National Library of Energy BETA

Sample records for refinery gases pentanes

  1. Refinery Yield of Liquefied Refinery Gases

    Energy Information Administration (EIA) (indexed site)

    Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources

  2. Refinery & Blenders Net Input of Crude Oil

    Energy Information Administration (EIA) (indexed site)

    Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils,

  3. U.S. Refinery & Blender Net Input

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 6,345,372 6,422,710 6,406,693 6,577,077 6,779,342 6,870,704 1981-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,908,550 1981-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 161,479 178,884 186,270 181,112 186,601 188,722 1981-2015 Pentanes Plus 56,686 63,385 63,596 60,394 56,037 53,465 1981-2015 Liquefied Petroleum Gases 104,793 115,499 122,674 120,718 130,564 135,257 1981-2015 Ethane 1981-1992 Normal Butane 43,802

  4. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Refinery Integration 4.1.1.31 NREL 4.1.1.51 PNNL Goal Statement GOALS: Model bio-intermediates insertion points to better define costs & ID opportunities, technical risks, information gaps, research needs Publish results Review with stakeholders 2 Leveraging existing refining infrastructure

  5. Refinery Capacity Report

    Gasoline and Diesel Fuel Update

    all operating and idle petroleum refineries (including new ... year, located in the 50 States, the District of ... When was the last refinery built in the United States? ...

  6. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Commodity PAD Districts I II III IV V United States Table 10a. Fuel Consumed at Refineries by PAD District, 2015 (Thousand Barrels, Except Where Noted) Crude Oil 0 0 0 0 0 0 Liquefied Petroleum Gases 0 1,834 309 20 846 3,009 Distillate Fuel Oil 0 26 220 8 110 364 Residual Fuel Oil 20 18 22 2 333 395 Still Gas 15,955 50,290 112,346 8,842 44,613 232,046 Marketable Petroleum Coke 0 0 0 520 90 610 Catalyst Petroleum Coke 8,229 17,001 43,013 2,876 10,891 82,010 Natural Gas (million cubic feet) 48,181

  7. Pentan isomers compound flame front structure

    SciTech Connect

    Mansurov, Z.A.; Mironenko, A.W.; Bodikov, D.U.; Rachmetkaliev, K.N.

    1995-08-13

    The fuels (hexane, pentane, diethyl ether) and conditions investigated in this study are relevant to engine knock in spark- ignition engines. A review is provided of the field of low temperature hydrocarbon oxidation. Studies were made of radical and stable intermediate distribution in the front of cool flames: Maximum concentrations of H atoms and peroxy radicals were observed in the luminous zone of the cool flame front. Peroxy radicals appear before the luminous zone at 430 K due to diffusion. H atoms were found in cool flames of butane and hexane. H atoms diffuses from the luminous zone to the side of the fresh mixture, and they penetrate into the fresh mixture to a small depth. Extension of action sphear of peroxy radicals in the fresh mixture is much greater than that of H atoms due to their small activity and high concentrations.

  8. Refinery Capacity Report

    Annual Energy Outlook

    Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 9 Shell Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 10...

  9. Refinery Capacity Report

    Reports and Publications

    2016-01-01

    Data series include fuel, electricity, and steam purchased for consumption at the refinery; refinery receipts of crude oil by method of transportation; and current and projected atmospheric crude oil distillation, downstream charge, and production capacities. Respondents are operators of all operating and idle petroleum refineries (including new refineries under construction) and refineries shut down during the previous year, located in the 50 states, the District of Columbia, Puerto Rico, the Virgin Islands, Guam, and other U.S. possessions. The Refinery Capacity Report does not contain working and shell storage capacity data. This data is now being collected twice a year as of March 31 and September 30 on the Form EIA-810, "Monthly Refinery Report", and is now released as a separate report Working and Net Available Shell Storage Capacity.

  10. Refinery Outages: Fall 2016

    Energy Information Administration (EIA) (indexed site)

    Full report Previous Issues First Half of 2016 (March 2016) Fourth-Quarter (October 2015) First Half of 2015 (February 2015) Fall 2014 (November 2014) First Half of 2014 (February 2014) March 2011 through June 2011 (April 2011) October 2010 through January 2011(November 2010) Refinery Outages: Fall 2016 Release date: November 16, 2016 This report examines U.S. refinery outages planned for September 2016 through December 2016 and the implications for available refinery production capacity,

  11. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Former Corporation/Refiner Total Atmospheric Crude Oil Distillation Capacity (bbl/cd) New Corporation/Refiner Date of Sale Table 12. Refinery Sales During 2015 CHS Inc./CHS McPherson Refinery Inc. CHS Inc./NCRA 9/15 McPherson, KS 86,000 PBF Energy Co LLC/Chalmette Refining LLC Chalmette Refining LLC 11/15 Chalmette, LA 192,500 bbl/cd= Barrels per calendar day Sources: Energy Information Administration (EIA) Form EIA-810, "Monthly Refinery Report" and Form EIA-820, "Annual Refinery

  12. Refinery Stocks of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    Product: Crude Oil and Petroleum Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils

  13. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Table 6. Operable Crude Oil and Downstream Charge Capacity of Petroleum Refineries, January 1, 1987 to (Thousand Barrels per Stream Day, Except Where Noted) January 1, 2016 JAN 1, ...

  14. Motiva Enterprises Refinery Expansion Groundbreaking | Department...

    Energy Saver

    ... (202) 586-4940 Addthis Related Articles Secretary Bodman Tours Refinery and Calls for More Domestic Refining Capacity Motiva Refinery GreenHunter Biodiesel Refinery Grand Opening

  15. U.S. Refinery Net Input

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 4,178,588 4,091,601 4,007,375 4,037,265 3,954,862 3,881,471 2005-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,908,550 2005-2015 Natural Gas Plant Liquids 154,941 171,074 175,607 168,808 172,563 172,400 2005-2015 Pentanes Plus 54,697 61,059 59,432 56,153 52,853 50,904 2005-2015 Liquefied Petroleum Gases 100,244 110,015 116,175 112,655 119,710 121,496 2005-2015 Normal Butane 39,253 42,087 45,747 42,461 45,916 48,091 2005-2015

  16. U.S. Refinery and Blender Net Production

    Energy Information Administration (EIA) (indexed site)

    Total 18,452 18,673 18,564 19,106 19,654 19,893 1983-2015 Liquefied Refinery Gases 659 619 630 623 653 612 1984-2015 EthaneEthylene 20 20 18 7 6 6 1985-2015 Ethane 14 14 13 7 5 5 ...

  17. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Vacuum State/Refiner/Location Barrels per Atmospheric Crude Oil Distillation Capacity Barrels per Operating Idle Operating Idle Downstream Charge Capacity Thermal Cracking Delayed Fluid Coking Visbreaking Other/Gas Calendar Day Stream Day Distillation Coking Oil Table 3. Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) ......................................................... Alabama 131,675 0 140,500 0 47,000 32,000 0 0 0

  18. Hydrogen Generation for Refineries

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen Generation for Refineries DOE Phase II SBIR Dr. Girish Srinivas P.I. gsrinivas@tda.com 303-940-2321 Dr. Steven Gebhard, P.E. Dr. Robert Copeland Mr. Jeff Martin TDA Research Inc. 1 This presentation does not contain any proprietary, confidential, or otherwise restricted information This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Overview *

  19. Outlook for Refinery Outages and Available Refinery Capacity...

    Annual Energy Outlook

    level of refinery outages outlined in this report. This report does not consider the impacts of refined product logistics and distribution, which could affect the movement of...

  20. U.S. Refinery Yield

    Energy Information Administration (EIA) (indexed site)

    2011 2012 2013 2014 2015 2016 View History Liquefied Refinery Gases 4.0 4.0 3.9 4.0 3.7 3.7 1993-2016 Finished Motor Gasoline 45.6 45.7 45.7 45.7 46.0 47.5 1993-2016 Finished Aviation Gasoline 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Kerosene-Type Jet Fuel 9.3 9.4 9.4 9.4 9.6 9.6 1993-2016 Kerosene 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Distillate Fuel Oil 28.6 28.7 29.1 29.5 29.5 28.1 1993-2016 Residual Fuel Oil 3.4 3.1 2.9 2.6 2.5 2.5 1993-2016 Naphtha for Petrochemical Feedstock Use 1.3 1.3 1.5 1.2 1.1

  1. U.S. Refinery Yield

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Liquefied Refinery Gases 3.9 4.9 5.2 5.1 4.9 4.8 1993-2016 Finished Motor Gasoline 46.7 46.3 46.7 46.1 45.8 45.4 1993-2016 Finished Aviation Gasoline 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Kerosene-Type Jet Fuel 9.4 9.6 9.5 9.6 10.0 10.4 1993-2016 Kerosene 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Distillate Fuel Oil 29.0 27.8 27.7 28.2 28.0 28.1 1993-2016 Residual Fuel Oil 2.5 2.6 2.5 2.3 2.3 2.4 1993-2016 Naphtha for Petrochemical Feedstock Use 1.1 1.2

  2. Total Number of Operable Refineries

    Energy Information Administration (EIA) (indexed site)

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  3. Virginia Biodiesel Refinery | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Refinery Jump to: navigation, search Name: Virginia Biodiesel Refinery Place: West Point, Virginia Zip: 23180 Product: Biodiesel producer based in Virginia References: Virginia...

  4. ,"U.S. Refinery Net Input"

    Energy Information Administration (EIA) (indexed site)

    ...petpnpinpt2dcnusmbbla.htm" ,"Source:","Energy Information Administration" ,"For Help, ... Barrels)","U.S. Refinery Net Input of Hydrogen (Thousand Barrels)","U.S. Refinery Net ...

  5. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    District and State Production Capacity Alkylates Aromatics Asphalt and Road Oil Isomers Lubricants Marketable Petroleum Coke Sulfur (short tons/day) Hydrogen (MMcfd) Table 2. Production Capacity of Operable Petroleum Refineries by PAD District and State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) a 83,429 10,111 26,500 92,765 21,045 21,120 69 1,159 PAD District I Delaware 11,729 5,191 0 6,000 0 13,620 40 596 New Jersey 29,200 0 70,000 4,000 12,000 7,500 26 280 Pennsylvania

  6. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    State/Refiner/Location Alkylates Aromatics Isobutane Lubricants Isomers Isopentane and Isohexane Asphalt and Road Oil Marketable Petroleum Coke Hydrogen (MMcfd) Sulfur (short tons per day) Table 4. Production Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) Isooctane a ..................................................................... Alabama 0 0 15,000 1,150 4,200 0 7,120 40 228 0 Hunt Refining Co 0 0 15,000 0 4,200 0 7,120

  7. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1987 to January 1, 2016 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

  8. Storage tracking refinery trends

    SciTech Connect

    Saunders, J.

    1996-05-01

    Regulatory and marketplace shakeups have made the refining and petrochemical industries highly competitive. The fight to survive has forced refinery consolidations, upgrades and companywide restructurings. Bulk liquid storage terminals are following suit. This should generate a flurry of engineering and construction by the latter part of 1997. A growing petrochemical industry translates into rising storage needs. Industry followers forecasted flat petrochemical growth in 1996 due to excessive expansion in 1994 and 1995. But expansion is expected to continue throughout this year on the strength of several products.

  9. U.S. Refinery

    Energy Information Administration (EIA) (indexed site)

    Stock Type: Total Stocks Strategic Petroleum Reserve Non-SPR Refinery Tank Farms and Pipelines Alaskan in Transit Bulk Terminal Pipeline Natural Gas Processing Plant Total Stocks (Incl. Lease Stock) Non-SPR (Incl. Lease Stock) Leases Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Stock Type Area Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Crude Oil and Petroleum Products 355,355 351,005 354,056

  10. Refinery, petrochemical plant injuries decline

    SciTech Connect

    Not Available

    1994-07-25

    The National Petroleum Refiners Association (NPRA) reports a 7% reduction in workplace injury and illness incidence rates for refineries in 1993, and a 21% decrease for petrochemical plants. The report summarizes data from 135 of the 162 US member refineries, and 117 of the 172 US member petrochemical plants. This paper summarizes the report findings.

  11. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    of Last Operation Date Shutdown Table 13. Refineries Permanently Shutdown By PAD District Between January 1, 1990 and January 1, 2016 PAD District I 570,450 Primary Energy Corp Richmond, VA 6,100 0 a GNC Energy Corp Greensboro, NC 3,000 0 a Saint Mary's Refining Co Saint Mary's, WV 4,000 4,480 02/93 03/93 Cibro Refining Albany, NY 41,850 27,000 07/93 09/93 Calumet Lubricants Co LP Rouseville, PA 12,800 26,820 03/00 06/00 Young Refining Corp. Douglasville, GA 5,400 0 07/04 07/04 Sunoco Inc

  12. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Method PAD Districts I II III IV V United States Table 9. Refinery Receipts of Crude Oil by Method of Transportation by PAD District, 2015 (Thousand Barrels) a Pipeline 25,319 1,270,581 1,894,658 178,448 290,577 3,659,583 Domestic 2,766 679,552 1,624,647 86,978 222,419 2,616,362 Foreign 22,553 591,029 270,011 91,470 68,158 1,043,221 Tanker 305,663 0 941,152 0 513,584 1,760,399 Domestic 119,833 0 28,324 0 180,353 328,510 Foreign 185,830 0 912,828 0 333,231 1,431,889 Barge 22,367 4,569 227,383 0

  13. U.S. Refinery Net Production

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total 357,855 343,444 362,961 360,498 379,164 378,541 2005-2016 Liquefied Refinery Gases 20,317 24,640 27,574 26,382 26,677 25,668 2005-2016 Ethane/Ethylene 141 146 170 25 68 186 2005-2016 Ethane 120 130 139 8 52 159 2005-2016 Ethylene 21 16 31 17 16 27 2005-2016 Propane/Propylene 18,157 17,729 18,884 17,690 18,108 17,692 2005-2016 Propane 9,095 9,011 10,066 9,549 9,801 9,278 2005-2016 Propylene 9,062 8,718 8,818 8,141 8,307 8,414 2005-2016

  14. U.S. Refinery Net Production

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 12,516 12,287 12,009 12,148 11,916 11,696 2005-2015 Liquefied Refinery Gases 659 619 630 623 653 615 2005-2015 Ethane/Ethylene 20 20 18 7 6 6 2005-2015 Ethane 14 14 13 7 5 5 2005-2015 Ethylene 6 6 5 1 1 1 2005-2015 Propane/Propylene 560 552 553 564 587 559 2005-2015 Propane 282 270 276 284 306 283 2005-2015 Propylene 278 282 277 281 281 276 2005-2015 Normal Butane/Butylene 83 48 56 57 70 56 2005-2015 Normal Butane 88 53 63 64 76 66 2005-2015

  15. Grupo Maris Capital ethanol refinery | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Maris Capital ethanol refinery Jump to: navigation, search Name: Grupo Maris (Capital ethanol refinery) Place: Nuporanga, Brazil Product: 32,000 m3 ethanol refinery owner...

  16. ,"U.S. Refinery Net Production"

    Energy Information Administration (EIA) (indexed site)

    ... Kerosene-Type Jet Fuel (Thousand Barrels)","U.S. Refinery Net Production of Military Kerosene-Type Jet Fuel (Thousand Barrels)","U.S. Refinery Net Production of Kerosene ...

  17. ,"U.S. Refinery Net Input"

    Energy Information Administration (EIA) (indexed site)

    ...RONUS1","MO9RONUS1","MBARONUS1" "Date","U.S. Refinery Net Input of Crude Oil and Petroleum Products (Thousand Barrels)","U.S. Refinery Net Input of Crude Oil (Thousand ...

  18. ,"U.S. Refinery Net Production"

    Energy Information Administration (EIA) (indexed site)

    10:25:07 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  19. ,"U.S. Refinery Net Production"

    Energy Information Administration (EIA) (indexed site)

    10:25:08 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  20. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOEpatents

    Senum, Gunnar I.; Dietz, Russell N.

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  1. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOEpatents

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  2. U.S. Refinery Net Production

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 4,568,301 4,484,600 4,395,128 4,433,893 4,349,316 4,269,058 2005-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 224,329 2005-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,103 2005-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,804 2005-2015 Ethylene 2,028 2,043 1,762 187 261 299 2005-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 204,069 2005-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,423

  3. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect

    Holmgren, Jennifer; Arena, Blaise; Marinangelli, Richard; McCall, Michael; Marker, Terry; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2006-10-11

    a summary of our collaborative 2005 project Opportunities for Biorenewables in Petroleum Refineries at the Rio Oil and Gas Conference this September.

  4. Myriant Succinic Acid BioRefinery

    Energy.gov [DOE] (indexed site)

    confidential, or otherwise restricted information Myriant Succinic Acid BioRefinery DOE ... This presentation does not contain any proprietary, confidential, or otherwise restricted ...

  5. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect

    Holmgren, Jennifer; Marinangelli, Richard; Marker, Terry; McCall, Michael; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2007-02-01

    A presentation by UOP based on collaborative work from FY05 using some results from PNNL for upgrading biomass pyrolysis oil to petroleum refinery feedstock

  6. Inorganic Membranes for Refinery Gas Separations

    SciTech Connect

    2009-02-01

    This factsheet describes a research project whose goal is to push the performance limits of inorganic membranes for large-scale gas separations in refinery applications.

  7. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural...

    Energy Information Administration (EIA) (indexed site)

    AM" "Back to Contents","Data 1: Finished Motor Gasoline Refinery, Bulk Terminal, and ... "Date","U.S. Finished Motor Gasoline Stocks at Refineries, Bulk ...

  8. NREL Refinery Process Shows Increased Effectiveness of Producing...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 ...

  9. Potential Vulnerability of US Petroleum Refineries to Increasing...

    Energy Saver

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature andor Reduced Water Availability Potential Vulnerability of US Petroleum Refineries to ...

  10. Refinery burner simulation design architecture summary.

    SciTech Connect

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

    2011-10-01

    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

  11. Innovative filter polishes oil refinery wastewater

    SciTech Connect

    Irwin, J.; Finkler, M.

    1982-07-01

    Describes how, after extensive testing of 4 different treatment techniques, a Hydro Clear rapid sand filter was installed at the Sohio oil refinery in Toledo, Ohio. This filtration system has proven to be more cost-effective than conventional approaches. The system handles the refinery's wastewater flow of 10.3 mgd. With the aid of the polishing filter, readily meets the NPDES permit limitations. The Toledo refinery is a highly integrated petroleum processing complex. It processes 127,000 barrels per day of crude oil, including 40,000 barrels per day of sour crude. Tables give dissolved air flotation performance data; biological system performance data; filter performance data; and refinery waste treatment unit compared with NPDES-BPT limitations. Diagram shows the Sohio refinery wastewater treatment facility. Through a separate backwash treatment system complete control is brought to the suspended solids in the effluent which also tends to control chemical oxygen demand and oil/grease levels.

  12. Former Soviet refineries face modernization, restructuring

    SciTech Connect

    Not Available

    1993-11-29

    A massive modernization and restructuring program is under way in the refining sector of Russia and other former Soviet republics. Economic reforms and resulting economic dislocation following the collapse of the Soviet Union has left refineries in the region grappling with a steep decline and changes in product demand. At the same time, rising oil prices and an aging, dilapidated infrastructure promise a massive shakeout. Even as many refineries in the former Soviet Union (FSU) face possible closure because they are running at a fraction of capacity, a host of revamps, expansions, and grass roots refineries are planned or under way. The paper discusses plans.

  13. A model-free temperature-dependent conformational study of n-pentane in nematic liquid crystals

    SciTech Connect

    Burnell, E. Elliott; Weber, Adrian C. J.; Dong, Ronald Y.; Meerts, W. Leo; Lange, Cornelis A. de

    2015-01-14

    The proton NMR spectra of n-pentane orientationally ordered in two nematic liquid-crystal solvents are studied over a wide temperature range and analysed using covariance matrix adaptation evolutionary strategy. Since alkanes possess small electrostatic moments, their anisotropic intermolecular interactions are dominated by short-range size-and-shape effects. As we assumed for n-butane, the anisotropic energy parameters of each n-pentane conformer are taken to be proportional to those of ethane and propane, independent of temperature. The observed temperature dependence of the n-pentane dipolar couplings allows a model-free separation between conformer degrees of order and conformer probabilities, which cannot be achieved at a single temperature. In this way for n-pentane 13 anisotropic energy parameters (two for trans trans, tt, five for trans gauche, tg, and three for each of gauche{sub +} gauche{sub +}, pp, and gauche{sub +} gauche{sub −}, pm), the isotropic trans-gauche energy difference E{sub tg} and its temperature coefficient E{sub tg}{sup ′} are obtained. The value obtained for the extra energy associated with the proximity of the two methyl groups in the gauche{sub +} gauche{sub −} conformers (the pentane effect) is sensitive to minute details of other assumptions and is thus fixed in the calculations. Conformer populations are affected by the environment. In particular, anisotropic interactions increase the trans probability in the ordered phase.

