Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle

Abstract

Application of high-voltage spinel LiNi0.5Mn1.5O4 cathode material is the closest and the most realistic approach to meeting the midterm goal of lithium-ion batteries for electric vehicles (EVs) and plug-in hybrid electric vehicles (HEVs). However, this application has been hampered by long-standing issues, such as capacity degradation and poor first-cycle Coulombic efficiency of LiNi0.5Mn1.5O4 cathode material. Although it is well-known that the structure of LiNi0.5Mn1.5O4 into which Li ions are reversibly intercalated plays a critical role in the above issues, performance degradation related to structural changes, particularly in the first cycle, are not fully understood. Here, we report detailed investigations of local atomic-level and average structure of LiNi0.5Mn1.5O4 during first cycle (3.5–4.9 V) at room temperature. We observed two types of local atomic-level migration of transition metals (TM) ions in the cathode of a well-prepared LiNi0.5Mn1.5O4//Li half-cell during first charge via an aberration-corrected scanning transmission electron microscopy (STEM). Surface regions (~2 nm) of the cycled LiNi0.5Mn1.5O4 particles show migration of TM ions into tetrahedral Li sites to form a Mn3O4-like structure. However, subsurface regions of the cycled particles exhibit migration of TM ions into empty octahedral sites to form a rocksalt-like structure. The migration of these TM ions are closely relatedmore » to dissolution of Ni/Mn ions and building-up of charge transfer impedance, which contribute significantly to the capacity degradation and the poor first-cycle Coulombic efficiency of spinel LiNi0.5Mn1.5O4 cathode material. Accordingly, we provide suggestions of effective stabilization of LiNi0.5Mn1.5O4 structure to obtain better electrochemical performance.« less

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [1];  [1];  [3]
+ Show Author Affiliations
  1. Chinese Academy of Sciences, Beijing (China)
  2. Brookhaven National Laboratory (BNL), Upton, NY (United States)
  3. CIC Energigune, Alava (Spain)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1169558
Report Number(s):
BNL-107260-2014-JA
Journal ID: ISSN 0897-4756; R&D Project: MA453MAEA; VT1201000
Grant/Contract Number:  
DE-SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 27; Journal Issue: 1; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; NSLS

Citation Formats

Huang, Xuejie, Yu, Xiqian, Lin, Mingxiang, Ben, Liubin, Sun, Yang, Wang, Hao, Yang, Zhenzhong, Gu, Lin, Yang, Xiao -Qing, Zhao, Haofei, Yu, Richeng, and Armand, Michel. Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle. United States: N. p., 2014. Web. doi:10.1021/cm503972a.
Copy to clipboard
Huang, Xuejie, Yu, Xiqian, Lin, Mingxiang, Ben, Liubin, Sun, Yang, Wang, Hao, Yang, Zhenzhong, Gu, Lin, Yang, Xiao -Qing, Zhao, Haofei, Yu, Richeng, & Armand, Michel. Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle. United States. https://doi.org/10.1021/cm503972a
Copy to clipboard
Huang, Xuejie, Yu, Xiqian, Lin, Mingxiang, Ben, Liubin, Sun, Yang, Wang, Hao, Yang, Zhenzhong, Gu, Lin, Yang, Xiao -Qing, Zhao, Haofei, Yu, Richeng, and Armand, Michel. Mon . "Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle". United States. https://doi.org/10.1021/cm503972a. https://www.osti.gov/servlets/purl/1169558.
Copy to clipboard
@article{osti_1169558,
title = {Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle},
author = {Huang, Xuejie and Yu, Xiqian and Lin, Mingxiang and Ben, Liubin and Sun, Yang and Wang, Hao and Yang, Zhenzhong and Gu, Lin and Yang, Xiao -Qing and Zhao, Haofei and Yu, Richeng and Armand, Michel},
abstractNote = {Application of high-voltage spinel LiNi0.5Mn1.5O4 cathode material is the closest and the most realistic approach to meeting the midterm goal of lithium-ion batteries for electric vehicles (EVs) and plug-in hybrid electric vehicles (HEVs). However, this application has been hampered by long-standing issues, such as capacity degradation and poor first-cycle Coulombic efficiency of LiNi0.5Mn1.5O4 cathode material. Although it is well-known that the structure of LiNi0.5Mn1.5O4 into which Li ions are reversibly intercalated plays a critical role in the above issues, performance degradation related to structural changes, particularly in the first cycle, are not fully understood. Here, we report detailed investigations of local atomic-level and average structure of LiNi0.5Mn1.5O4 during first cycle (3.5–4.9 V) at room temperature. We observed two types of local atomic-level migration of transition metals (TM) ions in the cathode of a well-prepared LiNi0.5Mn1.5O4//Li half-cell during first charge via an aberration-corrected scanning transmission electron microscopy (STEM). Surface regions (~2 nm) of the cycled LiNi0.5Mn1.5O4 particles show migration of TM ions into tetrahedral Li sites to form a Mn3O4-like structure. However, subsurface regions of the cycled particles exhibit migration of TM ions into empty octahedral sites to form a rocksalt-like structure. The migration of these TM ions are closely related to dissolution of Ni/Mn ions and building-up of charge transfer impedance, which contribute significantly to the capacity degradation and the poor first-cycle Coulombic efficiency of spinel LiNi0.5Mn1.5O4 cathode material. Accordingly, we provide suggestions of effective stabilization of LiNi0.5Mn1.5O4 structure to obtain better electrochemical performance.},
doi = {10.1021/cm503972a},
journal = {Chemistry of Materials},
number = 1,
volume = 27,
place = {United States},
year = {Mon Dec 22 00:00:00 EST 2014},
month = {Mon Dec 22 00:00:00 EST 2014}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/cm503972a
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 126 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries
journal, January 2014

