Multiferroic Phase Transition near Room Temperature in BiFeO3 Films

Infante, I. C.; Juraszek, J.; Fusil, S.; Dupé, B.; Gemeiner, P.; Diéguez, O.; Pailloux, F.; Jouen, S.; Jacquet, E.; Geneste, G.; Pacaud, J.; Íñiguez, J.; Bellaiche, L.; Barthélémy, A.; Dkhil, B.; Bibes, M.

doi:10.1103/PhysRevLett.107.237601

Title: Multiferroic Phase Transition near Room Temperature in BiFeO₃ Films

Authors:: Infante, I. C.; Juraszek, J.; Fusil, S.; Dupé, B.; Gemeiner, P.; Diéguez, O.; Pailloux, F.; Jouen, S.; Jacquet, E.; Geneste, G.; Pacaud, J.; Íñiguez, J.; Bellaiche, L.; Barthélémy, A.; Dkhil, B.; Bibes, M.

Publication Date:: Wed Nov 30 00:00:00 EST 2011

Sponsoring Org.:: USDOE

OSTI Identifier:: 1098324

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review Letters

Additional Journal Information:: Journal Name: Physical Review Letters Journal Volume: 107 Journal Issue: 23; Journal ID: ISSN 0031-9007

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Infante, I. C., Juraszek, J., Fusil, S., Dupé, B., Gemeiner, P., Diéguez, O., Pailloux, F., Jouen, S., Jacquet, E., Geneste, G., Pacaud, J., Íñiguez, J., Bellaiche, L., Barthélémy, A., Dkhil, B., and Bibes, M. Multiferroic Phase Transition near Room Temperature in BiFeO3 Films.  United States: N. p., 2011. 
Web.  doi:10.1103/PhysRevLett.107.237601.

Copy to clipboard


                    Infante, I. C., Juraszek, J., Fusil, S., Dupé, B., Gemeiner, P., Diéguez, O., Pailloux, F., Jouen, S., Jacquet, E., Geneste, G., Pacaud, J., Íñiguez, J., Bellaiche, L., Barthélémy, A., Dkhil, B., & Bibes, M. Multiferroic Phase Transition near Room Temperature in BiFeO3 Films.  United States.  https://doi.org/10.1103/PhysRevLett.107.237601

Copy to clipboard


                    Infante, I. C., Juraszek, J., Fusil, S., Dupé, B., Gemeiner, P., Diéguez, O., Pailloux, F., Jouen, S., Jacquet, E., Geneste, G., Pacaud, J., Íñiguez, J., Bellaiche, L., Barthélémy, A., Dkhil, B., and Bibes, M. Wed .  
"Multiferroic Phase Transition near Room Temperature in BiFeO3 Films".  United States.  https://doi.org/10.1103/PhysRevLett.107.237601.

Copy to clipboard


                    
@article{osti_1098324,

  title        = {Multiferroic Phase Transition near Room Temperature in BiFeO3 Films},

  author       = {Infante, I. C. and Juraszek, J. and Fusil, S. and Dupé, B. and Gemeiner, P. and Diéguez, O. and Pailloux, F. and Jouen, S. and Jacquet, E. and Geneste, G. and Pacaud, J. and Íñiguez, J. and Bellaiche, L. and Barthélémy, A. and Dkhil, B. and Bibes, M.},

  abstractNote = {},

  doi          = {10.1103/PhysRevLett.107.237601},

  journal      = {Physical Review Letters},

  number       = 23,

  volume       = 107,

  place        = {United States},

  year         = {Wed Nov 30 00:00:00 EST 2011},

  month        = {Wed Nov 30 00:00:00 EST 2011}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1103/PhysRevLett.107.237601

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 82 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Physics and Applications of Bismuth Ferrite
journal, June 2009

Catalan, Gustau; Scott, James F.
Advanced Materials, Vol. 21, Issue 24
DOI: 10.1002/adma.200802849

First-principles predictions of low-energy phases of multiferroic BiFeO $_{3}$
journal, March 2011

