Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries
Abstract
High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li1.2Ni0.13Mn0.54Co0.13O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li+ intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achieving around 70% (175 mAhg–1) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.
- Authors:
-
- Beijing Inst. of Technology (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and the Environment
- Beijing Inst. of Technology (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and the Environment; Beijing Higher Institution Engineering Research Center of Power Battery and Chemical Energy Materials (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1182479
- Report Number(s):
- BNL-107272-2014-JA
Journal ID: ISSN 1530-6984; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- AC02-98CH10886; 21443013; 2013AA050903; 2012039032; 20131039031
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 15; Journal Issue: 1; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; national synchrotron light source
Citation Formats
Zhang, Linjing, Li, Ning, Wu, Borong, Xu, Hongliang, Wang, Lei, Yang, Xiao-Qing, and Wu, Feng. Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries. United States: N. p., 2015.
Web. doi:10.1021/nl5041594.
Zhang, Linjing, Li, Ning, Wu, Borong, Xu, Hongliang, Wang, Lei, Yang, Xiao-Qing, & Wu, Feng. Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries. United States. https://doi.org/10.1021/nl5041594
Zhang, Linjing, Li, Ning, Wu, Borong, Xu, Hongliang, Wang, Lei, Yang, Xiao-Qing, and Wu, Feng. Wed .
"Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries". United States. https://doi.org/10.1021/nl5041594. https://www.osti.gov/servlets/purl/1182479.
@article{osti_1182479,
title = {Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries},
author = {Zhang, Linjing and Li, Ning and Wu, Borong and Xu, Hongliang and Wang, Lei and Yang, Xiao-Qing and Wu, Feng},
abstractNote = {High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li1.2Ni0.13Mn0.54Co0.13O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li+ intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achieving around 70% (175 mAhg–1) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.},
doi = {10.1021/nl5041594},
journal = {Nano Letters},
number = 1,
volume = 15,
place = {United States},
year = {Wed Jan 14 00:00:00 EST 2015},
month = {Wed Jan 14 00:00:00 EST 2015}
}
Web of Science
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