  • Manthiram, Arumugam; Chemelewski, Katharine; Lee, Eun-Sung
  • Energy & Environmental Science, Vol. 7, Issue 4
  • DOI: 10.1039/c3ee42981d

Microwave synthesis of LiMn2O4 cathode material
journal, September 1999

Failure mechanisms of LiNi0.5Mn1.5O4 electrode at elevated temperature
journal, October 2012

Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries
journal, July 2013

  • Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng
  • The Journal of Physical Chemistry C, Vol. 117, Issue 31
  • DOI: 10.1021/jp405158m

Failure Mechanism of Graphite/LiNi 0.5 Mn 1.5 O 4 Cells at High Voltage and Elevated Temperature
journal, January 2013

  • Lu, Dongsheng; Xu, Mengqing; Zhou, Liu
  • Journal of The Electrochemical Society, Vol. 160, Issue 5
  • DOI: 10.1149/2.022305jes

Comparison of Metal Ion Dissolutions from Lithium Ion Battery Cathodes
journal, January 2006

  • Choi, W.; Manthiram, A.
  • Journal of The Electrochemical Society, Vol. 153, Issue 9
  • DOI: 10.1149/1.2219710

Studies of cycling behavior, ageing, and interfacial reactions of LiNi0.5Mn1.5O4 and carbon electrodes for lithium-ion 5-V cells
journal, November 2006

Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries
journal, March 2007

Nano-LiNi0.5Mn1.5O4 spinel: a high power electrode for Li-ion batteries
journal, January 2008

  • Shaju, Kuthanapillil M.; Bruce, Peter G.
  • Dalton Transactions, Issue 40
  • DOI: 10.1039/b806662k

Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications
journal, September 2012

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

  • Arora, Pankaj; White, Ralph E.; Doyle, Marc
  • Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667
  • DOI: 10.1149/1.1838857

Mathematical Modeling of the Lithium Deposition Overcharge Reaction in Lithium-Ion Batteries Using Carbon-Based Negative Electrodes
journal, January 1999

  • Arora, Pankaj
  • Journal of The Electrochemical Society, Vol. 146, Issue 10
  • DOI: 10.1149/1.1392512

Overcharge Effect on Morphology and Structure of Carbon Electrodes for Lithium-Ion Batteries
journal, January 2012

  • Lu, Wenquan; López, Carmen M.; Liu, Nathan
  • Journal of The Electrochemical Society, Vol. 159, Issue 5
  • DOI: 10.1149/2.jes035205

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Insights about the irreversible capacity of LiNi0.5Mn1.5O4 cathode materials in lithium batteries
journal, September 2013

Compositional Change of Surface Film Deposited on LiNi 0.5 Mn 1.5 O 4 Positive Electrode
journal, January 2014

  • Yoon, Taeho; Kim, Daesoo; Park, Kern H.
  • Journal of The Electrochemical Society, Vol. 161, Issue 4
  • DOI: 10.1149/2.019404jes

