National Library of Energy BETA

Sample records for watt lighting mercury

  1. Transport and accumulation of cesium-137 and mercury in the Clinch River and Watts Bar Reservoir system. Environmental Restoration Program

    SciTech Connect

    Olsen, C.R.; Larsen, I.L.; Lowry, P.D.; Moriones, C.R.; Ford, C.J.; Dearstone, K.C.; Turner, R.R.; Kimmel, B.L.; Brandt, C.C.

    1992-06-01

    Operations and waste disposal activities at the Oak Ridge Y-12 Plant, the Oak Ridge National Laboratory (ORNL), and the Oak Ridge K-25 Site (formerly the Oak Ridge Gaseous Diffusion Plant) on the US Department of Energy (DOE) Oak Ridge Reservation (ORR) have introduced a variety of airborne, liquid, and solid wastes into the surrounding environment. Some of these wastes may affect off-site areas by entering local streams, which ultimately drain into the Clinch and Tennessee river system. Previously reported concentrations of radionuclides, metals and organic compounds in water, sediment, and biota of the Clinch River and Watts Bar Reservoir suggest the presence of a variety of contaminants of possible concern to the protection of human health and the environment. The work reported here represents part of the initial scoping phase for the Clinch River RCRA Facility Investigation. In this work, the distribution of {sup 137}Cs is used to identify contaminant accumulation patterns and potential problem, or ``hot-spot,`` areas with regard to environmental hazard or human health. Radiocesium was chosen for this scoping effort because (1) its history of release into the Clinch River is reasonably well documented, (2) it is easy and inexpensive to measure by gamma spectrometry, and (3) it is rapidly sorbed to particulate matter and thus serves as a cost-effective tracer for identifying the transport and accumulation patterns of many other particle-reactive contaminants, such as mercury (Hg), lead (Pb), and plutonium (Pu), and polychlorinated biphenyls (PCBs).

  2. Transport and accumulation of cesium-137 and mercury in the Clinch River and Watts Bar Reservoir system

    SciTech Connect

    Olsen, C.R.; Larsen, I.L.; Lowry, P.D.; Moriones, C.R.; Ford, C.J.; Dearstone, K.C.; Turner, R.R.; Kimmel, B.L.; Brandt, C.C.

    1992-06-01

    Operations and waste disposal activities at the Oak Ridge Y-12 Plant, the Oak Ridge National Laboratory (ORNL), and the Oak Ridge K-25 Site (formerly the Oak Ridge Gaseous Diffusion Plant) on the US Department of Energy (DOE) Oak Ridge Reservation (ORR) have introduced a variety of airborne, liquid, and solid wastes into the surrounding environment. Some of these wastes may affect off-site areas by entering local streams, which ultimately drain into the Clinch and Tennessee river system. Previously reported concentrations of radionuclides, metals and organic compounds in water, sediment, and biota of the Clinch River and Watts Bar Reservoir suggest the presence of a variety of contaminants of possible concern to the protection of human health and the environment. The work reported here represents part of the initial scoping phase for the Clinch River RCRA Facility Investigation. In this work, the distribution of {sup 137}Cs is used to identify contaminant accumulation patterns and potential problem, or hot-spot,'' areas with regard to environmental hazard or human health. Radiocesium was chosen for this scoping effort because (1) its history of release into the Clinch River is reasonably well documented, (2) it is easy and inexpensive to measure by gamma spectrometry, and (3) it is rapidly sorbed to particulate matter and thus serves as a cost-effective tracer for identifying the transport and accumulation patterns of many other particle-reactive contaminants, such as mercury (Hg), lead (Pb), and plutonium (Pu), and polychlorinated biphenyls (PCBs).

  3. The Watt Stopper Inc | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Watt Stopper Inc Jump to: navigation, search Name: The Watt Stopper Inc Place: Santa Clara, Colorado Zip: 95050 Product: Wattstoper produces stand-alone and networked lighting...

  4. Goodbye, Watts. Hello, Lumens. (High-Resolution EPS Billboard) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy EPS Billboard) Goodbye, Watts. Hello, Lumens. (High-Resolution EPS Billboard) High-resolution EPS of billboard reading, 'Goodbye Watts. Hello Lumens. The new way to shop for light. Energysaver.gov DoE_Billboard_Goodbye_Watts.EPS (17.27 MB) More Documents & Publications Goodbye, Watts. Hello, Lumens. (High-Resolution JPG

  5. Goodbye, Watts. Hello, Lumens. (High-Resolution JPG Billboard) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy JPG Billboard) Goodbye, Watts. Hello, Lumens. (High-Resolution JPG Billboard) High-resolution JPG of billboard reading, 'Goodbye Watts. Hello Lumens. The new way to shop for light. Energysaver.gov DoE_Billboard_Goodbye_Watts.jpg (2.4 MB) More Documents & Publications Goodbye, Watts. Hello, Lumens. (High-Resolution EPS

  6. Do it yourself lighting power survey: lighting power audit for use with the Massachusetts type watts per square foot method of calculating a building's lighting power budget

    SciTech Connect

    Not Available

    1980-06-01

    Advantages of the self-audit approach to energy conservation are presented. These are that it is cheaper to do it yourself; the employees become part of the corporate conservation effect; and no one knows the building and its needs better than the occupant. Steps described in the lighting survey procedure are: (1) divide the building into categories; (2) determine the total square footage for each category; (3) assign a power allowance for each category; (4) multiply the total square footage for each category by the respective power allowances; (5) add the budget sub-totals for each category to determine total building budget; and (6) walk through the building room-by-room and calculate the connected lighting load fixture-by-fixture. Some worksheets are provided. (MCW)

  7. Goodbye, Watts. Hello, Lumens. (Low-Resolution Billboard) | Department...

    Energy Saver

    Hello Lumens. The new way to shop for light. Energysaver.gov DoEBillboardGoodbyeWattsweb.jpg (245.76 KB) More Documents & Publications Goodbye, Watts. Hello, Lumens. ...

  8. Simulation of Watts Bar Unit 1 Initial Startup Tests with Continuous...

    Office of Scientific and Technical Information (OSTI)

    Title: Simulation of Watts Bar Unit 1 Initial Startup Tests with Continuous Energy Monte Carlo Methods The Consortium for Advanced Simulation of Light Water Reactors* is developing ...

  9. PlotWatt | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Tool Summary LAUNCH TOOL Name: PlotWatt AgencyCompany Organization: PlotWatt Sector: Energy Focus Area: Energy Efficiency Resource Type: Softwaremodeling tools User Interface:...

  10. Tennessee Nuclear Profile - Watts Bar Nuclear Plant

    Energy Information Administration (EIA) (indexed site)

    Watts Bar Nuclear Plant" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date" 1,"1,123","9,738",99.0,"PWR","application/vnd.ms-excel","application/vnd.ms-excel" ,"1,123","9,738",99.0 "Data for 2010" "PWR = Pressurized Light Water

  11. NoWatt | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    NoWatt Jump to: navigation, search Name: NoWatt Place: Manchester, England, United Kingdom Zip: M20 6UG Product: Manchester, UK-based provider of energy management solutions and...

  12. AlphaWatt Ltd | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AlphaWatt Ltd Jump to: navigation, search Name: AlphaWatt Ltd Place: London, United Kingdom Zip: EC1V 4PY Sector: Solar Product: Solar project developer, plans to become an...

  13. SpectraWatt | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    SpectraWatt Place: Hillsboro, Oregon Product: Spun off from Intel to manufacture PV cells. References: SpectraWatt1 This article is a stub. You can help OpenEI by expanding...

  14. WattQuiz | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    www.wattquiz.com Country: United States Web Application Link: www.wattquiz.com Cost: Free Northern America Language: English WattQuiz Screenshot References: Genability1 NYC...

  15. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest...

    Office of Environmental Management (EM)

    Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Case study ...

  16. MegaWatt Solar | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    energy company that delivers scalable solar power generation systems to the utility market. References: MegaWatt Solar1 This article is a stub. You can help OpenEI by...

  17. GlobalWatt Inc | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: GlobalWatt Inc Place: Dover, Delaware Zip: 19801 Product: Shell company, once planned to float on AIM to raise money in order to acquire the business of...

  18. The NPL moving-coil watt balance

    SciTech Connect

    Robinson, I.A.; Kibble, B.P.; Belliss, J.H.

    1994-12-31

    We describe Progress since the 1992 CPEM towards linking the electrical to the mechanical watt with less than 1 in 10{sup 8} uncertainty to measure Planck`s constant and monitor the stability of the kilogram.

  19. Watt Does It Cost To Use It?

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Watt Does It Cost to Use It? Grades: 5-8, 9-12 Topic: Energy Efficiency and Conservation Author: Mark Ziesmer Owner: Alliance to Save Energy This educational material is brought to you by the U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy. WATT DOES IT COST TO USE IT? By Mark Ziesmer, Sultana High School Hesperia Unified School District, California Overview: Familiarize students with how electrical usage is counted, electrical pricing, and measure and evaluate

  20. Localized surface plasmon resonance mercury detection system and methods

    DOEpatents

    James, Jay; Lucas, Donald; Crosby, Jeffrey Scott; Koshland, Catherine P.

    2016-03-22

    A mercury detection system that includes a flow cell having a mercury sensor, a light source and a light detector is provided. The mercury sensor includes a transparent substrate and a submonolayer of mercury absorbing nanoparticles, e.g., gold nanoparticles, on a surface of the substrate. Methods of determining whether mercury is present in a sample using the mercury sensors are also provided. The subject mercury detection systems and methods find use in a variety of different applications, including mercury detecting applications.

  1. Lighting Principles and Terms | Department of Energy

    Office of Environmental Management (EM)

    by lumens, not watts. To choose the best energy-efficient lighting options for your home, you should understand basic lighting principles and terms. Light Quantity...

  2. Development of a 100-Watt High Temperature Thermoelectric Generator

    Energy.gov [DOE]

    Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication.

  3. Watts Bar Operating Cycles Simulated to Present

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Coming in our next issue of Tech Notes: Fuel Performance Predictions with VERA Watts Bar Operating Cycles Simulated to Present Among the most important accomplishments during CASL Phase 1 is the development and deployment of CASL's Virtual Environment for Reactor Applications (VERA), a high-fidelity, multi-physics engineering tool that utilizes modest high- performance computing (HPC) systems and engineering-scale clusters to simultaneously simulate the local fuel rod neutronics and coolant

  4. Specification for strontium-90 500-watt(e) radioisotopic thermoelectric generator. Final report

    SciTech Connect

    Hammel, T.; Himes, J.; Lieberman, A.; McGrew, J.; Owings, D.; Schumann, F.

    1983-04-01

    A conceptual design for a demonstration 500-watt(e) radioisotopic thermoelectric generator has been created for the Department of Energy. The design effort was divided into two tasks, viz., create a design specification for a capsule strength member that utilizes a standard Strontium-90 fluoride-filled WESF inner liner, and create a conceptual design for a 500-watt(e) RTG. Both tasks have been accomplished. The strength-member specification was designed to survive an external pressure of 24,500 psi and meet the requirements of special-form radioisotope heat sources. Therefore the capsule can, if desired, be licensed for domestic and international transport. The design for the RTG features a radioisotopic heat source, an array of nine capsules in a tungsten biological shield, four current-technology series-connected thermoelectric-conversion modules, low-conductivity thermal insulation, and a passive finned-housing radiator for waste-heat dissipation. The preliminary RTG specification formulated previous to contract award has been met or exceeded. The power source will generate the required power for the required service period at 28 volts dc with a conversion efficiency of 8%, provided the existing in-pool capsules at WESF meet the assumed thermal-inventory requirements.

  5. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    National Lab | Department of Energy Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Case study describes Pacific Northwest National Laboratory's (PNNL) three-month Rock the Watt campaign to reduce energy use at its main campus in Richland, Washington. The campaign objectives were to educate PNNL employees about energy conservation opportunities in their workplace and to motivate

  6. Development of a 500 Watt High Temperature Thermoelectric Generator...

    Energy.gov [DOE] (indexed site)

    More Documents & Publications Development of a 100-Watt High Temperature Thermoelectric Generator Automotive Waste Heat Conversion to Power Program Automotive Waste Heat Conversion ...

  7. Development of a 500 Watt High Temperature Thermoelectric Generator

    Office of Energy Efficiency and Renewable Energy (EERE)

    A low temperature TEG has been built and tested providing over 500 watts electric power at a ∆T of 2000C

  8. Methyl mercury toxicity in plant cultures: modification of resistance and demethylation by light and/or 2,4-dichlorophenoxyacetic acid

    SciTech Connect

    Czuba, M.

    1987-04-01

    Cultures of Daucus carota, Ca-68-10, and Lactuca sativa, Le-67, were grown at increasing methyl mercury (MeHg) concentrations ranging from initial doses of 0.05 to 5.0 micrograms/ml per day for 4 days with or without 0.15 microgram/ml 2,4-dichlorophenoxyacetic acid (2,4-D) in the presence or absence of light. The presence of 2,4-D interacted with light synergistically in the expression of MeHg toxicity within the whole range of concentrations. Demethylation patterns increased or decreased depending on the species, the 2,4-D concentration in the medium, and methyl mercury concentration used in the treatment. Lettuce was more sensitive to this interaction than carrot. In lettuce, the presence of 2,4-D in the light lowered the concentration of total Hg (or MeHg) required to reduce growth by 50%, about 13 times relative to that in the dark (i.e., it sensitized the cells). In the absence of 2,4-D the pattern was reversed. In carrot the pattern was similar but less pronounced. This suggests that, in these cell populations, MeHg toxicity is partly a hormone-mediated and light-sensitive event.

  9. Reading Municipal Light Department- Residential Renewable Energy Rebates

    Energy.gov [DOE]

    Reading Municipal Light Department (RMLD) offers rebates of $1.00/watt for solar photovoltaic and small wind installations for residential customers. A $0.25/watt adder is available for using local...

  10. Sulphur Springs Valley EC - SunWatts Rebate Program | Department...

    Energy.gov [DOE] (indexed site)

    The SunWatts Program offers home and business owners incentives for purchasing photovoltaic (PV), wind and solar water heating systems. Systems must be grid-connected to be...

  11. Trico Electric Cooperative- SunWatts Incentive Program

    Energy.gov [DOE]

    Through the SunWatts Program, Trico Electric Cooperative offers residential and business customers a rebate for installing solar water heaters. Rebates equal $0.40 per expected first year of...

  12. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    light by passing electricity through mercury vapor, which causes the fluorescent coating to glow or fluoresce. High-Efficiency Ballast (HEB): A lighting conservation feature...

  13. Luminous Efficacy Standards for General Purpose Lights

    Energy.gov [DOE]

    *Efficacy refers to the overall energy efficiency of light and is measured in lumens (measure of light output) per watt (measure of power input). The efficacy of a typical incandescent light bulb...

  14. Tennessee Nuclear Profile - Watts Bar Nuclear Plant

    Energy Information Administration (EIA) (indexed site)

    expiration date" 1,"1,123","9,738",99.0,"PWR","applicationvnd.ms-excel","applicationvnd.ms-excel" ,"1,123","9,738",99.0 "Data for 2010" "PWR Pressurized Light Water Reactor."

  15. Goodbye, Watts. Hello, LUMENS! | Department of Energy

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Now that stores today carry more and more energy efficient lighting choices, I wanted to replace my old incandescents with new bulbs to save energy and money on my electricity ...

  16. Lead test assembly irradiation and analysis Watts Bar Nuclear Plant, Tennessee and Hanford Site, Richland, Washington

    SciTech Connect

    1997-07-01

    The U.S. Department of Energy (DOE) needs to confirm the viability of using a commercial light water reactor (CLWR) as a potential source for maintaining the nation`s supply of tritium. The Proposed Action discussed in this environmental assessment is a limited scale confirmatory test that would provide DOE with information needed to assess that option. This document contains the environmental assessment results for the Lead test assembly irradiation and analysis for the Watts Bar Nuclear Plant, Tennessee, and the Hanford Site in Richland, Washington.

  17. How Energy-Efficient Light Bulbs Compare with Traditional Incandescent...

    Energy Saver

    Light Bulbs Compare with Traditional ... The table below compares a 60 watt (W) traditional ... *Based on 2 hrsday of usage, an electricity rate of 11 ...

  18. VP 100: Retooling Michigan -- Yachts and Watts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Retooling Michigan -- Yachts and Watts VP 100: Retooling Michigan -- Yachts and Watts June 18, 2010 - 4:13pm Addthis Energetx Composites was able to purchase equipment such as this mold for utility-scale wind turbine blades thanks to a Recovery Act grant that matched the company’s $3.5 million investment. | Photo Courtesy of Energetx | Energetx Composites was able to purchase equipment such as this mold for utility-scale wind turbine blades thanks to a Recovery Act grant that matched the

  19. Lower Watts Bar Reservoir Clinch River/Poplar Creek | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Watts Bar Reservoir Clinch River/Poplar Creek Lower Watts Bar Reservoir Clinch River/Poplar Creek This document discusses the Lower Watts Bar Reservoir Clinch River/Poplar Creek. Topics include: * The area's safety * Any use limitations for the area * History and cleanup background for this area * How DOE's cleanup program addressed the problem Lower Watts Bar Reservoir Clinch River/Poplar Creek (982.57 KB) More Documents & Publications EA-1175: Final Environmental Assessment OREM

  20. High Temperature Compatibility of 60-Watt IHS Materials

    SciTech Connect

    Worley, C. M.; Merten, C. W.

    1995-11-21

    The 60-Watt Isotopic Heat Source (IHS) utilizes a variety of materials which have been selected for their properties at elevated temperatures. These include iridium, molybdenum, and the T-111 alloy which consists of 90 wt% tantalum, 8 wt% tungsten, and 2 wt% hafnium. Properties of interest in radioisotopic heat source applications include high temperature strength, resistance to oxidation, weldability, and ability to act as a diffusion barrier. Iridium is utilized as a clad for fuel pellets because of its high temperature mechanical properties and good compatibility with carbon and plutonium oxide. Molybdenum retains good high temperature strength and has been used as a diffusion barrier in past applications. However, molybdenum also exhibits poor resistance to oxidation. Therefore, it is necessary to enclose molybdenum components so that they are not exposed to the atmosphere. T-111 exhibits moderate oxidation resistance, good high temperature mechanical properties, and good weldability. For these reasons, it is used as the outer containment boundary for the 60-Watt IHS. Because the temperature in GPHS fueled dads is on the order of 1000 degrees Celsius in the 60-W configuration, the potential for diffusion of dissimilar materials from one into another exists. Deleterious effects of diffusion can include degradation of mechanical strength through the formation of brittle intermetallics, degradation of mechanical properties through simple alloying, or formation of voids through the Kirkendall effect. Because of the possibility of these effects, design methodology calls for use of diffusion barriers between materials likely to exhibit interdiffusion at elevated temperatures. The necessity to assure the long term integrity of the 60-Watt IHS dictates that the diffusion behavior of its component materials be known. This report describes the high temperature compatibility studies which were conducted on the component materials of the 60-Watt IHS.

  1. White LED Benchmark of 65 Lumens Per Watt Achieved

    Energy.gov [DOE]

    Novel chip design and the balance of multiple interrelated design parameters have enabled Cree, Inc.'s Santa Barbara Technology Center to demonstrate white LEDs with efficacies greater than 65 lumens per watt at 350 mA. The results are particularly significant because they were achieved with a pre-production prototype chip using the same package used in Cree's commercially available XLamp® 7090 high power LED, rather than a laboratory device.

  2. Apparatus for isotopic alteration of mercury vapor

    DOEpatents

    Grossman, Mark W.; George, William A.; Marcucci, Rudolph V.

    1988-01-01

    An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

  3. Mercury: A Diode-Pumped Solid-State Laser

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Advanced Optical Technologies Fiber Lasers Laser-Compton Light Source Technology ... Mercury: A Diode-Pumped Solid-State Laser Concurrent with the development of the National ...

  4. High-bay Lighting Energy Conservation Measures

    Energy Science and Technology Software Center

    2010-12-31

    This software requires inputs of simple high-bay lighting system inventory information and calculates the energy and cost benefits of various retrofit opportunities. This tool includes energy conservation measures for: 1000 Watt to 750 Watt High-pressure Sodium lighting retrofit, 400 Watt to 360 Watt High Pressure Sodium lighting retrofit, High Intensity Discharge to T5 lighting retrofit, High Intensity Discharge to T8 lighting retrofit, and Daylighting. This tool calculates energy savings, demand reduction, cost savings, building lifemore » cycle costs including: simple payback, discounted payback, net-present value, and savings to investment ratio. In addition this tool also displays the environmental benefits of a project.« less

  5. PROJECT PROFILE: WattGlass, LLC (T2M2)

    Office of Energy Efficiency and Renewable Energy (EERE)

    This project is further developing an antireflective coating for the top glass of solar modules. The coating has a refractive index closer to that of glass, leading to higher transmission and higher module power. This project allows WattGlass to test the coating on panels from a number of manufacturers in order to gauge wattage improvements achieved over competing coatings. Modules with the coating will be tested in various regions to evaluate increases in panel performance due to the antireflective coating and reductions in soiling rate due to the superhydrophilic nature of the coating.

  6. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Rock the Watt was a direct applica- tion of the Framework for Organiza- tional Change that included building sustainability champions, integration of a sustainability checklist, and sup- port for employees to come up with their own energy saving actions. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Pacifc Northwest National Laboratory (PNNL), one of the seventeen Department of Energy laboratories, implemented the 3-month Rock the Watt campaign in FY2015 to

  7. Chicopee Electric Light- Residential Solar Rebate Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    Chicopee Electric Light offers rebates to residential customers who install solar photovoltaic (PV) systems on their homes. Customer rebates are $0.50 per watt for a maximum of $2,500 per...

  8. 1999 Commercial Buildings Characteristics--Glossary--Lighting...

    Energy Information Administration (EIA) (indexed site)

    produces light by passing electricity through mercury vapor, causing the fluorescent coating to glow, or fluoresce. Excluded are compact fluorescent light bulbs, which are listed...

  9. ORNL Trusted Corridors Project: Watts Bar Dam Inland Waterway Project

    SciTech Connect

    Walker, Randy M; Gross, Ian G; Smith, Cyrus M; Hill, David E

    2011-11-01

    Radiation has existed everywhere in the environment since the Earth's formation - in rocks, soil, water, and plants. The mining and processing of naturally occurring radioactive materials for use in medicine, power generation, consumer products, and industry inevitably generate emissions and waste. Radiological measuring devices have been used by industry for years to measure for radiation in undesired locations or simply identify radioactive materials. Since the terrorist attacks on the United States on 9-11-01 these radiation measuring devices have proliferated in many places in our nation's commerce system. DOE, TVA, the Army Corps and ORNL collaborated to test the usefulness of these devices in our nation's waterway system on this project. The purpose of the Watts Bar Dam ORNL Trusted Corridors project was to investigate the security, safety and enforcement needs of local, state and federal government entities for state-of-the-art sensor monitoring in regards to illegal cargo including utilization of the existing infrastructure. TVA's inland waterways lock system is a recognized and accepted infrastructure by the commercial carrier industry. Safety Monitoring activities included tow boat operators, commercial barges and vessels, recreational watercraft and their cargo, identification of unsafe vessels and carriers, and, monitoring of domestic and foreign commercial vessels and cargo identification. Safety Enforcement activities included cargo safety, tracking, identification of hazardous materials, waterway safety regulations, and hazardous materials regulations. Homeland Security and Law Enforcement Applications included Radiological Dispersive Devices (RDD) identification, identification of unsafe or illicit transport of hazardous materials including chemicals and radiological materials, and screening for shipments of illicit drugs. In the Fall of 2005 the SensorNet funding for the project expired. After several unsuccessful attempts to find a Federal sponsor

  10. Further testing and development of an 11-watt Stirling converter

    SciTech Connect

    Ross, B.A.; Montgomery, W.L.

    1995-12-31

    Three previous IECEC papers describe the development of an 11-watt Radioisotope Stirling Generator (RSG) intended for remote power applications. This paper describes more recent testing and development activities. Testing of the engineering model (EM) was performed to determine the effect of heat rejection temperature, thermal input and initial charge pressure on thermal efficiency. Shock testing of the generator included a drop test and 3 hours of testing in a random vibration environment where g{sup 2}/Hz = 0.04. Endurance testing of a complete Stirling converter continues, with over 15,000 maintenance-free operating hours. Endurance testing of critical subsystems and components has achieved 14,000 to 26,000 hours of operation without failure. Minor changes to the RSG prototype design, based on the development of the EM, are described.

  11. Common Industrial Lighting Upgrade Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    The current causes mercury atoms to ionize generating ultraviolet photons otherwise known as ultraviolet light invisible to the human eye. These photons react with a phosphor ...

  12. Small stirling dynamic isotope power systems for multihundred-watt robotic missions

    SciTech Connect

    Bents, D.J.

    1991-01-01

    Free piston Stirling Engine (FPSE) and linear alternator (LA) technology is combined with radioisotope heat sources to produce a compact dynamic isotope power system (DIPS) suitable for multihundred watt space application which appears competitive with advanced radioisotope thermoelectric generators (RTGs). The small Stirling DIPS is scalable to multihundred watt power levels or lower. The FPSE/LA is a high efficiency convertor in sizes ranging from tens of kilowatts down to only a few watts. At multihundred watt unit size, the FPSE can be directly integrated with the General Purpose Heat Source (GPHS) via radiative coupling; the resulting dynamic isotope power system has a size and weight that compares favorably with the advanced modular (Mod) RTG, but requires less than a third the amount of isotope fuel. Thus the FPSE extends the high efficiency advantage of dynamic systems into a power range never previously considered competitive for DIPS. This results in lower fuel cost and reduced radiological hazard per delivered electrical watt.

  13. Request for One-Time Shipment of 32 Watt PU-328 Source in 9968 Packaging

    SciTech Connect

    Massey, W.M.

    1998-11-25

    The 9968 package is designed for surface shipment of fissile and other radioactive materials where a high degree of double containment is required. The use of the 9968 radioactive material package for a one time shipment of a 32 watt heat source versus the SARP approved maximum 30 watt heat source is addressed in this report. The analyses show that the small increase in heat load from 30 watts to 32 watts does not substantially increase internal temperatures or pressures that would approach limits for the package. Also, the weight of the content is within the current 9968 package limits. It is concluded that the 32-watt heat source can be safely shipped in the 9968 package and therefore a waiver to ship the source is justified.

  14. Mercury contamination extraction

    DOEpatents

    Fuhrmann, Mark; Heiser, John; Kalb, Paul

    2009-09-15

    Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

  15. Simulation of Watts Bar Unit 1 Initial Startup Tests with Continuous Energy Monte Carlo Methods

    SciTech Connect

    Godfrey, Andrew T; Gehin, Jess C; Bekar, Kursat B; Celik, Cihangir

    2014-01-01

    The Consortium for Advanced Simulation of Light Water Reactors* is developing a collection of methods and software products known as VERA, the Virtual Environment for Reactor Applications. One component of the testing and validation plan for VERA is comparison of neutronics results to a set of continuous energy Monte Carlo solutions for a range of pressurized water reactor geometries using the SCALE component KENO-VI developed by Oak Ridge National Laboratory. Recent improvements in data, methods, and parallelism have enabled KENO, previously utilized predominately as a criticality safety code, to demonstrate excellent capability and performance for reactor physics applications. The highly detailed and rigorous KENO solutions provide a reliable nu-meric reference for VERAneutronics and also demonstrate the most accurate predictions achievable by modeling and simulations tools for comparison to operating plant data. This paper demonstrates the performance of KENO-VI for the Watts Bar Unit 1 Cycle 1 zero power physics tests, including reactor criticality, control rod worths, and isothermal temperature coefficients.

  16. Watts Bar Unit 1 Cycle Zero Power Physics Tests Analysis with VERA-CS

    SciTech Connect

    Gehin, Jess C; Godfrey, Andrew T; Evans, Thomas M; Hamilton, Steven P; Francheschini, F.

    2014-01-01

    The Consortium for Advanced Simulation of Light Water Reactors (CASL) is developing a collection of methods and software products known as VERA, the Virtual Environment for Reactor Applications, including a core simulation capability called VERA-CS. A key milestone for this endeavor is to validate VERA against measurements from operating nuclear power reactors. The first step in validation against plant data is to determine the ability of VERA to accurately simulate the initial startup physics tests for Watts Bar Nuclear Power Station, Unit 1 (WBN1) cycle 1. VERA-CS calculations were performed with the Insilico code developed at ORNL using cross section processing from the SCALE system and the transport capabilities within the Denovo transport code using the SPN method. The calculations were performed with ENDF/B-VII.0 cross sections in 252 groups (collapsed to 23 groups for the 3D transport solution). The key results of the comparison of calculations with measurements include initial criticality, control rod worth critical configurations, control rod worth, differential boron worth, and isothermal temperature reactivity coefficient (ITC). The VERA results for these parameters show good agreement with measurements, with the exception of the ITC, which requires additional investigation. Results are also compared to those obtained with Monte Carlo methods and a current industry core simulator.

  17. Method for removal of mercury from various gas streams

    DOEpatents

    Granite, E.J.; Pennline, H.W.

    2003-06-10

    The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

  18. Third generation development of an 11-watt Stirling converter

    SciTech Connect

    Montgomery, W.L.; Ross, B.A.; Penswick, L.B.

    1996-12-31

    This paper describes recent design enhancements, performance results, and development of an artificial neural network (ANN) model related to the Radioisotope Stirling Generator (RSG), an 11-watt converter designed for remote power applications. Design enhancements include minor changes to improve performance, increase reliability, facilitate fabrication and assembly for limited production, and reduce mass. Innovative modifications were effected to increase performance and improve reliability of the vacuum foil insulation (VFI) package and linear alternator. High and low operating temperature acceptance testing of the Engineering Model (EM) demonstrated the robust system characteristics. These tests were conducted for 1 week of operation each, with rejector temperatures of 95 C and 20 C, respectively. Endurance testing continues for a complete Stirling converter, the Development Model (DM), with over 25,000 hours of maintenance-free operation. Endurance testing of flexures has attained over 540 flexure-years and endurance testing of linear motors/alternators has achieved nearly 27,000 hours of operation without failure. An ANN model was developed and tested successfully on the DM. Rejection temperatures were varied between 3 C and 75 C while load voltages ranged between engine stall and displacer overstroke. The trained ANN model, based solely on externally measured parameters, predicted values of piston amplitude, displacer amplitude, and piston-displacer phase angle within {+-}2% of the measured values over the entire operating regime. The ANN model demonstrated its effectiveness in the long-term evaluation of free-piston Stirling machines without adding the complexity, reduced reliability, and increased cost of sophisticated diagnostic instrumentation.

  19. Is the hourly data I get from NREL's PV Watts program adjusted...

    OpenEI (Open Energy Information) [EERE & EIA]

    Is the hourly data I get from NREL's PV Watts program adjusted for daylight savings time. Home I take the hourly AC output numbers and apply them to a program I built that assigns...

  20. Taunton Municipal Lighting Plant- Residential PV Rebate Program

    Energy.gov [DOE]

    Customers of Taunton Municipal Lighting Plant (TMLP) may be eligible for a $1.50/watt rebate on solar photovoltaic (PV) installations, up to a maximum rebate of $4,500. The system must be installed...

  1. Filter for isotopic alteration of mercury vapor

    DOEpatents

    Grossman, Mark W.; George, William A.

    1989-01-01

    A filter for enriching the .sup.196 Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The .sup.196 Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter.

  2. Filter for isotopic alteration of mercury vapor

    DOEpatents

    Grossman, M.W.; George, W.A.

    1989-06-13

    A filter is described for enriching the [sup 196]Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The [sup 196]Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is, less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter. 9 figs.

  3. Process for low mercury coal

    DOEpatents

    Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

    1995-04-04

    A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

  4. Process for low mercury coal

    DOEpatents

    Merriam, Norman W.; Grimes, R. William; Tweed, Robert E.

    1995-01-01

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  5. Frequently Asked Questions: Lighting Choices to Save You Money | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Frequently Asked Questions: Lighting Choices to Save You Money Frequently Asked Questions: Lighting Choices to Save You Money Frequently Asked Questions: Lighting Choices to Save You Money Below are some of the most frequently asked questions and answers about the new lighting efficiency standards. Learn more about your lighting choices and find out how to shop for lights by lumens, not watts. Why are my lighting choices changing? What is the Energy Independence and Security Act of

  6. Powering a Home with Just 25 Watts of Solar PV. Super-Efficient Appliances Can Enable Expanded Off-Grid Energy Service Using Small Solar Power Systems

    SciTech Connect

    Phadke, Amol A.; Jacobson, Arne; Park, Won Young; Lee, Ga Rick; Alstone, Peter; Khare, Amit

    2015-04-01

    Highly efficient direct current (DC) appliances have the potential to dramatically increase the affordability of off-grid solar power systems used for rural electrification in developing countries by reducing the size of the systems required. For example, the combined power requirement of a highly efficient color TV, four DC light emitting diode (LED) lamps, a mobile phone charger, and a radio is approximately 18 watts and can be supported by a small solar power system (at 27 watts peak, Wp). Price declines and efficiency advances in LED technology are already enabling rapidly increased use of small off-grid lighting systems in Africa and Asia. Similar progress is also possible for larger household-scale solar home systems that power appliances such as lights, TVs, fans, radios, and mobile phones. When super-efficient appliances are used, the total cost of solar home systems and their associated appliances can be reduced by as much as 50%. The results vary according to the appliances used with the system. These findings have critical relevance for efforts to provide modern energy services to the 1.2 billion people worldwide without access to the electrical grid and one billion more with unreliable access. However, policy and market support are needed to realize rapid adoption of super-efficient appliances.

  7. EM Mercury Challenge

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Technology Plan to Address the EM Mercury Challenge FEBRUARY 2016 Table of Contents SUMMARY 1 1. BACKGROUND 2 1.1 OAK RIDGE RESERVATION'S MERCURY CHALLENGE 2 1.2 SAVANNAH RIVER SITE'S MERCURY CHALLENGE 3 2. APPROACH 4 3. OREM'S 2014 TECHNOLOGY DEVELOPMENT PLAN 5 4. RESEARCH AND TECHNOLOGY DEVELOPMENT AREAS FOR OAK RIDGE 6 4.1 MERCURY DETECTION AND MEASUREMENT 6 4.2 Y-12 SITE CLEANUP 7 4.3 EAST FORK POPLAR CREEK REMEDIATION 9 4.4 MODELING 10 5. RESEARCH AND TECHNOLOGY DEVELOPMENT AREAS FOR THE

  8. Mercury in the environment

    ScienceCinema

    Idaho National Laboratory - Mike Abbott

    2016-07-12

    Abbott works for Idaho National Laboratory as an environmental scientist. Using state-of-thescienceequipment, he continuously samples the air, looking for mercury. In turn, he'll analyzethis long-term data and try to figure out the mercury's point of or

  9. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab

    SciTech Connect

    2016-01-01

    Case study describes Pacific Northwest National Laboratory's (PNNL) three-month Rock the Watt campaign to reduce energy use at its main campus in Richland, Washington. The campaign objectives were to educate PNNL employees about energy conservation opportunities in their workplace and to motivate them to help PNNL save energy and costs and to reduce greenhouse gas emissions.

  10. High lumen compact fluorescents boost light output in new fixtures

    SciTech Connect

    1992-12-31

    Some compact fluorescent lamps aren`t so compact. General Electric (GE), OSRAM, and Philips have been expanding offerings in longer, more powerful, hard wired CFLs that generate enough light to serve applications once limited to conventional fluorescents and metal halide systems. All three of these manufacturers have for some time offered 18- to 40-watt high-output CFLs, which use a fluorescent tube doubled back on itself to produce a lot of light in a compact source. Now GE has introduced an even larger, more powerful 50-watt unit, and OSRAM is soon to follow suit with a 55-watt lamp. These new entries to the field of turbocharged CFLs can provide general lighting at ceiling heights of 12 feet or more as well as indirect lighting, floodlighting, and wall washing. They are such a concentrated source of light that they can provide the desired illumination using fewer lamps and fixtures than would be needed with competing sources.

  11. CoServ Electric Cooperative- Commercial Energy Efficient Lighting Rebate Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    CoServ Electric Cooperative provides rebates for commercial and industrial customers who upgrade to high efficiency lighting for the workplace. A rebate of $0.20/watt saved is available on interior...

  12. Category:Mercury Vapor | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Mercury Vapor Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Mercury Vapor page? For detailed information on Mercury Vapor as...

  13. Mercury Metadata Toolset

    Energy Science and Technology Software Center

    2009-09-08

    Mercury is a federated metadata harvesting, search and retrieval tool based on both open source software and software developed at Oak Ridge National Laboratory. It was originally developed for NASA, and the Mercury development consortium now includes funding from NASA, USGS, and DOE. A major new version of Mercury (version 3.0) was developed during 2007 and released in early 2008. This Mercury 3.0 version provides orders of magnitude improvements in search speed, support for additionalmore » metadata formats, integration with Google Maps for spatial queries, facetted type search, support for RSS delivery of search results, and ready customization to meet the needs of the multiple projects which use Mercury. For the end users, Mercury provides a single portal to very quickly search for data and information contained in disparate data management systems. It collects metadata and key data from contributing project servers distributed around the world and builds a centralized index. The Mercury search interfaces then allow the users to perform simple, fielded, spatial, and temporal searches across these metadata sources. This centralized repository of metadata with distributed data sources provides extremely fast search results to the user, while allowing data providers to advertise the availability of their data and maintain complete control and ownership of that data.« less

  14. Recovery of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, Mark W.; George, William A.

    1988-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  15. Recovery of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, Mark W.; George, William A.

    1991-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  16. Recovery of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, Mark W.; George, William A.

    1989-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  17. Recovery of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, M.W.; George, W.A.

    1989-11-07

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figs.

  18. Recovery of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, M.W.; George, W.A.

    1991-06-18

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figures.

  19. EM Mercury Challenge

    Energy.gov [DOE] (indexed site)

    ... were discharged to the high level waste (HLW) tanks for storage and ultimate disposition. ... This mercury has been isolated within the LWS process vessels and HLW tanks, with minimal ...

  20. Method and apparatus for monitoring mercury emissions

    DOEpatents

    Durham, M.D.; Schlager, R.J.; Sappey, A.D.; Sagan, F.J.; Marmaro, R.W.; Wilson, K.G.

    1997-10-21

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber. 15 figs.

  1. Method and apparatus for monitoring mercury emissions

    DOEpatents

    Durham, Michael D.; Schlager, Richard J.; Sappey, Andrew D.; Sagan, Francis J.; Marmaro, Roger W.; Wilson, Kevin G.

    1997-01-01

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber.

  2. Recommendation and implementation of special seasonal flow releases to enhance sauger spawning in Watts Bar tailwater

    SciTech Connect

    Yeager, B.; Shiao, Ming.

    1992-05-01

    In recent years sauger populations in Chickamauga Reservoir, as well as several other areas in the Tennessee River Valley, have suffered drastic declines in numbers. Based on field creel evaluations the fisherman harvest of sauger in Chickamauga Reservoir has declined from an estimated high of 66,000 fish caught in 1979 to 0 fish in 1989. The Tennessee Wildlife Resources Agency began an aggressive effort in 1990 and 1991 to recover this population, as well as those of Ft. Loudon and Watts Bar Reservoirs, by stocking large numbers of fingerling sauger. This is however, only a short-term, stopgap measure. The decline in the population of Chickamauga Reservoir appears directly related to dramatically lower discharges from Watts Bar Dam during the recent drought. The primary factor affecting year-class strength (numbers of sauger successfully spawned in a year and reaching catchable size in subsequent years) is the amount of spawning habitat available in the month of April (the spawning season for sauger) at one particular site below Watts Bar Dam. This report documents studies aimed at optimizing sauger spawning in Chickamauga Reservoir.

  3. Application of atomic vapor laser isotope separation to the enrichment of mercury

    SciTech Connect

    Crane, J.K.; Erbert, G.V.; Paisner, J.A.; Chen, H.L.; Chiba, Z.; Beeler, R.G.; Combs, R.; Mostek, S.D.

    1986-09-01

    Workers at GTE/Sylvania have shown that the efficiency of fluorescent lighting may be markedly improved using mercury that has been enriched in the /sup 196/Hg isotope. A 5% improvement in the efficiency of fluorescent lighting in the United States could provide a savings of approx. 1 billion dollars in the corresponding reduction of electrical power consumption. We will discuss the results of recent work done at our laboratory to develop a process for enriching mercury. The discussion will center around the results of spectroscopic measurements of excited state lifetimes, photoionization cross sections and isotope shifts. In addition, we will discuss the mercury separator and supporting laser mesurements of the flow properties of mercury vapor. We will describe the laser system which will provide the photoionization and finally discuss the economic details of producing enriched mercury at a cost that would be attractive to the lighting industry.

  4. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect

    Pekney, Natalie J.; Martello, Donald; Schroeder, Karl; Granite, Evan

    2009-05-01

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7- day experiment averages ranging from -6.8 to 73 ng/m(2) h for the fly ash samples and -5.2 to 335 ng/m(2) h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  5. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect

    Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

    2009-05-01

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  6. Follow that mercury!

    SciTech Connect

    Linero, A.A.

    2008-07-01

    The article discusses one technology option for avoiding release of mercury captured by power plant pollution control equipment in order to render it usable in concrete. This is the use of selective catalytic reduction for NOx control and lime spray dryer absorbers (SDA) for SO{sub 2} control prior to particulate collection by fabric filters. In this scenario all mercury removed is trapped in the fabric filter baghouse. The US EPA did not establish mercury emission limits for existing cement plants in the latest regulation 40 CFR 63, Subpart LLL (December 2006) and was sued by the Portland Cement Association because of the Hg limits established for new kilns and by several states and environmental groups for the lack of limits on existing ones. A full version of this article is available on www.acaa-usa.org/AshatWork.htm. 2 figs.

  7. Water displacement mercury pump

    DOEpatents

    Nielsen, Marshall G.

    1985-01-01

    A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

  8. Water displacement mercury pump

    DOEpatents

    Nielsen, M.G.

    1984-04-20

    A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

  9. Lumen Maintenance Testing of the Philips 60-Watt Replacement Lamp L Prize Entry

    SciTech Connect

    Gordon, Kelly L.; Hafen, Ryan P.; Hathaway, John E.; McCullough, Jeffrey J.

