Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver
Abstract
Non-resonant tip-enhanced Raman images of 4,4'-dimercaptostilbene on silver reveal that different vibrational resonances of the reporter are selectively enhanced at different sites on the metal substrate. Sequentially recorded images track molecular diffusion within the diffraction-limited laser spot which illuminates the substrate. In effect, the recorded time resolved (Δt = 10 s) pixelated images (25 nm x 8 cm-1) broadcast molecule-local field interactions which take place on much finer scales.
- Authors:
-
- Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, United States
- Department of Chemistry, University of Puget Sound, Tacoma, Washington 98416, United States
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1164574
- Alternate Identifier(s):
- OSTI ID: 1170070
- Report Number(s):
- PNNL-SA-100249
Journal ID: ISSN 1932-7447
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Published Article
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Name: Journal of Physical Chemistry. C Journal Volume: 118 Journal Issue: 47; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Raman Scattering; SERS; TERS; Nanoscale; Chemical Imaging; Local Field; Dimercaptostilbene
Citation Formats
El-Khoury, Patrick Z., Ueltschi, Tyler W., Mifflin, Amanda L., Hu, Dehong, and Hess, Wayne P. Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver. United States: N. p., 2014.
Web. doi:10.1021/jp509082c.
El-Khoury, Patrick Z., Ueltschi, Tyler W., Mifflin, Amanda L., Hu, Dehong, & Hess, Wayne P. Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver. United States. https://doi.org/10.1021/jp509082c
El-Khoury, Patrick Z., Ueltschi, Tyler W., Mifflin, Amanda L., Hu, Dehong, and Hess, Wayne P. Wed .
"Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver". United States. https://doi.org/10.1021/jp509082c.
@article{osti_1164574,
title = {Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver},
author = {El-Khoury, Patrick Z. and Ueltschi, Tyler W. and Mifflin, Amanda L. and Hu, Dehong and Hess, Wayne P.},
abstractNote = {Non-resonant tip-enhanced Raman images of 4,4'-dimercaptostilbene on silver reveal that different vibrational resonances of the reporter are selectively enhanced at different sites on the metal substrate. Sequentially recorded images track molecular diffusion within the diffraction-limited laser spot which illuminates the substrate. In effect, the recorded time resolved (Δt = 10 s) pixelated images (25 nm x 8 cm-1) broadcast molecule-local field interactions which take place on much finer scales.},
doi = {10.1021/jp509082c},
journal = {Journal of Physical Chemistry. C},
number = 47,
volume = 118,
place = {United States},
year = {Wed Nov 12 00:00:00 EST 2014},
month = {Wed Nov 12 00:00:00 EST 2014}
}
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https://doi.org/10.1021/jp509082c
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