National Library of Energy BETA

Sample records for trap mass spectrometer

  1. Mini ion trap mass spectrometer

    DOEpatents

    Dietrich, Daniel D.; Keville, Robert F.

    1995-01-01

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  2. Mini ion trap mass spectrometer

    DOEpatents

    Dietrich, D.D.; Keville, R.F.

    1995-09-19

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  3. Microscale ion trap mass spectrometer

    DOEpatents

    Ramsey, J. Michael; Witten, William B.; Kornienko, Oleg

    2002-01-01

    An ion trap for mass spectrometric chemical analysis of ions is delineated. The ion trap includes a central electrode having an aperture; a pair of insulators, each having an aperture; a pair of end cap electrodes, each having an aperture; a first electronic signal source coupled to the central electrode; a second electronic signal source coupled to the end cap electrodes. The central electrode, insulators, and end cap electrodes are united in a sandwich construction where their respective apertures are coaxially aligned and symmetric about an axis to form a partially enclosed cavity having an effective radius r.sub.0 and an effective length 2z.sub.0, wherein r.sub.0 and/or z.sub.0 are less than 1.0 mm, and a ratio z.sub.0 /r.sub.0 is greater than 0.83.

  4. Differentially pumped dual linear quadrupole ion trap mass spectrometer

    DOEpatents

    Owen, Benjamin C.; Kenttamaa, Hilkka I.

    2015-10-20

    The present disclosure provides a new tandem mass spectrometer and methods of using the same for analyzing charged particles. The differentially pumped dual linear quadrupole ion trap mass spectrometer of the present disclose includes a combination of two linear quadrupole (LQIT) mass spectrometers with differentially pumped vacuum chambers.

  5. Electron source for a mini ion trap mass spectrometer

    DOEpatents

    Dietrich, D.D.; Keville, R.F.

    1995-12-19

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  6. Electron source for a mini ion trap mass spectrometer

    DOEpatents

    Dietrich, Daniel D.; Keville, Robert F.

    1995-01-01

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  7. Dipole Excitation With A Paul Ion Trap Mass Spectrometer

    SciTech Connect

    MacAskill, J. A.; Madzunkov, S. M.; Chutjian, A.

    2011-06-01

    Preliminary results are presented for the use of an auxiliary radiofrequency (rf) excitation voltage in combination with a high purity, high voltage rf generator to perform dipole excitation within a high precision Paul ion trap. These results show the effects of the excitation frequency over a continuous frequency range on the resultant mass spectra from the Paul trap with particular emphasis on ion ejection times, ion signal intensity, and peak shapes. Ion ejection times are found to decrease continuously with variations in dipole frequency about several resonant values and show remarkable symmetries. Signal intensities vary in a complex fashion with numerous resonant features and are driven to zero at specific frequency values. Observed intensity variations depict dipole excitations that target ions of all masses as well as individual masses. Substantial increases in mass resolution are obtained with resolving powers for nitrogen increasing from 114 to 325.

  8. MASS SPECTROMETER

    DOEpatents

    White, F.A.

    1960-08-23

    A mass spectrometer is designed with a first adjustable magnetic field for resolving an ion beam into beams of selected masses, a second adjustable magnetic field for further resolving the ion beam from the first field into beams of selected masses, a thin foil disposed in the path of the beam between the first and second magnets to dissociate molecular ions incident thereon, an electrostatic field for further resolving the ion beam from the second field into beams of selected masses, and a detector disposed adjacent to the electrostatic field to receive the ion beam.

  9. Finnigan ion trap mass spectrometer detection limits and thermal energy analyzer interface status report and present capabilities

    SciTech Connect

    Alcaraz, A.; Andresen, B.; Martin, W.

    1990-10-18

    A new Finnigan ion trap mass spectrometer was purchased and installed at LLNL. Over a period of several months the instrument was tested under a variety of conditions utilizing a capillary gas chromatography interface which allowed separated organic compounds to be carried directly into the ion source of the mass spectrometer. This direct interface allowed maximum analytical sensitivity. A variety of critical tests were performed in order to optimize the sensitivity of the system under a variety of analysis conditions. These tests altered the critical time cycles of the ionization, ion trapping, and detection. Various carrier gas pressures were also employed in order to ascertain the overall sensitivity of the instrument. In addition we have also interfaced a thermal energy analyzer (TEA) to the gas chromatograph in order to simultaneously detect volatile nitrogen containing compounds while mass spectral data is being acquired. This is the first application at this laboratory of simultaneous ultra-trace detections while utilizing two orthogonal analytical techniques. In particular, explosive-related compound and/or residues are of interest to the general community in water, soil and gas sampler. In this paper are highlighted a few examples of the analytical power of this new GC-TEA-ITMS technology.

  10. Ultra High Mass Range Mass Spectrometer System

    DOEpatents

    Reilly, Peter T. A. [Knoxville, TN

    2005-12-06

    Applicant's present invention comprises mass spectrometer systems that operate in a mass range from 1 to 10.sup.16 DA. The mass spectrometer system comprising an inlet system comprising an aerodynamic lens system, a reverse jet being a gas flux generated in an annulus moving in a reverse direction and a multipole ion guide; a digital ion trap; and a thermal vaporization/ionization detector system. Applicant's present invention further comprises a quadrupole mass spectrometer system comprising an inlet system having a quadrupole mass filter and a thermal vaporization/ionization detector system. Applicant's present invention further comprises an inlet system for use with a mass spectrometer system, a method for slowing energetic particles using an inlet system. Applicant's present invention also comprises a detector device and a method for detecting high mass charged particles.

  11. Miniaturized Mass Spectrometer

    Energy Innovation Portal

    2013-03-12

    Sandia's invention relates to a miniaturized mass spectrometer using a silicon chip field emitter array as the source of electrons for impact ionization of chemical species. ...

  12. Action spectroscopy of SrCl{sup +} using an integrated ion trap time-of-flight mass spectrometer

    SciTech Connect

    Puri, Prateek Schowalter, Steven J.; Hudson, Eric R.; Kotochigova, Svetlana; Petrov, Alexander

    2014-07-07

    The photodissociation cross-section of SrCl{sup +} is measured in the spectral range of 36 000–46 000 cm{sup −1} using a modular time-of-flight mass spectrometer (TOF-MS). By irradiating a sample of trapped SrCl{sup +} molecular ions with a pulsed dye laser, X{sup 1}Σ{sup +} state molecular ions are electronically excited to the repulsive wall of the A{sup 1}Π state, resulting in dissociation. Using the TOF-MS, the product fragments are detected and the photodissociation cross-section is determined for a broad range of photon energies. Detailed ab initio calculations of the SrCl{sup +} molecular potentials and spectroscopic constants are also performed and are found to be in good agreement with experiment. The spectroscopic constants for SrCl{sup +} are also compared to those of another alkaline earth halogen, BaCl{sup +}, in order to highlight structural differences between the two molecular ions. This work represents the first spectroscopy and ab initio calculations of SrCl{sup +}.

  13. Mass Spectrometer Laboratory | Photosynthetic Antenna Research Center

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mass Spectrometer Laboratory Mass Spectrometer Laboratory A look inside the recently updated Mass Spectrometer Facility managed by Staff Scientish Hao Zhang

  14. Method for calibrating mass spectrometers

    DOEpatents

    Anderson, Gordon A [Benton City, WA; Brands, Michael D [Richland, WA; Bruce, James E [Schwenksville, PA; Pasa-Tolic, Ljiljana [Richland, WA; Smith, Richard D [Richland, WA

    2002-12-24

    A method whereby a mass spectra generated by a mass spectrometer is calibrated by shifting the parameters used by the spectrometer to assign masses to the spectra in a manner which reconciles the signal of ions within the spectra having equal mass but differing charge states, or by reconciling ions having known differences in mass to relative values consistent with those known differences. In this manner, the mass spectrometer is calibrated without the need for standards while allowing the generation of a highly accurate mass spectra by the instrument.

  15. Method for increasing the dynamic range of mass spectrometers

    DOEpatents

    Belov, Mikhail; Smith, Richard D.; Udseth, Harold R.

    2004-09-07

    A method for enhancing the dynamic range of a mass spectrometer by first passing a sample of ions through the mass spectrometer having a quadrupole ion filter, whereupon the intensities of the mass spectrum of the sample are measured. From the mass spectrum, ions within this sample are then identified for subsequent ejection. As further sampling introduces more ions into the mass spectrometer, the appropriate rf voltages are applied to a quadrupole ion filter, thereby selectively ejecting the undesired ions previously identified. In this manner, the desired ions may be collected for longer periods of time in an ion trap, thus allowing better collection and subsequent analysis of the desired ions. The ion trap used for accumulation may be the same ion trap used for mass analysis, in which case the mass analysis is performed directly, or it may be an intermediate trap. In the case where collection is an intermediate trap, the desired ions are accumulated in the intermediate trap, and then transferred to a separate mass analyzer. The present invention finds particular utility where the mass analysis is performed in an ion trap mass spectrometer or a Fourier transform ion cyclotron resonance mass spectrometer.

  16. Imaging mass spectrometer with mass tags

    DOEpatents

    Felton, James S.; Wu, Kuang Jen; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2010-06-01

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  17. Imaging mass spectrometer with mass tags

    DOEpatents

    Felton, James S.; Wu, Kuang Jen J.; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2013-01-29

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  18. Time of flight mass spectrometer

    DOEpatents

    Ulbricht, Jr., William H.

    1984-01-01

    A time-of-flight mass spectrometer is described in which ions are desorbed from a sample by nuclear fission fragments, such that desorption occurs at the surface of the sample impinged upon by the fission fragments. This configuration allows for the sample to be of any thickness, and eliminates the need for complicated sample preparation.

  19. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    SciTech Connect

    Chastagner, P.

    2001-08-01

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  20. Mass Spectrometer Facility | Photosynthetic Antenna Research Center

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mass Spectrometer Facility Mass Spectrometer Facility The PARC Mass Spectrometer Facility uses customized instrumentation to directly measure the individual polypeptide mass of different light-harvesting complexes to do assignment to specific gene products and investigate protein processing. Newly developed techniques are also applied to measure the mass of native protein complexes. Structural information of complexes is extracted by combining protein chemical modification and H/D exchange

  1. Penning trap mass measurements on nobelium isotopes

    SciTech Connect

    Dworschak, M.; Block, M.; Ackermann, D.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Vorobyev, G. K.; Audi, G.; Blaum, K.; Droese, C.; Marx, G.; Schweikhard, L.; Eliseev, S.; Ketter, J.; Fleckenstein, T.; Haettner, E.; Plass, W. R.; Scheidenberger, C.; Ketelaer, J.; Kluge, H.-J.

    2010-06-15

    The Penning trap mass spectrometer SHIPTRAP at GSI Darmstadt allows accurate mass measurements of radionuclides, produced in fusion-evaporation reactions and separated by the velocity filter SHIP from the primary beam. Recently, the masses of the three nobelium isotopes {sup 252-254}No were determined. These are the first direct mass measurements of transuranium elements, which provide new anchor points in this region. The heavy nuclides were produced in cold-fusion reactions by irradiating a PbS target with a {sup 48}Ca beam, resulting in production rates of the nuclei of interest of about one atom per second. In combination with data from decay spectroscopy our results are used to perform a new atomic-mass evaluation in this region.

  2. Subcellular-level resolution MALDI-MS imaging of maize leaf metabolites by MALDI-linear ion trap-Orbitrap mass spectrometer

    DOE PAGES [OSTI]

    Korte, Andrew R.; Yandeau-Nelson, Marna D.; Nikolau, Basil J.; Lee, Young Jin

    2015-01-25

    A significant limiting factor in achieving high spatial resolution for matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS) imaging is the size of the laser spot at the sample surface. We present modifications to the beam-delivery optics of a commercial MALDI-linear ion trap-Orbitrap instrument, incorporating an external Nd:YAG laser, beam-shaping optics, and an aspheric focusing lens, to reduce the minimum laser spot size from ~50 μm for the commercial configuration down to ~9 μm for the modified configuration. This improved system was applied for MALDI-MS imaging of cross sections of juvenile maize leaves at 5-μm spatial resolution using an oversampling method. Theremore » are a variety of different metabolites including amino acids, glycerolipids, and defense-related compounds were imaged at a spatial resolution well below the size of a single cell. Such images provide unprecedented insights into the metabolism associated with the different tissue types of the maize leaf, which is known to asymmetrically distribute the reactions of C4 photosynthesis among the mesophyll and bundle sheath cell types. The metabolite ion images correlate with the optical images that reveal the structures of the different tissues, and previously known and newly revealed asymmetric metabolic features are observed.« less

  3. Subcellular-level resolution MALDI-MS imaging of maize leaf metabolites by MALDI-linear ion trap-Orbitrap mass spectrometer

    SciTech Connect

    Korte, Andrew R.; Yandeau-Nelson, Marna D.; Nikolau, Basil J.; Lee, Young Jin

    2015-01-25

    A significant limiting factor in achieving high spatial resolution for matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS) imaging is the size of the laser spot at the sample surface. We present modifications to the beam-delivery optics of a commercial MALDI-linear ion trap-Orbitrap instrument, incorporating an external Nd:YAG laser, beam-shaping optics, and an aspheric focusing lens, to reduce the minimum laser spot size from ~50 μm for the commercial configuration down to ~9 μm for the modified configuration. This improved system was applied for MALDI-MS imaging of cross sections of juvenile maize leaves at 5-μm spatial resolution using an oversampling method. There are a variety of different metabolites including amino acids, glycerolipids, and defense-related compounds were imaged at a spatial resolution well below the size of a single cell. Such images provide unprecedented insights into the metabolism associated with the different tissue types of the maize leaf, which is known to asymmetrically distribute the reactions of C4 photosynthesis among the mesophyll and bundle sheath cell types. The metabolite ion images correlate with the optical images that reveal the structures of the different tissues, and previously known and newly revealed asymmetric metabolic features are observed.

  4. Gas sampling system for a mass spectrometer

    DOEpatents

    2003-12-30

    The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

  5. Compact hydrogen/helium isotope mass spectrometer

    DOEpatents

    Funsten, Herbert O.; McComas, David J.; Scime, Earl E.

    1996-01-01

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  6. Micro mass spectrometer on a chip.

    SciTech Connect

    Cruz, Dolores Y.; Blain, Matthew Glenn; Fleming, James Grant

    2005-11-01

    The design, simulation, fabrication, packaging, electrical characterization and testing analysis of a microfabricated a cylindrical ion trap ({mu}CIT) array is presented. Several versions of microfabricated cylindrical ion traps were designed and fabricated. The final design of the individual trap array element consisted of two end cap electrodes, one ring electrode, and a detector plate, fabricated in seven tungsten metal layers by molding tungsten around silicon dioxide (SiO{sub 2}) features. Each layer of tungsten is then polished back in damascene fashion. The SiO{sub 2} was removed using a standard release processes to realize a free-hung structure. Five different sized traps were fabricated with inner radii of 1, 1.5, 2, 5 and 10 {micro}m and heights ranging from 3-24 {micro}m. Simulations examined the effects of ion and neutral temperature, the pressure and nature of cooling gas, ion mass, trap voltage and frequency, space-charge, fabrication defects, and other parameters on the ability of micrometer-sized traps to store ions. The electrical characteristics of the ion trap arrays were determined. The capacitance was 2-500 pF for the various sized traps and arrays. The resistance was in the order of 1-2 {Omega}. The inductance of the arrays was calculated to be 10-1500 pH, depending on the trap and array sizes. The ion traps' field emission characteristics were assessed. It was determined that the traps could be operated up to 125 V while maintaining field emission currents below 1 x 10{sup -15} A. The testing focused on using the 5-{micro}m CITs to trap toluene (C{sub 7}H{sub 8}). Ion ejection from the traps was induced by termination of the RF voltage applied to the ring electrode and current measured on the collector electrode suggested trapping of ions in 1-10% of the traps. Improvements to the to the design of the traps were defined to minimize voltage drop to the substrate, thereby increasing trapping voltage applied to the ring electrode, and to allow

  7. ELECTRONICS UPGRADE OF HIGH RESOLUTION MASS SPECTROMETERS

    SciTech Connect

    Mcintosh, J; Joe Cordaro, J

    2008-03-10

    High resolution mass spectrometers are specialized systems that allow researchers to determine the exact mass of samples to four significant digits by using magnetic and electronic sector mass analyzers. Many of the systems in use today at research laboratories and universities were designed and built more than two decades ago. The manufacturers of these systems have abandoned the support for some of the mass spectrometers and parts to power and control them have become scarce or obsolete. The Savannah River National Laboratory has been involved in the upgrade of the electronics and software for these legacy machines. The Electronics Upgrade of High Resolution Mass Spectrometers consists of assembling high-end commercial instrumentation from reputable manufacturers with a minimal amount of customization to replace the electronics for the older systems. By taking advantage of advances in instrumentation, precise magnet control can be achieved using high resolution current sources and continuous feedback from a high resolution hall-effect probe. The custom equipment include a precision voltage divider/summing amplifier chassis, high voltage power supply chassis and a chassis for controlling the voltage emission for the mass spectrometer source tube. The upgrade package is versatile enough to interface with valve control, vacuum and other instrumentation. Instrument communication is via a combination of Ethernet and traditional IEEE-488 GPIB protocols. The system software upgrades include precision control, feedback and spectral waveform analysis tools.

  8. Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements

    SciTech Connect

    Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S.; Blaum, K.; Droese, C.; Marx, G.; Schweikhard, L.; Duellmann, Ch. E.; Eibach, M.; Eliseev, S.; Haettner, E.; Plass, W. R.; Scheidenberger, C.; Hessberger, F. P.; Ramirez, E. Minaya; Nesterenko, D.; and others

    2013-03-19

    Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

  9. Interface for liquid chromatograph-mass spectrometer

    DOEpatents

    Andresen, Brian D.; Fought, Eric R.

    1989-01-01

    A moving belt interface for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer.

  10. Portable gas chromatograph-mass spectrometer

    DOEpatents

    Andresen, Brian D.; Eckels, Joel D.; Kimmons, James F.; Myers, David W.

    1996-01-01

    A gas chromatograph-mass spectrometer (GC-MS) for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units.

  11. Portable gas chromatograph-mass spectrometer

    DOEpatents

    Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Myers, D.W.

    1996-06-11

    A gas chromatograph-mass spectrometer (GC-MS) is described for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units. 4 figs.

  12. Interface for liquid chromatograph-mass spectrometer

    DOEpatents

    Andresen, B.D.; Fought, E.R.

    1989-09-19

    A moving belt interface is described for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer. 8 figs.

  13. Capillary zone electrophoresis-mass spectrometer interface

    DOEpatents

    D'Silva, Arthur

    1996-08-06

    A device for providing equal electrical potential between two loci unconnected by solid or liquid electrical conducts is provided. The device comprises a first electrical conducting terminal, a second electrical conducting terminal connected to the first terminal by a rigid dielectric structure, and an electrically conducting gas contacting the first and second terminals. This device is particularly suitable for application in the electrospray ionization interface between a capillary zone electrophoresis apparatus and a mass spectrometer.

  14. Capillary zone electrophoresis-mass spectrometer interface

    DOEpatents

    D`Silva, A.

    1996-08-06

    A device for providing equal electrical potential between two loci unconnected by solid or liquid electrical conductors is provided. The device comprises a first electrical conducting terminal, a second electrical conducting terminal connected to the first terminal by a rigid dielectric structure, and an electrically conducting gas contacting the first and second terminals. This device is particularly suitable for application in the electrospray ionization interface between a capillary zone electrophoresis apparatus and a mass spectrometer. 1 fig.

  15. Expert overseer for mass spectrometer system

    DOEpatents

    Filby, Evan E.; Rankin, Richard A.

    1991-01-01

    An expert overseer for the operation and real-time management of a mass spectrometer and associated laboratory equipment. The overseer is a computer-based expert diagnostic system implemented on a computer separate from the dedicated computer used to control the mass spectrometer and produce the analysis results. An interface links the overseer to components of the mass spectrometer, components of the laboratory support system, and the dedicated control computer. Periodically, the overseer polls these devices and as well as itself. These data are fed into an expert portion of the system for real-time evaluation. A knowledge base used for the evaluation includes both heuristic rules and precise operation parameters. The overseer also compares current readings to a long-term database to detect any developing trends using a combination of statistical and heuristic rules to evaluate the results. The overseer has the capability to alert lab personnel whenever questionable readings or trends are observed and provide a background review of the problem and suggest root causes and potential solutions, or appropriate additional tests that could be performed. The overseer can change the sequence or frequency of the polling to respond to an observation in the current data.

  16. Mass spectrometer vacuum housing and pumping system

    DOEpatents

    Coutts, G.W.; Bushman, J.F.; Alger, T.W.

    1996-07-23

    A vacuum housing and pumping system is described for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof. 7 figs.

  17. Mass spectrometer vacuum housing and pumping system

    DOEpatents

    Coutts, Gerald W.; Bushman, John F.; Alger, Terry W.

    1996-01-01

    A vacuum housing and pumping system for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof.

  18. Open-split interface for mass spectrometers

    DOEpatents

    Diehl, John W.

    1991-01-01

    An open-split interface includes a connector body having four leg members projecting therefrom within a single plane, the first and third legs being coaxial and the second and fourth legs being coaxial. A tubular aperture extends through the first and third legs and a second tubular aperture extends through the second and fourth legs, connecting at a juncture within the center of the connector body. A fifth leg projects from the connector body and has a third tubular aperture extending therethrough to the juncture of the first and second tubular apertures. A capillary column extends from a gas chromatograph into the third leg with its end adjacent the juncture. A flow restrictor tube extends from a mass spectrometer through the first tubular aperture in the first and third legs and into the capillary columnm end, so as to project beyond the end of the third leg within the capillary column. An annular gap between the tube and column allows excess effluent to pass to the juncture. A pair of short capillary columns extend from separate detectors into the second tubular aperture in the second and fourth legs, and are oriented with their ends spaced slightly from the first capillary column end. A sweep flow tube is mounted in the fifth leg so as to supply a helium sweep flow to the juncture.

  19. Mass spectrometer having a derivatized sample presentation apparatus

    DOEpatents

    Nelson, Randall W.

    2000-07-25

    A mass spectrometer having a derivatized sample presentation apparatus is provided. The sample presentation apparatus has a complex bound to the surface of the sample presentation apparatus. This complex includes a molecule which may chemically modify a biomolecule.

  20. SIEMENS ADVANCED QUANTRA FTICR MASS SPECTROMETER FOR ULTRA HIGH RESOLUTION AT LOW MASS

    SciTech Connect

    Spencer, W; Laura Tovo, L

    2008-07-08

    The Siemens Advanced Quantra Fourier Transform Ion Cyclotron Resonance (FTICR) mass spectrometer was evaluated as an alternative instrument to large double focusing mass spectrometers for gas analysis. High resolution mass spectrometers capable of resolving the common mass isomers of the hydrogen isotopes are used to provide data for accurate loading of reservoirs and to monitor separation of tritium, deuterium, and helium. Conventional double focusing magnetic sector instruments have a resolution that is limited to about 5000. The Siemens FTICR instrument achieves resolution beyond 400,000 and could possibly resolve the tritium ion from the helium-3 ion, which differ by the weight of an electron, 0.00549 amu. Working with Y-12 and LANL, SRNL requested Siemens to modify their commercial Quantra system for low mass analysis. To achieve the required performance, Siemens had to increase the available waveform operating frequency from 5 MHz to 40 MHz and completely redesign the control electronics and software. However, they were able to use the previous ion trap, magnet, passive pump, and piezo-electric pulsed inlet valve design. NNSA invested $1M in this project and acquired four systems, two for Y-12 and one each for SRNL and LANL. Siemens claimed a $10M investment in the Quantra systems. The new Siemens Advanced Quantra demonstrated phenomenal resolution in the low mass range. Resolution greater than 400,000 was achieved for mass 2. The new spectrometer had a useful working mass range to 500 Daltons. However, experiments found that a continuous single scan from low mass to high was not possible. Two useful working ranges were established covering masses 1 to 6 and masses 12 to 500 for our studies. A compromise performance condition enabled masses 1 to 45 to be surveyed. The instrument was found to have a dynamic range of about three orders of magnitude and quantitative analysis is expected to be limited to around 5 percent without using complex fitting algorithms

  1. Universal collisional activation ion trap mass spectrometry

    DOEpatents

    McLuckey, Scott A.; Goeringer, Douglas E.; Glish, Gary L.

    1993-01-01

    A universal collisional activation ion trap comprises an ion trapping means containing a bath gas and having connected thereto a noise signal generator. A method of operating a universal collisional activation ion trap comprises the steps of: providing an ion trapping means; introducing into the ion trapping means a bath gas; and, generating a noise signal within the ion trapping means; introducing into the ion trapping means a substance that, when acted upon by the noise signal, undergoes collisional activation to form product ions.

  2. Universal collisional activation ion trap mass spectrometry

    DOEpatents

    McLuckey, S.A.; Goeringer, D.E.; Glish, G.L.

    1993-04-27

    A universal collisional activation ion trap comprises an ion trapping means containing a bath gas and having connected thereto a noise signal generator. A method of operating a universal collisional activation ion trap comprises the steps of: providing an ion trapping means; introducing into the ion trapping means a bath gas; and, generating a noise signal within the ion trapping means; introducing into the ion trapping means a substance that, when acted upon by the noise signal, undergoes collisional activation to form product ions.

  3. A Recoil Mass Spectrometer for the HHIRF facility

    SciTech Connect

    Cole, J.D. ); Cormier, T.M. ); Hamilton, J.H. . Dept. of Physics and Astronomy)

    1989-01-01

    A Recoil Mass Spectrometer (RMS) is to be built that will carry out a broad research program in heavy-ion science. The RMS will make possible the study of otherwise inaccessible exotic nuclei. Careful attention has been given to match the RMS to all the beams available from the HHIRF accelerators, including those beams with the highest energy, as well as massive particles for use in inverse reactions. The RMS is to be a momentum achromat followed by a split electric-dipole mass spectrometer of the type operating at NSRL at the University of Rochester. The RMS is essential for many of the proposed experiments on short-lived and/or low cross-section products. The spectrometer design is discussed, with examples and comparisons with other spectrometers given. Detector arrays to be used with the RMS are also discussed. 21 refs., 4 figs., 1 tab.

  4. Miniaturized Mass Spectrometer - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Real-time exhaust gas analysis for automotive applications leak detection, residual gas analysis thermal desorption mass spectroscopy environmental analysis for liquid and gas...

  5. EXTENDING THE USEFUL LIFE OF OLDER MASS SPECTROMETERS

    SciTech Connect

    Johnson, S.; Cordaro, J.; Holland, M.; Jones, V.

    2010-06-17

    Thermal ionization and gas mass spectrometers are widely used across the Department of Energy (DOE) Complex and contractor laboratories. These instruments support critical missions, where high reliability and low measurement uncertainty are essential. A growing number of these mass spectrometers are significantly older than their original design life. The reality is that manufacturers have declared many of the instrument models obsolete, with direct replacement parts and service no longer available. Some of these obsolete models do not have a next generation, commercially available replacement. Today's budget conscious economy demands for the use of creative funds management. Therefore, the ability to refurbish (or upgrade) these valuable analytical tools and extending their useful life is a cost effective option. The Savannah River Site (SRS) has the proven expertise to breathe new life into older mass spectrometers, at a significant cost savings compared to the purchase and installation of new instruments. A twenty-seven year old Finnigan MAT-261{trademark} Thermal Ionization Mass Spectrometer (TIMS), located at the SRS F/H Area Production Support Laboratory, has been successfully refurbished. Engineers from the Savannah River National Laboratory (SRNL) fabricated and installed the new electronics. These engineers also provide continued instrument maintenance services. With electronic component drawings being DOE Property, other DOE Complex laboratories have the option to extend the life of their aged Mass Spectrometers.

  6. Sample introducing apparatus and sample modules for mass spectrometer

    DOEpatents

    Thompson, Cyril V.; Wise, Marcus B.

    1993-01-01

    An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus.

  7. Sample introducing apparatus and sample modules for mass spectrometer

    DOEpatents

    Thompson, C.V.; Wise, M.B.

    1993-12-21

    An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus. 5 figures.

  8. Compact mass spectrometer for plasma discharge ion analysis

    DOEpatents

    Tuszewski, Michel G.

    1997-01-01

    A mass spectrometer and methods for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector.

  9. Compact mass spectrometer for plasma discharge ion analysis

    DOEpatents

    Tuszewski, M.G.

    1997-07-22

    A mass spectrometer and methods are disclosed for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector. 7 figs.

  10. Mass spectrometer and methods of increasing dispersion between ion beams

    DOEpatents

    Appelhans, Anthony D.; Olson, John E.; Delmore, James E.

    2006-01-10

    A mass spectrometer includes a magnetic sector configured to separate a plurality of ion beams, and an electrostatic sector configured to receive the plurality of ion beams from the magnetic sector and increase separation between the ion beams, the electrostatic sector being used as a dispersive element following magnetic separation of the plurality of ion beams. Other apparatus and methods are provided.

  11. Synchrotron plus Mass Spectrometer equals New Insights Into Combustion

    Office of Science (SC)

    Chemistry | U.S. DOE Office of Science (SC) Synchrotron plus Mass Spectrometer equals New Insights Into Combustion Chemistry Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E:

  12. Design and test of magnetic shields for quadrupole mass spectrometers

    SciTech Connect

    Gervasini, G.; De Angeli, M.; Gittini, G.

    2007-03-15

    The use of quadrupole mass spectrometers in plasma experiments with magnetic field confinement presents troublesome problems because of the presence of static magnetic fields. In mass spectrometers, the Lorentz force associated with the magnetic field deflects the ion trajectory in the analyzer section with a subsequent loss of instrument sensitivity. In order to reduce the effect of the externally applied magnetic field in the quadrupole, different magnetic materials have been considered as a shielding structure (iron Fe-37, soft iron Armco{sup TM}, Amumetal{sup TM} sheets). The present work describes a solution to shielding quadrupole mass spectrometers against strong magnetic fields giving an introduction to magnetic shield design, by means of finite element calculations, taking into account many factors such as the material used, the length and thickness of the shield, and the effects of openings. To prove the efficiency of the shielding system, the hydrogen signal from the quadrupole instrument has been monitored. The intensity and the direction of the magnetic field with respect to the quadrupole head axes have been varied. Measurements of the magnetic field have been made in order to validate the calculations and an example of application of the shield design guidelines to a magnetic confined plasma device is presented and tested in situ. The principal aim of the present work is to indicate a possible approach to the problem and how to obtain a practical solution with a worthy compromise between costs and performances.

  13. Miniature quadrupole mass spectrometer having a cold cathode ionization source

    DOEpatents

    Felter, Thomas E.

    2002-01-01

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  14. Linear electric field time-of-flight ion mass spectrometer

    DOEpatents

    Funsten, Herbert O.; Feldman, William C.

    2008-06-10

    A linear electric field ion mass spectrometer having an evacuated enclosure with means for generating a linear electric field located in the evacuated enclosure and means for injecting a sample material into the linear electric field. A source of pulsed ionizing radiation injects ionizing radiation into the linear electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between ionization of atoms or molecules and arrival of an ion out of the ionized atoms or molecules at a predetermined position.

  15. Continuous time-of-flight ion mass spectrometer

    DOEpatents

    Funsten, Herbert O.; Feldman, William C.

    2004-10-19

    A continuous time-of-flight mass spectrometer having an evacuated enclosure with means for generating an electric field located in the evacuated enclosure and means for injecting a sample material into the electric field. A source of continuous ionizing radiation injects ionizing radiation into the electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between arrival of a secondary electron out of said ionized atoms or molecules at a first predetermined location and arrival of a sample ion out of said ionized atoms or molecules at a second predetermined location.

  16. Design and operational characteristics of a cast steel mass spectrometer

    SciTech Connect

    Blantocas, Gene Q.; Ramos, Henry J.; Wada, Motoi

    2004-09-01

    A cast steel magnetic sector mass analyzer is developed for studies of hydrogen and helium ion beams generated by a gas discharge compact ion source. The optimum induced magnetic flux density of 3500 G made it possible to scan the whole spectrum of hydrogen and helium ion species. Analysis of beam characteristics shows that the mass spectrometer sensitivity, and resolving power are approximately inversely proportional. The resolution is enhanced at higher pressures and lower current discharges. In contrast, the instrument sensitivity increased at higher current discharges and decreased at higher pressures. Calculations of the ultimate resolving power with reference to analyzer dimensions yield a numerical value of 30. System anomaly in the form of spherical aberrations was also analyzed using the paraxial beam envelope equation. Beam divergence is most significant at high discharge conditions where angular spread reaches an upper limit of 8.6 deg.

  17. Linear electronic field time-of-flight ion mass spectrometers

    DOEpatents

    Funsten, Herbert O. (Los Alamos, NM)

    2010-08-24

    Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber; a means of introducing an analyte of interest into the first drift region; a pulsed ionization source which produces molecular ions from said analyte of interest; a first foil positioned between the first drift region and the second drift region, which dissociates said molecular ions into constituent atomic ions and emits secondary electrons; an electrode which produces secondary electrons upon contact with a constituent atomic ion in second drift region; a stop detector comprising a first ion detection region and a second ion detection region; and a timing means connected to the pulsed ionization source, to the first ion detection region, and to the second ion detection region.

  18. GoAmazon 2014/15 Thermal Desorption Chemical Ionization Mass Spectrometer

    Office of Scientific and Technical Information (OSTI)

    (TDCIMS) Field Campaign Report (Technical Report) | SciTech Connect GoAmazon 2014/15 Thermal Desorption Chemical Ionization Mass Spectrometer (TDCIMS) Field Campaign Report Citation Details In-Document Search Title: GoAmazon 2014/15 Thermal Desorption Chemical Ionization Mass Spectrometer (TDCIMS) Field Campaign Report The Thermal Desorption Chemical Ionization Mass Spectrometer (TDCIMS) deployment to the U.S. Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Climate

  19. Rotary turret and reusable specimen holder for mass spectrometer

    DOEpatents

    Banar, Joseph C.; Perrin, Richard E.; Ostrenga, Raymond A.

    1988-01-01

    A sample holder for use in a mass spectrometer is provided for heating a sample to discharge ions through an electrostatic field which focuses and accelerates the ions for analysis. Individual specimen holders form a plurality of filaments for heating the sample materials for ion emission. Mounting devices hold the plurality of filaments at regular spaced apart angles in a closed configuration adjacent the electrostatic field elements. A substantially solid ceramic turret is provided with a plurality of electrical contacts which engage the individual holder means for energizing the filaments and forming a corresponding plurality of radially facing, axially extending first conductive surfaces. A substantially solid stationary turret bearing member is mounted about the rotating turret with a plurality of radially biased second electrical conductive surfaces, mounted to electrically contact facing ones of the plurality of radially facing first conductive surfaces. The assembly provides a large thermal mass for thermal stability and large electrical contact areas for repeatable, stable power input for heating the sample materials. An improved sample holder is also provided having a ceramic body portion for removably engaging conductive wires. The conductive wires are compatible with a selected filament element and the sample material to be analyzed.

  20. Extended-range grazing-incidence spectrometer for high-resolution extreme ultraviolet measurements on an electron beam ion trap

    SciTech Connect

    Beiersdorfer, P.; Magee, E. W.; Brown, G. V.; Träbert, E.; Widmann, K.; Hell, N.

    2014-11-15

    A high-resolution grazing-incidence grating spectrometer has been implemented on the Livermore electron beam ion traps for performing very high-resolution measurements in the soft x-ray and extreme ultraviolet region spanning from below 10 Å to above 300 Å. The instrument operates without an entrance slit and focuses the light emitted by highly charged ions located in the roughly 50 μm wide electron beam onto a cryogenically cooled back-illuminated charge-coupled device detector. The measured line widths are below 0.025 Å above 100 Å, and the resolving power appears to be limited by the source size and Doppler broadening of the trapped ions. Comparisons with spectra obtained with existing grating spectrometers show an order of magnitude improvement in spectral resolution.

  1. Electron Flood Charge Compensation Device for Ion Trap Secondary Ion Mass Spectrometry

    SciTech Connect

    Appelhans, Anthony David; Ward, Michael Blair; Olson, John Eric

    2002-11-01

    During secondary ion mass spectrometry (SIMS) analyses of organophosphorous compounds adsorbed onto soils, the measured anion signals were lower than expected and it was hypothesized that the low signals could be due to sample charging. An electron flood gun was designed, constructed and used to investigate sample charging of these and other sample types. The flood gun was integrated into one end cap of an ion trap secondary ion mass spectrometer and the design maintained the geometry of the self-stabilizing extraction optics used in this instrument. The SIMION ion optics program was used to design the flood gun, and experimental results agreed with the predicted performance. Results showed the low anion signals from the soils were not due to sample charging. Other insulating and conducting samples were tested using both a ReO4- and a Cs+ primary ion beam. The proximity of the sample and electron source to the ion trap aperture resulted in generation of background ions in the ion trap via electron impact (EI) ionization during the period the electron gun was flooding the sample region. When using the electron gun with the ReO4- primary beam, the required electron current was low enough that the EI background was negligible; however, the high electron flood current required with the Cs+ beam produced background EI ions that degraded the quality of the mass spectra. The consequences of the EI produced cations will have to be evaluated on a sample-by-sample basis when using electron flood. It was shown that the electron flood gun could be intentionally operated to produce EI spectra in this instrument. This offers the opportunity to measure, nearly simultaneously, species evaporating from a sample, via EI, and species bound to the surface, via SIMS.

  2. A compact time-of-flight mass spectrometer for ion source characterization

    SciTech Connect

    Chen, L. Wan, X.; Jin, D. Z.; Tan, X. H.; Huang, Z. X.; Tan, G. B.

    2015-03-15

    A compact time-of-flight mass spectrometer with overall dimension of about 413 × 250 × 414 mm based on orthogonal injection and angle reflection has been developed for ion source characterization. Configuration and principle of the time-of-flight mass spectrometer are introduced in this paper. The mass resolution is optimized to be about 1690 (FWHM), and the ion energy detection range is tested to be between about 3 and 163 eV with the help of electron impact ion source. High mass resolution and compact configuration make this spectrometer useful to provide a valuable diagnostic for ion spectra fundamental research and study the mass to charge composition of plasma with wide range of parameters.

  3. Ruthenium trisbipyridine as a candidate for gas-phase spectroscopic studies in a Fourier transform mass spectrometer

    DOE PAGES [OSTI]

    Scott, Jill R.; Ham, Jason E.; Durham, Bill; Tremblay, Paul L.

    2004-01-01

    Metal polypyridines are excellent candidates for gas-phase optical experiments where their intrinsic properties can be studied without complications due to the presence of solvent. The fluorescence lifetimes of [Ru(bpy) 3 ] 1+ trapped in an optical detection cell within a Fourier transform mass spectrometer were obtained using matrix-assisted laser desorption/ionization to generate the ions with either 2,5-dihydroxybenzoic acid (DHB) or sinapinic acid (SA) as matrix. All transients acquired, whether using DHB or SA for ion generation, were best described as approximately exponential decays. The rate constant for transients derived using DHB as matrix was 4×10 7 s −1 ,more » while the rate constant using SA was 1×10 7 s −1 . Some suggestions of multiple exponential decay were evident although limited by the quality of the signals. Photodissociation experiments revealed that [Ru(bpy) 3 ] 1+ generated using DHB can decompose to [Ru(bpy) 2 ] 1+ , whereas ions generated using SA showed no decomposition. Comparison of the mass spectra with the fluorescence lifetimes illustrates the promise of incorporating optical detection with trapped ion mass spectrometry techniques.« less

  4. Method for selective detection of explosives in mass spectrometer or ion mobility spectrometer at parts-per-quadrillion level

    SciTech Connect

    Ewing, Robert G.; Atkinson, David A.; Clowers, Brian H.

    2015-09-01

    A method for selective detection of volatile and non-volatile explosives in a mass spectrometer or ion mobility spectrometer at a parts-per-quadrillion level without preconcentration is disclosed. The method comprises the steps of ionizing a carrier gas with an ionization source to form reactant ions or reactant adduct ions comprising nitrate ions (NO.sub.3.sup.-); selectively reacting the reactant ions or reactant adduct ions with at least one volatile or non-volatile explosive analyte at a carrier gas pressure of at least about 100 Ton in a reaction region disposed between the ionization source and an ion detector, the reaction region having a length which provides a residence time (tr) for reactant ions therein of at least about 0.10 seconds, wherein the selective reaction yields product ions comprising reactant ions or reactant adduct ions that are selectively bound to the at least one explosive analyte when present therein; and detecting product ions with the ion detector to determine presence or absence of the at least one explosive analyte.

  5. Gas chromatograph-mass spectrometer (GC/MS) system for quantitative analysis of reactive chemical compounds

    DOEpatents

    Grindstaff, Quirinus G.

    1992-01-01

    Described is a new gas chromatograph-mass spectrometer (GC/MS) system and method for quantitative analysis of reactive chemical compounds. All components of such a GC/MS system external to the oven of the gas chromatograph are programmably temperature controlled to operate at a volatilization temperature specific to the compound(s) sought to be separated and measured.

  6. Laser desorption time-of-flight mass spectrometer DNA analyzer. Final report

    SciTech Connect

    Chen, C.H.W.; Martin, S.A.

    1997-02-01

    The objective of this project is the development of a laser desorption time-of-flight mass spectrometer DNA analyzer which can be broadly used for biomedical research. Tasks include: pulsed ion extraction to improve resolution; two-component matrices to enhance ionization; and solid phase DNA purification.

  7. An ion mobility mass spectrometer for investigating photoisomerization and photodissociation of molecular ions

    SciTech Connect

    Adamson, B. D.; Coughlan, N. J. A.; Markworth, P. B.; Bieske, E. J.; Continetti, R. E.

    2014-12-15

    An ion mobility mass spectrometry apparatus for investigating the photoisomerization and photodissociation of electrosprayed molecular ions in the gas phase is described. The device consists of a drift tube mobility spectrometer, with access for a laser beam that intercepts the drifting ion packet either coaxially or transversely, followed by a quadrupole mass filter. An ion gate halfway along the drift region allows the instrument to be used as a tandem ion mobility spectrometer, enabling mobility selection of ions prior to irradiation, with the photoisomer ions being separated over the second half of the drift tube. The utility of the device is illustrated with photoisomerization and photodissociation action spectra of carbocyanine molecular cations. The mobility resolution of the device for singly charged ions is typically 80 and it has a mass range of 100-440 Da, with the lower limit determined by the drive frequency for the ion funnels, and the upper limit by the quadrupole mass filter.

  8. Note: A novel dual-channel time-of-flight mass spectrometer for photoelectron imaging spectroscopy

    SciTech Connect

    Qin Zhengbo; Wu Xia; Tang Zichao [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)

    2013-06-15

    A novel dual-channel time-of-flight mass spectrometer (D-TOFMS) has been designed to select anions in the photoelectron imaging measurements. In this instrument, the radiation laser can be triggered precisely to overlap with the selected ion cloud at the first-order space focusing plane. Compared with that of the conventional single channel TOFMS, the in situ mass selection performance of D-TOFMS is significantly improved. Preliminary experiment results are presented for the mass-selected photodetachment spectrum of F{sup -} to demonstrate the capability of the instrument.

  9. The Multiplexed Chemical Kinetic Photoionization Mass Spectrometer: A New Approach To Isomer-resolved Chemical Kinetics

    SciTech Connect

    Osborne, David L.; Zou, Peng; Johnsen, Howard; Hayden, Carl C.; Taatjes, Craig A.; Knyazev, Vadim D.; North, Simon W.; Peterka, Darcy S.; Ahmed, Musahid; Leone, Stephen R.

    2008-08-28

    We have developed a multiplexed time- and photon-energy?resolved photoionizationmass spectrometer for the study of the kinetics and isomeric product branching of gasphase, neutral chemical reactions. The instrument utilizes a side-sampled flow tubereactor, continuously tunable synchrotron radiation for photoionization, a multi-massdouble-focusing mass spectrometer with 100percent duty cycle, and a time- and positionsensitive detector for single ion counting. This approach enables multiplexed, universal detection of molecules with high sensitivity and selectivity. In addition to measurement of rate coefficients as a function of temperature and pressure, different structural isomers can be distinguished based on their photoionization efficiency curves, providing a more detailed probe of reaction mechanisms. The multiplexed 3-dimensional data structure (intensity as a function of molecular mass, reaction time, and photoionization energy) provides insights that might not be available in serial acquisition, as well as additional constraints on data interpretation.