    2012-09-01

    This paper describes testing conducted to evaluate the Philips' L Prize award winning 60-watt LED replacement product's ability to meet the lifetime/lumen maintenance requirement of the competition, which was: "having 70 percent of the lumen value under subparagraph (A) [producing a luminous flux greater than 900 lumens] exceeding 25,000 hours under typical conditions expected in residential use." A custom test apparatus was designed and constructed for this testing and a statistical approach was developed for use in evaluating the test results. This will be the only publicly available, third-party data set of long-term LED product operation.

  10. Incandescent Lighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Incandescent Lighting Basics Incandescent Lighting Basics August 16, 2013 - 10:00am Addthis Incandescent lamps consist of a wire filament inside a glass bulb that is usually filled with inert gas, and they produce light when an electric current heats the filament to a high temperature. Incandescent lamps have a low efficacy (10-17 lumens per watt) compared with other lighting options-because most of the energy released is in the form of heat rather than light-and a short average operating life

  11. Method and apparatus for sampling atmospheric mercury

    DOEpatents

    Trujillo, Patricio E.; Campbell, Evan E.; Eutsler, Bernard C.

    1976-01-20

    A method of simultaneously sampling particulate mercury, organic mercurial vapors, and metallic mercury vapor in the working and occupational environment and determining the amount of mercury derived from each such source in the sampled air. A known volume of air is passed through a sampling tube containing a filter for particulate mercury collection, a first adsorber for the selective adsorption of organic mercurial vapors, and a second adsorber for the adsorption of metallic mercury vapor. Carbon black molecular sieves are particularly useful as the selective adsorber for organic mercurial vapors. The amount of mercury adsorbed or collected in each section of the sampling tube is readily quantitatively determined by flameless atomic absorption spectrophotometry.

  12. Method and apparatus for monitoring the flow of mercury in a system

    DOEpatents

    Grossman, Mark W.

    1987-01-01

    An apparatus and method for monitoring the flow of mercury in a system. The equipment enables the entrainment of the mercury in a carrier gas e.g., an inert gas, which passes as mercury vapor between a pair of optically transparent windows. The attenuation of the emission is indicative of the quantity of mercury (and its isotopes) in the system. A 253.7 nm light is shone through one of the windows and the unabsorbed light is detected through the other window. The absorption of the 253.7 nm light is thereby measured whereby the quantity of mercury passing between the windows can be determined. The apparatus includes an in-line sensor for measuring the quantity of mercury. It includes a conduit together with a pair of apertures disposed in a face to face relationship and arranged on opposite sides of the conduit. A pair of optically transparent windows are disposed upon a pair of viewing tubes. A portion of each of the tubes is disposed inside of the conduit and within each of the apertures. The two windows are disposed in a face to face relationship on the ends of the viewing tubes and the entire assembly is hermetically sealed from the atmosphere whereby when 253.7 nm ultraviolet light is shone through one of the windows and detected through the other, the quantity of mercury which is passing by can be continuously monitored due to absorption which is indicated by attenuation of the amplitude of the observed emission.

  13. Mercury Information Clearinghouse

    SciTech Connect

    Chad A. Wocken; Michael J. Holmes; Dennis L. Laudal; Debra F. Pflughoeft-Hassett; Greg F. Weber; Nicholas V. C. Ralston; Stanley J. Miller; Grant E. Dunham; Edwin S. Olson; Laura J. Raymond; John H. Pavlish; Everett A. Sondreal; Steven A. Benson

    2006-03-31

    The Canadian Electricity Association (CEA) identified a need and contracted the Energy & Environmental Research Center (EERC) to create and maintain an information clearinghouse on global research and development activities related to mercury emissions from coal-fired electric utilities. With the support of CEA, the Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates, and the U.S. Department of Energy (DOE), the EERC developed comprehensive quarterly information updates that provide a detailed assessment of developments in the various areas of mercury monitoring, control, policy, and research. A total of eight topical reports were completed and are summarized and updated in this final CEA quarterly report. The original quarterly reports can be viewed at the CEA Web site (www.ceamercuryprogram.ca). In addition to a comprehensive update of previous mercury-related topics, a review of results from the CEA Mercury Program is provided. Members of Canada's coal-fired electricity generation sector (ATCO Power, EPCOR, Manitoba Hydro, New Brunswick Power, Nova Scotia Power Inc., Ontario Power Generation, SaskPower, and TransAlta) and CEA, have compiled an extensive database of information from stack-, coal-, and ash-sampling activities. Data from this effort are also available at the CEA Web site and have provided critical information for establishing and reviewing a mercury standard for Canada that is protective of environment and public health and is cost-effective. Specific goals outlined for the CEA mercury program included the following: (1) Improve emission inventories and develop management options through an intensive 2-year coal-, ash-, and stack-sampling program; (2) Promote effective stack testing through the development of guidance material and the support of on-site training on the Ontario Hydro method for employees, government representatives, and contractors on an as-needed basis; (3) Strengthen laboratory analytical capabilities through

  14. Mercury control in 2009

    SciTech Connect

    Sjostrom, S.; Durham, M.; Bustard, J.; Martin, C.

    2009-07-15

    Although activated carbon injection (ACI) has been proven to be effective for many configurations and is a preferred option at many plants sufficient quantities of powdered activated coking (PAC) must be available to meet future needs. The authors estimate that upcoming federal and state regulations will result in tripling the annual US demand for activated carbon to nearly 1.5 billion lb from approximately 450 million lb. Rapid expansion of US production capacity is required. Many PAC manufacturers are discussing expansion of their existing production capabilities. One company, ADA Carbon Solutions, is in the process of constructing the largest activated carbon facility in North America to meet the future demand for PAC as a sorbent for mercury control. Emission control technology development and commercialization is driven by regulation and legislation. Although ACI will not achieve > 90% mercury control at every plant, the expected required MACT legislation level, it offers promise as a low-cost primary mercury control technology option for many configurations and an important trim technology for others. ACI has emerged as the clear mercury-specific control option of choice, representing over 98% of the commercial mercury control system orders to date. As state regulations are implemented and the potential for a federal rule becomes more imminent, suppliers are continuing to develop technologies to improve the cost effectiveness and limit the balance of plant impacts associated with ACI and are developing additional PAC production capabilities to ensure that the industry's needs are met. The commercialisation of ACI is a clear example of industry, through the dedication of many individuals and companies with support from the DOE and EPRI, meeting the challenge of developing cost-effectively reducing emissions from coal-fired power plants. 7 refs., 1 fig.

  15. Remedial investigation/feasibility study report for Lower Watts Bar Reservoir Operable Unit

    SciTech Connect

    1995-03-01

    This document is the combined Remedial Investigation and Feasibility Study Report for the lower Watts Bar Reservoir (LWBR) Operable Unit (OU). The LWBR is located in Roane, Rhea, and Meigs counties, Tennessee, and consists of Watts Bar Reservoir downstream of the Clinch river. This area has received hazardous substances released over a period of 50 years from the US Department of Energy`s Oak Ridge Reservation (ORR), a National Priority List site established under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). As required by this law, the ORR and all off-site areas that have received contaminants, including LWBR, must be investigated to determine the risk to human health and the environment resulting from these releases, the need for any remedial action to reduce these risks, and the remedial actions that are most feasible for implementation in this OU. Contaminants from the ORR are primarily transported to the LWBR via the Clinch River. There is little data regarding the quantities of most contaminants potentially released from the ORR to the Clinch River, particularly for the early years of ORR operations. Estimates of the quantities released during this period are available for most radionuclides and some inorganic contaminants, indicating that releases 30 to 50 years ago were much higher than today. Since the early 1970s, the release of potential contaminants has been monitored for compliance with environmental law and reported in the annual environmental monitoring reports for the ORR.

  16. DOE Publishes Final Rule for the Request for Exclusion of 100 Watt R20 Short Incandescent Reflector Lamps from Energy Conservation Standards

    Energy.gov [DOE]

    The Department of Energy has published a final rule regarding the request for exclusion of 100 Watt R20 short incandescent reflector lamps from energy conservation standards.

  17. Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors

    SciTech Connect

    Gary Blythe; John Currie; David DeBerry

    2008-03-31

    This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling efforts.

  18. Recovery of mercury from acid waste residues

    DOEpatents

    Greenhalgh, W.O.

    1987-02-27

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

  19. Recovery of mercury from acid waste residues

    DOEpatents

    Greenhalgh, Wilbur O.

    1989-01-01

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

  20. Recovery of mercury from acid waste residues

    DOEpatents

    Greenhalgh, Wilbur O.

    1989-12-05

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

  1. Mercury Strategic Plan Outfall 200 Mercury Treatment Facility

    Office of Environmental Management (EM)

    Plan for Mercury Remediation at Y-12 Laura Wilkerson Portfolio Federal Project Director ...sediment studies * Technology Development Plan * Debris treatability study * Fate and ...

  2. Mercury Treatment Facility overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mercury Treatment Facility overview Mercury Treatment Facility overview This fact sheet provides a brief overview for the need and capabilities of the Mercury Treatment Facility at Y-12. The project will provide a mechanism to control and limit mercury migration resulting from future large-scale demolition of the site's mercury contaminated facilities. Mercury Treatment Facility overview (796.41 KB) More Documents & Publications Upper East Fork Poplar Creek OREM overview Technology Plan to

  3. Mercury Vapor (Kooten, 1987) | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    DOE-funding Unknown Notes Surface soil-mercury surveys are an inexpensive and useful exploration tool for geothermal resources. ---- Surface geochemical surveys for mercury...

  4. Geothermal Exploration Using Surface Mercury Geochemistry | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Surface Mercury Geochemistry Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Geothermal Exploration Using Surface Mercury Geochemistry Abstract...

  5. Mercury Vapor | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    hydrothermal system. Other definitions:Wikipedia Reegle Introduction Mercury is a natural byproduct of mantle or deep-crustal derived fluids, high concentrations can be...

  6. Apparatus for mercury refinement

    DOEpatents

    Grossman, M.W.; Speer, R.; George, W.A.

    1991-07-16

    The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

  7. Method for mercury refinement

    DOEpatents

    Grossman, Mark W.; Speer, Richard; George, William A.

    1991-01-01

    The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

  8. Apparatus for mercury refinement

    DOEpatents

    Grossman, Mark W.; Speer, Richard; George, William A.

    1991-01-01

    The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

  9. Method for mercury refinement

    DOEpatents

    Grossman, M.W.; Speer, R.; George, W.A.

    1991-04-09

    The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

  10. Method for scavenging mercury

    DOEpatents

    Chang, Shih-ger; Liu, Shou-heng; Liu, Zhao-rong; Yan, Naiqiang

    2009-01-20

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  11. Method for scavenging mercury

    DOEpatents

    Chang, Shih-Ger; Liu, Shou-Heng; Liu, Zhao-Rong; Yan, Naiqiang

    2011-08-30

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  12. Method for scavenging mercury

    DOEpatents

    Chang, Shih-ger; Liu, Shou-heng; Liu, Zhao-rong; Yan, Naiqiang

    2010-07-13

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  13. Mercury removal sorbents

    DOEpatents

    Alptekin, Gokhan

    2016-03-29

    Sorbents and methods of using them for removing mercury from flue gases over a wide range of temperatures are disclosed. Sorbent materials of this invention comprise oxy- or hydroxyl-halogen (chlorides and bromides) of manganese, copper and calcium as the active phase for Hg.sup.0 oxidation, and are dispersed on a high surface porous supports. In addition to the powder activated carbons (PACs), this support material can be comprised of commercial ceramic supports such as silica (SiO.sub.2), alumina (Al.sub.2O.sub.3), zeolites and clays. The support material may also comprise of oxides of various metals such as iron, manganese, and calcium. The non-carbon sorbents of the invention can be easily injected into the flue gas and recovered in the Particulate Control Device (PCD) along with the fly ash without altering the properties of the by-product fly ash enabling its use as a cement additive. Sorbent materials of this invention effectively remove both elemental and oxidized forms of mercury from flue gases and can be used at elevated temperatures. The sorbent combines an oxidation catalyst and a sorbent in the same particle to both oxidize the mercury and then immobilize it.

  14. Examination of frit vent from Sixty-Watt Heat Source simulant fueled clad vent set

    SciTech Connect

    Ulrich, G.B.

    1995-11-01

    The flow rate and the metallurgical condition of a frit vent from a simulant-fueled clad vent set (CVS) that had been hot isostatically pressed (HIP) for the Sixty-Watt Heat Source program were evaluated. The flow rate form the defueled vent cup subassembly was reduced approximately 25% from the original flow rate. No obstructions were found to account for the reduced flow rate. Measurements indicate that the frit vent powder thickness was reduced about 30%. Most likely, the powder was compressed during the HIP operation, which increased the density of the powder layer and thus reduced the flow rate of the assembly. All other observed manufacturing attributes appeared to be normal, but the vent hole activation technique needs further refinement before it is used in applications requiring maximum CVS integrity.

  15. The Clean Air Mercury Rule

    SciTech Connect

    Michael Rossler

    2005-07-01

    Coming into force on July 15, 2005, the US Clean Air Mercury Rule will use a market-based cap-and-trade approach under Section 111 of the Clean Air Act to reduce mercury emissions from the electric power sector. This article provides a comprehensive summary of the new rule. 14 refs., 2 tabs.

  16. Methods for dispensing mercury into devices

    DOEpatents

    Grossman, Mark W.; George, William A.

    1987-04-28

    A process for dispensing mercury into devices which requires mercury. Mercury is first electrolytically separated from either HgO or Hg.sub.2 Cl.sub.2 and plated onto a cathode wire. The cathode wire is then placed into a device requiring mercury.

  17. Methods for dispensing mercury into devices

    DOEpatents

    Grossman, M.W.; George, W.A.

    1987-04-28

    A process is described for dispensing mercury into devices which requires mercury. Mercury is first electrolytically separated from either HgO or Hg[sub 2]Cl[sub 2] and plated onto a cathode wire. The cathode wire is then placed into a device requiring mercury. 2 figs.

  18. Breakthroughs in Practical-Sized, High Quality OLED Light Panel Source

    Energy.gov [DOE]

    General Electric Global Research has achieved a major breakthrough, developing a fully functional 2 ft. x 2 ft. light panel that produces more than 1200 lumens of quality white light with an efficacy of 15 lumens per watt. This device offers 50% better energy performance than their previous device, breaking two world records.

  19. After the Clean Air Mercury Eule: prospects for reducing mercury emissions from coal-fired power plants

    SciTech Connect

    Jana B. Milford; Alison Pienciak

    2009-04-15

    Recent court decisions have affected the EPA's regulation of mercury emissions from coal burning, but some state laws are helping to clear the air. In 2005, the US EPA issued the Clean Air Mercury Rule (CAMR), setting performance standards for new coal-fired power plants and nominally capping mercury emissions form new and existing plants at 38 tons per year from 2010 to 2017 and 15 tpy in 2018 and thereafter; these down from 48.5 tpy in 1999. To implement the CAMR, 21 states with non-zero emissions adopted EPA's new source performance standards and cap and trade program with little or no modification. By December 2007, 23 other states had proposed or adopted more stringent requirements; 16 states prohibited or restricted interstate trading of mercury emissions. On February 2008, the US Court of Appeal for the District of Columbia Circuit unanimously vacated the CAMR. This article assesses the status of mercury emission control requirements for coal-fired power plants in the US in light of this decision, focusing on state actions and prospects for a new federal rule. 34 refs., 1 fig.

  20. Lumens and the Lighting Facts Label | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Lumens and the Lighting Facts Label Lumens and the Lighting Facts Label Energy 101 Lumens: The new way to shop for light lighting_sub.jpg When you're shopping for lightbulbs, compare lumens to be sure you're getting the amount of light, or level of brightness, you want. The Lighting Facts Label will help. This new label will make it easy to compare bulb brightness, color, life, and estimated operating cost for the year. Buy Lumens, Not Watts In the past, we bought lightbulbs based on how much

  1. Fluorescent sensor for mercury

    DOEpatents

    Wang, Zidong; Lee, Jung Heon; Lu, Yi

    2011-11-22

    The present invention provides a sensor for detecting mercury, comprising: a first polynucleotide, comprising a first region, and a second region, a second polynucleotide, a third polynucleotide, a fluorophore, and a quencher, wherein the third polynucleotide is optionally linked to the second region; the fluorophore is linked to the first polynucleotide and the quencher is linked to the second polynucleotide, or the fluorophore is linked to the second polynucleotide and the quencher is linked to the first polynucleotide; the first region and the second region hybridize to the second polynucleotide; and the second region binds to the third polynucleotide in the presence of Hg.sup.2+ ions.

  2. Jebel Ali Hotel PV lighting systems

    SciTech Connect

    Ellis, M.

    1984-05-01

    A large stand-alone PV lighting project was installed in June 1983 at the Jebel Ali Hotel in Dubai, United Arab Emirates. A high mast lighting system provides illumination for a 130 meter diameter traffic roundabout. The high mast system is powered by a 15 kilowatt peak array of Mobil Solar ribbon PV modules. Along the 700 meter access road leading to the hotel entrance, twenty-one PV powered streetlights provide low-level lighting. Each streetlight consists of a 20 watt fluorescent tube powered by two 35 Wp modules. Operation of both systems is completely automatic. Design, installation, and operating experience to date are reviewed.

  3. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOEpatents

    Broderick, Thomas E.

    2005-09-13

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  4. Enhanced response of an oligonucleotide-based biosensor to environmental mercury

    SciTech Connect

    Edenborn, H.M.

    2006-10-01

    One environmental pollutant of particular relevance to the coal-generated power industry is mercury. Power plants in the U.S., led by Texas, Ohio, Pennsylvania, Indiana, and Alabama, collectively emitted over 90,000 pounds of mercury into the air in 2003. Calls for increased mercury monitoring activities have come from many groups concerned with environmental contamination and mercury bioconcentration in fish. Additionally, the benefits of improvements in the reduction of mercury emissions from existing power plants cannot be seriously evaluated without extensive monitoring of the environment. Low in situ mercury concentrations and the expense of traditional laboratory analyses currently limit such routine and effective monitoring. Microbial biosensors sensitive to mercury have been developed that quantitatively produce light in response to the amount of mercury (II) entering the cells. However, these sensors are typically difficult to prepare, can have long lag times between initial exposure and subsequent light emission, and are difficult to use in the field. Whole cell biosensors using living bacteria also require attention to the growth requirements of the cells, as well as complications brought on by the presence of other toxic compounds in addition to mercury. A molecular beacon sensor for mercury (II) reported by Ono and Togashi (Angew. Chem. Int. Ed. 2004, 43:4300-4302.) was modified to enhance its sensitivity and fluorescence response. The basic detection method involves the selective binding of mercury ions to thymine-thymine (T-T) base pairs in DNA duplexes. An oligonucleotide sequence in the sensor changes its conformation upon binding with mercury ions, and causes a fluorophore at one end of the oligonucleotide sequence to come in proximity with a quencher molecule attached to the other end. Enhanced fluorescence resonance energy transfer (FRET) results in a decrease in the intensity of the fluorescence spectrum. The use of fluorescein as a harvester

  5. A Winning Light Bulb With the Potential to Save the Nation Billions |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy A Winning Light Bulb With the Potential to Save the Nation Billions A Winning Light Bulb With the Potential to Save the Nation Billions August 4, 2011 - 3:09pm Addthis This 10-watt alternative LED bulb (which glows white when turned on) could save the nation about 35 terawatt-hours of electricity or $3.9 billion in one year and avoid 20 million metric tons of carbon emissions if every 60-watt incandescent bulb in the U.S. was replaced with the L Prize winner. | Photo

  6. Solid-State Lighting-L Prize Competition | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    L Prize Competition Solid-State Lighting-L Prize Competition Presenter: Marc Ledbetter, Pacific Northwest National Laboratory The L Prize competition spurs the development of new, ultra-efficient lighting products to replace common light sources, including the 60-watt (W) incandescent bulb and the PAR38 reflector bulb. The goal is to realize significant lighting energy savings through widespread product adoption. Winning manufacturers receive significant recognition, and retailers, energy

  7. Annual radiological environmental monitoring report: Watts Bar Nuclear Plant, 1992. Operations Services/Technical Programs

    SciTech Connect

    Not Available

    1993-04-01

    This report describes the preoperational environmental radiological monitoring program conducted by TVA in the vicinity of the Watts Bar Nuclear Plant (WBN) in 1992. The program includes the collection of samples from the environment and the determination of the concentrations of radioactive materials in the samples. Samples are taken from stations in the general area of the plant and from areas that will not be influenced by plant operations. Material sampled includes air, water, milk, foods, vegetation, soil, fish, sediment, and direct radiation levels. During plant operations, results from stations near the plant will be compared with concentrations from control stations and with preoperational measurements to determine potential impacts to the public. Exposures calculated from environmental samples were contributed by naturally occurring radioactive materials, from materials commonly found in the environment as a result of atmospheric fallout, or from the operation of other nuclear facilities in the area. Since WBN has not operated, there has been no contribution of radioactivity from the plant to the environment.

  8. Conceptual Design of 500 watt portable thermophotovoltaic power supply using JP-8 fuel

    SciTech Connect

    DeBellis, C.L.; Scotto, M.V.; Fraas, L.

    1997-03-01

    Babcock & Wilcox (B&W) and JX Crystals (JXC) have developed an innovative design for a compact, 500 watt net electric (We), 24-VDC thermophotovoltaic (TPV) power supply using JP-8 fuel. As currently envisioned, the TPV generator will be approximately 20 cm (8 inches) in diameter and 50 cm (20 inches) high, not including a fuel tank and controls. The total system may weigh as little as 7.5 kg (16.5 lb) without fuel. This system will achieve high efficiency and high power density relative to its size through the use of low bandgap gallium antimonide (GaSb) PV cells and a matched emitter. A thermally integrated fuel vaporizer and recuperator will boost system efficiency by transferring the unused energy in the exhaust stream to the incoming fuel and combustion air. At rated conditions and 500 We output, the system is expected to have an overall efficiency of 8{percent} to 10{percent}. This paper examines the trade-offs between system efficiency, power density, and weight required in the selection and configuration of the major system components. {copyright} {ital 1997 American Institute of Physics.}

  9. Recommendation and implementation of special seasonal flow releases to enhance sauger spawning in Watts Bar tailwater. Final report

    SciTech Connect

    Yeager, B.; Shiao, Ming

    1992-05-01

    In recent years sauger populations in Chickamauga Reservoir, as well as several other areas in the Tennessee River Valley, have suffered drastic declines in numbers. Based on field creel evaluations the fisherman harvest of sauger in Chickamauga Reservoir has declined from an estimated high of 66,000 fish caught in 1979 to 0 fish in 1989. The Tennessee Wildlife Resources Agency began an aggressive effort in 1990 and 1991 to recover this population, as well as those of Ft. Loudon and Watts Bar Reservoirs, by stocking large numbers of fingerling sauger. This is however, only a short-term, stopgap measure. The decline in the population of Chickamauga Reservoir appears directly related to dramatically lower discharges from Watts Bar Dam during the recent drought. The primary factor affecting year-class strength (numbers of sauger successfully spawned in a year and reaching catchable size in subsequent years) is the amount of spawning habitat available in the month of April (the spawning season for sauger) at one particular site below Watts Bar Dam. This report documents studies aimed at optimizing sauger spawning in Chickamauga Reservoir.

  10. Phytoremediation of Ionic and Methyl Mercury Pollution

    SciTech Connect

    Meagher, Richard B.

    2005-06-01

    Phytoremediation is defined as the use of plants to extract, resist, detoxify, and/or sequester toxic environmental pollutants. The long-term goal of the proposed research is to develop and test highly productive, field-adapted plant species that have been engineered for the phytoremediation of mercury. A variety of different genes, which should enable plants to clean mercury polluted sites are being tested as tools for mercury phytoremediation, first in model laboratory plants and then in potential field species. Several of these genes have already been shown to enhance mercury phytoremediation. Mercury pollution is a serious, world-wide problem affecting the health of human and wildlife populations. Environmentally, the most serious mercury threat is the production of methylmercury (CH3Hg+) by native bacteria at mercury contaminated wetland sites. Methylmercury is inherently more toxic than metallic (Hg(0)) or ionic (Hg(II)) mercury, and because methylmercury is prolifically biomagnified up the food chain, it poses the most immediate danger to animal populations. We have successfully engineered two model plants, Arabidopsis and tobacco, to use the bacterial merB gene to convert methylmercury to less toxic ionic mercury and to use the bacterial merA gene to further detoxify ionic mercury to the least toxic form of mercury, metallic mercury. Plants expressing both MerA and MerB proteins detoxify methylmercury in two steps to the metallic form. These plants germinate, grow, and set seed at normal growth rates on levels of methylmercury or ionic mercury that are lethal to normal plants. Our newest efforts involve engineering plants with several additional bacterial and plant genes that allow for higher levels of mercury resistance and mercury hyperaccumulation. The potential for these plants to hyperaccumulate mercury was further advanced by developing constitutive, aboveground, and root-specific gene expression systems. Our current strategy is to engineer plants to

  11. Results of Performance Tests Performed on the John Watts Casing Connection on 7" Pipe

    SciTech Connect

    John D. Watts

    1999-08-01

    Stress Engineering Services (SES) was contracted by Mr. John Watts to test his threaded connection developed for oilfield oil and gas service. This particular test required the application of a variety of loads including axial tension and compression, internal pressure (gas), external pressure (water), bending and both low and elevated temperature. These loads were used to determine the sealing and structural limits of the connection. The connection design tested had tapered threads with 10 threads per inch. A square thread form and a round thread form were tested. The square thread form had a 2{sup o} load flank and 15{sup o} stab flank. The round thread had a 0{sup o} load flank and 20{sup o} stab flank. Most of the testing was performed on the round thread form. Both a coupled connection design and an integral connection design were tested. The coupling was a pin by pin (male) thread, with the pipe having a box (female) thread. Both designs have outside and inside diameters that are flush with the pipe body. Both designs also contain a small external shoulder. The test procedure selected for this evaluation was the newly written ISO 13679 procedure for full scale testing of casing and tubing connections. The ISO procedure requires a variety of tests that includes makeup/breakout testing, internal gas sealability/external water sealability testing with axial tension, axial compression, bending, internal gas thermal cycle tests and limit load (failure) tests. This test was performed with four coupled samples and included most of these loads. Two integral samples were also included for limit load testing ISO makeup/breakout tests are divided into three types--initial makeup, IML1, repeated makeup within the same sample, MBL, and repeated makeup using several samples called round robin, RR. IMU and MBL were performed in this project. The ISO sealing and structural procedure is divided into four primary tests and identified as Series A, B, C and Limit Load (failure

  12. Method and apparatus for monitoring the flow of mercury in a system

    DOEpatents

    Grossman, M.W.

    1987-12-15

    An apparatus and method for monitoring the flow of mercury in a system are disclosed. The equipment enables the entrainment of the mercury in a carrier gas e.g., an inert gas, which passes as mercury vapor between a pair of optically transparent windows. The attenuation of the emission is indicative of the quantity of mercury (and its isotopes) in the system. A 253.7 nm light is shone through one of the windows and the unabsorbed light is detected through the other window. The absorption of the 253.7 nm light is thereby measured whereby the quantity of mercury passing between the windows can be determined. The apparatus includes an in-line sensor for measuring the quantity of mercury. It includes a conduit together with a pair of apertures disposed in a face to face relationship and arranged on opposite sides of the conduit. A pair of optically transparent windows are disposed upon a pair of viewing tubes. A portion of each of the tubes is disposed inside of the conduit and within each of the apertures. The two windows are disposed in a face to face relationship on the ends of the viewing tubes and the entire assembly is hermetically sealed from the atmosphere whereby when 253.7 nm ultraviolet light is shone through one of the windows and detected through the other, the quantity of mercury which is passing by can be continuously monitored due to absorption which is indicated by attenuation of the amplitude of the observed emission. 4 figs.

  13. Mercury switch with non-wettable electrodes

    DOEpatents

    Karnowsky, Maurice M.; Yost, Frederick G.

    1987-01-01

    A mercury switch device comprising a pool of mercury and a plurality of electrical contacts made of or coated with a non-wettable material such as titanium diboride.

  14. Method for the removal and recovery of mercury

    DOEpatents

    Easterly, C.E.; Vass, A.A.; Tyndall, R.L.

    1997-01-28

    The present invention is an enhanced method for the removal and recovery of mercury from mercury-contaminated matrices. The method involves contacting a mercury-contaminated matrix with an aqueous dispersant solution derived from specific intra-amoebic isolates to release the mercury from the mercury-contaminated matrix and emulsify the mercury; then, contacting the matrix with an amalgamating metal from a metal source to amalgamate the mercury to the amalgamating metal; removing the metallic source from the mercury-contaminated matrix; and heating the metallic source to vaporize the mercury in a closed system to capture the mercury vapors.

  15. Method for the removal and recovery of mercury

    DOEpatents

    Easterly, Clay E.; Vass, Arpad A.; Tyndall, Richard L.

    1997-01-01

    The present invention is an enhanced method for the removal and recovery of mercury from mercury-contaminated matrices. The method involves contacting a mercury-contaminated matrix with an aqueous dispersant solution derived from specific intra-amoebic isolates to release the mercury from the mercury-contaminated matrix and emulsify the mercury; then, contacting the matrix with an amalgamating metal from a metal source to amalgamate the mercury to the amalgamating metal; removing the metallic source from the mercury-contaminated matrix; and heating the metallic source to vaporize the mercury in a closed system to capture the mercury vapors.

  16. High Efficiency LED Lamp for Solid-State Lighting

    SciTech Connect

    James Ibbetson

    2006-12-31

    This report contains a summary of technical achievements during a three-year project to demonstrate high efficiency, solid-state lamps based on gallium nitride/silicon carbide light-emitting diodes. Novel chip designs and fabrication processes are described for a new type of nitride light-emitting diode with the potential for very high efficiency. This work resulted in the demonstration of blue light-emitting diodes in the one watt class that achieved up to 495 mW of light output at 350 mA drive current, corresponding to quantum and wall plug efficiencies of 51% and 45%, respectively. When combined with a phosphor in Cree's 7090 XLamp package, these advanced blue-emitting devices resulted in white light-emitting diodes whose efficacy exceeded 85 lumens per watt. In addition, up to 1040 lumens at greater than 85 lumens per watt was achieved by combining multiple devices to make a compact white lamp module with high optical efficiency.

  17. Phytoremediation of Ionic and Methyl Mercury Pollution

    SciTech Connect

    Meagher, Richard B.

    2004-12-01

    Phytoremediation is defined as the use of plants to extract, resist, detoxify, and/or sequester toxic environmental pollutants. The long-term goal of the proposed research is to develop and test highly productive, field-adapted plant species that have been engineered for the phytoremediation of mercury. A variety of different genes, which should enable plants to clean mercury polluted sites are being tested as tools for mercury phytoremediation, first in model laboratory plants and then in potential field species. Several of these genes have already been shown to enhance mercury phytoremediation. Mercury pollution is a serious, world-wide problem affecting the health of human and wildlife populations. Environmentally, the most serious mercury threat is the production of methylmercury (CH3Hg+) by native bacteria at mercury contaminated wetland sites. Methylmercury is inherently more toxic than metallic (Hg(0)) or ionic (Hg(II)) mercury, and because methylmercury is prolifically biomagnified up the food chain, it poses the most immediate danger to animal populations. We have successfully engineered two model plants, Arabidopsis and tobacco, to use the bacterial merB gene to convert methylmercury to less toxic ionic mercury and to use the bacterial merA gene to further detoxify ionic mercury to the least toxic form of mercury, metallic mercury. Plants expressing both MerA and MerB proteins detoxify methylmercury in two steps to the metallic form. These plants germinate, grow, and set seed at normal growth rates on levels of methylmercury or ionic mercury that are lethal to normal plants. Our newest efforts involve engineering plants with several additional bacterial and plant genes that allow for higher levels of mercury resistance and mercury hyperaccumulation. The potential for these plants to hyperaccumulate mercury was further advanced by developing constitutive, aboveground, and root-specific gene expression systems.

  18. Mercury Continuous Emmission Monitor Calibration

    SciTech Connect

    John Schabron; Eric Kalberer; Ryan Boysen; William Schuster; Joseph Rovani

    2009-03-12

    Mercury continuous emissions monitoring systems (CEMs) are being implemented in over 800 coal-fired power plant stacks throughput the U.S. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor calibrators/generators. These devices are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 and vacated by a Federal appeals court in early 2008 required that calibration be performed with NIST-traceable standards. Despite the vacature, mercury emissions regulations in the future will require NIST traceable calibration standards, and EPA does not want to interrupt the effort towards developing NIST traceability protocols. The traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued a conceptual interim traceability protocol for elemental mercury calibrators. The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially from about 2-40 {micro}g/m{sup 3} elemental mercury, and in the future down to 0.2 {micro}g/m{sup 3}, and this analysis will be directly traceable to analyses by NIST. The EPA traceability protocol document is divided into two separate sections. The first deals with the qualification of calibrator models by the vendors for use in mercury CEM calibration. The second describes the procedure that the vendors must use to certify the calibrators that meet the qualification specifications. The NIST traceable certification is performance based, traceable to analysis using isotope dilution inductively coupled plasma

  19. Coping with uncertainties of mercury regulation

    SciTech Connect

    Reich, K.

    2006-09-15

    The thermometer is rising as coal-fired plants cope with the uncertainties of mercury regulation. The paper deals with a diagnosis and a suggested cure. It describes the state of mercury emission rules in the different US states, many of which had laws or rules in place before the Clean Air Mercury Rule (CAMR) was promulgated.

  20. Study on the reduction of atmospheric mercury emissions from mine waste enriched soils through native grass cover in the Mt. Amiata region of Italy

    SciTech Connect

    Fantozzi, L.; Dini, F.; Tamburello, L.; Pirrone, N.; Sprovieri, F.

    2013-08-15

    Atmospheric mercury emissions from mine-waste enriched soils were measured in order to compare the mercury fluxes of bare soils with those from other soils covered by native grasses. Our research was conducted near Mt. Amiata in central Italy, an area that was one of the largest and most productive mining centers in Europe up into the 1980s. To determine in situ mercury emissions, we used a Plexiglas flux chamber connected to a portable mercury analyzer (Lumex RA-915+). This allowed us to detect, in real time, the mercury vapor in the air, and to correlate this with the meteorological parameters that we examined (solar radiation, soil temperature, and humidity). The highest mercury flux values (8000 ng m{sup −2} h{sup −1}) were observed on bare soils during the hours of maximum insulation, while lower values (250 ng m{sup −2} h{sup −1}) were observed on soils covered by native grasses. Our results indicate that two main environmental variables affect mercury emission: solar radiation intensity and soil temperature. The presence of native vegetation, which can shield soil surfaces from incident light, reduced mercury emissions, a result that we attribute to a drop in the efficiency of mercury photoreduction processes rather than to decreases in soil temperature. This finding is consistent with decreases in mercury flux values down to 3500 ng m{sup −2} h{sup −1}, which occurred under cloudy conditions despite high soil temperatures. Moreover, when the soil temperature was 28 °C and the vegetation was removed from the experimental site, mercury emissions increased almost four-fold. This increase occurred almost immediately after the grasses were cut, and was approximately eight-fold after 20 h. Thus, this study demonstrates that enhancing wild vegetation cover could be an inexpensive and effective approach in fostering a natural, self-renewing reduction of mercury emissions from mercury-contaminated soils. -- Highlights: ► Mercury air/surface exchange

  1. Assessing ecological risks to the fish community from residual coal fly ash in Watts Bar Reservoir, Tennessee

    SciTech Connect

    Rigg, David K.; Wacksman, Mitch N.; Iannuzzi, Jacqueline; Baker, Tyler F.; Adams, Marshall; Greeley, Jr., Mark Stephen

    2014-12-18

    For this research, extensive site-specific biological and environmental data were collected to support an evaluation of risks to the fish community in Watts Bar Reservoir from residual ash from the December 2008 Tennessee Valley Authority (TVA) Kingston ash release. This paper describes the approach used and results of the risk assessment for the fish community, which consists of multiple measurement endpoints (measures of exposure and effects) for fish. The lines of evidence included 1) comparing postspill annual fish community assessments with nearby prespill data and data from other TVA reservoirs, 2) evaluating possible effects of exposures of fish eggs and larval fish to ash in controlled laboratory toxicity tests, 3) evaluating reproductive competence of field-exposed fish, 4) assessing individual fish health through physical examination, histopathology, and blood chemistry, 5) comparing fish tissue concentrations with literature-based critical body residues, and 6) comparing concentrations of ash-related contaminants in surface waters with US Environmental Protection Agency's (USEPA) Ambient Water Quality Standards for Fish and Aquatic Life. These measurement endpoints were treated as independent lines of evidence that were integrated into an overall weight-of-evidence estimate of risk to the fish community. Collectively, the data and analysis presented here indicate that ash and ash-related constituents pose negligible risks to the fish communities in Watts Bar Reservoir. This conclusion contradicts the predictions by some researchers immediately following the ash release of devastating effects on the aquatic ecology of Watts Bar Reservoir. The information presented in this article reaffirms the wisdom of carefully evaluating the evidence before predicting probable ecological effects of a major event such as the TVA Kingston ash release. Lastly, this study demonstrates that a thorough and detailed investigation using multiple measurement endpoints is needed

  2. Assessing ecological risks to the fish community from residual coal fly ash in Watts Bar Reservoir, Tennessee

    DOE PAGES [OSTI]

    Rigg, David K.; Wacksman, Mitch N.; Iannuzzi, Jacqueline; Baker, Tyler F.; Adams, Marshall; Greeley, Jr., Mark Stephen

    2014-12-18

    For this research, extensive site-specific biological and environmental data were collected to support an evaluation of risks to the fish community in Watts Bar Reservoir from residual ash from the December 2008 Tennessee Valley Authority (TVA) Kingston ash release. This paper describes the approach used and results of the risk assessment for the fish community, which consists of multiple measurement endpoints (measures of exposure and effects) for fish. The lines of evidence included 1) comparing postspill annual fish community assessments with nearby prespill data and data from other TVA reservoirs, 2) evaluating possible effects of exposures of fish eggs andmore » larval fish to ash in controlled laboratory toxicity tests, 3) evaluating reproductive competence of field-exposed fish, 4) assessing individual fish health through physical examination, histopathology, and blood chemistry, 5) comparing fish tissue concentrations with literature-based critical body residues, and 6) comparing concentrations of ash-related contaminants in surface waters with US Environmental Protection Agency's (USEPA) Ambient Water Quality Standards for Fish and Aquatic Life. These measurement endpoints were treated as independent lines of evidence that were integrated into an overall weight-of-evidence estimate of risk to the fish community. Collectively, the data and analysis presented here indicate that ash and ash-related constituents pose negligible risks to the fish communities in Watts Bar Reservoir. This conclusion contradicts the predictions by some researchers immediately following the ash release of devastating effects on the aquatic ecology of Watts Bar Reservoir. The information presented in this article reaffirms the wisdom of carefully evaluating the evidence before predicting probable ecological effects of a major event such as the TVA Kingston ash release. Lastly, this study demonstrates that a thorough and detailed investigation using multiple measurement endpoints

  3. Apparatus for control of mercury

    SciTech Connect

    Downs, William; Bailey, Ralph T.

    2001-01-01

    A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.

  4. Final project report on arsenic biogeochemistry in the Clinch River and Watts Bar Reservoir: Volume 2, Quality assurance/quality control summary report for arsenic biogeochemistry in the Clinch River and Watts Bar Reservoir. Environmental Restoration Program

    SciTech Connect

    Newman, K.A.; Ford, C.J.; Byrd, J.T.

    1995-04-01

    Arsenic contamination was studied in the Clinch River/Watts Bar Reservoir (CR/WBR) system downstream from the US Department of Energy`s Oak Ridge Reservation (ORR). Arsenic is of particular interest and concern because (1) it occurs commonly in coal-bearing rock and waste products such as fly ash associated with the burning of coal, (2) it is classified as a Class A carcinogen by the US Environmental Protection Agency, and (3) disposal of fly ash, both on and off the ORR, may have contaminated surface water and sediments in the Clinch River and Watts Bar Reservoir. The present study dffers from previous reports on arsenic concentrations in the CR/WBR system in the use of much more sensitive and precise processing and analytical techniques to measure arsenic species (arsenate, arsenite, and organic arsenic) at levels well below the ecological and human health risk screening criteria. The absolute detection limits using these techniques are approximately 20 to 40 pmol/L or 0.0015 to 0.003 {mu}g/L.

  5. Chemical Form Matters: Differential Accumulation of Mercury Following Inorganic and Organic Mercury Exposures in Zebrafish Larvae

    SciTech Connect

    Korbas, Malgorzata; MacDonald, Tracy C.; Pickering, Ingrid J.; George, Graham N.; Krone, Patrick H.

    2013-04-08

    Mercury, one of the most toxic elements, exists in various chemical forms each with different toxicities and health implications. Some methylated mercury forms, one of which exists in fish and other seafood products, pose a potential threat, especially during embryonic and early postnatal development. Despite global concerns, little is known about the mechanisms underlying transport and toxicity of different mercury species. To investigate the impact of different mercury chemical forms on vertebrate development, we have successfully combined the zebrafish, a well-established developmental biology model system, with synchrotron-based X-ray fluorescence imaging. Our work revealed substantial differences in tissue-specific accumulation patterns of mercury in zebrafish larvae exposed to four different mercury formulations in water. Methylmercury species not only resulted in overall higher mercury burdens but also targeted different cells and tissues than their inorganic counterparts, thus revealing a significant role of speciation in cellular and molecular targeting and mercury sequestration. For methylmercury species, the highest mercury concentrations were in the eye lens epithelial cells, independent of the formulation ligand (chloride versus L-cysteine). For inorganic mercury species, in absence of L-cysteine, the olfactory epithelium and kidney accumulated the greatest amounts of mercury. However, with L-cysteine present in the treatment solution, mercuric bis-L-cysteineate species dominated the treatment, significantly decreasing uptake. Our results clearly demonstrate that the common differentiation between organic and inorganic mercury is not sufficient to determine the toxicity of various mercury species.

