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Title: Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T

Abstract

Nylon 13,T was successfully synthesized and chemical composition, thermal properties, crystal structure, and moisture absorption characterized. Melting temperature and glass transition temperature were determined to be 263 °C and 90 °C, respectively, while the equilibrium melting temperature was determined to be 289 °C. Characterization of the crystallization kinetics showed that nylon 13,T exhibits very fast crystallization compared to the industrially important nylons, nylon 6 and nylon 6,6. In addition, the moisture absorption of nylon 13,T was dramatically lower than nylon 6 and nylon 6,6 which is consistent with the much lower amide content of nylon 13,T. The crystal structure was determined to be pseudohexagonal.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. North Dakota State Univ., Fargo, ND (United States)
Publication Date:
Research Org.:
North Dakota State Univ., Fargo, ND (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1072208
Report Number(s):
DOE/GO/88160-50
Journal ID: ISSN 2049-1220
Grant/Contract Number:  
FG36-08GO88160
Resource Type:
Accepted Manuscript
Journal Name:
Green Materials
Additional Journal Information:
Journal Volume: 1; Journal Issue: 2; Journal ID: ISSN 2049-1220
Publisher:
ICE Publishing
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

He, Jie, Samanta, Satyabrata, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, and Chisholm, Bret J. Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T. United States: N. p., 2013. Web. doi:10.1680/gmat.12.00021.
He, Jie, Samanta, Satyabrata, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, & Chisholm, Bret J. Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T. United States. doi:10.1680/gmat.12.00021.
He, Jie, Samanta, Satyabrata, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, and Chisholm, Bret J. Sat . "Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T". United States. doi:10.1680/gmat.12.00021. https://www.osti.gov/servlets/purl/1072208.
@article{osti_1072208,
title = {Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T},
author = {He, Jie and Samanta, Satyabrata and Selvakumar, Sermadurai and Lattimer, Jessica and Ulven, Chad and Sibi, Mukund and Bahr, James and Chisholm, Bret J.},
abstractNote = {Nylon 13,T was successfully synthesized and chemical composition, thermal properties, crystal structure, and moisture absorption characterized. Melting temperature and glass transition temperature were determined to be 263 °C and 90 °C, respectively, while the equilibrium melting temperature was determined to be 289 °C. Characterization of the crystallization kinetics showed that nylon 13,T exhibits very fast crystallization compared to the industrially important nylons, nylon 6 and nylon 6,6. In addition, the moisture absorption of nylon 13,T was dramatically lower than nylon 6 and nylon 6,6 which is consistent with the much lower amide content of nylon 13,T. The crystal structure was determined to be pseudohexagonal.},
doi = {10.1680/gmat.12.00021},
journal = {Green Materials},
number = 2,
volume = 1,
place = {United States},
year = {2013},
month = {6}
}

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Cited by: 3 works
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