Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion
Abstract
Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-high vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) wasmore »
- Authors:
-
- Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
- Univ. of Central Florida, Orlando, FL (United States)
- Univ. of Newcastle, Callaghan (Australia)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1159422
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Phase Equilibria and Diffusion
- Additional Journal Information:
- Journal Volume: 35; Journal Issue: 6; Journal ID: ISSN 1547-7037
- Publisher:
- ASM International
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; DIFFUSION; ION MICROPROBE ANALYSIS; MASS SPECTROSCOPY; MAGNESIUM; tracer; diffusion; SIMS; magnesium; ICME; MGI; tracer diffusivity; self diffusivity; isotope; database
Citation Formats
Kulkarni, Nagraj S., Bruce Warmack, Robert J., Radhakrishnan, Bala, Hunter, Jerry L., Sohn, Yongho, Coffey, Kevin R., Murch, Graeme E., and Belova, Irina V.. Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion. United States: N. p., 2014.
Web. doi:10.1007/s11669-014-0344-4.
Kulkarni, Nagraj S., Bruce Warmack, Robert J., Radhakrishnan, Bala, Hunter, Jerry L., Sohn, Yongho, Coffey, Kevin R., Murch, Graeme E., & Belova, Irina V.. Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion. United States. https://doi.org/10.1007/s11669-014-0344-4
Kulkarni, Nagraj S., Bruce Warmack, Robert J., Radhakrishnan, Bala, Hunter, Jerry L., Sohn, Yongho, Coffey, Kevin R., Murch, Graeme E., and Belova, Irina V.. Tue .
"Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion". United States. https://doi.org/10.1007/s11669-014-0344-4. https://www.osti.gov/servlets/purl/1159422.
@article{osti_1159422,
title = {Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion},
author = {Kulkarni, Nagraj S. and Bruce Warmack, Robert J. and Radhakrishnan, Bala and Hunter, Jerry L. and Sohn, Yongho and Coffey, Kevin R. and Murch, Graeme E. and Belova, Irina V.},
abstractNote = {Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-high vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627° C (523 900 K).},
doi = {10.1007/s11669-014-0344-4},
journal = {Journal of Phase Equilibria and Diffusion},
number = 6,
volume = 35,
place = {United States},
year = {Tue Sep 23 00:00:00 EDT 2014},
month = {Tue Sep 23 00:00:00 EDT 2014}
}
Web of Science
Works referenced in this record:
A note on Manning's relations for concentrated multicomponent alloys
journal, August 1986
- Lidiard, A. B.
- Acta Metallurgica, Vol. 34, Issue 8
Anisotropie d'autodiffusion du magnesium
journal, December 1971
- Combronde, J.; Brebec, G.
- Acta Metallurgica, Vol. 19, Issue 12
Integrated computational materials engineering: A new paradigm for the global materials profession
journal, November 2006
- Allison, John; Backman, Dan; Christodoulou, Leo
- JOM, Vol. 58, Issue 11
Aluminum Impurity Diffusion in Magnesium
journal, March 2012
- Brennan, Sarah; Warren, Andrew P.; Coffey, Kevin R.
- Journal of Phase Equilibria and Diffusion, Vol. 33, Issue 2
Lattice and grain boundary diffusion of cations in 3YTZ analyzed using SIMS
journal, November 2005
- Swaroop, Sathya; Kilo, Martin; Argirusis, Christos
- Acta Materialia, Vol. 53, Issue 19
A self-consistent theory of matter transport in a random lattice gas and some simulation results
journal, January 1989
- Moleko, L. K.; Allnatt, A. R.; Allnatt, E. L.
- Philosophical Magazine A, Vol. 59, Issue 1
Influence of dislocations on diffusion kinetics in solids with particular reference to the alkali halides
journal, January 1961
- Harrison, L. G.
- Transactions of the Faraday Society, Vol. 57
Heterodiffusion de Ag, Cd, In, Sn et Sb dans le magnesium
journal, January 1972
- Combronde, J.; Brebec, G.
- Acta Metallurgica, Vol. 20, Issue 1
Correlation Factors for Diffusion in Nondilute Alloys
journal, August 1971
- Manning, John R.
- Physical Review B, Vol. 4, Issue 4
Probing Diffusion Kinetics with Secondary Ion Mass Spectrometry
journal, December 2009
- De Souza, Roger A.; Martin, Manfred
- MRS Bulletin, Vol. 34, Issue 12
Correlations for diffusion constants
journal, August 1980
- Brown, A. M.; Ashby, M. F.
- Acta Metallurgica, Vol. 28, Issue 8
Grain Boundary Diffusion in Metals: Recent Developments
journal, January 2003
- Herzig, Christian; Divinski, Sergiy V.
- MATERIALS TRANSACTIONS, Vol. 44, Issue 1
Diffusion kinetics in dilute binary alloys with the h.c.p. crystal structure
journal, June 2014
- Allnatt, A. R.; Belova, I. V.; Murch, G. E.
- Philosophical Magazine, Vol. 94, Issue 22
First-principles calculations of impurity diffusion coefficients in dilute Mg alloys using the 8-frequency model
journal, May 2011
- Ganeshan, S.; Hector, L. G.; Liu, Z. -K.
- Acta Materialia, Vol. 59, Issue 8
Atom Probe Tomography of Electronic Materials
journal, August 2007
- Kelly, Thomas F.; Larson, David J.; Thompson, Keith
- Annual Review of Materials Research, Vol. 37, Issue 1
Magnesium: Current and potential automotive applications
journal, February 2002
- Luo, Alan A.
- JOM, Vol. 54, Issue 2
Development of a diffusion mobility database for Ni-base superalloys
journal, February 2002
- Campbell, C. E.; Boettinger, W. J.; Kattner, U. R.
- Acta Materialia, Vol. 50, Issue 4
Thermo-Calc & DICTRA, computational tools for materials science
journal, June 2002
- Andersson, J-O; Helander, Thomas; Höglund, Lars
- Calphad, Vol. 26, Issue 2
DICTRA, a tool for simulation of diffusional transformations in alloys
journal, May 2000
- Borgenstam, Annika; Höglund, Lars; Ågren, John
- Journal of Phase Equilibria, Vol. 21, Issue 3