  14. U.S. Refinery and Blender Net Production

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total 615,821 596,893 629,128 623,399 648,666 650,346 1981-2016 Liquefied Refinery Gases 20,317 24,640 27,574 26,382 26,677 25,668 1981-2016 Ethane/Ethylene 141 146 170 25 68 186 1981-2016 Ethane 120 130 139 8 52 159 1993-2016 Ethylene 21 16 31 17 16 27 1993-2016 Propane/Propylene 18,157 17,729 18,884 17,690 18,108 17,692 1981-2016 Propane 9,095 9,011 10,066 9,549 9,801 9,278 1995-2016 Propylene 9,062 8,718 8,818 8,141 8,307 8,414 1993-2016

  15. From the Woods to the Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    the Woods to the Refinery CORRIM Life Cycle Analyses of Woody Feedstocks Dr. Steve Kelley ... composition, sugar types, residue fuel value * TC models are sensitive to MC, much less ...

  16. Iran to build new refinery at Arak

    SciTech Connect

    Not Available

    1990-01-01

    This paper reports Iranian plans to construct a grassroots 150,000-b/d refinery in Arak. The plant, to be completed in early 1993, will be capable of producing unleaded gasoline and other light products.

  17. Refinery siting workbook: appendices A and B

    SciTech Connect

    Not Available

    1980-07-01

    The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

  18. Where do California's greenhouse gases come from?

    ScienceCinema

    Fischer, Marc

    2013-05-29

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  19. Where do California's greenhouse gases come from?

    SciTech Connect

    Fischer, Marc

    2009-01-01

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  20. GreenHunter Biodiesel Refinery Grand Opening | Department of...

    Office of Environmental Management (EM)

    GreenHunter Biodiesel Refinery Grand Opening GreenHunter Biodiesel Refinery Grand Opening June 2, 2008 - 12:51pm Addthis Remarks as Prepared for (Acting) Deputy Secretary Kupfer ...

  1. ,"U.S. Refinery Crude Oil Input Qualities"

    Energy Information Administration (EIA) (indexed site)

    Content (Weighted Average) of Crude Oil Input to Refineries (Percent)","U.S. API Gravity (Weighted Average) of Crude Oil Input to Refineries (Degrees)" 31062,0.88,32.64 ...

  2. ,"U.S. Refinery Crude Oil Input Qualities"

    Energy Information Administration (EIA) (indexed site)

    Content (Weighted Average) of Crude Oil Input to Refineries (Percent)","U.S. API Gravity (Weighted Average) of Crude Oil Input to Refineries (Degrees)" 31228,0.91,32.46 ...

  3. ,"U.S. Downstream Charge Capacity of Operable Petroleum Refineries...

    Energy Information Administration (EIA) (indexed site)

    as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal Cracking Downstream Charge Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal ...

  4. Crude oil as refinery feed stock

    SciTech Connect

    Boduszynski, M.M.; Farrell, T.R.

    1995-12-31

    This paper gives a brief overview of the integrated oil refinery. It illustrates that crude oil refining involves {open_quotes}molecular tailoring,{close_quotes} where feed stock molecules are {open_quotes}tailored{close_quotes} through catalytic processing to make products with the most desirable composition. Chemical composition of crude oil as refinery feed stock is discussed. The emphasis is on the understanding of molecular transformations which occur in refinery processes to manufacture light transportation fuels. Diesel fuel manufacturing is used as an example. Recent environmental legislation in the United States has necessitated a significant upgrade in the quality of diesel fuel used for highway transportation. Examples are given to illustrate the impact that petroleum chemistry may have on the industry`s response to government regulations.

  5. Refinery Input by PADD - Petroleum Supply Annual (2004)

    SciTech Connect

    2009-01-18

    Table showing refinery input of crude oil and petroleum products by Petroleum Administration for Defense Districts (PADD).

  6. Exergoeconomic analysis of a refinery`s utilities plant: Part II-improvement proposals

    SciTech Connect

    Rivero, R.; Hernandez, R.

    1996-12-31

    A crude oil refinery normally consumes a large amount of energy, not only in the form of the combustion of fossil fuels in the process units, but also in the associated Utilities Plant which produces process steam at different pressure levels and electricity. Energy losses of the utilities plant represent some 40 % of the total refinery`s energy losses. It is then extremely important to evaluate the performance of this plant and the costs to be assigned to the production of steam and electricity as a supplier of energy to the process units. This paper presents the improvement proposals generated by the application of an exergoeconomic analysis to the Utilities Plant of an existing 150,000 BPD crude oil refinery. 2 refs., 7 figs.

  7. Refinery siting workbook: appendices C to O

    SciTech Connect

    Not Available

    1980-07-01

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  8. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    SciTech Connect

    Roberts, Michael; Marker, Terry; Ortiz-Toral, Pedro; Linck, Martin; Felix, Larry; Wangerow, Jim; Swanson, Dan; McLeod, Celeste; Del Paggio, Alan; Urade, Vikrant; Rao, Madhusudhan; Narasimhan, Laxmi; Gephart, John; Starr, Jack; Hahn, John; Stover, Daniel; Parrish, Martin; Maxey, Carl; Shonnard, David; Handler, Robert; Fan, Jiquig

    2015-08-31

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

  9. Opportunities for Biorenewables in Oil Refineries

    SciTech Connect

    Marker, T.L.

    2005-12-19

    Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

  10. U.S. Refineries Competitive Positions

    Gasoline and Diesel Fuel Update

    Refineries Competitive Positions 2014 EIA Energy Conference July 14, 2014 Joanne Shore American Fuel & Petrochemical Manufacturers Refiners competitive positions Function of optimizing feedstock costs, operating costs, and revenues through mix of products sold 2 Propane/butane Chemicals Gasoline Jet Fuel Diesel/heating oil Lubes Fuel for ships Asphalt FEEDSTOCKS Qualities: - Heavy/Light - Sweet/Sour Location (Distance) - Domestic - International PROCESSING Size Complexity Treating (sulfur)

  11. Greenhouse Gases into Gold

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO conversion into carbon-neutral fuels and chemicals November ...

  12. U.S. Refinery and Blender Net Production

    Energy Information Administration (EIA) (indexed site)

    6,735,067 6,815,590 6,794,407 6,973,710 7,173,730 7,258,314 1981-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 224,329 1981-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,103 1981-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,804 1993-2015 Ethylene 2,028 2,043 1,762 187 261 299 1993-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 204,069 1981-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,423 1995-2015 Propylene 101,310 102,984 101,376 102,470

  13. Ranking environmental liabilities at a petroleum refinery

    SciTech Connect

    Lupo, M.

    1995-12-31

    A new computer model is available to allow the management of a petroleum refinery to prioritize environmental action and construct a holistic approach to remediation. A large refinery may have numerous solid waste management units regulated by the Resource Conservation and Recovery Act (RCRA), as well as process units that emit hazardous chemicals into the environment. These sources can impact several environmental media, potentially including the air, the soil, the groundwater, the unsaturated zone water, and surface water. The number of chemicals of concern may be large. The new model is able to rank the sources by considering the impact of each chemical in each medium from each source in terms of concentration, release rate, and a weighted index based on toxicity. In addition to environmental impact, the sources can be ranked in three other ways: (1) by cost to remediate, (2) by environmental risk reduction caused by the remediation in terms of the decreases in release rate, concentration, and weighted index, and (3) by cost-benefit, which is the environmental risk reduction for each source divided by the cost of the remedy. Ranking each unit in the refinery allows management to use its limited environmental resources in a pro-active strategic manner that produces long-term results, rather than in reactive, narrowly focused, costly, regulatory-driven campaigns that produce only short-term results.

  14. Economic impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect

    1995-08-01

    An economic analysis of the industries affected by the Petroleum Refineries National Emmissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this standard. The industry for which economic impacts was computed was the petroleum refinery industry. Affected refineries must reduce HAP emissions by the level of control required in the standard. Several types of economic impacts, among them price product changes, output changes, job impacts, and effects on foriegn trade, were computed for the selected regulatory alternative.

  15. From the Woods to the Refinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    From the Woods to the Refinery From the Woods to the Refinery Breakout Session 2D-Building Market Confidence and Understanding II: Carbon Accounting and Woody Biofuels From the Woods to the Refinery Stephen S. Kelley, Principal and Department Head, Department of Forest Biomaterials, North Carolina State University kelley_biomass_2014.pdf (1.77 MB) More Documents & Publications GREET Bioenergy Life Cycle Analysis and Key Issues for Woody Feedstocks Biomass Program Peer Review Sustainability

  16. Potential Vulnerability of US Petroleum Refineries to Increasing Water

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Temperature and/or Reduced Water Availability | Department of Energy Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability This report discusses potential impacts of increased water temperature and reductions in water availability on petroleum refining and presents case studies related to refinery water use. Report

  17. ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    in California | Department of Energy Energy Efficiency Roadmap for Petroleum Refineries in California ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California refining_roadmap.pdf (1.34 MB) More Documents & Publications ITP Petroleum Refining: Profile of the Petroleum Refining Industry in California: California Industries of the Future Program ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California Bandwidth Study U.S.

  18. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. PDF icon Displacing Natural Gas Consumption and...

  19. Saudi Aramco Mobile Refinery Company (SAMREF) | Open Energy Informatio...

    OpenEI (Open Energy Information) [EERE & EIA]

    Company (SAMREF) Name: Saudi Aramco Mobile Refinery Company (SAMREF) Address: P.O. Box 30078 Place: Yanbu, Saudi Arabia Sector: Oil and Gas Product: Crude Oil Refining Phone...

  20. Potential Impacts of Reductions in Refinery Activity on Northeast...

    Annual Energy Outlook

    ... Ports serving Philadelphia-area refineries primarily handle crude oil and their docks and tanks are not equipped to offload waterborne products. Figure 1. Petroleum Product Assets ...

  1. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    capable of automatic, safe, reliable, efficient, and low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. ...

  2. Market Assessment of Refinery Outages Planned for October 2010...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    average values for 2002-2009 excluding months in 2005, 2006, and 2008 affected by hurricanes & refinery closures. Similarly, typical historical values are average planned...

  3. Vanadium removal from petroleum refinery wastewater

    SciTech Connect

    Nurdogan, Y.; Meyer, C.L.

    1996-11-01

    Although a numerical effluent limit has not been proposed for vanadium, San Francisco Bay Area refineries have been investigating reasonable source control and treatment measures to limit the discharge of vanadium as part of their National Pollution Discharge Elimination System (NPDES) permit requirements because vanadium may contribute to aquatic toxicity. The NPDES permit issued for the Shell Martinez Manufacturing Complex (MMC) by the Regional Water Quality Control Board (CRWQCB) required that in the investigation of control strategies for vanadium, consideration must be given to source control measures that would reduce the discharge to the extent practicable. This paper summarizes the results of bench- and pilot-scale studies to remove vanadium from process effluent of the Shell MMC. This study has resulted in the following conclusions: vanadium in the Shell MMC refinery wastewater is generated by two major sources--the Flexicoker and Stretford processes; ferric and ferrous salts are both effective in removing vanadium from wastewaters; there are tradeoffs between the initial vanadium concentration, the final pH, and the final dissolved vanadium concentration, for both ferrous and ferric reagents; recycle of iron hydroxide sludge can reduce the amount of reagent needed to attain a given vanadium concentration; other things being equal, less ferric than ferrous reagent is required to produce the same removal of vanadium; the dewatered sludge from the pilot plant was tested for its hazardous waste characteristics; a high pH sludge regeneration and reuse process appears to be a promising method of cleaning up the hazardous iron sludge.

  4. Separation of polar gases from nonpolar gases

    DOEpatents

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  5. Separation of polar gases from nonpolar gases

    DOEpatents

    Kulprathipanja, S.

    1986-08-19

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  6. Separation of polar gases from nonpolar gases

    DOEpatents

    Kulprathipanja, Santi

    1986-01-01

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  7. Separation of polar gases from nonpolar gases

    DOEpatents

    Kulprathipanja, Santi; Kulkarni, Sudhir S.

    1986-01-01

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  8. Coal-fired boiler for petroleum refinery

    SciTech Connect

    Ketterman, W.R.; Heinzmann, D.A.

    1982-01-01

    There has been a significant amount of interest in conversion from oil/gas fired boilers to coal-fired equipment since the Arab oil embargo of 1973. The CRA Incorporated Coffeyville Refinery decided in 1977 to proceed with the installation of a 86.183 Kg/h coal fired boiler to generate process steam at 650 psig (4,482 k Pa) 596/sup 0/F (313/sup 0/C). A significant portion of this steam is passed through steam turbines to obtain mechanical power. Building and operating a coal-fired steam plant is a ''Different Kettle of Fish'' from building and operating an oil/gas-fired steam plant. The intention of this paper is to deal with some of the ''Why's and Wherefores'' of the conversion to coal-fired equipment.

  9. Regulatory impact analysis for the petroleum refineries neshap. Draft report

    SciTech Connect

    Not Available

    1994-07-01

    The report analyzes the regulatory impacts of the Petroleum Refinery National Emission Standard for Hazardous Air Pollutants (NESHAP), which is being promulgated under Section 112 of the Clean Air Act Amendments of 1990 (CCA). This emission standard would regulate the emissions of certain hazardous air pollutants (HAPs) from petroleum refineries. The petroleum refineries industry group includes any facility engaged in the production of motor gasoline, naphthas, kerosene, jet fuels, distillate fuel oils, residual fuel oils, lubricants, or other products made from crude oil or unfinished petroleum derivatives. The report analyzes the impact that regulatory action is likely to have on the petroleum refining industry.

  10. Saber's heavy oil cracking refinery project

    SciTech Connect

    Benefield, C.S.; Glasscock, W.L.

    1983-03-01

    Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

  11. Effective Fouling Minimization Increases the Efficiency and Productivity of Refineries

    Energy.gov [DOE]

    This factsheet details a project to improve operating procedures, including physical and chemical methods and the use of high-temperature coatings, to allow refineries to operate equipment below threshold fouling conditions and use the most effective minimization techniques.

  12. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA...

    Office of Scientific and Technical Information (OSTI)

    The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The ...

  13. Integrating NABC bio-oil intermediates into the petroleum refinery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Breakout Session 2: Frontiers and Horizons Session 2–D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Thomas Foust, Director, National Bioenergy Center, National Renewable Energy Laboratory

  14. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  15. Combined-cycle cogeneration to power oil refinery

    SciTech Connect

    Broeker, R.J.

    1986-11-01

    A cogeneration plant now under construction at an oil refinery in Martinez, California, is an example of how the energy industry has been responding to the fundamental economic and technological challenges it has been facing over the past ten years. The industry is re-examining cogeneration as one way of meeting the requirements of the Public Utilities Regulatory Policy Act. The new plant is located at Tosco Corporation's Avon Oil Refinery, 45 miles northeast of San Francisco. It was designed by Foster Wheeler to supply process steam for the refinery as well as for a water-treatment installation that will benefit the Contra Costa Water District. Electric power produced will be used primarily by the refinery, with the balance purchased by the Pacific Gas and Electric Company.

  16. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications

    2016-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  17. Secretary Bodman Tours Refinery and Calls for More Domestic Refining

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Capacity | Department of Energy Refinery and Calls for More Domestic Refining Capacity Secretary Bodman Tours Refinery and Calls for More Domestic Refining Capacity May 18, 2006 - 10:43am Addthis Highlights President Bush's Four-Point Plan to Combat High Energy Prices PORT ARTHUR, TX - Secretary of Energy Samuel W. Bodman today renewed the call for expanded oil refining capacity in the United States and discussed additional steps the Department of Energy (DOE) is taking to prepare for the

  18. Greenhouse Gases into Gold

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO₂ conversion into carbon-neutral fuels and chemicals November 6, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Environmentalists have long lamented the destructive effects of greenhouse gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,

  19. Assessment of coal liquids as refinery feedstocks

    SciTech Connect

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  20. Assessment of coal liquids as refinery feedstocks

    SciTech Connect

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  1. EIA-820, Annual Refinery Report Page 1 U. S. ENERGY INFORMATION...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    crude oil that first traveled 5,000 miles by tanker and then traveled 105 miles by pipeline to the refinery, report pipeline as the method of transportation. * If the refinery...

  2. U.S. Fuel Consumed at Refineries

    Energy Information Administration (EIA) (indexed site)

    Barrels, Except Where Noted) Area: U.S. East Coast (PADD 1) Midwest (PADD 2) Gulf Coast (PADD 3) Rocky Mountain (PADD 4) West Coast (PADD 5) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History Crude Oil 0 0 0 0 0 0 1986-2015 Liquefied Petroleum Gases 2,404 1,291 1,521 1,311 2,305 3,009 1986-2015 Distillate Fuel Oil 440 483 539 475 309 364 1986-2015

  3. Mazheikiai refinery modernization study. Executive summary. Export trade information

    SciTech Connect

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. The volume contains the Executive Summary.

  4. Alternative multimedia regulatory programs for next-generation refineries

    SciTech Connect

    Elcock, D.; Gasper, J.; Arguerro, R.; Emerson, D.

    2000-06-22

    The 25-year-old command-and-control environmental regulatory structure in the US has resulted in significant environmental improvements. Recently, however, its limitations (e.g., rigid application regardless of site-specific conditions, disregard of cross-media and multimedia impacts, limited incentives for new technology development and use) have become increasingly apparent. New regulatory approaches that recognize current and anticipated economic constraints, new knowledge of environmental processes and impacts, and the benefits of new technologies are needed. Such approaches could be especially important for the US petroleum refining industry. This industry operates under thin profit margins, releases chemicals that can produce adverse health and environmental impacts, and must meet the technological challenges of producing more highly refined fuels from poorer quality feedstocks. Under a grant from the Environmental Technology Initiative (ETI), Argonne National Laboratory and its subcontractor, Analytical Services, Inc. developed two alternative environmental regulatory programs for next-generation petroleum refineries. (In this report, next-generation refineries refers to the refineries of today as they operate in the next 20 or more years rather than to fully reengineered future refineries.) The objective of the ETI refinery project was to develop future-oriented regulatory programs for next-generation refineries that will expand the use of innovative technologies, encourage pollution prevention, demonstrate environmental responsibility, and maintain refinery economic performance. Rather than suggesting targeted, short-term modifications to existing media-specific command-and-control regulations, the ETI project suggests the use of new approaches that are broader and more flexible. It recognizes that giving refineries flexibility in meeting environmental protection goals can stimulate new technology development and use. Unlike most US Environmental

  5. Monitoring near refineries or airborne chemicals on the SARA Title 3 section 313 list

    SciTech Connect

    Not Available

    1988-01-01

    In this volume, detailed procedures recommended for the measurement of selected petroleum refinery emissions in ambient air are presented.

  6. Monitoring near refineries or airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect

    Not Available

    1988-01-01

    This volume identifies publications and databases that address ambient air concentrations measured near petroleum refineries for the selected target chemicals.

  7. Monitoring near refineries for airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect

    Not Available

    1989-01-01

    This study provides an ambient air concentration perspective to the engineering estimates of petroleum refinery emissions required under SARA Title III Section 313. It presents and discusses ambient air concentrations of 25 selected target chemicals measured at and near the perimeter (fenceline) of three refineries. Measurements were made over three consecutive 24-hour sampling periods at each refinery. The extent to which the concentrations of the target chemicals were due to fugitive emissions from the refineries is estimated.

  8. Regulatory impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect

    1995-08-01

    A regulatory impact analysis (RIA) of the industries affected by the Petroleum Refineries National Emissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this regulation. This (RIA) was required because the proposal is economically significant according to Executive Order 12866. The industry for which these impacts was computed was the petroleum refinery industry. Several different impact analyses were included in total or summarized in different chapters in the document. Those analyses were: the compliance cost analysis, the economic impact analysis, and the benefits analysis. Benefits and costs were then compared and discussed in the document`s last chapter.

  9. Petroleum Supply Annual

    Energy Information Administration (EIA) (indexed site)

    0.PDF Table 20. Blender Net Inputs of Petroleum Products by PAD Districts, January 2015 (Thousand Barrels) Commodity PAD District 1 - East Coast PAD District 2 - Midwest East Coast Appalachian No. 1 Total Indiana, Illinois, Kentucky Minnesota, Wisconsin, North and South Dakota Oklahoma, Kansas, Missouri Total Natural Gas Plant Liquids and Liquefied Refinery Gases ....................................................... 595 - 595 75 42 287 404 Pentanes Plus

  10. Control of benzene waste NESHAP emissions from a petroleum refinery

    SciTech Connect

    Truelove, R.D. )

    1992-02-01

    This paper discusses the control of benzene emissions from a petroleum refinery as regulated by the National Emission Standards for Hazardous Air Pollutants (NESHAO) Subpart FF - National Standard for Benzene Waste Operations. This regulation is complex and confusing, but it provides flexibility to achieve compliance through various strategies to control benzene emissions. The first step to achieve compliance with the benzene waste NESHAP is understanding the regulation itself. Therefore, this paper summarizes the regulation to provide the reader with sufficient background to understand why specific controls are required for specific processes. The flexibility provided by the regulation to achieve compliance is not always readily apparent. This paper summarizes some of these subtleties. The author's involvement with an industry trade association in meetings with the Environmental Protection Agency during the development of the regulation allows some of EPA's expressions of their intent and internal interpretation to also be contained in the summary. The second step to achieve compliance with the benzene waste NESHAP is to actually design and operate a cost effective solution for a specific set of existing conditions within a refinery. This paper provides a case study of the equipment necessary to achieve compliance with the substantive requirements of the regulation at a large, integrated refinery. The retrofit requirements are very specific to the circumstances of this facility. Therefore, they will not be a universal, cost effective means of compliance for other refineries.

