National Library of Energy BETA

Sample records for two-dimensional 2d reflection

  1. SENSIT-2D: a two-dimensional cross-section sensitivity and uncertainty analysis code

    SciTech Connect

    Embrechts, M.J.

    1982-10-01

    SENSIT-2D is a computer program that calculates the sensitivity and/or uncertainty for an integral response (e.g., heating, radiation damage), obtained from the two-dimensional discrete ordinates transport code TRIDENT-CTR, to the cross sections and cross-section uncertainties. A design-sensitivity option allows one to calculate the integral response when the cross sections in certain regions are changed. A secondary-energy-distribution sensitivity- and uncertainty-analysis capability is included. SENSIT-2D incorporates all the essential features of TRIDENT-CTR (r,z geometry option, triangular mesh, nonorthogonal boundaries, group-dependent quadrature sets) and is aimed at the needs of the fusion community. The structure of SENSIT-2D is similar to the structure of the SENSIT code, a one-dimensional sensitivity- and uncertainty-analysis code. This report covers the theory used in SENSIT-2D, outlines the code structure, and gives detailed input specifications. Where appropriate, parts of the SENSIT report are taken over in this write-up. Two sample problems which illustrate the use of SENSIT-2D are explained.

  2. PRONTO 2D: A two-dimensional transient solid dynamics program

    SciTech Connect

    Taylor, L.M.; Flanagan, D.P.

    1987-03-01

    PRONTO 2D is a two-dimensional transient solid dynamics code for analyzing large deformations of highly nonlinear materials subjected to extremely high strain rates. This Lagrangian finite element program uses an explicit time integration operator to integrate the equations of motion. Four node uniform strain quadrilateral elements are used in the finite element formulation. A number of new numerical algorithms which have been developed for the code are described in this report. An adaptive time step control algorithm is described which greatly improves stability as well as performance in plasticity problems. A robust hourglass control scheme which eliminates hourglass distortions without disturbing the finite element solution is included. All constitutive models in PRONTO are cast in an unrotated configuration defined using the rotation determined from the polar decomposition of the deformation gradient. An accurate incremental algorithm was developed to determine this rotation and is described in detail. A robust contact algorithm was developed which allows for the impact and interaction of deforming contact surfaces of quite general geometry. A number of numerical examples are presented to demonstrate the utility of these algorithms. 41 refs., 51 figs., 5 tabs.

  3. A new model for two-dimensional numerical simulation of pseudo-2D gas-solids fluidized beds

    SciTech Connect

    Li, Tingwen; Zhang, Yongmin

    2013-10-11

    Pseudo-two dimensional (pseudo-2D) fluidized beds, for which the thickness of the system is much smaller than the other two dimensions, is widely used to perform fundamental studies on bubble behavior, solids mixing, or clustering phenomenon in different gas-solids fluidization systems. The abundant data from such experimental systems are very useful for numerical model development and validation. However, it has been reported that two-dimensional (2D) computational fluid dynamic (CFD) simulations of pseudo-2D gas-solids fluidized beds usually predict poor quantitative agreement with the experimental data, especially for the solids velocity field. In this paper, a new model is proposed to improve the 2D numerical simulations of pseudo-2D gas-solids fluidized beds by properly accounting for the frictional effect of the front and back walls. Two previously reported pseudo-2D experimental systems were simulated with this model. Compared to the traditional 2D simulations, significant improvements in the numerical predictions have been observed and the predicted results are in better agreement with the available experimental data.

  4. GEO2D - Two-Dimensional Computer Model of a Ground Source Heat Pump System

    DOE Data Explorer

    James Menart

    2013-06-07

    This file contains a zipped file that contains many files required to run GEO2D. GEO2D is a computer code for simulating ground source heat pump (GSHP) systems in two-dimensions. GEO2D performs a detailed finite difference simulation of the heat transfer occurring within the working fluid, the tube wall, the grout, and the ground. Both horizontal and vertical wells can be simulated with this program, but it should be noted that the vertical wall is modeled as a single tube. This program also models the heat pump in conjunction with the heat transfer occurring. GEO2D simulates the heat pump and ground loop as a system. Many results are produced by GEO2D as a function of time and position, such as heat transfer rates, temperatures and heat pump performance. On top of this information from an economic comparison between the geothermal system simulated and a comparable air heat pump systems or a comparable gas, oil or propane heating systems with a vapor compression air conditioner. The version of GEO2D in the attached file has been coupled to the DOE heating and cooling load software called ENERGYPLUS. This is a great convenience for the user because heating and cooling loads are an input to GEO2D. GEO2D is a user friendly program that uses a graphical user interface for inputs and outputs. These make entering data simple and they produce many plotted results that are easy to understand. In order to run GEO2D access to MATLAB is required. If this program is not available on your computer you can download the program MCRInstaller.exe, the 64 bit version, from the MATLAB website or from this geothermal depository. This is a free download which will enable you to run GEO2D..

  5. 2D Seismic Reflection Data across Central Illinois

    SciTech Connect

    Smith, Valerie; Leetaru, Hannes

    2014-09-30

    In a continuing collaboration with the Midwest Geologic Sequestration Consortium (MGSC) on the Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins project, Schlumberger Carbon Services and WesternGeco acquired two-dimensional (2D) seismic data in the Illinois Basin. This work included the design, acquisition and processing of approximately 125 miles of (2D) seismic reflection surveys running west to east in the central Illinois Basin. Schlumberger Carbon Services and WesternGeco oversaw the management of the field operations (including a pre-shoot planning, mobilization, acquisition and de-mobilization of the field personnel and equipment), procurement of the necessary permits to conduct the survey, post-shoot closure, processing of the raw data, and provided expert consultation as needed in the interpretation of the delivered product. Three 2D seismic lines were acquired across central Illinois during November and December 2010 and January 2011. Traversing the Illinois Basin, this 2D seismic survey was designed to image the stratigraphy of the Cambro-Ordovician sections and also to discern the basement topography. Prior to this survey, there were no regionally extensive 2D seismic data spanning this section of the Illinois Basin. Between the NW side of Morgan County and northwestern border of Douglas County, these seismic lines ran through very rural portions of the state. Starting in Morgan County, Line 101 was the longest at 93 miles in length and ended NE of Decatur, Illinois. Line 501 ran W-E from the Illinois Basin – Decatur Project (IBDP) site to northwestern Douglas County and was 25 miles in length. Line 601 was the shortest and ran N-S past the IBDP site and connected lines 101 and 501. All three lines are correlated to well logs at the IBDP site. Originally processed in 2011, the 2D seismic profiles exhibited a degradation of signal quality below ~400 millisecond (ms) which made

  6. Transmission and reflection of terahertz plasmons in two-dimensional plasmonic devices

    DOE PAGES [OSTI]

    Sydoruk, Oleksiy; Choonee, Kaushal; Dyer, Gregory Conrad

    2015-03-10

    We found that plasmons in two-dimensional semiconductor devices will be reflected by discontinuities, notably, junctions between gated and non-gated electron channels. The transmitted and reflected plasmons can form spatially- and frequency-varying signals, and their understanding is important for the design of terahertz detectors, oscillators, and plasmonic crystals. Using mode decomposition, we studied terahertz plasmons incident on a junction between a gated and a nongated channel. The plasmon reflection and transmission coefficients were found numerically and analytically and studied between 0.3 and 1 THz for a range of electron densities. At higher frequencies, we could describe the plasmons by a simplifiedmore » model of channels in homogeneous dielectrics, for which the analytical approximations were accurate. At low frequencies, however, the full geometry and mode spectrum had to be taken into account. Moreover, the results agreed with simulations by the finite-element method. As a result, mode decomposition thus proved to be a powerful method for plasmonic devices, combining the rigor of complete solutions of Maxwell's equations with the convenience of analytical expressions.« less

  7. Transmission and reflection of terahertz plasmons in two-dimensional plasmonic devices

    SciTech Connect

    Sydoruk, Oleksiy; Choonee, Kaushal; Dyer, Gregory Conrad

    2015-03-10

    We found that plasmons in two-dimensional semiconductor devices will be reflected by discontinuities, notably, junctions between gated and non-gated electron channels. The transmitted and reflected plasmons can form spatially- and frequency-varying signals, and their understanding is important for the design of terahertz detectors, oscillators, and plasmonic crystals. Using mode decomposition, we studied terahertz plasmons incident on a junction between a gated and a nongated channel. The plasmon reflection and transmission coefficients were found numerically and analytically and studied between 0.3 and 1 THz for a range of electron densities. At higher frequencies, we could describe the plasmons by a simplified model of channels in homogeneous dielectrics, for which the analytical approximations were accurate. At low frequencies, however, the full geometry and mode spectrum had to be taken into account. Moreover, the results agreed with simulations by the finite-element method. As a result, mode decomposition thus proved to be a powerful method for plasmonic devices, combining the rigor of complete solutions of Maxwell's equations with the convenience of analytical expressions.

  8. In-plane heterojunctions enable multiphasic two-dimensional (2D) MoS2 nanosheets as efficient photocatalysts for hydrogen evolution from water reduction

    DOE PAGES [OSTI]

    Peng, Rui; Liang, Liangbo; Hood, Zachary D.; Boulesbaa, Abdelaziz; Puretzky, Alexander; Ievlev, Anton V.; Come, Jeremy; Ovchinnikova, Olga S.; Wang, Hui; Ma, Cheng; et al

    2016-08-30

    Two-dimensional (2D) single-layer MoS2 nanosheets are demonstrated as efficient photocatalysts for hydrogen evolution reaction (HER) from water reduction, thanks to specific in-plane heterojunctions constructed in the MoS2 monolayer. These functional heterojunctions are formed among the different phases of chemically exfoliated MoS2 monolayers: semiconducting 2H, metallic 1T, and quasi-metallic 1T' phases. The proportion of the three MoS2 phases can be systematically controlled via thermal annealing of the nanosheets. Interestingly, a volcano relationship is observed between the photocatalytic HER activity and the annealing temperature with an optimum activity obtained after annealing at 60 °C. First-principles calculations were integrated with experimental studies tomore » shed light on the role of the multiphases of MoS2 and reveal that optimum photocatalytic HER activity results from the formation of the in-plane heterojunctions between 1T' MoS2 and 2H MoS2. Importantly, this facilitates not only balanced light absorption and charge generation by the 2H phase, efficient charge separation at the 1T'/2H interface, but also favorable HER over the basal sites of 1T' MoS2. Furthermore, our work manifests how the confluence of the optical, electronic and chemical properties of 2D MoS2 monolayers can be fully captured for efficient photocatalytic water reduction.« less

  9. BASIN STRUCTURE FROM TWO-DIMENSIONAL SEISMIC REFLECTION DATA, CRAZY MOUNTAINS BASIN, MONTANA

    SciTech Connect

    David J. Taylor

    2003-08-01

    Some 140 miles of multichannel seismic reflection data, acquired commercially in the 1970's, were reprocessed by the U.S. Geological Survey in late 2000 and early 2001 to interpret the subsurface geology of the Crazy Mountains Basin, an asymmetric Laramide foreland basin located in south-central Montana. The seismic data indicate that the northwestern basin margin is controlled by a thrust fault that places basement rocks over a thick (22,000 feet) sequence of Paleozoic and Mesozoic sedimentary rocks to the south. From the deep basin trough, Paleozoic through Tertiary rocks slope gently upward to the south and southeast. The northern boundary of the basin, which is not imaged well by the seismic data, appears to be folded over a basement ridge rather than being truncated against a fault plane. Seismic data along the basin margin to the south indicate that several fault controlled basement highs may have been created by thin-skinned tectonics where a series of shallow thrust faults cut Precambrian, Paleozoic, and early Mesozoic rocks, whereas, in contrast, Cretaceous and Tertiary strata are folded. The data are further interpreted to indicate that this fault-bounded asymmetric basin contains several structures that possibly could trap hydrocarbons, provided source rocks, reservoirs, and seals are present. In addition, faults in the deep basin trough may have created enough fracturing to enhance porosity, thus developing ''sweet spots'' for hydrocarbons in basin-centered continuous gas accumulations.

  10. Two-Dimensional IHCP Code

    Energy Science and Technology Software Center

    1997-11-18

    QUENCH2D* is developed for the solution of general, non-linear, two-dimensional inverse heat transfer problems. This program provides estimates for the surface heat flux distribution and/or heat transfer coefficient as a function of time and space by using transient temperature measurements at appropriate interior points inside the quenched body. Two-dimensional planar and axisymmetric geometries such as turnbine disks and blades, clutch packs, and many other problems can be analyzed using QUENCH2D*.

  11. Seismic isolation of two dimensional periodic foundations

    SciTech Connect

    Yan, Y.; Mo, Y. L.; Laskar, A.; Cheng, Z.; Shi, Z.; Menq, F.; Tang, Y.

    2014-07-28

    Phononic crystal is now used to control acoustic waves. When the crystal goes to a larger scale, it is called periodic structure. The band gaps of the periodic structure can be reduced to range from 0.5?Hz to 50?Hz. Therefore, the periodic structure has potential applications in seismic wave reflection. In civil engineering, the periodic structure can be served as the foundation of upper structure. This type of foundation consisting of periodic structure is called periodic foundation. When the frequency of seismic waves falls into the band gaps of the periodic foundation, the seismic wave can be blocked. Field experiments of a scaled two dimensional (2D) periodic foundation with an upper structure were conducted to verify the band gap effects. Test results showed the 2D periodic foundation can effectively reduce the response of the upper structure for excitations with frequencies within the frequency band gaps. When the experimental and the finite element analysis results are compared, they agree well with each other, indicating that 2D periodic foundation is a feasible way of reducing seismic vibrations.

  12. Magnetic Correlations in the Quasi-Two-Dimensional Semiconducting...

    Office of Scientific and Technical Information (OSTI)

    Title: Magnetic Correlations in the Quasi-Two-Dimensional Semiconducting Ferromagnet CrSiTe3 Intrinsic, 2D ferromagnetic semiconductors are an important class of materials for ...

  13. A spectroelectrochemical cell for ultrafast two-dimensional infrared spectroscopy

    SciTech Connect

    El Khoury, Youssef; Van Wilderen, Luuk J. G. W.; Vogt, Tim; Winter, Ernst; Bredenbeck, Jens E-mail: bredenbeck@biophysik.uni-frankfurt.de

    2015-08-15

    A spectroelectrochemical cell has been designed to combine electrochemistry and ultrafast two-dimensional infrared (2D-IR) spectroscopy, which is a powerful tool to extract structure and dynamics information on the femtosecond to picosecond time scale. Our design is based on a gold mirror with the dual role of performing electrochemistry and reflecting IR light. To provide the high optical surface quality required for laser spectroscopy, the gold surface is made by electron beam evaporation on a glass substrate. Electrochemical cycling facilitates in situ collection of ultrafast dynamics of redox-active molecules by means of 2D-IR. The IR beams are operated in reflection mode so that they travel twice through the sample, i.e., the signal size is doubled. This methodology is optimal for small sample volumes and successfully tested with the ferricyanide/ferrocyanide redox system of which the corresponding electrochemically induced 2D-IR difference spectrum is reported.

  14. Aniso2D

    Energy Science and Technology Software Center

    2005-07-01

    Aniso2d is a two-dimensional seismic forward modeling code. The earth is parameterized by an X-Z plane in which the seismic properties Can have monoclinic with x-z plane symmetry. The program uses a user define time-domain wavelet to produce synthetic seismograms anrwhere within the two-dimensional media.

  15. Wideband radar cross section reduction using two-dimensional phase gradient metasurfaces

    SciTech Connect

    Li, Yongfeng; Qu, Shaobo; Wang, Jiafu; Chen, Hongya; Zhang, Jieqiu; Xu, Zhuo; Zhang, Anxue

    2014-06-02

    Phase gradient metasurface (PGMs) are artificial surfaces that can provide pre-defined in-plane wave-vectors to manipulate the directions of refracted/reflected waves. In this Letter, we propose to achieve wideband radar cross section (RCS) reduction using two-dimensional (2D) PGMs. A 2D PGM was designed using a square combination of 49 split-ring sub-unit cells. The PGM can provide additional wave-vectors along the two in-plane directions simultaneously, leading to either surface wave conversion, deflected reflection, or diffuse reflection. Both the simulation and experiment results verified the wide-band, polarization-independent, high-efficiency RCS reduction induced by the 2D PGM.

  16. A compact chaotic laser device with a two-dimensional external cavity structure

    SciTech Connect

    Sunada, Satoshi Adachi, Masaaki; Fukushima, Takehiro; Shinohara, Susumu; Arai, Kenichi; Harayama, Takahisa

    2014-06-16

    We propose a compact chaotic laser device, which consists of a semiconductor laser and a two-dimensional (2D) external cavity for delayed optical feedback. The overall size of the device is within 230 μm × 1 mm. A long time delay sufficient for chaos generation can be achieved with the small area by the multiple reflections at the 2D cavity boundary, and the feedback strength is controlled by the injection current to the external cavity. We experimentally demonstrate that a variety of output properties, including chaotic output, can be selectively generated by controlling the injection current to the external cavity.

  17. Phase-sensitive two-dimensional neutron shearing interferometer and

    Office of Scientific and Technical Information (OSTI)

    Hartmann sensor (Patent) | SciTech Connect Patent: Phase-sensitive two-dimensional neutron shearing interferometer and Hartmann sensor Citation Details In-Document Search Title: Phase-sensitive two-dimensional neutron shearing interferometer and Hartmann sensor A neutron imaging system detects both the phase shift and absorption of neutrons passing through an object. The neutron imaging system is based on either of two different neutron wavefront sensor techniques: 2-D shearing

  18. Two dimensional unstable scar statistics.

    SciTech Connect

    Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Kotulski, Joseph Daniel; Lee, Kelvin S. H. (ITT Industries/AES Los Angeles, CA)

    2006-12-01

    This report examines the localization of time harmonic high frequency modal fields in two dimensional cavities along periodic paths between opposing sides of the cavity. The cases where these orbits lead to unstable localized modes are known as scars. This paper examines the enhancements for these unstable orbits when the opposing mirrors are both convex and concave. In the latter case the construction includes the treatment of interior foci.

  19. Two-dimensional heterostructures: fabrication, characterization, and application

    DOE PAGES [OSTI]

    Wang, Hong; Liu, Fucai; Fu, Wei; Fang, Zheyu; Zhou, Wu; Liu, Zheng

    2014-08-13

    Two-dimensional (2D) materials such as graphene, hexagonal boron nitrides (hBN), and transition metal dichalcogenides (TMDs, e.g., MoS2) have attracted considerable attention in the past few years because of their novel properties and versatile potential applications. These 2D layers can be integrated into a monolayer (lateral 2D heterostructure) or a multilayer stack (vertical 2D heterostructure). The resulting artificial 2D structures provide access to new properties and applications beyond their component 2D atomic crystals and hence, they are emerging as a new exciting field of research. Lastly, in this article, we review recent progress on the fabrication, characterization, and applications of variousmore » 2D heterostructures.« less

  20. Two-dimensional fourier transform spectrometer

    DOEpatents

    DeFlores, Lauren; Tokmakoff, Andrei

    2013-09-03

    The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.

  1. Mesh2d

    Energy Science and Technology Software Center

    2011-12-31

    Mesh2d is a Fortran90 program designed to generate two-dimensional structured grids of the form [x(i),y(i,j)] where [x,y] are grid coordinates identified by indices (i,j). The x(i) coordinates alone can be used to specify a one-dimensional grid. Because the x-coordinates vary only with the i index, a two-dimensional grid is composed in part of straight vertical lines. However, the nominally horizontal y(i,j0) coordinates along index i are permitted to undulate or otherwise vary. Mesh2d also assignsmore » an integer material type to each grid cell, mtyp(i,j), in a user-specified manner. The complete grid is specified through three separate input files defining the x(i), y(i,j), and mtyp(i,j) variations.« less

  2. Phase-sensitive two-dimensional neutron shearing interferometer and Hartmann sensor

    SciTech Connect

    Baker, Kevin

    2015-12-08

    A neutron imaging system detects both the phase shift and absorption of neutrons passing through an object. The neutron imaging system is based on either of two different neutron wavefront sensor techniques: 2-D shearing interferometry and Hartmann wavefront sensing. Both approaches measure an entire two-dimensional neutron complex field, including its amplitude and phase. Each measures the full-field, two-dimensional phase gradients and, concomitantly, the two-dimensional amplitude mapping, requiring only a single measurement.

  3. Synthesis of Two-Dimensional Materials for Capacitive Energy Storage

    DOE PAGES [OSTI]

    Mendoza-Sánchez, Beatriz; Gogotsi, Yury

    2016-06-02

    The unique properties and great variety of two-dimensional (2D) nanomaterials make them highly attractive for energy storage applications. Here, an insight into the progress made towards the application of 2D nanomaterials for capacitive energy storage is provided. Moreover, synthesis methods, and electrochemical performance of various classes of 2D nanomaterials, particularly based on graphene, transition metal oxides, dichalcogenides, and carbides, are presented. Some factors that directly influence capacitive performance are discussed throughout the text and include nanosheet composition, morphology and texture, electrode architecture, and device configuration. Recent progress in the fabrication of 2D-nanomaterials-based microsupercapacitors and flexible and free-standing supercapacitors is presented.more » The main electrode manufacturing techniques with emphasis on scalability and cost-effectiveness are discussed, and include laser scribing, printing, and roll-to-roll manufacture. Some various issues that prevent the use of the full energy-storage potential of 2D nanomaterials and how they have been tackled are discussed, and include nanosheet aggregation and the low electrical conductivity of some 2D nanomaterials. In particular, the design of hybrid and hierarchical 2D and 3D structures based on 2D nanomaterials is presented. Other challenges and opportunities are discussed and include: control of nanosheets size and thickness, chemical and electrochemical instability, and scale-up of electrode films.« less

  4. Recent Advances in Two-Dimensional Materials Beyond Graphene

    SciTech Connect

    Meunier, Vincent; Sumpter, Bobby G.; Terrones Maldonado, Mauricio; Terrones Maldonado, Humberto; Liang, Liangbo; Cooper, Valentino R.; Bhimanapati, Ganesh; Lin, Zhong; Jung, Yeongwoong; Cha, Judy; Das, Saptarshi; Xiao, Di; Son, Youngwoo; Strano, Michael; Louie, Steven G.; Ringe, Emilie; Xia, Fengnian; Wang, Yeliang; Akinwande, Deji; Zhu, Jun; Schuller, John; Schaak, Raymond; Robinson, Joshua A

    2015-11-06

    The isolation of graphene in 2004 by peeling apart the atomically-thin sheets that comprise graphite was a defining moment for the birth of a field: Two-dimensional (2D) materials. In recent years, there has been a rapidly increasing number of papers focusing on non-graphene layered materials, including transition-metal dichalcogenides (TMDs), because of the new properties and applications that emerge upon 2D confinement. Here we review significant recent advances and important new developments in 2D materials beyond graphene . We provide insight into the theoretical modeling and understanding of the van der Waals forces that hold together the 2D layers in bulk solids, as well as their excitonic properties and growth morphologies. Additionally, we highlight recent breakthroughs in TMD synthesis and characterization and discuss the newest families of 2D materials, including monoelement 2D materials (i.e., silicene, phosphorene, etc.) and transition metal carbide- and carbon nitride-based MXenes. We then discuss the doping and functionalization of 2D materials beyond graphene, which enable device applications, followed by advances in electronic, optoelectronic, and magnetic devices and theory. Finally, we provide perspectives on the future of 2D materials beyond graphene.

  5. Recent Advances in Two-Dimensional Materials Beyond Graphene

    DOE PAGES [OSTI]

    Meunier, Vincent; Sumpter, Bobby G.; Terrones Maldonado, Mauricio; Terrones Maldonado, Humberto; Liang, Liangbo; Cooper, Valentino R.; Bhimanapati, Ganesh; Lin, Zhong; Jung, Yeongwoong; Cha, Judy; et al

    2015-11-06

    The isolation of graphene in 2004 by peeling apart the atomically-thin sheets that comprise graphite was a defining moment for the birth of a field: Two-dimensional (2D) materials. In recent years, there has been a rapidly increasing number of papers focusing on non-graphene layered materials, including transition-metal dichalcogenides (TMDs), because of the new properties and applications that emerge upon 2D confinement. Here we review significant recent advances and important new developments in 2D materials beyond graphene . We provide insight into the theoretical modeling and understanding of the van der Waals forces that hold together the 2D layers in bulkmore » solids, as well as their excitonic properties and growth morphologies. Additionally, we highlight recent breakthroughs in TMD synthesis and characterization and discuss the newest families of 2D materials, including monoelement 2D materials (i.e., silicene, phosphorene, etc.) and transition metal carbide- and carbon nitride-based MXenes. We then discuss the doping and functionalization of 2D materials beyond graphene, which enable device applications, followed by advances in electronic, optoelectronic, and magnetic devices and theory. Finally, we provide perspectives on the future of 2D materials beyond graphene.« less

  6. Electronic transport in two-dimensional high dielectric constant nanosystems

    DOE PAGES [OSTI]

    Ortuño, M.; Somoza, A. M.; Vinokur, V. M.; Baturina, T. I.

    2015-04-10

    There has been remarkable recent progress in engineering high-dielectric constant two dimensional (2D) materials, which are being actively pursued for applications in nanoelectronics in capacitor and memory devices, energy storage, and high-frequency modulation in communication devices. Yet many of the unique properties of these systems are poorly understood and remain unexplored. Here we report a numerical study of hopping conductivity of the lateral network of capacitors, which models two-dimensional insulators, and demonstrate that 2D long-range Coulomb interactions lead to peculiar size effects. We find that the characteristic energy governing electronic transport scales logarithmically with either system size or electrostatic screeningmore » length depending on which one is shorter. Our results are relevant well beyond their immediate context, explaining, for example, recent experimental observations of logarithmic size dependence of electric conductivity of thin superconducting films in the critical vicinity of superconductor-insulator transition where a giant dielectric constant develops. Our findings mark a radical departure from the orthodox view of conductivity in 2D systems as a local characteristic of materials and establish its macroscopic global character as a generic property of high-dielectric constant 2D nanomaterials.« less

  7. Electronic transport in two-dimensional high dielectric constant nanosystems

    SciTech Connect

    Ortuño, M.; Somoza, A. M.; Vinokur, V. M.; Baturina, T. I.

    2015-04-10

    There has been remarkable recent progress in engineering high-dielectric constant two dimensional (2D) materials, which are being actively pursued for applications in nanoelectronics in capacitor and memory devices, energy storage, and high-frequency modulation in communication devices. Yet many of the unique properties of these systems are poorly understood and remain unexplored. Here we report a numerical study of hopping conductivity of the lateral network of capacitors, which models two-dimensional insulators, and demonstrate that 2D long-range Coulomb interactions lead to peculiar size effects. We find that the characteristic energy governing electronic transport scales logarithmically with either system size or electrostatic screening length depending on which one is shorter. Our results are relevant well beyond their immediate context, explaining, for example, recent experimental observations of logarithmic size dependence of electric conductivity of thin superconducting films in the critical vicinity of superconductor-insulator transition where a giant dielectric constant develops. Our findings mark a radical departure from the orthodox view of conductivity in 2D systems as a local characteristic of materials and establish its macroscopic global character as a generic property of high-dielectric constant 2D nanomaterials.

  8. Generates 2D Input for DYNA NIKE & TOPAZ

    Energy Science and Technology Software Center

    1996-07-15

    MAZE is an interactive program that serves as an input and two-dimensional mesh generator for DYNA2D, NIKE2D, TOPAZ2D, and CHEMICAL TOPAZ2D. MAZE also generates a basic template for ISLAND input. MAZE has been applied to the generation of input data to study the response of two-dimensional solids and structures undergoing finite deformations under a wide variety of large deformation transient dynamic and static problems and heat transfer analyses.

  9. Two-dimensional Imaging Velocity Interferometry: Technique and Data Analysis

    SciTech Connect

    Erskine, D J; Smith, R F; Bolme, C; Celliers, P; Collins, G

    2011-03-23

    We describe the data analysis procedures for an emerging interferometric technique for measuring motion across a two-dimensional image at a moment in time, i.e. a snapshot 2d-VISAR. Velocity interferometers (VISAR) measuring target motion to high precision have been an important diagnostic in shockwave physics for many years Until recently, this diagnostic has been limited to measuring motion at points or lines across a target. We introduce an emerging interferometric technique for measuring motion across a two-dimensional image, which could be called a snapshot 2d-VISAR. If a sufficiently fast movie camera technology existed, it could be placed behind a traditional VISAR optical system and record a 2d image vs time. But since that technology is not yet available, we use a CCD detector to record a single 2d image, with the pulsed nature of the illumination providing the time resolution. Consequently, since we are using pulsed illumination having a coherence length shorter than the VISAR interferometer delay ({approx}0.1 ns), we must use the white light velocimetry configuration to produce fringes with significant visibility. In this scheme, two interferometers (illuminating, detecting) having nearly identical delays are used in series, with one before the target and one after. This produces fringes with at most 50% visibility, but otherwise has the same fringe shift per target motion of a traditional VISAR. The 2d-VISAR observes a new world of information about shock behavior not readily accessible by traditional point or 1d-VISARS, simultaneously providing both a velocity map and an 'ordinary' snapshot photograph of the target. The 2d-VISAR has been used to observe nonuniformities in NIF related targets (polycrystalline diamond, Be), and in Si and Al.

  10. Two-dimensional interpreter for field-reversed configurations

    SciTech Connect

    Steinhauer, Loren

    2014-08-15

    An interpretive method is developed for extracting details of the fully two-dimensional (2D) “internal” structure of field-reversed configurations (FRC) from common diagnostics. The challenge is that only external and “gross” diagnostics are routinely available in FRC experiments. Inferring such critical quantities as the poloidal flux and the particle inventory has commonly relied on a theoretical construct based on a quasi-one-dimensional approximation. Such inferences sometimes differ markedly from the more accurate, fully 2D reconstructions of equilibria. An interpreter based on a fully 2D reconstruction is needed to enable realistic within-the-shot tracking of evolving equilibrium properties. Presented here is a flexible equilibrium reconstruction with which an extensive data base of equilibria was constructed. An automated interpreter then uses this data base as a look-up table to extract evolving properties. This tool is applied to data from the FRC facility at Tri Alpha Energy. It yields surprising results at several points, such as the inferences that the local β (plasma pressure/external magnetic pressure) of the plasma climbs well above unity and the poloidal flux loss time is somewhat longer than previously thought, both of which arise from full two-dimensionality of FRCs.

  11. A Two-Dimensional Compressible Gas Flow Code

    Energy Science and Technology Software Center

    1995-03-17

    F2D is a general purpose, two dimensional, fully compressible thermal-fluids code that models most of the phenomena found in situations of coupled fluid flow and heat transfer. The code solves momentum, continuity, gas-energy, and structure-energy equations using a predictor-correction solution algorithm. The corrector step includes a Poisson pressure equation. The finite difference form of the equation is presented along with a description of input and output. Several example problems are included that demonstrate the applicabilitymore » of the code in problems ranging from free fluid flow, shock tubes and flow in heated porous media.« less

  12. MOSS2D V1

    Energy Science and Technology Software Center

    2001-01-31

    This software reduces the data from two-dimensional kSA MOS program, k-Space Associates, Ann Arbor, MI. Initial MOS data is recorded without headers in 38 columns, with one row of data per acquisition per lase beam tracked. The final MOSS 2d data file is reduced, graphed, and saved in a tab-delimited column format with headers that can be plotted in any graphing software.

  13. Superfluid response of two-dimensional parahydrogen clusters in confinement

    SciTech Connect

    Idowu, Saheed; Boninsegni, Massimo

    2015-04-07

    We study by computer simulations the effect of confinement on the superfluid properties of small two-dimensional (2D) parahydrogen clusters. For clusters of fewer than twenty molecules, the superfluid response in the low temperature limit is found to remain comparable in magnitude to that of free clusters, within a rather wide range of depth and size of the confining well. The resilience of the superfluid response is attributable to the “supersolid” character of these clusters. We investigate the possibility of establishing a bulk 2D superfluid “cluster crystal” phase of p-H{sub 2}, in which a global superfluid response would arise from tunnelling of molecules across adjacent unit cells. The computed energetics suggests that for clusters of about ten molecules, such a phase may be thermodynamically stable against the formation of the equilibrium insulating crystal, for values of the cluster crystal lattice constant possibly allowing tunnelling across adjacent unit cells.

  14. Correlating hydrodynamic radii with that of two-dimensional nanoparticles

    SciTech Connect

    Yue, Yuan; Kan, Yuwei; Clearfield, Abraham; Choi, Hyunho; Liang, Hong

    2015-12-21

    Dynamic light scattering (DLS) is one of the most adapted methods to measure the size of nanoparticles, as referred to the hydrodynamic radii (R{sub h}). However, the R{sub h} represents only that of three-dimensional spherical nanoparticles. In the present research, the size of two-dimensional (2D) nanoparticles of yttrium oxide (Y{sub 2}O{sub 3}) and zirconium phosphate (ZrP) was evaluated through comparing their hydrodynamic diameters via DLS with lateral sizes obtained using scanning and transmission electron microscopy. We demonstrate that the hydrodynamic radii are correlated with the lateral sizes of both square and circle shaped 2D nanoparticles. Two proportional coefficients, i.e., correcting factors, are proposed for the Brownian motion status of 2D nanoparticles. The correction is possible by simplifying the calculation of integrals in the case of small thickness approximation. The correcting factor has great significance for investigating the translational diffusion behavior of 2D nanoparticles in a liquid and in effective and low-cost measurement in terms of size and morphology of shape-specific nanoparticles.

  15. Two-dimensional state in driven magnetohydrodynamic turbulence

    SciTech Connect

    Bigot, Barbara; Galtier, Sebastien

    2011-02-15

    The dynamics of the two-dimensional (2D) state in driven three-dimensional (3D) incompressible magnetohydrodynamic turbulence is investigated through high-resolution direct numerical simulations and in the presence of an external magnetic field at various intensities. For such a flow the 2D state (or slow mode) and the 3D modes correspond, respectively, to spectral fluctuations in the plane k{sub ||}=0 and in the area k{sub ||}>0. It is shown that if initially the 2D state is set to zero it becomes nonnegligible in few turnover times, particularly when the external magnetic field is strong. The maintenance of a large-scale driving leads to a break for the energy spectra of 3D modes; when the driving is stopped, the previous break is removed and a decay phase emerges with Alfvenic fluctuations. For a strong external magnetic field the energy at large perpendicular scales lies mainly in the 2D state, and in all situations a pinning effect is observed at small scales.

  16. Synthesis of Two-Dimensional Materials by Selective Extraction

    SciTech Connect

    Naguib, Michael; Gogotsi, Yury

    2014-12-09

    Two-dimensional (2D) materials have attracted much attention in the past decade. They offer high specific surface area, as well as electronic structure and properties that differ from their bulk counterparts due to the low dimensionality. Graphene is the best known and the most studied 2D material, but metal oxides and hydroxides (including clays), dichalcogenides, boron nitride (BN), and other materials that are one or several atoms thick are receiving increasing attention. They may deliver a combination of properties that cannot be provided by other materials. The most common synthesis approach in general is by reacting different elements or compounds to form a new compound. However, this approach does not necessarily work well for low-dimensional structures, since it favors formation of energetically preferred 3D (bulk) solids. Many 2D materials are produced by exfoliation of van der Waals solids, such as graphite or MoS2, breaking large particles into 2D layers. However, these approaches are not universal; for example, 2D transition metal carbides cannot be produced by any of them. An alternative but less studied way of material synthesis is the selective extraction process, which is based on the difference in reactivity and stability between the different components (elements or structural units) of the original material. It can be achieved using thermal, chemical, or electrochemical processes. Many 2D materials have been synthesized using selective extraction, such as graphene from SiC, transition metal oxides (TMO) from layered 3D salts, and transition metal carbides or carbonitrides (MXenes) from MAX phases. Selective extraction synthesis is critically important when the bonds between the building blocks of the material are too strong (e.g., in carbides) to be broken mechanically in order to form nanostructures. Unlike extractive metallurgy, where the extracted metal is the goal of the process, selective extraction of one or more elements from the precursor

  17. Synthesis of Two-Dimensional Materials by Selective Extraction

    DOE PAGES [OSTI]

    Naguib, Michael; Gogotsi, Yury

    2014-12-09

    Two-dimensional (2D) materials have attracted much attention in the past decade. They offer high specific surface area, as well as electronic structure and properties that differ from their bulk counterparts due to the low dimensionality. Graphene is the best known and the most studied 2D material, but metal oxides and hydroxides (including clays), dichalcogenides, boron nitride (BN), and other materials that are one or several atoms thick are receiving increasing attention. They may deliver a combination of properties that cannot be provided by other materials. The most common synthesis approach in general is by reacting different elements or compounds tomore » form a new compound. However, this approach does not necessarily work well for low-dimensional structures, since it favors formation of energetically preferred 3D (bulk) solids. Many 2D materials are produced by exfoliation of van der Waals solids, such as graphite or MoS2, breaking large particles into 2D layers. However, these approaches are not universal; for example, 2D transition metal carbides cannot be produced by any of them. An alternative but less studied way of material synthesis is the selective extraction process, which is based on the difference in reactivity and stability between the different components (elements or structural units) of the original material. It can be achieved using thermal, chemical, or electrochemical processes. Many 2D materials have been synthesized using selective extraction, such as graphene from SiC, transition metal oxides (TMO) from layered 3D salts, and transition metal carbides or carbonitrides (MXenes) from MAX phases. Selective extraction synthesis is critically important when the bonds between the building blocks of the material are too strong (e.g., in carbides) to be broken mechanically in order to form nanostructures. Unlike extractive metallurgy, where the extracted metal is the goal of the process, selective extraction of one or more elements from the

  18. Synthesis of Two-Dimensional Materials by Selective Extraction

    SciTech Connect

    Abdelmalak, Michael Naguib; Gogotsi, Yury

    2015-01-01

    Two-dimensional (2D) materials have attracted much attention in the past decade. They offer high specific surface area, as well as electronic structure and properties that differ from their bulk counterparts due to the low dimensionality. Graphene is the best known and the most studied 2D material, but metal oxides and hydroxides (including clays), dichalcogenides, boron nitride (BN), and other materials that are one or several atoms thick are receiving increasing attention. They may deliver a combination of properties that cannot be provided by other materials. The most common synthesis approach in general is by reacting different elements or compounds to form a new compound. However, this approach does not necessarily work well for low-dimensional structures, since it favors formation of energetically preferred 3D (bulk) solids. Many 2D materials are produced by exfoliation of van der Waals solids, such as graphite or MoS2, breaking large particles into 2D layers. However, these approaches are not universal; for example, 2D transition metal carbides cannot be produced by any of them. An alternative but less studied way of material synthesis is the selective extraction process, which is based on the difference in reactivity and stability between the different components (elements or structural units) of the original material. It can be achieved using thermal, chemical, or electrochemical processes. Many 2D materials have been synthesized using selective extraction, such as graphene from SiC, transition metal oxides (TMO) from layered 3D salts, and transition metal carbides or carbonitrides (MXenes) from MAX phases. Selective extraction synthesis is critically important when the bonds between the building blocks of the material are too strong (e.g., in carbides) to be broken mechanically in order to form nanostructures. Unlike extractive metallurgy, where the extracted metal is the goal of the process, selective extraction of one or more elements from the precursor

  19. Holographic and time-resolving ability of pulse-pair two-dimensional velocity interferometry

    SciTech Connect

    Erskine, David J. Smith, R. F.; Celliers, P. M.; Collins, G. W.; Bolme, C. A.; Ali, S. J.

    2014-06-15

    Previous velocity interferometers used at research laboratories for shock physics experiments measured target motion at a point or many points on a line on the target. Recently, a two-dimensional (2d) version (2d-velocity interferometer system for any reflector) has been demonstrated using a pair of ultrashort (3 ps) pulses for illumination, separated by 268 ps. We have discovered new abilities for this instrument, by treating the complex output image as a hologram. For data taken in an out of focus configuration, we can Fourier process to bring narrow features such as cracks into sharp focus, which are otherwise completely blurred. This solves a practical problem when using high numerical aperture optics having narrow depth of field to observe moving surface features such as cracks. Furthermore, theory predicts that the target appearance (position and reflectivity) at two separate moments in time are recorded by the main and conjugate images of the same hologram, and are partially separable during analysis for narrow features. Hence, for the cracks we bring into refocus, we can make a two-frame movie with a subnanosecond frame period. Longer and shorter frame periods are possible with different interferometer delays. Since the megapixel optical detectors we use have superior spatial resolution over electronic beam based framing cameras, this technology could be of great use in studying microscopic three-dimensional-behavior of targets at ultrafast times scales. Demonstrations on shocked silicon are shown.

  20. Stability of skyrmion lattices and symmetries of quasi-two-dimensional chiral magnets

    DOE PAGES [OSTI]

    Gungordu, Utkan; Nepal, Rabindra; Tretiakov, Oleg A.; Belashchenko, Kirill; Kovalev, Alexey A.

    2016-02-24

    Recently there has been substantial interest in realizations of skyrmions, in particular in quasi-two-dimensional (2D) systems due to increased stability resulting from reduced dimensionality. A stable skyrmion, representing the smallest realizable magnetic texture, could be an ideal element for ultradense magnetic memories. Here we use the most general form of the quasi-2D free energy with Dzyaloshinskii-Moriya interactions constructed from general symmetry considerations reflecting the underlying system. We predict that the skyrmion phase is robust and it is present even when the system lacks the in-plane rotational symmetry. In fact, the lowered symmetry leads to increased stability of vortex-antivortex lattices withmore » fourfold symmetry and in-plane spirals, in some instances even in the absence of an external magnetic field. Our results relate different hexagonal and square cell phases to the symmetries of materials used for realizations of skyrmions. This will give clear directions for experimental realizations of hexagonal and square cell phases, and will allow engineering of skyrmions with unusual properties. We also predict striking differences in gyrodynamics induced by spin currents for isolated skyrmions and for crystals where spin currents can be induced by charge carriers or by thermal magnons. As a result, we find that under certain conditions, isolated skyrmions can move along the current without a side motion which can have implications for realizations of magnetic memories.« less

  1. Two-dimensional heavy fermions on the strongly correlated boundaries...

    Office of Scientific and Technical Information (OSTI)

    Two-dimensional heavy fermions on the strongly correlated boundaries of Kondo topological insulators Prev Next Title: Two-dimensional heavy fermions on the strongly ...

  2. Two-dimensional stimulated resonance Raman spectroscopy of molecules...

    Office of Scientific and Technical Information (OSTI)

    Two-dimensional stimulated resonance Raman spectroscopy of molecules with broadband x-ray pulses Citation Details In-Document Search Title: Two-dimensional stimulated resonance ...

  3. Two-Dimensional Topological Insulator State and Topological Phase...

    Office of Scientific and Technical Information (OSTI)

    Two-Dimensional Topological Insulator State and Topological Phase Transition in Bilayer Graphene Citation Details In-Document Search Title: Two-Dimensional Topological Insulator ...

  4. Fully localized two-dimensional embedded solitons

    SciTech Connect

    Yang Jianke

    2010-11-15

    We report the prediction of fully localized two-dimensional embedded solitons. These solitons are obtained in a quasi-one-dimensional waveguide array which is periodic along one spatial direction and localized along the orthogonal direction. Under appropriate nonlinearity, these solitons are found to exist inside the Bloch bands (continuous spectrum) of the waveguide and thus are embedded solitons. These embedded solitons are fully localized along both spatial directions. In addition, they are fully stable under perturbations.

  5. Molecular dynamics study of two-dimensional sum frequency generation spectra at vapor/water interface

    SciTech Connect

    Ishiyama, Tatsuya; Morita, Akihiro; Tahara, Tahei

    2015-06-07

    Two-dimensional heterodyne-detected vibrational sum frequency generation (2D HD-VSFG) spectra at vapor/water interface were studied by molecular dynamics (MD) simulation with a classical flexible and nonpolarizable model. The present model well describes the spectral diffusion of 2D infrared spectrum of bulk water as well as 2D HD-VSFG at the interface. The effect of isotopic dilution on the 2D HD-VSFG was elucidated by comparing the normal (H{sub 2}O) water and HOD water. We further performed decomposition analysis of 2D HD-VSFG into the hydrogen-bonding and the dangling (or free) OH vibrations, and thereby disentangled the different spectral responses and spectral diffusion in the 2D HD-VSFG. The present MD simulation demonstrated the role of anharmonic coupling between these modes on the cross peak in the 2D HD-VSFG spectrum.

  6. 2-d Finite Element Code Postprocessor

    Energy Science and Technology Software Center

    1996-07-15

    ORION is an interactive program that serves as a postprocessor for the analysis programs NIKE2D, DYNA2D, TOPAZ2D, and CHEMICAL TOPAZ2D. ORION reads binary plot files generated by the two-dimensional finite element codes currently used by the Methods Development Group at LLNL. Contour and color fringe plots of a large number of quantities may be displayed on meshes consisting of triangular and quadrilateral elements. ORION can compute strain measures, interface pressures along slide lines, reaction forcesmore » along constrained boundaries, and momentum. ORION has been applied to study the response of two-dimensional solids and structures undergoing finite deformations under a wide variety of large deformation transient dynamic and static problems and heat transfer analyses.« less

  7. Simulated annealing applied to two-dimensional low-beta reduced magnetohydrodynamics

    SciTech Connect

    Chikasue, Y.; Furukawa, M.

    2015-02-15

    The simulated annealing (SA) method is applied to two-dimensional (2D) low-beta reduced magnetohydrodynamics (R-MHD). We have successfully obtained stationary states of the system numerically by the SA method with Casimir invariants preserved. Since the 2D low-beta R-MHD has two fields, the relaxation process becomes complex compared to a single field system such as 2D Euler flow. The obtained stationary state can have fine structure. We have found that the fine structure appears because the relaxation processes are different between kinetic energy and magnetic energy.

  8. Two-dimensional electronic spectroscopy signatures of the glass transition

    DOE PAGES [OSTI]

    Lewis, K. L. .M.; Myers, J. A.; Fuller, F.; Tekavec, P. F.; Ogilvie, J. P.

    2010-01-01

    Two-dimensional electronic spectroscopy is a sensitive probe of solvation dynamics. Using a pump–probe geometry with a pulse shaper [ Optics Express 15 (2007), 16681-16689; Optics Express 16 (2008), 17420-17428], we present temperature dependent 2D spectra of laser dyes dissolved in glass-forming solvents. At low waiting times, the system has not yet relaxed, resulting in a spectrum that is elongated along the diagonal. At longer times, the system loses its memory of the initial excitation frequency, and the 2D spectrum rounds out. As the temperature is lowered, the time scale of this relaxation grows, and the elongation persists for longermore » waiting times. This can be measured in the ratio of the diagonal width to the anti-diagonal width; the behavior of this ratio is representative of the frequency–frequency correlation function [ Optics Letters 31 (2006), 3354–3356]. Near the glass transition temperature, the relaxation behavior changes. Understanding this change is important for interpreting temperature-dependent dynamics of biological systems.« less

  9. Dragging two-dimensional discrete solitons by moving linear defects

    SciTech Connect

    Brazhnyi, Valeriy A.; Malomed, Boris A.

    2011-07-15

    We study the mobility of small-amplitude solitons attached to moving defects which drag the solitons across a two-dimensional (2D) discrete nonlinear Schroedinger lattice. Findings are compared to the situation when a free small-amplitude 2D discrete soliton is kicked in a uniform lattice. In agreement with previously known results, after a period of transient motion the free soliton transforms into a localized mode pinned by the Peierls-Nabarro potential, irrespective of the initial velocity. However, the soliton attached to the moving defect can be dragged over an indefinitely long distance (including routes with abrupt turns and circular trajectories) virtually without losses, provided that the dragging velocity is smaller than a certain critical value. Collisions between solitons dragged by two defects in opposite directions are studied too. If the velocity is small enough, the collision leads to a spontaneous symmetry breaking, featuring fusion of two solitons into a single one, which remains attached to either of the two defects.

  10. Two-Dimensional Ground Water Transport

    Energy Science and Technology Software Center

    1992-03-05

    FRACFLO computes the two-dimensional, space, time dependent, convective dispersive transport of a single radionuclide in an unbounded single or multiple parallel fracture system with constant aperture. It calculates the one-dimensional diffusive transport into the rock matrix as well as the mass flux and cumulative mass flux at any point in the fracture. Steady-state isothermal ground water flow and parallel streamlines are assumed in the fracture, and the rock matrix is considered to be fully saturatedmore » with immobile water. The model can treat a single or multiple finite patch source or a Gaussian distributed source subject to a step or band release mode.« less

  11. Theory and application of the RAZOR two-dimensional continuous energy lattice physics code

    SciTech Connect

    Zerkle, M.L.; Abu-Shumays, I.K.; Ott, M.W.; Winwood, J.P.

    1997-04-01

    The theory and application of the RAZOR two-dimensional, continuous energy lattice physics code are discussed. RAZOR solves the continuous energy neutron transport equation in one- and two-dimensional geometries, and calculates equivalent few-group diffusion theory constants that rigorously account for spatial and spectral self-shielding effects. A dual energy resolution slowing down algorithm is used to reduce computer memory and disk storage requirements for the slowing down calculation. Results are presented for a 2D BWR pin cell depletion benchmark problem.

  12. Two-dimensional Dirac signature of germanene

    SciTech Connect

    Zhang, L.; Bampoulis, P.; Houselt, A. van; Zandvliet, H. J. W.

    2015-09-14

    The structural and electronic properties of germanene coated Ge{sub 2}Pt clusters have been determined by scanning tunneling microscopy and spectroscopy at room temperature. The interior of the germanene sheet exhibits a buckled honeycomb structure with a lattice constant of 4.3 Å and a buckling of 0.2 Å. The zigzag edges of germanene are reconstructed and display a 4× periodicity. The differential conductivity of the interior of the germanene sheet has a V-shape, which is reminiscent of the density of states of a two-dimensional Dirac system. The minimum of the differential conductivity is located close to the Fermi level and has a non-zero value, which we ascribe to the metallic character of the underlying Ge{sub 2}Pt substrate. Near the reconstructed germanene zigzag edges the shape of the differential conductivity changes from a V-shape to a more parabolic-like shape, revealing that the reconstructed germanene zigzag edges do not exhibit a pronounced metallic edge state.

  13. Turbulent equipartitions in two dimensional drift convection

    SciTech Connect

    Isichenko, M.B.; Yankov, V.V.

    1995-07-25

    Unlike the thermodynamic equipartition of energy in conservative systems, turbulent equipartitions (TEP) describe strongly non-equilibrium systems such as turbulent plasmas. In turbulent systems, energy is no longer a good invariant, but one can utilize the conservation of other quantities, such as adiabatic invariants, frozen-in magnetic flux, entropy, or combination thereof, in order to derive new, turbulent quasi-equilibria. These TEP equilibria assume various forms, but in general they sustain spatially inhomogeneous distributions of the usual thermodynamic quantities such as density or temperature. This mechanism explains the effects of particle and energy pinch in tokamaks. The analysis of the relaxed states caused by turbulent mixing is based on the existence of Lagrangian invariants (quantities constant along fluid-particle or other orbits). A turbulent equipartition corresponds to the spatially uniform distribution of relevant Lagrangian invariants. The existence of such turbulent equilibria is demonstrated in the simple model of two dimensional electrostatically turbulent plasma in an inhomogeneous magnetic field. The turbulence is prescribed, and the turbulent transport is assumed to be much stronger than the classical collisional transport. The simplicity of the model makes it possible to derive the equations describing the relaxation to the TEP state in several limits.

  14. 2D 'Flat' Boron Yields a Superconducting Surprise

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2D 'Flat' Boron Yields a Superconducting Surprise 2D 'Flat' Boron Yields a Superconducting Surprise Simulations Run at NERSC Help Reveal Material's Superconducting Superpowers April 22, 2016 2Dboron Electrons with opposite momenta and spins pair up via lattice vibrations at low temperatures in 2D boron and give it superconducting properties. Image: Evgeni Penev, Rice University Density functional theory simulations run at NERSC helped Rice University researchers determine that two-dimensional

  15. Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

    DOE PAGES [OSTI]

    Lin, Ming -Wei; Zhung, Houlong L.; Yan, Jiaqiang; Ward, Thomas Zac; Puretzky, Alexander A.; Rouleau, Christopher M.; Gai, Zheng; Liang, Liangbo; Meunier, Vincent; Ganesh, Panchapakesan; et al

    2015-11-27

    Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have recently shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained elusive. In this work we for the first time exfoliate the CrSiTe3, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO2 substrate. The Raman spectra show the good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra ofmore » 2D CrSiTe3, giving a strong evidence for the existence of 2D CrSiTe3 crystals. When the thickness of the CrSiTe3 crystals is reduced to few-layers, we observed a clear change in resistivity at 80~120 K, consistent with the theoretical calculations on the Curie temperature (Tc) of ~80 K for the magnetic ordering of 2D CrSiTe3 crystals. As a result, the ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable numerous applications in nano-spintronics.« less

  16. Reconfigurable site-selective manipulation of atomic quantum systems in two-dimensional arrays of dipole traps

    SciTech Connect

    Kruse, J.; Gierl, C.; Schlosser, M.; Birkl, G.

    2010-06-15

    We trap atoms in versatile two-dimensional (2D) arrays of optical potentials, prepare flexible 2D spin configurations, perform site-selective coherent manipulation, and demonstrate the implementation of simultaneous measurements of different system properties, such as dephasing and decoherence. This approach for the flexible manipulation of atomic quantum systems is based on the combination of 2D arrays of microlenses and 2D arrays of liquid crystal light modulators. This offers extended types of control for the investigation of quantum degenerate gases, quantum information processing, and quantum simulations.

  17. Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum

    Office of Scientific and Technical Information (OSTI)

    Wells and Quantum Dots (Technical Report) | SciTech Connect Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots Citation Details In-Document Search Title: Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots This final report describes the activities undertaken under grant "Optical Two-Dimensional Spectroscopy of Disordered Semiconductor Quantum Wells and Quantum Dots". The goal of this program

  18. Local Imaging of High Mobility Two-Dimensional Electron Systems...

    Office of Scientific and Technical Information (OSTI)

    Tunneling Microscopy Citation Details In-Document Search Title: Local Imaging of High Mobility Two-Dimensional Electron Systems with Virtual Scanning Tunneling Microscopy You ...

  19. Ferroelasticity and domain physics in two-dimensional transition...

    Office of Scientific and Technical Information (OSTI)

    Accepted Manuscript: Ferroelasticity and domain physics in two-dimensional transition metal dichalcogenide monolayers Prev Next Title: Ferroelasticity and domain physics in ...

  20. Compositions comprising free-standing two-dimensional nanocrystals

    DOEpatents

    Barsoum, Michel W.; Gogotsi, Yury; Abdelmalak, Michael Naguib; Mashtalir, Olha

    2015-11-24

    The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.

  1. Exploring two-dimensional electron gases with two-dimensional Fourier transform spectroscopy

    DOE PAGES [OSTI]

    Paul, J.; Dey, P.; Tokumoto, T.; Reno, J. L.; Hilton, D. J.; Karaiskaj, D.

    2014-10-07

    The dephasing of excitons in a modulation doped single quantum well was carefully measured using time integrated four-wave mixing (FWM) and two-dimensional Fourier transform (2DFT) spectroscopy. These are the first 2DFT measurements performed on a modulation doped single quantum well. The inhomogeneous and homogeneous excitonic line widths were obtained from the diagonal and cross-diagonal profiles of the 2DFT spectra. The laser excitation density and temperature were varied and 2DFT spectra were collected. A very rapid increase of the dephasing decay, and as a result, an increase in the cross-diagonal 2DFT linewidths with temperature was observed. Furthermore, the lineshapes of themore » 2DFT spectra suggest the presence of excitation induced dephasing and excitation induced shift.« less

  2. Exploring two-dimensional electron gases with two-dimensional Fourier transform spectroscopy

    SciTech Connect

    Paul, J.; Dey, P.; Tokumoto, T.; Reno, J. L.; Hilton, D. J.; Karaiskaj, D.

    2014-10-07

    The dephasing of excitons in a modulation doped single quantum well was carefully measured using time integrated four-wave mixing (FWM) and two-dimensional Fourier transform (2DFT) spectroscopy. These are the first 2DFT measurements performed on a modulation doped single quantum well. The inhomogeneous and homogeneous excitonic line widths were obtained from the diagonal and cross-diagonal profiles of the 2DFT spectra. The laser excitation density and temperature were varied and 2DFT spectra were collected. A very rapid increase of the dephasing decay, and as a result, an increase in the cross-diagonal 2DFT linewidths with temperature was observed. Furthermore, the lineshapes of the 2DFT spectra suggest the presence of excitation induced dephasing and excitation induced shift.

  3. Terahertz spectroscopy of two-dimensional subwavelength plasmonic structures

    SciTech Connect

    Azad, Abul K; Chen, Houtong; Taylor, Antoinette; O' Hara, John F; Han, Jiaguang; Lu, Xinchao; Zhang, Weili

    2009-01-01

    The fascinating properties of plasmonic structures have had significant impact on the development of next generation ultracompact photonic and optoelectronic components. We study two-dimensional plasmonic structures functioning at terahertz frequencies. Resonant terahertz response due to surface plasmons and dipole localized surface plasmons were investigated by the state-of-the-art terahertz time domain spectroscopy (THz-TDS) using both transmission and reflection configurations. Extraordinary terahertz transmission was demonstrated through the subwavelength metallic hole arrays made from good conducting metals as well as poor metals. Metallic arrays m!lde from Pb, generally a poor metal, and having optically thin thicknesses less than one-third of a skin depth also contributed in enhanced THz transmission. A direct transition of a surface plasmon resonance from a photonic crystal minimum was observed in a photo-doped semiconductor array. Electrical controls of the surface plasmon resonances by hybridization of the Schottkey diode between the metallic grating and the semiconductor substrate are investigated as a function of the applied reverse bias. In addition, we have demonstrated photo-induced creation and annihilation of surface plasmons with appropriate semiconductors at room temperature. According to the Fano model, the transmission properties are characterized by two essential contributions: resonant excitation of surface plasmons and nonresonant direct transmission. Such plasmonic structures may find fascinating applications in terahertz imaging, biomedical sensing, subwavelength terahertz spectroscopy, tunable filters, and integrated terahertz devices.

  4. Terahertz magneto-optical spectroscopy of a two-dimensional hole gas

    SciTech Connect

    Kamaraju, N. Taylor, A. J.; Prasankumar, R. P.; Pan, W.; Reno, J.; Ekenberg, U.; Gvozdić, D. M.; Boubanga-Tombet, S.; Upadhya, P. C.

    2015-01-19

    Two-dimensional hole gases (2DHGs) have attracted recent attention for their unique quantum physics and potential applications in areas including spintronics and quantum computing. However, their properties remain relatively unexplored, motivating the use of different techniques to study them. We used terahertz magneto-optical spectroscopy to investigate the cyclotron resonance frequency in a high mobility 2DHG, revealing a nonlinear dependence on the applied magnetic field. This is shown to be due to the complex non-parabolic valence band structure of the 2DHG, as verified by multiband Landau level calculations. We also find that impurity scattering dominates cyclotron resonance decay in the 2DHG, in contrast with the dominance of superradiant damping in two-dimensional electron gases. Our results shed light on the properties of 2DHGs, motivating further studies of these unique 2D nanosystems.

  5. Terahertz magneto-optical spectroscopy of a two-dimensional hole gas

    DOE PAGES [OSTI]

    Kamaraju, N.; Pan, W.; Ekenberg, U.; Gvozdić, D. M.; Boubanga-Tombet, S.; Upadhya, P. C.; Reno, J.; Taylor, A. J.; Prasankumar, R. P.

    2015-01-21

    Two-dimensional hole gases (2DHGs) have attracted recent attention for their unique quantum physics and potential applications in areas including spintronics and quantum computing. However, their properties remain relatively unexplored, motivating the use of different techniques to study them. We then used terahertz magneto-optical spectroscopy to investigate the cyclotron resonance frequency in a high mobility 2DHG, revealing a nonlinear dependence on the applied magnetic field. This is shown to be due to the complex non-parabolic valence band structure of the 2DHG, as verified by multiband Landau level calculations. We also found that impurity scattering dominates cyclotron resonance decay in the 2DHG,more » in contrast with the dominance of superradiant damping in two-dimensional electron gases. Our results shed light on the properties of 2DHGs, motivating further studies of these unique 2D nanosystems.« less

  6. Terahertz magneto-optical spectroscopy of a two-dimensional hole gas

    SciTech Connect

    Kamaraju, N.; Pan, W.; Ekenberg, U.; Gvozdi?, D. M.; Boubanga-Tombet, S.; Upadhya, P. C.; Reno, J.; Taylor, A. J.; Prasankumar, R. P.

    2015-01-21

    Two-dimensional hole gases (2DHGs) have attracted recent attention for their unique quantum physics and potential applications in areas including spintronics and quantum computing. However, their properties remain relatively unexplored, motivating the use of different techniques to study them. We then used terahertz magneto-optical spectroscopy to investigate the cyclotron resonance frequency in a high mobility 2DHG, revealing a nonlinear dependence on the applied magnetic field. This is shown to be due to the complex non-parabolic valence band structure of the 2DHG, as verified by multiband Landau level calculations. We also found that impurity scattering dominates cyclotron resonance decay in the 2DHG, in contrast with the dominance of superradiant damping in two-dimensional electron gases. Our results shed light on the properties of 2DHGs, motivating further studies of these unique 2D nanosystems.

  7. Effective field theory and integrability in two-dimensional Mott transition

    SciTech Connect

    Bottesi, Federico L.; Zemba, Guillermo R.

    2011-08-15

    Highlights: > Mott transition in 2d lattice fermion model. > 3D integrability out of 2D. > Effective field theory for Mott transition in 2d. > Double Chern-Simons. > d-Density waves. - Abstract: We study the Mott transition in a two-dimensional lattice spinless fermion model with nearest neighbors density-density interactions. By means of a two-dimensional Jordan-Wigner transformation, the model is mapped onto the lattice XXZ spin model, which is shown to possess a quantum group symmetry as a consequence of a recently found solution of the Zamolodchikov tetrahedron equation. A projection (from three to two space-time dimensions) property of the solution is used to identify the symmetry of the model at the Mott critical point as U{sub q}(sl(2)-circumflex)xU{sub q}(sl(2)-circumflex), with deformation parameter q = -1. Based on this result, the low-energy effective field theory for the model is obtained and shown to be a lattice double Chern-Simons theory with coupling constant k = 1 (with the standard normalization). By further employing the effective filed theory methods, we show that the Mott transition that arises is of topological nature, with vortices in an antiferromagnetic array and matter currents characterized by a d-density wave order parameter. We also analyze the behavior of the system upon weak coupling, and conclude that it undergoes a quantum gas-liquid transition which belongs to the Ising universality class.