  6. Consortium for Advanced Simulation of Light Water Reactors (CASL)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Science and Technology Archive Energy Department Announces Five Year Renewal of Funding for First Energy Innovation Hub Consortium for Advanced Simulation of Light Water Reactors to Receive up to $121.5 Million Over Five Years. Posted: January 29, 2015 VERA-CS Coupled Multi-physics Capability demonstrated in a Full Core Simulation In December, CASL reported on the latest results from its Watts Bar reactor progression problem modeling. Posted: August 14, 2014 Westinghouse Completes its AP1000®

  7. Mercury emissions from municipal solid waste combustors

    SciTech Connect

    Not Available

    1993-05-01

    This report examines emissions of mercury (Hg) from municipal solid waste (MSW) combustion in the United States (US). It is projected that total annual nationwide MSW combustor emissions of mercury could decrease from about 97 tonnes (1989 baseline uncontrolled emissions) to less than about 4 tonnes in the year 2000. This represents approximately a 95 percent reduction in the amount of mercury emitted from combusted MSW compared to the 1989 mercury emissions baseline. The likelihood that routinely achievable mercury emissions removal efficiencies of about 80 percent or more can be assured; it is estimated that MSW combustors in the US could prove to be a comparatively minor source of mercury emissions after about 1995. This forecast assumes that diligent measures to control mercury emissions, such as via use of supplemental control technologies (e.g., carbon adsorption), are generally employed at that time. However, no present consensus was found that such emissions control measures can be implemented industry-wide in the US within this time frame. Although the availability of technology is apparently not a limiting factor, practical implementation of necessary control technology may be limited by administrative constraints and other considerations (e.g., planning, budgeting, regulatory compliance requirements, etc.). These projections assume that: (a) about 80 percent mercury emissions reduction control efficiency is achieved with air pollution control equipment likely to be employed by that time; (b) most cylinder-shaped mercury-zinc (CSMZ) batteries used in hospital applications can be prevented from being disposed into the MSW stream or are replaced with alternative batteries that do not contain mercury; and (c) either the amount of mercury used in fluorescent lamps is decreased to an industry-wide average of about 27 milligrams of mercury per lamp or extensive diversion from the MSW stream of fluorescent lamps that contain mercury is accomplished.

  8. Mercury exposure from interior latex paint

    SciTech Connect

    Agocs, M.M.; Etzel, R.A.; Parrish, R.G.; Paschal, D.C.; Campagna, P.R.; Cohen, D.S.; Kilbourne, E.M.; Hesse, J.L. )

    1990-10-18

    Many paint companies have used phenylmercuric acetate as a preservative to prolong the shelf life of interior latex paint. In August 1989, acrodynia, a form of mercury poisoning, occurred in a child exposed to paint fumes in a home recently painted with a brand containing 4.7 mmol of mercury per liter (at that time the Environmental Protection Agency's recommended limit was 1.5 mmol or less per liter). To determine whether the recent use of that brand of paint containing phenylmercuric acetate was associated with elevated indoor-air and urinary mercury concentrations, we studied 74 exposed persons living in 19 homes recently painted with the brand and 28 unexposed persons living in 10 homes not recently painted with paint containing mercury. The paint samples from the homes of exposed persons contained a median of 3.8 mmol of mercury per liter, and air samples from the homes had a median mercury content of 10.0 nmol per cubic meter (range, less than 0.5 to 49.9). No mercury was detected in paint or air samples from the homes of unexposed persons. The median urinary mercury concentration was higher in the exposed persons (4.7 nmol of mercury per millimole of creatinine; range, 1.4 to 66.5) than in the unexposed persons (1.1 nmol per millimole; range, 0.02 to 3.9; P less than 0.001). Urinary mercury concentrations within the range that we found in exposed persons have been associated with symptomatic mercury poisoning. We found that potentially hazardous exposure to mercury had occurred among persons whose homes were painted with a brand of paint containing mercury at concentrations approximately 2 1/2 times the Environmental Protection Agency's recommended limit.

  9. Energy Efficiency and Renewable Energy Technologies for Alaska

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... bulbs 60 watts 2,820 watts CFL bulbs 14 watts 658 watts LED bulbs 9.5 watts 446.5 watts Lighting using kilowatt price of 12 cents * Monthly Cost of Using Incandescent Light ...

  10. Improved Ex-Situ Mercury Remediation - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Improved Ex-Situ Mercury Remediation Brookhaven National Laboratory Contact BNL About This Technology Technology Marketing Summary The present invention provides a process for the treatment of mercury containing waste in a single reaction vessel. The process is effective in treating various types of mercury contaminated waste; such as elemental mercury or mercury compounds, mercury contaminated bulk material, or

  11. In-Situ Mercury Remediation - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    In-Situ Mercury Remediation Brookhaven National Laboratory Contact BNL About This Technology Technology Marketing Summary In Situ Mercury Stabilization (ISMS) is a method that can remove toxic mercury from soil, sediment, sludge, and other industrial waste. Description ISMS includes a device and method for remediation of mercury contamination in which mercury is first concentrated by inserting rods of sulfur reagent into the waste. Mercury is drawn to specially designed treatment rods, which

  12. Final Project Report on Arsenic Biogeochemistry in the Clinch River and Watts Bar Reservoir, Volume 2: Quality Assurance/Quality Control Summary Report for Arsenic Biogeochemistry in the Clinch River and Watts Bar Reservoir

    SciTech Connect

    Newman, K.A.

    1995-01-01

    Arsenic contamination was studied in the Clinch River/Watts Bar Reservoir (CR/WBR) system downstream from the U.S. Department of Energy's Oak Ridge Reservation (ORR). Arsenic is of particular interest and concern because (1) it occurs commonly in coal-bearing rock and waste products such as fly ash associated with the burning of coal, (2) it is classified as a Class A carcinogen by the U. S. Environmental Protection Agency, and (3) disposal of fly ash, both on and off the ORR, may have contaminated surface water and sediments in the Clinch River and Watts Bar Reservoir. The present study differs from previous reports on arsenic concentrations in the CR/WBR system in the use of much more sensitive and precise processing and analytical techniques to measure arsenic species (arsenate, arsenite, and organic arsenic) at levels well below the ecological and human health risk screening criteria. The absolute detection limits using these techniques are approximately 20 to 40 pmol/L, or 0.0015 to 0.003 {micro}g/L. Four main sites were sampled quarterly over a 3-year period (1990 through 1992). Sites investigated included Lower Watts Bar Reservoir near the Watts Bar Dam (Tennessee River kilometer 849.6), the Kingston area (Clinch River kilometer 1.6), Poplar Creek (Poplar Creek kilometer 1.6), and the McCoy Branch Embayment (McCoy Branch kilometer 0.3). Additional sites were investigated in the vicinity of these main stations to determine the distribution of contamination and to identify possible alternative or additional sources of arsenic. Detection limits that were a factor of 20 below the minimum risk screening criteria were achieved for 100% of arsenic speciation data. However, 118 samples for inductively coupled plasma metals analysis were not preserved to analytical specifications, and the analytical holding times for 180 ion chromatography samples were not met. More rigorous preservative testing protocols and more tightly defined analytical statements of work will

  13. Milestone Project Demonstrates Innovative Mercury Emissions Reduction

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Technology | Department of Energy Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology January 12, 2010 - 12:00pm Addthis Washington, DC - An innovative technology that could potentially help some coal-based power generation facilities comply with anticipated new mercury emissions standards was successfully demonstrated in a recently concluded milestone project at a Michigan power

  14. Process for removing mercury from aqueous solutions

    DOEpatents

    Googin, J.M.; Napier, J.M.; Makarewicz, M.A.; Meredith, P.F.

    1985-03-04

    A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

  15. Process for removing mercury from aqueous solutions

    DOEpatents

    Googin, John M.; Napier, John M.; Makarewicz, Mark A.; Meredith, Paul F.

    1986-01-01

    A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

  16. Microsoft PowerPoint - DOELM_Mercury_Storage.ppt

    Office of Legacy Management (LM)

    Mercury Storage Concept Pre-Environmental Impact Statement Grand Junction, Colorado, Scoping Meeting Information 2 Mercury Export Ban Act Passed into law in October 2008 Purpose is ...

  17. Evaluation of the Mercury Soil Mapping Geothermal Exploration...

    OpenEI (Open Energy Information) [EERE & EIA]

    the Mercury Soil Mapping Geothermal Exploration Techniques Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Evaluation of the Mercury Soil...

  18. Sorbents for the oxidation and removal of mercury (Patent) |...

    Office of Scientific and Technical Information (OSTI)

    Title: Sorbents for the oxidation and removal of mercury A promoted activated carbon ... the sorbent, or to the flue gas to enhance sorbent performance andor mercury capture. ...

  19. Sorbents for mercury removal from flue gas (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Fossil Energy Country of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; Flue Gas; Flue Gas; Mercury; Mercury; ...

  20. CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT Citation Details In-Document Search Title: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE ...

  1. Mercury Emission Measurement at a CFB Plant

    SciTech Connect

    John Pavlish; Jeffrey Thompson; Lucinda Hamre

    2009-02-28

    In response to pending regulation to control mercury emissions in the United States and Canada, several projects have been conducted to perform accurate mass balances at pulverized coal (pc)-fired utilities. Part of the mercury mass balance always includes total gaseous mercury as well as a determination of the speciation of the mercury emissions and a concentration bound to the particulate matter. This information then becomes useful in applying mercury control strategies, since the elemental mercury has traditionally been difficult to control by most technologies. In this instance, oxidation technologies have proven most beneficial for increased capture. Despite many years of mercury measurement and control projects at pc-fired units, far less work has been done on circulating fluidized-bed (CFB) units, which are able to combust a variety of feedstocks, including cofiring coal with biomass. Indeed, these units have proven to be more problematic because it is very difficult to obtain a reliable mercury mass balance. These units tend to have very different temperature profiles than pc-fired utility boilers. The flexibility of CFB units also tends to be an issue when a mercury balance is determined, since the mercury inputs to the system come from the bed material and a variety of fuels, which can have quite variable chemistry, especially for mercury. In addition, as an integral part of the CFB operation, the system employs a feedback loop to circulate the bed material through the combustor and the solids collection system (the primary cyclone), thereby subjecting particulate-bound metals to higher temperatures again. Despite these issues, CFB boilers generally emit very little mercury and show good native capture. The Energy & Environmental Research Center is carrying out this project for Metso Power in order to characterize the fate of mercury across the unit at Rosebud Plant, an industrial user of CFB technology from Metso. Appropriate solids were collected, and

  2. ccpi_mercury | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mercury Specie and Multi-Pollutant Control Project - Project Brief PDF-131KB NeuCo, Inc., Boston, MA (acquired original participant, Pegasus Technologies) PROJECT FACT SHEET...

  3. Alkaline sorbent injection for mercury control

    DOEpatents

    Madden, Deborah A.; Holmes, Michael J.

    2002-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  4. Alkaline sorbent injection for mercury control

    DOEpatents

    Madden, Deborah A.; Holmes, Michael J.

    2003-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  5. Identification of elemental mercury in the subsurface

    DOEpatents

    Jackson, Dennis G

    2015-01-06

    An apparatus and process is provided for detecting elemental mercury in soil. A sacrificial electrode of aluminum is inserted below ground to a desired location using direct-push/cone-penetrometer based equipment. The insertion process removes any oxides or previously found mercury from the electrode surface. Any mercury present adjacent the electrode can be detected using a voltmeter which indicates the presence or absence of mercury. Upon repositioning the electrode within the soil, a fresh surface of the aluminum electrode is created allowing additional new measurements.

  6. Sorbents for mercury removal from flue gas

    SciTech Connect

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  7. Environmental Remediation program completes legacy mercury cleanup...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Stories Legacy slope-side cleanup Environmental Remediation program completes legacy mercury cleanup near Smith's Marketplace Los Alamos National Laboratory performed a ...

  8. Phytoremediation of Ionic and Methyl Mercury Pollution

    SciTech Connect

    Meagher, Richard B.

    2005-06-01

    Phytoremediation is defined as the use of plants to extract, resist, detoxify, and/or sequester toxic environmental pollutants. The long-term goal of the proposed research is to develop and test highly productive, field-adapted plant species that have been engineered for the phytoremediation of mercury. A variety of different genes, which should enable plants to clean mercury polluted sites are being tested as tools for mercury phytoremediation, first in model laboratory plants and then in potential field species. Several of these genes have already been shown to enhance mercury phytoremediation. Mercury pollution is a serious, world-wide problem affecting the health of human and wildlife populations. Environmentally, the most serious mercury threat is the production of methylmercury (CH3Hg+) by native bacteria at mercury contaminated wetland sites. Methylmercury is inherently more toxic than metallic (Hg(0)) or ionic (Hg(II)) mercury, and because methylmercury is prolifically biomagnified up the food chain, it poses the most immediate danger to animal populations. We have successfully engineered two model plants, Arabidopsis and tobacco, to use the bacterial merB gene to convert methylmercury to less toxic ionic mercury and to use the bacterial merA gene to further detoxify ionic mercury to the least toxic form of mercury, metallic mercury. Plants expressing both MerA and MerB proteins detoxify methylmercury in two steps to the metallic form. These plants germinate, grow, and set seed at normal growth rates on levels of methylmercury or ionic mercury that are lethal to normal plants. Our newest efforts involve engineering plants with several additional bacterial and plant genes that allow for higher levels of mercury resistance and mercury hyperaccumulation. The potential for these plants to hyperaccumulate mercury was further advanced by developing constitutive, aboveground, and root-specific gene expression systems. Our current strategy is to engineer plants to

  9. Fly ash properties and mercury sorbent affect mercury release from curing concrete

    SciTech Connect

    Danold W. Golightly; Chin-Min Cheng; Linda K. Weavers; Harold W. Walker; William E. Wolfe

    2009-04-15

    The release of mercury from concrete containing fly ashes from various generator boilers and powdered activated carbon sorbent used to capture mercury was measured in laboratory experiments. Release of gaseous mercury from these concretes was less than 0.31% of the total quantity of mercury present. The observed gaseous emissions of mercury during the curing process demonstrated a dependency on the organic carbon content of the fly ash, with mercury release decreasing with increasing carbon content. Further, lower gaseous emissions of mercury were observed for concretes incorporating ash containing activated carbon sorbent than would be expected based on the observed association with organic carbon, suggesting that the powdered activated carbon more tightly binds the mercury as compared to unburned carbon in the ash. Following the initial 28-day curing interval, mercury release diminished with time. In separate leaching experiments, average mercury concentrations leached from fly ash concretes were less than 4.1 ng/L after 18 h and 7 days, demonstrating that less than 0.02% of the mercury was released during leaching. 25 refs., 4 figs., 5 tabs.

  10. Final project report on arsenic biogeochemistry in the Clinch River and Watts Bar Reservoir: Volume 1, Main text. Environmental Restoration Program

    SciTech Connect

    Ford, C.J.; Byrd, J.T.; Grebmeier, J.M.; Harris, R.A.; Moore, R.C.; Madix, S.E.; Newman, K.A.; Rash, C.D.

    1995-04-01

    This document reports on the study of arsenic contamination in the Clinch River/Watts Bar Reservoir (CR/WBR) system, downstream from the US Department of Energy`s Oak Ridge Reservation (ORR). Arsenic is of particular interest and concern because it occurs commonly in coal-bearing rock and waste products, such as fly ash associated with the burning of coal; it is classified as a Class A carcinogen by the Environmental Protection Agency; and disposal of fly ash, both on and off the ORR, may have contaminated surface water and sediments in the Clinch River and Watts Bar Reservoir. Four main sites were sampled quarterly over a 3-year period. Sites investigated included lower Watts Bar Reservoir near Watts Bar Dam [Tennessee River kilometer (TRK) 849.6], the Kingston area [Clinch River kilometer (CRK) 1.6], Poplar Creek, and the McCoy Branch Embayment. Additional sites were investigated in the vicinity of these main stations to determine the distribution of contamination and to identify possible alternative or additional sources of arsenic.

  11. Mercury capture by aerosol transformation in combustion environments. Appendix 5

    SciTech Connect

    1997-02-01

    Aerosol transformation of elemental mercury by oxidizing mercury in the air is investigated in this study by varying temperature and residence time. The experimental results show that mercury oxidation is not important at the temperature range and time scale studied. The rate of mercury oxidation is too slow that the capture of mercury vapor by transforming it into mercury oxide in aerosol phase is not practical in real systems. Studies are needed for alternative approaches to capture mercury vapor such as the use of sorbent materials.

  12. Oak Ridge Moves Forward in Mercury Cleanup | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Moves Forward in Mercury Cleanup Oak Ridge Moves Forward in Mercury Cleanup March 28, 2013 - 12:00pm Addthis Workers recently removed five large mercury-contaminated tanks from Y-12. Workers recently removed five large mercury-contaminated tanks from Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. Workers recently removed five large mercury-contaminated tanks

  13. Treatment of mercury containing waste

    DOEpatents

    Kalb, Paul D.; Melamed, Dan; Patel, Bhavesh R; Fuhrmann, Mark

    2002-01-01

    A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

  14. Remediation of Mercury and Industrial Contaminants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Remediation of Mercury and Industrial Contaminants Remediation of Mercury and Industrial Contaminants The mission of the Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative is to control the flux of contaminants in soil and water environments for the purpose of protecting surface water, groundwater, and ecological receptors. Remediation of Mercury and Industrial Contaminants (1.7 MB) More Documents & Publications Mitigation and Remediation of Mercury

  15. Removal of mercury from waste gases

    SciTech Connect

    Muster, U.; Marr, R.; Pichler, G.; Kremshofer, S.; Wilferl, R.; Draxler, J.

    1996-12-31

    Waste and process gases from thermal power, incineration and metallurgical plants or those from cement and alkali chloride industries contain metallic, inorganic and organic mercury. Widespread processes to remove the major amount of mercury are absorption and adsorption. Caused by the lowering of the emission limit from 200 to 50 {mu}g/m{sup 3} [STP] by national and European legislators, considerable efforts were made to enhance the efficiency of the main separation units of flue gas cleaning plants. Specially impregnated ceramic carriers can be used for the selective separation of metallic, inorganic and organic mercury. Using the ceramic reactor removal rates lower than 5 {mu}g/m{sup 3} [STP] of gaseous mercury and its compounds can be achieved. The ceramic reactor is active, regenerable and stable for a long term operation. 4 refs., 7 figs.

  16. Mercury sorbent delivery system for flue gas

    DOEpatents

    Klunder; ,Edgar B.

    2009-02-24

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  17. Mercury Solar Systems | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    of PV products and systems for commercial and residential clients in the New York metrotri-state area. References: Mercury Solar Systems1 This article is a stub. You can...

  18. Innovative Mercury Treatment Benefits Stream, Fish

    Energy.gov [DOE]

    AIKEN, S.C. – A team of scientists is working at the Savannah River Site (SRS) to evaluate the impact of an innovative, inexpensive treatment system that removes mercury from water.

  19. Summary - Mitigation and Remediation of Mercury Contamination...

    Office of Environmental Management (EM)

    for adequacy in reducing Hg levels in the fish and to indentify opportunities to achieve ... contamination in the East Fork Popular Creek and how to reduce mercury levels in the fish. ...

  20. Analysis of Alternative Mercury Control Strategies

    Reports and Publications

    2005-01-01

    This analysis responds to a September 14, 2004, request from Chairmen James M. Inhofe and George V. Voinovich asking the Energy Information Administration (EIA) to analyze the impacts of different approaches for removing mercury from coal-fired power plants.

  1. The Mercury Export Ban Act of 2008...

    Office of Environmental Management (EM)

    Statement (Mercury Storage EIS) DOE Grand Junction Disposal Site, CO The Grand Junction Disposal Site is located on DOE-owned land, 18 miles southeast of Grand Junction, Colorado. ...

  2. Results of sediment and water sampling for inorganic, organic, and radionuclide analysis at recreation areas and water intakes -- Norris, Melton Hill, and Watts Bar Lakes. Data report

    SciTech Connect

    1991-10-01

    Suspected water quality contamination in Watts Bar Reservoir as a result of activities in past decades at the Department of Energy`s (DOE) Oak Ridge facility is of public concern. DOE, the Tennessee Valley Authority (TVA), the State of Tennessee, and other agencies and officials have received many inquiries from the public in recent years concerning this suspected pollution, especially how this potential contamination may affect the health and safety of those persons who use beaches in the area for swimming or other water-body-contact sports. As a result of these concerns, TVA conducted a study in May and June 1991 to obtain data on potential contaminants of concern in the water and sediment of Watts Bar Reservoir. TVA collected water and sediment samples at a total of 29 sites, including 18 recreation areas and 11 water intake locations, located throughout Norris, Melton Hill, and Watts Bar Reservoirs. The samples were analyzed for radionuclides, metals, and organic compounds which could pose a threat to human health.

  3. Mercury-metadata data management system

    Energy Science and Technology Software Center

    2008-01-03

    Mercury is a federated metadata harvesting, search and retrieval tool based on both open source software and software developed at Oak Ridge National Laboratory. It was originally developed for NASA, USGS, and DOE. A major new version of Mercury (version 3.0) was developed during 2007 and released in early 2008. This Mercury 3.0 version provides orders of magnitude improvements in search speed, support for additional metadata formats, integration with Google Maps for spatial queries, facettedmore » type search, support for RSS delivery of search results, and ready customization to meet the needs of the multiple projects which use Mercury. For the end users, Mercury provides a single portal to very quickly search for data and information contained in disparate data management systems. It collects metadata and key data from contributing project servers distributed around the world and builds a centralized index. The Mercury search interfaces then allow the users to perform simple, fielded, spatial, and temporal searches across these metadata sources. This centralized repository of metadata with distributed data sources provides extremely fast search results to the user, while allowing data providers to advertise the availability of their data and maintain complete control and ownership of that data.« less

  4. Mercury cleanup efforts intensify | Y-12 National Security Complex

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mercury cleanup efforts ... Mercury cleanup efforts intensify Posted: February 11, 2013 - 3:31pm | Y-12 Report | Volume 9, Issue 2 | 2013 Millions of pounds of mercury were required to support Y-12's post-World War II mission of separating lithium isotopes. Cleaning up the toxic heavy metal poses many challenges, but what Y-12 is learning could help conquer mercury pollution worldwide. There's a reason you won't find mercury in many thermometers these days. Mercury is a heavy metal that occurs

  5. Statute - Mercury Export Ban Act of 2008 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Services » Waste Management » Waste Disposition » Long-Term Management and Storage of Elemental Mercury is in the Planning Stages » Statute - Mercury Export Ban Act of 2008 Statute - Mercury Export Ban Act of 2008 Public Law 110-414, 110th Congress - Mercury Export Ban Act of 2008 to prohibit the sale, distribution, transfer, and export of elemental mercury, and for other purposes. Mercury Export Ban Act of 2008 (166.11 KB) More Documents & Publications Section 129 of the Consolidated

  6. Replacement of Lighting Fixtures with LED Energy Efficient Lights at the Parking Facility, Milwaukee, Wisconsin

    SciTech Connect

    David Brien

    2012-06-21

    The Forest County Potawatomi Community (FCPC or Tribe) owns a six-story parking facility adjacent to its Potawatomi Bingo Casino (the Casino) in Milwaukee, Wisconsin, as well as a valet parking facility under the Casino (collectively, the Parking Facility). The Parking Facility contained 205-watt metal halide-type lights that, for security reasons, operated 24 hours per day, 7 days per week. Starting on August 30, 2010, the Tribe replaced these fixtures with 1,760 state-of-the-art, energy efficient 55-Watt LED lights. This project resulted in an immediate average reduction in monthly peak demand of 238 kW over the fourth quarter of 2010. The average reduction in monthly peak demand from October 1 through December 31, 2010 translates into a forecast annual electrical energy reduction of approximately 1,995,000 kWh or 47.3% of the pre-project demand. This project was technically effective, economically feasible, and beneficial to the public not only in terms of long term energy efficiency and associated emissions reductions, but also in the short-term jobs provided for the S.E. Wisconsin region. The project was implemented, from approval by U.S. Department of Energy (DOE) to completion, in less than 6 months. The project utilized off-the-shelf proven technologies that were fabricated locally and installed by local trade contractors.

  7. Formation of soluble mercury oxide coatings: Transformation of elemental mercury in soils

    SciTech Connect

    Miller, Carrie L.; Watson, David B.; Lester, Brian P.; Howe, Jane Y.; Phillips, Debra H.; He, Feng; Liang, Liyuan; Pierce, Eric M.

    2015-09-21

    In this study, the impact of mercury (Hg) on human and ecological health has been known for decades. Although a treaty signed in 2013 by 147 nations regulates future large-scale mercury emissions, legacy Hg contamination exists worldwide and small-scale releases will continue. The fate of elemental mercury, Hg(0), lost to the subsurface and its potential chemical transformation that can lead to changes in speciation and mobility are poorly understood. Here, we show that Hg(0) beads interact with soil or manganese oxide solids and X-ray spectroscopic analysis indicates that the soluble mercury coatings are HgO. Dissolution studies show that, after reacting with a composite soil, >20 times more Hg is released into water from the coated beads than from a pure liquid mercury bead. An even larger, >700 times, release occurs from coated Hg(0) beads that have been reacted with manganese oxide, suggesting that manganese oxides are involved in the transformation of the Hg(0) beads and creation of the soluble mercury coatings. Although the coatings may inhibit Hg(0) evaporation, the high solubility of the coatings can enhance Hg(II) migration away from the Hg(0)-spill site and result in potential changes in mercury speciation in the soil and increased mercury mobility.

  8. Formation of soluble mercury oxide coatings: Transformation of elemental mercury in soils

    DOE PAGES [OSTI]

    Miller, Carrie L.; Watson, David B.; Lester, Brian P.; Howe, Jane Y.; Phillips, Debra H.; He, Feng; Liang, Liyuan; Pierce, Eric M.

    2015-09-21

    In this study, the impact of mercury (Hg) on human and ecological health has been known for decades. Although a treaty signed in 2013 by 147 nations regulates future large-scale mercury emissions, legacy Hg contamination exists worldwide and small-scale releases will continue. The fate of elemental mercury, Hg(0), lost to the subsurface and its potential chemical transformation that can lead to changes in speciation and mobility are poorly understood. Here, we show that Hg(0) beads interact with soil or manganese oxide solids and X-ray spectroscopic analysis indicates that the soluble mercury coatings are HgO. Dissolution studies show that, after reactingmore » with a composite soil, >20 times more Hg is released into water from the coated beads than from a pure liquid mercury bead. An even larger, >700 times, release occurs from coated Hg(0) beads that have been reacted with manganese oxide, suggesting that manganese oxides are involved in the transformation of the Hg(0) beads and creation of the soluble mercury coatings. Although the coatings may inhibit Hg(0) evaporation, the high solubility of the coatings can enhance Hg(II) migration away from the Hg(0)-spill site and result in potential changes in mercury speciation in the soil and increased mercury mobility.« less

  9. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect

    Sharon Sjostrom

    2005-12-30

    The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at Laramie River Station Unit 3, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program is to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL are to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the benchmark established by DOE of $60,000/lb mercury removed. The goals of the program were exceeded at Laramie River Station by achieving over 90% mercury removal at a sorbent cost of $3,980/lb ($660/oz) mercury removed for a coal mercury content of 7.9 lb/TBtu.

  10. Nucleotide sequence of a chromosomal mercury resistance determinant from a Bacillus sp. with broad-spectrum mercury resistance. [Mercury reductase

    SciTech Connect

    Wang, Y.; Levinson, H.S.; Mahler, I. ); Moore, M.; Walsh, C. ); Silver, S. )

    1989-01-01

    A 13.5-kilobase HindIII fragment, bearing an intact mercury resistance (mer) operon, was isolated from chromosomal DNA of broad-spectrum mercury-resistant Bacillus sp. strain RC607 by using as a probe a clone containing the mercury reductase (merA) gene. The new clone, pYW33, expressed broad-spectrum mercury resistance both in Escherichia coli and in Bacillus subtilis, but only in B. subtilis was the mercuric reductase activity inducible. Sequencing of a 1.8-kilobase mercury hypersensitivity-producing fragment revealed four open reading frames (ORFs). ORF1 may code for a regulatory protein (MerR). ORF2 and ORF4 were associated with cellular transport function and the hypersensitivity phenotype. DNA fragments encompassing the merA and the merB genes were sequenced. The predicted Bacillus sp. strain RC607 MerA (mercuric reductase) and MerB (organomercurial lyase) were similar to those predicted from Staphylococcus aureus plasmid pI258 (67 and 73% amino acid identities, respectively); however, only 40% of the amino acid residues of RC607 MerA were identical to those of the mercuric reductase from gram-negative bacteria. A 69-kilodalton polypeptide was isolated and identified as the merA gene product by examination of its amino-terminal sequence.

  11. VEE-0020- In the Matter of Mercury Fuel Service, Inc.

    Energy.gov [DOE]

    On April 9, 1996, Mercury Fuel Service, Inc. (Mercury) of Waterbury, Connecticut, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE)....

  12. Removal of mercury from coal via a microbial pretreatment process

    DOEpatents

    Borole, Abhijeet P.; Hamilton, Choo Y.

    2011-08-16

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  13. Long-Term Management and Storage of Elemental Mercury | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    from the United States as of January 1, 2013, the Mercury Export Ban Act of 2008 (MEBA) ... and 2 it will not sell, or otherwise place the elemental mercury into commerce. ...

  14. Operating Experience Level 3, Safe Management of Mercury | Department...

    Energy.gov [DOE] (indexed site)

    to raise awareness about mercury hazards and to reinforce the informaiton in Safety and Health Bulleting 2005-08, Safe Management of Mercury. OE-3 2012-03: Safe Management of...

  15. Technology Plan to Address the EM Mercury Challenge

    Office of Energy Efficiency and Renewable Energy (EERE)

    EM’s Technology Plan to Address the EM Mercury Challenge addresses mercury contamination, and advocates for research and technology development to resolve key technical uncertainties with the pollutant in environmental remediation, facility deactivation and decommissioning, and tank waste processing.

  16. What's A Watt Worth

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... a) False positive: Incorrectly mark an analyzed contingency as being secure where, a voltage drop on a transmission bus can cause tripping of DER, which causes an increase in load. ...

  17. Watts111.pdf

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Wattman_bio.pdf Wattman_bio.pdf (20.19 KB) More Documents & Publications Aviation Management Professional Award Nomination for: LopezPersonalProfile.pdf 2014 Federal Energy and Water Management Award Winner Posters

  18. Method and apparatus for dispensing small quantities of mercury from evacuated and sealed glass capsules

    DOEpatents

    Grossman, Mark W.; George, William A.; Pai, Robert Y.

    1985-01-01

    A technique for opening an evacuated and sealed glass capsule containing a material that is to be dispensed which has a relatively high vapor pressure such as mercury. The capsule is typically disposed in a discharge tube envelope. The technique involves the use of a first light source imaged along the capsule and a second light source imaged across the capsule substantially transversely to the imaging of the first light source. Means are provided for constraining a segment of the capsule along its length with the constraining means being positioned to correspond with the imaging of the second light source. These light sources are preferably incandescent projection lamps. The constraining means is preferably a multiple looped wire support.

  19. Method and apparatus for dispensing small quantities of mercury from evacuated and sealed glass capsules

    DOEpatents

    Grossman, M.W.; George, W.A.; Pai, R.Y.

    1985-08-13

    A technique is disclosed for opening an evacuated and sealed glass capsule containing a material that is to be dispensed which has a relatively high vapor pressure such as mercury. The capsule is typically disposed in a discharge tube envelope. The technique involves the use of a first light source imaged along the capsule and a second light source imaged across the capsule substantially transversely to the imaging of the first light source. Means are provided for constraining a segment of the capsule along its length with the constraining means being positioned to correspond with the imaging of the second light source. These light sources are preferably incandescent projection lamps. The constraining means is preferably a multiple looped wire support. 6 figs.

  20. CFD Modeling for Mercury Control Technology

    SciTech Connect

    Madsen, J.I.

    2006-12-01

    Compliance with the Clean Air Mercury Rule will require implementation of dedicated mercury control solutions at a significant portion of the U.S. coal-fired utility fleet. Activated Carbon Injection (ACI) upstream of a particulate control device (ESP or baghouse) remains one of the most promising near-term mercury control technologies. The DOE/NETL field testing program has advanced the understanding of mercury control by ACI, but a persistent need remains to develop predictive models that may improve the understanding and practical implementation of this technology. This presentation describes the development of an advanced model of in-flight mercury capture based on Computational Fluid Dynamics (CFD). The model makes detailed predictions of the induct spatial distribution and residence time of sorbent, as well as predictions of mercury capture efficiency for particular sorbent flow rates and injection grid configurations. Hence, CFD enables cost efficient optimization of sorbent injection systems for mercury control to a degree that would otherwise be impractical both for new and existing plants. In this way, modeling tools may directly address the main cost component of operating an ACI system the sorbent expense. A typical 300 MW system is expected to require between $1 and $2 million of sorbent per year, and so even modest reductions (say 10-20%) in necessary sorbent feed injection rates will quickly make any optimization effort very worthwhile. There are few existing models of mercury capture, and these typically make gross assumptions of plug gas flow, zero velocity slip between particle and gas phase, and uniform sorbent dispersion. All of these assumptions are overcome with the current model, which is based on first principles and includes mass transfer processes occurring at multiple scales, ranging from the large-scale transport in the duct to transport within the porous structure of a sorbent particle. In principle any single one of these processes

  1. DOE Issues Final Mercury Storage Environmental Impact Statement: Texas Site Is Preferred for Long-Term Mercury Storage

    Energy.gov [DOE]

    WASHINGTON – The Department of Energy has prepared a Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement to analyze the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven locations

  2. Commercial Lighting

    Energy.gov [DOE]

    Commercial lighting accounts for more than 20 percent of total commercial building energy use. The Energy Department works to reduce lighting energy use through research and deployment.

  3. Geochemical, Genetic, and Community Controls on Mercury

    SciTech Connect

    Wall, Judy D.

    2014-11-10

    The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

  4. Phytoremediation of ionic and methyl mercury pollution

    SciTech Connect

    Meagher, R.B.

    1998-06-01

    'The long-term objective of the research is to manipulate single-gene traits into plants, enabling them to process heavy metals and remediate heavy-metal pollution by resistance, sequestration, removal, and management of these contaminants. The authors are focused on mercury pollution as a case study of this plant genetic engineering approach. The working hypothesis behind this proposal was that transgenic plants expressing both the bacterial organo mercury lyase (merB) and the mercuric ion reductase gene (merA) will: (A) remove the mercury from polluted sites and (B) prevent methyl mercury from entering the food chain. The results from the research are so positive that the technology will undoubtedly be applied in the very near future to cleaning large mercury contaminates sites. Many such sites were not remediable previously due to the excessive costs and the negative environmental impact of conventional mechanical-chemical technologies. At the time this grant was awarded 20 months ago, the authors had successfully engineered a small model plant, Arabidopsis thaliana, to use a highly modified bacterial mercuric ion reductase gene, merA9, to detoxify ionic mercury (Hg(II)), reducing it to much less toxic and volatile metallic Hg(0) (Rugh et al., 1996). Seeds from these plants germinate, grow, and set seed at normal growth rates on levels of Hg(II) that are lethal to normal plants. In assays on transgenic seedlings suspended in a solution of Hg(II), 10 ng of Hg(0) was evolved per min per mg wet weight of plant tissue. At that time, the authors had no information on expression of merA in any other plant species, nor had the authors tested merB in any plant. However, the results were so startlingly positive and well received that they clearly presaged a paradigm shift in the field of environmental remediation.'

  5. Sorbents for the oxidation and removal of mercury

    DOEpatents

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John H.

    2008-10-14

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  6. Sorbents for the oxidation and removal of mercury

    DOEpatents

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

    2014-09-02

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  7. Sorbents for the oxidation and removal of mercury

    DOEpatents

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John H.

    2012-05-01

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  8. Method for high temperature mercury capture from gas streams

    DOEpatents

    Granite, Evan J.; Pennline, Henry W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  9. MERCURY CONTROL WITH ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect

    Ye Zhuang; Stanley J. Miller

    2005-05-01

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addressed Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and has been marketed as the Advanced Hybrid{trademark} filter by Gore. The Advanced Hybrid{trademark} filter combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The Advanced Hybrid{trademark} filter provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The Advanced Hybrid{trademark} filter also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the project was to demonstrate 90% total mercury control in the Advanced Hybrid{trademark} filter at a lower cost than current mercury control estimates. The approach included bench-scale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW (9000-acfm) scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control

  10. Safety Evaluation Report related to the operation of Watts Bar Nuclear Plant, Units 1 and 2 (Docket Nos. 50-390 and 50-391). Supplement No. 12

    SciTech Connect

    Tam, P.S.

    1993-10-01

    Supplement No. 12 to the Safety Evaluation Report for the application filed by the Tennessee Valley Authority for license to operate Watts Bar Nuclear Plant, Units 1 and 2, Docket Nos. 50-390 and 50-391, located in Rhea County, Tennessee, has been prepared by the Office of Nuclear Reactor Regulation of the Nuclear Regulatory Commission. The purpose of this supplement is to update the Safety Evaluation of (1) additional information submitted by the applicant since Supplement No. 11 was issued, and (2) matters that the staff had under review when Supplement No. 11 was issued.

  11. Safety evaluation report related to the operation of Watts Bar Nuclear Plant, Units 1 and 2 (Docket Nos. 50-390 and 50-391): Supplement No. 19

    SciTech Connect

    1995-11-01

    Supplement No. 19 to the Safety Evaluation Report for the application filed by the Tennessee Valley Authority for license to operate Watts Bar Nuclear Plant, Units 1 and 2, Docket Nos. 50-390 and 50-391, located in Rhea County Tennessee, has been prepared by the Office of Nuclear Reactor Regulation of the Nuclear Regulatory Commission. The purpose of this supplement is to update the Safety Evaluation with (1) additional information submitted by the applicant since Supplement No. 18 was issued, and (2) matters that the staff had under review when Supplement No. 18 was issued.

  12. Utility flue gas mercury control via sorbent injection

    SciTech Connect

    Chang, R.; Carey, T.; Hargrove, B.

    1996-12-31

    The potential for power plant mercury control under Title III of the 1990 Clean Air Act Amendments generated significant interest in assessing whether cost effective technologies are available for removing the mercury present in fossil-fired power plant flue gas. One promising approach is the direct injection of mercury sorbents such as activated carbon into flue gas. This approach has been shown to be effective for mercury control from municipal waste incinerators. However, tests conducted to date on utility fossil-fired boilers show that it is much more difficult to remove the trace species of mercury present in flue gas. EPRI is conducting research in sorbent mercury control including bench-scale evaluation of mercury sorbent activity and capacity with simulated flue gas, pilot testing under actual flue gas conditions, evaluation of sorbent regeneration and recycle options, and the development of novel sorbents. A theoretical model that predicts maximum mercury removals achievable with sorbent injection under different operating conditions is also being developed. This paper presents initial bench-scale and model results. The results to date show that very fine and large amounts of sorbents are needed for mercury control unless long residence times are available for sorbent-mercury contact. Also, sorbent activity and capacity are highly dependent on flue gas composition, temperature, mercury species, and sorbent properties. 10 refs., 4 figs., 2 tabs.

  13. FY09 assessment of mercury reduction at SNL/NM.

    SciTech Connect

    McCord, Samuel Adam

    2010-02-01

    This assessment takes the result of the FY08 performance target baseline of mercury at Sandia National Laboratories/New Mexico, and records the steps taken in FY09 to collect additional data, encourage the voluntary reduction of mercury, and measure success. Elemental (metallic) mercury and all of its compounds are toxic, and exposure to excessive levels can permanently damage or fatally injure the brain and kidneys. Elemental mercury can also be absorbed through the skin and cause allergic reactions. Ingestion of inorganic mercury compounds can cause severe renal and gastrointestinal damage. Organic compounds of mercury such as methyl mercury, created when elemental mercury enters the environment, are considered the most toxic forms of the element. Exposures to very small amounts of these compounds can result in devastating neurological damage and death.1 SNL/NM is required to report annually on the site wide inventory of mercury for the Environmental Protection Agency's (EPA) Toxics Release Inventory (TRI) Program, as the site's inventory is excess of the ten pound reportable threshold quantity. In the fiscal year 2008 (FY08) Pollution Prevention Program Plan, Section 5.3 Reduction of Environmental Releases, a performance target stated was to establish a baseline of mercury, its principle uses, and annual quantity or inventory. This was accomplished on July 29, 2008 by recording the current status of mercury in the Chemical Information System (CIS).

  14. Lighting system replacement brings energy costs down, light levels up

    SciTech Connect

    Radmer, D.J.

    1984-11-08

    The R.J. Frisby Mfg. Co. operates on three shifts and produces precision screw machine products for a variety of industries, including automotive, marine, machine tool, hydraulics and pneumatics, business machines, electrical and electronics, photography, and precision instruments. The required degree of manufacturing precision demands high light levels in manufacturing areas. When the 100,000 sq ft plant was built in 1973, mercury vapor lighting was installed consistent with the current state of the art for lighting such facilities. In the ensuing years, it became apparent that the soaring electric bills that came in the wake of the Arab oil embargo of 1973-74 would have to be controlled. Estimates by the U.S. Department of Energy indicated that electric energy costs were likely to rise by 160 percent over the next 10 yr. Based on this estimate, and the fact that lighting accounted for $70,000, or half of the annual electric bill, it was estimated that $900,000 to $1,000,000 would be spent for lighting energy over the next decade. The concern over the probability of rapidly escalating electrical costs was soon justified when, in three steps over one 12 mo period, the electric energy rate increased from $0.0305/kwh to $0.0416/kwh -more than a 36 percent increase. During that same period, the demand charge was raised in two steps from $3.75/kw to $4.85/kw --more than a 29 percent increase.

  15. Catalytic Reactor For Oxidizing Mercury Vapor

    DOEpatents

    Helfritch, Dennis J.

    1998-07-28

    A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

  16. Conceptual studies for a mercury target circuit

    SciTech Connect

    Sigg, B.

    1996-06-01

    For the now favored target design of the European Spallation Source project, i.e. the version using mercury as target material, a basic concept of the primary system has been worked out. It does not include a detailed design of the various components of the target circuit, but tries to outline a feasible solution for the system. Besides the removal of the thermal power of about 3MW produced in the target by the proton beam, the primary system has to satisfy a number of other requirements related to processing, safety, and operation. The basic proposal uses an electromagnetic pump and a mercury-water intermediate heat excanger, but other alternatives are also being discussed. Basic safety requirements, i.e. protection against radiation and toxic mercury vapours, are satisfied by a design using an air-tight primary system containment, double-walled tubes in the intermediate heat exchanger, a fail-safe system for decay heat removal, and a remote handling facility for the active part of the system. Much engineering work has still to be done, because many details of the design of the mercury and gas processing systems remain to be clarified, the thermal-hydraulic components need further optimisation, the system for control and instrumentation is only known in outline and a through safety analysis will be required.