Diéguez, Oswaldo; González-Vázquez, O. E.; Wojdeł, Jacek C.
Physical Review B, Vol. 83, Issue 9
DOI: 10.1103/PhysRevB.83.094105

Evidence for Room-Temperature Multiferroicity in a Compound with a Giant Axial Ratio
journal, May 2009

Béa, H.; Dupé, B.; Fusil, S.
Physical Review Letters, Vol. 102, Issue 21
DOI: 10.1103/PhysRevLett.102.217603

Strain-induced isosymmetric phase transition in ${BiFeO}_{3}$
journal, February 2010

Hatt, Alison J.; Spaldin, Nicola A.; Ederer, Claude
Physical Review B, Vol. 81, Issue 5
DOI: 10.1103/PhysRevB.81.054109

A mechanism for the 150 µC cm⁻² polarization of BiFeO₃ films based on first-principles calculations and new structural data
journal, January 2006

Ricinschi, Dan; Yun, Kwi-Young; Okuyama, Masanori
Journal of Physics: Condensed Matter, Vol. 18, Issue 6, p. L97-L105
DOI: 10.1088/0953-8984/18/6/L03

Magnetoelectricity in BiFeO $_{3}$ films: First-principles-based computations and phenomenology
journal, January 2011

Prosandeev, S.; Kornev, Igor A.; Bellaiche, L.
Physical Review B, Vol. 83, Issue 2
DOI: 10.1103/PhysRevB.83.020102

A Strain-Driven Morphotropic Phase Boundary in BiFeO₃
journal, November 2009

Zeches, R. J.; Rossell, M. D.; Zhang, J. X.
Science, Vol. 326, Issue 5955, p. 977-980
DOI: 10.1126/science.1177046

First-Principles Investigation of Morphotropic Transitions and Phase-Change Functional Responses in ${BiFeO}_{3} − {BiCoO}_{3}$ Multiferroic Solid Solutions
journal, July 2011

Diéguez, Oswaldo; Íñiguez, Jorge
Physical Review Letters, Vol. 107, Issue 5
DOI: 10.1103/PhysRevLett.107.057601

A phase transition close to room temperature in BiFeO ₃ thin films
journal, August 2011

Kreisel, J.; Jadhav, P.; Chaix-Pluchery, O.
Journal of Physics: Condensed Matter, Vol. 23, Issue 34
DOI: 10.1088/0953-8984/23/34/342202

Multiferroicity: the coupling between magnetic and polarization orders
journal, July 2009

Wang, K. F.; Liu, J. -M.; Ren, Z. F.
Advances in Physics, Vol. 58, Issue 4
DOI: 10.1080/00018730902920554

Enhancement of Ferroelectricity in Strained BaTiO₃ Thin Films
journal, November 2004

Choi, K. J.; Biegalski, M.; Li, Y. L.
Science, Vol. 306, Issue 5698, p. 1005-1009
DOI: 10.1126/science.1103218

Electric-field-induced phase transitions in rhombohedral $Pb ({Zn}_{1 / 3} {Nb}_{2 / 3})_{1 - x} {Ti}_{x} O_{3}$
journal, May 2002

Noheda, B.; Zhong, Z.; Cox, D. E.
Physical Review B, Vol. 65, Issue 22
DOI: 10.1103/PhysRevB.65.224101

Stress-induced $R - M_{A} - M_{C} - T$ symmetry changes in BiFeO $_{3}$ films
journal, April 2011

Christen, H. M.; Nam, J. H.; Kim, H. S.
Physical Review B, Vol. 83, Issue 14
DOI: 10.1103/PhysRevB.83.144107

Competing phases in ${BiFeO}_{3}$ thin films under compressive epitaxial strain
journal, April 2010

Dupé, B.; Infante, I. C.; Geneste, G.
Physical Review B, Vol. 81, Issue 14
DOI: 10.1103/PhysRevB.81.144128

Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films
journal, August 2005

Béa, H.; Bibes, M.; Barthélémy, A.
Applied Physics Letters, Vol. 87, Issue 7
DOI: 10.1063/1.2009808

Temperature-Driven Structural Phase Transition in Tetragonal-Like BiFeO$_{3}$
journal, August 2011