  8. Local Imaging of High Mobility Two-Dimensional Electron Systems...

    Office of Scientific and Technical Information (OSTI)

    Dept. SLAC ; Pfeiffer, L.N. ; West, K.W. ; Princeton U., Elect. Engion. Dept. ; Goldhaber-Gordon, D. ; Stanford U., Phys.Dept.TITLELocal Imaging of High Mobility Two-Dimensional ...

  9. Chiral Jacobians and two-dimensional QED at finite temperature

    SciTech Connect

    Reuter, M.; Dittrich, W.

    1985-07-15

    We show that in massless two-dimensional QED there is no restoration of gauge symmetry at finite temperature (because the boson mass is temperature independent), using zeta-function techniques to solve the fermionic determinant exactly.

  10. NUBOW-2D Inelastic

    Energy Science and Technology Software Center

    2002-01-31

    This program solves the two-dimensional mechanical equilbrium configuration of a core restraint system, which is subjected to radial temperature and flux gradients, on a time increment basis. At each time increment, the code calculates the irradiation creep and swelling strains for each duct from user-specified creep and swelling correlations. Using the calculated thermal bowing, inelastic bowing and the duct dilation, the corresponding equilibrium forces, beam deflections, total beam displacements, and structural reactivity changes are calculated.

  11. Lateral and Vertical Two-Dimensional Layered Topological Insulator

    Office of Scientific and Technical Information (OSTI)

    Heterostructures (Journal Article) | SciTech Connect Lateral and Vertical Two-Dimensional Layered Topological Insulator Heterostructures Citation Details In-Document Search Title: Lateral and Vertical Two-Dimensional Layered Topological Insulator Heterostructures Authors: Li, Yanbin ; Zhang, Jinsong ; Zheng, Guangyuan ; Sun, Yongming ; Hong, Seung Sae ; Xiong, Feng ; Wang, Shuang ; Lee, Hye Ryoung ; Cui, Yi Publication Date: 2015-11-24 OSTI Identifier: 1257420 DOE Contract Number:

  12. Two-dimensional relativistic space charge limited current flow in the drift space

    SciTech Connect

    Liu, Y. L.; Chen, S. H.; Koh, W. S.; Ang, L. K.

    2014-04-15

    Relativistic two-dimensional (2D) electrostatic (ES) formulations have been derived for studying the steady-state space charge limited (SCL) current flow of a finite width W in a drift space with a gap distance D. The theoretical analyses show that the 2D SCL current density in terms of the 1D SCL current density monotonically increases with D/W, and the theory recovers the 1D classical Child-Langmuir law in the drift space under the approximation of uniform charge density in the transverse direction. A 2D static model has also been constructed to study the dynamical behaviors of the current flow with current density exceeding the SCL current density, and the static theory for evaluating the transmitted current fraction and minimum potential position have been verified by using 2D ES particle-in-cell simulation. The results show the 2D SCL current density is mainly determined by the geometrical effects, but the dynamical behaviors of the current flow are mainly determined by the relativistic effect at the current density exceeding the SCL current density.

  13. Experimentally determining the exchange parameters of quasi-two dimensional Heisenbert magnets

    SciTech Connect

    Singleton, John; Sengupta, P; Mcdonald, R D; Cox, S; Harrison, N; Goddard, P A; Lancaster, T; Blundell, S J; Pratt, F L; Manson, J L; Southerland, H I; Schlueter, J A

    2008-01-01

    Though long-range magnetic order cannot occur at temperatures T > 0 in a perfect two-dimensional (2D) Heisenberg magnet, real quasi-2D materials will invariably possess nonzero inter-plane coupling J{sub {perpendicular}} driving the system to order at elevated temperatures. This process can be studied using quantum Monte Carlo calculations. However, it is difficult to test the results of these calculations experimentally since for highly anisotropic materials in which the in-plane coupling is comparable with attainable magnetic fields J{sub {perpendicular}} is necessarily very small and inaccessible directly. In addition, because of the large anisotropy, the Neel temperatures are low and difficult to determine from thermodynamic measurements. Here, we present an elegant method of assessing the calculations via two independent experimental probes: pulsed-field magnetization in fields of up to 85 T, and muon-spin rotation.

  14. Communication: Vibrational and vibronic coherences in the two dimensional spectroscopy of coupled electron-nuclear motion

    SciTech Connect

    Albert, Julian; Falge, Mirjam; Hildenbrand, Heiko; Engel, Volker; Gomez, Sandra; Sola, Ignacio R.

    2015-07-28

    We theoretically investigate the photon-echo spectroscopy of coupled electron-nuclear quantum dynamics. Two situations are treated. In the first case, the Born-Oppenheimer (adiabatic) approximation holds. It is then possible to interpret the two-dimensional (2D) spectra in terms of vibrational motion taking place in different electronic states. In particular, pure vibrational coherences which are related to oscillations in the time-dependent third-order polarization can be identified. This concept fails in the second case, where strong non-adiabatic coupling leads to the breakdown of the Born-Oppenheimer-approximation. Then, the 2D-spectra reveal a complicated vibronic structure and vibrational coherences cannot be disentangled from the electronic motion.

  15. Static & Dynamic Response of 2D Solids

    Energy Science and Technology Software Center

    1996-07-15

    NIKE2D is an implicit finite-element code for analyzing the finite deformation, static and dynamic response of two-dimensional, axisymmetric, plane strain, and plane stress solids. The code is fully vectorized and available on several computing platforms. A number of material models are incorporated to simulate a wide range of material behavior including elasto-placicity, anisotropy, creep, thermal effects, and rate dependence. Slideline algorithms model gaps and sliding along material interfaces, including interface friction, penetration and single surfacemore » contact. Interactive-graphics and rezoning is included for analyses with large mesh distortions. In addition to quasi-Newton and arc-length procedures, adaptive algorithms can be defined to solve the implicit equations using the solution language ISLAND. Each of these capabilities and more make NIKE2D a robust analysis tool.« less

  16. Explicit 2-D Hydrodynamic FEM Program

    Energy Science and Technology Software Center

    1996-08-07

    DYNA2D* is a vectorized, explicit, two-dimensional, axisymmetric and plane strain finite element program for analyzing the large deformation dynamic and hydrodynamic response of inelastic solids. DYNA2D* contains 13 material models and 9 equations of state (EOS) to cover a wide range of material behavior. The material models implemented in all machine versions are: elastic, orthotropic elastic, kinematic/isotropic elastic plasticity, thermoelastoplastic, soil and crushable foam, linear viscoelastic, rubber, high explosive burn, isotropic elastic-plastic, temperature-dependent elastic-plastic. Themore » isotropic and temperature-dependent elastic-plastic models determine only the deviatoric stresses. Pressure is determined by one of 9 equations of state including linear polynomial, JWL high explosive, Sack Tuesday high explosive, Gruneisen, ratio of polynomials, linear polynomial with energy deposition, ignition and growth of reaction in HE, tabulated compaction, and tabulated.« less

  17. Static & Dynamic Response of 2D Solids

    Energy Science and Technology Software Center

    1996-07-15

    NIKE2D is an implicit finite-element code for analyzing the finite deformation, static and dynamic response of two-dimensional, axisymmetric, plane strain, and plane stress solids. The code is fully vectorized and available on several computing platforms. A number of material models are incorporated to simulate a wide range of material behavior including elasto-placicity, anisotropy, creep, thermal effects, and rate dependence. Slideline algorithms model gaps and sliding along material interfaces, including interface friction, penetration and single surfacemorecontact. Interactive-graphics and rezoning is included for analyses with large mesh distortions. In addition to quasi-Newton and arc-length procedures, adaptive algorithms can be defined to solve the implicit equations using the solution language ISLAND. Each of these capabilities and more make NIKE2D a robust analysis tool.less

  18. Explicit 2-D Hydrodynamic FEM Program

    SciTech Connect

    1996-08-07

    DYNA2D* is a vectorized, explicit, two-dimensional, axisymmetric and plane strain finite element program for analyzing the large deformation dynamic and hydrodynamic response of inelastic solids. DYNA2D* contains 13 material models and 9 equations of state (EOS) to cover a wide range of material behavior. The material models implemented in all machine versions are: elastic, orthotropic elastic, kinematic/isotropic elastic plasticity, thermoelastoplastic, soil and crushable foam, linear viscoelastic, rubber, high explosive burn, isotropic elastic-plastic, temperature-dependent elastic-plastic. The isotropic and temperature-dependent elastic-plastic models determine only the deviatoric stresses. Pressure is determined by one of 9 equations of state including linear polynomial, JWL high explosive, Sack Tuesday high explosive, Gruneisen, ratio of polynomials, linear polynomial with energy deposition, ignition and growth of reaction in HE, tabulated compaction, and tabulated.

  19. Investigation of organometallic reaction mechanisms with one and two dimensional vibrational spectroscopy

    SciTech Connect

    Cahoon, James Francis

    2008-12-16

    One and two dimensional time-resolved vibrational spectroscopy has been used to investigate the elementary reactions of several prototypical organometallic complexes in room temperature solution. The electron transfer and ligand substitution reactions of photogenerated 17-electron organometallic radicals CpW(CO){sub 3} and CpFe(CO){sub 2} have been examined with one dimensional spectroscopy on the picosecond through microsecond time-scales, revealing the importance of caging effects and odd-electron intermediates in these reactions. Similarly, an investigation of the photophysics of the simple Fischer carbene complex Cr(CO){sub 5}[CMe(OMe)] showed that this class of molecule undergoes an unusual molecular rearrangement on the picosecond time-scale, briefly forming a metal-ketene complex. Although time-resolved spectroscopy has long been used for these types of photoinitiated reactions, the advent of two dimensional vibrational spectroscopy (2D-IR) opens the possibility to examine the ultrafast dynamics of molecules under thermal equilibrium conditions. Using this method, the picosecond fluxional rearrangements of the model metal carbonyl Fe(CO){sub 5} have been examined, revealing the mechanism, time-scale, and transition state of the fluxional reaction. The success of this experiment demonstrates that 2D-IR is a powerful technique to examine the thermally-driven, ultrafast rearrangements of organometallic molecules in solution.

  20. Quantum fluctuations in the BCS-BEC crossover of two-dimensional Fermi gases

    DOE PAGES [OSTI]

    He, Lianyi; Lu, Haifeng; Cao, Gaoqing; Hu, Hui; Liu, Xia -Ji

    2015-08-14

    We present a theoretical study of the ground state of the BCS-BEC crossover in dilute two-dimensional Fermi gases. While the mean-field theory provides a simple and analytical equation of state, the pressure is equal to that of a noninteracting Fermi gas in the entire BCS-BEC crossover, which is not consistent with the features of a weakly interacting Bose condensate in the BEC limit and a weakly interacting Fermi liquid in the BCS limit. The inadequacy of the two-dimensional mean-field theory indicates that the quantum fluctuations are much more pronounced than those in three dimensions. In this work, we show thatmore » the inclusion of the Gaussian quantum fluctuations naturally recovers the above features in both the BEC and the BCS limits. In the BEC limit, the missing logarithmic dependence on the boson chemical potential is recovered by the quantum fluctuations. Near the quantum phase transition from the vacuum to the BEC phase, we compare our equation of state with the known grand canonical equation of state of two-dimensional Bose gases and determine the ratio of the composite boson scattering length aB to the fermion scattering length a2D. We find aB ≃ 0.56a2D, in good agreement with the exact four-body calculation. As a result, we compare our equation of state in the BCS-BEC crossover with recent results from the quantum Monte Carlo simulations and the experimental measurements and find good agreements.« less

  1. Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets.

    SciTech Connect

    Goddard, P. A.; Singleton, J.; Sengupta, P.; McDonald, R. D.; Lancaster, T.; Blundell, S. J.; Pratt, F. L.; Cox, S.; Harrison, N.; Manson, J. L.; Southerland, H. I.; Schlueter, J. A.; Materials Science Division; Univ. of Oxford; LANL; Rutherford Appleton Lab.; Eastern Washington Univ.

    2008-08-19

    Though long-range magnetic order cannot occur at temperatures T > 0 in a perfect two-dimensional (2D) Heisenberg magnet, real quasi-2D materials will invariably possess nonzero inter-plane coupling J{perpendicular} driving the system to order at elevated temperatures. This process can be studied using quantum Monte Carlo calculations. However, it is difficult to test the results of these calculations experimentally since for highly anisotropic materials in which the in-plane coupling is comparable with attainable magnetic fields J{perpendicular} is necessarily very small and inaccessible directly. In addition, because of the large anisotropy, the Neel temperatures are low and difficult to determine from thermodynamic measurements. Here, we present an elegant method of assessing the calculations via two independent experimental probes: pulsed-field magnetization in fields of up to 85 T, and muon-spin rotation. We successfully demonstrate the application of this method for nine metal-organic Cu-based quasi-2D magnets with pyrazine (pyz) bridges. Our results suggest the superexchange efficiency of the [Cu(HF{sub 2})(pyz){sub 2}]X family of compounds (where X can be ClO{sub 4}, BF{sub 4}, PF{sub 6}, SbF{sub 6} and AsF{sub 6}) might be controlled by the tilting of the pyz molecule with respect to the 2D planes.

  2. Revealing the preferred interlayer orientations and stackings of two-dimensional bilayer gallium selenide crystals

    DOE PAGES [OSTI]

    Li, Xufan; Basile Carrasco, Leonardo A.; Yoon, Mina; Ma, Cheng; Puretzky, Alexander A.; Lee, Jaekwang; Idrobo Tapia, Juan Carlos; Chi, Miaofang; Rouleau, Christopher M.; Geohegan, David B.; et al

    2015-01-21

    Characterizing and controlling the interlayer orientations and stacking order of bilayer two-dimensional (2D) crystals and van der Waals (vdW) heterostructure is crucial to optimize their electrical and optoelectronic properties. The four polymorphs of layered gallium selenide (GaSe) that result from different layer stacking provide an ideal platform to study the stacking configurations in bilayer 2D crystals. Here, through a controllable vapor-phase deposition method we selectively grow bilayer GaSe crystals and investigate their two preferred 0° or 60° interlayer rotations. The commensurate stacking configurations (AA' and AB-stacking) in as-grown 2D bilayer GaSe crystals are clearly observed at the atomic scale andmore » the Ga-terminated edge structure are identified for the first time by using atomic-resolution scanning transmission electron microscopy (STEM). Theoretical analysis of the interlayer coupling energetics vs. interlayer rotation angle reveals that the experimentally-observed orientations are energetically preferred among the bilayer GaSe crystal polytypes. Here, the combined experimental and theoretical characterization of the GaSe bilayers afforded by these growth studies provide a pathway to reveal the atomistic relationships in interlayer orientations responsible for the electronic and optical properties of bilayer 2D crystals and vdW heterostructures.« less

  3. Revealing the preferred interlayer orientations and stackings of two-dimensional bilayer gallium selenide crystals

    SciTech Connect

    Li, Xufan; Basile Carrasco, Leonardo A.; Yoon, Mina; Ma, Cheng; Puretzky, Alexander A.; Lee, Jaekwang; Idrobo Tapia, Juan Carlos; Chi, Miaofang; Rouleau, Christopher M.; Geohegan, David B.; Xiao, Kai

    2015-01-21

    Characterizing and controlling the interlayer orientations and stacking order of bilayer two-dimensional (2D) crystals and van der Waals (vdW) heterostructure is crucial to optimize their electrical and optoelectronic properties. The four polymorphs of layered gallium selenide (GaSe) that result from different layer stacking provide an ideal platform to study the stacking configurations in bilayer 2D crystals. Here, through a controllable vapor-phase deposition method we selectively grow bilayer GaSe crystals and investigate their two preferred 0° or 60° interlayer rotations. The commensurate stacking configurations (AA' and AB-stacking) in as-grown 2D bilayer GaSe crystals are clearly observed at the atomic scale and the Ga-terminated edge structure are identified for the first time by using atomic-resolution scanning transmission electron microscopy (STEM). Theoretical analysis of the interlayer coupling energetics vs. interlayer rotation angle reveals that the experimentally-observed orientations are energetically preferred among the bilayer GaSe crystal polytypes. Here, the combined experimental and theoretical characterization of the GaSe bilayers afforded by these growth studies provide a pathway to reveal the atomistic relationships in interlayer orientations responsible for the electronic and optical properties of bilayer 2D crystals and vdW heterostructures.

  4. Numerical experiment of thermal conductivity in two-dimensional Yukawa liquids

    SciTech Connect

    Shahzad, Aamir; He, Mao-Gang

    2015-12-15

    A newly improved homogenous nonequilibrium molecular dynamics simulation (HNEMDS) method, proposed by the Evans, has been used to compute the thermal conductivity of two-dimensional (2D) strongly coupled complex (dusty) plasma liquids (SCCDPLs), for the first time. The effects of equilibrium external field strength along with different system sizes and plasma states (Γ, κ) on the thermal conductivity of SCCDPLs have been calculated using an enhanced HNEMDS method. A simple analytical temperature representation of Yukawa 2D thermal conductivity with appropriate normalized frequencies (plasma and Einstein) has also been calculated. The new HNEMDS algorithm shows that the present method provides more accurate results with fast convergence and small size effects over a wide range of plasma states. The presented thermal conductivity obtained from HNEMDS method is found to be in very good agreement with that obtained through the previously known numerical simulations and experimental results for 2D Yukawa liquids (SCCDPLs) and with the three-dimensional nonequilibrium molecular dynamics simulation (MDS) and equilibrium MDS calculations. It is shown that the HNEMDS algorithm is a powerful tool, making the calculations very efficient and can be used to predict the thermal conductivity in 2D Yukawa liquid systems.

  5. Revealing the Preferred Interlayer Orientations and Stackings of Two-Dimensional Bilayer Gallium Selenide Crystals

    SciTech Connect

    Li, Xufan; Basile Carrasco, Leonardo A; Yoon, Mina; Ma, Cheng; Puretzky, Alexander A; Lee, Jaekwang; Idrobo Tapia, Juan Carlos; Chi, Miaofang; Rouleau, Christopher M; Geohegan, David B; Xiao, Kai

    2015-01-01

    Characterizing and controlling the interlayer orientations and stacking order of bilayer two-dimensional (2D) crystals and van der Waals (vdW) heterostructure is crucial to optimize their electrical and optoelectronic properties. The four polymorphs of layered gallium selenide (GaSe) that result from different layer stacking provide an ideal platform to study the stacking configurations in bilayer 2D crystals. Here, through a controllable vapor-phase deposition method we selectively grow bilayer GaSe crystals and investigate their two preferred 0 or 60 interlayer rotations. The commensurate stacking configurations (AA and AB-stacking) in as-grown 2D bilayer GaSe crystals are clearly observed at the atomic scale and the Ga-terminated edge structure are identified for the first time by using atomic-resolution scanning transmission electron microscopy (STEM). Theoretical analysis of the interlayer coupling energetics vs. interlayer rotation angle reveals that the experimentally-observed orientations are energetically preferred among the bilayer GaSe crystal polytypes. The combined experimental and theoretical characterization of the GaSe bilayers afforded by these growth studies provide a pathway to reveal the atomistic relationships in interlayer orientations responsible for the electronic and optical properties of bilayer 2D crystals and vdW heterostructures.

  6. Patterned arrays of lateral heterojunctions within monolayer two-dimensional semiconductors

    DOE PAGES [OSTI]

    Mahjouri-Samani, Masoud; Lin, Ming-Wei; Wang, Kai; Lupini, Andrew R.; Lee, Jaekwang; Basile, Leonardo; Boulesbaa, Abdelaziz; Rouleau, Christopher M.; Puretzky, Alexander A.; Ivanov, Ilia N.; et al

    2015-07-22

    The formation of semiconductor heterojunctions and their high density integration are foundations of modern electronics and optoelectronics. To enable two-dimensional (2D) crystalline semiconductors as building blocks in next generation electronics, developing methods to deterministically form lateral heterojunctions is crucial. Here we demonstrate a process strategy for the formation of lithographically-patterned lateral semiconducting heterojunctions within a single 2D crystal. E-beam lithography is used to pattern MoSe2 monolayer crystals with SiO2, and the exposed locations are selectively and totally converted to MoS2 using pulsed laser deposition (PLD) of sulfur in order to form MoSe2/MoS2 heterojunctions in predefined patterns. The junctions and conversionmore » process are characterized by atomically resolved scanning transmission electron microscopy, photoluminescence, and Raman spectroscopy. This demonstration of lateral semiconductor heterojunction arrays within a single 2D crystal is an essential step for the lateral integration of 2D semiconductor building blocks with different electronic and optoelectronic properties for high-density, ultrathin circuitry.« less

  7. Patterned arrays of lateral heterojunctions within monolayer two-dimensional semiconductors

    SciTech Connect

    Mahjouri-Samani, Masoud; Lin, Ming-Wei; Wang, Kai; Lupini, Andrew R.; Lee, Jaekwang; Basile, Leonardo; Boulesbaa, Abdelaziz; Rouleau, Christopher M.; Puretzky, Alexander A.; Ivanov, Ilia N.; Xiao, Kai; Yoon, Mina; Geohegan, David B.

    2015-07-22

    The formation of semiconductor heterojunctions and their high density integration are foundations of modern electronics and optoelectronics. To enable two-dimensional (2D) crystalline semiconductors as building blocks in next generation electronics, developing methods to deterministically form lateral heterojunctions is crucial. Here we demonstrate a process strategy for the formation of lithographically-patterned lateral semiconducting heterojunctions within a single 2D crystal. E-beam lithography is used to pattern MoSe2 monolayer crystals with SiO2, and the exposed locations are selectively and totally converted to MoS2 using pulsed laser deposition (PLD) of sulfur in order to form MoSe2/MoS2 heterojunctions in predefined patterns. The junctions and conversion process are characterized by atomically resolved scanning transmission electron microscopy, photoluminescence, and Raman spectroscopy. This demonstration of lateral semiconductor heterojunction arrays within a single 2D crystal is an essential step for the lateral integration of 2D semiconductor building blocks with different electronic and optoelectronic properties for high-density, ultrathin circuitry.

  8. Dynamical confinement in bosonized two-dimensional QCD

    SciTech Connect

    Ferrando, A. ); Vento, V. )

    1994-03-15

    In the bosonized version of two-dimensional theories nontrivial boundary conditions (topology) play a crucial role. They are inevitable if one wants to describe nonsinglet states. In Abelian bosonization, color is the charge of a topological current in terms of a nonlinear meson field. We show that confinement appears as the dynamical collapse of the topology associated with its nontrivial boundary conditions.

  9. Two-dimensional optimization of free electron laser designs

    DOEpatents

    Prosnitz, Donald; Haas, Roger A.

    1985-01-01

    Off-axis, two-dimensional designs for free electron lasers that maintain correspondence of a light beam with a "synchronous electron" at an optimal transverse radius r>0 to achieve increased beam trapping efficiency and enhanced laser beam wavefront control so as to decrease optical beam diffraction and other deleterious effects.

  10. Two-dimensional optimization of free-electron-laser designs

    DOEpatents

    Prosnitz, D.; Haas, R.A.

    1982-05-04

    Off-axis, two-dimensional designs for free electron lasers are described that maintain correspondence of a light beam with a synchronous electron at an optimal transverse radius r > 0 to achieve increased beam trapping efficiency and enhanced laser beam wavefront control so as to decrease optical beam diffraction and other deleterious effects.

  11. Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

    SciTech Connect

    Lin, Ming -Wei; Zhung, Houlong L.; Yan, Jiaqiang; Ward, Thomas Zac; Puretzky, Alexander A.; Rouleau, Christopher M.; Gai, Zheng; Liang, Liangbo; Meunier, Vincent; Ganesh, Panchapakesan; Kent, Paul R. C.; Sumpter, Bobby G.; Mandrus, David G.; Geohegan, David B.; Xiao, Kai

    2015-11-27

    Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have recently shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained elusive. In this work we for the first time exfoliate the CrSiTe3, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO2 substrate. The Raman spectra show the good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra of 2D CrSiTe3, giving a strong evidence for the existence of 2D CrSiTe3 crystals. When the thickness of the CrSiTe3 crystals is reduced to few-layers, we observed a clear change in resistivity at 80~120 K, consistent with the theoretical calculations on the Curie temperature (Tc) of ~80 K for the magnetic ordering of 2D CrSiTe3 crystals. As a result, the ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable numerous applications in nano-spintronics.

  12. Transport behavior of water molecules through two-dimensional nanopores

    SciTech Connect

    Zhu, Chongqin; Li, Hui; Meng, Sheng

    2014-11-14

    Water transport through a two-dimensional nanoporous membrane has attracted increasing attention in recent years thanks to great demands in water purification and desalination applications. However, few studies have been reported on the microscopic mechanisms of water transport through structured nanopores, especially at the atomistic scale. Here we investigate the microstructure of water flow through two-dimensional model graphene membrane containing a variety of nanopores of different size by using molecular dynamics simulations. Our results clearly indicate that the continuum flow transits to discrete molecular flow patterns with decreasing pore sizes. While for pores with a diameter ≥15 Å water flux exhibits a linear dependence on the pore area, a nonlinear relationship between water flux and pore area has been identified for smaller pores. We attribute this deviation from linear behavior to the presence of discrete water flow, which is strongly influenced by the water-membrane interaction and hydrogen bonding between water molecules.

  13. CASL - Analysis of Two-Dimensional Lattice Physics

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Analysis of Two-Dimensional Lattice Physics CASL is developing the Virtual Environment for Reactor Applications (VERA) as a key capability to support the analysis of the CASL Challenge Problems. VERA will include a range of physics modeling capabilities necessary to model reactors, including neutronics, thermal hydraulics, fuel performance, and coolant chemistry. Lattice physics analyses, utilizing the newly-developed Michigan lattice physics neutronics capability in MPACT 1.0, are important to

  14. Low-frequency Raman fingerprints of two-dimensional metal dichalcogenide layer stacking configurations

    DOE PAGES [OSTI]

    Puretzky, Alexander A.; Liang, Liangbo; Li, Xufan; Xiao, Kai; Wang, Kai; Mahjouri-Samani, Masoud; Basile, Leonardo; Idrobo, Juan Carlos; Sumpter, Bobby G.; Meunier, Vincent; et al

    2015-05-12

    In this study, stacked monolayers of two-dimensional (2D) materials present a new class of hybrid materials with tunable optoelectronic properties determined by their stacking orientation, order, and atomic registry. Atomic-resolution Z-contrast scanning transmission electron microscopy (AR-Z-STEM) and electron energy loss spectroscopy (EELS) can be used to determine the exact atomic registration between different layers, in few-layer 2D stacks, however fast optical characterization techniques are essential for rapid development of the field. Here, using two- and three-layer MoSe2 and WSe2 crystals synthesized by chemical vapor deposition we show that the generally unexplored low frequency (LF) Raman modes (< 50 cm-1) thatmore » originate from interlayer vibrations can serve as fingerprints to characterize not only the number of layers, but also their stacking configurations. Ab initio calculations and group theory analysis corroborate the experimental assignments determined by AR-Z-STEM and show that the calculated LF mode fingerprints are related to the 2D crystal symmetries.« less

  15. Low-frequency Raman fingerprints of two-dimensional metal dichalcogenide layer stacking configurations

    SciTech Connect

    Puretzky, Alexander A.; Liang, Liangbo; Li, Xufan; Xiao, Kai; Wang, Kai; Mahjouri-Samani, Masoud; Basile, Leonardo; Idrobo, Juan Carlos; Sumpter, Bobby G.; Meunier, Vincent; Geohegan, David B.

    2015-05-12

    In this study, stacked monolayers of two-dimensional (2D) materials present a new class of hybrid materials with tunable optoelectronic properties determined by their stacking orientation, order, and atomic registry. Atomic-resolution Z-contrast scanning transmission electron microscopy (AR-Z-STEM) and electron energy loss spectroscopy (EELS) can be used to determine the exact atomic registration between different layers, in few-layer 2D stacks, however fast optical characterization techniques are essential for rapid development of the field. Here, using two- and three-layer MoSe2 and WSe2 crystals synthesized by chemical vapor deposition we show that the generally unexplored low frequency (LF) Raman modes (< 50 cm-1) that originate from interlayer vibrations can serve as fingerprints to characterize not only the number of layers, but also their stacking configurations. Ab initio calculations and group theory analysis corroborate the experimental assignments determined by AR-Z-STEM and show that the calculated LF mode fingerprints are related to the 2D crystal symmetries.

  16. Unveiling Surface Redox Charge Storage of Interacting Two-Dimensional Hetero-Nanosheets in Hierarchical Architectures

    SciTech Connect

    Mahmood, Qasim; Bak, Seong-Min; Kim, Min G.; Yun, Sol; Yang, Xiao-Qing; Shin, Hyeon S.; Kim, Woo S.; Braun, Paul V.; Park, Ho S.

    2015-03-03

    Two-dimensional (2D) heteronanosheets are currently the focus of intense study due to the unique properties that emerge from the interplay between two low-dimensional nanomaterials with different properties. However, the properties and new phenomena based on the two 2D heteronanosheets interacting in a 3D hierarchical architecture have yet to be explored. Here, we unveil the surface redox charge storage mechanism of surface-exposed WS2 nanosheets assembled in a 3D hierarchical heterostructure using in situ synchrotron X-ray absorption and Raman spectroscopic methods. The surface dominating redox charge storage of WS2 is manifested in a highly reversible and ultrafast capacitive fashion due to the interaction of heteronanosheets and the 3D connectivity of the hierarchical structure. In contrast, compositionally identical 2D WS2 structures fail to provide a fast and high capacitance with different modes of lattice vibration. The distinctive surface capacitive behavior of 3D hierarchically structured heteronanosheets is associated with rapid proton accommodation into the in-plane W–S lattice (with the softening of the E2g bands), the reversible redox transition of the surface-exposed intralayers residing in the electrochemically active 1T phase of WS2 (with the reversible change in the interatomic distance and peak intensity of W–W bonds), and the change in the oxidation state during the proton insertion/deinsertion process. This proposed mechanism agrees with the dramatic improvement in the capacitive performance of the two heteronanosheets coupled in the hierarchical structure.

  17. Solitons and vortices in two-dimensional discrete nonlinear Schrdinger systems with spatially modulated nonlinearity

    SciTech Connect

    Kevrekidis, P. G.; Malomed, Boris A.; Saxena, Avadh; Bishop, A. R.; Frantzeskakis, D. J.

    2015-04-07

    We consider a two-dimensional (2D) generalization of a recently proposed model [Phys. Rev. E 88, 032905 (2013)], which gives rise to bright discrete solitons supported by the defocusing nonlinearity whose local strength grows from the center to the periphery. We explore the 2D model starting from the anticontinuum (AC) limit of vanishing coupling. In this limit, we can construct a wide variety of solutions including not only single-site excitations, but also dipole and quadrupole ones. Additionally, two separate families of solutions are explored: the usual extended unstaggered bright solitons, in which all sites are excited in the AC limit, with the same sign across the lattice (they represent the most robust states supported by the lattice, their 1D counterparts being those considered as 1D bright solitons in the above-mentioned work), and the vortex cross, which is specific to the 2D setting. For all the existing states, we explore their stability (also analytically, when possible). As a result, typical scenarios of instability development are exhibited through direct simulations.

  18. Two-dimensional solitons in media with stripe-shaped nonlinearity modulation

    SciTech Connect

    Hung, Nguyen Viet; Zin, Pawel; Trippenbach, Marek; Malomed, Boris A.

    2010-10-15

    We introduce a model of media with the cubic attractive nonlinearity concentrated along a single or double stripe in the two-dimensional (2D) plane. The model can be realized in terms of nonlinear optics (in the spatial and temporal domains alike) and BEC. It is known from recent works that search for stable 2D solitons in models with a spatially localized self-attractive nonlinearity is a challenging problem. We make use of the variational approximation (VA) and numerical methods to investigate conditions for the existence and stability of solitons in the present setting. The result crucially depends on the transverse shape of the stripe: while the rectangular profile supports stable 2D solitons, its smooth Gaussian-shaped counterpart makes all the solitons unstable. This difference is explained, in particular, by the VA. The double stripe with the rectangular profile admits stable solitons of three distinct types: symmetric and asymmetric ones with a single-peak, and double-peak symmetric solitons. The shape and stability of the single-peak solitons of either type are accurately predicted by the VA. Collisions between identical stable solitons are briefly considered too, by means of direct simulations. Depending on the collision velocity, we observe excitation of intrinsic oscillations of the solitons, or their decay, or the collapse (catastrophic self-focusing).

  19. Consideration of a ultracold neutron source in two-dimensional cylindrical geometry by taking simulated boundaries

    SciTech Connect

    Gheisari, R.; Firoozabadi, M. M.; Mohammadi, H.

    2014-01-15

    A new idea to calculate ultracold neutron (UCN) production by using Monte Carlo simulation method to calculate the cold neutron (CN) flux and an analytical approach to calculate the UCN production from the simulated CN flux was given. A super-thermal source (UCN source) was modeled based on an arrangement of D{sub 2}O and solid D{sub 2} (sD{sub 2}). The D{sub 2}O was investigated as the neutron moderator, and sD{sub 2} as the converter. In order to determine the required parameters, a two-dimensional (2D) neutron balance equation written in Matlab was combined with the MCNPX simulation code. The 2D neutron-transport equation in cylindrical (ρ − z) geometry was considered for 330 neutron energy groups in the sD{sub 2}. The 2D balance equation for UCN and CN was solved using simulated CN flux as boundary value. The UCN source dimensions were calculated for the development of the next UCN source. In the optimal condition, the UCN flux and the UCN production rate (averaged over the sD{sub 2} volume) equal to 6.79 × 10{sup 6} cm{sup −2}s{sup −1} and 2.20 ×10{sup 5} cm{sup −3}s{sup −1}, respectively.

  20. Unveiling Surface Redox Charge Storage of Interacting Two-Dimensional Hetero-Nanosheets in Hierarchical Architectures

    SciTech Connect

    Mahmood, Qasim; Bak, Seong-Min; Kim, Min G.; Yun, Sol; Yang, Xiao-Qing; Shin, Hyeon S.; Kim, Woo S.; Braun, Paul V.; Park, Ho S.

    2015-03-03

    Two-dimensional (2D) heteronanosheets are currently the focus of intense study due to the unique properties that emerge from the interplay between two low-dimensional nanomaterials with different properties. However, the properties and new phenomena based on the two 2D heteronanosheets interacting in a 3D hierarchical architecture have yet to be explored. Here, we unveil the surface redox charge storage mechanism of surface-exposed WS2 nanosheets assembled in a 3D hierarchical heterostructure using in situ synchrotron X-ray absorption and Raman spectroscopic methods. The surface dominating redox charge storage of WS2 is manifested in a highly reversible and ultrafast capacitive fashion due to the interaction of heteronanosheets and the 3D connectivity of the hierarchical structure. In contrast, compositionally identical 2D WS2 structures fail to provide a fast and high capacitance with different modes of lattice vibration. The distinctive surface capacitive behavior of 3D hierarchically structured heteronanosheets is associated with rapid proton accommodation into the in-plane WS lattice (with the softening of the E2g bands), the reversible redox transition of the surface-exposed intralayers residing in the electrochemically active 1T phase of WS2 (with the reversible change in the interatomic distance and peak intensity of WW bonds), and the change in the oxidation state during the proton insertion/deinsertion process. This proposed mechanism agrees with the dramatic improvement in the capacitive performance of the two heteronanosheets coupled in the hierarchical structure.

  1. Low-frequency Raman 'fingerprints' of two-dimensional metal dichalcogenide layer stacking configurations

    SciTech Connect

    Puretzky, Alexander A; Liang, Liangbo; Li, Xufan; Xiao, Kai; Wang, Kai; Mahjouri-Samani, Masoud; Basile, Leonardo; Idrobo Tapia, Juan Carlos; Sumpter, Bobby G; Meunier, Vincent; Geohegan, David B

    2015-01-01

    Stacked monolayers of two-dimensional (2D) materials present a new class of hybrid materials with tunable optoelectronic properties determined by their stacking orientation, order, and atomic registry. Atomic-resolution Z-contrast scanning transmission electron microscopy (AR-Z-STEM) and electron energy loss spectroscopy (EELS) can be used to determine the exact atomic registration between different layers, in few-layer 2D stacks, however fast optical characterization techniques are essential for rapid development of the field. Here, using two- and three-layer MoSe2 and WSe2 crystals synthesized by chemical vapor deposition we show that the generally unexplored low frequency (LF) Raman modes (< 50 cm-1) that originate from interlayer vibrations can serve as fingerprints to characterize not only the number of layers, but also their stacking configurations. Ab initio calculations and group theory analysis corroborate the experimental assignments determined by AR-Z-STEM and show that the calculated LF mode fingerprints are related to the 2D crystal symmetries.

  2. Weakly interacting two-dimensional system of dipoles: Limitations of the mean-field theory

    SciTech Connect

    Astrakharchik, G. E.; Boronat, J.; Casulleras, J.; Kurbakov, I. L.; Lozovik, Yu. E.

    2007-06-15

    We consider a homogeneous two-dimensional Bose gas with repulsive dipole-dipole interactions. The ground-state equation of state, calculated using the diffusion Monte Carlo method, shows quantitative differences from the predictions of the commonly used Gross-Pitaevskii mean-field theory. The static structure factor, pair distribution function, and condensate fraction are calculated in a wide range of the gas parameter. Differences from mean-field theory are reflected in the frequency of the lowest ''breathing'' mode for harmonically trapped systems.

  3. X-ray tests of a two-dimensional stigmatic imaging scheme with variable magnifications

    SciTech Connect

    Lu, J.; Bitter, M.; Hill, K. W.; Delgado-Aparicio, L. F.; Efthimion, P. C.; Pablant, N. A.; Beiersdorfer, P.; Caughey, T. A.; Brunner, J.

    2014-11-15

    A two-dimensional stigmatic x-ray imaging scheme, consisting of two spherically bent crystals, one concave and one convex, was recently proposed [M. Bitter et al., Rev. Sci. Instrum. 83, 10E527 (2012)]. The Bragg angles and the radii of curvature of the two crystals of this imaging scheme are matched to eliminate the astigmatism and to satisfy the Bragg condition across both crystal surfaces for a given x-ray energy. In this paper, we consider more general configurations of this imaging scheme, which allow us to vary the magnification for a given pair of crystals and x-ray energy. The stigmatic imaging scheme has been validated for the first time by imaging x-rays generated by a micro-focus x-ray source with source size of 8.4 ?m validated by knife-edge measurements. Results are presented from imaging the tungsten L?1 emission at 8.3976 keV, using a convex Si-422 crystal and a concave Si-533 crystal with 2d-spacings of 2.21707 and 1.65635 and radii of curvature of 500 1 mm and 823 1 mm, respectively, showing a spatial resolution of 54.9 ?m. This imaging scheme is expected to be of interest for the two-dimensional imaging of laser produced plasmas.

  4. Spin coherence of the two-dimensional electron gas in a GaAs quantum well

    SciTech Connect

    Larionov, A. V.

    2015-01-15

    The coherent spin dynamics of the quasi-two-dimensional electron gas in a GaAs quantum well is experimentally investigated using the time-resolved spin Kerr effect in an optical cryostat with a split coil inducing magnetic fields of up to 6 T at a temperature of about 2 K. The electron spin dephasing times and degree of anisotropy of the spin relaxation of electrons are measured in zero magnetic field at different electron densities. The dependence of the spin-orbit splitting on the electron-gas density is established. In the integral quantum-Hall-effect mode, the unsteady behavior of the spin dephasing time of 2D electrons of the lower Landau spin sublevel near the odd occupation factor ν = 3 is found. The experimentally observed unsteady behavior of the spin dephasing time can be explained in terms of new-type cyclotron modes that occur in a liquid spin texture.

  5. 2D FEM Heat Transfer & E&M Field Code

    Energy Science and Technology Software Center

    1992-04-02

    TOPAZ and TOPAZ2D are two-dimensional implicit finite element computer codes for heat transfer analysis. TOPAZ2D can also be used to solve electrostatic and magnetostatic problems. The programs solve for the steady-state or transient temperature or electrostatic and magnetostatic potential field on two-dimensional planar or axisymmetric geometries. Material properties may be temperature or potential-dependent and either isotropic or orthotropic. A variety of time and temperature-dependent boundary conditions can be specified including temperature, flux, convection, and radiation.more » By implementing the user subroutine feature, users can model chemical reaction kinetics and allow for any type of functional representation of boundary conditions and internal heat generation. The programs can solve problems of diffuse and specular band radiation in an enclosure coupled with conduction in the material surrounding the enclosure. Additional features include thermal contact resistance across an interface, bulk fluids, phase change, and energy balances.« less

  6. 2D FEM Heat Transfer & E&M Field Code

    Energy Science and Technology Software Center

    1992-04-02

    TOPAZ and TOPAZ2D are two-dimensional implicit finite element computer codes for heat transfer analysis. TOPAZ2D can also be used to solve electrostatic and magnetostatic problems. The programs solve for the steady-state or transient temperature or electrostatic and magnetostatic potential field on two-dimensional planar or axisymmetric geometries. Material properties may be temperature or potential-dependent and either isotropic or orthotropic. A variety of time and temperature-dependent boundary conditions can be specified including temperature, flux, convection, and radiation.moreBy implementing the user subroutine feature, users can model chemical reaction kinetics and allow for any type of functional representation of boundary conditions and internal heat generation. The programs can solve problems of diffuse and specular band radiation in an enclosure coupled with conduction in the material surrounding the enclosure. Additional features include thermal contact resistance across an interface, bulk fluids, phase change, and energy balances.less

  7. Integrated digital inverters based on two-dimensional anisotropic...

    Office of Scientific and Technical Information (OSTI)

    ... reported and has attracted considerable attention16. In contrast, semiconducting 2D TMDs ... In this study, we focus on monolayer and few-layer ReS2, with thicknesses ranging from 0.8 ...

  8. Band Engineering for Novel TwoDimensional Atomic Layers

    Office of Scientific and Technical Information (OSTI)

    These 2D materials also exhibit excep- tional properties and have promising applications in the fields of electronics, optics, chemical sensors etc.16,18,38,39 At present, there ...

  9. Theory of Bose-Einstein condensation and superfluidity of two-dimensional polaritons in an in-plane harmonic potential

    SciTech Connect

    Berman, Oleg L.; Lozovik, Yurii E.; Snoke, David W.

    2008-04-15

    Recent experiments have shown that it is possible to create an in-plane harmonic potential trap for a two-dimensional (2D) gas of exciton polaritons in a microcavity structure, and evidence has been reported of Bose-Einstein condensation of polaritons accumulated in this type of trap. We present here the theory of Bose-Einstein condensation (BEC) and superfluidity of the exciton polaritons in a harmonic potential trap. Along the way, we determine a general method for defining the superfluid fraction in a 2D trap, in terms of angular momentum representation. We show that in the continuum limit, as the trap becomes shallower, the superfluid fraction approaches the 2D Kosterlitz-Thouless limit, while the condensate fraction approaches zero, as expected.

  10. NREL Theory Establishes a Path to High-Performance 2D Semiconductor Devices

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    - News Releases | NREL Theory Establishes a Path to High-Performance 2D Semiconductor Devices April 22, 2016 Researchers at the Energy Department's National Renewable Energy Laboratory (NREL) have uncovered a way to overcome a principal obstacle in using two-dimensional (2D) semiconductors in electronic and optoelectronic devices. 2D semiconductors such as molybdenum disulfide are only a few layers thick and are considered promising candidates for next-generation devices. Scientists first

  11. Laminar flame and acoustic waves in two-dimensional flow

    SciTech Connect

    Zaytsev, M. L., E-mail: mlzaytsev@gmail.com; Akkerman, V. B., E-mail: slava.akkerman@gmail.com [Russian Academy of Sciences, Nuclear Safety Institute (Russian Federation)

    2011-03-15

    The complete system of fluid dynamics equations describing the development of instability of a reaction front in a two-dimensional flow in reversed time are reduced to a closed system of equations of front dynamics by using Lagrangian variables and integrals of motion. The system can be used to analyze processes behind the front without solving the complete system of fluid dynamics and chemical kinetics equations. It is demonstrated how the gas density disturbances induced by the moving front can be described in the adiabatic approximation.

  12. Quantum process tomography by 2D fluorescence spectroscopy

    SciTech Connect

    Pachón, Leonardo A.; Marcus, Andrew H.; Aspuru-Guzik, Alán

    2015-06-07

    Reconstruction of the dynamics (quantum process tomography) of the single-exciton manifold in energy transfer systems is proposed here on the basis of two-dimensional fluorescence spectroscopy (2D-FS) with phase-modulation. The quantum-process-tomography protocol introduced here benefits from, e.g., the sensitivity enhancement ascribed to 2D-FS. Although the isotropically averaged spectroscopic signals depend on the quantum yield parameter Γ of the doubly excited-exciton manifold, it is shown that the reconstruction of the dynamics is insensitive to this parameter. Applications to foundational and applied problems, as well as further extensions, are discussed.

  13. EM 2dV1.0.F

    Energy Science and Technology Software Center

    2012-01-05

    Code is for a layered electric medium with 2d structure. Includes air-earth interface at node z=2.. The electric ex and ez fields are calculated on edges of elemental grid and magnetic field hy is calculated on the face of the elemental grid. The code allows for a layered earth with 2d structures. Solutions of coupled first order Maxwell's equations are solved in the two dimensional environment using a finite- difference scheme on a staggered spationamore » and temporal grid.« less

  14. Two-step growth of two-dimensional WSe2/MoSe2 heterostructures

    DOE PAGES [OSTI]

    Gong, Yongji; Lei, Sidong; Lou, Jun; Liu, Zheng; Vajtai, Robert; Zhou, Wu; Ajayan, Pullikel M.; Ye, Gonglan; Li, Bo; He, Yongmin; et al

    2015-08-03

    Two dimensional (2D) materials have attracted great attention due to their unique properties and atomic thickness. Although various 2D materials have been successfully synthesized with different optical and electrical properties, a strategy for fabricating 2D heterostructures must be developed in order to construct more complicated devices for practical applications. Here we demonstrate for the first time a two-step chemical vapor deposition (CVD) method for growing transition-metal dichalcogenide (TMD) heterostructures, where MoSe2 was synthesized first and followed by an epitaxial growth of WSe2 on the edge and on the top surface of MoSe2. Compared to previously reported one-step growth methods, thismore » two-step growth has the capability of spatial and size control of each 2D component, leading to much larger (up to 169 μm) heterostructure size, and cross-contamination can be effectively minimized. Furthermore, this two-step growth produces well-defined 2H and 3R stacking in the WSe2/MoSe2 bilayer regions and much sharper in-plane interfaces than the previously reported MoSe2/WSe2 heterojunctions obtained from one-step growth methods. The resultant heterostructures with WSe2/MoSe2 bilayer and the exposed MoSe2 monolayer display rectification characteristics of a p-n junction, as revealed by optoelectronic tests, and an internal quantum efficiency of 91% when functioning as a photodetector. As a result, a photovoltaic effect without any external gates was observed, showing incident photon to converted electron (IPCE) efficiencies of approximately 0.12%, providing application potential in electronics and energy harvesting.« less

  15. 2D microwave imaging reflectometer electronics

    SciTech Connect

    Spear, A. G.; Domier, C. W. Hu, X.; Muscatello, C. M.; Ren, X.; Luhmann, N. C.; Tobias, B. J.

    2014-11-15

    A 2D microwave imaging reflectometer system has been developed to visualize electron density fluctuations on the DIII-D tokamak. Simultaneously illuminated at four probe frequencies, large aperture optics image reflections from four density-dependent cutoff surfaces in the plasma over an extended region of the DIII-D plasma. Localized density fluctuations in the vicinity of the plasma cutoff surfaces modulate the plasma reflections, yielding a 2D image of electron density fluctuations. Details are presented of the receiver down conversion electronics that generate the in-phase (I) and quadrature (Q) reflectometer signals from which 2D density fluctuation data are obtained. Also presented are details on the control system and backplane used to manage the electronics as well as an introduction to the computer based control program.

  16. Technical Review of the UNET2D Hydraulic Model

    SciTech Connect

    Perkins, William A.; Richmond, Marshall C.

    2009-05-18

    The Kansas City District of the US Army Corps of Engineers is engaged in a broad range of river management projects that require knowledge of spatially-varied hydraulic conditions such as velocities and water surface elevations. This information is needed to design new structures, improve existing operations, and assess aquatic habitat. Two-dimensional (2D) depth-averaged numerical hydraulic models are a common tool that can be used to provide velocity and depth information. Kansas City District is currently using a specific 2D model, UNET2D, that has been developed to meet the needs of their river engineering applications. This report documents a tech- nical review of UNET2D.

  17. Two-dimensional gravity with a dynamical aether

    SciTech Connect

    Eling, Christopher; Jacobson, Ted

    2006-10-15

    We investigate the two-dimensional behavior of gravity coupled to a dynamical unit timelike vector field, i.e. ''Einstein-aether theory.'' The classical solutions of this theory in two dimensions depend on one coupling constant. When this coupling is positive the only solutions are (i) flat spacetime with constant aether (ii) de Sitter or anti-de Sitter spacetimes with a uniformly accelerated unit vector invariant under a two-dimensional subgroup of SO(2,1) generated by a boost and a null rotation, and (iii) a nonconstant curvature spacetime that has no Killing symmetries and contains singularities. In this case the sign of the curvature is determined by whether the coupling is less or greater than one. When instead the coupling is negative only solutions (i) and (iii) are present. This classical study of the behavior of Einstein-aether theory in 1+1 dimensions may provide a starting point for further investigations into semiclassical and fully quantum toy models of quantum gravity with a dynamical preferred frame.

  18. Two-dimensional nuclear magnetic resonance of quadrupolar systems

    SciTech Connect

    Wang, Shuanhu

    1997-09-17

    This dissertation describes two-dimensional nuclear magnetic resonance theory and experiments which have been developed to study quadruples in the solid state. The technique of multiple-quantum magic-angle spinning (MQMAS) is extensively reviewed and expanded upon in this thesis. Specifically, MQMAS is first compared with another technique, dynamic-angle spinning (DAS). The similarity between the two techniques allows us to extend much of the DAS work to the MQMAS case. Application of MQMAS to a series of aluminum containing materials is then presented. The superior resolution enhancement through MQMAS is exploited to detect the five- and six-coordinated aluminum in many aluminosilicate glasses. Combining the MQMAS method with other experiments, such as HETCOR, greatly expands the possibility of the use of MQMAS to study a large range of problems and is demonstrated in Chapter 5. Finally, the technique switching-angle spinning (SAS) is applied to quadrupolar nuclei to fully characterize a quadrupolar spin system in which all of the 8 NMR parameters are accurately determined. This dissertation is meant to demonstrate that with the combination of two-dimensional NMR concepts and new advanced spinning technologies, a series of multiple-dimensional NMR techniques can be designed to allow a detailed study of quadrupolar nuclei in the solid state.

  19. One- and two-dimensional simulations of ultra-short-pulse reflectometry

    SciTech Connect

    Cohen, B.I.; Kaiser, T.B.; Garrison, J.C.

    1997-02-01

    Ultra-short-pulse reflectometry is studied by means of the numerical integration of one- and two-dimensional full-wave equations for ordinary and extraordinary modes propagating in a plasma. The numerical calculations illustrate the use of the reflection of ultra-short-pulse microwaves as an effective probe of the density or magnetic profile in the presence of density or magnetic fluctuations in the plasma. Bragg resonance effects can be identified in the reflected signals, which give information on fluctuations. It is also demonstrated that ultra-short-pulse reflectometry can be used to perform correlation reflectometry measurements in which correlation lengths for density fluctuations are deduced from the observed cross-correlation function of phase shifts as a function of frequency. {copyright} {ital 1997 American Institute of Physics.}

  20. One- and two-dimensional simulations of ultra-short-pulse reflectometry

    SciTech Connect

    Cohen, B.I.; Kaiser, T.B.; Garrison, J.C.

    1997-01-01

    Ultra-short-pulse reflectometry is studied by means of the numerical integration of one- and two-dimensional full-wave equations for ordinary and extraordinary modes propagating in a plasma. The numerical calculations illustrate the use of the reflection of ultra-short-pulse microwaves as an effective probe of the density or magnetic profile in the presence of density or magnetic fluctuations in the plasma. Bragg resonance effects can be identified in the reflected signals, which give information on fluctuations. It is also demonstrated that ultra-short-pulse reflectometry can be used to perform correlation reflectometry measurements in which correlation lengths for density fluctuations are deduced from the observed cross-correlation function of phase shifts as a function of frequency. {copyright} {ital 1997 American Institute of Physics.}

  1. Two-dimensional simulation of spatiotemporal generation of dielectric barrier columnar discharges in atmospheric helium

    SciTech Connect

    Huang, Zhiming; Hao, Yanpeng; Yang, Lin; Han, Yongxia; Li, Licheng

    2015-12-15

    A two-dimensional (2D) fluid model is presented to investigate the spatiotemporal generation and dynamic mechanics of dielectric barrier columnar discharges in atmospheric helium. The model was examined with discharge currents measured in experiments and images taken by an intensified charge couple device camera. Based on the model, a columnar discharge was simulated for several cycles after being ignited. The discharge could be regarded as an initial unstable stage for the first three and a half cycles, then a steady state for the following cycles. In the initial stage, the discharge evolves from a uniform pattern into a columnar one. The calculated equipotential lines, 2D radial electric field, and electron density distributions at the edge of uniform discharges show the radial electric field accounts for the shrinking discharge area and the formation of discharge columns in the end. The columnar glow discharges and the Townsend discharges beyond the columns could coexist in the initial stage, and a Townsend discharge might develop into a new glow column in the next half-cycle. The radial electric field surrounding a glow discharge column has an inhibiting effect on the ionization in the peripheral area.

  2. Two-dimensional flux-corrected transport solver for convectively dominated flows

    SciTech Connect

    Baer, M.R.; Gross, R.J.

    1986-01-01

    A numerical technique designed to solve a wide class of convectively dominated flow problems is presented. An attractive feature of the technique is its ability to resolve the behavior of field quantities possessing large gradients and/or shocks. The method is a finite-difference technique known as flux-corrected transport (FCT) that maintains four important numerical considerations - stability, accuracy, monotonicity, and conservation. The theory and methodology of two-dimensional FCT is presented. The method is applied in demonstrative example calculations of a 2-D Riemann problem with known exact solutions and to the Euler equations in a study of classical Rayleigh-Taylor and Kelvin-Helmholtz instability problems. The FCT solver has been vectorized for execution on the Cray 1S - a typical call with a 50 by 50 mesh requires about 0.00428 cpu seconds of execution time per call to the routine. Additionally, we have maintained a modular structure for the solver that eases its implementation. Fortran listings of two versions of the 2-D FCT solvers are appended with a driver main program illustrating the call sequence for the modules. 59 refs., 49 figs.

  3. Reconnection events in two-dimensional Hall magnetohydrodynamic turbulence

    SciTech Connect

    Donato, S.; Servidio, S.; Carbone, V. [Dipartimento di Fisica, Universita della Calabria, I-87036 Cosenza (Italy); Dmitruk, P. [Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and Instituto de Fisica de Buenos Aires, CONICET, Buenos Aires (Argentina); Shay, M. A.; Matthaeus, W. H. [Bartol Research Institute and Department of Physics and Astronomy, University of Delaware, Newark, Delaware 19716 (United States); Cassak, P. A. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506 (United States)

    2012-09-15

    The statistical study of magnetic reconnection events in two-dimensional turbulence has been performed by comparing numerical simulations of magnetohydrodynamics (MHD) and Hall magnetohydrodynamics (HMHD). The analysis reveals that the Hall term plays an important role in turbulence, in which magnetic islands simultaneously reconnect in a complex way. In particular, an increase of the Hall parameter, the ratio of ion skin depth to system size, broadens the distribution of reconnection rates relative to the MHD case. Moreover, in HMHD the local geometry of the reconnection region changes, manifesting bifurcated current sheets and quadrupolar magnetic field structures in analogy to laminar studies, leading locally to faster reconnection processes in this case of reconnection embedded in turbulence. This study supports the idea that the global rate of energy dissipation is controlled by the large scale turbulence, but suggests that the distribution of the reconnection rates within the turbulent system is sensitive to the microphysics at the reconnection sites.

  4. Dynamics of a Two-Dimensional System of Quantum Dipoles

    SciTech Connect

    Mazzanti, F.; Astrakharchik, G. E.; Boronat, J.; Zillich, R. E.

    2009-03-20

    A detailed microscopic analysis of the dynamic structure function S(k,{omega}) of a two-dimensional Bose system of dipoles polarized along the direction perpendicular to the plane is presented and discussed. Starting from ground-state quantities obtained using a quantum diffusion Monte Carlo algorithm, the density-density response is evaluated in the context of the correlated basis functions (CBF) theory. CBF predicts a sharp peak and a multiexcitation component at higher energies produced by the decay of excitations. We discuss the structure of the phonon-roton peak and show that the Feynman and Bogoliubov predictions depart from the CBF result already at low densities. We finally discuss the emergence of a roton in the spectrum, but find the roton energy not low enough to make the system unstable under density fluctuations up to the highest density considered that is close to the freezing point.

  5. High speed two-dimensional optical beam position detector

    SciTech Connect

    Rutten, Paul Edmond

    2011-07-15

    Disclosed is the design of a high speed two-dimensional optical beam position detector which outputs the X and Y displacement and total intensity linearly. The experimental detector measures the displacement from DC to 123 MHz and the intensity of an optical spot in a similar way as a conventional quadrant photodiode detector. The design uses four discrete photodiodes and simple dedicated optics for the position decomposition which enables higher spatial accuracy and faster electronic processing than conventional detectors. Measurements of the frequency response and the spatial sensitivity demonstrate high suitability for atomic force microscopy, scanning probe data storage applications, and wideband wavefront sensing. The operation principle allows for position measurements up to 20 GHz and more in bandwidth.

  6. A ballistic two-dimensional-electron-gas Andreev interferometer

    SciTech Connect

    Amado, M. Fornieri, A.; Sorba, L.; Giazotto, F.; Biasiol, G.

    2014-06-16

    We report the realization and investigation of a ballistic Andreev interferometer based on an InAs two dimensional electron gas coupled to a superconducting Nb loop. We observe strong magnetic modulations in the voltage drop across the device due to quasiparticle interference within the weak-link. The interferometer exhibits flux noise down to ∼80 μΦ{sub 0}/√(Hz) and a robust behavior in temperature with voltage oscillations surviving up to ∼7 K. Besides this remarkable performance, the device represents a crucial first step for the realization of a fully-tunable ballistic superconducting magnetometer and embodies a potential advanced platform for the investigation of Majorana bound states, non-local entanglement of Cooper pairs, as well as the manipulation and control of spin triplet correlations.

  7. Analysis of cancellation exponents in two-dimensional Vlasov turbulence

    SciTech Connect

    De Vita, G.; Valentini, F.; Servidio, S.; Primavera, L.; Carbone, V.; Veltri, P.; Sorriso-Valvo, L.

    2014-07-15

    Statistical properties of plasma turbulence are investigated by means of two-dimensional Vlasov simulations. In particular, a classical technique called signed measure is used to characterize the scaling behavior and the topology of sign-oscillating structures in simulations of the hybrid Vlasov-Maxwell model. Exploring different turbulence regimes, varying both the plasma β and the level of fluctuations, it is observed that Vlasov turbulence manifests two ranges with different exponents, the transition being observed near the ion skin depth. These results, which may have applications to both laboratory and astrophysical systems, further confirm the singular nature of small scale fluctuations in a plasma, mainly classified as intermittent, narrow, and intense current sheets.

  8. Spontaneous supersymmetry breaking in two dimensional lattice super QCD

    DOE PAGES [OSTI]

    Catterall, Simon; Veernala, Aarti

    2015-10-02

    We report on a non-perturbative study of two dimensional N=(2,2) super QCD. Our lattice formulation retains a single exact supersymmetry at non-zero lattice spacing, and contains Nf fermions in the fundamental representation of a U(Nc) gauge group. The lattice action we employ contains an additional Fayet-Iliopoulos term which is also invariant under the exact lattice supersymmetry. This work constitutes the first numerical study of this theory which serves as a toy model for understanding some of the issues that are expected to arise in four dimensional super QCD. As a result, we present evidence that the exact supersymmetry breaks spontaneouslymore » when Nf < Nc in agreement with theoretical expectations.« less

  9. Approaches to verification of two-dimensional water quality models

    SciTech Connect

    Butkus, S.R. . Water Quality Dept.)

    1990-11-01

    The verification of a water quality model is the one procedure most needed by decision making evaluating a model predictions, but is often not adequate or done at all. The results of a properly conducted verification provide the decision makers with an estimate of the uncertainty associated with model predictions. Several statistical tests are available for quantifying of the performance of a model. Six methods of verification were evaluated using an application of the BETTER two-dimensional water quality model for Chickamauga reservoir. Model predictions for ten state variables were compared to observed conditions from 1989. Spatial distributions of the verification measures showed the model predictions were generally adequate, except at a few specific locations in the reservoir. The most useful statistics were the mean standard error of the residuals. Quantifiable measures of model performance should be calculated during calibration and verification of future applications of the BETTER model. 25 refs., 5 figs., 7 tabs.

  10. Two-Dimensional Integral Combustion for Multiple Phase Flow

    Energy Science and Technology Software Center

    1997-05-05

    This ANL multiphase two-dimensional combustion computer code solves conservation equations for gaseous species and solid particles (or droplets) of various sizes. General conservation laws, expressed by ellipitic-type partial differential equations are used in conjunction with rate equations governing the mass, momentum, enthaply, species, turbulent kinetic energy, and turbulent dissipation for a two-phase reacting flow. Associated submodels include an integral combustion, a two-parameter turbulence, a particle evaporation, and interfacial submodels. A newly-developed integral combustion submodel replacingmore » an Arrhenius-type differential reaction submodel is implemented to improve numerical convergence and enhance numerical stability. The two-parameter turbulence submodel is modified for both gas and solid phases. The evaporation submodel treats size dispersion as well as particle evaporation. Interfacial submodels use correlations to model interfacial momentum and energy transfer.« less

  11. Spontaneous supersymmetry breaking in two dimensional lattice super QCD

    SciTech Connect

    Catterall, Simon; Veernala, Aarti

    2015-10-02

    We report on a non-perturbative study of two dimensional N=(2,2) super QCD. Our lattice formulation retains a single exact supersymmetry at non-zero lattice spacing, and contains Nf fermions in the fundamental representation of a U(Nc) gauge group. The lattice action we employ contains an additional Fayet-Iliopoulos term which is also invariant under the exact lattice supersymmetry. This work constitutes the first numerical study of this theory which serves as a toy model for understanding some of the issues that are expected to arise in four dimensional super QCD. As a result, we present evidence that the exact supersymmetry breaks spontaneously when Nf < Nc in agreement with theoretical expectations.

