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Title: Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [3];  [1]
  1. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
  2. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States, Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
  3. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States, Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1170506
Grant/Contract Number:  
FG02-87ER13808; FG02-99ER14999
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry Letters
Additional Journal Information:
Journal Name: Journal of Physical Chemistry Letters Journal Volume: 6 Journal Issue: 4; Journal ID: ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Hod, Idan, Bury, Wojciech, Gardner, Daniel M., Deria, Pravas, Roznyatovskiy, Vladimir, Wasielewski, Michael R., Farha, Omar K., and Hupp, Joseph T. Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound. United States: N. p., 2015. Web. doi:10.1021/acs.jpclett.5b00019.
Hod, Idan, Bury, Wojciech, Gardner, Daniel M., Deria, Pravas, Roznyatovskiy, Vladimir, Wasielewski, Michael R., Farha, Omar K., & Hupp, Joseph T. Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound. United States. https://doi.org/10.1021/acs.jpclett.5b00019
Hod, Idan, Bury, Wojciech, Gardner, Daniel M., Deria, Pravas, Roznyatovskiy, Vladimir, Wasielewski, Michael R., Farha, Omar K., and Hupp, Joseph T. Tue . "Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound". United States. https://doi.org/10.1021/acs.jpclett.5b00019.
@article{osti_1170506,
title = {Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound},
author = {Hod, Idan and Bury, Wojciech and Gardner, Daniel M. and Deria, Pravas and Roznyatovskiy, Vladimir and Wasielewski, Michael R. and Farha, Omar K. and Hupp, Joseph T.},
abstractNote = {},
doi = {10.1021/acs.jpclett.5b00019},
journal = {Journal of Physical Chemistry Letters},
number = 4,
volume = 6,
place = {United States},
year = {Tue Feb 03 00:00:00 EST 2015},
month = {Tue Feb 03 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.jpclett.5b00019

Citation Metrics:
Cited by: 114 works
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Works referenced in this record:

Controlling interpenetration in metal–organic frameworks by liquid-phase epitaxy
journal, May 2009

  • Shekhah, Osama; Wang, Hui; Paradinas, Markos
  • Nature Materials, Vol. 8, Issue 6
  • DOI: 10.1038/nmat2445

Stability and degradation mechanisms of metal–organic frameworks containing the Zr6O4(OH)4 secondary building unit
journal, January 2013

  • DeCoste, Jared B.; Peterson, Gregory W.; Jasuja, Himanshu
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta10662d

Metal–Organic Framework Thin Films: From Fundamentals to Applications.
journal, September 2011

  • Bétard, Angélique; Fischer, Roland A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1055-1083
  • DOI: 10.1021/cr200167v

Influence of supporting electrolyte concentration and composition on formal potentials and entropies of redox couples incorporated in Nafion coatings on electrodes
journal, November 1986

  • Naegeli, Ralph; Redepenning, Jody; Anson, Fred C.
  • The Journal of Physical Chemistry, Vol. 90, Issue 23
  • DOI: 10.1021/j100281a032

Light-Harvesting Metal–Organic Frameworks (MOFs) Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs
journal, October 2011

  • Lee, Chang Yeon; Farha, Omar K.; Hong, Bong Jin
  • Journal of the American Chemical Society, Vol. 133, Issue 40, p. 15858-15861
  • DOI: 10.1021/ja206029a

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013

  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
  • DOI: 10.1021/ja408959g

An ion gate membrane: electrochemical control of ion permeability through a membrane with an embedded electrode
journal, November 1982

  • Burgmayer, Paul; Murray, Royce W.
  • Journal of the American Chemical Society, Vol. 104, Issue 22
  • DOI: 10.1021/ja00386a061

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

Reductive Electrosynthesis of Crystalline Metal–Organic Frameworks
journal, August 2011

  • Li, Minyuan; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 133, Issue 33
  • DOI: 10.1021/ja2041546

Zr- and Hf-based nanoscale metal–organic frameworks as contrast agents for computed tomography
journal, January 2012

  • deKrafft, Kathryn E.; Boyle, William S.; Burk, Laurel M.
  • Journal of Materials Chemistry, Vol. 22, Issue 35
  • DOI: 10.1039/c2jm32299d

Nuclear reorganization barriers to electron transfer
journal, January 1988

  • Sutin, N.; Brunschwig, B. S.; Creutz, C.
  • Pure and Applied Chemistry, Vol. 60, Issue 12
  • DOI: 10.1351/pac198860121817

Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films
journal, October 2013

  • Wade, Casey R.; Li, Minyuan; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 52, Issue 50
  • DOI: 10.1002/anie.201306162

Chemical Reactions of Molecular Oxygen in Surface-Mediated Photolysis of Aromatic Compounds on Silica-Based Surfaces
journal, February 1995

  • Mao, Yun; Thomas, J. Kerry
  • The Journal of Physical Chemistry, Vol. 99, Issue 7
  • DOI: 10.1021/j100007a041

Are Zr 6 -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse
journal, January 2014

  • Mondloch, Joseph E.; Katz, Michael J.; Planas, Nora
  • Chemical Communications, Vol. 50, Issue 64
  • DOI: 10.1039/C4CC02401J

An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation
journal, January 2011

  • Vermoortele, Frederik; Ameloot, Rob; Vimont, Alexandre
  • Chem. Commun., Vol. 47, Issue 5
  • DOI: 10.1039/C0CC03038D

Metal–Organic Frameworks for Light Harvesting and Photocatalysis
journal, November 2012

