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Title: Polyethylenimine-Enhanced Electrocatalytic Reduction of CO 2 to Formate at Nitrogen-Doped Carbon Nanomaterials

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [2];  [1]
  1. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States
  2. Department of Electrical and Computer Engineering, Duke University, Durham, North Carolina 27708, United States
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1179601
Grant/Contract Number:  
SC0001011
Resource Type:
Published Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Name: Journal of the American Chemical Society Journal Volume: 136 Journal Issue: 22; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Zhang, Sheng, Kang, Peng, Ubnoske, Stephen, Brennaman, M. Kyle, Song, Na, House, Ralph L., Glass, Jeffrey T., and Meyer, Thomas J. Polyethylenimine-Enhanced Electrocatalytic Reduction of CO 2 to Formate at Nitrogen-Doped Carbon Nanomaterials. United States: N. p., 2014. Web. doi:10.1021/ja5031529.
Zhang, Sheng, Kang, Peng, Ubnoske, Stephen, Brennaman, M. Kyle, Song, Na, House, Ralph L., Glass, Jeffrey T., & Meyer, Thomas J. Polyethylenimine-Enhanced Electrocatalytic Reduction of CO 2 to Formate at Nitrogen-Doped Carbon Nanomaterials. United States. https://doi.org/10.1021/ja5031529
Zhang, Sheng, Kang, Peng, Ubnoske, Stephen, Brennaman, M. Kyle, Song, Na, House, Ralph L., Glass, Jeffrey T., and Meyer, Thomas J. Tue . "Polyethylenimine-Enhanced Electrocatalytic Reduction of CO 2 to Formate at Nitrogen-Doped Carbon Nanomaterials". United States. https://doi.org/10.1021/ja5031529.
@article{osti_1179601,
title = {Polyethylenimine-Enhanced Electrocatalytic Reduction of CO 2 to Formate at Nitrogen-Doped Carbon Nanomaterials},
author = {Zhang, Sheng and Kang, Peng and Ubnoske, Stephen and Brennaman, M. Kyle and Song, Na and House, Ralph L. and Glass, Jeffrey T. and Meyer, Thomas J.},
abstractNote = {},
doi = {10.1021/ja5031529},
journal = {Journal of the American Chemical Society},
number = 22,
volume = 136,
place = {United States},
year = {Tue May 20 00:00:00 EDT 2014},
month = {Tue May 20 00:00:00 EDT 2014}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/ja5031529

Citation Metrics:
Cited by: 496 works
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Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

Electrode reduction kinetics of carbon dioxide in aqueous solution
journal, October 1972

  • Ryu, J.; Andersen, T. N.; Eyring, H.
  • The Journal of Physical Chemistry, Vol. 76, Issue 22
  • DOI: 10.1021/j100666a029

Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction
journal, March 2010

  • Liu, Ruili; Wu, Dongqing; Feng, Xinliang
  • Angewandte Chemie International Edition, Vol. 49, Issue 14, p. 2565-2569
  • DOI: 10.1002/anie.200907289

Nanoporous Graphitic-C 3 N 4 @Carbon Metal-Free Electrocatalysts for Highly Efficient Oxygen Reduction
journal, December 2011

  • Zheng, Yao; Jiao, Yan; Chen, Jun
  • Journal of the American Chemical Society, Vol. 133, Issue 50
  • DOI: 10.1021/ja209206c

Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
journal, January 2014

  • Zhang, Sheng; Kang, Peng; Meyer, Thomas J.
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja4113885

Selective Conversion of CO 2 to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst
journal, June 2013

  • DiMeglio, John L.; Rosenthal, Joel
  • Journal of the American Chemical Society, Vol. 135, Issue 24
  • DOI: 10.1021/ja4033549

Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction
journal, December 2013

  • Kumar, Bijandra; Asadi, Mohammad; Pisasale, Davide
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3819

A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential
journal, July 1994

  • Seshadri, Gayatri; Lin, Chao; Bocarsly, Andrew B.
  • Journal of Electroanalytical Chemistry, Vol. 372, Issue 1-2, p. 145-150
  • DOI: 10.1016/0022-0728(94)03300-5

Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
journal, February 2009


Electrochemistry of Aqueous Pyridinium: Exploration of a Key Aspect of Electrocatalytic Reduction of CO 2 to Methanol
journal, September 2013

  • Yan, Yong; Zeitler, Elizabeth L.; Gu, Jing
  • Journal of the American Chemical Society, Vol. 135, Issue 38
  • DOI: 10.1021/ja4064052

On the mechanism of enhanced oxygen reduction reaction in nitrogen-doped graphene nanoribbons
journal, January 2011

  • Kim, Heejin; Lee, Kirak; Woo, Seong Ihl
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 39
  • DOI: 10.1039/c1cp21665a

Electrochemical Reduction of Carbon Dioxide I. Effects of the Electrolyte on the Selectivity and Activity with Sn Electrode
journal, January 2012

  • Wu, Jingjie; Risalvato, Frank G.; Ke, Fu-Sheng
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.049207jes

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
journal, August 1994

  • Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
  • Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839
  • DOI: 10.1016/0013-4686(94)85172-7

Development of high efficiency adsorbents for CO2 capture based on a double-functionalization method of grafting and impregnation
journal, January 2013