  12. Unveiling Surface Redox Charge Storage of Interacting Two-Dimensional Hetero-Nanosheets in Hierarchical Architectures

    DOE PAGES [OSTI]

    Mahmood, Qasim; Bak, Seong-Min; Kim, Min G.; Yun, Sol; Yang, Xiao-Qing; Shin, Hyeon S.; Kim, Woo S.; Braun, Paul V.; Park, Ho S.

    2015-03-03

    Two-dimensional (2D) heteronanosheets are currently the focus of intense study due to the unique properties that emerge from the interplay between two low-dimensional nanomaterials with different properties. However, the properties and new phenomena based on the two 2D heteronanosheets interacting in a 3D hierarchical architecture have yet to be explored. Here, we unveil the surface redox charge storage mechanism of surface-exposed WS2 nanosheets assembled in a 3D hierarchical heterostructure using in situ synchrotron X-ray absorption and Raman spectroscopic methods. The surface dominating redox charge storage of WS2 is manifested in a highly reversible and ultrafast capacitive fashion due to themore » interaction of heteronanosheets and the 3D connectivity of the hierarchical structure. In contrast, compositionally identical 2D WS2 structures fail to provide a fast and high capacitance with different modes of lattice vibration. The distinctive surface capacitive behavior of 3D hierarchically structured heteronanosheets is associated with rapid proton accommodation into the in-plane W–S lattice (with the softening of the E2g bands), the reversible redox transition of the surface-exposed intralayers residing in the electrochemically active 1T phase of WS2 (with the reversible change in the interatomic distance and peak intensity of W–W bonds), and the change in the oxidation state during the proton insertion/deinsertion process. This proposed mechanism agrees with the dramatic improvement in the capacitive performance of the two heteronanosheets coupled in the hierarchical structure.« less

  13. A two-dimensional matrix correction for off-axis portal dose prediction errors

    SciTech Connect

    Bailey, Daniel W.; Kumaraswamy, Lalith; Bakhtiari, Mohammad; Podgorsak, Matthew B.

    2013-05-15

    Purpose: This study presents a follow-up to a modified calibration procedure for portal dosimetry published by Bailey et al. ['An effective correction algorithm for off-axis portal dosimetry errors,' Med. Phys. 36, 4089-4094 (2009)]. A commercial portal dose prediction system exhibits disagreement of up to 15% (calibrated units) between measured and predicted images as off-axis distance increases. The previous modified calibration procedure accounts for these off-axis effects in most regions of the detecting surface, but is limited by the simplistic assumption of radial symmetry. Methods: We find that a two-dimensional (2D) matrix correction, applied to each calibrated image, accounts for off-axis prediction errors in all regions of the detecting surface, including those still problematic after the radial correction is performed. The correction matrix is calculated by quantitative comparison of predicted and measured images that span the entire detecting surface. The correction matrix was verified for dose-linearity, and its effectiveness was verified on a number of test fields. The 2D correction was employed to retrospectively examine 22 off-axis, asymmetric electronic-compensation breast fields, five intensity-modulated brain fields (moderate-high modulation) manipulated for far off-axis delivery, and 29 intensity-modulated clinical fields of varying complexity in the central portion of the detecting surface. Results: Employing the matrix correction to the off-axis test fields and clinical fields, predicted vs measured portal dose agreement improves by up to 15%, producing up to 10% better agreement than the radial correction in some areas of the detecting surface. Gamma evaluation analyses (3 mm, 3% global, 10% dose threshold) of predicted vs measured portal dose images demonstrate pass rate improvement of up to 75% with the matrix correction, producing pass rates that are up to 30% higher than those resulting from the radial correction technique alone. As in

  14. Method and apparatus for two-dimensional spectroscopy

    DOEpatents

    DeCamp, Matthew F.; Tokmakoff, Andrei

    2010-10-12

    Preferred embodiments of the invention provide for methods and systems of 2D spectroscopy using ultrafast, first light and second light beams and a CCD array detector. A cylindrically-focused second light beam interrogates a target that is optically interactive with a frequency-dispersed excitation (first light) pulse, whereupon the second light beam is frequency-dispersed at right angle orientation to its line of focus, so that the horizontal dimension encodes the spatial location of the second light pulse and the first light frequency, while the vertical dimension encodes the second light frequency. Differential spectra of the first and second light pulses result in a 2D frequency-frequency surface equivalent to double-resonance spectroscopy. Because the first light frequency is spatially encoded in the sample, an entire surface can be acquired in a single interaction of the first and second light pulses.

  15. Visibility of two-dimensional layered materials on various substrates

    SciTech Connect

    Müller, M. R. E-mail: knoch@iht.rwth-aachen.de; Gumprich, A.; Ecik, E.; Kallis, K. T.; Winkler, F.; Kardynal, B.; Petrov, I.; Kunze, U.; Knoch, J. E-mail: knoch@iht.rwth-aachen.de

    2015-10-14

    For the investigation of 2D layered materials such as graphene, transition-metal dichalcogenides, boron nitride, and their heterostructures, dedicated substrates are required to enable unambiguous identification through optical microscopy. A systematic study is conducted, focusing on various 2D layered materials and substrates. The simulated colors are displayed and compared with microscopy images. Additionally, the issue of defining an appropriate index for measuring the degree of visibility is discussed. For a wide range of substrate stacks, layer thicknesses for optimum visibility are given along with the resulting sRGB colors. Further simulations of customized stacks can be conducted using our simulation tool, which is available for download and contains a database featuring a wide range of materials.

  16. Pseudogap state of two-dimensional Kondo lattice

    SciTech Connect

    Barabanov, A. F. Belemuk, A. M.

    2010-08-15

    The pseudogap behavior of spectral function A(k, {omega}) of charge carriers is considered in the weak doping regime for a 2D Kondo lattice with a strong spin-hole antiferromagnetic interaction. The scattering of carriers is described in terms of a local polaron according to the irreducible Green functions. The behavior of the carrier spectrum in the nodal and antinodal domains is considered. The resultant value of the pseudogap is in conformity with experimental data on photoemission with angular resolution.

  17. Electromagnetic Wave Propagation in Two-Dimensional Photonic Crystals

    SciTech Connect

    Stavroula Foteinopoulou

    2003-12-12

    In this dissertation, they have undertaken the challenge to understand the unusual propagation properties of the photonic crystal (PC). The photonic crystal is a medium where the dielectric function is periodically modulated. These types of structures are characterized by bands and gaps. In other words, they are characterized by frequency regions where propagation is prohibited (gaps) and regions where propagation is allowed (bands). In this study they focus on two-dimensional photonic crystals, i.e., structures with periodic dielectric patterns on a plane and translational symmetry in the perpendicular direction. They start by studying a two-dimensional photonic crystal system for frequencies inside the band gap. The inclusion of a line defect introduces allowed states in the otherwise prohibited frequency spectrum. The dependence of the defect resonance state on different parameters such as size of the structure, profile of incoming source, etc., is investigated in detail. For this study, they used two popular computational methods in photonic crystal research, the Finite Difference Time Domain method (FDTD) and the Transfer Matrix Method (TMM). The results for the one-dimensional defect system are analyzed, and the two methods, FDTD and TMM, are compared. Then, they shift their attention only to periodic two-dimensional crystals, concentrate on their band properties, and study their unusual refractive behavior. Anomalous refractive phenomena in photonic crystals included cases where the beam refracts on the ''wrong'' side of the surface normal. The latter phenomenon, is known as negative refraction and was previously observed in materials where the wave vector, the electric field, and the magnetic field form a left-handed set of vectors. These materials are generally called left-handed materials (LHM) or negative index materials (NIM). They investigated the possibility that the photonic crystal behaves as a LHM, and how this behavior relates with the observed

  18. Femtosecond X-ray Diffraction From Two-Dimensional Protein Crystals...

    Office of Scientific and Technical Information (OSTI)

    Femtosecond X-ray Diffraction From Two-Dimensional Protein Crystals Citation Details In-Document Search Title: Femtosecond X-ray Diffraction From Two-Dimensional Protein Crystals...

  19. X-ray tests of a two-dimensional stigmatic imaging scheme with...

    Office of Scientific and Technical Information (OSTI)

    X-ray tests of a two-dimensional stigmatic imaging scheme with variable magnifications Citation Details In-Document Search Title: X-ray tests of a two-dimensional stigmatic imaging ...

  20. Alaska Maximum Number of Active Crews Engaged in Two-Dimensional...

    Annual Energy Outlook

    Two-Dimensional Seismic Surveying (Number of Elements) Alaska Maximum Number of Active Crews Engaged in Two-Dimensional Seismic Surveying (Number of Elements) Year Jan Feb Mar Apr...

  1. Two-Dimensional Electron Gas in Monolayer InN Quantum Wells....

    Office of Scientific and Technical Information (OSTI)

    Two-Dimensional Electron Gas in Monolayer InN Quantum Wells. Citation Details In-Document Search Title: Two-Dimensional Electron Gas in Monolayer InN Quantum Wells. Abstract not...

  2. Strong transmittance above the light line in mid-infrared two-dimensional photonic crystals

    SciTech Connect

    Kraeh, Christian; Martinez-Hurtado, J. L.; Zeitlmair, Martin; Finley, Jonathan J.; Popescu, Alexandru; Hedler, Harry

    2015-06-14

    The mid-infrared region of the electromagnetic spectrum between 3 and 8 μm hosts absorption lines of gases relevant for chemical and biological sensing. 2D photonic crystal structures capable of guiding light in this region of the spectrum have been widely studied, and their implementation into miniaturized sensors has been proposed. However, light guiding in conventional 2D photonic crystals is usually restricted to a frequency range below the light line, which is the dispersion relation of light in the media surrounding the structures. These structures rely on total internal reflection for confinement of the light in z-direction normal to the lattice plane. In this work, 2D mid-infrared photonic crystals consisting of microtube arrays that mitigate these limitations have been developed. Due to their high aspect ratios of ∼1:30, they are perceived as semi-infinite in the z-direction. Light transmission experiments in the 5–8 μm range reveal attenuations as low as 0.27 dB/100 μm, surpassing the limitations for light guiding above the light line in conventional 2D photonic crystals. Fair agreement is obtained between these experiments, 2D band structure and transmission simulations.

  3. 2d PDE Linear Symmetric Matrix Solver

    Energy Science and Technology Software Center

    1983-10-01

    ICCG2 (Incomplete Cholesky factorized Conjugate Gradient algorithm for 2d symmetric problems) was developed to solve a linear symmetric matrix system arising from a 9-point discretization of two-dimensional elliptic and parabolic partial differential equations found in plasma physics applications, such as resistive MHD, spatial diffusive transport, and phase space transport (Fokker-Planck equation) problems. These problems share the common feature of being stiff and requiring implicit solution techniques. When these parabolic or elliptic PDE''s are discretized withmore » finite-difference or finite-element methods,the resulting matrix system is frequently of block-tridiagonal form. To use ICCG2, the discretization of the two-dimensional partial differential equation and its boundary conditions must result in a block-tridiagonal supermatrix composed of elementary tridiagonal matrices. The incomplete Cholesky conjugate gradient algorithm is used to solve the linear symmetric matrix equation. Loops are arranged to vectorize on the Cray1 with the CFT compiler, wherever possible. Recursive loops, which cannot be vectorized, are written for optimum scalar speed. For matrices lacking symmetry, ILUCG2 should be used. Similar methods in three dimensions are available in ICCG3 and ILUCG3. A general source containing extensions and macros, which must be processed by a pre-compiler to obtain the standard FORTRAN source, is provided along with the standard FORTRAN source because it is believed to be more readable. The pre-compiler is not included, but pre-compilation may be performed by a text editor as described in the UCRL-88746 Preprint.« less

  4. 2d PDE Linear Asymmetric Matrix Solver

    Energy Science and Technology Software Center

    1983-10-01

    ILUCG2 (Incomplete LU factorized Conjugate Gradient algorithm for 2d problems) was developed to solve a linear asymmetric matrix system arising from a 9-point discretization of two-dimensional elliptic and parabolic partial differential equations found in plasma physics applications, such as plasma diffusion, equilibria, and phase space transport (Fokker-Planck equation) problems. These equations share the common feature of being stiff and requiring implicit solution techniques. When these parabolic or elliptic PDE''s are discretized with finite-difference or finite-elementmore » methods, the resulting matrix system is frequently of block-tridiagonal form. To use ILUCG2, the discretization of the two-dimensional partial differential equation and its boundary conditions must result in a block-tridiagonal supermatrix composed of elementary tridiagonal matrices. A generalization of the incomplete Cholesky conjugate gradient algorithm is used to solve the matrix equation. Loops are arranged to vectorize on the Cray1 with the CFT compiler, wherever possible. Recursive loops, which cannot be vectorized, are written for optimum scalar speed. For problems having a symmetric matrix ICCG2 should be used since it runs up to four times faster and uses approximately 30% less storage. Similar methods in three dimensions are available in ICCG3 and ILUCG3. A general source, containing extensions and macros, which must be processed by a pre-compiler to obtain the standard FORTRAN source, is provided along with the standard FORTRAN source because it is believed to be more readable. The pre-compiler is not included, but pre-compilation may be performed by a text editor as described in the UCRL-88746 Preprint.« less

  5. Calibration of the ORNL two-dimensional Thomson scattering system

    SciTech Connect

    Thomas, C.E. Jr.; Lazarus, E.A.; Kindsfather, R.R.; Murakami, M.; Stewart, K.A.

    1985-10-01

    A unified presentation of the calibrations needed for accurate calculation of electron temperature and density from Thomson scattering data for the Oak Ridge National Laboratory two-dimensional Thomson scattering system (SCATPAK II) is made. Techniques are described for measuring the range of wavelengths to which each channel is responsive. A statistical method for calibrating the gain of each channel in the system is given, and methods of checking for internal consistency and accuracy are presented. The relationship between the constants describing the relative light collection efficiency of each channel and plasma light-scattering theory is developed, methods for measuring the channel efficiencies and evaluating their accuracy are described, and the effect on these constants of bending fiber optics is discussed. The use of Rayleigh or Raman scattering for absolute efficiency (density) calibration, stray light measurement, and system efficiency evaluation is discussed; the relative merits of Rayleigh vs Raman scattering are presented; and the relationship among the Rayleigh/Raman calibrations, relative channel efficiency constants, and absolute efficiencies is developed.

  6. The intrinsic two-dimensional size of Sagittarius A*

    SciTech Connect

    Bower, Geoffrey C.; Markoff, Sera; Brunthaler, Andreas; Falcke, Heino; Law, Casey; Maitra, Dipankar; Clavel, M.; Goldwurm, A.; Morris, M. R.; Witzel, Gunther; Meyer, Leo; Ghez, A. M.

    2014-07-20

    We report the detection of the two-dimensional structure of the radio source associated with the Galactic Center black hole, Sagittarius A*, obtained from Very Long Baseline Array observations at a wavelength of 7 mm. The intrinsic source is modeled as an elliptical Gaussian with major-axis size 35.4 12.6 R{sub S} in position angle 95 east of north. This morphology can be interpreted in the context of both jet and accretion disk models for the radio emission. There is supporting evidence in large angular-scale multi-wavelength observations for both source models for a preferred axis near 95. We also place a maximum peak-to-peak change of 15% in the intrinsic major-axis size over five different epochs. Three observations were triggered by detection of near infrared (NIR) flares and one was simultaneous with a large X-ray flare detected by NuSTAR. The absence of simultaneous and quasi-simultaneous flares indicates that not all high energy events produce variability at radio wavelengths. This supports the conclusion that NIR and X-ray flares are primarily due to electron excitation and not to an enhanced accretion rate onto the black hole.

  7. Unexpected Stable Two-dimensional Silicon Phosphides with Different Stoichiometries

    DOE PAGES [OSTI]

    Yoon, Mina; Wei, Su-Huai; Sumpter, Bobby G

    2015-01-01

    The discovery of stable two-dimensional, earth-abundant, semiconducting materials is of great interest and may impact future electronic technologies. By combining global structural prediction and first-principles calculations, we have theoretically discovered several previously unknown semiconducting silicon phosphides (SixPy) monolayers, which could be formed stably at the stoichiometries of y/x1. Unexpectedly, some of these compounds, i.e., P-6m2 Si1P1 and Pm Si1P2, have comparable or even lower formation enthalpies than their previously known bulk allotropes. The band gaps (Eg) of SixPy compounds can be dramatically tuned in an extremely wide range (0< Eg < 3 eV) by simply changing the number of layersmore » or applying an in-plane strain. Moreover, we find that carrier doping can drive the ground state of C2/m Si1P3 from a nonmagnetic state into a robust half-metallic spin-polarized state, originating from its unique valence band structure, which can extend the use of Si-related compounds for spintronics.« less

  8. Unexpected Stable Two-dimensional Silicon Phosphides with Different Stoichiometries

    SciTech Connect

    Huang, Bing; Zhuang, Houlong; Yoon, Mina; Wei, Su-Huai; Sumpter, Bobby G

    2015-01-01

    The discovery of stable two-dimensional, earth-abundant, semiconducting materials is of great interest and may impact future electronic technologies. By combining global structural prediction and first-principles calculations, we have theoretically discovered several previously unknown semiconducting silicon phosphides (SixPy) monolayers, which could be formed stably at the stoichiometries of y/x1. Unexpectedly, some of these compounds, i.e., P-6m2 Si1P1 and Pm Si1P2, have comparable or even lower formation enthalpies than their previously known bulk allotropes. The band gaps (Eg) of SixPy compounds can be dramatically tuned in an extremely wide range (0< Eg < 3 eV) by simply changing the number of layers or applying an in-plane strain. Moreover, we find that carrier doping can drive the ground state of C2/m Si1P3 from a nonmagnetic state into a robust half-metallic spin-polarized state, originating from its unique valence band structure, which can extend the use of Si-related compounds for spintronics.

  9. Monolithic multigrid methods for two-dimensional resistive magnetohydrodynamics

    DOE PAGES [OSTI]

    Adler, James H.; Benson, Thomas R.; Cyr, Eric C.; MacLachlan, Scott P.; Tuminaro, Raymond S.

    2016-01-06

    Magnetohydrodynamic (MHD) representations are used to model a wide range of plasma physics applications and are characterized by a nonlinear system of partial differential equations that strongly couples a charged fluid with the evolution of electromagnetic fields. The resulting linear systems that arise from discretization and linearization of the nonlinear problem are generally difficult to solve. In this paper, we investigate multigrid preconditioners for this system. We consider two well-known multigrid relaxation methods for incompressible fluid dynamics: Braess--Sarazin relaxation and Vanka relaxation. We first extend these to the context of steady-state one-fluid viscoresistive MHD. Then we compare the two relaxationmore » procedures within a multigrid-preconditioned GMRES method employed within Newton's method. To isolate the effects of the different relaxation methods, we use structured grids, inf-sup stable finite elements, and geometric interpolation. Furthermore, we present convergence and timing results for a two-dimensional, steady-state test problem.« less

  10. Two-dimensional photochemical model of the troposphere. Master's thesis

    SciTech Connect

    Carlson, M.W.

    1990-01-01

    An experiment using a time-dependent, two-dimensional photochemical model of the troposphere to model the vertical and zonal distribution of ozone and its precursors is presented. The experiment examines two cases. Case I simulates vertical transport due to diffusion and zonal transport due to advection, with surface emissions of ozone precursors in the center of the model domain representing an urban environment with light wind conditions favorable for the formation of ozone in concentrations greater than 80 parts per billion by volume (ppbv). In Case II, an elevated source of ozone and its precursors is introduced at the upstream boundary in order to investigate the role of advection of these chemical species on ozone concentrations. the first simulation produces surface ozone concentrations greater than 120 ppbv in the air above the urban area, and the second simulation produces an increase of 3 - 10 percent in this region. A comparison of Case I and Case II results shows that enhanced photochemical production of ozone due to the addition of ozone's precursors play an important role in this increase.

  11. Kolmogorov flow in two dimensional strongly coupled dusty plasma

    SciTech Connect

    Gupta, Akanksha; Ganesh, R., E-mail: ganesh@ipr.res.in; Joy, Ashwin [Institute for Plasma Research, Bhat Gandhinagar, Gujarat 382 428 (India)

    2014-07-15

    Undriven, incompressible Kolmogorov flow in two dimensional doubly periodic strongly coupled dusty plasma is modelled using generalised hydrodynamics, both in linear and nonlinear regime. A complete stability diagram is obtained for low Reynolds numbers R and for a range of viscoelastic relaxation time ?{sub m} [0?

  12. Optical properties of two-dimensional metamaterial photonic crystals

    SciTech Connect

    Meja-Salazar, J. R.

    2013-12-14

    In the present work, we theoretically study a 2D photonic crystal (PC) comprised by double negative (DNG) metamaterial cylinders, showing that such a system presents a superior light-matter interaction when compared with their single negative (SNG) plasmonic PC counterparts, suggesting a route to enhance the performance of sensors and photovoltaic cells. On the other hand, we have observed that depending on the frequency, the mode symmetry resembles either the case of SNG electric (SNG-E) or SNG magnetic (SNG-M) PC, suggesting that either the electric or magnetic character of the DNG metamaterial dominates in each case.

  13. Strong anisotropy and magnetostriction in the two-dimensional Stoner ferromagnet Fe3GeTe2

    DOE PAGES [OSTI]

    Zhuang, Houlong L.; Kent, P. R. C.; Hennig, Richard G.

    2016-04-06

    Comore » mputationally characterizing magnetic properies of novel two-dimensional (2D) materials serves as an important first step of exploring possible applications. Using density-functional theory, we show that single-layer Fe3GeTe2 is a potential 2D material with sufficiently low formation energy to be synthesized by mechanical exfoliation from the bulk phase with a van der Waals layered structure. In addition, we calculated the phonon dispersion demonstrating that single-layer Fe3GeTe2is dynamically stable. Furthermore, we find that similar to the bulk phase, 2D Fe3GeTe2 exhibits amagnetic moment that originates from a Stoner instability. In contrast to other 2D materials, we find that single-layer Fe3GeTe2 exhibits a significant uniaxial magnetocrystalline anisotropy energy of 920μ eV per Fe atom originating from spin-orbit coupling. In conclusion, we show that applying biaxial tensile strains enhances the anisotropy energy, which reveals strong magnetostriction in single-layer Fe3GeTe2 with a sizable magneostrictive coefficient. Our results indicate that single-layer Fe3GeTe2 is potentially useful for magnetic storage applications.« less

  14. Two-dimensional topological insulators with tunable band gaps: Single-layer HgTe and HgSe

    DOE PAGES [OSTI]

    Li, Jin; He, Chaoyu; Meng, Lijun; Xiao, Huaping; Tang, Chao; Wei, Xiaolin; Kim, Jinwoong; Kioussis, Nicholas; Stocks, G. Malcolm; Zhong, Jianxin

    2015-09-14

    Here, we report that two-dimensional (2D) topological insulators (TIs) with large band gaps are of great importance for the future applications of quantum spin Hall (QSH) effect. Employing ab initio electronic calculations we propose a novel type of 2D topological insulators, the monolayer (ML) low-buckled (LB) mercury telluride (HgTe) and mercury selenide (HgSe), with tunable band gap. We demonstrate that LB HgTe (HgSe) monolayers undergo a trivial insulator to topological insulator transition under in-plane tensile strain of 2.6% (3.1%) due to the combination of the strain and the spin orbital coupling (SOC) effects. Furthermore, the band gaps can be tunedmore » up to large values (0.2 eV for HgTe and 0.05 eV for HgSe) by tensile strain, which far exceed those of current experimentally realized 2D quantum spin Hall insulators. Our results suggest a new type of material suitable for practical applications of 2D TI at room-temperature.« less

  15. Spinstand demonstration of areal density enhancement using two-dimensional magnetic recording (invited)

    SciTech Connect

    Lippman, Thomas Brockie, Richard; Contreras, John; Garzon, Samir; Leong, Tom; Marley, Arley; Wood, Roger; Zakai, Rehan; Zolla, Howard; Coker, Jon; Galbraith, Rick; Hanson, Weldon; Duquette, Paul; Petrizzi, Joe

    2015-05-07

    Exponential growth of the areal density has driven the magnetic recording industry for almost sixty years. But now areal density growth is slowing down, suggesting that current technologies are reaching their fundamental limit. The next generation of recording technologies, namely, energy-assisted writing and bit-patterned media, remains just over the horizon. Two-Dimensional Magnetic Recording (TDMR) is a promising new approach, enabling continued areal density growth with only modest changes to the heads and recording electronics. We demonstrate a first generation implementation of TDMR by using a dual-element read sensor to improve the recovery of data encoded by a conventional low-density parity-check (LDPC) channel. The signals are combined with a 2D equalizer into a single modified waveform that is decoded by a standard LDPC channel. Our detection hardware can perform simultaneous measurement of the pre- and post-combined error rate information, allowing one set of measurements to assess the absolute areal density capability of the TDMR system as well as the gain over a conventional shingled magnetic recording system with identical components. We discuss areal density measurements using this hardware and demonstrate gains exceeding five percent based on experimental dual reader components.

  16. Dynamical theory of strongly coupled two-dimensional Coulomb fluids in the weakly degenerate quantum domain

    SciTech Connect

    Das, Mukunda P.; Golden, Kenneth I.; Green, Frederick

    2001-10-01

    We study the problem of dynamical response and plasma mode dispersion in strongly coupled two-dimensional Coulomb fluids (2DCFs) in the weakly degenerate quantum domain. Adapting the nonlinear response function approach of Golden and Kalman [Phys. Rev. A 19, 2112 (1979)] to the 2DCF, we construct a self-consistent approximation scheme for the calculation of the density response functions and plasma mode dispersion at long wavelengths. The basic ingredients in the construction are (i) the first kinetic equation in the Bogoliubov-Born-Green-Kirkwood-Yvon hierarchy, (ii) the velocity-average-approximation (VAA) hypothesis, (iii) the quadratic fluctuation-dissipation theorem, and (iv) the dynamical superposition approximation (DSA) closure hypothesis. The reliability of the VAA-DSA theory can be assessed by observing that the principal coupling correction to the 2D temperature-dependent Lindhard function is identified as being precisely the part of the third-frequency-moment sum-rule coefficient proportional to the potential energy.

  17. Anisotropic stress correlations in two-dimensional liquids

    DOE PAGES [OSTI]

    Wu, Bin; Iwashita, Takuya; Egami, Takeshi

    2015-03-01

    In this paper we demonstrate the presence of anisotropic stress correlations in the simulated 2D liquids. Whereas the temporal correlation of macroscopic shear stress is known to contribute to viscosity via the Green-Kubo formula, the general question regarding angular dependence of the spatial correlation among atomic level stresses in liquids without external shear has not been explored. Besides the apparent anisotropicity with well-defined symmetry, we found that the characteristic length of shear stress correlation depends on temperature and follows the power law, suggesting divergence around the glass transition temperature. The anisotropy of the stress correlations can be explained in termsmore » of the inclusion model by Eshelby, based upon which we suggest that the mismatch between the atom and its nearest neighbor cage produces the atomic level stress as well as the long-range stress fields.« less

  18. Anisotropic stress correlations in two-dimensional liquids

    SciTech Connect

    Wu, Bin; Iwashita, Takuya; Egami, Takeshi

    2015-03-01

    In this paper we demonstrate the presence of anisotropic stress correlations in the simulated 2D liquids. Whereas the temporal correlation of macroscopic shear stress is known to contribute to viscosity via the Green-Kubo formula, the general question regarding angular dependence of the spatial correlation among atomic level stresses in liquids without external shear has not been explored. Besides the apparent anisotropicity with well-defined symmetry, we found that the characteristic length of shear stress correlation depends on temperature and follows the power law, suggesting divergence around the glass transition temperature. The anisotropy of the stress correlations can be explained in terms of the inclusion model by Eshelby, based upon which we suggest that the mismatch between the atom and its nearest neighbor cage produces the atomic level stress as well as the long-range stress fields.

  19. Refractory two-dimensional hole gas on hydrogenated diamond surface

    SciTech Connect

    Hiraiwa, Atsushi; Daicho, Akira; Kurihara, Shinichiro; Yokoyama, Yuki; Kawarada, Hiroshi

    2012-12-15

    Use of two-dimensional hole gas (2DHG), induced on a hydrogenated diamond surface, is a solution to overcoming one of demerits of diamond, i.e., deep energy levels of impurities. This 2DHG is affected by its environment and accordingly needs a passivation film to get a stable device operation especially at high temperature. In response to this requirement, we achieved the high-reliability passivation forming an Al{sub 2}O{sub 3} film on the diamond surface using an atomic-layer-deposition (ALD) method with an H{sub 2}O oxidant at 450 Degree-Sign C. The 2DHG thus protected survived air annealing at 550 Degree-Sign C for an hour, establishing a stable high-temperature operation of 2DHG devices in air. In part, this achievement is based on high stability of C-H bonds up to 870 Degree-Sign C in vacuum and above 450 Degree-Sign C in an H{sub 2}O-containing environment as in the ALD. Chemically, this stability is supported by the fact that both the thermal decomposition of C-H bonds and reaction between C-H bonds and H{sub 2}O are endothermic processes. It makes a stark contrast to the instability of Si-H bonds, which decompose even at room temperature being exposed to atomic hydrogen. In this respect, the diamond 2DHG devices are also promising as power devices expectedly being free from many instability phenomena, such as hot carrier effect and negative-bias temperature instability, associated with Si devices. As to adsorbate, which is the other prerequisite for 2DHG, it desorbed in vacuum below 250 Degree-Sign C, and accordingly some new adsorbates should have adsorbed during the ALD at 450 Degree-Sign C. As a clue to this question, we certainly confirmed that some adsorbates, other than those at room temperature, adsorbed in air above 100 Degree-Sign C and remained at least up to 290 Degree-Sign C. The identification of these adsorbates is open for further investigation.

  20. ARM - Datastreams - sonicwind2d

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : SONICWIND2D Horizontal wind speed and direction from ultrasonic wind sensor ...

  1. AnisWave 2D

    Energy Science and Technology Software Center

    2004-08-01

    AnisWave2D is a 2D finite-difference code for a simulating seismic wave propagation in fully anisotropic materials. The code is implemented to run in parallel over multiple processors and is fully portable. A mesh refinement algorithm has been utilized to allow the grid-spacing to be tailored to the velocity model, avoiding the over-sampling of high-velocity materials that usually occurs in fixed-grid schemes.

  2. LDRD final report on Bloch Oscillations in two-dimensional nanostructure arrays for high frequency applications.

    SciTech Connect

    Lyo, Sungkwun Kenneth; Pan, Wei; Reno, John Louis; Wendt, Joel Robert; Barton, Daniel Lee

    2008-09-01

    We have investigated the physics of Bloch oscillations (BO) of electrons, engineered in high mobility quantum wells patterned into lateral periodic arrays of nanostructures, i.e. two-dimensional (2D) quantum dot superlattices (QDSLs). A BO occurs when an electron moves out of the Brillouin zone (BZ) in response to a DC electric field, passing back into the BZ on the opposite side. This results in quantum oscillations of the electron--i.e., a high frequency AC current in response to a DC voltage. Thus, engineering a BO will yield continuously electrically tunable high-frequency sources (and detectors) for sensor applications, and be a physics tour-de-force. More than a decade ago, Bloch oscillation (BO) was observed in a quantum well superlattice (QWSL) in short-pulse optical experiments. However, its potential as electrically biased high frequency source and detector so far has not been realized. This is partially due to fast damping of BO in QWSLs. In this project, we have investigated the possibility of improving the stability of BO by fabricating lateral superlattices of periodic coupled nanostructures, such as metal grid, quantum (anti)dots arrays, in high quality GaAs/Al{sub x}Ga{sub 1-x}As heterostructures. In these nanostructures, the lateral quantum confinement has been shown theoretically to suppress the optical-phonon scattering, believed to be the main mechanism for fast damping of BO in QWSLs. Over the last three years, we have made great progress toward demonstrating Bloch oscillations in QDSLs. In the first two years of this project, we studied the negative differential conductance and the Bloch radiation induced edge-magnetoplasmon resonance. Recently, in collaboration with Prof. Kono's group at Rice University, we investigated the time-domain THz magneto-spectroscopy measurements in QDSLs and two-dimensional electron systems. A surprising DC electrical field induced THz phase flip was observed. More measurements are planned to investigate this

  3. Optical Properties and Wave Propagation in Semiconductor-Based Two-Dimensional Photonic Crystals

    SciTech Connect

    Mario Agio

    2002-12-31

    This work is a theoretical investigation on the physical properties of semiconductor-based two-dimensional photonic crystals, in particular for what concerns systems embedded in planar dielectric waveguides (GaAs/AlGaAs, GaInAsP/InP heterostructures, and self-standing membranes) or based on macro-porous silicon. The photonic-band structure of photonic crystals and photonic-crystal slabs is numerically computed and the associated light-line problem is discussed, which points to the issue of intrinsic out-of-lane diffraction losses for the photonic bands lying above the light line. The photonic states are then classified by the group theory formalism: each mode is related to an irreducible representation of the corresponding small point group. The optical properties are investigated by means of the scattering matrix method, which numerically implements a variable-angle-reflectance experiment; comparison with experiments is also provided. The analysis of surface reflectance proves the existence of selection rules for coupling an external wave to a certain photonic mode. Such rules can be directly derived from symmetry considerations. Lastly, the control of wave propagation in weak-index contrast photonic-crystal slabs is tackled in view of designing building blocks for photonic integrated circuits. The proposed designs are found to comply with the major requirements of low-loss propagation, high and single-mode transmission. These notions are then collected to model a photonic-crystal combiner for an integrated multi-wavelength-source laser.

  4. Results from laboratory tests of the two-dimensional Time-Encoded Imaging System.

    SciTech Connect

    Marleau, Peter; Brennan, James S.; Brubaker, Erik; Gerling, Mark D; Le Galloudec, Nathalie Joelle

    2014-09-01

    A series of laboratory experiments were undertaken to demonstrate the feasibility of two dimensional time-encoded imaging. A prototype two-dimensional time encoded imaging system was designed and constructed. Results from imaging measurements of single and multiple point sources as well as extended source distributions are presented. Time encoded imaging has proven to be a simple method for achieving high resolution two-dimensional imaging with potential to be used in future arms control and treaty verification applications.

  5. Bulk and shear viscosities of the two-dimensional electron liquid...

    Office of Scientific and Technical Information (OSTI)

    Bulk and shear viscosities of the two-dimensional electron liquid in a doped graphene ... electron liquid in a doped graphene sheet Authors: Principi, Alessandro ; ...

  6. Terahertz magneto-optical spectroscopy of a two-dimensional hole...

    Office of Scientific and Technical Information (OSTI)

    DOE PAGES Search Results Accepted Manuscript: Terahertz magneto-optical spectroscopy of a two-dimensional hole gas Title: Terahertz magneto-optical spectroscopy of a...

  7. Spontaneous soliton symmetry breaking in two-dimensional coupled Bose-Einstein condensates supported by optical lattices

    SciTech Connect

    Gubeskys, Arthur; Malomed, Boris A.

    2007-10-15

    Models of two-dimensional (2D) traps, with double-well structure in the third direction, for Bose-Einstein condensates are introduced with attractive or repulsive interactions between atoms. The models are based on systems of linearly coupled 2D Gross-Pitaevskii equations, where the coupling accounts for tunneling between the wells. Each well carries an optical lattice (OL) (stable 2D solitons cannot exist without OLs). The linear coupling splits each finite band gap in the spectrum of the single-component model into two subgaps. The main subject of the work is spontaneous symmetry breaking (SSB) in two-component 2D solitons and localized vortices (SSB was not considered before in 2D settings). Using variational approximation (VA) and numerical methods, we demonstrate that, in a system with attraction or repulsion, SSB occurs in families of symmetric or antisymmetric solitons (or vortices), respectively. The corresponding bifurcation destabilizes the original solution branch and gives rise to a stable branch of asymmetric solitons or vortices. The VA provides for an accurate description of the emerging branch of asymmetric solitons. In the model with attraction, all stable branches eventually terminate due to the onset of collapse. Stable asymmetric solitons in higher finite band gaps and vortices with a multiple topological charge are found too. The models also give rise to first examples of embedded solitons and embedded vortices (the states located inside Bloch bands) in two dimensions. In the linearly coupled system with opposite signs of the nonlinearity in the two cores, two distinct types of stable solitons and vortices are found, dominated by either the self-attractive component or the self-repulsive one. In the system with a mismatch between the two OLs, a pseudobifurcation is found: when the mismatch attains its largest value ({pi}), the bifurcation does not happen, as branches of different solutions asymptotically approach each other, but fail to merge.

  8. Solitons and vortices in two-dimensional discrete nonlinear Schrödinger systems with spatially modulated nonlinearity

    DOE PAGES [OSTI]

    Kevrekidis, P. G.; Malomed, Boris A.; Saxena, Avadh; Bishop, A. R.; Frantzeskakis, D. J.

    2015-04-07

    We consider a two-dimensional (2D) generalization of a recently proposed model [Phys. Rev. E 88, 032905 (2013)], which gives rise to bright discrete solitons supported by the defocusing nonlinearity whose local strength grows from the center to the periphery. We explore the 2D model starting from the anticontinuum (AC) limit of vanishing coupling. In this limit, we can construct a wide variety of solutions including not only single-site excitations, but also dipole and quadrupole ones. Additionally, two separate families of solutions are explored: the usual “extended” unstaggered bright solitons, in which all sites are excited in the AC limit, withmore » the same sign across the lattice (they represent the most robust states supported by the lattice, their 1D counterparts being those considered as 1D bright solitons in the above-mentioned work), and the vortex cross, which is specific to the 2D setting. For all the existing states, we explore their stability (also analytically, when possible). As a result, typical scenarios of instability development are exhibited through direct simulations.« less

  9. Solitons and vortices in two-dimensional discrete nonlinear Schrödinger systems with spatially modulated nonlinearity

    SciTech Connect

    Kevrekidis, P. G.; Malomed, Boris A.; Saxena, Avadh; Bishop, A. R.; Frantzeskakis, D. J.

    2015-04-07

    We consider a two-dimensional (2D) generalization of a recently proposed model [Phys. Rev. E 88, 032905 (2013)], which gives rise to bright discrete solitons supported by the defocusing nonlinearity whose local strength grows from the center to the periphery. We explore the 2D model starting from the anticontinuum (AC) limit of vanishing coupling. In this limit, we can construct a wide variety of solutions including not only single-site excitations, but also dipole and quadrupole ones. Additionally, two separate families of solutions are explored: the usual “extended” unstaggered bright solitons, in which all sites are excited in the AC limit, with the same sign across the lattice (they represent the most robust states supported by the lattice, their 1D counterparts being those considered as 1D bright solitons in the above-mentioned work), and the vortex cross, which is specific to the 2D setting. For all the existing states, we explore their stability (also analytically, when possible). As a result, typical scenarios of instability development are exhibited through direct simulations.

  10. Bose-Einstein condensation of trapped polaritons in two-dimensional electron-hole systems in a high magnetic field

    SciTech Connect

    Berman, Oleg L.; Kezerashvili, Roman Ya.; Lozovik, Yurii E.

    2009-09-15

    The Bose-Einstein condensation (BEC) of magnetoexcitonic polaritons (magnetopolaritons) in two-dimensional (2D) electron-hole system embedded in a semiconductor microcavity in a high magnetic field B is predicted. There are two physical realizations of 2D electron-hole system under consideration: a graphene layer and quantum well (QW). A 2D gas of magnetopolaritons is considered in a planar harmonic potential trap. Two possible physical realizations of this trapping potential are assumed: inhomogeneous local stress or harmonic electric field potential applied to excitons and a parabolic shape of the semiconductor cavity causing the trapping of microcavity photons. The effective Hamiltonian of the ideal gas of cavity polaritons in a QW and graphene in a high magnetic field and the BEC temperature as functions of magnetic field are obtained. It is shown that the effective polariton mass M{sub eff} increases with magnetic field as B{sup 1/2}. The BEC critical temperature T{sub c}{sup (0)} decreases as B{sup -1/4} and increases with the spring constant of the parabolic trap. The Rabi splitting related to the creation of a magnetoexciton in a high magnetic field in graphene and QW is obtained. It is shown that Rabi splitting in graphene can be controlled by the external magnetic field since it is proportional to B{sup -1/4} while in a QW the Rabi splitting does not depend on the magnetic field when it is strong.

  11. 2-D Multi-Group Diffusion Program

    Energy Science and Technology Software Center

    1992-07-21

    The multigroup, two-dimensional neutron diffusion equations are solved in x-y, r-z, or r-theta geometry.

  12. KIVA: a comprehensive model for 2D and 3D engine simulations

    SciTech Connect

    Amsden, A.A.; Butler, T.D.; O'Rourke, P.J.; Ramshaw, J.D.

    1985-01-01

    This paper summarizes a comprehensive numerical model that represents the spray dynamics, fluid flow, species transport, mixing, chemical reactions, and accompanying heat release that occur inside the cylinder of an internal combustion engine. The model is embodied in the KIVA computer code. The code calculates both two-dimensional (2D) and three-dimensional (3D) situations. It is an outgrowth of the earlier 2D CONCHAS-SPRAY computer program. Sample numerical calculations are presented to indicate the level of detail that is available from these simulations. These calculations are for a direct injection stratified charge engine with swirl. Both a 2D and a 3D example are shown.

  13. 2D electron density profile measurement in tokamak by laser-accelerated ion-beam probe

    SciTech Connect

    Chen, Y. H.; Yang, X. Y.; Lin, C. E-mail: cjxiao@pku.edu.cn; Wang, X. G.; Xiao, C. J. E-mail: cjxiao@pku.edu.cn; Wang, L.; Xu, M.

    2014-11-15

    A new concept of Heavy Ion Beam Probe (HIBP) diagnostic has been proposed, of which the key is to replace the electrostatic accelerator of traditional HIBP by a laser-driven ion accelerator. Due to the large energy spread of ions, the laser-accelerated HIBP can measure the two-dimensional (2D) electron density profile of tokamak plasma. In a preliminary simulation, a 2D density profile was reconstructed with a spatial resolution of about 2 cm, and with the error below 15% in the core region. Diagnostics of 2D density fluctuation is also discussed.

  14. MESH2D GRID GENERATOR DESIGN AND USE

    SciTech Connect

    Flach, G.; Smith, F.

    2012-01-20

    Mesh2d is a Fortran90 program designed to generate two-dimensional structured grids of the form [x(i),y(i,j)] where [x,y] are grid coordinates identified by indices (i,j). The x(i) coordinates alone can be used to specify a one-dimensional grid. Because the x-coordinates vary only with the i index, a two-dimensional grid is composed in part of straight vertical lines. However, the nominally horizontal y(i,j{sub 0}) coordinates along index i are permitted to undulate or otherwise vary. Mesh2d also assigns an integer material type to each grid cell, mtyp(i,j), in a user-specified manner. The complete grid is specified through three separate input files defining the x(i), y(i,j), and mtyp(i,j) variations. The overall mesh is constructed from grid zones that are typically then subdivided into a collection of smaller grid cells. The grid zones usually correspond to distinct materials or larger-scale geometric shapes. The structured grid zones are identified through uppercase indices (I,J). Subdivision of zonal regions into grid cells can be done uniformly, or nonuniformly using either a polynomial or geometric skewing algorithm. Grid cells may be concentrated backward, forward, or toward both ends. Figure 1 illustrates the above concepts in the context of a simple four zone grid.

  15. Generating and moving Dirac points in a two-dimensional deformed honeycomb lattice arrayed by coupled semiconductor quantum dots

    SciTech Connect

    Peng, Juan Duan, Yifeng; Chen, PeiJian; Peng, Yan

    2015-03-15

    Analysis of the electronic properties of a two-dimensional (2D) deformed honeycomb structure arrayed by semiconductor quantum dots (QDs) is conducted theoretically by using tight-binding method in the present paper. Through the compressive or tensile deformation of the honeycomb lattice, the variation of energy spectrum has been explored. We show that, the massless Dirac fermions are generated in this adjustable system and the positions of the Dirac cones as well as slope of the linear dispersions could be manipulated. Furthermore, a clear linear correspondence between the distance of movement d (the distance from the Dirac points to the Brillouin zone corners) and the tunable bond angle α of the lattice are found in this artificial planar QD structure. These results provide the theoretical basis for manipulating Dirac fermions and should be very helpful for the fabrication and application of high-mobility semiconductor QD devices.

  16. Simultaneous sensing of light and sound velocities of fluids in a two-dimensional phoXonic crystal with defects

    SciTech Connect

    Amoudache, Samira; Pennec, Yan Djafari Rouhani, Bahram; Khater, Antoine; Lucklum, Ralf; Tigrine, Rachid

    2014-04-07

    We theoretically investigate the potentiality of dual phononic-photonic (the so-called phoxonic) crystals for liquid sensing applications. We study the transmission through a two-dimensional (2D) crystal made of infinite cylindrical holes in a silicon substrate, where one row of holes oriented perpendicular to the propagation direction is filled with a liquid. The infiltrated holes may have a different radius than the regular holes. We show, in the defect structure, the existence of well-defined features (peaks or dips) in the transmission spectra of acoustic and optical waves and estimate their sensitivity to the sound and light velocity of the analyte. Some of the geometrical requirements behave in opposite directions when searching for an efficient sensing of either sound or light velocities. Hence, a compromise in the choice of the parameters may become necessary in making the phoxonic sensor.

  17. ELLIPT2D: A Flexible Finite Element Code Written Python

    SciTech Connect

    Pletzer, A.; Mollis, J.C.

    2001-03-22

    The use of the Python scripting language for scientific applications and in particular to solve partial differential equations is explored. It is shown that Python's rich data structure and object-oriented features can be exploited to write programs that are not only significantly more concise than their counter parts written in Fortran, C or C++, but are also numerically efficient. To illustrate this, a two-dimensional finite element code (ELLIPT2D) has been written. ELLIPT2D provides a flexible and easy-to-use framework for solving a large class of second-order elliptic problems. The program allows for structured or unstructured meshes. All functions defining the elliptic operator are user supplied and so are the boundary conditions, which can be of Dirichlet, Neumann or Robbins type. ELLIPT2D makes extensive use of dictionaries (hash tables) as a way to represent sparse matrices.Other key features of the Python language that have been widely used include: operator over loading, error handling, array slicing, and the Tkinter module for building graphical use interfaces. As an example of the utility of ELLIPT2D, a nonlinear solution of the Grad-Shafranov equation is computed using a Newton iterative scheme. A second application focuses on a solution of the toroidal Laplace equation coupled to a magnetohydrodynamic stability code, a problem arising in the context of magnetic fusion research.

  18. Patterned Arrays of Lateral Heterojunctions within Monolayer 2D Semiconductors

    SciTech Connect

    Mahjouri-Samani, Masoud; Lin, Ming-Wei; Wang, Kai; Lupini, Andrew R; Lee, Jaekwang; Basile Carrasco, Leonardo A; Rouleau, Christopher M; Boulesbaa, Abdelaziz; Puretzky, Alexander A; Ivanov, Ilia N; Xiao, Kai; Yoon, Mina; Geohegan, David B

    2015-01-01

    The formation of semiconductor heterojunctions and their high density integration are foundations of modern electronics and optoelectronics. To enable two-dimensional (2D) crystalline semiconductors as building blocks in next generation electronics, developing methods to deterministically form lateral heterojunctions is crucial. Here we demonstrate a process strategy for the formation of lithographically-patterned lateral semiconducting heterojunctions within a single 2D crystal. E-beam lithography is used to pattern MoSe2 monolayer crystals with SiO2, and the exposed locations are selectively and totally converted to MoS2 using pulsed laser deposition (PLD) of sulfur in order to form MoSe2/MoS2 heterojunctions in predefined patterns. The junctions and conversion process are characterized by atomically resolved scanning transmission electron microscopy, photoluminescence, and Raman spectroscopy. This demonstration of lateral semiconductor heterojunction arrays within a single 2D crystal is an essential step for the lateral integration of 2D semiconductor building blocks with different electronic and optoelectronic properties for high-density, ultrathin circuitry.

  19. Patterned Arrays of Lateral Heterojunctions within Monolayer 2D Semiconductors

    DOE PAGES [OSTI]

    Mahjouri-Samani, Masoud; Lin, Ming-Wei; Wang, Kai; Lupini, Andrew R; Lee, Jaekwang; Basile Carrasco, Leonardo A; Rouleau, Christopher M; Boulesbaa, Abdelaziz; Puretzky, Alexander A; Ivanov, Ilia N; et al

    2015-01-01

    The formation of semiconductor heterojunctions and their high density integration are foundations of modern electronics and optoelectronics. To enable two-dimensional (2D) crystalline semiconductors as building blocks in next generation electronics, developing methods to deterministically form lateral heterojunctions is crucial. Here we demonstrate a process strategy for the formation of lithographically-patterned lateral semiconducting heterojunctions within a single 2D crystal. E-beam lithography is used to pattern MoSe2 monolayer crystals with SiO2, and the exposed locations are selectively and totally converted to MoS2 using pulsed laser deposition (PLD) of sulfur in order to form MoSe2/MoS2 heterojunctions in predefined patterns. The junctions and conversionmoreprocess are characterized by atomically resolved scanning transmission electron microscopy, photoluminescence, and Raman spectroscopy. This demonstration of lateral semiconductor heterojunction arrays within a single 2D crystal is an essential step for the lateral integration of 2D semiconductor building blocks with different electronic and optoelectronic properties for high-density, ultrathin circuitry.less

  20. Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)

    DOE PAGES [OSTI]

    J. D. Kestell; Zhong, J. Q.; Shete, M.; Waluyo, I.; Sadowski, J. T.; Stacchiola, D. J.; Tsapatsis, M.; Boscoboinik, J. A.

    2016-07-26

    While surface science has provided fundamental insights into a variety a materials, the most used catalysts in the industry, namely zeolites, still remain a challenge. The recent preparation of two-dimensional versions of MFI zeolite frameworks and the possibility of their deposition on electrically conductive supports provides for the first time a viable strategy to perform detailed studies on industrially relevant zeolites using the vast toolkit of surface science. In this work we demonstrate the use of infrared reflection absorption spectroscopy (IRRAS) and synchrotron-based x-ray photoelectron spectroscopy (XPS) to study these materials. Furthermore, polarization modulation IRRAS is used to study themore » adsorption of methanol and its effect in phonon vibrations of the zeolite framework. The possibility of using surface science methods, in particular under ambient pressure conditions, for the study of well-defined zeolites and other microporous structures opens new avenues to understand structural and mechanistic aspects of these materials as catalysts, adsorbents and molecular sieves.« less

  1. TOPAZ2D heat transfer code users manual and thermal property data base

    SciTech Connect

    Shapiro, A.B.; Edwards, A.L.

    1990-05-01

    TOPAZ2D is a two dimensional implicit finite element computer code for heat transfer analysis. This user's manual provides information on the structure of a TOPAZ2D input file. Also included is a material thermal property data base. This manual is supplemented with The TOPAZ2D Theoretical Manual and the TOPAZ2D Verification Manual. TOPAZ2D has been implemented on the CRAY, SUN, and VAX computers. TOPAZ2D can be used to solve for the steady state or transient temperature field on two dimensional planar or axisymmetric geometries. Material properties may be temperature dependent and either isotropic or orthotropic. A variety of time and temperature dependent boundary conditions can be specified including temperature, flux, convection, and radiation. Time or temperature dependent internal heat generation can be defined locally be element or globally by material. TOPAZ2D can solve problems of diffuse and specular band radiation in an enclosure coupled with conduction in material surrounding the enclosure. Additional features include thermally controlled reactive chemical mixtures, thermal contact resistance across an interface, bulk fluid flow, phase change, and energy balances. Thermal stresses can be calculated using the solid mechanics code NIKE2D which reads the temperature state data calculated by TOPAZ2D. A three dimensional version of the code, TOPAZ3D is available. The material thermal property data base, Chapter 4, included in this manual was originally published in 1969 by Art Edwards for use with his TRUMP finite difference heat transfer code. The format of the data has been altered to be compatible with TOPAZ2D. Bob Bailey is responsible for adding the high explosive thermal property data.

  2. Method and system for determining a volume of an object from two-dimensional images

    DOEpatents

    Abercrombie, Robert K [Knoxville, TN; Schlicher, Bob G [Portsmouth, NH

    2010-08-10

    The invention provides a method and a computer program stored in a tangible medium for automatically determining a volume of three-dimensional objects represented in two-dimensional images, by acquiring at two least two-dimensional digitized images, by analyzing the two-dimensional images to identify reference points and geometric patterns, by determining distances between the reference points and the component objects utilizing reference data provided for the three-dimensional object, and by calculating a volume for the three-dimensional object.

  3. Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage

    DOE PAGES [OSTI]

    Ren, Chang E.; Zhao, M-Q; Makaryan, Taron; Halim, Joseph; Boota, M.; Kota, Sankalp; Anasori, Babak; Barsoum, M W; Gogotsi, Yury

    2016-02-16

    Herein we develop a chemical etching method to produce porous two-dimensional (2D) Ti3C2Tx MXenes at room temperature in aqueous solutions. The as-produced porous Ti3C2Tx (p-Ti3C2Tx) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nanotubes (CNTs). The as-fabricated p-Ti3C2Tx/CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti3C2Tx based films, with a very high capacity of ≈1250 mAh g-1 at 0.1 C, excellent cycling stability, and good rate performance (330 mAh g-1 at 10 C). Using the same chemicalmore » etching method, we also made porous Nb2CTx and V2CTx MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.« less

  4. Direct experimental visualization of the global Hamiltonian progression of two-dimensional Lagrangian flow topologies from integrable to chaotic state

    SciTech Connect

    Baskan, O.; Clercx, H. J. H; Speetjens, M. F. M.; Metcalfe, G.

    2015-10-15

    Countless theoretical/numerical studies on transport and mixing in two-dimensional (2D) unsteady flows lean on the assumption that Hamiltonian mechanisms govern the Lagrangian dynamics of passive tracers. However, experimental studies specifically investigating said mechanisms are rare. Moreover, they typically concern local behavior in specific states (usually far away from the integrable state) and generally expose this indirectly by dye visualization. Laboratory experiments explicitly addressing the global Hamiltonian progression of the Lagrangian flow topology entirely from integrable to chaotic state, i.e., the fundamental route to efficient transport by chaotic advection, appear non-existent. This motivates our study on experimental visualization of this progression by direct measurement of Poincaré sections of passive tracer particles in a representative 2D time-periodic flow. This admits (i) accurate replication of the experimental initial conditions, facilitating true one-to-one comparison of simulated and measured behavior, and (ii) direct experimental investigation of the ensuing Lagrangian dynamics. The analysis reveals a close agreement between computations and observations and thus experimentally validates the full global Hamiltonian progression at a great level of detail.

  5. Two-dimensional topological crystalline insulator phase in Sb/Bi planar honeycomb with tunable Dirac gap

    DOE PAGES [OSTI]

    Hsu, Chia -Hsiu; Huang, Zhi -Quan; Crisostomo, Christian P.; Yao, Liang -Zi; Chuang, Feng -Chuan; Liu, Yu -Tzu; Wang, Baokai; Hsu, Chuang -Han; Lee, Chi -Cheng; Lin, Hsin; et al

    2016-01-14

    We predict planar Sb/Bi honeycomb to harbor a two-dimensional (2D) topological crystalline insulator (TCI) phase based on first-principles computations. Although buckled Sb and Bi honeycombs support 2D topological insulator (TI) phases, their structure becomes planar under tensile strain. The planar Sb/Bi honeycomb structure restores the mirror symmetry, and is shown to exhibit non-zero mirror Chern numbers, indicating that the system can host topologically protected edge states. Our computations show that the electronic spectrum of a planar Sb/Bi nanoribbon with armchair or zigzag edges contains two Dirac cones within the band gap and an even number of edge bands crossing themore » Fermi level. Lattice constant of the planar Sb honeycomb is found to nearly match that of hexagonal-BN. As a result, the Sb nanoribbon on hexagonal-BN exhibits gapped edge states, which we show to be tunable by an out-of the-plane electric field, providing controllable gating of edge state important for device applications.« less

  6. A Two-Dimensional Model for the Analysis of Contaminant Transport in a Fractured Porous Medium.

    Energy Science and Technology Software Center

    1991-03-05

    CHAINT-MC is a two-dimensional finite element model applicable to the transport of a dissolved radionuclide in a fractured porous medium along with radioactive chain decay and subsequent transport of the dissolved daughters.

  7. All or nothing: On the small fluctuations of two-dimensional string theoretic black holes

    SciTech Connect

    Gilbert, Gerald; Raiten, Eric

    1992-10-01

    A comprehensive analysis of small fluctuations about two-dimensional string-theoretic and string-inspired black holes is presented. It is shown with specific examples that two-dimensional black holes behave in a radically different way from all known black holes in four dimensions. For both the SL(2,R)/U(1) black hole and the two-dimensional black hole coupled to a massive dilaton with constant field strength, it is shown that there are a {\\it continuous infinity} of solutions to the linearized equations of motion, which are such that it is impossible to ascertain the classical linear response. It is further shown that the two-dimensional black hole coupled to a massive, linear dilaton admits {\\it no small fluctuations at all}. We discuss possible implications of our results for the Callan-Giddings-Harvey-Strominger black hole.

  8. Electronic and magnetic properties of Fe and Mn doped two dimensional hexagonal germanium sheets

    SciTech Connect

    Soni, Himadri R. Jha, Prafulla K.

    2014-04-24

    Using first principles density functional theory calculations, the present paper reports systematic total energy calculations of the electronic properties such as density of states and magnetic moment of pristine and iron and manganese doped two dimensional hexagonal germanium sheets.

  9. Non-diffusive spin dynamics in a two-dimensional electrongas...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Non-diffusive spin dynamics in a two-dimensional electrongas Citation Details In-Document Search ... Publication Date: 2006-12-12 OSTI Identifier: 902139 Report ...

  10. DIOPTAS: a program for reduction of two-dimensional X-ray diffraction...

    Office of Scientific and Technical Information (OSTI)

    DIOPTAS: a program for reduction of two-dimensional X-ray diffraction data and data exploration Citation Details In-Document Search Title: DIOPTAS: a program for reduction of ...

  11. Manipulating one- and two-dimensional stimulated-x-ray resonant...

    Office of Scientific and Technical Information (OSTI)

    Manipulating one- and two-dimensional stimulated-x-ray resonant-Raman signals in molecules by pulse polarizations Citation Details In-Document Search Title: Manipulating one- and ...

  12. 2D Seismic Reflection Survey Crump Geyser Geothermal Prospect...

    OpenEI (Open Energy Information) [EERE & EIA]

    Additional Info Field Value Author Nevada Geothermal Power Company Maintainer Nicole Smith bureaucode 019:20 Catalog DOE harvestobjectid 80f3a9f1-e224-4a02-951b-229cd8e273fd...

  13. On the current drive capability of low dimensional semiconductors: 1D versus 2D

    DOE PAGES [OSTI]

    Zhu, Y.; Appenzeller, J.

    2015-10-29

    Low-dimensional electronic systems are at the heart of many scaling approaches currently pursuit for electronic applications. Here, we present a comparative study between an array of one-dimensional (1D) channels and its two-dimensional (2D) counterpart in terms of current drive capability. Lastly, our findings from analytical expressions derived in this article reveal that under certain conditions an array of 1D channels can outperform a 2D field-effect transistor because of the added degree of freedom to adjust the threshold voltage in an array of 1D devices.

  14. Single-valley quantum Hall ferromagnet in a dilute MgxZn1-xO/ZnO strongly correlated two-dimensional electron system

    DOE PAGES [OSTI]

    Kozuka, Y.; Tsukazaki, A.; Maryenko, D.; Falson, J.; Bell, C.; Kim, M.; Hikita, Y.; Hwang, H. Y.; Kawasaki, M.

    2012-02-03

    We investigate the spin susceptibility (g*m*) of dilute two-dimensional (2D) electrons confined at the MgxZn1-xO/ZnO heterointerface. Magnetotransport measurements show a four-fold enhancement of g*m*, dominated by the increase in the Landé g-factor. The g-factor enhancement leads to a ferromagnetic instability of the electron gas as evidenced by sharp resistance spikes. At high magnetic field, the large g*m* leads to full spin polarization, where we found sudden increase in resistance around the filling factors of half-integer, accompanied by complete disappearance of fractional quantum Hall (QH) states. Along with its large effective mass and the high electron mobility, our result indicates thatmore » the ZnO 2D system is ideal for investigating the effect of electron correlations in the QH regime.« less

  15. Numerical simulations of the two-dimensional multimode Richtmyer-Meshkov instability

    SciTech Connect

    Thornber, B.; Zhou, Y.

    2015-03-15

    The two-dimensional Richtmyer-Meshkov instability occurs as shock waves pass through a perturbed material interface, triggering transition to an inhomogeneous turbulence variable density flow. This paper presents a series of large-eddy-simulations of the two dimensional turbulent RM instability and compares the results to the fully three dimensional simulations. There are two aims for this paper, the first is to explore what numerical resolution is required for a statistically converged solution for a two dimensional inhomogeneous flow field. The second aim is to elucidate the key differences in flow physics between the two dimensional and three dimensional Richtmyer-Meshkov instabilities, particularly their asymptotic self-similar regime. Convergence is achieved using 64 independent realisations and grid resolutions up to 4096{sup 2} in the plane. It is shown that for narrowband cases the growth rate θ = 0.48 which is substantially higher than the three-dimensional equivalent. Mix measures are consistently lower compared to three-dimensional, and the kinetic energy distribution is homogeneous at late time. The broadband case has a similar initial growth rate as the three-dimensional case, with a marginally lower θ = 0.63. Mix is similar in magnitude, but is reducing at late time. The spectra in both cases exhibit the dual-cascade expected from two-dimensional turbulence.

  16. Vibrational coherence and energy transfer in two-dimensional spectra with the optimized mean-trajectory approximation

    SciTech Connect

    Alemi, Mallory; Loring, Roger F.

    2015-06-07

    The optimized mean-trajectory (OMT) approximation is a semiclassical method for computing vibrational response functions from action-quantized classical trajectories connected by discrete transitions that represent radiation-matter interactions. Here, we extend the OMT to include additional vibrational coherence and energy transfer processes. This generalized approximation is applied to a pair of anharmonic chromophores coupled to a bath. The resulting 2D spectra are shown to reflect coherence transfer between normal modes.