  17. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect

    Sharon Sjostrom

    2008-06-30

    ADA-ES, Inc., with support from DOE/NETL, EPRI, and industry partners, studied mercury control options at six coal-fired power plants. The overall objective of the this test program was to evaluate the capabilities of activated carbon injection at six plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, American Electric Power's Conesville Station Unit 6, and Labadie Power Plant Unit 2. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The financial goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000 per pound of mercury removed. Results from testing at Holcomb, Laramie, Meramec, Labadie, and Monroe indicate the DOE goal was successfully achieved. However, further improvements for plants with conditions similar to Conesville are recommended that would improve both mercury removal performance and economics.

  18. Mercury Control with Calcium-Based Sorbents and Oxidizing Agents

    SciTech Connect

    Thomas K. Gale

    2005-07-01

    This Final Report contains the test descriptions, results, analysis, correlations, theoretical descriptions, and model derivations produced from many different investigations performed on a project funded by the U.S. Department of Energy, to investigate calcium-based sorbents and injection of oxidizing agents for the removal of mercury. Among the technologies were (a) calcium-based sorbents in general, (b) oxidant-additive sorbents developed originally at the EPA, and (c) optimized calcium/carbon synergism for mercury-removal enhancement. In addition, (d) sodium-tetrasulfide injection was found to effectively capture both forms of mercury across baghouses and ESPs, and has since been demonstrated at a slipstream treating PRB coal. It has been shown that sodium-tetrasulfide had little impact on the foam index of PRB flyash, which may indicate that sodium-tetrasulfide injection could be used at power plants without affecting flyash sales. Another technology, (e) coal blending, was shown to be an effective means of increasing mercury removal, by optimizing the concentration of calcium and carbon in the flyash. In addition to the investigation and validation of multiple mercury-control technologies (a through e above), important fundamental mechanism governing mercury kinetics in flue gas were elucidated. For example, it was shown, for the range of chlorine and unburned-carbon (UBC) concentrations in coal-fired utilities, that chlorine has much less effect on mercury oxidation and removal than UBC in the flyash. Unburned carbon enhances mercury oxidation in the flue gas by reacting with HCl to form chlorinated-carbon sites, which then react with elemental mercury to form mercuric chloride, which subsequently desorbs back into the flue gas. Calcium was found to enhance mercury removal by stabilizing the oxidized mercury formed on carbon surfaces. Finally, a model was developed to describe these mercury adsorption, desorption, oxidation, and removal mechanisms, including

  19. Removal of Mercury from Coal-Derived Synthesis Gas

    SciTech Connect

    2005-09-29

    A paper study was completed to survey literature, patents, and companies for mercury removal technologies applicable to gasification technologies. The objective was to determine if mercury emissions from gasification of coal are more or less difficult to manage than those from a combustion system. The purpose of the study was to define the extent of the mercury problem for gasification-based coal utilization and conversion systems. It is clear that in coal combustion systems, the speciation of mercury between elemental vapor and oxidized forms depends on a number of factors. The most important speciation factors are the concentration of chlorides in the coal, the temperatures in the ducting, and residence times. The collection of all the mercury was most dependent upon the extent of carbon in the fly ash, and the presence of a wet gas desulfurization system. In combustion, high chloride content plus long residence times at intermediate temperatures leads to oxidation of the mercury. The mercury is then captured in the wet gas desulfurization system and in the fly ash as HgCl{sub 2}. Without chloride, the mercury oxidizes much slower, but still may be trapped on thick bag house deposits. Addition of limestone to remove sulfur may trap additional mercury in the slag. In gasification where the mercury is expected to be elemental, activated carbon injection has been the most effective method of mercury removal. The carbon is best injected downstream where temperatures have moderated and an independent collector can be established. Concentrations of mercury sorbent need to be 10,000 to 20,000 the concentrations of the mercury. Pretreatment of the activated carbon may include acidification or promotion by sulfur.

  20. Oxidation of Mercury in Products of Coal Combustion

    SciTech Connect

    Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

    2009-09-14

    Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot

  1. In situ remediation technologies for mercury-contaminated soil

    DOE PAGES [OSTI]

    He, Feng; Gao, Jie; Pierce, Eric; Strong, P. J.; Wang, Hailong; Liang, Liyuan

    2015-04-09

    A pollutant that poses significant risks to humans and the environment is mercury from anthropogenic activities. In soils, mercury remediation can be technically challenging and costly, depending on the subsurface mercury distribution, the types of mercury species, and the regulatory requirements. Our paper introduces the chemistry of mercury and its implications for in situ mercury remediation, which is followed by a detailed discussion of several in situ Hg remediation technologies in terms of applicability, cost, advantages, and disadvantages. The effect of Hg speciation on remediation performance, as well as Hg transformation during different remediation processes, was detailed. Thermal desorption, electrokinetic,more » and soil flushing/washing treatments are removal technologies that mobilize and capture insoluble Hg species, while containment, solidification/stabilization, and vitrification immobilize Hg by converting it to less soluble forms. We also discussed two emerging technologies, phytoremediation and nanotechnology, in this review.« less

  2. Mercury Emissions Control Technologies (released in AEO2006)

    Reports and Publications

    2006-01-01

    The Annual Energy Outlook 2006 reference case assumes that states will comply with the requirements of the Environmental Protection Agency's new Clean Air Mercury Rule (CAMR) regulation. CAMR is a two-phase program, with a Phase I cap of 38 tons of mercury emitted from all U.S. power plants in 2010 and a Phase II cap of 15 tons in 2018. Mercury emissions in the electricity generation sector in 2003 are estimated at around 50 tons. Generators have a variety of options to meet the mercury limits, such as: switching to coal with a lower mercury content, relying on flue gas desulfurization or selective catalytic reduction equipment to reduce mercury emissions, or installing conventional activated carbon injection (ACI) technology.

  3. Mercury residues in south Florida apple snails (Pomacea paludosa)

    SciTech Connect

    Eisemann, J.D.; Beyer, W.N.; Morton, A.; Bennetts, R.E.

    1997-05-01

    Mercury concentrations in the sediments of south Florida wetlands have increased three fold in the last century. Because south Florida is home to many endemic and endangered species, it is important to understand the potential impacts of mercury in this ecosystem`s food web. Recent research by Malley et al. has shown mollusks to be sensitive indicators of methyl mercury which can reflect small differences in background methyl mercury concentrations. In this study, we attempted to determine if the apple snail (Pomacea paludosa) or its eggs are good indicators of bioavailable mercury. Then, using the apple snail as an indicator, we attempted to determine geographic differences in the concentrations of mercury in south Florida. 12 refs., 1 fig., 1 tab.

  4. In situ remediation technologies for mercury-contaminated soil

    SciTech Connect

    He, Feng; Gao, Jie; Pierce, Eric; Strong, P. J.; Wang, Hailong; Liang, Liyuan

    2015-04-09

    A pollutant that poses significant risks to humans and the environment is mercury from anthropogenic activities. In soils, mercury remediation can be technically challenging and costly, depending on the subsurface mercury distribution, the types of mercury species, and the regulatory requirements. Our paper introduces the chemistry of mercury and its implications for in situ mercury remediation, which is followed by a detailed discussion of several in situ Hg remediation technologies in terms of applicability, cost, advantages, and disadvantages. The effect of Hg speciation on remediation performance, as well as Hg transformation during different remediation processes, was detailed. Thermal desorption, electrokinetic, and soil flushing/washing treatments are removal technologies that mobilize and capture insoluble Hg species, while containment, solidification/stabilization, and vitrification immobilize Hg by converting it to less soluble forms. We also discussed two emerging technologies, phytoremediation and nanotechnology, in this review.

  5. Evaluation of mercury in the liquid waste processing facilities

    SciTech Connect

    Jain, Vijay; Shah, Hasmukh; Occhipinti, John E.; Wilmarth, William R.; Edwards, Richard E.

    2015-08-13

    This report provides a summary of Phase I activities conducted to support an Integrated Evaluation of Mercury in Liquid Waste System (LWS) Processing Facilities. Phase I activities included a review and assessment of the liquid waste inventory and chemical processing behavior of mercury using a system by system review methodology approach. Gaps in understanding mercury behavior as well as action items from the structured reviews are being tracked. 64% of the gaps and actions have been resolved.

  6. Thief carbon catalyst for oxidation of mercury in effluent stream

    DOEpatents

    Granite, Evan J.; Pennline, Henry W.

    2011-12-06

    A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

  7. Argonne/EPA system captures mercury from air in gold shops |...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Typical gold shop hood used to purify gold by superheating the goldmercury amalgam until the mercury vaporizes. The vaporized mercury is directed outside the shop into the open...

  8. Estimate of federal relighting potential and demand for efficient lighting products

    SciTech Connect

    Shankle, S.A.; Dirks, J.A.; Elliott, D.B.; Richman, E.E.; Grover, S.E.

    1993-11-01

    The increasing level of electric utility rebates for energy-efficient lighting retrofits has recently prompted concern over the adequacy of the market supply of energy-efficient lighting products (Energy User News 1991). In support of the U.S. Department of Energy`s Federal Energy Management Program, Pacific Northwest Laboratory (PNL) has developed an estimate of the total potential for energy-efficient lighting retrofits in federally owned buildings. This estimate can be used to address the issue of the impact of federal relighting projects on the supply of energy-efficient lighting products. The estimate was developed in 1992, using 1991 data. Any investments in energy-efficient lighting products that occurred in 1992 will reduce the potential estimated here. This analysis proceeds by estimating the existing stock of lighting fixtures in federally owned buildings. The lighting technology screening matrix is then used to determine the minimum life-cycle cost retrofit for each type of existing lighting fixture. Estimates of the existing stock are developed for (1) four types of fluorescent lighting fixtures (2-, 3-, and 4-lamp, F40 4-foot fixtures, and 2-lamp, F96 8-foot fixtures, all with standard magnetic ballasts); (2) one type of incandescent fixture (a 75-watt single bulb fixture); and (3) one type of exit sign (containing two 20-watt incandescent bulbs). Estimates of the existing stock of lighting fixtures in federally owned buildings, estimates of the total potential demand for energy-efficient lighting products if all cost-effective retrofits were undertaken immediately, and total potential annual energy savings (in MWh and dollars), the total investment required to obtain the energy savings and the present value of the efficiency investment, are presented.

  9. Mercury Vapor At Hualalai Northwest Rift Area (Thomas, 1986)...

    OpenEI (Open Energy Information) [EERE & EIA]

    The Hualalai lower northwest rift and southern flank were sampled for soil mercury concentration and radon emanation rates (Cox and Cuff, 1981d). The data generated by these...

  10. Mercury Vapor At Olowalu-Ukumehame Canyon Area (Thomas, 1986...

    OpenEI (Open Energy Information) [EERE & EIA]

    could be useful with more improvements DOE-funding Unknown Notes Soil mercury concentration and radon emanometry surveys were conducted along the stream beds in both Olowalu...

  11. Mercury Vapor At Lahaina-Kaanapali Area (Thomas, 1986) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Activity Date Usefulness not indicated DOE-funding Unknown Notes The soil mercury concentration and radon emanometry patterns observed for the Lahaina prospect were similar to...

  12. Removal of mercury from coal via a microbial pretreatment process...

    Office of Scientific and Technical Information (OSTI)

    The mercury can be recovered in pure form from the sorbents via additional processing. Inventors: Borole, Abhijeet P. 1 ; Hamilton, Choo Y. 1 + Show Author Affiliations ...

  13. Soil mercury investigations, Waunita Hot Springs | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Report: Soil mercury investigations, Waunita Hot Springs Authors C. D. Ringrose and R. H. Pearl Organization Colorado Geological Survey in Cooperation with the U.S. Department...

  14. Mercury Energy formerly Aquus Energy | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Energy formerly Aquus Energy Jump to: navigation, search Name: Mercury Energy (formerly Aquus Energy) Place: New Rochelle, New York Zip: 10801 Sector: Solar Product: Integrator of...

  15. Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) Exploration Activity Details Location...

  16. Mercury Vapor At Lualualei Valley Area (Thomas, 1986) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Exploration Activity Details Location...

  17. Mercury Vapor At Kawaihae Area (Thomas, 1986) | Open Energy Informatio...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location Kawaihae...

  18. Mercury Vapor At Mauna Loa Northeast Rift Area (Thomas, 1986...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mauna Loa Northeast Rift Area (Thomas, 1986) Exploration Activity Details...

  19. Mercury Vapor At Socorro Mountain Area (Kooten, 1987) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Socorro Mountain Area (Kooten, 1987) Exploration Activity Details Location...

  20. The mission of the Remediation of Mercury and Industrial

    Office of Environmental Management (EM)

    ... Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative Technical Working Group DOE End-Users ITRC, CABs, regulators and stakeholders Universities, ...

  1. Advanced Gasification Mercury/Trace Metal Control with Monolith...

    Office of Scientific and Technical Information (OSTI)

    control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center ...

  2. Mercury Vapor At Medicine Lake Area (Kooten, 1987) | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Medicine Lake Area (Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Medicine Lake Area (Kooten, 1987) Exploration...

  3. Mercury Vapor At Mccoy Geothermal Area (DOE GTP) | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Mccoy Geothermal Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mccoy Geothermal Area (DOE GTP) Exploration...

  4. Sorbents for the oxidation and removal of mercury (Patent) |...

    Office of Scientific and Technical Information (OSTI)

    The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. ...

  5. Thermally Speciated Mercury in Mineral Exploration | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Speciated Mercury in Mineral Exploration Abstract Abstract unavailable. Author S.C. Smith Conference IGES; Dublin, CA; 20030901 Published IGES, 2003 DOI Not Provided Check...

  6. Mercury Specie and Multi-Pollutant Control

    SciTech Connect

    Rob James; Virgil Joffrion; John McDermott; Steve Piche

    2010-05-31

    This project was awarded to demonstrate the ability to affect and optimize mercury speciation and multi-pollutant control using non-intrusive advanced sensor and optimization technologies. The intent was to demonstrate plant-wide optimization systems on a large coal fired steam electric power plant in order to minimize emissions, including mercury (Hg), while maximizing efficiency and maintaining saleable byproducts. Advanced solutions utilizing state-of-the-art sensors and neural network-based optimization and control technologies were proposed to maximize the removal of mercury vapor from the boiler flue gas thereby resulting in lower uncontrolled releases of mercury into the atmosphere. Budget Period 1 (Phase I) - Included the installation of sensors, software system design and establishment of the as-found baseline operating metrics for pre-project and post-project data comparison. Budget Period 2 (Phase II) - Software was installed, data communications links from the sensors were verified, and modifications required to integrate the software system to the DCS were performed. Budget Period 3 (Phase III) - Included the validation and demonstration of all control systems and software, and the comparison of the optimized test results with the targets established for the project site. This report represents the final technical report for the project, covering the entire award period and representing the final results compared to project goals. NeuCo shouldered 61% of the total project cost; while DOE shouldered the remaining 39%. The DOE requires repayment of its investment. This repayment will result from commercial sales of the products developed under the project. NRG's Limestone power plant (formerly owned by Texas Genco) contributed the host site, human resources, and engineering support to ensure the project's success.

  7. Determination of total mercury in sorbent tubes using direct mercury analysis

    SciTech Connect

    Nortje, J.

    2008-08-15

    A U.S. EPA draft method, Method 30 B, has been approved as a reference method for relative accuracy testing audits of Continuous Emissions Monitoring Systems (CEMS) and sorbent trap monitoring systems installed at coal-fired utilities. It is also appropriate for mercury emissions testing at such facilities. This method is a procedure for measuring total vapor phase mercury emissions from coal-fired combustion sources using all extractive or thermal analytical technique and UV atomic absorption (AA) or UV atomic fluorescence (AF) cold vapor analyzers as the analytical system. The DMA-80 direct mercury analyzer uses thermal decomposition and ultimately AA spectrophotometry to analyze samples. The analyzer can be used for Method 30 B analysis.

  8. Light Source

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    a Light Source Data and Analysis Framework at NERSC Jack Deslippe, Shane Canon, Eli Dart, Abdelilah Essiari, Alexander Hexemer, Dula Parkinson, Simon Patton, Craig Tull + Many More The ALS Data Needs September 21, 2010 - NIST (MD) Light source data volumes are growing many times faster than Moore's law. ● Light source luminosity ● Detector resolution & rep-rates ● Sample automation BES user facilities serve 10,000 scientists and engineers every year. Mostly composed of many small

  9. HISTORY OF MERCURY USE AND ENVIRONMENTAL CONTAMINATION

    SciTech Connect

    Brooks, Scott C; Southworth, George R

    2011-01-01

    Between 1950 and 1963 approximately 11 million kilograms of mercury (Hg) were used at the Oak Ridge Y-12 National Security Complex (Y-12 NSC) for lithium isotope separation processes. About 3% of the Hg was lost to the air, soil and rock under facilities, and East Fork Poplar Creek (EFPC) which originates in the plant site. Smaller amounts of Hg were used at other Oak Ridge facilities with similar results. Although the primary Hg discharges from Y-12 NSC stopped in 1963, small amounts of Hg continue to be released into the creek from point sources and diffuse contaminated soil and groundwater sources within Y-12 NSC. Mercury concentration in EFPC has decreased 85% from not, vert, similar2000 ng/L in the 1980s. In general, methylmercury concentrations in water and in fish have not declined in response to improvements in water quality and exhibit trends of increasing concentration in some cases.Mercury discharges from an industrial plant have created a legacy contamination problem exhibiting complex and at times counter-intuitive patterns in Hg cycling.

  10. Residential Lighting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    & Events Expand News & Events Skip navigation links Residential Residential Lighting Energy Star Appliances Consumer Electronics Heat Pump Water Heaters Electric Storage Water...

  11. Cerenkov Light

    SciTech Connect

    Slifer, Karl

    2013-06-13

    The bright blue glow from nuclear reactors is Cerenkov light. Karl Slifer describes how nuclear physicists can use this phenomenon to study the nucleus of the atom.

  12. Lighting Renovations

    Energy.gov [DOE]

    When undertaking a lighting renovation in a Federal building, daylighting is the primary renewable energy opportunity. Photovoltaics (PV) also present an excellent opportunity. While this guide...

  13. Cerenkov Light

    ScienceCinema

    Slifer, Karl

    2014-05-22

    The bright blue glow from nuclear reactors is Cerenkov light. Karl Slifer describes how nuclear physicists can use this phenomenon to study the nucleus of the atom.

  14. Analysis of Halogen-Mercury Reactions in Flue Gas

    SciTech Connect

    Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

    2010-01-01

    Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation

  15. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases

  16. Evaluation of Regenerated Catalyst for Mercury Speciation

    SciTech Connect

    Dennis Laudal

    2007-06-01

    In March of 2005, U.S. Environmental Protection Agency (EPA) promulgated the Clean Air Mercury Rule (CAMR). Mercury from coal-fired power plants was to be reduced from the current 48 to 38 tons/yr by 2010 and then 15 tons/yr by 2018. It is expected that the first phase reduction of {approx}21% will be achieved by cobenefits that will occur as a result of installing additional selective catalytic reduction (SCR) and flue gas desulfurization (FGD) systems to meet the new Clean Air Interstate Rule (CAIR). Detroit Edison (DTE) is installing SCR at all four units at its Monroe Station and will eventually install wet-FGD systems. As such, the Electric Power Research Institute (EPRI), the U.S. Department of Energy (DOE), and DTE have contracted with the Energy & Environmental Research Center (EERC) to determine the extent of mercury oxidation that occurs at Monroe Station. The EERC originally did mercury speciation sampling at Monroe Station in 2004 and then went back in 2005 to determine if any changes occurred as a result of catalyst aging. During the second test, in addition to measuring the mercury speciation at the inlet and outlet of the SCR, the EERC also completed sampling at a location between the catalyst layers. The results are shown in Table 1. In Table 1, the results show that {approx}40% of the Hg was in oxidized form (Hg{sup 2+}) at the inlet and nearly 100% Hg{sup 2+} at the outlet. The results at the midpoint were between 40% and 100%. As part of their overall strategy to reduce SCR costs, utilities and SCR vendors are attempting to regenerate catalyst layers that have degenerated over time. If these regenerated catalysts are used, the question remains as to the effect this process will have on the ability of these catalysts to oxidize mercury as well as reduce NO{sub x}. The current project is designed to measure the Hg speciation across an SCR using a regenerated catalyst. The results were compared to previous results to determine what, if any, changes

  17. Retention of elemental mercury in fly ashes in different atmospheres

    SciTech Connect

    M.A. Lopez-Anton; M. Diaz-Somoano; M.R. Martinez-Tarazona

    2007-01-15

    Mercury is an extremely volatile element, which is emitted from coal combustion to the environment mostly in the vapor phase. To avoid the environmental problems that the toxic species of this element may cause, control technologies for the removal of mercury are necessary. Recent research has shown that certain fly ash materials have an affinity for mercury. Moreover, it has been observed that fly ashes may catalyze the oxidation of elemental mercury and facilitate its capture. However, the exact nature of Hg-fly ash interactions is still unknown, and mercury oxidation through fly ash needs to be investigated more thoroughly. In this work, the influence of a gas atmosphere on the retention of elemental mercury on fly ashes of different characteristics was evaluated. The retention capacity was estimated comparatively in inert and two gas atmospheres containing species present in coal gasification and coal combustion. Fly ashes produced in two pulverized coal combustion (PCC) plants, produced from coals of different rank (CTA and CTSR), and a fly ash (CTP) produced in a fluidized bed combustion (FBC) plant were used as raw materials. The mercury retention capacity of these fly ashes was compared to the retention obtained in different activated carbons. Although the capture of mercury is very similar in the gasification atmosphere and N{sub 2}, it is much more efficient in a coal combustion retention, being greater in fly ashes from PCC than those from FBC plants. 22 refs., 6 figs., 3 tabs.

  18. Activated carbon injection - a mercury control success story

    SciTech Connect

    2008-07-01

    Almost 100 full-scale activated carbon injection (ACI) systems have been ordered by US electric utilities. These systems have the potential to remove over 90% of the mercury in flue, at a cost below $10,000 per pound of mercury removal. Field trials of ACI systems arm outlined. 1 fig.

  19. Mercury removal in utility wet scrubber using a chelating agent

    DOEpatents

    Amrhein, Gerald T.

    2001-01-01

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  20. PyMercury: Interactive Python for the Mercury Monte Carlo Particle Transport Code

    SciTech Connect

    Iandola, F N; O'Brien, M J; Procassini, R J

    2010-11-29

    Monte Carlo particle transport applications are often written in low-level languages (C/C++) for optimal performance on clusters and supercomputers. However, this development approach often sacrifices straightforward usability and testing in the interest of fast application performance. To improve usability, some high-performance computing applications employ mixed-language programming with high-level and low-level languages. In this study, we consider the benefits of incorporating an interactive Python interface into a Monte Carlo application. With PyMercury, a new Python extension to the Mercury general-purpose Monte Carlo particle transport code, we improve application usability without diminishing performance. In two case studies, we illustrate how PyMercury improves usability and simplifies testing and validation in a Monte Carlo application. In short, PyMercury demonstrates the value of interactive Python for Monte Carlo particle transport applications. In the future, we expect interactive Python to play an increasingly significant role in Monte Carlo usage and testing.

  1. Bench-scale studies with mercury contaminated SRS soil

    SciTech Connect

    Cicero, C.A.

    1996-05-08

    The Savannah River Technology Center (SRTC) has been charactered by the Department of Enregy (DOE) - Office of Technology Development (OTD) to investigate vitrification technology for the treatment of Low Level Mixed Wastes (LLMW). In fiscal year 1995, LLW streams containing mercury and organics were targeted. This report will present the results of studies with mercury contaminated waste. In order to successfully apply vitrification technology to LLMW, the types and quantities of glass forming additives necessary for producing homogeneous glasses from the wastes had to be determined, and the treatment for the mercury portion had to also be determined. The selected additives had to ensure that a durable and leach resistant waste form was produced, while the mercury treatment had to ensure that hazardous amounts of mercury were not released into the environment.

  2. Apparatus and method for removing mercury vapor from a gas stream

    DOEpatents

    Ganesan, Kumar

    2008-01-01

    A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

  3. Emissions of airborne toxics from coal-fired boilers: Mercury

    SciTech Connect

    Huang, H.S.; Livengood, C.D.; Zaromb, S.

    1991-09-01

    Concerns over emissions of hazardous air Pollutants (air toxics) have emerged as a major environmental issue, and the authority of the US Environmental Protection Agency to regulate such pollutants was greatly expanded through the Clean Air Act Amendments of 1990. Mercury has been singled out for particular attention because of concerns over possible effects of emissions on human health. This report evaluates available published information on the mercury content of coals mined in the United States, on mercury emitted in coal combustion, and on the efficacy of various environmental control technologies for controlling airborne emissions. Anthracite and bituminous coals have the highest mean-mercury concentrations, with subbituminous coals having the lowest. However, all coal types show very significant variations in mercury concentrations. Mercury emissions from coal combustion are not well-characterized, particularly with regard to determination of specific mercury compounds. Variations in emission rates of more than an order of magnitude have been reported for some boiler types. Data on the capture of mercury by environmental control technologies are available primarily for systems with electrostatic precipitators, where removals of approximately 20% to over 50% have been reported. Reported removals for wet flue-gas-desulfurization systems range between 35 and 95%, while spray-dryer/fabric-filter systems have given removals of 75 to 99% on municipal incinerators. In all cases, better data are needed before any definitive judgments can be made. This report briefly reviews several areas of research that may lead to improvements in mercury control for existing flue-gas-clean-up technologies and summarizes the status of techniques for measuring mercury emissions from combustion sources.

  4. Highly Automated Module Production Incorporating Advanced Light Management

    SciTech Connect

    Perelli-Minetti, Michael; Roof, Kyle

    2015-08-11

    The objective was to enable a high volume, cost effective solution for increasing the amount of light captured by PV modules through utilization of an advanced Light Re-directing Film and to follow a phased approach to develop and implement this new technology in order to achieve an expected power gain of up to 12 watts per module. Full size PV modules were manufactured using a new Light Redirecting Film (LRF) material applied to two different areas of PV modules in order to increase the amount of light captured by the modules. One configuration involved applying thin strips of LRF film over the tabbing ribbon on the cells in order to redirect the light that is normally absorbed by the tabbing ribbon to the active areas of the cells. A second configuration involved applying thin strips of LRF film over the white spaces between cells within a module in order to capture some of the light that is normally reflected from the white areas back through the front glass of the modules. Significant power increases of 1.4% (3.9 watts) and 1.0% (3.2 watts), respectively, compared to standard PV modules were measured under standard test conditions. The performance of PV modules with LRF applied to the tabbing ribbon was modeled. The results showed that the power increase provided by LRF depended greatly on the angle of incident light with the optimum performance only occurring when the light was within a narrow range of being perpendicular to the solar module. The modeling showed that most of the performance gain would be lost when the angle of incident light was greater than 28 degrees off axis. This effect made the orientation of modules with LRF applied to tabbing ribbons very important as modules mounted in “portrait” mode were predicted to provide little to no power gain from LRF under real world conditions. Based on these results, modules with LRF on tabbing ribbons would have to be mounted in “landscape” mode to realize a performance advantage. In addition

  5. Environmental release of mercury from coal utilization by-products: will new mercury controls at power plants make a difference?

    SciTech Connect

    Aljoe, W.W.; Feeley, T.J., III; Brickett, L.A.; Schroeder, K.T.; Murphy, J.T. [National Energy Technology Laboratory, Pittsburgh, PA (US)

    2005-09-30

    The US Department of Energy's National Energy Technology Laboratory (DOE/NETL) uses the term coal utilization by-products (CUBs) to describe the solid materials produced by the combustion or gasification of coal. The following general observations can be drawn from results of field tests that have been carried out thus far to determine whether new technologies for mercury emission control at coal power plants will affect the release of mercury from CUBs. There appears to be only minimal potential mercury release to the environment in typical disposal or utilization application for CUBs generated using ACI control technologies. There appears to be only minimal mercury release to the environment for CUBs generated using wet FGD control technologies. The amount of mercury leached from CUBs samples tested is significantly lower than the federal drinking water standards and water quality criteria for the protection of aquatic life. 3 figs., 2 tabs.

  6. JV Task 5 - Evaluation of Residual Oil Fly Ash As A Mercury Sorbent For Coal Combustion Flue Gas

    SciTech Connect

    Robert Patton

    2006-12-31

    The mercury adsorption capacity of a residual oil fly ash (ROFA) sample collected form Florida Power and Light Company's Port Everglades Power Plant was evaluated using a bituminous coal combustion flue gas simulator and fixed-bed testing protocol. A size-segregated (>38 {micro}g) fraction of ROFA was ground to a fine powder and brominated to potentially enhance mercury capture. The ROFA and brominated-ROFA were ineffective in capturing or oxidizing the Hg{sup 0} present in a simulated bituminous coal combustion flue gas. In contrast, a commercially available DARCO{reg_sign} FGD initially adsorbed Hg{sup 0} for about an hour and then catalyzed Hg{sup 0} oxidation to produce Hg{sup 2+}. Apparently, the unburned carbon in ROFA needs to be more rigorously activated in order for it to effectively capture and/or oxidize Hg{sup 0}.

  7. Light weight radioisotope heater unit (LWRHU) production for the Cassini mission

    SciTech Connect

    Rinehart, G.H.

    1997-01-01

    The Light-Weight Radioisotope Heater Unit (LWRHU) is a [sup 238]PuO[sub 2] fueled heat source designed to provide one thermal watt in each of various locations on a spacecraft. The heat sources are required to maintain the temperature of specific components within normal operating ranges. The heat source consists of a hot- pressed [sup 238]PuO[sub 2] fuel pellet, a Pt-3ORh vented capsule, a pyrolytic graphite insulator, and a woven graphite aeroshell assembly. Los Alamos National Laboratory has fabricated 180 heat sources, 157 of which will be used on the Cassini mission.

  8. FINAL REPORT ON THE AQUATIC MERCURY ASSESSMENT STUDY

    SciTech Connect

    Halverson, N

    2008-09-30

    In February 2000, the United States Environmental Protection Agency (EPA) Region 4 issued a proposed Total Maximum Daily Load (TMDL) for total mercury in the middle and lower Savannah River. The initial TMDL, which would have imposed a 1 ng/l mercury limit for discharges to the middle/lower Savannah River, was revised to 2.8 ng/l in the final TMDL released in February 2001. The TMDL was intended to protect people from the consumption of contaminated fish, which is the major route of mercury exposure to humans. The most bioaccumulative form of mercury is methylmercury, which is produced in aquatic environments by the action of microorganisms on inorganic mercury. Because of the environmental and economic significance of the mercury discharge limits that would have been imposed by the TMDL, the Savannah River Site (SRS) initiated several studies concerning: (1) mercury in SRS discharges, SRS streams and the Savannah River, (2) mercury bioaccumulation factors for Savannah River fish, (3) the use of clams to monitor the influence of mercury from tributary streams on biota in the Savannah River, and (4) mercury in rainwater falling on the SRS. The results of these studies are presented in detail in this report. The first study documented the occurrence, distribution and variation of total and methylmercury at SRS industrial outfalls, principal SRS streams and the Savannah River where it forms the border with the SRS. All of the analyses were performed using the EPA Method 1630/31 ultra low-level and contaminant-free techniques for measuring total and methylmercury. Total mercury at National Pollutant Discharge Elimination System (NPDES) outfalls ranged from 0.31-604 ng/l with a mean of 8.71 ng/l. Mercury-contaminated groundwater was the source for outfalls with significantly elevated mercury concentrations. Total mercury in SRS streams ranged from 0.95-15.7 ng/l. Mean total mercury levels in the streams varied from 2.39 ng/l in Pen Branch to 5.26 ng/l in Tims Branch

  9. BEHAVIOR OF MERCURY DURING DWPF CHEMICAL PROCESS CELL PROCESSING

    SciTech Connect

    Zamecnik, J.; Koopman, D.

    2012-04-09

    The Defense Waste Processing Facility has experienced significant issues with the stripping and recovery of mercury in the Chemical Processing Cell (CPC). The stripping rate has been inconsistent, often resulting in extended processing times to remove mercury to the required endpoint concentration. The recovery of mercury in the Mercury Water Wash Tank has never been high, and has decreased significantly since the Mercury Water Wash Tank was replaced after the seventh batch of Sludge Batch 5. Since this time, essentially no recovery of mercury has been seen. Pertinent literature was reviewed, previous lab-scale data on mercury stripping and recovery was examined, and new lab-scale CPC Sludge Receipt and Adjustment Tank (SRAT) runs were conducted. For previous lab-scale data, many of the runs with sufficient mercury recovery data were examined to determine what factors affect the stripping and recovery of mercury and to improve closure of the mercury material balance. Ten new lab-scale SRAT runs (HG runs) were performed to examine the effects of acid stoichiometry, sludge solids concentration, antifoam concentration, form of mercury added to simulant, presence of a SRAT heel, operation of the SRAT condenser at higher than prototypic temperature, varying noble metals from none to very high concentrations, and higher agitation rate. Data from simulant runs from SB6, SB7a, glycolic/formic, and the HG tests showed that a significant amount of Hg metal was found on the vessel bottom at the end of tests. Material balance closure improved from 12-71% to 48-93% when this segregated Hg was considered. The amount of Hg segregated as elemental Hg on the vessel bottom was 4-77% of the amount added. The highest recovery of mercury in the offgas system generally correlated with the highest retention of Hg in the slurry. Low retention in the slurry (high segregation on the vessel bottom) resulted in low recovery in the offgas system. High agitation rates appear to result in lower

  10. Commercial Lighting and LED Lighting Incentives | Department...

    Energy.gov [DOE] (indexed site)

    Schools Institutional Savings Category Lighting Lighting ControlsSensors Other EE LED Lighting Maximum Rebate Up to 100% of cost; incentives that exceed 5,000 should be...

  11. Light's Darkness

    ScienceCinema

    Padgett, Miles [University of Glasgow, Glasgow, Scotland

    2016-07-12

    Optical vortices and orbital angular momentum are currently topical subjects in the optics literature. Although seemingly esoteric, they are, in fact, the generic state of light and arise whenever three or more plane waves interfere. To be observed by eye the light must be monochromatic. Laser speckle is one such example, where the optical energy circulates around each black spot, giving a local orbital angular momentum. This talk with report three on-going studies. First, when considering a volume of interfering waves, the laser specs map out threads of complete darkness embedded in the light. Do these threads form loops? Links? Or even knots? Second, when looking through a rapidly spinning window, the image of the world on the other side is rotated: true or false? Finally, the entanglement of orbital angular momentum states means measuring how the angular position of one photons sets the angular momentum of another: is this an angular version of the EPR (Einstein, Podolsky, and Rosen) paradox?

  12. Design of polarizers for a mega-watt long-pulse millimeter-wave transmission line on the large helical device

    SciTech Connect

    Ii, T. Kubo, S.; Shimozuma, T.; Kobayashi, S.; Okada, K.; Yoshimura, Y.; Igami, H.; Takahashi, H.; Ito, S.; Mizuno, Y.; Okada, K.; Mutoh, T.; Makino, R.; Kobayashi, K.; Goto, Y.

    2015-02-15

    The polarizer is one of the critical components in a high-power millimeter-wave transmission line. It requires full and highly efficient coverage of any polarization states, high-power tolerance, and low-loss feature. Polarizers with rounded shape at the edge of the periodic groove surface are designed and fabricated by the machining process for a mega-watt long-pulse millimeter-wave transmission line of the electron cyclotron resonance heating system in the large helical device. The groove shape of λ/8- and λ/4-type polarizers for an 82.7 GHz transmission line is optimally designed in an integral method developed in the vector theories of diffraction gratings so that the efficiency to realize any polarization state can be maximized. The dependence of the polarization states on the combination of the two polarizer rotation angles (Φ{sub λ/8}, Φ{sub λ/4}) is examined experimentally in a low-power test with the newly developed polarization monitor. The results show that the measured polarization characteristics are in good agreement with the calculated ones.

  13. Fluorescence dye tagging scheme for mercury quantification and speciation

    DOEpatents

    Jiao, Hong; Catterall, Hannah

    2015-09-22

    A fluorescent dye or fluorophore capable of forming complexes with mercury comprises 6,8-difluoro-7-hydroxy-2-oxo-2H-chromene-3-carboxylate amide, wherein the amide is formed by reacting the succinimidyl ester (Pacific Blue.TM.) with an amino acid containing a thiol group, such as cysteine or glutathione. Mercury complexes of the fluorophore fluoresce when excited by a UV or violet laser diode, and the detected intensity can be calibrated to quantify the concentration of mercury in a sample reacted with the fluorophore.

  14. Demonstration of Mer-Cure Technology for Enhanced Mercury Control

    SciTech Connect

    John Marion; Dave O'Neill; Kevin Taugher; Shin Kang; Mark Johnson; Gerald Pargac; Jane Luedecke; Randy Gardiner; Mike Silvertooth; Jim Hicks; Carl Edberg; Ray Cournoyer; Stanley Bohdanowicz; Ken Peterson; Kurt Johnson; Steve Benson; Richard Schulz; Don McCollor; Mike Wuitshick

    2008-06-01

    Alstom Power Inc. has completed a DOE/NETL-sponsored program (under DOE Cooperative Agreement No. De-FC26-07NT42776) to demonstrate Mer-Cure{trademark}, one of Alstom's mercury control technologies for coal-fired boilers. The Mer-Cure{trademark}system utilizes a small amount of Mer-Clean{trademark} sorbent that is injected into the flue gas stream for oxidation and adsorption of gaseous mercury. Mer-Clean{trademark} sorbents are carbon-based and prepared with chemical additives that promote oxidation and capture of mercury. The Mer-Cure{trademark} system is unique in that the sorbent is injected into an environment where the mercury capture kinetics is accelerated. The full-scale demonstration program originally included test campaigns at two host sites: LCRA's 480-MW{sub e} Fayette Unit No.3 and Reliant Energy's 190-MW{sub e} Shawville Unit No.3. The only demonstration tests actually done were the short-term tests at LCRA due to budget constraints. This report gives a summary of the demonstration testing at Fayette Unit No.3. The goals for this Mercury Round 3 program, established by DOE/NETL under the original solicitation, were to reduce the uncontrolled mercury emissions by 90% at a cost significantly less than 50% of the previous target of $60,000/lb mercury removed. The results indicated that Mer-Cure{trademark} technology could achieve mercury removal of 90% based on uncontrolled stack emissions. The estimated costs for 90% mercury control, at a sorbent cost of $0.75 to $2.00/lb respectively, were $13,400 to $18,700/lb Hg removed. In summary, the results from demonstration testing show that the goals established by DOE/NETL were met during this test program. The goal of 90% mercury reduction was achieved. Estimated mercury removal costs were 69-78% lower than the benchmark of $60,000/lb mercury removed, significantly less than 50% of the baseline removal cost.

  15. Advanced Utility Mercury-Sorbent Field-Testing Program

    SciTech Connect

    Ronald Landreth

    2007-12-31

    This report summarizes the work conducted from September 1, 2003 through December 31, 2007 on the project entitled Advanced Utility Mercury-Sorbent Field-Testing Program. The project covers the testing at the Detroit Edison St. Clair Plant and the Duke Power Cliffside and Buck Stations. The St. Clair Plant used a blend of subbituminous and bituminous coal and controlled the particulate emissions by means of a cold-side ESP. The Duke Power Stations used bituminous coals and controlled their particulate emissions by means of hot-side ESPs. The testing at the Detroit Edison St. Clair Plant demonstrated that mercury sorbents could be used to achieve high mercury removal rates with low injection rates at facilities that burn subbituminous coal. A mercury removal rate of 94% was achieved at an injection rate of 3 lb/MMacf over the thirty day long-term test. Prior to this test, it was believed that the mercury in flue gas of this type would be the most difficult to capture. This is not the case. The testing at the two Duke Power Stations proved that carbon- based mercury sorbents can be used to control the mercury emissions from boilers with hot-side ESPs. It was known that plain PACs did not have any mercury capacity at elevated temperatures but that brominated B-PAC did. The mercury removal rate varies with the operation but it appears that mercury removal rates equal to or greater than 50% are achievable in facilities equipped with hot-side ESPs. As part of the program, both sorbent injection equipment and sorbent production equipment was acquired and operated. This equipment performed very well during this program. In addition, mercury instruments were acquired for this program. These instruments worked well in the flue gas at the St. Clair Plant but not as well in the flue gas at the Duke Power Stations. It is believed that the difference in the amount of oxidized mercury, more at Duke Power, was the difference in instrument performance. Much of the equipment was

  16. Operating temperatures for a convectively cooled recessed incandescent light fixture

    SciTech Connect

    Yarbrough, D.W.; Toor, I.

    1980-12-01

    Test results are given for the operation of a recessed incandescent light fixture intended for residential use. The fixture is labeled for use in direct contact with attic thermal insulation. Temperature control of the powered fixture is provided by convective heat transfer from the ceiling side of the fixture. The fixture was operated at power levels up to two times the rated power of 75 watts and under thermal insulations up to R-40. In all operating configurations tested the fixture surface in contact with attic insulation was found to be less than 175/sup 0/C. The observed surface temperatures are judged to be safe for operation in contact with loose-fill or batt-type insulations. It was observed that the power leads inside one fixture configuration are exposed to temperatures as high as 168/sup 0/C. The electrical insulation could, therefore, have a limited life. The properties of the internal fixture wiring were not, however, studied in detail.