  10. Portable gas chromatograph mass spectrometer for on-site chemical analyses

    DOEpatents

    Haas, Jeffrey S.; Bushman, John F.; Howard, Douglas E.; Wong, James L.; Eckels, Joel D.

    2002-01-01

    A portable, lightweight (approximately 25 kg) gas chromatograph mass spectrometer, including the entire vacuum system, can perform qualitative and quantitative analyses of all sample types in the field. The GC/MS has a conveniently configured layout of components for ease of serviceability and maintenance. The GC/MS system can be transported under operating or near-operating conditions (i.e., under vacuum and at elevated temperature) to reduce the downtime before samples can be analyzed on-site.

  11. DOE SC ARM TR 160 Proton Transfer Time of Flight Mass Spectrometer

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    0 Proton Transfer Time-of-Flight Mass Spectrometer Instrument Handbook TB Watson March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not

  12. Elimination of ``memory`` from sample handling and inlet system of a mass spectrometer

    DOEpatents

    Chastgner, P.

    1991-05-08

    This paper describes a method for preparing the sample handling and inlet system of a mass spectrometer for analysis of a subsequent sample following analysis of a previous sample comprising the flushing of the system interior with supercritical CO{sub 2} and venting the interior. The method eliminates the effect of system ``memory`` on the subsequent analysis, especially following persistent samples such as xenon and krypton.

  13. High-precision Penning trap mass measurements for tests of the Standard Model

    SciTech Connect

    Blaum, Klaus; Eliseev, Sergey; Nagy, Szilard

    2010-08-04

    With the nowadays achievable accuracy in Penning trap mass spectrometry on short-lived exotic nuclides as well as stable atoms, precision fundamental tests can be performed, among them a test of the Standard Model, in particular with regard to the weak interaction, the CPT symmetry conservation, and the unitarity of the Cabibbo-Kobayashi-Maskawa quark mixing matrix. In addition, accurate mass values of specific nuclides are important for neutrino physics. The presently best tests of the Standard Model with high-precision Penning trap mass spectrometry will be reviewed.

  14. Off-resonance energy absorption in a linear Paul trap due to mass selective resonant quenching

    SciTech Connect

    Sivarajah, I.; Goodman, D. S.; Wells, J. E.; Smith, W. W.; Narducci, F. A.

    2013-11-15

    Linear Paul traps (LPT) are used in many experimental studies such as mass spectrometry, atom-ion collisions, and ion-molecule reactions. Mass selective resonant quenching (MSRQ) is implemented in LPT either to identify a charged particle's mass or to remove unwanted ions from a controlled experimental environment. In the latter case, MSRQ can introduce undesired heating to co-trapped ions of different mass, whose secular motion is off resonance with the quenching ac field, which we call off-resonance energy absorption (OREA). We present simulations and experimental evidence that show that the OREA increases exponentially with the number of ions loaded into the trap and with the amplitude of the off-resonance external ac field.

  15. Solid Phase Microextraction and Miniature Time-of-Flight Mass Spectrometer

    SciTech Connect

    Hiller, j.m.

    1999-01-26

    A miniature mass spectrometer, based on the time-of-flight principle, has been developed for the detection of chemical warfare agent precursor molecules. The instrument, with minor modifications, could fulfill many of the needs for sensing organic molecules in various Defense Programs, including Enhanced Surveillance. The basic footprint of the instrument is about that of a lunch box. The instrument has a mass range to about 300, has parts-per-trillion detection limits, and can return spectra in less than a second. The instrument can also detect permanent gases and is especially sensitive to hydrogen. In volume, the device could be manufactured for under $5000.

  16. Method for studying a sample of material using a heavy ion induced mass spectrometer source

    DOEpatents

    Fries, D.P.; Browning, J.F.

    1999-02-16

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu. 3 figs.

  17. Method for studying a sample of material using a heavy ion induced mass spectrometer source

    DOEpatents

    Fries, David P.; Browning, James F.

    1999-01-01

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  18. System for studying a sample of material using a heavy ion induced mass spectrometer source

    DOEpatents

    Fries, D.P.; Browning, J.F.

    1998-07-21

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high (n,f) reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu. 3 figs.

  19. System for studying a sample of material using a heavy ion induced mass spectrometer source

    DOEpatents

    Fries, David P.; Browning, James F.

    1998-01-01

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  20. A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames

    SciTech Connect

    Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

    2000-12-15

    The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

  1. Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer

    DOEpatents

    Grossman, M.W.; Evans, R.

    1991-11-26

    A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the [sup 196]Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of [+-]0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour. 8 figures.

  2. Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer

    DOEpatents

    Grossman, Mark W.; Evans, Roger

    1991-01-01

    A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the .sup.196 Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of .+-.0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour.

  3. Feasibility of a Fieldable Mass Spectrometer FY 2015 Year-end Report

    SciTech Connect

    Barinaga, Charles J.; Hager, George J.; Hoegg, Edward D.; Carman, April J.; Hart, Garret L.

    2015-10-30

    Currently, the International Atomic Energy Agency (IAEA) monitors the production of enriched uranium hexafluoride (UF6) at declared facilities by collecting a few grams of product in sample tubes that are then sent to central laboratories for processing and isotope ratio analysis by thermal ionization mass spectrometry. Analysis of results may not be available for some time after collection. In addition, new shipping regulations will make it more difficult to transport this amount of UF6 to a laboratory. The IAEA is interested in an isotope ratio technique for uranium in UF6 that can be moved to and operated at the enrichment facility itself. This report covers the tasks and activities of the Feasibility of a Fieldable Mass Spectrometer Project for FY 2015, which investigates the feasibility of an in-field isotope ratio technique— the forward deployment of a technique to the non-laboratory situation of a protected room with power and heat at the facility of interest.

  4. Mass spectrometer with electron source for reducing space charge effects in sample beam

    DOEpatents

    Houk, Robert S.; Praphairaksit, Narong

    2003-10-14

    A mass spectrometer includes an ion source which generates a beam including positive ions, a sampling interface which extracts a portion of the beam from the ion source to form a sample beam that travels along a path and has an excess of positive ions over at least part of the path, thereby causing space charge effects to occur in the sample beam due to the excess of positive ions in the sample beam, an electron source which adds electrons to the sample beam to reduce space charge repulsion between the positive ions in the sample beam, thereby reducing the space charge effects in the sample beam and producing a sample beam having reduced space charge effects, and a mass analyzer which analyzes the sample beam having reduced space charge effects.

  5. Development of a New Ion Mobility Time-of-Flight Mass Spectrometer

    SciTech Connect

    Ibrahim, Yehia M.; Baker, Erin Shammel; Danielson, William F.; Norheim, Randolph V.; Prior, David C.; Anderson, Gordon A.; Belov, Mikhail E.; Smith, Richard D.

    2015-02-01

    A new ion mobility spectrometer (IMS) platform was developed to improve upon the sensitivity and reproducibility of our previous platforms, and further enhance IMS-MS utility for broad pan-omics measurements. The new platform incorporated an improved electrospray ionization source and interface for enhanced sensitivity, and providing the basis for further benefits based upon implementation of multiplexed IMS. The ion optics included electrodynamic ion funnels at both the entrance and exit of the IMS, an ion funnel trap for ion injection, and a design in which nearly all ion optics (e.g. drift rings, ion funnels) were fabricated using printed circuit board technology. The IMS resolving power achieved was ~73 for singly-charged ions, very close to the predicted diffusion-limited resolving power (~75). The platforms performance evaluation (e.g. for proteomics measurements) include LC-IMS-TOF MS datasets for 30 technical replicates for a trypsin digested human serum, and included platform performance in each dimension (LC, IMS and MS) separately.

  6. Method for calibrating a Fourier transform ion cyclotron resonance mass spectrometer

    DOEpatents

    Smith, Richard D.; Masselon, Christophe D.; Tolmachev, Aleksey

    2003-08-19

    A method for improving the calibration of a Fourier transform ion cyclotron resonance mass spectrometer wherein the frequency spectrum of a sample has been measured and the frequency (f) and intensity (I) of at least three species having known mass to charge (m/z) ratios and one specie having an unknown (m/z) ratio have been identified. The method uses the known (m/z) ratios, frequencies, and intensities at least three species to calculate coefficients A, B, and C, wherein the mass to charge ratio of a least one of the three species (m/z).sub.i is equal to ##EQU1## wherein f.sub.i is the detected frequency of the specie, G(I.sub.i) is a predetermined function of the intensity of the species, and Q is a predetermined exponent. Using the calculated values for A, B, and C, the mass to charge ratio of the unknown specie (m/z).sub.ii is calculated as the sum of ##EQU2## wherein f.sub.ii is the measured frequency of the unknown specie, and (I.sub.ii) is the measured intensity of the unknown specie.

  7. Invited Article: Characterization of background sources in space-based time-of-flight mass spectrometers

    SciTech Connect

    Gilbert, J. A.; Gershman, D. J.; Gloeckler, G.; Lundgren, R. A.; Zurbuchen, T. H.; Orlando, T. M.; McLain, J.; Steiger, R. von

    2014-09-15

    For instruments that use time-of-flight techniques to measure space plasma, there are common sources of background signals that evidence themselves in the data. The background from these sources may increase the complexity of data analysis and reduce the signal-to-noise response of the instrument, thereby diminishing the science value or usefulness of the data. This paper reviews several sources of background commonly found in time-of-flight mass spectrometers and illustrates their effect in actual data using examples from ACE-SWICS and MESSENGER-FIPS. Sources include penetrating particles and radiation, UV photons, energy straggling and angular scattering, electron stimulated desorption of ions, ion-induced electron emission, accidental coincidence events, and noise signatures from instrument electronics. Data signatures of these sources are shown, as well as mitigation strategies and design considerations for future instruments.

  8. Ion Trap Array-Based Systems And Methods For Chemical Analysis

    DOEpatents

    Whitten, William B [Oak Ridge, TN; Ramsey, J Michael [Knoxville, TN

    2005-08-23

    An ion trap-based system for chemical analysis includes an ion trap array. The ion trap array includes a plurality of ion traps arranged in a 2-dimensional array for initially confining ions. Each of the ion traps comprise a central electrode having an aperture, a first and second insulator each having an aperture sandwiching the central electrode, and first and second end cap electrodes each having an aperture sandwiching the first and second insulator. A structure for simultaneously directing a plurality of different species of ions out from the ion traps is provided. A spectrometer including a detector receives and identifies the ions. The trap array can be used with spectrometers including time-of-flight mass spectrometers and ion mobility spectrometers.

  9. Detection of Chemical/Biological Agents and Stimulants using Quadrupole Ion Trap Mass Spectrometry

    SciTech Connect

    Harmon, S.H.; Hart, K.J.; Vass, A.A.; Wise, M.B.; Wolf, D.A.

    1999-06-14

    Detection of Chemical/Biological Agents and Simulants A new detector for chemical and biological agents is being developed for the U. S. Army under the Chemical and Biological Mass Spectrometer Block II program. The CBMS Block II is designed to optimize detection of both chemical and biological agents through the use of direct sampling inlets [I], a multi- ported sampling valve and a turbo- based vacuum system to support chemical ionization. Unit mass resolution using air as the buffer gas [2] has been obtained using this design. Software to control the instrument and to analyze the data generated from the instrument has also been newly developed. Detection of chemical agents can be accomplished. using the CBMS Block II design via one of two inlets - a l/ I 6'' stainless steel sample line -Chemical Warfare Air (CW Air) or a ground probe with enclosed capillary currently in use by the US Army - CW Ground. The Block II design is capable of both electron ionization and chemical ionization. Ethanol is being used as the Cl reagent based on a study indicating best performance for the Biological Warfare (BW) detection task (31). Data showing good signal to noise for 500 pg of methyl salicylate injected into the CW Air inlet, 50 ng of dimethylmethylphosphonate exposed to the CW Ground probe and 5 ng of methyl stearate analyzed using the pyrolyzer inlet were presented. Biological agents are sampled using a ''bio-concentrator'' unit that is designed to concentrate particles in the low micron range. Particles are collected in the bottom of a quartz pyrolyzer tube. An automated injector is being developed to deliver approximately 2 pL of a methylating reagent, tetramethylamonium- hydroxide to 'the collected particles. Pyrolysis occurs by rapid heating to ca. 55OOC. Biological agents are then characterized by their fatty acid methyl ester profiles and by other biomarkers. A library of ETOH- Cl/ pyrolysis MS data of microorganisms used for a recently published study [3] has been

  10. Improved ion optics for introduction of ions into a 9.4-T Fourier transform ion cyclotron resonance mass spectrometer

    DOE PAGES [OSTI]

    Chen, Yu; Leach, Franklin E.; Kaiser, Nathan K.; Dang, Xibei; Ibrahim, Yehia M.; Norheim, Randolph V.; Anderson, Gordon A.; Smith, Richard D.; Marshall, Alan G.

    2015-01-19

    Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry provides unparalleled mass accuracy and resolving power.[1],[2] With electrospray ionization (ESI), ions are typically transferred into the mass spectrometer through a skimmer, which serves as a conductance-limiting orifice. However, the skimmer allows only a small fraction of incoming ions to enter the mass spectrometer. An ion funnel, originally developed by Smith and coworkers at Pacific Northwest National Laboratory (PNNL)[3-5] provides much more efficient ion focusing and transfer. The large entrance aperture of the ion funnel allows almost all ions emanating from a heated capillary to be efficiently captured and transferred, resulting inmore » nearly lossless transmission.« less

  11. A Novel Phase-Coherent Programmable Clock for High-Precision Arbitrary Waveform Generation Applied to Digital Ion Trap Mass Spectrometry

    SciTech Connect

    Koizumi, Hideya; Jatko, William Bruce; Andrews Jr, William H; Whitten, William B; Reilly, Pete

    2010-01-01

    Digital ion trap (DIT) mass spectrometry requires the ability to precisely and accurately produce waveforms. The quality of the mass spectra produced in terms of resolution and mass accuracy depend on the resolution and precision of the applied waveforms. This publication reveals a novel method for the production of arbitrary waveforms in general and then applies the method to the production of DIT waveforms. Arbitrary waveforms can be created by varying the clock frequency input to a programmable read only memory that is then input to a digital-to-analog converter (DAC). The arbitrary waveform is composed of a defined number of points that are triggered to be written after programmed numbers of clock cycles to define the arbitrary waveform. The novelty introduced here is that the direct digital synthesis (DDS) generated clock frequency can be precisely changed as the arbitrary waveform is written because we have developed a method to rapidly switch the DDS frequency exactly at the end of the output clock cycle allowing exact timing of multiple transitions to produce precise and temporally complex waveforms. Changing the frequency only at the end of the output clock cycle is a phase coherent process that permits precise timing between each point in the arbitrary waveform. The waveform generation technique was demonstrated by creating a prototype that was used to operate a digital ion trap mass spectrometer. The jitter in the phase-coherent DDS TTL output that was used as the frequency variable clock was 20 ps. This jitter represents the realizable limit of precision for waveform generation. The rectangular waveforms used to operate the mass spectrometer were created with counters that increased the jitter to 100 ps. The mass resolution achieved was 5000 at m/z = 414. This resolution corresponds to a jitter of 275 ps assuming DC fluctuations and overshoots in the waveform are insignificant. Resolution should improve with increasing mass because the waveforms have

  12. Toward a Fieldable Atomic Mass Spectrometer for Safeguards Applications: Sample Preparation and Ionization

    SciTech Connect

    Barinaga, Charles J.; Hager, George J.; Hart, Garret L.; Koppenaal, David W.; Marcus, R. Kenneth; Jones, Sarah MH; Manard, Benjamin T.

    2014-10-31

    The International Atomic Energy Agency’s (IAEA’s) long-term research and development plan calls for the development of new methods to detect misuse at nuclear fuel cycle facilities such as reprocessing and enrichment plants. At enrichment plants, for example, the IAEA’s contemporary safeguards approaches are based on a combination of routine and random inspections that include collection of UF6 samples from in-process material and selected cylinders for subsequent analyses. These analyses include destructive analysis (DA) in a laboratory (typically by mass spectrometry [MS]) for isotopic characterization, and environmental sampling (ES) for subsequent laboratory elemental and isotopic analysis (also both typically by MS). One area of new method development includes moving this kind of isotope ratio analytical capability for DA and ES activities into the field. Some of the reasons for these developments include timeliness of results, avoidance of hazardous material shipments, and guidance for additional sample collecting. However, this capability does not already exist for several reasons, such as that most lab-based chemical and instrumental methods rely on laboratory infrastructure (highly trained staff, power, space, hazardous material handling, etc.) and require significant amounts of consumables (power, compressed gases, etc.). In addition, there are no currently available, fieldable instruments for atomic or isotope ratio analysis. To address these issues, Pacific Northwest National Laboratory (PNNL) and collaborator, Clemson University, are studying key areas that limit the fieldability of isotope ratio mass spectrometry for atomic ions: sample preparation and ionization, and reducing the physical size of a fieldable mass spectrometer. PNNL is seeking simple and robust techniques that could be effectively used by inspectors who may have no expertise in analytical MS. In this report, we present and describe the preliminary findings for three candidate

  13. Development of Soft Ionization for Particulate Organic Detection with the Aerodyne Aerosol Mass Spectrometer

    SciTech Connect

    Trimborn, A; Williams, L R; Jayne, J T; Worsnop, D R

    2008-06-19

    During this DOE SBIR Phase II project, we have successfully developed several soft ionization techniques, i.e., ionization schemes which involve less fragmentation of the ions, for use with the Aerodyne time-of-flight aerosol mass spectrometer (ToF-AMS). Vacuum ultraviolet single photon ionization was demonstrated in the laboratory and deployed in field campaigns. Vacuum ultraviolet single photon ionization allows better identification of organic species in aerosol particles as shown in laboratory experiments on single component particles, and in field measurements on complex multi-component particles. Dissociative electron attachment with lower energy electrons (less than 30 eV) was demonstrated in the measurement of particulate organics in chamber experiments in Switzerland, and is now a routine approach with AMS systems configured for bipolar, negative ion detection. This technique is particularly powerful for detection of acidic and other highly oxygenated secondary organic aerosol (SOA) chemical functionality. Low energy electron ionization (10 to 12 eV) is also a softer ionization approach routinely available to AMS users. Finally, Lithium ion attachment has been shown to be sensitive to more alkyl-like chemical functionality in SOA. Results from Mexico City are particularly exciting in observing changes in SOA molecular composition under different photochemical/meteorological conditions. More recent results detecting biomass burns at the Montana fire lab have demonstrated quantitative and selective detection of levoglucosan. These soft ionization techniques provide the ToF-AMS with better capability for identifying organic species in ambient atmospheric aerosol particles. This, in turn, will allow more detailed study of the sources, transformations and fate of organic-containing aerosol.

  14. First Use of High Charge States for Mass Measurements of Short-Lived Nuclides in a Penning Trap

    SciTech Connect

    Ettenauer, S.; Gallant, A. T.; Dilling, J.; Simon, M. C.; Chaudhuri, A.; Mane, E.; Delheij, P.; Pearson, M. R.; Brunner, T.; Chowdhury, U.; Simon, V. V.; Brodeur, M.; Andreoiu, C.; Audi, G.; Lopez-Urrutia, J. R. Crespo; Ullrich, J.; Gwinner, G.; Lapierre, A.; Lunney, D.; Ringle, R.

    2011-12-30

    Penning trap mass measurements of short-lived nuclides have been performed for the first time with highly charged ions, using the TITAN facility at TRIUMF. Compared to singly charged ions, this provides an improvement in experimental precision that scales with the charge state q. Neutron-deficient Rb isotopes have been charge bred in an electron beam ion trap to q=8-12+ prior to injection into the Penning trap. In combination with the Ramsey excitation scheme, this unique setup creating low energy, highly charged ions at a radioactive beam facility opens the door to unrivaled precision with gains of 1-2 orders of magnitude. The method is particularly suited for short-lived nuclides such as the superallowed {beta} emitter {sup 74}Rb (T{sub 1/2}=65 ms). The determination of its atomic mass and an improved Q{sub EC} value are presented.

  15. Simulation of lean NOx trap performance with microkinetic chemistry and without mass transfer.

    SciTech Connect

    Larson, Rich; Daw, C. Stuart; Pihl, Josh A.; Chakravarthy, V. Kalyana

    2011-08-01

    A microkinetic chemical reaction mechanism capable of describing both the storage and regeneration processes in a fully formulated lean NO{sub x} trap (LNT) is presented. The mechanism includes steps occurring on the precious metal, barium oxide (NO{sub x} storage), and cerium oxide (oxygen storage) sites of the catalyst. The complete reaction set is used in conjunction with a transient plug flow reactor code to simulate not only conventional storage/regeneration cycles with a CO/H{sub 2} reductant, but also steady flow temperature sweep experiments that were previously analyzed with just a precious metal mechanism and a steady state code. The results show that NO{sub x} storage is not negligible during some of the temperature ramps, necessitating a re-evaluation of the precious metal kinetic parameters. The parameters for the entire mechanism are inferred by finding the best overall fit to the complete set of experiments. Rigorous thermodynamic consistency is enforced for parallel reaction pathways and with respect to known data for all of the gas phase species involved. It is found that, with a few minor exceptions, all of the basic experimental observations can be reproduced with these purely kinetic simulations, i.e., without including mass-transfer limitations. In addition to accounting for normal cycling behavior, the final mechanism should provide a starting point for the description of further LNT phenomena such as desulfation and the role of alternative reductants.

  16. Molecular beam mass spectrometer equipped with a catalytic wall reactor for in situ studies in high temperature catalysis research

    SciTech Connect

    Horn, R.; Ihmann, K.; Ihmann, J.; Jentoft, F.C.; Geske, M.; Taha, A.; Pelzer, K.; Schloegl, R.

    2006-05-15

    A newly developed apparatus combining a molecular beam mass spectrometer and a catalytic wall reactor is described. The setup has been developed for in situ studies of high temperature catalytic reactions (>1000 deg. C), which involve besides surface reactions also gas phase reactions in their mechanism. The goal is to identify gas phase radicals by threshold ionization. A tubular reactor, made from the catalytic material, is positioned in a vacuum chamber. Expansion of the gas through a 100 {mu}m sampling orifice in the reactor wall into differentially pumped nozzle, skimmer, and collimator chambers leads to the formation of a molecular beam. A quadrupole mass spectrometer with electron impact ion source designed for molecular beam inlet and threshold ionization measurements is used as the analyzer. The sampling time from nozzle to detector is estimated to be less than 10 ms. A detection time resolution of up to 20 ms can be reached. The temperature of the reactor is measured by pyrometry. Besides a detailed description of the setup components and the physical background of the method, this article presents measurements showing the performance of the apparatus. After deriving the shape and width of the energy spread of the ionizing electrons from measurements on N{sub 2} and He we estimated the detection limit in threshold ionization measurements using binary mixtures of CO in N{sub 2} to be in the range of several hundreds of ppm. Mass spectra and threshold ionization measurements recorded during catalytic partial oxidation of methane at 1250 deg. C on a Pt catalyst are presented. The detection of CH{sub 3}{center_dot} radicals is successfully demonstrated.

  17. Combined distance-of-flight and time-of-flight mass spectrometer

    DOEpatents

    Enke, Christie G; Ray, Steven J; Graham, Alexander W; Hieftje, Gary M; Barinaga, Charles J; Koppenaal, David W

    2014-02-11

    A combined distance-of-flight mass spectrometry (DOFMS) and time-of-flight mass spectrometry (TOFMS) instrument includes an ion source configured to produce ions having varying mass-to-charge ratios, a first detector configured to determine when each of the ions travels a predetermined distance, a second detector configured to determine how far each of the ions travels in a predetermined time, and a detector extraction region operable to direct portions of the ions either to the first detector or to the second detector.

  18. Studies of the mechanism of the cluster formation in a thermally sampling atmospheric pressure ionization mass spectrometer

    SciTech Connect

    Albrecht, Sascha Stroh, Fred; Klopotowski, Sebastian Derpmann, Valerie Klee, Sonja Brockmann, Klaus J. Benter, Thorsten

    2014-01-15

    In this study a thermally sampling atmospheric pressure ionization mass spectrometer is described and characterized. The ion transfer stage offers the capability to sample cluster ions at thermal equilibrium and during this transfer fundamental processes possibly affecting the cluster distribution are also readily identified. Additionally, the transfer stage combines optional collision-induced dissociation (CID) analysis of the cluster composition with thermal equilibrium sampling of clusters. The performance of the setup is demonstrated with regard to the proton-bound water cluster system. The benefit of the studied processes is that they can help to improve future transfer stages and to understand cluster ion reactions in ion mobility tubes and high-pressure ion sources. In addition, the instrument allows for the identification of fragmentation and protonation reactions caused by CID.

  19. Design of a Portable, Battery-Powered Quadrupole Mass Spectrometer for Real-Time Sampling of Materials

    SciTech Connect

    T. R. Dillingham, T. L. Porter, D. M. Cornelison, R. J. Venedam

    2009-04-01

    We have designed and constructed a low cost, portable, battery-powered quadrupole mass spectrometer for use in the materials analysis of gaseous, liquid or solid field samples. The system may be configured for continuous sampling of ambient gas samples, or for the analysis of small solid, liquid or gas samples in sealed glass vials. The system is capable of measuring partial pressures down to the 10<-10> Torr range, and may be operated on battery power for several hours in a field deployment. Information is presented on the specific design parameters and on the testing of the instrument. Preliminary results are reported for solid dinitrotoluene (DNT) and for chlorinated hydrocarbons and other contaminants in water.

  20. Preparation and in situ Characterization of Surfaces Using Soft-Landing in a Fourier Transform Ion Cyclotron Resonance Mass Spectrometer

    SciTech Connect

    Alvarez, Jormarie; Cooks, Robert G.; Barlow, Stephan E.; Gaspar, Dan J.; Futrell, Jean H.; Laskin, Julia

    2005-06-01

    Mass-selected peptide ions produced by electrospray ionization were deposited onto fluorinated self-assembled monolayer surfaces (FSAM) surfaces by soft-landing using a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) specially designed for studying interactions of large ions with surfaces. Analysis of the modified surface was performed in situ by combining 2 keV Cs+ secondary ion mass spectrometry with FT-ICR detection of the sputtered ions (FT-ICR-SIMS). Regardless of the initial charge state of the precursor ion, the SIMS mass spectra included singly-protonated peptide fragment ions and peaks characteristic of the surfaces in all cases. In some experiments multiply-protonated peptide ions and [M+Au]+ ions were also observed upon SIMS analysis of modified surfaces. For comparison with the in situ analysis of the modified surfaces, ex situ analysis of some of the modified surfaces was performed by 25 kV Ga+ time of flight ? secondary ion mass spectrometry (ToF-SIMS). The ex situ analysis demonstrated that a significant number of soft-landed peptide ions remain charged on the surface even when exposed to air for several hours after deposition. Charge retention of soft-landed ions dramatically increases the ion yields obtained during SIMS analysis very sensitive detection of deposited material at less than 1% of monolayer coverage. Accumulation of charged species on the surface undergoes saturation due to Coulomb repulsion between charges at close to 30% coverage. We estimated that close to 1 ng of peptide could be deposited on the spot area of 4 mm2 of the FSAM surface without reaching saturation.

  1. Mass spectrometers for studying the ionic and neutral composition of the upper layers of the atmosphere

    SciTech Connect

    Shutov, M.D.

    1984-04-01

    The investigation of the ionic and neutral composition of the upper layers of the atmosphere and outer space which is of interest for solving theoretical and applied problems of astrophysics, geophysics, space biology, and other closely-tied areas of science is discussed. The upper layers of the atmosphere are of practical significance for launching rockets and artificial satellites, for which the nature of movement depends on the structure and composition of the atmosphere. The study of the chemical composition of the ionosphere, the degree of ionization of the upper layers of the atmosphere at different latitudes and different times of day, and the dependence of ionization on the action of ultraviolet and corpuscular radiation is necessary to study the processes of the propagation of radio waves, and to explain the chemical and photochemical reaction which cause the ionosphere to exist. The most modern methods of study the composition of the mass spectral method which is a direct method and is especially valuable at great altitudes to study the composition of the upper atmosphere is considered. The mass spectrometric method is the only one to analyze the composition of ionizing gases.

  2. Real-time quadrupole mass spectrometer analysis of gas in boreholefluid samples acquired using the U-Tube sampling methodology

    SciTech Connect

    Freifeld, Barry M.; Trautz, Robert C.

    2006-01-11

    Sampling of fluids in deep boreholes is challenging becauseof the necessity to minimize external contamination and maintain sampleintegrity during recovery. The U-tube sampling methodology was developedto collect large volume, multiphase samples at in situ pressures. As apermanent or semi-permanent installation, the U-tube can be used forrapidly acquiring multiple samples or it may be installed for long-termmonitoring applications. The U-tube was first deployed in Liberty County,TX to monitor crosswell CO2 injection as part of the Frio CO2sequestration experiment. Analysis of gases (dissolved or separate phase)was performed in the field using a quadrupole mass spectrometer, whichserved as the basis for determining the arrival of the CO2 plume. Thepresence of oxygen and argon in elevated concentrations, along withreduced methane concentration, indicate sample alteration caused by theintroduction of surface fluids during borehole completion. Despiteproducing the well to eliminate non-native fluids, measurementsdemonstrate that contamination persists until the immiscible CO2injection swept formation fluid into the observationwellbore.

  3. High-efficiency cross-beam magnetic electron-impact source for improved miniature Mattauch-Herzog mass spectrometer performance

    SciTech Connect

    Hadjar, O.; Fowler, W. K.

    2012-06-15

    We describe a newly designed cross-beam magnetic electron-impact ion source (CBM-EI). We demonstrate its superiority in comparison with a conventional source (CB-EI) when used with a commercial miniature sector-field-type, non-scanning mass spectrometer featuring Mattauch-Herzog geometry (MH-MS) and a permanent sector-field magnet. This paper clearly shows the value of the CBM-EI for enhancing MH-MS sensitivity. Unlike secondary electron-multiplier type detectors, the pixelated detector (IonCCD Trade-Mark-Sign ) used in the commercial MH-MS has no gain. The MH-MS/IonCCD system is therefore challenged to compete with time-of-flight and quadrupole MS systems due to their higher ion transmissions and detector gains. Using the new CBM-EI, we demonstrate an instrument sensitivity increase of 20-fold to 100-fold relative to the CB-EI-equipped instrument. This remarkable signal increase by the simple addition of the magnet assembly arises from the magnet-induced gyromotion of the thermionic electrons, which vastly increases the effective path length of the electrons through the ionization region, and the collimated nature of the electron flux, which optimizes the ion transmission through the 100-{mu}m object slit of the MH-MS. Some or all of the realized sensitivity increase may be exchanged for an increase in resolution and/or mass range through the use of a narrower object slit, or for a reduction in ion-source pressure to limit quenching. The CBM-EI should facilitate development of a differentially pumped ion source to extend the lifetime of the filament, especially in otherwise intractable applications associated with oxidizing and corrosive samples.

  4. In-Situ Characterization of Cloud Condensation Nuclei, Interstitial, and background Particles using Single Particle Mass Spectrometer, SPLAT II

    SciTech Connect

    Zelenyuk, Alla; Imre, D.; Earle, Michael; Easter, Richard C.; Korolev, Alexei; Leaitch, W. R.; Liu, Peter; Macdonald, A. M.; Ovchinnikov, Mikhail; Strapp, Walter

    2010-10-01

    Aerosol indirect effect remains the most uncertain aspect of climate change modeling because proper test requires knowledge of individual particles sizes and compositions with high spatial and temporal resolution. We present the first deployment of a single particle mass spectrometer (SPLAT II) that is operated in a dual data acquisition mode to measure all the required individual particle properties with sufficient temporal resolution to definitively resolve the aerosol-cloud interaction in this exemplary case. We measured particle number concentrations, asphericity, and individual particle size, composition, and density with better than 60 seconds resolution. SPLAT II measured particle number concentrations between 70 particles cm-3and 300 particles cm-3, an average particle density of 1.4 g cm-3. Found that most particles are composed of oxygenated organics, many of which are mixed with sulfates. Biomass burn particles some with sulfates were prevalent, particularly at higher altitudes, and processed sea-salt was observed over the ocean. Analysis of cloud residuals shows that with time cloud droplets acquire sulfate by the reaction of peroxide with SO2. Based on the particle mass spectra and densities we find that the compositions of cloud condensation nuclei are similar to those of background aerosol but, contain on average ~7% more sulfate, and do not include dust and metallic particles. A comparison between the size distributions of background, activated, and interstitial particles shows that while nearly none of the activated particles is smaller than 115 nm, more than 80% of interstitial particles are smaller than 115 nm. We conclude that for this cloud the most important difference between CCN and background aerosol is particle size although having more sulfate also helps.

  5. Apparatus and methods for continuous beam fourier transform mass spectrometry

    DOEpatents

    McLuckey, Scott A.; Goeringer, Douglas E.

    2002-01-01

    A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.

  6. Portable mass spectrometer with one or more mechanically adjustable electrostatic sectors and a mechanically adjustable magnetic sector all mounted in a vacuum chamber

    DOEpatents

    Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Martin, W.H.; Myers, D.W.; Keville, R.F.

    1992-10-06

    A portable mass spectrometer is described having one or more electrostatic focusing sectors and a magnetic focusing sector, all of which are positioned inside a vacuum chamber, and all of which may be adjusted via adjustment means accessible from outside the vacuum chamber. Mounting of the magnetic sector entirely within the vacuum chamber permits smaller magnets to be used, thus permitting reductions in both weight and bulk. 13 figs.

  7. Portable mass spectrometer with one or more mechanically adjustable electrostatic sectors and a mechanically adjustable magnetic sector all mounted in a vacuum chamber

    DOEpatents

    Andresen, Brian D.; Eckels, Joel D.; Kimmons, James F.; Martin, Walter H.; Myers, David W.; Keville, Robert F.

    1992-01-01

    A portable mass spectrometer is described having one or more electrostatic focusing sectors and a magnetic focusing sector, all of which are positioned inside a vacuum chamber, and all of which may be adjusted via adjustment means accessible from outside the vacuum chamber. Mounting of the magnetic sector entirely within the vacuum chamber permits smaller magnets to be used, thus permitting reductions in both weight and bulk.

  8. Collection efficiency of the soot-particle aerosol mass spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE PAGES [OSTI]

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-12-18

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of 2. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  9. Collection efficiency of the Soot-Particle Aerosol Mass Spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE PAGES [OSTI]

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-05-26

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of two. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  10. Monolithic spectrometer

    DOEpatents

    Rajic, S.; Egert, C.M.; Kahl, W.K.; Snyder, W.B. Jr.; Evans, B.M. III; Marlar, T.A.; Cunningham, J.P.

    1998-05-19

    A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays. 6 figs.

  11. Monolithic spectrometer

    DOEpatents

    Rajic, Slobodan; Egert, Charles M.; Kahl, William K.; Snyder, Jr., William B.; Evans, III, Boyd M.; Marlar, Troy A.; Cunningham, Joseph P.

    1998-01-01

    A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays.

  12. A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode

    SciTech Connect

    Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A.

    2013-07-15

    Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions.

  13. Use of the ECL-CAMAC trigger processor system for recoil missing mass triggers at the Tagged Photon Spectrometer at Fermilab

    SciTech Connect

    Martin, J.; Bracker, S.; Hartner, G.; Appel, J.; Nash, T.

    1981-05-01

    A trigger processor in operation since May 1980 at the Tagged Photon Spectrometer at Fermilab will be described. The processor, based on the Fermilab ECL-CAMAC system, allows fast selection of high mass diffractive events from the total hadronic cross section. Data from a recoil detector, consisting of 3 wire chambers and 4 layers of scintillator concentric about a 1.5 m liquid hydrogen target, is digitized and presented to the processor within 3 sec. From the chamber data are found the vertices and angles of all recoiling tracks.

  14. Development of Tandem, Double-Focusing, Electron Impact, Gas Source Mass Spectrometer for Measurement of Rare Double-Substituted Isotoplogues in Geochemistry

    SciTech Connect

    Young, Edward D.

    2015-07-30

    This project culminated in construction and delivery of the world’s first large-radius gas-source isotope ratio mass spectrometer that permits unparalleled analyses of the stable isotopic composition of methane gas. The instrument, referred to as the “Panorama” and installed at UCLA in March 2015, can now be used to determine the relative abundances of rare isotopic species of methane that serve as tracers of temperature of formation and/or subsequent processing of gas. With this technology we can begin to delineate different sources and sinks of methane isotopically in ways not possible until now.

  15. Cyclotron Institute » MDM Spectrometer

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    MDM Spectrometer MDM Spectrometer Oxford Detector The MDM Spectrometer is a high-resolution, broad range spectrometer. The layout of the magnetic elements is in the order: entrance sextupole and multipole, gradient-field dipole, and exit multipole. The device has a "normal" focal plane, and the 1.6 m radius dipole magnet has a maximum mass-energy product of 315 MeV amu. At the maximum solid angle of 8 msr, the ratio of energies that can be accepted by the spectrometer (Emax/Emin) is

  16. Correlation spectrometer

    DOEpatents

    Sinclair, Michael B. (Albuquerque, NM); Pfeifer, Kent B. (Los Lunas, NM); Flemming, Jeb H. (Albuquerque, NM); Jones, Gary D. (Tijeras, NM); Tigges, Chris P. (Albuquerque, NM)

    2010-04-13

    A correlation spectrometer can detect a large number of gaseous compounds, or chemical species, with a species-specific mask wheel. In this mode, the spectrometer is optimized for the direct measurement of individual target compounds. Additionally, the spectrometer can measure the transmission spectrum from a given sample of gas. In this mode, infrared light is passed through a gas sample and the infrared transmission signature of the gasses present is recorded and measured using Hadamard encoding techniques. The spectrometer can detect the transmission or emission spectra in any system where multiple species are present in a generally known volume.

  17. Multidimensional spectrometer

    DOEpatents

    Zanni, Martin Thomas; Damrauer, Niels H.

    2010-07-20

    A multidimensional spectrometer for the infrared, visible, and ultraviolet regions of the electromagnetic spectrum, and a method for making multidimensional spectroscopic measurements in the infrared, visible, and ultraviolet regions of the electromagnetic spectrum. The multidimensional spectrometer facilitates measurements of inter- and intra-molecular interactions.

  18. Market Research Survey of Commercial Off-the-Shelf Mass Spectrometers for In-Field Analysis. FY 15 Update

    SciTech Connect

    Yoshida, Thomas M.; Leibman, Christopher Patrick; Stark, Peter C.

    2015-11-12

    This report is an update of the 2013 Market Research Survey1-3 of field-deployable commercial off-the-shelf (COTS) mass spectrometry instruments for safeguards application.

  19. Airborne Single Particle Mass Spectrometers (SPLAT II & miniSPLAT) and New Software for Data Visualization and Analysis in a Geo-Spatial Context

    SciTech Connect

    Zelenyuk, Alla; Imre, D.; Wilson, Jacqueline M.; Zhang, Zhiyuan; Wang, Jun; Mueller, Klaus

    2015-02-01

    Understanding the effect of aerosols on climate requires knowledge of the size and chemical composition of individual aerosol particles - two fundamental properties that determine an aerosol’s optical properties and ability to serve as cloud condensation or ice nuclei. Here we present miniSPLAT, our new aircraft compatible single particle mass spectrometer, that measures in-situ and in real-time size and chemical composition of individual aerosol particles with extremely high sensitivity, temporal resolution, and sizing precision on the order of a monolayer. miniSPLAT operates in dual data acquisition mode to measure, in addition to single particle size and composition, particle number concentrations, size distributions, density, and asphericity with high temporal resolution. When compared to our previous instrument, SPLAT II, miniSPLAT has been significantly reduced in size, weight, and power consumption without loss in performance. We also present ND-Scope, our newly developed interactive visual analytics software package. ND-Scope is designed to explore and visualize the vast amount of complex, multidimensional data acquired by our single particle mass spectrometers, along with other aerosol and cloud characterization instruments on-board aircraft. We demonstrate that ND-Scope makes it possible to visualize the relationships between different observables and to view the data in a geo-spatial context, using the interactive and fully coupled Google Earth and Parallel Coordinates displays. Here we illustrate the utility of ND-Scope to visualize the spatial distribution of atmospheric particles of different compositions, and explore the relationship between individual particle composition and their activity as cloud condensation nuclei.

  20. SCINTILLATION SPECTROMETER

    DOEpatents

    Bell, P.R.; Francis, J.E.

    1960-06-21

    A portable scintillation spectrometer is described which is especially useful in radio-biological studies for determining the uptake and distribution of gamma -emitting substances in tissue. The spectrometer includes a collimator having a plurality of apertures that are hexagonal in cross section. Two crystals are provided: one is activated to respond to incident rays from the collimator; the other is not activated and shields the first from external radiation.

  1. Microfabricated ion trap array

    DOEpatents

    Blain, Matthew G.; Fleming, James G.

    2006-12-26

    A microfabricated ion trap array, comprising a plurality of ion traps having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale ion traps to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The reduced electrode voltage enables integration of the microfabricated ion trap array with on-chip circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of the microfabricated ion trap array can be realized in truly field portable, handheld microanalysis systems.

  2. Mass measurements of rare isotopes with SHIPTRAP

    SciTech Connect

    Dworschak, M.

    2010-06-01

    The Penning-trap mass spectrometer SHIPTRAP was set up with the aim to perform high-precision mass measurements. Since autumn 2005, the masses of 63 neutron-deficient nuclides in the mass range from A = 80 to A = 254 have been determined with relative uncertainties of down to 10{sup -8}. Nuclides with half-lives down to 580 ms and production rates of less than one atom per minute were investigated. The results are valuable for nuclear structure investigations and nuclear astrophysics. The most remarkable successes were the first direct mass measurements beyond the proton drip line and in the region above Z = 100.

  3. Spectrometer gun

    DOEpatents

    Waechter, D.A.; Wolf, M.A.; Umbarger, C.J.

    1981-11-03

    A hand-holdable, battery-operated, microprocessor-based spectrometer gun is described that includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

  4. Spectrometer gun

    DOEpatents

    Waechter, David A.; Wolf, Michael A.; Umbarger, C. John

    1985-01-01

    A hand-holdable, battery-operated, microprocessor-based spectrometer gun includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

  5. Analysis of passivated A-286 stainless steel surfaces for mass spectrometer inlet systems by Auger electron and X-ray photoelectron spectroscopy and scanning electron microscopy

    SciTech Connect

    Ajo, Henry; Blankenship, Donnie; Clark, Elliot

    2014-07-25

    In this study, various commercially available surface treatments are being explored for use on stainless steel components in mass spectrometer inlet systems. Type A-286 stainless steel coupons, approximately 12.5 mm in diameter and 3 mm thick, were passivated with one of five different surface treatments; an untreated coupon served as a control. The surface and near-surface microstructure and chemistry of the coupons were investigated using sputter depth profiling using Auger electron spectroscopy, x-ray photoelectron spectroscopy, and scanning electron microscopy (SEM). All the surface treatments studied appeared to change the surface morphology dramatically, as evidenced by lack of tool marks on the treated samples in SEM images. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7–0.9 nm thick), as well as to the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E’s silicon coating appears to be on the order of 200 nm thick.

  6. Analysis of passivated A-286 stainless steel surfaces for mass spectrometer inlet systems by Auger electron and X-ray photoelectron spectroscopy and scanning electron microscopy

    DOE PAGES [OSTI]

    Ajo, Henry; Blankenship, Donnie; Clark, Elliot

    2014-07-25

    In this study, various commercially available surface treatments are being explored for use on stainless steel components in mass spectrometer inlet systems. Type A-286 stainless steel coupons, approximately 12.5 mm in diameter and 3 mm thick, were passivated with one of five different surface treatments; an untreated coupon served as a control. The surface and near-surface microstructure and chemistry of the coupons were investigated using sputter depth profiling using Auger electron spectroscopy, x-ray photoelectron spectroscopy, and scanning electron microscopy (SEM). All the surface treatments studied appeared to change the surface morphology dramatically, as evidenced by lack of tool marks onmore » the treated samples in SEM images. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7–0.9 nm thick), as well as to the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E’s silicon coating appears to be on the order of 200 nm thick.« less

  7. Gated charged-particle trap

    DOEpatents

    Benner, W. Henry

    1999-01-01

    The design and operation of a new type of charged-particle trap provides simultaneous measurements of mass, charge, and velocity of large electrospray ions. The trap consists of a detector tube mounted between two sets of center-bored trapping plates. Voltages applied to the trapping plates define symmetrically-opposing potential valleys which guide axially-injected ions to cycle back and forth through the charge-detection tube. A low noise charge-sensitive amplifier, connected to the tube, reproduces the image charge of individual ions as they pass through the detector tube. Ion mass is calculated from measurement of ion charge and velocity following each passage through the detector.