  • Sanz, Raúl; Calleja, Guillermo; Arencibia, Amaya
  • Journal of Materials Chemistry A, Vol. 1, Issue 6
  • DOI: 10.1039/c2ta01343f

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011

  • Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
  • Science, Vol. 334, Issue 6056, p. 643-644
  • DOI: 10.1126/science.1209786

Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst
journal, January 2013

  • Kang, Peng; Meyer, Thomas J.; Brookhart, Maurice
  • Chemical Science, Vol. 4, Issue 9
  • DOI: 10.1039/c3sc51339d

Modern Global Climate Change
journal, December 2003


Polyelectrolyte Functionalized Carbon Nanotubes as Efficient Metal-free Electrocatalysts for Oxygen Reduction
journal, April 2011

  • Wang, Shuangyin; Yu, Dingshan; Dai, Liming
  • Journal of the American Chemical Society, Vol. 133, Issue 14
  • DOI: 10.1021/ja1112904

Responsive microcapsule reactors based on hydrogen-bonded tannic acid layer-by-layer assemblies
journal, January 2010

  • Kozlovskaya, Veronika; Kharlampieva, Eugenia; Drachuk, Irina
  • Soft Matter, Vol. 6, Issue 15
  • DOI: 10.1039/b927369g

A selective and efficient electrocatalyst for carbon dioxide reduction
journal, January 2014

  • Lu, Qi; Rosen, Jonathan; Zhou, Yang
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4242

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
journal, October 2012


Electrochemical reduction of CO2 on a polyaniline electrode under ambient conditions and at high pressure in methanol
journal, November 2002


Electrochemical reduction of CO2 over Sn-Nafion® coated electrode for a fuel-cell-like device
journal, February 2013


Selective Electrocatalytic Reduction of CO 2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes
journal, March 2012

  • Kang, Peng; Cheng, Chen; Chen, Zuofeng
  • Journal of the American Chemical Society, Vol. 134, Issue 12
  • DOI: 10.1021/ja300543s

High-Yield Electrochemical Production of Formaldehyde from CO 2 and Seawater
journal, November 2013

  • Nakata, Kazuya; Ozaki, Takuya; Terashima, Chiaki
  • Angewandte Chemie International Edition, Vol. 53, Issue 3
  • DOI: 10.1002/anie.201308657

Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation
journal, August 2013

  • Zhao, Yong; Nakamura, Ryuhei; Kamiya, Kazuhide
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3390

Aligned graphene nanoribbons and crossbars from unzipped carbon nanotubes
journal, April 2010


Conversion of Carbon Dioxide into Methanol with Silanes over N-Heterocyclic Carbene Catalysts
journal, April 2009

  • Riduan, Siti Nurhanna; Zhang, Yugen; Ying, Jackie Y.
  • Angewandte Chemie International Edition, Vol. 48, Issue 18
  • DOI: 10.1002/anie.200806058

Electrostatic Self-Assembly of a Pt-around-Au Nanocomposite with High Activity towards Formic Acid Oxidation
journal, March 2010

  • Zhang, Sheng; Shao, Yuyan; Yin, Geping
  • Angewandte Chemie International Edition, Vol. 49, Issue 12, p. 2211-2214
  • DOI: 10.1002/anie.200906987

Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces
journal, January 2011

  • Le, M.; Ren, M.; Zhang, Z.
  • Journal of The Electrochemical Society, Vol. 158, Issue 5
  • DOI: 10.1149/1.3561636

Nitrogen-doped graphene and its electrochemical applications
journal, January 2010

  • Shao, Yuyan; Zhang, Sheng; Engelhard, Mark H.
  • Journal of Materials Chemistry, Vol. 20, Issue 35
  • DOI: 10.1039/c0jm00782j

Nitrogen-Based Catalysts for the Electrochemical Reduction of CO 2 to CO
journal, November 2012

  • Tornow, Claire E.; Thorson, Michael R.; Ma, Sichao
  • Journal of the American Chemical Society, Vol. 134, Issue 48
  • DOI: 10.1021/ja308217w

Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights
journal, August 2010

  • Barton Cole, Emily; Lakkaraju, Prasad S.; Rampulla, David M.
  • Journal of the American Chemical Society, Vol. 132, Issue 33, p. 11539-11551
  • DOI: 10.1021/ja1023496

Electrocatalytic Carbon Dioxide Activation: The Rate-Determining Step of Pyridinium-Catalyzed CO2 Reduction
journal, February 2011

  • Morris, Amanda J.; McGibbon, Robert T.; Bocarsly, Andrew B.
  • ChemSusChem, Vol. 4, Issue 2, p. 191-196
  • DOI: 10.1002/cssc.201000379

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

Chemistry of Carbon Nanotubes
journal, March 2006

  • Tasis, Dimitrios; Tagmatarchis, Nikos; Bianco, Alberto
  • Chemical Reviews, Vol. 106, Issue 3
  • DOI: 10.1021/cr050569o

Tin Oxide Dependence of the CO 2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts
journal, January 2012

  • Chen, Yihong; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 4
  • DOI: 10.1021/ja2108799

An oxygen reduction electrocatalyst based on carbon nanotube–graphene complexes
journal, May 2012

  • Li, Yanguang; Zhou, Wu; Wang, Hailiang
  • Nature Nanotechnology, Vol. 7, Issue 6
  • DOI: 10.1038/nnano.2012.72