Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method

Gao, Hong; Lu, Zhou; Yang, Lei; Zhou, Jingang; Ng, C. Y.

doi:10.1063/1.4764306

Title: Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method

Authors:

Gao, Hong ^[1]; Lu, Zhou ^[1]; Yang, Lei ^[1]; Zhou, Jingang ^[1]; Ng, C. Y. ^[1]

Department of Chemistry, University of California, Davis, California 95616, USA

Publication Date:: Thu Oct 25 00:00:00 EDT 2012

Sponsoring Org.:: USDOE

OSTI Identifier:: 1074843

Grant/Contract Number:: FG02-02ER15306

Resource Type:: Published Article

Journal Name:: Journal of Chemical Physics

Additional Journal Information:: Journal Name: Journal of Chemical Physics Journal Volume: 137 Journal Issue: 16; Journal ID: ISSN 0021-9606

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Gao, Hong, Lu, Zhou, Yang, Lei, Zhou, Jingang, and Ng, C. Y. Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method.  United States: N. p., 2012. 
Web.  doi:10.1063/1.4764306.

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                    Gao, Hong, Lu, Zhou, Yang, Lei, Zhou, Jingang, & Ng, C. Y. Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method.  United States.  https://doi.org/10.1063/1.4764306

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                    Gao, Hong, Lu, Zhou, Yang, Lei, Zhou, Jingang, and Ng, C. Y. Thu .  
"Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method".  United States.  https://doi.org/10.1063/1.4764306.

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@article{osti_1074843,

  title        = {Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method},

  author       = {Gao, Hong and Lu, Zhou and Yang, Lei and Zhou, Jingang and Ng, C. Y.},

  abstractNote = {},

  doi          = {10.1063/1.4764306},

  journal      = {Journal of Chemical Physics},

  number       = 16,

  volume       = 137,

  place        = {United States},

  year         = {Thu Oct 25 00:00:00 EDT 2012},

  month        = {Thu Oct 25 00:00:00 EDT 2012}

}

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Works referenced in this record:

Direct identification of propargyl radical in combustion flames by vacuum ultraviolet photoionization mass spectrometry
journal, February 2006

Zhang, T.; Tang, X. N.; Lau, K. -C.
The Journal of Chemical Physics, Vol. 124, Issue 7
DOI: 10.1063/1.2168448

Determination of absolute photoionization cross sections for vinyl and propargyl radicals
journal, September 2003

Robinson, Jason C.; Sveum, Niels E.; Neumark, Daniel M.
The Journal of Chemical Physics, Vol. 119, Issue 11
DOI: 10.1063/1.1606440

Vacuum ultraviolet laser pulsed field ionization-photoelectron study of allyl radical CH2CHCH2
journal, May 2007

Xing, Xi; Reed, Beth; Lau, Kai-Chung
The Journal of Chemical Physics, Vol. 126, Issue 17
DOI: 10.1063/1.2737443

Highly Accurate Quartic Force Fields, Vibrational Frequencies, and Spectroscopic Constants for Cyclic and Linear C₃H₃⁺
journal, April 2011

Huang, Xinchuan; Taylor, Peter R.; Lee, Timothy J.
The Journal of Physical Chemistry A, Vol. 115, Issue 19
DOI: 10.1021/jp2019704

One-dimensional tomography: a comparison of Abel, onion-peeling, and filtered backprojection methods
journal, January 1992

Dasch, Cameron J.
Applied Optics, Vol. 31, Issue 8
DOI: 10.1364/AO.31.001146

Applications of slow electron velocity map imaging to the study of spectroscopy and dynamics in small aromatic molecules
journal, January 2008

Hammond, Chris J.; Reid, Katharine L.
Physical Chemistry Chemical Physics, Vol. 10, Issue 45
DOI: 10.1039/b812254g

High-resolution threshold photoelectron study of the propargyl radical by the vacuum ultraviolet laser velocity-map imaging method
journal, December 2011

