Studying localized corrosion using liquid cell transmission electron microscopy

Chee, See Wee; Pratt, Sarah H.; Hattar, Khalid; Duquette, David; Ross, Frances M.; Hull, Robert

doi:10.1039/C4CC06443G

Title: Studying localized corrosion using liquid cell transmission electron microscopy

Abstract

Using liquid cell transmission electron microscopy (LCTEM), localized corrosion of Cu and Al thin films immersed in aqueous NaCl solutions was studied. We demonstrate that potentiostatic control can be used to initiate pitting and that local compositional changes, due to focused ion beam implantation of Au⁺ ions, can modify the corrosion susceptibility of Al films. Likewise, a discussion on strategies to control the onset of pitting is also presented.

Authors:

Chee, See Wee ^[1]; Pratt, Sarah H. ^[2]; Hattar, Khalid ^[2]; Duquette, David ^[1]; Ross, Frances M. ^[3]; Hull, Robert ^[1]

Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Materials Science and Engineering
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
IBM, Yorktown Heights, NY (United States). Thomas J. Watson Research Center

Publication Date:: Fri Nov 07 00:00:00 EST 2014

Research Org.:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1183094

Report Number(s):: SAND-2014-16901J
Journal ID: ISSN 1359-7345; CHCOFS; 536884

Grant/Contract Number:: AC04-94AL85000

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 51; Journal Issue: 1; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Chee, See Wee, Pratt, Sarah H., Hattar, Khalid, Duquette, David, Ross, Frances M., and Hull, Robert. Studying localized corrosion using liquid cell transmission electron microscopy.  United States: N. p., 2014. 
Web.  doi:10.1039/C4CC06443G.

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                    Chee, See Wee, Pratt, Sarah H., Hattar, Khalid, Duquette, David, Ross, Frances M., & Hull, Robert. Studying localized corrosion using liquid cell transmission electron microscopy.  United States.  https://doi.org/10.1039/C4CC06443G

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                    Chee, See Wee, Pratt, Sarah H., Hattar, Khalid, Duquette, David, Ross, Frances M., and Hull, Robert. Fri .  
"Studying localized corrosion using liquid cell transmission electron microscopy".  United States.  https://doi.org/10.1039/C4CC06443G.  https://www.osti.gov/servlets/purl/1183094.

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@article{osti_1183094,

  title        = {Studying localized corrosion using liquid cell transmission electron microscopy},

  author       = {Chee, See Wee and Pratt, Sarah H. and Hattar, Khalid and Duquette, David and Ross, Frances M. and Hull, Robert},

  abstractNote = {Using liquid cell transmission electron microscopy (LCTEM), localized corrosion of Cu and Al thin films immersed in aqueous NaCl solutions was studied. We demonstrate that potentiostatic control can be used to initiate pitting and that local compositional changes, due to focused ion beam implantation of Au+ ions, can modify the corrosion susceptibility of Al films. Likewise, a discussion on strategies to control the onset of pitting is also presented.},

  doi          = {10.1039/C4CC06443G},

  journal      = {ChemComm},

  number       = 1,

  volume       = 51,

  place        = {United States},

  year         = {Fri Nov 07 00:00:00 EST 2014},

  month        = {Fri Nov 07 00:00:00 EST 2014}

}

Copy to clipboard

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Works referenced in this record:

Dynamic microscopy of nanoscale cluster growth at the solid–liquid interface
journal, July 2003

Williamson, M. J.; Tromp, R. M.; Vereecken, P. M.
Nature Materials, Vol. 2, Issue 8
DOI: 10.1038/nmat944

In Situ Electron Energy-Loss Spectroscopy in Liquids
journal, May 2013

Holtz, Megan E.; Yu, Yingchao; Gao, Jie
Microscopy and Microanalysis, Vol. 19, Issue 4
DOI: 10.1017/S1431927613001505

Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes
journal, November 2013

Gu, Meng; Parent, Lucas R.; Mehdi, B. Layla
Nano Letters, Vol. 13, Issue 12
DOI: 10.1021/nl403402q

Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte
journal, February 2014

Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz
Nano Letters, Vol. 14, Issue 3
DOI: 10.1021/nl404577c

Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy
journal, January 2014

Sacci, Robert L.; Dudney, Nancy J.; More, Karren L.
Chemical Communications, Vol. 50, Issue 17
DOI: 10.1039/c3cc49029g

Observation of growth of metal nanoparticles
journal, January 2013

Liao, Hong-Gang; Niu, Kaiyang; Zheng, Haimei
Chemical Communications, Vol. 49, Issue 100
DOI: 10.1039/c3cc47473a

Pitting Corrosion of Metals
journal, January 1998

Frankel, G. S.
Journal of The Electrochemical Society, Vol. 145, Issue 6
DOI: 10.1149/1.1838615