Effects of cell positive cans and separators on the performance of high-voltage Li-ion batteries
journal, September 2012

Comprehensive reinvestigation on the initial coulombic efficiency and capacity fading mechanism of LiNi0.5Mn1.5O4 at low rate and elevated temperature
journal, December 2012

  • Wu, Xianwen; Li, Xinhai; Wang, Zhixing
  • Journal of Solid State Electrochemistry, Vol. 17, Issue 4
  • DOI: 10.1007/s10008-012-1963-5

Synthesis of Li2CoSiO4 nanoparticles and structure observation by annular bright and dark field electron microscopy
journal, January 2013

  • Devaraju, M. K.; Truong, Q. D.; Honma, I.
  • RSC Advances, Vol. 3, Issue 43
  • DOI: 10.1039/c3ra42540a

Direct Observation of Antisite Defects in LiCoPO 4 Cathode Materials by Annular Dark- and Bright-Field Electron Microscopy
journal, October 2013

  • Truong, Quang Duc; Devaraju, Murukanahally Kempaiah; Tomai, Takaaki
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 20
  • DOI: 10.1021/am403018n

Antisite defects in LiCoPO 4 nanocrystals synthesized via a supercritical fluid process
journal, January 2014

  • Devaraju, Murukanahally Kempaiah; Truong, Quang Duc; Tomai, Takaaki
  • RSC Adv., Vol. 4, Issue 94
  • DOI: 10.1039/C4RA10689J

Relocation of Cobalt Ions in Electrochemically Delithiated LiCoPO 4 Cathode Materials
journal, April 2014

  • Truong, Quang Duc; Devaraju, Murukanahally Kempaiah; Sasaki, Yoshikazu
  • Chemistry of Materials, Vol. 26, Issue 9
  • DOI: 10.1021/cm501452p

Conflicting Roles of Nickel in Controlling Cathode Performance in Lithium Ion Batteries
journal, September 2012

  • Gu, Meng; Belharouak, Ilias; Genc, Arda
  • Nano Letters, Vol. 12, Issue 10
  • DOI: 10.1021/nl302249v

First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries
journal, July 2013

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl4019275

Atomic Structure of Li 2 MnO 3 after Partial Delithiation and Re-Lithiation
journal, June 2013

Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process
journal, July 2013

  • Zheng, Jianming; Gu, Meng; Xiao, Jie
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl401849t

Investigation of Changes in the Surface Structure of Li x Ni 0.8 Co 0.15 Al 0.05 O 2 Cathode Materials Induced by the Initial Charge
journal, December 2013

  • Hwang, Sooyeon; Chang, Wonyoung; Kim, Seung Min
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403332s

The role of composition in the atomic structure, oxygen loss, and capacity of layered Li–Mn–Ni oxide cathodes
journal, January 2014

  • Jarvis, Karalee A.; Wang, Chih-Chieh; Manthiram, Arumugam
  • J. Mater. Chem. A, Vol. 2, Issue 5
  • DOI: 10.1039/C3TA12440A

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014

  • Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4529

Surface Structure Evolution of LiMn 2 O 4 Cathode Material upon Charge/Discharge
journal, May 2014

  • Tang, Daichun; Sun, Yang; Yang, Zhenzhong
  • Chemistry of Materials, Vol. 26, Issue 11
  • DOI: 10.1021/cm501125e

Direct Observation of Lithium Staging in Partially Delithiated LiFePO 4 at Atomic Resolution
journal, April 2011

  • Gu, Lin; Zhu, Changbao; Li, Hong
  • Journal of the American Chemical Society, Vol. 133, Issue 13
  • DOI: 10.1021/ja109412x

Rutile-TiO 2 Nanocoating for a High-Rate Li 4 Ti 5 O 12 Anode of a Lithium-Ion Battery
journal, April 2012

  • Wang, Yong-Qing; Gu, Lin; Guo, Yu-Guo
  • Journal of the American Chemical Society, Vol. 134, Issue 18
  • DOI: 10.1021/ja301266w

Comparative Study of LiNi 0.5 Mn 1.5 O 4 - δ and LiNi 0.5 Mn 1.5 O 4 Cathodes Having Two Crystallographic Structures:  Fd 3̄ m and P 4 3 32
journal, March 2004

