1H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles

Bordonali, L.; Furukawa, Y.; Kraken, M.; Litterst, F. J.; Sangregorio, C.; Casula, M. F.; Lascialfari, A.

doi:10.1103/PhysRevB.85.174426

Title: ¹H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles

Authors:: Bordonali, L.; Furukawa, Y.; Kraken, M.; Litterst, F. J.; Sangregorio, C.; Casula, M. F.; Lascialfari, A.

Publication Date:: Thu May 17 00:00:00 EDT 2012

Sponsoring Org.:: USDOE

OSTI Identifier:: 1104074

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review. B, Condensed Matter and Materials Physics

Additional Journal Information:: Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Volume: 85 Journal Issue: 17; Journal ID: ISSN 1098-0121

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Bordonali, L., Furukawa, Y., Kraken, M., Litterst, F. J., Sangregorio, C., Casula, M. F., and Lascialfari, A. 1H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles.  United States: N. p., 2012. 
Web.  doi:10.1103/PhysRevB.85.174426.

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                    Bordonali, L., Furukawa, Y., Kraken, M., Litterst, F. J., Sangregorio, C., Casula, M. F., & Lascialfari, A. 1H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles.  United States.  https://doi.org/10.1103/PhysRevB.85.174426

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                    Bordonali, L., Furukawa, Y., Kraken, M., Litterst, F. J., Sangregorio, C., Casula, M. F., and Lascialfari, A. Thu .  
"1H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles".  United States.  https://doi.org/10.1103/PhysRevB.85.174426.

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@article{osti_1104074,

  title        = {1H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles},

  author       = {Bordonali, L. and Furukawa, Y. and Kraken, M. and Litterst, F. J. and Sangregorio, C. and Casula, M. F. and Lascialfari, A.},

  abstractNote = {},

  doi          = {10.1103/PhysRevB.85.174426},

  journal      = {Physical Review. B, Condensed Matter and Materials Physics},

  number       = 17,

  volume       = 85,

  place        = {United States},

  year         = {Thu May 17 00:00:00 EDT 2012},

  month        = {Thu May 17 00:00:00 EDT 2012}

}

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https://doi.org/10.1103/PhysRevB.85.174426

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Works referenced in this record:

Spin-glass behavior in an interacting $γ {-Fe}_{2} O_{3}$ nanoparticle system
journal, March 2008

Parker, D.; Dupuis, V.; Ladieu, F.
Physical Review B, Vol. 77, Issue 10
DOI: 10.1103/PhysRevB.77.104428

Scaling behavior of the proton spin-lattice relaxation rate in antiferromagnetic molecular rings
journal, October 2004

Baek, S. H.; Luban, M.; Lascialfari, A.
Physical Review B, Vol. 70, Issue 13
DOI: 10.1103/PhysRevB.70.134434

Magnetic resonance in iron oxide nanoparticles: Quantum features and effect of size
journal, September 2008

Noginov, Maxim M.; Noginova, N.; Amponsah, O.
Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 18
DOI: 10.1016/j.jmmm.2008.04.154

NMR and spin relaxation in systems with magnetic nanoparticles: effects of size and molecular motion
journal, June 2009

Noginova, N.; Weaver, T.; Andreyev, A.
Journal of Physics: Condensed Matter, Vol. 21, Issue 25
DOI: 10.1088/0953-8984/21/25/255301

Spin dynamics of the ferric wheel ${Fe}_{6} {(triethanolaminate 3 −)}_{6}$ studied by electron and nuclear spin resonance
journal, May 2005

Pilawa, B.; Boffinger, R.; Keilhauer, I.
Physical Review B, Vol. 71, Issue 18
DOI: 10.1103/PhysRevB.71.184419

Low temperature specific heat of molecular rings: a study on the effects of the internal guest substitution and on the lattice contribution
journal, June 2000

Affronte, M.; Lasjaunias, J. C.; Cornia, A.
The European Physical Journal B, Vol. 15, Issue 4
DOI: 10.1007/s100510051166

Looking for quantum effects in magnetic nanoparticles using the molecular nanomagnet approach
journal, March 2011

Fittipaldi, M.; Innocenti, C.; Ceci, P.
Physical Review B, Vol. 83, Issue 10
DOI: 10.1103/PhysRevB.83.104409

