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Title: Nitrogen is a deep acceptor in ZnO

Abstract

Zinc oxide is a promising material for blue and UV solid-state lighting devices, among other applications. Nitrogen has been regarded as a potential p-type dopant for ZnO. However, recent calculations indicate that nitrogen is a deep acceptor. This paper presents experimental evidence that nitrogen is, in fact, a deep acceptor and therefore cannot produce p-type ZnO. A broad photoluminescence (PL) emission band near 1.7 eV, with an excitation onset of ~2.2 eV, was observed, in agreement with the deep-acceptor model of the nitrogen defect. Thus the deep-acceptor behavior can be explained by the low energy of the ZnO valence band relative to the vacuum level.

Authors:
 [1];  [2];  [1]
+ Show Author Affiliations
  1. Washington State Univ., Pullman, WA (United States)
  2. COMSATS Institute of Information Technology (Pakistan)
Publication Date:
Research Org.:
Washington State Univ., Pullman, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
OSTI Identifier:
1076494
Grant/Contract Number:  
FG02-07ER46386; DMR-1004804
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 1; Journal Issue: 2; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; II-IV semiconductors; photoluminescence; annealing; doping; vacancies

Citation Formats

Tarun, M. C., Iqbal, M. Zafar, and McCluskey, M. D. Nitrogen is a deep acceptor in ZnO. United States: N. p., 2011. Web. doi:10.1063/1.3582819.
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Tarun, M. C., Iqbal, M. Zafar, & McCluskey, M. D. Nitrogen is a deep acceptor in ZnO. United States. https://doi.org/10.1063/1.3582819
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Tarun, M. C., Iqbal, M. Zafar, and McCluskey, M. D. Thu . "Nitrogen is a deep acceptor in ZnO". United States. https://doi.org/10.1063/1.3582819. https://www.osti.gov/servlets/purl/1076494.
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@article{osti_1076494,
title = {Nitrogen is a deep acceptor in ZnO},
author = {Tarun, M. C. and Iqbal, M. Zafar and McCluskey, M. D.},
abstractNote = {Zinc oxide is a promising material for blue and UV solid-state lighting devices, among other applications. Nitrogen has been regarded as a potential p-type dopant for ZnO. However, recent calculations indicate that nitrogen is a deep acceptor. This paper presents experimental evidence that nitrogen is, in fact, a deep acceptor and therefore cannot produce p-type ZnO. A broad photoluminescence (PL) emission band near 1.7 eV, with an excitation onset of ~2.2 eV, was observed, in agreement with the deep-acceptor model of the nitrogen defect. Thus the deep-acceptor behavior can be explained by the low energy of the ZnO valence band relative to the vacuum level.},
doi = {10.1063/1.3582819},
journal = {AIP Advances},
number = 2,
volume = 1,
place = {United States},
year = {Thu Apr 14 00:00:00 EDT 2011},
month = {Thu Apr 14 00:00:00 EDT 2011}
}
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https://doi.org/10.1063/1.3582819
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