  8. Digitally synthesized high purity, high-voltage radio frequency drive electronics for mass spectrometry

    SciTech Connect

    Schaefer, R. T.; Mojarradi, M.; MacAskill, J. A.; Chutjian, A.; Darrach, M. R.; Madzunkov, S. M.; Shortt, B. J.

    2008-09-15

    Reported herein is development of a quadrupole mass spectrometer controller (MSC) with integrated radio frequency (rf) power supply and mass spectrometer drive electronics. Advances have been made in terms of the physical size and power consumption of the MSC, while simultaneously making improvements in frequency stability, total harmonic distortion, and spectral purity. The rf power supply portion of the MSC is based on a series-resonant LC tank, where the capacitive load is the mass spectrometer itself, and the inductor is a solenoid or toroid, with various core materials. The MSC drive electronics is based on a field programmable gate array (FPGA), with serial peripheral interface for analog-to-digital and digital-to-analog converter support, and RS232/RS422 communications interfaces. The MSC offers spectral quality comparable to, or exceeding, that of conventional rf power supplies used in commercially available mass spectrometers; and as well an inherent flexibility, via the FPGA implementation, for a variety of tasks that includes proportional-integral derivative closed-loop feedback and control of rf, rf amplitude, and mass spectrometer sensitivity. Also provided are dc offsets and resonant dipole excitation for mass selective accumulation in applications involving quadrupole ion traps; rf phase locking and phase shifting for external loading of a quadrupole ion trap; and multichannel scaling of acquired mass spectra. The functionality of the MSC is task specific, and is easily modified by simply loading FPGA registers or reprogramming FPGA firmware.

  9. COLD TRAPS

    DOEpatents

    Thompson, W.I.

    1958-09-30

    A cold trap is presented for removing a condensable component from a gas mixture by cooling. It consists of a shell, the exterior surface of which is chilled by a refrigerant, and conductive fins welded inside the shell to condense the gas, and distribute the condensate evenly throughout the length of the trap, so that the trap may function until it becomes completely filled with the condensed solid. The contents may then be removed as either a gas or as a liquid by heating the trap. This device has particuinr use as a means for removing uranium hexafluoride from the gaseous diffusion separation process during equipment breakdown and repair periods.

  10. Characterization of a real-time tracer for Isoprene Epoxydiols-derived Secondary Organic Aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements

    DOE PAGES [OSTI]

    Hu, W. W.; Campuzano-Jost, P.; Palm, B. B.; Day, D. A.; Ortega, A. M.; Hayes, P. L.; Krechmer, J. E.; Chen, Q.; Kuwata, M.; Liu, Y. J.; et al

    2015-04-16

    Substantial amounts of secondary organic aerosol (SOA) can be formed from isoprene epoxydiols (IEPOX), which are oxidation products of isoprene mainly under low-NO conditions. Total IEPOX-SOA, which may include SOA formed from other parallel isoprene low-NO oxidation pathways, was quantified by applying Positive Matrix Factorization (PMF) to aerosol mass spectrometer (AMS) measurements. The IEPOX-SOA fractions of OA in multiple field studies across several continents are summarized here and show consistent patterns with the concentration of gas-phase IEPOX simulated by the GEOS-Chem chemical transport model. During the SOAS study, 78% of IEPOX-SOA is accounted for the measured molecular tracers, making itmore » the highest level of molecular identification of an ambient SOA component to our knowledge. Enhanced signal at C5H6O+ (m/z 82) is found in PMF-resolved IEPOX-SOA spectra. To investigate the suitability of this ion as a tracer for IEPOX-SOA, we examine fC5H6O ( fC5H6O = C5H6O+/OA) across multiple field, chamber and source datasets. A background of ~ 1.7 ± 0.1‰ is observed in studies strongly influenced by urban, biomass-burning and other anthropogenic primary organic aerosol (POA). Higher background values of 3.1 ± 0.8‰ are found in studies strongly influenced by monoterpene emissions. The average laboratory monoterpene SOA value (5.5 ± 2.0‰) is 4 times lower than the average for IEPOX-SOA (22 ± 7‰). Locations strongly influenced by isoprene emissions under low-NO levels had higher fC5H6O (~ 6.5 ± 2.2‰ on average) than other sites, consistent with the expected IEPOX-SOA formation in those studies. fC5H6O in IEPOX-SOA is always elevated (12–40‰) but varies substantially between locations, which is shown to reflect large variations in its detailed molecular composition. The low fC5H6O (< 3‰) observed in non IEPOX-derived isoprene-SOA indicates that this tracer ion is specifically enhanced from IEPOX-SOA, and is not a tracer for all SOA

  11. Microfabricated cylindrical ion trap

    DOEpatents

    Blain, Matthew G.

    2005-03-22

    A microscale cylindrical ion trap, having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale cylindrical ion trap to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The microscale CIT has a reduced ion mean free path, allowing operation at higher pressures with less expensive and less bulky vacuum pumping system, and with lower battery power than conventional- and miniature-sized ion traps. The reduced electrode voltage enables integration of the microscale cylindrical ion trap with on-chip integrated circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of microscale cylindrical ion traps can be realized in truly field portable, handheld microanalysis systems.

  12. Thermoelectrically cooled water trap

    DOEpatents

    Micheels, Ronald H.

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  13. Microfabricated linear Paul-Straubel ion trap

    DOEpatents

    Mangan, Michael A.; Blain, Matthew G.; Tigges, Chris P.; Linker, Kevin L.

    2011-04-19

    An array of microfabricated linear Paul-Straubel ion traps can be used for mass spectrometric applications. Each ion trap comprises two parallel inner RF electrodes and two parallel outer DC control electrodes symmetric about a central trap axis and suspended over an opening in a substrate. Neighboring ion traps in the array can share a common outer DC control electrode. The ions confined transversely by an RF quadrupole electric field potential well on the ion trap axis. The array can trap a wide array of ions.

  14. Rapid and sensitive gas chromatography ion-trap mass spectrometry method for the determination of tobacco specific N-nitrosamines in secondhand smoke

    SciTech Connect

    SLEIMAN, Mohamad; MADDALENA, Randy L.; GUNDEL, Lara A.; DESTAILLATS, Hugo

    2009-07-01

    Tobacco-specific nitrosamines (TSNAs) are some of the most potent carcinogens in tobacco and cigarette smoke. Accurate quantification of these chemicals is needed to help assess public health risks. We developed and validated a specific and sensitive method to measure four TSNAs in both the gas- and particle-phase of secondhand smoke (SHS) using gas chromatography and ion-trap tandem mass spectrometry,. A smoking machine in an 18-m3 room-sized chamber generated relevant concentrations of SHS that were actively sampled on Teflon coated fiber glass (TCFG) filters, and passively sampled on cellulose substrates. A simple solid-liquid extraction protocol using methanol as solvent was successfully applied to both filters with high recoveries ranging from 85 to 115percent. Tandem MS parameters were optimized to obtain the best sensitivity in terms of signal to-noise ratio (S/N) for the target compounds. For each TSNA, the major fragmentation pathways as well as ion structures were elucidated and compared with previously published data. The method showed excellent performances with a linear dynamic range between 2 and 1000 ng mL-1, low detection limits (S/N> 3) of 30-300 pg.ml-1 and precision with experimental errors below 10percent for all compounds. Moreover, no interfering peaks were observed indicating a high selectivity of MS/MS without the need for a sample clean up step. The sampling and analysis method provides a sensitive and accurate tool to detect and quantify traces of TSNA in SHS polluted indoor environments.

  15. Highly charged ion secondary ion mass spectroscopy

    DOEpatents

    Hamza, Alex V.; Schenkel, Thomas; Barnes, Alan V.; Schneider, Dieter H.

    2001-01-01

    A secondary ion mass spectrometer using slow, highly charged ions produced in an electron beam ion trap permits ultra-sensitive surface analysis and high spatial resolution simultaneously. The spectrometer comprises an ion source producing a primary ion beam of highly charged ions that are directed at a target surface, a mass analyzer, and a microchannel plate detector of secondary ions that are sputtered from the target surface after interaction with the primary beam. The unusually high secondary ion yield permits the use of coincidence counting, in which the secondary ion stops are detected in coincidence with a particular secondary ion. The association of specific molecular species can be correlated. The unique multiple secondary nature of the highly charged ion interaction enables this new analytical technique.

  16. Gated charged-particle trap

    DOEpatents

    Benner, W.H.

    1999-03-09

    The design and operation of a new type of charged-particle trap provides simultaneous measurements of mass, charge, and velocity of large electrospray ions. The trap consists of a detector tube mounted between two sets of center-bored trapping plates. Voltages applied to the trapping plates define symmetrically-opposing potential valleys which guide axially-injected ions to cycle back and forth through the charge-detection tube. A low noise charge-sensitive amplifier, connected to the tube, reproduces the image charge of individual ions as they pass through the detector tube. Ion mass is calculated from measurement of ion charge and velocity following each passage through the detector. 5 figs.

  17. TRAP) K. S. Marble

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The trap's electric quadrupole field is provided by a SHIP TRAPS RF electronic circuit to the four segmented electrodes at the center of the trap while the trap's 7 Tesla magnetic ...

  18. VACUUM TRAP

    DOEpatents

    Gordon, H.S.

    1959-09-15

    An improved adsorption vacuum trap for use in vacuum systems was designed. The distinguishing feature is the placement of a plurality of torsionally deformed metallic fins within a vacuum jacket extending from the walls to the central axis so that substantially all gas molecules pass through the jacket will impinge upon the fin surfaces. T fins are heated by direct metallic conduction, thereby ol taining a uniform temperature at the adeorbing surfaces so that essentially all of the condensible impurities from the evacuating gas are removed from the vacuum system.

  19. COLD TRAP

    DOEpatents

    Milleron, N.

    1963-03-12

    An improved linear-flow cold trap is designed for highvacuum applications such as mitigating back migration of diffusion pump oil moiecules. A central pot of liquid nitrogen is nested within and supported by a surrounding, vertical, helical coil of metai sheet, all enveloped by a larger, upright, cylindrical, vacuum vessel. The vertical interstices between successive turns of the coil afford lineal, axial, high-vacuum passages between open mouths at top and bottom of said vessel, while the coil, being cold by virtue of thermal contact of its innermost turn with the nitrogen pot, affords expansive proximate condensation surfaces. (AEC)

  20. Method of multiplexed analysis using ion mobility spectrometer

    DOEpatents

    Belov, Mikhail E. (Richland, WA); Smith, Richard D. (Richland, WA)

    2009-06-02

    A method for analyzing analytes from a sample introduced into a Spectrometer by generating a pseudo random sequence of a modulation bins, organizing each modulation bin as a series of submodulation bins, thereby forming an extended pseudo random sequence of submodulation bins, releasing the analytes in a series of analyte packets into a Spectrometer, thereby generating an unknown original ion signal vector, detecting the analytes at a detector, and characterizing the sample using the plurality of analyte signal subvectors. The method is advantageously applied to an Ion Mobility Spectrometer, and an Ion Mobility Spectrometer interfaced with a Time of Flight Mass Spectrometer.

  1. Computer model for analyzing sodium cold traps

    SciTech Connect

    McPheeters, C C; Raue, D J

    1983-05-01

    A computer model was developed to simulate the processes that occur in sodium cold traps. The Model for Analyzing Sodium Cold Traps (MASCOT) simulates any desired configuration of mesh arrangements and dimensions and calculates pressure drops and flow distributions, temperature profiles, impurity concentration profiles, and impurity mass distributions. The calculated pressure drop as a function of impurity mass content determines the capacity of the cold trap. The accuracy of the model was checked by comparing calculated mass distributions with experimentally determined mass distributions from literature publications and with results from our own cold trap experiments. The comparisons were excellent in all cases. A parametric study was performed to determine which design variables are most important in maximizing cold trap capacity.

  2. Mobile Ice Nucleus Spectrometer

    SciTech Connect

    Kulkarni, Gourihar R.; Kok, G. L.

    2012-05-07

    This first year report presents results from a computational fluid dynamics (CFD) study to assess the flow and temperature profiles within the mobile ice nucleus spectrometer.

  3. Advanced quadrupole ion trap instrumentation for low level vehicle emissions measurements. CRADA final report for number ORNL93-0238

    SciTech Connect

    McLuckey, S.A.; Buchanan, M.V.; Asano, K.G.; Hart, K.J.; Goeringer, D.E.; Dearth, M.A.

    1997-09-01

    Quadrupole ion trap mass spectrometry has been evaluated for its potential use in vehicle emissions measurements in vehicle test facilities as an analyzer for the top 15 compounds contributing to smog generation. A variety of ionization methods were explored including ion trap in situ chemical ionization, atmospheric sampling glow discharge ionization, and nitric oxide chemical ionization in a glow discharge ionization source coupled with anion trap mass spectrometer. Emphasis was placed on the determination of hydrocarbons and oxygenated hydrocarbons at parts per million to parts per billion levels. Ion trap in situ water chemical ionization and atmospheric sampling glow discharge ionization were both shown to be amenable to the analysis of arenes, alcohols, aldehydes and, to some degree, alkenes. Atmospheric sampling glow discharge also generated molecular ions of methyl-t-butyl ether (MTBE). Neither of these ionization methods, however, were found to generate diagnostic ions for the alkanes. Nitric oxide chemical ionization, on the other hand, was found to yield diagnostic ions for alkanes, alkenes, arenes, alcohols, aldehydes, and MTBE. The ability to measure a variety of hydrocarbons present at roughly 15 parts per billion at measurement rates of 3 Hz was demonstrated. These results have demonstrated that the ion trap has an excellent combination of sensitivity, specificity, speed, and flexibility with respect to the technical requirements of the top 15 analyzer.

  4. High explosives vapor detection by atmospheric sampling glow discharge ionization/tandem mass spectrometry

    SciTech Connect

    McLuckey, S.A.; Goeringer, D.E.; Asano, K.G.

    1996-02-01

    The combination of atmospheric sampling glow discharge ionization with tandem mass spectrometry for the detection of traces of high explosives is described. Particular emphasis is placed on use of the quadrupole ion trap as the type of tandem mass spectrometer. Atmospheric sampling glow discharge provides a simple, rugged, and efficient means for anion formation while the quadrupole ion trap provides for efficient tandem mass spectrometry. Mass selective ion accumulation and non-specific ion activation methods can be used to overcome deleterious effects arising from ion/ion interactions. Such interactions constitute the major potential technical barrier to the use of the ion trap for real-time monitoring of targeted compounds in uncontrolled and highly variable matrices. Tailored waveforms can be used to effect both mass selective ion accumulation and ion activation. Concatenated tailored waveforms allow for both functions in a single experiment thereby providing the capability for monitoring several targeted species simultaneously. The combination of atmospheric sampling glow discharge ionization with a state-of-the-art analytical quadrupole ion trap is a highly sensitive and specific detector for traces of high explosives. The combination is also small and inexpensive relative to virtually any other form of tandem mass spectrometry. The science and technology underlying the glow discharge/ion trap combination is sufficiently mature to form the basis for an engineering effort to make the detector portable. 85 refs.

  5. MASS SPECTROMETRY

    DOEpatents

    Friedman, L.

    1962-01-01

    method is described for operating a mass spectrometer to improve its resolution qualities and to extend its period of use substantially between cleanings. In this method, a small amount of a beta emitting gas such as hydrogen titride or carbon-14 methane is added to the sample being supplied to the spectrometer for investigation. The additive establishes leakage paths on the surface of the non-conducting film accumulating within the vacuum chamber of the spectrometer, thereby reducing the effect of an accumulated static charge on the electrostatic and magnetic fields established within the instrument. (AEC)

  6. Final Technical Report [Toward Simultaneous Single-Particle Chemical and Optical Characterization: Development of a Multi-Angle Optical Scattering Module for the Aerosol Time-of-Flight Mass Spectrometer

    SciTech Connect

    Buckley, Steven

    2013-10-22

    This project was an initial effort to investigate the feasibility of an instrument combining real-time atmospheric particle composition measurements using an ATOFMS (Atmospheric Time-Of-Flight Mass Spectrometer) such as those performed by Prather’s group at the University of California, San Diego (UCSD) with multi-wavelength scattering measurements of the type investigated by Sorensen et al., of Kansas State University (KSU). In this Phase I effort we proposed to investigate near-angle scattering and the possibility of integration of a multi-wavelength scattering instrument into the UCSD ATOFMS. After an initial optical design and calculations, we discovered issues with the theory of measurement and with mechanical integration. Evidence emerged that the method of multi-wavelength scattering is only efficacious for spherical particles, while most atmospheric particles are non-spherical fractal aggregates. We also determined that the integration of the detector into existing ATOFMS instruments would be severely limited by volume constraints, and additional volume would require prohibitive additional pumping compared with the existing ATOFMS systems. Based on this evidence, we decided not to pursue a Phase II effort.

  7. HELIcal Orbit Spectrometer (HELIOS)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    HELIOS: The Helical Orbit Spectrometer at ATLAS B.B.Back Argonne National Laboratory B.B.Back, Argonne National Laboratory PHY Colloquium May 21, 2010 2 Outline: Motivation for studying light-ion reactions in inverse kinematics The HELIOS Spectrometer concept The Argonne implementation of HELIOS Commissioning experiment Planned upgrades Helios elsewhere B.B.Back, Argonne National Laboratory PHY Colloquium May 21, 2010 3 Motivation for studying light-ion reactions in inverse kinematics B.B.Back,

  8. The Results of Tests of the MICE Spectrometer Solenoids

    SciTech Connect

    Green, Michael A.; Virostek, Steve P.

    2009-10-19

    The Muon Ionization Cooling Experiment (MICE) spectrometer solenoid magnets will be the first magnets to be installed within the MICE cooling channel. The spectrometer magnets are the largest magnets in both mass and surface area within the MICE ooling channel. Like all of the other magnets in MICE, the spectrometer solenoids are kept cold using 1.5 W (at 4.2 K) pulse tube coolers. The MICE spectrometer solenoid is quite possibly the largest magnet that has been cooled using small coolers. Two pectrometer magnets have been built and tested. This report discusses the results of current and cooler tests of both magnets.

  9. Investigating the role of hydrogen in silicon deposition using an energy-resolved mass spectrometer and a Langmuir probe in an Ar/H{sub 2} radio frequency magnetron discharge

    SciTech Connect

    Mensah, S. L.; Naseem, Hameed H.; Abu-Safe, Husam; Gordon, M. H.

    2012-07-15

    The plasma parameters and ion energy distributions (IED) of the dominant species in an Ar-H{sub 2} discharge are investigated with an energy resolved mass spectrometer and a Langmuir probe. The plasmas are generated in a conventional magnetron chamber powered at 150 W, 13.56 MHz at hydrogen flow rates ranging from 0 to 25 sccm with a fixed argon gas flow rate of 15 sccm. Various H{sub n}{sup +}, SiH{sub n}{sup +}, SiH{sub n} fragments (with n = 1, 2, 3) together with Ar{sup +} and ArH{sup +} species are detected in the discharge. The most important species for the film deposition is SiH{sub n} (with n = 0, 1, 2). H fragments affect the hydrogen content in the material. The flux of Ar{sup +} decreases and the flux of ArH{sup +} increases when the hydrogen flow rate is increased; however, both fluxes saturate at hydrogen flow rates above 15 sccm. Electron density, n{sub e}, electron energy, T{sub e}, and ion density, n{sub i}, are estimated from the Langmuir probe data. T{sub e} is below 1.2 eV at hydrogen flow rates below 8 sccm, and about 2 eV at flow rates above 8 sccm. n{sub e} and n{sub i} decrease with increased hydrogen flow but the ratio of n{sub i} to n{sub e} increases. The formation of H{sup +} ions with energies above 36 eV and electrons with energies greater than 2 eV contributes to the decrease in hydrogen content at hydrogen flow rates above 8 sccm. Analysis of the IEDs indicates an inter-dependence of the species and their contribution to the thin film growth and properties.

  10. MASS SPECTROMETRY

    DOEpatents

    Nier, A.O.C.

    1959-08-25

    A voltage switching apparatus is described for use with a mass spectrometer in the concentratron analysis of several components of a gas mixture. The system automatically varies the voltage on the accelerating electrode of the mass spectrometer through a program of voltages which corresponds to the particular gas components under analysis. Automatic operation may be discontinued at any time to permit the operator to manually select any desired predetermined accelerating voltage. Further, the system may be manually adjusted to vary the accelerating voltage over a wide range.

  11. Broad band waveguide spectrometer

    DOEpatents

    Goldman, Don S.

    1995-01-01

    A spectrometer for analyzing a sample of material utilizing a broad band source of electromagnetic radiation and a detector. The spectrometer employs a waveguide possessing an entry and an exit for the electromagnetic radiation emanating from the source. The waveguide further includes a surface between the entry and exit portions which permits interaction between the electromagnetic radiation passing through the wave guide and a sample material. A tapered portion forms a part of the entry of the wave guide and couples the electromagnetic radiation emanating from the source to the waveguide. The electromagnetic radiation passing from the exit of the waveguide is captured and directed to a detector for analysis.

  12. FAST NEUTRON SPECTROMETER

    DOEpatents

    Davis, F.J.; Hurst, G.S.; Reinhardt, P.W.

    1959-08-18

    An improved proton recoil spectrometer for determining the energy spectrum of a fast neutron beam is described. Instead of discriminating against and thereby"throwing away" the many recoil protons other than those traveling parallel to the neutron beam axis as do conventional spectrometers, this device utilizes protons scattered over a very wide solid angle. An ovoidal gas-filled recoil chamber is coated on the inside with a scintillator. The ovoidal shape of the sensitive portion of the wall defining the chamber conforms to the envelope of the range of the proton recoils from the radiator disposed within the chamber. A photomultiplier monitors the output of the scintillator, and a counter counts the pulses caused by protons of energy just sufficient to reach the scintillator.

  13. Neutron range spectrometer

    DOEpatents

    Manglos, S.H.

    1988-03-10

    A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are colliminated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. 1 fig.

  14. Electron impact action spectroscopy of mass/charge selected macromolecular ions: Inner-shell excitation of ubiquitin protein

    DOE PAGES [OSTI]

    Rankovic, Milos Lj.; Giuliani, Alexandre; Milosavljevic, Aleksandar R.

    2016-02-11

    In this study, we have performed inner-shell electron impact action spectroscopy of mass and charge selected macromolecular ions. For this purpose, we have coupled a focusing electron gun with a linear quadrupole ion trap mass spectrometer. This experiment represents a proof of principle that an energy-tunable electron beam can be used in combination with radio frequency traps as an activation method in tandem mass spectrometry (MS2) and allows performing action spectroscopy. Electron impact MS2 spectra of multiply protonated ubiquitin protein ion have been recorded at incident electron energies around the carbon 1s excitation. Both MS2 and single ionization energy dependencemore » spectra are compared with literature data obtained using the soft X-ray activation conditions.« less

  15. Resonant ultrasound spectrometer

    DOEpatents

    Migliori, Albert; Visscher, William M.; Fisk, Zachary

    1990-01-01

    An ultrasound resonant spectrometer determines the resonant frequency spectrum of a rectangular parallelepiped sample of a high dissipation material over an expected resonant response frequency range. A sample holder structure grips corners of the sample between piezoelectric drive and receive transducers. Each transducer is mounted on a membrane for only weakly coupling the transducer to the holder structure and operatively contacts a material effective to remove system resonant responses at the transducer from the expected response range. i.e., either a material such as diamond to move the response frequencies above the range or a damping powder to preclude response within the range. A square-law detector amplifier receives the response signal and retransmits the signal on an isolated shield of connecting cabling to remove cabling capacitive effects. The amplifier also provides a substantially frequency independently voltage divider with the receive transducer. The spectrometer is extremely sensitive to enable low amplitude resonance to be detected for use in calculating the elastic constants of the high dissipation sample.

  16. Prototype Neutron Energy Spectrometer

    SciTech Connect

    Stephen Mitchell, Sanjoy Mukhopadhyay, Richard Maurer, Ronald Wolff

    2010-06-16

    The project goals are: (1) Use three to five pressurized helium tubes with varying polyethylene moderators to build a neutron energy spectrometer that is most sensitive to the incident neutron energy of interest. Neutron energies that are of particular interest are those from the fission neutrons (typically around 1-2 MeV); (2) Neutron Source Identification - Use the neutron energy 'selectivity' property as a tool to discriminate against other competing processes by which neutrons are generated (viz. Cosmic ray induced neutron production [ship effect], [a, n] reactions); (3) Determine the efficiency as a function of neutron energy (response function) of each of the detectors, and thereby obtain the composite neutron energy spectrum from the detector count rates; and (4) Far-field data characterization and effectively discerning shielded fission source. Summary of the presentation is: (1) A light weight simple form factor compact neutron energy spectrometer ready to be used in maritime missions has been built; (2) Under laboratory conditions, individual Single Neutron Source Identification is possible within 30 minutes. (3) Sources belonging to the same type of origin viz., (a, n), fission, cosmic cluster in the same place in the 2-D plot shown; and (4) Isotopes belonging to the same source origin like Cm-Be, Am-Be (a, n) or Pu-239, U-235 (fission) do have some overlap in the 2-D plot.

  17. The isobaric multiplet mass equation for A?71 revisited

    SciTech Connect

    Lam, Yi Hua; Blank, Bertram; Smirnova, Nadezda A.; Bueb, Jean Bernard; Antony, Maria Susai

    2013-11-15

    Accurate mass determination of short-lived nuclides by Penning-trap spectrometers and progress in the spectroscopy of proton-rich nuclei have triggered renewed interest in the isobaric multiplet mass equation (IMME). The energy levels of the members of T=1/2,1,3/2, and 2 multiplets and the coefficients of the IMME are tabulated for A?71. The new compilation is based on the most recent mass evaluation (AME2011) and it includes the experimental results on energies of the states evaluated up to end of 2011. Taking into account the error bars, a significant deviation from the quadratic form of the IMME for the A=9,35 quartets and the A=32 quintet is observed.

  18. Mass measurements near the Z = N line with JYFLTRAP

    SciTech Connect

    Kankainen, Anu; Collaboration: JYFLTRAP Collaboration

    2011-11-30

    Masses of nuclides involved in astrophysical rp and {nu}p processes have to be known precisely in order to model these processes reliably. Mass excesses for 90 ground state and 8 isomeric states of neutron-deficient nuclides have been determined with a precision of better than 10 keV with the JYFLTRAP double Penning trap mass spectrometer at the Ion-Guide Isotope Separator On-Line facility in Jyvaeskylae. Highlights of the measurements related to nuclear astrophysics are given. Some of the measured isomers, such as {sup 53}Co{sup m}, {sup 90}Tc{sup m}, and {sup 95}Pd{sup m}, and implications for the excitation energy of the 21{sup +} isomer in {sup 94}Ag are briefly discussed.

  19. Quench anaylsis of MICE spectrometer superconducting solenoid

    SciTech Connect

    Kashikhin, Vladimir; Bross, Alan; Prestemon, Soren; / /LBL, Berkeley

    2011-09-01

    MICE superconducting spectrometer solenoids fabrication and tests are in progress now. First tests of the Spectrometer Solenoid discovered some issues which could be related to the chosen passive quench protection system. Both solenoids do not have heaters and quench propagation relied on the 'quench back' effect, cold diodes, and shunt resistors. The solenoids have very large inductances and stored energy which is 100% dissipated in the cold mass during a quench. This makes their protection a challenging task. The paper presents the quench analysis of these solenoids based on 3D FEA solution of coupled transient electromagnetic and thermal problems. The simulations used the Vector Fields QUENCH code. It is shown that in some quench scenarios, the quench propagation is relatively slow and some areas can be overheated. They describe ways of improving the solenoids quench protection in order to reduce the risk of possible failure.

  20. Photo ion spectrometer

    DOEpatents

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-12-26

    A charged particle spectrometer is described for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode. 12 figs.

  1. Photo ion spectrometer

    DOEpatents

    Gruen, Dieter M.; Young, Charles E.; Pellin, Michael J.

    1989-01-01

    A charged particle spectrometer for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode.

  2. Simplifying steam trap selection

    SciTech Connect

    Debat, R.J. )

    1994-01-01

    In the current economic world order, there is an obligation to eliminate waste and conserve economic and natural resources. One trap blowing 100-lb of steam through a 1/4-in. orifice can cost more than $12,000 a year in wasted energy. Richard J. Debat of Armstrong International, Inc. explains the operating principles of the four basic types of steam traps as the first step in simplifying the selection process so the right trap can be specified for a given application.

  3. Lessons Learned for the MICE Coupling Solenoid from the MICE Spectrometer Solenoids

    SciTech Connect

    Green, Michael A.; Wang, Li; Pan, Heng; Wu, Hong; Guo, Xinglong; Li, S. Y.; Zheng, S. X.; Virostek, Steve P.; DeMello, Allen J.; Li, Derun; Trillaud, Frederick; Zisman, Michael S.

    2010-05-30

    Tests of the spectrometer solenoids have taught us some important lessons. The spectrometer magnet lessons learned fall into two broad categories that involve the two stages of the coolers that are used to cool the magnets. On the first spectrometer magnet, the problems were centered on the connection of the cooler 2nd-stage to the magnet cold mass. On the first test of the second spectrometer magnet, the problems were centered on the cooler 1st-stage temperature and its effect on the operation of the HTS leads. The second time the second spectrometer magnet was tested; the cooling to the cold mass was still not adequate. The cryogenic designs of the MICE and MuCOOL coupling magnets are quite different, but the lessons learned from the tests of the spectrometer magnets have affected the design of the coupling magnets.

  4. Steam trap monitor

    DOEpatents

    Ryan, M.J.

    1987-05-04

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

  5. Neutron range spectrometer

    DOEpatents

    Manglos, Stephen H.

    1989-06-06

    A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are collimnated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. The computer solves the following equation in the analysis: ##EQU1## where: N(x).DELTA.x=the number of neutron interactions measured between a position x and x+.DELTA.x, A.sub.i (E.sub.i).DELTA.E.sub.i =the number of incident neutrons with energy between E.sub.i and E.sub.i +.DELTA.E.sub.i, and C=C(E.sub.i)=N .sigma.(E.sub.i) where N=the number density of absorbing atoms in the position sensitive counter means and .sigma. (E.sub.i)=the average cross section of the absorbing interaction between E.sub.i and E.sub.i +.DELTA.E.sub.i.

  6. Aerosol mobility size spectrometer

    DOEpatents

    Wang, Jian; Kulkarni, Pramod

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  7. Photo ion spectrometer

    DOEpatents

    Gruen, Dieter M.; Young, Charles E.; Pellin, Michael J.

    1989-01-01

    A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.

  8. Photo ion spectrometer

    DOEpatents

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-08-08

    A method and apparatus are described for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected auto-ionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy. 8 figs.

  9. Gamma ray spectrometer for ITER

    SciTech Connect

    Gin, D.; Chugunov, I.; Shevelev, A.; Khilkevitch, E.; Doinikov, D.; Naidenov, V.; Pasternak, A.; Polunovsky, I.; Kiptily, V.

    2014-08-21

    Gamma diagnostics is considered to be primary for the confined α-particles and runaway electrons measurements on ITER. The gamma spectrometer will be embedded into a neutron dump of the ITER Neutral Particle Analyzer diagnostic complex. It will supplement NPA measurements on the fuel isotope ratio and confined alphas/fast ions. In this paper an update on ITER gamma spectrometer developments is given. A new geometry of the system is described and detailed analysis of expected signals for the spectrometer is presented.

  10. Ion funnel ion trap and process

    DOEpatents

    Belov, Mikhail E [Richland, WA; Ibrahim, Yehia M [Richland, WA; Clowers, Biran H [West Richland, WA; Prior, David C [Hermiston, OR; Smith, Richard D [Richland, WA

    2011-02-15

    An ion funnel trap is described that includes a inlet portion, a trapping portion, and a outlet portion that couples, in normal operation, with an ion funnel. The ion trap operates efficiently at a pressure of .about.1 Torr and provides for: 1) removal of low mass-to-charge (m/z) ion species, 2) ion accumulation efficiency of up to 80%, 3) charge capacity of .about.10,000,000 elementary charges, 4) ion ejection time of 40 to 200 .mu.s, and 5) optimized variable ion accumulation times. Ion accumulation with low concentration peptide mixtures has shown an increase in analyte signal-to-noise ratios (SNR) of a factor of 30, and a greater than 10-fold improvement in SNR for multiply charged analytes.

  11. Dynamic multiplexed analysis method using ion mobility spectrometer

    DOEpatents

    Belov, Mikhail E [Richland, WA

    2010-05-18

    A method for multiplexed analysis using ion mobility spectrometer in which the effectiveness and efficiency of the multiplexed method is optimized by automatically adjusting rates of passage of analyte materials through an IMS drift tube during operation of the system. This automatic adjustment is performed by the IMS instrument itself after determining the appropriate levels of adjustment according to the method of the present invention. In one example, the adjustment of the rates of passage for these materials is determined by quantifying the total number of analyte molecules delivered to the ion trap in a preselected period of time, comparing this number to the charge capacity of the ion trap, selecting a gate opening sequence; and implementing the selected gate opening sequence to obtain a preselected rate of analytes within said IMS drift tube.

  12. Asymmetric ion trap

    DOEpatents

    Barlow, S.E.; Alexander, M.L.; Follansbee, J.C.

    1997-12-02

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode is disclosed. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity. 4 figs.

  13. Asymmetric ion trap

    DOEpatents

    Barlow, Stephan E.; Alexander, Michael L.; Follansbee, James C.

    1997-01-01

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity.

  14. Steam trap monitor

    DOEpatents

    Ryan, Michael J. (Plainfield, IL)

    1988-01-01

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

  15. WATER-TRAPPED WORLDS

    SciTech Connect

    Menou, Kristen [Department of Astronomy, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)

    2013-09-01

    Although tidally locked habitable planets orbiting nearby M-dwarf stars are among the best astronomical targets to search for extrasolar life, they may also be deficient in volatiles and water. Climate models for this class of planets show atmospheric transport of water from the dayside to the nightside, where it is precipitated as snow and trapped as ice. Since ice only slowly flows back to the dayside upon accumulation, the resulting hydrological cycle can trap a large amount of water in the form of nightside ice. Using ice sheet dynamical and thermodynamical constraints, I illustrate how planets with less than about a quarter the Earth's oceans could trap most of their surface water on the nightside. This would leave their dayside, where habitable conditions are met, potentially dry. The amount and distribution of residual liquid water on the dayside depend on a variety of geophysical factors, including the efficiency of rock weathering at regulating atmospheric CO{sub 2} as dayside ocean basins dry up. Water-trapped worlds with dry daysides may offer similar advantages as land planets for habitability, by contrast with worlds where more abundant water freely flows around the globe.

  16. Mass Measurements of Very Neutron-Deficient Mo and Tc Isotopes and Their Impact on rp Process Nucleosynthesis

    SciTech Connect

    Haettner, E.; Plass, W. R.; Scheidenberger, C.; Ackermann, D.; Block, M.; Eliseev, S.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Kluge, H.-J.; Audi, G.; Blaum, K.; Ketter, J.; Fleckenstein, T.; Ketelaer, J.; Marx, G.; Schweikhard, L.; Mazzocco, M.; Novikov, Yu. N.; Vorobjev, G.

    2011-03-25

    The masses of ten proton-rich nuclides, including the N=Z+1 nuclides {sup 85}Mo and {sup 87}Tc, were measured with the Penning trap mass spectrometer SHIPTRAP. Compared to the Atomic Mass Evaluation 2003 a systematic shift of the mass surface by up to 1.6 MeV is observed causing significant abundance changes of the ashes of astrophysical x-ray bursts. Surprisingly low {alpha} separation energies for neutron-deficient Mo and Tc are found, making the formation of a ZrNb cycle in the rp process possible. Such a cycle would impose an upper temperature limit for the synthesis of elements beyond Nb in the rp process.

  17. Radial cold trap

    DOEpatents

    Grundy, Brian R.

    1981-01-01

    The radial cold trap comprises a housing having a plurality of mesh bands disposed therein. The mesh bands comprise concentrically arranged bands of mesh with the mesh specific surface area of each band increasing from the outermost mesh band to the innermost mesh band. An inlet nozzle is attached to the outside section of the housing while an outlet nozzle is attached to the inner portion of the housing so as to be concentrically connected to the innermost mesh band. An inlet baffle having orifices therein may be disposed around the outermost mesh band and within the housing for directing the flow of the fluid from the inlet nozzle to the outermost mesh band in a uniform manner. The flow of fluid passes through each consecutive mesh band and into the outlet nozzle. The circular pattern of the symmetrically arranged mesh packing allows for better utilization of the entire cold trap volume.

  18. Radial cold trap

    DOEpatents

    Grundy, B.R.

    1981-09-29

    The radial cold trap comprises a housing having a plurality of mesh bands disposed therein. The mesh bands comprise concentrically arranged bands of mesh with the mesh specific surface area of each band increasing from the outermost mesh band to the innermost mesh band. An inlet nozzle is attached to the outside section of the housing while an outlet nozzle is attached to the inner portion of the housing so as to be concentrically connected to the innermost mesh band. An inlet baffle having orifices therein may be disposed around the outermost mesh band and within the housing for directing the flow of the fluid from the inlet nozzle to the outermost mesh band in a uniform manner. The flow of fluid passes through each consecutive mesh band and into the outlet nozzle. The circular pattern of the symmetrically arranged mesh packing allows for better utilization of the entire cold trap volume. 2 figs.

  19. Filter vapor trap

    DOEpatents

    Guon, Jerold

    1976-04-13

    A sintered filter trap is adapted for insertion in a gas stream of sodium vapor to condense and deposit sodium thereon. The filter is heated and operated above the melting temperature of sodium, resulting in a more efficient means to remove sodium particulates from the effluent inert gas emanating from the surface of a liquid sodium pool. Preferably the filter leaves are precoated with a natrophobic coating such as tetracosane.

  20. MICE Spectrometer Magnet System Progress

    SciTech Connect

    Green, Michael A.; Virostek, Steve P.

    2007-08-27

    The first magnets for the muon ionization cooling experimentwill be the tracker solenoids that form the ends of the MICE coolingchannel. The primary purpose of the tracker solenoids is to provide auniform 4 T field (to better than +-0.3 percent over a volume that is 1meter long and 0.3 meters in diameter) spectrometer magnet field for thescintillating fiber detectors that are used to analyze the muons in thechannel before and after ionization cooling. A secondary purpose for thetracker magnet is the matching of the muon beam between the rest of theMICE cooling channel and the uniform field spectrometer magnet. Thetracker solenoid is powered by three 300 amp power supplies. Additionaltuning of the spectrometer is provided by a pair of 50 amp power suppliesacross the spectrometer magnet end coils. The tracker magnet will becooled using a pair of 4 K pulse tube coolers that each provide 1.5 W ofcooling at 4.2 K. Final design and construction of the tracker solenoidsbegan during the summer of 2006. This report describes the progress madeon the construction of the tracker solenoids.

  1. Fabrication, Testing and Modeling of the MICE Superconducting Spectrometer Solenoids

    SciTech Connect

    Virostek, S.P.; Green, M.A.; Trillaud, F.; Zisman, M.S.

    2010-05-16

    The Muon Ionization Cooling Experiment (MICE), an international collaboration sited at Rutherford Appleton Laboratory in the UK, will demonstrate ionization cooling in a section of realistic cooling channel using a muon beam. A five-coil superconducting spectrometer solenoid magnet will provide a 4 tesla uniform field region at each end of the cooling channel. Scintillating fiber trackers within the 400 mm diameter magnet bore tubes measure the emittance of the beam as it enters and exits the cooling channel. Each of the identical 3-meter long magnets incorporates a three-coil spectrometer magnet section and a two-coil section to match the solenoid uniform field into the other magnets of the MICE cooling channel. The cold mass, radiation shield and leads are currently kept cold by means of three two-stage cryocoolers and one single-stage cryocooler. Liquid helium within the cold mass is maintained by means of a re-condensation technique. After incorporating several design changes to improve the magnet cooling and reliability, the fabrication and acceptance testing of the spectrometer solenoids have proceeded. The key features of the spectrometer solenoid magnets, the development of a thermal model, the results of the recently completed tests, and the current status of the project are presented.

  2. Linear electric field mass spectrometry

    DOEpatents

    McComas, D.J.; Nordholt, J.E.

    1992-12-01

    A mass spectrometer and methods for mass spectrometry are described. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field. 8 figs.

  3. Linear electric field mass spectrometry

    DOEpatents

    McComas, David J.; Nordholt, Jane E.

    1992-01-01

    A mass spectrometer and methods for mass spectrometry. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field.

  4. Electrostatic ion beam trap for electron collision studies

    SciTech Connect

    Heber, O.; Witte, P.D.; Diner, A.; Bhushan, K.G.; Strasser, D.; Toker, Y.; Rappaport, M.L.; Ben-Itzhak, I.; Altstein, N.; Schwalm, D.; Wolf, A.; Zajfman, D.

    2005-01-01

    We describe a system combining an ion beam trap and a low energy electron target in which the interaction between electrons and vibrationally cold molecular ions and clusters can be studied. The entire system uses only electrostatic fields for both trapping and focusing, thus being able to store particles without a mass limit. Preliminary results for the electron impact neutralization of C{sub 2}{sup -} ions and aluminum clusters are presented.

  5. Preliminary results from the lunar prospector alpha particle spectrometer

    SciTech Connect

    Lawson, S. L.

    2001-01-01

    The Lunar Prospector Alpha Particle Spectrometer (LP APS) builds on Apollo heritage and maps the distribution of outgassing sites on the Moon. The APS searches for lunar surface gas release events and maps their distribution by detecting alpha particles produced by the decay of gaseous radon-222 (5.5 MeV, 3.8 day half-life) and solid polonium-210 (5.3 MeV, 138 day half-life, but remains on the surface with a 21 year half-life as lead-210), which are radioactive daughters from the decay of uranium-238. Radon is in such small quantities that it is not released directly from the lunar interior, rather it is entrained in a stream of gases and serves as a tracer for such gases. Once released, the radon spreads out by 'bouncing' across the surface on ballistic trajectories in a random-walk process. The 3.8 day half-life of radon-222 allows the gas to spread out by several 100 km before it decays and allows the APS to detect gas release events up to a few days after they occur. The long residence time (10s of years) of the lead-210 precursor to the polonium-210 allows the mapping of gas vents which have been active over the last approximately 50 years. Because radon and polonium are daughter products of the decay of uranium, the background level of alpha particle activity is a function of the lunar crustal uranium distribution. Using radioactive radon and polonium as tracers, the Apollo 15 and 16 Command Module orbital alpha particle experiments obtained evidence for the release of gases at several sites beneath the orbit tracks, especially over the Aristarchus Plateau and Mare Fecunditatis [1]. Aristarchus crater had previously been identified by ground-based observers as the site of transient optical events [2]. The Apollo 17 surface mass spectrometer showed that argon-40 is released from the lunar interior every few months, apparently in concert with some of the shallow moonquakes that are believed to be of tectonic origin [3]. The latter tectonic events could be

  6. Sample rotating turntable kit for infrared spectrometers

    DOEpatents

    Eckels, Joel Del (Livermore, CA); Klunder, Gregory L. (Oakland, CA)

    2008-03-04

    An infrared spectrometer sample rotating turntable kit has a rotatable sample cup containing the sample. The infrared spectrometer has an infrared spectrometer probe for analyzing the sample and the rotatable sample cup is adapted to receive the infrared spectrometer probe. A reflectance standard is located in the rotatable sample cup. A sleeve is positioned proximate the sample cup and adapted to receive the probe. A rotator rotates the rotatable sample cup. A battery is connected to the rotator.

  7. Electron spectrometer for gas-phase spectroscopy

    SciTech Connect

    Bozek, J.D.; Schlachter, A.S.

    1997-04-01

    An electron spectrometer for high-resolution spectroscopy of gaseous samples using synchrotron radiation has been designed and constructed. The spectrometer consists of a gas cell, cylindrical electrostatic lens, spherical-sector electron energy analyzer, position-sensitive detector and associated power supplies, electronics and vacuum pumps. Details of the spectrometer design are presented together with some representative spectra.