  11. Low temperature thermal treatment for petroleum refinery waste sludges

    SciTech Connect

    Ayen, R.J.; Swanstrom, C.P. )

    1992-05-01

    Treatment requirements for waste sludges generated by petroleum refinery operations and designated as waste codes K048, K049, K050, K051 and K052 under the Resource Conservation and Recovery Act (RCRA) became effective in November, 1990 under the Landban regulations. An experimental program evaluated low temperature thermal treatment of filter cakes produced from these sludges using laboratory and pilot-scale equipment. One set of experiments on waste samples from two different refineries demonstrated the effective removal of organics of concern from the sludges to meet the RCRA Best Demonstrated Available Technology (BDAT) treatment standards. Cyanides were also within the acceptable limit. Combined with stabilization of heavy metals in the treatment residues, low temperature thermal treatment therefore provides an effective and efficient means of treating refinery sludges, with most hydrocarbons recovered and recycled to the refinery. A milder thermal treatment was used to remove the bulk of the water from a previously filtered waste sludge, providing effective waste minimization through a 40% decrease in the mass of sludge to be disposed. The heating value of the sludge was increased simultaneously by one-third, thereby producing a residue of greater value in an alternative fuels program. A process based on this approach was successfully designed and commercialized.

  12. Energy Efficiency Roadmap for Petroleum Refineries in California

    SciTech Connect

    none,

    2004-04-01

    Through the California State IOF initiative, the California Energy Commission PIER Program developed a petroleum refining roadmap to identify energy issues and priorities unique to the refining industry in California and create a plan for future R&D that could help California refineries implement energy efficient technologies.

  13. Refinery Outages: Description and Potential Impact on Petroleum Product Prices

    Reports and Publications

    2007-01-01

    This report responds to a July 13, 2006 request from Chairman Jeff Bingaman of the Senate Committee on Energy and Natural Resources requested that the Energy Information Administration conduct a study of the impact that refinery shutdowns have had on the price of oil and gasoline.

  14. Energy efficiency improvement and cost saving opportunities forpetroleum refineries

    SciTech Connect

    Worrell, Ernst; Galitsky, Christina

    2005-02-15

    The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide

  15. Congested site challenges designers of refinery IPP plant

    SciTech Connect

    Collins, S.

    1993-09-01

    This article describes a new IPP plant which has successfully met the challenges of an extremely congested site--including overcoming physical space constraints, meeting low air-emissions regulations, and minimizing water consumption--located next to a busy highway and near a major airport. The 650-MW Linden cogeneration plant is located on a 13.5-acre plot within the confines of Bayway Refinery Co's facility near Newark, NJ. Since starting operation one year ago, the plant has been reliably supplying steam for the refinery's process heating and mechanical drive needs and efficiently generating steam and electricity with minimal environmental impact. To achieve these goals, designers chose a combined-cycle configuration/generators, five supplementary-fired heat-recovery steam generators (HRSGs), and three 90-MW steam turbine/generators. Thus far, the facility has operated with an average availability above 90%.

  16. Alternative future environmental regulatory approaches for petroleum refineries.

    SciTech Connect

    Elcock, D.; Gasper, J.; Moses, D. O.; Emerson, D.; Arguerro, R.; Environmental Assessment; DOE; Analytical Services, Inc.

    2000-01-01

    Recently, many industrial, regulatory, and community leaders have expressed concern that the current environmental regulatory structure disregards multimedia environmental impacts, provides few incentives to develop and use new technologies, and fails to consider site-specific conditions. For the US petroleum refining industry, faced with the need to produce higher-quality fuels from poorer-quality feedstocks, such criticisms are expected to increase. This article offers two alternative environmental regulatory approaches for existing petroleum refineries to use in the future. These alternative approaches are multimedia in scope, provide for new technology development and use, and allow flexibility in the means for meeting environmental goals. They have been reviewed and critiqued by various stakeholders, including industry representatives, regulators, and local and national community and environmental organizations. The integration of stakeholder comments and findings of ongoing national and international regulatory reinvention efforts in the development of these approaches positions them for potential use by other industries in addition to petroleum refineries.

  17. Greenhouse Gases Converted to Fuel

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Greenhouse Gases Converted to Fuel Greenhouse Gases Converted to Fuel carbon-conversion-fig-1.jpg Key Challenges: An important strategy for reducing global CO2 emissions calls for...

  18. Kidney cancer and hydrocarbon exposures among petroleum refinery workers

    SciTech Connect

    Poole, C.; Dreyer, N.A.; Satterfield, M.H.; Levin, L.

    1993-12-01

    To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

  19. Renewable Fuels from Algae Boosted by NREL Refinery Process | Bioenergy |

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    NREL Renewable Fuels from Algae Boosted by NREL Refinery Process February 9, 2016 A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) has proven to be significantly more effective at producing ethanol from algae than previous research. The process, dubbed Combined Algal Processing (CAP), is detailed in a new paper by NREL's Tao Dong, Eric Knoshaug, Ryan Davis, Lieve Laurens, Stefanie Van Wychen, Philip Pienkos, and Nick

  20. Martinez Refinery Completes Plant-Wide Energy Assessment

    SciTech Connect

    2002-11-01

    This OIT BestPractices Case Study describes how the Equilon Enterprises oil refinery in Martinez, California undertook a plant-wide energy assessment that focused on three key areas: waste minimization, process debottlenecking, and operations optimization. The assessment yielded recommendations, which, if implemented, can save more than 6,000,000 MMBtu per year and an estimated $52,000,000 per year, plus improve process control and reduce waste.

  1. University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

    SciTech Connect

    Pendse, Hemant P.

    2010-11-23

    This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

  2. Application of x-ray imaging to oil refinery processes

    SciTech Connect

    Gamblin, B.R.; Newton, D.; Smith, G.B.

    1996-12-31

    X-ray imaging is a non-intrusive method of visualizing the flow patterns of rapidly changing multiphase systems and is based on the variation in the absorbance of X-rays by the different phases. BP has applied the X-ray technique to a variety of problems encountered within the oil and petrochemical industries in which two or three phases are present e.g. Fluid Catalytic Cracking (riser, stripper, regenerator) and three phase systems such as slurry bubble column reactors. In general, to obtain the maximum productivity from these units it is essential to optimize the contacting between a catalyst and a process fluid or fluids. This work reports on laboratory experimental work in which full scale refinery components were visualized in order to characterize the existing designs. Modified designs were then tested and evaluated before implementation on the refinery unit. Economic assessments of some of the benefits which can be realized in an oil refinery as a result of such design improvements are also presented. 3 refs., 1 fig.

  3. Updated estimation of energy efficiencies of U.S. petroleum refineries.

    SciTech Connect

    Palou-Rivera, I.; Wang, M. Q.

    2010-12-08

    Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels such as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.

  4. Table 5.9 Refinery Capacity and Utilization, 1949-2011

    Energy Information Administration (EIA) (indexed site)

    ... Energy Information Administration (EIA), Energy Data Reports, Petroleum Refineries in the United States, annual reports. * 1981-2005EIA, Petroleum Supply Annual (PSA), ...

  5. Initial Assessment of U.S. Refineries for Purposes of Potential...

    Office of Scientific and Technical Information (OSTI)

    U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Freeman, Charles J.; Jones, Susanne B.; Padmaperuma, Asanga B.; Santosa, Daniel M.; Valkenburg, Corinne; Shinn,...

  6. Aspects of Holly Corporation's Acquisition of Sunoco Inc.'s Tulsa, Oklahoma Refinery

    Reports and Publications

    2009-01-01

    The Energy Information Administration has produced a review of aspects of the Holly's acquisition of Sunoco's 85,000-barrels-per-day Tulsa refinery.

  7. US DOE Refinery Water Study 01-19-16 PublicE_docx

    Energy Saver

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature andor Reduced Water Availability Executive Summary of Final Report Prepared for US Department of ...

  8. Raman Scattering Sensor for On-Line Monitoring of Amines and Acid Gases

    SciTech Connect

    Uibel, Rory; Smith, Lee

    2010-05-20

    Sulfur and CO2 removal from hydrocarbon streams and power plant effluents are a major problem. The sulfur is normally in the form of H2S. These two acid gases are scrubbed using aqueous amine solutions that are difficult to control with conventional technology. Process Instruments Inc. developed Raman scattering technology for on-line, real-time monitoring of amine streams to improve their efficiency in scrubbing H2S and CO2 from hydrocarbon streams and power plant effluents. Improved control of amine and acid gas concentrations will allow refineries, natural gas processes and power plants to more efficiently scrub Sulfur and CO2, saving energy, time and financial resources.

  9. Evaluation audit report. Romanian petroleum refinery, Petrobrazi, Ploiesti. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Jurish, R.A.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Petrobrazi refinery which is located 12 kilometers southwest of Ploiesti, Romania. Other defined and specified goals of the study include a consideration of the refinery's operating flexibility; an evaluation of fuel switching including the use of coal as a substitute for energy supply; and an observation of the refinery's general condition and its maintenance practice for its effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and the capital requirements anticipated.

  10. Total Crude Oil and Petroleum Products Exports

    Energy Information Administration (EIA) (indexed site)

    Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter

  11. Total Crude Oil and Petroleum Products Imports by Area of Entry

    Energy Information Administration (EIA) (indexed site)

    by Area of Entry Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel

  12. Economic impact analysis for the petroleum refineries NESHAP. Draft report

    SciTech Connect

    Not Available

    1994-07-01

    The purpose of this economic impact analysis (EIA) is to evaluate the effect of the control costs associated with the Petroleum Refining National Emission Standard for Hazardous Air Pollutants (NESHAP) on the behavior of the regulated petroleum refiners. The EIA was conducted based on the cost estimates for one hybrid regulatory option above the maximum achievable control technology (MACT) 'floor' (or minimum standard). This analysis compares the quantitative economic impacts of regulation to baseline industry conditions which would occur in the absence of regulation. The economic impacts of regulation are estimated for the industry, using costs which were supplied on both a national and a refinery level.

  13. ,"U.S. Refinery Net Production"

    Energy Information Administration (EIA) (indexed site)

    mbblpd_a.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_refp2_dc_nus_mbblpd_a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.gov" ,,"(202) 586-8800",,,"10/31/2016 2:38:58 AM" "Back to Contents","Data 1: U.S. Refinery Net Production"

  14. ,"U.S. Refinery Net Production"

    Energy Information Administration (EIA) (indexed site)

    mbbl_a.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_refp2_dc_nus_mbbl_a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.gov" ,,"(202) 586-8800",,,"10/31/2016 2:38:57 AM" "Back to Contents","Data 1: U.S. Refinery Net Production"

  15. Clean air amendments put big burden on refinery planners

    SciTech Connect

    Scherr, R.C.; Smalley, G.A. Jr.; Norman, M.E. )

    1991-06-10

    The Clean Air Act Amendments of 1990 will not only require the production of reformulated gasoline but also have significant impact on other refinery-related construction. This must be considered when developing sound planning strategy. The three titles of the Clean Air Act Amendments that will have the greatest effect on refining are: Title I: Nonattainment; Title III: Air toxics; Title V: Permitting. To understand the ramifications of these amendments, it is necessary to review the interactions of new requirements with the permitting and construction schedule shown.

  16. ARM - What are Greenhouse Gases?

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What are Greenhouse Gases? Carbon Dioxide Methane Gas Oxides of Nitrogen Halocarbons Ozone Water Vapor Greenhouse gases are atmospheric gases that trap infrared radiation emitted from the earth, lower atmosphere, or clouds or aerosols and, as

  17. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    SciTech Connect

    Not Available

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  18. Motor System Upgrades Smooth the Way to Savings of $700,000 at Chevron Refinery

    Energy.gov [DOE]

    Chevron, the largest U.S. refiner operating six gasoline-producing refineries, completed a motor system efficiency improvement project in 1997 at its Richmond, California, refinery that resulted in savings of $700,000 annually. This two-page fact sheet describes how they achieved the savings.

  19. Investigating and Using Biomass Gases

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Investigating and Using Biomass Gases Grades: 9-12 Topic: Biomass Authors: Eric Benson and Melissa Highfill Owner: National Renewable Energy Laboratory This educational material is...

  20. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  1. Biodegradation of oil refinery wastes under OPA and CERCLA

    SciTech Connect

    Gamblin, W.W.; Banipal, B.S.; Myers, J.M.

    1995-12-31

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

  2. Voluntary Reporting of Greenhouse Gases

    Reports and Publications

    2011-01-01

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  3. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    SciTech Connect

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  4. Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices

    Energy Information Administration (EIA) (indexed site)

    Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices U.S. gasoline prices are expected to fall as more oil refineries come back on line and crude oil prices decline. In its new monthly forecast, the U.S. Energy Information Administration expects pump prices will average $3.38 a gallon during the second half of this year. That's down from the current weekly price of $3.50. A recovery in oil refinery fuel production, particularly from facilities that were temporary

  5. House Passage of H.R. 5254 - The Refinery Permit Process Schedule Act |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Passage of H.R. 5254 - The Refinery Permit Process Schedule Act House Passage of H.R. 5254 - The Refinery Permit Process Schedule Act June 8, 2006 - 2:17pm Addthis Statement from Secretary Bodman WASHINGTON, DC - The following is a statement from the Secretary Samuel W. Bodman of the Department of Energy on the passage of House Resolution 5254, The Refinery Permit Process Schedule Act: "I commend the House of Representatives for their passage of this important piece

  6. ,"Virginia Natural Gas Nonhydrocarbon Gases Removed (Million...

    Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Virginia Natural Gas Nonhydrocarbon Gases Removed ... 2:52:09 AM" "Back to Contents","Data 1: Virginia Natural Gas Nonhydrocarbon Gases Removed ...

  7. Opportunities for Biomass-Based Fuels and Products in a Refinery

    Energy.gov [DOE]

    Breakout Session 2: Frontiers and Horizons Session 2–D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Corinne Valkenburg, Staff Engineer, Pacific Northwest National Laboratory

  8. Valero: Houston Refinery Uses Plant-Wide Assessment to Develop an Energy Optimization and Management System

    SciTech Connect

    2005-08-01

    This Industrial Technologies Program case study describes an energy assessment team's recommendations for saving $5 million in energy, water, and other costs at an oil refinery in Houston, Texas.

  9. Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations Using a Davison Circulating Riser (DCR) 2.4.2.402 March 25, 2015 Bio-Oil Technology Area Alan Zacher Pacific ...

  10. Assuring Mechanical Integrity of Refinery Equipment Through Global ON-Stream Inspection

    SciTech Connect

    John W. Berthold

    2006-02-22

    The development of global on-stream inspection technology will have a dramatic effect on how refinery operations are managed in the U.S. in the future. Global on-stream inspection will provide assurance of the mechanical integrity of critical plant equipment and will allow refineries to operate more efficiently with less impact on our environment and with an increased margin of safety.

  11. Waste minimization and recycling of listed hazardous wastes in petroleum refineries

    SciTech Connect

    Koopersmith, C.A.

    1995-09-01

    Refiners have many options available to optimize hazardous waste programs. The Scalfuel{trademark} process is one such program for effectively transforming various types of refinery oily sludges into a high solids content, high Btu, low water content waste-derived fuel. This waste-derived fuel is widely accepted by permitted cement kilns. Five hundred thirty four truckloads from eight refineries have been successfully recycled at seven different cement kilns.

  12. Refinery Upgrading of Hydropyrolysis Oil from Biomass Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Refinery Upgrading of Hydropyrolysis Oil from Biomass March 25,2015 Technology Area Review PI - Terry Marker Gas Technology Institute This presentation does not contain any proprietary, confidential, or otherwise restricted information Goals * Develop a cost-effective route for converting biomass to transportation fuels by first converting biomass to hydropyrolysis oil and then upgrading the hydropyrolysis oil in existing refinery equipment - Study properties and corrosion characteristics of

  13. Evaluation audit report. Bulgarian petroleum refinery, Neftochim, Bourgas. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Adams, N.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Neftochim refinery in Bourgas, Bulgaria. Other defined and specified goals include a consideration of refinery operating flexibility, an observation of the plants general condition, and comments on maintenance practices for their effect on operations. It is a further objective to characterize modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated. The report details the results of an Evaluation and Audit Study performed on selected process units. The conclusions of the study are a series of recommendations.

  14. Evaluation audit report. Czechoslovakian petroleum refinery, Slovnaft, Bratislava. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Slovnaft refinery in Bratislava, Czechoslovakia. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. It is a further objective to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  15. Evaluation audit report. Polish petroleum refinery, Plock, Poland. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Jurish, R.A.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and the reduction of emissions for the Mazovian refinery in Plock, Poland. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of their maintenance practices with their effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of the effort and the capital requirements anticipated.

  16. Evaluation audit report. Polish petroleum refinery, Gdansk, Poland. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Jurish, R.A.

    1992-05-01

    The primary objective of the report is to present opportunities for energy improvement and reduction of emissions for the Gdansk Refinery. A secondary objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated. Other goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching, including the use of coal as a substitute energy supply, and an observation of the plant's general condition and of its maintenance practices for their effect on operations.

  17. Evaluation audit report. Czechoslovakian petroleum refinery, Chemopetrol, Litvinov. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Chemopetrol Refinery in Litvinov, CSFR. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, an observation of the plants' general condition and the effect of its maintenance practice on operations. It is a further objective to characterize modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  18. Evaluation audit report. Romanian petroleum refinery, Petrotel, Ploiesti. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Not Available

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Petrotel Refinery in Brazi near Ploiesti, Romania. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching opportunities, including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  19. Evaluation audit report. Czechoslovakian petroleum refinery, Kaucuk, Kralupy. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Kaucuk refinery in Kralupy, Czechoslovakia. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. It is a further objective to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  20. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    SciTech Connect

    Goldberg, M.

    2013-12-31

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

  1. The sublethal effects of petroleum refinery effluents: Mixed function oxygenase (MFO) induction in rainbow trout

    SciTech Connect

    Sherry, J.; Scott, B.; Parrott, J.; Hodson, P.; Rao, S.

    1995-12-31

    Canada uses a single biological parameter which is based on the ability of rainbow trout (Oncorhynchus mykiss) to survive a 24 hour exposure to assess and regulate the toxicity of refinery effluents. The acute toxicity of Canadian refinery effluents is generally well controlled. Long term exposures to sublethal toxicants, which are not covered by the current regulations, could have adverse ecological effects. Since PAHs, such as benzo(a)pyrene, can occur in refinery effluents, the authors tested the hypothesis that refinery effluents can induce mixed-function oxygenase measured as ethoxyresorufin-O-deethylase activity (EROD) activity in fish. Two end of pipe effluent samples were collected from each of four Ontario refineries. All effluents induced EROD activity in young trout in a dose dependent manner. The EROD parameter has potential as a bioindicator of exposure to refinery effluents. The samples were also tested for toxicity to fathead minnow (Pimephales promelas) larvae and to a fish cell line (Ictalurus nebulosus). Fathead minnow growth was significantly reduced by six out of eight samples, and larval survival was affected by one sample. The in vitro data were less consistent: weak toxicity was detected in some samples but the dose response relationship was poor. Direct acting mutagens were detected in two effluents using the Ames Fluctuation assay.

  2. Emission factors for leaks in refinery components in heavy liquid service

    SciTech Connect

    Taback, H.; Godec, M.

    1996-12-31

    The objective of this program was to provide sufficient screening data so that EPA can develop an official set of emission factors (expressed in lb/hr/component) for refinery components (valves, flanged connectors, non-flanged connectors, pumps, open-ended lines, and other) in heavy liquid (BL) service. To accomplish this, 211,000 existing HL screening values from Southern California refineries were compiled and compared with 2,500 new HL screening measurements taken at two refineries in the state of Washington. Since Southern California is an area in extreme non-attainment of the National Ambient Air Quality Standards (NAAQS) and therefore has tight emission control regulations, it was felt that its screening data may not be representative of refineries without tight emission controls. Thus, the Southern California screening data were compared to screening measurements at refineries in an area that is in attainment of the NAAQS and without emissions control, which is the case for those refineries in Washington. It was found that statistically there was no significant difference in emission factors between the two areas and, therefore, there appears to be no difference in emissions from heavy liquid components in areas with and without leak detection and repair (LDAR) programs. The new emission factors range from 1/7 to 1/3 times the current EPA emission factors. This program was sponsored by the American Petroleum Institute (API) and an API report will soon be released providing complete details.