  17. Discriminating trpzip2 and trpzip4 peptides folding landscape using the two-dimensional infrared spectroscopy: A simulation study

    SciTech Connect

    Wu, Tianmin; Zhang, Ruiting; Li, Huanhuan; Zhuang, Wei, E-mail: wzhuang@dicp.ac.cn, E-mail: lijiangy@pku.edu.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning (China); Yang, Lijiang, E-mail: wzhuang@dicp.ac.cn, E-mail: lijiangy@pku.edu.cn [College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871 (China)] [College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871 (China)

    2014-02-07

    We analyzed, based on the theoretical spectroscopic modeling, how the differences in the folding landscapes of two ?-hairpin peptides trpzip2 and trpzip4 are reflected in their thermal unfolding infrared measurements. The isotope-edited equilibrium FTIR and two dimensional infrared spectra of the two peptides were calculated, using the nonlinear exciton propagation method, at a series of temperatures. The spectra calculations were based on the configuration distributions generated using the GB{sup OBC} implicit solvent MD simulation and the integrated tempering sampling technique. Conformational analysis revealed the different local thermal stabilities for these two peptides, which suggested the different folding landscapes. Our study further suggested that the ellipticities of the isotope peaks in the coherent IR signals are more sensitive to these local stability differences compared with other spectral features such as the peak intensities. Our technique can thus be combined with the relevant experimental measurements to achieve a better understanding of the peptide folding behaviors.

  18. Development of a novel x-ray focusing technique using crystals with two-dimensionally modulated surfaces

    SciTech Connect

    Chang, W.Z.; Kley, E.B.; Fuchs, H.J.; Schnabel, B.; Foerster, E.; Chukhovskii, F.N.

    1995-12-31

    Theoretical investigations for obtaining x-ray point focusing by using crystals with two-dimensionally modulated surfaces are carried out. Based on the Bragg and Fresnel diffraction principles, formulae of modulated surfaces (structures) are derived for both flat and bent crystals for focusing x-rays to micron or submicron size. It is found that elliptically-shaped and linearly modulated structures are suitable for flat and cylindrically bent crystals, respectively. For the given Ti K{alpha} radiation and geometric parameters, Si(111) and InSb(111) reflections are used for the calculations of flat and bent crystals in terms of their focus characteristics, namely the focusing efficiency and the focus width. The influence of the distribution of the Bragg amplitude on flat and bent crystals is also discussed.

  19. Quantum oscillations in a two-dimensional electron gas at the

    Office of Scientific and Technical Information (OSTI)

    rocksalt/zincblende interface of PbTe/CdTe (111) heterostructures (Journal Article) | SciTech Connect Quantum oscillations in a two-dimensional electron gas at the rocksalt/zincblende interface of PbTe/CdTe (111) heterostructures Citation Details In-Document Search Title: Quantum oscillations in a two-dimensional electron gas at the rocksalt/zincblende interface of PbTe/CdTe (111) heterostructures Quantum oscillations are observed in the 2DEG system at the interface of novel

  20. Two-dimensional electron gas in monolayer InN quantum wells

    SciTech Connect

    Pan, Wei; Dimakis, Emmanouil; Wang, George T.; Moustakas, Theodore D.; Tsui, Daniel C.

    2014-11-24

    We report in this letter experimental results that confirm the two-dimensional nature of the electron systems in monolayer InN quantum wells embedded in GaN barriers. The electron density and mobility of the two-dimensional electron system (2DES) in these InN quantum wells are 5×1015 cm-2 and 420 cm2 /Vs, respectively. Moreover, the diagonal resistance of the 2DES shows virtually no temperature dependence in a wide temperature range, indicating the topological nature of the 2DES.

  1. Two-dimensional electron gas in monolayer InN quantum wells

    DOE PAGES [OSTI]

    Pan, Wei; Dimakis, Emmanouil; Wang, George T.; Moustakas, Theodore D.; Tsui, Daniel C.

    2014-11-24

    We report in this letter experimental results that confirm the two-dimensional nature of the electron systems in monolayer InN quantum wells embedded in GaN barriers. The electron density and mobility of the two-dimensional electron system (2DES) in these InN quantum wells are 5×1015 cm-2 and 420 cm2 /Vs, respectively. Moreover, the diagonal resistance of the 2DES shows virtually no temperature dependence in a wide temperature range, indicating the topological nature of the 2DES.

  2. [Research in two-dimensional critical phenomena and conformal field theory]. Final report

    SciTech Connect

    Not Available

    1990-12-31

    A very theoretical description is given of research in two- dimensional critical phenomena and conformal field theory. Major progress is reported in the field of fluctuating two-dimensional surfaces. A discretized representation of fluctuating geometry is used where surfaces are represented by triangulations; continuum surfaces are recovered by taking the size of the triangles to zero. One of the central goals of the theory of critical phenomena is to find all possible universality classes of n-dimensional critical phenomena; this goal has been translated into the problem of clasifying all possible scale-invariant euclidean quantum field theories. (RWR)

  3. System for generating two-dimensional masks from a three-dimensional model using topological analysis

    DOEpatents

    Schiek, Richard

    2006-06-20

    A method of generating two-dimensional masks from a three-dimensional model comprises providing a three-dimensional model representing a micro-electro-mechanical structure for manufacture and a description of process mask requirements, reducing the three-dimensional model to a topological description of unique cross sections, and selecting candidate masks from the unique cross sections and the cross section topology. The method further can comprise reconciling the candidate masks based on the process mask requirements description to produce two-dimensional process masks.

  4. Quantum Monte Carlo simulation of a two-dimensional Bose gas

    SciTech Connect

    Pilati, S.; Boronat, J.; Casulleras, J.; Giorgini, S.

    2005-02-01

    The equation of state of a homogeneous two-dimensional Bose gas is calculated using quantum Monte Carlo methods. The low-density universal behavior is investigated using different interatomic model potentials, both finite ranged and strictly repulsive and zero ranged, supporting a bound state. The condensate fraction and the pair distribution function are calculated as a function of the gas parameter, ranging from the dilute to the strongly correlated regime. In the case of the zero-range pseudopotential we discuss the stability of the gaslike state for large values of the two-dimensional scattering length, and we calculate the critical density where the system becomes unstable against cluster formation.

  5. Stability analysis for two-dimensional ion-acoustic waves in quantum plasmas

    SciTech Connect

    Seadawy, A. R.

    2014-05-15

    The quantum hydrodynamic model is applied to two-dimensional ion-acoustic waves in quantum plasmas. The two-dimensional quantum hydrodynamic model is used to obtain a deformed Kortewegde Vries (dKdV) equation by reductive perturbation method. By using the solution of auxiliary ordinary equations, a extended direct algebraic method is described to construct the exact solutions for nonlinear quantum dKdV equation. The present results are describing the generation and evolution of such waves, their interactions, and their stability.

  6. Van der Waals epitaxial growth of two-dimensional single-crystalline GaSe domains on graphene

    DOE PAGES [OSTI]

    Li, Xufan; Basile, Leonardo; Huang, Bing; Ma, Cheng; Lee, Jaekwang; Vlassiouk, Ivan V.; Puretzky, Alexander A.; Lin, Ming -Wei; Chi, Miaofang; Idrobo Tapia, Juan Carlos; et al

    2015-07-22

    Two-dimensional (2D) van der Waals (vdW) heterostructures are a family of artificially-structured materials that promise tunable optoelectronic properties for devices with enhanced functionalities. Compared to stamping, direct epitaxy of vdW heterostructures is ideal for clean interlayer interfaces and scalable device fabrication. Here, we explore the synthesis and preferred orientations of 2D GaSe atomic layers on graphene (Gr) by vdW epitaxy. Guided by the wrinkles on graphene, GaSe nuclei form that share a predominant lattice orientation. Due to vdW epitaxial growth many nuclei grow as perfectly aligned crystals and coalesce to form large (tens of microns), single-crystal flakes. Through theoretical investigationsmore » of interlayer energetics, and measurements of preferred orientations by atomic-resolution STEM and electron diffraction, a 10.9 interlayer rotation of the GaSe lattice with respect to the underlying graphene is found to be the most energetically preferred vdW heterostructure with the largest binding energy and the longest-range ordering. These GaSe/Gr vdW heterostructures exhibit an enhanced Raman E21g band of monolayer GaSe along with highly-quenched photoluminescence due to strong charge transfer. Despite the very large lattice mismatch of GaSe/Gr through vdW epitaxy, the predominant orientation control and convergent formation of large single-crystal flakes demonstrated here is promising for the scalable synthesis of large-area vdW heterostructures for the development of new optical and optoelectronic devices.« less

  7. Van der Waals epitaxial growth of two-dimensional single-crystalline GaSe domains on graphene

    SciTech Connect

    Li, Xufan; Basile, Leonardo; Huang, Bing; Ma, Cheng; Lee, Jaekwang; Vlassiouk, Ivan V.; Puretzky, Alexander A.; Lin, Ming -Wei; Chi, Miaofang; Idrobo Tapia, Juan Carlos; Rouleau, Christopher M.; Sumpter, Bobby G.; Yoon, Mina; Geohegan, David B.; Xiao, Kai

    2015-07-22

    Two-dimensional (2D) van der Waals (vdW) heterostructures are a family of artificially-structured materials that promise tunable optoelectronic properties for devices with enhanced functionalities. Compared to stamping, direct epitaxy of vdW heterostructures is ideal for clean interlayer interfaces and scalable device fabrication. Here, we explore the synthesis and preferred orientations of 2D GaSe atomic layers on graphene (Gr) by vdW epitaxy. Guided by the wrinkles on graphene, GaSe nuclei form that share a predominant lattice orientation. Due to vdW epitaxial growth many nuclei grow as perfectly aligned crystals and coalesce to form large (tens of microns), single-crystal flakes. Through theoretical investigations of interlayer energetics, and measurements of preferred orientations by atomic-resolution STEM and electron diffraction, a 10.9 interlayer rotation of the GaSe lattice with respect to the underlying graphene is found to be the most energetically preferred vdW heterostructure with the largest binding energy and the longest-range ordering. These GaSe/Gr vdW heterostructures exhibit an enhanced Raman E21g band of monolayer GaSe along with highly-quenched photoluminescence due to strong charge transfer. Despite the very large lattice mismatch of GaSe/Gr through vdW epitaxy, the predominant orientation control and convergent formation of large single-crystal flakes demonstrated here is promising for the scalable synthesis of large-area vdW heterostructures for the development of new optical and optoelectronic devices.

  8. Van der Waals Epitaxial Growth of Single-Crystal Two-Dimensional GaSe on Graphene

    DOE PAGES [OSTI]

    Li, Xufan; Basile, Leonardo; Huang, Bing; Ma, Cheng; Lee, Jaekwang; Vlassiouk, Ivan V.; Puretzky, Alexander A.; Lin, Ming-Wei; Chi, Miaofang; Idrobo Tapia, Juan Carlos; et al

    2015-07-22

    Two-dimensional (2D) van der Waals (vdW) heterostructures are a family of artificially-structured materials that promise tunable optoelectronic properties for devices with enhanced functionalities. Compared to stamping, direct epitaxy of vdW heterostructures is ideal for clean interlayer interfaces and scalable device fabrication. Here, we explore the synthesis and preferred orientations of 2D GaSe atomic layers on graphene (Gr) by vdW epitaxy. Guided by the wrinkles on graphene, GaSe nuclei form that share a predominant lattice orientation. Due to vdW epitaxial growth many nuclei grow as perfectly aligned crystals and coalesce to form large (tens of microns), single-crystal flakes. Through theoretical investigationsmoreof interlayer energetics, and measurements of preferred orientations by atomic-resolution STEM and electron diffraction, a 10.9 interlayer rotation of the GaSe lattice with respect to the underlying graphene is found to be the most energetically preferred vdW heterostructure with the largest binding energy and the longest-range ordering. These GaSe/Gr vdW heterostructures exhibit an enhanced Raman E21g band of monolayer GaSe along with highly-quenched photoluminescence due to strong charge transfer. Despite the very large lattice mismatch of GaSe/Gr through vdW epitaxy, the predominant orientation control and convergent formation of large single-crystal flakes demonstrated here is promising for the scalable synthesis of large-area vdW heterostructures for the development of new optical and optoelectronic devices.less

  9. Couplings between hierarchical conformational dynamics from multi-time correlation functions and two-dimensional lifetime spectra: Application to adenylate kinase

    SciTech Connect

    Ono, Junichi; Takada, Shoji; Saito, Shinji

    2015-06-07

    An analytical method based on a three-time correlation function and the corresponding two-dimensional (2D) lifetime spectrum is developed to elucidate the time-dependent couplings between the multi-timescale (i.e., hierarchical) conformational dynamics in heterogeneous systems such as proteins. In analogy with 2D NMR, IR, electronic, and fluorescence spectroscopies, the waiting-time dependence of the off-diagonal peaks in the 2D lifetime spectra can provide a quantitative description of the dynamical correlations between the conformational motions with different lifetimes. The present method is applied to intrinsic conformational changes of substrate-free adenylate kinase (AKE) using long-time coarse-grained molecular dynamics simulations. It is found that the hierarchical conformational dynamics arise from the intra-domain structural transitions among conformational substates of AKE by analyzing the one-time correlation functions and one-dimensional lifetime spectra for the donor-acceptor distances corresponding to single-molecule Förster resonance energy transfer experiments with the use of the principal component analysis. In addition, the complicated waiting-time dependence of the off-diagonal peaks in the 2D lifetime spectra for the donor-acceptor distances is attributed to the fact that the time evolution of the couplings between the conformational dynamics depends upon both the spatial and temporal characters of the system. The present method is expected to shed light on the biological relationship among the structure, dynamics, and function.

  10. A two dimensional silicon detectors array for quality assurance in stereotactic radiotherapy: MagicPlate-512

    SciTech Connect

    Aldosari, A. H.; Petasecca, M. Espinoza, A.; Newall, M.; Fuduli, I.; Porumb, C.; Alshaikh, S.; Alrowaili, Z. A.; Weaver, M.; Metcalfe, P.; Lerch, M. L. F.; Rosenfeld, A. B.; Carolan, M.; Perevertaylo, V.

    2014-09-15

    Purpose: Silicon diode arrays are commonly implemented in radiation therapy quality assurance applications as they have a number of advantages including: real time operation (compared to the film) and high spatial resolution, large dynamic range and small size (compared to ionizing chambers). Most diode arrays have detector pitch that is too coarse for routine use in small field applications. The goal of this work is to characterize the two-dimensional monolithic silicon diode array named “MagicPlate-512” (MP512) designed for QA in stereotactic body radiation therapy (SBRT) and stereotactic radio surgery (SRS). Methods: MP512 is a silicon monolithic detector manufactured on ap-type substrate. An array contains of 512 pixels with size 0.5 × 0.5 mm{sup 2} and pitch 2 mm with an overall dimension of 52 × 52 mm{sup 2}. The MP512 monolithic detector is wire bonded on a printed circuit board 0.5 mm thick and covered by a thin layer of raisin to preserve the silicon detector from moisture and chemical contamination and to protect the bonding wires. Characterization of the silicon monolithic diode array response was performed, and included pixels response uniformity, dose linearity, percent depth dose, output factor, and beam profiling for beam sizes relevant to SBRT and SRS and depth dose response in comparison with ionization chamber. Results: MP512 shows a good dose linearity (R{sup 2} = 0.998) and repeatability within 0.2%. The measured depth dose response for field size of 10 × 10 cm{sup 2} agreed to within 1.3%, when compared to a CC13 ionization chamber for depths in PMMA up to 30 cm. The output factor of a 6 MV Varian 2100EX medical linac beam measured by MP512 at the isocenter agrees to within 2% when compared to PTW diamond, Scanditronix point EDD-2 diode and MOSkin detectors for field sizes down to 1 × 1 cm{sup 2}. An over response of 4% was observed for square beam size smaller than 1 cm when compared to EBT3 films, while the beam profiles (FWHM) of MP

  11. Tuning the conductivity threshold and carrier density of two-dimensional electron gas at oxide interfaces through interface engineering

    SciTech Connect

    Ma, H. J. Harsan E-mail: ariando@nus.edu.sg; Zeng, S. W.; Annadi, A.; Ariando E-mail: ariando@nus.edu.sg; Huang, Z.; Venkatesan, T.

    2015-08-15

    The two-dimensional electron gas (2DEG) formed at the perovskite oxides heterostructures is of great interest because of its potential applications in oxides electronics and nanoscale multifunctional devices. A canonical example is the 2DEG at the interface between a polar oxide LaAlO{sub 3} (LAO) and non-polar SrTiO{sub 3} (STO). Here, the LAO polar oxide can be regarded as the modulating or doping layer and is expected to define the electronic properties of 2DEG at the LAO/STO interface. However, to practically implement the 2DEG in electronics and device design, desired properties such as tunable 2D carrier density are necessary. Here, we report the tuning of conductivity threshold, carrier density and electronic properties of 2DEG in LAO/STO heterostructures by insertion of a La{sub 0.5}Sr{sub 0.5}TiO{sub 3} (LSTO) layer of varying thicknesses, and thus modulating the amount of polarization of the oxide over layers. Our experimental result shows an enhancement of carrier density up to a value of about five times higher than that observed at the LAO/STO interface. A complete thickness dependent metal-insulator phase diagram is obtained by varying the thickness of LAO and LSTO providing an estimate for the critical thickness needed for the metallic phase. The observations are discussed in terms of electronic reconstruction induced by polar oxides.

  12. High-precision determination of low-energy effective parameters for a two-dimensional Heisenberg quantum antiferromagnet

    SciTech Connect

    Jiang, F.-J.; Wiese, U.-J.

    2011-04-15

    The two-dimensional (2D) spin-(1/2) Heisenberg antiferromagnet with exchange coupling J is investigated on a periodic square lattice of spacing a at very small temperatures using the loop-cluster algorithm. Monte Carlo data for the staggered and uniform susceptibilities are compared with analytic results obtained in the systematic low-energy effective field theory for the staggered magnetization order parameter. The low-energy parameters of the effective theory, i.e., the staggered magnetization density M{sub s}=0.307 43(1)/a{sup 2}, the spin stiffness {rho}{sub s}=0.180 81(11)J, and the spin wave velocity c=1.6586(3)Ja, are determined with very high precision. Our study may serve as a test case for the comparison of lattice quantum chromodynamics Monte Carlo data with analytic predictions of the chiral effective theory for pions and nucleons, which is vital for the quantitative understanding of the strong interaction at low energies.

  13. Investigation of transient, two-dimensional coupled heat and moisture flow in soils

    SciTech Connect

    Shen, L.S.W.

    1986-01-01

    A two-dimensional finite difference numerical model has been developed to study coupled heat and moisture flow in the soil surrounding an earth-sheltered construction. The model is based on a mechanistic approach formulated by Milly and developed from the work of Philip and deVries. Using soil temperatures and matric potentials as the dependent variables, the model is capable of simulating unsaturated/saturated flow conditions in heterogeneous soil domains. The model is a fully implicit, integrated finite difference approach based on the Patankar Spalding method. The numerical modeling of the governing heat and moisture equations was validated against a number of analytical and quasi-analytical solutions. An axisymmetric, two-dimensional experiment was then defined to which the numerical model could be compared. The experimental apparatus was composed of a cylinder filled with a dredged Mississippi River sand. A series of one and two dimensional heat and moisture flow experiments were run, using boundary conditions consistent with those that occur in the soil surrounding a building. Soil properties used in the model were either calculated from theoretical models or measured experimentally. Agreement between the model and experiments were good, with an error of 10-15% obtained for the two-dimensional coupled heat and moisture flow experiment.

  14. Scalable salt-templated synthesis of two-dimensional transition metal oxides

    DOE PAGES [OSTI]

    Xiao, Xu; Song, Huaibing; Lin, Shizhe; Zhou, Ying; Zhan, Xiaojun; Hu, Zhimi; Zhang, Qi; Sun, Jiyu; Yang, Bo; Li, Tianqi; et al

    2016-04-22

    Two-dimensional atomic crystals, such as two-dimensional oxides, have attracted much attention in energy storage because nearly all of the atoms can be exposed to the electrolyte and involved in redox reactions. However, current strategies are largely limited to intrinsically layered compounds. Here we report a general strategy that uses the surfaces of water-soluble salt crystals as growth templates and is applicable to not only layered compounds but also various transition metal oxides, such as hexagonal-MoO3, MoO2, MnO and hexagonal-WO3. The planar growth is hypothesized to occur via a match between the crystal lattices of the salt and the growing oxide.more » Restacked two-dimensional hexagonal-MoO3 exhibits high pseudocapacitive performances (for example, 300Fcm-3 in an Al2(SO4)3 electrolyte). Furthermore, the synthesis of various two-dimensional transition metal oxides and the demonstration of high capacitance are expected to enable fundamental studies of dimensionality effects on their properties and facilitate their use in energy storage and other applications.« less

  15. Demonstration of two-dimensional time-encoded imaging of fast neutrons

    SciTech Connect

    Brennan, J.; Brubaker, E.; Gerling, M.; Marleau, P.; McMillan, K.; Nowack, A.; Galloudec, N. Renard-Le; Sweany, M.

    2015-09-09

    Here, we present a neutron detector system based on time-encoded imaging, and demonstrate its applicability toward the spatial mapping of special nuclear material. We also demonstrate that two-dimensional fast-neutron imaging with 2 resolution at 2 m stand-off is feasible with only two instrumented detectors.

  16. Numerical Studies of Collective Phenomena in Two-Dimensional Electron and Cold Atom Systems

    SciTech Connect

    Rezayi, Edward

    2013-07-25

    Numerical calculations were carried out to investigate a number of outstanding questions in both two-dimensional electron and cold atom systems. These projects aimed to increase our understanding of the properties of and prospects for non-Abelian states in quantum Hall matter.

  17. Integrated digital inverters based on two-dimensional anisotropic ReS₂ field-effect transistors

    DOE PAGES [OSTI]

    Liu, Erfu; Fu, Yajun; Wang, Yaojia; Feng, Yanqing; Liu, Huimei; Wan, Xiangang; Zhou, Wei; Wang, Baigeng; Shao, Lubin; Ho, Ching -Hwa; et al

    2015-05-07

    Semiconducting two-dimensional transition metal dichalcogenides are emerging as top candidates for post-silicon electronics. While most of them exhibit isotropic behaviour, lowering the lattice symmetry could induce anisotropic properties, which are both scientifically interesting and potentially useful. Here we present atomically thin rhenium disulfide (ReS₂) flakes with unique distorted 1T structure, which exhibit in-plane anisotropic properties. We fabricated monolayer and few-layer ReS₂ field-effect transistors, which exhibit competitive performance with large current on/off ratios (~10⁷) and low subthreshold swings (100 mV per decade). The observed anisotropic ratio along two principle axes reaches 3.1, which is the highest among all known two-dimensional semiconductingmore » materials. Furthermore, we successfully demonstrated an integrated digital inverter with good performance by utilizing two ReS₂ anisotropic field-effect transistors, suggesting the promising implementation of large-scale two-dimensional logic circuits. Our results underscore the unique properties of two-dimensional semiconducting materials with low crystal symmetry for future electronic applications.« less

  18. Integrated digital inverters based on two-dimensional anisotropic ReS₂ field-effect transistors

    SciTech Connect

    Liu, Erfu; Fu, Yajun; Wang, Yaojia; Feng, Yanqing; Liu, Huimei; Wan, Xiangang; Zhou, Wei; Wang, Baigeng; Shao, Lubin; Ho, Ching -Hwa; Huang, Ying -Sheng; Cao, Zhengyi; Wang, Laiguo; Li, Aidong; Zeng, Junwen; Song, Fengqi; Wang, Xinran; Shi, Yi; Yuan, Hongtao; Hwang, Harold Y.; Cui, Yi; Miao, Feng; Xing, Dingyu

    2015-05-07

    Semiconducting two-dimensional transition metal dichalcogenides are emerging as top candidates for post-silicon electronics. While most of them exhibit isotropic behaviour, lowering the lattice symmetry could induce anisotropic properties, which are both scientifically interesting and potentially useful. Here we present atomically thin rhenium disulfide (ReS₂) flakes with unique distorted 1T structure, which exhibit in-plane anisotropic properties. We fabricated monolayer and few-layer ReS₂ field-effect transistors, which exhibit competitive performance with large current on/off ratios (~10⁷) and low subthreshold swings (100 mV per decade). The observed anisotropic ratio along two principle axes reaches 3.1, which is the highest among all known two-dimensional semiconducting materials. Furthermore, we successfully demonstrated an integrated digital inverter with good performance by utilizing two ReS₂ anisotropic field-effect transistors, suggesting the promising implementation of large-scale two-dimensional logic circuits. Our results underscore the unique properties of two-dimensional semiconducting materials with low crystal symmetry for future electronic applications.

  19. Two-dimensional spatiotemporal focusing of femtosecond pulses and its applications in microscopy

    SciTech Connect

    Song, Qiyuan; Nakamura, Aoi; Hirosawa, Kenichi; Kannari, Fumihiko; Isobe, Keisuke; Midorikawa, Katsumi

    2015-08-15

    We demonstrate and theoretically analyze the two-dimensional spatiotemporal focusing of femtosecond pulses by utilizing a two-dimensional spectral disperser. Compared with spatiotemporal focusing with a diffraction grating, it can achieve widefield illumination with better sectioning ability for a multiphoton excitation process. By utilizing paraxial approximation, our analytical method improves the axial confinement ability and identifies that the free spectra range (FSR) of the two-dimensional spectral disperser affects the out-of-focus multiphoton excitation intensity due to the temporal self-imaging effect. Based on our numerical simulation, a FSR of 50 GHz is necessary to reduce the out-of-focus two-photon excitation by 2 orders of magnitude compared with that in a grating-based spatiotemporal focusing scheme for a 90-fs excitation laser pulse. We build a two-dimensional spatiotemporal focusing microscope using a virtually imaged phased array and achieve an axial resolution of 1.3 μm, which outperforms the resolution of conventional spatiotemporal focusing using a grating by a factor of 1.7, and demonstrate better image contrast inside a tissue-like phantom.

  20. Symmetry operators for Dirac's equation on two-dimensional spin manifolds

    SciTech Connect

    Fatibene, Lorenzo; McLenaghan, Raymond G.; Smith, Shane N.; Rastelli, Giovanni

    2009-05-15

    It is shown that the second order symmetry operators for the Dirac equation on a general two-dimensional spin manifold may be expressed in terms of Killing vectors and valence 2 Killing tensors. The role of these operators in the theory of separation of variables for the Dirac equation is studied.

  1. Demonstration of two-dimensional time-encoded imaging of fast neutrons

    DOE PAGES [OSTI]

    Brennan, J.; Brubaker, E.; Gerling, M.; Marleau, P.; McMillan, K.; Nowack, A.; Galloudec, N. Renard-Le; Sweany, M.

    2015-09-09

    Here, we present a neutron detector system based on time-encoded imaging, and demonstrate its applicability toward the spatial mapping of special nuclear material. We also demonstrate that two-dimensional fast-neutron imaging with 2° resolution at 2 m stand-off is feasible with only two instrumented detectors.

  2. Soliton Theory of Two-Dimensional Lattices: The Discrete Nonlinear Schroedinger Equation

    SciTech Connect

    Arevalo, Edward

    2009-06-05

    We theoretically investigate the motion of collective excitations in the two-dimensional nonlinear Schroedinger equation with cubic nonlinearity. The form of these excitations for a broad range of parameters is derived. Their evolution and interaction is numerically studied and the modulation instability is discussed. The case of saturable nonlinearity is revisited.

  3. Accuracy of the Quasistatic Method for Two-Dimensional Thermal Reactor Transients with Feedback

    SciTech Connect

    Dodds, H.L. Jr.

    2001-10-23

    An important aspect in the design and safe operation of a nuclear reactor is the behavior of a reactor in a transient, or nonsteady state, condition. This study shows that the quasistatic method is capable of producing highly accurate results, relative to the direct finite-difference method, for two-dimensional thermal reactor transients with feedback.

  4. Alaska Maximum Number of Active Crews Engaged in Two-Dimensional Seismic

    Gasoline and Diesel Fuel Update

    Surveying (Number of Elements) Two-Dimensional Seismic Surveying (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 4 2 12 6 0 0 0 0 NA 0 2010's 0

  5. 2D Wavefront Sensor Analysis and Control

    Energy Science and Technology Software Center

    1996-02-19

    This software is designed for data acquisition and analysis of two dimensional wavefront sensors. The software includes data acquisition and control functions for an EPIX frame grabber to acquire data from a computer and all the appropriate analysis functions necessary to produce and display intensity and phase information. This software is written in Visual Basic for windows.

  6. Characterization of a novel two dimensional diode array the ''magic plate'' as a radiation detector for radiation therapy treatment

    SciTech Connect

    Wong, J. H. D.; Fuduli, I.; Carolan, M.; Petasecca, M.; Lerch, M. L. F.; Perevertaylo, V. L.; Metcalfe, P.; Rosenfeld, A. B.

    2012-05-15

    Purpose: Intensity modulated radiation therapy (IMRT) utilizes the technology of multileaf collimators to deliver highly modulated and complex radiation treatment. Dosimetric verification of the IMRT treatment requires the verification of the delivered dose distribution. Two dimensional ion chamber or diode arrays are gaining popularity as a dosimeter of choice due to their real time feedback compared to film dosimetry. This paper describes the characterization of a novel 2D diode array, which has been named the ''magic plate'' (MP). It was designed to function as a 2D transmission detector as well as a planar detector for dose distribution measurements in a solid water phantom for the dosimetric verification of IMRT treatment delivery. Methods: The prototype MP is an 11 x 11 detector array based on thin (50 {mu}m) epitaxial diode technology mounted on a 0.6 mm thick Kapton substrate using a proprietary ''drop-in'' technology developed by the Centre for Medical Radiation Physics, University of Wollongong. A full characterization of the detector was performed, including radiation damage study, dose per pulse effect, percent depth dose comparison with CC13 ion chamber and build up characteristics with a parallel plane ion chamber measurements, dose linearity, energy response and angular response. Results: Postirradiated magic plate diodes showed a reproducibility of 2.1%. The MP dose per pulse response decreased at higher dose rates while at lower dose rates the MP appears to be dose rate independent. The depth dose measurement of the MP agrees with ion chamber depth dose measurements to within 0.7% while dose linearity was excellent. MP showed angular response dependency due to the anisotropy of the silicon diode with the maximum variation in angular response of 10.8% at gantry angle 180 deg. Angular dependence was within 3.5% for the gantry angles {+-} 75 deg. The field size dependence of the MP at isocenter agrees with ion chamber measurement to within 1.1%. In

  7. Excitonic effects in two-dimensional semiconductors: Path integral Monte Carlo approach

    DOE PAGES [OSTI]

    Velizhanin, Kirill A.; Saxena, Avadh

    2015-11-11

    The most striking features of novel two-dimensional semiconductors (e.g., transition metal dichalcogenide monolayers or phosphorene) is a strong Coulomb interaction between charge carriers resulting in large excitonic effects. In particular, this leads to the formation of multicarrier bound states upon photoexcitation (e.g., excitons, trions, and biexcitons), which could remain stable at near-room temperatures and contribute significantly to the optical properties of such materials. In our work we have used the path integral Monte Carlo methodology to numerically study properties of multicarrier bound states in two-dimensional semiconductors. Specifically, we have accurately investigated and tabulated the dependence of single-exciton, trion, and biexcitonmore » binding energies on the strength of dielectric screening, including the limiting cases of very strong and very weak screening. Our results of this work are potentially useful in the analysis of experimental data and benchmarking of theoretical and computational models.« less

  8. Resonant tunneling device with two-dimensional quantum well emitter and base layers

    DOEpatents

    Simmons, J.A.; Sherwin, M.E.; Drummond, T.J.; Weckwerth, M.V.

    1998-10-20

    A double electron layer tunneling device is presented. Electrons tunnel from a two dimensional emitter layer to a two dimensional tunneling layer and continue traveling to a collector at a lower voltage. The emitter layer is interrupted by an isolation etch, a depletion gate, or an ion implant to prevent electrons from traveling from the source along the emitter to the drain. The collector is similarly interrupted by a backgate, an isolation etch, or an ion implant. When the device is used as a transistor, a control gate is added to control the allowed energy states of the emitter layer. The tunnel gate may be recessed to change the operating range of the device and allow for integrated complementary devices. Methods of forming the device are also set forth, utilizing epoxy-bond and stop etch (EBASE), pre-growth implantation of the backgate or post-growth implantation. 43 figs.

  9. Resonant tunneling device with two-dimensional quantum well emitter and base layers

    DOEpatents

    Simmons, Jerry A.; Sherwin, Marc E.; Drummond, Timothy J.; Weckwerth, Mark V.

    1998-01-01

    A double electron layer tunneling device is presented. Electrons tunnel from a two dimensional emitter layer to a two dimensional tunneling layer and continue traveling to a collector at a lower voltage. The emitter layer is interrupted by an isolation etch, a depletion gate, or an ion implant to prevent electrons from traveling from the source along the emitter to the drain. The collector is similarly interrupted by a backgate, an isolation etch, or an ion implant. When the device is used as a transistor, a control gate is added to control the allowed energy states of the emitter layer. The tunnel gate may be recessed to change the operating range of the device and allow for integrated complementary devices. Methods of forming the device are also set forth, utilizing epoxy-bond and stop etch (EBASE), pre-growth implantation of the backgate or post-growth implantation.

  10. Coherent imaging with two-dimensional focal-plane arrays: design and applications

    SciTech Connect

    Simpson, M.L.; Bennett, C.A.; Emery, M.S.; Hutchinson, D.P.; Miller, G.H.; Richards, R.K.; Sitter, D.N.

    1997-09-01

    Scanned, single-channel optical heterodyne detection has been used in a variety of lidar applications from ranging and velocity measurements to differential absorption spectroscopy. We describe the design of a coherent camera system that is based on a two-dimensional staring array of heterodyne receivers for coherent imaging applications. Experimental results with a single HgCdTe detector translated in the image plane to form a synthetic two-dimensional array demonstrate the ability to obtain passive heterodyne images of chemical vapor plumes that are invisible to normal video infrared cameras. We describe active heterodyne imaging experiments with use of focal-plane arrays that yield hard-body Doppler lidar images and also demonstrate spatial averaging to reduce speckle effects in static coherent images. {copyright} 1997 Optical Society of America

  11. Two-dimensional fluid droplet arrays generated using a single nozzle

    DOEpatents

    Lee, Eric R.; Perl, Martin L.

    1999-11-02

    Amplitudes of drive pulses received by a horizontally-placed dropper determine the horizontal displacements of droplets relative to an ejection aperture of the dropper. The drive pulses are varied such that the dropper generates a two-dimensional array of vertically-falling droplets. Vertical and horizontal interdroplet spacings may be varied in real time. Applications include droplet analysis experiments such as Millikan fractional charge searches and aerosol characterization, as well as material deposition applications.

  12. Coulomb reacceleration as a clock for nuclear reactions: A two-dimensional model

    SciTech Connect

    Bertulani, C.A. ); Bertsch, G.F. )

    1994-05-01

    Reacceleration effects in the Coulomb breakup of nuclei are modeled with the two-dimensional time-dependent Schroedinger equation, extending a previous one-dimensional study. The present model better describes the individual contributions of longitudinal and transverse forces to the breakup and reacceleration. Reacceleration effects are found to preserve a strong memory of the pre-breakup phase of the reaction, as was concluded with the one-dimensional model.

  13. A Two-Dimensional Thermal-Electrochemical Model for Prismatic Lithium Ion

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Cells - Energy Innovation Portal Energy Storage Energy Storage Find More Like This Return to Search A Two-Dimensional Thermal-Electrochemical Model for Prismatic Lithium Ion Cells National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Existing battery management algorithms rely upon empirical correlations between the cell voltage and the load profile. This approach limits the predictive ability of the battery management system to forecast

  14. Two-dimensional Laguerre-Gaussian soliton family in strongly nonlocal nonlinear media

    SciTech Connect

    Zhong Weiping; Yi Lin

    2007-06-15

    We have studied Laguerre-Gaussian spatial solitary waves in strongly nonlocal nonlinear media analytically and numerically. An exact analytical solution of two-dimensional self-similar waves is obtained. Furthermore, a family of different spatial solitary waves has been found. It is interesting that the spatial soliton profile and its width remain unchanged with increasing propagation distance. The theoretical predictions may give new insights into low-energetic spatial soliton transmission with high fidelity.

  15. Inertial ranges and resistive instabilities in two-dimensional magnetohydrodynamic turbulence

    SciTech Connect

    Politano, H.; Pouquet, A.; Sulem, P.L. )

    1989-12-01

    Direct numerical simulations of decaying two-dimensional magnetohydrodynamic flows at Reynolds numbers of several thousand are performed, using resolutions of 1024{sup 2} collocation points. An inertial range extending to about one decade is observed, with spectral properties depending on the velocity--magnetic field correlation. At very small scales, resistive tearing destabilizes current sheets generated by the inertial dynamics and leads to the formation of small-scale magnetic islands, which may then grow and reach the size of inertial scales.

  16. Instantons and the fixed point topological charge in the two-dimensional O(3) {sigma} model

    SciTech Connect

    Blatter, M.; Burkhalter, R.; Hasenfratz, P.; Niedermayer, F.

    1996-01-01

    We define a fixed point topological charge for the two-dimensional O(3) lattice {sigma} model which is free of topological defects. We use this operator in combination with the fixed point action to measure the topological susceptibility for a wide range of correlation lengths. The results strongly suggest that it is not a physical quantity in this model. The procedure, however, can be applied to other asymptotically free theories as well. {copyright} {ital 1996 The American Physical Society.}

  17. Large scale two-dimensional arrays of magnesium diboride superconducting quantum interference devices

    SciTech Connect

    Cybart, Shane A. Dynes, R. C.; Wong, T. J.; Cho, E. Y.; Beeman, J. W.; Yung, C. S.; Moeckly, B. H.

    2014-05-05

    Magnetic field sensors based on two-dimensional arrays of superconducting quantum interference devices were constructed from magnesium diboride thin films. Each array contained over 30?000 Josephson junctions fabricated by ion damage of 30?nm weak links through an implant mask defined by nano-lithography. Current-biased devices exhibited very large voltage modulation as a function of magnetic field, with amplitudes as high as 8?mV.

  18. Preliminary results for a two-dimensional simulation of the working process of a Stirling engine

    SciTech Connect

    Makhkamov, K.K.; Ingham, D.B.

    1998-07-01

    Stirling engines have several potential advantages over existing types of engines, in particular they can use renewable energy sources for power production and their performance meets the demands on the environmental security. In order to design Stirling Engines properly, and to put into effect their potential performance, it is important to more accurately mathematically simulate its working process. At present, a series of very important mathematical models are used for describing the working process of Stirling Engines and these are, in general, classified as models of three levels. All the models consider one-dimensional schemes for the engine and assume a uniform fluid velocity, temperature and pressure profiles at each plane of the internal gas circuit of the engine. The use of two-dimensional CFD models can significantly extend the capabilities for the detailed analysis of the complex heat transfer and gas dynamic processes which occur in the internal gas circuit, as well as in the external circuit of the engine. In this paper a two-dimensional simplified frame (no construction walls) calculation scheme for the Stirling Engine has been assumed and the standard {kappa}-{var{underscore}epsilon} turbulence model has been used for the analysis of the engine working process. The results obtained show that the use of two-dimensional CFD models gives the possibility of gaining a much greater insight into the fluid flow and heat transfer processes which occur in Stirling Engines.

  19. Magnetohydrodynamic waves in two-dimensional prominences embedded in coronal arcades

    SciTech Connect

    Terradas, J.; Soler, R.; Daz, A. J.; Oliver, R.; Ballester, J. L.

    2013-11-20

    Solar prominence models used so far in the analysis of MHD waves in two-dimensional structures are quite elementary. In this work, we calculate numerically magnetohydrostatic models in two-dimensional configurations under the presence of gravity. Our interest is in models that connect the magnetic field to the photosphere and include an overlying arcade. The method used here is based on a relaxation process and requires solving the time-dependent nonlinear ideal MHD equations. Once a prominence model is obtained, we investigate the properties of MHD waves superimposed on the structure. We concentrate on motions purely two-dimensional, neglecting propagation in the ignorable direction. We demonstrate how, by using different numerical tools, we can determine the period of oscillation of stable waves. We find that vertical oscillations, linked to fast MHD waves, are always stable and have periods in the 4-10 minute range. Longitudinal oscillations, related to slow magnetoacoustic-gravity waves, have longer periods in the range of 28-40 minutes. These longitudinal oscillations are strongly influenced by the gravity force and become unstable for short magnetic arcades.

  20. Staring 2-D hadamard transform spectral imager

    DOEpatents

    Gentry, Stephen M.; Wehlburg, Christine M.; Wehlburg, Joseph C.; Smith, Mark W.; Smith, Jody L.

    2006-02-07

    A staring imaging system inputs a 2D spatial image containing multi-frequency spectral information. This image is encoded in one dimension of the image with a cyclic Hadamarid S-matrix. The resulting image is detecting with a spatial 2D detector; and a computer applies a Hadamard transform to recover the encoded image.

  1. Application of 2D VSP Imaging Technology to the Targeting of...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Project objectives: A novel 2D VSP imaging technology and patented processing techniques will be used to create accurate, high-resolution reflection images of a classic Basin and ...

  2. Two-dimensional GaSe/MoSe2 misfit bilayer heterojunctions by van der Waals epitaxy

    DOE PAGES [OSTI]

    Li, Xufan; Lin, Ming-Wei; Lin, Junhao; Huang, Bing; Puretzky, Alexander A.; Ma, Cheng; Wang, Kai; Zhou, Wu; Pantelides, Sokrates T.; Chi, Miaofang; et al

    2016-04-01

    Two-dimensional (2D) heterostructures hold the promise for future atomically-thin electronics and optoelectronics due to their diverse functionalities. While heterostructures consisting of different transition metal dichacolgenide monolayers with well-matched lattices and novel physical properties have been successfully fabricated via van der Waals (vdW) or edge epitaxy, constructing heterostructures from monolayers of layered semiconductors with large lattice misfits still remains challenging. Here, we report the growth of monolayer GaSe/MoSe2 heterostructures with large lattice misfit by two-step chemical vapor deposition (CVD). Both vertically stacked and lateral heterostructures are demonstrated. The vertically stacked GaSe/MoSe2 heterostructures exhibit vdW epitaxy with well-aligned lattice orientation between themore » two layers, forming an incommensurate vdW heterostructure. However, the lateral heterostructures exhibit no lateral epitaxial alignment at the interface between GaSe and MoSe2 crystalline domains. Instead of a direct lateral connection at the boundary region where the same lattice orientation is observed between GaSe and MoSe2 monolayer domains in lateral GaSe/MoSe2 heterostructures, GaSe monolayers are found to overgrow MoSe2 during CVD, forming a stripe of vertically stacked vdW heterostructure at the crystal interface. Such vertically-stacked vdW GaSe/MoSe2 heterostructures are shown to form p-n junctions with effective transport and separation of photo-generated charge carriers between layers, resulting in a gate-tunable photovoltaic response. In conclusion, these GaSe/MoSe2 vdW heterostructures should have applications as gate-tunable field-effect transistors, photodetectors, and solar cells.« less

  3. A Computer Program for the Reactivity and Kinetic Parameters for Two-Dimensional Triangular Geometry by Transport Perturbation Theory.

    Energy Science and Technology Software Center

    1990-04-25

    Version 00 TPTRIA calculates reactivity, effective delayed neutron fractions and mean generation time for two-dimensional triangular geometry on the basis of neutron transport perturbation theory. DIAMANT2 (also designated as CCC-414), is a multigroup two-dimensional discrete ordinates transport code system for triangular and hexagonal geometry which calculates direct and adjoint angular fluxes.

  4. Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional...

    Office of Scientific and Technical Information (OSTI)

    As a result, the ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable ... Type: Accepted Manuscript Journal Name: Journal of Materials Chemistry. C Additional ...

  5. TWO-DIMENSIONAL CORE-COLLAPSE SUPERNOVA MODELS WITH MULTI-DIMENSIONAL...

    Office of Scientific and Technical Information (OSTI)

    Our main motivation for carrying out this study is to compare with recent 2D models produced by other groups who have obtained explosions for some progenitor stars and with recent ...

  6. Twisted conformal symmetry in noncommutative two-dimensional quantum field theory

    SciTech Connect

    Lizzi, Fedele; Vitale, Patrizia; Vaidya, Sachindeo

    2006-06-15

    By twisting the commutation relations between creation and annihilation operators, we show that quantum conformal invariance can be implemented in the 2-d Moyal plane. This is an explicit realization of an infinite dimensional symmetry as a quantum algebra.

  7. Phonon Instability with Respect to Soliton Formation in Two-Dimensional Dipolar Bose-Einstein Condensates

    SciTech Connect

    Nath, R.; Santos, L.; Pedri, P.

    2009-02-06

    The partially attractive character of the dipole-dipole interaction leads to phonon instability in dipolar Bose-Einstein condensates, which is followed by collapse in 3D geometries. We show that in 2D, the nature of the post-instability dynamics is fundamentally different, due to the stabilization of 2D solitons. As a result, a transient gas of attractive solitons is formed, and collapse may be avoided. In the presence of an harmonic trap, the post-instability dynamics is characterized by a transient pattern formation followed by the creation of stable 2D solitons. This dynamics should be observable in ongoing experiments, allowing for the creation of stable 2D solitons for the first time ever in quantum gases.

  8. A neural approach for the numerical modeling of two-dimensional...

    Office of Scientific and Technical Information (OSTI)

    inductions components at each time step and it is trained by 2-d measurements ... of the neural system returns the predicted value of the field H at the same time step. ...

  9. One- and two-dimensional Stirling machine simulation using experimentally generated reversing flow turbuulence models

    SciTech Connect

    Goldberg, L.F.

    1990-08-01

    The activities described in this report do not constitute a continuum but rather a series of linked smaller investigations in the general area of one- and two-dimensional Stirling machine simulation. The initial impetus for these investigations was the development and construction of the Mechanical Engineering Test Rig (METR) under a grant awarded by NASA to Dr. Terry Simon at the Department of Mechanical Engineering, University of Minnesota. The purpose of the METR is to provide experimental data on oscillating turbulent flows in Stirling machine working fluid flow path components (heater, cooler, regenerator, etc.) with particular emphasis on laminar/turbulent flow transitions. Hence, the initial goals for the grant awarded by NASA were, broadly, to provide computer simulation backup for the design of the METR and to analyze the results produced. This was envisaged in two phases: First, to apply an existing one-dimensional Stirling machine simulation code to the METR and second, to adapt a two-dimensional fluid mechanics code which had been developed for simulating high Rayleigh number buoyant cavity flows to the METR. The key aspect of this latter component was the development of an appropriate turbulence model suitable for generalized application to Stirling simulation. A final-step was then to apply the two-dimensional code to an existing Stirling machine for which adequate experimental data exist. The work described herein was carried out over a period of three years on a part-time basis. Forty percent of the first year`s funding was provided as a match to the NASA funds by the Underground Space Center, University of Minnesota, which also made its computing facilities available to the project at no charge.

  10. Generalized perturbation theory using two-dimensional, discrete ordinates transport theory

    SciTech Connect

    Childs, R.L.

    1980-06-01

    Perturbation theory for changes in linear and bilinear functionals of the forward and adjoint fluxes in a critical reactor has been implemented using two-dimensional discrete ordinates transport theory. The computer program DOT IV was modified to calculate the generalized functions GAMMA and GAMMA*. Demonstration calculations were performed for changes in a reaction-rate ratio and a reactivity worth caused by system perturbations. The perturbation theory predictions agreed with direct calculations to within about 2%. A method has been developed for calculating higher lambda eigenvalues and eigenfunctions using techniques similar to those developed for generalized functions. Demonstration calculations have been performed to obtain these eigenfunctions.

  11. Quantum confinement effects across two-dimensional planes in MoS{sub 2} quantum dots

    SciTech Connect

    Gan, Z. X.; Liu, L. Z.; Wu, H. Y.; Hao, Y. L.; Shan, Y.; Wu, X. L. E-mail: paul.chu@cityu.edu.hk; Chu, Paul K. E-mail: paul.chu@cityu.edu.hk

    2015-06-08

    The low quantum yield (∼10{sup −5}) has restricted practical use of photoluminescence (PL) from MoS{sub 2} composed of a few layers, but the quantum confinement effects across two-dimensional planes are believed to be able to boost the PL intensity. In this work, PL from 2 to 9 nm MoS{sub 2} quantum dots (QDs) is excluded from the solvent and the absorption and PL spectra are shown to be consistent with the size distribution. PL from MoS{sub 2} QDs is also found to be sensitive to aggregation due to the size effect.

  12. Near-infrared gallium nitride two-dimensional photonic crystal platform on silicon

    SciTech Connect

    Roland, I.; Zeng, Y.; Han, Z.; Checoury, X.; Blin, C.; El Kurdi, M.; Ghrib, A.; Sauvage, S.; Boucaud, P.; Gayral, B.; Brimont, C.; Guillet, T.; Semond, F.

    2014-07-07

    We demonstrate a two-dimensional free-standing gallium nitride photonic crystal platform operating around 1550 nm and fabricated on a silicon substrate. Width-modulated waveguide cavities are integrated and exhibit loaded quality factors up to 34 000 at 1575 nm. We show the resonance tunability by varying the ratio of air hole radius to periodicity, and cavity hole displacement. We deduce a ∼7.9 dB/cm linear absorption loss for the suspended nitride structure from the power dependence of the cavity in-plane transmission.

  13. Fundamental solutions in a half space of two-dimensional hexagonal quasicrystal and their applications

    SciTech Connect

    Wang, T.; Li, X. Y.; Zhang, X.; Müller, R.

    2015-04-21

    Fundamental phonon-phason field in a half-infinite space of two-dimensional hexagonal quasicrystal is derived, on the basis of general solutions in terms of quasi-harmonic functions, by virtue of the trial-and-error technique. Extended Boussinesq and Cerruti problems are studied. Appropriate potential functions are assumed and corresponding fundamental solutions are explicitly derived in terms of elementary functions. The boundary integral equations governing the contact and crack problems are constructed from the present fundament solutions. The obtained analytical solutions can serve as guidelines for future indentation tests via scanning probe microscopy and atomic force microscopy methods.

  14. Miniband Transport in a Two-Dimensional Electron Gas with a Strong Periodic Unidirectional Potential Modulation

    SciTech Connect

    Lyo, Sungkwun K.; Pan, Wei

    2014-08-07

    In this paper, we study the Bloch oscillations of a two-dimensional electron gas with a strong periodic potential-modulation and miniband transport along the field at low temperatures, assuming a free motion in the transverse direction. The dependence of the current on the field, the electron density, and the temperature is investigated by using a relaxation-time approximation for inelastic scattering. Moreover, for a fixed total scattering rate, the field dependence of the current is sensitive to the ratio of the elastic and inelastic scattering rates in contrast with the recent result of a multiband but otherwise similar model with a weak potential modulation.

  15. Two-dimensional quantification of the corrosion process in metal surfaces using digital speckle pattern interferometry

    SciTech Connect

    Andres, N.; Lobera, J.; Arroyo, M. P.; Angurel, L. A.

    2011-04-01

    The applicability of digital speckle pattern interferometry (DSPI) to the analysis of surface corrosion processes has been evaluated by studying the evolution of an Fe surface immersed in sulfuric acid. This work describes the analysis process required to obtain quantitative information about the corrosion process. It has been possible to evaluate the corrosion rate, and the results agree with those derived from the weight loss method. In addition, a two-dimensional analysis has been applied, showing that DSPI measurements can be used to extract information about the corrosion rate at any region of the surface.

  16. Thermal conductivity of configurable two-dimensional carbon nanotube architecture and strain modulation

    SciTech Connect

    Zhan, H. F.; Bell, J. M.; Gu, Y. T., E-mail: yuantong.gu@qut.edu.au [School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, 2 George St., Brisbane, Queensland 4000 (Australia); Zhang, G. [Institute of High Performance Computing, Agency for Science, Technology and Research, 1 Fusionopolis Way, Singapore 138632 (Singapore)

    2014-10-13

    We reported the thermal conductivity of the two-dimensional carbon nanotube (CNT)-based architecture, which can be constructed through welding of single-wall CNTs by electron beam. Using large-scale nonequilibrium molecular dynamics simulations, the thermal conductivity is found to vary with different junction types due to their different phonon scatterings at the junction. The strong length and strain dependence of the thermal conductivity suggests an effective avenue to tune the thermal transport properties of the CNT-based architecture, benefiting the design of nanoscale thermal rectifiers or phonon engineering.

  17. CURRENT - A Computer Code for Modeling Two-Dimensional, Chemically Reaccting, Low Mach Number Flows

    SciTech Connect

    Winters, W.S.; Evans, G.H.; Moen, C.D.

    1996-10-01

    This report documents CURRENT, a computer code for modeling two- dimensional, chemically reacting, low Mach number flows including the effects of surface chemistry. CURRENT is a finite volume code based on the SIMPLER algorithm. Additional convergence acceleration for low Peclet number flows is provided using improved boundary condition coupling and preconditioned gradient methods. Gas-phase and surface chemistry is modeled using the CHEMKIN software libraries. The CURRENT user-interface has been designed to be compatible with the Sandia-developed mesh generator and post processor ANTIPASTO and the post processor TECPLOT. This report describes the theory behind the code and also serves as a user`s manual.

  18. Flat Bogomolnyi-Prasad-Sommerfeld domain walls on two-dimensional Kaehler-Ricci soliton

    SciTech Connect

    Gunara, Bobby Eka; Zen, Freddy Permana

    2009-06-15

    In this paper we address several aspects of flat Bogomolnyi-Prasad-Sommerfeld (BPS) domain walls together with their Lorentz invariant vacua of four-dimensional N=1 supergravity coupled to a chiral multiplet. The scalar field spans a one-parameter family of two-dimensional Kaehler manifolds satisfying a Kaehler-Ricci flow equation. We find that BPS equations and the scalar potential deform with respect to the real parameter related to the Kaehler-Ricci soliton. In addition, the analysis using gradient and renormalization group flows is carried out to ensure the existence of Lorentz invariant vacua related to anti-de Sitter/conformal field theory correspondence.

  19. Infrared magneto-spectroscopy of two-dimensional and three-dimensional massless fermions: A comparison

    SciTech Connect

    Orlita, M.; Faugeras, C.; Barra, A.-L.; Martinez, G.; Potemski, M.; Basko, D. M.; Teppe, F.; Knap, W.; Gavrilenko, V. I.; Mikhailov, N. N.; Dvoretskii, S. A.; Neugebauer, P.; Berger, C.

    2015-03-21

    Here, we report on a magneto-optical study of two distinct systems hosting massless fermions—two-dimensional graphene and three-dimensional HgCdTe tuned to the zero band gap condition at the point of the semiconductor-to-semimetal topological transition. Both materials exhibit, in the quantum regime, a fairly rich magneto-optical response, which is composed from a series of intra- and interband inter-Landau level resonances with for massless fermions typical √(B) dependence. The impact of the system's dimensionality and of the strength of the spin-orbit interaction on the optical response is also discussed.

  20. Form 2D | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    D Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Permit ApplicationPermit Application: Form 2DLegal Abstract Form 2D: Application for Permit to...

  1. Complete photonic band gaps and tunable self-collimation in the two-dimensional plasma photonic crystals with a new structure

    SciTech Connect

    Zhang, Hai-Feng; Ding, Guo-Wen; Li, Hai-Ming; Liu, Shao-Bin

    2015-02-15

    In this paper, the properties of complete photonic band gaps (CPBGs) and tunable self-collimation in two-dimensional plasma photonic crystals (2D PPCs) with a new structure in square lattices, whose dielectric fillers (GaAs) are inserted into homogeneous and nomagnetized plasma background are theoretically investigated by a modified plane wave expansion (PWE) method with a novel technique. The novel PWE method can be utilized to compute the dispersion curves of 2D PPCs with arbitrary-shaped cross section in any lattices. As a comparison, CPBGs of PPCs for four different configurations are numerically calculated. The computed results show that the proposed design has the advantages of achieving the larger CPBGs compared to the other three configurations. The influences of geometric parameters of filled unit cell and plasma frequency on the properties of CPBGs are studied in detail. The calculated results demonstrate that CPBGs of the proposed 2D PPCs can be easily engineered by changing those parameters, and the larger CPBGs also can be obtained by optimization. The self-collimation in such 2D PPCs also is discussed in theory under TM wave. The theoretical simulations reveal that the self-collimation phenomena can be found in the TM bands, and both the frequency range of self-collimation and the equifrequency surface contours can be tuned by the parameters as mentioned above. It means that the frequency range and direction of electromagnetic wave can be manipulated by designing, as it propagates in the proposed PPCs without diffraction. Those results can hold promise for designing the tunable applications based on the proposed PPCs.

  2. 2-D Finite Element Heat Conduction

    Energy Science and Technology Software Center

    1989-10-30

    AYER is a finite element program which implicitly solves the general two-dimensional equation of thermal conduction for plane or axisymmetric bodies. AYER takes into account the effects of time (transient problems), in-plane anisotropic thermal conductivity, a three-dimensional velocity distribution, and interface thermal contact resistance. Geometry and material distributions are arbitrary, and input is via subroutines provided by the user. As a result, boundary conditions, material properties, velocity distributions, and internal power generation may be mademore » functions of, e.g., time, temperature, location, and heat flux.« less

  3. Detector-Response Correction of Two-Dimensional γ -Ray Spectra from Neutron Capture

    DOE PAGES [OSTI]

    Rusev, G.; Jandel, M.; Arnold, C. W.; Bredeweg, T. A.; Couture, A.; Mosby, S. M.; Ullmann, J. L.

    2015-05-28

    The neutron-capture reaction produces a large variety of γ-ray cascades with different γ-ray multiplicities. A measured spectral distribution of these cascades for each γ-ray multiplicity is of importance to applications and studies of γ-ray statistical properties. The DANCE array, a 4π ball of 160 BaF2 detectors, is an ideal tool for measurement of neutron-capture γ-rays. The high granularity of DANCE enables measurements of high-multiplicity γ-ray cascades. The measured two-dimensional spectra (γ-ray energy, γ-ray multiplicity) have to be corrected for the DANCE detector response in order to compare them with predictions of the statistical model or use them in applications. Themore » detector-response correction problem becomes more difficult for a 4π detection system than for a single detector. A trial and error approach and an iterative decomposition of γ-ray multiplets, have been successfully applied to the detector-response correction. Applications of the decomposition methods are discussed for two-dimensional γ-ray spectra measured at DANCE from γ-ray sources and from the 10B(n, γ) and 113Cd(n, γ) reactions.« less

  4. High-mobility capacitively-induced two-dimensional electrons in a lateral superlattice potential

    SciTech Connect

    Lu, Tzu -Ming; Laroche, Dominique; Huang, S. -H.; Chuang, Y.; Li, J. -Y.; Liu, C. W.

    2016-01-01

    In the presence of a lateral periodic potential modulation, two-dimensional electrons may exhibit interesting phenomena, such as a graphene-like energy-momentum dispersion, Bloch oscillations, or the Hofstadter butterfly band structure. To create a sufficiently strong potential modulation using conventional semiconductor heterostructures, aggressive device processing is often required, unfortunately resulting in strong disorder that masks the sought-after effects. Here, we report a novel fabrication process flow for imposing a strong lateral potential modulation onto a capacitively induced two-dimensional electron system, while preserving the host material quality. Using this process flow, the electron density in a patterned Si/SiGe heterostructure can be tuned over a wide range, from 4.4 × 1010 cm–2 to 1.8 × 1011 cm–2, with a peak mobility of 6.4 × 105 cm2/V·s. The wide density tunability and high electron mobility allow us to observe sequential emergence of commensurability oscillations as the density, the mobility, and in turn the mean free path, increase. Magnetic-field-periodic quantum oscillations associated with various closed orbits also emerge sequentially with increasing density. We show that, from the density dependence of the quantum oscillations, one can directly extract the steepness of the imposed superlattice potential. Lastly, this result is then compared to a conventional lateral superlattice model potential.

  5. Two-dimensional numerical simulation of boron diffusion for pyramidally textured silicon

    SciTech Connect

    Ma, Fa-Jun Duttagupta, Shubham; Shetty, Kishan Devappa; Meng, Lei; Hoex, Bram; Peters, Ian Marius; Samudra, Ganesh S.

    2014-11-14

    Multidimensional numerical simulation of boron diffusion is of great relevance for the improvement of industrial n-type crystalline silicon wafer solar cells. However, surface passivation of boron diffused area is typically studied in one dimension on planar lifetime samples. This approach neglects the effects of the solar cell pyramidal texture on the boron doping process and resulting doping profile. In this work, we present a theoretical study using a two-dimensional surface morphology for pyramidally textured samples. The boron diffusivity and segregation coefficient between oxide and silicon in simulation are determined by reproducing measured one-dimensional boron depth profiles prepared using different boron diffusion recipes on planar samples. The established parameters are subsequently used to simulate the boron diffusion process on textured samples. The simulated junction depth is found to agree quantitatively well with electron beam induced current measurements. Finally, chemical passivation on planar and textured samples is compared in device simulation. Particularly, a two-dimensional approach is adopted for textured samples to evaluate chemical passivation. The intrinsic emitter saturation current density, which is only related to Auger and radiative recombination, is also simulated for both planar and textured samples. The differences between planar and textured samples are discussed.

  6. Confinement effects of magnetic field on two-dimensional hydrogen atom in plasmas

    SciTech Connect

    Bahar, M. K.; Soylu, A.

    2015-05-15

    In this study, for the first time, the Schrödinger equation with more general exponential cosine screened Coulomb (MGECSC) potential is solved numerically in the presence and in the absence of an external magnetic field within two-dimensional formalism using the asymptotic iteration method. The MGECSC potential includes four different potential forms when considering different sets of the parameters in the potential. The plasma screening effects in the weak and strong magnetic field regimes as well as the confinement effects of magnetic field on the two-dimensional hydrogen atom in Debye and quantum plasmas are investigated by solving the corresponding equations. It is found that applying a uniform magnetic field on the hydrogen atom embedded in a plasma leads to change in the profile of the total interaction potential. Thus, confinement effects of magnetic field on hydrogen atom embedded in Debye and quantum plasmas modeled by a MGECSC potential lead to shift bound state energies. This effect would be important to isolate the plasma from the external environment in the experimental applications of plasma physics.

  7. Evidence for the presence of quasi-two-dimensional nearly incompressible fluctuations in the solar wind

    SciTech Connect

    Matthaeus, W.H. ); Goldstein, M.L.; Roberts, D.A. )

    1990-12-01

    Solar wind fluctuations are commonly regarded as a superposition of MHD waves primarily in the Alven mode. These MHD fluctuations are frequently assumed to possess slab or isotropic symmetry, particularly in the development of models of the propagation of cosmic rays throughout the heliosphere. There are, however, several long-standing problems with either of these choices. One problem is that the mean free path for pitch angle scattering of cosmic rays in the heliosphere is apparently longer than can be accounted for by using either assumption about the statistical symmetry of the fluctuations. Another problem is the prediction of WKB theory that the direction of minimum variance should tend to lie along the radial direction rather than along the mean magnetic field as is observed. Motivated by laboratory plasma experiments, a series of two-dimensional MHD simulations, recent theoretical work, and extensive analyses of solar wind data, the authors suggest that there is a third possible viewpoint with potentially important implications for solar wind studies. From this perspective they suggest that solar wind fluctuations contain a subpopulation that have wave vectors nearly transverse to both the mean magnetic field and the fluctuations about the mean. For this quasi-two-dimensional component the direction of minimum variance lies along the mean magnetic field, density fluctuations are small and anticorrelated with {vert bar}B{vert bar}, the total pressure at small scales is nearly constant, and pitch angle scattering by resonant wave-particle interactions is suppressed.