  • Kim, J. -H.; Myung, S. -T.; Yoon, C. S.
  • Chemistry of Materials, Vol. 16, Issue 5
  • DOI: 10.1021/cm035050s

Phase Transitions in Li[sub 1−δ]Ni[sub 0.5]Mn[sub 1.5]O[sub 4] during Cycling at 5 V
journal, January 2004

  • Kim, J. -H.; Yoon, C. S.; Myung, S. -T.
  • Electrochemical and Solid-State Letters, Vol. 7, Issue 7
  • DOI: 10.1149/1.1753252

A practical approach for STEM image simulation based on the FFT multislice method
journal, February 2002

Dynamics of annular bright field imaging in scanning transmission electron microscopy
journal, June 2010

Oxygen-Vacancy Ordering at Surfaces of Lithium Manganese(III,IV) Oxide Spinel Nanoparticles
journal, February 2011

  • Huang, Rong; Ikuhara, Yumi H.; Mizoguchi, Teruyasu
  • Angewandte Chemie International Edition, Vol. 50, Issue 13
  • DOI: 10.1002/anie.201004638

Crystal structural change during charge?discharge process of LiMnNiO as cathode material for 5 V class lithium secondary battery
journal, January 2005

Oxygen Nonstoichiometry and Phase Transitions in LiMn[sub 1.5]Ni[sub 0.5]O[sub 4−δ]
journal, January 2008

  • Pasero, D.; Reeves, N.; Pralong, V.
  • Journal of The Electrochemical Society, Vol. 155, Issue 4
  • DOI: 10.1149/1.2832650

Evolution of Phase Transformation Behavior in Li(Mn1.5Ni0.5)O4 Cathodes Studied By In Situ XRD
journal, January 2011

  • Rhodes, Kevin; Meisner, Roberta; Kim, Yoongu
  • Journal of The Electrochemical Society, Vol. 158, Issue 8
  • DOI: 10.1149/1.3596376

Improved cycling and rate performance of Sm-doped LiNi0.5Mn1.5O4 cathode materials for 5V lithium ion batteries
journal, January 2014

In situ synchrotron X-ray studies on copper–nickel 5 V Mn oxide spinel cathodes for Li-ion batteries
journal, August 2004

Nanosized high voltage cathode material LiMg0.05Ni0.45Mn1.5O4: Structural, electrochemical and in situ investigation
journal, April 2009

High potential durability of LiNi0.5Mn1.5O4 electrodes studied by surface sensitive X-ray absorption spectroscopy
journal, January 2014

Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
journal, December 2013

Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li 1 - x Co 1/3 Ni 1/3 Mn 1/3 O 2 Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy
journal, December 2005

  • Yoon, Won-Sub; Balasubramanian, Mahalingam; Chung, Kyung Yoon
  • Journal of the American Chemical Society, Vol. 127, Issue 49
  • DOI: 10.1021/ja0530568

A First-Principles Approach to Studying the Thermal Stability of Oxide Cathode Materials
journal, February 2007

  • Wang, L.; Maxisch, T.; Ceder, G.
  • Chemistry of Materials, Vol. 19, Issue 3
  • DOI: 10.1021/cm0620943

Electrochemically Induced Cation Disorder and Phase Transformations in Lithium Intercalation Oxides
journal, January 2001

  • Chiang, Yet-Ming; Wang, Haifeng; Jang, Young-Il
  • Chemistry of Materials, Vol. 13, Issue 1
  • DOI: 10.1021/cm000569z

Thermal Instability of Cycled Li x Ni 0.5 Mn 0.5 O 2 Electrodes: An in Situ Synchrotron X-ray Powder Diffraction Study
journal, August 2008

  • Yabuuchi, Naoaki; Kim, Yong-Tae; Li, Hayley H.
  • Chemistry of Materials, Vol. 20, Issue 15
  • DOI: 10.1021/cm800314d

Structural Origin of Overcharge-Induced Thermal Instability of Ni-Containing Layered-Cathodes for High-Energy-Density Lithium Batteries
journal, September 2011

  • Wu, Lijun; Nam, Kyung-Wan; Wang, Xiaojian
  • Chemistry of Materials, Vol. 23, Issue 17
  • DOI: 10.1021/cm201452q