  3. Investigating and Using Biomass Gases

    Office of Energy Efficiency and Renewable Energy (EERE)

    Students will be introduced to biomass gasification and will generate their own biomass gases. Students generate these everyday on their own and find it quite amusing, but this time they’ll do it by heating wood pellets or wood splints in a test tube. They will collect the resulting gases and use the gas to roast a marshmallow. Students will also evaluate which biomass fuel is the best according to their own criteria or by examining the volume of gas produced by each type of fuel.

  4. U.S. Crude Oil Stocks by Type

    Energy Information Administration (EIA) (indexed site)

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Ethylene Propane/Propylene Propylene (Nonfuel Use) Normal Butane/Butylene Refinery Grade Butane Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils,

  5. Petroleum Supply Annual

    Energy Information Administration (EIA) (indexed site)

    1.PDF Table 31. Exports of Crude Oil and Petroleum Products by PAD District, January 2015 (Thousand Barrels) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1 ............................................................ 2,386 4,114 8,370 471 1 15,342 495 Natural Gas Plant Liquids and Liquefied Refinery Gases ................................................... 733 7,747 15,744 248 579 25,051 808 Pentanes Plus .................................................. 316 5,241

  6. TABLE16.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update

    6. Refinery Input of Crude Oil and Petroleum Products by PAD and Refining Districts, January 1998 Crude Oil ................................................................... 44,047 2,783 46,830 70,320 12,891 21,794 105,005 Natural Gas Liquids ................................................. 252 0 252 2,613 131 1,076 3,820 Pentanes Plus ....................................................... 0 0 0 202 45 522 769 Liquefied Petroleum Gases ................................... 252 0 252 2,411 86

  7. TABLE18.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update

    8. Refinery Stocks of Crude Oil and Petroleum Products by PAD and Refining Districts, January 1998 Crude Oil .................................................................... 14,835 511 15,346 8,591 1,779 2,386 12,756 Petroleum Products .................................................. 53,526 2,604 56,130 37,545 10,689 14,376 62,610 Pentanes Plus .......................................................... 0 0 0 4 209 225 438 Liquefied Petroleum Gases ......................................

  8. U.S. Crude Oil and Natural Gas Active Well Service Rigs in operation

    Gasoline and Diesel Fuel Update

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Ethylene Propane/Propylene Propylene (Nonfuel Use) Normal Butane/Butylene Refinery Grade Butane Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils,

  9. U.S. Crude Oil and Petroleum Products Stocks by Type

    Energy Information Administration (EIA) (indexed site)

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Ethylene Propane/Propylene Propylene (Nonfuel Use) Normal Butane/Butylene Refinery Grade Butane Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils,

  10. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  11. U.S. Total Shell Storage Capacity at Operable Refineries

    Energy Information Administration (EIA) (indexed site)

    Area: U.S. East Coast (PADD 1) Midwest (PADD 2) Gulf Coast (PADD 3) Rocky Mountain (PADD 4) West Coast (PADD 5) Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2011 2012 2013 2014 2015 2016 View History Total -- -- -- -- -- -- 1982-2016 Crude Oil -- -- -- -- -- -- 1985-2016 Liquefied Petroleum Gases -- -- -- -- -- -- 1982-2016 Propane/Propylene -- -- -- -- -- -- 1982-2016

  12. U.S. Working Storage Capacity at Operable Refineries

    Energy Information Administration (EIA) (indexed site)

    Area: U.S. East Coast (PADD 1) Midwest (PADD 2) Gulf Coast (PADD 3) Rocky Mountain (PADD 4) West Coast (PADD 5) Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2011 2012 2013 2014 2015 2016 View History Total -- -- -- -- -- -- 1982-2016 Crude Oil -- -- -- -- -- -- 1982-2016 Liquefied Petroleum Gases -- -- -- -- -- -- 1982-2016 Propane/Propylene -- -- -- -- -- -- 1982-2016

  13. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA APACHE TRIBE

    SciTech Connect

    John D. Jones

    2004-10-01

    A feasibility study for a proposed petroleum refinery for the Jicarilla Apache Indian Reservation was performed. The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The proposed refinery will utilize a lower temperature, smaller crude fractionation unit. It will have a Naphtha Hydrodesulfurizer and Reformer to produce high octane gasoline. The surplus hydrogen from the reformer will be used in a specialized hydrocracker to convert the heavier crude oil fractions to ultra low sulfur gasoline and diesel fuel products. The proposed refinery will produce gasoline, jet fuel, diesel fuel, and a minimal amount of lube oil. The refinery will require about $86,700,000 to construct. It will have net annual pre-tax profit of about $17,000,000. The estimated return on investment is 20%. The feasibility is positive subject to confirmation of long term crude supply. The study also identified procedures for evaluating processing options as a means for American Indian Tribes and Native American Corporations to maximize the value of their crude oil production.

  14. Purchase, Delivery, and Storage of Gases

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the...

  15. Purchase, Delivery, and Storage of Gases

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Coordination. Gases are stored either in the racks between buildings 6 and 7; toxic and corrosive gases are stored in Building 6, room 6C across the walkway from beamline...

  16. Green House Gases | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Green House Gases Did You Know? If it were not for naturally occurring greenhouse gases, the Earth would be too cold to support life as we know it. Without the greenhouse effect,...

  17. Independent quality assurance of refinery fugitives testing by western states petroleum association. Final audit report

    SciTech Connect

    Not Available

    1993-09-01

    Research Triangle Institute (RTI) undertook this task for the U.S. Environmental Protection Agency's (EPA's) Office of Air Quality Planning and Standards to provide third-party Quality Assurance (QA) support to a Western States' Petroleum Association (WSPA) program to measure fugitive emissions at petroleum refineries. The primary objectives of the WSPA study were to determine the correlation between screening values and true mass emission rates and to develop a relationship between liquid and gas composition. EPA's QA effort, however, focused only on the correlation objective because the number of leaking components in the California refineries cannot be expected to be representative of refineries in general. The number of components leaking at a given screening value is used in conjunction with the mass correlations to derive the average emission factors.

  18. Probabilistic ecological risk assessment of selected PAH`s in sediments near a petroleum refinery

    SciTech Connect

    Arnold, W.R.; Biddinger, G.R.

    1995-12-31

    Sediment samples were collected and analyzed for a number of polynuclear aromatic hydrocarbons (PAHs) along a gradient from a petroleum refinery`s wastewater diffuser. These data were used to calculate the potential risk to aquatic organisms using probabilistic modeling and Monte Carlo sampling procedures. Sediment chemistry data were used in conjunction with estimates of Biota-Sediment Accumulation Factors and Non-Polar Narcosis Theory to predict potential risk to bivalves. Bivalves were the receptors of choice because of their lack of a well-developed enzymatic system for metabolizing PAHs. Thus, they represent a species of higher inherent risk of adverse impact. PAHs considered in this paper span a broad range of octanol-water partition coefficients. Results indicate negligible risk of narcotic effects from PAHs existing near the refinery wastewater discharge.

  19. Characterization study of Hungary's petroleum refinery industry: A sector in transition. Phase 1 final report

    SciTech Connect

    Not Available

    1991-08-01

    Part of a USAID effort to assist Hungary's oil refinery sector during a period of transition, the report reviews the sector, with emphasis on the two major refineries -- DKV and TIPO. Key findings are as follows: (1) DKV and TIPO staffs are superbly qualified and up to date and have aggressively promoted energy conservation for a decade. Environmental compliance lags considerably behind the West; (2) Refinery managers are facing serious problems as the country moves from a command to a market economy; (3) There is a need for new criteria for evaluating the best use of limited investment resources during the austere period of transition. Replacing petroleum hydrocarbon fuels with indigenous coal does not seem viable at present.

  20. Mazheikiai refinery modernization study. Final report. Volume 2. Export trade information

    SciTech Connect

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 2 of the study.

  1. Mazheikiai refinery modernization study. Final report. Volume 3. Export trade information

    SciTech Connect

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 3 of the study.

  2. Mazheikiai refinery modernization study. Final report. Volume 1. Export trade information

    SciTech Connect

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 1 of the study.

  3. Correcting systematic bias and instrument measurement drift with mzRefinery

    SciTech Connect

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-12-01

    MOTIVATION: Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. RESULTS: We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. AVAILABILITY: The mzRefinery tool is part of msConvert, available with the ProteoWizard open source package at http://proteowizard.sourceforge.net/

  4. Correcting systematic bias and instrument measurement drift with mzRefinery

    DOE PAGES [OSTI]

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, availablemore » with the ProteoWizard open source package at http://proteowizard.sourceforge.net/« less

  5. Correcting systematic bias and instrument measurement drift with mzRefinery

    SciTech Connect

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, available with the ProteoWizard open source package at http://proteowizard.sourceforge.net/

  6. Energy Efficiency and Greenhouse Gases | Department of Energy

    Energy Saver

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as ...

  7. EIA-Voluntary Reporting of Greenhouse Gases Program

    Energy Information Administration (EIA) (indexed site)

    of Greenhouse Gases Program Voluntary Reporting of Greenhouse Gases Program ***THE VOLUNTARY REPORTING OF GREENHOUSE GASES ("1605(b)") PROGRAM HAS BEEN SUSPENDED.*** This affects ...

  8. EIA-Voluntary Reporting of Greenhouse Gases Program - What are...

    Energy Information Administration (EIA) (indexed site)

    What are Greenhouse Gases? Voluntary Reporting of Greenhouse Gases Program What are Greenhouse Gases? Many chemical compounds found in the Earth's atmosphere act as "greenhouse ...

  9. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  10. Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based

    Office of Scientific and Technical Information (OSTI)

    Oil Insertions (Technical Report) | SciTech Connect Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Citation Details In-Document Search Title: Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions In order to meet U.S. biofuel objectives over the coming decade the conversion of a broad range of biomass feedstocks, using diverse processing options, will be required. Further, the production of both gasoline and diesel

  11. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    Energy Information Administration (EIA) (indexed site)

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","8/2016","1/15/1985" ,"Release Date:","10/31/2016" ,"Next Release

  12. ,"U.S. Production Capacity of Operable Petroleum Refineries"

    Energy Information Administration (EIA) (indexed site)

    Production Capacity of Operable Petroleum Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Production Capacity of Operable Petroleum Refineries",11,"Annual",2016,"06/30/1982" ,"Release Date:","06/22/2016" ,"Next Release Date:","06/30/2017"

  13. ,"U.S. Total Shell Storage Capacity at Operable Refineries"

    Energy Information Administration (EIA) (indexed site)

    Shell Storage Capacity at Operable Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Total Shell Storage Capacity at Operable Refineries",28,"Annual",2016,"06/30/1982" ,"Release Date:","06/22/2016" ,"Next Release Date:","06/30/2017" ,"Excel File

  14. ,"U.S. Working Storage Capacity at Operable Refineries"

    Energy Information Administration (EIA) (indexed site)

    Storage Capacity at Operable Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Working Storage Capacity at Operable Refineries",28,"Annual",2016,"06/30/1982" ,"Release Date:","06/22/2016" ,"Next Release Date:","06/30/2017" ,"Excel File

  15. Allocation of energy use in petroleum refineries to petroleum products : implications for life-cycle energy use and emission inventory of petroleum transportation fuels.

    SciTech Connect

    Wang, M.; Lee, H.; Molburg, J.

    2004-01-01

    Studies to evaluate the energy and emission impacts of vehicle/fuel systems have to address allocation of the energy use and emissions associated with petroleum refineries to various petroleum products because refineries produce multiple products. The allocation is needed in evaluating energy and emission effects of individual transportation fuels. Allocation methods used so far for petroleum-based fuels (e.g., gasoline, diesel, and liquefied petroleum gas [LPG]) are based primarily on mass, energy content, or market value shares of individual fuels from a given refinery. The aggregate approach at the refinery level is unable to account for the energy use and emission differences associated with producing individual fuels at the next sub-level: individual refining processes within a refinery. The approach ignores the fact that different refinery products go through different processes within a refinery. Allocation at the subprocess level (i.e., the refining process level) instead of at the aggregate process level (i.e., the refinery level) is advocated by the International Standard Organization. In this study, we seek a means of allocating total refinery energy use among various refinery products at the level of individual refinery processes. We present a petroleum refinery-process-based approach to allocating energy use in a petroleum refinery to petroleum refinery products according to mass, energy content, and market value share of final and intermediate petroleum products as they flow through refining processes within a refinery. The results from this study reveal that product-specific energy use based on the refinery process-level allocation differs considerably from that based on the refinery-level allocation. We calculated well-to-pump total energy use and greenhouse gas (GHG) emissions for gasoline, diesel, LPG, and naphtha with the refinery process-based allocation approach. For gasoline, the efficiency estimated from the refinery-level allocation

  16. Mining machinery/equipment/parts/services. Oil and gas field equipment/machinery/parts/supplies (Ecuador). Refinery equipment, parts, and accessories, March 1991. Export trade information

    SciTech Connect

    Not Available

    1991-03-01

    The petroleum sector in Ecuador brings in about 65 percent of the country's revenue. Three of the refineries are located in the coastal region. The other two, plus the Liquified Petroleum Gas Plant (LPG), are located in the Oriente region (Amazon jungle). The refineries operate at about 85% of their installation capacity. The Petroindustrial and Petropeninsula investment plan for 1991 comtemplates the expansion of the Esmeraldas refinery to 110,000 barrels a day, and the up-grading of the Shushufindi and Libertad refineries located near the city of Guayaquil. The United States is by far the largest supplier of refinery equipment, parts and accessories, controlling about 90% of the total market.

  17. Improving energy usage at the Borger Refinery and NGL Process Center

    SciTech Connect

    Haage, P.R.

    1982-05-01

    The Phillips Petroleum Company's Borger Refinery and NGL Process Center energy conservation program began prior to the 1973 oil embargo and was greatly intensified after that event. This paper describes recent progress made in the reduction of energy use at the facility, with emphasis on the furnace and boiler efficiency control program, computer control of fractionation columns, and the steam-trap survey program.

  18. Refining and end use study of coal liquids. Topical report: Petroleum Refinery; Linear Programming Model; and Design Basis

    SciTech Connect

    1995-03-01

    A model was developed for use in the Bechtel PIMS (Process Industry Modeling System) linear programming software to simulate a generic Midwest (PADD II) petroleum refinery of the future. This ``petroleum-only`` version of the model establishes the size and complexity of the refinery after the year 2000 and prior to the introduction of coal liquids. It should be noted that no assumption has been made on when a plant can be built to produce coal liquids except that it will be after the year 2000. The year 2000 was chosen because it is the latest year where fuel property and emission standards have been set by the Environmental Protection Agency. It assumes the refinery has been modified to accept crudes that are heavier in gravity and higher in sulfur than today`s average crude mix. In addition, the refinery has also been modified to produce a product slate of transportation fuels of the future (i.e. 40% reformulated gasolines). This model will be used as a basis for determining the optimum scheme for processing coal liquids in a petroleum refinery. This report summarizes the design basis for this ``petroleum only`` LP refinery model. A report detailing the refinery configuration when coal liquids are processed will be provided at a later date.

  19. APPARATUS FOR CATALYTICALLY COMBINING GASES

    DOEpatents

    Busey, H.M.

    1958-08-12

    A convection type recombiner is described for catalytically recombining hydrogen and oxygen which have been radiolytically decomposed in an aqueous homogeneous nuclear reactor. The device is so designed that the energy of recombination is used to circulate the gas mixture over the catalyst. The device consists of a vertical cylinder having baffles at its lower enda above these coarse screens having platinum and alumina pellets cemented thereon, and an annular passage for the return of recombined, condensed water to the reactor moderator system. This devicea having no moving parts, provides a simple and efficient means of removing the danger of accumulated hot radioactive, explosive gases, and restoring them to the moderator system for reuse.

  20. Program development to identify and characterize potential emergency situations at a petroleum refinery and determination of industrial hygiene emergency responses

    SciTech Connect

    Oransky, J.J.; Delp, S.N.; Deppen, E.A.; Barrett, D.

    1995-12-31

    In the modern world the field of industrial hygiene continues to grow beyond the traditional definition of the profession. This case study documents the problem solving approach used to identify potential exposures and evaluate industrial hygiene preparedness to handle emergencies due to fire or major spill at a complex multi-process petroleum refinery. In the recent past an environmental engineer and industrial hygiene consulting firm was retained by a mature, multi-process petroleum refinery to assist in the program development to identify and characterize potential emergency situations due to a fire, major release, or spill. This study would assist the refinery in compliance with the process safety and emergency response standards and to protect refinery operations and fire fighting personnel by minimizing potential exposures and risk when responding to such a major incident.

  1. Evaluating the need and feasibility of cathodically protecting above ground storage tanks in a petroleum refinery

    SciTech Connect

    Barrien, P.; Solomon, I.

    1994-12-31

    Managing soil-side corrosion problems on Above Ground Storage Tanks (AGSTs) presents an important challenge to refinery corrosion engineers. Cathodic protection and periodic internal inspection are two methods of managing soil-side corrosion. Mobil Oil Australia conducted a study into the need and feasibility of cathodically protecting up to 120 tanks at its Altona refinery in Melbourne, Australia. The need was determined by assessing the corrosivity of the environment under the tanks from soil samples and inspection data, and the feasibility determined by conducting current drainage testing on representative tanks. Results indicated that the tanks can be cathodically protected at less than 10mA/m{sup 2} current density, using perimeter anodes. They also showed that there is little correlation between bulk foundation or surrounding soil properties, and soil-side corrosion. The paper also demonstrates how the extension of intervals between internal inspections can economically justify the application of cathodic protection.

  2. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  3. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  5. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  6. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect

    Erickson, D.C.; Kelly, F.

    1998-07-01

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  7. U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet)

    Energy Information Administration (EIA) (indexed site)

    Refinery Gas (Million Cubic Feet) U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10,243 11,231 12,001 12,021 8,782 13,405 12,734 14,373 14,999 14,661 1990's 14,973 18,055 16,732 16,724 8,935 7,568 9,354 9,746 10,900 6,781 2000's 8,684 13,085 3,817 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  8. Evaluating electric-resistance-welded tubing for refinery and chemical plant applications

    SciTech Connect

    Polk, C.J.; Hotaling, A.C. )

    1993-02-01

    A laboratory technique was developed to assess the potential for preferential attack along the longitudinal seam of electric-resistance-welded (ERW) carbon steel tubing exposed to refinery and chemical plant process streams. Used in conjunction with an evaluation of mill fabrication practices, the test procedure can identify high-quality ERW products that can be used in many applications in place of seamless components at significant cost savings.

  9. Renewable Fuels from Algae Boosted by NREL Refinery Process - News Releases

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    | NREL Renewable Fuels from Algae Boosted by NREL Refinery Process February 9, 2016 A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) has proven to be significantly more effective at producing ethanol from algae than previous research. The process, dubbed Combined Algal Processing (CAP), is detailed in a new paper by NREL's Tao Dong, Eric Knoshaug, Ryan Davis, Lieve Laurens, Stefanie Van Wychen, Philip Pienkos, and Nick

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  11. Method of concurrently filtering particles and collecting gases

    SciTech Connect

    Mitchell, Mark A; Meike, Annemarie; Anderson, Brian L

    2015-04-28

    A system for concurrently filtering particles and collecting gases. Materials are be added (e.g., via coating the ceramic substrate, use of loose powder(s), or other means) to a HEPA filter (ceramic, metal, or otherwise) to collect gases (e.g., radioactive gases such as iodine). The gases could be radioactive, hazardous, or valuable gases.

  12. The Use of Oil Refinery Wastes as a Dust Suppression Surfactant for Use in Mining

    SciTech Connect

    Dixon-Hardy, D.W.; Beyhan, S.; Ediz, I.G.; Erarslan, K.

    2008-10-15

    In this research, the suitability of a selection of petroleum refinery wastes as a dust suppressant were examined. Dust is a significant problem in surface and underground mining mainly because of its adverse effects on human health and machinery. Hence, dust control and suppression is a vital part of mine planning for mining engineers. Water is the oldest and the cheapest suppressant in dealing with the mine dusts. However, surfactant use has recently been used for a wider range of applications in the mining industry. In order to carry out laboratory experiments, a dust chamber was designed and manufactured. The chamber has an inlet for coal dust entrance and a nozzle for spraying water and the oil refinery wastes. Water and the surfactants were mixed at various ratios and then sprayed onto the coal dusts within the cell. Dust concentration was measured systematically to determine the effects of surfactant containing solution on the coal dust and the data obtained by the measurements were analyzed. The results showed that the oil refinery wastes could be used as a dust suppressant, which may create an economical utilization for the wastes concerned.