  17. Thermodynamics in variable speed of light theories

    SciTech Connect

    Racker, Juan [CONICET, Centro Atomico Bariloche, Avenida Bustillo 9500 (8400), San Carlos De Bariloche (Argentina); Facultad de Ciencias Astronomicas y Geofisicas, Universidad Nacional de La Plata, Paseo del Bosque S/N (1900), La Plata (Argentina); Sisterna, Pablo [Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes 3350 (7600), Mar del Plata (Argentina); Vucetich, Hector [Facultad de Ciencias Astronomicas y Geofisicas, Universidad Nacional de La Plata, Paseo del Bosque S/N (1900), La Plata (Argentina)

    2009-10-15

    The perfect fluid in the context of a covariant variable speed of light theory proposed by J. Magueijo is studied. On the one hand the modified first law of thermodynamics together with a recipe to obtain equations of state are obtained. On the other hand the Newtonian limit is performed to obtain the nonrelativistic hydrostatic equilibrium equation for the theory. The results obtained are used to determine the time variation of the radius of Mercury induced by the variability of the speed of light (c), and the scalar contribution to the luminosity of white dwarfs. Using a bound for the change of that radius and combining it with an upper limit for the variation of the fine structure constant, a bound on the time variation of c is set. An independent bound is obtained from luminosity estimates for Stein 2015B.

  18. ALTERNATIVE FIELD METHODS TO TREAT MERCURY IN SOIL

    SciTech Connect

    Ernest F. Stine Jr; Steven T. Downey

    2002-08-14

    U.S. Department of Energy (DOE) used large quantities of mercury in the uranium separating process from the 1950s until the late 1980s in support of national defense. Some of this mercury, as well as other hazardous metals and radionuclides, found its way into, and under, several buildings, soil and subsurface soils and into some of the surface waters. Several of these areas may pose potential health or environmental risks and must be dealt with under current environmental regulations. DOE's National Energy Technology Laboratory (NETL) awarded a contract ''Alternative Field Methods to Treat Mercury in Soil'' to IT Group, Knoxville TN (IT) and its subcontractor NFS, Erwin, TN to identify remedial methods to clean up mercury-contaminated high-clay content soils using proven treatment chemistries. The sites of interest were the Y-12 National Security Complex located in Oak Ridge, Tennessee, the David Witherspoon properties located in Knoxville, Tennessee, and at other similarly contaminated sites. The primary laboratory-scale contract objectives were (1) to safely retrieve and test samples of contaminated soil in an approved laboratory and (2) to determine an acceptable treatment method to ensure that the mercury does not leach from the soil above regulatory levels. The leaching requirements were to meet the TC (0.2 mg/l) and UTS (0.025 mg/l) TCLP criteria. In-situ treatments were preferred to control potential mercury vapors emissions and liquid mercury spills associated with ex-situ treatments. All laboratory work was conducted in IT's and NFS laboratories. Mercury contaminated nonradioactive soil from under the Alpha 2 building in the Y-12 complex was used. This soils contained insufficient levels of leachable mercury and resulted in TCLP mercury concentrations that were similar to the applicable LDR limits. The soil was spiked at multiple levels with metallic (up to 6000 mg/l) and soluble mercury compounds (up to 500 mg/kg) to simulate expected ranges of mercury

  19. Mercury Vapor At Kilauea East Rift Area (Thomas, 1986) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    located within the rift zone, but an analysis of the data showed that soil type and soil pH also had a marked impact on mercury concentration. Making corrections for these effects...

  20. Advanced Gasification Mercury/Trace Metal Control with Monolith...

    Office of Scientific and Technical Information (OSTI)

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400F and pressure of 600 ...

  1. Mercury Contents of Natural Thermal and Mineral Fluids, In- U...

    OpenEI (Open Energy Information) [EERE & EIA]

    Paper 713 Jump to: navigation, search OpenEI Reference LibraryAdd to library Book Section: Mercury Contents of Natural Thermal and Mineral Fluids, In- U.S. Geological...

  2. Surface Mercury Geochemistry As A Guide To Volcanic Vent Structure...

    OpenEI (Open Energy Information) [EERE & EIA]

    Mercury Geochemistry As A Guide To Volcanic Vent Structure And Zones Of High Heat Flow In The Valley Of Ten Thousand Smokes, Katmai National Park, Alaska Jump to: navigation,...

  3. Fly Ash and Mercury Oxidation/Chlorination Reactions

    SciTech Connect

    Sukh Sidhu; Patanjali Varanasi

    2008-12-31

    Mercury is a known pollutant that has detrimental effect on human health and environment. The anthropogenic emissions of mercury account for 10 to 30% of worldwide mercury emissions. There is a need to control/reduce anthropogenic mercury emissions. Many mercury control technologies are available but their effectiveness is dependent on the chemical form of mercury, because different chemical forms of mercury have different physical and chemical properties. Mercury leaves the boiler in its elemental form but goes through various transformations in the post-combustion zone. There is a need to understand how fly ash and flue gas composition affect speciation, partitioning, and reactions of mercury under the full range of post-combustion zone conditions. This knowledge can then be used to predict the chemical transformation of mercury (elemental, oxidized or particulate) in the post combustion zone and thus help with the control of mercury emissions from coal-burning power plants. To accomplish this goal present study was conducted using five coal fly ashes. These ashes were characterized and their catalytic activity was compared under selected reaction conditions in a fixed bed reactor. Based on the results from these fly ash experiments, three key components (carbon, iron oxide and calcium oxide) were chosen. These three components were then used to prepare model fly ashes. Silica/alumina was used as a base for these model fly ashes. One, two or three component model fly ashes were then prepared to investigate mercury transformation reactions. The third set of experiments was performed with CuO and CuCl2 catalysts to further understand the mercury oxidation process. Based on the results of these three studies the key components were predicted for different fly ash compositions under variety of flue gas conditions. A fixed bed reactor system was used to conduct this study. In all the experiments, the inlet concentration of Hg0(g) was maintained at 35 {micro}g/m3 using

  4. Multiple Species of Bacteria Convert Elemental Mercury to Toxic...

    Office of Science (SC)

    Researchers are studying how bacteria transform mercury into a toxic form in the environment that can accumulate in the food web, posing a threat to wildlife and people. The ...

  5. National Lighting Energy Consumption

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Lighting Energy National Lighting Energy Consumption Consumption 390 Billion kWh used for lighting in all 390 Billion kWh used for lighting in all commercial buildings in commercial buildings in 2001 2001 LED (<.1% ) Incandescent 40% HID 22% Fluorescent 38% Lighting Energy Consumption by Lighting Energy Consumption by Breakdown of Lighting Energy Breakdown of Lighting Energy Major Sector and Light Source Type Major Sector and Light Source Type Source: Navigant Consulting, Inc., U.S. Lighting

  6. Electrolytic recovery of mercury enriched in isotopic abundance

    DOEpatents

    Grossman, Mark W.

    1991-01-01

    The present invention is directed to a method of electrolytically extracting liquid mercury from HgO or Hg.sub.2 Cl.sub.2. Additionally there are disclosed two related techniques associated with the present invention, namely (1) a technique for selectively removing product from different regions of a long photochemical reactor (photoreactor) and (2) a method of accurately measuring the total quantity of mercury formed as either HgO or Hg.sub.2 Cl.sub.2.

  7. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; MILIAN, L.; LIPFERT, F.; SUBRAMANIAM, S.; BLAKE, R.

    2005-09-21

    Mercury is a neurotoxin that accumulates in the food chain and is therefore a health concern. The primary human exposure pathway is through fish consumption. Coal-fired power plants emit mercury and there is uncertainty over whether this creates localized hot spots of mercury leading to substantially higher levels of mercury in water bodies and therefore higher exposure. To obtain direct evidence of local deposition patterns, soil and vegetations samples from around three U.S. coal-fired power plants were collected and analyzed for evidence of hot spots and for correlation with model predictions of deposition. At all three sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. It was estimated that less than 2% of the total mercury emissions from these plants deposited within 15 km of these plants. These small percentages of deposition are consistent with the literature review findings of only minor perturbations in environmental levels, as opposed to hot spots, near the plants. The major objective of the sampling studies was to determine if there was evidence for hot spots of mercury deposition around coal-fired power plants. From a public health perspective, such a hot spot must be large enough to insure that it did not occur by chance, and it must increase mercury concentrations to a level in which health effects are a concern in a water body large enough to support a population of subsistence fishers. The results of this study suggest that neither of these conditions has been met.

  8. Geological and Anthropogenic Factors Influencing Mercury Speciation in Mine

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Wastes Geological and Anthropogenic Factors Influencing Mercury Speciation in Mine Wastes Christopher S. Kim,1 James J. Rytuba,2 Gordon E. Brown, Jr.3 1Department of Physical Sciences, Chapman University, Orange, CA 92866 2U.S. Geological Survey, Menlo Park, CA 94025 3Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305 Introduction Figure 1. Dr. Christopher Kim collects a mine waste sample from the Oat Hill mercury mine in Northern California. The

  9. Mercury Speciation in Piscivorous Fish from Mining-impacted Reservoirs

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mercury Speciation in Piscivorous Fish from Mining-impacted Reservoirs Mercury toxicity generates environmental concerns in diverse aquatic systems because methylmercury enters the water column in diverse ways then biomagnifies through food webs. At the apex of many freshwater food webs, piscivorous fish can then extend that trophic transfer and potential for neurotoxicity to wildlife and humans. Mining activities, particularly those associated with the San Francisco Bay region, can generate

  10. Thiacrown polymers for removal of mercury from waste streams

    DOEpatents

    Baumann, Theodore F.; Reynolds, John G.; Fox, Glenn A.

    2004-02-24

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  11. DOE Interim Guidance on Mercury Management Procedures and Standards

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE, in consultation with the USEPA and State agencies, prepared this guidance on packaging, transportation, receipt, management, and long-term storage of elemental mercury at a DOE facility or facilities as mandated by the MEBA (the Act). This guidance document establishes basic standards and procedures for the receipt, management, and long-term storage of elemental mercury at a DOE facility as mandated by the Act.

  12. Thiacrown polymers for removal of mercury from waste streams

    DOEpatents

    Baumann, Theodore F.; Reynolds, John G.; Fox, Glenn A.

    2002-01-01

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  13. Light Show

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    9 Lightning - Nature's Light Show Lightning provides one of nature's most spectacular displays of energy. Though fascinating to observe, lightning can be dangerous and deadly. Protecting ARM instruments from lightning damage is vital. Putting equipment worth millions of dollars into open fields (Photo: NOAA) ARM Facilities Newsletter is published by Argonne National Laboratory, a multiprogram laboratory operated by The University of Chicago under contract W-31-109-Eng-38 with the U.S. Department

  14. MERCURY CONTAMINATED MATERIAL DECONTAMINATION METHODS: INVESTIGATION AND ASSESSMENT

    SciTech Connect

    M.A. Ebadian, Ph.D.

    2001-01-01

    Over the years mercury has been recognized as having serious impacts on human health and the environment. This recognition has led to numerous studies that deal with the properties of various mercury forms, the development of methods to quantify and speciate the forms, fate and transport, toxicology studies, and the development of site remediation and decontamination technologies. This report reviews several critical areas that will be used in developing technologies for cleaning mercury from mercury-contaminated surfaces of metals and porous materials found in many DOE facilities. The technologies used for decontamination of water and mixed wastes (solid) are specifically discussed. Many technologies that have recently appeared in the literature are included in the report. Current surface decontamination processes have been reviewed, and the limitations of these technologies for mercury decontamination are discussed. Based on the currently available technologies and the processes published recently in the literature, several processes, including strippable coatings, chemical cleaning with iodine/iodide lixiviant, chemisorbing surface wipes with forager sponge and grafted cotton, and surface/pore fixation through amalgamation or stabilization, have been identified as potential techniques for decontamination of mercury-contaminated metal and porous surfaces. Their potential merits and applicability are discussed. Finally, two processes, strippable coatings and chemical cleaning with iodine/iodide lixiviant, were experimentally investigated in Phase II of this project.

  15. Mercury control challenge for industrial boiler MACT affected facilities

    SciTech Connect

    2009-09-15

    An industrial coal-fired boiler facility conducted a test program to evaluate the effectiveness of sorbent injection on mercury removal ahead of a fabric filter with an inlet flue gas temperature of 375{sup o}F. The results of the sorbent injection testing are essentially inconclusive relative to providing the facility with enough data upon which to base the design and implementation of permanent sorbent injection system(s). The mercury removal performance of the sorbents was significantly less than expected. The data suggests that 50 percent mercury removal across a baghouse with flue gas temperatures at or above 375{sup o}F and containing moderate levels of SO{sub 3} may be very difficult to achieve with activated carbon sorbent injection alone. The challenge many coal-fired industrial facilities may face is the implementation of additional measures beyond sorbent injection to achieve high levels of mercury removal that will likely be required by the upcoming new Industrial Boiler MACT rule. To counter the negative effects of high flue gas temperature on mercury removal with sorbents, it may be necessary to retrofit additional boiler heat transfer surface or spray cooling of the flue gas upstream of the baghouse. Furthermore, to counter the negative effect of moderate or high SO{sub 3} levels in the flue gas on mercury removal, it may be necessary to also inject sorbents, such as trona or hydrated lime, to reduce the SO{sub 3} concentrations in the flue gas. 2 refs., 1 tab.

  16. Controlling mercury emissions from coal-fired power plants

    SciTech Connect

    Chang, R.

    2009-07-15

    Increasingly stringent US federal and state limits on mercury emissions form coal-fired power plants demand optimal mercury control technologies. This article summarises the successful removal of mercury emissions achieved with activated carbon injection and boiler bromide addition, technologies nearing commercial readiness, as well as several novel control concepts currently under development. It also discusses some of the issues standing in the way of confident performance and cost predictions. In testing conducted on western coal-fired units with fabric filters or TOXECON to date, ACI has generally achieved mercury removal rates > 90%. At units with ESPs, similar performance requires brominated ACI. Alternatively, units firing western coals can use boiler bromide addition to increase flue gas mercury oxidation and downstream capture in a wet scrubber, or to enhance mercury removal by ACI. At eastern bituminous fired units with ESPs, ACI is not as effective, largely due to SO{sub 3} resulting from the high sulfur content of the coal or the use of SO{sub 3} flue gas conditioning to improve ESP performance. 7 refs., 3 figs.

  17. Method and apparatus for controlling the flow rate of mercury in a flow system

    DOEpatents

    Grossman, Mark W.; Speer, Richard

    1991-01-01

    A method for increasing the mercury flow rate to a photochemical mercury enrichment utilizing an entrainment system comprises the steps of passing a carrier gas over a pool of mercury maintained at a first temperature T1, wherein the carrier gas entrains mercury vapor; passing said mercury vapor entrained carrier gas to a second temperature zone T2 having temperature less than T1 to condense said entrained mercury vapor, thereby producing a saturated Hg condition in the carrier gas; and passing said saturated Hg carrier gas to said photochemical enrichment reactor.

  18. JV Task 98 - Controlling Mercury Emissions for Utilities Firing Lignites from North America

    SciTech Connect

    Steven Benson

    2007-06-15

    This project compiled and summarized the findings and conclusions of research, development, and demonstration projects on controlling mercury from lignite coals. A significant amount of work has been conducted since 1994 on mercury in lignite, mercury measurement in flue gases, sorbent, sorbent enhancement additives, oxidation agent development, and full-scale demonstration of mercury control technologies. This report is focused on providing the lignite industry with an understanding of mercury issues associated with the combustion of lignite, as well as providing vital information on the methods to control mercury emissions in coal-fired power plants.

  19. Direct Measurement of Mercury Reactions In Coal Power Plant Plumes

    SciTech Connect

    Leonard Levin

    2005-12-31

    Recent field and pilot-scale results indicate that divalent mercury emitted from power plants may rapidly transform to elemental mercury within the power plant plumes. Simulations of mercury chemistry in plumes based on measured rates to date have improved regional model fits to Mercury Deposition Network wet deposition data for particular years, while not degrading model verification fits for remaining years of the ensemble. The years with improved fit are those with simulated deposition in grid cells in the State of Pennsylvania that have matching MDN station data significantly less than the model values. This project seeks to establish a full-scale data basis for whether or not significant reduction or oxidation reactions occur to mercury emitted from coal-fired power plants, and what numerical redox rate should apply for extension to other sources and for modeling of power plant mercury plumes locally, regionally, and nationally. Although in-stack mercury (Hg) speciation measurements are essential to the development of control technologies and to provide data for input into atmospheric fate and transport models, the determination of speciation in a cooling coal combustion plume is more relevant for use in estimating Hg fate and effects through the atmosphere. It is mercury transformations that may occur in the plume that determine the eventual rate and patterns of mercury deposited to the earth's surface. A necessary first step in developing a supportable approach to modeling any such transformations is to directly measure the forms and concentrations of mercury from the stack exit downwind to full dispersion in the atmosphere. As a result, a study was sponsored by EPRI and jointly funded by EPRI, the U.S Department of Energy (DOE), and the Wisconsin Department of Administration. The study was designed to further our understanding of plume chemistry. The study was carried out at the We Energies Pleasant Prairie Power Plant, Pleasant Prairie, Wisconsin, just

  20. Mercury Emission Control Technologies for PPL Montana-Colstrip Testing

    SciTech Connect

    John P. Kay; Michael L. Jones; Steven A. Benson

    2007-04-01

    The Energy & Environmental Research Center (EERC) was asked by PPL Montana LLC (PPL) to provide assistance and develop an approach to identify cost-effective options for mercury control at its coal-fired power plants. The work conducted focused on baseline mercury level and speciation measurement, short-term parametric testing, and week long testing of mercury control technology at Colstrip Unit 3. Three techniques and various combinations of these techniques were identified as viable options for mercury control. The options included oxidizing agents or sorbent enhancement additives (SEAs) such as chlorine-based SEA1 and an EERC proprietary SEA2 with and without activated carbon injection. Baseline mercury emissions from Colstrip Unit 3 are comparatively low relative to other Powder River Basin (PRB) coal-fired systems and were found to range from 5 to 6.5 g/Nm3 (2.9 to 3.8 lb/TBtu), with a rough value of approximately 80% being elemental upstream of the scrubber and higher than 95% being elemental at the outlet. Levels in the stack were also greater than 95% elemental. Baseline mercury removal across the scrubber is fairly variable but generally tends to be about 5% to 10%. Parametric results of carbon injection alone yielded minimal reduction in Hg emissions. SEA1 injection resulted in 20% additional reduction over baseline with the maximum rate of 400 ppm (3 gal/min). Week long testing was conducted with the combination of SEA2 and carbon, with injection rates of 75 ppm (10.3 lb/hr) and 1.5 lb/MMacf (40 lb/hr), respectively. Reduction was found to be an additional 30% and, overall during the testing period, was measured to be 38% across the scrubber. The novel additive injection method, known as novel SEA2, is several orders of magnitude safer and less expensive than current SEA2 injection methods. However, used in conjunction with this plant configuration, the technology did not demonstrate a significant level of mercury reduction. Near-future use of this

  1. Heat-source specification 500 watt(e) RTG

    SciTech Connect

    Not Available

    1983-02-01

    This specification establishes the requirements for a /sup 90/SrF/sub 2/ heat source and its fuel capsule for application in a 500 W(e) thermoelectric generator. The specification covers: fuel composition and quantity; the Hastelloy S fuel capsule material and fabrication; and the quality assurance requirements for the assembled heat source. (LCL)

  2. Methods and sorbents for utilizing a hot-side electrostatic precipitator for removal of mercury from combustion gases

    SciTech Connect

    Nelson, Sidney

    2011-02-15

    Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.

  3. Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Lighting Lighting When you're shopping for lightbulbs, compare lumens and use the Lighting Facts label to be sure you're getting the amount of light, or level of brightness, you want. You can save money and energy while lighting your home and still maintaining good light quantity and quality. Consider energy-efficient lighting options to use the same amount of light for less money. Learn strategies for comparing and buying lighting products and using them efficiently. Featured Lighting Choices

  4. Light-weight radioisotope heater impact tests

    SciTech Connect

    Reimus, M.A.H.; Rinehart, G.H.; Herrera, A.

    1998-12-31

    The light-weight radioisotope heater unit (LWRHU) is a {sup 238}PuO{sub 2}-fueled heat source designed to provide one thermal watt in each of various locations on a spacecraft. Los Alamos National Laboratory designed, fabricated, and safety tested the LWRHU. The heat source consists of a hot-pressed {sup 238}PuO{sub 2} fuel pellet, a Pt-30Rh vented capsule, a pyrolytic graphite insulator, and a fineweave-pierced fabric graphite aeroshell assembly. To compare the performance of the LWRHUs fabricated for the Cassini mission with the performance of those fabricated for the Galileo mission, and to determine a failure threshold, two types of impact tests were conducted. A post-reentry impact test was performed on one of 180 flight-quality units produced for the Cassini mission and a series of sequential impact tests using simulant-fueled LWRHU capsules were conducted respectively. The results showed that deformation and fuel containment of the impacted Cassini LWRHU was similar to that of a previously tested Galileo LWRHU. Both units sustained minimal deformation of the aeroshell and fueled capsule; the fuel was entirely contained by the platinum capsule. Sequential impacting, in both end-on and side-on orientations, resulted in increased damage with each subsequent impact. Sequential impacting of the LWRHU appears to result in slightly greater damage than a single impact at the final impact velocity of 50 m/s.

  5. 500-watt commercialized concentrator system

    SciTech Connect

    Ronney, K.; Aerni, E.

    1983-02-01

    A passively cooled, single-axis tracking, polar-axis mounted photovoltaic concentrator system has been designed, fabricated, installed, and tested. System description, design considerations, system performance and a production cost estimate are detailed.

  6. Elimination of mercury and organomercurials by nitrogen-fixing bacteria

    SciTech Connect

    Ghosh, S.; Sadhukhan, P.C.; Ghosh, D.K.

    1997-06-01

    Bacteria isolated from mercury-polluted environments are often resistant to mercuric ions (Hg{sup 2+}) and organomercurials. Plasmids determining mercury resistance have been well characterized in gram-negative system. However, in Staphylococcus aureus mercury resistance has been found to be chromosomally determined. The known mechanism of bacterial Hg{sup 2+}-resistance is detoxification of the toxic Hg{sup 2+} by its enzymatic transformation by mercuric reductase to Hg (o). Organomercurial lyase mediates the degradation of organomercurial compounds to Hg{sup 2+}. Mercury and organomercurial resistances have been studied in different bacterial genera. There is little information on Hg-resistance in N{sub 2}-fixing soil bacteria, however, in many developing countries, including India, mercury pollution is still a problem because Hg-based pesticides and fungicides are still used routinely as seed-dressers in agriculture to control soil-borne and seed-borne fungal diseases. Volatilization of Hg from laboratory media by mercury-resistant bacteria containing low levels of mercury has been reported by several workers. It is interesting to note that N{sub 2}-fixing, Hg-resistant soil isolates could volatilize Hg from medium containing very high amounts of HgCl{sub 2}. In the present paper we report the volatilization patterns of five N{sub 2}-fixing bacterial strains, the effect of different inducers on mercuric reductase, and the pattern of substrate utilization by organomercurial lyase. In the presence of a low concentration of HgCl{sub 2}. enzymatic detoxification is sufficient to combat the adverse situation created by the presence of Hg{sup 2+} ions. In the presence of a high concentration of HgCl{sub 2}, intracellular sequestration by Hg{sup 2+} binding components may play an additional role in counteracting Hg-toxicity.

  7. Mitigation and Remediation of Mercury Contamination at the Y-12 Plant Oak

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Ridge | Department of Energy Mitigation and Remediation of Mercury Contamination at the Y-12 Plant Oak Ridge Mitigation and Remediation of Mercury Contamination at the Y-12 Plant Oak Ridge Full Document and Summary Versions are available for download Mitigation and Remediation of Mercury Contamination at the Y-12 Plant Oak Ridge (1.04 MB) Summary - Mitigation and Remediation of Mercury Contamination at the Y-12 Plant, Oak Ridge, TN (44.29 KB) More Documents & Publications Technology Plan

  8. Reading Municipal Light Department - Business Lighting Rebate...

    Energy.gov [DOE] (indexed site)

    with Electronic Ballasts: 100fixture De-lamping: 4 - 9lamp Lighting Sensors: 20sensor LED Exit Signs: 20fixture Summary Reading Municipal Light Department (RMLD) offers...

  9. light-emitting diode

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Cost The high-brightness, rapidly pulsed, multicolor light-emitting diode (LED) driver delivers lighting performance that exceeds that of conventional (laserarc-light) sources ...

  10. ALTERNATIVE FIELD METHODS TO TREAT MERCURY IN SOIL

    SciTech Connect

    Ernie F. Stine

    2002-08-14

    The Department of Energy (DOE) currently has mercury (Hg) contaminated materials and soils at the various sites. Figure 1-1 (from http://www.ct.ornl.gov/stcg.hg/) shows the estimated distribution of mercury contaminated waste at the various DOE sites. Oak Ridge and Idaho sites have the largest deposits of contaminated materials. The majorities of these contaminated materials are soils, sludges, debris, and waste waters. This project concerns treatment of mercury contaminated soils. The technology is applicable to many DOE sites, in-particular, the Y-12 National Security Complex in Oak Ridge Tennessee and Idaho National Engineering and Environmental Laboratory (INEEL). These sites have the majority of the soils and sediments contaminated with mercury. The soils may also be contaminated with other hazardous metals and radionuclides. At the Y12 plant, the baseline treatment method for mercury contaminated soil is low temperature thermal desorption (LTTD), followed by on-site landfill disposal. LTTD is relatively expensive (estimated cost of treatment which exclude disposal cost for the collect mercury is greater than $740/per cubic yard [cy] at Y-12), does not treat any of the metal or radionuclides. DOE is seeking a less costly alternative to the baseline technology. As described in the solicitation (DE-RA-01NT41030), this project initially focused on evaluating cost-effective in-situ alternatives to stabilize or remove the mercury (Hg) contamination from high-clay content soil. It was believed that ex-situ treatment of soil contaminated with significant quantities of free-liquid mercury might pose challenges during excavation and handling. Such challenges may include controlling potential mercury vapors and containing liquid mercury beads. As described below, the focus of this project was expanded to include consideration of ex-situ treatment after award of the contract to International Technology Corporation (IT). After award of the contract, IT became part of Shaw

  11. Critical review of mercury chemistry in flue gas.

    SciTech Connect

    Mendelsohn, M. H.; Livengood, C. D.

    2006-11-27

    Mercury (Hg) and its compounds have long been recognized as potentially hazardous to human health and the environment. Many man-made sources of mercury have been reduced in recent years through process changes and control measures. However, emissions of mercury from coal-fired power plants, while exceedingly dilute by the usual pollution standards, still constitute a major source when considered in the aggregate. Concerns over those emissions and the prospect of impending emissions regulations have led to a wide range of research projects dealing with the measurement and control of mercury in flue gas. This work has made considerable progress in improving the understanding of mercury emissions and their behavior, but inconsistencies and unexpected results have also shown that a better understanding of mercury chemistry is needed. To develop a more complete understanding of where additional research on mercury chemistry is needed, the U.S. Department of Energy (DOE) asked Argonne National Laboratory (Argonne) to conduct a critical review of the available information as reported in the technical literature. The objectives were to summarize the current state of the art of chemistry knowledge, identify significant knowledge gaps, and recommend future research to resolve those gaps. An initial evaluation of potential review topics indicated that the scope of the review would need to be limited and focused on the most important topics relative to mercury control. To aid in this process, Argonne developed a brief survey that was circulated to researchers in the field who could help identify and prioritize the many aspects of the problem. The results of the survey were then used to design and guide a highly focused literature search that identified key papers for analysis. Each paper was reviewed, summarized, and evaluated for the relevance and quality of the information presented. The results of that work provided the basis for conclusions regarding the state of knowledge

  12. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    SciTech Connect

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  13. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOEpatents

    Mendelsohn, Marshall H.; Livengood, C. David

    2006-10-10

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  14. Method for the removal of elemental mercury from a gas stream

    DOEpatents

    Mendelsohn, M.H.; Huang, H.S.

    1999-05-04

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

  15. Method for the removal of elemental mercury from a gas stream

    DOEpatents

    Mendelsohn, Marshall H.; Huang, Hann-Sheng

    1999-01-01

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

  16. Novel sorbents for mercury removal from flue gas

    SciTech Connect

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    2000-04-01

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, the capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons as well as novel sorbents were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  17. Thief process for the removal of mercury from flue gas

    DOEpatents

    Pennline, Henry W.; Granite, Evan J.; Freeman, Mark C.; Hargis, Richard A.; O'Dowd, William J.

    2003-02-18

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  18. Natural mercury isotope variation in coal deposits and organic soils

    SciTech Connect

    Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie

    2008-11-15

    There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

  19. The fate of mercury in coal utilization byproducts

    SciTech Connect

    William Aljoe; Thomas Feeley; James Murphy; Lynn Brickett [US Department of Energy's National Energy Technology Laboratory (DOE/NETL), Pittsburgh, PA (US)

    2005-05-01

    The US Department of Energy National Energy Technology Laboratory's (DOE/NETL's) research has helped to further scientific understanding of the environmental characteristics of coal-utilization by-products (CUBs) in both disposal and beneficial utilization applications. The following general observations can be drawn from results of the research that has been carried out to date: There appears to be only minimal mercury release to the environment in typical disposal or utilization applications for CUBs generated using activated carbon injection (ACI) control technologies; There appears to be only minimal mercury release to the environment in typical disposal and utilization applications for CUBs generated using wet FGD control technologies. The potential release of mercury from wet FGD gypsum during the manufacture of wallboard is still under evaluation; The amount of mercury leached from CUB samples tested by DOE/NETL is significantly lower than the federal drinking water standards and water quality criteria for the protection of aquatic life; in many cases, leachate concentrations were below the standard test method detection limits. DOE/NETL will continue to partner with industry and other key stakeholders in carrying out research to better understand the fate of mercury and other trace elements in the byproducts from coal combustion. 16 refs., 6 tabs.

  20. Mercury Oxidation via Catalytic Barrier Filters Phase II

    SciTech Connect

    Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

    2007-09-30

    In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

  1. DMPS (DIMAVAL) as a challenge test to assess the mercury and arsenic body/kidney load in humans and as a treatment of mercury toxicity

    SciTech Connect

    Aposhian, H.V.; Maiorino, R.M.; Aposhian, M.M.; Hurlbut, K.M.

    1996-12-31

    Mercury is an element which, with its compounds, is hazardous and is found in hazardous wastes. In Order to develop suitable diagnostic and therapeutic agents for mercury exposure, we have sought alternative test systems. We have used the chelating agent 2,3-dimercaptopropane-1-sulfonate (DMPS, DIMAVAL{reg_sign}) for estimating the body burden of mercury in normal humans and in dental personnel in a developing country, and for detoxifying humans with mercurous chloride exposure. Use of the DMPS-mercury challenge test has shown that two-thirds of the mercury excreted in the urine of volunteers with dental amalgams appears to be derived from the mercury vapor released from their amalgams. The DMPS challenge test (300 mg, by mouth, after an 11 hr fast) was useful for monitoring dental personnel for mercury vapor exposure. The DMPS challenge test was given to 11 factory workers who make a skin lotion that contains mercurous chloride, 8 users of the skin lotion, and 9 controls. The increases in urinary Hg resulting from the DMPS challenge were 45, 87, and 38-fold, respectively. The results demonstrate that in humans exposed to mercurous chloride, the DMPS-mercury challenge test is of value for a more realistic estimation of mobilizable Hg. DMPS should be considered for use to determine mercury body burdens and to treat humans exposed to mercury and its compounds via exposure to hazardous wastes. 42 refs., 2 figs., 5 tabs.

  2. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar

    2006-07-31

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.

  3. DIRECT MEASUREMENT OF MERCURY REACTIONS IN COAL POWER PLANT PLUMES

    SciTech Connect

    Leonard Levin

    2006-06-01

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-02NT41422 and specifically addresses Program Area of Interest: No.5--Environmental and Water Resources. The project team includes the Electric Power Research Institute (EPRI) as the contractor and the University of North Dakota Energy & Environmental Research Center (EERC) and Frontier Geosciences as subcontractors. Wisconsin Energies and its Pleasant Prairie Power Plant acted as host for the field-testing portion of the research. The project is aimed at clarifying the role, rates, and end results of chemical transformations that may occur to mercury that has been emitted from elevated stacks of coal-fired electric power plants. Mercury emitted from power plants emerges in either its elemental, divalent, or particulate-bound form. Deposition of the divalent form is more likely to occur closer to the source than that of the other two forms, due to its solubility in water. Thus, if chemical transformations occur in the stack emissions plume, measurements in the stack may mischaracterize the fate of the material. Initial field and pilot plant measurements have shown significant and rapid chemical reduction of divalent to elemental mercury may occur in these plumes. Mercury models currently assume that the chemical form of mercury occurring in stacks is the same as that which enters the free atmosphere, with no alteration occurring in the emissions plume. Recent data indicate otherwise, but need to be evaluated at full operating scale under field conditions. Prestbo and others have demonstrated the likelihood of significant mercury chemical reactions occurring in power plant plumes (Prestbo et al., 1999; MDNR-PPRP, 2000; EERC, 2001). This experiment will thus increase our understanding of mercury atmospheric chemistry, allowing informed decisions regarding source attribution. The experiment was carried out during the period August 22

  4. Clean Air Mercury Rule (released in AEO2009)

    Reports and Publications

    2009-01-01

    On February 8, 2008, a three-judge panel on the D.C. Circuit of the U.S. Court of Appeals issued a decision to vacate the Clean Air Mercury Rule (CAMR). In its ruling, the panel cited the history of hazardous air pollutant regulation under Section 112 of the Clean Air Act (CAA). Section 112, as written by Congress, listed emitted mercury as a hazardous air pollutant that must be subject to regulation unless it can be proved harmless to public welfare and the environment. In 2000, the Environmental Protection Agency ruled that mercury was indeed hazardous and must be regulated under Section 112 and, therefore, subjected to the best available control technology for mitigation.

  5. Catalysts for oxidation of mercury in flue gas

    DOEpatents

    Granite, Evan J.; Pennline, Henry W.

    2010-08-17

    Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

  6. Support Facility for a Mercury Target Neutrino Factory

    SciTech Connect

    Spampinato, P.T.

    2001-12-06

    A conceptual design for a neutrino-producing facility is presented, including the mercury-jet target system, beam absorber, and facility for the target/capture region. The mercury system is a closed loop that includes a containment structure in the high-magnetic field region, a mercury pool beam absorber, conventional equipment such as magnetic-coupled pumps, valves, a heat exchanger, and a special nozzle insert. The superconducting solenoids in the target region are protected from nuclear heating and radiation damage with water-cooled tungsten-carbide shielding; the decay channel solenoids are protected with water-cooled steel shielding. The target region and decay channel have high-neutron fluxes resulting in components that are highly activated. Therefore, the facility configuration is based on remotely maintaining the target system and the magnets, as well as providing sufficient shielding for personnel. Summaries of cost estimates for the target system, magnet shielding, maintenance equipment, and the facility are also presented.

  7. Mercury emissions from German fluidized bed sludge incinerators -- A status report

    SciTech Connect

    Saenger, M.; Werther, J.; Lungwitz, H.

    1999-07-01

    In 1996 19% of the 2.7 million tons dry matter of sewage sludge produced in Germany were disposed by incineration. Incineration of the sludge is carried out mainly in fluidized bed combustors. German emission regulations set a limit to the mercury emission of 0.05 mg/m{sup 3} (under standard condition, dry basis) the observance of which requires special flue gas cleaning installations. In the present paper, an overview is given on the state of the art of flue gas cleaning with respect to mercury emissions from sewage sludge incineration in Germany. A total of 13 plants were examined. Because of the thermochemical instability of the mercury compounds only elemental mercury will exist inside the combustion chamber. During the cooling of the flue gas the elemental mercury reacts depending on the presence of other flue gas components to several mercurous and mercuric compounds. Measurements in the plants investigated indicate that the ratio of elemental to chemically bound mercury decreases with increasing chlorine content in the sludge feed. Different types of gas cleaning systems are used to remove the mercury from the flue gas which may be grouped into two categories, namely scrubbers and adsorbers, respectively. The mercury sink in the cleaning system will therefore be either the excess water of a wet scrubber or the laden adsorbent from an adsorber. If the amount of the practically water-insoluble elemental mercury is below the emission limit wet scrubbers will be sufficient to remove the mercuric and mercurous species. Otherwise elemental mercury has to be additionally removed by adding agents to oxidize the mercury for capture in a scrubber or by an adsorbent. Only 1--6% of the mercury supplied with the sludge is found in the fly ash separated with electrostatic precipitators. The different kinds of mercury capture systems used in German fluidized bed sludge incineration plants, the mercury concentrations in the cleaned flue gas and the removal efficiencies with

  8. Light weight radioisotope heater unit (LWRHU): a technical description of the reference design

    SciTech Connect

    Tate, R.E.

    1982-01-01

    The Light Weight Radioisotope Heater Unit (LWRHU), a new radioisotope heater unit for use in space missions, is a /sup 238/PuO/sub 2/-fueled unit designed to provide a thermal watt in dispersed locations on a spacecraft. The LWRHU is required to maintain the temperature of a component at a level where the component will function reliably in space. Two major constraints are placed on the unit's design; it must be as light as possible and must provide enough protection to immobilize the plutonium fuel to the maximum extent in all phases of the unit's lifetime. The four components are pelletized fuel, platinum-alloy encapsulation, pyrolytic graphite thermal insulation, and high-technology graphite ablation shell. The LWRHU is a cylinder 32 mm (1.26 in.) high and 26 mm (1.02 in.) in diameter. It weighs slightly less than 40 g(.09 lb).

  9. Long-Term Management and Storage of Elemental Mercury | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Long-Term Management and Storage of Elemental Mercury Long-Term Management and Storage of Elemental Mercury In addition to banning the export of elemental mercury from the United States as of January 1, 2013, the Mercury Export Ban Act of 2008 (MEBA) (Public Law No. 110-414) requires the Department of Energy (DOE) to establish a facility for the long-term management and storage of elemental mercury (generated with the U.S.). DOE used the National Environmental Policy Act (NEPA)

  10. Characterization of Gatewell Orifice Lighting at the Bonneville Dam Second Powerhouse and Compendium of Research on Light Guidance with Juvenile Salmonids

    SciTech Connect

    Mueller, Robert P.; Simmons, Mary Ann

    2007-12-29

    The goal of the study described in this report is to provide U.S. Army Corps of Engineers (USACE) biologists and engineers with general design guidelines for using artificial lighting to enhance the passage of juvenile salmonids into the collection channel at the Bonneville Dam second powerhouse (B2). During fall 2007, Pacific Northwest National Laboratory (PNNL) researchers measured light levels in the field at one powerhouse orifice through which fish must pass to reach the collection channel. Two light types were evaluatedlight-emitting diode (LED) lights and halogen spot lights. Additional measurements with mercury lamps were made at the PNNL Aquatic Research Laboratory to determine baseline intensity of the current lighting. A separate chapter synthesizes the relevant literature related to light and fish guidance for both field and laboratory studies. PNNL will also review the Corps plans for existing lighting protocol at all of the Portland District projects and help develop a uniform lighting scheme which could be implemented. The specific objectives for this study are to 1. Create a synthesis report of existing lighting data for juvenile salmonid attraction and deterrence and how the data are used at fish bypass facilities. 2. Evaluate current B2 orifice lighting conditions with both LED and halogen sources. 3. Make recommendations as to what lighting intensity, source, and configuration would improve passage at the B2 orifices. 4. Review USACE plans for retrofit of existing systems (to be assessed at a later date).

  11. Optimizing Technology to Reduce Mercury and Acid Gas Emissions from Electric Power Plants

    SciTech Connect

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-01-31

    Revised maps and associated data show potential mercury, sulfur, and chlorine emissions for U.S. coal by county of origin. Existing coal mining and coal washing practices result in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Selection of low-mercury coal is a good mercury control option for plants having hot-side ESP, cold-side ESP, or hot-side ESP/FGD emission controls. Chlorine content is more important for plants having cold-side ESP/FGD or SDA/FF controls; optimum net mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions.

  12. A study of the effect of chloride on mercury removal in a fluidized bed combustion (FBC) system

    SciTech Connect

    Liu, K.; Gao, Y.; Li, F.; Pan, W.P.; Riley, J.T.; Mehta, A.K.; Ho, K.K.; Smith, S.R.

    2000-07-01

    Mercury exists in three forms, which are elemental mercury, inorganic mercury compounds, and organic mercury. Each form of mercury has a very different exposure potential. Oxidized mercury is soluble and has a tendency to associate with particles. Nearly all the post-combustion flue gas cleaning systems proposed to remove mercury may be categorized as either scrubbers or adsorbers. Therefore, the mercury sink in the cleaning system will be either the excess water of a wet scrubber or the mercury laden sorbent from an absorber. The major problem for post-combustion mercury capture systems is capturing the practically water-insoluble elemental mercury. Co-firing with high chlorine coal or RDF in utility boiler systems can provide an HCI atmosphere for the oxidation of elemental mercury in flue gas at relatively low temperatures (500--600 C). The objective of this study is to increase the efficiency of mercury emission cleaning methods by using HCl to convert elemental mercury to oxidized mercury species at low monetary costs and lower other toxic air emissions. When high chlorine (0.3--0.5%) coals were burned and a high intensity vortex flow (from secondary air) was used, around 70% of the total mercury in the fuel was condensed and absorbed by the fly ash (including calcium compounds). The remaining 30% of total fuel mercury was emitted in the gas phase in the flue gas. As for the gas phase mercury, about 98% of it exists in an oxidized form with a higher boiling temperature than elemental mercury and can be easily captured by an ESP or FGP apparatus. Only about 0.5% of the total fuel mercury was released to the atmosphere in elemental form.

  13. Ranking low cost sorbents for mercury capture from simulated flue gases

    SciTech Connect

    H. Revata Seneviratne; Cedric Charpenteau; Anthe George; Marcos Millan; Denis R. Dugwell; Rafael Kandiyoti

    2007-12-15

    Coal fired utility boilers are the largest anthropogenic source of mercury release to the atmosphere, and mercury abatement legislation is already in place in the USA. The present study aimed to rank low cost mercury sorbents (char and activated carbon from the pyrolysis of scrap tire rubber and two coal fly ashes from UK power plants) against Norit Darco HgTM for mercury retention by using a novel bench-scale reactor. In this scheme, a fixed sorbent bed was tested for mercury capture efficiency from a simulated flue gas stream. Experiments with a gas stream of only mercury and nitrogen showed that while the coal ashes were the most effective in mercury capture, char from the pyrolysis of scrap tire rubber was as effective as the commercial sorbent Norit Darco HgTM. Tests conducted at 150{sup o}C, with a simulated flue gas mix that included N{sub 2}, NO, NO{sub 2}, CO{sub 2}, O{sub 2}, SO{sub 2} and HCl, showed that all the sorbents captured approximately 100% of the mercury in the gas stream. The introduction of NO and NO{sub 2} was found to significantly improve the mercury capture, possibly by reactions between NOx and the mercury. Since the sorbents' efficiency decreased with increasing test temperature, physical sorption could be the initial step in the mercury capture process. As the sorbents were only exposed to 64 ng of mercury in the gas stream, the mercury loadings on the samples were significantly less than their equilibrium capacities. The larger capacities of the activated carbons due to their more microporous structure were therefore not utilized. Although the sorbents have been characterized by BET surface area analysis and XRD analysis, further analysis is needed in order to obtain a more conclusive correlation of how the characteristics of the different sorbents correlate with the observed variations in mercury capture ability. 34 refs., 8 figs., 6 tabs.

