Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization
Abstract
The polysulfide species dissolved in aprotic solvents can be separated and analyzed by reverse phase (RP) high performance liquid chromatography (HPLC) in tandem with electrospray-mass spectroscopy. The relative distribution of polysulfide species in the electrolyte recovered from Li-S batteries is quantitatively and reliably determined for the first time.
- Authors:
-
- Univ. of Massachusetts Boston, Boston, MA (United States). Dept. of Chemistry
- Wuhan Univ. of Technology, Wuhan (China). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Univ. of Massachusetts Boston, Boston, MA (United States) Dept. of Chemistry
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1172109
- Report Number(s):
- BNL-107589-2015-JA; BNL-107589-2015-JAAM
Journal ID: ISSN 1614-6832; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 16; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Zheng, Dong, Qu, Deyu, Yang, Xiao-Qing, Yu, Xiqian, Lee, Hung-Sui, and Qu, Deyang. Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization. United States: N. p., 2015.
Web. doi:10.1002/aenm.201401888.
Zheng, Dong, Qu, Deyu, Yang, Xiao-Qing, Yu, Xiqian, Lee, Hung-Sui, & Qu, Deyang. Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization. United States. https://doi.org/10.1002/aenm.201401888
Zheng, Dong, Qu, Deyu, Yang, Xiao-Qing, Yu, Xiqian, Lee, Hung-Sui, and Qu, Deyang. Thu .
"Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization". United States. https://doi.org/10.1002/aenm.201401888. https://www.osti.gov/servlets/purl/1172109.
@article{osti_1172109,
title = {Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization},
author = {Zheng, Dong and Qu, Deyu and Yang, Xiao-Qing and Yu, Xiqian and Lee, Hung-Sui and Qu, Deyang},
abstractNote = {The polysulfide species dissolved in aprotic solvents can be separated and analyzed by reverse phase (RP) high performance liquid chromatography (HPLC) in tandem with electrospray-mass spectroscopy. The relative distribution of polysulfide species in the electrolyte recovered from Li-S batteries is quantitatively and reliably determined for the first time.},
doi = {10.1002/aenm.201401888},
journal = {Advanced Energy Materials},
number = 16,
volume = 5,
place = {United States},
year = {Thu Jan 29 00:00:00 EST 2015},
month = {Thu Jan 29 00:00:00 EST 2015}
}
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Works referencing / citing this record:
Lithiophilic gel polymer electrolyte to stabilize the lithium anode for a quasi-solid-state lithium–sulfur battery
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Synthesis and Characterization of a Molecularly Designed High‐Performance Organodisulfide as Cathode Material for Lithium Batteries
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Recent Progress in Liquid Electrolyte-Based Li–S Batteries: Shuttle Problem and Solutions
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Fast Determination of the Main Reduced Sulfur Species in Aquatic Systems by a Direct and Second-Derivative Spectrophotometric Method
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