  8. Peak picking and the assessment of separation performance in two-dimensional high performance liquid chromatography

    SciTech Connect

    Guiochon, Georges A; Shalliker, R. Andrew

    2010-01-01

    An algorithm was developed for 2DHPLC that automated the process of peak recognition, measuring their retention times, and then subsequently plotting the information in a two-dimensional retention plane. Following the recognition of peaks, the software then performed a series of statistical assessments of the separation performance, measuring for example, correlation between dimensions, peak capacity and the percentage of usage of the separation space. Peak recognition was achieved by interpreting the first and second derivatives of each respective one-dimensional chromatogram to determine the 1D retention times of each solute and then compiling these retention times for each respective fraction 'cut'. Due to the nature of comprehensive 2DHPLC adjacent cut fractions may contain peaks common to more than one cut fraction. The algorithm determined which components were common in adjacent cuts and subsequently calculated the peak maximum profile by interpolating the space between adjacent peaks. This algorithm was applied to the analysis of a two-dimensional separation of an apple flesh extract separated in a first dimension comprising a cyano stationary phase and an aqueous/THF mobile phase as the first dimension and a second dimension comprising C18-Hydro with an aqueous/MeOH mobile phase. A total of 187 peaks were detected.

  9. High-mobility capacitively-induced two-dimensional electrons in a lateral superlattice potential

    DOE PAGES [OSTI]

    Lu, Tzu -Ming; Laroche, Dominique; Huang, S. -H.; Chuang, Y.; Li, J. -Y.; Liu, C. W.

    2016-01-01

    In the presence of a lateral periodic potential modulation, two-dimensional electrons may exhibit interesting phenomena, such as a graphene-like energy-momentum dispersion, Bloch oscillations, or the Hofstadter butterfly band structure. To create a sufficiently strong potential modulation using conventional semiconductor heterostructures, aggressive device processing is often required, unfortunately resulting in strong disorder that masks the sought-after effects. Here, we report a novel fabrication process flow for imposing a strong lateral potential modulation onto a capacitively induced two-dimensional electron system, while preserving the host material quality. Using this process flow, the electron density in a patterned Si/SiGe heterostructure can be tuned overmore » a wide range, from 4.4 × 1010 cm–2 to 1.8 × 1011 cm–2, with a peak mobility of 6.4 × 105 cm2/V·s. The wide density tunability and high electron mobility allow us to observe sequential emergence of commensurability oscillations as the density, the mobility, and in turn the mean free path, increase. Magnetic-field-periodic quantum oscillations associated with various closed orbits also emerge sequentially with increasing density. We show that, from the density dependence of the quantum oscillations, one can directly extract the steepness of the imposed superlattice potential. Lastly, this result is then compared to a conventional lateral superlattice model potential.« less

  10. Determining the static electronic and vibrational energy correlations via two-dimensional electronic-vibrational spectroscopy

    DOE PAGES [OSTI]

    Dong, Hui; Lewis, Nicholas H. C.; Oliver, Thomas A. A.; Fleming, Graham R.

    2015-05-07

    Changes in the electronic structure of pigments in protein environments and of polar molecules in solution inevitably induce a re-adaption of molecular nuclear structure. Both changes of electronic and vibrational energies can be probed with visible or infrared lasers, such as two-dimensional electronic spectroscopy or vibrational spectroscopy. The extent to which the two changes are correlated remains elusive. The recent demonstration of two-dimensional electronic-vibrational (2DEV) spectroscopy potentially enables a direct measurement of this correlation experimentally. However, it has hitherto been unclear how to characterize the correlation from the spectra. In this report, we present a theoretical formalism to demonstrate themore » slope of the nodal line between the excited state absorption and ground state bleach peaks in the spectra as a characterization of the correlation between electronic and vibrational transition energies. In conclusion, we also show the dynamics of the nodal line slope is correlated to the vibrational spectral dynamics. Additionally, we demonstrate the fundamental 2DEV spectral line-shape of a monomer with newly developed response functions« less

  11. Ground-state and dynamical properties of two-dimensional dipolar Fermi liquids

    SciTech Connect

    Abedinpour, Saeed H.; Asgari, Reza; Tanatar, B.; Polini, Marco

    2014-01-15

    We study the ground-state properties of a two-dimensional spin-polarized fluid of dipolar fermions within the EulerLagrange Fermi-hypernetted-chain approximation. Our method is based on the solution of a scattering Schrdinger equation for the pair amplitude ?(g(r)), where g(r) is the pair distribution function. A key ingredient in our theory is the effective pair potential, which includes a bosonic term from JastrowFeenberg correlations and a fermionic contribution from kinetic energy and exchange, which is tailored to reproduce the HartreeFock limit at weak coupling. Very good agreement with recent results based on quantum Monte Carlo simulations is achieved over a wide range of coupling constants up to the liquid-to-crystal quantum phase transition. Using the fluctuationdissipation theorem and a static approximation for the effective inter-particle interactions, we calculate the dynamical densitydensity response function, and furthermore demonstrate that an undamped zero-sound mode exists for any value of the interaction strength, down to infinitesimally weak couplings. -- Highlights: We have studied the ground state properties of a strongly correlated two-dimensional fluid of dipolar fermions. We have calculated the effective inter-particle interaction and the dynamical densitydensity response function. We have shown that an undamped zero sound mode exists at any value of the interaction strength.

  12. Electronic structure of Ce2 RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE PAGES [OSTI]

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    In this study, we use angle-resolved photoemission spectroscopy (ARPES) to study the two-dimensional (2D) heavy-fermion superconductor, Ce2 RhIn8. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q vector of (0.32, 0.32) π/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band-structure calculations suggests that a localized picture of the f electrons works best. While there is some agreement in the overall band dispersionmore » and location of the Fermi sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band-structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  13. Engineering two-dimensional superconductivity and Rashba spin–orbit coupling in LaAlO3/SrTiO3 quantum wells by selective orbital occupancy

    DOE PAGES [OSTI]

    Herranz, Gervasi; Singh, Gyanendra; Bergeal, Nicolas; Jouan, Alexis; Lesueur, Jérôme; Gázquez, Jaume; Varela, María; Scigaj, Mateusz; Dix, Nico; Sánchez, Florencio; et al

    2015-01-13

    We find the discovery of two-dimensional electron gases (2DEGs) at oxide interfaces—involving electrons in narrow d-bands—has broken new ground, enabling the access to correlated states that are unreachable in conventional semiconductors based on s- and p- electrons. There is a growing consensus that emerging properties at these novel quantum wells—such as 2D superconductivity and magnetism—are intimately connected to specific orbital symmetries in the 2DEG sub-band structure. Here we show that crystal orientation allows selective orbital occupancy, disclosing unprecedented ways to tailor the 2DEG properties. By carrying out electrostatic gating experiments in ​LaAlO3/​SrTiO3 wells of different crystal orientations, we show thatmore » the spatial extension and anisotropy of the 2D superconductivity and the Rashba spin–orbit field can be largely modulated by controlling the 2DEG sub-band filling. Such an orientational tuning expands the possibilities for electronic engineering of 2DEGs at ​LaAlO3/​SrTiO3 interfaces.« less

  14. A method for the direct measurement of electronic site populations in a molecular aggregate using two-dimensional electronic-vibrational spectroscopy

    SciTech Connect

    Lewis, Nicholas H. C.; Dong, Hui; Oliver, Thomas A. A.; Fleming, Graham R.

    2015-09-28

    Two dimensional electronic spectroscopy has proved to be a valuable experimental technique to reveal electronic excitation dynamics in photosynthetic pigment-protein complexes, nanoscale semiconductors, organic photovoltaic materials, and many other types of systems. It does not, however, provide direct information concerning the spatial structure and dynamics of excitons. 2D infrared spectroscopy has become a widely used tool for studying structural dynamics but is incapable of directly providing information concerning electronic excited states. 2D electronic-vibrational (2DEV) spectroscopy provides a link between these domains, directly connecting the electronic excitation with the vibrational structure of the system under study. In this work, we derive response functions for the 2DEV spectrum of a molecular dimer and propose a method by which 2DEV spectra could be used to directly measure the electronic site populations as a function of time following the initial electronic excitation. We present results from the response function simulations which show that our proposed approach is substantially valid. This method provides, to our knowledge, the first direct experimental method for measuring the electronic excited state dynamics in the spatial domain, on the molecular scale.

  15. Casting Process Simulator 2D Mold Fill and Solidification

    Energy Science and Technology Software Center

    1995-05-06

    The CaPS software is a tool used to setup, simulate, and examine the results from two-dimensional filling and solidification of a sand casting.

  16. A Computer Program for the Calculation of Reactivity and Kinetic Parameters by Two-Dimensional Neutron Transport Perturbation Theory.

    Energy Science and Technology Software Center

    1985-02-01

    Version 00 TP2 is a transport theory code, developed to determine reactivity effects and kinetic parameters such as effective delayed neutron fractions and mean generation time by applying the usual perturbation formalism for two-dimensional geometry.

  17. On the diagonal susceptibility of the two-dimensional Ising model

    SciTech Connect

    Tracy, Craig A.; Widom, Harold

    2013-12-15

    We consider the diagonal susceptibility of the isotropic 2D Ising model for temperatures below the critical temperature. For a parameter k related to temperature and the interaction constant, we extend the diagonal susceptibility to complex k inside the unit disc, and prove the conjecture that the unit circle is a natural boundary.

  18. Revealing origin of quasi-one dimensional current transport in defect rich two dimensional materials

    SciTech Connect

    Lotz, Mikkel R.; Boll, Mads; Bøggild, Peter; Petersen, Dirch H.; Hansen, Ole; Kjær, Daniel

    2014-08-04

    The presence of defects in graphene have for a long time been recognized as a bottleneck for its utilization in electronic and mechanical devices. We recently showed that micro four-point probes may be used to evaluate if a graphene film is truly 2D or if defects in proximity of the probe will lead to a non-uniform current flow characteristic of lower dimensionality. In this work, simulations based on a finite element method together with a Monte Carlo approach are used to establish the transition from 2D to quasi-1D current transport, when applying a micro four-point probe to measure on 2D conductors with an increasing amount of line-shaped defects. Clear 2D and 1D signatures are observed at low and high defect densities, respectively, and current density plots reveal the presence of current channels or branches in defect configurations yielding 1D current transport. A strong correlation is found between the density filling factor and the simulation yield, the fraction of cases with 1D transport and the mean sheet conductance. The upper transition limit is shown to agree with the percolation threshold for sticks. Finally, the conductance of a square sample evaluated with macroscopic edge contacts is compared to the micro four-point probe conductance measurements and we find that the micro four-point probe tends to measure a slightly higher conductance in samples containing defects.

  19. Miniband Transport in a Two-Dimensional Electron Gas with a Strong Periodic Unidirectional Potential Modulation

    DOE PAGES [OSTI]

    Lyo, Sungkwun K.; Pan, Wei

    2014-08-07

    In this paper, we study the Bloch oscillations of a two-dimensional electron gas with a strong periodic potential-modulation and miniband transport along the field at low temperatures, assuming a free motion in the transverse direction. The dependence of the current on the field, the electron density, and the temperature is investigated by using a relaxation-time approximation for inelastic scattering. Moreover, for a fixed total scattering rate, the field dependence of the current is sensitive to the ratio of the elastic and inelastic scattering rates in contrast with the recent result of a multiband but otherwise similar model with a weakmore » potential modulation.« less

  20. Analytical and numerical solution of one- and two-dimensional steady heat transfer in a coldplate

    SciTech Connect

    Jones, G.F.; Bennett, G.A.; Bultman, D.H.

    1987-01-01

    We develop analytical models for steady-state, one- and two-dimensional heat transfer in a single-material, flat-plate coldplate. Discrete heat sources are mounted on one side of the plate and heat transfer to a flowing fluid occurs on the other. The models are validated numerically using finite differences. We propose a simple procedure for estimating maximum coldplate temperature at the location of each heat source which includes thermal interaction among the sources. Results from one model are compared with data obtained for a composite coldplate operated in the laboratory. We demonstrate the utility of the models as diagnostic tools to be used for predicting the existence and extent of void volumes and delaminations in the composite material that can occur with coldplates of this type. Based on our findings, recommendations for effective coldplate design are given.

  1. Two-dimensional modeling of the cathode sheath formation during the streamer-cathode interaction

    SciTech Connect

    Yan, Wen; Sang, Chaofeng; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Liu, Fucheng [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)] [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2014-01-15

    In this paper, a computational simulation of the sheath formation during the streamer-surface interaction at atmospheric pressure is presented. A two-dimensional fluid model of a point-to-plane configuration is applied to investigate the evolution of the discharge in the vicinity of cathode plane. The effects of the surfaces on the properties of streamer have been studied for three cases, i.e., conductive surface with secondary electron emission (SEE), conductive surface without SEE, and dielectric surface. In all cases, we found that the axial propagation velocity of the streamer front decreases as the streamer arrives at the boundary of the cathode sheath. And the simulation results showed that the properties of the surface have a significant effect on the streamer. Besides the influences, the secondary emission coefficient and the relative permittivity on the streamer-surface interactions are also studied.

  2. Interaction of surface and bulk acoustic waves with a two-dimensional semimetal

    SciTech Connect

    Kovalev, V. M. Chaplik, A. V.

    2015-02-15

    The interaction of a surface elastic Rayleigh wave with an electron-hole plasma in a two-dimensional semimetal has been theoretically studied as determined by the deformation potential and piezoelectric mechanisms. Dispersion equations describing the coupled plasmon-acoustic modes for both types of interaction are derived, and damping of the Rayleigh wave is calculated. The damping of the acoustic and optical plasmon modes, which is related to the sound emission by plasma oscillations into the substrate volume, is calculated and it is shown that this sound emission is predominantly determined by the acoustic plasmon mode in the case of a deformation potential mechanism and by the optical mode in the case of a piezoelectric mechanism.

  3. Photonic-band-gap effects in two-dimensional polycrystalline and amorphous structures

    SciTech Connect

    Yang, Jin-Kyu; Noh, Heeso; Liew, Seng-Fatt; Schreck, Carl; Guy, Mikhael I.; O'Hern, Corey S.; Cao, Hui

    2010-11-15

    We study numerically the density of optical states (DOS) in two-dimensional photonic structures with short-range positional order and observe a transition from polycrystalline to amorphous photonic systems. In polycrystals, photonic band gaps (PBGs) are formed within individual domains, which leads to a depletion of the DOS similar to that in periodic structures. In amorphous photonic media, the domain sizes are too small to form PBGs, thus the depletion of the DOS is weakened significantly. The critical domain size that separates the polycrystalline and amorphous regimes is determined by the attenuation length of Bragg scattering, which depends not only on the degree of positional order but also the refractive-index contrast of the photonic material. Even with relatively low-refractive-index contrast, we find that modest short-range positional order in photonic structures enhances light confinement via collective scattering and interference.

  4. Antiferromagnetic fluctuations in a quasi-two-dimensional organic superconductor detected by Raman spectroscopy.

    SciTech Connect

    Drichko, Natalia; Hackl, Rudi; Schlueter, John A.

    2015-10-15

    Using Raman scattering, the quasi-two-dimensional organic superconductor kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Br (T-c = 11.8 K) and the related antiferromagnet kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Cl are studied. Raman scattering provides unique spectroscopic information about magnetic degrees of freedom that has been otherwise unavailable on such organic conductors. Below T = 200 K a broad band at about 500 cm(-1) develops in both compounds. We identify this band with two-magnon excitation. The position and the temperature dependence of the spectral weight are similar in the antiferromagnet and in the metallic Fermi liquid. We conclude that antiferromagnetic correlations are similarly present in the magnetic insulator and the Fermi-liquid state of the superconductor.

  5. Two-dimensional nanostructured Y{sub 2}O{sub 3} particles for viscosity modification

    SciTech Connect

    He, Xingliang; Xiao, Huaping; Liang, Hong; Kyle, Jonathan P.; Terrell, Elon J.

    2014-04-21

    Nanoparticle additives have been shown to improve the mechanical and transport phenomena of various liquids; however, little has been done to try and explain the rheological modifications provided from such modifications from a theoretical standpoint. Here, we report a non-Einstein-like reduction of viscosity of mineral oil with the utilization of yttrium oxide nanosheet additives. Experimental results, coupled with generalized smoothed-particle hydrodynamics simulations, provide insight into the mechanism behind this reduction of fluid shear stress. The ordered inclination of these two-dimensional nanoparticle additives markedly improves the lubricating properties of the mineral oil, ultimately reducing the friction, and providing a way in designing and understanding next generation of lubricants.

  6. MEASUREMENT OF GALACTIC LOGARITHMIC SPIRAL ARM PITCH ANGLE USING TWO-DIMENSIONAL FAST FOURIER TRANSFORM DECOMPOSITION

    SciTech Connect

    Davis, Benjamin L.; Berrier, Joel C.; Shields, Douglas W.; Kennefick, Julia; Kennefick, Daniel; Seigar, Marc S.; Lacy, Claud H. S.; Puerari, Ivanio

    2012-04-01

    A logarithmic spiral is a prominent feature appearing in a majority of observed galaxies. This feature has long been associated with the traditional Hubble classification scheme, but historical quotes of pitch angle of spiral galaxies have been almost exclusively qualitative. We have developed a methodology, utilizing two-dimensional fast Fourier transformations of images of spiral galaxies, in order to isolate and measure the pitch angles of their spiral arms. Our technique provides a quantitative way to measure this morphological feature. This will allow comparison of spiral galaxy pitch angle to other galactic parameters and test spiral arm genesis theories. In this work, we detail our image processing and analysis of spiral galaxy images and discuss the robustness of our analysis techniques.

  7. Improvement of the electrical contact resistance at rough interfaces using two dimensional materials

    SciTech Connect

    Hu, Jianchen; Pan, Chengbin; Lanza, Mario; Li, Heng; Shen, Panpan; Sun, Hui; Duan, Huiling

    2015-12-07

    Reducing the electronic contact resistance at the interfaces of nanostructured materials is a major goal for many kinds of planar and three dimensional devices. In this work, we develop a method to enhance the electronic transport at rough interfaces by inserting a two dimensional flexible and conductive graphene sheet. We observe that an ultra-thin graphene layer with a thickness of 0.35 nm can remarkably reduce the roughness of a sample in a factor of 40%, avoiding the use of thick coatings, leading to a more homogeneous current flow, and extraordinarily increasing the total current compared to the graphene-free counterpart. Due to its simplicity and performance enhancement, this methodology can be of interest to many interface and device designers.

  8. Two-dimensional water quality modeling of Town Creek embayment on Guntersville Reservoir

    SciTech Connect

    Bender, M.D.; Shiao, Ming C.; Hauser, G.E. . Engineering Lab.); Butkus, S.R. . Water Quality Dept.)

    1990-09-01

    TVA investigated water quality of Town Creek embayment using a branched two-dimensional model of Guntersville Reservoir. Simulation results were compared in terms of algal biomass, nutrient concentrations, and volume of embayment with depleted dissolved oxygen. Stratification and flushing play a significant role in the embayment water quality. Storms introduce large loadings of organics, nutrients, and suspended solids. Dissolved oxygen depletion is most severe after storms followed by low flow that fails to flush the embayment. Embayment water quality responses to potential animal waste and erosion controls were explored. Modeling indicated animal waste controls were much more cost-effective than erosion controls. Erosion controls will decrease embayment suspended solids and thereby increase algal biomass due to greater light penetration. 29 refs., 16 figs., 4 tabs.

  9. Statistics of particle transport in a two-dimensional dusty plasma cluster

    SciTech Connect

    Ratynskaia, S.; Knapek, C.; Rypdal, K.; Khrapak, S.; Morfill, G.

    2005-02-01

    Statistical analysis is performed on long time series of dust particle trajectories in a two-dimensional dusty plasma cluster. Particle transport is found to be superdiffusive on all time scales until the range of particle displacements approaches the size of the cluster. Analysis of probability distribution functions and rescaled range analysis of the position increments show that the signal is non-Gaussian self-similar with Hurst exponent H=0.6, indicating that the superdiffusion is caused by long-range dependencies in the system. Investigation of temporal and spatial characteristics of persistent particle slips demonstrates that they are associated with collective events present on all time scales and responsible for the non-Gaussianity and long-memory effects.

  10. Quantum Phase Transition in a Two-Dimensional System of Dipoles

    SciTech Connect

    Astrakharchik, G. E.; Boronat, J.; Kurbakov, I. L.; Lozovik, Yu. E.

    2007-02-09

    The ground-state phase diagram of a two-dimensional Bose system with dipole-dipole interactions is studied by means of a quantum Monte Carlo technique. Our calculation predicts a quantum phase transition from a gas to a solid phase when the density increases. In the gas phase, the condensate fraction is calculated as a function of the density. Using the Feynman approximation, the collective excitation branch is studied and the appearance of a roton minimum is observed. The results of the static structure factor at both sides of the gas-solid phase are also presented. The Lindemann ratio at the transition point becomes {gamma}=0.230(6). The condensate fraction in the gas phase is estimated as a function of the density.

  11. Study of vaneless diffuser rotating stall based on two-dimensional inviscid flow analysis

    SciTech Connect

    Tsujimoto, Yoshinobu; Yoshida, Yoshiki [Osaka Univ., Toyonaka, Osaka (Japan); Mori, Yasumasa [Mitsubishi Motors Corp., Ohta, Tokyo (Japan)

    1996-03-01

    Rotating stalls in vaneless diffusers are studied from the viewpoint that they are basically two-dimensional inviscid flow instability under the boundary conditions of vanishing velocity disturbance at the diffuser inlet and of vanishing pressure disturbance at the diffuser outlet. The linear analysis in the present report shows that the critical flow angle and the propagation velocity are functions of only the diffuser radius ratio. It is shown that the present analysis can reproduce most of the general characteristics observed in experiments: critical flow angle, propagation velocity, velocity, and pressure disturbance fields. It is shown that the vanishing velocity disturbance at the diffuser inlet is caused by the nature of impellers as a resistance and an inertial resistance, which is generally strong enough to suppress the velocity disturbance at the diffuser inlet. This explains the general experimental observations that vaneless diffuser rotating stalls are not largely affected by the impeller.

  12. Epitaxial two-dimensional nitrogen atomic sheet in GaAs

    SciTech Connect

    Harada, Yukihiro Yamamoto, Masuki; Baba, Takeshi; Kita, Takashi

    2014-01-27

    We have grown an epitaxial two-dimensional nitrogen (N) atomic sheet in GaAs by using the site-controlled N δ-doping technique. We observed a change of the electronic states in N δ-doped GaAs from the isolated impurity centers to the delocalized impurity band at 1.49 eV with increasing N-doping density. According to the excitation-power- and temperature-dependent photoluminescence (PL) spectra, the emission related to localized levels below the impurity band edge was dominant at low excitation power and temperature, whereas the effects of the localized levels can be neglected by increasing the excitation power and temperature. Furthermore, a clear Landau shift of the PL-peak energy was observed at several Tesla in the Faraday configuration, in contrast to the case in the impurity limit.

  13. Lifshitz transitions and crystallization of fully polarized dipolar fermions in an anisotropic two-dimensional lattice

    SciTech Connect

    Carr, Sam T.; Quintanilla, Jorge; Betouras, Joseph J.

    2010-07-15

    We consider a two-dimensional model of noninteracting chains of spinless fermions weakly coupled via a small interchain hopping and a repulsive interchain interaction. The phase diagram of this model has a surprising feature: an abrupt change in the Fermi surface as the interaction is increased. We study in detail this metanematic transition and show that the well-known 2(1/2)-order Lifshitz transition is the critical end point of this first-order quantum phase transition. Furthermore, in the vicinity of the end point, the order parameter has a nonperturbative BCS-type form. We also study a competing crystallization transition in this model and derive the full phase diagram. This physics can be demonstrated experimentally in dipolar ultracold atomic or molecular gases. In the presence of a harmonic trap, it manifests itself as a sharp jump in the density profile.

  14. Collision-dependent power law scalings in two dimensional gyrokinetic turbulence

    SciTech Connect

    Cerri, S. S. Ban Navarro, A.; Told, D.; Jenko, F.

    2014-08-15

    Nonlinear gyrokinetics provides a suitable framework to describe short-wavelength turbulence in magnetized laboratory and astrophysical plasmas. In the electrostatic limit, this system is known to exhibit a free energy cascade towards small scales in (perpendicular) real and/or velocity space. The dissipation of free energy is always due to collisions (no matter how weak the collisionality), but may be spread out across a wide range of scales. Here, we focus on freely decaying two dimensional electrostatic turbulence on sub-ion-gyroradius scales. An existing scaling theory for the turbulent cascade in the weakly collisional limit is generalized to the moderately collisional regime. In this context, non-universal power law scalings due to multiscale dissipation are predicted, and this prediction is confirmed by means of direct numerical simulations.

  15. Dielectric response of metal/SrTiO{sub 3}/two-dimensional electron liquid heterostructures

    SciTech Connect

    Mikheev, Evgeny; Raghavan, Santosh; Stemmer, Susanne

    2015-08-17

    Maximizing the effective dielectric constant of the gate dielectric stack is important for electrostatically controlling high carrier densities inherent to strongly correlated materials. SrTiO{sub 3} is uniquely suited for this purpose, given its extremely high dielectric constant, which can reach 10{sup 4}. Here, we present a systematic study of the thickness dependence of the dielectric response and leakage of SrTiO{sub 3} that is incorporated into a vertical structure on a high-carrier-density two-dimensional electron liquid (2DEL). A simple model can be used to interpret the data. The results show a need for improved interface control in the design of metal/SrTiO{sub 3}/2DEL devices.

  16. Anisotropy of stress correlation in two-dimensional liquids and a pseudospin model

    SciTech Connect

    Wu, Bin; Iwashita, Takuya; Egami, Takeshi

    2015-11-04

    Liquids are condensed matter in which atoms are strongly correlated in position and momentum. The atomic pair density function (PDF) is used often in describing such correlation. However, elucidation of many properties requires higher degrees of correlation than the pair correlation. For instance, viscosity depends upon the stress correlations in space and time. We examine the cross correlation between the stress correlation at the atomic level and the PDF for two-dimensional liquids. We introduce the concept of the stress-resolved pair distribution function (SRPDF) that uses the sign of atomic-level stress as a selection rule to include particles from density correlations. The connection between SRPDFs and stress correlation function is explained through an approximation in which the shear stress is replaced by a pseudospin. Lastly, we further assess the possibility of interpreting the long-range stress correlation as a consequence of short-range Ising-like pseudospin interactions.

  17. Anisotropy of stress correlation in two-dimensional liquids and a pseudospin model

    DOE PAGES [OSTI]

    Wu, Bin; Iwashita, Takuya; Egami, Takeshi

    2015-11-04

    Liquids are condensed matter in which atoms are strongly correlated in position and momentum. The atomic pair density function (PDF) is used often in describing such correlation. However, elucidation of many properties requires higher degrees of correlation than the pair correlation. For instance, viscosity depends upon the stress correlations in space and time. We examine the cross correlation between the stress correlation at the atomic level and the PDF for two-dimensional liquids. We introduce the concept of the stress-resolved pair distribution function (SRPDF) that uses the sign of atomic-level stress as a selection rule to include particles from density correlations.more » The connection between SRPDFs and stress correlation function is explained through an approximation in which the shear stress is replaced by a pseudospin. Lastly, we further assess the possibility of interpreting the long-range stress correlation as a consequence of short-range Ising-like pseudospin interactions.« less

  18. Two-dimensional model of direct solar slab-on-grade heating floor

    SciTech Connect

    Youcef, L. )

    1991-01-01

    The altering direction implicit (ADI) method is used to solve the two-dimensional heat equation applied to the system described in this paper. The coupling equations between flat-plate collectors, heating floor and ground had been developed. The model also takes into account the solar flux falling on the floor through the south oriented glazed wall. The theoretical results were compared to the experimental data performed in Bassens (southwest of France) during the period of September 1981 to May 1982. It was shown that the model outputs were in good agreement with the measured data. However, some doubts are considered concerning lower boundary conditions. Also is given a simple technique to evaluate the most appropriate initial conditions to drive the computational program developed here. Finally a study of some main parameters was carried out.

  19. A TWO-DIMENSIONAL INFRARED MAP OF THE EXTRASOLAR PLANET HD 189733b

    SciTech Connect

    Majeau, Carl; Agol, Eric; Cowan, Nicolas B.

    2012-03-10

    We derive the first secondary eclipse map of an exoplanet, HD 189733b, based on Spitzer IRAC 8 {mu}m data. We develop two complementary techniques for deriving the two-dimensional planet intensity: regularized slice mapping and spherical harmonic mapping. Both techniques give similar derived intensity maps for the infrared dayside flux of the planet, while the spherical harmonic method can be extended to include phase variation data which better constrain the map. The longitudinal offset of the dayside hot spot is consistent with that found in prior studies, strengthening the claim of super-rotating winds, and eliminating the possibility of phase variations being caused by stellar variability. The latitude of the hot spot is within 12.{sup 0}5 (68% confidence) of the planet's equator, confirming the predictions of general circulation models for hot Jupiters and indicative of a small planet obliquity.

  20. Device for two-dimensional gas-phase separation and characterization of ion mixtures

    SciTech Connect

    Tang, Keqi; Shvartsburg, Alexandre A.; Smith, Richard D.

    2006-12-12

    The present invention relates to a device for separation and characterization of gas-phase ions. The device incorporates an ion source, a field asymmetric waveform ion mobility spectrometry (FAIMS) analyzer, an ion mobility spectrometry (IMS) drift tube, and an ion detector. In one aspect of the invention, FAIMS operating voltages are electrically floated on top of the IMS drift voltage. In the other aspect, the FAIMS/IMS interface is implemented employing an electrodynamic ion funnel, including in particular an hourglass ion funnel. The present invention improves the efficiency (peak capacity) and sensitivity of gas-phase separations; the online FAIMS/IMS coupling creates a fundamentally novel two-dimensional gas-phase separation technology with high peak capacity, specificity, and exceptional throughput.

  1. Two-dimensional positive column structure in a discharge tube with radius discontinuity

    SciTech Connect

    Zobnin, A. V. Usachev, A. D.; Petrov, O. F.; Fortov, V. E.

    2014-11-15

    The low-pressure (40 and 90?Pa) low-current (4 and 10?mA) direct current discharge in a tube with a sharp change of its radius is studied both numerically and experimentally. A fully self-consistent hybrid numerical model of a two-dimensional non-uniform positive column in neon is developed using a nonlocal approach. The model combines kinetic simulation of the electrons (under two-terms approach) and fluid description of the neon ions and permits to calculate the distribution of all plasma parameters in the direct current discharges in the cameras with cylindrical geometry and radius discontinuity. The simulation results are compared with the measured 585.3?nm neon spectral line absolute intensities and excited 1s{sub 3} metastable neon atom number densities. Non-local electron kinetics in the transition region and formation of standing strata are discussed.

  2. Resonant second harmonic generation in a gallium nitride two-dimensional photonic crystal on silicon

    SciTech Connect

    Zeng, Y.; Roland, I.; Checoury, X.; Han, Z.; El Kurdi, M.; Sauvage, S.; Boucaud, P.; Gayral, B.; Brimont, C.; Guillet, T.; Mexis, M.; Semond, F.

    2015-02-23

    We demonstrate second harmonic generation in a gallium nitride photonic crystal cavity embedded in a two-dimensional free-standing photonic crystal platform on silicon. The photonic crystal nanocavity is optically pumped with a continuous-wave laser at telecom wavelengths in the transparency window of the nitride material. The harmonic generation is evidenced by the spectral range of the emitted signal, the quadratic power dependence vs. input power, and the spectral dependence of second harmonic signal. The harmonic emission pattern is correlated to the harmonic polarization generated by the second-order nonlinear susceptibilities χ{sub zxx}{sup (2)}, χ{sub zyy}{sup (2)} and the electric fields of the fundamental cavity mode.

  3. Fuel-air mixing and combustion in a two-dimensional Wankel engine

    SciTech Connect

    Shih, T.I.P.; Schock, H.J.; Ramos, J.I.

    1987-01-01

    The effects of mixture stratification at the intake port and gaseous fuel injection on the flow field and fuel-air mixing in a two-dimensional rotary engine model have been investigated by means of a two-equation model of turbulence, an algebraic grid generation method and an approximate factorization time-linearized numerical technique. It is shown that the fuel distribution in the combustion chamber is a function of the air-fuel mixture fluctuations at the intake port. The fuel is advected by the flow field induced by the rotor and is concentrated near the leading apex during the intake stroke. During compression, the fuel concentration is highest near the trailing apex and lowest near the rotor. The penetration of gaseous fuel injected into the combustion chamber during the compression stroke increases with the injection velocity.

  4. Conical wave propagation and diffraction in two-dimensional hexagonally packed granular lattices

    DOE PAGES [OSTI]

    Chong, C.; Kevrekidis, P. G.; Ablowitz, M. J.; Ma, Yi-Ping

    2016-01-25

    We explore linear and nonlinear mechanisms for conical wave propagation in two-dimensional lattices in the realm of phononic crystals. As a prototypical example, a statically compressed granular lattice of spherical particles arranged in a hexagonal packing configuration is analyzed. Upon identifying the dispersion relation of the underlying linear problem, the resulting diffraction properties are considered. Analysis both via a heuristic argument for the linear propagation of a wave packet and via asymptotic analysis leading to the derivation of a Dirac system suggests the occurrence of conical diffraction. This analysis is valid for strong precompression, i.e., near the linear regime. Formore » weak precompression, conical wave propagation is still possible, but the resulting expanding circular wave front is of a nonoscillatory nature, resulting from the complex interplay among the discreteness, nonlinearity, and geometry of the packing. Lastly, the transition between these two types of propagation is explored.« less

  5. Spectral evolution of two-dimensional kinetic plasma turbulence in the wavenumber-frequency domain

    SciTech Connect

    Comişel, H.; Verscharen, D.; Narita, Y.; Motschmann, U.

    2013-09-15

    We present a method for studying the evolution of plasma turbulence by tracking dispersion relations in the energy spectrum in the wavenumber-frequency domain. We apply hybrid plasma simulations in a simplified two-dimensional geometry to demonstrate our method and its applicability to plasma turbulence in the ion kinetic regime. We identify four dispersion relations: ion-Bernstein waves, oblique whistler waves, oblique Alfvén/ion-cyclotron waves, and a zero-frequency mode. The energy partition and frequency broadening are evaluated for these modes. The method allows us to determine the evolution of decaying plasma turbulence in our restricted geometry and shows that it cascades along the dispersion relations during the early phase with an increasing broadening around the dispersion relations.

  6. Two-dimensional cylindrical ion-acoustic solitary and rogue waves in ultrarelativistic plasmas

    SciTech Connect

    Ata-ur-Rahman; National Centre for Physics at QAU Campus, Shahdrah Valley Road, Islamabad 44000 ; Ali, S.; Moslem, W. M.; Mushtaq, A.; Department of Physics, Abdul Wali Khan University, Mardan 23200

    2013-07-15

    The propagation of ion-acoustic (IA) solitary and rogue waves is investigated in a two-dimensional ultrarelativistic degenerate warm dense plasma. By using the reductive perturbation technique, the cylindrical KadomtsevPetviashvili (KP) equation is derived, which can be further transformed into a Kortewegde Vries (KdV) equation. The latter admits a solitary wave solution. However, when the frequency of the carrier wave is much smaller than the ion plasma frequency, the KdV equation can be transferred to a nonlinear Schrdinger equation to study the nonlinear evolution of modulationally unstable modified IA wavepackets. The propagation characteristics of the IA solitary and rogue waves are strongly influenced by the variation of different plasma parameters in an ultrarelativistic degenerate dense plasma. The present results might be helpful to understand the nonlinear electrostatic excitations in astrophysical degenerate dense plasmas.

  7. Electrophoretic extraction of proteins from two-dimensional electrophoresis gel spots

    DOEpatents

    Zhang, Jian-Shi; Giometti, Carol S.; Tollaksen, Sandra L.

    1989-01-01

    After two-dimensional electrophoresis of proteins or the like, resulting in a polyacrylamide gel slab having a pattern of protein gel spots thereon, an individual protein gel spot is cored out from the slab, to form a gel spot core which is placed in an extraction tube, with a dialysis membrane across the lower end of the tube. Replicate gel spots can be cored out from replicate gel slabs and placed in the extraction tube. Molten agarose gel is poured into the extraction tube where the agarose gel hardens to form an immobilizing gel, covering the gel spot cores. The upper end portion of the extraction tube is filled with a volume of buffer solution, and the upper end is closed by another dialysis membrane. Upper and lower bodies of a buffer solution are brought into contact with the upper and lower membranes and are provided with electrodes connected to the positive and negative terminals of a DC power supply, thereby producing an electrical current which flows through the upper membrane, the volume of buffer solution, the agarose, the gel spot cores and the lower membrane. The current causes the proteins to be extracted electrophoretically from the gel spot cores, so that the extracted proteins accumulate and are contained in the space between the agarose gel and the upper membrane. A high percentage extraction of proteins is achieved. The extracted proteins can be removed and subjected to partial digestion by trypsin or the like, followed by two-dimensional electrophoresis, resulting in a gel slab having a pattern of peptide gel spots which can be cored out and subjected to electrophoretic extraction to extract individual peptides.

  8. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    SciTech Connect

    Sharpes, Nathan; Abdelkefi, Abdessattar; Priya, Shashank

    2015-08-31

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm{sup 2} area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  9. Development and validation of a two-dimensional fast-response flood estimation model

    SciTech Connect

    Judi, David R; Mcpherson, Timothy N; Burian, Steven J

    2009-01-01

    A finite difference formulation of the shallow water equations using an upwind differencing method was developed maintaining computational efficiency and accuracy such that it can be used as a fast-response flood estimation tool. The model was validated using both laboratory controlled experiments and an actual dam breach. Through the laboratory experiments, the model was shown to give good estimations of depth and velocity when compared to the measured data, as well as when compared to a more complex two-dimensional model. Additionally, the model was compared to high water mark data obtained from the failure of the Taum Sauk dam. The simulated inundation extent agreed well with the observed extent, with the most notable differences resulting from the inability to model sediment transport. The results of these validation studies complex two-dimensional model. Additionally, the model was compared to high water mark data obtained from the failure of the Taum Sauk dam. The simulated inundation extent agreed well with the observed extent, with the most notable differences resulting from the inability to model sediment transport. The results of these validation studies show that a relatively numerical scheme used to solve the complete shallow water equations can be used to accurately estimate flood inundation. Future work will focus on further reducing the computation time needed to provide flood inundation estimates for fast-response analyses. This will be accomplished through the efficient use of multi-core, multi-processor computers coupled with an efficient domain-tracking algorithm, as well as an understanding of the impacts of grid resolution on model results.

  10. Parallel stitching of 2D materials

    DOE PAGES [OSTI]

    Ling, Xi; Wu, Lijun; Lin, Yuxuan; Ma, Qiong; Wang, Ziqiang; Song, Yi; Yu, Lili; Huang, Shengxi; Fang, Wenjing; Zhang, Xu; et al

    2016-01-27

    Diverse parallel stitched 2D heterostructures, including metal–semiconductor, semiconductor–semiconductor, and insulator–semiconductor, are synthesized directly through selective “sowing” of aromatic molecules as the seeds in the chemical vapor deposition (CVD) method. Lastly, the methodology enables the large-scale fabrication of lateral heterostructures, which offers tremendous potential for its application in integrated circuits.

  11. Retrospective analysis of 2D patient-specific IMRT verifications

    SciTech Connect

    Childress, Nathan L.; White, R. Allen; Bloch, Charles; Salehpour, Mohammad; Dong, Lei; Rosen, Isaac I.

    2005-04-01

    We performed 858 two-dimensional (2D) patient-specific intensity modulated radiotherapy verifications over a period of 18 months. Multifield, composite treatment plans were measured in phantom using calibrated Kodak EDR2 film and compared with the calculated dose extracted from two treatment planning systems. This research summarizes our findings using the normalized agreement test (NAT) index and the percent of pixels failing the gamma index as metrics to represent the agreement between measured and computed dose distributions. An in-house dose comparison software package was used to register and compare all verifications. We found it was important to use an automatic positioning algorithm to achieve maximum registration accuracy, and that our automatic algorithm agreed well with anticipated results from known phantom geometries. We also measured absolute dose for each case using an ion chamber. Because the computed distributions agreed with ion chamber measurements better than the EDR2 film doses, we normalized EDR2 data to the computed distributions. The distributions of both the NAT indices and the percentage of pixels failing the gamma index were found to be exponential distributions. We continue to use both the NAT index and percent of pixels failing gamma with 5%/3 mm criteria to evaluate future verifications, as these two metrics were found to be complementary. Our data showed that using 2%/2 mm or 3%/3 mm criteria produces results similar to those using 5%/3 mm criteria. Normalized comparisons that have a NAT index greater than 45 and/or more than 20% of the pixels failing gamma for 5%/3 mm criteria represent outliers from our clinical data set and require further analysis. Because our QA verification results were exponentially distributed, rather than a tight grouping of similar results, we continue to perform patient-specific QA in order to identify and correct outliers in our verifications. The data from this work could be useful as a reference for

  12. Two-dimensional double layer in plasma in a diverging magnetic field

    SciTech Connect

    Saha, S. K.; Raychaudhuri, S.; Chowdhury, S.; Janaki, M. S.; Hui, A. K.

    2012-09-15

    Plasma created by an inductive RF discharge is allowed to expand along a diverging magnetic field. Measurement of the axial plasma potential profile reveals the formation of an electric double layer near the throat of the expansion chamber. An accelerated ion beam has been detected in the downstream region, confirming the presence of the double layer. The 2-D nature of the ion energy distribution function of the downstream plasma has been studied by a movable ion energy analyser, which shows that the beam radius increases along the axial distance. The 2-D structure of the plasma potential has been studied by a movable emissive probe. The existence of a secondary lobe in the contour plot of plasma equipotential is a new observation. It is also an interesting observation that the most diverging magnetic field line not intercepting the junction of the discharge tube and the expansion chamber has an electric field aligned with it.

  13. Spin eigen-states of Dirac equation for quasi-two-dimensional electrons

    SciTech Connect

    Eremko, Alexander; Brizhik, Larissa; Loktev, Vadim

    2015-10-15

    Dirac equation for electrons in a potential created by quantum well is solved and the three sets of the eigen-functions are obtained. In each set the wavefunction is at the same time the eigen-function of one of the three spin operators, which do not commute with each other, but do commute with the Dirac Hamiltonian. This means that the eigen-functions of Dirac equation describe three independent spin eigen-states. The energy spectrum of electrons confined by the rectangular quantum well is calculated for each of these spin states at the values of energies relevant for solid state physics. It is shown that the standard Rashba spin splitting takes place in one of such states only. In another one, 2D electron subbands remain spin degenerate, and for the third one the spin splitting is anisotropic for different directions of 2D wave vector.

  14. Testable Signatures of Quantum Nonlocality in a Two-Dimensional Chiral p-Wave Superconductor

    SciTech Connect

    Tewari, Sumanta; Zhang Chuanwei; Das Sarma, S.; Nayak, Chetan; Lee, Dung-Hai

    2008-01-18

    A class of topological excitations--the odd-winding number vortices--in a spinless 2D chiral p-wave (p{sub x}+ip{sub y}) superconductor traps Majorana fermion states in the vortex cores. For a dilute gas of such vortices, the lowest energy fermionic eigenstates are intrinsically nonlocal. We predict two testable signatures of this unusual quantum nonlocality in quasiparticle tunneling experiments. We discuss why the associated teleportationlike phenomenon does not imply the violation of causality.

  15. Two-dimensional inverse planning and delivery with a preclinical image guided microirradiator

    SciTech Connect

    Stewart, James M. P.; Lindsay, Patricia E.; Jaffray, David A.; Radiation Medicine Program, Princess Margaret Cancer Centre, University Health Network, Toronto, Ontario M5G 2M9; Department of Radiation Oncology, Faculty of Medicine, University of Toronto, Toronto, Ontario M5S 3E2; Department of Medical Biophysics, University of Toronto, Toronto, Ontario M5G 2M9; The Techna Institute for the Advancement of Technology for Health, Toronto, Ontario M5G 1P5

    2013-10-15

    Purpose: Recent advances in preclinical radiotherapy systems have provided the foundation for scaling many of the elements of clinical radiation therapy practice to the dimensions and energy demanded in small animal studies. Such systems support the technical capabilities to accurately deliver highly complex dose distributions, but methods to optimize and deliver such distributions remain in their infancy. This study developed an optimization method based on empirically measured two-dimensional dose kernel measurements to deliver arbitrary planar dose distributions on a recently developed small animal radiotherapy platform.Methods: A two-dimensional dose kernel was measured with repeated radiochromic film measurements for the circular 1 mm diameter fixed collimator of the small animal radiotherapy system at 1 cm depth in a solid water phantom. This kernel was utilized in a sequential quadratic programming optimization framework to determine optimal beam positions and weights to deliver an arbitrary desired dose distribution. The positions and weights were then translated to a set of stage motions to automatically deliver the optimized dose distribution. End-to-end efficacy of the framework was quantified through five repeated deliveries of two dosimetric challenges: (1) a 5 mm radius bullseye distribution, and (2) a sock distribution contained within a 9 13 mm bounding box incorporating rectangular, semicircular, and exponentially decaying geometric constructs and a rectangular linear dose gradient region. These two challenges were designed to gauge targeting, geometric, and dosimetric fidelity.Results: Optimization of the bullseye and sock distributions required 2.1 and 5.9 min and utilized 50 and 77 individual beams for delivery, respectively. Automated delivery of the resulting optimized distributions, validated using radiochromic film measurements, revealed an average targeting accuracy of 0.32 mm, and a dosimetric delivery error along four line profiles

  16. Hydrothermal synthesis and characterization of a two-dimensional piperazinium cobalt–zinc phosphate via a metastable one-dimensional phase

    SciTech Connect

    Torre-Fernández, Laura; Khainakova, Olena A.; Espina, Aránzazu; Amghouz, Zakariae; Khainakov, Sergei A.; Alfonso, Belén F.; Blanco, Jesús A.; García, José R.; García-Granda, Santiago

    2015-05-15

    A two-dimensional piperazinium cobalt–zinc phosphate, formulated as (C{sub 4}N{sub 2}H{sub 12}){sub 1.5}(Co{sub 0.6}Zn{sub 0.4}){sub 2}(HPO{sub 4}){sub 2}(PO{sub 4})·H{sub 2}O (2D), was synthesized under hydrothermal conditions. The crystal structure was determined using single-crystal X-ray diffraction data (monoclinic P2{sub 1}/c, a=8.1165(3) Å, b=26.2301(10) Å, c=8.3595(4) Å, and β=110.930(5)°) and the hydrogen atom positions were optimized by DFT calculations. A single-crystal corresponding to one-dimensional metastable phase, (C{sub 4}N{sub 2}H{sub 12})Co{sub 0.3}Zn{sub 0.7}(HPO{sub 4}){sub 2}·H{sub 2}O (1D), was also isolated and the crystal structure was determined (monoclinic P2{sub 1}/c, a=8.9120(6) Å, b=14.0290(1) Å, c=12.2494(5) Å, and β=130.884(6)°). The bulk was characterized by chemical (C–H–N) analysis, powder X-ray diffraction (PXRD), powder X-ray thermodiffractometry (HT-XRD), transmission electron microscopy (STEM(DF)-EDX and EFTEM), and thermal analysis (TG/SDTA-MS), including activation energy data of its thermal decomposition. The magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Graphical abstract: Hydrothermal synthesis and structural characterization of a two-dimensional piperazinium cobalt–zinc phosphate, (C{sub 4}N{sub 2}H{sub 12}){sub 1.5}(Co{sub 0.6}Zn{sub 0.4}){sub 2}(HPO{sub 4}){sub 2}(PO{sub 4})·H{sub 2}O (2D), have been reported. The crystal structure of a one-dimensional piperazinium cobalt–zinc phosphate, (C{sub 4}N{sub 2}H{sub 12})Co{sub 0.3}Zn{sub 0.7}(HPO{sub 4}){sub 2}·H{sub 2}O (1D) a metastable phase during the hydrothermal synthesis, was also determined. The thermal behavior of 2D compound is strongly dependent on the selected heating rate and the magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Highlights: • A 2D piperazinium cobalt–zinc phosphate has been synthesized and characterized. • Crystal

  17. Stochastic Inversion of 2D Magnetotelluric Data

    Energy Science and Technology Software Center

    2010-07-01

    The algorithm is developed to invert 2D magnetotelluric (MT) data based on sharp boundary parametrization using a Bayesian framework. Within the algorithm, we consider the locations and the resistivity of regions formed by the interfaces are as unknowns. We use a parallel, adaptive finite-element algorithm to forward simulate frequency-domain MT responses of 2D conductivity structure. Those unknown parameters are spatially correlated and are described by a geostatistical model. The joint posterior probability distribution function ismore » explored by Markov Chain Monte Carlo (MCMC) sampling methods. The developed stochastic model is effective for estimating the interface locations and resistivity. Most importantly, it provides details uncertainty information on each unknown parameter. Hardware requirements: PC, Supercomputer, Multi-platform, Workstation; Software requirements C and Fortan; Operation Systems/version is Linux/Unix or Windows« less

  18. Towards enhancing two-dimensional electron gas quantum confinement effects in perovskite oxide heterostructures

    SciTech Connect

    Nazir, Safdar; Behtash, Maziar; Yang, Kesong

    2015-03-21

    We explore the possibility of achieving highly confined two-dimensional electron gas (2DEG) within one single atomic layer through a comprehensive comparison study on three prototypical perovskite heterostructures, LaAlO{sub 3}/ATiO{sub 3} (A = Ca, Sr, and Ba), using first-principles electronic structure calculations. We predict that the heterostructure LaAlO{sub 3}/BaTiO{sub 3} has a highly confined 2DEG within a single atomic layer of the substrate BaTiO{sub 3}, and exhibits relatively higher interfacial charge carrier density and larger magnetic moments than the well-known LaAlO{sub 3}/SrTiO{sub 3} system. The long Ti-O bond length in the ab-plane of the LaAlO{sub 3}/BaTiO{sub 3} heterostructure is responsible for the superior charge confinement. We propose BaTiO{sub 3} as an exceptional substrate material for 2DEG systems with potentially superior properties.

  19. Elucidation of reactive wavepackets by two-dimensional resonance Raman spectroscopy

    SciTech Connect

    Guo, Zhenkun; Molesky, Brian P.; Cheshire, Thomas P.; Moran, Andrew M.

    2015-09-28

    Traditional second-order kinetic theories fail to describe sub-picosecond photochemical reactions when solvation and vibrational dephasing undermine the assumption of equilibrium initial conditions. Four-wave mixing spectroscopies may reveal insights into such non-equilibrium processes but are limited by the single “population time” available in these types of experiments. Here, we use two-dimensional resonance Raman (2DRR) spectroscopy to expose correlations between coherent nuclear motions of the reactant and product in the photodissociation reaction of triiodide. It is shown that the transition of a nuclear wavepacket from the reactant (triiodide) to product (diiodide) states gives rise to a unique pattern of 2DRR resonances. Peaks associated with this coherent reaction mechanism are readily assigned, because they are isolated in particular quadrants of the 2DRR spectrum. A theoretical model in which the chemical reaction is treated as a vibronic coherence transfer transition from triiodide to diiodide reproduces the patterns of 2DRR resonances detected in experiments. These signal components reveal correlation between the nonequilibrium geometry of triiodide and the vibrational coherence frequency of diiodide. The 2DRR signatures of coherent reaction mechanisms established in this work may generalize to studies of ultrafast energy and charge transfer processes.

  20. Natural abundance 17O DNP two-dimensional and surface-enhanced NMR spectroscopy

    DOE PAGES [OSTI]

    Perras, Frédéric A.; Kobayashi, Takeshi; Pruski, Marek

    2015-06-22

    Due to its extremely low natural abundance and quadrupolar nature, the 17O nuclide is very rarely used for spectroscopic investigation of solids by NMR without isotope enrichment. Additionally, the applicability of dynamic nuclear polarization (DNP), which leads to sensitivity enhancements of 2 orders of magnitude, to 17O is wrought with challenges due to the lack of spin diffusion and low polarization transfer efficiency from 1H. Here, we demonstrate new DNP-based measurements that extend 17O solid-state NMR beyond its current capabilities. The use of the PRESTO technique instead of conventional 1H–17O cross-polarization greatly improves the sensitivity and enables the facile measurementmore » of undistorted line shapes and two-dimensional 1H–17O HETCOR NMR spectra as well as accurate internuclear distance measurements at natural abundance. This was applied for distinguishing hydrogen-bonded and lone 17O sites on the surface of silica gel; the one-dimensional spectrum of which could not be used to extract such detail. As a result, this greatly enhanced sensitivity has enabled, for the first time, the detection of surface hydroxyl sites on mesoporous silica at natural abundance, thereby extending the concept of DNP surface-enhanced NMR spectroscopy to the 17O nuclide.« less

  1. A two-dimensional regional basin model of Williston basin hydrocarbon systems

    SciTech Connect

    Burrus, J.; Wolf, S.; Doligez, B.

    1996-02-01

    Institut Francais du Petrole`s two-dimensional model, TEMISPACK, is used to discuss the functioning of petroleum systems in the Williston basin along a 330-km-long section, focusing on four regional source intervals: Ordovician Yeoman formation, Lower Devonian Winnipegosis Formation, Upper Devonian-Lower Mississippian Bakken Formation, and Mississippian Lodgepole formation. Thermal history calibration against present temperature and source rock maturity profiles suggests that the Williston basin can be divided into a region of constant heat flow of about 55 mW/m{sup 2} away from the Nesson anticline, and a region of higher heat flow and enhanced thermal maturity in the vicinity of the Nesson anticline. Original kinetic parameters used in the calibration were derived for each of the four source rocks from Rock-Eval yield curves. Bakken overpressures are entirely due to oil generation, not compaction disequilibrium. Very low Bakken vertical permeabilities range from 0.01 to 0.001 and are matched against observed overpressures, whereas Bakken porosities based on the model and confirmed by measurements are inferred to be also unusually low, around 3%.

  2. Design, testing and two-dimensional flow modeling of a multiple-disk fan

    SciTech Connect

    Engin, Tahsin; Oezdemir, Mustafa; Cesmeci, Sevki

    2009-11-15

    A multiple-disk Tesla type fan has been designed, tested and analyzed two-dimensionally using the conservation of angular momentum principle. Experimental results showed that such multiple-disk fans exhibited exceptionally low performance characteristics, which could be attributed to the low viscosity, tangential nature of the flow, and large mechanical energy losses at both suction and discharge sections that are comparable to the total input power. By means of theoretical analysis, local and overall shearing stresses on the disk surfaces have been determined based on tangential and radial velocity distributions of the air flow of different volume flow rates at prescribed disk spaces and rotational speeds. Then the total power transmitted by rotating disks to air flow, and the power acquired by the air flow in the gap due to transfer of angular momentum have been obtained by numerically integrating shearing stresses over the disk surfaces. Using the measured shaft and hydraulic powers, these quantities were utilized to evaluate mechanical energy losses associated with the suction and discharge sections of the fan. (author)

  3. A two-dimensional multispecies fluid model of the plasma in an ac plasma display panel

    SciTech Connect

    Campbell, R.B.; Veerasingam, R.; McGrath, R.T.

    1995-08-01

    A time dependent, two-dimensional mode for simulating the plasma evolution in an AC plasma display panel (AC-PDP) is described. Reaction-convection (mobility)-diffusion equations for charged particles and excited heavy neutral species are solved along with Poisson`s equation, a radiation transport equation, a surface charge buildup equation, and an external L-R-C circuit equation using a fully implicit numerical method. Electron-driven rate coefficients are computed with a 0-D Boltzmann solver in the local field approximation. For studying the particle dynamics in pure helium, they consider a reduced model in which radiation transport is ignored and the excited species manifold is collapsed to composite metastable and excited states. The model predictions of breakdown voltage are quite sensitive to the value of the secondary electron emission coefficient assumed and the uncertainties in the electron-driven reaction rates. An initial comparison between the model predictions and I-V measurements from a specially constructed helium-filled panel is made with qualitatively similar behavior. The lack of quantitative agreement can be explained by a combination of uncertainties in the model input data and uncertainty in the initial surface charge state in the experiments.

  4. Apparatus for reading two-dimensional electrophoretograms containing. beta. -ray-emitting labeled compounds

    DOEpatents

    Anderson, H.L.; Kinnison, W.W.; Lillberg, J.W.

    1985-04-30

    An apparatus and method for electronically reading planar two-dimensional ..beta..-ray emitter-labeled gel electrophoretograms. A single, flat rectangular multiwire proportional chamber is placed in close proximity to the gel and the assembly placed in an intense uniform magnetic field disposed in a perpendicular manner to the rectangular face of the proportional chamber. Beta rays emitted in the direction of the proportional chamber are caused to execute helical motions which substantially preserve knowledge the coordinates of their origin in the gel. Perpendicularly oriented, parallel wire, parallel plane cathodes electronically sense the location of the ..beta..-rays from ionization generated thereby in a detection gas coupled with an electron avalanche effect resulting from the action of a parallel wire anode located therebetween. A scintillator permits the present apparatus to be rendered insensitive when signals are generated from cosmic rays incident on the proportional chamber. Resolution for concentrations of radioactive compounds in the gel exceeds 700-..mu..m. The apparatus and method of the present invention represent a significant improvement over conventional autoradiographic techniques in dynamic range, linearity and sensitivity of data collection. A concentration and position map for gel electrophoretograms having significant concentrations of labeled compounds and/or highly radioactive labeling nuclides can generally be obtained in less than one hour.

  5. Apparatus and method for reading two-dimensional electrophoretograms containing .beta.-ray-emitting labeled compounds

    DOEpatents

    Anderson, Herbert L.; Kinnison, W. Wayne; Lillberg, John W.

    1987-01-01

    Apparatus and method for electronically reading planar two dimensional .beta.-ray emitter-labeled gel electrophoretograms. A single, flat rectangular multiwire proportional chamber is placed in close proximity to the gel and the assembly placed in an intense uniform magnetic field disposed in a perpendicular manner to the rectangular face of the proportional chamber. Beta rays emitted in the direction of the proportional chamber are caused to execute helical motions which substantially preserve knowledge of the coordinates of their origin in the gel. Perpendicularly oriented, parallel wire, parallel plane cathodes electronically sense the location of the .beta.-rays from ionization generated thereby in a detection gas coupled with an electron avalanche effect resulting from the action of a parallel wire anode located therebetween. A scintillator permits the present apparatus to be rendered insensitive when signals are generated from cosmic rays incident on the proportional chamber. Resolution for concentrations of radioactive compounds in the gel exceeds 700 .mu.m. The apparatus and method of the present invention represent a significant improvement over conventional autoradiographic techniques in dynamic range, linearity and sensitivity of data collection. A concentration and position map for gel electrophoretograms having significant concentrations of labeled compounds and/or highly radioactive labeling nuclides can generally be obtained in less than one hour.

  6. Method for laser-based two-dimensional navigation system in a structured environment

    DOEpatents

    Boultinghouse, Karlan D.; Schoeneman, J. Lee; Tise, Bertice L.

    1989-01-01

    A low power, narrow laser beam, generated by a laser carried by a mobile vehicle, is rotated about a vertical reference axis as the vehicle navigates within a structured environment. At least three stationary retroreflector elements are located at known positions, preferably at the periphery of the structured environment, with one of the elements having a distinctive retroreflection. The projected rotating beam traverses each retroreflector in succession, and the corresponding retroreflections are received at the vehicle and focussed on a photoelectric cell to generate corresponding electrical signals. The signal caused by the distinctive retroreflection serves as an angle-measurement datum. An angle encoder coupled to the apparatus rotating the projected laser beam provides the angular separation from this datum of the lines connecting the mobile reference axis to successive retroreflectors. This real-time angular data is utilized with the known locations of the retroreflectors to trigonometrically compute using three point resection, the exact real-time location of the mobile reference axis (hence the navigating vehicle) vis-a-vis the structured environment, e.g., in terms of two-dimensional Cartesian coordinates associated with the environment.

  7. Electrophoretic extraction of proteins from two-dimensional electrophoresis gel spots

    DOEpatents

    Zhang, Jian-Shi; Giometti, C.S.; Tollaksen, S.L.

    1987-09-04

    After two-dimensional electrophoresis of proteins or the like, resulting in a polyacrylamide gel slab having a pattern of protein gel spots thereon, an individual protein gel spot is cored out from the slab, to form a gel spot core which is placed in an extraction tube, with a dialysis membrane across the lower end of the tube. Replicate gel spots can be cored out from replicate gel slabs and placed in the extraction tube. Molten agarose gel is poured into the extraction tube where the agarose gel hardens to form an immobilizing gel, covering the gel spot cores. The upper end portion of the extraction tube is filled with a volume of buffer solution, and the upper end is closed by another dialysis membrane. Upper and lower bodies of a buffer solution are brought into contact with the upper and lower membranes and are provided with electrodes connected to the positive and negative terminals of a dc power supply, thereby producing an electrical current which flows through the upper membrane, the volume of buffer solution, the agarose, the gel spot cores and the lower membrane. The current causes the proteins to be extracted electrophoretically from the gel spot cores, so that the extracted proteins accumulate and are contained in the space between the agarose gel and the upper membrane. 8 figs.

  8. Two-dimensional forced convection perpendicular to the outdoor fenestration surface--FEM solution

    SciTech Connect

    Curcija, D.; Goss, W.P.

    1995-08-01

    Two-dimensional laminar forced convection on an outdoor fenestration surface, with the wind perpendicular to the glazing surface, was analyzed using the penalty function approach finite-element method (FEM). The air far from the fenestration surface (free-stream conditions) was assumed to be at ASHRAE standard fenestration conditions of {minus}18 C (0 F) and 6.7 m/s (15 mph). A prototype fenestration configuration of a typical wood casement window, consisting of a double-step frame and an insulating glazing unit (IGU), was used in defining the outdoor fenestration profile. A flat-plate geometry was also considered for purposes of comparison with other available numerical and experimental results and for validation of the results for the actual fenestration profile. The results are reported in the form of velocity vector plots and local convective surface heat transfer coefficients. Recommendations on the local outdoor surface convective heat transfer coefficient for use in two- and three-dimensional heat transfer analyses of fenestration systems are presented.