Layered-to-Spinel Phase Transition in Li[sub x]MnO[sub 2]
journal, January 2001

  • Reed, J.; Ceder, G.; Van Der Ven, A.
  • Electrochemical and Solid-State Letters, Vol. 4, Issue 6
  • DOI: 10.1149/1.1368896

Role of Electronic Structure in the Susceptibility of Metastable Transition-Metal Oxide Structures to Transformation
journal, October 2004

  • Reed, John; Ceder, Gerbrand
  • Chemical Reviews, Vol. 104, Issue 10
  • DOI: 10.1021/cr020733x

Relative stability of normal vs. inverse spinel for 3d transition metal oxides as lithium intercalation cathodes
journal, January 2013

  • Bhattacharya, Jishnu; Wolverton, C.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 17
  • DOI: 10.1039/c3cp50910a

Thermodynamic analysis using first-principles calculations of phases and structures of LixNi0.5Mn1.5O4 (0 ≤ x ≤ 1)
journal, November 2013

A comparative study of Fd-3m and P4332 “LiNi0.5Mn1.5O4”
journal, June 2011

Role of Oxygen Vacancies on the Performance of Li[Ni 0.5– x Mn 1.5+ x ]O 4 ( x = 0, 0.05, and 0.08) Spinel Cathodes for Lithium-Ion Batteries
journal, July 2012

  • Song, Jie; Shin, Dong Wook; Lu, Yuhao
  • Chemistry of Materials, Vol. 24, Issue 15
  • DOI: 10.1021/cm301825h

Unraveling structural evolution of LiNi0.5Mn1.5O4 by in situ neutron diffraction
journal, January 2013

  • Cai, Lu; Liu, Zengcai; An, Ke
  • Journal of Materials Chemistry A, Vol. 1, Issue 23
  • DOI: 10.1039/c3ta00145h

Oxygen-Release-Related Thermal Stability and Decomposition Pathways of Li x Ni 0.5 Mn 1.5 O 4 Cathode Materials
journal, December 2013

  • Hu, Enyuan; Bak, Seong-Min; Liu, Jue
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403400y

Synthesis and Electrochemistry of LiNi[sub x]Mn[sub 2−x]O[sub 4]
journal, January 1997

  • Zhong, Qiming
  • Journal of The Electrochemical Society, Vol. 144, Issue 1
  • DOI: 10.1149/1.1837386

Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged Li x Ni 0.8 Co 0.15 Al 0.05 O 2 Cathode Materials
journal, January 2013

  • Bak, Seong-Min; Nam, Kyung-Wan; Chang, Wonyoung
  • Chemistry of Materials, Vol. 25, Issue 3
  • DOI: 10.1021/cm303096e

Electrochemical extraction of lithium from LiMn2O4
journal, February 1984

High Rate Micron-Sized Ordered LiNi[sub 0.5]Mn[sub 1.5]O[sub 4]
journal, January 2010

  • Ma, Xiaohua; Kang, Byoungwoo; Ceder, Gerbrand
  • Journal of The Electrochemical Society, Vol. 157, Issue 8
  • DOI: 10.1149/1.3439678

Factors affecting Li mobility in spinel LiMn2O4—A first-principles study by GGA and GGA+U methods
journal, August 2010

Lithium insertion into manganese spinels
journal, April 1983

  • Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
  • Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
  • DOI: 10.1016/0025-5408(83)90138-1

Synthesis, Characterization and Electrochemistry of Lithium Battery Electrodes: x Li 2 MnO 3 ·(1 − x )LiMn 0.333 Ni 0.333 Co 0.333 O 2 (0 ≤ x ≤ 0.7)
journal, October 2008

  • Johnson, Christopher S.; Li, Naichao; Lefief, Christina
  • Chemistry of Materials, Vol. 20, Issue 19
  • DOI: 10.1021/cm801245r

Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li 2 MnO 3 −LiCo 1/3 Ni 1/3 Mn 1/3 O 2
journal, March 2011

  • Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek
  • Journal of the American Chemical Society, Vol. 133, Issue 12
  • DOI: 10.1021/ja108588y
    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Tuning Anionic Redox Activity and Reversibility for a High‐Capacity Li‐Rich Mn‐Based Oxide Cathode via an Integrated Strategy
    journal, March 2019

    • Li, Qingyuan; Zhou, Dong; Zhang, Lijuan
    • Advanced Functional Materials, Vol. 29, Issue 10
    • DOI: 10.1002/adfm.201806706