Gao, Hong; Xu, Yuntao; Yang, Lei
The Journal of Chemical Physics, Vol. 135, Issue 22
DOI: 10.1063/1.3664864

A photodissociation study of CH2BrCl in the A-band using the time-sliced ion velocity imaging method
journal, January 2006

Zhou, Jingang; Lau, Kai-Chung; Hassanein, Elsayed
The Journal of Chemical Physics, Vol. 124, Issue 3
DOI: 10.1063/1.2158999

Accurate ab initio predictions of ionization energies of hydrocarbon radicals: CH2, CH3, C2H, C2H3, C2H5, C3H3, and C3H5
journal, June 2005

Lau, K. -C.; Ng, C. Y.
The Journal of Chemical Physics, Vol. 122, Issue 22
DOI: 10.1063/1.1926274

Calculated photoelectron spectra of isotopomers of the propargyl radical (H2C3H): An explicitly correlated coupled cluster study
journal, December 2010

Botschwina, Peter; Oswald, Rainer
Chemical Physics, Vol. 378, Issue 1-3
DOI: 10.1016/j.chemphys.2010.07.030

Astronomical detection of H2CCCC
journal, February 1991

Cernicharo, J.; Gottlieb, C. A.; Guelin, M.
The Astrophysical Journal, Vol. 368
DOI: 10.1086/185944

Mechanisms for the formation of benzene in the atmosphere of Titan: FORMATION OF BENZENE IN TITAN'S ATMOSPHERE
journal, February 2003

Wilson, E. H.; Atreya, S. K.; Coustenis, A.
Journal of Geophysical Research: Planets, Vol. 108, Issue E2
DOI: 10.1029/2002JE001896

A vacuum-ultraviolet laser pulsed field ionization-photoelectron study of sulfur monoxide (SO) and its cation (SO⁺)
journal, April 2011

Lam, Chow-Shing; Wang, Hailing; Xu, Yuntao
The Journal of Chemical Physics, Vol. 134, Issue 14
DOI: 10.1063/1.3575227

Communications: Infrared spectroscopy of gas phase C3H3+ ions: The cyclopropenyl and propargyl cations
journal, February 2010

Ricks, Allen M.; Douberly, Gary E.; Schleyer, Paul v. R.
The Journal of Chemical Physics, Vol. 132, Issue 5
DOI: 10.1063/1.3298881

Kinetic and thermodynamic issues in the formation of aromatic compounds in flames of aliphatic fuels
journal, October 1992

Miller, James A.; Melius, Carl F.
Combustion and Flame, Vol. 91, Issue 1
DOI: 10.1016/0010-2180(92)90124-8

Slow Electron Velocity-Map Imaging of Negative Ions: Applications to Spectroscopy and Dynamics ^†
journal, December 2008

Neumark, Daniel M.
The Journal of Physical Chemistry A, Vol. 112, Issue 51
DOI: 10.1021/jp807182q

Infrared Spectra of C₃H₃⁺-N₂ Dimers: Identification of Proton-Bound c-C₃H₃⁺-N₂ and H₂CCCH⁺-N₂ Isomers
journal, December 2001

Dopfer, Otto; Roth, Doris; Maier, John P.
Journal of the American Chemical Society, Vol. 124, Issue 3
DOI: 10.1021/ja012004p

Interaction of C3H3+ isomers with molecular nitrogen: IR spectra of C3H3+–(N2)n clusters (n=1–6)
journal, July 2002

Dopfer, Otto; Roth, Doris; Maier, John P.
International Journal of Mass Spectrometry, Vol. 218, Issue 3
DOI: 10.1016/S1387-3806(02)00737-6

Detection of Vibrational Bending Mode ν₈ and Overtone Bands of the Propargyl Radical, HCCCH₂ X̃ ²B₁
journal, October 2010

Zhang, Xu; Sander, Stanley P.; Chaimowitz, Adam
The Journal of Physical Chemistry A, Vol. 114, Issue 45
DOI: 10.1021/jp105605f