  13. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  14. Light Collection in Liquid Noble Gases

    SciTech Connect

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  15. New model more accurately tracks gases for underground nuclear...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Model tracks gases for underground nuclear explosion detection New model more accurately tracks gases for underground nuclear explosion detection Scientists have developed a new, ...

  16. Method and apparatus for separating mixtures of gases using an...

    Office of Scientific and Technical Information (OSTI)

    Method and apparatus for separating mixtures of gases using an acoustic wave Title: Method and apparatus for separating mixtures of gases using an acoustic wave A thermoacoustic ...

  17. OSTIblog Articles in the greenhouse gases Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    greenhouse gases Topic Carbon Sequestration - Helping to Save Our Beautiful World by Kathy ... Related Topics: carbon dioxide, carbon sequestration, climate change, greenhouse gases

  18. EIA-Voluntary Reporting of Greenhouse Gases Program - About the...

    Energy Information Administration (EIA) (indexed site)

    of Greenhouse Gases Program About the 1605(b) Program History Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases ...

  19. EIA-Voluntary Reporting of Greenhouse Gases Program - Under Constructi...

    Energy Information Administration (EIA) (indexed site)

    of Greenhouse Gases Program This Page is Currently Under Construction Please check back at a later time For more information on the Voluntary Reporting of Greenhouse Gases ...

  20. EIA-Voluntary Reporting of Greenhouse Gases Program -Data and...

    Energy Information Administration (EIA) (indexed site)

    Data and Reports Voluntary Reporting of Greenhouse Gases Program Data and Reports The first reporting cycle under the revised Voluntary Reporting of Greenhouse Gases Program closed ...

  1. EIA-Voluntary Reporting of Greenhouse Gases Program - Getting...

    Energy Information Administration (EIA) (indexed site)

    Getting Started Voluntary Reporting of Greenhouse Gases Program Getting Started Form ... The Voluntary Reporting of Greenhouse Gases Program suggests that prospective reporters ...

  2. EIA-Voluntary Reporting of Greenhouse Gases Program - Contact

    Energy Information Administration (EIA) (indexed site)

    Contact Voluntary Reporting of Greenhouse Gases Program Contact For more information on the Voluntary Reporting of Greenhouse Gases Program, contact us via e-mail, phone, fax, or ...

  3. Denitrification of combustion gases. [Patent application

    DOEpatents

    Yang, R.T.

    1980-10-09

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  4. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect

    1996-07-01

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  5. ARM - Lesson Plans: Dissolved Gases in Water

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Although the extent to which earth's oceans can take up greenhouse gases is still not ... Count the number of times you repeat the process. Questions What causes the whoosh when ...

  6. Biological production of products from waste gases

    DOEpatents

    Gaddy, James L.

    2002-01-22

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  7. TABLE17.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update

    7. Refinery Net Production of Finished Petroleum Products by PAD and Refining Districts, January 1998 Liquefied Refinery Gases ...... 576 -7 ...

  8. ,"U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks of Selected Petroleum Products"

    Energy Information Administration (EIA) (indexed site)

    Refinery, Bulk Terminal, and Natural Gas Plant Stocks of Selected Petroleum Products" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks of Selected Petroleum Products",13,"Monthly","8/2016","1/15/1993" ,"Release

  9. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W.

    2012-05-15

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  10. Case history of a toxicity identification/reduction evaluation (TI/RE) at a petroleum refinery

    SciTech Connect

    Arnold, W.R.; Zaleski, R.T.; Biddinger, G.R.; Simmerman, J.J.; Stewart, J.D.

    1994-12-31

    During an operational turn-around at a high conversion petroleum refinery, the final wastewater effluent became toxic to three fish species used in continuous on-line flow-through acute toxicity tests. Discharge of effluent to the receiving bay was promptly halted. Wastewater treatment continued and the treated effluent was diverted to a series of holding ponds with limited capacity. A refinery team was formed to coordinate toxicity identification studies as well as to facilitate modifications of waste disposal practices and treatment operations. A test program was conducted, consisting of one rainbow trout Phase 1 TIE and 84 strategic acute toxicity tests. As a result, a treatment methodology was identified within three days and within eight days of first observing toxicity a cationic water treatment polymer was identified as the primary toxicant. The toxicity was due to increased bioavailability of the polymer when suspended solids loads dropped during turn-around. Use of the polymer was immediately stopped and discharge to the bay was resumed with 100% survival of all three monitoring species. The authors present an overview of the studies and decisions leading to the successful identification and management of this situation.

  11. Lead exposure in a petroleum refinery during maintenance and repair activities

    SciTech Connect

    Booher, L.E.; Zampello, F.C.

    1994-02-01

    Exposure to inorganic lead (Pb) may result in a petroleum refinery when paints that contain Pb are disturbed. Frequently performed activities that disturb paint include welding, burning, cutting, abrasive blasting, sanding, grinding, and needle gun chipping. The purpose of the study reported in this article was: to determine the Pb content of paint on metal surfaces in a petroleum refinery; to measure air Pb concentrations during abrasive blasting, torch cutting and burning, and power disk sanding/grinding on surfaces coated with Pb paint; and to evaluate the effectiveness of worker exposure controls by monitoring worker blood Pb (PbB) levels. Pb levels on representative metal surfaces were measured, and most painted surfaces were found to contain significant amounts of Pb. Personal air samples collected indicated that abrasive blasting and torch burning/cutting resulted in elevated air Pb levels, while short duration power disk sanding (less than 30 minutes duration) did not result in elevated air Pb levels as compared to the Occupational Safety and Health Administration permissible exposure limit. Despite these elevated air Pb levels, exposure controls including personal protective equipment, housekeeping, showering, work area isolation, and training effectively prevented elevated worker PbB levels. 6 refs., 4 figs., 3 tabs.

  12. Managing biogeochemical cycles to reduce greenhouse gases

    SciTech Connect

    Post, Wilfred M; Venterea, Rodney

    2012-01-01

    This special issue focuses on terrestrial biogeochemical cycles as they relate to North America-wide budgeting and future projection of biogenic greenhouse gases (GHGs). Understanding the current magnitude and providing guidance on the future trajectories of atmospheric concentrations of these gases requires investigation of their (i) biogeochemical origins, (ii) response to climate feedbacks and other environmental factors, and (iii) susceptibility to management practices. This special issue provides a group of articles that present the current state of continental scale sources and sinks of biogenic GHGs and the potential to better manage them in the future.

  13. Oxidation of ultrathin GaSe

    SciTech Connect

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  14. Oxidation of ultrathin GaSe

    DOE PAGES [OSTI]

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  15. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 ...

  16. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  17. Separation of petroleum refinery wastes from a landfill by liquid chromatography

    SciTech Connect

    Mazzocco, D.L.; Willis, W.V.

    1995-12-01

    Large amounts of acidic petroleum refinery wastes (PRW) have been buried in landfills during the period 1930-1950. Many of the compounds IN PRW have not identified. Organosulfur compounds constitute an important fraction of these wastes, and are significant in site closure planning and cleanup operations. Some are difficult analytes because they undergo facile conversions during standard methods of sample preparation and analysis. A mild liquid chromatographic method using cyanopropyl and octadecyl stationary phases and a modified hexane mobile phase was found to separate PRW into five major groups, two of which contain sulfur compounds. GC/MS analysis of collected HPLC fractions identified over 80% of the compounds present. Wastes from three different landfills used in the period 1940-1950 show major similarities, but differ in relative composition. Implications for remediation of PRW in these and similar landfills designated as Superfund sites are discussed.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  19. Reformulated Gasoline Foreign Refinery Rules (Released in the STEO January 1998)

    Reports and Publications

    1998-01-01

    On August 27, 1997, the Environmental Protection Agency (EPA) promulgated revised the rules that allow foreign refiners to establish and use individual baselines, but it would not be mandatory (the optional use of an individual refinery baseline is not available to domestic refiners.) If a foreign refiner did not establish and use an individual baseline, the gasoline they export to the United States would be regulated through the importer, and subject to the importer's baseline (most likely the statutory baseline). Specific regulatory provisions are implemented to ensure that the option to use an individual baseline would not lead to adverse environmental impacts. This involves monitoring the average quality of imported gasoline, and if a specified benchmark is exceeded, remedial action would be taken by adjusting the requirements applicable to imported gasoline.

  20. Refinery chooses ORC to convert process waste heat to electric power

    SciTech Connect

    Makansi, J.

    1985-03-01

    The organic Rankine-cycle (ORC) waste-heat-recovery system is one of several concepts that DOE, energy-systems suppliers, and others have been developing to make use of low-level waste-heat streams at process and manufacturing plants. Now, several years after the oil crisis of the 1970s accelerated this development, one ORC system has found a home in the energy-intensive refining industry. Mobil Oil Corp has been generating electric power with an ORC system supplied by Turbonetics Energy Inc, a subsidiary of Mechanical Technology Inc (MTI), Latham, NY - at its Torrence (Calif) refinery complex for about nine months. Two modules, each rated at 1070 kW, recover heat from a 300F vapor product stream leaving a fluidcatalytic-cracking (FCC) unit. As a result, cooling duty on the existing overhead coolers has been reduced by about 70-million Btu/hr.

  1. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial

  2. Petroleum Supply Annual

    Energy Information Administration (EIA) (indexed site)

    5.PDF Table 25. Imports of Crude Oil and Petroleum Products by PAD District, January 2015 (Thousand Barrels, Except Where Noted) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1,2 ................................................................................. 18,930 63,788 97,152 8,362 34,083 222,315 7,171 Natural Gas Plant Liquids and Liquefied Refinery Gases ...... 2,570 1,997 732 476 298 6,073 196 Pentanes Plus

  3. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOEpatents

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  4. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOEpatents

    Turick, C.E.

    1997-06-10

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  5. Method for introduction of gases into microspheres

    DOEpatents

    Hendricks, Charles D.; Koo, Jackson C.; Rosencwaig, Allan

    1981-01-01

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  6. Glass Membrane For Controlled Diffusion Of Gases

    DOEpatents

    Shelby, James E.; Kenyon, Brian E.

    2001-05-15

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  7. Method for introduction of gases into microspheres

    DOEpatents

    Hendricks, C.D.; Koo, J.C.; Rosencwaig, A.

    A method is described for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500..mu.. with both thin walls (0.5 to 4/sub ..mu../) and thick walls (5 to 20/sub ..mu../) that contain various fill gases, such as Ar, Kr, Xe, Br, D, H/sub 2/, DT, He, N/sub 2/, Ne, CO/sub 2/, etc., in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-form-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace.

  8. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  9. Method for detecting trace impurities in gases

    DOEpatents

    Freund, Samuel M.; Maier, II, William B.; Holland, Redus F.; Beattie, Willard H.

    1981-01-01

    A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (.about.2 ppm) present in commercial Xe and ppm levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

  10. Traveling dark solitons in superfluid Fermi gases

    SciTech Connect

    Liao Renyuan; Brand, Joachim

    2011-04-15

    Families of dark solitons exist in superfluid Fermi gases. The energy-velocity dispersion and number of depleted particles completely determine the dynamics of dark solitons on a slowly varying background density. For the unitary Fermi gas, we determine these relations from general scaling arguments and conservation of local particle number. We find solitons to oscillate sinusoidally at the trap frequency reduced by a factor of 1/{radical}(3). Numerical integration of the time-dependent Bogoliubov-de Gennes equation determines spatial profiles and soliton-dispersion relations across the BEC-BCS crossover, and proves consistent with the scaling relations at unitarity.

  11. Method for detecting trace impurities in gases

    DOEpatents

    Freund, S.M.; Maier, W.B. II; Holland, R.F.; Beattie, W.H.

    A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (approx. 2 ppM) present in commercial Xe and ppM levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

  12. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of

  13. Study of electron transport in hydrocarbon gases

    SciTech Connect

    Hasegawa, H.; Date, H.

    2015-04-07

    The drift velocity and the effective ionization coefficient of electrons in the organic gases, C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, C{sub 2}H{sub 6}, CH{sub 3}OH, C{sub 2}H{sub 5}OH, C{sub 6}H{sub 6}, and C{sub 6}H{sub 5}CH{sub 3}, have been measured over relatively wide ranges of density-reduced electric fields (E/N) at room temperature (around 300?K). The drift velocity was measured, based on the arrival-time spectra of electrons by using a double-shutter drift tube over the E/N range from 300 to 2800 Td, and the effective ionization coefficient (?????) was determined by the steady-state Townsend method from 150 to 3000 Td. Whenever possible, these parameters were compared with those available in the literature. It has been shown that the swarm parameters for these gases have specific tendencies, depending on their molecular configurations.

  14. Sensitivity of screening-level toxicity tests using soils from a former petroleum refinery

    SciTech Connect

    Pauwels, S.; Bureau, J.; Roy, Y.; Allen, B.; Robidoux, P.Y.; Soucy, M.

    1995-12-31

    The authors tested five composite soil samples from a former refinery. The samples included a reference soil (Mineral Oil and Grease, MO and G < 40 ppm), thermally-treated soil, biotreated soil, and two untreated soils. They evaluated toxicity using the earthworm E. foetida, lettuce, cress, barley, Microtox, green algae, fathead minnow, and D. magna. The endpoints measured were lethality, seed germination, root elongation, growth, and bioluminescence. Toxicity, as measured by the number of positive responses, increased as follows: biotreated soil < untreated soil No. 1 < reference soil < thermally-treated soil and untreated soil No. 2. The biotreated soil generated only one positive response, whereas the thermally-treated soil and untreated soil No. 2 generated five positive responses. The most sensitive and discriminant terrestrial endpoint was lettuce root elongation which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was barley seed germination for which no toxicity was detected. The most sensitive and discriminant aquatic endpoint was green algae growth which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was D. magna for which no toxicity was detected. Overall, soil and aqueous extract toxicity was spotty and no consistent patterns emerged to differentiate the five soils. Biotreatment significantly reduced the effects of the contamination. Aqueous toxicity was measured in the reference soil, probably because of the presence of unknown dissolved compounds in the aqueous extract. Finally, clear differences in sensitivity existed among the test species.

  15. Gasification of refinery sludge in an updraft reactor for syngas production

    SciTech Connect

    Ahmed, Reem; Eldmerdash, Usama; Sinnathambi, Chandra M.

    2014-10-24

    The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

  16. Optimization of ferric hydroxide coprecipitation process for selenium removal from petroleum refinery stripped four water

    SciTech Connect

    Gerhardt, M.B.; Marrs, D.R.; Roehl, R.

    1996-12-31

    Iron coprecipitation was used in bench-scale tests to remove selenium from stripped sour water generated by two petroleum refineries. Chlorine dioxide and hydrogen peroxide were found to convert selenocyanate in the stripped sour water to selenite, which can be removed by iron coprecipitation. An iodometric titration procedure was developed to determine the required oxidant dose. Iron coprecipitation reduced selenium concentrations by 40 to 99 percent in stripped sour water after chlorine dioxide pretreatment Removal was less effective with hydrogen peroxide as the oxidant: total selenium concentrations were reduced by 28 to 92 percent in stripped sour water after hydrogen peroxide pretreatment. Highest removals were obtained at the highest oxidant and iron doses. Sludges produced in coprecipitation tests were hazardous under California regulations. Ozone oxidized selenocyanate but prevented ferric hydroxide precipitation or coagulation. Air was ineffective at selenocyanate oxidation. Repeatedly contacting iron hydroxide with stripped sour water pretreated with hydrogen peroxide, in a simulation of a countercurrent adsorption process, increased the selenium adsorbed on the solids from 32 to 147 pg selenium per mg of iron, but some of the adsorbed selenite was oxidized to selenate and desorbed back into solution.

  17. Identification of the cause of weak acute toxicity to rainbow trout at a petroleum refinery

    SciTech Connect

    Arnold, W.R.; Zaleski, R.T.; Biddinger, G.R.

    1995-12-31

    The refinery in question performs flow through acute toxicity tests on its effluent four times per month using three fish species: fathead minnows (Pimephales promelas), threespine sticklebacks (Gasterosteus oculeatus) and rainbow trout (Oncorhynchus mykiss). Several months of monitoring data indicated a transient low level acute toxicity to rainbow trout. In most cases, several days were required for mortality to occur in the flow through tests and numerous attempts to reproduce toxicity in static and static renewal tests were unsuccessful. A decision was made to manipulate the effluent in an attempt to enhance the toxic effect in the static mode so that conventional methods could be used to identify the cause. these tests indicated that toxicity was pH dependent. Additional testing, using EPA`s Phase 1 Toxicity Identification Evaluation methods suggested that the cause of toxicity was probably an organic acid. Experiments were subsequently begun to identify the specific cause and source of toxicity. This paper reviews the problems confronted during the various phases of the study and the decisions that were made that eventually led to an understanding of the basis of toxicity.

  18. Biofacts: Fueling a stronger economy. Renewable fuel solutions for petroleum refineries

    SciTech Connect

    1995-07-01

    The DOE Biofuels Program is investigating processes to condition synthesis gas (syngas) produced from the gasification of biomass, coke, waste oils, and other inexpensive feedstocks and low-cost by-products. Syngas technologies offer refiners economical, flexible solutions to the challenges presented by today`s market forces and regulatory environment, such as: increasingly stringent environmental regulations that dictate the composition of petroleum products; increasingly sour crudes; increased coke production and hydrogen use resulting from heavier crude; increased disposal cost for coke and residuals oils; and decreasing hydrogen supply resulting from decreased catalytic reforming severity--a necessity to comply with requirements for reduced aromatic content. Most importantly, refiners can use the DOE syngas processes to upgrade refinery residuals and coke, which minimizes environmental problems and maximizes profitability. DOE`s solution also offers refiners the flexibility to economically supplement petroleum feedstocks with a wide variety of locally available renewable feedstocks that can be fed into the gasifier--feedstocks such as energy crops, municipal solid wastes, many industrial wastes, and agricultural by-products.

  19. A perimeter-based groundwater protection strategy for waste management units at a petroleum refinery

    SciTech Connect

    Wenzlau, R.K.

    1996-12-01

    This article presents a groundwater management strategy and its application to regulatory compliance for the Shell Oil Company Martinez Manufacturing Complex, a refinery located within northern California. The purpose of the strategy is to protect the beneficial uses of groundwater which are present beyond the facility boundary while recognizing the occurrence of limited degradation of groundwater upgradient of the perimeter. The strategy applies perimeter-based groundwater monitoring and control to two general sources of groundwater quality degradation: historic spill and leak sites and inactive waste management units. To regulate the groundwater contaminant plumes originating form historic spill and leak sites the California Regional Water Quality Control Board (Regional Board) has issued Site Cleanup Requirements (SCR). To satisfy the SCR Shell developed in 1989 a Basin Boundary Control Plan as the first implementation of the groundwater strategy. To regulate groundwater quality impacts from solid waste management units, the Regional Board issues Waste Discharge Requirements (WDR). In 1995 the Regional Board issued revised WDR that established consistency between waste management unit regulation and the facility groundwater management strategy. The Regional Board made two findings that allowed this consistency. The first finding was that the Points of Compliance for all 23 solid waste management units are at the down-gradient perimeter of the facility. The second finding was that all waste management units were within corrective action, regardless of whether a known release of waste constituents occurred from a given waste unit.

  20. Utilization and results of hazard and operability studies in a petroleum refinery

    SciTech Connect

    Pully, A.S. )

    1993-04-01

    The petroleum refining industry has been performing hazard analyses in process units to some extent since at least 1988 and in earnest since 1990, when the American Petroleum Institute published Recommended Practice No. 750, [open quotes]Process Hazards Management.[close quotes] The Hazard and Operability Study (HAZOPS) is the most widely used of the various analysis techniques available, in part because this highly structured technique is easy to teach and well-suited for continuous process units. The results of HAZOPS fall into two broad categories, tangible and intangible. The tangible results are obvious: worksheets which detail event scenarios for potential process deviations, and action items, or recommendations for changes to process equipment of procedures. In many cases, the action items address issues which have a purely economic impact or which are procedural in nature, involving little or no capital investment. The intangible results or products of a HAZOPS include: the training and knowledge gained by the team participants, and better utilization of limited capital funds resulting from more detailed up-front engineering when a HAZOPS is required prior to funding. An aggressive HAZOPS schedule also aids facilities in planning resources for process safety information updates where the necessary P ID's or PFD's are out-of-date. This paper details the experiences with HAZOPS at Chevron USA Products Company's Pascagoula, Mississippi Refinery. The manner in which HAZOPS are performed, the types of results obtained, and the benefits of the HAZOPS program are discussed. 8 refs., 1 fig., 1 tab.