  8. Inverse time-of-flight spectrometer for beam plasma research

    SciTech Connect

    Yushkov, Yu. G., E-mail: yuyushkov@gmail.com; Zolotukhin, D. B.; Tyunkov, A. V. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Oks, E. M. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation); Savkin, K. P. [Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation)

    2014-08-15

    The paper describes the design and principle of operation of an inverse time-of-flight spectrometer for research in the plasma produced by an electron beam in the forevacuum pressure range (520 Pa). In the spectrometer, the deflecting plates as well as the drift tube and the primary ion beam measuring system are at high potential with respect to ground. This provides the possibility to measure the mass-charge constitution of the plasma created by a continuous electron beam with a current of up to 300 mA and electron energy of up to 20 keV at forevacuum pressures in the chamber placed at ground potential. Research results on the mass-charge state of the beam plasma are presented and analyzed.

  9. Concerning the Spatial Heterodyne Spectrometer

    DOE PAGES [OSTI]

    Lenzner, Matthias; Diels, Jean -Claude

    2016-01-22

    A modified Spatial Heterodyne Spectrometer (SHS) is used for measuring atomic emission spectra with high resolution. This device is basically a Fourier Transform Spectrometer, but the Fourier transform is taken in the directions perpendicular to the optical propagation and heterodyned around one preset wavelength. In recent descriptions of this device, one specific phenomenon - the tilt of the energy front of wave packets when diffracted from a grating - was neglected. This led to an overestimate of the resolving power of this spectrograph, especially in situations when the coherence length of the radiation under test is in the order ofmore » the effective aperture of the device. In conclusion, the limits of usability are shown here together with some measurements of known spectral lines.« less

  10. ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    engineering data Title: ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST): engineering data Atmospheric Sounder Spectrometer for Infrared Spectral ...

  11. Electron Trapping by Molecular Vibration

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally...

  12. Inspect and Repair Steam Traps

    Energy.gov [DOE]

    This tip sheet on inspecting and repairing steam traps provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  13. Direct Sampling and Analysis from Solid Phase Extraction Cards using an Automated Liquid Extraction Surface Analysis Nanoelectrospray Mass Spectrometry System

    SciTech Connect

    Walworth, Matthew J; ElNaggar, Mariam S; Stankovich, Joseph J; WitkowskiII, Charles E.; Norris, Jeremy L; Van Berkel, Gary J

    2011-01-01

    Direct liquid extraction based surface sampling, a technique previously demonstrated with continuous flow and autonomous pipette liquid microjunction surface sampling probes, has recently been implemented as the Liquid Extraction Surface Analysis (LESA) mode on the commercially available Advion NanoMate chip-based infusion nanoelectrospray ionization system. In the present paper, the LESA mode was applied to the analysis of 96-well format custom solid phase extraction (SPE) cards, with each well consisting of either a 1 or 2 mm diameter monolithic hydrophobic stationary phase. These substrate wells were conditioned, loaded with either single or multi-component aqueous mixtures, and read out using the LESA mode of a TriVersa NanoMate or a Nanomate 100 coupled to an ABI/Sciex 4000QTRAPTM hybrid triple quadrupole/linear ion trap mass spectrometer and a Thermo LTQ XL linear ion trap mass spectrometer. Extraction conditions, including extraction/nanoESI solvent composition, volume, and dwell times, were optimized in the analysis of targeted compounds. Limit of detection and quantitation as well as analysis reproducibility figures of merit were measured. Calibration data was obtained for propranolol using a deuterated internal standard which demonstrated linearity and reproducibility. A 10x increase in signal and cleanup of micromolar Angiotensin II from a concentrated salt solution was demonstrated. Additionally, a multicomponent herbicide mixture at ppb concentration levels was analyzed using MS3 spectra for compound identification in the presence of isobaric interferences.

  14. Greenpower Trap Mufflerl System

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Water GREENPOWER TRAP-MUFFLER(tm) System (US Patent #6892531, 5085049, PCT, others pending) www.dieselnet.com/dr.rim Catalyst/DPF EGR Accumulator Air Intake Filter Turbo Charger Engine Intercooler EGR+water vapor Clean Exhaust PM 93% NOx 50% ECU E-Igniter FBC/OBC Water Lubrication Fuel + FBC Emissions Test Results Verified by Japan Automotive Research Inst., Tokyo, Japan 0 1 2 3 4 5 6 Before After NOx 2.676 5.51 g/kwH 51.4% 0 0.05 0.1 0.15 0.2 0.25 0.3 Before After PM g/kwH 0.278 0.03 89.2% NOx

  15. Portable neutron spectrometer and dosimeter

    DOEpatents

    Waechter, D.A.; Erkkila, B.H.; Vasilik, D.G.

    The disclosure relates to a battery operated neutron spectrometer/dosimeter utilizing a microprocessor, a built-in tissue equivalent LET neutron detector, and a 128-channel pulse height analyzer with integral liquid crystal display. The apparatus calculates doses and dose rates from neutrons incident on the detector and displays a spectrum of rad or rem as a function of keV per micron of equivalent tissue and also calculates and displays accumulated dose in millirads and millirem as well as neutron dose rates in millirads per hour and millirem per hour.

  16. Portable neutron spectrometer and dosimeter

    DOEpatents

    Waechter, David A. (Los Alamos, NM); Erkkila, Bruce H. (Los Alamos, NM); Vasilik, Dennis G. (Los Alamos, NM)

    1985-01-01

    The disclosure relates to a battery operated neutron spectrometer/dosimeter utilizing a microprocessor, a built-in tissue equivalent LET neutron detector, and a 128-channel pulse height analyzer with integral liquid crystal display. The apparatus calculates doses and dose rates from neutrons incident on the detector and displays a spectrum of rad or rem as a function of keV per micron of equivalent tissue and also calculates and displays accumulated dose in millirads and millirem as well as neutron dose rates in millirads per hour and millirem per hour.

  17. Giga-Dalton Mass Spectrometry - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Giga-Dalton Mass Spectrometry Major leap forward for Mass Spectrometry Applications to Life Sciences Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryCurrent techniques to study large bio?molecules using mass spectrometer require fragmentation for the mass?to?charge ratios to be within the working range of the mass spectrometer. Analysis

  18. Compact reflective imaging spectrometer utilizing immersed gratings

    DOEpatents

    Chrisp, Michael P. (Danville, CA)

    2006-05-09

    A compact imaging spectrometer comprising an entrance slit for directing light, a first mirror that receives said light and reflects said light, an immersive diffraction grating that diffracts said light, a second mirror that focuses said light, and a detector array that receives said focused light. The compact imaging spectrometer can be utilized for remote sensing imaging spectrometers where size and weight are of primary importance.

  19. The Aerodynamic, Dual- Wavelength Optical Spectrometer

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Aerodynamic, Dual- Wavelength Optical Spectrometer James C. Wilson Mechanical and ... 467. * Aerodynamic Particle Sizing - Wilson J.C., Liu B.Y.H., "Aerodynamic Particle ...

  20. ARM: Ultrahigh Sensitivity Aerosol Spectrometer (Dataset) | Data...

    Office of Scientific and Technical Information (OSTI)

    Ultrahigh Sensitivity Aerosol Spectrometer Authors: Cynthia Salwen ; Derek Hageman ; Bill Behrens ; Scott Smith ; Janek Uin ; Janek Uin ; Cynthia Salwen ; Annette Koontz ; Annette ...

  1. CNEEC - Nanophotonic Light Trapping Tutorial by Shanhui Fan

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Nanophotonic Light Trapping for Solar Cells

  2. The Design and Construction of the MICE Spectrometer Solenoids

    SciTech Connect

    Wang, Bert; Wahrer, Bob; Taylor, Clyde; Xu, L.; Chen, J. Y.; Wang, M.; Juang, Tiki; Zisman, Michael S.; Virostek, Steve P.; Green, Michael A.

    2008-08-02

    The purpose of the MICE spectrometer solenoid is to provide a uniform field for a scintillating fiber tracker. The uniform field is produced by a long center coil and two short end coils. Together, they produce 4T field with a uniformity of better than 1% over a detector region of 1000 mm long and 300 mm in diameter. Throughout most of the detector region, the field uniformity is better than 0.3%. In addition to the uniform field coils, we have two match coils. These two coils can be independently adjusted to match uniform field region to the focusing coil field. The coil package length is 2544 mm. We present the spectrometer solenoid cold mass design, the powering and quench protection circuits, and the cryogenic cooling system based on using three cryocoolers with re-condensers.

  3. Thermostatic steam trap

    SciTech Connect

    Anderson, A.H.; Mac Nicol, A.E.

    1987-03-03

    A thermostatic trap is described for a heating system having a feed pipe connected to a source of steam and a discharge pipe for discharge of condensate and comprising: housing means defining a volume and comprising a bowl shaped body, a removable cover therefor, a housing inlet pipe portion projecting from a side wall portion of the body and adapted for connection to the discharge pipe. A housing outlet pipe portion projects from a bottom wall portion of the body, and an outlet orifice defined by the bottom wall portion and extends between the volume and the outlet pipe portion; a valve body means retained within the volume and comprising an end wall, a side wall and a retaining ring portion that together define a valve chamber. The end wall defines a valve inlet opening communicating with the chamber and an annular valve seat within the chamber and encircling the valve inlet opening. The valve body means comprises a valve outlet pipe that defines a valve outlet opening axially aligned with the valve inlet opening and communicating with the chamber, the outlet pipe being fixed in the outlet orifice; a resilient, annular seal means disposed within the valve chamber and encircling the valve inlet opening; and a bi-metallic disc disposed within the valve chamber between the annular seal means and the outlet opening and having an outer peripheral portion retained by the retaining ring portion of the valve body means.

  4. Protection #2: Trap and Remove Sediment

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Trap and Remove Sediment Protection 2: Trap and Remove Sediment The 3 Protections Defense in Depth August 1, 2013 Sediment behind LA Canyon weir is sampled and excavated...

  5. Fundamental Electroweak Studies using Trapped Ions & Atoms

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    collaboration performs fundamental electroweak studies on trapped ions & atoms. We use neutral atom and ion trapping techniques at radioactive ion beam facilities here and...

  6. Production of Ultracold Trapped Molecular Hydrogen Ions

    SciTech Connect

    Blythe, P.; Roth, B.; Froehlich, U.; Wenz, H.; Schiller, S.

    2005-10-28

    We have cooled ensembles of the molecular hydrogen ions H{sub 2}{sup +}, H{sub 3}{sup +}, and all their deuterated variants to temperatures of a few mK in a radio frequency trap, by sympathetic cooling with laser-cooled beryllium ions. The molecular ions are embedded in the central regions of Coulomb crystals. Mass spectroscopy and molecular dynamics simulations were used to accurately characterize the properties of the ultracold multispecies crystals. We demonstrate species-selective purification of multispecies ensembles. These molecules are of fundamental importance as the simplest of all molecules, and have the potential to be used for precision tests of molecular structure theory, tests of Lorentz invariance, and measurements of electron to nuclear mass ratios and their time variation.

  7. Hydrodynamic enhanced dielectrophoretic particle trapping

    DOEpatents

    Miles, Robin R.

    2003-12-09

    Hydrodynamic enhanced dielectrophoretic particle trapping carried out by introducing a side stream into the main stream to squeeze the fluid containing particles close to the electrodes producing the dielelectrophoretic forces. The region of most effective or the strongest forces in the manipulating fields of the electrodes producing the dielectrophoretic forces is close to the electrodes, within 100 .mu.m from the electrodes. The particle trapping arrangement uses a series of electrodes with an AC field placed between pairs of electrodes, which causes trapping of particles along the edges of the electrodes. By forcing an incoming flow stream containing cells and DNA, for example, close to the electrodes using another flow stream improves the efficiency of the DNA trapping.

  8. Inspect and Repair Steam Traps

    SciTech Connect

    Not Available

    2006-01-01

    This revised ITP tip sheet on inspecting and repairing steam traps provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  9. Progress on the Design and Fabircation of the MICE SpectrometerSolenoids

    SciTech Connect

    Virostek, S.P.; Green, M.A.; Lia, D.; Sizman, M.S.

    2007-06-20

    The Muon Ionization Cooling Experiment (MICE) willdemonstrate ionization cooling in a short section of a realistic coolingchannel using a muon beam at Rutherford Appleton Laboratory (RAL) in theUK. A five-coil, superconducting spectrometer solenoid magnet at each endof the cooling channel will provide a 4 T uniform field region for thescintillating fiber tracker within the magnet bore tubes. The trackermodules are used to measure the muon beam emittance as it enters andexits the cooling channel. The cold mass for the 400 mm warm bore magnetconsists of two sections: a three-coil spectrometer magnet and a two-coilmatching section that matches the uniform field of the solenoid into theMICE cooling channel. The spectrometer solenoid detailed designandanalysis has been completed, and the fabrication of the magnets is wellunder way. The primary features of the spectrometer solenoid magnet andmechanical designs are presented along with a summary of key fabricationissues and photos of the construction.

  10. Effect of the size of experimental channels of the lead slowing-down spectrometer SVZ-100 (Institute for Nuclear Research, Moscow) on the moderation constant

    SciTech Connect

    Latysheva, L. N.; Bergman, A. A.; Sobolevsky, N. M.; Ilic, R. D.

    2013-04-15

    Lead slowing-down (LSD) spectrometers have a low energy resolution (about 30%), but their luminosity is 10{sup 3} to 10{sup 4} times higher than that of time-of-flight (TOF) spectrometers. A high luminosity of LSD spectrometers makes it possible to use them to measure neutron cross section for samples of mass about several micrograms. These features specify a niche for the application of LSD spectrometers in measuring neutron cross sections for elements hardly available in macroscopic amounts-in particular, for actinides. A mathematical simulation of the parameters of SVZ-100 LSD spectrometer of the Institute for Nuclear Research (INR, Moscow) is performed in the present study on the basis of the MCNPX code. It is found that the moderation constant, which is the main parameter of LSD spectrometers, is highly sensitive to the size and shape of detecting volumes in calculations and, hence, to the real size of experimental channels of the LSD spectrometer.

  11. An Adaptable Multiple Power Source for Mass Spectrometry and other Scientific Instruments

    SciTech Connect

    Lin, Tzu-Yung; Anderson, Gordon A.; Norheim, Randolph V.; Prost, Spencer A.; Lamarche, Brian L.; Leach, Franklin E.; Auberry, Kenneth J.; Smith, Richard D.; Koppenaal, David W.; Robinson, Errol W.; Pasa-Tolic, Ljiljana

    2015-09-18

    Power supplies are commonly used in the operation of many types of scientific equipment, including mass spectrometers and ancillary instrumentation. A generic modern mass spectrometer comprises an ionization source, such as electrospray ionization (ESI), ion transfer devices such as ion funnels and multipole ion guides, and ion signal detection apparatus. Very often such platforms include, or are interfaced with ancillary elements in order to manipulate samples before or after ionization. In order to operate such scientific instruments, numerous direct current (DC) channels and radio frequency (RF) signals are required, along with other controls such as temperature regulation. In particular, DC voltages in the range of ±400 V, along with MHz range RF signals with peak-to-peak amplitudes in the hundreds of volts range are commonly used to transfer ionized samples under vacuum. Additionally, an ESI source requires a high voltage (HV) DC source capable of producing several thousand volts and heaters capable of generating temperatures up to 300°C. All of these signals must be properly synchronized and managed in order to carry out ion trapping, accumulation and detection.

  12. TSI Model 3936 Scanning Mobility Particle Spectrometer Instrument...

    Office of Scientific and Technical Information (OSTI)

    TSI Model 3936 Scanning Mobility Particle Spectrometer Instrument Handbook Citation Details In-Document Search Title: TSI Model 3936 Scanning Mobility Particle Spectrometer ...

  13. A Spatially Resolving X-ray Crystal Spectrometer for Measurement...

    Office of Scientific and Technical Information (OSTI)

    394 PPPL- 4394 A Spatially Resolving X-ray Crystal Spectrometer for Measurement of ... Fusion Links A spatially resolving x-ray crystal spectrometer for measurement of ...

  14. Development of a Spatially Resolving X-Ray Crystal Spectrometer...

    Office of Scientific and Technical Information (OSTI)

    Development of a Spatially Resolving X-Ray Crystal Spectrometer For Measurement of ... Links Development of a spatially resolving x-ray crystal spectrometer for measurement of ...

  15. Development Of a Spatially Resolving X-ray Crystal Spectrometer...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Development Of a Spatially Resolving X-ray Crystal Spectrometer For ... Title: Development Of a Spatially Resolving X-ray Crystal Spectrometer For Measurement Of ...

  16. ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    1 data Title: ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST): channel 1 data Atmospheric Sounder Spectrometer for Infrared Spectral Technology ...

  17. ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    summary data Title: ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST): summary data Atmospheric Sounder Spectrometer for Infrared Spectral Technology ...

  18. Computer analysis of sodium cold trap design and performance. [LMFBR

    SciTech Connect

    McPheeters, C.C.; Raue, D.J.

    1983-11-01

    Normal steam-side corrosion of steam-generator tubes in Liquid Metal Fast Breeder Reactors (LMFBRs) results in liberation of hydrogen, and most of this hydrogen diffuses through the tubes into the heat-transfer sodium and must be removed by the purification system. Cold traps are normally used to purify sodium, and they operate by cooling the sodium to temperatures near the melting point, where soluble impurities including hydrogen and oxygen precipitate as NaH and Na/sub 2/O, respectively. A computer model was developed to simulate the processes that occur in sodium cold traps. The Model for Analyzing Sodium Cold Traps (MASCOT) simulates any desired configuration of mesh arrangements and dimensions and calculates pressure drops and flow distributions, temperature profiles, impurity concentration profiles, and impurity mass distributions.

  19. Orthogonal Injection Ion Funnel Interface Providing Enhanced Performance for Selected Reaction Monitoring-Triple Quadrupole Mass Spectrometry

    SciTech Connect

    Chen, Tsung-Chi; Fillmore, Thomas L.; Prost, Spencer A.; Moore, Ronald J.; Ibrahim, Yehia M.; Smith, Richard D.

    2015-06-24

    The electrodynamic ion funnel facilitates efficient focusing and transfer of charged particles in the higher pressure regions (e.g. ion source interfaces) of mass spectrometers, and thus providing increased sensitivity. An “off-axis” ion funnel design has been developed to reduce the source contamination and interferences from, e.g. ESI droplet residue and other poorly focused neutral or charged particles with very high mass-to charge ratios. In this study a dual ion funnel interface consisting of an orthogonal higher pressure electrodynamic ion funnel (HPIF) and an ion funnel trap combined with a triple quadruple mass spectrometer was developed and characterized. An orthogonal ion injection inlet and a repeller plate electrode was used to direct ions to an ion funnel HPIF at 9-10 Torr pressure. Several critical factors for the HPIF were characterized, including the effects of RF amplitude, DC gradient and operating pressure. Compared to the triple quadrupole standard interface more than 4-fold improvement in the limit of detection for the direct quantitative MS analysis of low abundance peptides was observed. Lastly, the sensitivity enhancement in liquid chromatography selected reaction monitoring (SRM) analyses of low abundance peptides spiked into a highly complex mixture was also compared with that obtained using a both commercial s-lens interface and a in-line dual ion funnel interface.

  20. Orthogonal Injection Ion Funnel Interface Providing Enhanced Performance for Selected Reaction Monitoring-Triple Quadruple Mass Spectrometry

    SciTech Connect

    Chen, Tsung-Chi; Fillmore, Thomas L.; Prost, Spencer A.; Moore, Ronald J.; Ibrahim, Yehia M.; Smith, Richard D.

    2015-07-21

    The electrodynamic ion funnel facilitates efficient focusing and transfer of charged particles in the higher pressure regions (e.g. ion source interfaces) of mass spectrometers, and thus providing increased sensitivity. An “off-axis” ion funnel design has been developed to reduce the source contamination and interferences from, e.g. ESI droplet residue and other poorly focused neutral or charged particles with very high mass-to charge ratios. In this study a dual ion funnel interface consisting of an orthogonal higher pressure electrodynamic ion funnel (HPIF) and an ion funnel trap combined with a triple quadruple mass spectrometer was developed and characterized. An orthogonal ion injection inlet and a repeller plate electrode was used to direct ions to an ion funnel HPIF at 9-10 Torr pressure. Several critical factors for the HPIF were characterized, including the effects of RF amplitude, DC gradient and operating pressure. Compared to the triple quadrupole standard interface more than 4-fold improvement in the limit of detection for the direct quantitative MS analysis of low abundance peptides was observed. The sensitivity enhancement in liquid chromatography selected reaction monitoring (SRM) analyses of low abundance peptides spiked into a highly complex mixture was also compared with that obtained using a both commercial s-lens interface and a in-line dual ion funnel interface.

  1. Orthogonal Injection Ion Funnel Interface Providing Enhanced Performance for Selected Reaction Monitoring-Triple Quadrupole Mass Spectrometry

    DOE PAGES [OSTI]

    Chen, Tsung-Chi; Fillmore, Thomas L.; Prost, Spencer A.; Moore, Ronald J.; Ibrahim, Yehia M.; Smith, Richard D.

    2015-06-24

    The electrodynamic ion funnel facilitates efficient focusing and transfer of charged particles in the higher pressure regions (e.g. ion source interfaces) of mass spectrometers, and thus providing increased sensitivity. An “off-axis” ion funnel design has been developed to reduce the source contamination and interferences from, e.g. ESI droplet residue and other poorly focused neutral or charged particles with very high mass-to charge ratios. In this study a dual ion funnel interface consisting of an orthogonal higher pressure electrodynamic ion funnel (HPIF) and an ion funnel trap combined with a triple quadruple mass spectrometer was developed and characterized. An orthogonal ionmore » injection inlet and a repeller plate electrode was used to direct ions to an ion funnel HPIF at 9-10 Torr pressure. Several critical factors for the HPIF were characterized, including the effects of RF amplitude, DC gradient and operating pressure. Compared to the triple quadrupole standard interface more than 4-fold improvement in the limit of detection for the direct quantitative MS analysis of low abundance peptides was observed. Lastly, the sensitivity enhancement in liquid chromatography selected reaction monitoring (SRM) analyses of low abundance peptides spiked into a highly complex mixture was also compared with that obtained using a both commercial s-lens interface and a in-line dual ion funnel interface.« less

  2. VACUUM TRAP AND VALVE COMBINATION

    DOEpatents

    Milleron, N.; Levenson, L.

    1963-02-19

    This patent relates to a vacuum trap and valve combination suitable for use in large ultra-high vacuum systems. The vacuum trap is a chamber having an inlet and outlet opening which may be made to communicate with a chamber to be evacuated and a diffusion pump, respectively. A valve is designed to hermeticaliy seal with inlet opening and, when opened, block the line-of- sight'' between the inlet and outlet openings, while allowing a large flow path between the opened vaive and the side walls of the trap. The interior of the trap and the side of the valve facing the inlet opening are covered with an impurity absorbent, such as Zeolite or activated aluminum. Besides the advantage of combining two components of a vacuum system into one, the present invention removes the need for a baffle between the pump and the chamber to be evacuated. In one use of a specific embodiment of this invention, the transmission probability was 45 and the partial pressure of the pump fluid vapor in the vacuum chamber was at least 100 times lower than its vapor pressure. (AEC)

  3. The LASS (Larger Aperture Superconducting Solenoid) spectrometer

    SciTech Connect

    Aston, D.; Awaji, N.; Barnett, B.; Bienz, T.; Bierce, R.; Bird, F.; Bird, L.; Blockus, D.; Carnegie, R.K.; Chien, C.Y.

    1986-04-01

    LASS is the acronym for the Large Aperture Superconducting Solenoid spectrometer which is located in an rf-separated hadron beam at the Stanford Linear Accelerator Center. This spectrometer was constructed in order to perform high statistics studies of multiparticle final states produced in hadron reactions. Such reactions are frequently characterized by events having complicated topologies and/or relatively high particle multiplicity. Their detailed study requires a spectrometer which can provide good resolution in momentum and position over almost the entire solid angle subtended by the production point. In addition, good final state particle identification must be available so that separation of the many kinematically-overlapping final states can be achieved. Precise analyses of the individual reaction channels require high statistics, so that the spectrometer must be capable of high data-taking rates in order that such samples can be acquired in a reasonable running time. Finally, the spectrometer must be complemented by a sophisticated off-line analysis package which efficiently finds tracks, recognizes and fits event topologies and correctly associates the available particle identification information. This, together with complicated programs which perform specific analysis tasks such as partial wave analysis, requires a great deal of software effort allied to a very large computing capacity. This paper describes the construction and performance of the LASS spectrometer, which is an attempt to realize the features just discussed. The configuration of the spectrometer corresponds to the data-taking on K and K interactions in hydrogen at 11 GeV/c which took place in 1981 and 1982. This constitutes a major upgrade of the configuration used to acquire lower statistics data on 11 GeV/c K p interactions during 1977 and 1978, which is also described briefly.

  4. Ion temperature gradient driven turbulence with strong trapped...

    Office of Scientific and Technical Information (OSTI)

    driven turbulence with strong trapped ion resonance is presented. The role of trapped ion granulations, clusters of trapped ions correlated by precession resonance, is the focus. ...

  5. Extending the frontiers of mass spectrometric instrumentation and methods

    SciTech Connect

    Schieffer, Gregg

    2010-12-15

    The focus of this dissertation is two-fold: developing novel analysis methods using mass spectrometry and the implementation and characterization of a novel ion mobility mass spectrometry instrumentation. The novel mass spectrometry combines ion trap for ion/ion reactions coupled to an ion mobility cell. The long term goal of this instrumentation is to use ion/ion reactions to probe the structure of gas phase biomolecule ions. The three ion source - ion trap - ion mobility - qTOF mass spectrometer (IT - IM - TOF MS) instrument is described. The analysis of the degradation products in coal (Chapter 2) and the imaging plant metabolites (Appendix III) fall under the methods development category. These projects use existing commercial instrumentation (JEOL AccuTOF MS and Thermo Finnigan LCQ IT, respectively) for the mass analysis of the degraded coal products and the plant metabolites, respectively. The coal degradation paper discusses the use of the DART ion source for fast and easy sample analysis. The sample preparation consisted of a simple 50 fold dilution of the soluble coal products in water and placing the liquid in front of the heated gas stream. This is the first time the DART ion source has been used for analysis of coal. Steven Raders under the guidance of John Verkade came up with the coal degradation projects. Raders performed the coal degradation reactions, worked up the products, and sent them to me. Gregg Schieffer developed the method and wrote the paper demonstrating the use of the DART ion source for the fast and easy sample analysis. The plant metabolite imaging project extends the use of colloidal graphite as a sample coating for atmospheric pressure LDI. DC Perdian and I closely worked together to make this project work. Perdian focused on building the LDI setup whereas Schieffer focused on the MSn analysis of the metabolites. Both Perdian and I took the data featured in the paper. Perdian was the primary writer of the paper and used it as a

  6. Review of Orifice Plate Steam Traps

    Office of Energy Efficiency and Renewable Energy (EERE)

    This guide was prepared to serve as a foundation for making informed decisions about when orifice plate steam traps should be considered for use in new or existing steam systems. It presents background information about different types of steam traps and defines their unique functional and operational characteristics. The advantages and disadvantages associated with using orifice plate steam traps are provided to highlight their capabilities and limitations. Finally, recommendations for using orifice plate steam traps are presented, and possible applications are identified.

  7. Guide to Orifice Plate Steam Traps

    SciTech Connect

    Oland, C.B.

    2001-01-11

    This guide was prepared to serve as a foundation for making informed decisions about when orifice plate steam traps should be considered for use in new or existing steam systems. It presents background information about different types of steam traps and defines their unique functional and operational characteristics. The advantages and disadvantages associated with using orifice plate steam traps are provided to highlight their capabilities and limitations. Finally, recommendations for using orifice plate steam traps are presented, and possible applications are identified.

  8. Method and apparatus for multispray emitter for mass spectrometry

    DOEpatents

    Smith, Richard D.; Tang, Keqi; Lin, Yuehe

    2004-12-14

    A method and apparatus that utilizes two or more emitters simultaneously to form an electrospray of a sample that is then directed into a mass spectrometer, thereby increasing the total ion current introduced into an electrospray ionization mass spectrometer, given a liquid flow rate of a sample. The method and apparatus are most conveniently constructed as an array of spray emitters fabricated on a single chip, however, the present invention encompasses any apparatus wherein two or more emitters are simultaneously utilized to form an electrospray of a sample that is then directed into a mass spectrometer.

  9. Compact Imaging Spectrometer Utilizing Immersed Gratings

    DOEpatents

    Chrisp, Michael P.; Lerner, Scott A.; Kuzmenko, Paul J.; Bennett, Charles L.

    2006-03-21

    A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, a system for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through an optical element to the detector array.

  10. Wide size range fast integrated mobility spectrometer

    DOEpatents

    Wang, Jian

    2013-10-29

    A mobility spectrometer to measure a nanometer particle size distribution is disclosed. The mobility spectrometer includes a conduit and a detector. The conduit is configured to receive and provide fluid communication of a fluid stream having a charged nanometer particle mixture. The conduit includes a separator section configured to generate an electrical field of two dimensions transverse to a dimension associated with the flow of the charged nanometer particle mixture through the separator section to spatially separate charged nanometer particles of the charged nanometer particle mixture in said two dimensions. The detector is disposed downstream of the conduit to detect concentration and position of the spatially-separated nanometer particles.

  11. The SPIDER fission fragment spectrometer for fission product yield measurements

    SciTech Connect

    Meierbachtol, K.; Tovesson, F.; Shields, D.; Arnold, C.; Blakeley, R.; Bredeweg, T.; Devlin, M.; Hecht, A. A.; Heffern, L. E.; Jorgenson, J.; Laptev, A.; Mader, D.; O׳Donnell, J. M.; Sierk, A.; White, M.

    2015-04-01

    The SPectrometer for Ion DEtermination in fission Research (SPIDER) developed for measuring mass yield distributions of fission products from spontaneous and neutron-induced fission. The 2E–2v method of measuring the kinetic energy (E) and velocity (v) of both outgoing fission products utilized, with the goal of measuring the mass of the fission products with an average resolution of 1 atomic mass unit (amu). The SPIDER instrument, consisting of detector components for time-of-flight, trajectory, and energy measurements, assembled and tested using 229Th and 252Cf radioactive decay sources. For commissioning, the fully assembled system measured fission products from spontaneous fission of 252Cf. Finally, individual measurement resolutions were met for time-of-flight (250 ps FWHM), spacial resolution (2 mm FHWM), and energy (92 keV FWHM for 8.376 MeV). These mass yield results measured from 252Cf spontaneous fission products are reported from an E–v measurement.

  12. The SPIDER fission fragment spectrometer for fission product yield measurements

    DOE PAGES [OSTI]

    Meierbachtol, K.; Tovesson, F.; Shields, D.; Arnold, C.; Blakeley, R.; Bredeweg, T.; Devlin, M.; Hecht, A. A.; Heffern, L. E.; Jorgenson, J.; et al

    2015-04-01

    The SPectrometer for Ion DEtermination in fission Research (SPIDER) developed for measuring mass yield distributions of fission products from spontaneous and neutron-induced fission. The 2E–2v method of measuring the kinetic energy (E) and velocity (v) of both outgoing fission products utilized, with the goal of measuring the mass of the fission products with an average resolution of 1 atomic mass unit (amu). The SPIDER instrument, consisting of detector components for time-of-flight, trajectory, and energy measurements, assembled and tested using 229Th and 252Cf radioactive decay sources. For commissioning, the fully assembled system measured fission products from spontaneous fission of 252Cf. Finally,more » individual measurement resolutions were met for time-of-flight (250 ps FWHM), spacial resolution (2 mm FHWM), and energy (92 keV FWHM for 8.376 MeV). These mass yield results measured from 252Cf spontaneous fission products are reported from an E–v measurement.« less

  13. Ion traps fabricated in a CMOS foundry

    SciTech Connect

    Mehta, K. K.; Ram, R. J.; Eltony, A. M.; Chuang, I. L.; Bruzewicz, C. D.; Sage, J. M. Chiaverini, J.

    2014-07-28

    We demonstrate trapping in a surface-electrode ion trap fabricated in a 90-nm CMOS (complementary metal-oxide-semiconductor) foundry process utilizing the top metal layer of the process for the trap electrodes. The process includes doped active regions and metal interconnect layers, allowing for co-fabrication of standard CMOS circuitry as well as devices for optical control and measurement. With one of the interconnect layers defining a ground plane between the trap electrode layer and the p-type doped silicon substrate, ion loading is robust and trapping is stable. We measure a motional heating rate comparable to those seen in surface-electrode traps of similar size. This demonstration of scalable quantum computing hardware utilizing a commercial CMOS process opens the door to integration and co-fabrication of electronics and photonics for large-scale quantum processing in trapped-ion arrays.

  14. Electrostatic particle trap for ion beam sputter deposition ...

    Office of Scientific and Technical Information (OSTI)

    The electrostatic particle trap consists of an array of electrode surfaces, each ... particle; trap; consists; array; electrode; surfaces; maintained; electrostatic; ...

  15. Compact imaging spectrometer utilizing immersed gratings

    DOEpatents

    Lerner, Scott A.

    2005-12-20

    A compact imaging spectrometer comprising an entrance slit for directing light, lens means for receiving the light, refracting the light, and focusing the light; an immersed diffraction grating that receives the light from the lens means and defracts the light, the immersed diffraction grating directing the detracted light back to the lens means; and a detector that receives the light from the lens means.

  16. Lens system for a photo ion spectrometer

    DOEpatents

    Gruen, Dieter M.; Young, Charles E.; Pellin, Michael J.

    1990-01-01

    A lens system in a photo ion spectrometer for manipulating a primary ion beam and ionized atomic component. The atomic components are removed from a sample by a primary ion beam using the lens system, and the ions are extracted for analysis. The lens system further includes ionization resistant coatings for protecting the lens system.

  17. Lens system for a photo ion spectrometer

    DOEpatents

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1990-11-27

    A lens system in a photo ion spectrometer for manipulating a primary ion beam and ionized atomic component is disclosed. The atomic components are removed from a sample by a primary ion beam using the lens system, and the ions are extracted for analysis. The lens system further includes ionization resistant coatings for protecting the lens system. 8 figs.

  18. Electrophoresis-mass spectrometry probe

    DOEpatents

    Andresen, B.D.; Fought, E.R.

    1987-11-10

    The invention involves a new technique for the separation of complex mixtures of chemicals, which utilizes a unique interface probe for conventional mass spectrometers which allows the electrophoretically separated compounds to be analyzed in real-time by a mass spectrometer. This new chemical analysis interface, which couples electrophoresis with mass spectrometry, allows complex mixtures to be analyzed very rapidly, with much greater specificity, and with greater sensitivity. The interface or probe provides a means whereby large and/or polar molecules in complex mixtures to be completely characterized. The preferred embodiment of the probe utilizes a double capillary tip which allows the probe tip to be continually wetted by the buffer, which provides for increased heat dissipation, and results in a continually operating interface which is more durable and electronically stable than the illustrated single capillary tip probe interface. 8 figs.

  19. Electrophoresis-mass spectrometry probe

    DOEpatents

    Andresen, Brian D.; Fought, Eric R.

    1987-01-01

    The invention involves a new technique for the separation of complex mixtures of chemicals, which utilizes a unique interface probe for conventional mass spectrometers which allows the electrophoretically separated compounds to be analyzed in real-time by a mass spectrometer. This new chemical analysis interface, which couples electrophoresis with mass spectrometry, allows complex mixtures to be analyzed very rapidly, with much greater specificity, and with greater sensitivity. The interface or probe provides a means whereby large and/or polar molecules in complex mixtures to be completely characterized. The preferred embodiment of the probe utilizes a double capillary tip which allows the probe tip to be continually wetted by the buffer, which provides for increased heat dissipation, and results in a continually operating interface which is more durable and electronically stable than the illustrated single capillary tip probe interface.

  20. Analysis of fission gas release kinetics by on-line mass spectrometry

    SciTech Connect

    Zerega, Y.; Reynard-Carette, C.; Parrat, D.; Carette, M.; Brkic, B.; Lyoussi, A.; Bignan, G.; Janulyte, A.; Andre, J.; Pontillon, Y.; Ducros, G.; Taylor, S.

    2011-07-01

    The release of fission gas (Xe and Kr) and helium out of nuclear fuel materials in normal operation of a nuclear power reactor can constitute a strong limitation of the fuel lifetime. Moreover, radioactive isotopes of Xe and Kr contribute significantly to the global radiological source term released in the primary coolant circuit in case of accidental situations accompanied by fuel rod loss of integrity. As a consequence, fission gas release investigation is of prime importance for the nuclear fuel cycle economy, and is the driven force of numerous R and D programs. In this domain, for solving current fuel behavior understanding issues, preparing the development of new fuels (e.g. for Gen IV power systems) and for improving the modeling prediction capability, there is a marked need for innovations in the instrumentation field, mainly for: . Quantification of very low fission gas concentrations, released from fuel sample and routed in sweeping lines. Monitoring of quick gas release variations by quantification of elementary release during a short period of time. Detection of a large range of atomic masses (e.g. H{sub 2}, HT, He, CO, CO{sub 2}, Ne, Ar, Kr, Xe), together with a performing separation of isotopes for Xe and Kr elements. Coupling measurement of stable and radioactive gas isotopes, by using in parallel mass spectrometry and gamma spectrometry techniques. To fulfill these challenging needs, a common strategy for analysis equipment implementation has been set up thanks to a recently launched collaboration between the CEA and the Univ. of Provence, with the technological support of the Liverpool Univ.. It aims at developing a chronological series of mass spectrometer devices based upon mass filter and 2D/3D ion traps with Fourier transform operating mode and having increasing levels of performances to match the previous challenges for out-of pile and in-pile experiments. The final objective is to install a high performance online mass spectrometer coupled to

  1. Structural determination of intact proteins using mass spectrometry

    DOEpatents

    Kruppa, Gary; Schoeniger, Joseph S.; Young, Malin M.

    2008-05-06

    The present invention relates to novel methods of determining the sequence and structure of proteins. Specifically, the present invention allows for the analysis of intact proteins within a mass spectrometer. Therefore, preparatory separations need not be performed prior to introducing a protein sample into the mass spectrometer. Also disclosed herein are new instrumental developments for enhancing the signal from the desired modified proteins, methods for producing controlled protein fragments in the mass spectrometer, eliminating complex microseparations, and protein preparatory chemical steps necessary for cross-linking based protein structure determination.Additionally, the preferred method of the present invention involves the determination of protein structures utilizing a top-down analysis of protein structures to search for covalent modifications. In the preferred method, intact proteins are ionized and fragmented within the mass spectrometer.

  2. Trapping of intense light in hollow shell

    SciTech Connect

    Luan, Shixia; Yu, Wei; Yu, M. Y.; Weng, Suming; Wang, Jingwei; Xu, Han; Zhuo, Hongbin; Wong, A. Y.

    2015-09-15

    A small hollow shell for trapping laser light is proposed. Two-dimensional particle-in-cell simulation shows that under appropriate laser and plasma conditions a part of the radiation fields of an intense short laser pulse can enter the cavity of a small shell through an over-critical density plasma in an adjacent guide channel and become trapped. The trapped light evolves into a circulating radial wave pattern until its energy is dissipated.

  3. Measurements of PM Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Measurements of PM Traps 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentantion: West Virginia University PDF icon 2004deerclark.pdf More Documents & Publications ...

  4. Cavity sideband cooling of trapped molecules

    SciTech Connect

    Kowalewski, Markus; Vivie-Riedle, Regina de [Department of Chemistry, Ludwig-Maximilian-Universitaet, D-81377 Munich (Germany); Morigi, Giovanna [Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); Theoretische Physik, Universitaet des Saarlandes, D-66041 Saarbruecken (Germany); Pinkse, Pepijn W. H. [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500AE Enschede (Netherlands)

    2011-09-15

    The efficiency of cavity sideband cooling of trapped molecules is theoretically investigated for the case in which the infrared transition between two rovibrational states is used as a cycling transition. The molecules are assumed to be trapped either by a radiofrequency or optical trapping potential, depending on whether they are charged or neutral, and confined inside a high-finesse optical resonator that enhances radiative emission into the cavity mode. Using realistic experimental parameters and COS as a representative molecular example, we show that in this setup, cooling to the trap ground state is feasible.

  5. Compact imaging spectrometer utilizing immersed gratings

    DOEpatents

    Chrisp, Michael P.; Lerner, Scott A.; Kuzmenko, Paul J.; Bennett, Charles L.

    2007-07-03

    A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, means for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the means for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the means for receiving the light and the means for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light to the means for receiving the light, and the means for receiving the light directs the light to the detector array.

  6. Associated Particle Tagging (APT) in Magnetic Spectrometers

    SciTech Connect

    Jordan, David V.; Baciak, James E.; Stave, Sean C.; Chichester, David; Dale, Daniel; Kim, Yujong; Harmon, Frank

    2012-10-16

    Summary In Brief The Associated Particle Tagging (APT) project, a collaboration of Pacific Northwest National Laboratory (PNNL), Idaho National Laboratory (INL) and the Idaho State University (ISU)/Idaho Accelerator Center (IAC), has completed an exploratory study to assess the role of magnetic spectrometers as the linchpin technology in next-generation tagged-neutron and tagged-photon active interrogation (AI). The computational study considered two principle concepts: (1) the application of a solenoidal alpha-particle spectrometer to a next-generation, large-emittance neutron generator for use in the associated particle imaging technique, and (2) the application of tagged photon beams to the detection of fissile material via active interrogation. In both cases, a magnetic spectrometer momentum-analyzes charged particles (in the neutron case, alpha particles accompanying neutron generation in the D-T reaction; in the tagged photon case, post-bremsstrahlung electrons) to define kinematic properties of the relevant neutral interrogation probe particle (i.e. neutron or photon). The main conclusions of the study can be briefly summarized as follows: Neutron generator: • For the solenoidal spectrometer concept, magnetic field strengths of order 1 Tesla or greater are required to keep the transverse size of the spectrometer smaller than 1 meter. The notional magnetic spectrometer design evaluated in this feasibility study uses a 5-T magnetic field and a borehole radius of 18 cm. • The design shows a potential for 4.5 Sr tagged neutron solid angle, a factor of 4.5 larger than achievable with current API neutron-generator designs. • The potential angular resolution for such a tagged neutron beam can be less than 0.5o for modest Si-detector position resolution (3 mm). Further improvement in angular resolution can be made by using Si-detectors with better position resolution. • The report documents several features of a notional generator design incorporating the

  7. Neutron spectrometer for improved SNM search.

    SciTech Connect

    Vance, Andrew L.; Aigeldinger, Georg

    2007-03-01

    With the exception of large laboratory devices with very low sensitivities, a neutron spectrometer have not been built for fission neutrons such as those emitted by special nuclear materials (SNM). The goal of this work was to use a technique known as Capture Gated Neutron Spectrometry to develop a solid-state device with this functionality. This required modifications to trans-stilbene, a known solid-state scintillator. To provide a neutron capture signal we added lithium to this material. This unique triggering signal allowed identification of neutrons that lose all of their energy in the detector, eliminating uncertainties that arise due to partial energy depositions. We successfully implemented a capture gated neutron spectrometer and were able to distinguish an SNM like fission spectrum from a spectrum stemming from a benign neutron source.

  8. Imaging spectrometer wide field catadioptric design

    DOEpatents

    Chrisp; Michael P.

    2008-08-19

    A wide field catadioptric imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The catadioptric design has zero Petzval field curvature. The imaging spectrometer comprises an entrance slit for transmitting light, a system with a catadioptric lens and a dioptric lens for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through the system for receiving the light to the detector array.

  9. Frequency-feedback cavity enhanced spectrometer

    DOEpatents

    Hovde, David Christian; Gomez, Anthony

    2015-08-18

    A spectrometer comprising an optical cavity, a light source capable of producing light at one or more wavelengths transmitted by the cavity and with the light directed at the cavity, a detector and optics positioned to collect light transmitted by the cavity, feedback electronics causing oscillation of amplitude of the optical signal on the detector at a frequency that depends on cavity losses, and a sensor measuring the oscillation frequency to determine the cavity losses.

  10. Time Dispersive Spectrometer Using Digital Switching Means

    DOEpatents

    Tarver, III, Edward E.; Siems, William F.

