Polyamides based on the renewable monomer, 1,13-tridecane diamine II: Synthesis and characterization of nylon 13,6
Abstract
The nylon 13,6 was successfully synthesized and its chemical composition, thermal properties, crystal structure, and moisture absorption characterized. Melting temperature and glass transition temperature were determined to be 206 °C and 60 °C, respectively, while the equilibrium melting temperature was determined to be 248 °C. Characterization of the crystallization kinetics showed that nylon 13,6 exhibits very fast crystallization compared to the industrially important nylons, nylon 6 and nylon 6,6. Additionally, the moisture absorption of nylon 13,6 was dramatically lower than nylon 6 and nylon 6,6 which is consistent with the much lower amide content of nylon 13,6. The crystal structure was determined to be different from the expected γ-form, which possess a pseudohexagonal unit cell. Instead, the x-ray scattering pattern was more similar to the α-form. Furthermore, a similar result has been obtained for other odd–even nylons including nylon 5,6, nylon 5,10, nylon 9,2, nylon 11,10, and nylon 11,12.
- Authors:
-
- North Dakota State Univ., Fargo, ND (United States)
- Publication Date:
- Research Org.:
- North Dakota State Univ., Fargo, ND (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1059697
- Report Number(s):
- DOE/GO/88160-49
Journal ID: ISSN 0032-3861
- Grant/Contract Number:
- FG36-08GO88160
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polymer
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 3; Journal ID: ISSN 0032-3861
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; nylon; polyamide; semicrystalline
Citation Formats
Samanta, Satyabrata, He, Jie, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, and Chisholm, Bret J. Polyamides based on the renewable monomer, 1,13-tridecane diamine II: Synthesis and characterization of nylon 13,6. United States: N. p., 2012.
Web. doi:10.1016/j.polymer.2012.12.034.
Samanta, Satyabrata, He, Jie, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, & Chisholm, Bret J. Polyamides based on the renewable monomer, 1,13-tridecane diamine II: Synthesis and characterization of nylon 13,6. United States. https://doi.org/10.1016/j.polymer.2012.12.034
Samanta, Satyabrata, He, Jie, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, and Chisholm, Bret J. Wed .
"Polyamides based on the renewable monomer, 1,13-tridecane diamine II: Synthesis and characterization of nylon 13,6". United States. https://doi.org/10.1016/j.polymer.2012.12.034. https://www.osti.gov/servlets/purl/1059697.
@article{osti_1059697,
title = {Polyamides based on the renewable monomer, 1,13-tridecane diamine II: Synthesis and characterization of nylon 13,6},
author = {Samanta, Satyabrata and He, Jie and Selvakumar, Sermadurai and Lattimer, Jessica and Ulven, Chad and Sibi, Mukund and Bahr, James and Chisholm, Bret J.},
abstractNote = {The nylon 13,6 was successfully synthesized and its chemical composition, thermal properties, crystal structure, and moisture absorption characterized. Melting temperature and glass transition temperature were determined to be 206 °C and 60 °C, respectively, while the equilibrium melting temperature was determined to be 248 °C. Characterization of the crystallization kinetics showed that nylon 13,6 exhibits very fast crystallization compared to the industrially important nylons, nylon 6 and nylon 6,6. Additionally, the moisture absorption of nylon 13,6 was dramatically lower than nylon 6 and nylon 6,6 which is consistent with the much lower amide content of nylon 13,6. The crystal structure was determined to be different from the expected γ-form, which possess a pseudohexagonal unit cell. Instead, the x-ray scattering pattern was more similar to the α-form. Furthermore, a similar result has been obtained for other odd–even nylons including nylon 5,6, nylon 5,10, nylon 9,2, nylon 11,10, and nylon 11,12.},
doi = {10.1016/j.polymer.2012.12.034},
journal = {Polymer},
number = 3,
volume = 54,
place = {United States},
year = {Wed Dec 19 00:00:00 EST 2012},
month = {Wed Dec 19 00:00:00 EST 2012}
}
Web of Science
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