  1. Summary of the proceedings of the workshop on the refinery of the future

    SciTech Connect

    Not Available

    1994-06-01

    This report on the Workshop on the Refinery of the Future has been prepared for participants to provide them with a succinct summary of the presentations, deliberations, and discussions. In preparing the summary, we have striven to capture the key findings (conclusions) and highlight the issues and concerns raised during the plenary and breakout sessions. The presentation of the summary of the proceedings follows the final workshop agenda, which is given in Section I; each section is tabbed to facilitate access to specific workshop topics. The material presented relies heavily on the outline summaries prepared and presented by the Plenary Session Chairman and the Facilitators for each breakout group. These summaries are included essentially as presented. In addition, individuals were assigned to take notes during each session; these notes were used to reconstruct critical issues that were discussed in more detail. The key comments made by the participants, which tended to represent the range of views expressed relative to the issues, are presented immediately following the facilitator`s summary outline in order to convey the flavor of the discussions. The comments are not attributed to individuals, since in many instances they represent a composite of several similar views expressed during the discussion. The facilitators were asked to review the writeups describing the outcomes of their sessions for accuracy and content; their suggested changes were incorporated. Every effort has thus been made to reconstruct the views expressed as accurately as possible; however, errors and/or misinterpretations undoubtedly have occurred.

  2. New process technology already existing in your refinery: Hydroprocessing-FCC Synergy

    SciTech Connect

    Stanger, C.W. Jr.; Fletcher, R.; Johnson, C.; Reid, T.

    1996-12-01

    New processing technology is now available to improve refinery operating margins. The cost of this technology is minor if a refiner has a VGO or Resid hydrotreater and an FCCU. The primary requirement is changing the way work is done. Addition of new capital can be an optional step. The New technology is Hydroprocessing-FCC Synergy. Redirecting the work effort to operate, optimize, and budget the FCC pretreater, the FCC and any FCC post-treaters as one unit can optimize margins. Calculating the unit operating margins on the difference of FCC final product value minus the pretreater and FCC operating costs highlights the new technology`s enhanced profitability. The synergy connectiveness is made through the hydrocarbon flow and properties. Selecting the proper conditions and catalyst to complement each other`s performance is the technical key. This paper discusses the techniques for catalyst and operating condition selection. The concept of changing formulations with processing age is discussed. Finally a case study comparing Hydroprocessing-FCC Synergy versus classical non-synergistic approaches is presented, including the effect of new Hydroprocessing and FCC catalysts on the profitability increase.

  3. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  4. Energetic Materials for EGS Well Stimulation (solids, liquids, gases) |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) presentation at the April 2013 peer review meeting held in Denver, Colorado. energetics_peer2013.pdf (1.66 MB) More Documents & Publications Controlled Rapid Pressurization Using Liquid Propellants for EGS Well Stimulation track 4: enhanced geothermal systems

  5. Method for controlling corrosion in thermal vapor injection gases

    DOEpatents

    Sperry, John S.; Krajicek, Richard W.

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  6. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  7. BOC Lienhwa Industrial Gases BOCLH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Lienhwa Industrial Gases (BOCLH) Place: Taipei, Taiwan Sector: Solar Product: BOCLH is a joint venture between the Lien Hwa Industrial Corporation and the BOC Group in the United...

  8. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation ...

  9. Deviation from the Knudsen law on quantum gases

    SciTech Connect

    Babac, Gulru

    2014-12-09

    Gas flow in micro/nano scale systems has been generally studied for the Maxwell gases. In the limits of very low temperature and very confined domains, the Maxwellian approximation can break down and the quantum character of the gases becomes important. In these cases, Knudsen law, which is one of the important equations to analyze rarefied gas flows is invalid and should be reanalyzed for quantum gases. In this work, the availability of quantum gas conditions in the high Knudsen number cases is discussed and Knudsen law is analyzed for quantum gases.

  10. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    Energy Information Administration (EIA) (indexed site)

    Schedule Voluntary Reporting of Greenhouse Gases Program Revised Launch Schedule EIA will begin accepting both Start Year and Reporting Year reports using the Workbook Form on ...

  11. EIA-Voluntary Reporting of Greenhouse Gases Program - Section...

    Energy Information Administration (EIA) (indexed site)

    Section 1605 Text Voluntary Reporting of Greenhouse Gases Program Section 1605 Text Energy ... national aggregate emissions of each greenhouse gas for each calendar year of the ...

  12. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    Energy Information Administration (EIA) (indexed site)

    Program Voluntary Reporting of Greenhouse Gases Program Original 1605(b) Program Section 1605(b) of the Energy Policy Act of 1992 established the Voluntary Reporting of Greenhouse ...

  13. EIA-Voluntary Reporting of Greenhouse Gases Program - Emission...

    Energy Information Administration (EIA) (indexed site)

    Emission Factors Voluntary Reporting of Greenhouse Gases Program Emission Factors and Global Warming Potentials The greenhouse gas emission factors and global warming potentials ...

  14. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    Energy Information Administration (EIA) (indexed site)

    of Greenhouse Gases Program Original 1605(b) Program Calculation Tools The workbooks below were developed to assist participants in the original Voluntary Reporting of Greenhouse ...

  15. Removal of mercury from waste gases

    SciTech Connect

    Muster, U.; Marr, R.; Pichler, G.; Kremshofer, S.; Wilferl, R.; Draxler, J.

    1996-12-31

    Waste and process gases from thermal power, incineration and metallurgical plants or those from cement and alkali chloride industries contain metallic, inorganic and organic mercury. Widespread processes to remove the major amount of mercury are absorption and adsorption. Caused by the lowering of the emission limit from 200 to 50 {mu}g/m{sup 3} [STP] by national and European legislators, considerable efforts were made to enhance the efficiency of the main separation units of flue gas cleaning plants. Specially impregnated ceramic carriers can be used for the selective separation of metallic, inorganic and organic mercury. Using the ceramic reactor removal rates lower than 5 {mu}g/m{sup 3} [STP] of gaseous mercury and its compounds can be achieved. The ceramic reactor is active, regenerable and stable for a long term operation. 4 refs., 7 figs.

  16. Voluntary reporting of greenhouse gases 1997

    SciTech Connect

    1999-05-01

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  17. Greenhouse gases: What is their role in climate change

    SciTech Connect

    Edmonds, J.A.; Chandler, W.U. ); Wuebbles, D. )

    1990-12-01

    This paper summarizes information relevant to understanding the role of greenhouse gases in the atmosphere. It examines the nature of the greenhouse effect, the Earth's radiation budget, the concentrations of these gases in the atmosphere, how these concentrations have been changing, natural processes which regulate these concentrations of greenhouse gases, residence times of these gases in the atmosphere, and the rate of release of gases affecting atmospheric composition by human activities. We address the issue of the greenhouse effect itself in the first section. In the second section we examine trends in atmospheric concentration of greenhouse gases and emissions sources. In the third section, we examine the natural carbon cycle and its role in determining the atmospheric residence time of carbon dioxide (CO{sub 2}). In the fourth section, we examine the role atmospheric chemistry plays in the determining the concentrations of greenhouse gases. This paper is not intended to be an exhaustive treatment of these issues. Exhaustive treatments can be found in other volumes, many of which are cited throughout this paper. Rather, this paper is intended to summarize some of the major findings, unknowns, and uncertainties associated with the current state of knowledge regarding the role of greenhouse gases in the atmosphere. 57 refs., 11 figs., 11 tabs.

  18. Single particle density of trapped interacting quantum gases

    SciTech Connect

    Bala, Renu; Bosse, J.; Pathak, K. N.

    2015-05-15

    An expression for single particle density for trapped interacting gases has been obtained in first order of interaction using Greens function method. Results are easily simplified for homogeneous quantum gases and are found to agree with famous results obtained by Huang-Yang-Luttinger and Lee-Yang.

  19. Continuous cryopump with a method for removal of solidified gases

    DOEpatents

    Carlson, Larry W.; Herman, Harold

    1989-01-01

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases absorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel.

  20. Continuous cryopump with a method for removal of solidified gases

    DOEpatents

    Carlson, L.W.; Herman, H.

    1988-05-05

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  1. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

    SciTech Connect

    Not Available

    1993-10-15

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

  2. Polycyclic aromatic hydrocarbons (PAHs): a possible cause of lung cancer mortality among nickel/copper smelter and refinery workers

    SciTech Connect

    Verma, D.K.; Julian, J.A.; Roberts, R.S.; Muir, D.C.; Jadon, N.; Shaw, D.S. )

    1992-05-01

    A retrospective industrial hygiene investigation was undertaken to explain the cause of a statistically significant excess lung cancer mortality observed in a subset of a large cohort of nickel workers involved in mining, smelting, and refining of nickel and copper in Ontario. The focus of this paper is to demonstrate how an industrial hygiene follow-up assessment of an epidemiologic finding can help to identify a likely cause. Polycyclic aromatic hydrocarbons (PAHs) alone or in association with particulate and gaseous contaminants (e.g., SO2) were likely the causative agents of the excess lung cancer observed among the lead welders, cranemen, and arc furnace workers of the copper refinery.

  3. Regional respiratory tract absorption of inhaled reactive gases

    SciTech Connect

    Miller, F.J.; Overton, J.H.; Kimbell, J.S.; Russell, M.L.

    1992-06-29

    Highly reactive gases present unique problems due to the number of factors which must be taken into account to determine regional respiratory tract uptake. The authors reviewed some of the physical, chemical, and biological factors that affect dose and that must be understood to interpret toxicological data, to evaluate experimental dosimetry studies, and to develop dosimetry models. Selected dosimetry experiments involving laboratory animals and humans were discussed, showing the variability and uptake according to animal species and respiratory tract region for various reactive gases. New experimental dosimetry approaches, such as those involving isotope ratio mass spectroscopy and cyclotron generation reactive gases, were discussed that offer great promise for improving the ability to study regional respiratory tract absorption of reactive gases. Various dosimetry modeling applications were discussed which demonstrate: the importance of airflow patterns for site-specific dosimetry in the upper respiratory tract, the influence of the anatomical model used to make inter- and intraspecies dosimetric comparisons, the influence of tracheobronchial path length on predicted dose curves, and the implications of ventilatory unit structure and volume on dosimetry and response. Collectively, these examples illustrate important aspects of regional respiratory tract absorption of inhaled reactive gases. Given the complex nature of extent and pattern of injury in the respiratory tract from exposure to reactive gases, understanding interspecies differences in the absorption of reactive gases will continue to be an important area for study.

  4. Cryogenic method for measuring nuclides and fission gases

    DOEpatents

    Perdue, P.T.; Haywood, F.F.

    1980-05-02

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  5. Process for the removal of acid forming gases from exhaust gases

    DOEpatents

    Chang, S.G.; Liu, D.K.

    1992-11-17

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  6. Process for the removal of acid forming gases from exhaust gases

    DOEpatents

    Chang, Shih-Ger; Liu, David K.

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  7. Method for monitoring stack gases for uranium activity

    DOEpatents

    Beverly, Claude R.; Ernstberger, Harold G.

    1988-01-01

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  8. Method for monitoring stack gases for uranium activity

    DOEpatents

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  9. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  10. World Energy Projection System Plus Model Documentation: Greenhouse Gases Model

    Reports and Publications

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Greenhouse Gases Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  11. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    OpenEI (Open Energy Information) [EERE & EIA]

    isotope ratios in gases of thirty hot springs and geothermal wells and of five natural gas wells in the western United States show no relationship to regional conductive heat...

  12. Method of producing pyrolysis gases from carbon-containing materials

    DOEpatents

    Mudge, Lyle K.; Brown, Michael D.; Wilcox, Wayne A.; Baker, Eddie G.

    1989-01-01

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  13. METHOD FOR PUMPING GASES AT LOW VACUUM PRESSURES

    DOEpatents

    Milleron, N.

    1962-06-01

    A method is given for pumping overpressure "pulses" or "bursts" of gases without a significant rise in base pressure within a "gettering-type" vacuum pump having surfaces within the pumping cavity coated with or comprising clean gettering metal, e.g., Mo or Ta. The cavity is first pumped down by any convenient means to an equilibrium base pressure in the range desired, generally below 10/sup -6/ mm Hg. At this pressure, the metal immediately adsorbs overpressures or "bursts" of gases striking same with thermal motion without raising the base pressure significantiy. Desorption takes place at an equilibrium rate which, of course, is dependent upon the equilibrium pressure, and such desorbed gases are continuously removed by diffuaion pump or other pumping, whereby said overpressures or "bursts" of gases are removed without a rise in the equilibrium pressure and/or back diffusion of the gaseous pulse from the pumping cavity. (AEC)

  14. EIA-Voluntary Reporting of Greenhouse Gases Program - Why Report

    Energy Information Administration (EIA) (indexed site)

    Reporting of Greenhouse Gases Program Why Report What Is the Purpose of Form EIA-1605? Form EIA-1605 provides the means for the voluntary reporting of greenhouse gas emissions, ...

  15. New model more accurately tracks gases for underground nuclear explosion

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    detection Model tracks gases for underground nuclear explosion detection New model more accurately tracks gases for underground nuclear explosion detection Scientists have developed a new, more thorough method for detecting underground nuclear explosions by coupling two fundamental elements-seismic models with gas-flow models. December 17, 2015 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and

  16. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOEpatents

    Gaddy, James L.

    2000-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  17. National emission standards for hazardous air pollutants petroleum refineries. Background information for final standards. Summary of public comments and responses. Final report

    SciTech Connect

    1995-07-01

    National emission standards for hazardous air pollutants (NESHAP) are promulgated for the petroleum refinery industry under authority of section 112 of the Clean Air Act. This background information document provides technical information and analyses used in the development of the final NESHAP and Agency reponses to public comments on the proposed rule.

  18. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOEpatents

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  19. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOEpatents

    Gross, Kenneth C.; Markun, Francis; Zawadzki, Mary T.

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  20. Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases

    SciTech Connect

    Beavon, D.K.; Mackles, M.

    1980-11-11

    Liquified hydrocarbon gases containing at least carbonyl sulfide as an impurity are purified by intimately mixing the liquified hydrocarbon gas with an aqueous absorbent for hydrogen sulfide in a hydrolysis zone maintained at a temperature and a pressure sufficient to maintain the liquified hydrocarbon gas in the liquid state and hydrolyze the carbonyl sulfide to hydrogen sulfide and carbon dioxide. The liquified hydrocarbon gas containing at least a portion of the formed carbonyl sulfide and carbon dioxide is separated from the liquid absorbent and passed to an absorption zone where it is contacted with a liquid hydrogen sulfide absorbent where at least the formed hydrogen sulfide is separated from the liquified petroleum gas. A stage of absorption of at least hydrogen sulfide may proceed mixing of the liquified hydrocarbon gas with the absorbent in the hydrolysis reaction zone. The absorbent employed does not combine irreversibly with carbonyl sulfide, hydrogen sulfide, and carbon dioxide, and preferably is an aqueous solution of diethanolamine.

  1. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOEpatents

    Chang, Shih-Ger; Liu, David K.

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  2. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect

    M. Aslam K. Khalil

    2009-07-16

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small

  3. U.S. Exports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 2,353 2,986 3,205 3,621 4,176 4,738 1973-2015 Crude Oil 42 47 67 134 351 465 1910-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 164 249 314 468 703 966 1983-2015 Pentanes Plus 32 101 118 137 166 183 1984-2015 Liquefied Petroleum Gases 132 148 196 332 537 783 1973-2015 Ethane/Ethylene 0 0 0 38 65 1983-2015 Propane/Propylene 109 124 171 302 423 615 1973-2015 Normal Butane/Butylene 22 24 26 30 76 97 1983-2015 Isobutane/Isobutylene 7

  4. U.S. Imports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 11,793 11,436 10,598 9,859 9,241 9,449 1973-2015 Crude Oil 9,213 8,935 8,527 7,730 7,344 7,363 1910-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 179 183 170 182 143 156 1983-2015 Pentanes Plus 26 48 29 34 14 11 1983-2015 Liquefied Petroleum Gases 153 135 141 148 128 145 1973-2015 Ethane 1993-2007 Ethylene 0 0 0 0 0 0 1993-2015 Propane 93 82 85 103 89 104 1995-2015 Propylene 29 28 31 24 19 19 1993-2015 Normal Butane 12 8 9 6 7 7

  5. U.S. Exports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total 5,002 5,154 5,658 5,240 5,209 5,114 1973-2016 Crude Oil 508 591 662 383 474 657 1920-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 1,079 1,147 1,367 1,144 1,164 1,059 1981-2016 Pentanes Plus 200 220 228 208 208 212 1984-2016 Liquefied Petroleum Gases 879 927 1,139 936 956 847 1973-2016 Ethane/Ethylene 85 86 94 80 90 105 1981-2016 Propane/Propylene 673 700 894 742 755 676 1973-2016 Normal Butane/Butylene 117 132 148 108

  6. U.S. Imports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total 10,002 9,829 10,183 10,076 10,507 10,311 1973-2016 Crude Oil 8,042 7,637 7,946 7,611 8,092 8,035 1920-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 144 116 136 116 149 169 1981-2016 Pentanes Plus 0 0 19 0 23 31 1981-2016 Liquefied Petroleum Gases 144 116 116 116 127 138 1973-2016 Ethane 1993-2016 Ethylene 1993-2015 Propane 98 80 81 69 76 93 1995-2016 Propylene 24 23 20 27 29 24 1993-2016 Normal Butane 5 0 2 6 7 10

  7. U.S. Blender Net Input

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total Input 2,166,784 2,331,109 2,399,318 2,539,812 2,824,480 2,989,233 2005-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 6,538 7,810 10,663 12,304 14,038 16,322 2008-2015 Pentanes Plus 1,989 2,326 4,164 4,241 3,184 2,561 2005-2015 Liquid Petroleum Gases 4,549 5,484 6,499 8,063 10,854 13,761 2008-2015 Normal Butane 4,549 5,484 6,499 8,063 10,823 13,722 2005-2015 Isobutane 31 39 2005-2015 Other Liquids 2,160,246 2,323,299 2,388,655

  8. U.S. Blender Net Input

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total Input 257,960 253,448 266,176 262,899 269,507 271,792 2005-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 1,783 1,315 339 414 336 657 2008-2016 Pentanes Plus 423 177 194 276 191 288 2005-2016 Liquid Petroleum Gases 1,360 1,138 145 138 145 369 2008-2016 Normal Butane 1,360 1,138 145 138 145 369 2005-2016 Isobutane 2005-2015 Other Liquids 256,177 252,133 265,837 262,485 269,171 271,135 2008-2016 Oxygenates/Renewables 27,683

  9. U.S. Exports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 858,685 1,089,848 1,172,965 1,321,787 1,524,170 1,729,378 1981-2015 Crude Oil 15,198 17,158 24,693 48,968 128,233 169,741 1870-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 59,842 90,968 115,054 170,941 256,587 352,618 1981-2015 Pentanes Plus 11,792 36,837 43,136 49,883 60,533 66,642 1984-2015 Liquefied Petroleum Gases 48,050 54,131 71,918 121,058 196,054 285,976 1981-2015 Ethane/Ethylene 0 0 0 13,820 23,619 1983-2015

  10. U.S. Exports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total 155,073 154,624 175,388 157,194 161,473 158,545 1981-2016 Crude Oil 15,742 17,736 20,511 11,489 14,684 20,370 1920-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 33,450 34,405 42,385 34,311 36,076 32,838 1981-2016 Pentanes Plus 6,195 6,600 7,067 6,226 6,433 6,571 1984-2016 Liquefied Petroleum Gases 27,254 27,805 35,318 28,085 29,643 26,267 1981-2016 Ethane/Ethylene 2,621 2,587 2,923 2,414 2,802 3,256 1981-2016

  11. U.S. Imports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History Total 4,304,533 4,174,210 3,878,852 3,598,454 3,372,904 3,448,734 1981-2015 Crude Oil 3,362,856 3,261,422 3,120,755 2,821,480 2,680,626 2,687,409 1910-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 65,314 66,851 62,192 66,290 52,031 56,789 1981-2015 Pentanes Plus 9,498 17,681 10,680 12,241 5,186 4,009 1981-2015 Liquefied Petroleum Gases 55,816 49,170 51,512 54,049 46,845 52,780 1981-2015 Ethane 1993-2007 Ethylene 135 119 115 123 129 36

  12. U.S. Imports of Crude Oil and Petroleum Products

    Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Total 310,060 294,858 315,660 302,286 325,716 319,629 1981-2016 Crude Oil 249,300 229,100 246,323 228,320 250,845 249,099 1920-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 4,462 3,491 4,213 3,475 4,624 5,238 1981-2016 Pentanes Plus 5 4 604 4 702 953 1981-2016 Liquefied Petroleum Gases 4,457 3,487 3,609 3,471 3,922 4,285 1981-2016 Ethane 1993-2016 Ethylene 1993-2015 Propane 3,045 2,413 2,497 2,060 2,346 2,893 1995-2016

  13. Hard probes of strongly-interacting atomic gases

    SciTech Connect

    Nishida, Yusuke

    2012-06-18

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  14. Emissions of greenhouse gases in the United States 1997

    SciTech Connect

    1998-10-01

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  15. Method for removing acid gases from a gaseous stream

    DOEpatents

    Gorin, Everett; Zielke, Clyde W.