  14. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    SciTech Connect

    Charles Mones

    2006-12-01

    Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the

  15. Buildings Energy Data Book: 5.6 Lighting

    Buildings Energy Data Book

    9 Typical Efficacies and Lifetimes of Lamps (1) Current Technology CRI (2) Incandescent 10 - 19 97 Halogen 14 - 20 99 Fluorescent - T5 25 - 55 52 - 75 Fluorescent - T8 35 - 87 7,500 - 20,000 52 - 90 Fluorescent - T12 35 - 92 7,500 - 20,000 50 - 92 Compact Fluorescent 40 - 70 82 Mercury Vapor 25 - 50 15 - 50 Metal Halide 65 - 70 High-Pressure Sodium 22 Low-Pressure Sodium 0 Solid State Lighting 33-97 Note(s): Source(s): 18 - 180 18,000 20 - 100 15,000 - 50,000 1) Theoretical maximum luminous

  16. Spectroscopy of triply and quadruply ionized states of mercury

    SciTech Connect

    Huttula, M.; Huttula, S.-M.; Lablanquie, P.; Palaudoux, J.; Penent, F.; Andric, L.; Eland, J. H. D.

    2011-03-15

    Multielectron coincidence spectroscopy has been used to study multiple ionization of atomic mercury. The binding energies of triply and quadruply ionized states of Hg have been determined from three- and fourfold electron coincidences. Relativistic ab initio theory has been used to calculate the state energies and predict the experimental findings.

  17. Predictable SCR co-benefits for mercury control

    SciTech Connect

    Pritchard, S.

    2009-01-15

    A test program, performed in cooperation with Dominion Power and the Babcock and Wilcox Co., was executed at Dominion Power's Mount Storm power plant in Grant County, W. Va. The program was focused on both the selective catalytic reduction (SCR) catalyst capability to oxide mercury as well as the scrubber's capability to capture and retain the oxidized mercury. This article focuses on the SCR catalyst performance aspects. The Mount Storm site consists of three units totaling approximately 1,660 MW. All units are equipped with SCR systems for NOx control. A full-scale test to evaluate the effect of the SCR was performed on Unit 2, a 550 MWT-fired boiler firing a medium sulfur bituminous coal. This test program demonstrated that the presence of an SCR catalyst can significantly affect the mercury speciation profile. Observation showed that in the absence of an SCR catalyst, the extent of oxidation of element a mercury at the inlet of the flue gas desulfurization system was about 64%. The presence of a Cornertech SCR catalyst improved this oxidation to levels greater than 95% almost all of which was captured by the downstream wet FGD system. Cornertech's proprietary SCR Hg oxidation model was used to accurately predict the field results. 1 ref., 2 figs., 1 tab.

  18. Novel sorbents for mercury removal from flue gas

    SciTech Connect

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    1999-07-01

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  19. Enhanced control of mercury emissions through modified speciation

    SciTech Connect

    Livengood, C.D.; Mendelsohn, M.H.

    1997-07-01

    In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. Argonne National Laboratory has supported the DOE Fossil Energy Program for over 15 years with research on advanced environmental control technologies. The emphasis in Argonne`s work has been on integrated systems that combine control of several pollutants. Specific topics have included spray drying for sulfur dioxide and particulate-matter control with high-sulfur coal, combined sulfur dioxide and nitrogen oxides control technologies, and techniques to enhance mercury control in existing FGC systems. The latter area has focused on low-cost dry sorbents for use with fabric filters or electrostatic precipitators and techniques for improving the capture of mercury in wet flue-gas desulfurization (FGD) systems. This paper presents results from recent work that has studied the effects of several oxidizing agents in combination with typical flue-gas species (e.g., nitrogen oxides and sulfur dioxide) on the oxidation of Hg{sup 0}.

  20. Oak Ridge EM Program Increases Focus on Mercury Cleanup

    Energy.gov [DOE]

    OAK RIDGE, Tenn. – EM Senior Advisor Dave Huizenga recently joined local lawmakers and state and federal officials to announce their partnership to increase focus on cleanup of mercury — one of Oak Ridge’s greatest environmental threats — at the Y-12 National Security Complex.

  1. ADVANCED GASIFICATION MERCURY/TRACE METAL CONTROL WITH MONOLITH TRAPS

    SciTech Connect

    Mark A. Musich; Michael L. Swanson; Grant E. Dunham; Joshua J. Stanislowski

    2010-07-31

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m3 (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m3 (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and

  2. Mercury stabilization in chemically bonded phosphate ceramics

    SciTech Connect

    Wagh, A. S.; Singh, D.; Jeong, S. Y.

    2000-04-04

    Mercury stabilization and solidification is a significant challenge for conventional stabilization technologies. This is because of the stringent regulatory limits on leaching of its stabilized products. In a conventional cement stabilization process, Hg is converted at high pH to its hydroxide, which is not a very insoluble compound; hence the preferred route for Hg sulfidation to convert it into insoluble cinnabar (HgS). Unfortunately, efficient formation of this compound is pH-dependent. At a high pH, one obtains a more soluble Hg sulfate, in a very low pH range, insufficient immobilization occurs because of the escape of hydrogen sulfide, while efficient formation of HgS occurs only in a moderately acidic region. Thus, the pH range of 4 to 8 is where stabilization with Chemically Bonded Phosphate Ceramics (CBPC) is carried out. This paper discusses the authors experience on bench-scale stabilization of various US Department of Energy (DOE) waste streams containing Hg in the CBPC process. This process was developed to treat DOE's mixed waste streams. It is a room-temperature-setting process based on an acid-base reaction between magnesium oxide and monopotassium phosphate solution that forms a dense ceramic within hours. For Hg stabilization, addition of a small amount (< 1 wt.%) of Na{sub 2}S or K{sub 2}S is sufficient in the binder composition. Here the Toxicity Characteristic Leaching Procedure (TCLP) results on CBPC waste forms of surrogate waste streams representing secondary Hg containing wastes such as combustion residues and Delphi DETOX{trademark} residues are presented. The results show that although the current limit on leaching of Hg is 0.2 mg/L, the results from the CBPC waste forms are at least one order lower than this stringent limit. Encouraged by these results on surrogate wastes, they treated actual low-level Hg-containing mixed waste from their facility at Idaho. TCLP results on this waste are presented here. The efficient stabilization in

  3. Mobile lighting apparatus

    DOEpatents

    Roe, George Michael; Klebanoff, Leonard Elliott; Rea, Gerald W; Drake, Robert A; Johnson, Terry A; Wingert, Steven John; Damberger, Thomas A; Skradski, Thomas J; Radley, Christopher James; Oros, James M; Schuttinger, Paul G; Grupp, David J; Prey, Stephen Carl

    2013-05-14

    A mobile lighting apparatus includes a portable frame such as a moveable trailer or skid having a light tower thereon. The light tower is moveable from a stowed position to a deployed position. A hydrogen-powered fuel cell is located on the portable frame to provide electrical power to an array of the energy efficient lights located on the light tower.

  4. High Efficiency, Illumination Quality OLEDs for Lighting

    SciTech Connect

    Joseph Shiang; James Cella; Kelly Chichak; Anil Duggal; Kevin Janora; Chris Heller; Gautam Parthasarathy; Jeffery Youmans; Joseph Shiang

    2008-03-31

    The goal of the program was to demonstrate a 45 lumen per watt white light device based upon the use of multiple emission colors through the use of solution processing. This performance level is a dramatic extension of the team's previous 15 LPW large area illumination device. The fundamental material system was based upon commercial polymer materials. The team was largely able to achieve these goals, and was able to deliver to DOE a 90 lumen illumination source that had an average performance of 34 LPW a 1000 cd/m{sup 2} with peak performances near 40LPW. The average color temperature is 3200K and the calculated CRI 85. The device operated at a brightness of approximately 1000cd/m{sup 2}. The use of multiple emission colors particularly red and blue, provided additional degrees of design flexibility in achieving white light, but also required the use of a multilayered structure to separate the different recombination zones and prevent interconversion of blue emission to red emission. The use of commercial materials had the advantage that improvements by the chemical manufacturers in charge transport efficiency, operating life and material purity could be rapidly incorporated without the expenditure of additional effort. The program was designed to take maximum advantage of the known characteristics of these material and proceeded in seven steps. (1) Identify the most promising materials, (2) assemble them into multi-layer structures to control excitation and transport within the OLED, (3) identify materials development needs that would optimize performance within multilayer structures, (4) build a prototype that demonstrates the potential entitlement of the novel multilayer OLED architecture (5) integrate all of the developments to find the single best materials set to implement the novel multilayer architecture, (6) further optimize the best materials set, (7) make a large area high illumination quality white OLED. A photo of the final deliverable is shown. In

  5. Mercury Reduction and Removal from High Level Waste at the Defense Waste Processing Facility - 12511

    SciTech Connect

    Behrouzi, Aria; Zamecnik, Jack

    2012-07-01

    The Defense Waste Processing Facility processes legacy nuclear waste generated at the Savannah River Site during production of enriched uranium and plutonium required by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. One of the constituents in the nuclear waste is mercury, which is present because it served as a catalyst in the dissolution of uranium-aluminum alloy fuel rods. At high temperatures mercury is corrosive to off-gas equipment, this poses a major challenge to the overall vitrification process in separating mercury from the waste stream prior to feeding the high temperature melter. Mercury is currently removed during the chemical process via formic acid reduction followed by steam stripping, which allows elemental mercury to be evaporated with the water vapor generated during boiling. The vapors are then condensed and sent to a hold tank where mercury coalesces and is recovered in the tank's sump via gravity settling. Next, mercury is transferred from the tank sump to a purification cell where it is washed with water and nitric acid and removed from the facility. Throughout the chemical processing cell, compounds of mercury exist in the sludge, condensate, and off-gas; all of which present unique challenges. Mercury removal from sludge waste being fed to the DWPF melter is required to avoid exhausting it to the environment or any negative impacts to the Melter Off-Gas system. The mercury concentration must be reduced to a level of 0.8 wt% or less before being introduced to the melter. Even though this is being successfully accomplished, the material balances accounting for incoming and collected mercury are not equal. In addition, mercury has not been effectively

  6. Selective partitioning of mercury from co-extracted actinides in a simulated acidic ICPP waste stream

    SciTech Connect

    Brewer, K.N.; Herbst, R.S.; Tranter, T.J.

    1995-12-01

    The TRUEX process is being evaluated at the Idaho Chemical Processing Plant (ICPP) as a means to partition the actinides from acidic sodium-bearing waste (SBW). The mercury content of this waste averages 1 g/l. Because the chemistry of mercury has not been extensively evaluated in the TRUEX process, mercury was singled out as an element of interest. Radioactive mercury, {sup 203}Hg, was spiked into a simulated solution of SBW containing 1 g/l mercury. Successive extraction batch contacts with the mercury spiked waste simulant and successive scrubbing and stripping batch contacts of the mercury loaded TRUEX solvent (0.2 M CMPO-1.4 M TBP in dodecane) show that mercury will extract into and strip from the solvent. The extraction distribution coefficient for mercury, as HgCl{sub 2} from SBW having a nitric acid concentration of 1.4 M and a chloride concentration of 0.035 M was found to be 3. The stripping distribution coefficient was found to be 0.5 with 5 M HNO{sub 3} and 0.077 with 0.25 M Na{sub 2}CO{sub 3}. An experimental flowsheet was designed from the batch contact tests and tested counter-currently using 5.5 cm centrifugal contactors. Results from the counter-current test show that mercury can be removed from the acidic mixed SBW simulant and recovered separately from the actinides.

  7. Investigation of a mercury speciation technique for flue gas desulfurization materials

    SciTech Connect

    Lee, J.Y.; Cho K.; Cheng L.; Keener, T.C.; Jegadeesan G.; Al-Abed, S.R.

    2009-08-15

    Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method and samples from power plants in Pennsylvania. Potential candidates of pure mercury standards including mercuric chloride, mercurous chloride, mercury oxide, mercury sulfide, and mercuric sulfate were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not exactly match with those of the FGD gypsum and wallboard samples, it was identified that Hg{sub 2}Cl{sub 2} and HgCl{sub 2} could be candidates. An additional chlorine analysis from the gypsum and wallboard samples indicated that the chlorine concentrations were approximately 2 orders of magnitude higher than the mercury concentrations, suggesting possible chlorine association with mercury. 21 refs., 5 figs., 3 tabs.

  8. Measured Off-Grid LED Lighting System Performance

    SciTech Connect

    Granderson, Jessica; Galvin, James; Bolotov, Dmitriy; Clear, Robert; Jacobson, Arne; Mills, Evan

    2008-12-18

    This report is a product of our ongoing effort to support the development of high-quality yet affordable products for off-grid lighting in the developing world that have good potential to succeed in the market. The effort includes work to develop low-cost testing procedures, to identify useful performance metrics, and to facilitate the development of industry standards and product rating protocols. We conducted laboratory testing of nine distinct product lines. In some cases we also tested multiple generations of a single product line and/or operating modes for a product. The resultsare summarized in Table 1. We found that power consumption and light output varied by nearly a factor of 12, with efficacy varying by a factor of more than six. Of particular note, overall luminous efficacy varied from 8.2 to 53.1 lumens per watt. Color quality indices variedmaterially, especially for correlated color temperature. Maximum illuminance, beamcandlepower, and luminance varied by 8x, 32x, and 61x respectively, suggesting considerable differences among products in terms of service levels and visual comfort. Glare varied by1.4x, and was above acceptable thresholds in most cases. Optical losses play a role in overall performance, varying by a factor of 3.2 and ranging as high as 24percent. These findings collectively indicate considerable potential for improved product design.

  9. Sustainable LED Fluorescent Light Replacement Technology

    SciTech Connect

    2011-06-30

    Ilumisys and the National Center for Manufacturing Sciences (NCMS) partnered on a three-year project awarded by the United States (U.S.) Department of Energy (DOE), to quantify the impacts of LED lamps, incandescent lamps and fluorescent benchmark lamps over a product lifecycle – i.e. to develop a sustainable design and manufacturing strategy that addresses product manufacturing, use, recycling and disposal scenarios for LED-based lighting. Based on the knowledge gained from extensive product tear-down studies of fluorescent and screw-in lighting products, lifecycle assessment tools, and accelerated lifecycle testing protocols, an interactive Sustainable LED Design Guide has been developed to aid architectural and lighting designers and engineers in making design decisions that consider three important environmental impacts (greenhouse gas emissions, energy use and mercury emission) across all phases of the life of an LED lighting product. Critical information developed for the lifecycle analysis and product feature comparisons is the useful life of the lighting product as well as its performance. The Design Guide is available at www.ncms.org, and was developed based on operational and durability testing of a variety of lighting products including power consumption, light output, and useful life of a lamp in order to allow a more realistic comparison of lamp designs. This report describes the main project tasks, results and innovative features of the lifecycle assessment (LCA)-based design tools, and the key considerations driving the sustainable design of LED lighting systems. The Design Guide incorporates the following three novel features for efficiently evaluating LED lighting features in value-chains: • Bill-of-Materials (BOM) Builder – Designers may import process data for each component and supply functional data for the product, including power, consumption, lumen output and expected useful life. • Environmental Impact Review – Designs are

  10. Prospects for LED lighting.

    SciTech Connect

    Tsao, Jeffrey Yeenien; Gee, James Martin; Simmons, Jerry Alvon

    2003-08-01

    Solid-state lighting using light-emitting diodes (LEDs) has the potential to reduce energy consumption for lighting by 50% while revolutionizing the way we illuminate our homes, work places, and public spaces. Nevertheless, substantial technical challenges remain in order for solid-state lighting to significantly displace the well-developed conventional lighting technologies. We review the potential of LED solid-state lighting to meet the long-term cost goals.

  11. Tips: Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    a similar shape to traditional incandescent bulbs. CFLs contain a very small amount of mercury and require special handling if they are broken. CFLs should be recycled at the end...

  12. Low-Cost Options for Moderate Levels of Mercury Control

    SciTech Connect

    Sharon Sjostrom

    2008-02-09

    This is the final technical report for a three-site project that is part of an overall program funded by the U.S. Department of Energy's National Energy Technology Laboratory (DOE/NETL) and industry partners to obtain the necessary information to assess the feasibility and costs of controlling mercury from coal-fired utility plants. This report summarizes results from tests conducted at MidAmerican's Louisa Generating Station and Entergy's Independence Steam Electric Station (ISES) and sorbent screening at MidAmerican's Council Bluffs Energy Center (CBEC) (subsequently renamed Walter Scott Energy Center (WSEC)). Detailed results for Independence and Louisa are presented in the respective Topical Reports. As no full-scale testing was conducted at CBEC, screening updates were provided in the quarterly updates to DOE. ADA-ES, Inc., with support from DOE/NETL, EPRI, and other industry partners, has conducted evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. An overview of each plant configuration is presented: (1) MidAmerican's Louisa Generating Station burns Powder River Basin (PRB) coal in its 700-MW Unit 1 and employs hot-side electrostatic precipitators (ESPs) with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal. (2) MidAmerican's Council Bluffs Energy Center typically burns PRB coal in its 88-MW Unit 2. It employs a hot-side ESP for particulate control. Solid sorbents were screened for hot-side injection. (3) Entergy's Independence Steam Electric Station typically burns PRB coal in its 880-MW Unit 2. Various sorbent injection tests were conducted on 1/8 to 1/32 of the flue gas stream either within or in front of one

  13. Lighting Developments to 2030

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Energy Frontier Research Centers: Solid-State Lighting Science Center for Frontiers of ... Twitter Google + Vimeo Newsletter Signup SlideShare Lighting Developments to 2030 Home...

  14. Exciting White Lighting

    Energy.gov [DOE]

    Windows that emit light and are more energy efficient? Universal Display’s PHOLED technology enables windows that have transparent light-emitting diodes in them.

  15. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    more comprehensive understanding of commercial lighting and the potential for lighting energy savings. Steps to build on this analysis can be taken in many directions. One...

  16. Light Creation Materials

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management ... Lighting Science EFRCOverviewLight Creation Materials ...

  17. Leavenworth Tree Lighting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Join HERO for our annual Leavenworth Tree Lighting Ceremony & Shopping SATURDAY DECEMBER 12, 2015 Leavenworth Christmas Lighting Festival Visitors return year after year for some...

  18. Tips: Shopping for Lighting

    Energy.gov [DOE]

    When shopping for lighting, you can now use the Lighting Facts label and lumens to compare bulbs and purchase a bulb with the amount of brightness you want.

  19. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    are also under consideration. Outside the DOE, the Environmental Protection Agency's Green Lights program promotes energy-efficient lighting as a means to reducing...

  20. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    Motivation and Computation of Lighting Measures Floorspace by Lighting Equipment Configuration As described in Appendix A, for each building b, the CBECS data set has the total...

  1. residential-lighting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Efficiency Progress Report Evaluation Utility Toolkit Residential Lighting Market Research The Residential Lighting Market Research Project will estimate market savings from...

  2. Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton

    SciTech Connect

    David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

    2007-03-31

    The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being

  3. Cree LED Lighting Solutions Formerly LED Lighting Fixtures LLF...

    OpenEI (Open Energy Information) [EERE & EIA]

    LED Lighting Solutions Formerly LED Lighting Fixtures LLF Jump to: navigation, search Name: Cree LED Lighting Solutions (Formerly LED Lighting Fixtures (LLF)) Place: Morrisville,...

  4. Light Duty Combustion Research: Advanced Light-Duty Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments 2009 DOE Hydrogen Program and ...

  5. Atmospheric Mercury near Salmon Falls Creek Reservoir in Southern Idaho

    SciTech Connect

    Michael L. Abbott; Jeffrey J. Einerson

    2007-12-01

    Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over two-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran mercury analyzers. GEM, RGM, and particulate mercury (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize mercury air concentrations in the southern Idaho area for the first time, estimate mercury dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 0.9 ng m-3) and RGM (8.1 5.6 pg m-3) concentrations occurring in the summer and lower values in the winter (1.32 0.3 ng m-3, 3.2 2.9 pg m-3 for GEM, RGM respectively). The summer-average HgP concentrations were generally below detection limit (0.6 1 pg m-3). Seasonally-averaged deposition velocities calculated using a resistance model were 0.034 0.032, 0.043 0.040, 0.00084 0.0017 and 0.00036 0.0011 cm s-1 for GEM (spring, summer, fall, and winter, respectively) and 0.50 0.39, 0.40 0.31, 0.51 0.43 and 0.76 0.57 cm s-1 for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 3.3 g m-2, or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2 12 ng m-3) and RGM (50 - 150 pg m-3) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicated predominant source directions from the southeast (western Utah, northeastern Nevada) through the southwest (north-central Nevada) with fewer inputs from the northwest (southeastern Oregon and southwestern Idaho).

  6. EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS

    SciTech Connect

    J.A. Withum; S.C. Tseng; J.E. Locke

    2005-11-01

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dryer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the seventh in a series of topical reports, describes the results and analysis of mercury sampling performed on a 1,300 MW unit burning a bituminous coal containing three percent sulfur. The unit was equipped with an ESP and a limestone-based wet FGD to control particulate and SO2 emissions, respectively. At the time of sampling an SCR was not installed on this unit. Four sampling tests were performed in September 2003. Flue gas mercury speciation and concentrations were determined at the ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. The results show that the FGD inlet flue gas oxidized:elemental mercury ratio was roughly 2:1, with 66% oxidized mercury and 34% elemental mercury. Mercury removal, on a coal

  7. PFP Emergency Lighting Study

    SciTech Connect

    BUSCH, M.S.

    2000-02-02

    NFPA 101, section 5-9 mandates that, where required by building classification, all designated emergency egress routes be provided with adequate emergency lighting in the event of a normal lighting outage. Emergency lighting is to be arranged so that egress routes are illuminated to an average of 1.0 footcandle with a minimum at any point of 0.1 footcandle, as measured at floor level. These levels are permitted to drop to 60% of their original value over the required 90 minute emergency lighting duration after a power outage. The Plutonium Finishing Plant (PFP) has two designations for battery powered egress lights ''Emergency Lights'' are those battery powered lights required by NFPA 101 to provide lighting along officially designated egress routes in those buildings meeting the correct occupancy requirements. Emergency Lights are maintained on a monthly basis by procedure ZSR-12N-001. ''Backup Lights'' are battery powered lights not required by NFPA, but installed in areas where additional light may be needed. The Backup Light locations were identified by PFP Safety and Engineering based on several factors. (1) General occupancy and type of work in the area. Areas occupied briefly during a shiftly surveillance do not require backup lighting while a room occupied fairly frequently or for significant lengths of time will need one or two Backup lights to provide general illumination of the egress points. (2) Complexity of the egress routes. Office spaces with a standard hallway/room configuration will not require Backup Lights while a large room with several subdivisions or irregularly placed rooms, doors, and equipment will require Backup Lights to make egress safer. (3) Reasonable balance between the safety benefits of additional lighting and the man-hours/exposure required for periodic light maintenance. In some plant areas such as building 236-Z, the additional maintenance time and risk of contamination do not warrant having Backup Lights installed in all rooms

  8. CALiPER Exploratory Study: Recessed Troffer Lighting

    SciTech Connect

    Miller, Naomi J.; Royer, Michael P.; Poplawski, Michael E.

    2013-04-28

    This report describes an exploration of troffer lighting as used in office and classroom spaces, which was conducted by the CALiPER program. Twenty-four pairs of 2×2 and 2×4 troffers were procured anonymously, documented, tested for photometric and electrical performance, and installed in a mockup office space in Portland, Oregon. Three of the pairs were T8 fluorescent benchmark products, 12 were dedicated LED troffers, five were fluorescent troffers modified for LED lamps (sometimes referred to as "tubes"), and another four troffers were modified with LED retrofit kits. The modifications were performed by a commercial electrical contractor, following the instructions provided by the retrofit lamp or kit manufacturer. Once installed in the mockup facility, the converted luminaires were examined by a NRTL (Nationally Recognized Testing Laboratory) safety expert, who provided feedback on safety issues. In September 2012, a group of lighting designers, engineers, and facility managers were brought in to observe the LED luminaires in comparison to fluorescent benchmarks. This report documents performance in measures that go beyond illuminance values or luminaire efficacy. Dedicated LED troffers are ready to compete with fluorescent troffers in terms of efficacy (lumens per watt), and in many lighting quality issues such as glare, light distribution, visual appearance, and color quality. That is not to say that each one is stellar, but each one tested in this CALiPER study bested the fluorescent benchmarks in terms of efficacy, and almost all were rated highly in several categories -- only one luminaire of twelve performed consistently poorly.

  9. Evaluation of mercury in liquid waste processing facilities - Phase I report

    SciTech Connect

    Jain, V.; Occhipinti, J. E.; Shah, H.; Wilmarth, W. R.; Edwards, R. E.

    2015-07-01

    This report provides a summary of Phase I activities conducted to support an Integrated Evaluation of Mercury in Liquid Waste System (LWS) Processing Facilities. Phase I activities included a review and assessment of the liquid waste inventory and chemical processing behavior of mercury using a system by system review methodology approach. Gaps in understanding mercury behavior as well as action items from the structured reviews are being tracked. 64% of the gaps and actions have been resolved.

  10. Evaluation of Mercury in Liquid Waste Processing Facilities - Phase I Report

    SciTech Connect

    Jain, V.; Occhipinti, J.; Shah, H.; Wilmarth, B.; Edwards, R.

    2015-07-01

    This report provides a summary of Phase I activities conducted to support an Integrated Evaluation of Mercury in Liquid Waste System (LWS) Processing Facilities. Phase I activities included a review and assessment of the liquid waste inventory and chemical processing behavior of mercury using a system by system review methodology approach. Gaps in understanding mercury behavior as well as action items from the structured reviews are being tracked. 64% of the gaps and actions have been resolved.

  11. Obtaining accurate amounts of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, Mark W.; George, William A.

    1987-01-01

    A process for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H.sub.2 O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg.sub.2 Cl.sub.2. The method for doing this involves dissolving a precise amount of Hg.sub.2 Cl.sub.2 in an electrolyte solution comprised of concentrated HCl and H.sub.2 O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg.

  12. Obtaining accurate amounts of mercury from mercury compounds via electrolytic methods

    DOEpatents

    Grossman, M.W.; George, W.A.

    1987-07-07

    A process is described for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H[sub 2]O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg[sub 2]Cl[sub 2]. The method for doing this involves dissolving a precise amount of Hg[sub 2]Cl[sub 2] in an electrolyte solution comprised of concentrated HCl and H[sub 2]O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg. 1 fig.

  13. Lighting Energy Conservation Measures | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Technology Deployment Efficient Technologies & Products Lighting Energy Conservation Measures Lighting Energy Conservation Measures Lighting Improvements Lighting ...

  14. Achieving Energy Savings with Highly-Controlled Lighting in an Open-Plan Office

    SciTech Connect

    Rubinstein, Francis; Enscoe, Abby

    2010-04-19

    An installation in a Federal building tested the effectiveness of a highly-controlled, workstation-specific lighting retrofit. The study took place in an open-office area with 86 cubicles and low levels of daylight. Each cubicle was illuminated by a direct/indirectpendant luminaire with three 32 watt lamps, two dimmable DALI ballasts, and an occupancy sensor. A centralized control system programmed all three lamps to turn on and off according to occupancy on a workstation-by-workstation basis. Field measurements taken over the course of several monthsdemonstrated 40% lighting energy savings compared to a baseline without advanced controls that conforms to GSA's current retrofit standard. A photometric analysis found that the installation provided higher desktop light levels than the baseline, while an occupant survey found that occupants in general preferred the lighting system to thebaseline.Simple payback is fairly high; projects that can achieve lower installation costs and/or higher energy savings and those in which greenhouse gas reduction and occupant satisfaction are significant priorities provide the ideal setting for workstation-specific lighting retrofits.

  15. Pedestrian Friendly Outdoor Lighting

    SciTech Connect

    Miller, N. J.; Koltai, R. N.; McGowan, T. K.

    2013-12-01

    The GATEWAY program followed two pedestrian-scale lighting projects that required multiple mockups – one at Stanford University in California and the other at Chautauqua Institution in upstate New York. The report provides insight into pedestrian lighting criteria, how they differ from street and area lighting criteria, and how solid-state lighting can be better applied in pedestrian applications.

  16. FGD Additives to Segregate and Sequester Mercury in Solid Byproducts - Final Report

    SciTech Connect

    Searcy, K; Bltyhe, G M; Steen, W A

    2012-02-28

    Many mercury control strategies for U.S. coal-fired power generating plants involve co-benefit capture of oxidized mercury from flue gases treated by wet flue gas desulfurization (FGD) systems. For these processes to be effective at overall mercury control, the captured mercury must not be re-emitted to the atmosphere or into surface or ground water. The project sought to identify scrubber additives and FGD operating conditions under which mercury re-emissions would decrease and mercury would remain in the liquor and be blown down from the system in the chloride purge stream. After exiting the FGD system, mercury would react with precipitating agents to form stable solid byproducts and would be removed in a dewatering step. The FGD gypsum solids, free of most of the mercury, could then be disposed or processed for reuse as wallboard or in other beneficial reuse. The project comprised extensive bench-scale FGD scrubber tests in Phases I and II. During Phase II, the approaches developed at the bench scale were tested at the pilot scale. Laboratory wastewater treatment tests measured the performance of precipitating agents in removing mercury from the chloride purge stream. Finally, the economic viability of the approaches tested was evaluated.

  17. Real-time analysis of total, elemental, and total speciated mercury

    SciTech Connect

    Schlager, R.J.; Wilson, K.G.; Sappey, A.D.

    1995-11-01

    ADA Technologies, Inc., is developing a continuous emissions monitoring system that measures the concentrations of mercury in flue gas. Mercury is emitted as an air pollutant from a number of industrial processes. The largest contributors of these emissions are coal and oil combustion, municipal waste combustion, medical waste combustion, and the thermal treatment of hazardous materials. It is difficult, time consuming, and expensive to measure mercury emissions using current testing methods. Part of the difficulty lies in the fact that mercury is emitted from sources in several different forms, such as elemental mercury and mercuric chloride. The ADA analyzer measures these emissions in real time, thus providing a number of advantages over existing test methods: (1) it will provide a real-time measure of emission rates, (2) it will assure facility operators, regulators, and the public that emissions control systems are working at peak efficiency, and (3) it will provide information as to the nature of the emitted mercury (elemental mercury or speciated compounds). This update presents an overview of the CEM and describes features of key components of the monitoring system--the mercury detector, a mercury species converter, and the analyzer calibration system.

  18. Mercury Vapor At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Silver Peak Area (Henkle, Et Al., 2005) Exploration Activity Details...

  19. Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    19811025; Houston, TX. Davis, CA: Geothermal Resources Council; p. 95-98 S.C. Smith. 2003. Thermally Speciated Mercury in Mineral Exploration. In: Programs & Abstracts:...

  20. Mercury capture within coal-fired power plant electrostatic precipitators: model evaluation

    SciTech Connect

    Clack, H.L.

    2009-03-01

    Efforts to reduce anthropogenic mercury emissions worldwide have recently focused on a variety of sources, including mercury emitted during coal combustion. Toward that end, much research has been ongoing seeking to develop new processes for reducing coal combustion mercury emissions. Among air pollution control processes that can be applied to coal-fired boilers, electrostatic precipitators (ESPs) are by far the most common, both on a global scale and among the principal countries of India, China, and the U.S. that burn coal for electric power generation. A previously reported theoretical model of in-flight mercury capture within ESPs is herein evaluated against data from a number of full-scale tests of activated carbon injection for mercury emissions control. By using the established particle size distribution of the activated carbon and actual or estimated values of its equilibrium mercury adsorption capacity, the incremental reduction in mercury concentration across each ESP can be predicted and compared to experimental results. Because the model does not incorporate kinetics associated with gas-phase mercury transformation or surface adsorption, the model predictions represent the mass-transfer-limited performance. Comparing field data to model results reveals many facilities performing at or near the predicted mass-transfer-limited maximum, particularly at low rates of sorbent injection. Where agreement is poor between field data and model predictions, additional chemical or physical phenomena may be responsible for reducing mercury removal efficiencies. 26 refs., 5 figs., 1 tab.

  1. Packaging a liquid metal ESD with micro-scale Mercury droplet...

    Office of Scientific and Technical Information (OSTI)

    There are many challenges surrounding the deposition and containment of micro scale mercury droplets. Novel methods of micro liquid transfer are developed to deliver controllable ...

  2. Final Long-Term Management and Storage of Elemental Mercury Supplement...

    Office of Environmental Management (EM)

    Elemental Mercury Supplemental Environmental Impact Statement 2-58 Commentor No. 15: Carlos ... establishes basic standards and procedures for the receipt, management, and ...

  3. Kids vs. Mercury: Food fight at the creek | Y-12 National Security Complex

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Kids vs. Mercury: Food ... Kids vs. Mercury: Food fight at the creek Posted: May 7, 2014 - 5:26pm | Y-12 Report | Volume 10, Issue 2 | 2014 For years Y-12 has dealt with environmental mercury contamination from historical manufacturing processes. The potential for mercury to seep into nearby streams and harm aquatic life is a continuing issue. To combat the issue, Y-12 recently opened its doors and a local creek to sharp, energetic sixth-grade innovators who have developed a proprietary

  4. Mercury Vapor At Valley Of Ten Thousand Smokes Region Area (Kodosky...

    OpenEI (Open Energy Information) [EERE & EIA]

    on air-dried ( < 80 mesh fraction) samples using the Jerome Instrument 301 Au-film Hg degrees detector. References Lawrence G. Kodosky (1989) Surface Mercury Geochemistry As...

  5. Packaging a liquid metal ESD with micro-scale Mercury droplet.

    SciTech Connect

    Barnard, Casey Anderson

    2011-08-01

    A liquid metal ESD is being developed to provide electrical switching at different acceleration levels. The metal will act as both proof mass and electric contact. Mercury is chosen to comply with operation parameters. There are many challenges surrounding the deposition and containment of micro scale mercury droplets. Novel methods of micro liquid transfer are developed to deliver controllable amounts of mercury to the appropriate channels in volumes under 1 uL. Issues of hermetic sealing and avoidance of mercury contamination are also addressed.

  6. Concentrations and mass balance of mercury in a fluidized bed sewage sludge incineration plant

    SciTech Connect

    Saenger, M.; Werther, J.; Hanssen, H.

    1999-07-01

    The fluidized bed sewage sludge incineration plant of the city of Hamburg started its operation in May 1997. In cooperation with Hamburger Stadtentwaesserung the Technical University Hamburg-Harburg undertook an experimental program to measure the mass balance of mercury across this plant. During the first months of full operation the mercury concentrations in the flue gas and in the solid residues were measured. The measurements show that the concentration in the raw flue gas is between 500 to 950 {micro}g/m{sup 3} and part of the elemental mercury depends on the chlorine content of the fuel. The concentration of the mercury in the flue gas is reduced over the first scrubber to 35--460 {micro}m/m{sup 3}. Some 77% of the mercury input are found in the sediment separated from the liquid of the acid scrubber. It is remarkable that the concentration of the elemental mercury increases while the gas passes through the scrubber. The concentration of mercury in the cleaned stack gas is less than 40 {micro}g/m{sup 3}. Since it is generally known that it is not easy to meet the limit of 50 {micro}g mercury per m{sup 3} (standard conditions, dry basis) of flue gas which is set by the German regulations for waste incineration, the measurements provide a comprehensive picture of the fate of mercury in a fluidized bed sludge incineration plant.

  7. Demonstration Assessment of Light Emitting Diode (LED) Residential Downlights and Undercabinet Lights in the Lane County Tour of Homes, Eugene, Oregon

    SciTech Connect

    Ton, My K.; Richman, Eric E.; Gilbride, Theresa L.

    2008-11-10

    In August 2008 the Pacific Northwest National Laboratory (PNNL) conducted a light emitting diode (LED) residential lighting demonstration project for the U.S. Department of Energy (DOE), Office of Building Technologies, as part of DOE’s Solid State Lighting (SSL) Technology Demonstration Gateway Program. Two lighting technologies, an LED replacement for downlight lamps (bulbs) and an LED undercabinet lighting fixture, were tested in the demonstration which was conducted in two homes built for the 2008 Tour of Homes in Eugene, Oregon. The homes were built by the Lane County Home Builders Association (HBA), and Future B Homes. The Energy Trust of Oregon (ETO) also participated in the demonstration project. The LED downlight product, the LR6, made by Cree LED Lighting Solutions acts as a screw-in replacement for incandescent and halogen bulbs in recessed can downlights. The second product tested is Phillips/Color Kinetics’ eW® Profile Powercore undercabinet fixture designed to mount under kitchen cabinets to illuminate the countertop and backsplash surfaces. Quantitative and qualitative measurements of light performance and electrical power usage were taken at each site before and after initially installed halogen and incandescent lamps were replaced with the LED products. Energy savings and simple paybacks were also calculated and builders who toured the homes were surveyed for their responses to the LED products. The LED downlight product drew 12 Watts of power, cutting energy use by 82% compared to the 65W incandescent lamp and by 84% compared to the 75W halogen lamp. The LED undercabinet fixture drew 10 watts, cutting energy use by 83% to 90% compared to the halogen product, which was tested at two power settings: a low power 60W setting and a high power 105W setting. The LED downlight consistently provided more light than the halogen and incandescent lamps in horizontal measurements at counter height and floor level. It also outperformed in vertical

  8. Method of preparing mercury with an arbitrary isotopic distribution

    DOEpatents

    Grossman, Mark W.; George, William A.

    1986-01-01

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg.sub.2 Cl.sub.2, corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H.sub.2 O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H.sub.2 O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered.

  9. Compatibility of structural materials with liquid bismuth, lead, and mercury

    SciTech Connect

    Weeks, J.R.

    1996-06-01

    During the 1950s and 1960s, a substantial program existed at Brookhaven National Laboratory as part of the Liquid Metal Fuel reactor program on the compatibility of bismuth, lead, and their alloys with structural materials. Subsequently, compatibility investigations of mercury with structural materials were performed in support of development of Rankine cycle mercury turbines for nuclear applications. The present talk will review present understanding of the corrosion/mass-transfer reactions of structural materials with these liquid metal coolants. Topics to be discussed include the basic solubility relationships of iron, chromium, nickel, and refractory metals in these liquid metals, the results of inhibition studies, the role of oxygen on the corrosion processes, and specialized topics such as cavitation-corrosion and liquid metal embrittlement. Emphasis will be placed on utilizing the understanding gained in this earlier work on the development of heavy liquid metal targets in spallation neutron sources.

  10. Method of preparing mercury with an arbitrary isotopic distribution

    DOEpatents

    Grossman, M.W.; George, W.A.

    1986-12-16

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg[sub 2]Cl[sub 2], corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H[sub 2]O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H[sub 2]O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered. 1 fig.

  11. LED Lighting Facts Snapshot: Indoor Ambient Lighting

    SciTech Connect

    2013-04-01

    LED Lighting Facts Snapshot reports reveal how today's products really perform, drawing on analysis of verified performance data from the program's online product list.

  12. EIS-0423: Storage and Management of Elemental Mercury

    Energy.gov [DOE]

    This EIS evaluates the environmental impacts associated with the reasonable alternatives for managing and storing elemental mercury at seven candidate locations (i.e., Colorado, Idaho, Missouri, Nevada, South Carolina, Texas, and Washington). The U.S. Environmental Protection Agency, the Texas Commission on Environmental Quality, and the Mesa County Board of Commissioners (Mesa County, Colorado) are cooperating agencies in the preparation of this EIS.

  13. Separation of iodine from mercury containing scrubbing solutions

    DOEpatents

    Burger, Leland L.; Scheele, Randall D.

    1979-01-01

    Radioactive iodines can be recovered from a nitric acid scrub solution containing mercuric nitrate by passing a current through the scrub solution to react the iodine with the mercuric nitrate to form mercuric iodate which precipitates out. The mercuric iodate can then be reacted to recover the radioiodine for further processing into a form suitable for long-term storage and to recover the mercury for recycling.

  14. Environmental Remediation program completes legacy mercury cleanup near

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Smith's Marketplace Stories » Legacy slope-side cleanup Environmental Remediation program completes legacy mercury cleanup near Smith's Marketplace Los Alamos National Laboratory performed a high-angle canyon-side cleanup on U.S. Department of Energy property just south of Smith's Marketplace. May 1, 2015 A telescoping crane hoists a spider excavator over Los Alamos Canyon before placing it on the canyon slope to excavate historically contaminated soil. In ongoing efforts to reduce the

  15. Semi-continuous detection of mercury in gases

    DOEpatents

    Granite, Evan J.; Pennline, Henry W.

    2011-12-06

    A new method for the semi-continuous detection of heavy metals and metalloids including mercury in gaseous streams. The method entails mass measurement of heavy metal oxides and metalloid oxides with a surface acoustic wave (SAW) sensor having an uncoated substrate. An array of surface acoustic wave (SAW) sensors can be used where each sensor is for the semi-continuous emission monitoring of a particular heavy metal or metalloid.

  16. Mercury and tritium removal from DOE waste oils

    SciTech Connect

    Klasson, E.T.