Understanding localized corrosion
journal, October 2008

Frankel, G. S.; Sridhar, N.
Materials Today, Vol. 11, Issue 10
DOI: 10.1016/S1369-7021(08)70206-2

Transmission electron microscopy with a liquid flow cell
journal, January 2011

Klein, K. L.; Anderson, I. M.; De Jonge, N.
Journal of Microscopy, Vol. 242, Issue 2, p. 117-123
DOI: 10.1111/j.1365-2818.2010.03484.x

Electron microscopy of specimens in liquid
journal, October 2011

de Jonge, Niels; Ross, Frances M.
Nature Nanotechnology, Vol. 6, Issue 11, p. 695-704
DOI: 10.1038/nnano.2011.161

X-ray Energy-Dispersive Spectrometry During In Situ Liquid Cell Studies Using an Analytical Electron Microscope
journal, February 2014

Zaluzec, Nestor J.; Burke, M. Grace; Haigh, Sarah J.
Microscopy and Microanalysis, Vol. 20, Issue 2
DOI: 10.1017/S1431927614000154

Real-time imaging and local elemental analysis of nanostructures in liquids
journal, January 2014

Lewis, Edward A.; Haigh, Sarah J.; Slater, Thomas J. A.
Chem. Commun., Vol. 50, Issue 70
DOI: 10.1039/C4CC02743D

Atomic-Scale Imaging and Spectroscopy for In Situ Liquid Scanning Transmission Electron Microscopy
journal, May 2012

Jungjohann, Katherine L.; Evans, James E.; Aguiar, Jeffery A.
Microscopy and Microanalysis, Vol. 18, Issue 3
DOI: 10.1017/S1431927612000104

The pitting corrosion of copper
journal, July 1994

Edwards, Marc; Ferguson, John F.; Reiber, Steve H.
Journal - American Water Works Association, Vol. 86, Issue 7
DOI: 10.1002/j.1551-8833.1994.tb06226.x

Passivity and Pit Stability Behavior of Copper as a Function of Selected Water Chemistry Variables
journal, January 2009

Cong, Hongbo; Michels, Harold T.; Scully, John R.
Journal of The Electrochemical Society, Vol. 156, Issue 1
DOI: 10.1149/1.2999351

Pitting corrosion of copper in chloride solutions
journal, February 2004

El Warraky, A.; El Shayeb, H. A.; Sherif, E. M.
Anti-Corrosion Methods and Materials, Vol. 51, Issue 1
DOI: 10.1108/00035590410512735

Scavenging of es− and OH radicals in concentrated HCl and NaCl aqueous solutions
journal, July 2008

Atinault, E.; De Waele, V.; Schmidhammer, U.
Chemical Physics Letters, Vol. 460, Issue 4-6
DOI: 10.1016/j.cplett.2008.06.048

Products formed from alpha radiolysis of chloride brines
journal, July 2001

Kelm, M.; Bohnert, E.; Pashalidis, I.
Research on Chemical Intermediates, Vol. 27, Issue 4-5
DOI: 10.1163/156856701104202147

Factors influencing quantitative liquid (scanning) transmission electron microscopy
journal, January 2014

Abellan, P.; Woehl, T. J.; Parent, L. R.
Chem. Commun., Vol. 50, Issue 38
DOI: 10.1039/C3CC48479C

Bubble and Pattern Formation in Liquid Induced by an Electron Beam
journal, December 2013

Grogan, Joseph M.; Schneider, Nicholas M.; Ross, Frances M.
Nano Letters, Vol. 14, Issue 1
DOI: 10.1021/nl404169a

Electron–Water Interactions and Implications for Liquid Cell Electron Microscopy
journal, September 2014

Schneider, Nicholas M.; Norton, Michael M.; Mendel, Brian J.
The Journal of Physical Chemistry C, Vol. 118, Issue 38
DOI: 10.1021/jp507400n

Metastable Structures in Al Thin Films Before the Onset of Corrosion Pitting as Observed using Liquid Cell Transmission Electron Microscopy
journal, February 2014

Chee, See Wee; Duquette, David J.; Ross, Frances M.
Microscopy and Microanalysis, Vol. 20, Issue 2
DOI: 10.1017/S1431927614000221

Sequence of steps in the pitting of aluminum by chloride ions
journal, July 2003

McCafferty, E.
Corrosion Science, Vol. 45, Issue 7
DOI: 10.1016/S0010-938X(02)00231-7

Two-dimensional pitting corrosion of aluminium thin layers
journal, August 1995

Balázs, L.; Gouyet, J. -F.
Physica A: Statistical Mechanics and its Applications, Vol. 217, Issue 3-4
DOI: 10.1016/0378-4371(95)00048-C

SRIM – The stopping and range of ions in matter (2010)
journal, June 2010

Ziegler, James F.; Ziegler, M. D.; Biersack, J. P.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12
DOI: 10.1016/j.nimb.2010.02.091

Passivity and Pit Stability Behavior of Copper as a Function of Selected Water Chemistry Variables
journal, August 2009

Cong, Hongbo; Michels, Harold; Scully, John R.
ECS Transactions, Vol. 16, Issue 52
DOI: 10.1149/1.3229963

Pitting Corrosion of Metals
journal, January 2010

Newman, Roger
The Electrochemical Society Interface, Vol. 19, Issue 1
DOI: 10.1149/2.f03101if

Pitting Corrosion of Metals [金属の孔食]
journal, January 1967

Kolotyrkin, Ja. M.
CORROSION ENGINEERING DIGEST, Vol. 16, Issue 1
DOI: 10.3323/jcorr1954.16.1_12

In Situ Electron Energy-Loss Spectroscopy in Liquids
text, January 2012

Holtz, Megan E.; Yu, Yingchao; Gao, Jie
arXiv
DOI: 10.48550/arxiv.1212.1501

Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte
text, January 2013

Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz
arXiv
DOI: 10.48550/arxiv.1311.6490

Works referencing / citing this record:

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journal, August 2019

Hutzler, Andreas; Fritsch, Birk; Jank, Michael P. M.
Advanced Materials Interfaces, Vol. 6, Issue 20
DOI: 10.1002/admi.201901027

In Situ Transmission Electron Microscopy
book, January 2019

Ross, Frances M.; Minor, Andrew M.
Springer Handbook of Microscopy
DOI: 10.1007/978-3-030-00069-1_3

In Situ Transmission Electron Microscopy Studies of Electrochemical Reaction Mechanisms in Rechargeable Batteries
journal, June 2019

Wu, Xiaoyu; Li, Songmei; Yang, Bin
Electrochemical Energy Reviews, Vol. 2, Issue 3
DOI: 10.1007/s41918-019-00046-2

In Situ LC-TEM Studies of Corrosion of Metal Thin Films in Aqueous Solutions
journal, August 2015

Hun Park, Jeung; Wee Chee, See; Kodambaka, Suneel
Microscopy and Microanalysis, Vol. 21, Issue S3
DOI: 10.1017/s1431927615009733

Localized corrosion of low-carbon steel at the nanoscale
journal, April 2019

Hayden, Steven C.; Chisholm, Claire; Grudt, Rachael O.
npj Materials Degradation, Vol. 3, Issue 1
DOI: 10.1038/s41529-019-0078-1

Investigation of the magnetosome biomineralization in magnetotactic bacteria using graphene liquid cell – transmission electron microscopy
journal, January 2019

Firlar, Emre; Ouy, Meagan; Bogdanowicz, Agata
Nanoscale, Vol. 11, Issue 2
DOI: 10.1039/c8nr08647h

The radiation chemistry of focused electron-beam induced etching of copper in liquids
journal, January 2019

Lami, Sarah K.; Smith, Gabriel; Cao, Eric
Nanoscale, Vol. 11, Issue 24
DOI: 10.1039/c9nr01857c

Imaging of soft materials using in situ liquid-cell transmission electron microscopy
journal, January 2019

He, Kun; Shokuhfar, Tolou; Shahbazian-Yassar, Reza
Journal of Physics: Condensed Matter, Vol. 31, Issue 10
DOI: 10.1088/1361-648x/aaf616

High flow rate nanofluidics for in-liquid electron microscopy and diffraction
journal, July 2019

Petruk, Ariel A.; Allen, Caroline; Rivas, Nicolás
Nanotechnology, Vol. 30, Issue 39
DOI: 10.1088/1361-6528/ab2cf2

Liquid cell transmission electron microscopy and its applications
journal, January 2020

Pu, Shengda; Gong, Chen; Robertson, Alex W.
Royal Society Open Science, Vol. 7, Issue 1
DOI: 10.1098/rsos.191204

Opportunities and challenges in liquid cell electron microscopy
journal, December 2015

Ross, F. M.
Science, Vol. 350, Issue 6267
DOI: 10.1126/science.aaa9886

An In Situ Transmission Electron Microscopy Study of Localized Corrosion on Aluminum
journal, January 2016

Pinkowitz, Ainsley; Chee, See Wee; Engler, Brent J.
MRS Advances, Vol. 1, Issue 25
DOI: 10.1557/adv.2016.334

Cryogenic specimens for nanoscale characterization of solid–liquid interfaces
journal, December 2019

Zachman, Michael J.; de Jonge, Niels; Fischer, Robert
MRS Bulletin, Vol. 44, Issue 12
DOI: 10.1557/mrs.2019.289

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Title: Studying localized corrosion using liquid cell transmission electron microscopy

Abstract

Citation Formats

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