Siemons, Wolter; Biegalski, Michael D.; Nam, Joong Hee
Applied Physics Express, Vol. 4, Issue 9
DOI: 10.1143/APEX.4.095801

Ultrathin oxide films and interfaces for electronics and spintronics
journal, February 2011

Bibes, Manuel; Villegas, Javier E.; Barthélémy, Agnès
Advances in Physics, Vol. 60, Issue 1
DOI: 10.1080/00018732.2010.534865

Bridging Multiferroic Phase Transitions by Epitaxial Strain in ${BiFeO}_{3}$
journal, July 2010

Infante, I. C.; Lisenkov, S.; Dupé, B.
Physical Review Letters, Vol. 105, Issue 5
DOI: 10.1103/PhysRevLett.105.057601

Ab Initio Indications for Giant Magnetoelectric Effects Driven by Structural Softness
journal, July 2010

Wojdeł, Jacek C.; Íñiguez, Jorge
Physical Review Letters, Vol. 105, Issue 3
DOI: 10.1103/PhysRevLett.105.037208

Phase stability and structural temperature dependence in powdered multiferroic ${BiFeO}_{3}$
journal, October 2008

Haumont, R.; Kornev, Igor A.; Lisenkov, S.
Physical Review B, Vol. 78, Issue 13
DOI: 10.1103/PhysRevB.78.134108

Evidence for a first-order transition from monoclinic $α$ to monoclinic $β$ phase in ${BiFeO}_{3}$ thin films
journal, April 2010

Toupet, H.; Le Marrec, F.; Lichtensteiger, C.
Physical Review B, Vol. 81, Issue 14
DOI: 10.1103/PhysRevB.81.140101

Spintronics with multiferroics
journal, October 2008

Béa, H.; Gajek, M.; Bibes, M.
Journal of Physics: Condensed Matter, Vol. 20, Issue 43
DOI: 10.1088/0953-8984/20/43/434221

A setup combining magneto-optical Kerr effect and conversion electron Mössbauer spectrometry for analysis of the near-surface magnetic properties of thin films
journal, April 2009

Juraszek, J.; Zivotsky, O.; Chiron, H.
Review of Scientific Instruments, Vol. 80, Issue 4
DOI: 10.1063/1.3121215

Similar Records in DOE PAGES and OSTI.GOV collections:

Temperature dependent photoexcited carrier dynamics in multiferroic BiFeO{sub 3} film: A hidden phase transition

Journal Article Zhang, Zeyu ; Jin, Zuanming ; Pan, Qunfeng ; ... - Applied Physics Letters

The ultrafast carrier dynamics of the multiferroic BiFeO{sub 3} film in a broad temperature range is investigated using optical pump-probe spectroscopy. The photoexcited electrons release their energy with optical phonons emission through electron-phonon coupling in about 1 ps. The following intermediate process is identified as dynamical spin-lattice coupling in several picoseconds. Furthermore, the peak values of the optical reflectivity and the time constants of carrier relaxation channels show significant changes while the temperature varies from 137.5 K to around 195 K, this aligns with the previously reported hidden phase transition. Our study demonstrates that ultrafast spectroscopy is a sensitive method to lookmore »« less
https://doi.org/10.1063/1.4871689
Deterministic optical control of room temperature multiferroicity in BiFeO₃ thin films

Journal Article Liou, Yi-De ; Chiu, Yu-You ; Hart, Ryan Thomas ; ... - Nature Materials

Controlling ferroic orders (ferroelectricity, ferromagnetism and ferroelasticity) by optical methods is a significant challenge due to the large mismatch in energy scales between the order parameter coupling strengths and the incident photons. In this work, we demonstrate an approach to manipulate multiple ferroic orders in an epitaxial mixed-phase BiFeO₃ thin film at ambient temperature via laser illumination. Phase-field simulations indicate that a light-driven flexoelectric effect enables the targeted formation of ordered domains. We also achieved precise sequential laser writing and erasure of different domain patterns, which demonstrates a deterministic optical control of multiferroicity at room temperature. As ferroic orders directlymore »« less
Cited by 54
https://doi.org/10.1038/s41563-019-0348-x