    1997-10-01

    This work covers the investigation of vacuum extraction as a means to remove tritiated contamination as well as the removal via sorption of dissolved mercury from contaminated oils. The radiation damage in oils from tritium causes production of hydrogen, methane, and low-molecular-weight hydrocarbons. When tritium gas is present in the oil, the tritium atom is incorporated into the formed hydrocarbons. The transformer industry measures gas content/composition of transformer oils as a diagnostic tool for the transformers` condition. The analytical approach (ASTM D3612-90) used for these measurements is vacuum extraction of all gases (H{sub 2}, N{sub 2}, O{sub 2}, CO, CO{sub 2}, etc.) followed by analysis of the evolved gas mixture. This extraction method will be adapted to remove dissolved gases (including tritium) from the SRS vacuum pump oil. It may be necessary to heat (60{degrees}C to 70{degrees}C) the oil during vacuum extraction to remove tritiated water. A method described in the procedures is a stripper column extraction, in which a carrier gas (argon) is used to remove dissolved gases from oil that is dispersed on high surface area beads. This method appears promising for scale-up as a treatment process, and a modified process is also being used as a dewatering technique by SD Myers, Inc. (a transformer consulting company) for transformers in the field by a mobile unit. Although some mercury may be removed during the vacuum extraction, the most common technique for removing mercury from oil is by using sulfur-impregnated activated carbon (SIAC). SIAC is currently being used by the petroleum industry to remove mercury from hydrocarbon mixtures, but the sorbent has not been previously tested on DOE vacuum oil waste. It is anticipated that a final process will be similar to technologies used by the petroleum industry and is comparable to ion exchange operations in large column-type reactors.

  17. LED Street Lighting

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    21, 2016 LED Street Lighting The American Medical Association's (AMA) recently adopted community guidance on street lighting adds another influential voice to issues that have been discussed in the lighting community for some time now, regarding light at night, its potential impacts on human health and the environment, and how best to minimize those impacts. While the AMA's guidance is intended to reduce the harmful human and environmental effects of street lighting in general, it focuses on

  18. lighting in the library

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The amount and quality of light around us affects our health, safety, comfort, and productivity. Our country spends more than $37 billion each year on electricity for lighting, but technologies developed during the past 10 years can help us cut lighting costs by 30% to 60% while enhancing lighting quality and reducing environmental impacts. In a typical indoor lighting system, 50 percent or more of the energy supplied to the lamp can be wasted by obsolete equipment, poor maintenance, or

  19. Survey of mercury, cadmium and lead content of household batteries

    SciTech Connect

    Recknagel, Sebastian; Radant, Hendrik; Kohlmeyer, Regina

    2014-01-15

    Highlights: • A well selected sample of 146 batteries was analysed for its heavy metals content. • A comparison was made between heavy metals contents in batteries in 2006 and 2011. • No significant change after implementation of the new EU Batteries Directive. • Severe differences in heavy metal contents were found in different battery-types. - Abstract: The objective of this work was to provide updated information on the development of the potential impact of heavy metal containing batteries on municipal waste and battery recycling processes following transposition of the new EU Batteries Directive 2006/66/EC. A representative sample of 146 different types of commercially available dry and button cells as well as lithium-ion accumulators for mobile phones were analysed for their mercury (Hg)-, cadmium (Cd)- and lead (Pb)-contents. The methods used for preparing the cells and analysing the heavy metals Hg, Cd, and Pb were either developed during a former study or newly developed. Several batteries contained higher mass fractions of mercury or cadmium than the EU limits. Only half of the batteries with mercury and/or lead fractions above the marking thresholds were labelled. Alkaline–manganese mono-cells and Li-ion accumulators, on average, contained the lowest heavy metal concentrations, while zinc–carbon batteries, on average, contained the highest levels.

  20. Sources of Mercury to East Fork Poplar Creek Downstream from the Y-12 National Security Complex: Inventories and Export Rates

    SciTech Connect

    Southworth, George R; Greeley Jr, Mark Stephen; Peterson, Mark J; Lowe, Kenneth Alan; Ketelle, Richard H; Floyd, Stephanie B

    2010-02-01

    East Fork Poplar Creek (EFPC) in Oak Ridge, Tennessee, has been heavily contaminated with mercury (also referred to as Hg) since the 1950s as a result of historical activities at the U.S. Department of Energy (DOE) Y-12 National Security Complex (formerly the Oak Ridge Y-12 Plant and hereinafter referred to as Y-12). During the period from 1950 to 1963, spills and leaks of elemental mercury (Hg{sup 0}) contaminated soil, building foundations, and subsurface drainage pathways at the site, while intentional discharges of mercury-laden wastewater added 100 metric tons of mercury directly to the creek (Turner and Southworth 1999). The inventory of mercury estimated to be lost to soil and rock within the facility was 194 metric tons, with another estimated 70 metric tons deposited in floodplain soils along the 25 km length of EFPC (Turner and Southworth 1999). Remedial actions within the facility reduced mercury concentrations in EFPC water at the Y-12 boundary from > 2500 ng/L to about 600 ng/L by 1999 (Southworth et al. 2000). Further actions have reduced average total mercury concentration at that site to {approx}300 ng/L (2009 RER). Additional source control measures planned for future implementation within the facility include sediment/soil removal, storm drain relining, and restriction of rainfall infiltration within mercury-contaminated areas. Recent plans to demolish contaminated buildings within the former mercury-use areas provide an opportunity to reconstruct the storm drain system to prevent the entry of mercury-contaminated water into the flow of EFPC. Such actions have the potential to reduce mercury inputs from the industrial complex by perhaps as much as another 80%. The transformation and bioaccumulation of mercury in the EFPC ecosystem has been a perplexing subject since intensive investigation of the issue began in the mid 1980s. Although EFPC was highly contaminated with mercury (waterborne mercury exceeded background levels by 1000-fold, mercury in

  1. Microbial- and thiosulfate-mediated dissolution of mercury sulfide minerals and transformation to gaseous mercury

    DOE PAGES [OSTI]

    Vázquez-Rodríguez, Adiari I.; Hansel, Colleen M.; Zhang, Tong; Lamborg, Carl H.; Santelli, Cara M.; Webb, Samuel M.; Brooks, Scott C.

    2015-06-23

    Mercury (Hg) is a toxic heavy metal that poses significant environmental and human health risks. Soils and sediments, where Hg can exist as the Hg sulfide mineral metacinnabar (β-HgS), represent major Hg reservoirs in aquatic environments. Metacinnabar has historically been considered a sink for Hg in all but severely acidic environments, and thus disregarded as a potential source of Hg back to aqueous or gaseous pools. In this study, we conducted a combination of field and laboratory incubations to identify the potential for metacinnabar as a source of dissolved Hg within near neutral pH environments and the underpinning (a)biotic mechanismsmore » at play. We show that the abundant and widespread sulfur-oxidizing bacteria of the genus Thiobacillus extensively colonized metacinnabar chips incubated within aerobic, near neutral pH creek sediments. Laboratory incubations of axenic Thiobacillus thioparus cultures led to the release of metacinnabar-hosted Hg(II) and subsequent volatilization to Hg(0). This dissolution and volatilization was greatly enhanced in the presence of thiosulfate, which served a dual role by enhancing HgS dissolution through Hg complexation and providing an additional metabolic substrate for Thiobacillus. These findings reveal a new coupled abiotic-biotic pathway for the transformation of metacinnabar-bound Hg(II) to Hg(0), while expanding the sulfide substrates available for neutrophilic chemosynthetic bacteria to Hg-laden sulfides. Lastly, they also point to mineral-hosted Hg as an underappreciated source of gaseous elemental Hg to the environment.« less

  2. Microbial- and thiosulfate-mediated dissolution of mercury sulfide minerals and transformation to gaseous mercury

    SciTech Connect

    Vázquez-Rodríguez, Adiari I.; Hansel, Colleen M.; Zhang, Tong; Lamborg, Carl H.; Santelli, Cara M.; Webb, Samuel M.; Brooks, Scott C.

    2015-06-23

    Mercury (Hg) is a toxic heavy metal that poses significant environmental and human health risks. Soils and sediments, where Hg can exist as the Hg sulfide mineral metacinnabar (β-HgS), represent major Hg reservoirs in aquatic environments. Metacinnabar has historically been considered a sink for Hg in all but severely acidic environments, and thus disregarded as a potential source of Hg back to aqueous or gaseous pools. In this study, we conducted a combination of field and laboratory incubations to identify the potential for metacinnabar as a source of dissolved Hg within near neutral pH environments and the underpinning (a)biotic mechanisms at play. We show that the abundant and widespread sulfur-oxidizing bacteria of the genus Thiobacillus extensively colonized metacinnabar chips incubated within aerobic, near neutral pH creek sediments. Laboratory incubations of axenic Thiobacillus thioparus cultures led to the release of metacinnabar-hosted Hg(II) and subsequent volatilization to Hg(0). This dissolution and volatilization was greatly enhanced in the presence of thiosulfate, which served a dual role by enhancing HgS dissolution through Hg complexation and providing an additional metabolic substrate for Thiobacillus. These findings reveal a new coupled abiotic-biotic pathway for the transformation of metacinnabar-bound Hg(II) to Hg(0), while expanding the sulfide substrates available for neutrophilic chemosynthetic bacteria to Hg-laden sulfides. Lastly, they also point to mineral-hosted Hg as an underappreciated source of gaseous elemental Hg to the environment.

  3. Mercury(II) nitroprusside: A framework with an unusual topology

    SciTech Connect

    Cano, A.; Osiry, H.; Reguera, L.; Lemus-Santana, A.A.; Reguera, E.

    2015-05-15

    The titled compound was prepared by the precipitation method from diluted aqueous solution of sodium nitroprusside and mercury(II) nitrate. The orange solid formed, with formula unit Hg[Fe(CN){sub 5}NO], crystallizes with an orthorhombic unit cell in the Pmna space group with cell parameters: a=11.2788(3), b=6.1965(3), and c=12.3786(6) Å. The unit cell accommodates four formula of the compound (Z=4). Its crystal structure was solved from X-ray powder patterns and then refined by the Rietveld method. The material framework is formed by tetrahedral coordination of Hg atoms at the N end of the equatorial CN groups of the [Fe(CN){sub 5}NO] building block. That framework results from the interpenetration of two identical sub-frameworks with a relative shift of (a/2, b/2, c/2). The sub-framework has two types of cavities, ellipsoidal and rhombohedral, with transversal section of ca. 4.5×9.2 Å and ca. 8.5 Å transversal section, respectively. That system of cavities results eclipsed by the relative shift of neighboring sub-frameworks. No transport of H{sub 2} and N{sub 2} molecules through the material framework was observed. The thermal decomposition also reveals limitation for the decomposition products diffusion through the practically compact structure. The structural study was complemented with TG, IR, UV–vis and N{sub 2} and H{sub 2} adsorption data. Neighboring Hg atoms are distant 4.54(3) Å, a relatively large distance to suppose the existence of metal–metal interaction. No previous study on the crystal structure and related properties of mercury(II) nitroprusside has been reported. - Graphical abstract: Mercury(II) nitroprusside framework formed by two identical interpenetrated porous subframeworks where neighboring cavities appear eclipsed. - Highlights: • Interpenetrated frameworks in metal nitroprusside. • Eclipsed porous framework in metal nitroprusside. • Structure and related properties for mercury(II) nitroprusside. • Spectral features for

  4. Evaluation of Mercury Emissions from Coal-Fired Facilities with SCR and FGD Systems

    SciTech Connect

    J. A. Withum; S. C. Tseng; J. E. Locke

    2006-01-31

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NO{sub x}, and SO{sub 2} control technologies. It is expected that these data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of SCR catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the ninth in a series of topical reports, describes the results and analysis of mercury sampling performed on Unit 1 at Plant 7, a 566 MW unit burning a bituminous coal containing 3.6% sulfur. The unit is equipped with a SCR, ESP, and wet FGD to control NO{sub x}, particulate, and SO{sub 2} emissions

  5. Tips: Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Tips: Lighting Tips: Lighting Lighting choices save you money. Energy-efficient light bulbs are available in a wide variety of sizes and shapes. Lighting choices save you money....

  6. Bench-scale vitrification studies with Savannah River Site mercury contaminated soil

    SciTech Connect

    Cicero, C.A.; Bickford, D.F.

    1995-12-31

    The Savannah River Technology Center (SRTC) has been charted by the Department of Energy (DOE)--Office of Technology Development (OTD) to investigate vitrification technology for the treatment of Low Level Mixed Wastes (LLMW). In fiscal year 1995, mercury containing LLMW streams were targeted. In order to successfully apply vitrification technology to mercury containing LLMW, the types and quantities of glass forming additives necessary for producing homogeneous glasses from the wastes have to be determined and the treatment for the mercury portion must also be determined. Selected additives should ensure that a durable and leach resistant waste form is produced, while the mercury treatment should ensure that hazardous amounts of mercury are not released into the environment. The mercury containing LLMW selected for vitrification studies at the SRTC was mercury contaminated soil from the TNX pilot-plant facility at the Savannah River Site (SRS). Samples of this soil were obtained so bench-scale vitrification studies could be performed at the SRTC to determine the optimum waste loading obtainable in the glass product without sacrificing durability and leach resistance. Vitrifying this waste stream also required offgas treatment for the capture of the vaporized mercury.

  7. Avoiding exposure to mercury during inspection and maintenance operations in oil and gas processing

    SciTech Connect

    Wilhelm, S.M.

    1999-11-01

    Exposure to mercury and its compounds poses a potential health risk to workers involved with inspection and maintenance activities in facilities that process hydrocarbons containing significant amounts. The risks of exposure to mercury are often underestimated for a variety of reasons. Foremost is the fact that the exact amount of mercury present in processed petroleum often is not known with certainty. Secondly, the specific quantities of mercury compounds that may be present in hydrocarbon liquids seldom are known at all. Thirdly, monitoring for mercury vapor in work environments is not a routine procedure for many processing facilities. Lastly, mercury toxicity is gradual and produces no immediately apparent impairment that can easily be associated with occupational exposure. Superimposed on the risk issues are several aspects of the chemistry of mercury that make it illusive both to quantitative analysis and to detection in work environments. The combination of the cited factors increases the likelihood that workers who are inadvertently exposed to occupational environments that contain mercury will be adversely affected.

  8. Lighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Homes & Buildings » Lighting & Daylighting » Lighting Basics Lighting Basics August 15, 2013 - 5:12pm Addthis Text Version There are many different types of artificial lights (formally called "lamps" in the lighting industry,) which have different applications and uses. Types of lighting include: Fluorescent Lighting High-intensity Discharge Lighting Incandescent Lighting LED Lighting. New lamp designs that use energy-efficient technology are now readily available in the

  9. Solid-State Lighting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Energy Frontier Research Centers: Solid-State Lighting Science Center for Frontiers of ... Twitter Google + Vimeo Newsletter Signup SlideShare Solid-State Lighting HomeSolid-State ...

  10. Connected Lighting Systems Meeting

    Office of Energy Efficiency and Renewable Energy (EERE)

    There is a lot of buzz today about the Internet of Things and the convergence of intelligent controllable light sources, communication networks, sensors, and data exchange in future lighting...

  11. CONNECTED LIGHTING SYSTEMS MEETING

    Office of Energy Efficiency and Renewable Energy (EERE)

    There is a lot of buzz today about the Internet of Things and the convergence of intelligent controllable light sources, communication networks, sensors, and data exchange in future lighting...

  12. lighting in the library

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Determine the Feasibility of Installing Energy Efficient Lighting In this part of the exercise, you will plan a new approach to lighting your school library. This new plan will use ...

  13. lighting in the library

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The amount and quality of light around us affects our health, safety, comfort, and productivity. Our country spends more than 37 billion each year on electricity for lighting, but ...

  14. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, D.D.; MORRIS, S.M.; BANDO, A.; ET AL.

    2004-03-30

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. There are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows (Lopez et al. 2003)). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg

  15. Light-weight radioisotope heater unit (LWRHU) impact tests

    SciTech Connect

    Reimus, M. A. H.; Rinehart, G. H.; Herrera, A.; Lopez, B.; Lynch, C.; Moniz, P.

    1998-01-15

    The light-weight radioisotope heater unit (LWRHU) is a {sup 238}PuO{sub 2}-fueled heat source designed to provide one thermal watt in each of various locations on a spacecraft. Los Alamos National Laboratory designed, fabricated, and safety tested the LWRHU. The heat source consists of a hot-pressed {sup 238}PuO{sub 2} fuel pellet, a Pt-30Rh vented capsule, a pyrolytic graphite insulator, and a fineweave-pierced fabric graphite aeroshell assembly. To compare the performance of the LWRHUs fabricated for the Cassini mission with the performance of those fabricated for the Galileo mission, and to determine a failure threshold, two types of impact tests were conducted. A post-reentry impact test was performed on one of 180 flight-quality units produced for the Cassini mission and a series of sequential impact tests using simulant-fueled LWRHU capsules were conducted respectively. The results showed that deformation and fuel containment of the impacted Cassini LWRHU was similar to that of a previously tested Galileo LWRHU. Both units sustained minimal deformation of the aeroshell and fueled capsule; the fuel was entirely contained by the platinum capsule. Sequential impacting, in both end-on and side-on orientations, resulted in increased damage with each subsequent impact. Sequential impacting of the LWRHU appears to result in slightly greater damage than a single impact at the final impact velocity of 50 m/s.

  16. Light-weight radioisotope heater unit (LWRHU) impact tests

    SciTech Connect

    Reimus, M.A.; Rinehart, G.H.; Herrera, A.; Lopez, B.; Lynch, C.; Moniz, P.

    1998-01-01

    The light-weight radioisotope heater unit (LWRHU) is a {sup 238}PuO{sub 2}-fueled heat source designed to provide one thermal watt in each of various locations on a spacecraft. Los Alamos National Laboratory designed, fabricated, and safety tested the LWRHU. The heat source consists of a hot-pressed {sup 238}PuO{sub 2} fuel pellet, a Pt-30Rh vented capsule, a pyrolytic graphite insulator, and a fineweave-pierced fabric graphite aeroshell assembly. To compare the performance of the LWRHUs fabricated for the Cassini mission with the performance of those fabricated for the Galileo mission, and to determine a failure threshold, two types of impact tests were conducted. A post-reentry impact test was performed on one of 180 flight-quality units produced for the Cassini mission and a series of sequential impact tests using simulant-fueled LWRHU capsules were conducted respectively. The results showed that deformation and fuel containment of the impacted Cassini LWRHU was similar to that of a previously tested Galileo LWRHU. Both units sustained minimal deformation of the aeroshell and fueled capsule; the fuel was entirely contained by the platinum capsule. Sequential impacting, in both end-on and side-on orientations, resulted in increased damage with each subsequent impact. Sequential impacting of the LWRHU appears to result in slightly greater damage than a single impact at the final impact velocity of 50 m/s. {copyright} {ital 1998 American Institute of Physics.}

  17. Light-Weight Radioisotope Heater Unit (LWRHU) sequential impact tests

    SciTech Connect

    Reimus, M.A.H.; Rinehart, G.H.

    1997-08-01

    The light-weight radioisotope heater unit (LWRHU) is a {sup 238}PuO{sub 2}-fueled heat source designed to provide one thermal watt in each of various locations on a spacecraft. Los Alamos National Laboratory designed, fabricated, and safety tested the LWRHU. The heat source consists of a hot-pressed {sup 238}PuO{sub 2} fuel pellet, a Pt-30Rh vented capsule, a pyrolytic graphite insulator, and a fineweave-pierced fabric graphite aeroshell assembly. A series of sequential impacts tests using simulant-fueled LWRHU capsules was recently conducted to determine a failure threshold. Sequential impacting, in both end-on and side-on orientations, resulted in increased damage with each subsequent impact. Although the tests were conducted until the aeroshells were sufficiently distorted to be out of dimensional specification, the simulant-fueled capsules used in these tests were not severely deformed. Sequential impacting of the LWRHU appears to result in slightly greater damage than a single impact at the final impact velocity of 50 m/s. Postimpact examination revealed that the sequentially impacted capsules were slightly more deformed and were outside of dimensional specifications.

  18. Commercial / Industrial Lighting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    New Commercial Program Development Commercial Current Promotions Industrial Federal Agriculture Commercial & Industrial Lighting Efficiency Program The Commercial & Industrial...

  19. lighting in the library

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Determine the Feasibility of Installing Energy Efficient Lighting In this part of the exercise, you will plan a new approach to lighting your school library. This new plan will use less energy, cost less, and result in less greenhouse gas. Your plan will also include bottom line calculations and decision factors such as: identifying the costs and payback for buying and installing new lighting equipment and making a determination about whether or not the new, more efficient lighting will provide

  20. Mercury reduction studies to facilitate the thermal decontamination of phosphor powder residues from spent fluorescent lamps

    SciTech Connect

    Alves Durao, Walter; Andreva de Castro, Camila; Carvalhinho Windmoeller, Claudia

    2008-11-15

    This work investigates the thermal release of mercury from phosphor powder of spent fluorescent lamps. The treatment conditions and the ability of various reducing agents (primarily sodium borohydride) to lower the overall heating temperature required to improve the release of Hg have been evaluated. Hg species in samples were monitored in a thermal desorption atomic absorption spectrometer system, and total mercury was analyzed in a cold vapor atomic absorption spectrometer. Sodium borohydride was the best reducing agent among the ones studied. However, citric acid presented a high capacity to weaken mercury bonds with the matrix. When the sample was crushed with sodium borohydride for 40 min in a mass ratio of 10:1 (sample:reducing agent) and submitted to thermal treatment at 300 deg. C for 2 h, the concentration of mercury in a phosphor powder sample with 103 mg kg{sup -1} of mercury reached 6.6 mg kg{sup -1}.

  1. Evaluation of Mercury Emissions from Coal-Fired Facilities with SCR and FGD Systems

    SciTech Connect

    J. A. Withum; J. E. Locke

    2006-02-01

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NO{sub x}, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of SCR catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the tenth in a series of topical reports, describes the results and analysis of mercury sampling performed on two 468 MW units burning bituminous coal containing 1.3-1.7% sulfur. Unit 2 is equipped with an SCR, ESP, and wet FGD to control NO{sub x}, particulate, and SO{sub 2} emissions, respectively. Unit 1

  2. Induction Lighting: An Old Lighting Technology Made New Again | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Induction Lighting: An Old Lighting Technology Made New Again Induction Lighting: An Old Lighting Technology Made New Again July 27, 2009 - 5:00am Addthis John Lippert Induction lighting is one of the best kept secrets in energy-efficient lighting. Simply stated, induction lighting is essentially a fluorescent light without electrodes or filaments, the items that frequently cause other bulbs to burn out quickly. Thus, many induction lighting units have an extremely long life of up

  3. Effective White Light Options for Parking Area Lighting | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Effective White Light Options for Parking Area Lighting Effective White Light Options for Parking Area Lighting Document details lighting technologies that provide low-maintenance alternatives to high-pressure sodium lighting. Download the document detailing effective white light options for parking area lighting. (189.54 KB) More Documents & Publications LED Provides Effective and Efficient Parking Area Lighting at the NAVFAC Engineering Service Center Demonstration Assessment of

  4. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect

    Constance Senior; Temi Linjewile

    2003-10-31

    This is the third Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-03NT41728. The objective of this program is to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel. The Electric Power Research Institute (EPRI) and Argillon GmbH are providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, the second set of mercury measurements was made after the catalysts had been exposed to flue gas for about 2,000 hours. There was good agreement between the Ontario Hydro measurements and the SCEM measurements. Carbon trap measurements of total mercury agreed fairly well with the SCEM. There did appear to be some loss of mercury in the sampling system toward the end of the sampling campaign. NO{sub x} reductions across the catalysts ranged from 60% to 88%. Loss of total mercury across the commercial catalysts was not observed, as it had been in the March/April test series. It is not clear whether this was due to aging of the catalyst or to changes in the sampling system made between March/April and August. In the presence of ammonia, the blank monolith showed no oxidation. Two of the commercial catalysts showed mercury oxidation that was comparable to that in the March/April series. The other three commercial catalysts showed a decrease in mercury oxidation relative to the March/April series. Oxidation of mercury increased without ammonia present. Transient experiments showed that when ammonia was turned on, mercury appeared to desorb from the catalyst, suggesting displacement of adsorbed mercury by the ammonia.

  5. The retention time of inorganic mercury in the brain — A systematic review of the evidence

    SciTech Connect

    Rooney, James P.K.

    2014-02-01

    Reports from human case studies indicate a half-life for inorganic mercury in the brain in the order of years—contradicting older radioisotope studies that estimated half-lives in the order of weeks to months in duration. This study systematically reviews available evidence on the retention time of inorganic mercury in humans and primates to better understand this conflicting evidence. A broad search strategy was used to capture 16,539 abstracts on the Pubmed database. Abstracts were screened to include only study types containing relevant information. 131 studies of interest were identified. Only 1 primate study made a numeric estimate for the half-life of inorganic mercury (227–540 days). Eighteen human mercury poisoning cases were followed up long term including autopsy. Brain inorganic mercury concentrations at death were consistent with a half-life of several years or longer. 5 radionucleotide studies were found, one of which estimated head half-life (21 days). This estimate has sometimes been misinterpreted to be equivalent to brain half-life—which ignores several confounding factors including limited radioactive half-life and radioactive decay from surrounding tissues including circulating blood. No autopsy cohort study estimated a half-life for inorganic mercury, although some noted bioaccumulation of brain mercury with age. Modelling studies provided some extreme estimates (69 days vs 22 years). Estimates from modelling studies appear sensitive to model assumptions, however predications based on a long half-life (27.4 years) are consistent with autopsy findings. In summary, shorter estimates of half-life are not supported by evidence from animal studies, human case studies, or modelling studies based on appropriate assumptions. Evidence from such studies point to a half-life of inorganic mercury in human brains of several years to several decades. This finding carries important implications for pharmcokinetic modelling of mercury and potentially for

  6. The use of a mercury biosensor to evaluate the bioavailability of mercury-thiol complexes and mechanisms of mercury uptake in bacteria

    SciTech Connect

    Ndu, Udonna; Barkay, Tamar; Mason, Robert P.; Schartup, Amina Traore; Al-Farawati, Radwan; Liu, Jie; Reinfelder, John R.; Chang, Yung -Fu

    2015-09-15

    We discuss as mercury (Hg) biosensors are sensitive to only intracellular Hg, they are useful in the investigation of Hg uptake mechanisms and the effects of speciation on Hg bioavailability to microbes. In this study, bacterial biosensors were used to evaluate the roles that several transporters such as the glutathione, cystine/cysteine, and Mer transporters play in the uptake of Hg from Hg-thiol complexes by comparing uptake rates in strains with functioning transport systems to strains where these transporters had been knocked out by deletion of key genes. The Hg uptake into the biosensors was quantified based on the intracellular conversion of inorganic mercury (Hg(II)) to elemental mercury (Hg(0)) by the enzyme MerA. It was found that uptake of Hg from Hg-cysteine (Hg(CYS)2) and Hg-glutathione (Hg(GSH)2) complexes occurred at the same rate as that of inorganic complexes of Hg(II) into Escherichia coli strains with and without intact Mer transport systems. However, higher rates of Hg uptake were observed in the strain with a functioning Mer transport system. These results demonstrate that thiol-bound Hg is bioavailable to E. coli and that this bioavailability is higher in Hg-resistant bacteria with a complete Mer system than in non-resistant strains. No difference in the uptake rate of Hg from Hg(GSH)2 was observed in E. coli strains with or without functioning glutathione transport systems. There was also no difference in uptake rates between a wildtype Bacillus subtilis strain with a functioning cystine/cysteine transport system, and a mutant strain where this transport system had been knocked out. These results cast doubt on the viability of the hypothesis that the entire Hg-thiol complex is taken up into the cell by a thiol transporter. It is more likely that the Hg in the Hg-thiol complex is transferred to a transport protein on the cell membrane and is subsequently internalized.

  7. The use of a mercury biosensor to evaluate the bioavailability of mercury-thiol complexes and mechanisms of mercury uptake in bacteria

    DOE PAGES [OSTI]

    Ndu, Udonna; Barkay, Tamar; Mason, Robert P.; Schartup, Amina Traore; Al-Farawati, Radwan; Liu, Jie; Reinfelder, John R.; Chang, Yung -Fu

    2015-09-15

    We discuss as mercury (Hg) biosensors are sensitive to only intracellular Hg, they are useful in the investigation of Hg uptake mechanisms and the effects of speciation on Hg bioavailability to microbes. In this study, bacterial biosensors were used to evaluate the roles that several transporters such as the glutathione, cystine/cysteine, and Mer transporters play in the uptake of Hg from Hg-thiol complexes by comparing uptake rates in strains with functioning transport systems to strains where these transporters had been knocked out by deletion of key genes. The Hg uptake into the biosensors was quantified based on the intracellular conversionmore » of inorganic mercury (Hg(II)) to elemental mercury (Hg(0)) by the enzyme MerA. It was found that uptake of Hg from Hg-cysteine (Hg(CYS)2) and Hg-glutathione (Hg(GSH)2) complexes occurred at the same rate as that of inorganic complexes of Hg(II) into Escherichia coli strains with and without intact Mer transport systems. However, higher rates of Hg uptake were observed in the strain with a functioning Mer transport system. These results demonstrate that thiol-bound Hg is bioavailable to E. coli and that this bioavailability is higher in Hg-resistant bacteria with a complete Mer system than in non-resistant strains. No difference in the uptake rate of Hg from Hg(GSH)2 was observed in E. coli strains with or without functioning glutathione transport systems. There was also no difference in uptake rates between a wildtype Bacillus subtilis strain with a functioning cystine/cysteine transport system, and a mutant strain where this transport system had been knocked out. These results cast doubt on the viability of the hypothesis that the entire Hg-thiol complex is taken up into the cell by a thiol transporter. It is more likely that the Hg in the Hg-thiol complex is transferred to a transport protein on the cell membrane and is subsequently internalized.« less

  8. Consortium for Advanced Simulation of Light Water Reactors

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    for TVA Watts Bar plant * First-of-a-kind three-dimensional (3D) assessment of fuel pellet-to- cladding interaction * VERA 1.0 established with infrastructure and basic industry...

  9. OLED Lighting in the Offices of Aurora Lighting Design, Inc.

    Energy.gov [DOE] (indexed site)

    the Offices of Aurora Lighting Design, Inc. DOE Booth Pacific Northwest National Laboratory Leslie North, DesignerPrincipal Aurora Lighting Design, Inc. 2 OLED Lighting at Aurora ...

  10. Light emitting device comprising phosphorescent materials for white light generation

    DOEpatents

    Thompson, Mark E.; Dapkus, P. Daniel

    2014-07-22

    The present invention relates to phosphors for energy downconversion of high energy light to generate a broadband light spectrum, which emit light of different emission wavelengths.

  11. Light-storing photocatalyst

    SciTech Connect

    Zhang Junying; Pan Feng; Hao Weichang; Ge Qi; Wang Tianmian

    2004-12-06

    Light-storing photocatalyst was prepared by coating light-storing phosphor and TiO{sub 2} photocatalyst in sequence on ceramic. The light-storing photocatalyst can store light irradiation and emit slowly. Consequently, the photocatalyst remains active when the irradiation source is cut off. Rhodamine B (RhB) can be decomposed efficiently by this photocatalyst in the dark after it absorbs light irradiation. This photocatalyst is photoreactive in an outdoor environment or can save energy by supplying irradiation intermittently for the photocatalyst.

  12. Advanced Materials for Mercury 50 Gas Turbine Combustion System

    SciTech Connect

    Price, Jeffrey

    2008-09-30

    Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector

  13. Design, components, controls and operational experience of mercury circuits

    SciTech Connect

    Lielausis, O.

    1996-06-01

    The main activities of the Institute of Physics are connected with magnetohydrodynamics of incompressible media, first at all, liquid metals. Along side with Li, Na, NaK and low temperature eutectic InGaSn, mercury serves as one of the best working medium. A special Hg laboratory complex was built including a 350 m{sup 2} experimental hall. The amount of Hg in use reaches 8x10{sup 3} kg. As an important practical result the development and production of different electromagnetic pumps for heavy metals (Hg, Pb, Bi, Zn, Sn, InGaSn, steel) can be considered. The same can be said about new technologies for Hg chemical treatment (purification). Mercury is used as an effective modeling material for the investigation of a great number of metallurgical processes, as well as for thermohydraulic testing of systems, proposed for other (more aggressive or high temperature) heavy liquid metals. The laboratory is equipped with three easy transferable d=3-5 cm mercury loops as well as with a large closed 12 m long d=10 cm stationary loop. The electromagnetic feeding pump delivers 5 l/s at 5 atm. The loading mercury weights 4.7x10{sup 3} kg. For investigation in magnetohydrodynamics a 2 m long solenoid calculated for a 2 T magnetic field in a d=20cm bore is used, as well as an electromagnet providing 1.5 T in a 15 cm gap between round d=50 cm poles. Since in the case of Hg almost all traditional measuring techniques (including thermoanemometry) can be applied, complex physical problems can be considered. So, results gained in this laboratory, served as a base for ideas about 2D MHD turbulence, possessing all the strange features predicted by theory for 2D turbulence. So, recently it was showed that by means of an outer magnetic field the intensity of heat transfer can be enhanced by an order compared with an ordinary turbulent motion outside the field. Detailed modeling of heat transfer processes typical to the liquid metal blanket of proposed thermonuclear reactors was performed.

  14. Photonic crystal light source

    DOEpatents

    Fleming, James G.; Lin, Shawn-Yu; Bur, James A.

    2004-07-27

    A light source is provided by a photonic crystal having an enhanced photonic density-of-states over a band of frequencies and wherein at least one of the dielectric materials of the photonic crystal has a complex dielectric constant, thereby producing enhanced light emission at the band of frequencies when the photonic crystal is heated. The dielectric material can be a metal, such as tungsten. The spectral properties of the light source can be easily tuned by modification of the photonic crystal structure and materials. The photonic crystal light source can be heated electrically or other heating means. The light source can further include additional photonic crystals that exhibit enhanced light emission at a different band of frequencies to provide for color mixing. The photonic crystal light source may have applications in optical telecommunications, information displays, energy conversion, sensors, and other optical applications.

  15. Exposure to mercury among Spanish preschool children: Trend from birth to age four

    SciTech Connect

    Llop, Sabrina; Murcia, Mario; Aguinagalde, Xabier; Vioque, Jesus; Rebagliato, Marisa; Iñiguez, Carmen; Lopez-Espinosa, Maria-Jose; Amurrio, Ascensión; María Navarrete-Muñoz, Eva; and others

    2014-07-15

    The purpose of this study is to describe the total hair mercury concentrations and their determinants in preschool Spanish children, as well as to explore the trend in mercury exposure from birth to the age four. This evolution has been scarcely studied in other birth cohort studies. The study population was 580 four year old children participating in the INMA (i.e. Childhood and Environment) birth cohort study in Valencia (2008–2009). Total mercury concentration at age four was measured in hair samples by atomic absorption spectrometry. Fish consumption and other covariates were obtained by questionnaire. Multivariate linear regression models were conducted in order to explore the association between mercury exposure and fish consumption, socio-demographic characteristics and prenatal exposure to mercury. The geometric mean was 1.10 µg/g (95%CI: 1.02, 1.19). Nineteen percent of children had mercury concentrations above the equivalent to the Provisional Tolerable Weekly Intake proposed by WHO. Mercury concentration was associated with increasing maternal age, fish consumption and cord blood mercury levels, as well as decreasing parity. Children whose mothers worked had higher mercury levels than those with non working mothers. Swordfish, lean fish and canned fish were the fish categories most associated with hair mercury concentrations. We observed a decreasing trend in mercury concentrations between birth and age four. In conclusion, the children participating in this study had high hair mercury concentrations compared to reported studies on children from other European countries and similar to other countries with high fish consumption. The INMA study design allows the evaluation of the exposure to mercury longitudinally and enables this information to be used for biomonitoring purposes and dietary recommendations. - Highlights: • The geometric mean of hair Hg concentrations was 1.10 µg/g. • 19% of children had Hg concentrations above the RfD proposed by

  16. Potential Moderating Effects of Selenium on Mercury Uptake and Selenium:Mercury Molar Ratios in Fish From Oak Ridge and Savannah River Site - 12086

    SciTech Connect

    Burger, Joanna; Gochfeld, Michael; Donio, Mark; Jeitner, Christian; Pittfield, Taryn

    2012-07-01

    Mercury contamination is an important remediation issue at the U.S. Department of Energy's (DOE) Oak Ridge Reservation and to a lesser extent at other DOE sites because of the hazard it presents, potential consequences to humans and eco-receptors, and completed pathways, to offsite receptors. Recent work has emphasized that selenium might ameliorate the toxicity of mercury, and we examine the selenium:mercury (Se:Hg) molar ratios in fish from Oak Ridge, and compare them to Se:Hg molar ratios in fish from the Savannah River. Selenium/mercury molar ratios varied considerably among and within fish species. There was considerable variation in the molar ratios for individual fish (as opposed to mean ratios by species) for freshwater fish from both sites. The inter-individual variation in molar ratios indicates that such that the molar ratios of mean Se and Hg concentrations may not be representative. Even for fish species with relatively low mercury levels, some individual fish have molar ratios less than unity, the value sometime thought to be protective. Selenium levels varied narrowly regardless of fish size, consistent with homeostatic regulation of this essential trace element. The data indicate that considerable attention will need to be directed toward variations and variances, as well as the mechanisms of the interaction of selenium and mercury, before risk assessment and risk management policies can use this information to manage mercury pollution and risk. Even so, if there are high levels of selenium in the fish from Poplar Creek on Oak Ridge, then the potential exists for some amelioration of adverse health effects, on the fish themselves, predators that eat them, and people who consume them. This work will aid DOE because it will allow managers and scientists to understand another aspect that affects fate and transport of mercury, as well as the potential effects of methylmercury in fish for human and ecological receptors. The variability within fish

  17. Removal of Mercury from Aqueous Streams of Fossil Fuel Power Plants Using Novel Functionalized Nanoporous Sorbents

    SciTech Connect

    Mattigod, Shas V.; Fryxell, Glen E.; Feng, X; Parker, Kent E.; Pierce, Eric M.

    2006-01-11

    A new class of hybrid nanoporous materials has been developed at the Pacific Northwest National Laboratory for removing toxic heavy metals such as mercury from aqueous and nonaqueous waste streams. These novel materials consist of functional molecules capable of selectively binding mercury (thiol groups) covalently bound (as densely populated monolayers) to the synthetic nanoporous substrates. Tests indicated that this sorbent (Self-Assembled Monolayers on Mesoporous Silica - SAMMS) can achieve mercury loading as high as {approx}635 mg/g. The high affinity for Hg adsorption by this material was reflected by Kd values as high as 3.5 x 108 ml/g. Data indicated that SAMMS can adsorb both inorganic and organic forms of mercury. Experimental data indicated that mercury adsorption performance of SAMMS was not significantly affected by pH, ionic strength, presence of other cations (Na, Ca, Cd, Cu, Fe, Ni, Pb, and Zn), and complexing anions (Cl, CN, CO3, SO4, and PO4) in solution. Adsorption kinetics studies indicated that SAMMS adsorbed mercury very rapidly (about 99.9% adsorption occurring within first five minutes). Tests conducted using samples of different aqueous and non-aqueous waste streams have confirmed the exemplary performance characteristics of SAMMS sorbents. Preliminary cost estimates indicated that using SAMMS would result in significant savings in mercury remediation costs as compared to the use of conventional adsorbents such as ion exchange resin and activated carbon.

  18. Biomonitoring of mercury pollution in a wetland near Ravenna, Italy by translocated bivalves (Mytilus galloprovincialis)

    SciTech Connect

    Cattani, O.; Fabbri, D.; Salvati, M.; Trombini, C.; Vassura, I.

    1999-08-01

    An active biomonitoring experiment using mussels (Mytilus galloprovincialis) was performed in Pialassa Baiona, a mercury-polluted coastal wetland near Ravenna, Italy. Three stations (A, B, and C) were selected along the south to north axis. Following a 52-d field exposure, organisms transplanted in the southernmost polluted area (station A) showed mean mercury concentration values of 660 ng/g (dry weight), 4.4 times the initial background level, and were still accumulating mercury. Mussels in both the central area (station B) and the northern area (station C) seemed to reach a steady state with mean mercury concentration values of 323 and 412 ng/g, respectively. This field experiment is the first study carried out in the Ravenna wetlands to evaluate mercury bioavailability in this environment. Finally, the efficiency of the population of Mytilus galloprovincialis selected for the field experiment as mercury bioaccumulators was tested in a laboratory experiment that revealed that up to 135 {micro}g/g (dry weight) could be reached after 77 d of exposure to mercury-polluted water.

  19. PRELIMINARY FIELD EVALUATION OF MERCURY CONTROL USING COMBUSTION MODIFICATIONS

    SciTech Connect

    Vitali Lissianski; Antonio Marquez

    2004-02-19

    In this project General Electric Energy and Environmental Research Corporation conducts a preliminary field evaluation of a novel technology, referred to as Hg/NO{sub x}, that can reduce emissions of both mercury (Hg) and oxides of nitrogen (NO{sub x}) from coal-fired power plants. The evaluation takes place in Green Station Unit 2 operated by Western Kentucky Energy. Reduction of Hg and NO{sub x} emissions in Unit 2 is achieved using coal reburning. Activities during first project year (January 23, 2003--January 22, 2004) included measurements of baseline Hg emissions in Unit 2 and pilot-scale testing. Baseline testing of Hg emissions in Green Unit 2 has been completed. Two fuels were tested with OFA system operating at minimum air flow. Mercury emissions were measured at ESP inlet and outlet, and at the stack using Ontario Hydro revised method. Testing demonstrated that baseline Hg reductions at ESP outlet and stack were 30-45% and 70-80%, respectively. Pilot-scale testing demonstrated good agreement with baseline measurements in Unit 2. Testing showed that fuel composition had an effect on the efficiency of Hg absorption on fly ash. Maximum achieved Hg removal in reburning was close to 90%. Maximum achieved Hg reduction at air staging conditions was 60%. Testing also demonstrated that lowering ESP temperature improved efficiency of Hg removal.