    Exploring the origin of electrochemical performance of Cr-doped LiNi 0.5 Mn 1.5 O 4
    journal, January 2020

    • Li, Fei; Ma, Jiani; Lin, Jianyan
    • Physical Chemistry Chemical Physics, Vol. 22, Issue 7
    • DOI: 10.1039/c9cp06545h

    Application of Li 2 S to compensate for loss of active lithium in a Si–C anode
    journal, January 2018

    • Zhan, Yuanjie; Yu, Hailong; Ben, Liubin
    • Journal of Materials Chemistry A, Vol. 6, Issue 15
    • DOI: 10.1039/c8ta00496j

    Nanoscale Manipulation of Spinel Lithium Nickel Manganese Oxide Surface by Multisite Ti Occupation as High-Performance Cathode
    journal, October 2017

    Uniform Na + Doping‐Induced Defects in Li‐ and Mn‐Rich Cathodes for High‐Performance Lithium‐Ion Batteries
    journal, May 2019

    Atomic Insights into the Enhanced Surface Stability in High Voltage Cathode Materials by Ultrathin Coating
    journal, January 2017

    • Fang, Xin; Lin, Feng; Nordlund, Dennis
    • Advanced Functional Materials, Vol. 27, Issue 7
    • DOI: 10.1002/adfm.201602873

    Multi-scale computation methods: Their applications in lithium-ion battery research and development
    journal, January 2016

    Atomic-Scale Direct Identification of Surface Variations in Cathode Oxides for Aqueous and Nonaqueous Lithium-Ion Batteries
    journal, January 2019

    Construction of uniform transition-metal phosphate nanoshells and their potential for improving Li-ion battery performance
    journal, January 2018

    • Zhang, Dong; Hu, Lin-Lin; Sun, Yong-Gang
    • Journal of Materials Chemistry A, Vol. 6, Issue 19
    • DOI: 10.1039/c8ta01320a

    Comparative study of the electrochemical properties of P4332 and Fd3m space group of LiNi0.45Cu0.05Mn1.5O4 cathode materials
    journal, November 2018

    Three-dimensional atomic-scale observation of structural evolution of cathode material in a working all-solid-state battery
    journal, August 2018

    Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries
    journal, July 2018

    • Sun, Yang; Guo, Shaohua; Zhou, Haoshen
    • Advanced Energy Materials, Vol. 9, Issue 23
    • DOI: 10.1002/aenm.201800212

    Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries
    journal, January 2016

    Advances in the Cathode Materials for Lithium Rechargeable Batteries
    journal, February 2020

    • Lee, Wontae; Muhammad, Shoaib; Sergey, Chernov
    • Angewandte Chemie International Edition, Vol. 59, Issue 7
    • DOI: 10.1002/anie.201902359

    Comparative study of the electrochemical properties of LiNi0.5Mn1.5O4 doped by bivalent ions (Cu2+, Mg2+, and Zn2+)
    journal, March 2017

    • Deng, Miao-Miao; Zou, Bang-Kun; Shao, Yu
    • Journal of Solid State Electrochemistry, Vol. 21, Issue 6
    • DOI: 10.1007/s10008-017-3545-z

    Atomic-Scale Structure Evolution in a Quasi-Equilibrated Electrochemical Process of Electrode Materials for Rechargeable Batteries
    journal, February 2015

    Do imaging techniques add real value to the development of better post-Li-ion batteries?
    journal, January 2018

    • Conder, Joanna; Marino, Cyril; Novák, Petr
    • Journal of Materials Chemistry A, Vol. 6, Issue 8
    • DOI: 10.1039/c7ta10622j

    Kathodenmaterialien für wiederaufladbare Lithiumbatterien
    journal, November 2019

    • Lee, Wontae; Muhammad, Shoaib; Sergey, Chernov
    • Angewandte Chemie, Vol. 132, Issue 7
    • DOI: 10.1002/ange.201902359

    High-voltage positive electrode materials for lithium-ion batteries
    journal, January 2017

    • Li, Wangda; Song, Bohang; Manthiram, Arumugam
    • Chemical Society Reviews, Vol. 46, Issue 10
    • DOI: 10.1039/c6cs00875e

    Three-dimensional atomic-scale observation of structural evolution of cathode material in a working all-solid-state battery
    journal, August 2018

      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: