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Title: ESM of ionic and electrochemical phenomena on the nanoscale

Abstract

Operation of energy storage and conversion devices is ultimately controlled by series of intertwined ionic and electronic transport processes and electrochemical reactions at surfaces and interfaces, strongly mediated by strain and mechanical processes. In a typical fuel cell, these include chemical species transport in porous cathode and anode materials, gas-solid electrochemical reactions at grains and triple-phase boundaries (TPBs), ionic and electronic flows in multicomponent electrodes, and chemical and electronic potential drops at internal interfaces in electrodes and electrolytes. Furthermore, all these phenomena are sensitively affected by the microstructure of materials from device level to the atomic scales. Similar spectrum of length scales and phenomena underpin operation of other energy systems including primary and secondary batteries, as well as hybrid systems such flow and metal-air/water batteries.

Authors:
 [1];  [2];  [2];  [2];  [2];  [2];  [2]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Org.:
The Center for Nanophase Materials Sciences (ORNL)
OSTI Identifier:
1065868
Grant/Contract Number:  
ERKCC61
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials and Processes
Additional Journal Information:
Journal Volume: 169; Journal Issue: 11; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; Journal ID: ISSN 0882-7958
Publisher:
ASM International
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (heterogeneous); solar (fuels); energy storage (including batteries and capacitors); hydrogen and fuel cells; electrodes - solar; mechanical behavior; charge transport; materials and chemistry by design; synthesis (novel materials)

Citation Formats

Kalinin, Sergei V., Kumar, Amit, Balke, Nina, McCorkle, Morgan, Guo, Senli, Arruda, Thomas, and Jesse, Stephen. ESM of ionic and electrochemical phenomena on the nanoscale. United States: N. p., 2011. Web.
Kalinin, Sergei V., Kumar, Amit, Balke, Nina, McCorkle, Morgan, Guo, Senli, Arruda, Thomas, & Jesse, Stephen. ESM of ionic and electrochemical phenomena on the nanoscale. United States.
Kalinin, Sergei V., Kumar, Amit, Balke, Nina, McCorkle, Morgan, Guo, Senli, Arruda, Thomas, and Jesse, Stephen. Sat . "ESM of ionic and electrochemical phenomena on the nanoscale". United States. https://www.osti.gov/servlets/purl/1065868.
@article{osti_1065868,
title = {ESM of ionic and electrochemical phenomena on the nanoscale},
author = {Kalinin, Sergei V. and Kumar, Amit and Balke, Nina and McCorkle, Morgan and Guo, Senli and Arruda, Thomas and Jesse, Stephen},
abstractNote = {Operation of energy storage and conversion devices is ultimately controlled by series of intertwined ionic and electronic transport processes and electrochemical reactions at surfaces and interfaces, strongly mediated by strain and mechanical processes. In a typical fuel cell, these include chemical species transport in porous cathode and anode materials, gas-solid electrochemical reactions at grains and triple-phase boundaries (TPBs), ionic and electronic flows in multicomponent electrodes, and chemical and electronic potential drops at internal interfaces in electrodes and electrolytes. Furthermore, all these phenomena are sensitively affected by the microstructure of materials from device level to the atomic scales. Similar spectrum of length scales and phenomena underpin operation of other energy systems including primary and secondary batteries, as well as hybrid systems such flow and metal-air/water batteries.},
doi = {},
journal = {Advanced Materials and Processes},
number = 11,
volume = 169,
place = {United States},
year = {2011},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
The DOI is not currently available

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