    2004-09-07

    Methods and apparatus are described for time dispersive spectroscopy. In particular, a modulated flow of ionized molecules of a sample are introduced into a drift region of an ion spectrometer. The ions are subsequently detected by an ion detector to produce an ion detection signal. The ion detection signal can be modulated to obtain a signal useful in assaying the chemical constituents of the sample.

  11. The GRETINA Spectrometer.docx.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    GRETINA Spectrometer GRETINA is a first-generation, HPGe-based, gamma-ray tracking detector. It uses highly segmented Ge crystals to provide position and energy information on each gamma-ray interaction point. This capability enables precise event-by-event Doppler correction of events from the position of the first interaction point, which allows the array to maintain spectroscopic resolution for sources with high recoil velocity. It also allows GRETINA to track the path of the incident

  12. Porous materials with pre-designed single-molecule traps for CO2 selective adsorption

    SciTech Connect

    Li, JR; Yu, JM; Lu, WG; Sun, LB; Sculley, J; Balbuena, PB; Zhou, HC

    2013-02-26

    Despite tremendous efforts, precise control in the synthesis of porous materials with pre-designed pore properties for desired applications remains challenging. Newly emerged porous metal-organic materials, such as metal-organic polyhedra and metal-organic frameworks, are amenable to design and property tuning, enabling precise control of functionality by accurate design of structures at the molecular level. Here we propose and validate, both experimentally and computationally, a precisely designed cavity, termed a 'single-molecule trap', with the desired size and properties suitable for trapping target CO2 molecules. Such a single-molecule trap can strengthen CO2-host interactions without evoking chemical bonding, thus showing potential for CO2 capture. Molecular single-molecule traps in the form of metal-organic polyhedra are designed, synthesised and tested for selective adsorption of CO2 over N-2 and CH4, demonstrating the trapping effect. Building these pre-designed single-molecule traps into extended frameworks yields metal-organic frameworks with efficient mass transfer, whereas the CO2 selective adsorption nature of single-molecule traps is preserved.

  13. Progress on the Fabrication and Testing of the MICE Spectrometer Solenoids

    SciTech Connect

    Virostek, Steve; Green, M.A.; Li, Derun; Zisman, Michael

    2009-05-19

    The Muon Ionization Cooling Experiment (MICE) is an international collaboration that will demonstrate ionization cooling in a section of a realistic cooling channel using a muon beam at Rutherford Appleton Laboratory (RAL) in the UK. At each end of the cooling channel a spectrometer solenoid magnet consisting of five superconducting coils will provide a 4 tesla uniform field region. The scintillating fiber tracker within the magnet bore will measure the muon beam emittance as it enters and exits the cooling channel. The 400 mm diameter warm bore, 3 meter long magnets incorporate a cold mass consisting of two coil sections wound on a single aluminum mandrel: a three-coil spectrometer magnet and a two-coil section that matches the solenoid uniform field into the MICE cooling channel. The fabrication of the first of two spectrometer solenoids has been completed, and preliminary testing of the magnet is nearly complete. The key design features of the spectrometer solenoid magnets are presented along with a summary of the progress on the training and testing of the first magnet.

  14. Single event mass spectrometry

    DOEpatents

    Conzemius, Robert J.

    1990-01-16

    A means and method for single event time of flight mass spectrometry for analysis of specimen materials. The method of the invention includes pulsing an ion source imposing at least one pulsed ion onto the specimen to produce a corresponding emission of at least one electrically charged particle. The emitted particle is then dissociated into a charged ion component and an uncharged neutral component. The ion and neutral components are then detected. The time of flight of the components are recorded and can be used to analyze the predecessor of the components, and therefore the specimen material. When more than one ion particle is emitted from the specimen per single ion impact, the single event time of flight mass spectrometer described here furnis This invention was made with Government support under Contract No. W-7405-ENG82 awarded by the Department of Energy. The Government has certain rights in the invention.

  15. Determination of the direct double- β -decay Q value of Zr 96 and atomic masses of Zr 90 - 92 , 94 , 96 and Mo 92 , 94 - 98 , 100

    DOE PAGES [OSTI]

    Gulyuz, K.; Ariche, J.; Bollen, G.; Bustabad, S.; Eibach, M.; Izzo, C.; Novario, S. J.; Redshaw, M.; Ringle, R.; Sandler, R.; et al

    2015-05-06

    Experimental searches for neutrinoless double-β decay offer one of the best opportunities to look for physics beyond the standard model. Detecting this decay would confirm the Majorana nature of the neutrino, and a measurement of its half-life can be used to determine the absolute neutrino mass scale. Important to both tasks is an accurate knowledge of the Q value of the double-β decay. The LEBIT Penning trap mass spectrometer was used for the first direct experimental determination of the ⁹⁶Zr double-β decay Q value: Qββ=3355.85(15) keV. This value is nearly 7 keV larger than the 2012 Atomic Mass Evaluation [M.more » Wang et al., Chin. Phys. C 36, 1603 (2012)] value and one order of magnitude more precise. The 3-σ shift is primarily due to a more accurate measurement of the ⁹⁶Zr atomic mass: m(⁹⁶Zr)=95.90827735(17) u. Using the new Q value, the 2νββ-decay matrix element, |M2ν|, is calculated. Improved determinations of the atomic masses of all other zirconium (90-92,94,96Zr) and molybdenum (92,94-98,100Mo) isotopes using both ¹²C₈ and ⁸⁷Rb as references are also reported.« less

  16. Compact catadioptric imaging spectrometer utilizing reflective grating

    DOEpatents

    Lerner, Scott A.

    2005-12-27

    An imaging spectrometer apparatus comprising an entrance slit for directing light, a light means for receiving the light and directing the light, a grating that receives the light from the light means and defracts the light back onto the light means which focuses the light, and a detector that receives the focused light. In one embodiment the light means is a rotationally symmetric ZNSE aspheric lens. In another embodiment the light means comprises two ZNSE aspheric lenses that are coaxial. In another embodiment the light means comprises an aspheric mirror and a ZNSE aspheric lens.

  17. Micro-optical-mechanical system photoacoustic spectrometer

    DOEpatents

    Kotovsky, Jack; Benett, William J.; Tooker, Angela C.; Alameda, Jennifer B.

    2013-01-01

    All-optical photoacoustic spectrometer sensing systems (PASS system) and methods include all the hardware needed to analyze the presence of a large variety of materials (solid, liquid and gas). Some of the all-optical PASS systems require only two optical-fibers to communicate with the opto-electronic power and readout systems that exist outside of the material environment. Methods for improving the signal-to-noise are provided and enable mirco-scale systems and methods for operating such systems.

  18. Dual waveband compact catadioptric imaging spectrometer

    DOEpatents

    Chrisp, Michael P.

    2012-12-25

    A catadioptric dual waveband imaging spectrometer that covers the visible through short-wave infrared, and the midwave infrared spectral regions, dispersing the visible through shortwave infrared with a zinc selenide grating and midwave infrared with a sapphire prism. The grating and prism are at the cold stop position, enabling the pupil to be split between them. The spectra for both wavebands are focused onto the relevant sections of a single dual waveband detector. Spatial keystone distortion is controlled to less than one tenth of a pixel over the full wavelength range, facilitating the matching of the spectra in the midwave infrared with the shorter wavelength region.

  19. Lead Slowing Down Spectrometer Status Report

    SciTech Connect

    Warren, Glen A.; Anderson, Kevin K.; Bonebrake, Eric; Casella, Andrew M.; Danon, Yaron; Devlin, M.; Gavron, Victor A.; Haight, R. C.; Imel, G. R.; Kulisek, Jonathan A.; O'Donnell, J. M.; Weltz, Adam

    2012-06-07

    This report documents the progress that has been completed in the first half of FY2012 in the MPACT-funded Lead Slowing Down Spectrometer project. Significant progress has been made on the algorithm development. We have an improve understanding of the experimental responses in LSDS for fuel-related material. The calibration of the ultra-depleted uranium foils was completed, but the results are inconsistent from measurement to measurement. Future work includes developing a conceptual model of an LSDS system to assay plutonium in used fuel, improving agreement between simulations and measurement, design of a thorium fission chamber, and evaluation of additional detector techniques.

  20. Conceptual design of a Disk Chopper Spectrometer

    SciTech Connect

    Copley, J.R.D.

    1997-09-01

    We describe methods that we have used for the conceptual design of the Disk Chopper Spectrometer at the Cold Neutron Research Facility, National Institute of Standards and Technology. Most of the discussion concerns the multiple chopper system. No single design method is best in every situation. We believe that an analytical approach is preferable, whenever possible. Graphical methods of expressing problems have been very instructive. We have also found it useful, and occasionally invaluable, to cross-check results obtained using different methods, such as analytical integration and ray-tracing.

  1. MPS (Multiparticle Spectrometer) data acquisition software system

    SciTech Connect

    Saulys, A.C.; Etkin, A.; Foley, K.J.; Hackenburg, R.W.; Longacre, R.S.; Love, W.A.; Morris, T.W.; Platner, E.D.; Lindenbaum, S.J.; Chan, C.S.

    1989-04-04

    A description of the software for a FASTBUS based data acquisition system in use at the Brookhaven National Laboratory Multiparticle Spectrometer is presented. Data reading and formatting is done by the SLAC Scanner Processors (SSP's) resident in the FASTBUS system. A multiprocess software system on VAX computers is used to communicate with the SSP's, record the data, and monitor on-line the progress of high energy and heavy ion experiments. The structure and the performance of this system are discussed. 4 refs., 1 fig.

  2. 140 GHz pulsed Fourier transform microwave spectrometer

    DOEpatents

    Kolbe, W.F.; Leskovar, B.

    1985-07-29

    A high frequency energy pulsing system suitable for use in a pulsed microwave spectrometer, including means for generating a high frequency carrier signal, and means for generating a low frequency modulating signal. The carrier signal is continuously fed to a modulator and the modulating signal is fed through a pulse switch to the modulator. When the pulse switch is on, the modulator will produce sideband signals above and below the carrier signal frequency. A frequency-responsive device is tuned to one of the sideband signals and sway from the carrier frequency so that the high frequency energization of the frequency-responsive device is controlled by the pulse switch.

  3. Photoacoustic Soot Spectrometer (PASS) Instrument Handbook

    SciTech Connect

    Dubey, M; Springston, S; Koontz, A; Aiken, A

    2013-01-17

    The photoacoustic soot spectrometer (PASS) measures light absorption by aerosol particles. As the particles pass through a laser beam, the absorbed energy heats the particles and in turn the surrounding air, which sets off a pressure wave that can be detected by a microphone. The PASS instruments deployed by ARM can also simultaneously measure the scattered laser light at three wavelengths and therefore provide a direct measure of the single-scattering albedo. The Operator Manual for the PASS-3100 is included here with the permission of Droplet Measurement Technologies, the instruments manufacturer.

  4. Ion mobility spectrometer with virtual aperture grid

    DOEpatents

    Pfeifer, Kent B. (Los Lunas, NM); Rumpf, Arthur N. (Albuquerque, NM)

    2010-11-23

    An ion mobility spectrometer does not require a physical aperture grid to prevent premature ion detector response. The last electrodes adjacent to the ion collector (typically the last four or five) have an electrode pitch that is less than the width of the ion swarm and each of the adjacent electrodes is connected to a source of free charge, thereby providing a virtual aperture grid at the end of the drift region that shields the ion collector from the mirror current of the approaching ion swarm. The virtual aperture grid is less complex in assembly and function and is less sensitive to vibrations than the physical aperture grid.

  5. The Paul Trap Simulator Experiment (PTSX) | Princeton Plasma...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The Paul Trap Simulator Experiment (PTSX) The Paul Trap Simulator Experiment (PTSX) at the U.S. Department of Energy's Princeton Plasma Physics Laboratory doesn't trap people named...

  6. Ultra-high-mass mass spectrometry with charge discrimination using cryogenic detectors

    DOEpatents

    Frank, Matthias; Mears, Carl A.; Labov, Simon E.; Benner, W. Henry

    1999-01-01

    An ultra-high-mass time-of-flight mass spectrometer using a cryogenic particle detector as an ion detector with charge discriminating capabilities. Cryogenic detectors have the potential for significantly improving the performance and sensitivity of time-of-flight mass spectrometers, and compared to ion multipliers they exhibit superior sensitivity for high-mass, slow-moving macromolecular ions and can be used as "stop" detectors in time-of-flight applications. In addition, their energy resolving capability can be used to measure the charge state of the ions. Charge discrimination is very valuable in all time-of-flight mass spectrometers. Using a cryogenically-cooled Nb-Al.sub.2 O.sub.3 -Nb superconductor-insulator-superconductor (SIS) tunnel junction (STJ) detector operating at 1.3 K as an ion detector in a time-of-flight mass spectrometer for large biomolecules it was found that the STJ detector has charge discrimination capabilities. Since the cryogenic STJ detector responds to ion energy and does not rely on secondary electron production, as in the conventionally used microchannel plate (MCP) detectors, the cryogenic detector therefore detects large molecular ions with a velocity-independent efficiency approaching 100%.

  7. Production and Trapping of Ultracold Polar Molecules

    SciTech Connect

    David, DeMille

    2015-04-21

    We report a set of experiments aimed at the production and trapping of ultracold polar molecules. We begin with samples of laser-cooled and trapped Rb and Cs atoms, and bind them together to form polar RbCs molecules. The binding is accomplished via photoassociation, which uses a laser to catalyze the sticking process. We report results from investigation of a new pathway for photoassociation that can produce molecules in their absolute ground state of vibrational and rotational motion. We also report preliminary observations of collisions between these ground-state molecules and co-trapped atoms.

  8. NAC 503 - Hunting, Fishing and Trapping | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Fishing and TrappingLegal Abstract These code sections outline the protective measures and restrictions on hunting, fishing, and trapping in the state of Nevada. Published...

  9. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine ...

  10. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of ...

  11. Bear Trap Hot Spring Pool & Spa Low Temperature Geothermal Facility...

    OpenEI (Open Energy Information) [EERE & EIA]

    Trap Hot Spring Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Bear Trap Hot Spring Pool & Spa Low Temperature Geothermal Facility Facility Bear...

  12. Modeling the Regeneration Chemistry of Lean NOx Traps | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored ...

  13. Charge Trapping in High Efficiency Alternating Copolymers: Implication...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Charge Trapping in High Efficiency Alternating Copolymers: Implications in Organic Photovoltaic Device Efficiency Home > Research > ANSER Research Highlights > Charge Trapping in ...

  14. Inspect and Repair Steam Traps, Energy Tips: STEAM, Steam Tip...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... There are four basic ways to test steam traps: temperature, sound, visual, and electronic. Recommended Steam Trap Testing Intervals * High-Pressure (150 psig and above): Weekly to ...

  15. A Wide Field of View Plasma Spectrometer

    DOE PAGES [OSTI]

    Skoug, Ruth M.; Funsten, Herbert O.; Moebius, Eberhard; Harper, Ron W.; Kihara, Keith H.; Bower, Jonathan S.

    2016-07-23

    Here we present a fundamentally new type of space plasma spectrometer, the wide field of view plasma spectrometer, whose field of view is >1.25π ster using fewer resources than traditional methods. The enabling component is analogous to a pinhole camera with an electrostatic energy-angle filter at the image plane. Particle energy-per-charge is selected with a tunable bias voltage applied to the filter plate relative to the pinhole aperture plate. For a given bias voltage, charged particles from different directions are focused by different angles to different locations. Particles with appropriate locations and angles can transit the filter plate and aremore » measured using a microchannel plate detector with a position-sensitive anode. Full energy and angle coverage are obtained using a single high-voltage power supply, resulting in considerable resource savings and allowing measurements at fast timescales. Lastly, we present laboratory prototype measurements and simulations demonstrating the instrument concept and discuss optimizations of the instrument design for application to space measurements.« less

  16. Electro-optic Phase Grating Streak Spectrometer

    SciTech Connect

    Goldin, F. J.

    2012-08-02

    The electro-optic phase grating streak spectrometer (EOPGSS) generates a time-resolved spectra equivalent to that obtained with a conventional spectrometer/streak camera combination, but without using a streak camera (by far the more expensive and problematic component of the conventional system). The EOPGSS is based on a phase, rather than an amplitude grating. Further, this grating is fabricated of electro-optic material such as, for example, KD*P, by either etching grooves into an E-O slab, or by depositing lines of the E-O material onto an optical flat. An electric field normal to the grating alters the material’s index of refraction and thus affects a shift (in angle) of the output spectrum. Ramping the voltage streaks the spectrum correspondingly. The streak and dispersion directions are the same, so a second (static, conventional) grating disperses the spectrum in the orthogonal direction to prevent different wavelengths from “overwriting” each other. Because the streaking is done by the grating, the streaked output spectrum is recorded with a time-integrating device, such as a CCD. System model, typical design, and performance expectations will be presented.

  17. What Caused the Lead burn-out in Spectrometer Magnet 2B

    SciTech Connect

    Green, Michael A

    2010-11-29

    The spectrometer solenoids are supposed to be the first magnets installed in the MICE Cooling Channel. The results of the test of Spectrometer Magnet 2B are reported in a previous MICE Note. Magnet 2B was tested with all five coils connected in series. The magnet failed because a lead to coil M2 failed before it could be trained to its full design current of 275 A. First, this report describes the condition of the magnet when the lead failure occurred. The lead that failed was between the cold mass feed-through and the heavy lead that connected to coil M2 and the quench protection diodes. It is believed that the lead failed because the minimum propagation zone (MPZ) length was too short. The quench was probably triggered by lead motion in the field external to the magnet center coil. The effect of heat transfer on quench propagation and MPZ length is discussed. The MPZ length is compared for a number of cases that apply to the spectrometer solenoid 2B as built and as it has been repaired. The required heat transfer coefficient for cryogenic stability and the quench propagation velocity along the leads are compared for various parts of the Magnet leads inside the cold mass cryostat. The effect of the insulation on leads on heat transfer is and stability is discussed.

  18. Precipitation and Hydrology Experiment Counter-Flow Spectrometer and

    Office of Scientific and Technical Information (OSTI)

    Impactor Field Campaign Report (Program Document) | SciTech Connect Precipitation and Hydrology Experiment Counter-Flow Spectrometer and Impactor Field Campaign Report Citation Details In-Document Search Title: Precipitation and Hydrology Experiment Counter-Flow Spectrometer and Impactor Field Campaign Report The U.S. Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Climate Research Facility Aerial Facility (ARM AAF) counter-flow spectrometer and impactor (CSI) probe was

  19. Wide swath imaging spectrometer utilizing a multi-modular design

    DOEpatents

    Chrisp, Michael P.

    2010-10-05

    A wide swath imaging spectrometer utilizing an array of individual spectrometer modules in the telescope focal plane to provide an extended field of view. The spectrometer modules with their individual detectors are arranged so that their slits overlap with motion on the scene providing contiguous spatial coverage. The number of modules can be varied to take full advantage of the field of view available from the telescope.

  20. Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST)

    Office of Scientific and Technical Information (OSTI)

    Handbook (Dataset) | Data Explorer Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Handbook Title: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Handbook The Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST), like the AERI, measures infrared spectral zenith radiance at high spectral resolution. Authors: Flynn,Connor ; Mendoza,Albert Publication Date: 2016-03-01 OSTI Identifier: 1253919 DOE Contract Number:

  1. OLYMPEX Counterflow Spectrometer and Impactor Field Campaign Report

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect OLYMPEX Counterflow Spectrometer and Impactor Field Campaign Report Citation Details In-Document Search Title: OLYMPEX Counterflow Spectrometer and Impactor Field Campaign Report The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility's ARM Aerial Facility (AAF) Counterflow Spectrometer and Impactor (CSI) probe was flown on the University of North Dakota Cessna Citation research aircraft during the Olympic

  2. Mobility-Selected Ion Trapping and Enrichment Using Structures for Lossless Ion Manipulations

    DOE PAGES [OSTI]

    Chen, Tsung-Chi; Ibrahim, Yehia M.; Webb, Ian K.; Garimella, Sandilya V. B.; Zhang, Xing; Hamid, Ahmed M.; Deng, Liulin; Karnesky, William E.; Prost, Spencer A.; Sandoval, Jeremy A.; et al

    2016-01-11

    The integration of ion mobility spectrometry (IMS) with mass spectrometry (MS) and the ability to trap ions in IMS-MS measurements is of great importance for performing reactions, accumulating ions, and increasing analytical measurement sensitivity. The development of Structures for Lossless Ion Manipulations (SLIM) offers the potential for ion manipulations in a more reliable and cost-effective manner, while opening opportunities for much more complex sequences of manipulations. Here, we demonstrate an ion separation and trapping module and a method based upon SLIM that consists of a linear mobility ion drift region, a switch/tee and a trapping region that allows the isolationmore » and accumulation of mobility-separated species. The operation and optimization of the SLIM switch/tee and trap are described and demonstrated for the enrichment of the low abundance ions. Lastly, we observed a linear increase in ion intensity with the number of trapping/accumulation events using the SLIM trap, illustrating its potential for enhancing the sensitivity of low abundance or targeted species.« less

  3. Micro-optical-mechanical system photoacoustic spectrometer (Patent...

    Office of Scientific and Technical Information (OSTI)

    All-optical photoacoustic spectrometer sensing systems (PASS system) and methods include all the hardware needed to analyze the presence of a large variety of materials (solid, ...

  4. Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron...

    Office of Scientific and Technical Information (OSTI)

    Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron Spectroscopy Resources with Additional Information Bertram Brockhouse Courtesy of McMaster University Bertram...

  5. Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron Spectroscopy Resources with Additional Information Bertram Brockhouse Courtesy of McMaster University Bertram ...

  6. Shale gas is natural gas trapped inside

    Energy.gov [DOE] (indexed site)

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary rocks that can be rich sources of petroleum and natural gas. Just a few years ago, much of ...

  7. Trapped Ion Optical Clocks at NPL

    SciTech Connect

    Margolis, H. S.; Barwood, G. P.; Hosaka, K.; Klein, H. A.; Lea, S. N.; Walton, B. R.; Webster, S. A.; Gill, P.; Huang, G.; Stannard, A.

    2006-11-07

    Forbidden transitions in single laser-cooled trapped ions provide highly stable and accurate references for optical frequency standards. This paper describes recent progress on strontium and ytterbium ion optical frequency standards under development at NPL.

  8. Protection #2: Trap and Remove Sediment

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Trap and Remove Sediment Protection #2: Trap and Remove Sediment The 3 Protections = Defense in Depth August 1, 2013 Sediment behind LA Canyon weir is sampled and excavated regularly. As of 2012, no sediment required disposal as hazardous or radioactive waste. Sediment behind LA Canyon weir is sampled and excavated regularly. As of 2012, no sediment required disposal as hazardous or radioactive waste. The 3 Protections Protection #1: Remove the source of contamination Protection #2: Stabilize,

  9. Solid state NMR spectrometer. Final project report

    SciTech Connect

    Jensen, C.M.

    1997-11-01

    The new Varian Unity INOVA 400 is being utilized on a daily basis. The instrument is available 24 hours a day seven days a week for scheduled experiments. In addition, a limited amount of time is available on a walk-in basis for researchers on the project. The instrument has operated with no down time since the end of the Varian installation process. Minor problems have been corrected by the facility staff (spent fused, malfunctioning boards and components and interrupted data transfers). Most of the initial problems were covered under the warrantee period. Since the end of this period there have been no major operational problems. This report discusses two research projects using the new spectrometer: dynamics of dihydrogen and alkane complexes of iridium and catalytic dehydrogenation by iridium hydride complexes.

  10. 140 GHz pulsed fourier transform microwave spectrometer

    DOEpatents

    Kolbe, William F.; Leskovar, Branko

    1987-01-01

    A high frequency energy pulsing system suitable for use in a pulsed microwave spectrometer (10), including means (11, 19) for generating a high frequency carrier signal, and means (12) for generating a low frequency modulating signal. The carrier signal is continuously fed to a modulator (20) and the modulating signal is fed through a pulse switch (23) to the modulator. When the pulse switch (23) is on, the modulator (20) will produce sideband signals above and below the carrier signal frequency. A frequency-responsive device (31) is tuned to one of the sideband signals and away from the carrier frequency so that the high frequency energization of the frequency-responsive device (31) is controlled by the pulse switch (23).

  11. 140 GHz pulsed Fourier transform microwave spectrometer

    DOEpatents

    Kolbe, W.F.; Leskovar, B.

    1987-10-27

    A high frequency energy pulsing system suitable for use in a pulsed microwave spectrometer, including means for generating a high frequency carrier signal, and means for generating a low frequency modulating signal is disclosed. The carrier signal is continuously fed to a modulator and the modulating signal is fed through a pulse switch to the modulator. When the pulse switch is on, the modulator will produce sideband signals above and below the carrier signal frequency. A frequency-responsive device is tuned to one of the sideband signals and away from the carrier frequency so that the high frequency energization of the frequency-responsive device is controlled by the pulse switch. 5 figs.

  12. Antihydrogen Trapped in the ALPHA Experiment

    ScienceCinema

    None

    2016-07-12

    In 2010 the ALPHA collaboration succeeded in trapping antihydrogen atoms for the first time.[i]  Stored antihydrogen promises to be a unique tool for making high precision measurements of the structure of this first anti-atom. Achieving this milestone presented several substantial experimental challenges and this talk will describe how they were overcome.   The unique design features of the ALPHA apparatus will be explained.[ii]  These allow a high intensity positron source and an antiproton imaging detector similar to the one used in the ATHENA[iii] experiment to be combined with an innovative magnet design of the anti-atom trap. This seeks to minimise the perturbations to trapped charged particles which may cause particle loss and heating[iv].   The diagnostic techniques used to measure the diameter, number, density, and temperatures of both plasmas will be presented as will the methods developed to actively compress and cool of both plasma species to sizes and temperatures [v],[vi], [vii] where trapping attempts with a reasonable chance of success can be tried.   The results of the successful trapping experiments will be outlined as well as some subsequent experiments to improve the trapping rate and storage time. [i] 'Trapped antihydrogen' G.B. Andresen et al., Nature 468, 673 (2010) [ii]'A Magnetic Trap for Antihydrogen Confinement' W. Bertsche et al., Nucl. Instr. Meth. Phys. Res. A566, 746 (2006) [iii] Production and detection of cold antihydrogen atoms M.Amoretti et al., Nature 419, 456 (2002). [iv]' Antihydrogen formation dynamics in a multipolar neutral anti-atom trap' G.B. Andresen et al., Phys. Lett. B 685, 141 (2010) [v]' Evaporative Cooling of Antiprotons to Cryogenic Temperatures',                                   G.B. Andresen et al. Phys. Rev. Lett 105, 013003 (2010) [vi]'Compression of Antiproton Clouds for Antihydrogen Trapping' G. B. Andresen et al. Phys. Rev. Lett 100, 203401 (2008) [vii]  'Autoresonant

  13. In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

    DOEpatents

    Braymen, Steven D.

    1996-06-11

    A method and apparatus for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization.

  14. Ion mobility spectrometer, spectrometer analyte detection and identification verification system, and method

    DOEpatents

    Atkinson, David A.

    2002-01-01

    Methods and apparatus for ion mobility spectrometry and analyte detection and identification verification system are disclosed. The apparatus is configured to be used in an ion mobility spectrometer and includes a plurality of reactant reservoirs configured to contain a plurality of reactants which can be reacted with the sample to form adducts having varying ion mobilities. A carrier fluid, such as air or nitrogen, is used to carry the sample into the spectrometer. The plurality of reactants are configured to be selectively added to the carrier stream by use inlet and outlet manifolds in communication with the reagent reservoirs, the reservoirs being selectively isolatable by valves. The invention further includes a spectrometer having the reagent system described. In the method, a first reactant is used with the sample. Following a positive result, a second reactant is used to determine whether a predicted response occurs. The occurrence of the second predicted response tends to verify the existence of a component of interest within the sample. A third reactant can also be used to provide further verification of the existence of a component of interest. A library can be established of known responses of compounds of interest with various reactants and the results of a specific multi-reactant survey of a sample can be compared against the library to determine whether a component detected in the sample is likely to be a specific component of interest.

  15. Characterization of trapped gas saturation and heterogeneity in core sampling using miscible-displacement experiments

    SciTech Connect

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  16. Spectroscopic Investigations of Highly Charged Ions using X-Ray Calorimeter Spectrometers

    SciTech Connect

    Thorn, D B

    2008-11-03

    Spectroscopy of K-shell transitions in highly charged heavy ions, like hydrogen-like uranium, has the potential to yield information about quantum electrodynamics (QED) in extremely strong nuclear fields as well as tests of the standard model, specifically parity violation in atomic systems. These measurements would represent the 'holy grail' in high-Z atomic spectroscopy. However, the current state-of-the-art detection schemes used for recording the K-shell spectra from highly charged heavy ions does not yet have the resolving power to be able to attain this goal. As such, to push the field of high-Z spectroscopy forward, new detectors must be found. Recently, x-ray calorimeter spectrometers have been developed that promise to make such measurements. In an effort to make the first steps towards attaining the 'holy grail', measurements have been performed with two x-ray calorimeter spectrometers (the XRS/EBIT and the ECS) designed and built at Goddard Space Flight Center in Greenbelt, MD. The calorimeter spectrometers have been used to record the K-shell spectra of highly charged ions produced in the SuperEBIT electron beam ion trap at Lawrence Livermore National Laboratory in Livermore, CA. Measurements performed with the XRS/EBIT calorimeter array found that the theoretical description of well-above threshold electron-impact excitation cross sections for hydrogen-like iron and nickel ions are correct. Furthermore, the first high-resolution spectrum of hydrogen-like through carbon-like praseodymium ions was recorded with a calorimeter. In addition, the new high-energy array on the EBIT Calorimeter Spectrometer (ECS) was used to resolve the K-shell x-ray emission spectrum of highly charged xenon ions, where a 40 ppm measurement of the energy of the K-shell resonance transition in helium-like xenon was achieved. This is the highest precision result, ever, for an element with such high atomic number. In addition, a first-of-its-kind measurement of the effect of the

  17. Multi-element Neutron Energy Spectrometer

    SciTech Connect

    Sanjoy Mukhopadhyay, Richard Maurer, Ronald Wolff, Stephen Mitchell, Alexis Reed

    2009-09-11

    In the area of nuclear radiological emergency response and preparedness applications, interest in neutron detection stems from several factors. Unlike gamma rays, which are abundant in nature and present serious difficulties in differentiating a signal from a changing background, whose values are location specific, neutrons are rare and nearly homogenous in spatial distribution. Additionally, many special nuclear materials (SNM) emit neutrons either directly by spontaneous fission or produce neutrons indirectly through (α, n) reactions in nearby light elements. Also of importance in detection scenarios is the fact that neutrons are not easily attenuated. Typically neutron detection is done by simply counting the low energy thermal neutrons by employing pressurized helium tubes operated at high voltages. Not much emphasis is put on determining the energy of the incident neutrons. However, critical information can be obtained by analyzing the neutron energy given off from radioactive materials. In the detection of an SNM, neutron energy information from an unknown source can be of paramount importance. We have modeled, designed, and prototyped multi-element neutron energy spectrometers that contain three to five pressurized helium tubes of dimensions 2" diam. x 10" in length. Each individual helium tube has a specific amount of high density plastic neutron moderators to slow down the incident energetic neutrons to an accurately estimated energy. A typical spectrometer is a set of moderator cylinders surrounding detectors that have high efficiency for detecting thermal neutrons. The larger the moderator, the higher the energy of incident neutrons for which the detector assembly has matched detection efficiency. If all the detectors are exposed to the same radiation field and the efficiency as a function of energy (response function) of each of the detectors is known, the neutron energy spectrum can be determined from the detector count rates. Monte Carlo simulation

  18. HEGRS: Mechanical design of a high-energy, gamma-ray spectrometer

    SciTech Connect

    Pedersen, K.B.

    1993-06-04

    A large, 3200-kg (7000-lb) gamma-ray spectrometer was designed to move in a 1500 arc with an arc accuracy of 0.50, and to move radially over a distance of 650 mm (25 in.). The entire structure is aluminum rather than steel because of the high neutron background. The two-layer support accommodates rapid, accurate positioning of the spectrometer in both the rotational and radial directions within 0.1 mm (0.004 in.). All movements and positioning are computer-controlled. The centerline deviation over the entire surface is 0.25 mm (0.0100 in.). The bottom layer, called the table, permits arc motion. The table is a baseplate consisting of two 3.6-m {times} 1.2-m (12-ft {times} 4-ft) cast-aluminum jig plates. The top layer, called the sled, is an aluminum plate 2.12-m {times} 1.22-m (83.38-in. {times} 48-in.) wide, which provides for radial motion. Due to the large mass of the spectrometer and the accurate positioning required, air pads are used to facilitate movement. Hydraulic brakes are applied when the detector is in its rest position to comply with the seismic requirements of the installation.

  19. Development of position-sensitive time-of-flight spectrometer for fission fragment research

    DOE PAGES [OSTI]

    Arnold, C. W.; Tovesson, F.; Meierbachtol, K.; Bredeweg, T.; Jandel, M.; Jorgenson, H. J.; Laptev, A.; Rusev, G.; Shields, D. W.; White, M.; et al

    2014-07-09

    A position-sensitive, high-resolution time-of-flight detector for fission fragments has been developed. The SPectrometer for Ion DEtermination in fission Research (SPIDER) is a 2E–2v spectrometer designed to measure the mass of light fission fragments to a single mass unit. The time pick-off detector pairs to be used in SPIDER have been tested with α-particles from 229Th and its decay chain and α-particles and spontaneous fission fragments from 252Cf. Each detector module is comprised of thin electron conversion foil, electrostatic mirror, microchannel plates, and delay-line anodes. Particle trajectories on the order of 700 mm are determined accurately to within 0.7 mm. Flightmore » times were measured with 250 ps resolution FWHM. Computed particle velocities are accurate to within 0.06 mm/ns corresponding to a precision of 0.5%. As a result, an ionization chamber capable of 400 keV energy resolution coupled with the velocity measurements described here will pave the way for modestly efficient measurements of light fission fragments with unit mass resolution.« less

  20. Signal enhancement using a switchable magnetic trap

    DOEpatents

    Beer, Neil Reginald

    2012-05-29

    A system for analyzing a sample including providing a microchannel flow channel; associating the sample with magnetic nanoparticles or magnetic polystyrene-coated beads; moving the sample with said magnetic nanoparticles or magnetic polystyrene-coated beads in the microchannel flow channel; holding the sample with the magnetic nanoparticles or magnetic polystyrene-coated beads in a magnetic trap in the microchannel flow channel; and analyzing the sample obtaining an enhanced analysis signal. An apparatus for analysis of a sample includes magnetic particles connected to the sample, a microchip, a flow channel in the microchip, a source of carrier fluid connected to the flow channel for moving the sample in the flow channel, an electromagnet trap connected to the flow line for selectively magnetically trapping the sample and the magnetic particles, and an analyzer for analyzing the sample.

  1. Screening the Hanford tanks for trapped gas

    SciTech Connect

    Whitney, P.

    1995-10-01

    The Hanford Site is home to 177 large, underground nuclear waste storage tanks. Hydrogen gas is generated within the waste in these tanks. This document presents the results of a screening of Hanford`s nuclear waste storage tanks for the presence of gas trapped in the waste. The method used for the screening is to look for an inverse correlation between waste level measurements and ambient atmospheric pressure. If the waste level in a tank decreases with an increase in ambient atmospheric pressure, then the compressibility may be attributed to gas trapped within the waste. In this report, this methodology is not used to estimate the volume of gas trapped in the waste. The waste level measurements used in this study were made primarily to monitor the tanks for leaks and intrusions. Four measurement devices are widely used in these tanks. Three of these measure the level of the waste surface. The remaining device measures from within a well embedded in the waste, thereby monitoring the liquid level even if the liquid level is below a dry waste crust. In the past, a steady rise in waste level has been taken as an indicator of trapped gas. This indicator is not part of the screening calculation described in this report; however, a possible explanation for the rise is given by the mathematical relation between atmospheric pressure and waste level used to support the screening calculation. The screening was applied to data from each measurement device in each tank. If any of these data for a single tank indicated trapped gas, that tank was flagged by this screening process. A total of 58 of the 177 Hanford tanks were flagged as containing trapped gas, including 21 of the 25 tanks currently on the flammable gas watch list.

  2. High resolving power spectrometer for beam analysis

    SciTech Connect

    Moshammer, H.W.; Spencer, J.E.

    1992-03-01

    We describe a system designed to analyze the high energy, closely spaced bunches from individual RF pulses. Neither a large solid angle nor momentum range is required so this allows characteristics that appear useful for other applications such as ion beam lithography. The spectrometer is a compact, double-focusing QBQ design whose symmetry allows the Quads to range between F or D with a correspondingly large range of magnifications, dispersion and resolving power. This flexibility insures the possibility of spatially separating all of the bunches along the focal plane with minimal transverse kicks and bending angle for differing input conditions. The symmetry of the system allows a simple geometric interpretationof the resolving power in terms of thin lenses and ray optics. We discuss the optics and the hardware that is proposed to measure emittance, energy, energy spread and bunch length for each bunch in an RF pulse train for small bunch separations. We also discuss how to use such measurements for feedback and feedforward control of these bunch characteristics as well as maintain their stability. 2 refs.

  3. Analysis of a magnetically trapped atom clock

    SciTech Connect

    Kadio, D.; Band, Y. B.

    2006-11-15

    We consider optimization of a rubidium atom clock that uses magnetically trapped Bose condensed atoms in a highly elongated trap, and determine the optimal conditions for minimum Allan variance of the clock using microwave Ramsey fringe spectroscopy. Elimination of magnetic field shifts and collisional shifts are considered. The effects of spin-dipolar relaxation are addressed in the optimization of the clock. We find that for the interstate interaction strength equal to or larger than the intrastate interaction strengths, a modulational instability results in phase separation and symmetry breaking of the two-component condensate composed of the ground and excited hyperfine clock levels, and this mechanism limits the clock accuracy.

  4. Entanglement of trapped-ion clock states

    SciTech Connect

    Haljan, P. C.; Lee, P. J.; Brickman, K-A.; Acton, M.; Deslauriers, L.; Monroe, C.

    2005-12-15

    A Moelmer-Soerensen entangling gate is realized for pairs of trapped {sup 111}Cd{sup +} ions using magnetic-field insensitive 'clock' states and an implementation offering reduced sensitivity to optical phase drifts. The gate is used to generate the complete set of four entangled states, which are reconstructed and evaluated with quantum-state tomography. An average target-state fidelity of 0.79 is achieved, limited by available laser power and technical noise. The tomographic reconstruction of entangled states demonstrates universal quantum control of two ion qubits, which through multiplexing can provide a route to scalable architectures for trapped-ion quantum computing.

  5. Thermal electric vapor trap arrangement and method

    DOEpatents

    Alger, Terry (Tracy, CA)

    1988-01-01

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself.

  6. Entanglement generation in planar Penning traps

    SciTech Connect

    Martins, Ana M.; Mendonca, J. T.; Guerreiro, A.; Vieira, V. R.

    2010-07-15

    We investigate the generation of entanglement between the axial degrees of freedom of electrons confined in separated locations in planar Penning traps. We show that there are two different sources of entanglement: one is related with the mechanism of switching on and off the electrical coupling between the two electrons, and the other is due to the two-quanta-transition term of the coupling interaction. We show that the degree of entanglement can be controlled by adjusting the strength of the coupling between the traps and the time of interaction. We show that the coupled electrons behave as a temporal active interferometer.

  7. Thermal electric vapor trap arrangement and method

    DOEpatents

    Alger, T.

    1988-03-15

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  8. Ball-grid array architecture for microfabricated ion traps

    SciTech Connect

    Guise, Nicholas D. Fallek, Spencer D.; Stevens, Kelly E.; Brown, K. R.; Volin, Curtis; Harter, Alexa W.; Amini, Jason M.; Higashi, Robert E.; Lu, Son Thai; Chanhvongsak, Helen M.; Nguyen, Thi A.; Marcus, Matthew S.; Ohnstein, Thomas R.; Youngner, Daniel W.

    2015-05-07

    State-of-the-art microfabricated ion traps for quantum information research are approaching nearly one hundred control electrodes. We report here on the development and testing of a new architecture for microfabricated ion traps, built around ball-grid array (BGA) connections, that is suitable for increasingly complex trap designs. In the BGA trap, through-substrate vias bring electrical signals from the back side of the trap die to the surface trap structure on the top side. Gold-ball bump bonds connect the back side of the trap die to an interposer for signal routing from the carrier. Trench capacitors fabricated into the trap die replace area-intensive surface or edge capacitors. Wirebonds in the BGA architecture are moved to the interposer. These last two features allow the trap die to be reduced to only the area required to produce trapping fields. The smaller trap dimensions allow tight focusing of an addressing laser beam for fast single-qubit rotations. Performance of the BGA trap as characterized with {sup 40}Ca{sup +} ions is comparable to previous surface-electrode traps in terms of ion heating rate, mode frequency stability, and storage lifetime. We demonstrate two-qubit entanglement operations with {sup 171}Yb{sup +} ions in a second BGA trap.

  9. Development of a High Resolution X-Ray Imaging Crystal Spectrometer

    Office of Scientific and Technical Information (OSTI)

    Development of a High Resolution X-Ray Imaging Crystal Spectrometer for Measurement of ... Development of a High Resolution X-Ray Imaging Crystal Spectrometer for ...

  10. Development of a High Resolution X-Ray Imaging Crystal Spectrometer...

    Office of Scientific and Technical Information (OSTI)

    Development of a High Resolution X-Ray Imaging Crystal Spectrometer for Measurement of ... Development of a High Resolution X-Ray Imaging Crystal Spectrometer for Measurement of ...

  11. Sulfate Storage and Stability on Common Lean NOx Trap Components

    SciTech Connect

    Ottinger, Nathan A; Toops, Todd J; Pihl, Josh A; Roop, Justin T; Choi, Jae-Soon; Partridge Jr, William P

    2012-01-01

    Components found in a commercial lean NO{sub x} trap have been studied in order to determine their impact on sulfate storage and release. A micro-reactor and a diffuse reflectance infrared Fourier transform spectrometer (DRIFTS) were used to compare components MgAl{sub 2}O{sub 4}, Pt/MgAl{sub 2}O{sub 4}, Pt/Al{sub 2}O{sub 3}, Pt/Ba/Al{sub 2}O{sub 3}, Pt/CeO{sub 2}-ZrO{sub 2}, and Pt/Ba/CeO{sub 2}-ZrO{sub 2}, as well as physical mixtures of Pt/Al{sub 2}O{sub 3} + MgAl{sub 2}O{sub 4} and Pt/Ba/CeO{sub 2}-ZrO{sub 2} + MgAl{sub 2}O{sub 4}. Desulfation temperature profiles as well as DRIFTS NO{sub x} and SO{sub x} storage spectra are presented for all components. This systematic approach highlighted the ability of the underlying support to impact sulfate stability, in particular when Ba was supported on ceria-zirconia rather than alumina the desulfation temperature decreased by 60-120 C. A conceptual model of sulfation progression on the ceria-zirconia support is proposed that explains the high uptake of sulfur and low temperature release when it is employed. It was also determined that the close proximity of platinum is not necessary for much of the sulfation and desulfation chemistry that occurs, as physical mixtures with platinum dispersed on only one phase displayed similar behavior to samples with platinum dispersed on both phases.

  12. Bucket-type steam traps removed in $82K retrofit

    SciTech Connect

    Poplett, J.

    1985-08-19

    A retrofit of 481 mostly failed steam traps at Martin Marietta's Aerospace Division should reduce steam costs by $70,000 and require little or no maintenance. Payback should occur within 14 months. The new traps include orifice, bellow-type thermostatic, and float-type traps that have few or no moving parts. Lack of maintenance was responsible for the poor performance of the bucket traps that were replaced, although manufacturers of the bucket traps disagree that replacement of certain parts is necessary every six months. The author describes the design and operation of each type of trap.

  13. Design Considerations for Passive Gamma-Ray Spectrometers

    SciTech Connect

    Smith, Leon E.; Swickard, Andrea R.; Heredia-Langner, Alejandro; Warren, Glen A.; Siciliano, Edward R.; Miller, Steven D.