Full Text Available
Self-Assembled Room Temperature Multiferroic BiFeO₃-LiFe₅O₈ Nanocomposites

Journal Article Sharma, Yogesh ; Agarwal, Radhe ; Collins, Liam ; ... - Advanced Functional Materials

Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room-temperature multiferroics and understanding their fundamental properties are important to reveal unanticipated physical phenomena and potential applications. Here, a new room temperature multiferroic nanocomposite comprised of an ordered ferrimagnetic spinel α-LiFe₅O₈ (LFO) and a ferroelectric perovskite BiFeO₃ (BFO) is presented. It is observed that lithium (Li)-doping in BFO favors the formation of LFO spinel as a secondary phase during the synthesis of Li_xBi_1-xFeO₃ ceramics. Multimodal functional and chemical imaging methods are used to map the relationship between doping-induced phase separation and local ferroic properties inmore »« less
Cited by 11
https://doi.org/10.1002/adfm.201906849

Full Text Available
Optical diode effect at spin-wave excitations in the room-temperature multiferroic BiFeO₃.

Journal Article Kezsmarki, I. ; Nagel, U. ; Bordacs, S. ; ... - Physical Review Letters

The ability to read and write a magnetic state current-free by an electric voltage would provide a huge technological advantage. Dynamic or optical ME effects are equally interesting, because they give rise to unidirectional light propagation as recently observed in low-temperature multiferroics. This phenomenon, if realized at room temperature, would allow the development of optical diodes which transmit unpolarized light in one, but not in the opposite, direction. Here, we report strong unidirectional transmission in the room-temperature multiferroic BiFeO₃ over the gigahertz-terahertz frequency range. The supporting theory attributes the observed unidirectional transmission to the spin-current-driven dynamic ME effect. Our findingsmore »« less
Cited by 61
https://doi.org/10.1103/PhysRevLett.115.127203

Full Text Available
Spin-Induced Polarizations and Nonreciprocal Directional Dichroism of the Room-Temperature Multiferroic BiFeO₃

Journal Article Fishman, Randy Scott ; Lee, Jun Hee ; Bordacs, Sandor ; ... - Physical Review. B, Condensed Matter and Materials Physics

A microscopic model for the room-temperature multiferroic BiFeO₃ that includes two Dzyaloshinskii-Moriya interactions and single-ion anisotropy along the ferroelectric polarization predicts both the zero-field spectroscopic modes as well as their splitting and evolution in a magnetic field. Due to simultaneously broken time-reversal and spatial-inversion symmetries, the absorption of light changes as the magnetic field or the direction of light propagation is reversed. We discuss three physical mechanisms that may contribute to this absorption asymmetry known as directional dichroism: the spin current, magnetostriction, and single-ion anisotropy. We conclude that the directional dichroism in BiFeO₃ is dominated by the spin-current polarization andmore »« less
Cited by 25
https://doi.org/10.1103/PhysRevB.92.094422

Full Text Available

Similar Records

Title: Multiferroic Phase Transition near Room Temperature in BiFeO3 Films

Citation Formats

Physics and Applications of Bismuth Ferrite journal, June 2009

First-principles predictions of low-energy phases of multiferroic BiFeO 3 journal, March 2011

Evidence for Room-Temperature Multiferroicity in a Compound with a Giant Axial Ratio journal, May 2009

Strain-induced isosymmetric phase transition in BiFeO 3 journal, February 2010

A mechanism for the 150 µC cm−2 polarization of BiFeO3 films based on first-principles calculations and new structural data journal, January 2006

Magnetoelectricity in BiFeO 3 films: First-principles-based computations and phenomenology journal, January 2011

A Strain-Driven Morphotropic Phase Boundary in BiFeO3 journal, November 2009

First-Principles Investigation of Morphotropic Transitions and Phase-Change Functional Responses in BiFeO 3 − BiCoO 3 Multiferroic Solid Solutions journal, July 2011

A phase transition close to room temperature in BiFeO 3 thin films journal, August 2011