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  16. Radiolytic and thermal generation of gases from Hanford grout samples

    SciTech Connect

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Mulac, W.A.

    1993-10-01

    Gamma irradiation of WHC-supplied samples of grouted Tank 102-AP simulated nonradioactive waste has been carried out at three dose rates, 0.25, 0.63, and 130 krad/hr. The low dose rate corresponds to that in the actual grout vaults; with the high dose rate, doses equivalent to more than 40 years in the grout vault were achieved. An average G(H{sub 2}) = 0.047 molecules/100 eV was found, independent of dose rate. The rate of H2 production decreases above 80 Mrad. For other gases, G(N{sub 2}) = 0.12, G(O{sub 2}) = 0.026, G(N{sub 2}O) = 0.011 and G(CO) = 0.0042 at 130 krad/hr were determined. At lower dose rates, N{sub 2} and O{sub 2} could not be measured because of interference by trapped air. The value of G(H{sub 2}) is higher than expected, suggesting segregation of water from nitrate and nitrite salts in the grout. The total pressure generated by the radiolysis at 130 krad/h has been independently measured, and total amounts of gases generated were calculated from this measurement. Good agreement between this measurement and the sum of all the gases that were independently determined was obtained. Therefore, the individual gas measurements account for most of the major components that are generated by the radiolysis. At 90 {degree}C, H{sub 2}, N{sub 2}, and N{sub 2}O were generated at a rate that could be described by exponential formation of each of the gases. Gases measured at the lower temperatures were probably residual trapped gases. An as yet unknown product interfered with oxygen determinations at temperatures above ambient. The thermal results do not affect the radiolytic findings.

  17. FAQs for Survey Forms 800, 810, and 820

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Liquefied Refinery Gases (LRG) are products of refinery processing (distillation, cracking, etc.) of crude oil and unfinished oils and include the following product Codes: - 641 ...

  18. TABLE29.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update

    9. Refinery Net Production of Finished Petroleum Products by PAD and Refining Districts, July 2004 Liquefied Refinery Gases ... 2,082 70...

  19. Methods, systems, and devices for deep desulfurization of fuel gases

    DOEpatents

    Li, Liyu; King, David L.; Liu, Jun; Huo, Qisheng

    2012-04-17

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  20. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  1. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOEpatents

    Joubert, James I.

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  2. Natural Gas Plant Stocks of Natural Gas Liquids

    Gasoline and Diesel Fuel Update

    Product: Natural Gas Liquids Pentanes Plus Liquefied Petroleum Gases Ethane Propane Normal Butane Isobutane Period: Monthly Annual Download Series History Download Series History ...

  3. Crude Oil and Petroleum Products Total Stocks Stocks by Type

    Energy Information Administration (EIA) (indexed site)

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases EthaneEthylene PropanePropylene Normal ButaneButylene ...

  4. TABLE28.CHP:Corel VENTURA

    Annual Energy Outlook

    Oil and Petroleum Products by Destination, (Thousand Barrels) Destination Liquefied Finished Crude Pentanes Petroleum Motor Distillate Fuel Residual Oil a Plus Gases Gasoline Jet ...

  5. Carbon Capture and Sequestration (via Enhanced Oil Recovery) from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect

    Stewart Mehlman

    2010-06-16

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE’s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  6. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oils Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oils March 23-27, 2015 Thermochemical Conversion Principal Investigator: Santosh Gangwal Technical Leaders: August Meng and Kevin McCabe Southern Research January 5 th , 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement  Project Goal - Develop a mild thermochemical liquefaction process to convert woody biomass to stabilized

  7. OPTIONS FOR ABATING GREENHOUSE GASES FROM EXHAUST STREAMS.

    SciTech Connect

    FTHENAKIS,V.

    2001-12-01

    This report examines different alternatives for replacing, treating, and recycling greenhouse gases. It is concluded that treatment (abatement) is the only viable short-term option. Three options for abatement that were tested for use in semiconductor facilities are reviewed, and their performance and costs compared. This study shows that effective abatement options are available to the photovoltaic (PV) industry, at reasonable cost.

  8. Use of low temperature blowers for recirculation of hot gases

    DOEpatents

    Maru, H.C.; Forooque, M.

    1982-08-19

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  9. Habitat of natural gases in Papua New Guinea

    SciTech Connect

    Schoell, M.; Beeunas, M.A. Baskin, D.K.; Monnier, F. ); Eisenberg, L.I.; Valenti, G.L. )

    1996-01-01

    Thermogenic natural gases in Papua New Guinea occur in hanging wall anticlines and related structures along a 160 mile section of the Papuan fold and thrust belt between S.E. Hedinia in the SE and Pnyang in the NW. Isotopic compositions of the oil associated gases in the SE between Hedinia and Mananda varies little ([delta][sup l3]C[sub CH4]=-44[+-]2[per thousand] and [delta]D[sub CH4]=-200[+-]20[per thousand]). However, subtle isotopic and compositional patterns in these gases are structurally controlled and indicate primary differences in the filling history of the individual structures. In addition, secondary redistribution of the gases between the Agogo and Iagifu structure can be traced through isotopic similarities. In S.E. Mananda, however, gas isotope patterns are affected by bacterial degradation of the gas. Tire concentration of CO[sub 2] in the oil associated gases in the SE is low (0.6-3.0 %) and the carbon isotope values ([delta][sup 13]C[sub CO2]=-10 to -19[per thousand]) suggest an organic origin with minor inorganic contributions. Gas in the Juha structure ([delta][sup 13]C[sub CH4]=-36.8[per thousand]) is likely from a more mature source and has a CO[sub 2] concentration of 9.6% with a [delta][sup 13]C[sub CO2]=-5.9[per thousand], indicating additional CO[sub 2] generating processes in this area, likely related to magmatic activity in the vicinity of the Juha structure. The Pnyang structure in the NW of the area holds a gas ([delta][sup 13]C[sub CH4]-40.5[per thousand]) which is isotopically intermediate between the Juha gas and the oil associated gases in the SE. The low CO[sub 2] concentration of 0.2% suggests that Pnyang is sourced from a gas kitchen similar to, but more mature than, the kitchen for the oil associated gases in the SE of the province. This is consistent with the high GOR in this structure and the association of the gas with a high API gravity condensate.

  10. Habitat of natural gases in Papua New Guinea

    SciTech Connect

    Schoell, M.; Beeunas, M.A. Baskin, D.K.; Monnier, F.; Eisenberg, L.I.; Valenti, G.L.

    1996-12-31

    Thermogenic natural gases in Papua New Guinea occur in hanging wall anticlines and related structures along a 160 mile section of the Papuan fold and thrust belt between S.E. Hedinia in the SE and Pnyang in the NW. Isotopic compositions of the oil associated gases in the SE between Hedinia and Mananda varies little ({delta}{sup l3}C{sub CH4}=-44{+-}2{per_thousand} and {delta}D{sub CH4}=-200{+-}20{per_thousand}). However, subtle isotopic and compositional patterns in these gases are structurally controlled and indicate primary differences in the filling history of the individual structures. In addition, secondary redistribution of the gases between the Agogo and Iagifu structure can be traced through isotopic similarities. In S.E. Mananda, however, gas isotope patterns are affected by bacterial degradation of the gas. Tire concentration of CO{sub 2} in the oil associated gases in the SE is low (0.6-3.0 %) and the carbon isotope values ({delta}{sup 13}C{sub CO2}=-10 to -19{per_thousand}) suggest an organic origin with minor inorganic contributions. Gas in the Juha structure ({delta}{sup 13}C{sub CH4}=-36.8{per_thousand}) is likely from a more mature source and has a CO{sub 2} concentration of 9.6% with a {delta}{sup 13}C{sub CO2}=-5.9{per_thousand}, indicating additional CO{sub 2} generating processes in this area, likely related to magmatic activity in the vicinity of the Juha structure. The Pnyang structure in the NW of the area holds a gas ({delta}{sup 13}C{sub CH4}-40.5{per_thousand}) which is isotopically intermediate between the Juha gas and the oil associated gases in the SE. The low CO{sub 2} concentration of 0.2% suggests that Pnyang is sourced from a gas kitchen similar to, but more mature than, the kitchen for the oil associated gases in the SE of the province. This is consistent with the high GOR in this structure and the association of the gas with a high API gravity condensate.

  11. Strategic planning for and implementation of reclaimed municipal waste water as make-up to a refinery cooling system

    SciTech Connect

    Francis, W.R.; Mazur, J.J.; Rao, N.M.

    1996-08-01

    This paper discusses the successful use of treated municipal plant waste water effluent (Title 22) in a refinery cooling water system. Conversion from well water to this make-up water source was preceded by developing a carefully crafted transition plan. Steps were taken to identify key system performance indicators, establish desired performance goals, and implement stringent monitoring and control protocols. In addition, all possible contingencies were considered and solutions developed. Treating Title 22 waters is very challenging and entails risks not associated with normal makeup waters. Several novel on-line monitoring and control tools are available which help minimize these risks while enhancing tower operation. Performance monitoring of critical system parameters is essential in order to provide early warning of problems so that corrective measures can be implemented. In addition, a high level of system automation enhances reliable operation. Corrosion, scaling and microbiological performance of the system with Title 22 water is discussed in comparison to previous well water make-up.

  12. Methanol production from eucalyptus wood chips. Attachment III. Florida's eucalyptus energy farm and methanol refinery: the background environment

    SciTech Connect

    Fishkind, H.H.

    1982-04-01

    A wide array of general background information is presented on the Central Florida area in which the eucalyptus energy plantation and methanol refinery will be located. Five counties in Central Florida may be affected by the project, DeSoto, Hardee, Hillsborough, Manatee, and Polk. The human resources of the area are reviewed. Included are overviews of population demographic and economic trends. Land use patterns and the transportation are system described, and the region's archeological and recreational resources are evaluated. The region's air quality is emphasized. The overall climate is described along with noise and air shed properties. An analysis of the region's water resources is included. Ground water is discussed first followed by an analysis of surface water. Then the overall quality and water supply/demand balance for the area is evaluated. An overview of the region's biota is presented. Included here are discussions of the general ecosystems in Central Florida, and an analysis of areas with important biological significance. Finally, land resources are examined.

  13. Assessment of the potential for refinery applications of inorganic membrane technology: An identification and screening analysis. Final report

    SciTech Connect

    Johnson, H.E.; Schulman, B.L.

    1993-05-01

    Commercial application of membrane technology in the separation of gas, liquid, and solid streams has grown to a business with worldwide revenues exceeding $1 billion annually. Use of organic membranes for industrial gas separation, particularly in the refining industry, is one of the major growth areas. However, organic membranes based on polymeric separation barriers, are susceptible to damage by liquids, and careful precautions must be taken to retain the system integrity. Researchers are currently developing small pore sized inorganic membranes which may substantially increase the efficiency and economics in selected refinery separation applications. Expected advantages of these advanced inorganic membranes include high permeability, high selectivity, and low manufacturing cost. SFA Pacific conducted a screening analysis to identify applications for inorganic membrane technology in the petroleum refining industry and their potential cost advantages over competing separation systems. Two meetings were held in connection with this project. Copies of Viewgraphs presented by SFA Pacific at these meetings are attached in Appendices A and C. Potential high priority applications and market impacts of advanced inorganic membrane technology in the refining industry are addressed in this report, and include the following areas: Competitive separation technologies; application of those technologies; incentives for inorganic membranes; market benefits and impacts of inorganic membranes.

  14. Influence of a combustion-driven oscillation on global mixing in the flame from a refinery flare

    SciTech Connect

    Langman, A.S.; Nathan, G.J.

    2011-01-15

    An assessment of the influence of strong combustion-driven oscillations on mixing rates and visible radiation in the flame from a full-scale refinery flare is reported. Importantly, the oscillations were generated naturally, with no external forcing, and at a high Reynolds number of 4 x 10{sup 6}. These conditions differentiate this study from those of previous investigations, which all involved some external forcing and were at a Re too low to ensure fully turbulent flow within the flame. A frame-by-frame analysis of video footage, providing good resolution of the instantaneous edge of each flame, was used to assess flame dimensions, and so to determine a global residence time. Since the flames are in the fast-chemistry regime, the visual imagers can be used to determine a global mixing rate. The analysis reveals a consistent picture that the combustion-driven oscillations do not result in a significant change to the global mixing rate, but do increase the visible radiation. This is in contrast to previous investigations, using externally forced jets, where forcing at the preferred mode has been found to increase mixing rates and reduce radiation. (author)

  15. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025 Fact 825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years ...

  16. ARM Carbon Cycle Gases Flasks at SGP Site (Dataset) | Data Explorer

    Office of Scientific and Technical Information (OSTI)

    Carbon Cycle Gases Flasks at SGP Site Title: ARM Carbon Cycle Gases Flasks at SGP Site Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern ...

  17. System for trapping and storing gases for subsequent chemical reduction to solids

    DOEpatents

    Vogel, John S.; Ognibene, Ted J.; Bench, Graham S.; Peaslee, Graham F.

    2009-11-03

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  18. Clostridium stain which produces acetic acid from waste gases

    DOEpatents

    Gaddy, James L.

    1997-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  19. Nanostructured carbon materials for adsorption of methane and other gases

    DOEpatents

    Stadie, Nicholas P.; Fultz, Brent T.; Ahn, Channing; Murialdo, Maxwell

    2015-06-30

    Provided are methods for storing gases on porous adsorbents, methods for optimizing the storage of gases on porous adsorbents, methods of making porous adsorbents, and methods of gas storage of optimized compositions, as in systems containing porous adsorbents and gas adsorbed on the surface of the porous adsorbent. The disclosed methods and systems feature a constant or increasing isosteric enthalpy of adsorption as a function of uptake of the gas onto the exposed surface of a porous adsorbent. Adsorbents with a porous geometry and surface dimensions suited to a particular adsorbate are exposed to the gas at elevated pressures in the specific regime where n/V (density) is larger than predicted by the ideal gas law by more than several percent.

  20. Apparatus for hot-gas desulfurization of fuel gases

    DOEpatents

    Bissett, Larry A. (Morgantown, WV)

    1992-01-01

    An apparatus for removing sulfur values from a hot fuel gas stream in a fdized bed contactor containing particulate sorbent material by employing a riser tube regeneration arrangement. Sulfur-laden sorbent is continuously removed from the fluidized bed through a stand pipe to the riser tube and is rapidly regenerated in the riser tube during transport of the sorbent therethrough by employing an oxygen-containing sorbent regenerating gas stream. The riser tube extends from a location below the fluidized bed to an elevation above the fluidized bed where a gas-solid separating mechanism is utilized to separate the regenerated particulate sorbent from the regeneration gases and reaction gases so that the regenerated sorbent can be returned to the fluidized bed for reuse.

  1. Decontamination of combustion gases in fluidized bed incinerators

    DOEpatents

    Leon, Albert M.

    1982-01-01

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  2. Clostridium strain which produces acetic acid from waste gases

    DOEpatents

    Gaddy, J.L.

    1997-01-14

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  3. Apparatus for the plasma destruction of hazardous gases

    DOEpatents

    Kang, Michael

    1995-01-01

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  4. Apparatus for the plasma destruction of hazardous gases

    DOEpatents

    Kang, M.

    1995-02-07

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  5. Flash pyrolysis of biomass with reactive and nonreactive gases

    SciTech Connect

    Sundaram, M.S.; Steinberg, M.; Fallon, P.

    1982-10-01

    Studies were done on the flash pyrolysis of Douglas fir wood in the presence of reactive and nonreactive gases including hydrogen, methane, and helium. Pyrolysis and gasification of the wood particles was done in one step, without catalysts. Almost complete (98%) gasification of the carbon in Douglas fir wood was achieved at 1000/sup 0/C and 500-psi hydrogen pressure. The reaction products were methane, ethane, ethylene, carbon monoxide, BTX, and water. Flash hydropyrolysis produced a large yield of hydrocarbon gases (up to 78% C) comprising methane and ethane. High yields of ethylene (up to 21% C) and BTX (up to 12% C) were obtained via methane pyrolysis of fir wood; a free-radical mechanism is proposed to explain the enhanced yield of ethylene in a methane atmosphere.

  6. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Energy Information Administration (EIA) (indexed site)

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,813 3,440 3,591 7,549 6,265 8,763 9,872 18,776 13,652 9,971 1990's 9,981 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  7. Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

    SciTech Connect

    Jordan, I.; Huppert, M.; Wörner, H. J.; Brown, M. A.; Bokhoven, J. A. van

    2015-12-15

    A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

  8. Flask Samplers for Carbon Cycle Gases and Isotopes (FLASK) Handbook

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    1 Flask Samplers for Carbon Cycle Gases and Isotopes (FLASK) Handbook S Biraud March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not

  9. Improving Desulfurization to Enable Fuel Cell Utilization of Digester Gases

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Desulfurization to Enable Fuel Cell Utilization of Digester Gases Introduction With their clean and quiet operation, fuel cells represent a promising means of implementing small-scale distributed power generation. Waste heat from the fuel cell can be harnessed for heating, creating an effcient combined heat and power (CHP) system. If the fuel cell is fueled from a renewable source, its use has the potential to reduce greenhouse gas emissions and natural gas consumption. Derived from

  10. APPARATUS FOR CLEANING GASES WITH ELECTROSTATICALLY CHARGED PARTICLES

    DOEpatents

    Johnstone, H.F.

    1960-02-01

    An apparatus is described for cleaning gases with the help of electrostatically charged pellets. The pellets are blown past baffles in a conduit and into the center of a rotuting body of the gas to be cleaned. The pellets are charged electrostatically by impinging on the baffles. The pellets collect the particles suspended in the gas in their passage from the center of the rotating body to its edge.

  11. Extraction of uranium from spent fuels using liquefied gases

    SciTech Connect

    Sawada, Kayo; Hirabayashi, Daisuke; Enokida, Youichi

    2007-07-01

    For reprocessing of spent nuclear fuels, a novel method to extract actinides from spent fuel using highly compressed gases, nitrogen dioxide and carbon dioxide was proposed. As a fundamental study, the nitrate conversion with liquefied nitrogen dioxide and the nitrate extraction with supercritical carbon dioxide were demonstrated by using uranium dioxide powder, uranyl nitrate and tri-n-butylphosphate complex in the present study. (authors)

  12. Emissions of greenhouse gases in the United States 1996

    SciTech Connect

    1997-10-01

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  13. Greenhouse gases mitigation options and strategies for Tanzania

    SciTech Connect

    Mwandosya, M.J.; Meena, H.E.

    1996-12-31

    Tanzania became a party to the United Nations Framework on Climate Change (UN FCCC) when she ratified the Convention in March, 1996. Now that Tanzania and other developing countries are Parties to the UN FCCC, compliance with its provisions is mandatory. The legal requirements therefore provide a basis for their participation in climate change studies and policy formulation. All parties to the Convention are required by Article 4.1 of the United Nations Convention on Climate Change (UN FCCC) to develop, periodically update, publish, and make available national inventories of anthropogenic emissions and removal of greenhouse gases that are not controlled by the Montreal Protocol. This study on possible options for the mitigation of greenhouse gases in Tanzania is a preliminary effort towards the fulfilment of the obligation. In order to fulfil their obligations under the UN FCCC and have a meaningful mitigation assessment, identification and quantification of anthropogenic sources of atmospheric emissions of greenhouse gases in the country was undertaken. In this respect, the study of anthropogenic emissions by source and removals by sink of GHGs in Tanzania was done with the main objective of increasing the quantity and quality of base-line data available in order to further scientific understanding of the relationship of greenhouse gas emissions to climate change. Furthermore, the study facilitated identification of national policy and technological options that could reduce the level of emissions in the country.

  14. Chemical production from industrial by-product gases: Final report

    SciTech Connect

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  15. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  16. Short-Term Energy Outlook Model Documentation: Petroleum Products Supply Module

    Reports and Publications

    2013-01-01

    The Petroleum Products Supply Module of the Short-Term Energy Outlook (STEO) model provides forecasts of petroleum refinery inputs (crude oil, unfinished oils, pentanes plus, liquefied petroleum gas, motor gasoline blending components, and aviation gasoline blending components) and refinery outputs (motor gasoline, jet fuel, distillate fuel, residual fuel, liquefied petroleum gas, and other petroleum products).

  17. Plasma-chemical waste treatment of acid gases

    SciTech Connect

    Harkness, J.B.L.; Doctor, R.D.; Daniels, E.J.