    2005-10-01

    Passive gamma-ray spectrometers composed of attenuation filters and integrating detection materials provide important advantages for measurements in high-radiation environments and for long-term monitoring. Each of these applications has requirements that constrain the design of the instrument, such as incident energy range of interest, sensor size and weight, readout method and cost. In addition, the multitude of variable parameters in passive spectrometer design (e.g. attenuation filter material and thickness, integrating sensor type, numbers of pixels, reconstructed energy bin structure) results in a large design space to analyze. The development of generalized design optimization tools to interrogate this space and identify promising spectrometer designs are discussed, particularly the methods used to rapidly calculate system transfer functions and the search for suitable design evaluation metrics. Finally, specific examples of candidate spectrometer designs are provided, and preliminary measurements to validate the design tools are described.

  14. Diamond neutral particle spectrometer for fusion reactor ITER

    SciTech Connect

    Krasilnikov, V.; Amosov, V.; Kaschuck, Yu.; Skopintsev, D.

    2014-08-21

    A compact diamond neutral particle spectrometer with digital signal processing has been developed for fast charge-exchange atoms and neutrons measurements at ITER fusion reactor conditions. This spectrometer will play supplementary role for Neutral Particle Analyzer providing 10 ms time and 30 keV energy resolutions for fast particle spectra in non-tritium ITER phase. These data will also be implemented for independent studies of fast ions distribution function evolution in various plasma scenarios with the formation of a single fraction of high-energy ions. In tritium ITER phase the DNPS will measure 14 MeV neutrons spectra. The spectrometer with digital signal processing can operate at peak counting rates reaching a value of 10{sup 6} cps. Diamond neutral particle spectrometer is applicable to future fusion reactors due to its high radiation hardness, fast response and high energy resolution.

  15. Field Observation GoAmazon Neutral cluster Air Ion Spectrometer...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    of the Green Ocean Amazon: Neutral Cluster Air Ion Spectrometer (NAIS) Final Campaign ... DOESC-ARM-15-060 Field Observation of the Green Ocean Amazon: Neutral Cluster Air Ion ...

  16. Tunable light source for use in photoacoustic spectrometers

    DOEpatents

    Bisson, Scott E.; Kulp, Thomas J.; Armstrong, Karla M.

    2005-12-13

    The present invention provides a photoacoustic spectrometer that is field portable and capable of speciating complex organic molecules in the gas phase. The spectrometer has a tunable light source that has the ability to resolve the fine structure of these molecules over a large wavelength range. The inventive light source includes an optical parametric oscillator (OPO) having combined fine and coarse tuning. By pumping the OPO with the output from a doped-fiber optical amplifier pumped by a diode seed laser, the inventive spectrometer is able to speciate mixtures having parts per billion of organic compounds, with a light source that has a high efficiency and small size, allowing for portability. In an alternative embodiment, the spectrometer is scanned by controlling the laser wavelength, thus resulting in an even more compact and efficient design.

  17. A Spatially Resolving X-ray Crystal Spectrometer for Measurement...

    Office of Scientific and Technical Information (OSTI)

    A Spatially Resolving X-ray Crystal Spectrometer for Measurement of Ion-temperature and ... Citation Details In-Document Search Title: A Spatially Resolving X-ray Crystal ...

  18. Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

    SciTech Connect

    Jordan, I.; Huppert, M.; Wörner, H. J.; Brown, M. A.; Bokhoven, J. A. van

    2015-12-15

    A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

  19. ARM - Field Campaign - ASSIST: Atmospheric Sounder Spectrometer for

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Infrared Spectral Technology govCampaignsASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : ASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology 2008.07.08 - 2008.07.18 Lead Scientist : Michael Howard For data sets, see below. Abstract Goals of assist were to intercompare radiance spectra and profile retrievals

  20. Characterization of Plasma Membrane Proteins from Ovarian Cancer Cells Using Mass Spectrometry

    SciTech Connect

    Springer, David L.; Auberry, Deanna L.; Ahram, Mamoun; Adkins, Joshua N.; Feldhaus, Jane M.; Wahl, Jon H.; Wunsch, David M.; Rodland, Karin D.

    2003-01-01

    To determine how the repertoire of plasma membrane proteins change with disease state, specifically related to cancer, several methods for preparation of plasma membrane proteins were evaluated. Cultured cells derived from stage IV ovarian tumors were grown to 90% confluence and harvested in buffer containing CHAPS detergent. This preparation was centrifuged at low speed to remove insoluble cellular debris resulting in a crude homogenate. Glycosylated proteins in the crude homogenate were selectively enriched using lectin affinity chromatography. The crude homogenate and the lectin purified sample were prepared for mass spectrometric evaluation. The general procedure for protein identification began with trypsin digestion of protein fractions followed by separation by reversed phase liquid chromatography that was coupled directly to a conventional tandem mass spectrometer (i.e. LCQ ion trap). Mass and fragmentation data for the peptides were searched against a human proteome data base using the informatics program SEQUEST. Using this procedure 398 proteins were identified with high confidence, including receptors, membrane-associated ligands, proteases, phosphatases, as well as structural and adhesion proteins. Results indicate that lectin chromatography provides a select subset of proteins and that the number and quality of the identifications improve as does the confidence of the protein identifications for this subset. These results represent the first step in development of methods to separate and successfully identify plasma membrane proteins from advanced ovarian cancer cells. Further characterization of plasma membrane proteins will contribute to our understanding of the mechanisms underlying progression of this deadly disease and may lead to new targeted interventions as well as new biomarkers for diagnosis.

  1. Characterization of Plasma Membrane Proteins from Ovarian Cancer Cells Using Mass Spectrometry

    DOE PAGES [OSTI]

    Springer, David L.; Auberry, Deanna L.; Ahram, Mamoun; Adkins, Joshua N.; Feldhaus, Jane M.; Wahl, Jon H.; Wunschel, David S.; Rodland, Karin D.

    2004-01-01

    To determine how the repertoire of plasma membrane proteins change with disease state, specifically related to cancer, several methods for preparation of plasma membrane proteins were evaluated. Cultured cells derived from stage IV ovarian tumors were grown to 90% confluence and harvested in buffer containing CHAPS detergent. This preparation was centrifuged at low speed to remove insoluble cellular debris resulting in a crude homogenate. Glycosylated proteins in the crude homogenate were selectively enriched using lectin affinity chromatography. The crude homogenate and the lectin purified sample were prepared for mass spectrometric evaluation. The general procedure for protein identification began with trypsinmore » digestion of protein fractions followed by separation by reversed phase liquid chromatography that was coupled directly to a conventional tandem mass spectrometer (i.e. LCQ ion trap). Mass and fragmentation data for the peptides were searched against a human proteome data base using the informatics program SEQUEST. Using this procedure 398 proteins were identified with high confidence, including receptors, membrane-associated ligands, proteases, phosphatases, as well as structural and adhesion proteins. Results indicate that lectin chromatography provides a select subset of proteins and that the number and quality of the identifications improve as does the confidence of the protein identifications for this subset. These results represent the first step in development of methods to separate and successfully identify plasma membrane proteins from advanced ovarian cancer cells. Further characterization of plasma membrane proteins will contribute to our understanding of the mechanisms underlying progression of this deadly disease and may lead to new targeted interventions as well as new biomarkers for diagnosis.« less

  2. Review of Orifice Plate Steam Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Review of Orifice Plate Steam Traps Review of Orifice Plate Steam Traps This guide was prepared to serve as a foundation for making informed decisions about when orifice plate...

  3. Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Duty Linehaul Platform Project Update Effect of Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap Pt-free, Perovskite-based Lean NOx Trap Catalysts

  4. Developing a narrow-line laser spectrometer based on a tunable continuous-wave dye laser

    SciTech Connect

    Wang, Chun; Lv, Shasha; Bi, Jin; Liu, Fang; Li, Liufeng; Chen, Lisheng

    2014-08-15

    We present the development of a dye-laser-based spectrometer operating at 550–600 nm. The spectrometer will be used to detect an ultra-narrow clock transition ({sup 1}S{sub 0}-{sup 3}P{sub 0}) in an Ytterbium optical lattice clock and perform high-resolution spectroscopy of iodine molecules trapped in the sub-nanometer channels of zeolite crystal (AlPO{sub 4}-11). Two-stage Pound-Drever-Hall frequency stabilization is implemented on the tunable continuous-wave dye laser to obtain a reliable operation and provide stable laser radiations with two different spectral linewidths. In the first-stage frequency locking, a compact home-built intracavity electro-optic modulator is adopted for suppressing fast frequency noise. With an acquisition time of 0.1 s the 670-kHz linewidth of the free-running dye laser is reduced to 2 kHz when locked to a pre-stabilization optical cavity with a finesse of 1170. When the pre-stabilized laser is locked to a high-finesse optical cavity, a linewidth of 1.4 Hz (2 s) is observed and the frequency stability is 3.7 × 10{sup −15} (3 s). We also measure and analyze the individual noise contributions such as those from residual amplitude modulation and electronic noise. The ongoing upgrades include improving long-term frequency stability at time scales from 10 to 100 s and implementing continuous frequency scan across 10 GHz with radio-frequency precision.

  5. Lead Slowing Down Spectrometer Research Plans

    SciTech Connect

    Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

    2013-03-22

    The MPACT-funded Lead Slowing Down Spectrometry (LSDS) project has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. The LSDS collaborations suggests that the next step to in empirically testing the feasibility is to conduct measurements on fresh fuel assemblies to understand investigate self-attenuation and fresh mixed-oxide (MOX) fuel rodlets so we may betterto understand extraction of masses for 235U and 239Pu. While progressing toward these goals, the collaboration also strongly suggests the continued development of enabling technology such as detector development and algorithm development, thatwhich could provide significant performance benefits.

  6. November 18, 2010: Antimatter Trapped and Stored | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    8, 2010: Antimatter Trapped and Stored November 18, 2010: Antimatter Trapped and Stored November 18, 2010: Antimatter Trapped and Stored November 18, 2010 The Department's Lawrence Berkeley National Laboratory (LBNL) announces that atoms of antimatter have been trapped and stored for the first time in a magnetic bottle-like device by the ALPHA collaboration, an international team of scientists working at CERN, the European Organization for Nuclear Research near Geneva, Switzerland. Scientists

  7. Trapping and Measuring Charged Particles in Liquids - Energy Innovation

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Portal Advanced Materials Advanced Materials Find More Like This Return to Search Trapping and Measuring Charged Particles in Liquids Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication Printable fact sheet (552 KB) Planar aqueous Paul trap (PAPT) devices and experimental platform Planar aqueous Paul trap (PAPT) devices and experimental platform Technology Marketing SummaryA nanoscale version of the Paul ion trap was developed by

  8. Laser Mass Spectrometry in Planetary Science

    SciTech Connect

    Wurz, P.; Whitby, J. A.; Managadze, G. G.

    2009-06-16

    Knowing the chemical, elemental, and isotopic composition of planetary objects allows the study of their origin and evolution within the context of our solar system. Exploration plans in planetary research of several space agencies consider landing spacecraft for future missions. Although there have been successful landers in the past, more landers are foreseen for Mars and its moons, Venus, the jovian moons, and asteroids. Furthermore, a mass spectrometer on a landed spacecraft can assist in the sample selection in a sample-return mission and provide mineralogical context, or identify possible toxic soils on Mars for manned Mars exploration. Given the resources available on landed spacecraft mass spectrometers, as well as any other instrument, have to be highly miniaturised.

  9. High voltage gas insulated transmission line with continuous particle trapping

    DOEpatents

    Cookson, Alan H. (Pittsburgh, PA); Dale, Steinar J. (Monroeville, PA)

    1983-01-01

    This invention provides a novel high voltage gas insulated transmission line utilizing insulating supports spaced at intervals with snap-in means for supporting a continuous trapping apparatus and said trapping apparatus having perforations and cutouts to facilitate trapping of contaminating particles and system flexibility.

  10. Non-vanishing ponderomotive AC electrophoretic effect for particle trapping

    SciTech Connect

    Guan, Weihau; Park, Jae Hyun nmn; Krstic, Predrag S; Reed, Mark A

    2011-01-01

    We present here a study on overlooked aspects of alternating current (AC) electrokinetics AC electrophoretic (ACEP) phenomena. The dynamics of a particle with both polarizability and net charges in a non-uniform AC electric trapping field is investigated. It is found that either electrophoretic (EP) or dielectrophoretic (DEP) effects can dominate the trapping dynamics, depending on experimental conditions. A dimensionless parameter gamma is developed to predict the relative strength of EP and DEP effects in a quadrupole AC field. An ACEP trap is feasible for charged particles in salt-free or low salt concentration solutions. In contrast to DEP traps, an ACEP trap favors the downscaling of the particle size.

  11. Zinc-oxide charge trapping memory cell with ultra-thin chromium-oxide trapping layer

    SciTech Connect

    El-Atab, Nazek; Rizk, Ayman; Nayfeh, Ammar; Okyay, Ali K.; UNAM-National Nanotechnology Research Center and Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara

    2013-11-15

    A functional zinc-oxide based SONOS memory cell with ultra-thin chromium oxide trapping layer was fabricated. A 5 nm CrO{sub 2} layer is deposited between Atomic Layer Deposition (ALD) steps. A threshold voltage (V{sub t}) shift of 2.6V was achieved with a 10V programming voltage. Also for a 2V V{sub t} shift, the memory with CrO{sub 2} layer has a low programming voltage of 7.2V. Moreover, the deep trapping levels in CrO{sub 2} layer allows for additional scaling of the tunnel oxide due to an increase in the retention time. In addition, the structure was simulated using Physics Based TCAD. The results of the simulation fit very well with the experimental results providing an understanding of the charge trapping and tunneling physics.

  12. Design Considerations for Passive Gamma-Ray Spectrometers

    SciTech Connect

    Smith, Leon E.; Swickard, Andrea R.; Heredia-Langner, Alejandro; Warren, Glen A.; Siciliano, Edward R.; Miller, Steven D.

    2005-10-01

    Passive gamma-ray spectrometers composed of attenuation filters and integrating detection materials provide important advantages for measurements in high-radiation environments and for long-term monitoring. Each of these applications has requirements that constrain the design of the instrument, such as incident energy range of interest, sensor size and weight, readout method, and cost. In addition, the multitude of variable parameters in passive spectrometer design (e.g. attenuation filter material and thickness, integrating sensor type, numbers of pixels, reconstructed energy bin structure) results in a large design space to analyze. The development of generalized design optimization tools to interrogate this space and identify promising spectrometer designs are discussed, particularly the methods used to rapidly calculate system transfer functions and the use of genetic algorithms for design optimization. Finally, preliminary measurements to validate the design tools are described, and specific examples of preliminary design optimization efforts are provided.

  13. Photo-Spectrometer Realized In A Standard Cmos Ic Process

    DOEpatents

    Simpson, Michael L.; Ericson, M. Nance; Dress, William B.; Jellison, Gerald E.; Sitter, Jr., David N.; Wintenberg, Alan L.

    1999-10-12

    A spectrometer, comprises: a semiconductor having a silicon substrate, the substrate having integrally formed thereon a plurality of layers forming photo diodes, each of the photo diodes having an independent spectral response to an input spectra within a spectral range of the semiconductor and each of the photo diodes formed only from at least one of the plurality of layers of the semiconductor above the substrate; and, a signal processing circuit for modifying signals from the photo diodes with respective weights, the weighted signals being representative of a specific spectral response. The photo diodes have different junction depths and different polycrystalline silicon and oxide coverings. The signal processing circuit applies the respective weights and sums the weighted signals. In a corresponding method, a spectrometer is manufactured by manipulating only the standard masks, materials and fabrication steps of standard semiconductor processing, and integrating the spectrometer with a signal processing circuit.

  14. Calibration techniques for a fast duo-spectrometer

    SciTech Connect

    Chapman, J.T.; Den Hartog, D.J.

    1996-06-01

    The authors have completed the upgrade and calibration of the Ion Dynamics Spectrometer (IDS), a high-speed Doppler duo-spectrometer which measures ion flow and temperature in the MST Reversed-field Pinch. This paper describes an in situ calibration of the diagnostic`s phase and frequency response. A single clock was employed to generate both a digital test signal and a digitizer trigger thus avoiding frequency drift and providing a highly resolved measurement over the system bandwidth. Additionally, they review the measurement of the spectrometer instrument function and absolute intensity response. This calibration and subsequent performance demonstrate the IDS to be one of the fastest, highest throughput diagnostics of its kind. Typical measurements are presented.

  15. Broadband EUV survey spectrometer for short-timescale experiments

    SciTech Connect

    Chapman, B.E.; Hartog, D.J. Den; Fonck, R.J.

    1993-11-01

    A fast and inexpensive spectrometer system has been developed to record EUV impurity spectra in a magnetic fusion research device. To simplify the vacuum system, light is passed out of the spectrometer`s vacuum to the detector using a sodium-salicylate-coated fiber optic coupler. This coupler is positioned such that the focal field is nearly flat over its aperture. The system`s detector is a microchannel-plate-intensified, linear, self-scanning photodiode array. The 1024-pixel array covers a bandwidth of over 80 nm and is read out once every millisecond. The readout, which is four times faster than the manufacturer`s maximum rating, is fully synchronized to the experiment using a locally-designed control circuit.

  16. Development of multichannel low-energy neutron spectrometer

    SciTech Connect

    Arikawa, Y. Nagai, T.; Abe, Y.; Kojima, S.; Sakata, S.; Inoue, H.; Utsugi, M.; Iwasa, Y.; Sarukura, N.; Nakai, M.; Shiraga, H.; Fujioka, S.; Azechi, H.; Murata, T.

    2014-11-15

    A multichannel low-energy neutron spectrometer for down-scattered neutron (DSN) measurements in inertial confinement fusion (ICF) experiments has been developed. Our compact-size 256-channel lithium-glass-scintillator-based spectrometer has been implemented and tested in ICF experiments with the GEKKO XII laser. We have performed time calibration of the 256-channel analog-to-digital convertor system used for DSN measurements via X-ray pulse signals. We have clearly observed the DD-primary fusion neutron signal and have successfully studied the detector's impulse response. Our detector is soon to be implemented in future ICF experiments.

  17. Bragg x-ray survey spectrometer for ITER

    SciTech Connect

    Varshney, S. K.; Jakhar, S.; Barnsley, R.; O'Mullane, M. G.

    2012-10-15

    Several potential impurity ions in the ITER plasmas will lead to loss of confined energy through line and continuum emission. For real time monitoring of impurities, a seven channel Bragg x-ray spectrometer (XRCS survey) is considered. This paper presents design and analysis of the spectrometer, including x-ray tracing by the Shadow-XOP code, sensitivity calculations for reference H-mode plasma and neutronics assessment. The XRCS survey performance analysis shows that the ITER measurement requirements of impurity monitoring in 10 ms integration time at the minimum levels for low-Z to high-Z impurity ions can largely be met.

  18. Gas turbine engines with particle traps

    DOEpatents

    Boyd, Gary L.; Sumner, D. Warren; Sheoran, Yogendra; Judd, Z. Daniel

    1992-01-01

    A gas turbine engine (10) incorporates a particle trap (46) that forms an entrapment region (73) in a plenum (24) which extends from within the combustor (18) to the inlet (32) of a radial-inflow turbine (52, 54). The engine (10) is thereby adapted to entrap particles that originate downstream from the compressor (14) and are otherwise propelled by combustion gas (22) into the turbine (52, 54). Carbonaceous particles that are dislodged from the inner wall (50) of the combustor (18) are incinerated within the entrapment region (73) during operation of the engine (10).

  19. Isotopic abundance in atom trap trace analysis

    DOEpatents

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  20. Sales lag sparks steam trap diversity

    SciTech Connect

    Crawford, E.

    1980-03-03

    Competing manufacturers have broadened their product range and customer services in an effort to survive a tightened market and the introduction of unconventional devices. Users and vendors agree that rising energy costs now give inspection and maintenance of steam traps top priority. New products on the market are described. Competition has led to some questionable advertising and legal action. Fixed orifice and temperature-actuated valves are among the alternative products offered. Models of the major manufacturers are compared by type, pressure and condensate load range, primary use, and price.

  1. Review of Orifice Plate Steam Traps

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    0/353/R1 Review of Orifice Plate Steam Traps C. B. Oland DOCUMENT AVAILABILITY Reports produced after January 1, 1996, are generally available free via the U.S. Department of Energy (DOE) Information Bridge. Web site http://www.osti.gov/bridge Reports produced before January 1, 1996, may be purchased by members of the public from the following source. National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone 703-605-6000 (1-800-553-6847) TDD 703-487-4639 Fax

  2. Total internal reflection fluorescence spectrometer to study dynamic adsorption phenomena at liquid/liquid interfaces

    SciTech Connect

    Tupy, M.J.; Blanch, H.W.; Radke, C.J.

    1998-08-01

    Adsorption at oil/water interfaces affects the performance of many industrial systems including oil recovery, extraction processes, cosmetic products, and food technology. However, no technique currently available can monitor adsorption dynamics using molecularly sensitive methods. The authors have constructed a novel total internal reflection fluorescence spectrometer (TIRFS) to follow dynamic adsorption events at the oil/water interface. The TIRFS monitors changes in fluorescence intensity and fluorescence spectra over time by maintaining an optical focus on the fluid interface during adsorption and desorption processes. Kinetic adsorption phenomena are examined by altering the composition of the aqueous phase and recording surface fluorescence response without mechanically disturbing the fluid/fluid interface. The spectrometer captures changes in the fluorescence intensity over tenths of seconds and maintains optical focus for periods of days. Mass transport of fluorescing surface-active material to and from the oil/water interface is accurately modeled using the simple one-dimensional diffusion equation. The geometry designed for this apparatus can be applied to other light-based techniques studying adsorption at liquid/liquid interfaces. Here, the authors apply the TIRFS apparatus to the study of {beta}-casein adsorption and desorption at an aliphatic oil/water interface. The observed increase in interfacial fluorescence due to {beta}-casein adsorption is slower than the diffusive flux, and desorption is found to be very slow if not irreversible. The TIRF spectrum indicates interaction of sorbed {beta}-casein with the oil phase and subsequent rearrangement of the native structure.

  3. Evaluation of Technologies to Complement/Replace Mass Spectrometers in the Tritium Facilities

    SciTech Connect

    Tovo, L. L.; Lascola, R. J.; Spencer, W. A.; McWhorter, C. S.; Zeigler, K. E.

    2005-08-30

    The primary goal of this work is to determine the suitability of the Infraran sensor for use in the Palladium Membrane Reactor. This application presents a challenge for the sensor, since the process temperature exceeds its designed operating range. We have demonstrated that large baseline offsets, comparable to the sensor response to the analyte, are obtained if cool air is blown across the sensor. We have also shown that there is a strong environmental component to the noise. However, the current arrangement does not utilize a reference detector. The strong correlation between the CO and H{sub 2}O sensor responses to environmental changes indicate that a reference detector can greatly reduce the environmental sensitivity. In fact, incorporation of a reference detector is essential for the sensor to work in this application. We have also shown that the two sensor responses are adequately independent. Still, there are several small corrections which must to be made to the sensor response to accommodate chemical and physical effects. Interactions between the two analytes will alter the relationship between number density and pressure. Temperature and pressure broadening will alter the relationship between absorbance and number density. The individual effects are small--on the order of a few percent or less--but cumulatively significant. Still, corrections may be made if temperature and total pressure are independently measured and incorporated into a post-analysis routine. Such corrections are easily programmed and automated and do not represent a significant burden for installation. The measurements and simulations described above indicate that with appropriate corrections, the Infraran sensor can approach the 1-1.5% measurement accuracy required for effective PMR process control. It is also worth noting that the Infraran may be suitable for other gas sensing applications, especially those that do not need to be made in a high-temperature environment. Any gas with an infrared absorption (methane, ammonia, etc.) may be detected so long as an appropriate bandpass filter can be manufactured. Note that homonuclear diatomic molecules (hydrogen and its isotopes, nitrogen, oxygen) do not have infrared absorptions. We have shown that the sensor response may be adequately predicted using commercially available software. Measurement of trace concentrations is limited by the broad spectral bandpass, since the total signal includes non-absorbed frequencies. However, cells with longer pathlengths can be designed to address this problem.

  4. Mesoscopic supersolid of dipoles in a trap

    SciTech Connect

    Golomedov, A. E.; Astrakharchik, G. E.; Lozovik, Yu. E.

    2011-09-15

    A mesoscopic system of dipolar bosons trapped by a harmonic potential is considered. The system has a number of physical realizations including dipole excitons, atoms with large dipolar moment, polar molecules, and Rydberg atoms in inhomogeneous electric field. We carry out a diffusion Monte Carlo simulation to define the quantum properties of a two-dimensional system of trapped dipoles at zero temperature. In dimensionless units the system is described by two control parameters, namely, the number of particles and the strength of the interparticle interaction. We have shown that when the interparticle interaction is strong enough a mesoscopic crystal is formed. As the strength of interactions is decreased a multistage melting takes place. Off-diagonal order in the system is tested using natural-orbitals analysis. We have found that the system might be Bose condensed even in the case of strong interparticle interactions. There is a set of parameters for which a spatially ordered structure is formed while simultaneously the fraction of Bose-condensed particles is nonzero. This might be considered as a realization of a mesoscopic supersolid.

  5. Compact Catadioptric Imaging Spectrometer Designs Utilizing Immersed Gratings

    DOEpatents

    Lerner, Scott A. (Livermore, CA)

    2006-02-28

    An imaging spectrometer comprising an entrance slit for directing light, a lens that receives said light and reflects said light, a grating that defracts said light back onto said lens which focuses said light, and a detector array that receives said focused light. In one embodiment the grating has rulings immersed into a germanium surface.

  6. Pair spectrometer hodoscope for Hall D at Jefferson Lab

    DOE PAGES [OSTI]

    Barbosa, Fernando J.; Hutton, Charles L.; Sitnikov, Alexandre; Somov, Alexander S.; Somov, S.; Tolstukhin, Ivan

    2015-09-01

    We present the design of the pair spectrometer hodoscope fabricated at Jefferson Lab and installed in the experimental Hall D. The hodoscope consists of thin scintillator tiles; the light from each tile is collected using wave-length shifting fibers and detected using a Hamamatsu silicon photomultiplier. Light collection was measured using relativistic electrons produced in the tagger area of the experimental Hall B.

  7. Optical system for high resolution spectrometer/monochromator

    DOEpatents

    Hettrick, Michael C.; Underwood, James H.

    1988-01-01

    An optical system for use in a spectrometer or monochromator employing a mirror which reflects electromagnetic radiation from a source to converge with same in a plane. A straight grooved, varied-spaced diffraction grating receives the converging electromagnetic radiation from the mirror and produces a spectral image for capture by a detector, target or like receiver.

  8. Optical system for high resolution spectrometer/monochromator

    DOEpatents

    Hettrick, M.C.; Underwood, J.H.

    1988-10-11

    An optical system for use in a spectrometer or monochromator employing a mirror which reflects electromagnetic radiation from a source to converge with same in a plane is disclosed. A straight grooved, varied-spaced diffraction grating receives the converging electromagnetic radiation from the mirror and produces a spectral image for capture by a detector, target or like receiver. 11 figs.

  9. The Los Alamos National Laboratory precision double crystal spectrometer

    SciTech Connect

    Morgan, D.V.; Stevens, C.J.; Liefield, R.J.

    1994-03-01

    This report discusses the following topics on the LANL precision double crystal X-ray spectrometer: Motivation for construction of the instrument; a brief history of the instrument; mechanical systems; motion control systems; computer control system; vacuum system; alignment program; scan programs; observations of the copper K{alpha} lines; and characteristics and specifications.

  10. Fast temperature spectrometer for samples under extreme conditions

    SciTech Connect

    Zhang, Dongzhou; Jackson, Jennifer M.; Sturhahn, Wolfgang; Zhao, Jiyong; Alp, E. Ercan; Toellner, Thomas S.; Hu, Michael Y.

    2015-01-15

    We have developed a multi-wavelength Fast Temperature Readout (FasTeR) spectrometer to capture a sample’s transient temperature fluctuations, and reduce uncertainties in melting temperature determination. Without sacrificing accuracy, FasTeR features a fast readout rate (about 100 Hz), high sensitivity, large dynamic range, and a well-constrained focus. Complimenting a charge-coupled device spectrometer, FasTeR consists of an array of photomultiplier tubes and optical dichroic filters. The temperatures determined by FasTeR outside of the vicinity of melting are, generally, in good agreement with results from the charge-coupled device spectrometer. Near melting, FasTeR is capable of capturing transient temperature fluctuations, at least on the order of 300 K/s. A software tool, SIMFaster, is described and has been developed to simulate FasTeR and assess design configurations. FasTeR is especially suitable for temperature determinations that utilize ultra-fast techniques under extreme conditions. Working in parallel with the laser-heated diamond-anvil cell, synchrotron Mössbauer spectroscopy, and X-ray diffraction, we have applied the FasTeR spectrometer to measure the melting temperature of {sup 57}Fe{sub 0.9}Ni{sub 0.1} at high pressure.

  11. Pair spectrometer hodoscope for Hall D at Jefferson Lab

    SciTech Connect

    Barbosa, Fernando J.; Hutton, Charles L.; Sitnikov, Alexandre; Somov, Alexander S.; Somov, S.; Tolstukhin, Ivan

    2015-09-21

    We present the design of the pair spectrometer hodoscope fabricated at Jefferson Lab and installed in the experimental Hall D. The hodoscope consists of thin scintillator tiles; the light from each tile is collected using wave-length shifting fibers and detected using a Hamamatsu silicon photomultiplier. Light collection was measured using relativistic electrons produced in the tagger area of the experimental Hall B.

  12. Identification of microscopic hole-trapping mechanisms in nitride semiconductors

    SciTech Connect

    John L. Lyons; Krishnaswamy, Karthik; Luke Gordon; Van de Walle, Chris G.; Anderson, Janotti

    2015-12-17

    Hole trapping has been observed in nitride heterostructure devices, where the Fermi level is in the vicinity of the valence-band maximum. Using hybrid density functional calculations, we examine microscopic mechanisms for hole trapping in GaN and AlN. In a defect-free material, hole trapping does not spontaneously occur, but trapping can occur in the vicinity of impurities, such as C-a common unintentional impurity in nitrides. As a result, using Schrödinger-Poisson simulations, we assess the effects of C-derived hole traps on N-face high-electron mobility transistors, which we find to be more detrimental than the previously proposed interface traps.

  13. Gas insulated transmission line having tapered particle trapping ring

    DOEpatents

    Cookson, Alan H.

    1982-01-01

    A gas-insulated transmission line includes an outer sheath, an inner conductor, insulating supports and an insulating gas. A particle-trapping ring is secured to each insulating support, and it is comprised of a central portion and two tapered end portions. The ends of the particle trapping ring have a smaller diameter than the central portion of the ring, so as to enable the use of the particle trapping ring in a curved transmission line.

  14. Steam trap maintenance management saves $180,000 annually

    SciTech Connect

    Franks, F.C.; Wickersham, C.

    1985-12-01

    The Reichhold Chemical plant is located in Elizabeth, NJ. At this location, the cost of steam had skyrocketed to $5.30 per million Btu. The plant has 600 steam traps manufactured by ten different companies. Some 17 different models of traps are used with 33 piping configurations. There are five different operating pressures throughout the plant ranging from 15-175 psig, including 30, 65, and 120 psig. Five different applications of steam usage can be broken down as follows: steam tracing (56%); drip (21%); comfort heating (18%); tank coil (4%); and process (1%). In the fall of 1983, the annual yearly inspection of steam traps was supplanted with an independent trap survey service, specializing in detecting the malfunctioning of various types of steam traps. The basic program included location and tagging of all steam traps; survey and inspection of steam trap population; development of a trap map; and full computer analysis of collected data. It was determined that approximately 3919 lb/hr of steam could be saved by repairing the failed open traps and implementing the report's recommendations. There were also benefits from fixing the failed closed traps which were out of service at the time of the survey. These traps do not allow the flow of steam or condensate to pass through the orifice. This condition causes condensate to back up and reduce efficiency. The maintenance management has been pleased with the results and recommendations of the program. It has provided them with a complete inventory and status report of the 600 traps plantwide. It saved $180,000 over the previous year in energy expenditures. This was the most important contribution in lowering the plant energy costs.

  15. Thermostatic/orifice trap reduces fuel, repair costs

    SciTech Connect

    Not Available

    1982-11-01

    This article is an evaluation of a steam trap that combines the continuous drain oriface with a thermostatically controlled trap oriface to efficiently remove condensate from virtually any steam system within its operating limits. This trap effectively reduces fuel and repair costs and has a capacity of 6000 il/hr, handles various pressures up to 600 psig, and operates against back pressures up to 90% of inlet pressure.

  16. Spectra of clinical CT scanners using a portable Compton spectrometer

    SciTech Connect

    Duisterwinkel, H. A.; Abbema, J. K. van; Kawachimaru, R.; Paganini, L.; Graaf, E. R. van der; Brandenburg, S.; Goethem, M. J. van

    2015-04-15

    Purpose: Spectral information of the output of x-ray tubes in (dual source) computer tomography (CT) scanners can be used to improve the conversion of CT numbers to proton stopping power and can be used to advantage in CT scanner quality assurance. The purpose of this study is to design, validate, and apply a compact portable Compton spectrometer that was constructed to accurately measure x-ray spectra of CT scanners. Methods: In the design of the Compton spectrometer, the shielding materials were carefully chosen and positioned to reduce background by x-ray fluorescence from the materials used. The spectrum of Compton scattered x-rays alters from the original source spectrum due to various physical processes. Reconstruction of the original x-ray spectrum from the Compton scattered spectrum is based on Monte Carlo simulations of the processes involved. This reconstruction is validated by comparing directly and indirectly measured spectra of a mobile x-ray tube. The Compton spectrometer is assessed in a clinical setting by measuring x-ray spectra at various tube voltages of three different medical CT scanner x-ray tubes. Results: The directly and indirectly measured spectra are in good agreement (their ratio being 0.99) thereby validating the reconstruction method. The measured spectra of the medical CT scanners are consistent with theoretical spectra and spectra obtained from the x-ray tube manufacturer. Conclusions: A Compton spectrometer has been successfully designed, constructed, validated, and applied in the measurement of x-ray spectra of CT scanners. These measurements show that our compact Compton spectrometer can be rapidly set-up using the alignment lasers of the CT scanner, thereby enabling its use in commissioning, troubleshooting, and, e.g., annual performance check-ups of CT scanners.

  17. Johann Spectrometer for High Resolution X-ray Spectroscopy

    SciTech Connect

    Machek, Pavel; Froeba, Michael; Welter, Edmund; Caliebe, Wolfgang; Brueggmann, Ulf; Draeger, Guenter

    2007-01-19

    A newly designed vacuum Johann spectrometer with a large focusing analyzer crystal for inelastic x-ray scattering and high resolution fluorescence spectroscopy has been installed at the DORIS III storage ring. Spherically bent crystals with a maximum diameter of 125 mm, and cylindrically bent crystals are employed as dispersive optical elements. Standard radius of curvature of the crystals is 1000 mm, however, the design of the mechanical components also facilitates measurements with smaller and larger bending radii. Up to four crystals are mounted on a revolving crystal changer which enables crystal changes without breaking the vacuum. The spectrometer works at fixed Bragg angle. It is preferably designed for the measurements in non-scanning mode with a broad beam spot, and offers a large flexibility to set the sample to the optimum position inside the Rowland circle. A deep depletion CCD camera is employed as a position sensitive detector to collect the energy-analyzed photons on the circumference of the Rowland circle. The vacuum in the spectrometer tank is typically 10-6 mbar. The sample chamber is separated from the tank either by 25 {mu}m thick Kapton windows, which allows samples to be measured under ambient conditions, or by two gate valves. The spectrometer is currently installed at wiggler beamline W1 whose working range is 4-10.5 keV with typical flux at the sample of 5x1010photons/s/mm2. The capabilities of the spectrometer are illustrated by resonant inelastic experiments on 3d transition metals and rare earth compounds, and by chemical shift measurements on chromium compounds.

  18. Results from the NSTX X-ray Crystal Spectrometer

    SciTech Connect

    M. Bitter; K. Hill; L. Roquemore; P. Beiersdorfer; D. Thorn; Ming Feng Gu

    2003-01-14

    A high-resolution X-ray crystal spectrometer has recently been installed at the National Spherical Torus Experiment to record the satellite spectra of helium-like argon, ArXVII, in the wavelength range from 3.94 to 4.00 {angstrom} for measurements of ion and electron temperatures, and measurements of the ionization equilibrium of argon, which is of interest for studies of ion transport. The instrument presently consists of a spherically bent quartz crystal and a conventional one-dimensional position-sensitive multi-wire proportional counter, but it will soon be upgraded to a new type of X-ray imaging crystal spectrometer by the installation of a large size (10 cm x 30 cm) two-dimensional position-sensitive detector that will allow us to obtain temporally and spatially resolved spectra from an 80 cm high cross-section of the plasma. In its present configuration, the spectrometer has been optimized for high throughput so that it is possible to record spectra with small statistical errors with a time resolution of 10 ms by adding only small, nonperturbing amounts of argon to the plasma. The spectrometer is most valuable for measurements of the ion temperature in the absence of a neutral beam in ohmically heated and radio-frequency heated discharges, when charge exchange recombination spectroscopy does not function. Electron temperature measurements from the satellite-to-resonance line ratios have been important for a quantitative comparison with (and verification of) the Thomson scattering data. The paper will describe the instrumental details of the present and future spectrometer configurations, and present recent experimental results.

  19. Particle trapping: A key requisite of structure formation and...

    Office of Scientific and Technical Information (OSTI)

    Particle trapping is shown to control the existence of ... Journal Volume: 22; Journal Issue: 4; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International ...

  20. Ball-grid array architecture for microfabricated ion traps (Journal...

    Office of Scientific and Technical Information (OSTI)

    Ball-grid array architecture for microfabricated ion traps Citation Details In-Document ... Country of Publication: United States Language: English Subject: 71 CLASSICAL AND QUANTUM ...

  1. Light Trapping, Absorption and Solar Energy Harvesting by Artificial...

    Office of Scientific and Technical Information (OSTI)

    Energy Harvesting by Artificial Materials Citation Details In-Document Search Title: Light Trapping, Absorption and Solar Energy Harvesting by Artificial Materials We provide ...

  2. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor 2003deercrane.pdf (630.37 KB) More Documents & Publications ...

  3. On the Equivalence of Trapped Colloids, Pinned Vortices, and...

    Office of Scientific and Technical Information (OSTI)

    Title: On the Equivalence of Trapped Colloids, Pinned Vortices, and Spin Ice We investigate the recently reported analogies between pinned vortices in nano-structured ...

  4. Lean NOx Traps - Microstructural Studies of Real World and Model...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    KB) More Documents & Publications Low Temperature Emission Control Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps Investigation ...

  5. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and Differences Between ... More Documents & Publications Spatiotemporal Distribution of NOx Storage: a Factor ...

  6. Dynamically adjustable annular laser trapping based on axicons

    SciTech Connect

    Shao, Bing; Esener, Sadik C.; Nascimento, Jaclyn M.; Botvinick, Elliot L.; Berns, Michael W

    2006-09-01

    To study the chemotactic response of sperm to an egg and to characterize sperm motility, an annular laser trap based on axicons is designed, simulated with the ray-tracing tool, and implemented. The diameter of the trapping ring can be adjusted dynamically for a range of over 400 {mu}m by simply translating one axicon along the optical axis. Trapping experiments with microspheres and dog sperm demonstrate the feasibility of the system,and the power requirement agrees with theoretical expectation. This new type of laser trapping could provide a prototype of a parallel, objective, and quantitative tool for animal fertility and biotropism study.

  7. Wolf Trap, Virginia: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Bureau 2005 Place to 2006 CBSA Retrieved from "http:en.openei.orgwindex.php?titleWolfTrap,Virginia&oldid253815" Feedback Contact needs updating Image needs updating...

  8. A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads...

    Office of Scientific and Technical Information (OSTI)

    a paramagnetic microsphere trapping and separation device consisting of a copper solenoid ... to the design of magnetic-based separation devices because the ...

  9. Stable metal-organic frameworks containing single-molecule traps...

    Office of Scientific and Technical Information (OSTI)

    Title: Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation Authors: Feng, Dawei ; Liu, Tian-Fu ; Su, Jie ; Bosch, Mathieu ; Wei, Zhangwen ; ...

  10. Biogas Purifications for Fuel Cells: SulfaTrap Sorbents

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Biogas Purifications for Fuel Cells SulfaTrap TM Sorbents Gökhan Alptekin, PhD Vice President, Technology Tel: 303 940 2349 galptekin@tda.com DOE Workshop on Gas Clean-up for Fuel Cell Applications Argonne National Laboratory March 7, 2014 TDA Research Inc. * Wheat Ridge, CO 80033 * www.tda.com Background - SulfaTrap TM Sorbents Bio-ethanol desulfurizer SulfaTrap TM sorbents for stationary/mobile fuel cell applications * Fundamental work started at TDA Research in 2002 * SulfaTrap LLC was

  11. In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

    DOEpatents

    Braymen, S.D.

    1996-06-11

    A method and apparatus are disclosed for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present in situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization. 5 figs.

  12. Real-time monitoring of volatile organic compounds using chemical ionization mass spectrometry

    DOEpatents

    Mowry, Curtis Dale; Thornberg, Steven Michael

    1999-01-01

    A system for on-line quantitative monitoring of volatile organic compounds (VOCs) includes pressure reduction means for carrying a gaseous sample from a first location to a measuring input location maintained at a low pressure, the system utilizing active feedback to keep both the vapor flow and pressure to a chemical ionization mode mass spectrometer constant. A multiple input manifold for VOC and gas distribution permits a combination of calibration gases or samples to be applied to the spectrometer.

  13. Eolian paleotopographic highs as stratigraphic traps: origin and distinction

    SciTech Connect

    Eschner, T.B.; Kocurek, G.A.

    1985-02-01

    Significant hydrocarbon accumulations occur where eolian paleotopographic highs are preserved beneath transgressive marine deposits. Paleotopographic highs can represent erosional remnants of an unconformity, or partly preserved eolian dunes, or combinations of both. Paleotopography reflects the extent of modification undergone by eolian units prior to or during transgression. Modification varies between extremes of (1) destruction - where eolian deposits are deeply eroded and the former dunal profile is lost, and (2) preservation - where dunes and interdune areas are preserved nearly intact. The extent of modification that occurs during transgression is controlled primarily by (1) the energy of the transgressing sea, (2) the speed of transgression, and (3) the abundance of sand-stabilizing early cements or plants. High-energy seas destroy dunes through persistent erosion by tides and waves and by initiating dune collapse and mass flowage of dune sands. Preservation occurs where quiescent seas flood interdune areas and create shallow to periodically emergent marine environments, such as interdune sabkhas or tidal flats. Gradual filling of interdune areas with shallow marine sediments can fortify and preserve adjacent dunes. These varied processes that interact between marine and eolian environments to create different types of topography are exemplified in ancient eolian-marine sequences of the Western Interior of North America, and preserved Holocene dunes of coastal Australia. Different types of eolian highs can be recognized by analysis of bounding surfaces in outcrop or core. An understanding of eolian-marine processes and environments that create topography allows for prediction of areas of potential stratigraphic traps.

  14. Extending the applicability of an open-ring trap to perform experiments with a single laser-cooled ion

    SciTech Connect

    Cornejo, J. M.; Colombano, M.; Doménech, J.; Rodríguez, D.; Block, M.; Delahaye, P.

    2015-10-15

    A special ion trap was initially built up to perform β-ν correlation experiments with radioactive ions. The trap geometry is also well suited to perform experiments with laser-cooled ions, serving for the development of a new type of Penning trap, in the framework of the project TRAPSENSOR at the University of Granada. The goal of this project is to use a single {sup 40}Ca{sup +} ion as detector for single-ion mass spectrometry. Within this project and without any modification to the initial electrode configuration, it was possible to perform Doppler cooling on {sup 40}Ca{sup +} ions, starting from large clouds and reaching single ion sensitivity. This new feature of the trap might be important also for other experiments with ions produced at radioactive ion beam facilities. In this publication, the trap and the laser system will be described, together with their performance with respect to laser cooling applied to large ion clouds down to a single ion.

  15. A high-resolution imaging x-ray crystal spectrometer for high...

    Office of Scientific and Technical Information (OSTI)

    A high-resolution imaging x-ray crystal spectrometer for high energy density plasmas Citation Details In-Document Search Title: A high-resolution imaging x-ray crystal spectrometer ...

  16. Streaked x-ray spectrometer having a discrete selection of Bragg...

    Office of Scientific and Technical Information (OSTI)

    Streaked x-ray spectrometer having a discrete selection of Bragg geometries for Omega Citation Details In-Document Search Title: Streaked x-ray spectrometer having a discrete selection ...