Multiferroicity: the coupling between magnetic and polarization orders journal, July 2009

Enhancement of Ferroelectricity in Strained BaTiO3 Thin Films journal, November 2004

Electric-field-induced phase transitions in rhombohedral Pb ( Zn 1 / 3 Nb 2 / 3 ) 1 − x Ti x O 3 journal, May 2002

Stress-induced R − M A − M C − T symmetry changes in BiFeO 3 films journal, April 2011

Competing phases in BiFeO 3 thin films under compressive epitaxial strain journal, April 2010

Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films journal, August 2005

Temperature-Driven Structural Phase Transition in Tetragonal-Like BiFeO$_{3}$ journal, August 2011

Ultrathin oxide films and interfaces for electronics and spintronics journal, February 2011

Bridging Multiferroic Phase Transitions by Epitaxial Strain in BiFeO 3 journal, July 2010

Ab Initio Indications for Giant Magnetoelectric Effects Driven by Structural Softness journal, July 2010

Phase stability and structural temperature dependence in powdered multiferroic BiFeO 3 journal, October 2008

Evidence for a first-order transition from monoclinic α to monoclinic β phase in BiFeO 3 thin films journal, April 2010

Spintronics with multiferroics journal, October 2008

A setup combining magneto-optical Kerr effect and conversion electron Mössbauer spectrometry for analysis of the near-surface magnetic properties of thin films journal, April 2009

Title: Multiferroic Phase Transition near Room Temperature in BiFeO₃ Films

Physics and Applications of Bismuth Ferrite
journal, June 2009

First-principles predictions of low-energy phases of multiferroic BiFeO $_{3}$
journal, March 2011

Evidence for Room-Temperature Multiferroicity in a Compound with a Giant Axial Ratio
journal, May 2009

Strain-induced isosymmetric phase transition in ${BiFeO}_{3}$
journal, February 2010

A mechanism for the 150 µC cm⁻² polarization of BiFeO₃ films based on first-principles calculations and new structural data
journal, January 2006

Magnetoelectricity in BiFeO $_{3}$ films: First-principles-based computations and phenomenology
journal, January 2011

A Strain-Driven Morphotropic Phase Boundary in BiFeO₃
journal, November 2009

First-Principles Investigation of Morphotropic Transitions and Phase-Change Functional Responses in ${BiFeO}_{3} − {BiCoO}_{3}$ Multiferroic Solid Solutions
journal, July 2011

A phase transition close to room temperature in BiFeO ₃ thin films
journal, August 2011

Multiferroicity: the coupling between magnetic and polarization orders
journal, July 2009

Enhancement of Ferroelectricity in Strained BaTiO₃ Thin Films
journal, November 2004

Electric-field-induced phase transitions in rhombohedral $Pb ({Zn}_{1 / 3} {Nb}_{2 / 3})_{1 - x} {Ti}_{x} O_{3}$
journal, May 2002

Stress-induced $R - M_{A} - M_{C} - T$ symmetry changes in BiFeO $_{3}$ films
journal, April 2011

Competing phases in ${BiFeO}_{3}$ thin films under compressive epitaxial strain
journal, April 2010

Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films
journal, August 2005

Temperature-Driven Structural Phase Transition in Tetragonal-Like BiFeO$_{3}$
journal, August 2011

Ultrathin oxide films and interfaces for electronics and spintronics
journal, February 2011

Bridging Multiferroic Phase Transitions by Epitaxial Strain in ${BiFeO}_{3}$
journal, July 2010

Ab Initio Indications for Giant Magnetoelectric Effects Driven by Structural Softness
journal, July 2010

Phase stability and structural temperature dependence in powdered multiferroic ${BiFeO}_{3}$
journal, October 2008

Evidence for a first-order transition from monoclinic $α$ to monoclinic $β$ phase in ${BiFeO}_{3}$ thin films
journal, April 2010

Spintronics with multiferroics
journal, October 2008

A setup combining magneto-optical Kerr effect and conversion electron Mössbauer spectrometry for analysis of the near-surface magnetic properties of thin films
journal, April 2009