  • Wang, Jin-Liang; Wang, Cheng; Lin, Wenbin
  • ACS Catalysis, Vol. 2, Issue 12
  • DOI: 10.1021/cs3005874

Interfacial microfluidic processing of metal-organic framework hollow fiber membranes
journal, July 2014


Metal–organic framework growth at functional interfaces: thin films and composites for diverse applications
journal, January 2012

  • Bradshaw, Darren; Garai, Ashesh; Huo, Jia
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15276A

Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks
journal, December 2012

  • Son, Ho-Jin; Jin, Shengye; Patwardhan, Sameer
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja310596a

Tailoring of network dimensionality and porosity adjustment in Zr- and Hf-based MOFs
journal, January 2013

  • Bon, Volodymyr; Senkovska, Irena; Weiss, Manfred S.
  • CrystEngComm, Vol. 15, Issue 45
  • DOI: 10.1039/c3ce41121d

A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
journal, September 2011

  • Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie
  • Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388
  • DOI: 10.1002/chem.201101595

Ion gate electrodes. Polypyrrole as a switchable ion conductor membrane
journal, June 1984

  • Burgmayer, Paul; Murray, Royce W.
  • The Journal of Physical Chemistry, Vol. 88, Issue 12
  • DOI: 10.1021/j150656a017

Solvothermal Preparation of an Electrocatalytic Metalloporphyrin MOF Thin Film and its Redox Hopping Charge-Transfer Mechanism
journal, January 2014

  • Ahrenholtz, Spencer R.; Epley, Charity C.; Morris, Amanda J.
  • Journal of the American Chemical Society, Vol. 136, Issue 6
  • DOI: 10.1021/ja410684q

Engineering ZIF-8 Thin Films for Hybrid MOF-Based Devices
journal, June 2012


Artificial photosynthesis as a frontier technology for energy sustainability
journal, January 2013

  • Faunce, Thomas; Styring, Stenbjorn; Wasielewski, Michael R.
  • Energy & Environmental Science, Vol. 6, Issue 4
  • DOI: 10.1039/c3ee40534f

Chemically Modified Opals as Thin Permselective Nanoporous Membranes
journal, May 2005

  • Newton, Michael R.; Bohaty, Andrew K.; White, Henry S.
  • Journal of the American Chemical Society, Vol. 127, Issue 20
  • DOI: 10.1021/ja043275d

Directed Growth of Electroactive Metal-Organic Framework Thin Films Using Electrophoretic Deposition
journal, July 2014

  • Hod, Idan; Bury, Wojciech; Karlin, David M.
  • Advanced Materials, Vol. 26, Issue 36
  • DOI: 10.1002/adma.201401940

Layer-by-Layer Fabrication of Oriented Porous Thin Films Based on Porphyrin-Containing Metal–Organic Frameworks
journal, October 2013

  • So, Monica C.; Jin, Shengye; Son, Ho-Jin
  • Journal of the American Chemical Society, Vol. 135, Issue 42
  • DOI: 10.1021/ja4078705

Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014

  • Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
  • DOI: 10.1021/jz501899j

Liquid phase stepwise growth of surface mounted metal–organic frameworks for exploratory research and development of applications
journal, January 2014

  • Tu, Min; Wannapaiboon, Suttipong; Fischer, Roland A.
  • Inorganic Chemistry Frontiers, Vol. 1, Issue 6
  • DOI: 10.1039/c4qi00037d

Permselectivities of polyelectrolyte electrode coatings as inferred from measurements with incorporated redox probes or concentration cells
journal, August 1987

  • Redepenning, Jody.; Anson, Fred C.
  • The Journal of Physical Chemistry, Vol. 91, Issue 17
  • DOI: 10.1021/j100301a025

Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF 3 -Terminated Self-Assembled Monolayers on Au(111)
journal, October 2005

  • Hermes, Stephan; Schröder, Felicitas; Chelmowski, Rolf
  • Journal of the American Chemical Society, Vol. 127, Issue 40
  • DOI: 10.1021/ja053523l

Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism
journal, December 2013

  • Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E.
  • Chemistry of Materials, Vol. 25, Issue 24
  • DOI: 10.1021/cm403726v

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013

  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
  • DOI: 10.1021/ja4050828

Photochemical reactions of pyrene on surfaces of .gamma.-alumina and silica-alumina
journal, October 1992


Water Stable Zr-Benzenedicarboxylate Metal-Organic Frameworks as Photocatalysts for Hydrogen Generation
journal, August 2010

  • Gomes Silva, Cláudia; Luz, Ignacio; Llabrés i. Xamena, Francesc X.
  • Chemistry - A European Journal, Vol. 16, Issue 36
  • DOI: 10.1002/chem.200903526

Electrical potentials across porous plugs and membranes. Ion-exchange resin-solution systems
journal, January 1956

  • Spiegler, K. S.; Yoest, R. L.; Wyllie, M. R. J.
  • Discussions of the Faraday Society, Vol. 21
  • DOI: 10.1039/df9562100174

A Water-Stable Porphyrin-Based Metal-Organic Framework Active for Visible-Light Photocatalysis
journal, June 2012

  • Fateeva, Alexandra; Chater, Philip A.; Ireland, Christopher P.
  • Angewandte Chemie International Edition, Vol. 51, Issue 30
  • DOI: 10.1002/anie.201202471

Energy Transfer from Quantum Dots to Metal–Organic Frameworks for Enhanced Light Harvesting
journal, January 2013

  • Jin, Shengye; Son, Ho-Jin; Farha, Omar K.
  • Journal of the American Chemical Society, Vol. 135, Issue 3
  • DOI: 10.1021/ja3097114