  9. Thermoelectric properties of two-dimensional topological insulators doped with nonmagnetic impurities

    SciTech Connect

    Li, L. L.; Xu, W.

    2014-07-07

    We present a theoretical study on the thermoelectric properties of two-dimensional topological insulators (2DTIs) doped with nonmagnetic impurities. We develop a tractable model to calculate the electronic band structure without additional input parameters and to evaluate the thermoelectric properties of 2DTIs based on CdTe/HgTe quantum wells. We find that with increasing the doping concentration of nonmagnetic impurity, the edge states dominate the thermoelectric transport and the bulk-state conduction is largely suppressed. For typical sample parameters, the thermoelectric figure of merit ZT (a quantity used to characterize the conversion efficiency of a thermoelectric device between the heat and electricity) can be much larger than 1, which is a great advance over conventional thermoelectric materials. Furthermore, we show that with decreasing the 2DTI ribbon width or the Hall-bar width, ZT can be considerably further improved. These results indicate that the CdTe/HgTe 2DTIs doped with nonmagnetic impurities can be potentially applied as high-efficiency thermoelectric materials and devices.

  10. Nano-Scale Hydroxyapatite: Synthesis, Two-Dimensional Transport Experiments, and Application for Uranium Remediation

    DOE PAGES [OSTI]

    Kanel, S. R.; Clement, T. P.; Barnett, M. O.; Goltz, M. N.

    2011-01-01

    Synthetic nano-scale hydroxyapatite (NHA) was prepared and characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. The XRD data confirmed that the crystalline structure and chemical composition of NHA correspond to Ca 5 OH(PO 4 ) 3 . The SEM data confirmed the size of NHA to be less than 50 nm. A two-dimensional physical model packed with saturated porous media was used to study the transport characteristics of NHA under constant flow conditions. The data show that the transport patterns of NHA were almost identical to tracer transport patterns. This result indicates that the NHA material canmore » move with water like a tracer, and its movement was neither retarded nor influenced by any physicochemical interactions and/or density effects. We have also tested the reactivity of NHA with 1 mg/L hexavalent uranium (U(VI)) and found that complete removal of U(VI) is possible using 0.5 g/L NHA at pH 5 to 6. Our results demonstrate that NHA has the potential to be injected as a dilute slurry for in situ treatment of U(VI)-contaminated groundwater systems.« less

  11. Dark States in the Light-Harvesting complex 2 Revealed by Two-dimensional Electronic Spectroscopy

    DOE PAGES [OSTI]

    Ferretti, Marco; Hendrikx, Ruud; Romero, Elisabet; Southall, June; Cogdell, Richard J.; Novoderezhkin, Vladimir I.; Scholes, Gregory D.; van Grondelle, Rienk

    2016-02-09

    Energy transfer and trapping in the light harvesting antennae of purple photosynthetic bacteria is an ultrafast process, which occurs with a quantum efficiency close to unity. However the mechanisms behind this process have not yet been fully understood. Recently it was proposed that low-lying energy dark states, such as charge transfer states and polaron pairs, play an important role in the dynamics and directionality of energy transfer. However, it is difficult to directly detect those states because of their small transition dipole moment and overlap with the B850/B870 exciton bands. Here we present a new experimental approach, which combines themore » selectivity of two-dimensional electronic spectroscopy with the availability of genetically modified light harvesting complexes, to reveal the presence of those dark states in both the genetically modified and the wild-type light harvesting 2 complexes of Rhodopseudomonas palustris. In conclusion, we suggest that Nature has used the unavoidable charge transfer processes that occur when LH pigments are concentrated to enhance and direct the flow of energy.« less

  12. Hollow cathode theory and experiment. II. A two-dimensional theoretical model of the emitter region

    SciTech Connect

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.

    2005-12-01

    Despite their long history and wide range of applicability that includes electric propulsion, detailed understanding of the driving physics inside orificed hollow cathodes remains elusive. The theoretical complexity associated with the multicomponent fluid inside the cathode, and the difficulty of accessing empirically this region, have limited our ability to design cathodes that perform better and last longer. A two-dimensional axisymmetric theoretical model of the multispecies fluid inside an orificed hollow cathode is presented. The level of detail attained by the model is allowed by its extended system of governing equations not solved for in the past within the hollow cathode. Such detail is motivated in part by the need to quantify the effect(s) of the plasma on the emitter life, and by the need to build the foundation for future modeling that will assess erosion of the keeper plate. Results from numerical simulations of a 1.2-cm-diam cathode operating at a discharge current of 25 A and a gas flow rate of 5 SCCM show that approximately 10 A of electron current, and 3.45 A of ion current return back to the emitter surface. The total emitted electron current is 33.8 A and the peak emitter temperature is found to be 1440 K. Comparisons with the measurements suggest that anomalous heating of the plasma is possible near the orifice region. The model predicts heavy species temperatures as high as 2034 K and peak voltage drops near the emitting surface not exceeding 8 V.

  13. TWO-DIMENSIONAL CELLULAR AUTOMATON MODEL FOR THE EVOLUTION OF ACTIVE REGION CORONAL PLASMAS

    SciTech Connect

    Lpez Fuentes, Marcelo; Klimchuk, James A.

    2015-02-01

    We study a two-dimensional cellular automaton (CA) model for the evolution of coronal loop plasmas. The model is based on the idea that coronal loops are made of elementary magnetic strands that are tangled and stressed by the displacement of their footpoints by photospheric motions. The magnetic stress accumulated between neighbor strands is released in sudden reconnection events or nanoflares that heat the plasma. We combine the CA model with the Enthalpy Based Thermal Evolution of Loops model to compute the response of the plasma to the heating events. Using the known response of the X-Ray Telescope on board Hinode, we also obtain synthetic data. The model obeys easy-to-understand scaling laws relating the output (nanoflare energy, temperature, density, intensity) to the input parameters (field strength, strand length, critical misalignment angle). The nanoflares have a power-law distribution with a universal slope of 2.5, independent of the input parameters. The repetition frequency of nanoflares, expressed in terms of the plasma cooling time, increases with strand length. We discuss the implications of our results for the problem of heating and evolution of active region coronal plasmas.

  14. Thermopower Enhancement by Fractional Layer Control in 2D Oxide...

    Office of Scientific and Technical Information (OSTI)

    Thermopower Enhancement by Fractional Layer Control in 2D Oxide Superlattices Citation Details In-Document Search Title: Thermopower Enhancement by Fractional Layer Control in 2D ...

  15. Quantum Oscillations in an Interfacial 2D Electron Gas. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Quantum Oscillations in an Interfacial 2D Electron Gas. Citation Details In-Document Search Title: Quantum Oscillations in an Interfacial 2D Electron Gas. Abstract not provided....

  16. Enhanced Absorption in 2D Materials Via Fano- Resonant Photonic...

    Office of Scientific and Technical Information (OSTI)

    Enhanced Absorption in 2D Materials Via Fano- Resonant Photonic Crystals Citation Details In-Document Search Title: Enhanced Absorption in 2D Materials Via Fano- Resonant Photonic ...

  17. Nonlinear Heat Transfer 2d Structure

    Energy Science and Technology Software Center

    1987-09-01

    DOT-BPMD is a general-purpose, finite-element, heat-transfer program used to predict thermal environments. The code considers linear and nonlinear transient or steady-state heat conduction in two-dimensional planar or axisymmetric representations of structures. Capabilities are provided for modeling anisotropic heterogeneous materials with temperature-dependent thermal properties and time-dependent temperature, heat flux, convection and radiation boundary conditions, together with time-dependent internal heat generation. DOT-BPMD may be used in the evaluation of steady-state geothermal gradients as well as in themore » transient heat conduction analysis of repository and waste package subsystems. Strengths of DOT-BPMD include its ability to account for a wide range of possible boundary conditions, nonlinear material properties, and its efficient equation solution algorithm. Limitations include the lack of a three-dimensional analysis capability, no radiative or convective internal heat transfer, and the need to maintain a constant time-step in each program execution.« less

  18. GBL-2D Version 1.0: a 2D geometry boolean library.

    SciTech Connect

    McBride, Cory L. (Elemental Technologies, American Fort, UT); Schmidt, Rodney Cannon; Yarberry, Victor R.; Meyers, Ray J. (Elemental Technologies, American Fort, UT)

    2006-11-01

    This report describes version 1.0 of GBL-2D, a geometric Boolean library for 2D objects. The library is written in C++ and consists of a set of classes and routines. The classes primarily represent geometric data and relationships. Classes are provided for 2D points, lines, arcs, edge uses, loops, surfaces and mask sets. The routines contain algorithms for geometric Boolean operations and utility functions. Routines are provided that incorporate the Boolean operations: Union(OR), XOR, Intersection and Difference. A variety of additional analytical geometry routines and routines for importing and exporting the data in various file formats are also provided. The GBL-2D library was originally developed as a geometric modeling engine for use with a separate software tool, called SummitView [1], that manipulates the 2D mask sets created by designers of Micro-Electro-Mechanical Systems (MEMS). However, many other practical applications for this type of software can be envisioned because the need to perform 2D Boolean operations can arise in many contexts.

  19. [Research in two-dimensional critical phenomena and conformal field theory]. [Rutgers, The State Univ. , New Brunswick, New Jersey

    SciTech Connect

    Not Available

    1990-01-01

    A very theoretical description is given of research in two- dimensional critical phenomena and conformal field theory. Major progress is reported in the field of fluctuating two-dimensional surfaces. A discretized representation of fluctuating geometry is used where surfaces are represented by triangulations; continuum surfaces are recovered by taking the size of the triangles to zero. One of the central goals of the theory of critical phenomena is to find all possible universality classes of n-dimensional critical phenomena; this goal has been translated into the problem of clasifying all possible scale-invariant euclidean quantum field theories. (RWR)

  20. Magnetic Correlations in the Quasi-Two-Dimensional Semiconducting Ferromagnet CrSiTe3

    DOE PAGES [OSTI]

    Williams, Travis J.; Aczel, Adam A.; Lumsden, Mark D.; Nagler, Stephen E.; Stone, Matthew B.; Yan, Jiaqiang -Q.; Mandrus, D.

    2015-10-02

    Intrinsic, 2D ferromagnetic semiconductors are an important class of materials for overcoming dilute magnetic semiconductors’ limitations for spintronics. CrSiTe3 is a particularly interesting material of this class, since it can likely be exfoliated to single layers, for which Tc is predicted to increase dramatically. Establishing the nature of the bulk material’s magnetism is necessary for understanding the thin-film magnetic behavior and the material’s possible applications. In this work, we use elastic and inelastic neutron scattering to measure the magnetic properties of single crystalline CrSiTe3. We find a very small single ion anisotropy that favors magnetic ordering along the c-axis andmore » that the measured spin waves fit well to a model in which the moments are only weakly coupled along that direction. Then, we find that both static and dynamic correlations persist within the ab-plane up to at least 300 K, which is strong evidence of the material's 2D characteristics that are relevant for future studies on thin film and monolayer samples.« less

  1. Two-dimensional studies of relativistic electron beam plasma instabilities in an inhomogeneous plasma

    SciTech Connect

    Shukla, Chandrasekhar; Das, Amita; Patel, Kartik

    2015-11-15

    Relativistic electron beam propagation in plasma is fraught with several micro instabilities like two stream, filamentation, etc., in plasma. This results in severe limitation of the electron transport through a plasma medium. Recently, however, there has been an experimental demonstration of improved transport of Mega Ampere of electron currents (generated by the interaction of intense laser with solid target) in a carbon nanotube structured solid target [G. Chatterjee et al., Phys. Rev. Lett. 108, 235005 (2012)]. This then suggests that the inhomogeneous plasma (created by the ionization of carbon nanotube structured target) helps in containing the growth of the beam plasma instabilities. This manuscript addresses this issue with the help of a detailed analytical study and 2-D Particle-In-Cell simulations. The study conclusively demonstrates that the growth rate of the dominant instability in the 2-D geometry decreases when the plasma density is chosen to be inhomogeneous, provided the scale length 1/k{sub s} of the inhomogeneous plasma is less than the typical plasma skin depth (c/ω{sub 0}) scale. At such small scale lengths channelization of currents is also observed in simulation.

  2. Two-dimensional simulations of explosive eruptions of Kick-em Jenny and other submarine volcanos

    SciTech Connect

    Gisler, Galen R.; Weaver, R. P.; Mader, Charles L.; Gittings, M. L.

    2004-01-01

    Kick-em Jenny, in the Eastern Caribbean, is a submerged volcanic cone that has erupted a dozen or more times since its discovery in 1939. The most likely hazard posed by this volcano is to shipping in the immediate vicinity (through volcanic missiles or loss-of-buoyancy), but it is of interest to estimate upper limits on tsunamis that might be produced by a catastrophic explosive eruption. To this end, we have performed two-dimensional simulations of such an event in a geometry resembling that of Kick-em Jenny with our SAGE adaptive mesh Eulerian multifluid compressible hydrocode. We use realistic equations of state for air, water, and basalt, and follow the event from the initial explosive eruption, through the generation of a transient water cavity and the propagation of waves away from the site. We find that even for extremely catastrophic explosive eruptions, tsunamis from Kick-em Jenny are unlikely to pose significant danger to nearby islands. For comparison, we have also performed simulations of explosive eruptions at the much larger shield volcano Vailuluu in the Samoan chain, where the greater energy available can produce a more impressive wave. In general, however, we conclude that explosive eruptions do not couple well to water waves. The waves that are produced from such events are turbulent and highly dissipative, and don't propagate well. This is consistent with what we have found previously in simulations of asteroid-impact generated tsunamis. Non-explosive events, however, such as landslides or gas hydrate releases, do couple well to waves, and our simulations of tsunamis generated by subaerial and sub-aqueous landslides demonstrate this.

  3. Transfer matrix computation of critical polynomials for two-dimensional Potts models

    DOE PAGES [OSTI]

    Jacobsen, Jesper Lykke; Scullard, Christian R.

    2013-02-04

    We showed, In our previous work, that critical manifolds of the q-state Potts model can be studied by means of a graph polynomial PB(q, v), henceforth referred to as the critical polynomial. This polynomial may be defined on any periodic two-dimensional lattice. It depends on a finite subgraph B, called the basis, and the manner in which B is tiled to construct the lattice. The real roots v = eK — 1 of PB(q, v) either give the exact critical points for the lattice, or provide approximations that, in principle, can be made arbitrarily accurate by increasing the size ofmore » B in an appropriate way. In earlier work, PB(q, v) was defined by a contraction-deletion identity, similar to that satisfied by the Tutte polynomial. Here, we give a probabilistic definition of PB(q, v), which facilitates its computation, using the transfer matrix, on much larger B than was previously possible.We present results for the critical polynomial on the (4, 82), kagome, and (3, 122) lattices for bases of up to respectively 96, 162, and 243 edges, compared to the limit of 36 edges with contraction-deletion. We discuss in detail the role of the symmetries and the embedding of B. The critical temperatures vc obtained for ferromagnetic (v > 0) Potts models are at least as precise as the best available results from Monte Carlo simulations or series expansions. For instance, with q = 3 we obtain vc(4, 82) = 3.742 489 (4), vc(kagome) = 1.876 459 7 (2), and vc(3, 122) = 5.033 078 49 (4), the precision being comparable or superior to the best simulation results. More generally, we trace the critical manifolds in the real (q, v) plane and discuss the intricate structure of the phase diagram in the antiferromagnetic (v < 0) region.« less

  4. Two dimensional point of use fuel cell : a final LDRD project report.

    SciTech Connect

    Zavadil, Kevin Robert; Hickner, Michael A.; Gross, Matthew L.

    2011-03-01

    The Proliferation Assessment (program area - Things Thin) within the Defense Systems and Assessment Investment Area desires high energy density and long-lived power sources with moderate currents (mA) that can be used as building blocks in platforms for the continuous monitoring of chemical, biological, and radiological agents. Fuel cells can be an optimum choice for a power source because of the high energy densities that are possible with liquid fuels. Additionally, power generation and fuel storage can be decoupled in a fuel cell for independent control of energy and power density for customized, application-driven power solutions. Direct methanol fuel cells (DMFC) are explored as a possible concept to develop into ultrathin or two-dimensional power sources. New developments in nanotechnology, advanced fabrication techniques, and materials science are exploited to create a planar DMFC that could be co-located with electronics in a chip format. Carbon nanotubes and pyrolyzed polymers are used as building block electrodes - porous, mechanically compliant current collectors. Directed assembly methods including surface functionalization and layer-by-layer deposition with polyelectrolytes are used to pattern, build, and add functionality to these electrodes. These same techniques are used to incorporate nanoscale selective electrocatalyst into the carbon electrodes to provide a high density of active electron transfer sites for the methanol oxidation and oxygen reduction reactions. The resulting electrodes are characterized in terms of their physical properties, electrocatalytic function, and selectivity to better understand how processing impacts their performance attributes. The basic function of a membrane electrode assembly is demonstrated for several prototype devices.

  5. Periodically sheared 2D Yukawa systems

    SciTech Connect

    Kovács, Anikó Zsuzsa; Hartmann, Peter; Donkó, Zoltán

    2015-10-15

    We present non-equilibrium molecular dynamics simulation studies on the dynamic (complex) shear viscosity of a 2D Yukawa system. We have identified a non-monotonic frequency dependence of the viscosity at high frequencies and shear rates, an energy absorption maximum (local resonance) at the Einstein frequency of the system at medium shear rates, an enhanced collective wave activity, when the excitation is near the plateau frequency of the longitudinal wave dispersion, and the emergence of significant configurational anisotropy at small frequencies and high shear rates.

  6. Digital Transfer Growth of Patterned 2D Metal Chalcogenides by Confined Nanoparticle Evaporation

    SciTech Connect

    Mahjouri-Samani, Masoud; Tian, Mengkun; Wang, Kai; Boulesbaa, Abdelaziz; Rouleau, Christopher M.; Puretzky, Alexander A.; McGuire, Michael A.; Srijanto, Bernadeta R.; Xiao, Kai; Eres, Gyula; Duscher, Gerd; Geohegan, David B.

    2014-10-19

    Developing methods for the facile synthesis of two-dimensional (2D) metal chalcogenides and other layered materials is crucial for emerging applications in functional devices. Controlling the stoichiometry, number of the layers, crystallite size, growth location, and areal uniformity is challenging in conventional vapor phase synthesis. Here, we demonstrate a new route to control these parameters in the growth of metal chalcogenide (GaSe) and dichalcogenide (MoSe2) 2D crystals by precisely defining the mass and location of the source materials in a confined transfer growth system. A uniform and precise amount of stoichiometric nanoparticles are first synthesized and deposited onto a substrate by pulsed laser deposition (PLD) at room temperature. This source substrate is then covered with a receiver substrate to form a confined vapor transport growth (VTG) system. By simply heating the source substrate in an inert background gas, a natural temperature gradient is formed that evaporates the confined nanoparticles to grow large, crystalline 2D nanosheets on the cooler receiver substrate, the temperature of which is controlled by the background gas pressure. Large monolayer crystalline domains (~ 100 m lateral sizes) of GaSe and MoSe2 are demonstrated, as well as continuous monolayer films through the deposition of additional precursor materials. This novel PLD-VTG synthesis and processing method offers a unique approach for the controlled growth of large-area, metal chalcogenides with a controlled number of layers in patterned growth locations for optoelectronics and energy related applications.

  7. Persistent photoconductivity in two-dimensional Mo1-xW xSe2–MoSe2 van der Waals heterojunctions

    DOE PAGES [OSTI]

    Puretzky, Alexander A.; Basile, Leonardo; Idrobo, Juan Carlos; Rouleau, Christopher M.; Geohegan, David B.; Xiao, Kai; Li, Xufan; Lin, Ming -Wei; Wang, Kei

    2016-02-16

    Van der Waals (vdW) heterojunctions consisting of vertically-stacked individual or multiple layers of two-dimensional (2D) layered semiconductors, especially the transition metal dichalcogenides (TMDs), are fascinating new artificial solids just nanometers-thin that promise novel optoelectronic functionalities due to the sensitivity of their electronic and optical properties to strong quantum confinement and interfacial interactions. Here, monolayers of n-type MoSe2 and p-type Mo1-xW xSe2–MoSe2 are grown by vapor transport methods, then transferred and stamped to form artificial vdW heterostructures with different interlayer orientations. Atomic-resolution Z-contrast electron microscopy and electron diffraction are used to characterize both the individual monolayers and the atomic registry betweenmore » layers in the bilayer vdW heterostructures. These measurements are compared with photoluminescence and low-frequency Raman spectroscopy, which indicates strong interlayer coupling in heterostructures. Remarkably, the heterojunctions exhibit an unprecedented photoconductivity effect that persists at room temperature for several days. This persistent photoconductivity is shown to be tunable by applying a gate bias that equilibrates the charge distribution. Furthermore, these measurements indicate that such ultrathin vdW heterojunctions can function as rewritable optoelectronic switches or memory elements under time-dependent photo-illumination, an effect which appears promising for new monolayer TMDs-based optoelectronic devices applications.« less

  8. Quasi-optical theory of relativistic surface-wave oscillators with one-dimensional and two-dimensional periodic planar structures

    SciTech Connect

    Ginzburg, N. S.; Zaslavsky, V. Yu.; Institute of Applied Physics of Russian Academy of Sciences, 46 Ulyanov St., Nizhny Novgorod 603950 ; Malkin, A. M.; Sergeev, A. S.

    2013-11-15

    Within the framework of a quasi-optical approach, we develop 2D and 3D self-consistent theory of relativistic surface-wave oscillators. Presenting the radiation field as a sum of two counter-propagating wavebeams coupled on a shallow corrugated surface, we describe formation of an evanescent slow wave. Dispersion characteristics of the evanescent wave following from this method are in good compliance with those found from the direct cst simulations. Considering excitation of the slow wave by a sheet electron beam, we simulate linear and nonlinear stages of interaction, which allows us to determine oscillation threshold conditions, electron efficiency, and output coupling. The transition from the model of surface-wave oscillator operating in the ?-mode regime to the canonical model of relativistic backward wave oscillator is considered. We also described a modified scheme of planar relativistic surface-wave oscillators exploiting two-dimensional periodic gratings. Additional transverse propagating waves emerging on these gratings synchronize the emission from a wide sheet rectilinear electron beam allowing realization of a Cherenkov millimeter-wave oscillators with subgigawatt output power level.

  9. LaTiO₃/KTaO₃ interfaces: A new two-dimensional electron gas system

    SciTech Connect

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO₃, and a band insulator, KTaO₃. For LaTiO₃/KTaO₃ interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO₃-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO₃ at room temperature. By using KTaO₃, we achieve mobilities in LaTiO₃/KTaO₃ interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO₃. By density functional theory, we attribute the higher mobility in KTaO₃ 2DEGs to the smaller effective mass for electrons in KTaO₃.

  10. LaTiO₃/KTaO₃ interfaces: A new two-dimensional electron gas system

    DOE PAGES [OSTI]

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO₃, and a band insulator, KTaO₃. For LaTiO₃/KTaO₃ interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO₃-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO₃ at room temperature. By using KTaO₃, we achieve mobilities in LaTiO₃/KTaO₃ interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO₃. By density functional theory, we attribute the higher mobilitymore » in KTaO₃ 2DEGs to the smaller effective mass for electrons in KTaO₃.« less

  11. White Noise Path Integral Treatment of a Two-dimensional Dirac Oscillator in a Uniform Magnetic Field

    SciTech Connect

    Bastatas, Lyndon D.; Bornales, Jinky B.

    2008-06-18

    White noise path integral prescription is applied to solve the Dirac equation for a two-dimensional Dirac oscillator in a uniform magnetic field. The energy spectrum obtained agrees with the result obtained by Villalba and Maggiolo using the differential approach.

  12. 2d Affine XY-Spin Model/4d Gauge Theory Duality and Deconfinement

    SciTech Connect

    Anber, Mohamed M.; Poppitz, Erich; Unsal, Mithat; /SLAC /Stanford U., Phys. Dept. /San Francisco State U.

    2012-08-16

    We introduce a duality between two-dimensional XY-spin models with symmetry-breaking perturbations and certain four-dimensional SU(2) and SU(2) = Z{sub 2} gauge theories, compactified on a small spatial circle R{sup 1,2} x S{sup 1}, and considered at temperatures near the deconfinement transition. In a Euclidean set up, the theory is defined on R{sup 2} x T{sup 2}. Similarly, thermal gauge theories of higher rank are dual to new families of 'affine' XY-spin models with perturbations. For rank two, these are related to models used to describe the melting of a 2d crystal with a triangular lattice. The connection is made through a multi-component electric-magnetic Coulomb gas representation for both systems. Perturbations in the spin system map to topological defects in the gauge theory, such as monopole-instantons or magnetic bions, and the vortices in the spin system map to the electrically charged W-bosons in field theory (or vice versa, depending on the duality frame). The duality permits one to use the two-dimensional technology of spin systems to study the thermal deconfinement and discrete chiral transitions in four-dimensional SU(N{sub c}) gauge theories with n{sub f} {ge} 1 adjoint Weyl fermions.

  13. Two-dimensional lift-up problem for a rigid porous bed

    SciTech Connect

    Chang, Y.; Huang, L. H.; Yang, F. P. Y.

    2015-05-15

    The present study analytically reinvestigates the two-dimensional lift-up problem for a rigid porous bed that was studied by Mei, Yeung, and Liu [“Lifting of a large object from a porous seabed,” J. Fluid Mech. 152, 203 (1985)]. Mei, Yeung, and Liu proposed a model that treats the bed as a rigid porous medium and performed relevant experiments. In their model, they assumed the gap flow comes from the periphery of the gap, and there is a shear layer in the porous medium; the flow in the gap is described by adhesion approximation [D. J. Acheson, Elementary Fluid Dynamics (Clarendon, Oxford, 1990), pp. 243-245.] and the pore flow by Darcy’s law, and the slip-flow condition proposed by Beavers and Joseph [“Boundary conditions at a naturally permeable wall,” J. Fluid Mech. 30, 197 (1967)] is applied to the bed interface. In this problem, however, the gap flow initially mainly comes from the porous bed, and the shear layer may not exist. Although later the shear effect becomes important, the empirical slip-flow condition might not physically respond to the shear effect, and the existence of the vertical velocity affects the situation so greatly that the slip-flow condition might not be appropriate. In contrast, the present study proposes a more general model for the problem, applying Stokes flow to the gap, the Brinkman equation to the porous medium, and Song and Huang’s [“Laminar poroelastic media flow,” J. Eng. Mech. 126, 358 (2000)] complete interfacial conditions to the bed interface. The exact solution to the problem is found and fits Mei’s experiments well. The breakout phenomenon is examined for different soil beds, mechanics that cannot be illustrated by Mei’s model are revealed, and the theoretical breakout times obtained using Mei’s model and our model are compared. The results show that the proposed model is more compatible with physics and provides results that are more precise.

  14. Doppler Velocimetry of Current Driven Spin Helices in a Two-Dimensional Electron Gas

    SciTech Connect

    Yang, Luyi

    2013-05-17

    Spins in semiconductors provide a pathway towards the development of spin-based electronics. The appeal of spin logic devices lies in the fact that the spin current is even under time reversal symmetry, yielding non-dissipative coupling to the electric field. To exploit the energy-saving potential of spin current it is essential to be able to control it. While recent demonstrations of electrical-gate control in spin-transistor configurations show great promise, operation at room temperature remains elusive. Further progress requires a deeper understanding of the propagation of spin polarization, particularly in the high mobility semiconductors used for devices. This dissertation presents the demonstration and application of a powerful new optical technique, Doppler spin velocimetry, for probing the motion of spin polarization at the level of 1 nm on a picosecond time scale. We discuss experiments in which this technique is used to measure the motion of spin helices in high mobility n-GaAs quantum wells as a function of temperature, in-plane electric field, and photoinduced spin polarization amplitude. We find that the spin helix velocity changes sign as a function of wave vector and is zero at the wave vector that yields the largest spin lifetime. This observation is quite striking, but can be explained by the random walk model that we have developed. We discover that coherent spin precession within a propagating spin density wave is lost at temperatures near 150 K. This finding is critical to understanding why room temperature operation of devices based on electrical gate control of spin current has so far remained elusive. We report that, at all temperatures, electron spin polarization co-propagates with the high-mobility electron sea, even when this requires an unusual form of separation of spin density from photoinjected electron density. Furthermore, although the spin packet co-propagates with the two-dimensional electron gas, spin diffusion is strongly

  15. Characterization of a two-dimensional liquid-filled ion chamber detector array used for verification of the treatments in radiotherapy

    SciTech Connect

    Markovic, Miljenko Stathakis, Sotirios; Mavroidis, Panayiotis; Jurkovic, Ines-Ana; Papanikolaou, Nikos

    2014-05-15

    Purpose: The purpose of the study is to investigate the characteristics of a two-dimensional (2D) liquid-filled ion chamber detector array, which is used for the verification of radiotherapy treatment plans that use small field sizes of up to 10 10 cm. Methods: The device used in this study was Octavius 1000 SRS model (PTW, Freiburg, Germany). Its 2D array of detectors consists of 977 liquid-filled ion chambers arranged over an area of 11 11 cm. The size of the detectors is 2.3 2.3 0.5 mm (volume of 0.003 cm{sup 3}) and their spacing in the inner area of 5.5 5.5 cm is 2.5 mm center-to-center, whereas in the outer area it is 5 mm center-to-center. The detector reproducibility, dose linearity, and sensitivity to positional changes of the collimator were tested. Also, the output factors of field sizes ranging from 0.5 0.5 to 10 10 cm{sup 2} both for open and wedged fields have been measured and compared against those measured by a pin-point ionization chamber, liquid filled microchamber, SRS diode, and EDR2 film. Results: Its short-term reproducibility was within 0.2% and its medium and long-term reproducibility was within 0.5% (verified with air ionization chamber absolute dose measurements), which is an excellent result taking into account the daily fluctuation of the linear accelerator and the errors in the device setup reproducibility. The dose linearity and dose rate dependence were measured in the range of 0.585 Gy and 0.510 Gy?min{sup ?1}, respectively, and were verified with air ionization chamber absolute dose measurements was within 3%. The measurements of the sensitivity showed that the 2D Array could detect millimetric collimator positional changes. The measured output factors showed an agreement of better than 0.3% with the pinpoint chamber and microliquid filled chamber for the field sizes between 3 3 and 10 10 cm{sup 2}. For field sizes down to 1 1 cm{sup 2}, the agreement with SRS diode and microliquid filled chamber is better

  16. On physical interpretation of two dimensional time-correlations regarding time delay velocities and eddy shaping

    SciTech Connect

    Fedorczak, N.; Manz, P.; Thakur, S. C.; Xu, M.; Tynan, G. R.; Xu, G. S.; Liu, S. C.

    2012-12-15

    Time delay estimation (TDE) techniques are frequently used to estimate the flow velocity from fluctuating measurements. Tilted structures carried by the flow lead to misinterpretation of the time delays in terms of velocity direction and amplitude. It affects TDE measurements from probes, and is also intrinsically important for beam emission spectroscopy and gas puff imaging measurements. Local eddy shapes estimated from 2D fluctuating field are necessary to gain a more accurate flow estimate from TDE, as illustrated by Langmuir probe array measurements. A least square regression approach is proposed to estimate both flow field and shaping parameters. The technique is applied to a test case built from numerical simulation of interchange fluctuations. The local eddy shape does not only provide corrections for the velocity field but also quantitative information about the statistical interaction mechanisms between local eddies and E Multiplication-Sign B flow shear. The technique is then tested on gaz puff imaging data collected at the edge of EAST tokamak plasmas. It is shown that poloidal asymmetries of the fluctuation fields-velocity and eddy shape-are consistent at least qualitatively with a ballooning type of turbulence immersed in a radially sheared equilibrium flow.

  17. Angular dependence of the spin textures in two-dimensional chiral magnets

    SciTech Connect

    Tang, Dan; Qi, Yang

    2015-05-28

    The angular dependence of spin textures in thin helimagnetic films is investigated by a Monte Carlo simulation. When an external field is applied at an angle relative to the film normal, we find that the skyrmion states with broken axis-symmetric structure are able to persist over a wide range of angles by changing the spin orientation. In addition, the uniaxial anisotropy is able to stabilize the distorted skyrmions. This behavior reflects the robust topological stability of skyrmion states in helimagnets and favors their application in spintronic devices.

  18. Kinetic theory of the electron bounce instability in two dimensional current sheetsFull electromagnetic treatment

    SciTech Connect

    Tur, A.; Fruit, G.; Louarn, P.

    2014-03-15

    In the general context of understanding the possible destabilization of a current sheet with applications to magnetospheric substorms or solar flares, a kinetic model is proposed for studying the resonant interaction between electromagnetic fluctuations and trapped bouncing electrons in a 2D current sheet. Tur et al. [A. Tur et al., Phys. Plasmas 17, 102905 (2010)] and Fruit et al. [G. Fruit et al., Phys. Plasmas 20, 022113 (2013)] already used this model to investigate the possibilities of electrostatic instabilities. Here, the model is completed for full electromagnetic perturbations. Starting with a modified Harris sheet as equilibrium state, the linearized gyrokinetic Vlasov equation is solved for electromagnetic fluctuations with period of the order of the electron bounce period. The particle motion is restricted to its first Fourier component along the magnetic field and this allows the complete time integration of the non local perturbed distribution functions. The dispersion relation for electromagnetic modes is finally obtained through the quasineutrality condition and the Ampere's law for the current density. It is found that for mildly strechted current, undamped modes oscillate at typical electron bounce frequency with wavelength of the order of the plasma sheet half thickness. As the stretching of the plasma sheet becomes more intense, the frequency of these normal modes decreases and beyond a certain threshold in ??=?B{sub z}/B{sub lobes}, the mode becomes explosive with typical growth rate of a few tens of seconds. The free energy contained in the bouncing motion of the electrons may trigger an electromagnetic instability able to disrupt the cross-tail current in a few seconds. This new instabilityelectromagnetic electron-bounce instabilitymay explain fast and global scale destabilization of current sheets as required to describe substorm phenomena.

  19. Terahertz signal detection in a short gate length field-effect transistor with a two-dimensional electron gas

    SciTech Connect

    Vostokov, N. V. Shashkin, V. I.

    2015-11-28

    We consider the problem of non-resonant detection of terahertz signals in a short gate length field-effect transistor having a two-dimensional electron channel with zero external bias between the source and the drain. The channel resistance, gate-channel capacitance, and quadratic nonlinearity parameter of the transistor during detection as a function of the gate bias voltage are studied. Characteristics of detection of the transistor connected in an antenna with real impedance are analyzed. The consideration is based on both a simple one-dimensional model of the transistor and allowance for the two-dimensional distribution of the electric field in the transistor structure. The results given by the different models are discussed.

  20. Spatially correlated two-dimensional arrays of semiconductor and metal quantum dots in GaAs-based heterostructures

    SciTech Connect

    Nevedomskiy, V. N. Bert, N. A.; Chaldyshev, V. V.; Preobrazhernskiy, V. V.; Putyato, M. A.; Semyagin, B. R.

    2015-12-15

    A single molecular-beam epitaxy process is used to produce GaAs-based heterostructures containing two-dimensional arrays of InAs semiconductor quantum dots and AsSb metal quantum dots. The twodimensional array of AsSb metal quantum dots is formed by low-temperature epitaxy which provides a large excess of arsenic in the epitaxial GaAs layer. During the growth of subsequent layers at a higher temperature, excess arsenic forms nanoinclusions, i.e., metal quantum dots in the GaAs matrix. The two-dimensional array of such metal quantum dots is created by the δ doping of a low-temperature GaAs layer with antimony which serves as a precursor for the heterogeneous nucleation of metal quantum dots and accumulates in them with the formation of AsSb metal alloy. The two-dimensional array of InAs semiconductor quantum dots is formed via the Stranski–Krastanov mechanism at the GaAs surface. Between the arrays of metal and semiconductor quantum dots, a 3-nm-thick AlAs barrier layer is grown. The total spacing between the arrays of metal and semiconductor quantum dots is 10 nm. Electron microscopy of the structure shows that the arrangement of metal quantum dots and semiconductor quantum dots in the two-dimensional arrays is spatially correlated. The spatial correlation is apparently caused by elastic strain and stress fields produced by both AsSb metal and InAs semiconductor quantum dots in the GaAs matrix.

  1. Closed loop engine control for regulating NOx emissions, using a two-dimensional fuel-air curve

    DOEpatents

    Bourn, Gary D.; Smith, Jack A.; Gingrich, Jess W.

    2007-01-30

    An engine control strategy that ensures that NOx emissions from the engine will be maintained at an acceptable level. The control strategy is based on a two-dimensional fuel-air curve, in which air manifold pressure (AMP) is a function of fuel header pressure and engine speed. The control strategy provides for closed loop NOx adjustment to a base AMP value derived from the fuel-air curve.

  2. 2D Gridded Surface Data Value-Added Product

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2 2D Gridded Surface Data Value-Added Product Q Tang S Xie July 2015 DISCLAIMER This ... DOESC-ARMTR-152 2D Gridded Surface Data Value-Added Product Version 1.0 Q Tang S Xie ...

  3. THE VEX RADIATION MODULE: 2D RADIATION TRANSPORT WITH MIMETIC...

    Office of Scientific and Technical Information (OSTI)

    THE VEX RADIATION MODULE: 2D RADIATION TRANSPORT WITH MIMETIC DIFFUSION FOR EXAFLAG Citation Details In-Document Search Title: THE VEX RADIATION MODULE: 2D RADIATION TRANSPORT WITH ...

  4. THE VEX RADIATION MODULE: 2D RADIATION TRANSPORT WITH MIMETIC...

    Office of Scientific and Technical Information (OSTI)

    THE VEX RADIATION MODULE: 2D RADIATION TRANSPORT WITH MIMETIC DIFFUSION FOR EXAFLAG Citation Details In-Document Search Title: THE VEX RADIATION MODULE: 2D RADIATION TRANSPORT WITH...

  5. Enhanced Absorption in 2D Materials Via Fano- Resonant Photonic Crystals

    DOE PAGES [OSTI]

    Wang, Wenyi; Klotz, Andrey; Yang, Yuanmu; Li, Wei; Kravchenko, Ivan I.; Briggs, Dayrl P.; Bolotin, Kirill; Valentine, Jason

    2015-05-01

    The use of two-dimensional (2D) materials in optoelectronics has attracted much attention due to their fascinating optical and electrical properties. For instance, graphenebased devices have been employed for applications such as ultrafast and broadband photodetectors and modulators while transition metal dichalcogenide (TMDC) based photodetectors can be used for ultrasensitive photodetection. However, the low optical absorption of 2D materials arising from their atomic thickness limits the maximum attainable external quantum efficiency. For example, in the visible and NIR regimes monolayer MoS2 and graphene absorb only ~10% and 2.3% of incoming light, respectively. Here, we experimentally demonstrate the use of Fano-resonant photonicmore » crystals to significantly boost absorption in atomically thin materials. Using graphene as a test bed, we demonstrate that absorption in the monolayer thick material can be enhanced to 77% within the telecommunications band, the highest value reported to date. We also show that the absorption in the Fano-resonant structure is non-local, with light propagating up to 16 μm within the structure. This property is particularly beneficial in harvesting light from large areas in field-effect-transistor based graphene photodetectors in which separation of photo-generated carriers only occurs ~0.2 μm adjacent to the graphene/electrode interface.« less

  6. Nanoscale elastic changes in 2D Ti3C2Tx (MXene) pseudocapacitive electrodes

    DOE PAGES [OSTI]

    Come, Jeremy; Xie, Yu; Naguib, Michael; Jesse, Stephen; Kalinin, Sergei V.; Gogotsi, Yury; Kent, Paul R. C.; Balke, Nina

    2016-02-01

    Designing sustainable electrodes for next generation energy storage devices relies on the understanding of their fundamental properties at the nanoscale, including the comprehension of ions insertion into the electrode and their interactions with the active material. One consequence of ion storage is the change in the electrode volume resulting in mechanical strain and stress that can strongly affect the cycle life. Therefore, it is important to understand the changes of dimensions and mechanical properties occurring during electrochemical reactions. While the characterization of mechanical properties via macroscopic measurements is well documented, in-situ characterization of their evolution has never been achieved atmore » the nanoscale. Two dimensional (2D) carbides, known as MXenes, are promising materials for supercapacitors and various kinds of batteries, and understating the coupling between their mechanical and electrochemical properties is therefore necessary. Here we report on in-situ imaging, combined with density functional theory of the elastic changes, of a 2D titanium carbide (Ti3C2Tx) electrode in direction normal to the basal plane during cation intercalation. The results show a strong correlation between the Li+ ions content and the elastic modulus, whereas little effects of K+ ions are observed. Moreover, this strategy enables identifying the preferential intercalation pathways within a single particle.« less

  7. Caffeine increases striatal dopamine D2/D3 receptor availability in the human brain

    DOE PAGES [OSTI]

    Volkow, N. D.; Wang, G. -J.; Logan, J.; Alexoff, D.; Fowler, J. S.; Thanos, P. K.; Wong, C.; Casado, V.; Ferre, S.; Tomasi, D.

    2015-04-14

    Caffeine, the most widely consumed psychoactive substance in the world, is used to promote wakefulness and enhance alertness. Like other wake-promoting drugs (stimulants and modafinil), caffeine enhances dopamine (DA) signaling in the brain, which it does predominantly by antagonizing adenosine A2A receptors (A2AR). However, it is unclear if caffeine, at the doses consumed by humans, increases DA release or whether it modulates the functions of postsynaptic DA receptors through its interaction with adenosine receptors, which modulate them. We used positron emission tomography and [11C]raclopride (DA D2/D3 receptor radioligand sensitive to endogenous DA) to assess if caffeine increased DA release inmore » striatum in 20 healthy controls. Caffeine (300mg p.o.) significantly increased the availability of D2/D3 receptors in putamen and ventral striatum, but not in caudate, when compared with placebo. In addition, caffeine-induced increases in D2/D3 receptor availability in the ventral striatum were associated with caffeine-induced increases in alertness. Our findings indicate that in the human brain, caffeine, at doses typically consumed, increases the availability of DA D2/D3 receptors, which indicates that caffeine does not increase DA in the striatum for this would have decreased D2/D3 receptor availability. Instead, we interpret our findings to reflect an increase in D2/D3 receptor levels in striatum with caffeine (or changes in affinity). Furthermore, the association between increases in D2/D3 receptor availability in ventral striatum and alertness suggests that caffeine might enhance arousal, in part, by upregulating D2/D3 receptors.« less

  8. Digital Transfer Growth of Patterned 2D Metal Chalcogenides by Confined Nanoparticle Evaporation

    DOE PAGES [OSTI]

    Mahjouri-Samani, Masoud; Tian, Mengkun; Wang, Kai; Boulesbaa, Abdelaziz; Rouleau, Christopher M.; Puretzky, Alexander A.; McGuire, Michael A.; Srijanto, Bernadeta R.; Xiao, Kai; Eres, Gyula; et al

    2014-10-19

    Developing methods for the facile synthesis of two-dimensional (2D) metal chalcogenides and other layered materials is crucial for emerging applications in functional devices. Controlling the stoichiometry, number of the layers, crystallite size, growth location, and areal uniformity is challenging in conventional vapor phase synthesis. Here, we demonstrate a new route to control these parameters in the growth of metal chalcogenide (GaSe) and dichalcogenide (MoSe2) 2D crystals by precisely defining the mass and location of the source materials in a confined transfer growth system. A uniform and precise amount of stoichiometric nanoparticles are first synthesized and deposited onto a substrate bymore » pulsed laser deposition (PLD) at room temperature. This source substrate is then covered with a receiver substrate to form a confined vapor transport growth (VTG) system. By simply heating the source substrate in an inert background gas, a natural temperature gradient is formed that evaporates the confined nanoparticles to grow large, crystalline 2D nanosheets on the cooler receiver substrate, the temperature of which is controlled by the background gas pressure. Large monolayer crystalline domains (~ 100 m lateral sizes) of GaSe and MoSe2 are demonstrated, as well as continuous monolayer films through the deposition of additional precursor materials. This novel PLD-VTG synthesis and processing method offers a unique approach for the controlled growth of large-area, metal chalcogenides with a controlled number of layers in patterned growth locations for optoelectronics and energy related applications.« less

  9. Extinction maps toward the Milky Way bulge: Two-dimensional and three-dimensional tests with apogee

    SciTech Connect

    Schultheis, M.; Zasowski, G.; Allende Prieto, C.; Beaton, R. L.; García Pérez, A. E.; Majewski, S. R.; Beers, T. C.; Bizyaev, D.; Frinchaboy, P. M.; Ge, J.; Hearty, F.; Schneider, D. P.; Holtzman, J.; Muna, D.; Nidever, D.; Shetrone, M. E-mail: gail.zasowski@gmail.com

    2014-07-01

    Galactic interstellar extinction maps are powerful and necessary tools for Milky Way structure and stellar population analyses, particularly toward the heavily reddened bulge and in the midplane. However, due to the difficulty of obtaining reliable extinction measures and distances for a large number of stars that are independent of these maps, tests of their accuracy and systematics have been limited. Our goal is to assess a variety of photometric stellar extinction estimates, including both two-dimensional and three-dimensional extinction maps, using independent extinction measures based on a large spectroscopic sample of stars toward the Milky Way bulge. We employ stellar atmospheric parameters derived from high-resolution H-band Apache Point Observatory Galactic Evolution Experiment (APOGEE) spectra, combined with theoretical stellar isochrones, to calculate line-of-sight extinction and distances for a sample of more than 2400 giants toward the Milky Way bulge. We compare these extinction values to those predicted by individual near-IR and near+mid-IR stellar colors, two-dimensional bulge extinction maps, and three-dimensional extinction maps. The long baseline, near+mid-IR stellar colors are, on average, the most accurate predictors of the APOGEE extinction estimates, and the two-dimensional and three-dimensional extinction maps derived from different stellar populations along different sightlines show varying degrees of reliability. We present the results of all of the comparisons and discuss reasons for the observed discrepancies. We also demonstrate how the particular stellar atmospheric models adopted can have a strong impact on this type of analysis, and discuss related caveats.

  10. Finite-size effects on the phase diagram of difermion condensates in two-dimensional four-fermion interaction models

    SciTech Connect

    Abreu, L. M.; Malbouisson, J. M. C.; Malbouisson, A. P. C.

    2011-01-15

    We investigate finite-size effects on the phase structure of chiral and difermion condensates at finite temperature and density in the framework of the two-dimensional large-N Nambu-Jona-Lasinio model. We take into account size-dependent effects by making use of zeta-function and compactification methods. The thermodynamic potential and the gap equations for the chiral and difermion condensed phases are then derived in the mean-field approximation. Size-dependent critical lines separating the different phases are obtained considering antiperiodic boundary conditions for the spatial coordinate.

  11. Surface harmonics method for two-dimensional time-dependent neutron transport problems of square-lattice nuclear reactors

    SciTech Connect

    Boyarinov, V. F.; Kondrushin, A. E.; Fomichenko, P. A.

    2013-07-01

    Time-dependent equations of the Surface Harmonics Method (SHM) have been derived from the time-dependent neutron transport equation with explicit representation of delayed neutrons for solving the two-dimensional time-dependent problems. These equations have been realized in the SUHAM-TD code. The TWIGL benchmark problem has been used for verification of the SUHAM-TD code. The results of the study showed that computational costs required to achieve necessary accuracy of the solution can be an order of magnitude less than with the use of the conventional finite difference method (FDM). (authors)

  12. One- and two-dimensional infrared spectroscopic studies of solution-phase homogeneous catalysis and spin-forbidden reactions

    SciTech Connect

    Sawyer, Karma Rae

    2008-12-01

    Understanding chemical reactions requires the knowledge of the elementary steps of breaking and making bonds, and often a variety of experimental techniques are needed to achieve this goal. The initial steps occur on the femto- through picosecond time-scales, requiring the use of ultrafast spectroscopic methods, while the rate-limiting steps often occur more slowly, requiring alternative techniques. Ultrafast one and two-dimensional infrared and step-scan FTIR spectroscopies are used to investigate the photochemical reactions of four organometallic complexes. The analysis leads to a detailed understanding of mechanisms that are general in nature and may be applicable to a variety of reactions.

  13. Reconstruction of two-dimensional molecular structure with laser-induced electron diffraction from laser-aligned polyatomic molecules

    DOE PAGES [OSTI]

    Yu, Chao; Wei, Hui; Wang, Xu; Le, Anh -Thu; Lu, Ruifeng; Lin, C. D.

    2015-10-27

    Imaging the transient process of molecules has been a basic way to investigate photochemical reactions and dynamics. Based on laser-induced electron diffraction and partial one-dimensional molecular alignment, here we provide two effective methods for reconstructing two-dimensional structure of polyatomic molecules. We demonstrate that electron diffraction images in both scattering angles and broadband energy can be utilized to retrieve complementary structure information, including positions of light atoms. Lastly, with picometre spatial resolution and the inherent femtosecond temporal resolution of lasers, laser-induced electron diffraction method offers significant opportunities for probing atomic motion in a large molecule in a typical pump-probe measurement.

  14. Ultra-directional source of longitudinal acoustic waves based on a two-dimensional solid/solid phononic crystal

    SciTech Connect

    Morvan, B.; Tinel, A.; Sainidou, R.; Rembert, P.; Vasseur, J. O.; Hladky-Hennion, A.-C.; Swinteck, N.; Deymier, P. A.

    2014-12-07

    Phononic crystals (PC) can be used to control the dispersion properties of acoustic waves, which are essential to direct their propagation. We use a PC-based two-dimensional solid/solid composite to demonstrate experimentally and theoretically the spatial filtering of a monochromatic non-directional wave source and its emission in a surrounding water medium as an ultra-directional beam with narrow angular distribution. The phenomenon relies on square-shaped equifrequency contours (EFC) enabling self-collimation of acoustic waves within the phononic crystal. Additionally, the angular width of collimated beams is controlled via the EFC size-shrinking when increasing frequency.

  15. Gas-Liquid Transition in a Two-Dimensional System of Millimeter-Sized Like-Charged Metal Balls

    SciTech Connect

    Tata, B. V. R.; Rajamani, P. V.; Wasan, D. T.

    2000-04-17

    Metal balls with a diameter of 1.59 mm, gently rubbed against a dielectric surface using a shaker, are seen to spontaneously exhibit a two-dimensional liquidlike order with macroscopic dimensions, viz., interball distances of several millimeters. This liquidlike order transforms to a gaslike order through coexistence upon decreasing the area fraction of the balls. The measured pair interaction of like-charged balls surprisingly exhibits a long-range attractive term analogous to that in charged colloids. (c) 2000 The American Physical Society.

  16. Synthesis, structures and properties of a family of four two-dimensional coordination polymers constructed from 5-hydroxyisophthalate

    SciTech Connect

    Zhang, Kou-Lin; Zhang, Jing-Bo; Jing, Chu-Yue; Zhang, Lei; Walton, Richard I.; Zhu, Peizhi; Ng, Seik Weng

    2014-03-15

    Four 2D coordination polymers (CPs) with different structures containing the multifunctional ligand 5-hydroxyisophthalate (5-OH-BDC{sup 2−}), [Zn(5-OH-BDC)(btb)]·2H{sub 2}O (1), [Cd(5-OH-BDC)(btp)(H{sub 2}O)]·3H{sub 2}O (2), [Cd(5-OH-BDC)(bth){sub 2}(H{sub 2}O)]·H{sub 2}O (3) and [Pb(5-OH-BDC)]·H{sub 2}O (4) [btp=1, 3-bis(1,2,4-triazol-1-yl)propane, btb=1,4-bis(1,2,4-triazol-1-yl)butane, bth=1, 6-bis(1,2,4-triazol-1-yl)hexane] were obtained. 1–3 were synthesised hydrothermally, while 4 was obtained under ambient condition. The adjacent (2D→2D) polycatenated 2D layers of 1 polythread in a parallel manner to form an unusual 2D→3D polythreaded framework. 2 contains an undulated 2D (4, 4) network and further extends into an “embracing” double-layer structure through the C–H···π and π···π stacking interactions. 3 exhibits a non-interpenetrating 2D (4, 4)-network. 4 exhibits a 2D double-layered binodal (4, 4)-net containing oblong nanochannels with symbol (4{sup 3}6{sup 3}){sub 2}. Reversible dehydration–rehydration is observed in 1, 2 and 4, which fall within the category of “recoverable collapsing” and “guest-induced re-formation” frameworks, while 3 exhibits irreversible dehydration–rehydration behaviour. The solid state fluorescent properties of 1–4 have been investigated. -- Graphical abstract: Among four 2D CPs reported, 1 is an unusual 2D→3D polythreaded framework. 4 exhibits 2D double-layered binodal (4, 4)-net containing nanochannels. Reversible dehydration–rehydration is observed in 1, 2 and 4. Highlights: • Four 2D CPs based on 5-hydroxyisophthalate with d{sup 10} and Pb(II) ions were reported. • 1 is an unusual 2D→3D polythreaded framework. • 4 shows a binodal (4, 4)-connected 2D double-layer network with nanochannels. • The materials 1, 2 and 4 show reversible dehydration–rehydration behaviours. • Solid state fluorescent properties were investigated.

  17. R2D Ingenierie SAS | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: R2D Ingenierie SAS Place: Montpellier, France Product: French automation equipment manufacturer for PV cells and semiconductor chips. Coordinates:...

  18. A Geometric Boolean Library for 2D Objects

    Energy Science and Technology Software Center

    2006-01-05

    The 2D Boolean Library is a collection of C++ classes -- which primarily represent 2D geometric data and relationships, and routines -- which contain algorithms for 2D geometric Boolean operations and utility functions. Classes are provided for 2D points, lines, arcs, edgeuses, loops, surfaces and mask sets. Routines are provided that incorporate the Boolean operations Union(OR), XOR, Intersection and Difference. Various analytical geometry routines and routines for importing and exporting the data in various filemore » formats, are also provided in the library.« less

  19. AnisWave2D: User's Guide to the 2d Anisotropic Finite-DifferenceCode

    SciTech Connect

    Toomey, Aoife

    2005-01-06

    This document describes a parallel finite-difference code for modeling wave propagation in 2D, fully anisotropic materials. The code utilizes a mesh refinement scheme to improve computational efficiency. Mesh refinement allows the grid spacing to be tailored to the velocity model, so that fine grid spacing can be used in low velocity zones where the seismic wavelength is short, and coarse grid spacing can be used in zones with higher material velocities. Over-sampling of the seismic wavefield in high velocity zones is therefore avoided. The code has been implemented to run in parallel over multiple processors and allows large-scale models and models with large velocity contrasts to be simulated with ease.

  20. Two-dimensional resonant magnetic excitation in BaFe1.84Co0.16As2

    SciTech Connect

    Lumsden, Mark D; Christianson, Andrew D; Parshall, Daniel; Stone, Matthew B; Nagler, Stephen E; Mook Jr, Herbert A; Lokshin, Konstantin A; Egami, Takeshi; Abernathy, Douglas L; Goremychkin, E. A.; Osborn, R.; McGuire, Michael A; Safa-Sefat, Athena; Jin, Rongying; Sales, Brian C; Mandrus, David

    2009-01-01

    Inelastic neutron scattering measurements on single crystals of superconducting BaFe1.84Co0.16As2 clearly reveal a magnetic excitation located at wavevectors (1/2 1/2 L) in tetragonal notation. The scattering is much broader in L than are spin waves observed in the parent compound BaFe2As2 indicating that the excitations in the superconducting material are more two-dimensional in nature. The excitation appears gapless for T > TC and becomes gapped on cooling below TC. The observed gap energy is approximately 9.6 meV corresponding to 5 kBTC which is remarkably similar to the canonical value for the resonance energy in the cuprates.

  1. Simultaneous negative refraction and focusing of fundamental frequency and second-harmonic fields by two-dimensional photonic crystals

    SciTech Connect

    Zhang, Jun; Zhang, Xiangdong

    2015-09-28

    Simultaneous negative refraction for both the fundamental frequency (FF) and second-harmonic (SH) fields in two-dimensional nonlinear photonic crystals have been found through both the physical analysis and exact numerical simulation. By combining such a property with the phase-matching condition and strong second-order susceptibility, we have designed a SH lens to realize focusing for both the FF and SH fields at the same time. Good-quality non-near field images for both FF and SH fields have been observed. The physical mechanism for such SH focusing phenomena has been disclosed, which is different from the backward SH generation as has been pointed out in the previous investigations. In addition, the effect of absorption losses on the phenomena has also been discussed. Thus, potential applications of these phenomena to biphotonic microscopy technique are anticipated.

  2. Two-dimensional electromagnetic quantum-hydrodynamic simulations of isochoric heating of a solid target by proton beams

    SciTech Connect

    Zhang, Ya; Jiang, Wei; Song, Yuan-Hong; Wang, You-Nian

    2015-02-15

    Isochoric heating of an aluminum target by proton beams has been studied with a two-dimensional self-consistent electromagnetic quantum-hydrodynamic model, including the nonlinear quantum effects. It is shown that most protons deposit their energy within several micrometers near the surface, and the aluminum metal target is heated up to several electron volts in tens of Mbar pressure regime within one picosecond. Comparison between electrostatic and electromagnetic cases shows that the strength of electromagnetic field is much smaller than that of the electrostatic field at initial stage but increases more rapidly and becomes larger at later time. The results show that the time evolution of electric field has a significant influence on the interaction of intense beams with a solid target, while the effect of the self-magnetic field is small for non-relativistic beams considered here.

  3. Two-dimensional numerical study of two counter-propagating helium plasma jets in air at atmospheric pressure

    SciTech Connect

    Yan, Wen; Sang, Chaofeng; Wang, Dezhen; Liu, Fucheng

    2014-06-15

    In this paper, a computational study of two counter-propagating helium plasma jets in ambient air is presented. A two-dimensional fluid model is applied to investigate the physical processes of the two plasma jets interaction (PJI) driven by equal and unequal voltages, respectively. In all studied cases, the PJI results in a decrease of both plasma bullets propagation velocity. When the two plasma jets are driven by equal voltages, they never merge but rather approach each other around the middle of the gas gap at a minimum approach distance, and the minimal distance decreases with the increase of both the applied voltages and initial electron density, but increases with the increase of the relative permittivity. When the two plasma jets are driven by unequal voltages, we observe the two plasma jets will merge at the position away from the middle of the gas gap. The effect of applied voltage difference on the PJI is also studied.

  4. Electron heating due to microwave photoexcitation in the high mobility GaAs/AlGaAs two dimensional electron system

    SciTech Connect

    Ramanayaka, A. N.; Mani, R. G.; Wegscheider, W.

    2013-12-04

    We extract the electron temperature in the microwave photo-excited high mobility GaAs/AlGaAs two dimensional electron system (2DES) by studying the influence of microwave radiation on the amplitude of Shubnikov-de Haas oscillations (SdHOs) in a regime where the cyclotron frequency, ?{sub c}, and the microwave angular frequency, ?, satisfy 2? ? ?{sub c} ? 3.5? The results indicate that increasing the incident microwave power has a weak effect on the amplitude of the SdHOs and therefore the electron temperature, in comparison to the influence of modest temperature changes on the dark-specimen SdH effect. The results indicate negligible electron heating under modest microwave photo-excitation, in good agreement with theoretical predictions.

  5. The internal structure of a vortex in a two-dimensional superfluid with long healing length and its implications

    SciTech Connect

    Klein, Avraham; Aleiner, Igor L.; Agam, Oded

    2014-07-15

    We analyze the motion of quantum vortices in a two-dimensional spinless superfluid within Popov’s hydrodynamic description. In the long healing length limit (where a large number of particles are inside the vortex core) the superfluid dynamics is determined by saddle points of Popov’s action, which, in particular, allows for weak solutions of the Gross–Pitaevskii equation. We solve the resulting equations of motion for a vortex moving with respect to the superfluid and find the reconstruction of the vortex core to be a non-analytic function of the force applied on the vortex. This response produces an anomalously large dipole moment of the vortex and, as a result, the spectrum associated with the vortex motion exhibits narrow resonances lying within the phonon part of the spectrum, contrary to traditional view.

  6. Mott-insulator-to-superfluid transition in Bose-Bose mixtures in a two-dimensional lattice

    SciTech Connect

    Guglielmino, M.; Penna, V.; Capogrosso-Sansone, B.

    2010-08-15

    We perform a numeric study (worm algorithm Monte Carlo simulations) of ultracold two-component bosons in two-dimensional optical lattices. We study how the Mott-insulator-to-superfluid transition is affected by the presence of a second superfluid bosonic species. We find that, at fixed interspecies interaction, the upper and lower boundaries of the Mott lobe are differently modified. The lower boundary is strongly renormalized even for relatively low filling factor of the second component and moderate (interspecies) interaction. The upper boundary, instead, is affected only for large enough filling of the second component. Whereas boundaries are renormalized we find evidence of polaron-like excitations. Our results are of interest for current experimental setups.

  7. Studies of scattering mechanisms in gate tunable InAs/(Al,Ga)Sb two dimensional electron gases

    SciTech Connect

    Shojaei, B.; McFadden, A.; Schultz, B. D.; Shabani, J.; Palmstrøm, C. J.

    2015-06-01

    A study of scattering mechanisms in gate tunable two dimensional electron gases confined to InAs/(Al,Ga)Sb heterostructures with varying interface roughness and dislocation density is presented. By integrating an insulated gate structure the evolution of the low temperature electron mobility and single-particle lifetime was determined for a previously unexplored density regime, 10{sup 11}–10{sup 12 }cm{sup −2}, in this system. Existing theoretical models were used to analyze the density dependence of the electron mobility and single particle lifetime in InAs quantum wells. Scattering was found to be dominated by charged dislocations and interface roughness. It was demonstrated that the growth of InAs quantum wells on nearly lattice matched GaSb substrate results in fewer dislocations, lower interface roughness, and improved low temperature transport properties compared to growth on lattice mismatched GaAs substrates.

  8. Laser acceleration of electrons in two-dimensionally inhomogeneous plasma at the boundary of a metal foil

    SciTech Connect

    Pugachev, L. P. Andreev, N. E. Levashov, P. R.; Malkov, Yu. A. Stepanov, A. N. Yashunin, D. A.

    2015-07-15

    The electron acceleration mechanism associated with the generation of a plasma wave due to self-modulation instability of laser radiation in a subcritical plasma produced by a laser prepulse coming 10 ns before the arrival of the main intense femtosecond pulse is considered. Three-dimensional particle-in-cell simulations of the interaction of laser radiation with two-dimensionally inhomogeneous subcritical plasma have shown that, for a sufficiently strong plasma inhomogeneity and a sharp front of the laser pulse, efficient plasma wave excitation, electron trapping, and generation of collimated electron beams with energies on the order of 0.2–0.5 MeV can occur. The simulation results agree with experiments on the generation of collimated beams of accelerated electrons from metal targets irradiated by intense femtosecond laser pulses.

  9. Permeability and kinetic coefficients for mesoscale BCF surface step dynamics: Discrete two-dimensional deposition-diffusion equation analysis

    DOE PAGES [OSTI]

    Zhao, Renjie; Evans, James W.; Oliveira, Tiago J.

    2016-04-08

    Here, a discrete version of deposition-diffusion equations appropriate for description of step flow on a vicinal surface is analyzed for a two-dimensional grid of adsorption sites representing the stepped surface and explicitly incorporating kinks along the step edges. Model energetics and kinetics appropriately account for binding of adatoms at steps and kinks, distinct terrace and edge diffusion rates, and possible additional barriers for attachment to steps. Analysis of adatom attachment fluxes as well as limiting values of adatom densities at step edges for nonuniform deposition scenarios allows determination of both permeability and kinetic coefficients. Behavior of these quantities is assessedmore » as a function of key system parameters including kink density, step attachment barriers, and the step edge diffusion rate.« less

  10. TWO-DIMENSIONAL NUMERICAL STUDY FOR RAYLEIGH-TAYLOR AND RICHTMYER-MESHKOV INSTABILITIES IN RELATIVISTIC JETS

    SciTech Connect

    Matsumoto, Jin; Masada, Youhei

    2013-07-20

    We study the stability of a non-rotating single-component jet using two-dimensional special relativistic hydrodynamic simulations. By assuming translational invariance along the jet axis, we exclude the destabilization effect by Kelvin-Helmholtz mode. The nonlinear evolution of the transverse structure of the jet with a normal jet velocity is highlighted. An intriguing finding in our study is that Rayleigh-Taylor and Richtmyer-Meshkov type instabilities can destroy cylindrical jet configuration as a result of spontaneously induced radial oscillating motion. This is powered by in situ energy conversion between the thermal and bulk kinetic energies. The effective inertia ratio of the jet to the surrounding medium {eta} determines a threshold for the onset of instabilities. The condition {eta} < 1 should be satisfied for the transverse structure of the jet being persisted.

  11. Development of an aerosol microphysical module: Aerosol Two-dimensional bin module for foRmation and Aging Simulation (ATRAS)

    SciTech Connect

    Matsui, H.; Koike, Makoto; Kondo, Yutaka; Fast, Jerome D.; Takigawa, M.

    2014-09-30

    Number concentrations, size distributions, and mixing states of aerosols are essential parameters for accurate estimation of aerosol direct and indirect effects. In this study, we developed an aerosol module, designated Aerosol Two-dimensional bin module for foRmation and Aging Simulation (ATRAS), that can represent these parameters explicitly by considering new particle formation (NPF), black carbon (BC) aging, and secondary organic aerosol (SOA) processes. A two-dimensional bin representation is used for particles with dry diameters from 40 nm to 10 m to resolve both aerosol size (12 bins) and BC mixing state (10 bins) for a total of 120 bins. The particles with diameters from 1 to 40 nm are resolved using an additional 8 size bins to calculate NPF. The ATRAS module was implemented in the WRF-chem model and applied to examine the sensitivity of simulated mass, number, size distributions, and optical and radiative parameters of aerosols to NPF, BC aging and SOA processes over East Asia during the spring of 2009. BC absorption enhancement by coating materials was about 50% over East Asia during the spring, and the contribution of SOA processes to the absorption enhancement was estimated to be 10 20% over northern East Asia and 20 35% over southern East Asia. A clear north-south contrast was also found between the impacts of NPF and SOA processes on cloud condensation nuclei (CCN) concentrations: NPF increased CCN concentrations at higher supersaturations (smaller particles) over northern East Asia, whereas SOA increased CCN concentrations at lower supersaturations (larger particles) over southern East Asia. Application of ATRAS to East Asia also showed that the impact of each process on each optical and radiative parameter depended strongly on the process and the parameter in question. The module can be used in the future as a benchmark model to evaluate the accuracy of simpler aerosol models and examine interactions between NPF, BC aging, and SOA processes

  12. Turbulence structure of drag-reducing surfactant solution in two-dimensional channel with additional heat transfer enhancement method

    SciTech Connect

    Li, P.W.; Daisaka, H.; Kawaguchi, Y.; Yabe, A.; Hishida, K.; Maeda, M.

    1999-07-01

    The turbulent characteristics of a surfactant water solution in changing from drag-reducing flow to turbulent flow inside a two-dimensional smooth channel and in changing from turbulent flow to drag-reducing flow in the same channel with a mesh plug were investigated through LDV measurement in this study. The mesh plug was used to exert high shear stress to destroy micelle structures in the surfactant solution so that turbulence could be produced for better heat transfer. The two-component LDV system was installed on a movable platform, which could be moved streamwise of the flow to measure the two-dimensional velocity at different stations downstream from the mesh plug. The surfactant tested was Cetyltrimethyl ammonium chloride (C{sub 16}H{sub 33}N(CH{sub 3}){sub 3}Cl, abbreviated as CTAC). Local tap water was used as solvent and same weight concentration of sodium salicylate was used as the counter-ion material. The investigation of turbulent parameters for the drag-reducing flow with increasing Reynolds number showed that when the Reynolds number exceeded the drag-reducing region, the turbulent character was the same as that of water. The turbulent parameters of surfactant flow downstream the mesh plug showed that the high heat transfer region had the same turbulent intensity as that of water flow. As the critical Reynolds number was approached, it became easier to obtain such a turbulent region by mesh plug. In such cases, the mesh helped to create high wall shear stress and therefore to destroy the super-ordered structures of rod-like micelles for introducing turbulence. However, it was found that the turbulent intensities of the velocity gradually decreased to the same as those of drag-reducing flow downstream from the mesh because the mesh plug only produced a local high shear stress.

  13. Two-dimensional

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The simulated emission lies on a set of circular surfaces, shifted horizontally by a quan- tity varying between the shift of the magnetic axis and the Shafranov shift of the last ...

  14. Comparison of 2D and 3D gamma analyses

    SciTech Connect

    Pulliam, Kiley B.; Huang, Jessie Y.; Howell, Rebecca M.; Followill, David; Kry, Stephen F.; Bosca, Ryan; ODaniel, Jennifer

    2014-02-15

    Purpose: As clinics begin to use 3D metrics for intensity-modulated radiation therapy (IMRT) quality assurance, it must be noted that these metrics will often produce results different from those produced by their 2D counterparts. 3D and 2D gamma analyses would be expected to produce different values, in part because of the different search space available. In the present investigation, the authors compared the results of 2D and 3D gamma analysis (where both datasets were generated in the same manner) for clinical treatment plans. Methods: Fifty IMRT plans were selected from the authors clinical database, and recalculated using Monte Carlo. Treatment planning system-calculated (evaluated dose distributions) and Monte Carlo-recalculated (reference dose distributions) dose distributions were compared using 2D and 3D gamma analysis. This analysis was performed using a variety of dose-difference (5%, 3%, 2%, and 1%) and distance-to-agreement (5, 3, 2, and 1 mm) acceptance criteria, low-dose thresholds (5%, 10%, and 15% of the prescription dose), and data grid sizes (1.0, 1.5, and 3.0 mm). Each comparison was evaluated to determine the average 2D and 3D gamma, lower 95th percentile gamma value, and percentage of pixels passing gamma. Results: The average gamma, lower 95th percentile gamma value, and percentage of passing pixels for each acceptance criterion demonstrated better agreement for 3D than for 2D analysis for every plan comparison. The average difference in the percentage of passing pixels between the 2D and 3D analyses with no low-dose threshold ranged from 0.9% to 2.1%. Similarly, using a low-dose threshold resulted in a difference between the mean 2D and 3D results, ranging from 0.8% to 1.5%. The authors observed no appreciable differences in gamma with changes in the data density (constant difference: 0.8% for 2D vs 3D). Conclusions: The authors found that 3D gamma analysis resulted in up to 2.9% more pixels passing than 2D analysis. It must be noted

  15. Multifractal analysis and modeling of one- and two-dimensional data with discrete wavelet transforms, isotropic or not

    SciTech Connect

    Davis, A.B.

    1998-12-01

    The authors compare several ways of uncovering multifractal properties of data in 1D and 2D using wavelet transforms. The WTMM or (Continuous) Wavelet Transform Maximum Modulus method has been extensively documented and widely applied by Dr. Alain Arneodo`s (Bordeaux) group, to the point where their successes have overshadowed simpler techniques that use the Discrete WT. What the latter lack in robustness is gained in efficiency, thus enabling virtually real-time multifractal analysis of data as it is collected. Another advantage of DWT-based approaches is that tensor products of dyadic and triadic branching schemes enable a straightforward attack on strong anisotropy in natural and artificial 2D random fields.

  16. Thermopower Enhancement by Fractional Layer Control in 2D Oxide

    Office of Scientific and Technical Information (OSTI)

    Superlattices (Journal Article) | SciTech Connect Thermopower Enhancement by Fractional Layer Control in 2D Oxide Superlattices Citation Details In-Document Search Title: Thermopower Enhancement by Fractional Layer Control in 2D Oxide Superlattices Authors: Choi, Woo Seok [1] ; Ohta, Hiromichi [2] ; Lee, Ho Nyung [1] + Show Author Affiliations ORNL Nagoya University, Japan Publication Date: 2014-01-01 OSTI Identifier: 1149750 DOE Contract Number: DE-AC05-00OR22725 Resource Type: Journal

  17. Structural design of 2D materials for electronic and optoelectronic

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    applications | MIT-Harvard Center for Excitonics Structural design of 2D materials for electronic and optoelectronic applications May 19, 2015 at 4:30 pm/36-428 Ju Li Department of Nuclear Science and Engineering and Department of Materials Science and Engineering 009-cropped-small abstract In accordance with Richard Feynman's 1959 statement, "there's plenty of room at the bottom," we explore the structural design space of 2D materials for electronic and optoelectronic

  18. Simultaneous 3D–2D image registration and C-arm calibration: Application to endovascular image-guided interventions

    SciTech Connect

    Mitrović, Uroš; Pernuš, Franjo; Likar, Boštjan; Špiclin, Žiga

    2015-11-15

    Purpose: Three-dimensional to two-dimensional (3D–2D) image registration is a key to fusion and simultaneous visualization of valuable information contained in 3D pre-interventional and 2D intra-interventional images with the final goal of image guidance of a procedure. In this paper, the authors focus on 3D–2D image registration within the context of intracranial endovascular image-guided interventions (EIGIs), where the 3D and 2D images are generally acquired with the same C-arm system. The accuracy and robustness of any 3D–2D registration method, to be used in a clinical setting, is influenced by (1) the method itself, (2) uncertainty of initial pose of the 3D image from which registration starts, (3) uncertainty of C-arm’s geometry and pose, and (4) the number of 2D intra-interventional images used for registration, which is generally one and at most two. The study of these influences requires rigorous and objective validation of any 3D–2D registration method against a highly accurate reference or “gold standard” registration, performed on clinical image datasets acquired in the context of the intervention. Methods: The registration process is split into two sequential, i.e., initial and final, registration stages. The initial stage is either machine-based or template matching. The latter aims to reduce possibly large in-plane translation errors by matching a projection of the 3D vessel model and 2D image. In the final registration stage, four state-of-the-art intrinsic image-based 3D–2D registration methods, which involve simultaneous refinement of rigid-body and C-arm parameters, are evaluated. For objective validation, the authors acquired an image database of 15 patients undergoing cerebral EIGI, for which accurate gold standard registrations were established by fiducial marker coregistration. Results: Based on target registration error, the obtained success rates of 3D to a single 2D image registration after initial machine-based and

  19. 2-D traveling-wave patterns in binary fluid convection

    SciTech Connect

    Surko, C.M.; Porta, A.L.

    1996-12-31

    An overview is presented of recent experiments designed to study two-dimensional traveling-wave convection in binary fluid convection in a large aspect ratio container. Disordered patterns are observed when convection is initiated. As time proceeds, they evolve to more ordered patterns, consisting of several domains of traveling-waves separated by well-defined domain boundaries. The detailed character of the patterns depends sensitively on the Rayleigh number. Numerical techniques are described which were developed to provide a quantitative characterization of the traveling-wave patterns. Applications of complex demodulation techniques are also described, which make a detailed study of the structure and dynamics of the domain boundaries possible.

  20. 2D MHD AND 1D HD MODELS OF A SOLAR FLARE—A COMPREHENSIVE COMPARISON OF THE RESULTS

    SciTech Connect

    Falewicz, R.; Rudawy, P.; Murawski, K.; Srivastava, A. K. E-mail: rudawy@astro.uni.wroc.pl E-mail: asrivastava.app@iitbhu.ac.in

    2015-11-01

    Without any doubt, solar flaring loops possess a multithread internal structure that is poorly resolved, and there are no means to observe heating episodes and thermodynamic evolution of the individual threads. These limitations cause fundamental problems in numerical modeling of flaring loops, such as selection of a structure and a number of threads, and an implementation of a proper model of the energy deposition process. A set of one-dimensional (1D) hydrodynamic and two-dimensional (2D) magnetohydrodynamic models of a flaring loop are developed to compare energy redistribution and plasma dynamics in the course of a prototypical solar flare. Basic parameters of the modeled loop are set according to the progenitor M1.8 flare recorded in AR 10126 on 2002 September 20 between 09:21 UT and 09:50 UT. The nonideal 1D models include thermal conduction and radiative losses of the optically thin plasma as energy-loss mechanisms, while the nonideal 2D models take into account viscosity and thermal conduction as energy-loss mechanisms only. The 2D models have a continuous distribution of the parameters of the plasma across the loop and are powered by varying in time and space along and across the loop heating flux. We show that such 2D models are an extreme borderline case of a multithread internal structure of the flaring loop, with a filling factor equal to 1. Nevertheless, these simple models ensure the general correctness of the obtained results and can be adopted as a correct approximation of the real flaring structures.

  1. Solutions of the two-dimensional Hubbard model: Benchmarks and results from a wide range of numerical algorithms

    SciTech Connect

    LeBlanc, J. P. F.; Antipov, Andrey E.; Becca, Federico; Bulik, Ireneusz W.; Chan, Garnet Kin-Lic; Chung, Chia -Min; Deng, Youjin; Ferrero, Michel; Henderson, Thomas M.; Jiménez-Hoyos, Carlos A.; Kozik, E.; Liu, Xuan -Wen; Millis, Andrew J.; Prokof’ev, N. V.; Qin, Mingpu; Scuseria, Gustavo E.; Shi, Hao; Svistunov, B. V.; Tocchio, Luca F.; Tupitsyn, I. S.; White, Steven R.; Zhang, Shiwei; Zheng, Bo -Xiao; Zhu, Zhenyue; Gull, Emanuel

    2015-12-14

    Numerical results for ground-state and excited-state properties (energies, double occupancies, and Matsubara-axis self-energies) of the single-orbital Hubbard model on a two-dimensional square lattice are presented, in order to provide an assessment of our ability to compute accurate results in the thermodynamic limit. Many methods are employed, including auxiliary-field quantum Monte Carlo, bare and bold-line diagrammatic Monte Carlo, method of dual fermions, density matrix embedding theory, density matrix renormalization group, dynamical cluster approximation, diffusion Monte Carlo within a fixed-node approximation, unrestricted coupled cluster theory, and multireference projected Hartree-Fock methods. Comparison of results obtained by different methods allows for the identification of uncertainties and systematic errors. The importance of extrapolation to converged thermodynamic-limit values is emphasized. Furthermore, cases where agreement between different methods is obtained establish benchmark results that may be useful in the validation of new approaches and the improvement of existing methods.

  2. Hysteresis phenomena of the two dimensional electron gas density in lattice-matched InAlN/GaN heterostructures

    SciTech Connect

    Sang, Ling; Yang, Xuelin Cheng, Jianpeng; Guo, Lei; Hu, Anqi; Xiang, Yong; Yu, Tongjun; Xu, Fujun; Tang, Ning; Jia, Lifang; He, Zhi; Wang, Maojun; Wang, Xinqiang; Shen, Bo; Ge, Weikun

    2015-08-03

    High-temperature transport properties in high-mobility lattice-matched InAlN/GaN heterostructures have been investigated. An interesting hysteresis phenomenon of the two dimensional electron gas (2DEG) density is observed in the temperature-dependent Hall measurements. After high-temperature thermal cycles treatment, the reduction of the 2DEG density is observed, which is more serious in thinner InAlN barrier samples. This reduction can then be recovered by light illumination. We attribute these behaviors to the shallow trap states with energy level above the Fermi level in the GaN buffer layer. The electrons in the 2DEG are thermal-excited when temperature is increased and then trapped by these shallow trap states in the buffer layer, resulting in the reduction and hysteresis phenomenon of their density. Three trap states are observed in the GaN buffer layer and C{sub Ga} may be one of the candidates responsible for the observed behaviors. Our results provide an alternative approach to assess the quality of InAlN/GaN heterostructures for applications in high-temperature electronic devices.

  3. Magnonic band structure, complete bandgap, and collective spin wave excitation in nanoscale two-dimensional magnonic crystals

    SciTech Connect

    Kumar, D.; Barman, A.; K?os, J. W.; Krawczyk, M.

    2014-01-28

    We present the observation of a complete bandgap and collective spin wave excitation in two-dimensional magnonic crystals comprised of arrays of nanoscale antidots and nanodots, respectively. Considering that the frequencies dealt with here fall in the microwave band, these findings can be used for the development of suitable magnonic metamaterials and spin wave based signal processing. We also present the application of a numerical procedure, to compute the dispersion relations of spin waves for any high symmetry direction in the first Brillouin zone. The results obtained from this procedure have been reproduced and verified by the well established plane wave method for an antidot lattice, when magnetization dynamics at antidot boundaries are pinned. The micromagnetic simulation based method can also be used to obtain isofrequency contours of spin waves. Isofrequency contours are analogous of the Fermi surfaces and hence, they have the potential to radicalize our understanding of spin wave dynamics. The physical origin of bands, partial and full magnonic bandgaps have been explained by plotting the spatial distribution of spin wave energy spectral density. Although, unfettered by rigid assumptions and approximations, which afflict most analytical methods used in the study of spin wave dynamics, micromagnetic simulations tend to be computationally demanding. Thus, the observation of collective spin wave excitation in the case of nanodot arrays, which can obviate the need to perform simulations, may also prove to be valuable.

  4. Analysis of photonic band gaps in two-dimensional photonic crystals with rods covered by a thin interfacial layer

    SciTech Connect

    Trifonov, T.; Marsal, L.F.; Pallares, J.; Rodriguez, A.; Alcubilla, R.

    2004-11-15

    We investigate different aspects of the absolute photonic band gap (PBG) formation in two-dimensional photonic structures consisting of rods covered with a thin dielectric film. Specifically, triangular and honeycomb lattices in both complementary arrangements, i.e., air rods drilled in silicon matrix and silicon rods in air, are studied. We consider that the rods are formed of a dielectric core (silicon or air) surrounded by a cladding layer of silicon dioxide (SiO{sub 2}), silicon nitride (Si{sub 3}N{sub 4}), or germanium (Ge). Such photonic lattices present absolute photonic band gaps, and we study the evolution of these gaps as functions of the cladding material and thickness. Our results show that in the case of air rods in dielectric media the existence of dielectric cladding reduces the absolute gap width and may cause complete closure of the gap if thick layers are considered. For the case of dielectric rods in air, however, the existence of a cladding layer can be advantageous and larger absolute PBG's can be achieved.

  5. Apparatus and method for heterodyne-generated two-dimensional detector array using a single element detector

    DOEpatents

    Strauss, Charlie E.

    1997-01-01

    Apparatus and method for heterodyne-generated, two-dimensional detector array using a single detector. Synthetic-array heterodyne detection, permits a single-element optical detector to behave as though it were divided into an array of separate heterodyne detector elements. A fifteen-element synthetic array has successfully been experimentally realized on a single-element detector, permitting all of the array elements to be read out continuously and in parallel from one electrical connection. A CO.sub.2 laser and a single-element HgCdTe photodiode are employed. A different heterodyne local oscillator frequency is incident upon the spatially resolvable regions of the detector surface. Thus, different regions are mapped to different heterodyne beat frequencies. One can determine where the photons were incident on the detector surface even though a single electrical connection to the detector is used. This also prevents the destructive interference that occurs when multiple speckles are imaged (similar to spatial diversity), In coherent LIDAR this permits a larger field of view. An acoustooptic modulator generates the local oscillator frequencies and can achieve adequate spatial separation of optical frequencies of the order of a megahertz apart.

  6. Apparatus and method for heterodyne-generated two-dimensional detector array using a single element detector

    DOEpatents

    Strauss, C.E.

    1997-11-18

    Apparatus and method are disclosed for heterodyne-generated, two-dimensional detector array using a single detector. Synthetic-array heterodyne detection, permits a single-element optical detector to behave as though it were divided into an array of separate heterodyne detector elements. A fifteen-element synthetic array has successfully been experimentally realized on a single-element detector, permitting all of the array elements to be read out continuously and in parallel from one electrical connection. A CO{sub 2} laser and a single-element HgCdTe photodiode are employed. A different heterodyne local oscillator frequency is incident upon the spatially resolvable regions of the detector surface. Thus, different regions are mapped to different heterodyne beat frequencies. One can determine where the photons were incident on the detector surface even though a single electrical connection to the detector is used. This also prevents the destructive interference that occurs when multiple speckles are imaged (similar to spatial diversity), In coherent LIDAR this permits a larger field of view. An acoustooptic modulator generates the local oscillator frequencies and can achieve adequate spatial separation of optical frequencies of the order of a megahertz apart. 4 figs.

  7. Solutions of the two-dimensional Hubbard model: Benchmarks and results from a wide range of numerical algorithms

    DOE PAGES [OSTI]

    LeBlanc, J. P. F.; Antipov, Andrey E.; Becca, Federico; Bulik, Ireneusz W.; Chan, Garnet Kin-Lic; Chung, Chia -Min; Deng, Youjin; Ferrero, Michel; Henderson, Thomas M.; Jiménez-Hoyos, Carlos A.; et al

    2015-12-14

    Numerical results for ground-state and excited-state properties (energies, double occupancies, and Matsubara-axis self-energies) of the single-orbital Hubbard model on a two-dimensional square lattice are presented, in order to provide an assessment of our ability to compute accurate results in the thermodynamic limit. Many methods are employed, including auxiliary-field quantum Monte Carlo, bare and bold-line diagrammatic Monte Carlo, method of dual fermions, density matrix embedding theory, density matrix renormalization group, dynamical cluster approximation, diffusion Monte Carlo within a fixed-node approximation, unrestricted coupled cluster theory, and multireference projected Hartree-Fock methods. Comparison of results obtained by different methods allows for the identification ofmore » uncertainties and systematic errors. The importance of extrapolation to converged thermodynamic-limit values is emphasized. Furthermore, cases where agreement between different methods is obtained establish benchmark results that may be useful in the validation of new approaches and the improvement of existing methods.« less

  8. Trigonometrical sums connected with the chiral Potts model, Verlinde dimension formula, two-dimensional resistor network, and number theory

    SciTech Connect

    Chair, Noureddine

    2014-02-15

    We have recently developed methods for obtaining exact two-point resistance of the complete graph minus N edges. We use these methods to obtain closed formulas of certain trigonometrical sums that arise in connection with one-dimensional lattice, in proving Scotts conjecture on permanent of Cauchy matrix, and in the perturbative chiral Potts model. The generalized trigonometrical sums of the chiral Potts model are shown to satisfy recursion formulas that are transparent and direct, and differ from those of Gervois and Mehta. By making a change of variables in these recursion formulas, the dimension of the space of conformal blocks of SU(2) and SO(3) WZW models may be computed recursively. Our methods are then extended to compute the corner-to-corner resistance, and the Kirchhoff index of the first non-trivial two-dimensional resistor network, 2N. Finally, we obtain new closed formulas for variant of trigonometrical sums, some of which appear in connection with number theory. -- Highlights: Alternative derivation of certain trigonometrical sums of the chiral Potts model are given. Generalization of these trigonometrical sums satisfy recursion formulas. The dimension of the space of conformal blocks may be computed from these recursions. Exact corner-to-corner resistance, the Kirchhoff index of 2N are given.

  9. Berry phase mechanism of the anomalous Hall effect in a disordered two-dimensional magnetic semiconductor structure.

    DOE PAGES [OSTI]

    Oveshnikov, L. N.; Kulbachinskii, V. A.; Davydov, A. B.; Aronzon, B. A.; Rozhansky, I. V.; Averkiev, N. S.; Kugel, K. I.; Tripathi, V.

    2015-11-24

    In this study, the anomalous Hall effect (AHE) arises from the interplay of spin-orbit interactions and ferromagnetic order and is a potentially useful probe of electron spin polarization, especially in nanoscale systems where direct measurement is not feasible. While AHE is rather well-understood in metallic ferromagnets, much less is known about the relevance of different physical mechanisms governing AHE in insulators. As ferromagnetic insulators, but not metals, lend themselves to gatecontrol of electron spin polarization, understanding AHE in the insulating state is valuable from the point of view of spintronic applications. Among the mechanisms proposed in the literature for AHEmore » in insulators, the one related to a geometric (Berry) phase effect has been elusive in past studies. The recent discovery of quantized AHE in magnetically doped topological insulators - essentially a Berry phase effect - provides strong additional motivation to undertake more careful search for geometric phase effects in AHE in the magnetic semiconductors. Here we report our experiments on the temperature and magnetic field dependences of AHE in insulating, strongly-disordered two-dimensional Mn delta-doped semiconductor heterostructures in the hopping regime. In particular, it is shown that at sufficiently low temperatures, the mechanism of AHE related to the Berry phase is favoured.« less

  10. Berry phase mechanism of the anomalous Hall effect in a disordered two-dimensional magnetic semiconductor structure.

    SciTech Connect

    Oveshnikov, L. N.; Kulbachinskii, V. A.; Davydov, A. B.; Aronzon, B. A.; Rozhansky, I. V.; Averkiev, N. S.; Kugel, K. I.; Tripathi, V.

    2015-11-24

    In this study, the anomalous Hall effect (AHE) arises from the interplay of spin-orbit interactions and ferromagnetic order and is a potentially useful probe of electron spin polarization, especially in nanoscale systems where direct measurement is not feasible. While AHE is rather well-understood in metallic ferromagnets, much less is known about the relevance of different physical mechanisms governing AHE in insulators. As ferromagnetic insulators, but not metals, lend themselves to gatecontrol of electron spin polarization, understanding AHE in the insulating state is valuable from the point of view of spintronic applications. Among the mechanisms proposed in the literature for AHE in insulators, the one related to a geometric (Berry) phase effect has been elusive in past studies. The recent discovery of quantized AHE in magnetically doped topological insulators - essentially a Berry phase effect - provides strong additional motivation to undertake more careful search for geometric phase effects in AHE in the magnetic semiconductors. Here we report our experiments on the temperature and magnetic field dependences of AHE in insulating, strongly-disordered two-dimensional Mn delta-doped semiconductor heterostructures in the hopping regime. In particular, it is shown that at sufficiently low temperatures, the mechanism of AHE related to the Berry phase is favoured.

  11. Using comprehensive two-dimensional gas chromatography to explore the geochemistry of the Santa Barbara oil seeps

    SciTech Connect

    Reddy, Christopher; Nelson, Robert

    2013-03-27

    The development of comprehensive two-dimensional gas chromatography (GC x GC) has expanded the analytical window for studying complex mixtures like oil. Compared to traditional gas chromatography, this technology separates and resolves at least an order of magnitude more compounds, has a much larger signal to noise ratio, and sorts compounds based on their chemical class; hence, providing highly refined inventories of petroleum hydrocarbons in geochemical samples that was previously unattainable. In addition to the increased resolution afforded by GC x GC, the resulting chromatograms have been used to estimate the liquid vapor pressures, aqueous solubilities, octanol-water partition coefficients, and vaporization enthalpies of petroleum hydrocarbons. With these relationships, powerful and incisive analyses of phase-transfer processes affecting petroleum hydrocarbon mixtures in the environment are available. For example, GC x GC retention data has been used to quantitatively deconvolve the effects of phase transfer processes such as water washing and evaporation. In short, the positive attributes of GC x GC-analysis have led to a methodology that has revolutionized the analysis of petroleum hydrocarbons. Overall, this research has opened numerous fields of study on the biogeochemical "genetics" (referred to as petroleomics) of petroleum samples in both subsurface and surface environments. Furthermore, these new findings have already been applied to the behavior of oil at other seeps as well, for petroleum exploration and oil spill studies.

  12. Natural abundance 17O DNP two-dimensional and surface-enhanced NMR spectroscopy

    SciTech Connect

    Perras, Frédéric A.; Kobayashi, Takeshi; Pruski, Marek

    2015-06-22

    Due to its extremely low natural abundance and quadrupolar nature, the 17O nuclide is very rarely used for spectroscopic investigation of solids by NMR without isotope enrichment. Additionally, the applicability of dynamic nuclear polarization (DNP), which leads to sensitivity enhancements of 2 orders of magnitude, to 17O is wrought with challenges due to the lack of spin diffusion and low polarization transfer efficiency from 1H. Here, we demonstrate new DNP-based measurements that extend 17O solid-state NMR beyond its current capabilities. The use of the PRESTO technique instead of conventional 1H–17O cross-polarization greatly improves the sensitivity and enables the facile measurement of undistorted line shapes and two-dimensional 1H–17O HETCOR NMR spectra as well as accurate internuclear distance measurements at natural abundance. This was applied for distinguishing hydrogen-bonded and lone 17O sites on the surface of silica gel; the one-dimensional spectrum of which could not be used to extract such detail. As a result, this greatly enhanced sensitivity has enabled, for the first time, the detection of surface hydroxyl sites on mesoporous silica at natural abundance, thereby extending the concept of DNP surface-enhanced NMR spectroscopy to the 17O nuclide.

  13. On drag and lift forces in two-dimensional flows of a particulate mixture: A theoretical study

    SciTech Connect

    Massoudi, M.

    2006-06-01

    In this paper we propose and derive expressions for the drag and lift forces in a two-phase particulate mixture. The analysis is limited to two-dimensional laminar flows. In the Section after the Introduction, a brief review of the single particle approach is provided; it is then shown that in most multiphase flow problems some generalization of these forces acting on a single particle is used. We then describe a different way of defining the lift force and the drag force, an approach used in non-Newtonian fluid mechanics. In the following Section, the essential equations of Mixture Theory are provided and the specific approach of [1] is used. In this scheme, the lift force is part of the interaction mechanisms, which are to be modeled as constitutive parameters. In the final Section, we derive an expression for the lift force, whereby it is shown that the normal component of the force acting on the body, obtained by integrating the traction vector of the mixture acting on a single isolated particle, will give us the desired expression for the lift force in multi-component flows.

  14. Two-dimensional s-polarized solitary waves in plasmas. II. Stability, collisions, electromagnetic bursts, and post-soliton evolution

    SciTech Connect

    Sanchez-Arriaga, G.; Lefebvre, E.

    2011-09-15

    The dynamics of two-dimensional s-polarized solitary waves is investigated with the aid of particle-in-cell (PIC) simulations. Instead of the usual excitation of the waves with a laser pulse, the PIC code was directly initialized with the numerical solutions from the fluid plasma model. This technique allows the analysis of different scenarios including the theoretical problems of the solitary wave stability and their collision as well as features already measured during laser-plasma experiments such as the emission of electromagnetic bursts when the waves reach the plasma-vacuum interface, or their expansion on the ion time scale, usually named post-soliton evolution. Waves with a single density depression are stable whereas multihump solutions decay to several waves. Contrary to solitons, two waves always interact through a force that depends on their relative phases, their amplitudes, and the distance between them. On the other hand, the radiation pattern at the plasma-vacuum interface was characterized, and the evolution of the diameter of different waves was computed and compared with the ''snow plow'' model.

  15. Two-dimensional profile measurement of plasma parameters in radio frequency-driven argon atmospheric pressure plasma jet

    SciTech Connect

    Seo, B. H.; Kim, J. H.; Kim, D. W.; You, S. J.

    2015-09-15

    The two-dimensional profiles of the electron density, electron temperature, neutral translational temperature, and molecular rotational temperature are investigated in an argon atmospheric pressure plasma jet, which is driven by the radio frequency of 13.56 MHz by means of the laser scattering methods of Thomson, Rayleigh, and Raman. All measured parameters have maximum values at the center of the discharge and decrease toward the plasma edge. The results for the electron temperature profile are contrary to the results for the microwave-driven plasma. From our experimental results, the profiles of the plasma parameters arise from the radial contraction of plasmas and the time averaged profile of the electric field, which is obtained by a microwave simulation performed under identical conditions to the plasma jet. In the case of the neutral temperature, a higher translational temperature than the rotational temperature is measured, and its discrepancy is tentatively explained in terms of the low ion-neutral charge exchange rate and the additional degrees of freedom of the molecules. The description of our experimental results and the underlying physics are addressed in detail.

  16. Detection of dark states in two-dimensional electronic photon-echo signals via ground-state coherence

    SciTech Connect

    Egorova, Dassia

    2015-06-07

    Several recent experiments report on possibility of dark-state detection by means of so called beating maps of two-dimensional photon-echo spectroscopy [Ostroumov et al., Science 340, 52 (2013); Bakulin et al., Ultrafast Phenomena XIX (Springer International Publishing, 2015)]. The main idea of this detection scheme is to use coherence induced upon the laser excitation as a very sensitive probe. In this study, we investigate the performance of ground-state coherence in the detection of dark electronic states. For this purpose, we simulate beating maps of several models where the excited-state coherence can be hardly detected and is assumed not to contribute to the beating maps. The models represent strongly coupled electron-nuclear dynamics involving avoided crossings and conical intersections. In all the models, the initially populated optically accessible excited state decays to a lower-lying dark state within few hundreds femtoseconds. We address the role of Raman modes and of interstate-coupling nature. Our findings suggest that the presence of low-frequency Raman active modes significantly increases the chances for detection of dark states populated via avoided crossings, whereas conical intersections represent a more challenging task.

  17. The inversion layer of electric fields and electron phase-space-hole structure during two-dimensional collisionless magnetic reconnection

    SciTech Connect

    Chen Lijen; Lefebvre, Bertrand; Torbert, Roy B.; Daughton, William S.

    2011-01-15

    Based on two-dimensional fully kinetic simulations that resolve the electron diffusion layer in undriven collisionless magnetic reconnection with zero guide field, this paper reports the existence and evolution of an inversion layer of bipolar electric fields, its corresponding phase-space structure (an electron-hole layer), and the implication to collisionless dissipation. The inversion electric field layer is embedded in the layer of bipolar Hall electric field and extends throughout the entire length of the electron diffusion layer. The electron phase-space hole structure spontaneously arises during the explosive growth phase when there exist significant inflows into the reconnection layer, and electrons perform meandering orbits across the layer while being cyclotron-turned toward the outflow directions. The cyclotron turning of meandering electrons by the magnetic field normal to the reconnection layer is shown to be a primary factor limiting the current density in the region where the reconnection electric field is balanced by the gradient (along the current sheet normal) of the off-diagonal electron pressure-tensor.

  18. Impact of electric-field dependent dielectric constants on two-dimensional electron gases in complex oxides

    SciTech Connect

    Peelaers, H.; Gordon, L.; Steiauf, D.; Janotti, A.; Van de Walle, C. G.; Krishnaswamy, K.; Sarwe, A.

    2015-11-02

    High-density two-dimensional electron gas (2DEG) can be formed at complex oxide interfaces such as SrTiO{sub 3}/GdTiO{sub 3} and SrTiO{sub 3}/LaAlO{sub 3}. The electric field in the vicinity of the interface depends on the dielectric properties of the material as well as on the electron distribution. However, it is known that electric fields can strongly modify the dielectric constant of SrTiO{sub 3} as well as other complex oxides. Solving the electrostatic problem thus requires a self-consistent approach in which the dielectric constant varies according to the local magnitude of the field. We have implemented the field dependence of the dielectric constant in a Schrödinger-Poisson solver in order to study its effect on the electron distribution in a 2DEG. Using the SrTiO{sub 3}/GdTiO{sub 3} interface as an example, we demonstrate that including the field dependence results in the 2DEG being confined closer to the interface compared to assuming a single field-independent value for the dielectric constant. Our conclusions also apply to SrTiO{sub 3}/LaAlO{sub 3} as well as other similar interfaces.

  19. One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4

    DOE PAGES [OSTI]

    Disseler, S. M.; Chen, Y.; Yeo, S.; Gasparovic, G.; Piccoli, P. M. B.; Schultz, A. J.; Qiu, Y.; Huang, Q.; Cheong, S. -W.; Ratcliff, W.

    2015-12-08

    In this paper we report on the intriguing evolution of the dynamical spin correlations of the frustrated spinel ZnMn2O4. Inelastic neutron scattering and magnetization studies reveal that the dynamical correlations at high temperatures are 1D. At lower temperature, these dynamical correlations become 2D. Surprisingly, the dynamical correlations condense into a quasi 2D Ising-like ordered state, making this a rare observation of two dimensional order on the spinel lattice. Remarkably, 3D ordering is not observed down to temperatures as low as 300 mK. This unprecedented dimensional crossover stems from frustrated exchange couplings due to the huge Jahn-Teller distortions around Mn3+ ionsmore » on the spinel lattice.« less

  20. One Dimensional(1D)-to-2D Crossover of Spin Correlations in the 3D Magnet ZnMn2O4

    SciTech Connect

    Disseler, S. M.; Chen, Y.; Yeo, S.; Gasparovic, G.; Piccoli, P. M. B.; Schultz, A. J.; Qiu, Y.; Huang, Q.; Cheong, S. -W.; Ratcliff, W.

    2015-12-08

    In this paper we report on the intriguing evolution of the dynamical spin correlations of the frustrated spinel ZnMn2O4. Inelastic neutron scattering and magnetization studies reveal that the dynamical correlations at high temperatures are 1D. At lower temperature, these dynamical correlations become 2D. Surprisingly, the dynamical correlations condense into a quasi 2D Ising-like ordered state, making this a rare observation of two dimensional order on the spinel lattice. Remarkably, 3D ordering is not observed down to temperatures as low as 300 mK. This unprecedented dimensional crossover stems from frustrated exchange couplings due to the huge Jahn-Teller distortions around Mn3+ ions on the spinel lattice.

  1. Commercial and Cost Effective Production of Two-Dimensional Read-Out Boards for Sub-Atomic Particle Detectors

    SciTech Connect

    Crary, David; Majka, Richard

    2010-10-22

    We report results from research aimed at developing and demonstrating production of 2-D readout structures for GEM (Gas Electron Multiplier) charged particle tracking chambers at Tech-Etch. Readout boards of two types, bi-planar and single plane, were fabricated and evaluated. The results show that Tech-Etch can produce suitable boards of either type however the single plane board has a number of advantages both in production and use that will likely make it the preferred choice for GEM tracking chambers.

  2. Equation of state of a weakly interacting two-dimensional Bose gas studied at zero temperature by means of quantum Monte Carlo methods

    SciTech Connect

    Astrakharchik, G. E.; Boronat, J.; Casulleras, J.; Kurbakov, I. L.; Lozovik, Yu. E.

    2009-05-15

    The equation of state of a weakly interacting two-dimensional Bose gas is studied at zero temperature by means of quantum Monte Carlo methods. Going down to as low densities as na{sup 2}{proportional_to}10{sup -100} permits us to obtain agreement on beyond mean-field level between predictions of perturbative methods and direct many-body numerical simulation, thus providing an answer to the fundamental question of the equation of state of a two-dimensional dilute Bose gas in the universal regime (i.e., entirely described by the gas parameter na{sup 2}). We also show that the measure of the frequency of a breathing collective oscillation in a trap at very low densities can be used to test the universal equation of state of a two-dimensional Bose gas.

  3. Two-dimensional equations of the surface harmonics method for solving problems of spatial neutron kinetics in square-lattice reactors

    SciTech Connect

    Boyarinov, V. F. Kondrushin, A. E. Fomichenko, P. A.

    2014-12-15

    Two-dimensional time-dependent finite-difference equations of the surface harmonics method (SHM) for the description of the neutron transport are derived for square-lattice reactors. These equations are implemented in the SUHAM-TD code. Verification of the derived equations and the developed code are performed by the example of known test problems, and the potential and efficiency of the SHM as applied to the solution of the time-dependent neutron transport equation in the diffusion approximation in two-dimensional geometry are demonstrated. These results show the substantial advantage of SHM over direct finite-difference modeling in computational costs.

  4. Magnetic Correlations in the Quasi-Two-Dimensional Semiconducting Ferromagnet CrSiTe3

    SciTech Connect

    Williams, Travis J.; Aczel, Adam A.; Lumsden, Mark D.; Nagler, Stephen E.; Stone, Matthew B.; Yan, Jiaqiang -Q.; Mandrus, D.

    2015-10-02

    Intrinsic, 2D ferromagnetic semiconductors are an important class of materials for overcoming dilute magnetic semiconductors’ limitations for spintronics. CrSiTe3 is a particularly interesting material of this class, since it can likely be exfoliated to single layers, for which Tc is predicted to increase dramatically. Establishing the nature of the bulk material’s magnetism is necessary for understanding the thin-film magnetic behavior and the material’s possible applications. In this work, we use elastic and inelastic neutron scattering to measure the magnetic properties of single crystalline CrSiTe3. We find a very small single ion anisotropy that favors magnetic ordering along the c-axis and that the measured spin waves fit well to a model in which the moments are only weakly coupled along that direction. Then, we find that both static and dynamic correlations persist within the ab-plane up to at least 300 K, which is strong evidence of the material's 2D characteristics that are relevant for future studies on thin film and monolayer samples.

  5. Commercial and Cost Effective Production of Two-Dimensional Read-Out Boards for Sub-Atomic Particle Detectors

    SciTech Connect

    Crary, David; Majka, Richard

    2010-10-22

    Tech-Etch has considerable experience in numerous related high precision etched Kapton® products including production of GEM foils. The required precision and production process for 2-D readout boards is similar to that developed for GEM foil production. Additionally, Tech-Etch has strong ties with several research institutions (namely Brookhaven National Laboratory, MIT and Yale University) that can help design and evaluate the performance of the readout boards produced at Tech-Etch. Since Tech-Etch is a small company, it also has the capability to produce a large variety of part configurations, optimized for a particular customer's requirements. We report results from research aimed at developing and demonstrating production of 2-D readout structures for GEM (Gas Electron Multiplier) charged particle tracking chambers at Tech-Etch. Readout boards of two types, bi-planar and single plane, were fabricated and evaluated. The results show that Tech-Etch can produce suitable boards of either type however the single plane board has a number of advantages both in production and use that will likely make it the preferred choice for GEM tracking chambers.

  6. Two-dimensional wave-number spectral analysis techniques for phase contrast imaging turbulence imaging data on large helical device

    SciTech Connect

    Michael, C. A.; Tanaka, K.; Kawahata, K.; Vyacheslavov, L.; Sanin, A.

    2015-09-15

    An analysis method for unfolding the spatially resolved wave-number spectrum and phase velocity from the 2D CO{sub 2} laser phase contrast imaging system on the large helical device is described. This is based on the magnetic shear technique which identifies propagation direction from 2D spatial Fourier analysis of images detected by a 6 × 8 detector array. Because the strongest modes have wave-number at the lower end of the instrumental k range, high resolution spectral techniques are necessary to clearly resolve the propagation direction and hence the spatial distribution of fluctuations along the probing laser beam. Multiple-spatial point cross-correlation averaging is applied before calculating the spatial power spectrum. Different methods are compared, and it is found that the maximum entropy method (MEM) gives best results. The possible generation of artifacts from the over-narrowing of spectra are investigated and found not to be a significant problem. The spatial resolution Δρ (normalized radius) around the peak wave-number, for conventional Fourier analysis, is ∼0.5, making physical interpretation difficult, while for MEM, Δρ ∼ 0.1.

  7. Images of gravitational and magnetic phenomena derived from two-dimensional back-projection Doppler tomography of interacting binary stars

    SciTech Connect

    Richards, Mercedes T.; Cocking, Alexander S.; Fisher, John G.; Conover, Marshall J. E-mail: asc5097@psu.edu

    2014-11-10

    We have used two-dimensional back-projection Doppler tomography as a tool to examine the influence of gravitational and magnetic phenomena in interacting binaries that undergo mass transfer from a magnetically active star onto a non-magnetic main-sequence star. This multitiered study of over 1300 time-resolved spectra of 13 Algol binaries involved calculations of the predicted dynamical behavior of the gravitational flow and the dynamics at the impact site, analysis of the velocity images constructed from tomography, and the influence on the tomograms of orbital inclination, systemic velocity, orbital coverage, and shadowing. The H? tomograms revealed eight sources: chromospheric emission, a gas stream along the gravitational trajectory, a star-stream impact region, a bulge of absorption or emission around the mass-gaining star, a Keplerian accretion disk, an absorption zone associated with hotter gas, a disk-stream impact region, and a hot spot where the stream strikes the edge of a disk. We described several methods used to extract the physical properties of the emission sources directly from the velocity images, including S-wave analysis, the creation of simulated velocity tomograms from hydrodynamic simulations, and the use of synthetic spectra with tomography to sequentially extract the separate sources of emission from the velocity image. In summary, the tomography images have revealed results that cannot be explained solely by gravitational effects: chromospheric emission moving with the mass-losing star, a gas stream deflected from the gravitational trajectory, and alternating behavior between stream state and disk state. Our results demonstrate that magnetic effects cannot be ignored in these interacting binaries.

  8. Non-intrusive, high-resolution, real-time, two-dimensional imaging of multiphase materials using acoustic array sensors

    SciTech Connect

    Cassiède, M.; Shaw, J. M.

    2015-04-15

    Two parallel multi-element ultrasonic acoustic arrays combined with sets of focal laws for acoustic signal generation and a classical tomographic inversion algorithm are used to generate real-time two-dimensional micro seismic acoustic images of multiphase materials. Proof of concept and calibration measurements were performed for single phase and two phase liquids, uniform polyvinyl chloride (PVC) plates, and aluminum cylinders imbedded in PVC plates. Measurement artefacts, arising from the limited range of viewing angles, and the compromise between data acquisition rate and image quality are discussed. The angle range of scanning and the image resolution were varied, and the effects on the quality of the reproduction of the speed of sound profiles of model solids and liquids with known geometries and compositions were analysed in detail. The best image quality results were obtained for a scanning angle range of [−35°, 35°] at a step size of 2.5° post processed to generate images on a 40 μm square grid. The data acquisition time for high quality images with a 30 mm × 40 mm view field is 10 min. Representation of two-phase solids with large differences in speed of sound between phases and where one phase is dispersed in the form of macroscopic objects (greater than 1 mm in diameter) proved to be the most difficult to image accurately. Liquid-liquid and liquid-vapor phase boundaries, in micro porous solids by contrast, were more readily defined. Displacement of air by water and water by heptane in natural porous limestone provides illustrative kinetic examples. Measurement results with these realistic cases demonstrate the feasibility of the technique to monitor in real time and on the micrometer length scale local composition and flow of organic liquids in inorganic porous media, one of many envisioned engineering applications. Improvement of data acquisition rate is an area for future collaborative study.

  9. Two-dimensional Vlasov simulation of electron plasma wave trapping, wavefront bowing, self-focusing, and sideloss

    SciTech Connect

    Banks, J. W.; Berger, R. L.; Cohen, B. I.; Hittinger, J. A. F.; Brunner, S.

    2011-05-15

    Two-dimensional Vlasov simulations of nonlinear electron plasma waves are presented, in which the interplay of linear and nonlinear kinetic effects is evident. The plasma wave is created with an external traveling wave potential with a transverse envelope of width {Delta}y such that thermal electrons transit the wave in a ''sideloss'' time, t{sub sl{approx}{Delta}}y/v{sub e}. Here, v{sub e} is the electron thermal velocity. The quasisteady distribution of trapped electrons and its self-consistent plasma wave are studied after the external field is turned off. In cases of particular interest, the bounce frequency, {omega}{sub be}=k{radical}(e{phi}/m{sub e}), satisfies the trapping condition {omega}{sub be}t{sub sl}>2{pi} such that the wave frequency is nonlinearly downshifted by an amount proportional to the number of trapped electrons. Here, k is the wavenumber of the plasma wave and {phi} is its electric potential. For sufficiently short times, the magnitude of the negative frequency shift is a local function of {phi}. Because the trapping frequency shift is negative, the phase of the wave on axis lags the off-axis phase if the trapping nonlinearity dominates linear wave diffraction. In this case, the phasefronts are curved in a focusing sense. In the opposite limit, the phasefronts are curved in a defocusing sense. Analysis and simulations in which the wave amplitude and transverse width are varied establish criteria for the development of each type of wavefront. The damping and trapped-electron-induced focusing of the finite-amplitude electron plasma wave are also simulated. The damping rate of the field energy of the wave is found to be about the sideloss rate, {nu}{sub e{approx}}t{sub sl}{sup -1}. For large wave amplitudes or widths {Delta}y, a trapping-induced self-focusing of the wave is demonstrated.

  10. Spatially separated excitons in 2D and 1D

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    separated excitons in 2D and 1D David Abergel March 10th, 2015 D.S.L. Abergel 3/10/15 1 / 24 Outline 1 Introduction 2 Spatially separated excitons in 2D - The role of disorder 3 Spatially separated excitons in 1D D.S.L. Abergel 3/10/15 2 / 24 Introduction D.S.L. Abergel 3/10/15 3 / 24 The fundamental idea Key ingredients: Independent contacts to each layer High degree of nesting of Fermi surfaces Low SP tunneling rate between layers Picture credit: Kharitonov et al., Phys. Rev. B 78 Phase

  11. Radiative heat transfer in 2D Dirac materials

    SciTech Connect

    Rodriguez-López, Pablo; Tse, Wang -Kong; Dalvit, Diego A. R.

    2015-05-12

    We compute the radiative heat transfer between two sheets of 2D Dirac materials, including topological Chern insulators and graphene, within the framework of the local approximation for the optical response of these materials. In this approximation, which neglects spatial dispersion, we derive both numerically and analytically the short-distance asymptotic of the near-field heat transfer in these systems, and show that it scales as the inverse of the distance between the two sheets. In conclusion, we discuss the limitations to the validity of this scaling law imposed by spatial dispersion in 2D Dirac materials.

  12. A 2D/1D coupling neutron transport method based on the matrix MOC and NEM methods

    SciTech Connect

    Zhang, H.; Zheng, Y.; Wu, H.; Cao, L.

    2013-07-01

    A new 2D/1D coupling method based on the matrix MOC method (MMOC) and nodal expansion method (NEM) is proposed for solving the three-dimensional heterogeneous neutron transport problem. The MMOC method, used for radial two-dimensional calculation, constructs a response matrix between source and flux with only one sweep and then solves the linear system by using the restarted GMRES algorithm instead of the traditional trajectory sweeping process during within-group iteration for angular flux update. Long characteristics are generated by using the customization of commercial software AutoCAD. A one-dimensional diffusion calculation is carried out in the axial direction by employing the NEM method. The 2D and ID solutions are coupled through the transverse leakage items. The 3D CMFD method is used to ensure the global neutron balance and adjust the different convergence properties of the radial and axial solvers. A computational code is developed based on these theories. Two benchmarks are calculated to verify the coupling method and the code. It is observed that the corresponding numerical results agree well with references, which indicates that the new method is capable of solving the 3D heterogeneous neutron transport problem directly. (authors)

  13. Probing carrier dynamics of individual layers in a heterostructure using transient reflectivity

    SciTech Connect

    Khan, Salahuddin; Jayabalan, J. Singh, Asha; Yogi, Rachana; Chari, Rama

    2015-09-21

    We report the wavelength dependent transient reflectivity measurements in AlGaAs-GaAs heterostructures having two-dimensional electron (or hole) gas near the interface. Using a multilayer model for transient reflectivity, we show that the magnitude and sign of contributions from the carriers in two-dimensional electron (or hole) gas and GaAs to the total signal depends on the wavelength. Further, it has been shown that it is possible to study the carrier dynamics in a given layer of a heterostructure by performing transient reflectivity at specific wavelengths.

  14. 110th Congress 2D Session H.R. 5746

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    VerDate Aug 31 2005 03:31 Apr 11, 2008 Jkt 069200 PO 00000 Frm 00001 Fmt 6652 Sfmt 6201 E:BILLSH5746.IH H5746 wwoods2 on PRODPC68 with BILLS I 110TH CONGRESS 2D SESSION H. R. ...

  15. Microscopic entropy of nondilatonic branes: A 2D approach

    SciTech Connect

    Cadoni, Mariano; Serra, Nicola

    2004-12-15

    We investigate nondilatonic p-branes in the near-extremal, near-horizon regime. A two-dimensional gravity model, obtained from dimensional reduction, gives an effective description of the brane. We show that the AdS{sub p+2}/CFT{sub p+1} correspondence at finite temperature admits an effective description in terms of a AdS{sub 2}/CFT{sub 1} duality endowed with a scalar field, which breaks the conformal symmetry and generates a nonvanishing central charge. The entropy of the CFT{sub 1} is computed using Cardy formula. Fixing in a natural way a free, dimensionless, parameter introduced in the model by a renormalization procedure, we find exact agreement between the CFT{sub 1} entropy and the Bekenstein-Hawking entropy of the brane.

  16. Tunable exchange bias-like effect in patterned hard-soft two-dimensional lateral composites with perpendicular magnetic anisotropy

    SciTech Connect

    Hierro-Rodriguez, A. Alvarez-Prado, L. M.; Martín, J. I.; Alameda, J. M.; Teixeira, J. M.; Vélez, M.

    2014-09-08

    Patterned hard-soft 2D magnetic lateral composites have been fabricated by e-beam lithography plus dry etching techniques on sputter-deposited NdCo{sub 5} thin films with perpendicular magnetic anisotropy. Their magnetic behavior is strongly thickness dependent due to the interplay between out-of-plane anisotropy and magnetostatic energy. Thus, the spatial modulation of thicknesses leads to an exchange coupled system with hard/soft magnetic regions in which rotatable anisotropy of the thicker elements provides an extra tool to design the global magnetic behavior of the patterned lateral composite. Kerr microscopy studies (domain imaging and magneto-optical Kerr effect magnetometry) reveal that the resulting hysteresis loops exhibit a tunable exchange bias-like shift that can be switched on/off by the applied magnetic field.

  17. Two-dimensional simulations of thermonuclear burn in ignition-scale inertial confinement fusion targets under compressed axial magnetic fields

    SciTech Connect

    Perkins, L. J.; Logan, B. G.; Zimmerman, G. B.; Werner, C. J.

    2013-07-15

    We report for the first time on full 2-D radiation-hydrodynamic implosion simulations that explore the impact of highly compressed imposed magnetic fields on the ignition and burn of perturbed spherical implosions of ignition-scale cryogenic capsules. Using perturbations that highly convolute the cold fuel boundary of the hotspot and prevent ignition without applied fields, we impose initial axial seed fields of 20100 T (potentially attainable using present experimental methods) that compress to greater than 4 10{sup 4} T (400 MG) under implosion, thereby relaxing hotspot areal densities and pressures required for ignition and propagating burn by ?50%. The compressed field is high enough to suppress transverse electron heat conduction, and to allow alphas to couple energy into the hotspot even when highly deformed by large low-mode amplitudes. This might permit the recovery of ignition, or at least significant alpha particle heating, in submarginal capsules that would otherwise fail because of adverse hydrodynamic instabilities.

  18. Evaluation of delivered monitor unit accuracy of gated step-and-shoot IMRT using a two-dimensional detector array

    SciTech Connect

    Cheong, Kwang-Ho; Kang, Sei-Kwon; Lee, MeYeon; Kim, Su SSan; Park, SoAh; Hwang, Tae-Jin; Kim, Kyoung Ju; Oh, Do Hoon; Bae, Hoonsik; Suh, Tae-Suk

    2010-03-15

    Purpose: To overcome the problem of organ motion in intensity-modulated radiation therapy (IMRT), gated IMRT is often used for the treatment of lung cancer. In this study, the authors investigated the accuracy of the delivered monitor units (MUs) from each segment during gated IMRT using a two-dimensional detector array for user-specific verification purpose. Methods: The authors planned a 6 MV photon, seven-port step-and-shoot lung IMRT delivery. The respiration signals for gated IMRT delivery were obtained from the one-dimensional moving phantom using the real-time position management (RPM) system (Varian Medical Systems, Palo Alto, CA). The beams were delivered using a Clinac iX (Varian Medical Systems, Palo Alto, CA) with the Millennium 120 MLC. The MatriXX (IBA Dosimetry GmbH, Germany) was validated through consistency and reproducibility tests as well as comparison with measurements from a Farmer-type ion chamber. The authors delivered beams with varying dose rates and duty cycles and analyzed the MatriXX data to evaluate MU delivery accuracy. Results: There was quite good agreement between the planned segment MUs and the MUs computed from the MatriXX within {+-}2% error. The beam-on times computed from the MatriXX data were almost identical for all cases, and they matched well with the RPM beam-on and beam-off signals. A slight difference was observed between them, but it was less than 40 ms. The gated IMRT delivery demonstrated an MU delivery accuracy that was equivalent to ungated IMRT, and the delivered MUs with a gating signal agreed with the planned MUs within {+-}0.5 MU regardless of dose rate and duty cycle. Conclusions: The authors can conclude that gated IMRT is able to deliver an accurate dose to a patient during a procedure. The authors believe that the methodology and results can be transferred to other vendors' devices, particularly those that do not provide MLC log data for a verification purpose.

  19. Electrical Conductivity of 2D-SiCf/CVI-SiC

    SciTech Connect

    Youngblood, Gerald E.; Thomsen, Edwin C.; Shinavski, Robert J.

    2011-07-11

    Electrical conductivity (EC) data for several plate forms of two-dimensional, silicon carbide composite made with chemical vapor infiltration matrix and with Hi Nicalon{trademark} type S fibers (2D-SiCf/CVI-SiC) were acquired. The composite fibers were coated with pyrocarbon (PyC) of various thicknesses (50 to 310 nm) and an outer thin ({approx}60 {mu}m) SiC 'seal coat' was applied by CVD to the infiltrated plates. The EC was highly anisotropic in the transverse and in-plane directions. In-plane EC ranged from {approx}150 to 1600 S/m, increased slowly with increasing temperature, and depended primarily on the total PyC thickness. High in-plane EC-values occur because it is dominated by conduction along the numerous, continuous PyC fiber coating pathways. Transverse EC ranged from {approx}1 to 60 S/m, and increased strongly with increasing temperature up to 800 C. The transverse EC is controlled by conduction through the interconnections of the carboncoating network within and between fiber bundles, especially at moderate temperatures ({approx}300 to 700 C). Below {approx}300 C, the electrical resistance of the pure SiC seal coat becomes increasingly more important as temperatures are further lowered. Importantly, a '3-layer series' model predicts that transverse EC-values for a standard seal-coated 2DSiCf/ CVI-SiC with a monolayer PyC fiber coating of {approx}50-nm thickness will be <20 S/m for all temperatures up to 800 C, as desired for a flow channel insert in a fusion reactor blanket component.

  20. Diesel combustion and emissions formation using multiple 2-D imaging diagnostics

    SciTech Connect

    Dec, J.E.

    1997-12-31

    Understanding how emissions are formed during diesel combustion is central to developing new engines that can comply with increasingly stringent emission standards while maintaining or improving performance levels. Laser-based planar imaging diagnostics are uniquely capable of providing the temporally and spatially resolved information required for this understanding. Using an optically accessible research engine, a variety of two-dimensional (2-D) imaging diagnostics have been applied to investigators of direct-injection (DI) diesel combustion and emissions formation. These optical measurements have included the following laser-sheet imaging data: Mie scattering to determine liquid-phase fuel distributions, Rayleigh scattering for quantitative vapor-phase-fuel/air mixture images, laser induced incandescence (LII) for relative soot concentrations, simultaneous LII and Rayleigh scattering for relative soot particle-size distributions, planar laser-induced fluorescence (PLIF) to obtain early PAH (polyaromatic hydrocarbon) distributions, PLIF images of the OH radical that show the diffusion flame structure, and PLIF images of the NO radical showing the onset of NO{sub x} production. In addition, natural-emission chemiluminescence images were obtained to investigate autoignition. The experimental setup is described, and the image data showing the most relevant results are presented. Then the conceptual model of diesel combustion is summarized in a series of idealized schematics depicting the temporal and spatial evolution of a reacting diesel fuel jet during the time period investigated. Finally, recent PLIF images of the NO distribution are presented and shown to support the timing and location of NO formation hypothesized from the conceptual model.

  1. SU-E-T-291: Sensitivity of a Simple 2D EPID in Vivo Dosimetry

    SciTech Connect

    Peca, S; Brown, D

    2014-06-01

    Purpose: As radiotherapy (RT) increases in complexity, so does motivation for in vivo dosimetry (IVD), which may detect errors such as: setup, beam shaping and dose delivered. We have recently developed an easy-toimplement method for two-dimensional IVD based on images taken with the electronic portal imaging device (EPID) in cine mode during treatment. The purpose of this work is to characterize its sensitivity to possible RT delivery errors. Methods: We introduced a series of modifications to a simple RT field (1010, 100MU, 300RR, 20cm homogeneous phantom) to simulate errors. These modifications included multi-leaf collimator (MLC) position, number of MUs, and collimator angle. We quantified the sensitivity to inhomogeneities by inserting variable amounts of solid lung and bone. Finally we delivered realistic fields to an anthropomorphic phantom to estimate sensitivity to gantry angle and setup errors. Results: Our EPIDIVD is sensitive to MLC positioning errors of 1mm and 3mm in the closed and open directions respectively, and to 3% MU variations. Sensitivity to collimator angle depends on field shape irregularity; in the case of a 10x10 field, we are sensitive to errors of 0.8. The sensitivity to inhomogeneities is limited by the nature of MV imaging: approximately 1% signal change is noted when switching 5cm of water to equal amounts of bone or lung. This suggests that the EPID-IVD is likely not sensitive to small setup or gantry angle errors, as confirmed by anthropomorphic tests. Conclusion: We have characterized a simple method of 2D dose reconstruction at isocenter depth inside the patient, which is sensitive to possible RT delivery errors. This method may be useful as a secondary safety check, to prevent large errors from being carried on to following fractions, and to record delivered dose. By using readily available hardware, it is easily implemented and may prove especially useful in centers with limited resources.

  2. Simultaneous 2D single-shot imaging of OH concentrations and temperature fields in an SI engine simulator

    SciTech Connect

    Orth, A.; Sick, V.; Wolfrum, J.; Maly, R.R.; Zahn, M.