  20. Waste Coal Fines Reburn for NOx and Mercury Emission Reduction

    SciTech Connect

    Stephen Johnson; Chetan Chothani; Bernard Breen

    2008-04-30

    Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury

  1. Anaerobic Mercury Methylation and Demethylation by Geobacter bemidjiensis Bem

    DOE PAGES [OSTI]

    Lu, Xia; Liu, Yurong; Johs, Alexander; Zhao, Linduo; Wang, Tieshan; Yang, Ziming; Lin, Hui; Elias, Dwayne A.; Pierce, Eric M.; Liang, Liyuan; et al

    2016-03-28

    Two competing processes controlling the net production and bioaccumulation of neurotoxic methylmercury (MeHg) in natural ecosystems are microbial methylation and demethylation. Though mercury (Hg) methylation by anaerobic microorganisms and demethylation by aerobic Hg-resistant bacteria have both been extensively studied, little attention has been given to MeHg degradation by anaerobic bacteria, particularly the iron-reducing bacterium Geobacter bemidjensis Bem. Here we report, for the first time, that the strain G. bemidjensis Bem can methylate inorganic Hg and degrade MeHg concurrently under anoxic conditions. Our results suggest that G. bemidjensis cells utilize a reductive demethylation pathway to degrade MeHg, with elemental Hg(0) asmore » the major reaction product, possibly due to the presence of homologs encoding both organo-mercurial lyase (MerB) and mercuric reductase (MerA) in this organism. In addition, the cells can mediate multiple reactions including Hg/MeHg sorption, Hg reduction and oxidation, resulting in both time and concentration dependent Hg species transformations. Moderate concentrations (10 500 M) of Hg-binding ligands such as cysteine enhance Hg(II) methylation but inhibit MeHg degradation. These findings indicate a cycle of methylation and demethylation among anaerobic bacteria and suggest that mer-mediated demethylation may play a role in the net balance of MeHg production in anoxic water and sediments.« less

  2. Near-Zero NOx Combustion Technology for ATS Mercury 50 Gas Turbine

    SciTech Connect

    Kenneth Smith

    2004-12-31

    A project to demonstrate a near-zero NOx, catalytic combustion technology for natural gas-fired, industrial gas turbines is described. In a cooperative effort between Solar Turbines Incorporated and Precision Combustion Incorporated (PCI), proof-of-concept rig testing of PCI's fuel-rich catalytic combustion technology has been completed successfully. The primary technical goal of the project was to demonstrate NOx and CO emissions below 5ppm and 10 ppm, respectively, (corrected to 15% O{sub 2}) at realistic gas turbine operating conditions. The program consisted of two tasks. In the first task, a single prototype RCL{trademark} (Rich Catalytic Lean Burn) module was demonstrated at Taurus 70 (7.5 Mw) operating conditions (1.6 MPa, 16 atm) in a test rig. For a Taurus 70 engine, eight to twelve RCL modules will be required, depending on the final system design. In the second task, four modules of a similar design were adapted to a Saturn engine (1 Mw) test rig (600 kPa, 6 atm) to demonstrate gas turbine light-off and operation with an RCL combustion system. This project was initially focused on combustion technology for the Mercury 50 engine. However, early in the program, the Taurus 70 replaced the Mercury. This substitution was motivated by the larger commercial market for an ultra-low NOx Taurus 70 in the near-term. Rig tests using a single prototype RCL module at Taurus 70 conditions achieved NOx emissions as low as 0.75 ppm. A combustor turndown of approximately 110C (200F) was achieved with NOx and CO emissions below 3 ppm and 10 ppm, respectively. Catalyst light-off occurred at an inlet temperature of 310C (590F). Once lit the module remained active at inlet air temperatures as low as 204C (400F). Combustor pressure oscillations were acceptably low during module testing. Single module rig tests were also conducted with the Taurus 70 module reconfigured with a central pilot fuel injector. Such a pilot will be required in a commercial RCL system for turbine light

  3. Light metal production

    DOEpatents

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  4. Fluorescent lighting with aluminum nitride phosphors

    DOEpatents

    Cherepy, Nerine J.; Payne, Stephen A.; Seeley, Zachary M.; Srivastava, Alok M.

    2016-05-10

    A fluorescent lamp includes a glass envelope; at least two electrodes connected to the glass envelope; mercury vapor and an inert gas within the glass envelope; and a phosphor within the glass envelope, wherein the phosphor blend includes aluminum nitride. The phosphor may be a wurtzite (hexagonal) crystalline structure Al.sub.(1-x)M.sub.xN phosphor, where M may be drawn from beryllium, magnesium, calcium, strontium, barium, zinc, scandium, yttrium, lanthanum, cerium, praseodymium, europium, gadolinium, terbium, ytterbium, bismuth, manganese, silicon, germanium, tin, boron, or gallium is synthesized to include dopants to control its luminescence under ultraviolet excitation. The disclosed Al.sub.(1-x)M.sub.xN:Mn phosphor provides bright orange-red emission, comparable in efficiency and spectrum to that of the standard orange-red phosphor used in fluorescent lighting, Y.sub.2O.sub.3:Eu. Furthermore, it offers excellent lumen maintenance in a fluorescent lamp, and does not utilize "critical rare earths," minimizing sensitivity to fluctuating market prices for the rare earth elements.

  5. Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement Volume1

    SciTech Connect

    Not Available

    2011-01-01

    Pursuant to the Mercury Export Ban Act of 2008 (P.L. 110-414), DOE was directed to designate a facility or facilities for the long-term management and storage of elemental mercury generated within the United States. Therefore, DOE has analyzed the storage of up to 10,000 metric tons (11,000 tons) of elemental mercury in a facility(ies) constructed and operated in accordance with the Solid Waste Disposal Act, as amended by the Resource Conservation and Recovery Act (74 FR 31723).DOE prepared this Final Mercury Storage EIS in accordance with the National Environmental Policy Act of 1969 (NEPA), as amended (42 U.S.C. 4321 et seq.), the Council on Environmental Quality (CEQ) implementing regulations (40 CFR 1500–1508), and DOE’s NEPA implementing procedures (10 CFR 1021) to evaluate reasonable alternatives for a facility(ies) for the long-term management and storage of elemental mercury. This Final Mercury Storage EIS analyzes the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven candidate locations:Grand Junction Disposal Site near Grand Junction, Colorado; Hanford Site near Richland, Washington; Hawthorne Army Depot near Hawthorne, Nevada; Idaho National Laboratory near Idaho Falls, Idaho;Kansas City Plant in Kansas City, Missouri; Savannah River Site near Aiken, South Carolina; and Waste Control Specialists, LLC, site near Andrews, Texas. As required by CEQ NEPA regulations, the No Action Alternative was also analyzed as a basis for comparison. DOE intends to decide (1) where to locate the elemental mercury storage facility(ies) and (2) whether to use existing buildings, new buildings, or a combination of existing and new buildings. DOE’s Preferred Alternative for the long-term management and storage of mercury is the Waste Control Specialists, LLC, site near Andrews, Texas.

  6. Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement Volume 2

    SciTech Connect

    Not Available

    2011-01-01

    Pursuant to the Mercury Export Ban Act of 2008 (P.L. 110-414), DOE was directed to designate a facility or facilities for the long-term management and storage of elemental mercury generated within the United States. Therefore, DOE has analyzed the storage of up to 10,000 metric tons (11,000 tons) of elemental mercury in a facility(ies) constructed and operated in accordance with the Solid Waste Disposal Act, as amended by the Resource Conservation and Recovery Act (74 FR 31723). DOE prepared this Final Mercury Storage EIS in accordance with the National Environmental Policy Act of 1969 (NEPA), as amended (42 U.S.C. 4321 et seq.), the Council on Environmental Quality (CEQ) implementing regulations (40 CFR 1500–1508), and DOE’s NEPA implementing procedures (10 CFR 1021) to evaluate reasonable alternatives for a facility(ies) for the long-term management and storage of elemental mercury. This Final Mercury Storage EIS analyzes the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven candidate locations: Grand Junction Disposal Site near Grand Junction, Colorado; Hanford Site near Richland, Washington; Hawthorne Army Depot near Hawthorne, Nevada; Idaho National Laboratory near Idaho Falls, Idaho; Kansas City Plant in Kansas City, Missouri; Savannah River Site near Aiken, South Carolina; and Waste Control Specialists, LLC, site near Andrews, Texas. As required by CEQ NEPA regulations, the No Action Alternative was also analyzed as a basis for comparison. DOE intends to decide (1) where to locate the elemental mercury storage facility(ies) and (2) whether to use existing buildings, new buildings, or a combination of existing and new buildings. DOE’s Preferred Alternative for the long-term management and storage of mercury is the Waste Control Specialists, LLC, site near Andrews, Texas.

  7. Subtask 1.23 - Mercury Removal from Barite the Oil Industry

    SciTech Connect

    Michael Holmes; Carolyn Nyberg; Katie Brandt; Kurt Eylands; Nathan Fiala; Grant Dunham

    2008-09-01

    Drilling muds are used by the oil and gas industry to provide a seal and to float rock chips to the surface during the drilling process. Barite (naturally occurring barium sulfate ore) is commonly used as a weighting agent additive in drilling muds because it is chemically nonreactive and has a high specific gravity (between 4.2 and 4.25 at 20 C). Because of environmental concerns, barite used by the oil and gas industry in the Gulf of Mexico must be certified to contain less than 1 mg/kg of mercury. Faced with these regulations, the U.S. Gulf Coast oil industry has looked to foreign sources of low-mercury barite, primarily India and China. These sources tend to have high-grade barite deposits and relatively inexpensive domestic transportation costs; as of late, however, U.S. purchasers have been forced to pay increasing costs for shipping to U.S. grinding plants. The objective of this project was to demonstrate two mercury removal techniques for high-mercury barite sources. Two barite samples of unique origins underwent processing to reduce mercury to required levels. The chemical treatment with dilute acid removed a portion of the mercury in both barite samples. The desired concentration of 1 mg/kg was achieved in both barite samples. An economic analysis indicates that thermal removal of mercury would not significantly add to the cost of barite processing, making higher-mercury barite a viable alternative to more expensive barite sources that contain lower concentrations of mercury.

  8. Light diffusing fiber optic chamber (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: light; diffusing; fiber; optic; chamber; light; diffusion; transmitting; light; target; light; transmitted; ...

  9. Evaluation of MerCAP for Power Plant Mercury Control

    SciTech Connect

    Carl Richardson

    2008-09-30

    This report is submitted to the U.S. Department of Energy National Energy Technology Laboratory (DOE-NETL) as part of Cooperative Agreement DE-FC26-03NT41993, 'Evaluation of EPRI's MerCAP{trademark} Technology for Power Plant Mercury Control'. This project has investigated the mercury removal performance of EPRI's Mercury Capture by Amalgamation Process (MerCAP{trademark}) technology. Test programs were conducted to evaluate gold-based MerCAP{trademark} at Great River Energy's Stanton Station Unit 10 (Site 1), which fired both North Dakota lignite (NDL) and Power River Basin (PRB) coal during the testing period, and at Georgia Power's Plant Yates Unit 1 (Site 2) [Georgia Power is a subsidiary of The Southern Company] which fires a low sulfur Eastern bituminous coal. Additional tests were carried out at Alabama Power's Plant Miller, which fires Powder River Basin Coal, to evaluate a carbon-based MerCAP{trademark} process for removing mercury from flue gas downstream of an electrostatic precipitator [Alabama Power is a subsidiary of The Southern Company]. A full-scale gold-based sorbent array was installed in the clean-air plenum of a single baghouse compartment at GRE's Stanton Station Unit 10, thereby treating 1/10th of the unit's exhaust gas flow. The substrates that were installed were electroplated gold screens oriented parallel to the flue gas flow. The sorbent array was initially installed in late August of 2004, operating continuously until its removal in July 2006, after nearly 23 months. The initial 4 months of operation were conducted while the host unit was burning North Dakota lignite (NDL). In November 2004, the host unit switched fuel to burn Powder River Basin (PRB) subbituminous coal and continued to burn the PRB fuel for the final 19 months of this program. Tests were conducted at Site 1 to evaluate the impacts of flue gas flow rate, sorbent plate spacing, sorbent pre-cleaning and regeneration, and spray dryer operation on Mer

  10. High efficiency incandescent lighting

    DOEpatents

    Bermel, Peter; Ilic, Ognjen; Chan, Walker R.; Musabeyoglu, Ahmet; Cukierman, Aviv Ruben; Harradon, Michael Robert; Celanovic, Ivan; Soljacic, Marin

    2014-09-02

    Incandescent lighting structure. The structure includes a thermal emitter that can, but does not have to, include a first photonic crystal on its surface to tailor thermal emission coupled to, in a high-view-factor geometry, a second photonic filter selected to reflect infrared radiation back to the emitter while passing visible light. This structure is highly efficient as compared to standard incandescent light bulbs.

  11. National Synchrotron Light Source

    ScienceCinema

    BNL

    2016-07-12

    A tour of Brookhaven's National Synchrotron Light Source (NSLS), hosted by Associate Laboratory Director for Light Sources, Stephen Dierker. The NSLS is one of the world's most widely used scientific research facilities, hosting more than 2,500 guest researchers each year. The NSLS provides intense beams of infrared, ultraviolet, and x-ray light for basic and applied research in physics, chemistry, medicine, geophysics, environmental, and materials sciences.

  12. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    Illuminance Assignments for CBECS Building Activity Categories Illuminance ranges were adopted from the 1987 Illuminating Engineering Society (IES) Lighting Handbook. The IES...

  13. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    from the engineering literature, based on CBECS building activity.) 4. Efficacy: an energy efficiency measure. Technically, the amount of light produced per unit of energy...

  14. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    (CEC), March 1990. Advanced Lighting Technologies Application Guidelines (ALTAG), Building and Appliance Efficiency Office. 3. Dubin, F.S., Mindell, H.L., and Bloome, S., 1976....

  15. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    energy are presented in this section. Statistics are presented by subgroups based on building characteristics, and by subgroups based on lighting equipment. The three sets of...

  16. White Light Creation Architectures

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management ... White Light Creation Architectures Overview Brief History of ...

  17. Comparing Light Bulbs

    Office of Energy Efficiency and Renewable Energy (EERE)

    In this exercise, students will use a light to demonstrate the difference between being energy-efficient and energy-wasteful, and learn what energy efficiency means.

  18. And there was light

    SciTech Connect

    Bertulani, C. A.

    2015-02-24

    I discuss the use of light as a collection of real and virtual photons to study some lingering questions in particle and nuclear physics.

  19. Extragalactic Background Light

    Office of Scientific and Technical Information (OSTI)

    Extragalactic Background Light from Hierarchical Galaxy Formation: Gamma-ray Attenuation up to the Epoch of Cosmic Reionization and the First Stars Yoshiyuki Inoue 1 , Susumu Inoue...

  20. Lighting Test Facilities

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Lighting-Test-Facilities Sign In About | Careers | Contact | Investors | bpa.gov Search Policy & Reporting Expand Policy & Reporting EE Sectors Expand EE Sectors Technology &...

  1. Summary - Mitigation and Remediation of Mercury Contamination at the Y-12 Plant, Oak Ridge, TN

    Office of Environmental Management (EM)

    Oak Ridge, TN EM Project: Mitigation/Remediation of Hg ETR Report Date: April 2008 ETR-13 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Mitigation and Remediation of Mercury Contamination at the Y-12 Plant, Oak Ridge, TN Why DOE-EM Did This Review From 1953 to 1983, ~240,000 pounds of mercury (Hg) were released to the East Fork Popular Creek during the operation of the Y-12 Plant. In 1963, direct systematic releases of mercury

  2. Incandescent Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Lighting » Incandescent Lighting Incandescent Lighting Incandescent lighting is the most common, and least energy efficient, type of lighting used in homes. | Photo courtesy of ©iStockphoto/TokenPhoto. Incandescent lighting is the most common, and least energy efficient, type of lighting used in homes. | Photo courtesy of ©iStockphoto/TokenPhoto. Incandescent lamps are often considered the least energy efficient type of electric lighting commonly found in residential buildings. Although

  3. EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS

    SciTech Connect

    J.A. Withum

    2006-03-07

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), evaluated the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)-wet flue gas desulfurization (FGD) combination or a spray dyer absorber-fabric filter (SDA-FF) combination. In this program CONSOL determined mercury speciation and removal at 10 bituminous coal-fired facilities; at four of these facilities, additional tests were performed on units without SCR, or with the existing SCR bypassed. This project final report summarizes the results and discusses the findings of the body of work as a whole. Eleven Topical Reports were issued (prior to this report) that describe in great detail the sampling results at each of the ten power plants individually. The results showed that the SCR-FGD combination removed a substantial fraction of mercury from flue gas. The coal-to-stack mercury removals ranged from 65% to 97% for the units with SCR and from 53% to 87% for the units without SCR. There was no indication that any type of FGD system was more effective at mercury removal than others. The coal-to-stack mercury removal and the removal in the wet scrubber were both negatively correlated with the elemental mercury content of the flue gas and positively correlated with the scrubber liquid chloride concentration. The coal chlorine content was not a statistically significant factor in either case. Mercury removal in the ESP was positively correlated with the fly ash carbon content and negatively correlated with the flue gas temperature. At most of the units, a substantial fraction (>35%) of the flue gas mercury was in the elemental form at the boiler economizer outlet. After passing through the SCR-air heater combination very little of the total mercury (<10%) remained in the elemental form in

  4. Light intensity compressor

    DOEpatents

    Rushford, Michael C.

    1990-01-01

    In a system for recording images having vastly differing light intensities over the face of the image, a light intensity compressor is provided that utilizes the properties of twisted nematic liquid crystals to compress the image intensity. A photoconductor or photodiode material that is responsive to the wavelength of radiation being recorded is placed adjacent a layer of twisted nematic liquid crystal material. An electric potential applied to a pair of electrodes that are disposed outside of the liquid crystal/photoconductor arrangement to provide an electric field in the vicinity of the liquid crystal material. The electrodes are substantially transparent to the form of radiation being recorded. A pair of crossed polarizers are provided on opposite sides of the liquid crystal. The front polarizer linearly polarizes the light, while the back polarizer cooperates with the front polarizer and the liquid crystal material to compress the intensity of a viewed scene. Light incident upon the intensity compressor activates the photoconductor in proportion to the intensity of the light, thereby varying the field applied to the liquid crystal. The increased field causes the liquid crystal to have less of a twisting effect on the incident linearly polarized light, which will cause an increased percentage of the light to be absorbed by the back polarizer. The intensity of an image may be compressed by forming an image on the light intensity compressor.

  5. Explosively pumped laser light

    DOEpatents

    Piltch, Martin S.; Michelotti, Roy A.

    1991-01-01

    A single shot laser pumped by detonation of an explosive in a shell casing. The shock wave from detonation of the explosive causes a rare gas to luminesce. The high intensity light from the gas enters a lasing medium, which thereafter outputs a pulse of laser light to disable optical sensors and personnel.

  6. Otter Tail Power Company - Commercial & Industrial Energy Efficiency...

    Energy.gov [DOE] (indexed site)

    load 12 fluorescent to hard-wired LED lighting systems: .60 per watt reduced Hard-wired systems: 60 per watt saved Screw-in LED lamps: 20 per watt saved Conversions from...

  7. Solid-State Lighting-Lighting Facts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Lighting Facts Solid-State Lighting-Lighting Facts Presenter: Marc Ledbetter, Pacific Northwest National Laboratory The LED Lighting Facts program provides credible, verified performance information about light-emitting diode (LED) lighting products to retailers, utilities, specifiers, energy efficiency program sponsors, and lighting users. The goal is to enable widespread market adoption of energy-efficient LED products by removing the lack-of-information market barrier. For the solid-state

  8. Mercury contamination of terrestrial vegetation near a caustic soda factory in Thailand

    SciTech Connect

    Suckcharoen, S.

    1980-03-01

    The present study is concerned with the fall-out of mercury on some terrestrial plants and one species of aquatic plant growing in the vicinity of the TACSCO factory.

  9. INVESTIGATION AND DEMONSTRATION OF DRY CARBON-BASED SORBENT INJECTION FOR MERCURY CONTROL

    SciTech Connect

    Terry Hunt; Mark Fox; Lillian Stan; Sheila Haythornthwaite; Justin Smith; Jason Ruhl

    1998-10-01

    This quarterly report describes the activities that have taken place during the first full quarter of the Phase II project ''Investigation and Demonstration of Dry Carbon-Based Sorbent Injection for Mercury Control''. Modifications were completed and sampling began at the 600 acfm pilot-scale particulate control module (PCM) located at the Comanche Station in Pueblo, CO. The PCM was configured as an electrostatic precipitator for these tests. A Perkin-Elmer flue gas mercury analyzer was installed on-site and operated. Initial test results using both manual sampling methodology and the mercury analyzer are presented herein. Preparations were made during this period for full-scale mercury testing of several PSCo units. A site visit was made to Arapahoe and Cherokee Generating Stations to determine sample locations and to develop a test plan.

  10. EM's Los Alamos Site Completes Canyon-Side Cleanup ofMercury...

    Office of Environmental Management (EM)

    A spider excavator extracts mercury-contaminated soil. Workers position a crane above the project site. Workers position a crane above the project site. A waste container is loaded ...

  11. Mercury retention by fly ashes from coal combustion: Influence of the unburned carbon content

    SciTech Connect

    Lopez-Anton, M.A.; Diaz-Somoano, M.; Martinez-Tarazona, M.R.

    2007-01-31

    The objective of this study was to evaluate the effect of unburned carbon particles present in fly ashes produced by coal combustion on mercury retention. To achieve this objective, the work was divided into two parts. The aim of the first part of the study was to estimate the amount of mercury captured by the fly ashes during combustion in power stations and the relationship of this retention to the unburned carbon content. The second part was a laboratory-scale study aimed at evaluating the retention of mercury concentrations greater than those produced in power stations by fly ashes of different characteristics and by unburned carbon particles. From the results obtained it can be inferred that the unburned carbon content is not the only variable that controls mercury capture in fly ashes. The textural characteristics of these unburned particles and of other components of fly ashes also influence retention.

  12. EIS-0347: Long-Term Management of the National Defense Stockpile Inventory of Excess Mercury

    Energy.gov [DOE]

    This Defense Logistics Agency EIS evaluated alternatives for managing the Defense National Stockpile Center inventory of excess mercury. DOE was a cooperating agency for preparation of the draft EIS.

  13. Comparative study of the embrittlement of Monel 400 at room temperature by hydrogen and by mercury

    SciTech Connect

    Price, C.E.; Fredell, R.S.

    1986-05-01

    Slow strain rate tensile tests were performed at room temperature on Monel 400 specimens of grain sizes 35 to 500 microns, in the environments of air, mercury, and electrolytically generated hydrogen. Specimens of grain size 250 microns were tested at a range of strain rates in the three environments. It was found that cracks initiated easiest in hydrogen but propagated easiest in mercury; consequently the embrittlement was usually more severe in mercury. The embrittlement decreased with increasing strain rate, and with increasing grain size in hydrogen. Embrittlement in mercury was maximum at intermediate grain sizes. A fracture sequence of intergranular to transgranular to microvoid coalescence was common. The intergranular and transgranular fractures are interpreted in terms of the reduced cohesive stress and enhanced shear models of embrittlement, respectively. 52 references.

  14. Emissions, Monitoring and Control of Mercury from Subbituminous Coal-Fired Power Plants

    SciTech Connect

    Alan Bland; Kumar Sellakumar; Craig Cormylo

    2007-08-01

    The Subbituminous Energy Coalition (SEC) identified a need to re-test stack gas emissions from power plants that burn subbituminous coal relative to compliance with the EPA mercury control regulations for coal-fired plants. In addition, the SEC has also identified the specialized monitoring needs associated with mercury continuous emissions monitors (CEM). The overall objectives of the program were to develop and demonstrate solutions for the unique emission characteristics found when burning subbituminous coals. The program was executed in two phases; Phase I of the project covered mercury emission testing programs at ten subbituminous coal-fired plants. Phase II compared the performance of continuous emission monitors for mercury at subbituminous coal-fired power plants and is reported separately. Western Research Institute and a number of SEC members have partnered with Eta Energy and Air Pollution Testing to assess the Phase I objective. Results of the mercury (Hg) source sampling at ten power plants burning subbituminous coal concluded Hg emissions measurements from Powder River Basin (PBR) coal-fired units showed large variations during both ICR and SEC testing. Mercury captures across the Air Pollution Control Devices (APCDs) present much more reliable numbers (i.e., the mercury captures across the APCDs are positive numbers as one would expect compared to negative removal across the APCDs for the ICR data). Three of the seven units tested in the SEC study had previously shown negative removals in the ICR testing. The average emission rate is 6.08 lb/TBtu for seven ICR units compared to 5.18 lb/TBtu for ten units in the SEC testing. Out of the ten (10) SEC units, Nelson Dewey Unit 1, burned a subbituminous coal and petcoke blend thus lowering the total emission rate by generating less elemental mercury. The major difference between the ICR and SEC data is in the APCD performance and the mercury closure around the APCD. The average mercury removal values

  15. EM’s Los Alamos Site Completes Canyon-Side Cleanup of Mercury-Contaminated Soil

    Energy.gov [DOE]

    LOS ALAMOS, N.M. – EM’s Los Alamos Field Office recently completed a steep canyon-side cleanup of mercury-contaminated soil on DOE property just south of a shopping center here.

  16. Emissions, Monitoring, and Control of Mercury from Subbituminous Coal-Fired Power Plants - Phase II

    SciTech Connect

    Alan Bland; Jesse Newcomer; Allen Kephart; Volker Schmidt; Gerald Butcher

    2008-10-31

    Western Research Institute (WRI), in conjunction with Western Farmers Electric Cooperative (WFEC), has teamed with Clean Air Engineering of Pittsburgh PA to conduct a mercury monitoring program at the WEFC Hugo plant in Oklahoma. Sponsored by US Department of Energy Cooperative Agreement DE-FC-26-98FT40323, the program included the following members of the Subbituminous Energy Coalition (SEC) as co-sponsors: Missouri Basin Power Project; DTE Energy; Entergy; Grand River Dam Authority; and Nebraska Public Power District. This research effort had five objectives: (1) determine the mass balance of mercury for subbituminous coal-fired power plant; (2) assess the distribution of mercury species in the flue gas (3) perform a comparison of three different Hg test methods; (4) investigate the long-term (six months) mercury variability at a subbituminous coal-fired power plant; and (5) assess operation and maintenance of the Method 324 and Horiba CEMS utilizing plant personnel.

  17. OPTIMIZING TECHNOLOGY TO REDUCE MERCURY AND ACID GAS EMISSIONS FROM ELECTRIC POWER PLANTS

    SciTech Connect

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-10-01

    Maps showing potential mercury, sulfur, chlorine, and moisture emissions for U.S. coal by county of origin were made from publicly available data (plates 1, 2, 3, and 4). Published equations that predict mercury capture by emission control technologies used at U.S. coal-fired utilities were applied to average coal quality values for 169 U.S. counties. The results were used to create five maps that show the influence of coal origin on mercury emissions from utility units with: (1) hot-side electrostatic precipitator (hESP), (2) cold-side electrostatic precipitator (cESP), (3) hot-side electrostatic precipitator with wet flue gas desulfurization (hESP/FGD), (4) cold-side electrostatic precipitator with wet flue gas desulfurization (cESP/FGD), and (5) spray-dry adsorption with fabric filter (SDA/FF) emission controls (plates 5, 6, 7, 8, and 9). Net (lower) coal heating values were calculated from measured coal Btu values, and estimated coal moisture and hydrogen values; the net heating values were used to derive mercury emission rates on an electric output basis (plate 10). Results indicate that selection of low-mercury coal is a good mercury control option for plants having hESP, cESP, or hESP/FGD emission controls. Chlorine content is more important for plants having cESP/FGD or SDA/FF controls; optimum mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions. Comparison of in-ground coal quality with the quality of commercially mined coal indicates that existing coal mining and coal washing practice results in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Further pre-combustion mercury reductions may be possible, especially for coal from Texas, Ohio, parts of Pennsylvania and much of the western U.S.

  18. Final Technical Report: Mercury Release from Organic Matter (OM) and OM-Coated Mineral Surfaces

    SciTech Connect

    Nagy, Kathryn L.

    2015-08-18

    Chemical reactions between mercury, a neurotoxin, and sulfur, an essential nutrient, in the environment control to a large extent the distribution and amount of mercury available for uptake by living organisms. The largest reservoir of sulfur in soils is in living, decaying, and dissolved natural organic matter. The decaying and dissolved organic matter can also coat the surfaces of minerals in the soil. Mercury (as a divalent cation) can bind to the sulfur species in the organic matter as well as to the bare mineral surfaces, but the extent of binding and release of this mercury is not well understood. The goals of the research were to investigate fundamental relationships among mercury, natural organic matter, and selected minerals to better understand specifically the fate and transport of mercury in contaminated soils downstream from the Y-12 plant along East Fork Poplar Creek, Tennessee, and more generally in any contaminated soil. The research focused on (1) experiments to quantify the uptake and release of mercury from two clay minerals in the soil, kaolinite and vermiculite, in the presence and absence of dissolved organic matter; (2) release of mercury from cinnabar under oxic and anoxic conditions; (3) characterization of the forms of mercury in the soil using synchrotron X-ray absorption spectroscopic techniques; and, (4) determination of molecular forms of mercury in the presence of natural organic matter. We also leveraged funding from the National Science Foundation to (5) evaluate published approaches for determining sulfur speciation in natural organic matter by fitting X-ray Absorption Near Edge Structure (XANES) spectra obtained at the sulfur K-edge and apply optimized fitting schemes to new measurements of sulfur speciation in a suite of dissolved organic matter samples from the International Humic Substances Society. Lastly, in collaboration with researchers at the University of Colorado and the U.S. Geological Survey in Boulder, Colorado, (6

  19. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect

    Gary Blythe; Conor Braman; Katherine Dombrowski; Tom Machalek

    2010-12-31

    This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period January 1, 2004 through December 31, 2010. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency. The project was co-funded by the U.S. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. URS Group was the prime contractor. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The project has tested candidate materials at pilot scale and in a commercial form, to provide engineering data for future full-scale designs. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed

  20. Removing mercury from coal emissions: options for ash-friendly technologies

    SciTech Connect

    Sager, J.

    2009-07-01

    The article gives a brief description of techniques to remove mercury emitted from coal-fired power plants and discusses environmental considerations associated with the effect of emission controls on coal fly ash. Techniques covered include use of injected mercury sorbents (activated carbon, metal oxide catalysts, MerCAP{trademark} and MercScreen{trademark}) and fuel cleaning. Technologies currently being researched are mentioned. 8 refs.

  1. Processing results of 1,800 gallons of mercury and radioactively contaminated mixed waste rinse solution

    SciTech Connect

    Thiesen, B.P.

    1993-01-01

    The mercury-contaminated rinse solution (INEL waste ID{number_sign} 123; File 8 waste) was successfully treated at the Idaho National Engineering Laboratory (INEL). This waste was generated during the decontamination of the Heat Transfer Reactor Experiment 3 (HTRE-3) reactor shield tank. Approximately 1,800 gal of waste was generated and was placed into 33 drums. Each drum contained precipitated sludge material ranging from 1--10 in. in depth, with the average depth of about 2.5 in. The pH of each drum varied from 3--11. The bulk liquid waste had a mercury level of 7.0 mg/l, which exceeded the Resource Conservation and Recovery Act (RCRA) limit of 0.2 mg/l. The average liquid bulk radioactivity was about 2.1 pCi/ml, while the average sludge contamination was about 13,800 pci/g. Treatment of the waste required separation of the liquid from the sludge, filtration, pH adjustment, and ion exchange. Because of difficulties in processing, three trials were required to reduce the mercury levels to below the RCRA limit. In the first trial, insufficient filtration of the waste allowed solid particulate produced during pH adjustment to enter into the ion exchange columns and ultimately the waste storage tank. In the second trial, the waste was filtered down to 0.1 {mu} to remove all solid mercury compounds. However, before filtration could take place, a solid mercury complex dissolved and mercury levels exceeded the RCRA limit after filtration. In the third trial, the waste was filtered through 0.3-A filters and then passed through the S-920 resin to remove the dissolved mercury. The resulting solution had mercury levels at 0.0186 mg/l and radioactivity of 0.282 pCi/ml. This solution was disposed of at the TAN warm waste pond, TAN782, TSF-10.

  2. Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Catalysts for Oxidation of Mercury in Flue Gas National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 7776780.pdf (365 KB) Technology Marketing Summary Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), platinum/iridium (Pt/Ir), and Thief carbons. The catalyst materials will adsorb

  3. Lighting fundamentals handbook: Lighting fundamentals and principles for utility personnel

    SciTech Connect

    Eley, C.; Tolen, T. Associates, San Francisco, CA ); Benya, J.R. )

    1992-12-01

    Lighting accounts for approximately 30% of overall electricity use and demand in commercial buildings. This handbook for utility personnel provides a source of basic information on lighting principles, lighting equipment, and other considerations related to lighting design. The handbook is divided into three parts. Part One, Physics of Light, has chapters on light, vision, optics, and photometry. Part Two, Lighting Equipment and Technology, focuses on lamps, luminaires, and lighting controls. Part Three, Lighting Design Decisions, deals with the manner in which lighting design decisions are made and reviews relevant methods and issues. These include the quantity and quality of light needed for visual tasks, calculation methods for verifying that lighting needs are satisfied, lighting economics and methods for evaluating investments in efficient lighting systems, and miscellaneous design issues including energy codes, power quality, photobiology, and disposal of lighting equipment. The handbook contains a discussion of the role of the utility in promoting the use of energy-efficient lighting. The handbook also includes a lighting glossary and a list of references for additional information. This convenient and comprehensive handbook is designed to enable utility lighting personnel to assist their customers in developing high-quality, energy-efficient lighting systems. The handbook is not intended to be an up-to-date reference on lighting products and equipment.

  4. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W.

    2012-05-15

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  5. Development Of Chemical Reduction And Air Stripping Processes To Remove Mercury From Wastewater

    SciTech Connect

    Jackson, Dennis G.; Looney, Brian B.; Craig, Robert R.; Thompson, Martha C.; Kmetz, Thomas F.

    2013-07-10

    This study evaluates the removal of mercury from wastewater using chemical reduction and air stripping using a full-scale treatment system at the Savannah River Site. The existing water treatment system utilizes air stripping as the unit operation to remove organic compounds from groundwater that also contains mercury (C ~ 250 ng/L). The baseline air stripping process was ineffective in removing mercury and the water exceeded a proposed limit of 51 ng/L. To test an enhancement to the existing treatment modality a continuous dose of reducing agent was injected for 6-hours at the inlet of the air stripper. This action resulted in the chemical reduction of mercury to Hg(0), a species that is removable with the existing unit operation. During the injection period a 94% decrease in concentration was observed and the effluent satisfied proposed limits. The process was optimized over a 2-day period by sequentially evaluating dose rates ranging from 0.64X to 297X stoichiometry. A minimum dose of 16X stoichiometry was necessary to initiate the reduction reaction that facilitated the mercury removal. Competing electron acceptors likely inhibited the reaction at the lower 1 doses, which prevented removal by air stripping. These results indicate that chemical reduction coupled with air stripping can effectively treat large-volumes of water to emerging part per trillion regulatory standards for mercury.

  6. HERO Leavenworth Tree Lighting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    HERO Leavenworth Shopping and Christmas Lighting Festival We'll take you, friends and family, to a Leavenworth that is particularly magical in the Christmas season. There is something for everyone, from roasted chestnuts at the gazebo, to shopping and sleigh rides...all just minutes away! And at dusk, everyone gathers to witness the lighting of a magical wonderland, as they light up the village and park. With a greeting from "Old Saint Nick" at the gazebo, the Leavenworth Christmas

  7. Lighting in the Library

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    lores.pdf (1.43

    hires.pdf (1.65

    The purpose of the Lighting in the Library Activity is to calculate the electricity used to provide lighting in the school library and determine the feasibility of saving energy and money by using energy efficient lighting fixtures. Your students will assume the role of an energy auditor assigned the task of assessing the current situation and making a recommendation for energy-efficient improvements. This activitity requires a trip to the library, an

  8. Green Light Pulse Oximeter

    DOEpatents

    Scharf, John Edward

    1998-11-03

    A reflectance pulse oximeter that determines oxygen saturation of hemoglobin using two sources of electromagnetic radiation in the green optical region, which provides the maximum reflectance pulsation spectrum. The use of green light allows placement of an oximetry probe at central body sites (e.g., wrist, thigh, abdomen, forehead, scalp, and back). Preferably, the two green light sources alternately emit light at 560 nm and 577 nm, respectively, which gives the biggest difference in hemoglobin extinction coefficients between deoxyhemoglobin, RHb, and oxyhemoglobin, HbO.sub.2.

  9. White light velocity interferometer

    DOEpatents

    Erskine, D.J.

    1997-06-24

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s. 41 figs.

  10. White light velocity interferometer

    DOEpatents

    Erskine, David J.

    1997-01-01

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s.

  11. White light velocity interferometer

    DOEpatents

    Erskine, David J.

    1999-01-01

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s.

  12. White light velocity interferometer

    DOEpatents

    Erskine, D.J.

    1999-06-08

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s. 41 figs.

  13. EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS

    SciTech Connect

    J. A. Withum; S.C. Tseng; J. E. Locke

    2004-10-31

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP) - wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on Hg speciation and the efficacy of different FGD technologies for Hg capture. This document, the second in a series of topical reports, describes the results and analysis of mercury sampling performed on a 330 MW unit burning a bituminous coal containing 1.0% sulfur. The unit is equipped with a SCR system for NOx control and a spray dryer absorber for SO{sub 2} control followed by a baghouse unit for particulate emissions control. Four sampling tests were performed in March 2003. Flue gas mercury speciation and concentrations were determined at the SCR inlet, air heater outlet (ESP inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. Due to mechanical problems with the boiler feed water pumps, the actual gross output was between 195 and 221 MW during the tests. The results showed that the SCR/air heater combination oxidized nearly 95% of the elemental mercury. Mercury removal, on a

  14. JV Task 122 - Assessment of Mercury Control Options for the San Miguel Electric Cooperative Power Plant

    SciTech Connect

    Nicholas Lentz; Brandon Pavlish; John Kay; Michael Jones

    2009-02-01

    In the United States, testing has been under way at electric coal-fired power plants to find viable and economical mercury control strategies to meet pending regulations. San Miguel Electric Cooperative (SMEC) engaged the Energy & Environmental Research Center (EERC) through a request for proposal (RFP) to perform research tests to evaluate sorbent-based technologies at its coal-fired San Miguel Generating Station to identify possible technology options that could be used by SMEC to meet the mercury reduction requirements of future U.S. federal standards. The goal of the testing was to target a mercury removal of {ge}90%. The EERC has successfully field-tested several sorbent-based technologies in previous projects that offer promise and potential to achieve a target removal of {ge}90%. Based on these field test results, yet recognizing that fuel type and plant operating conditions affect mercury capture significantly, the EERC proposed research tests to evaluate potential sorbent-based technologies provided by Norit Americas and the EERC that could potentially meet SMEC's mercury control objectives. Over the period of May through mid-June 2008, the EERC tested injection of both treated and nontreated activated carbon (AC) provided by Norit Americas and sorbent enhancement additives (SEAs) provided by the EERC. Tests were performed at San Miguel Unit 1 (450 MW) and included injection at the inlet of the air heater (AH) (temperature of 720 F). The test coal was a Texas lignite fuel with an average moisture content of 31.19%, an ash content of 26.6%, a heating value of 5,094 Btu/lb, a sulfur content of 2.7%, and a mercury concentration of 0.182 ppm, all reported on an as-received basis. Pilot-scale testing results identified DARCO{reg_sign} Hg-LH, SEA2 + DARCO{reg_sign} Hg, and the ChemMod sorbents as technologies with the potential to achieve the target mercury removal of {ge}90% at the full-scale test. Mercury concentrations were tracked with continuous mercury

  15. LOCAL IMPACTS OF MERCURY EMISSIONS FROM THE MONTICELLO COAL FIRED POWER PLANT.

    SciTech Connect

    SULLIVAN, T.M.; ADAMS, J.; MILIAN, L.; SUBRAMANIAN, S.; FEAGIN, L.; WILLIAMS, J.; BOYD, A.

    2006-10-31

    The Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule (CAMR) as currently proposed by the U.S. Environmental Protection Agency (EPA) when fully implemented will lead to reduction in mercury emissions from coal-fired power plants by 70 percent to fifteen tons per year by 2018. The EPA estimates that mercury deposition would be reduced 8 percent on average in the Eastern United States. The CAMR permits cap-and-trade approach that requires the nationwide emissions to meet the prescribed level, but do not require controls on each individual power plant. This has led to concerns that there may be hot-spots of mercury contamination near power plants. Partially because of this concern, many states including Pennsylvania have implemented, or are considering, state regulations that are stricter on mercury emissions than those in the CAMR. This study examined the possibility that coal-fired power plants act as local sources leading to mercury ''hot spots'', using two types of evidence. First, the world-wide literature was searched for reports of deposition around mercury sources, including coal-fired power plants. Second, soil samples from around two mid-sized U.S. coal-fired power plants were collected and analyzed for evidence of ''hot spots'' and for correlation with model predictions of deposition. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (A) local soil concentration Hg increments of 30%-60%, (B) sediment increments of 18-30%, (C) wet deposition increments of 11-12%, and (D) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content

  16. Lighting Controls | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Controls Lighting Controls Use lighting controls to automatically turn lights on and off as needed, and save energy. Use lighting controls to automatically turn lights on and off as needed, and save energy. Use lighting controls to automatically turn lights on and off as needed, and save energy. Of course you can save energy by turning off lights when they're not needed, but sometimes we forget or don't notice that we've left them on. The most common types of lighting controls include: Dimmers

  17. National Synchrotron Light Source

    ScienceCinema

    None

    2016-07-12

    A tour of Brookhaven's National Synchrotron Light Source (NSLS). The NSLS is one of the world's most widely used scientific research facilities, hosting more than 2,500 guest researchers each year. The NSLS provides intense beams of infrared, ultraviole

  18. Lighting in Commercial Buildings

    Energy Information Administration (EIA) (indexed site)

    5.2 152.6 160.5 54.6 Assembly Health Care Lodging Office 0 20 40 60 80 100 120 140 160 180 Energy Information Administration Energy Consumption Series: Lighting in Commercial...

  19. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting

    SciTech Connect

    Kinzey, B. R.; Myer, M. A.

    2009-11-01

    A U.S. Department of Energy Solid-State Lighting Gateway Report on a Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting in Lija Loop, Portland, Oregon.

  20. Lakeview Light and Power- Commercial Lighting Rebate Program

    Energy.gov [DOE]

    Lakeview Light and Power offers a commercial lighting rebate program. Rebates apply to the installation of energy efficient lighting retrofits in non-residential buildings. The rebate program is...