Nuclear Magnetic Relaxation in Antiferromagnetics
journal, July 1956

Moriya, Tôru
Progress of Theoretical Physics, Vol. 16, Issue 1
DOI: 10.1143/PTP.16.23

Low Temperature Surface Spin-Glass Transition in $γ$ - ${Fe}_{2} O_{3}$ Nanoparticles
journal, January 1998

Martínez, B.; Obradors, X.; Balcells, Ll.
Physical Review Letters, Vol. 80, Issue 1
DOI: 10.1103/PhysRevLett.80.181

Surface effects in noninteracting and interacting γ-Fe2O3 nanoparticles
journal, May 2003

Tronc, E.; Fiorani, D.; Noguès, M.
Journal of Magnetism and Magnetic Materials, Vol. 262, Issue 1
DOI: 10.1016/S0304-8853(03)00011-8

Core-Shell Magnetic Morphology of Structurally Uniform Magnetite Nanoparticles
journal, May 2010

Krycka, K. L.; Booth, R. A.; Hogg, C. R.
Physical Review Letters, Vol. 104, Issue 20
DOI: 10.1103/PhysRevLett.104.207203

Nuclear Magnetic Relaxation near the Curie Temperature
journal, August 1962

Moriya, Tôru
Progress of Theoretical Physics, Vol. 28, Issue 2
DOI: 10.1143/PTP.28.371

NMR and μSR investigation of spin dynamics in {Mo72Fe30} molecular clusters
journal, May 2004

Micotti, E.; Procissi, D.; Lascialfari, A.
Journal of Magnetism and Magnetic Materials, Vol. 272-276
DOI: 10.1016/j.jmmm.2003.12.038

Interparticle interactions in magnetic core/shell nanoarchitectures
journal, July 2009

Papaefthymiou, Georgia C.; Devlin, Eamonn; Simopoulos, Athanassios
Physical Review B, Vol. 80, Issue 2
DOI: 10.1103/PhysRevB.80.024406

NMR study of the molecular nanomagnet $[{Fe}_{8} (N_{3} C_{6} H_{15})_{6} O_{2} (OH)_{12}]$ $\cdot [{Br}_{8} \cdot 9 H_{2} O]$ in the high-spin magnetic ground state
journal, August 2001

Furukawa, Y.; Kumagai, K.; Lascialfari, A.
Physical Review B, Vol. 64, Issue 9
DOI: 10.1103/PhysRevB.64.094439

Finite-size effects in fine particles: magnetic and transport properties
journal, March 2002

Batlle, Xavier; Labarta, Amílcar
Journal of Physics D: Applied Physics, Vol. 35, Issue 6
DOI: 10.1088/0022-3727/35/6/201

Spin disorder and magnetic anisotropy in Fe3O4 nanoparticles
journal, April 2006

Lima, E.; Brandl, A. L.; Arelaro, A. D.
Journal of Applied Physics, Vol. 99, Issue 8
DOI: 10.1063/1.2191471

Surface effects in nanoparticles: application to maghemite -Fe O
journal, April 2000

Kachkachi, H.; Ezzir, A.; Noguès, M.
The European Physical Journal B, Vol. 14, Issue 4
DOI: 10.1007/s100510051079

Fragility of the spin-glass-like collective state to a magnetic field in an interacting Fe-C nanoparticle system
journal, November 2001

Jönsson, P. E.; Felton, S.; Svedlindh, P.
Physical Review B, Vol. 64, Issue 21
DOI: 10.1103/PhysRevB.64.212402

Moment fluctuations in 7nm γ‐Fe2O3 nanoparticles probed at the atomic level using Mössbauer spectroscopy
journal, April 2008

Desautels, R. D.; Skoropata, E.; van Lierop, J.
Journal of Applied Physics, Vol. 103, Issue 7
DOI: 10.1063/1.2830963

Magnetic Dynamics of Iron-Oxide Nanoparticles in Frozen Ferrofluids and Ferronematics
journal, August 2004

Goya, Gerardo F.; Gómez, S. L.; Shibli, S. M.
Journal of Metastable and Nanocrystalline Materials, Vol. 22
DOI: 10.4028/www.scientific.net/JMNM.22.33

Static and dynamic magnetic properties of spherical magnetite nanoparticles
journal, September 2003