    1994-12-31

    Two-dimensional (2D) temperature measurements in engines are required for the detailed understanding of the combustion process. Because of the unsteady and turbulent nature of engine combustion, these measurements must be performed on a single-shot basis to obtain cycle-resolved results. Details of the flame front structure are also important to know for the numerical modeling of internal combustion processes. Simultaneous measurements of temperature and hydroxyl radical distributions provide such data sets. The combustion of methane in a fully transparent square piston engine was studied with a combination of 2D laser-induced fluorescence of hydroxyl radicals and 2D Rayleigh scattering. A tunable KrF excimer laser at 248 nm was used for the measurements. The wavelength of the laser was tuned to excite the P{sub 2}(8) transition in the OH (3,0) band of the A-X system. Spectral filtering of the resulting fluorescence to detect solely the fluorescence from the (3,2) band significantly reduces the effect of collisional quenching imposed to the fluorescence of the predissociating v{prime} = 3 level by vibrational energy transfer (VET) to lower vibrational levels. Using a second camera, which only records the Rayleigh signals after appropriate filtering, allows the simultaneous measurement of temperature fields with a single laser. The analysis of corresponding OH and temperature images allowed the decision that the combustion conditions are in a regime where the flamelet approach for modeling is appropriate. Good agreement with model predictions has been achieved for the peak temperatures.

  3. Simulations of the infrared, Raman, and 2D-IR photon echo spectra of water in nanoscale silica pores

    DOE PAGES [OSTI]

    Burris, Paul C.; Laage, Damien; Thompson, Ward H.

    2016-05-20

    Vibrational spectroscopy is frequently used to characterize nanoconfined liquids and probe the effect of the confining framework on the liquid structure and dynamics relative to the corresponding bulk fluid. However, it is still unclear what molecular-level information can be obtained from such measurements. In this Paper, we address this question by using molecular dynamics (MD) simulations to reproduce the linear infrared (IR), Raman, and two-dimensional IR (2D-IR) photon echo spectra for water confined within hydrophilic (hydroxyl-terminated) silica mesopores. To simplify the spectra the OH stretching region of isotopically dilute HOD in D2O is considered. An empirical mapping approach is usedmore » to obtain the OH vibrational frequencies, transition dipoles, and transition polarizabilities from the MD simulations. The simulated linear IR and Raman spectra are in good general agreement with measured spectra of water in mesoporous silica reported in the literature. The key effect of confinement on the water spectrum is a vibrational blueshift for OH groups that are closest to the pore interface. The blueshift can be attributed to the weaker hydrogen bonds (H-bonds) formed between the OH groups and silica oxygen acceptors. Non-Condon effects greatly diminish the contribution of these OH moieties to the linear IR spectrum, but these weaker H-bonds are readily apparent in the Raman spectrum. The 2D-IR spectra have not yet been measured and thus the present results represent a prediction. Lastly, the simulated spectra indicate that it should be possible to probe the slower spectral diffusion of confined water compared to the bulk liquid by analysis of the 2D-IR spectra.« less

  4. Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers

    DOE PAGES [OSTI]

    Anasori, Babak; Shi, Chenyang; Moon, Eun Ju; Xie, Yu; Voigt, Cooper A.; Kent, Paul R. C.; May, Steven J.; Billinge, Simon J. L.; Barsoum, Michel W.; Gogotsi, Yury

    2016-02-24

    In this paper, a transition from metallic to semiconducting-like behavior has been demonstrated in two-dimensional (2D) transition metal carbides by replacing titanium with molybdenum in the outer transition metal (M) layers of M3C2 and M4C3 MXenes. The MXene structure consists of n + 1 layers of near-close packed M layers with C or N occupying the octahedral site between them in an [MX]nM arrangement. Recently, two new families of ordered 2D double transition metal carbides MXenes were discovered, M'2M"C2 and M'2M"2C3 – where M' and M" are two different early transition metals, such as Mo, Cr, Ta, Nb, V, andmore » Ti. The M' atoms only occupy the outer layers and the M" atoms fill the middle layers. In other words, M' atomic layers sandwich the middle M"–C layers. Using X-ray atomic pair distribution function (PDF) analysis on Mo2TiC2 and Mo2Ti2C3 MXenes, we present the first quantitative analysis of structures of these novel materials and experimentally confirm that Mo atoms are in the outer layers of the [MC]nM structures. The electronic properties of these Mo-containing MXenes are compared with their Ti3C2 counterparts, and are found to be no longer metallic-like conductors; instead the resistance increases mildly with decreasing temperatures. Density functional theory (DFT) calculations suggest that OH terminated Mo–Ti MXenes are semiconductors with narrow band gaps. Measurements of the temperature dependencies of conductivities and magnetoresistances have confirmed that Mo2TiC2Tx exhibits semiconductor-like transport behavior, while Ti3C2Tx is a metal. Finally, this finding opens new avenues for the control of the electronic and optical applications of MXenes and for exploring new applications, in which semiconducting properties are required.« less

  5. 2D heterodyne-detected sum frequency generation study on the ultrafast vibrational dynamics of H{sub 2}O and HOD water at charged interfaces

    SciTech Connect

    Inoue, Ken-ichi; Singh, Prashant C.; Nihonyanagi, Satoshi; Tahara, Tahei; Yamaguchi, Shoichi

    2015-06-07

    Two-dimensional heterodyne-detected vibrational sum-frequency generation (2D HD-VSFG) spectroscopy is applied to study the ultrafast vibrational dynamics of water at positively charged aqueous interfaces, and 2D HD-VSFG spectra of cetyltrimethylammonium bromide (CTAB)/water interfaces in the whole hydrogen-bonded OH stretch region (3000 cm{sup ?1} ? ?{sub pump} ? 3600 cm{sup ?1}) are measured. 2D HD-VSFG spectrum of the CTAB/isotopically diluted water (HOD-D{sub 2}O) interface exhibits a diagonally elongated bleaching lobe immediately after excitation, which becomes round with a time constant of ?0.3 ps due to spectral diffusion. In contrast, 2D HD-VSFG spectrum of the CTAB/H{sub 2}O interface at 0.0 ps clearly shows two diagonal peaks and their cross peaks in the bleaching region, corresponding to the double peaks observed at 3230 cm{sup ?1} and 3420 cm{sup ?1} in the steady-state HD-VSFG spectrum. Horizontal slices of the 2D spectrum show that the relative intensity of the two peaks of the bleaching at the CTAB/H{sub 2}O interface gradually change with the change of the pump frequency. We simulate the pump-frequency dependence of the bleaching feature using a model that takes account of the Fermi resonance and inhomogeneity of the OH stretch vibration, and the simulated spectra reproduce the essential features of the 2D HD-VSFG spectra of the CTAB/H{sub 2}O interface. The present study demonstrates that heterodyne detection of the time-resolved VSFG is critically important for studying the ultrafast dynamics of water interfaces and for unveiling the underlying mechanism.

  6. SU-E-T-223: Investigation of the Accuracy of Two-Dimensional Dose Distributions Measurement From High-Dose-Rate Brachytherapy Ir-192 Source Using Multiple-Diode-Array Detector (MapCheck2)

    SciTech Connect

    Taguenang, J; De La Fuente, T Herman; Ahmad, S; Ali, I

    2014-06-01

    Purpose: To investigate the dosimetric accuracy of multiple-diode-array detector (Mapcheck2) for high-dose-rate brachytherapy Ir-192 source. The two-dimensional (2D) dose distributions measured with MapCheck2 were validated with EBT2 Gafchromic film measurement and AAPM task-group- 43 (TG-43) modeling. Methods: 2D-dose distributions from Ir-192 source were measured with MapCheck2 and EBT2-films. MapCheck2 response was corrected for effects: directional dependence, diode and phantom heterogeneity. Optical density growth of the film was controlled by synchronized scanning of the film exposed to Ir-192 and calibration films exposed to 6 MV linac beams. Similarly, MapCheck2 response was calibrated to dose using 6 MV beams. An empirical model was developed for the dose distributions measured with Mapcheck2 that considered directional, diode and phantom heterogeneity corrections. The dose deposited in solid-state-detectors was modeled using a cavity theory model for the diode. This model was then validated with measurements using EBT2-films and calculations with TG-43. Results: The response of MapCheck2 has been corrected for different effects including: (a) directional dependence of 0–20% over angular range 0o–90o, (b) phantom heterogeneity (3%) and (c) diode heterogeneity (9%). The corrected dose distributions measured with MapCheck2 agreed well with the measured dose distributions from EBT2-film and with calculations using TG-43 within 5% over a wide range of dose levels and rates. The advantages of MapCheck2 include less noisy, linear and stable response compared with film. The response of MapCheck2 exposed to 192Ir-source showed no energy dependence similar to its response to MV energy beam. Detection spatial-resolution of individual diodes was 0.8×0.8 mm2, however, 2DMapCheck2 resolution is limited by distance between diodes (7.07 mm). Conclusion: The dose distribution measured with MapCheck2 agreed well within 5% with that measured using EBT2-films; and

  7. 2D Monolayers Could Yield Thinnest Solar Cells Ever

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Thinnest solar cells ever 2D Monolayers Could Yield Thinnest Solar Cells Ever October 21, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Efforts to improve solar cells have historically focused on improving energy conversion efficiencies and lowering manufacturing costs. But new computer simulations have shown how using a different type of material could yield thinner, more lightweight solar panels that provide power densities - watts per kilogram of material - orders of

  8. Computational Study and Analysis of Structural Imperfections in 1D and 2D Photonic Crystals

    SciTech Connect

    K.R. Maskaly

    2005-06-01

    Dielectric reflectors that are periodic in one or two dimensions, also known as 1D and 2D photonic crystals, have been widely studied for many potential applications due to the presence of wavelength-tunable photonic bandgaps. However, the unique optical behavior of photonic crystals is based on theoretical models of perfect analogues. Little is known about the practical effects of dielectric imperfections on their technologically useful optical properties. In order to address this issue, a finite-difference time-domain (FDTD) code is employed to study the effect of three specific dielectric imperfections in 1D and 2D photonic crystals. The first imperfection investigated is dielectric interfacial roughness in quarter-wave tuned 1D photonic crystals at normal incidence. This study reveals that the reflectivity of some roughened photonic crystal configurations can change up to 50% at the center of the bandgap for RMS roughness values around 20% of the characteristic periodicity of the crystal. However, this reflectivity change can be mitigated by increasing the index contrast and/or the number of bilayers in the crystal. In order to explain these results, the homogenization approximation, which is usually applied to single rough surfaces, is applied to the quarter-wave stacks. The results of the homogenization approximation match the FDTD results extremely well, suggesting that the main role of the roughness features is to grade the refractive index profile of the interfaces in the photonic crystal rather than diffusely scatter the incoming light. This result also implies that the amount of incoherent reflection from the roughened quarterwave stacks is extremely small. This is confirmed through direct extraction of the amount of incoherent power from the FDTD calculations. Further FDTD studies are done on the entire normal incidence bandgap of roughened 1D photonic crystals. These results reveal a narrowing and red-shifting of the normal incidence bandgap with

  9. OECD 2-D Core Concrete Interaction (CCI) tests : CCI-2 test plan, Rev. 0 January 31, 2004.

    SciTech Connect

    Farmer, M. T.; Kilsdonk, D. J.; Lomperski, S.; Aeschlimann, R. W.; Basu, S.

    2011-05-23

    The Melt Attack and Coolability Experiments (MACE) program addressed the issue of the ability of water to cool and thermally stabilize a molten core-concrete interaction when the reactants are flooded from above. These tests provided data regarding the nature of corium interactions with concrete, the heat transfer rates from the melt to the overlying water pool, and the role of noncondensable gases in the mixing processes that contribute to melt quenching. As a follow-on program to MACE, The Melt Coolability and Concrete Interaction Experiments (MCCI) project is conducting reactor material experiments and associated analysis to achieve the following objectives: (1) resolve the ex-vessel debris coolability issue through a program that focuses on providing both confirmatory evidence and test data for the coolability mechanisms identified in MACE integral effects tests, and (2) address remaining uncertainties related to long-term two-dimensional molten core-concrete interactions under both wet and dry cavity conditions. Achievement of these two program objectives will demonstrate the efficacy of severe accident management guidelines for existing plants, and provide the technical basis for better containment designs for future plants. In terms of satisfying these objectives, the Management Board (MB) approved the conduct of two long-term 2-D Core-Concrete Interaction (CCI) experiments designed to provide information in several areas, including: (i) lateral vs. axial power split during dry core-concrete interaction, (ii) integral debris coolability data following late phase flooding, and (iii) data regarding the nature and extent of the cooling transient following breach of the crust formed at the melt-water interface. The first of these two tests, CCI-1, was conducted on December 19, 2003. This test investigated the interaction of a fully oxidized 400 kg PWR core melt, initially containing 8 wt % calcined siliceous concrete, with a specially designed two-dimensional

  10. OECD/MCCI 2-D Core Concrete Interaction (CCI) tests : final report February 28, 2006.

    SciTech Connect

    Farmer, M. T.; Lomperski, S.; Kilsdonk, D. J.; Aeschlimann, R. W.; Basu, S.

    2011-05-23

    reactor material database for dry cavity conditions is solely one-dimensional. Although the MACE Scoping Test was carried out with a two-dimensional concrete cavity, the interaction was flooded soon after ablation was initiated to investigate debris coolability. Moreover, due to the scoping nature of this test, the apparatus was minimally instrumented and therefore the results are of limited value from the code validation viewpoint. Aside from the MACE program, the COTELS test series also investigated 2-D CCI under flooded cavity conditions. However, the input power density for these tests was quite high relative to the prototypic case. Finally, the BETA test series provided valuable data on 2-D core concrete interaction under dry cavity conditions, but these tests focused on investigating the interaction of the metallic (steel) phase with concrete. Due to these limitations, there is significant uncertainty in the partition of energy dissipated for the ablation of concrete in the lateral and axial directions under dry cavity conditions for the case of a core oxide melt. Accurate knowledge of this 'power split' is important in the evaluation of the consequences of an ex-vessel severe accident; e.g., lateral erosion can undermine containment structures, while axial erosion can penetrate the basemat, leading to ground contamination and/or possible containment bypass. As a result of this uncertainty, there are still substantial differences among computer codes in the prediction of 2-D cavity erosion behavior under both wet and dry cavity conditions. In light of the above issues, the OECD-sponsored Melt Coolability and Concrete Interaction (MCCI) program was initiated at Argonne National Laboratory. The project conducted reactor materials experiments and associated analysis to achieve the following technical objectives: (1) resolve the ex-vessel debris coolability issue through a program that focused on providing both confirmatory evidence and test data for the coolability

  11. Two-dimensional electron gas at the Ti-diffused BiFeO{sub 3}/SrTiO{sub 3} interface

    SciTech Connect

    Chen, Chunlin; Li, Junjie; Wang, Zhongchang Liang, Xiaobin; Nakajima, Ken; Lv, Shuhui; Li, Yanxi; Viehland, Dwight; Ikuhara, Yuichi

    2015-07-20

    Oxide heterostructures with the broken translational symmetry often trigger a two-dimensional quantum confinement and associated unique electronic properties that cannot be observed in bulk constituents. Particular interest is devoted to the formation of two-dimensional electron gas (2DEG) at heterointerfaces between two insulators, which offers a fertile ground for fabricating advanced electronic devices. Here, we combine atomic force microscopy, transmission electron microscopy, and atomistic first-principles calculations to demonstrate that the (100) BiFeO{sub 3}/SrTiO{sub 3} interface takes on a metallic nature and a 2DEG is generated at this interface. Our findings also reveal that the electronic reconstruction due to the polar discontinuity and the variation in valence state of Ti arising from diffusion of Ti cations in SrTiO{sub 3} to Fe sites of BiFeO{sub 3} are critical to the formation of 2DEG at the heterointerface.

  12. Compact and high-particle-flux thermal-lithium-beam probe system for measurement of two-dimensional electron density profile

    SciTech Connect

    Shibata, Y. Manabe, T.; Ohno, N.; Takagi, M.; Kajita, S.; Tsuchiya, H.; Morisaki, T.

    2014-09-15

    A compact and high-particle-flux thermal-lithium-beam source for two-dimensional measurement of electron density profiles has been developed. The thermal-lithium-beam oven is heated by a carbon heater. In this system, the maximum particle flux of the thermal lithium beam was ∼4 × 10{sup 19} m{sup −2} s{sup −1} when the temperature of the thermal-lithium-beam oven was 900 K. The electron density profile was evaluated in the small tokamak device HYBTOK-II. The electron density profile was reconstructed using the thermal-lithium-beam probe data and this profile was consistent with the electron density profile measured with a Langmuir electrostatic probe. We confirm that the developed thermal-lithium-beam probe can be used to measure the two-dimensional electron density profile with high time and spatial resolutions.

  13. Note: Fiber optic transport probe for Hall measurements under light and magnetic field at low temperatures: Case study of a two dimensional electron gas

    SciTech Connect

    Bhadauria, P. P. S.; Gupta, Anurag; Kumar, Pramod; Dogra, Anjana; Budhani, R. C.

    2015-05-15

    A fiber optic based probe is designed and developed for electrical transport measurements in presence of quasi-monochromatic (360–800 nm) light, varying temperature (T = 1.8–300 K), and magnetic field (B = 0–7 T). The probe is tested for the resistivity and Hall measurements performed on a LaAlO{sub 3}–SrTiO{sub 3} heterointerface system with a conducting two dimensional electron gas.

  14. Black liquor gasification phase 2D final report

    SciTech Connect

    Kohl, A.L.; Stewart, A.E.

    1988-06-01

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  15. Quantum Oscillations in an Interfacial 2D Electron Gas.

    SciTech Connect

    Zhang, Bingop; Lu, Ping; Liu, Henan; Lin, Jiao; Ye, Zhenyu; Jaime, Marcelo; Balakirev, Fedor F.; Yuan, Huiqiu; Wu, Huizhen; Pan, Wei; Zhang, Yong

    2016-01-01

    Recently, it has been predicted that topological crystalline insulators (TCIs) may exist in SnTe and Pb1-xSnxTe thin films [1]. To date, most studies on TCIs were carried out either in bulk crystals or thin films, and no research activity has been explored in heterostructures. We present here the results on electronic transport properties of the 2D electron gas (2DEG) realized at the interfaces of PbTe/ CdTe (111) heterostructures. Evidence of topological state in this interfacial 2DEG was observed.

  16. Transport Experiments on 2D Correlated Electron Physics in Semiconductors

    SciTech Connect

    Tsui, Daniel

    2014-03-24

    This research project was designed to investigate experimentally the transport properties of the 2D electrons in Si and GaAs, two prototype semiconductors, in several new physical regimes that were previously inaccessible to experiments. The research focused on the strongly correlated electron physics in the dilute density limit, where the electron potential energy to kinetic energy ratio rs>>1, and on the fractional quantum Hall effect related physics in nuclear demagnetization refrigerator temperature range on samples with new levels of purity and controlled random disorder.

  17. TH-C-19A-12: Two-Dimensional High Spatial-Resolution Dosimeter Using Europium Doped Potassium Chloride

    SciTech Connect

    Li, H; Yang, D; Xiao, Z; Driewer, J; Han, Z; Low, D

    2014-06-15

    Purpose: Recent research has shown that KCl:Eu2+ has great potential for use in megavoltage radiation therapy dosimetry because this material exhibits excellent storage performance and is reusable due to strong radiation hardness. This work reports our attempts to fabricate 2D KCl:Eu2+ storage phosphor films (SPFs) using both a physical vapor deposition (PVD) method and a tape casting method. Methods: A thin layer of KCl:Eu2+ was deposited on a substrate of borosilicate glass (e.g., laboratory slides) with a PVD system. For tape casting, a homogenous suspension containing storage phosphor particles, liquid vehicle and polymer binder was formed and subsequently cast by doctor-blade onto a polyethylene terephthalate substrate to form a 150 μm thick SPF. Results: X ray diffraction analysis showed that a 10 μm thick PVD sample was composed of highly crystalline KCl. No additional phases were observed, suggesting that the europium activator had completed been incorporated into the KCl matrix. Photostimulated luminescence and photoluminescence spectra suggested that F (Cl−) centers were the electron storage centers post x ray irradiation and that Eu2+ cations acted as luminescence centers in the photostimulation process. The 150 μm thick casted KCl:Eu2+ SPF showed sub-millimeter spatial resolution. Monte Carlo simulations further demonstrated that the admixture of 20% KCl:Eu2+ and 80% low Z polymer binder exhibited almost no energy dependence in a 6 MV beam. KCl:Eu2+ pellet samples showed a large dynamic range from 0.01 cGy to 60 Gy dose-to-water, and saturated at approximately 500 Gy as a Result of its intrinsic high radiation hardness. Conclusions: This discovery research provides strong evidence that KCl:Eu2+ based SPF with associated readout apparatus could Result in a novel electronic film system that has all the desirable features associated with classic radiographic film and, importantly, water equivalence and the capability of permanent identification of

  18. Two Keggin-type heteropolytungstates with transition metal as a central atom: Crystal structure and magnetic study with 2D-IR correlation spectroscopy

    SciTech Connect

    Chai, Feng [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); Chen, YiPing, E-mail: ypchen007@sina.com [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); You, ZhuChai; Xia, ZeMin; Ge, SuZhi; Sun, YanQiong; Huang, BiHua [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China)

    2013-06-01

    Two Keggin-type heteropolytungstates, [Co(phen)?]?[CoW??O??]9H?O 1 (phen=1,10-phenanthroline) and [Fe(phen)?]?[FeW??O??]H?OH?O 2, have been synthesized via the hydrothermal technique and characterized by single crystal X-ray diffraction analyses, IR, XPS, TG analysis, UVDRS, XRD, thermal-dependent and magnetic-dependent 2D-COS IR (two-dimensional infrared correlation spectroscopy). Crystal structure analysis reveals that the polyanions in compound 1 are linked into 3D supramolecule through hydrogen bonding interactions between lattice water molecules and terminal oxygen atoms of polyanion units, and [Co(phen)?]? cations distributed in the polyanion framework with many hydrogen bonding interactions. The XPS spectra indicate that all the Co atoms in 1 are +2 oxidation state, the Fe atoms in 2 existing with +2 and +3 mixed oxidation states. - Graphical abstract: The magnetic-dependent synchronous 2D correlation IR spectra of 1 (a), 2 (b) over 050 mT in the range of 6001000 cm?, the obvious response indicate two Keggin polyanions skeleton susceptible to applied magnetic field. Highlights: Two Keggin-type heteropolytungstates with transition metal as a central atom has been obtained. Compound 1 forms into 3D supramolecular architecture through hydrogen bonding between water molecules and polyanions. Magnetic-dependent 2D-IR correlation spectroscopy was introduced to discuss the magnetism of polyoxometalate.

  19. 2D Gridded Surface Data Value-Added Product

    SciTech Connect

    Tang, Q; Xie, S

    2015-08-30

    This report describes the Atmospheric Radiation Measurement (ARM) Best Estimate (ARMBE) 2-dimensional (2D) gridded surface data (ARMBE2DGRID) value-added product. Spatial variability is critically important to many scientific studies, especially those that involve processes of great spatial variations at high temporal frequency (e.g., precipitation, clouds, radiation, etc.). High-density ARM sites deployed at the Southern Great Plains (SGP) allow us to observe the spatial patterns of variables of scientific interests. The upcoming megasite at SGP with its enhanced spatial density will facilitate the studies at even finer scales. Currently, however, data are reported only at individual site locations at different time resolutions for different datastreams. It is difficult for users to locate all the data they need and requires extra effort to synchronize the data. To address these problems, the ARMBE2DGRID value-added product merges key surface measurements at the ARM SGP sites and interpolates the data to a regular 2D grid to facilitate the data application.

  20. 2D Thermal Hydraulic Analysis and Benchmark in Support of HFIR...

    Office of Scientific and Technical Information (OSTI)

    A secondary goal of this two-dimensional phase of the research is to establish methodology and data base libraries that are also needed in the full three-dimensional COMSOL ...

  1. REFLECT HOME

    Energy.gov [DOE]

    Sacramento is nicknamed the City of Trees, so it made sense for the California State University, Sacramento, team to showcase nature in its Solar Decathlon 2015 project. The team’s Reflect Home does just that by embracing the city’s sense of expansive greenery.

  2. Interactive initialization of 2D/3D rigid registration

    SciTech Connect

    Gong, Ren Hui; Gler, zgr; Krkloglu, Mustafa; Lovejoy, John; Yaniv, Ziv

    2013-12-15

    Purpose: Registration is one of the key technical components in an image-guided navigation system. A large number of 2D/3D registration algorithms have been previously proposed, but have not been able to transition into clinical practice. The authors identify the primary reason for the lack of adoption with the prerequisite for a sufficiently accurate initial transformation, mean target registration error of about 10 mm or less. In this paper, the authors present two interactive initialization approaches that provide the desired accuracy for x-ray/MR and x-ray/CT registration in the operating room setting. Methods: The authors have developed two interactive registration methods based on visual alignment of a preoperative image, MR, or CT to intraoperative x-rays. In the first approach, the operator uses a gesture based interface to align a volume rendering of the preoperative image to multiple x-rays. The second approach uses a tracked tool available as part of a navigation system. Preoperatively, a virtual replica of the tool is positioned next to the anatomical structures visible in the volumetric data. Intraoperatively, the physical tool is positioned in a similar manner and subsequently used to align a volume rendering to the x-ray images using an augmented reality (AR) approach. Both methods were assessed using three publicly available reference data sets for 2D/3D registration evaluation. Results: In the authors' experiments, the authors show that for x-ray/MR registration, the gesture based method resulted in a mean target registration error (mTRE) of 9.3 5.0 mm with an average interaction time of 146.3 73.0 s, and the AR-based method had mTREs of 7.2 3.2 mm with interaction times of 44 32 s. For x-ray/CT registration, the gesture based method resulted in a mTRE of 7.4 5.0 mm with an average interaction time of 132.1 66.4 s, and the AR-based method had mTREs of 8.3 5.0 mm with interaction times of 58 52 s. Conclusions: Based on the authors

  3. Verification of electrical spin injection into InGaAs two-dimensional electron gas from CoFe electrode by four-terminal non-local geometry

    SciTech Connect

    Hidaka, S.; Kondo, T.; Akabori, M.; Yamada, S.

    2013-12-04

    We performed electrical spin injection into In{sub 0.75}Ga{sub 0.25}As two-dimensional electron gases from Co{sub 0.8}Fe{sub 0.2} electrodes by four-terminal non-local spin-valve (NLSV) measurement. We observed clear SV signals in NL resistance at 1.5 K. From the electrode spacing dependence of the signals, we estimated spin diffusion length and spin polarization to be ?5.1 ?m and ?5.7 %, respectively. These are larger than those reported in similar systems.

  4. Three- and two-dimensional simulations of counter-propagating shear experiments at high energy densities at the National Ignition Facility

    DOE PAGES [OSTI]

    Wang, Ping; Zhou, Ye; MacLaren, Stephan A.; Huntington, Channing M.; Raman, Kumar S.; Doss, Forrest W.; Flippo, Kirk A.

    2015-11-06

    Three- and two-dimensional numerical studies have been carried out to simulate recent counter-propagating shear flow experiments on the National Ignition Facility. A multi-physics three-dimensional, time-dependent radiation hydrodynamics simulation code is used. Using a Reynolds Averaging Navier-Stokes model, we show that the evolution of the mixing layer width obtained from the simulations agrees well with that measured from the experiments. A sensitivity study is conducted to illustrate a 3D geometrical effect that could confuse the measurement at late times, if the energy drives from the two ends of the shock tube are asymmetric. Implications for future experiments are discussed.

  5. Self-assembled two-dimensional nanoporous molecular arrays and photoinduced polymerization of 4-bromo-4′-hydroxybiphenyl on Ag(111)

    SciTech Connect

    Shen, Qian; He, Jing Hui; Zhang, Jia Lin; Wu, Kai; Xu, Guo Qin; Wee, Andrew Thye Shen; Chen, Wei

    2015-03-14

    Self-assembled two-dimensional molecular arrays and photoinduced polymerization of 4-bromo-4′-hydroxybiphenyl on Ag(111) were studied using low-temperature scanning tunneling microscopy combined with density functional theory calculations. Square-like self-assembled structures of 4-bromo-4′-hydroxybiphenyl stabilized by intermolecular hydrogen and halogen bonds were transformed into hexagonal nanopores of biphenyl biradicals by 266 nm UV laser irradiation at 80 K. The biradicals further coupled to each other and formed covalently linked polyphenylene polymer chains at room temperature.

  6. Tunable bilayer two-dimensional electron gas in LaAlO{sub 3}/SrTiO{sub 3} superlattices

    SciTech Connect

    Ma, H. J. Harsan E-mail: phyarian@nus.edu.sg; Annadi, A.; Zeng, S. W.; Ariando E-mail: phyarian@nus.edu.sg; Huang, Z.; L, W. M.; Wong, L. M.; Wang, S. J.; Venkatesan, T.

    2014-07-07

    We report magnetotransport properties of double heterointerfaces in LaAlO{sub 3}/SrTiO{sub 3}/LaAlO{sub 3}/SrTiO{sub 3}(001) (LAO/STO/LAO/STO). A strong nonlinearity in the Hall resistivity is found when the temperature is below 80?K. This effect is attributed to multichannel conduction of interfacial charges generated in double heterostructures of LAO/STO where two-dimensional electron gas (2DEG) is produced. The multichannel conduction is confirmed by back gating modulation of Hall effect. Our result suggests the possibility to achieve coupled bilayer 2DEG layers in LAO/STO superlattices.

  7. Large voltage modulation in magnetic field sensors from two-dimensional arrays of Y-Ba-Cu-O nano Josephson junctions

    SciTech Connect

    Cybart, Shane A. Dynes, R. C.; Cho, E. Y.; Wong, T. J.; Glyantsev, V. N.; Huh, J. U.; Yung, C. S.; Moeckly, B. H.; Beeman, J. W.; Ulin-Avila, E.; Wu, S. M.

    2014-02-10

    We have fabricated and tested two-dimensional arrays of YBa{sub 2}Cu{sub 3}O{sub 7??} superconducting quantum interference devices. The arrays contain over 36?000 nano Josephson junctions fabricated from ion irradiation of YBa{sub 2}Cu{sub 3}O{sub 7??} through narrow slits in a resist-mask that was patterned with electron beam lithography and reactive ion etching. Measurements of current-biased arrays in magnetic field exhibit large voltage modulations as high as 30?mV.

  8. Vacuum compatible, high-speed, 2-D mirror tilt stage

    DOEpatents

    Denham; Paul E.

    2007-09-25

    A compact and vacuum compatible magnetic-coil driven tiltable stage that is equipped with a high efficiency reflective coating can be employed as a scanner in EUV applications. The drive electronics for the scanner is fully in situ programmable and rapidly switchable.

  9. Characterization and use of a 2D-array of ion chambers for brachytherapy dosimetric quality assurance

    SciTech Connect

    Yewondwossen, Mammo

    2012-10-01

    The two-dimensional (2D) ionization chamber array MatriXX Evolution is one of the 2D ionization chamber arrays developed by IBA Dosimetry (IBA Dosimetry, Germany) for megavoltage real-time absolute 2D dosimetry and verification of intensity-modulated radiation therapy (IMRT). The purpose of this study was to (1) evaluate the performance of ion chamber array for submegavoltage range brachytherapy beam dose verification and quality assurance (QA) and (2) use the end-to-end dosimetric evaluation that mimics a patient treatment procedure and confirm the primary source strength calibration agrees in both the treatment planning system (TPS) and treatment delivery console computers. The dose linearity and energy dependence of the 2D ion chamber array was studied using kilovoltage X-ray beams (100, 180 and 300 kVp). The detector calibration factor was determined using 300 kVp X-ray beams so that we can use the same calibration factor for dosimetric verification of high-dose-rate (HDR) brachytherapy. The phantom used for this measurement consists of multiple catheters, the IBA MatriXX detector, and water-equivalent slab of RW3 to provide full scattering conditions. The treatment planning system (TPS) (Oncentra brachy version 3.3, Nucletron BV, Veenendaal, the Netherlands) dose distribution was calculated on the computed tomography (CT) scan of this phantom. The measured and TPS calculated distributions were compared in IBA Dosimetry OmniPro-I'mRT software. The quality of agreement was quantified by the gamma ({gamma}) index (with 3% delta dose and distance criterion of 2 mm) for 9 sets of plans. Using a dedicated phantom capable of receiving 5 brachytherapy intralumenal catheters a QA procedure was developed for end-to-end dosimetric evaluation for routine QA checks. The 2D ion chamber array dose dependence was found to be linear for 100-300 kVp and the detector response (k{sub user}) showed strong energy dependence for 100-300 kVp energy range. For the Ir-192 brachytherapy

  10. Application of 2D VSP Imaging Technology to the Targeting of Exploration and Production Wells in a Basin and Range Geothermal System

    Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: A novel 2D VSP imaging technology and patented processing techniques will be used to create accurate, high-resolution reflection images of a classic Basin and Range fault system in a fraction of previous compute times.

  11. Two-Dimensional Measurement of n+-p Asymmetrical Junctions in Multicrystalline Silicon Solar Cells using AFM-Based Electrical Techniques with Nanometer Resolution

    SciTech Connect

    Jiang, C. S.; Heath, J. T.; Moutinho, H. R.; Li, J. V.; Al-Jassim, M. M.

    2011-01-01

    Lateral inhomogeneities of modern solar cells demand direct electrical imaging with nanometer resolution. We show that atomic force microscopy (AFM)-based electrical techniques provide unique junction characterizations, giving a two-dimensional determination of junction locations. Two AFM-based techniques, scanning capacitance microscopy/spectroscopy (SCM/SCS) and scanning Kelvin probe force microscopy (SKPFM), were significantly improved and applied to the junction characterizations of multicrystalline silicon (mc-Si) cells. The SCS spectra were taken pixel by pixel by precisely controlling the tip positions in the junction area. The spectra reveal distinctive features that depend closely on the position relative to the electrical junction, which allows us to indentify the electrical junction location. In addition, SKPFM directly probes the built-in potential over the junction area modified by the surface band bending, which allows us to deduce the metallurgical junction location by identifying a peak of the electric field. Our results demonstrate resolutions of 10-40 nm, depending on the techniques (SCS or SKPFM). These direct electrical measurements with nanometer resolution and intrinsic two-dimensional capability are well suited for investigating the junction distribution of solar cells with lateral inhomogeneities.

  12. Two-Dimensional Measurement of n+-p Asymmetrical Junctions in Multicrystalline Silicon Solar Cells Using AFM-Based Electrical Techniques with Nanometer Resolution: Preprint

    SciTech Connect

    Jiang, C. S.; Moutinho, H. R.; Li, J. V.; Al-Jassim, M. M.; Heath, J. T.

    2011-07-01

    Lateral inhomogeneities of modern solar cells demand direct electrical imaging with nanometer resolution. We show that atomic force microscopy (AFM)-based electrical techniques provide unique junction characterizations, giving a two-dimensional determination of junction locations. Two AFM-based techniques, scanning capacitance microscopy/spectroscopy (SCM/SCS) and scanning Kelvin probe force microscopy (SKPFM), were significantly improved and applied to the junction characterizations of multicrystalline silicon (mc-Si) cells. The SCS spectra were taken pixel by pixel by precisely controlling the tip positions in the junction area. The spectra reveal distinctive features that depend closely on the position relative to the electrical junction, which allows us to indentify the electrical junction location. In addition, SKPFM directly probes the built-in potential over the junction area modified by the surface band bending, which allows us to deduce the metallurgical junction location by identifying a peak of the electric field. Our results demonstrate resolutions of 10-40 nm, depending on the techniques (SCS or SKPFM). These direct electrical measurements with nanometer resolution and intrinsic two-dimensional capability are well suited for investigating the junction distribution of solar cells with lateral inhomogeneities.

  13. Magneto-transport analysis of an ultra-low-density two-dimensional hole gas in an undoped strained Ge/SiGe heterostructure

    DOE PAGES [OSTI]

    Laroche, D.; Huang, S. -H.; Chuang, Y.; Li, J. -Y.; Liu, C. W.; Lu, T. M.

    2016-06-06

    We report the magneto-transport, scattering mechanisms, and e ective mass analysis of an ultralow density two-dimensional hole gas capacitively induced in an undoped strained Ge/Si0:2Ge0:8 heterostructure. This fabrication technique allows hole densities as low as p 1:1 1010 cm² to be achieved, more than one order of magnitude lower than previously reported in doped Ge/SiGe heterostructures. The power-law exponent of the electron mobility versus density curve, / n , is found to be 0:29 over most of the density range, implying that background impurity scattering is the dominant scattering mechanism at intermediate densities in such devices. A charge migration modelmore » is used to explain the mobility decrease at the highest achievable densities. The hole e ective mass is deduced from the temperature dependence of Shubnikov-de Haas oscillations. At p 1:0 1011cm², the e ective mass m is 0:105 m0, which is signi cantly larger than masses obtained from modulation-doped Ge/SiGe two-dimensional hole gases.« less

  14. 2D/3D registration algorithm for lung brachytherapy

    SciTech Connect

    Zvonarev, P. S.; Farrell, T. J.; Hunter, R.; Wierzbicki, M.; Hayward, J. E.; Sur, R. K.

    2013-02-15

    Purpose: A 2D/3D registration algorithm is proposed for registering orthogonal x-ray images with a diagnostic CT volume for high dose rate (HDR) lung brachytherapy. Methods: The algorithm utilizes a rigid registration model based on a pixel/voxel intensity matching approach. To achieve accurate registration, a robust similarity measure combining normalized mutual information, image gradient, and intensity difference was developed. The algorithm was validated using a simple body and anthropomorphic phantoms. Transfer catheters were placed inside the phantoms to simulate the unique image features observed during treatment. The algorithm sensitivity to various degrees of initial misregistration and to the presence of foreign objects, such as ECG leads, was evaluated. Results: The mean registration error was 2.2 and 1.9 mm for the simple body and anthropomorphic phantoms, respectively. The error was comparable to the interoperator catheter digitization error of 1.6 mm. Preliminary analysis of data acquired from four patients indicated a mean registration error of 4.2 mm. Conclusions: Results obtained using the proposed algorithm are clinically acceptable especially considering the complications normally encountered when imaging during lung HDR brachytherapy.

  15. Image Appraisal for 2D and 3D Electromagnetic Inversion

    SciTech Connect

    Alumbaugh, D.L.; Newman, G.A.

    1999-01-28

    Linearized methods are presented for appraising image resolution and parameter accuracy in images generated with two and three dimensional non-linear electromagnetic inversion schemes. When direct matrix inversion is employed, the model resolution and posterior model covariance matrices can be directly calculated. A method to examine how the horizontal and vertical resolution varies spatially within the electromagnetic property image is developed by examining the columns of the model resolution matrix. Plotting the square root of the diagonal of the model covariance matrix yields an estimate of how errors in the inversion process such as data noise and incorrect a priori assumptions about the imaged model map into parameter error. This type of image is shown to be useful in analyzing spatial variations in the image sensitivity to the data. A method is analyzed for statistically estimating the model covariance matrix when the conjugate gradient method is employed rather than a direct inversion technique (for example in 3D inversion). A method for calculating individual columns of the model resolution matrix using the conjugate gradient method is also developed. Examples of the image analysis techniques are provided on 2D and 3D synthetic cross well EM data sets, as well as a field data set collected at the Lost Hills Oil Field in Central California.

  16. Design of wheel motor using Maxwell 2D simulation

    SciTech Connect

    Chen, G.H.; Tseng, K.J.

    1995-12-31

    This paper presents a high efficiency direct wheel motor drive for electric vehicles (EVs). The proposed motor is a permanent magnet square-wave motor whose rotor with rare earth magnets forms the outside of the motor to be set within each rear wheel tire to realize the direct drive. The inner stator with its windings is rigidly linked to the suspension and frame structure of the vehicle. In order to achieve the direct drive without any mechanical transmission for EVs, the wheel motor has been designed as a low-speed high-torque motor. The design and optimization of the motor was done with the aid of finite element electromagnetic field analysis using the Maxwell 2D Simulator software. The motor parameters and characteristics can be accurately calculated and predicted in terms of field computation and analysis results. The design procedure of the 6.6 kW, 1,000 rpm wheel motor and its technical data are given in this paper.

  17. Test Problem: Tilted Rayleigh-Taylor for 2-D Mixing Studies

    SciTech Connect

    Andrews, Malcolm J.; Livescu, Daniel; Youngs, David L.

    2012-08-14

    reasonable quality photographic data. The photographs in Figure 2 also reveal the appearance of a boundary layer at the left and right walls; this boundary layer has not been included in the test problem as preliminary calculations suggested it had a negligible effect on plume penetration and RT mixing. The significance of this test problem is that, unlike planar RT experiments such as the Rocket-Rig (Youngs, 1984), Linear Electric Motor - LEM (Dimonte, 1990), or the Water Tunnel (Andrews, 1992), the Tilted-Rig is a unique two-dimensional RT mixing experiment that has experimental data and now (in this TP) Direct Numerical Simulation data from Livescu and Wei. The availability of DNS data for the tilted-rig has made this TP viable as it provides detailed results for comparison purposes. The purpose of the test problem is to provide 3D simulation results, validated by comparison with experiment, which can be used for the development and validation of 2D RANS models. When such models are applied to 2D flows, various physics issues are raised such as double counting, combined buoyancy and shear, and 2-D strain, which have not yet been adequately addressed. The current objective of the test problem is to compare key results, which are needed for RANS model validation, obtained from high-Reynolds number DNS, high-resolution ILES or LES with explicit sub-grid-scale models. The experiment is incompressible and so is directly suitable for algorithms that are designed for incompressible flows (e.g. pressure correction algorithms with multi-grid); however, we have extended the TP so that compressible algorithms, run at low Mach number, may also be used if careful consideration is given to initial pressure fields. Thus, this TP serves as a useful tool for incompressible and compressible simulation codes, and mathematical models. In the remainder of this TP we provide a detailed specification; the next section provides the underlying assumptions for the TP, fluids, geometry details

  18. OECD MCCI project long-term 2-D molten core concrete interaction test design report, Rev. 0. September 30, 2002.

    SciTech Connect

    Farmer, M. T.; Kilsdonk, D. J.; Lomperski, S.; Aeschliman, R. W.; Basu, S.

    2011-05-23

    experiments to address remaining uncertainties related to long-term two-dimensional molten core-concrete interaction. In particular, for both wet and dry cavity conditions, there is uncertainty insofar as evaluating the lateral vs. axial power split during a core-concrete interaction due to a lack of experiment data. As a result, there are differences in the 2-D cavity erosion predicted by codes such as MELCOR, WECHSL, and COSACO. The first step towards generating this data is to produce a test plan for review by the Project Review Group (PRG). The purpose of this document is to provide this plan.

  19. 2-D and 3-D Models of Convective Turbulence and Oscillations...

    Office of Scientific and Technical Information (OSTI)

    2-D and 3-D Models of Convective Turbulence and Oscillations in Intermediate-Mass Main-Sequence Stars Citation Details In-Document Search Title: 2-D and 3-D Models of Convective ...

  20. A 2D Radiation Transport Package with Mimetic Diffusion for ExaFlag...

    Office of Scientific and Technical Information (OSTI)

    A 2D Radiation Transport Package with Mimetic Diffusion for ExaFlag Citation Details In-Document Search Title: A 2D Radiation Transport Package with Mimetic Diffusion for ExaFlag ...

  1. A 2D Radiation Transport Package with Mimetic Diffusion for ExaFlag...

    Office of Scientific and Technical Information (OSTI)

    A 2D Radiation Transport Package with Mimetic Diffusion for ExaFlag Citation Details In-Document Search Title: A 2D Radiation Transport Package with Mimetic Diffusion for ExaFlag...

  2. BioEnergy 2016: Mobilizing the Bio Economy through Innovation 2D -

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Integrated Bio Refineries - Building Blocks to Success | Department of Energy BioEnergy 2016: Mobilizing the Bio Economy through Innovation 2D - Integrated Bio Refineries - Building Blocks to Success BioEnergy 2016: Mobilizing the Bio Economy through Innovation 2D - Integrated Bio Refineries - Building Blocks to Success Breakout Session 2D: Integrated Biorefineries - Building Blocks to Success BioEnergy 2016: Mobilizing the Bio Economy through Innovation 2D - Integrated Bio Refineries -

  3. When R2D2 Meets RoCo | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    When R2D2 Meets RoCo When R2D2 Meets RoCo Addthis Watch what happens R2-D2 meets the Roving Comforter at Bay Area Maker Faire in May 2016. The Roving Comforter is a personalized cooling device developed by the University of Maryland.

  4. 2-D Time-Dependent Fuel Element, Thermal Analysis Code System.

    Energy Science and Technology Software Center

    2001-09-24

    Version 00 WREM-TOODEE2 is a two dimensional, time-dependent, fuel-element thermal analysis program. Its primary purpose is to evaluate fuel-element thermal response during post-LOCA refill and reflood in a pressurized water reactor (PWR). TOODEE2 calculations are carried out in a two-dimensional mesh region defined in slab or cylindrical geometry by orthogonal grid lines. Coordinates which form order pairs are labeled x-y in slab geometry, and those in cylindrical geometry are labeled r-z for the axisymmetric casemore » and r-theta for the polar case. Conduction and radiation are the only heat transfer mechanisms assumed within the boundaries of the mesh region. Convective and boiling heat transfer mechanisms are assumed at the boundaries. The program numerically solves the two-dimensional, time-dependent, heat conduction equation within the mesh region. KEYWORDS: FUEL MANAGEMENT; HEAT TRANSFER; LOCA; PWR« less

  5. Self-assembly of 2D sandwich-structured MnFe{sub 2}O{sub 4}/graphene composites for high-performance lithium storage

    SciTech Connect

    Li, Songmei Wang, Bo; Li, Bin; Liu, Jianhua; Yu, Mei; Wu, Xiaoyu

    2015-01-15

    Highlights: • MFO/GN composites were synthesized by a facile in situ solvothermal approach. • The MFO microspheres are sandwiched between the graphene layers. • Each MFO microsphere is an interstitial cluster of nanoparticles. • The MFO/GN electrode exhibits an enhanced cyclability for Li-ion batteries anodes. - Abstract: In this study, two-dimensional (2D) sandwich-structured MnFe{sub 2}O{sub 4}/graphene (MFO/GN) composites are synthesized by a facile in situ solvothermal approach, using cetyltrimethylammonium bromide (CTAB) as cationic surfactant. As a consequence, the nanocomposites of MFO/GN self-assembled into a 2D sandwich structure, in which the interstitial cluster structure of microsphere-type MnFe{sub 2}O{sub 4} is sandwiched between the graphene layers. This special structure of the MFO/GN composites used as anodes for lithium-ion batteries will be favorable for the maximum accessible surface of electroactive materials, fast diffusion of lithium ions and migration of electron, and elastomeric space to accommodate volume changes during the discharge–charge processes. The as-synthesized MFO/GN composites deliver a high specific reversible capacity of 987.95 mA h g{sup −1} at a current density of 200 mA g{sup −1}, a good capacity retention of 69.27% after 80 cycles and excellent rate performance for lithium storage.

  6. 2D IR spectroscopy reveals the role of water in the binding of channel-blocking drugs to the influenza M2 channel

    SciTech Connect

    Ghosh, Ayanjeet E-mail: gai@sas.upenn.edu; Gai, Feng E-mail: gai@sas.upenn.edu; Hochstrasser, Robin M.; Wang, Jun; DeGrado, William F.; Moroz, Yurii S.; Korendovych, Ivan V.; Zanni, Martin

    2014-06-21

    Water is an integral part of the homotetrameric M2 proton channel of the influenza A virus, which not only assists proton conduction but could also play an important role in stabilizing channel-blocking drugs. Herein, we employ two dimensional infrared (2D IR) spectroscopy and site-specific IR probes, i.e., the amide I bands arising from isotopically labeled Ala30 and Gly34 residues, to probe how binding of either rimantadine or 7,7-spiran amine affects the water dynamics inside the M2 channel. Our results show, at neutral pH where the channel is non-conducting, that drug binding leads to a significant increase in the mobility of the channel water. A similar trend is also observed at pH 5.0 although the difference becomes smaller. Taken together, these results indicate that the channel water facilitates drug binding by increasing its entropy. Furthermore, the 2D IR spectral signatures obtained for both probes under different conditions collectively support a binding mechanism whereby amantadine-like drugs dock in the channel with their ammonium moiety pointing toward the histidine residues and interacting with a nearby water cluster, as predicted by molecular dynamics simulations. We believe these findings have important implications for designing new anti-influenza drugs.

  7. The effect of charged quantum dots on the mobility of a two-dimensional electron gas: How important is the Coulomb scattering?

    SciTech Connect

    Kurzmann, A. Beckel, A.; Lorke, A.; Geller, M.; Ludwig, A.; Wieck, A. D.

    2015-02-07

    We have investigated the influence of a layer of charged self-assembled quantum dots (QDs) on the mobility of a nearby two-dimensional electron gas (2DEG). Time-resolved transconductance spectroscopy was used to separate the two contributions of the change in mobility, which are: (i) The electrons in the QDs act as Coulomb scatterers for the electrons in the 2DEG. (ii) The screening ability and, hence, the mobility of the 2DEG decreases when the charge carrier density is reduced by the charged QDs, i.e., the mobility itself depends on the charge carrier concentration. Surprisingly, we find a negligible influence of the Coulomb scattering on the mobility for a 2DEG, separated by a 30 nm tunneling barrier to the layer of QDs. This means that the mobility change is completely caused by depletion, i.e., reduction of the charge carrier density in the 2DEG, which indirectly influences the mobility.

  8. Structural and subband changes at the LaAlO{sub 3}/SrTiO{sub 3} interface investigated by two-dimensional correlation spectroscopy

    SciTech Connect

    Feng, Xin; Zhao, Kun Zhan, Hong-Lei; Xiang, Wen-Feng; Lu, Zhi-Qing; Xiao, Li-Zhi

    2015-06-15

    The interplay among many ground states in correlated electron materials, especially at the LaAlO{sub 3}/SrTiO{sub 3} interface is central in deeply understanding the physical characteristics and improving further applications of these materials. Here, we use two-dimensional infrared correlation spectroscopy to study the influence of magnetic fields and temperature on the mid-infrared spectral responsivity of the interface. The magnetic field plays the main role at temperatures below the transition temperature, T{sub C}. Two additional spectral peaks were identified at wavelengths of 2800 nm and 3400 nm, when compared with our prior studies. All of these response bands are related to the spin-orbit coupling effect and crystal structure changes. Detailed structural and subband changes in the interface are also investigated.

  9. Numerical modeling of the groundwater contaminant transport for the Lake Karachai Area: The methodological approach and the basic two- dimensional regional model

    SciTech Connect

    Petrov, A.V.; Samsonova, L.M.; Vasil`kova, N.A.; Zinin, A.I.; Zinina, G.A. |

    1994-06-01

    Methodological aspects of the numerical modeling of the groundwater contaminant transport for the Lake Karachay area are discussed. Main features of conditions of the task are the high grade of non-uniformity of the aquifer in the fractured rock massif and the high density of the waste solutions, and also the high volume of the input data: both on the part of parameters of the aquifer (number of pump tests) and on the part of observations of functions of processes (long-time observations by the monitoring well grid). The modeling process for constructing the two dimensional regional model is described, and this model is presented as the basic model for subsequent full three-dimensional modeling in sub-areas of interest. Original powerful mathematical apparatus and computer codes for finite-difference numerical modeling are used.

  10. Two-Dimensional Modeling of Time-Varying Hydrodynamics and Juvenile Chinook Salmon Habitat in the Hanford Reach of the Columbia River

    SciTech Connect

    Perkins, William A.; Richmond, Marshall C.; McMichael, Geoffrey A.

    2007-10-10

    The Hanford Reach is the only remaining unimpounded reach of the Columbia River in the United States above Bonneville Dam. Discharge in the Hanford Reach is regulated by several dams and is often subject to rapid changes. Sharp flow reductions have led to the stranding or entrapment, and subsequent mortality, of juvenile chinook salmon (Oncorynchus tshawytscha) and other important fish species within the Hanford Reach. A multi-block two-dimensional depth-averaged hydrodynamic model was used to simulate time-varying river velocity and stage in a 37~km portion of the Hanford Reach. Simulation results were used to estimate time-varying juvenile chinook salmon habitat area, and the part of that habitat affected by discharge fluctuations. Affected habitat area estimates were made for the chinook salmon rearing period of four years. These estimates were used, along with other important factors, to establish a statistical relationship between discharge fluctuation and juvenile chinook salmon mortality.

  11. Thermodynamic versus kinetic control in self-assembly of zero-, one-, quasi-two-, and two-dimensional metal-organic coordination structures

    SciTech Connect

    Lin, Tao; Wu, Qi; Shi, Ziliang; Lin, Nian; Liu, Jun; Liu, Pei Nian

    2015-03-14

    Four types of metal-organic structures exhibiting specific dimensionality were studied using scanning tunneling microscopy and Monte Carlo simulations. The four structures were self-assembled out of specifically designed molecular building blocks via the same coordination motif on an Au(111) surface. We found that the four structures behaved differently in response to thermal annealing treatments: The two-dimensional structure was under thermodynamic control while the structures of lower dimension were under kinetic control. Monte Carlo simulations revealed that the self-assembly pathways of the four structures are associated with the characteristic features of their specific heat. These findings provide insights into how the dimensionality of supramolecular coordination structures affects their thermodynamic properties.

  12. On square-integrability of solutions of the stationary Schrödinger equation for the quantum harmonic oscillator in two dimensional constant curvature spaces

    SciTech Connect

    Noguera, Norman; Rózga, Krzysztof

    2015-07-15

    In this work, one provides a justification of the condition that is usually imposed on the parameters of the hypergeometric equation, related to the solutions of the stationary Schrödinger equation for the harmonic oscillator in two-dimensional constant curvature spaces, in order to determine the solutions which are square-integrable. One proves that in case of negative curvature, it is a necessary condition of square integrability and in case of positive curvature, a necessary condition of regularity. The proof is based on the analytic continuation formulas for the hypergeometric function. It is observed also that the same is true in case of a slightly more general potential than the one for harmonic oscillator.

  13. Proton transfer through hydrogen bonds in two-dimensional water layers: A theoretical study based on ab initio and quantum-classical simulations

    SciTech Connect

    Bankura, Arindam; Chandra, Amalendu

    2015-01-28

    The dynamics of proton transfer (PT) through hydrogen bonds in a two-dimensional water layer confined between two graphene sheets at room temperature are investigated through ab initio and quantum-classical simulations. The excess proton is found to be mostly solvated as an Eigen cation where the hydronium ion donates three hydrogen bonds to the neighboring water molecules. In the solvation shell of the hydronium ion, the three coordinated water molecules with two donor hydrogen bonds are found to be properly presolvated to accept a proton. Although no hydrogen bond needs to be broken for transfer of a proton to such presolvated water molecules from the hydronium ion, the PT rate is still found to be not as fast as it is for one-dimensional chains. Here, the PT is slowed down as the probability of finding a water with two donor hydrogen bonds in the solvation shell of the hydronium ion is found to be only 25%-30%. The hydroxide ion is found to be solvated mainly as a complex anion where it accepts four H-bonds through its oxygen atom and the hydrogen atom of the hydroxide ion remains free all the time. Here, the presolvation of the hydroxide ion to accept a proton requires that one of its hydrogen bonds is broken and the proton comes from a neighboring water molecule with two acceptor and one donor hydrogen bonds. The coordination number reduction by breaking of a hydrogen bond is a slow process, and also the population of water molecules with two acceptor and one donor hydrogen bonds is only 20%-25% of the total number of water molecules. All these factors together tend to slow down the hydroxide ion migration rate in two-dimensional water layers compared to that in three-dimensional bulk water.

  14. Unexpected Stable Two-dimensional ...

    Office of Scientific and Technical Information (OSTI)

    ... Lett. 105, 136805 (2010). 4 M. Peruzzini and Luca Gonsalvi, Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences, Springer (2011). 5 P. Vogt, P. De Padova, ...

  15. Reversible Exsolution of Nanometric Fe2O3 Particles in BaFe2-x(PO4)2 (0 ? x ? 2/3):The Logic of Vacancy Ordering in Novel Metal-Depleted Two-Dimensional Lattices

    SciTech Connect

    Alcover, Ignacio Blazquez; David, Rnald; Daviero-Minaud, Sylvie; Filimonov, Dmitry; Huv, Marielle; Roussel, Pascal; Kabbour, Houria; Mentr, Olivier

    2015-08-12

    We show here that the exsolution of Fe2+ ions out of two-dimensional (2D) honeycomb layers of BaFe2(PO4)2 into iron-deficient BaFe2x(PO4)2 phases and nanometric ?-Fe2O3 (typically 50 nm diameter at the grain surface) is efficient and reversible until x = 2/3 in mild oxidizing/reducing conditions. It corresponds to the renewable conversion of 12 wt % of the initial mass into iron oxide. After analyzing single crystal X-ray diffraction data of intermediate members x = 2/7, x = 1/3, x = 1/2 and the ultimate Fe-depleted x = 2/3 term, we then observed a systematic full ordering between Fe ions and vacancies (VFe) that denote unprecedented easy in-plane metal diffusion driven by the Fe2+/Fe3+ redox. Besides the discovery of a diversity of original depleted triangular ?{Fe2/3+2xO6} topologies, we propose a unified model correlating the x Fe-removal and the experimental Fe/VFe ordering into periodic one-dimensional motifs paving the layers, gaining insights into predictive crystahemistry of complex low dimensional oxides. When we increased the x values it led to a progressive change of the materials from 2D ferromagnets (Fe2+) to 2D ferrimagnets (Fe2/3+) to antiferromagnets for x = 2/3 (Fe3+).

  16. Quasi-two-dimensional electron gas at the interface of γ-Al{sub 2}O{sub 3}/SrTiO{sub 3} heterostructures grown by atomic layer deposition

    SciTech Connect

    Ngo, Thong Q.; McDaniel, Martin D.; Ekerdt, John G.; Goble, Nicholas J.; Gao, Xuan P. A.; Posadas, Agham; Kormondy, Kristy J.; Demkov, Alexander A.; Lu, Sirong; Jordan-Sweet, Jean; Smith, David J.

    2015-09-21

    We report the formation of a quasi-two-dimensional electron gas (2-DEG) at the interface of γ-Al{sub 2}O{sub 3}/TiO{sub 2}-terminated SrTiO{sub 3} (STO) grown by atomic layer deposition (ALD). The ALD growth of Al{sub 2}O{sub 3} on STO(001) single crystal substrates was performed at temperatures in the range of 200–345 °C. Trimethylaluminum and water were used as co-reactants. In situ reflection high energy electron diffraction, ex situ x-ray diffraction, and ex situ cross-sectional transmission electron microscopy were used to determine the crystallinity of the Al{sub 2}O{sub 3} films. As-deposited Al{sub 2}O{sub 3} films grown above 300 °C were crystalline with the γ-Al{sub 2}O{sub 3} phase. In situ x-ray photoelectron spectroscopy was used to characterize the Al{sub 2}O{sub 3}/STO interface, indicating that a Ti{sup 3+} feature in the Ti 2p spectrum of STO was formed after 2–3 ALD cycles of Al{sub 2}O{sub 3} at 345 °C and even after the exposure to trimethylaluminum alone at 300 and 345 °C. The interface quasi-2-DEG is metallic and exhibits mobility values of ∼4 and 3000 cm{sup 2} V{sup −1} s{sup −1} at room temperature and 15 K, respectively. The interfacial conductivity depended on the thickness of the Al{sub 2}O{sub 3} layer. The Ti{sup 3+} signal originated from the near-interfacial region and vanished after annealing in an oxygen environment.

  17. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE PAGES [OSTI]

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimoresheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.less

  18. Quantum oscillations and subband properties of the two-dimensional electron gas at the LaAlO{sub 3}/SrTiO{sub 3} interface

    SciTech Connect

    McCollam, A. Guduru, V. K.; Zeitler, U.; Maan, J. C.; Wenderich, S.; Kruize, M. K.; Molegraaf, H. J. A.; Huijben, M.; Koster, G.; Blank, D. H. A.; Rijnders, G.; Brinkman, A.; Hilgenkamp, H.

    2014-02-01

    We have performed high field magnetotransport measurements to investigate the interface electron gas in a high mobility SrTiO{sub 3}/SrCuO{sub 2}/LaAlO{sub 3}/SrTiO{sub 3} heterostructure. Shubnikov-de Haas oscillations reveal several 2D conduction subbands with carrier effective masses of 0.9m{sub e} and 2m{sub e}, quantum mobilities of order 2000 cm{sup 2}/V s, and band edges only a few millielectronvolts below the Fermi energy. Measurements in tilted magnetic fields confirm the 2D character of the electron gas, and show evidence of inter-subband scattering.

  19. Multiple copies of orbital angular momentum states through second-harmonic generation in a two-dimensional periodically poled LiTaO{sub 3} crystal

    SciTech Connect

    Fang, Xinyuan; Wei, Dunzhao; Liu, Dongmei; Zhong, Weihao; Ni, Rui; Chen, Zhenhua; Hu, Xiaopeng; Zhang, Yong Zhu, S. N.; Xiao, Min

    2015-10-19

    We experimentally demonstrate multiple copies of optical orbital angular momentum (OAM) states through quasi-phase-matched (QPM) second-harmonic (SH) generation in a 2D periodically poled LiTaO{sub 3} (PPLT) crystal. Since the QPM condition is satisfied by involving different reciprocal vectors in the 2D PPLT crystal, collinear and noncollinear SH beams carrying OAMs of l{sub 2} are simultaneously generated by the input fundamental beam with an OAM of l{sub 1}. The OAM conservation law (i.e., l{sub 2} = 2l{sub 1}) holds well in the experiment, which can tolerate certain phase-mismatch between the interacting waves. Our results provide an efficient way to obtain multiple copies of the wavelength-converted OAM states, which can be used to enhance the capacity in optical communications.

  20. Two-dimensional DORT discrete ordinates X-Y geometry neutron flux calculations for the Halden Heavy Boiling Water Reactor core configurations

    SciTech Connect

    Slater, C.O.

    1990-07-01

    Results are reported for two-dimensional discrete ordinates, X-Y geometry calculations performed for seven Halden Heavy Boiling Water Reactor core configurations. The calculations were performed in support of an effort to reassess the neutron fluence received by the reactor vessel. Nickel foil measurement data indicated considerable underprediction of fluences by the previously used multigroup removal- diffusion method. Therefore, calculations by a more accurate method were deemed appropriate. For each core configuration, data are presented for (1) integral fluxes in the core and near the vessel wall, (2) neutron spectra at selected locations, (3) isoflux contours superimposed on the geometry models, (4) plots of the geometry models, and (5) input for the calculations. The initial calculations were performed with several mesh sizes. Comparisons of the results from these calculations indicated that the uncertainty in the calculated fluxes should be less than 10%. However, three-dimensional effects (such as axial asymmetry in the fuel loading) could contribute to much greater uncertainty in the calculated neutron fluxes. 7 refs., 22 figs., 11 tabs.