  17. X-ray crystal spectrometer for opacity measurements in the 8...

    Office of Scientific and Technical Information (OSTI)

    X-ray crystal spectrometer for opacity measurements in the 8-18 A spectral range at the LULI laser facility Citation Details In-Document Search Title: X-ray crystal spectrometer ...

  18. The NIF X-ray Spectrometer (NXS) calibration campaign at Omega...

    Office of Scientific and Technical Information (OSTI)

    The NIF X-ray Spectrometer (NXS) calibration campaign at Omega Citation Details In-Document Search Title: The NIF X-ray Spectrometer (NXS) calibration campaign at Omega Authors: ...

  19. Atomic data for the ITER Core Imaging X-ray Spectrometer (Conference...

    Office of Scientific and Technical Information (OSTI)

    Atomic data for the ITER Core Imaging X-ray Spectrometer Citation Details In-Document Search Title: Atomic data for the ITER Core Imaging X-ray Spectrometer You are accessing a ...

  20. The LCLS variable-energy hard X-ray single-shot spectrometer...

    Office of Scientific and Technical Information (OSTI)

    The LCLS variable-energy hard X-ray single-shot spectrometer Citation Details In-Document Search Title: The LCLS variable-energy hard X-ray single-shot spectrometer The engineering ...

  1. The NIF X-ray Spectrometer (NXS) calibration campaign at Omega...

    Office of Scientific and Technical Information (OSTI)

    The NIF X-ray Spectrometer (NXS) calibration campaign at Omega Citation Details In-Document Search Title: The NIF X-ray Spectrometer (NXS) calibration campaign at Omega You are ...

  2. Debris trap in a turbine cooling system

    DOEpatents

    Wilson, Ian David

    2002-01-01

    In a turbine having a rotor and a plurality of stages, each stage comprising a row of buckets mounted on the rotor for rotation therewith; and wherein the buckets of at least one of the stages are cooled by steam, the improvement comprising at least one axially extending cooling steam supply conduit communicating with an at least partially annular steam supply manifold; one or more axially extending cooling steam feed tubes connected to the manifold at a location radially outwardly of the cooling steam supply conduit, the feed tubes arranged to supply cooling steam to the buckets of at least one of the plurality of stages; the manifold extending radially beyond the feed tubes to thereby create a debris trap region for collecting debris under centrifugal loading caused by rotation of the rotor.

  3. Contaminant trap for gas-insulated apparatus

    DOEpatents

    Adcock, James L.; Pace, Marshall O.; Christophorou, Loucas G.

    1984-01-01

    A contaminant trap for a gas-insulated electrical conductor is provided. A resinous dielectric body such as Kel-F wax, grease or other sticky polymeric or oligomeric compound is disposed on the inside wall of the outer housing for the conductor. The resinous body is sufficiently sticky at ambient temperatures to immobilize contaminant particles in the insulating gas on the exposed surfaces thereof. An electric resistance heating element is disposed in the resinous body to selectively raise the temperature of the resinous body to a molten state so that the contaminant particles collected on the surface of the body sink into the body so that the surface of the resinous body is renewed to a particle-less condition and, when cooled, returns to a sticky collecting surface.

  4. Quark Masses

    SciTech Connect

    Gasser, Juerg

    2005-10-26

    In my talk, I reviewed some basic aspects of quark masses: what do they mean, how can they be determined, what is our present knowledge on them. The talk was addressed to non specialists in the field, and so is this write up.

  5. Atmospheric pressure plasma analysis by modulated molecular beam mass spectrometry

    SciTech Connect

    Aranda Gonzalvo, Y.; Whitmore, T.D.; Rees, J.A.; Seymour, D.L.; Stoffels, E.

    2006-05-15

    Fractional number density measurements for a rf plasma 'needle' operating at atmospheric pressure have been obtained using a molecular beam mass spectrometer (MBMS) system designed for diagnostics of atmospheric plasmas. The MBMS system comprises three differentially pumped stages and a mass/energy analyzer and includes an automated beam-to-background measurement facility in the form of a software-controlled chopper mechanism. The automation of the beam modulation allows the neutral components in the plasma to be rapidly and accurately measured using the mass spectrometer by threshold ionization techniques. Data are reported for plasma generated by a needle plasma source operated using a helium/air mixture. In particular, data for the conversion of atmospheric oxygen and nitrogen into nitric oxide are discussed with reference to its significance for medical applications such as disinfecting wounds and dental cavities and for microsurgery.

  6. Quantum chaos of an ion trapped in a linear ion trap

    SciTech Connect

    Berman, Gennady P. [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); James, Daniel F. V. [Theoretical Division T-4, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Theoretical Division T-4, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Kamenev, Dimitri I. [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States) [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Nizhny Novgorod State University, Nizhny Novgorod, 603600, Russia (Russian Federation)

    2000-06-01

    We describe the transition to quantum chaos of an ion trapped in a linear ion trap and interacting with two laser fields. Under the conditions of adiabatic illumination of the upper level of the ion, and when the frequencies of the two laser beams are slightly different, the system is reduced to a quantum linear oscillator interacting with a monochromatic wave. The property of localization over the quantum resonance cells is proposed to exploit in order to facilitate the process of measurement of the probability distribution of an ion on the vibrational levels. In the regime of strong chaos the time-averaged values of the energy and dispersion of energy are computed and compared with the corresponding classical quantities for different values of the perturbation amplitude. In the exact resonance case, the classical analog of the system possesses an infinite inhomogeneous stochastic web. We analyze the quantum dynamics inside the inhomogeneous web. It is shown that the quantum system mimics on average the dynamics of the corresponding classical system. Formation of the quantum resonance cells is illustrated in the case of a finite detuning from the exact resonance, and under increasing of the wave amplitude. The parameters of the model and the initial conditions are close to the real physical situation which can be realized in the system of cold trapped ion perturbed by two lasers fields with close frequencies. (c) 2000 American Institute of Physics.

  7. Waveguide-integrated photonic crystal spectrometer with camera readout

    SciTech Connect

    Meng, Fan; Shiue, Ren-Jye; Li, Luozhou; Nie, Jing; Harris, Nicholas C.; Chen, Edward H.; Schröder, Tim; Englund, Dirk; Wan, Noel; Pervez, Nadia; Kymissis, Ioannis

    2014-08-04

    We demonstrate an infrared spectrometer based on waveguide-coupled nanocavity filters in a planar photonic crystal structure. The input light is coupled into the waveguide, from which spectral components are dropped into the cavities and radiated off-chip for detection on a commercial InGaAs camera. The spectrometer has a footprint of only 60 μm by 8 μm. The spectral resolution is about 1 nm in the operation bandwidth of 1522–1545 nm. By substituting the membrane material and structure parameters, this design can be easily extended into the visible regime and developed for a variety of highly efficient, miniature photonic applications.

  8. Electrostatic particle trap for ion beam sputter deposition

    DOEpatents

    Vernon, Stephen P.; Burkhart, Scott C.

    2002-01-01

    A method and apparatus for the interception and trapping of or reflection of charged particulate matter generated in ion beam sputter deposition. The apparatus involves an electrostatic particle trap which generates electrostatic fields in the vicinity of the substrate on which target material is being deposited. The electrostatic particle trap consists of an array of electrode surfaces, each maintained at an electrostatic potential, and with their surfaces parallel or perpendicular to the surface of the substrate. The method involves interception and trapping of or reflection of charged particles achieved by generating electrostatic fields in the vicinity of the substrate, and configuring the fields to force the charged particulate material away from the substrate. The electrostatic charged particle trap enables prevention of charged particles from being deposited on the substrate thereby enabling the deposition of extremely low defect density films, such as required for reflective masks of an extreme ultraviolet lithography (EUVL) system.

  9. Ionization-Induced Electron Trapping inUltrarelativistic Plasma Wakes

    SciTech Connect

    Oz, E.; Deng, S.; Katsouleas, T.; Muggli, P.; Barnes, C.D.; Blumenfeld, I.; Decker, F.J.; Emma, P.; Hogan, M.J.; Ischebeck, R.; Iverson, R.H.; Kirby, N.; Krejcik, P.; O'Connell, C.; Siemann, R.H.; Walz, D.; Auerbach, D.; Clayton, C.E.; Huang, C.; Johnson, D.K.; Joshi, C.; /UCLA

    2007-04-06

    The onset of trapping of electrons born inside a highly relativistic, 3D beam-driven plasma wake is investigated. Trapping occurs in the transition regions of a Li plasma confined by He gas. Li plasma electrons support the wake, and higher ionization potential He atoms are ionized as the beam is focused by Li ions and can be trapped. As the wake amplitude is increased, the onset of trapping is observed. Some electrons gain up to 7.6 GeV in a 30.5 cm plasma. The experimentally inferred trapping threshold is at a wake amplitude of 36 GV/m, in good agreement with an analytical model and PIC simulations.

  10. A Pneumatic Actuated Microfluidic Beads-Trapping Device

    SciTech Connect

    Shao, Guocheng; Cai, Ziliang; Wang, Jun; Wang, Wanjun; Lin, Yuehe

    2011-08-20

    The development of a polydimethylsiloxane (PDMS) microfluidic microbeads trapping device is reported in this paper. Besides fluid channels, the proposed device includes a pneumatic control chamber and a beads-trapping chamber with a filter array structure. The pneumatic flow control chamber and the beads-trapping chamber are vertically stacked and separated by a thin membrane. By adjusting the pressure in the pneumatic control chamber, the membrane can either be pushed against the filter array to set the device in trapping mode or be released to set the device in releasing mode. In this paper, a computational fluid dynamics simulation was conducted to optimize the geometry design of the filter array structure; the device fabrication was also carried out. The prototype device was tested and the preliminary experimental results showed that it can be used as a beads-trapping unit for various biochemistry and analytical chemistry applications, especially for flow injection analysis systems.

  11. Optical trapping apparatus, methods and applications using photonic crystal resonators

    DOEpatents

    Erickson, David; Chen, Yih-Fan

    2015-06-16

    A plurality of photonic crystal resonator optical trapping apparatuses and a plurality optical trapping methods using the plurality of photonic crystal resonator optical trapping apparatuses include located and formed over a substrate a photonic waveguide that is coupled (i.e., either separately coupled or integrally coupled) with a photonic crystal resonator. In a particular embodiment, the photonic waveguide and the photonic crystal resonator comprise a monocrystalline silicon (or other) photonic material absent any chemical functionalization. In another particular embodiment, the photonic waveguide and the photonic crystal resonator comprise a silicon nitride material which when actuating the photonic crystal resonator optical trapping apparatus with a 1064 nanometer resonant photonic radiation wavelength (or other resonant photonic radiation wavelength in a range from about 700 to about 1200 nanometers) provides no appreciable heating of an aqueous sample fluid that is analyzed by the photonic crystal resonator optical trapping apparatus.

  12. Compact Refractive Imaging Spectrometer Designs Utilizing Immersed Gratings

    DOEpatents

    Lerner, Scott A.; Bennett, Charles L.; Bixler, Jay V.; Kuzmenko, Paul J.; Lewis, Isabella T.

    2005-07-26

    A compact imaging spectrometer comprising an entrance slit for directing light, a first means for receiving the light and focusing the light, an immersed diffraction grating that receives the light from the first means and defracts the light, a second means for receiving the light from the immersed diffraction grating and focusing the light, and an image plane that receives the light from the second means

  13. Imaging Spectrometer Designs Utilizing Immersed Gratings With Accessible Entrance Slit

    DOEpatents

    Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR)

    2006-03-21

    A compact imaging spectrometer comprises an entrance slit, a catadioptric lens with a mirrored surface, a grating, and a detector array. The entrance slit directs light to the mirrored surface of the catadioptric lens; the mirrored surface reflects the light back through the lens to the grating. The grating receives the light from the catadioptric lens and diffracts the light to the lens away from the mirrored surface. The lens transmits the light and focuses it onto the detector array.

  14. Pulsed Ionization Source for Ion Mobility Spectrometers - Energy Innovation

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Pulsed Ionization Source for Ion Mobility Spectrometers Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication 12-G00261-1114-1209.pdf (185 KB) Technology Marketing SummaryORNL's new wave of detection devices based on ion mobility spectrometry offer enhanced sensitivity and resolution and increased safety and flexibility. Leading the

  15. Time-of-flight direct recoil ion scattering spectrometer

    DOEpatents

    Krauss, A.R.; Gruen, D.M.; Lamich, G.J.

    1994-09-13

    A time-of-flight direct recoil and ion scattering spectrometer beam line is disclosed. The beam line includes an ion source which injects ions into pulse deflection regions and separated by a drift space. A final optics stage includes an ion lens and deflection plate assembly. The ion pulse length and pulse interval are determined by computerized adjustment of the timing between the voltage pulses applied to the pulsed deflection regions. 23 figs.

  16. Time-of-flight direct recoil ion scattering spectrometer

    DOEpatents

    Krauss, Alan R.; Gruen, Dieter M.; Lamich, George J.

    1994-01-01

    A time of flight direct recoil and ion scattering spectrometer beam line (10). The beam line (10) includes an ion source (12) which injects ions into pulse deflection regions (14) and (16) separated by a drift space (18). A final optics stage includes an ion lens and deflection plate assembly (22). The ion pulse length and pulse interval are determined by computerized adjustment of the timing between the voltage pulses applied to the pulsed deflection regions (14) and (16).

  17. Extracting source parameters from beam monitors on a chopper spectrometer

    SciTech Connect

    Abernathy, Douglas L [ORNL; Niedziela, Jennifer L [ORNL; Stone, Matthew B [ORNL

    2015-01-01

    The intensity distributions of beam monitors in direct-geometry time-of-flight neutron spectrometers provide important information about the instrument resolution. For short-pulse spallation neutron sources in particular, the asymmetry of the source pulse may be extracted and compared to Monte Carlo source simulations. An explicit formula using a Gaussian-convolved Ikeda-Carpenter distribution is given and compared to data from the ARCS instrument at the Spallation Neutron Source.

  18. Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Handbook

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    4 Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Handbook C Flynn March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use

  19. Slow Neutron Velocity Spectrometer Transmission Studies Of Pu

    DOE R&D Accomplishments

    Havens, W. W. Jr.; Melkonian, E.; Rainwater, L. J.; Levin, M.

    1951-05-28

    The slow neutron transmission of several samples of Pu has been investigated with the Columbia Neutron Velocity Spectrometer. Data are presented in two groups, those covering the energy region from 0 to 6 ev, and those covering the region above 6 ev. Below 6 ev the resolution was relatively good, and a detailed study of the cross section variation was made. Work above 6 ev consisted of merely locating levels and obtaining a rough idea of their strengths.

  20. Cooling the motion of diamond nanocrystals in a magneto-gravitational trap in high vacuum

    DOE PAGES [OSTI]

    Hsu, Jen -Feng; Ji, Peng; Lewandowski, Charles W.; D’Urso, Brian

    2016-07-22

    Levitated diamond nanocrystals with nitrogen-vacancy (NV) centres in high vacuum have been proposed as a unique system for experiments in fundamental quantum mechanics, including the generation of large quantum superposition states and tests of quantum gravity. This system promises extreme isolation from its environment while providing quantum control and sensing through the NV centre spin. While optical trapping has been the most explored method of levitation, recent results indicate that excessive optical heating of the nanodiamonds under vacuum may make the method impractical with currently available materials. Here, we study an alternative magneto-gravitational trap for diamagnetic particles, such as diamondmore » nanocrystals, with stable levitation from atmospheric pressure to high vacuum. Magnetic field gradients from permanent magnets confine the particle in two dimensions, while confinement in the third dimension is gravitational. Furthermore, we demonstrate that feedback cooling of the centre-of-mass motion of a trapped nanodiamond cluster results in cooling of one degree of freedom to less than 1 K.« less

  1. Characterization of trapped gas saturation and heterogeneity in core samples using miscible-displacement experiments

    SciTech Connect

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. A simple dispersion model and a three-coefficient dispersion-capacitance model (Coates-Smith) were fit to the experimental data. The dispersion-capacitance model successfully matched the experiments in which foam lamella formed, while the simple dispersion model was used only for determining initial core flow heterogeneity. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  2. Plasma Mass Filters For Nuclear Waste Reprocessing

    SciTech Connect

    Abraham J. Fetterman and Nathaniel J. Fisch

    2011-05-25

    Practical disposal of nuclear waste requires high-throughput separation techniques. The most dangerous part of nuclear waste is the fission product, which contains the most active and mobile radioisotopes and produces most of the heat. We suggest that the fission products could be separated as a group from nuclear waste using plasma mass filters. Plasmabased processes are well suited to separating nuclear waste, because mass rather than chemical properties are used for separation. A single plasma stage can replace several stages of chemical separation, producing separate streams of bulk elements, fission products, and actinoids. The plasma mass filters may have lower cost and produce less auxiliary waste than chemical processing plants. Three rotating plasma configurations are considered that act as mass filters: the plasma centrifuge, the Ohkawa filter, and the asymmetric centrifugal trap.

  3. Plasma Mass Filters For Nuclear Waste Reprocessing

    SciTech Connect

    Abraham J. Fetterman and Nathaniel J. Fisch

    2011-05-26

    Practical disposal of nuclear waste requires high-throughput separation techniques. The most dangerous part of nuclear waste is the fission product, which contains the most active and mobile radioisotopes and produces most of the heat. We suggest that the fission products could be separated as a group from nuclear waste using plasma mass filters. Plasmabased processes are well suited to separating nuclear waste, because mass rather than chemical properties are used for separation. A single plasma stage can replace several stages of chemical separation, producing separate streams of bulk elements, fission products, and actinoids. The plasma mass filters may have lower cost and produce less auxiliary waste than chemical processing plants. Three rotating plasma configurations are considered that act as mass filters: the plasma centrifuge, the Ohkawa filter, and the asymmetric centrifugal trap.

  4. Interface for the rapid analysis of liquid samples by accelerator mass spectrometry

    DOEpatents

    Turteltaub, Kenneth; Ognibene, Ted; Thomas, Avi; Daley, Paul F; Salazar Quintero, Gary A; Bench, Graham

    2014-02-04

    An interface for the analysis of liquid sample having carbon content by an accelerator mass spectrometer including a wire, defects on the wire, a system for moving the wire, a droplet maker for producing droplets of the liquid sample and placing the droplets of the liquid sample on the wire in the defects, a system that converts the carbon content of the droplets of the liquid sample to carbon dioxide gas in a helium stream, and a gas-accepting ion source connected to the accelerator mass spectrometer that receives the carbon dioxide gas of the sample in a helium stream and introduces the carbon dioxide gas of the sample into the accelerator mass spectrometer.

  5. Noise reduction in negative-ion quadrupole mass spectrometry

    DOEpatents

    Chastagner, Philippe

    1993-01-01

    A quadrupole mass spectrometer (QMS) system having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  6. Noise reduction in negative-ion quadrupole mass spectrometry

    DOEpatents

    Chastagner, P.

    1993-04-20

    A quadrupole mass spectrometer (QMS) system is described having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  7. Small system for tritium accelerator mass spectrometry

    DOEpatents

    Roberts, Mark L.; Davis, Jay C.

    1993-01-01

    Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and .sup.3 He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

  8. Small system for tritium accelerator mass spectrometry

    DOEpatents

    Roberts, M.L.; Davis, J.C.

    1993-02-23

    Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and [sup 3]He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

  9. Cast-to-shape electrokinetic trapping medium

    DOEpatents

    Shepodd, Timothy J.; Franklin, Elizabeth; Prickett, Zane T.; Artau, Alexander

    2004-08-03

    A three-dimensional microporous polymer network material, or monolith, cast-to-shape in a microchannel. The polymer monolith, produced by a phase separation process, is capable of trapping and retaining charged protein species from a mixture of charged and uncharged species under the influence of an applied electric field. The retained charged protein species are released from the porous polymer monolith by a pressure driven flow in the substantial absence of the electric field. The pressure driven flow is independent of direction and thus neither means to reverse fluid flow nor a multi-directional flow field is required, a single flow through the porous polymer monolith can be employed, in contrast to prior art systems. The monolithic polymer material produced by the invention can function as a chromatographic medium. Moreover, by virtue of its ability to retain charged protein species and quantitatively release the retained species the porous polymer monolith can serve as a means for concentrating charged protein species from, for example, a dilute solution.

  10. Cast-to-shape electrokinetic trapping medium

    DOEpatents

    Shepodd, Timothy J.; Franklin, Elizabeth; Prickett, Zane T.; Artau, Alexander

    2006-05-30

    A three-dimensional microporous polymer network material, or monolith, cast-to-shape in a microchannel. The polymer monolith, produced by a phase separation process, is capable of trapping and retaining charged protein species from a mixture of charged and uncharged species under the influence of an applied electric field. The retained charged protein species are released from the porous polymer monolith by a pressure driven flow in the substantial absence of the electric field. The pressure driven flow is independent of direction and thus neither means to reverse fluid flow nor a multi-directional flow field is required, a single flow through the porous polymer monolith can be employed, in contrast to prior art systems. The monolithic polymer material produced by the invention can function as a chromatographic medium. Moreover, by virtue of its ability to retain charged protein species and quantitatively release the retained species the porous polymer monolith can serve as a means for concentrating charged protein species from, for example, a dilute solution.

  11. Hydrogen isotope trapping in Al-Cu binary alloys

    SciTech Connect

    Chao, Paul; Karnesky, Richard A.

    2016-01-01

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high; for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.

  12. Hydrogen isotope trapping in Al-Cu binary alloys

    DOE PAGES [OSTI]

    Chao, Paul; Karnesky, Richard A.

    2016-01-01

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high;more » for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.« less

  13. Using malaise traps to sample ground beetles (Coleoptera. Carabidae)

    SciTech Connect

    Ulyshen, Michael D.; Hanula, James L.; Horn, Scott

    2012-04-02

    Pitfall traps provide an easy and inexpensive way to sample ground-dwelling arthropods (Spence and Niemela 1994; Spence et al. 1997; Abildsnes and Tommeras 2000) and have been used exclusively in many studies of the abundance and diversity of ground beetles (Coleoptera: Carabidae). Despite the popularity of this trapping technique, pitfall traps have many disadvantages. For example, they often fail to collect both small (Spence and Niemela 1994) and trap-shy species (Benest 1989), eventually deplete the local carabid population (Digweed et al. 1995), require a species to be ground-dwelling in order to be captured (Liebherr and Mahar 1979), and produce different results depending on trap diameter and material, type of preservative used, and trap placement (Greenslade 1964; Luff 1975; Work et al. 2002). Further complications arise from seasonal patterns of movement among the beetles themselves (Maelfait and Desender 1990), as well as numerous climatic factors, differences in plant cover, and variable surface conditions (Adis 1979). Because of these limitations, pitfall trap data give an incomplete picture of the carabid community and should be interpreted carefully. Additional methods, such as use of Berlese funnels and litter washing (Spence and Niemela 1994), collection from lights (Usis and MacLean 1998), and deployment of flight intercept devices (Liebherr and Mahar 1979; Paarmann and Stork 1987), should be incorporated in surveys to better ascertain the species composition and relative numbers of ground beetles. Flight intercept devices, like pitfall traps, have the advantage of being easy to use and replicate, but their value to carabid surveys is largely unknown. Here we demonstrate the effectiveness of Malaise traps for sampling ground beetles in a bottomland hardwood forest.

  14. Using malaise traps to sample ground beetles (Coleoptera: Carabidae).

    SciTech Connect

    Ulyshen, Michael D., James L. Hanula, and Scott Horn

    2005-01-01

    Pitfall traps provide an easy and inexpensive way to sample ground-dwelling arthropods (Spence and Niemela 1994; Spence et al. 1997; Abildsnes and Tommeras 2000) and have been used exclusively in many studies of the abundance and diversity of ground beetles (Coleoptera: Carabidae). Despite the popularity of this trapping technique, pitfall traps have many disadvantages. For example, they often fail to collect both small (Spence and Niemela 1994) and ? ????trap-shy?¢??? species (Benest 1989), eventually deplete the local carabid population (Digweed et al. 1995), require a species to be ground-dwelling in order to be captured (Liebherr and Mahar 1979), and produce different results depending on trap diameter and material, type of preservative used, and trap placement (Greenslade 1964; Luff 1975; Work et al. 2002). Further complications arise from seasonal patterns of movement among the beetles themselves (Maelfait and Desender 1990), as well as numerous climatic factors, differences in plant cover, and variable surface conditions (Adis 1979). Because of these limitations, pitfall trap data give an incomplete picture of the carabid community and should be interpreted carefully. Additional methods, such as use of Berlese funnels and litter washing (Spence and Niemela 1994), collection from lights (Usis and MacLean 1998), and deployment of flight intercept devices (Liebherr and Mahar 1979; Paarmann and Stork 1987), should be incorporated in surveys to better ascertain the species composition and relative numbers of ground beetles. Flight intercept devices, like pitfall traps, have the advantage of being easy to use and replicate, but their value to carabid surveys is largely unknown. Here we demonstrate the effectiveness of Malaise traps for sampling ground beetles in a bottomland hardwood forest.

  15. Further developments of capillary absorption spectrometers using small hollow-waveguide fibers

    SciTech Connect

    Kelly, James F.; Sams, Robert L.; Blake, Thomas A.; Kriesel, Jason M.

    2014-05-01

    Our objective is to enhance quantification of stable carbon and oxygen isotope ratios to better than 1 relative isotope precision for sample sizes < 1 pico-mole. A newer variant Capillary Absorption Spectrometer (CAS) is described using a proprietary linear-taper hollow waveguide in conjunction with wavelength and frequency modulation techniques of tunable laser absorption spectrometry. Previous work used circular capillaries with uniform 1 mm ID to measure 13C/12C ratios with ? 20 pico-mole samples to ? 10 ppm (1 precision against standards) [1]. While performing fairly well, it generated residual modal noise due to multipath propagation in the hollow-waveguides (HWGs). This system has been utilized with laser ablation-catalytic combustion techniques to analyze small resolution (~ 25 ?m spot diameter) laser ablation events on solids. Using smaller ID capillary waveguides could improve detection limits and spatial resolutions. Reducing an IR compatible hollow waveguides inner diameter (ID) to < 300 ?m, reduces modal noise significantly for mid-IR operation, but feedback noise with high gain semiconductor lasers can become problematic. A proprietary linear-taper small waveguide (mean ID = 0.35 mm, L = 1 m) was tested to understand whether modal noise and optical feedback effects could be simultaneously reduced. We see better mode filtering and, significant reductions of feedback noise under favorable coupling of a multi-spatial mode QC laser to the smaller ID of the linear-tapered HWG. We demonstrate that better modal coupling operation is consistent with Liouvilles theorem, where greater suppression of feedback from spurious scatter within the HWG occurs by injecting the laser into the smaller ID port. Our progress on developing lighter weight, potentially fieldable alternatives to Isotope Ratio Mass Spectrometers (IRMS) with a small volume (? 0.1 cm3) CAS system will be discussed and compared to other competitive systems.

  16. Method for predicting peptide detection in mass spectrometry

    DOEpatents

    Kangas, Lars [West Richland, WA; Smith, Richard D [Richland, WA; Petritis, Konstantinos [Richland, WA

    2010-07-13

    A method of predicting whether a peptide present in a biological sample will be detected by analysis with a mass spectrometer. The method uses at least one mass spectrometer to perform repeated analysis of a sample containing peptides from proteins with known amino acids. The method then generates a data set of peptides identified as contained within the sample by the repeated analysis. The method then calculates the probability that a specific peptide in the data set was detected in the repeated analysis. The method then creates a plurality of vectors, where each vector has a plurality of dimensions, and each dimension represents a property of one or more of the amino acids present in each peptide and adjacent peptides in the data set. Using these vectors, the method then generates an algorithm from the plurality of vectors and the calculated probabilities that specific peptides in the data set were detected in the repeated analysis. The algorithm is thus capable of calculating the probability that a hypothetical peptide represented as a vector will be detected by a mass spectrometry based proteomic platform, given that the peptide is present in a sample introduced into a mass spectrometer.

  17. Movement of particles using sequentially activated dielectrophoretic particle trapping

    DOEpatents

    Miles, Robin R.

    2004-02-03

    Manipulation of DNA and cells/spores using dielectrophoretic (DEP) forces to perform sample preparation protocols for polymerized chain reaction (PCR) based assays for various applications. This is accomplished by movement of particles using sequentially activated dielectrophoretic particle trapping. DEP forces induce a dipole in particles, and these particles can be trapped in non-uniform fields. The particles can be trapped in the high field strength region of one set of electrodes. By switching off this field and switching on an adjacent electrodes, particles can be moved down a channel with little or no flow.

  18. Scalable error correction in distributed ion trap computers

    SciTech Connect

    Oi, Daniel K. L.; Devitt, Simon J.; Hollenberg, Lloyd C. L.

    2006-11-15

    A major challenge for quantum computation in ion trap systems is scalable integration of error correction and fault tolerance. We analyze a distributed architecture with rapid high-fidelity local control within nodes and entangled links between nodes alleviating long-distance transport. We demonstrate fault-tolerant operator measurements which are used for error correction and nonlocal gates. This scheme is readily applied to linear ion traps which cannot be scaled up beyond a few ions per individual trap but which have access to a probabilistic entanglement mechanism. A proof-of-concept system is presented which is within the reach of current experiment.

  19. Trap seal for open circuit liquid cooled turbines

    DOEpatents

    Grondahl, Clayton M.; Germain, Malcolm R.

    1980-01-01

    An improved trap seal for open circuit liquid cooled turbines is disclosed. The trap seal of the present invention includes an annular recess formed in the supply conduit of cooling channels formed in the airfoil of the turbine buckets. A cylindrical insert is located in the annular recesses and has a plurality of axial grooves formed along the outer periphery thereof and a central recess formed in one end thereof. The axial grooves and central recess formed in the cylindrical insert cooperate with the annular recess to define a plurality of S-shaped trap seals which permit the passage of liquid coolant but prohibit passage of gaseous coolant.

  20. Design of blade-shaped-electrode linear ion traps with reduced anharmonic contributions

    SciTech Connect

    Deng, K.; Che, H.; Ge, Y. P.; Xu, Z. T.; Yuan, W. H.; Zhang, J.; Lu, Z. H.; Lan, Y.

    2015-09-21

    RF quadrupole linear Paul traps are versatile tools in quantum physics experiments. Linear Paul traps with blade-shaped electrodes have the advantages of larger solid angles for fluorescence collection. But with these kinds of traps, the existence of higher-order anharmonic terms of the trap potentials can cause large heating rate for the trapped ions. In this paper, we theoretically investigate the dependence of higher-order terms of trap potentials on the geometry of blade-shaped traps, and offer an optimized design. A modified blade electrodes trap is proposed to further reduce higher-order anharmonic terms while still retaining large fluorescence collection angle.

  1. Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts investigation of potential ...

  2. Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich...

    Office of Scientific and Technical Information (OSTI)

    Conference: Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich Materials Citation Details In-Document Search Title: Nitrogen Oxides as a Chemistry Trap in Detonating ...

  3. Determination of the direct double- β -decay Q value of Zr 96 and atomic masses of Zr 90 - 92 , 94 , 96 and Mo 92 , 94 - 98 , 100

    SciTech Connect

    Gulyuz, K.; Ariche, J.; Bollen, G.; Bustabad, S.; Eibach, M.; Izzo, C.; Novario, S. J.; Redshaw, M.; Ringle, R.; Sandler, R.; Schwarz, S.; Valverde, A. A.

    2015-05-06

    Experimental searches for neutrinoless double-β decay offer one of the best opportunities to look for physics beyond the standard model. Detecting this decay would confirm the Majorana nature of the neutrino, and a measurement of its half-life can be used to determine the absolute neutrino mass scale. Important to both tasks is an accurate knowledge of the Q value of the double-β decay. The LEBIT Penning trap mass spectrometer was used for the first direct experimental determination of the ⁹⁶Zr double-β decay Q value: Qββ=3355.85(15) keV. This value is nearly 7 keV larger than the 2012 Atomic Mass Evaluation [M. Wang et al., Chin. Phys. C 36, 1603 (2012)] value and one order of magnitude more precise. The 3-σ shift is primarily due to a more accurate measurement of the ⁹⁶Zr atomic mass: m(⁹⁶Zr)=95.90827735(17) u. Using the new Q value, the 2νββ-decay matrix element, |M|, is calculated. Improved determinations of the atomic masses of all other zirconium (90-92,94,96Zr) and molybdenum (92,94-98,100Mo) isotopes using both ¹²C₈ and ⁸⁷Rb as references are also reported.

  4. Focused analyte spray emission apparatus and process for mass spectrometric analysis

    DOEpatents

    Roach, Patrick J.; Laskin, Julia; Laskin, Alexander

    2012-01-17

    An apparatus and process are disclosed that deliver an analyte deposited on a substrate to a mass spectrometer that provides for trace analysis of complex organic analytes. Analytes are probed using a small droplet of solvent that is formed at the junction between two capillaries. A supply capillary maintains the droplet of solvent on the substrate; a collection capillary collects analyte desorbed from the surface and emits analyte ions as a focused spray to the inlet of a mass spectrometer for analysis. The invention enables efficient separation of desorption and ionization events, providing enhanced control over transport and ionization of the analyte.

  5. Fuel traps: mapping stability via water association.

    SciTech Connect

    Rempe, Susan L.; Clawson, Jacalyn S.; Greathouse, Jeffery A.; Alam, Todd M; Leung, Kevin; Varma, Sameer; Sabo, Dubravko; Martin, Marcus Gary; Cygan, Randall Timothy

    2007-03-01

    Hydrogen storage is a key enabling technology required for attaining a hydrogen-based economy. Fundamental research can reveal the underlying principles controlling hydrogen uptake and release by storage materials, and also aid in characterizing and designing novel storage materials. New ideas for hydrogen storage materials come from exploiting the properties of hydrophobic hydration, which refers to water s ability to stabilize, by its mode of association, specific structures under specific conditions. Although hydrogen was always considered too small to support the formation of solid clathrate hydrate structures, exciting new experiments show that water traps hydrogen molecules at conditions of low temperatures and moderate pressures. Hydrogen release is accomplished by simple warming. While these experiments lend credibility to the idea that water could form an environmentally attractive alternative storage compound for hydrogen fuel, which would advance our nation s goals of attaining a hydrogen-based economy, much work is yet required to understand and realize the full potential of clathrate hydrates for hydrogen storage. Here we undertake theoretical studies of hydrogen in water to establish a firm foundation for predictive work on clathrate hydrate H{sub 2} storage capabilities. Using molecular simulation and statistical mechanical theories based in part on quantum mechanical descriptions of molecular interactions, we characterize the interactions between hydrogen and liquid water in terms of structural and thermodynamic properties. In the process we validate classical force field models of hydrogen in water and discover new features of hydrophobic hydration that impact problems in both energy technology and biology. Finally, we predict hydrogen occupancy in the small and large cages of hydrogen clathrate hydrates, a property unresolved by previous experimental and theoretical work.

  6. IR Spectrometer Using 90-degree Off-axis Parabolic Mirrors

    SciTech Connect

    Robert M. Malone, Richard, G. Hacking, Ian J. McKenna, and Daniel H. Dolan

    2008-09-02

    A gated spectrometer has been designed for real-time, pulsed infrared (IR) studies at the National Synchrotron Light ource at the Brookhaven National Laboratory. A pair of 90-degree, off-axis parabolic mirrors are used to relay the light from an entrance slit to an output IR recording camera. With an initial wavelength range of 1500–4500 nm required, gratings could not be used in the spectrometer because grating orders would overlap. A magnesium oxide prism, placed between these parabolic mirrors, serves as the dispersion element. The spectrometer is doubly telecentric. With proper choice of the air spacing between the prism and the second parabolic mirror, any spectral region of interest within the InSb camera array’s sensitivity region can be recorded. The wavelengths leaving the second parabolic mirror are collimated, thereby relaxing the camera positioning tolerance. To set up the instrument, two different wavelength (visible) lasers are introduced at the entrance slit and made collinear with the optical axis via flip mirrors. After dispersion by the prism, these two laser beams are directed to tick marks located on the outside housing of the gated IR camera. This provides first-order wavelength calibration for the instrument. Light that is reflected off the front prism face is coupled into a high-speed detector to verify steady radiance during the gated spectral imaging. Alignment features include tick marks on the prism and parabolic mirrors. This instrument was designed to complement singlepoint pyrometry, which provides continuous time histories of a small collection of spots from shock-heated targets.

  7. FTIR spectrometer with solid-state drive system

    DOEpatents

    Rajic, Slobodan; Seals, Roland D.; Egert, Charles M.

    1999-01-01

    An FTIR spectrometer (10) and method using a solid-state drive system with thermally responsive members (27) that are subject to expansion upon heating and to contraction upon cooling. Such members (27) are assembled in the device (10) so as to move an angled, reflective surface (22) a small distance. The sample light beam (13) is received at a detector (24) along with a reference light beam (13) and there it is combined into a resulting signal. This allows the "interference" between the two beams to occur for spectral analysis by a processor (29).

  8. Positron lifetime spectrometer using a DC positron beam

    DOEpatents

    Xu, Jun; Moxom, Jeremy

    2003-10-21

    An entrance grid is positioned in the incident beam path of a DC beam positron lifetime spectrometer. The electrical potential difference between the sample and the entrance grid provides simultaneous acceleration of both the primary positrons and the secondary electrons. The result is a reduction in the time spread induced by the energy distribution of the secondary electrons. In addition, the sample, sample holder, entrance grid, and entrance face of the multichannel plate electron detector assembly are made parallel to each other, and are arranged at a tilt angle to the axis of the positron beam to effectively separate the path of the secondary electrons from the path of the incident positrons.

  9. Chemical detection using the airborne thermal infrared imaging spectrometer (TIRIS)

    SciTech Connect

    Gat, N.; Subramanian, S.; Sheffield, M.; Erives, H.; Barhen, J.

    1997-04-01

    A methodology is described for an airborne, downlooking, longwave infrared imaging spectrometer based technique for the detection and tracking of plumes of toxic gases. Plumes can be observed in emission or absorption, depending on the thermal contrast between the vapor and the background terrain. While the sensor is currently undergoing laboratory calibration and characterization, a radiative exchange phenomenology model has been developed to predict sensor response and to facilitate the sensor design. An inverse problem model has also been developed to obtain plume parameters based on sensor measurements. These models, the sensors, and ongoing activities are described.

  10. Laser-driven Sisyphus cooling in an optical dipole trap

    SciTech Connect

    Ivanov, Vladyslav V.; Gupta, Subhadeep

    2011-12-15

    We propose a laser-driven Sisyphus-cooling scheme for atoms confined in a far-off resonance optical dipole trap. Utilizing the differential trap-induced ac Stark shift, two electronic levels of the atom are resonantly coupled by a cooling laser preferentially near the trap bottom. After absorption of a cooling photon, the atom loses energy by climbing the steeper potential, and then spontaneously decays preferentially away from the trap bottom. The proposed method is particularly suited to cooling alkaline-earth-metal-like atoms where two-level systems with narrow electronic transitions are present. Numerical simulations for the cases of {sup 88}Sr and {sup 174}Yb demonstrate the expected recoil and Doppler temperature limits. The method requires a relatively small number of scattered photons and can potentially lead to phase-space densities approaching quantum degeneracy in subsecond time scales.

  11. DOE - NNSA/NFO -- News & Views Accident Trap

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Accident Traps Four Workers 1,800 Feet below Ground Photo - rescue from 1,800 feet below ... Thousands of workers have completed millions of accident-free hours at this heavy industry ...

  12. Stable Metal-Organic Frameworks Containing Single-Molecule Traps...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Stable Metal-Organic Frameworks Containing Single-Molecule Traps for Enzyme Encapsulation Previous Next List Dawei Feng, Tian-Fu Liu, Jie Su, Mathieu Bosch, Zhangwen Wei, Wei Wan,...

  13. Catch and Release: Reaction Dynamics from a Freed "Tension Trapped...

    Office of Scientific and Technical Information (OSTI)

    Title: Catch and Release: Reaction Dynamics from a Freed "Tension Trapped Transition State" Authors: Wang, J ; Ong, M T ; Kouznetsova, T B ; Lenhardt, J M ; Martinez, T J ; Craig, ...

  14. Light Trapping, Absorption and Solar Energy Harvesting by Artificial Materials

    SciTech Connect

    John, Sajeev

    2014-08-15

    We provide designs of thin-film solar cells utilizing optimized photonic-crystal light-trapping and numerical simulations of their solar-to-electrical power conversion efficiencies.

  15. Stories of Discovery & Innovation: Trapping the Light Fantastic...

    Office of Science (SC)

    Stories of Discovery & Innovation: Trapping the Light Fantastic Print Text Size: A A A Subscribe FeedbackShare Page New solar cell design uses advanced optics and nanotechnology to ...

  16. Inspect and Repair Steam Traps - Steam Tip Sheet #1

    SciTech Connect

    2012-01-31

    This revised AMO tip sheet on inspecting and repairing steam traps provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  17. Bose-Einstein condensation of trapped polaritons in two-dimensional electron-hole systems in a high magnetic field

    SciTech Connect

    Berman, Oleg L.; Kezerashvili, Roman Ya.; Lozovik, Yurii E.

    2009-09-15

    The Bose-Einstein condensation (BEC) of magnetoexcitonic polaritons (magnetopolaritons) in two-dimensional (2D) electron-hole system embedded in a semiconductor microcavity in a high magnetic field B is predicted. There are two physical realizations of 2D electron-hole system under consideration: a graphene layer and quantum well (QW). A 2D gas of magnetopolaritons is considered in a planar harmonic potential trap. Two possible physical realizations of this trapping potential are assumed: inhomogeneous local stress or harmonic electric field potential applied to excitons and a parabolic shape of the semiconductor cavity causing the trapping of microcavity photons. The effective Hamiltonian of the ideal gas of cavity polaritons in a QW and graphene in a high magnetic field and the BEC temperature as functions of magnetic field are obtained. It is shown that the effective polariton mass M{sub eff} increases with magnetic field as B{sup 1/2}. The BEC critical temperature T{sub c}{sup (0)} decreases as B{sup -1/4} and increases with the spring constant of the parabolic trap. The Rabi splitting related to the creation of a magnetoexciton in a high magnetic field in graphene and QW is obtained. It is shown that Rabi splitting in graphene can be controlled by the external magnetic field since it is proportional to B{sup -1/4} while in a QW the Rabi splitting does not depend on the magnetic field when it is strong.

  18. Grooved impactor and inertial trap for sampling inhalable particulate matter

    DOEpatents

    Loo, Billy W.

    1984-01-01

    An inertial trap and grooved impactor for providing a sharp cutoff for particles over 15 microns from entering an inhalable particulate sampler. The impactor head has a tapered surface and is provided with V-shaped grooves. The tapered surface functions for reducing particle blow-off or reentrainment while the grooves prevent particle bounce. Water droplets and any resuspended material over the 15 micron size are collected by the inertial trap and deposited in a reservoir associated with the impactor.

  19. Optical apparatus for forming correlation spectrometers and optical processors

    DOEpatents

    Butler, M.A.; Ricco, A.J.; Sinclair, M.B.; Senturia, S.D.

    1999-05-18

    Optical apparatus is disclosed for forming correlation spectrometers and optical processors. The optical apparatus comprises one or more diffractive optical elements formed on a substrate for receiving light from a source and processing the incident light. The optical apparatus includes an addressing element for alternately addressing each diffractive optical element thereof to produce for one unit of time a first correlation with the incident light, and to produce for a different unit of time a second correlation with the incident light that is different from the first correlation. In preferred embodiments of the invention, the optical apparatus is in the form of a correlation spectrometer; and in other embodiments, the apparatus is in the form of an optical processor. In some embodiments, the optical apparatus comprises a plurality of diffractive optical elements on a common substrate for forming first and second gratings that alternately intercept the incident light for different units of time. In other embodiments, the optical apparatus includes an electrically-programmable diffraction grating that may be alternately switched between a plurality of grating states thereof for processing the incident light. The optical apparatus may be formed, at least in part, by a micromachining process. 24 figs.

  20. High resolution, high rate X-ray spectrometer

    DOEpatents

    Goulding, Frederick S.; Landis, Donald A.