Goya, G. F.; Berquó, T. S.; Fonseca, F. C.
Journal of Applied Physics, Vol. 94, Issue 5
DOI: 10.1063/1.1599959

Preparation of aqueous magnetic liquids in alkaline and acidic media
journal, March 1981

Massart, R.
IEEE Transactions on Magnetics, Vol. 17, Issue 2
DOI: 10.1109/TMAG.1981.1061188

Relaxation Effects in Nuclear Magnetic Resonance Absorption
journal, April 1948

Bloembergen, N.; Purcell, E. M.; Pound, R. V.
Physical Review, Vol. 73, Issue 7
DOI: 10.1103/PhysRev.73.679

Progress in applications of magnetic nanoparticles in biomedicine
journal, November 2009

Pankhurst, Q. A.; Thanh, N. T. K.; Jones, S. K.
Journal of Physics D: Applied Physics, Vol. 42, Issue 22
DOI: 10.1088/0022-3727/42/22/224001

Field Dependence of Blocking Temperature in Magnetite Nanoparticles
journal, July 2004

Goya, Gerardo F.; Morales, M. P.
Journal of Metastable and Nanocrystalline Materials, Vol. 20-21
DOI: 10.4028/www.scientific.net/JMNM.20-21.673

Spin Dynamics of the Molecular Nanomagnet Fe8 Studied by 1 H-NMR
journal, January 2002

Furukawa, Yuji; Aizawa, Kota; Kumagai, Ken-Ichi
Molecular Crystals and Liquid Crystals, Vol. 379, Issue 1
DOI: 10.1080/713738664

Surface and Internal Spin Canting in γ-Fe ₂ O ₃ Nanoparticles
journal, November 1999

Morales, M. P.; Veintemillas-Verdaguer, S.; Montero, M. I.
Chemistry of Materials, Vol. 11, Issue 11
DOI: 10.1021/cm991018f

Strategies of Large Scale Synthesis of Monodisperse Nanoparticles
journal, January 2009

Cui, Hongtao; Feng, Yongmei; Ren, Wanzhong
Recent Patents on Nanotechnology, Vol. 3, Issue 1
DOI: 10.2174/187221009787003302

Surface anisotropy broadening of the energy barrier distribution in magnetic nanoparticles
journal, October 2008

Pérez, N.; Guardia, P.; Roca, A. G.
Nanotechnology, Vol. 19, Issue 47
DOI: 10.1088/0957-4484/19/47/475704

Spin-glass-like characteristics of extremely small γ-Fe ₂ O ₃ nanoparticles
journal, January 2010

Leite, E. S.; Coaquira, J. A. H.; Viali, W. R.
Journal of Physics: Conference Series, Vol. 200, Issue 7
DOI: 10.1088/1742-6596/200/7/072060

Magnetic relaxation in terms of microscopic energy barriers in a model of dipolar interacting nanoparticles
journal, October 2004

Iglesias, Òscar; Labarta, Amílcar
Physical Review B, Vol. 70, Issue 14
DOI: 10.1103/PhysRevB.70.144401

NMR and spin relaxation in systems with magnetic nanoparticles
journal, February 2007

Noginova, N.; Weaver, T.; King, M.
Journal of Physics: Condensed Matter, Vol. 19, Issue 7
DOI: 10.1088/0953-8984/19/7/076210

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Title: 1H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles

Citation Formats

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Surface and Internal Spin Canting in γ-Fe 2 O 3 Nanoparticles journal, November 1999

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Title: ¹H-NMR study of the spin dynamics of fine superparamagnetic nanoparticles

Spin-glass behavior in an interacting $γ {-Fe}_{2} O_{3}$ nanoparticle system
journal, March 2008

Scaling behavior of the proton spin-lattice relaxation rate in antiferromagnetic molecular rings
journal, October 2004

Magnetic resonance in iron oxide nanoparticles: Quantum features and effect of size
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NMR and spin relaxation in systems with magnetic nanoparticles: effects of size and molecular motion
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Spin dynamics of the ferric wheel ${Fe}_{6} {(triethanolaminate 3 −)}_{6}$ studied by electron and nuclear spin resonance
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Low temperature specific heat of molecular rings: a study on the effects of the internal guest substitution and on the lattice contribution
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Looking for quantum effects in magnetic nanoparticles using the molecular nanomagnet approach
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