Electronic and infrared spectra of H2C3H+ and cyclic C3H3+ in neon matrices
journal, June 2001

Wyss, Muriel; Riaplov, Evgueni; Maier, John P.
The Journal of Chemical Physics, Vol. 114, Issue 23
DOI: 10.1063/1.1367394

Photoionization of Propargyl and Bromopropargyl Radicals: A Threshold Photoelectron Spectroscopic Study
journal, March 2011

Hemberger, Patrick; Lang, Melanie; Noller, Bastian
The Journal of Physical Chemistry A, Vol. 115, Issue 11
DOI: 10.1021/jp112110j

Explicitly correlated coupled cluster calculations for the propargyl cation (H2C3H+) and related species
journal, January 2011

Botschwina, Peter; Oswald, Rainer; Rauhut, Guntram
Physical Chemistry Chemical Physics, Vol. 13, Issue 17
DOI: 10.1039/c1cp20206e

The VUV photochemistry of radicals: C ₃ H ₃ and C ₂ H ₅
journal, January 2005

Schüßler, T.; Roth, W.; Gerber, T.
Phys. Chem. Chem. Phys., Vol. 7, Issue 5
DOI: 10.1039/B414163F

Absolute photoionization cross-section of the propargyl radical
journal, April 2012

Savee, John D.; Soorkia, Satchin; Welz, Oliver
The Journal of Chemical Physics, Vol. 136, Issue 13
DOI: 10.1063/1.3698282

Propargyl Radical: Ab Initio Anharmonic Modes and the Polarized Infrared Absorption Spectra of Matrix-Isolated HCCCH ₂
journal, May 2005

Jochnowitz, Evan B.; Zhang, Xu; Nimlos, Mark R.
The Journal of Physical Chemistry A, Vol. 109, Issue 17
DOI: 10.1021/jp040719j

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Title: Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method

Citation Formats

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Applications of slow electron velocity map imaging to the study of spectroscopy and dynamics in small aromatic molecules journal, January 2008

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A photodissociation study of CH2BrCl in the A-band using the time-sliced ion velocity imaging method journal, January 2006

Accurate ab initio predictions of ionization energies of hydrocarbon radicals: CH2, CH3, C2H, C2H3, C2H5, C3H3, and C3H5 journal, June 2005

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Astronomical detection of H2CCCC journal, February 1991

Mechanisms for the formation of benzene in the atmosphere of Titan: FORMATION OF BENZENE IN TITAN'S ATMOSPHERE journal, February 2003

A vacuum-ultraviolet laser pulsed field ionization-photoelectron study of sulfur monoxide (SO) and its cation (SO+) journal, April 2011

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Kinetic and thermodynamic issues in the formation of aromatic compounds in flames of aliphatic fuels journal, October 1992

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Infrared Spectra of C3H3+-N2 Dimers: Identification of Proton-Bound c-C3H3+-N2 and H2CCCH+-N2 Isomers journal, December 2001

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Electronic and infrared spectra of H2C3H+ and cyclic C3H3+ in neon matrices journal, June 2001

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Explicitly correlated coupled cluster calculations for the propargyl cation (H2C3H+) and related species journal, January 2011

The VUV photochemistry of radicals: C 3 H 3 and C 2 H 5 journal, January 2005

Absolute photoionization cross-section of the propargyl radical journal, April 2012

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Direct identification of propargyl radical in combustion flames by vacuum ultraviolet photoionization mass spectrometry
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Determination of absolute photoionization cross sections for vinyl and propargyl radicals
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Vacuum ultraviolet laser pulsed field ionization-photoelectron study of allyl radical CH2CHCH2
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Highly Accurate Quartic Force Fields, Vibrational Frequencies, and Spectroscopic Constants for Cyclic and Linear C₃H₃⁺
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One-dimensional tomography: a comparison of Abel, onion-peeling, and filtered backprojection methods
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