    1987-01-01

    A pulse processing system (10) for use in an X-ray spectrometer in which a ain channel pulse shaper (12) and a fast channel pulse shaper (13) each produce a substantially symmetrical triangular pulse (f, p) for each event detected by the spectrometer, with the pulse width of the pulses being substantially independent of the magnitude of the detected event and with the pulse width of the fast pulses (p) being substantially shorter than the pulse width of the main channel pulses (f). A pile-up rejector circuit (19) allows output pulses to be generated, with amplitudes linearly related to the magnitude of the detected events, whenever the peak of a main channel pulse (f) is not affected by a preceding or succeeding main channel pulse, while inhibiting output pulses wherein peak magnitudes of main channel pulses are affected by adjacent pulses. The substantially symmetrical triangular main channel pulses (f) are generated by the weighted addition (27-31) of successive RC integrations (24, 25, 26) of an RC differentiated step wave (23). The substantially symmetrical triangular fast channel pulses (p) are generated by the RC integration ( 43) of a bipolar pulse (o) in which the amplitude of the second half is 1/e that of the first half, with the RC time constant of integration being equal to one-half the width of the bipolar pulse.

  1. Optical apparatus for forming correlation spectrometers and optical processors

    DOEpatents

    Butler, Michael A.; Ricco, Antonio J.; Sinclair, Michael B.; Senturia, Stephen D.

    1999-01-01

    Optical apparatus for forming correlation spectrometers and optical processors. The optical apparatus comprises one or more diffractive optical elements formed on a substrate for receiving light from a source and processing the incident light. The optical apparatus includes an addressing element for alternately addressing each diffractive optical element thereof to produce for one unit of time a first correlation with the incident light, and to produce for a different unit of time a second correlation with the incident light that is different from the first correlation. In preferred embodiments of the invention, the optical apparatus is in the form of a correlation spectrometer; and in other embodiments, the apparatus is in the form of an optical processor. In some embodiments, the optical apparatus comprises a plurality of diffractive optical elements on a common substrate for forming first and second gratings that alternately intercept the incident light for different units of time. In other embodiments, the optical apparatus includes an electrically-programmable diffraction grating that may be alternately switched between a plurality of grating states thereof for processing the incident light. The optical apparatus may be formed, at least in part, by a micromachining process.

  2. Light ion transfer reactions with the HELIOS spectrometer

    SciTech Connect

    Back, B. B.; Collaboration: HELIOS Collaboration

    2012-10-20

    Light-ion induced transfer and inelastic scattering reactions on stable or long-lived targets have been used extensively to study the structure of nuclei near the line of {beta}-stability, and much of the detailed information on the single-particle structure of nuclei has been derived from such studies. Recently, however, a substantial expansion of the range of isotopes, for which this nuclear structure information can be obtained, has presented itself by using radioactive beams in inverse kinematics reactions. Such beams are now available at a number of facilities around the world, including the in-flight production method and CARIBU facility at ATLAS. The HELIOS spectrometer, which has been used since August 2008 at ATLAS, circumvents many of the problems associated with inverse kinematics. In this talk I will discuss the principle of the spectrometer as well as some of main physics results that have been obtained to date in nuclei ranging from {sup 13}B to {sup 137}Xe using both stable and radioactive beams.

  3. Ion source for high-precision mass spectrometry

    DOEpatents

    Todd, P.J.; McKown, H.S.; Smith, D.H.

    1982-04-26

    The invention is directed to a method for increasing the precision of positive-ion relative abundance measurements conducted in a sector mass spectrometer having an ion source for directing a beam of positive ions onto a collimating slit. The method comprises incorporating in the source an electrostatic lens assembly for providing a positive-ion beam of circular cross section for collimation by the slit. 2 figures, 3 tables.

  4. Ion source for high-precision mass spectrometry

    DOEpatents

    Todd, Peter J.; McKown, Henry S.; Smith, David H.

    1984-01-01

    The invention is directed to a method for increasing the precision of positive-ion relative abundance measurements conducted in a sector mass spectrometer having an ion source for directing a beam of positive ions onto a collimating slit. The method comprises incorporating in the source an electrostatic lens assembly for providing a positive-ion beam of circular cross section for collimation by the slit.

  5. Investigation of Aging Mechanisms in Lean NOx Traps

    SciTech Connect

    Mark Crocker

    2010-03-31

    Lean NO{sub x} traps (LNTs) represent a promising technology for the abatement of NO{sub x} under lean conditions. Although LNTs are starting to find commercial application, the issue of catalyst durability remains problematic. LNT susceptibility to sulfur poisoning is the single most important factor determining effective catalyst lifetime. The NO{sub x} storage element of the catalyst has a greater affinity for SO{sub 3} than it does for NO{sub 2}, and the resulting sulfate is more stable than the stored nitrate. Although this sulfate can be removed from the catalyst by means of high temperature treatment under rich conditions, the required conditions give rise to deactivation mechanisms such as precious metal sintering, total surface area loss, and solid state reactions between the various oxides present. The principle objective of this project was to improve understanding of the mechanisms of lean NO{sub x} trap aging, and to understand the effect of washcoat composition on catalyst aging characteristics. The approach utilized involved detailed characterization of model catalysts prior to and after aging, in tandem with measurement of catalyst performance in NO{sub x} storage and reduction. In this manner, NO{sub x} storage and reduction characteristics were correlated with the evolution of catalyst physico-chemical properties upon aging. Rather than using poorly characterized proprietary catalysts, or simple model catalysts of the Pt/BaO/Al{sub 2}O{sub 3} type (representing the first generation of LNTs), Pt/Rh/BaO/Al{sub 2}O{sub 3} catalysts were employed which also incorporated CeO{sub 2} or CeO{sub 2}-ZrO{sub 2}, representing a model system which more accurately reflects current LNT formulations. Catalysts were prepared in which the concentration of each of the main components was systematically varied: Pt (50, 75 or 100 g/ft{sup 3}), Rh (10 or 20 g/ft{sup 3}), BaO (15, 30 or 45 g/L), and either CeO{sub 2} (0, 50 or 100 g/L) or CeO{sub 2}-ZrO{sub 2} (0, 50

  6. A high-resolution imaging X-ray crystal spectrometer for intense...

    Office of Scientific and Technical Information (OSTI)

    for intense laser plasma interaction experiments Citation Details In-Document Search Title: A high-resolution imaging X-ray crystal spectrometer for intense laser plasma ...

  7. Spin Spectrometer at the ALS and APS (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Resource Type: Journal Article Resource Relation: Journal Name: Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and ...

  8. Atomic data for the ITER Core Imaging X-ray Spectrometer (Conference...

    Office of Scientific and Technical Information (OSTI)

    Here, some aspects of the underlying physics are discussed using experimental data and ... L SHELL; MEETINGS; PHYSICS; PLASMA; SIMULATION; SPECTRA; SPECTROMETERS; TUNGSTEN; ...

  9. High-resolution grazing-incidence grating spectrometer for temperature measurements of low-Z ions emitting in the 100–300 Å spectral band

    SciTech Connect

    Widmann, K. Beiersdorfer, P.; Magee, E. W.; Boyle, D. P.; Kaita, R.; Majeski, R.

    2014-11-15

    We have constructed a high-resolution grazing-incidence spectrometer designed for measuring the ion temperature of low-Z elements, such as Li{sup +} or Li{sup 2+}, which radiate near 199 Å and 135 Å, respectively. Based on measurements at the Livermore Electron Beam Ion Trap we have shown that the instrumental resolution is better than 48 mÅ at the 200 Å setting and better than 40 mÅ for the 135-Å range. Such a high spectral resolution corresponds to an instrumental limit for line-width based temperature measurements of about 45 eV for the 199 Å Li{sup +} and 65 eV for the 135 Å Li{sup 2+} lines. Recently obtained survey spectra from the Lithium Tokamak Experiment at the Princeton Plasma Physics Laboratory show the presence of these lithium emission lines and the expected core ion temperature of approximately 70 eV is sufficiently high to demonstrate the feasibility of utilizing our high-resolution spectrometer as an ion-temperature diagnostic.

  10. Characterisation of deuterium spectra from laser driven multi-species sources by employing differentially filtered image plate detectors in Thomson spectrometers

    SciTech Connect

    Alejo, A.; Kar, S. Ahmed, H.; Doria, D.; Green, A.; Jung, D.; Lewis, C. L. S.; Nersisyan, G.; Krygier, A. G.; Freeman, R. R.; Clarke, R.; Green, J. S.; Notley, M.; Fernandez, J.; Fuchs, J.; Kleinschmidt, A.; Roth, M.; Morrison, J. T.; Najmudin, Z.; Nakamura, H.; and others

    2014-09-15

    A novel method for characterising the full spectrum of deuteron ions emitted by laser driven multi-species ion sources is discussed. The procedure is based on using differential filtering over the detector of a Thompson parabola ion spectrometer, which enables discrimination of deuterium ions from heavier ion species with the same charge-to-mass ratio (such as C{sup 6+}, O{sup 8+}, etc.). Commonly used Fuji Image plates were used as detectors in the spectrometer, whose absolute response to deuterium ions over a wide range of energies was calibrated by using slotted CR-39 nuclear track detectors. A typical deuterium ion spectrum diagnosed in a recent experimental campaign is presented, which was produced from a thin deuterated plastic foil target irradiated by a high power laser.

  11. Development of high-spatial and high-mass resolution mass spectrometric imaging (MSI) and its application to the study of small metabolites and endogenous molecules of plants

    SciTech Connect

    Jun, Ji Hyun

    2011-11-30

    High-spatial and high-mass resolution laser desorption ionization (LDI) mass spectrometric (MS) imaging technology was developed for the attainment of MS images of higher quality containing more information on the relevant cellular and molecular biology in unprecedented depth. The distribution of plant metabolites is asymmetric throughout the cells and tissues, and therefore the increase in the spatial resolution was pursued to reveal the localization of plant metabolites at the cellular level by MS imaging. For achieving high-spatial resolution, the laser beam size was reduced by utilizing an optical fiber with small core diameter (25 μm) in a vacuum matrix-assisted laser desorption ionization-linear ion trap (vMALDI-LTQ) mass spectrometer. Matrix application was greatly improved using oscillating capillary nebulizer. As a result, single cell level spatial resolution of ~ 12 μm was achieved. MS imaging at this high spatial resolution was directly applied to a whole Arabidopsis flower and the substructures of an anther and single pollen grains at the stigma and anther were successfully visualized. MS imaging of high spatial resolution was also demonstrated to the secondary roots of Arabidopsis thaliana and a high degree of localization of detected metabolites was successfully unveiled. This was the first MS imaging on the root for molecular species. MS imaging with high mass resolution was also achieved by utilizing the LTQ-Orbitrap mass spectrometer for the direct identification of the surface metabolites on the Arabidopsis stem and root and differentiation of isobaric ions having the same nominal mass with no need of tandem mass spectrometry (MS/MS). MS imaging at high-spatial and high-mass resolution was also applied to cer1 mutant of the model system Arabidopsis thaliana to demonstrate its usefulness in biological studies and reveal associated metabolite changes in terms of spatial distribution and/or abundances compared to those of wild-type. The spatial

  12. Method for analyzing the mass of a sample using a cold cathode ionization source mass filter

    DOEpatents

    Felter, Thomas E.

    2003-10-14

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  13. System and method for trapping and measuring a charged particle in a liquid

    DOEpatents

    Reed, Mark A; Krstic, Predrag S; Guan, Weihua; Zhao, Xiongce

    2013-07-23

    A system and method for trapping a charged particle is disclosed. A time-varying periodic multipole electric potential is generated in a trapping volume. A charged particle under the influence of the multipole electric field is confined to the trapping volume. A three electrode configuration giving rise to a 3D Paul trap and a four planar electrode configuration giving rise to a 2D Paul trap are disclosed.

  14. System and method for trapping and measuring a charged particle in a liquid

    DOEpatents

    Reed, Mark A; Krstic, Predrag S; Guan, Weihua; Zhao, Xiongce

    2012-10-23

    A system and method for trapping a charged particle is disclosed. A time-varying periodic multipole electric potential is generated in a trapping volume. A charged particle under the influence of the multipole electric field is confined to the trapping volume. A three electrode configuration giving rise to a 3D Paul trap and a four planar electrode configuration giving rise to a 2D Paul trap are disclosed.

  15. Aerosol beam-focus laser-induced plasma spectrometer device

    DOEpatents

    Cheng, Meng-Dawn

    2002-01-01

    An apparatus for detecting elements in an aerosol includes an aerosol beam focuser for concentrating aerosol into an aerosol beam; a laser for directing a laser beam into the aerosol beam to form a plasma; a detection device that detects a wavelength of a light emission caused by the formation of the plasma. The detection device can be a spectrometer having at least one grating and a gated intensified charge-coupled device. The apparatus may also include a processor that correlates the wavelength of the light emission caused by the formation of the plasma with an identity of an element that corresponds to the wavelength. Furthermore, the apparatus can also include an aerosol generator for forming an aerosol beam from bulk materials. A method for detecting elements in an aerosol is also disclosed.

  16. Isotopic response with small scintillator based gamma-ray spectrometers

    DOEpatents

    Madden, Norman W.; Goulding, Frederick S.; Asztalos, Stephen J.

    2012-01-24

    The intrinsic background of a gamma ray spectrometer is significantly reduced by surrounding the scintillator with a second scintillator. This second (external) scintillator surrounds the first scintillator and has an opening of approximately the same diameter as the smaller central scintillator in the forward direction. The second scintillator is selected to have a higher atomic number, and thus has a larger probability for a Compton scattering interaction than within the inner region. Scattering events that are essentially simultaneous in coincidence to the first and second scintillators, from an electronics perspective, are precluded electronically from the data stream. Thus, only gamma-rays that are wholly contained in the smaller central scintillator are used for analytic purposes.

  17. Absolute calibration for a broad range single shot electron spectrometer

    SciTech Connect

    Glinec, Y.; Faure, J.; Guemnie-Tafo, A.; Malka, V.; Monard, H.; Larbre, J. P.; De Waele, V.; Marignier, J. L.; Mostafavi, M.

    2006-10-15

    This article gives a detailed description of a single shot electron spectrometer which was used to characterize electron beams produced by laser-plasma interaction. Contrary to conventional electron sources, electron beams from laser-plasma accelerators can produce a broad range of energies. Therefore, diagnosing these electron spectra requires specific attention and experimental development. Here, we provide an absolute calibration of the Lanex Kodak Fine screen on a laser-triggered radio frequency picosecond electron accelerator. The efficiency of scintillating screens irradiated by electron beams has never been investigated so far. This absolute calibration is then compared to charge measurements from an integrating current transformer for quasimonoenergetic electron spectra from laser-plasma interaction.

  18. Ion mobility spectrometer using frequency-domain separation

    DOEpatents

    Martin, Stephen J.; Butler, Michael A.; Frye, Gregory C.; Schubert, W. Kent

    1998-01-01

    An apparatus and method is provided for separating and analyzing chemical species in an ion mobility spectrometer using a frequency-domain technique wherein the ions generated from the chemical species are selectively transported through an ion flow channel having a moving electrical potential therein. The moving electrical potential allows the ions to be selected according to ion mobility, with certain of the ions being transported to an ion detector and other of the ions being effectively discriminated against. The apparatus and method have applications for sensitive chemical detection and analysis for monitoring of exhaust gases, hazardous waste sites, industrial processes, aerospace systems, non-proliferation, and treaty verification. The apparatus can be formed as a microelectromechanical device (i.e. a micromachine).

  19. Imaging X-ray Thomson Scattering Spectrometer Design and Demonstration

    SciTech Connect

    Gamboa, E.J.; Huntington, C.M.; Trantham, M.R.; Keiter, P.A; Drake, R.P.; Montgomery, David; Benage, John F.; Letzring, Samuel A.

    2012-05-04

    In many laboratory astrophysics experiments, intense laser irradiation creates novel material conditions with large, one-dimensional gradients in the temperature, density, and ionization state. X-ray Thomson scattering is a powerful technique for measuring these plasma parameters. However, the scattered signal has previously been measured with little or no spatial resolution, which limits the ability to diagnose inhomogeneous plasmas. We report on the development of a new imaging x-ray Thomson spectrometer (IXTS) for the Omega laser facility. The diffraction of x-rays from a toroidally-curved crystal creates high-resolution images that are spatially resolved along a one-dimensional profile while spectrally dispersing the radiation. This focusing geometry allows for high brightness while localizing noise sources and improving the linearity of the dispersion. Preliminary results are presented from a scattering experiment that used the IXTS to measure the temperature profile of a shocked carbon foam.

  20. THE ABSOLUTE CALIBRATION OF THE EUV IMAGING SPECTROMETER ON HINODE

    SciTech Connect

    Warren, Harry P.; Ugarte-Urra, Ignacio; Landi, Enrico

    2014-07-01

    We investigate the absolute calibration of the EUV Imaging Spectrometer (EIS) on Hinode by comparing EIS full-disk mosaics with irradiance observations from the EUV Variability Experiment on the Solar Dynamics Observatory. We also use extended observations of the quiet corona above the limb combined with a simple differential emission measure model to establish new effective area curves that incorporate information from the most recent atomic physics calculations. We find that changes to the EIS instrument sensitivity are a complex function of both time and wavelength. We find that the sensitivity is decaying exponentially with time and that the decay constants vary with wavelength. The EIS short wavelength channel shows significantly longer decay times than the long wavelength channel.

  1. Ion mobility spectrometer using frequency-domain separation

    DOEpatents

    Martin, S.J.; Butler, M.A.; Frye, G.C.; Schubert, W.K.

    1998-08-04

    An apparatus and method are provided for separating and analyzing chemical species in an ion mobility spectrometer using a frequency-domain technique wherein the ions generated from the chemical species are selectively transported through an ion flow channel having a moving electrical potential therein. The moving electrical potential allows the ions to be selected according to ion mobility, with certain of the ions being transported to an ion detector and other of the ions being effectively discriminated against. The apparatus and method have applications for sensitive chemical detection and analysis for monitoring of exhaust gases, hazardous waste sites, industrial processes, aerospace systems, non-proliferation, and treaty verification. The apparatus can be formed as a microelectromechanical device (i.e. a micromachine). 6 figs.

  2. Automatic Energy Calibration of Gamma-Ray Spectrometers

    Energy Science and Technology Software Center

    2011-09-19

    The software provides automatic method for calibrating the energy scale of high-purity germanium (HPGe) and scintillation gamma-ray spectrometers, using natural background radiation as the source of calibration gamma rays. In field gamma-ray spectroscopy, radioactive check sources may not be available; temperature changes can shift detector electronic gain and scintillator light output; and a user’s experience and training may not include gamma-ray energy calibration. Hence, an automated method of calibrating the spectrometer using natural background wouldmore » simplify its operation, especially by technician-level users, and by enhancing spectroscopic data quality, it would reduce false detections. Following a typically one-minute count of background gamma-rays, the measured spectrum is searched for gamma-ray peaks, producing a list of peak centroids, in channels1. Next, the ratio algorithm attempts to match the peak centroids found in the search to a user-supplied list of calibration gamma-ray energies. Finally, if three or more calibration energies have been matched to peaks, the energy equation parameters are determined by a least-squares fit2, and the spectrum has been energy-calibrated. The ratio algorithm rests on the repeatable but irregular spacing of the background gammaray energies—together they form a unique set of ratios, when normalized to the highest energy calibration gamma ray; so too, the corresponding peak centroids in the spectrum. The algorithm matches energy ratios to peak centroid ratios, to determine which peak matches a given calibration energy.« less

  3. Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry

    DOEpatents

    Yeung, Edward S.; Chang, Yu-chen

    1999-06-29

    The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent.

  4. Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry

    DOEpatents

    Yeung, E.S.; Chang, Y.C.

    1999-06-29

    The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

  5. Passive Spectroscopy Bolometers, Grating- And X-Ray Imaging Crystal Spectrometers

    SciTech Connect

    Bitter, M; Hill, K W; Scott, S; Paul, S; Ince-Cushmann, A; Reinke, M; Rice, J; Beiersdorfer, P; Gu, M F; Lee, S G; Broennimann, C; Eikenberry, E F

    2007-11-07

    This tutorial gives a brief introduction into passive spectroscopy and describes the working principles of bolometers, a high-resolution grating spectrometer, and a novel X-ray imaging crystal spectrometer, which is of particular interest for profile measurements of the ion temperature and plasma rotation velocity on ITER and future burning plasma experiments.

  6. Simulation-guided optimization of small-angle analyzer geometry in the neutron backscattering spectrometer SPHERES

    SciTech Connect

    Wuttke, Joachim; Zamponi, Michaela [Forschungszentrum Jlich GmbH, Jlich Centre for Neutron Science at MLZ, Lichtenbergstrae 1, 85747 Garching (Germany)] [Forschungszentrum Jlich GmbH, Jlich Centre for Neutron Science at MLZ, Lichtenbergstrae 1, 85747 Garching (Germany)

    2013-11-15

    The resolution of neutron backscattering spectrometers deteriorates at small scattering angles where analyzers deviate from exact backscattering. By reducing the azimuth angle range of the analyzers, the resolution can be improved with little loss of peak intensity. Measurements at the spectrometer SPHERES are in excellent agreement with simulations, which proves the dominance of geometric effects.

  7. Optical lattice clock with atoms confined in a shallow trap

    SciTech Connect

    Lemonde, Pierre; Wolf, Peter

    2005-09-15

    We study the trap depth requirement for the realization of an optical clock using atoms confined in a lattice. We show that site-to-site tunneling leads to a residual sensitivity to the atom dynamics hence requiring large depths [(50-100)E{sub r} for Sr] to avoid any frequency shift or line broadening of the atomic transition at the 10{sup -17}-10{sup -18} level. Such large depths and the corresponding laser power may, however, lead to difficulties (e.g., higher-order light shifts, two-photon ionization, technical difficulties) and therefore one would like to operate the clock in much shallower traps. To circumvent this problem we propose the use of an accelerated lattice. Acceleration lifts the degeneracy between adjacents potential wells which strongly inhibits tunneling. We show that using the Earth's gravity, much shallower traps (down to 5E{sub r} for Sr) can be used for the same accuracy goal.

  8. Recent progress in tailoring trap-based positron beams

    SciTech Connect

    Natisin, M. R.; Hurst, N. C.; Danielson, J. R.; Surko, C. M.

    2013-03-19

    Recent progress is described to implement two approaches to specially tailor trap-based positron beams. Experiments and simulations are presented to understand the limits on the energy spread and pulse duration of positron beams extracted from a Penning-Malmberg (PM) trap after the particles have been buffer-gas cooled (or heated) in the range of temperatures 1000 {>=} T {>=} 300 K. These simulations are also used to predict beam performance for cryogenically cooled positrons. Experiments and simulations are also presented to understand the properties of beams formed when plasmas are tailored in a PM trap in a 5 tesla magnetic field, then non-adiabatically extracted from the field using a specially designed high-permeability grid to create a new class of electrostatically guided beams.

  9. Global strings in extra dimensions: The full map of solutions, matter trapping, and the hierarchy problem

    SciTech Connect

    Bronnikov, K. A.; Meierovich, B. E.

    2008-02-15

    We consider (d{sub 0} + 2)-dimensional configurations with global strings in two extra dimensions and a flat metric in d{sub 0} dimensions, endowed with a warp factor e{sup 2{gamma}} depending on the distance l from the string center. All possible regular solutions of the field equations are classified by the behavior of the warp factor and the extradimensional circular radius r(l). Solutions with r {yields} {infinity} and r {yields} const > 0 as l {yields} {infinity} are interpreted in terms of thick brane-world models. Solutions with r {yields} 0 as l {yields} l{sub c} > 0, i.e., those with a second center, are interpreted as either multibrane systems (which are appropriate for large enough distances l{sub c} between the centers) or as Kaluza-Klein-type configurations with extra dimensions invisible due to their smallness. In the case of the Mexican-hat symmetry-breaking potential, we build the full map of regular solutions on the ({epsilon}, {Gamma}) parameter plane, where {epsilon} acts as an effective cosmological constant and {Gamma} characterizes the gravitational field strength. The trapping properties of candidate brane worlds for test scalar fields are discussed. Good trapping properties for massive fields are found for models with increasing warp factors. Kaluza-Klein-type models are shown to have nontrivial warp factor behaviors, leading to matter particle mass spectra that seem promising from the standpoint of hierarchy problems.

  10. Global strings in extra dimensions: The full map of solutions, matter trapping, and the hierarchy problem

    SciTech Connect

    Bronnikov, K. A.; Meierovich, B. E.

    2008-02-15

    We consider (d{sub 0} + 2)-dimensional configurations with global strings in two extra dimensions and a flat metric in d{sub 0} dimensions, endowed with a warp factor e{sup 2{gamma}} depending on the distance l from the string center. All possible regular solutions of the field equations are classified by the behavior of the warp factor and the extradimensional circular radius r(l). Solutions with r {sup {yields}} {infinity} and r {sup {yields}} const > 0 as l {sup {yields}} {infinity} are interpreted in terms of thick brane-world models. Solutions with r {sup {yields}} 0 as l {sup {yields}} l{sub c} > 0, i.e., those with a second center, are interpreted as either multibrane systems (which are appropriate for large enough distances l{sub c} between the centers) or as Kaluza-Klein-type configurations with extra dimensions invisible due to their smallness. In the case of the Mexican-hat symmetry-breaking potential, we build the full map of regular solutions on the ({epsilon}, {gamma}) parameter plane, where {epsilon} acts as an effective cosmological constant and {gamma} characterizes the gravitational field strength. The trapping properties of candidate brane worlds for test scalar fields are discussed. Good trapping properties for massive fields are found for models with increasing warp factors. Kaluza-Klein-type models are shown to have nontrivial warp factor behaviors, leading to matter particle mass spectra that seem promising from the standpoint of hierarchy problems.

  11. Echelle grating multi-order imaging spectrometer utilizing a catadioptric lens

    DOEpatents

    Chrisp, Michael P; Bowers, Joel M

    2014-05-27

    A cryogenically cooled imaging spectrometer that includes a spectrometer housing having a first side and a second side opposite the first side. An entrance slit is on the first side of the spectrometer housing and directs light to a cross-disperser grating. An echelle immersions grating and a catadioptric lens are positioned in the housing to receive the light. A cryogenically cooled detector is located in the housing on the second side of the spectrometer housing. Light from the entrance slit is directed to the cross-disperser grating. The light is directed from the cross-disperser grating to the echelle immersions grating. The light is directed from the echelle immersions grating to the cryogenically cooled detector on the second side of the spectrometer housing.

  12. Electron beam ion source and electron beam ion trap (invited)

    SciTech Connect

    Becker, Reinard [Scientific Software Service, Kapellenweg 2a, D-63571 Gelnhausen (Germany); Kester, Oliver [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)

    2010-02-15

    The electron beam ion source (EBIS) and its trap variant [electron beam ion trap (EBIT)] celebrated their 40th and 20th anniversary, respectively, at the EBIS/T Symposium 2007 in Heidelberg. These technologically challenging sources of highly charged ions have seen a broad development in many countries over the last decades. In contrast to most other ion sources the recipe of improvement was not ''sorcery'' but a clear understanding of the physical laws and obeying the technological constraints. This review will report important achievements of the past as well as promising developments in the future.

  13. Three dimensional separation trap based on dielectrophoresis and use thereof

    DOEpatents

    Mariella, Jr., Raymond P.

    2004-05-04

    An apparatus is adapted to separate target materials from other materials in a flow containing the target materials and other materials. A dielectrophoretic trap is adapted to receive the target materials and the other materials. At least one electrode system is provided in the trap. The electrode system has a three-dimensional configuration. The electrode system includes a first electrode and a second electrode that are shaped and positioned relative to each such that application of an electrical voltage to the first electrode and the second electrode creates a dielectrophoretic force and said dielectrophoretic force does not reach zero between the first electrode and the second electrode.

  14. Theory of magic optical traps for Zeeman-insensitive clock transitions in alkali-metal atoms

    SciTech Connect

    Derevianko, Andrei

    2010-05-15

    Precision measurements and quantum-information processing with cold atoms may benefit from trapping atoms with specially engineered, 'magic' optical fields. At the magic trapping conditions, the relevant atomic properties remain immune to strong perturbations by the trapping fields. Here we develop a theoretical analysis of magic trapping for especially valuable Zeeman-insensitive clock transitions in alkali-metal atoms. The involved mechanism relies on applying a magic bias B field along a circularly polarized trapping laser field. We map out these B fields as a function of trapping laser wavelength for all commonly used alkalis. We also highlight a common error in evaluating Stark shifts of hyperfine manifolds.

  15. Single particle density of trapped interacting quantum gases

    SciTech Connect

    Bala, Renu; Bosse, J.; Pathak, K. N.

    2015-05-15

    An expression for single particle density for trapped interacting gases has been obtained in first order of interaction using Greens function method. Results are easily simplified for homogeneous quantum gases and are found to agree with famous results obtained by Huang-Yang-Luttinger and Lee-Yang.

  16. An extension of the multiple-trapping model

    SciTech Connect

    Shkilev, V. P.

    2012-07-15

    The hopping charge transport in disordered semiconductors is considered. Using the concept of the transport energy level, macroscopic equations are derived that extend a multiple-trapping model to the case of semiconductors with both energy and spatial disorders. It is shown that, although both types of disorder can cause dispersive transport, the frequency dependence of conductivity is determined exclusively by the spatial disorder.

  17. Upgrades of the high resolution imaging x-ray crystal spectrometers on experimental advanced superconducting tokamak

    SciTech Connect

    Lu, B.; Wang, F.; Fu, J.; Li, Y.; Wan, B.; Shi, Y.; Bitter, M.; Hill, K. W.; Lee, S. G.

    2012-10-15

    Two imaging x-ray crystal spectrometers, the so-called 'poloidal' and 'tangential' spectrometers, were recently implemented on experimental advanced superconducting tokamak (EAST) to provide spatially and temporally resolved impurity ion temperature (T{sub i}), electron temperature (T{sub e}) and rotation velocity profiles. They are derived from Doppler width of W line for Ti, the intensity ratio of Li-like satellites to W line for Te, and Doppler shift of W line for rotation. Each spectrometer originally consisted of a spherically curved crystal and a two-dimensional multi-wire proportional counter (MWPC) detector. Both spectrometers have now been upgraded. The layout of the tangential spectrometer was modified, since it had to be moved to a different port, and the spectrometer was equipped with two high count rate Pilatus detectors (Model 100 K) to overcome the count rate limitation of the MWPC and to improve its time resolution. The poloidal spectrometer was equipped with two spherically bent crystals to record the spectra of He-like and H-like argon simultaneously and side by side on the original MWPC. These upgrades are described, and new results from the latest EAST experimental campaign are presented.

  18. THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE LOW RESOLUTION SPECTROMETER

    SciTech Connect

    Tsumura, K.; Arai, T.; Matsumoto, T.; Matsuura, S.; Murata, K.; Battle, J.; Bock, J.; Brown, S.; Lykke, K.; Smith, A.; Cooray, A.; Hristov, V.; Levenson, L. R.; Mason, P.; Keating, B.; Renbarger, T.; Kim, M. G.; Lee, D. H.; Nam, U. W.; Sullivan, I.; and others

    2013-08-15

    Absolute spectrophotometric measurements of diffuse radiation at 1 {mu}m to 2 {mu}m are crucial to our understanding of the radiative content of the universe from nucleosynthesis since the epoch of reionization, the composition and structure of the zodiacal dust cloud in our solar system, and the diffuse galactic light arising from starlight scattered by interstellar dust. The Low Resolution Spectrometer (LRS) on the rocket-borne Cosmic Infrared Background Experiment is a {lambda}/{Delta}{lambda} {approx} 15-30 absolute spectrophotometer designed to make precision measurements of the absolute near-infrared sky brightness between 0.75 {mu}m <{lambda} < 2.1 {mu}m. This paper presents the optical, mechanical, and electronic design of the LRS, as well as the ground testing, characterization, and calibration measurements undertaken before flight to verify its performance. The LRS is shown to work to specifications, achieving the necessary optical and sensitivity performance. We describe our understanding and control of sources of systematic error for absolute photometry of the near-infrared extragalactic background light.

  19. In-situ droplet monitoring for self-tuning spectrometers

    DOEpatents

    Montaser, Akbar; Jorabchi, Kaveh; Kahen, Kaveh

    2010-09-28

    A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

  20. ASIC for SDD-Based X-ray Spectrometers

    SciTech Connect

    De Geronimo, G.; Fried, J.; Rehak, P.; Ackley, K.; Carini, G.; Chen, W.; Keister, J.; Li, S.; Li, Z.; Pinelli, D.A.; Siddons, D.P.; Vernon, E.; Gaskin, J.A.; Ramsey, B.D.; Tyson, T.A.

    2010-06-16

    We present an application-specific integrated circuit (ASIC) for high-resolution x-ray spectrometers (XRS). The ASIC reads out signals from pixelated silicon drift detectors (SDDs). The pixel does not have an integrated field effect transistor (FET); rather, readout is accomplished by wire-bonding the anodes to the inputs of the ASIC. The ASIC dissipates 32 mW, and offers 16 channels of low-noise charge amplification, high-order shaping with baseline stabilization, discrimination, a novel pile-up rejector, and peak detection with an analog memory. The readout is sparse and based on custom low-power tristatable low-voltage differential signaling (LPT-LVDS). A unit of 64 SDD pixels, read out by four ASICs, covers an area of 12.8 cm{sup 2} and dissipates with the sensor biased about 15 mW/cm{sup 2}. As a tile-based system, the 64-pixel units cover a large detection area. Our preliminary measurements at -44 C show a FWHM of 145 eV at the 5.9 keV peak of a {sup 55}Fe source, and less than 80 eV on a test-pulse line at 200 eV.

  1. Cold Mass Issues in the MICE Coupling Magnet

    SciTech Connect

    Green, Michael A.

    2011-01-19

    I have identified two potential issues in the design of the attachments to the MICE coupling magnet cold mass. One of these attachment issues may extend into the cold mass. Both issues came to light during the analysis of what happened to the spectrometer solenoids. We must not make the same mistakes that were made on the spectrometer solenoids. The two questions that result from the identified issues are; 1) Are the superconducting low temperature superconducting leads between the coupling coil and the lower end of the high temperature superconducting (LTS) leads robust enough not quench and burn out? In the spectrometer solenoid one part of the LTS lead was not robust enough to prevent quenching and a burn out of the LTS lead and ; 2) Will there be problems with the quench protection resistors and diodes when the magnet quenches as a result of an HTS lead burning out or a disconnect of the magnet from its power supply? The second question is very important because the coupling coil has a large stored energy and inductance. As result, when current flows through the diodes and the resistors, both can be over heated. We observed resistor overheating in spectrometer magnet 2. This heating probably happened when the HTS lead the LTS lead burned out during the tests of magnet 2A and 2B respectively. (See MICE Note 324.) The answer to the first question is simple and straightforward. This is the issue that is primarily dealt with in MICE Note 324. If the resistance across the coil sub-divisions is high enough, the whole magnet will turn normal through quench-back. Making the resistance across a coil sub-division high enough is not simple.

  2. A high-resolution imaging x-ray crystal spectrometer for high energy density plasmas

    SciTech Connect

    Chen, Hui E-mail: bitter@pppl.gov; Magee, E.; Nagel, S. R.; Park, J.; Schneider, M. B.; Stone, G.; Williams, G. J.; Beiersdorfer, P.; Bitter, M. E-mail: bitter@pppl.gov; Hill, K. W.; Kerr, S.

    2014-11-15

    Adapting a concept developed for magnetic confinement fusion experiments, an imaging crystal spectrometer has been designed and tested for HED plasmas. The instrument uses a spherically bent quartz [211] crystal with radius of curvature of 490.8 mm. The instrument was tested at the Titan laser at Lawrence Livermore National Laboratory by irradiating titanium slabs with laser intensities of 10{sup 19}–10{sup 20} W/cm{sup 2}. He-like and Li-like Ti lines were recorded, from which the spectrometer performance was evaluated. This spectrometer provides very high spectral resolving power (E/dE > 7000) while acquiring a one-dimensional image of the source.

  3. DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers

    DOEpatents

    Fan, N.Q.; Clarke, J.

    1993-10-19

    A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced. 7 figures.

  4. DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers

    DOEpatents

    Fan, Non Q.; Clarke, John

    1993-01-01

    A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced.

  5. X-ray crystal spectrometer upgrade for ITER-like wall experiments at JET

    SciTech Connect

    Shumack, A. E.; Rzadkiewicz, J.; Chernyshova, M.; Czarski, T.; Karpinski, L.; Jakubowska, K.; Scholz, M.; Byszuk, A.; Cieszewski, R.; Kasprowicz, G.; Pozniak, K.; Wojenski, A.; Zabolotny, W.; Dominik, W.; Conway, N. J.; Dalley, S.; Tyrrell, S.; Zastrow, K.-D.; Figueiredo, J. [EFDA-CSU, Culham Science Centre, Abingdon OX14 3DB; Associação EURATOM and others

    2014-11-15

    The high resolution X-Ray crystal spectrometer at the JET tokamak has been upgraded with the main goal of measuring the tungsten impurity concentration. This is important for understanding impurity accumulation in the plasma after installation of the JET ITER-like wall (main chamber: Be, divertor: W). This contribution provides details of the upgraded spectrometer with a focus on the aspects important for spectral analysis and plasma parameter calculation. In particular, we describe the determination of the spectrometer sensitivity: important for impurity concentration determination.

  6. SulfaTrap(tm): Novel Sorbent to Clean Biogas for Fuel Cell Combined...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SulfaTrap(tm): Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power SulfaTrap(tm): Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power Improving ...

  7. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given ...

  8. Optical trapping of core-shell magnetic microparticles by cylindrical vector beams

    SciTech Connect

    Zhong, Min-Cheng; Gong, Lei; Li, Di; Zhou, Jin-Hua; Wang, Zi-Qiang; Li, Yin-Mei

    2014-11-03

    Optical trapping of core-shell magnetic microparticles is experimentally demonstrated by using cylindrical vector beams. Second, we investigate the optical trapping efficiencies. The results show that radially and azimuthally polarized beams exhibit higher axial trapping efficiencies than the Gaussian beam. Finally, a trapped particle is manipulated to kill a cancer cell. The results make possible utilizing magnetic particles for optical manipulation, which is an important advantage for magnetic particles as labeling agent in targeted medicine and biological analysis.

  9. Upgrade of the PNNL TEPC and Multisphere Spectrometer

    SciTech Connect

    Scherpelz, Robert I.; Conrady, Matthew M.

    2008-09-10

    The Pacific Northwest National Laboratory (PNNL) has used two types of instruments, the tissue equivalent proportional counter (TEPC) and the multisphere spectrometer for characterizing neutron radiation fields in support of neutron dosimetry at the Hanford site. The US Department of Energy recently issued new requirements for radiation protection standards in 10 CFR 835 which affect the way that neutron dose equivalent rates are evaluated. In response to the new requirements, PNNL has upgraded the analyses used in conjunction with the TEPC and multisphere. The analysis software for the TEPC was modified for this effort, and a new analysis code was selected for the multisphere. These new analysis techniques were implemented and tested with measurement data that had been collected in previous measurements. In order to test the effectiveness of the changes, measurements were taken in PNNL’s Low Scatter Room using 252Cf sources in both unmoderated and D2O-moderated configurations that generate well-characterized neutron fields. The instruments were also used at Los Alamos National Laboratory (LANL), in their Neutron Free-in-Air calibration room, also using neutron sources that generate well-characterized neutron fields. The results of the software modifications and the measurements are documented in this report. The TEPC measurements performed at PNNL agreed well with accepted dose equivalent rates using the traditional analysis, agreeing with the accepted value to within 13% for both unmoderated and moderated 252Cf sources. When the new analysis was applied to the TEPC measurement data, the results were high compared to the new accepted value. A similar pattern was seen for TEPC measurements at LANL. Using the traditional analysis method, results for all neutron sources showed good agreement with accepted values, nearly always less than 10%. For the new method of analysis, however, the TEPC responded with higher dose equivalent rates than accepted, by as much as 25

  10. Mass spectrometric immunoassay

    DOEpatents

    Nelson, Randall W.; Williams, Peter; Krone, Jennifer Reeve

    2005-12-13

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  11. Mass spectrometric immunoassay

    DOEpatents

    Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

    2013-07-16

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  12. Mass spectrometric immunoassay

    DOEpatents

    Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

    2007-12-04

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  13. A simple scanning spectrometer based on a stretchable elastomeric reflective grating

    SciTech Connect

    Ghisleri, C.; Milani, P., E-mail: paolo.milani@mi.infn.it [CIMAINA and Dipartimento di Fisica, Universit di Milano, via Celoria 16, 20133 Milano (Italy); WISE srl, Piazza Duse 2, 20122 Milano (Italy); Potenza, M. A. C.; Bellacicca, A. [CIMAINA and Dipartimento di Fisica, Universit di Milano, via Celoria 16, 20133 Milano (Italy); Ravagnan, L. [WISE srl, Piazza Duse 2, 20122 Milano (Italy)

    2014-02-10

    We report a scanning optical spectrometer based on the use of a stretchable elastomeric reflective grating. The grating is obtained by supersonic cluster beam implantation of silver nanoparticles on polydimethylsiloxane previously grooved by molding to create a replica of a commercial digital versatile disk grating. The use of a stretchable grating allows the spectrometer spanning the whole optical wavelength range by solely extending the diffraction element by more than 100% of its original dimensions. The stretchable reflective optical grating shows excellent performances and stability upon thousands of stretching cycles. The use of this elastomeric element makes the optical layout and the mechanics of the spectrometer extremely simple and advantageous for those applications where spectral resolution is not a major requirement. As a proof of principle, we present the absorption spectrum of Rhodamine B in solution obtained by our spectrometer and compared to commercial instruments.

  14. A NOVEL X-RAY IMAGING CRYSTAL SPECTROMETER FOR DOPPLER MEASUREMENTS...

    Office of Scientific and Technical Information (OSTI)

    A NOVEL X-RAY IMAGING CRYSTAL SPECTROMETER FOR DOPPLER MEASUREMENTS OF ION TEMPERATURE AND PLASMA ROTATION VELOCITY PROFILES Citation Details In-Document Search Title: A NOVEL X-RA...

  15. Superconducting gamma and fast-neutron spectrometers with high energy resolution

    DOEpatents

    Friedrich, Stephan; , Niedermayr, Thomas R.; Labov, Simon E.

    2008-11-04

    Superconducting Gamma-ray and fast-neutron spectrometers with very high energy resolution operated at very low temperatures are provided. The sensor consists of a bulk absorber and a superconducting thermometer weakly coupled to a cold reservoir, and determines the energy of the incident particle from the rise in temperature upon absorption. A superconducting film operated at the transition between its superconducting and its normal state is used as the thermometer, and sensor operation at reservoir temperatures around 0.1 K reduces thermal fluctuations and thus enables very high energy resolution. Depending on the choice of absorber material, the spectrometer can be configured either as a Gamma-spectrometer or as a fast-neutron spectrometer.

  16. A NOVEL X-RAY IMAGING CRYSTAL SPECTROMETER FOR DOPPLER MEASUREMENTS...

    Office of Scientific and Technical Information (OSTI)

    X-RAY IMAGING CRYSTAL SPECTROMETER FOR DOPPLER MEASUREMENTS OF ION TEMPERATURE AND PLASMA ROTATION VELOCITY PROFILES Citation Details In-Document Search Title: A NOVEL X-RAY ...

  17. A new spectrometer design for the x-ray spectroscopy of laser...

    Office of Scientific and Technical Information (OSTI)

    the x-ray spectroscopy of laser-produced plasmas with high (sub-ns) time resolution Citation Details In-Document Search Title: A new spectrometer design for the x-ray ...

  18. A single-shot transmissive spectrometer for hard x-ray free electron...

    Office of Scientific and Technical Information (OSTI)

    Results Journal Article: A single-shot transmissive spectrometer for hard x-ray free electron lasers Citation Details ... We report hard x-ray single-shot spectral measurements of ...

  19. Development of a TIM-based, flexible, broadband two-crystal spectromet...

    Office of Scientific and Technical Information (OSTI)

    Title: Development of a TIM-based, flexible, broadband two-crystal spectrometer Authors: Steel, A B ; Dunn, J ; Emig, J ; Beiersdorfer, P ; Brown, G V ; Shepherd, R ; Marley, E V ; ...

  20. A high-resolution imaging X-ray crystal spectrometer for high...

    Office of Scientific and Technical Information (OSTI)

    A high-resolution imaging X-ray crystal spectrometer for high energy density (HED) plasmas Citation Details In-Document Search Title: A high-resolution imaging X-ray crystal ...