2015

  • Chen, Yong-Siou; Manser, Joseph S.; Kamat, Prashant V.
  • Journal of the American Chemical Society, Vol. 137, Issue 2
  • DOI: 10.1021/ja511739y

Correlated electron–hole plasma in organometal perovskites
journal, September 2014

  • Saba, Michele; Cadelano, Michele; Marongiu, Daniela
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6049

Excitons versus free charges in organo-lead tri-halide perovskites
journal, April 2014

  • D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4586

Analysis of Multivalley and Multibandgap Absorption and Enhancement of Free Carriers Related to Exciton Screening in Hybrid Perovskites
journal, May 2014

  • Even, Jacky; Pedesseau, Laurent; Katan, Claudine
  • The Journal of Physical Chemistry C, Vol. 118, Issue 22
  • DOI: 10.1021/jp503337a

Dual nature of the excited state in organic–inorganic lead halide perovskites
journal, January 2015

  • Stamplecoskie, Kevin G.; Manser, Joseph S.; Kamat, Prashant V.
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE02988G

The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells
journal, January 2014

  • Sun, Shuangyong; Salim, Teddy; Mathews, Nripan
  • Energy Environ. Sci., Vol. 7, Issue 1
  • DOI: 10.1039/C3EE43161D

Elucidating the charge carrier separation and working mechanism of CH3NH3PbI3−xClx perovskite solar cells
journal, March 2014

  • Edri, Eran; Kirmayer, Saar; Mukhopadhyay, Sabyasachi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4461

Conducting tin halides with a layered organic-based perovskite structure
journal, June 1994

  • Mitzi, D. B.; Feild, C. A.; Harrison, W. T. A.
  • Nature, Vol. 369, Issue 6480, p. 467-469
  • DOI: 10.1038/369467a0

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications
journal, January 2013

  • Baikie, Tom; Fang, Yanan; Kadro, Jeannette M.
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta10518k

Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic–Inorganic Lead Halide Perovskites
journal, September 2014

  • Noel, Nakita K.; Abate, Antonio; Stranks, Samuel D.
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn5036476

Homogeneous Emission Line Broadening in the Organo Lead Halide Perovskite CH 3 NH 3 PbI 3– x Cl x
journal, March 2014

  • Wehrenfennig, Christian; Liu, Mingzhen; Snaith, Henry J.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 8
  • DOI: 10.1021/jz500434p

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells
journal, March 1961

  • Shockley, William; Queisser, Hans J.
  • Journal of Applied Physics, Vol. 32, Issue 3, p. 510-519
  • DOI: 10.1063/1.1736034

High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites
journal, December 2013

  • Wehrenfennig, Christian; Eperon, Giles E.; Johnston, Michael B.
  • Advanced Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adma.201305172

Pathways for solar photovoltaics
journal, January 2015

  • Jean, Joel; Brown, Patrick R.; Jaffe, Robert L.
  • Energy & Environmental Science, Vol. 8, Issue 4
  • DOI: 10.1039/C4EE04073B

Alkylammonium lead halides. Part 1. Isolated PbI 6 4− ions in (CH 3 NH 3 ) 4 PbI 6 •2H 2 O
journal, May 1987

  • Vincent, Beverly R.; Robertson, Katherine N.; Cameron, T. Stanley
  • Canadian Journal of Chemistry, Vol. 65, Issue 5
  • DOI: 10.1139/v87-176

Rain on Methylammonium Lead Iodide Based Perovskites: Possible Environmental Effects of Perovskite Solar Cells
journal, April 2015

  • Hailegnaw, Bekele; Kirmayer, Saar; Edri, Eran
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 9
  • DOI: 10.1021/acs.jpclett.5b00504

An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide
journal, December 2013

  • Christians, Jeffrey A.; Fung, Raymond C. M.; Kamat, Prashant V.
  • Journal of the American Chemical Society, Vol. 136, Issue 2, p. 758-764
  • DOI: 10.1021/ja411014k

Highly efficient electroluminescence from a heterostructure device combined with emissive layered-perovskite and an electron-transporting organic compound
journal, May 1996

Advancements in perovskite solar cells: photophysics behind the photovoltaics
journal, January 2014

  • Sum, Tze Chien; Mathews, Nripan
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE00673A

Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells
journal, February 2014

  • Dualeh, Amalie; Tétreault, Nicolas; Moehl, Thomas
  • Advanced Functional Materials, Vol. 24, Issue 21, p. 3250-3258
  • DOI: 10.1002/adfm.201304022

Magnetoabsorption of the lowest exciton in perovskite-type compound (CH3NH3)PbI3
journal, July 1994

Formation of Thin Films of Organic-Inorganic Perovskites for High-Efficiency Solar Cells
journal, February 2015

  • Stranks, Samuel D.; Nayak, Pabitra K.; Zhang, Wei
  • Angewandte Chemie International Edition, Vol. 54, Issue 11
  • DOI: 10.1002/anie.201410214

Spectra, equilibrium and photoredox chemistry of iodobismuthate(III) complexes in acetonitrile
journal, June 2000

Parameters Affecting I – V Hysteresis of CH 3 NH 3 PbI 3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO 2 Layer
journal, August 2014

  • Kim, Hui-Seon; Park, Nam-Gyu
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 17
  • DOI: 10.1021/jz501392m

Improvement of the humidity stability of organic–inorganic perovskite solar cells using ultrathin Al2O3 layers prepared by atomic layer deposition
journal, January 2015

  • Dong, Xu; Fang, Xiang; Lv, Minghang
  • Journal of Materials Chemistry A, Vol. 3, Issue 10, p. 5360-5367
  • DOI: 10.1039/C4TA06128D

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013

  • Snaith, Henry J.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630
  • DOI: 10.1021/jz4020162

Tuning the Light Emission Properties by Band Gap Engineering in Hybrid Lead Halide Perovskite
journal, December 2014

  • D’Innocenzo, Valerio; Srimath Kandada, Ajay Ram; De Bastiani, Michele
  • Journal of the American Chemical Society, Vol. 136, Issue 51
  • DOI: 10.1021/ja511198f

Carbon Nanotube/Polymer Composites as a Highly Stable Hole Collection Layer in Perovskite Solar Cells
journal, September 2014

  • Habisreutinger, Severin N.; Leijtens, Tomas; Eperon, Giles E.
  • Nano Letters, Vol. 14, Issue 10, p. 5561-5568
  • DOI: 10.1021/nl501982b
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: