The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]
Abstract
The coefficient of restitution of alkaline batteries had been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive x-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and that the coefficient of restitution saturates at a value of 0.63 ± .05 at 50% state if charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity on in situ energy-dispersive x-ray diffraction spectroscopy.
- Authors:
-
- Princeton Univ., NJ (United States)
- Rutgers Univ., Piscataway, NJ (United States)
- City Univ. of New York Energy Inst., New York, NY (United States)
- City College of New York, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1183288
- Report Number(s):
- BNL-107767-2015-JA
Journal ID: ISSN 2050-7488; JMCAET; YN0100000
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 18; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Bhadra, S., Hertzberg, B. J., Croft, M., Gallaway, J. W., Van Tassell, B. J., Chamoun, M., Erdonmez, C., Zhong, Z., and Steingart, D. A. The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]. United States: N. p., 2015.
Web. doi:10.1039/C5TA01576F.
Bhadra, S., Hertzberg, B. J., Croft, M., Gallaway, J. W., Van Tassell, B. J., Chamoun, M., Erdonmez, C., Zhong, Z., & Steingart, D. A. The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]. United States. https://doi.org/10.1039/C5TA01576F
Bhadra, S., Hertzberg, B. J., Croft, M., Gallaway, J. W., Van Tassell, B. J., Chamoun, M., Erdonmez, C., Zhong, Z., and Steingart, D. A. Fri .
"The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]". United States. https://doi.org/10.1039/C5TA01576F. https://www.osti.gov/servlets/purl/1183288.
@article{osti_1183288,
title = {The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]},
author = {Bhadra, S. and Hertzberg, B. J. and Croft, M. and Gallaway, J. W. and Van Tassell, B. J. and Chamoun, M. and Erdonmez, C. and Zhong, Z. and Steingart, D. A.},
abstractNote = {The coefficient of restitution of alkaline batteries had been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive x-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and that the coefficient of restitution saturates at a value of 0.63 ± .05 at 50% state if charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity on in situ energy-dispersive x-ray diffraction spectroscopy.},
doi = {10.1039/C5TA01576F},
journal = {Journal of Materials Chemistry. A},
number = 18,
volume = 3,
place = {United States},
year = {Fri Mar 13 00:00:00 EDT 2015},
month = {Fri Mar 13 00:00:00 EDT 2015}
}
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Works referencing / citing this record:
Understanding the Dynamics of Primary Zn-MnO 2 Alkaline Battery Gassing with Operando Visualization and Pressure Cells
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Understanding the Dynamics of Primary Zn-MnO2 Alkaline Battery Gassing with Operando Visualization and Pressure Cells
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