    1993-09-01

    The research to date has shown that a H{sub 2}S waste-treatment process based on plasma-chemical dissociation technology is compatible with refinery and high-carbon-oxide acid-gas streams. The minor amounts of impurities produced in the plasma-chemical reactor should be treatable by an internal catalytic reduction step. Furthermore, the plasma-chemical technology appears to be more efficient and more economical than the current technology. The principal key to achieving high conversions with relatively low energies of dissociation is the concept of the high-velocity, cyclonic-flow pattern in the plasma reaction zone coupled with the recycling of unconverted hydrogen sulfide. Future work will include testing the effects of components that might be carried over to the plasma reactor by ``upset`` conditions in the amine purification system of a plant and testing the plasma-chemical process on other industrial wastes streams that contain potentially valuable chemical reagents. The strategy for the commercialization of this technology is to form a Cooperative Research and Development Agreement with the Institute of Hydrogen Energy and Plasma Technology of the Russian Scientific Center/Kurchatov Institute and with an American start-up company to develop an ``American`` version of the process and to build a commercial-scale demonstration unit in the United States. The timetable proposed would involve building a ``field test`` facility which would test the plasma-chemical reactor and sulfur recovery unit operations on an industrial hydrogen sulfide waste s at a scale large enough to obtain the energy and material balance data required for a final analysis of the commercial potential of this technology. The field test would then be followed by construction of a commercial demonstration unit in two to three years. The commercial demonstration unit would be a fully integrated plant consisting of one commercial-scale module.

  18. Conceptual design assessment for the co-firing of bio-refinery supplied lignin project. Quarterly report, June 23--July 1, 2000

    SciTech Connect

    Berglund, T.; Ranney, J.T.; Babb, C.L.

    2000-07-27

    The Conceptual Design Assessment for the Co-Firing of Bio-Refinery Supplied Lignin Project was successfully kicked off on July 23, 2000 during a meeting at the TVA-PPI facility in Muscle Shoals, AL. An initial timeline for the study was distributed, issues of concern were identified and a priority actions list was developed. Next steps include meeting with NETL to discuss de-watering and lignin fuel testing, the development of the mass balance model and ethanol facility design criteria, providing TVA-Colbert with preliminary lignin fuel analysis and the procurement of representative feed materials for the pilot and bench scale testing of the hydrolysis process.

  19. Chevron: Refinery Identifies $4.4 Million in Annual Savings by Using Process Simulation Models to Perform Energy-Efficiency Assessment

    SciTech Connect

    2004-05-01

    In an energy-efficiency study at its refinery near Salt Lake City, Utah, Chevron focused on light hydrocarbons processing. The company found it could recover hydrocarbons from its fuel gas system and sell them. By using process simulation models of special distillation columns and associated reboilers and condensers, Chevron could predict the performance of potential equipment configuration changes and process modifications. More than 25,000 MMBtu in natural gas could be saved annually if a debutanizer upgrade project and a new saturated gas plant project were completed. Together, these projects would save $4.4 million annually.

  20. Solubilities of heavy fossil fuels in compressed gases

    SciTech Connect

    Monge, A. Jr.

    1982-01-01

    Design of processes for upgrading heavy fossil fuels such as coal-derived liquids, heavy petroleum fractions, tar sands, and shale oil, requires quantitative information for equilibrium properties of the fossil fuel in the presence of compressed light gases at elevated temperatures. Presented here are methods to predict and measure solubilities of heavy fossil fuels in compressed gases in the region ambient to 100 bar and 600 K. A molecular-thermodynamic model is used to predict heavy fossil-fuel solubilities. The heavy fuel is fractionated ina spinning-band column at low pressure and high reflux; each fraction is considered to be a pseudo-component. Each fraction is characterized by one vapor-pressure datum (obtained during fractionation), elemental analysis, and proton-NMR spectra (to determine aromaticity). Liquid-phase properties are obtained from the SWAP equation for vapor pressure and from a density correlation. Vapor-phase properties are obtained using the virial equation of state with virial coefficients from Kaul's correlation. The molecular-thermodynamic model has been used to establish a design-oriented computer program for calculating heavy, fossil-fuel solubility for general application in process design and, in particular, for isobaric condensation as a function of temperature as required for design of a continuous-flow heat exchanger. A total-vaporization technique is used to measure the solubilities of narrow-boiling, heavy fossil-fuel fractions in compressed gases. The solubility of a heavy fraction is determined from the volume of gas required to vaporize completely a small, measured mass of fossil-fuel sample. To test the molecular-thermodynamic model, the total-vaporization technique has been used to measure the solubilities of two Lurgi coal-tar fractions in compressed methane. Predicted and experimental solubilities agree well.

  1. Liquefaction and storage of thermal treatment off-gases

    SciTech Connect

    Stull, D.M. . Rocky Flats Plant); Golden, J.O. )

    1992-09-08

    A fluidized bed catalytic oxidation unit is being developed for use in the destruction of mixed waste at the Rocky Flats Plant. Cyclones, filters, in situ neutralization of acid gases, and a catalytic converter are used to meet emission standards. Because there is concern by the public that these measures may not be adequate, two off-gas capture systems were evaluated. Both systems involve liquefaction of carbon dioxide produced in the oxidation process. The carbon dioxide would be released only after analysis proved that all appropriate emission standards are met.

  2. Separation of gases through gas enrichment membrane composites

    DOEpatents

    Swedo, Raymond J.; Kurek, Paul R.

    1988-01-01

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  3. Separation of gases through gas enrichment membrane composites

    DOEpatents

    Swedo, R.J.; Kurek, P.R.

    1988-07-19

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  4. PPPL wins Department of Energy award for reducing greenhouse gases |

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Princeton Plasma Physics Lab wins Department of Energy award for reducing greenhouse gases By Jeanne Jackson DeVoe October 2, 2012 Tweet Widget Google Plus One Share on Facebook PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon dioxide. PPPL reduced leaks of SF6 by 65 percent over three years - reducing overall greenhouse gas

  5. MAGNETIC METHOD FOR PRODUCING HIGH VELOCITY SHOCK WAVES IN GASES

    DOEpatents

    Josephson, V.

    1960-01-26

    A device is described for producing high-energy plasmas comprising a tapered shock tube of dielectric material and having a closed small end, an exceedingly low-inductance coll supported about and axially aligned with the small end of the tapered tube. an elongated multiturn coil supported upon the remninder of the exterior wall of the shock tube. a potential source and switch connected in series with the low-inductance coil, a potential source and switch connected in series with the elongated coil, means for hermetically sealing the large end of the tube, means for purging the tube of gases, and means for admitting a selected gas into the shock tube.

  6. Prospecting by sampling and analysis of airborne particulates and gases

    DOEpatents

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  7. Nonperturbative Predictions for Cold Atom Bose Gases with Tunable Interactions

    SciTech Connect

    Cooper, Fred; Chien, Chih-Chun; Mihaila, Bogdan; Timmermans, Eddy; Dawson, John F.

    2010-12-10

    We derive a theoretical description for dilute Bose gases as a loop expansion in terms of composite-field propagators by rewriting the Lagrangian in terms of auxiliary fields related to the normal and anomalous densities. We demonstrate that already in leading order this nonperturbative approach describes a large interval of coupling-constant values, satisfies Goldstone's theorem, yields a Bose-Einstein transition that is second order, and is consistent with the critical temperature predicted in the weak-coupling limit by the next-to-leading-order large-N expansion.

  8. U.S. Nuclear Deterrent

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Energy U.S. Hydropower Potential from Existing Non-powered Dams U.S. Hydropower Potential from Existing Non-powered Dams U.S. Hydropower Potential from Existing Non-powered Dams

    2010 2011 2012 2013 2014 2015 View History Total 4,304,533 4,174,210 3,878,852 3,598,454 3,372,904 3,448,734 1981-2015 Crude Oil 3,362,856 3,261,422 3,120,755 2,821,480 2,680,626 2,687,409 1910-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 65,314 66,851 62,192 66,290 52,031 56,789 1981-2015 Pentanes

  9. Emissions of greenhouse gases in the United States 1995

    SciTech Connect

    1996-10-01

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  10. Influence of impurity gases and operating conditions on PAFC performance

    SciTech Connect

    Hirai, K.; Iwasa, N.; Suzuki, M.; Okada, O.

    1996-12-31

    On-site Phosphoric Acid Fuel Cell (PAFC) Cogeneration system is installed at various test sites, such as at underground parking lot, within chemical plant premises and near urban streets. Since in the current PAFC system, cathode air is supplied to the cell with no particular pretreatment, impurity gases in the air might influence on cell performance. We have investigated the influence of various impurity gases in the cathode gas, on sub-scale single cells, and have found that NO{sub 2}, SO{sub 2} and toluene affect negatively on cell performance. The results of these experiments and the conceivable mechanism of these effects on cell degradation are reported. We have also investigated the influence of other operating parameters, such as temperature, current density, fuel utilization on cell performance. From these experiments, we have found that operating temperature is a significant factor, which mainly determines cell voltage decline rate. The results of sub-scale single cell tests and a short-stack verification test are also reported.

  11. Process for recovery of sulfur from acid gases

    DOEpatents

    Towler, Gavin P.; Lynn, Scott

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  12. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOEpatents

    Levy, Donald J.; Berman, Samuel M.

    1988-01-01

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  13. Refinery Capacity Report

    Gasoline and Diesel Fuel Update

    ... Nevada...... 5 5 0 631,700 631,700 0 657,500 657,500 0 ... Nevada 294,700 82,800 148,400 3,000 65,000 137,900 460,900 24,300 ......

  14. Refinery Outages: Fall 2014

    Gasoline and Diesel Fuel Update

    gasoline supply in a particular region because pipeline infrastructure, geography and marine shipping regulations constrain the amount of product that can flow among the different...

  15. The ultimate biomass refinery

    SciTech Connect

    Bungay, H.R. )

    1988-01-01

    Bits and pieces of refining schemes and both old and new technology have been integrated into a complete biomass harvesting, processing, waste recycle, and marketing complex. These choices are justified with economic estimates and technology assessments.

  16. Hydrogen Generation for Refineries

    Energy.gov [DOE] (indexed site)

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen ... or otherwise restricted information 2 Hydrogen from Heavy, Renewable and Waste Oils - ...

  17. U.S. Refinery

    Energy Information Administration (EIA) (indexed site)

    Oxygenates (excluding Fuel Ethanol) 24 58 112 65 76 104 2009-2015 MTBE 24 58 112 65 76 104 1993-2015 Other Oxygenates 1993-2005 Renewables (including Fuel Ethanol) 454 562 750 773 ...

  18. Refinery Outages: Fall 2014

    Annual Energy Outlook

    some Libyan crude oil production to the market, and increasing U.S. crude production. Economic growth in 2014 outside of the United States has been slow, and some recent data...

  19. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    6 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels ... Catalytic Cracking Downstream Charge Capacity (Barrels per Stream Day) Cracking Thermal ...

  20. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Pelican Refining Company LLC Lake Charles, LA 0 12,000 1214 0115 a b bblcdBarrels per calendar day. bblsdBarrels per stream day. Sources: Energy Information Administration ...

  1. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    1 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels ... Catalytic Cracking Downstream Charge Capacity (Barrels per Stream Day) Cracking Thermal ...

  2. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    532,910 476,230 680,811 454,959 PADD V 364,937 529,406 2014 2,686,917 5,616,015 ... 535,500 470,603 687,879 465,115 PADD V 382,181 523,660 2015 2,686,299 5,583,169 ...

  3. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    ... CHEVRON CORP 951,271 Chevron USA Inc ......KOCH INDUSTRIES INC 585,630 Flint Hills Resources LP ... Dickinson, North Dakota 19,500 BLACK ELK REFINING LLC ...

  4. Load Preheating Using Flue Gases from a Fuel-Fired Heating System |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Load Preheating Using Flue Gases from a Fuel-Fired Heating System Load Preheating Using Flue Gases from a Fuel-Fired Heating System This tip sheet discusses how the thermal efficiency of a process heating system can be improved significantly by using heat contained in furnace flue gases to preheat the furnace load. PROCESS HEATING TIP SHEET #9 Load Preheating Using Flue Gases from a Fuel-Fired Heating System (January 2006) (265.1 KB) More Documents & Publications

  5. Process for the cooling and separating of small particle-containing gases

    SciTech Connect

    Mink, B.H.

    1984-11-13

    Process for the cooling and separating of small particle-containing gases comprising fine, very fine and coarser particles and having a temperature in the range of from 800/sup 0/-1400/sup 0/ C. and a pressure in the range of from 3-60 bar in which the gases are first cooled in a heat exchanger for producing superheated steam, and then the coarser particles are separated from the gases in a cyclone whereafter the gases are further cooled by passing them into a helically coiled tube(s) which is (are) cooled with a cooling medium.

  6. Changing the Way We Fly: Biofuels Made from Waste Gases Reaching New Heights with Airline Industry

    Office of Energy Efficiency and Renewable Energy (EERE)

    Booking a flight soon? You may be leaving on a plane powered by renewable bio-based jet fuel that was made from industrial waste gases.

  7. Noble gases and cosmogenic radionuclides in the Eltanin Pacific meteorite

    SciTech Connect

    Bogard, D D; Garrison, D H; Caffee, M W; Kyte, F; Nishiizumi, K

    2000-01-14

    A 1.5 cm long, 1.2 g specimen of the Eltanin meteorite was found at 10.97 m depth in Polarstern piston core PS2704-1. The early studies indicated that the small fragments of the Eltanin meteorite was debris from a km-sized asteroid which impacted into the deep-ocean basin. In this study, the authors measured {sup 39}Ar-{sup 40}Ar age, noble gases, and cosmogenic radionuclides in splits of specimen as a part of consortium studies of Eltanin meteorite. They concluded that the specimen was about 3 m deep from the asteroid surface. The exposure age of the Eltanin asteroid was about 20 Myr.

  8. Fuel cell stack with internal manifolds for reactant gases

    DOEpatents

    Schnacke, A.W.

    1983-10-12

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  9. Nuclear magnetic resonance imaging with hyper-polarized noble gases

    SciTech Connect

    Schmidt, D.M.; George, J.S.; Penttila, S.I.; Caprihan, A.

    1997-10-01

    This is the final report of a six-month, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The nuclei of noble gases can be hyper polarized through a laser-driven spin exchange to a degree many orders of magnitude larger than that attainable by thermal polarization without requiring a strong magnetic field. The increased polarization from the laser pumping enables a good nuclear magnetic resonance (NMR) signal from a gas. The main goal of this project was to demonstrate diffusion-weighted imaging of such hyper-polarized noble gas with magnetic resonance imaging (MRI). Possible applications include characterizing porosity of materials and dynamically imaging pressure distributions in biological or acoustical systems.

  10. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect

    Lelas, K.; Seva, T.; Buljan, H.

    2011-12-15

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  11. Wave speeds in the macroscopic extended model for ultrarelativistic gases

    SciTech Connect

    Borghero, F.; Demontis, F.; Pennisi, S.

    2013-11-15

    Equations determining wave speeds for a model of ultrarelativistic gases are investigated. This model is already present in literature; it deals with an arbitrary number of moments and it was proposed in the context of exact macroscopic approaches in Extended Thermodynamics. We find these results: the whole system for the determination of the wave speeds can be divided into independent subsystems which are expressed by linear combinations, through scalar coefficients, of tensors all of the same order; some wave speeds, but not all of them, are expressed by square roots of rational numbers; finally, we prove that these wave speeds for the macroscopic model are the same of those furnished by the kinetic model.

  12. Fuel cell stack with internal manifolds for reactant gases

    DOEpatents

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  13. Catalytic process for removing toxic gases from gas streams

    SciTech Connect

    Baglio, J.A.; Gaudet, G.G.; Palilla, F.C.

    1983-02-22

    A multi-stage process for reducing the content of sulfurcontaining gases-notably hydrogen sulfide, sulfur dioxide, carbonyl sulfide and carbon disulfide-in waste gas streams is provided. In the first stage, the gas stream is passed through a reaction zone at a temperature between about 150 and 350/sup 0/C in the presence of a pretreated novel catalyst of the formula xLn/sub 2/O/sub 3/ in which Ln is yttrium or a rare earth element and T is cobalt, iron or nickel, and each of x and y is independently a number from 0 to 3, said catalyst being substantially non-crystalline and having a surface area of from about 10 m/sup 2//g to about 40 m/sup 2//g. The preferred catalyst is one in which Ln is lanthanum, T is cobalt, and x and y range from 1 to 3, including non-integers. The first stage yields a product stream having a reduced content of sulfur-containing gases, including specifically, substantial reduction of carbonyl sulfide and virtual elimination of carbon disulfide. An intermediate stage is a claus reaction, which may take place in one or more reaction zones, at temperatures less than about 130/sup 0/ C, in the presence of known catalysts such as bauxite, alumina or cobalt molybdates. The final stage is the air oxidation of hydrogen sulfide at a temperature between about 150 and 300/sup 0/ C in the presence of a catalyst usable in first stage.

  14. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  15. Device for accurately measuring mass flow of gases

    DOEpatents

    Hylton, J.O.; Remenyik, C.J.

    1994-08-09

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure is disclosed. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel. 5 figs.

  16. On flame kernel formation and propagation in premixed gases

    SciTech Connect

    Eisazadeh-Far, Kian; Metghalchi, Hameed [Northeastern University, Mechanical and Industrial Engineering Department, Boston, MA 02115 (United States); Parsinejad, Farzan [Chevron Oronite Company LLC, Richmond, CA 94801 (United States); Keck, James C. [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2010-12-15

    Flame kernel formation and propagation in premixed gases have been studied experimentally and theoretically. The experiments have been carried out at constant pressure and temperature in a constant volume vessel located in a high speed shadowgraph system. The formation and propagation of the hot plasma kernel has been simulated for inert gas mixtures using a thermodynamic model. The effects of various parameters including the discharge energy, radiation losses, initial temperature and initial volume of the plasma have been studied in detail. The experiments have been extended to flame kernel formation and propagation of methane/air mixtures. The effect of energy terms including spark energy, chemical energy and energy losses on flame kernel formation and propagation have been investigated. The inputs for this model are the initial conditions of the mixture and experimental data for flame radii. It is concluded that these are the most important parameters effecting plasma kernel growth. The results of laminar burning speeds have been compared with previously published results and are in good agreement. (author)

  17. Sorption of atmospheric gases by bulk lithium metal

    SciTech Connect

    Hart, C. A.; Skinner, C. H.; Capece, A. M.; Koel, B. E.

    2016-01-01

    Lithium conditioning of plasma facing components has enhanced the performance of several fusion devices. Elemental lithium will react with air during maintenance activities and with residual gases (H2O, CO, CO2) in the vacuum vessel during operations. We have used a mass balance (microgram sensitivity) to measure the mass gain of lithium samples during exposure of a similar to 1 cm(2) surface to ambient and dry synthetic air. For ambient air, we found an initial mass gain of several mg/h declining to less than 1 mg/h after an hour and decreasing by an order of magnitude after 24 h. A 9 mg sample achieved a final mass gain corresponding to complete conversion to Li2CO3 after 5 days. Exposure to dry air resulted in a 30 times lower initial rate of mass gain. The results have implications for the chemical state of lithium plasma facing surfaces and for safe handling of lithium coated components. (C) 2015 Elsevier B.V. All rights reserved.

  18. Ultra-low level radon assays in gases

    SciTech Connect

    Liu, Xin Ran

    2015-08-17

    The SuperNEMO experiment aims to search for the neutrinoless double beta decay (0νβ β) to T{sub 1{sub /{sub 2}}}(0ν) > 10{sup 26} years, this corresponds to an effective neutrino mass of 50-100 meV. The extremely rare event rate means the minimisation of background is of critical concern. The stringent strategy instigated to ensure detector radiopurity is outlined here for all construction materials. In particular the large R&D programme undertaken to reach the challengingly low level of radon, < 0.15 mBq/m{sup 3}, required inside the SuperNEMO gaseous tracker will be detailed. This includes an experiment designed to measure radon diffusion through various materials. A “Radon Concentration Line” (RnCL) was developed to be used in conjunction with a state-of-the-art radon detector in order to achieve world leading sensitivity to {sup 222}Rn content in large gas volumes at the level of a few µBq/m{sup 3}. A radon purification system was developed and installed which has demonstrated radon suppression by several orders of magnitude depending on the carrier gas. This apparatus has now been commissioned and measurements of cylindered gas have been made to confirm radon suppression by a factor 20 when using nitrogen as the carrier gas. The results from measurements of radon content in various gases, used inside SuperNEMO, using the RnCL will be presented.

  19. Oklahoma Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Energy Information Administration (EIA) (indexed site)

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0

  20. Glass surface deactivants for sulfur-containing gases

    SciTech Connect

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  1. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Energy Information Administration (EIA) (indexed site)

    Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0

  2. Process for removal of sulfur compounds from fuel gases

    DOEpatents

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  3. Device for accurately measuring mass flow of gases

    DOEpatents

    Hylton, James O.; Remenyik, Carl J.

    1994-01-01

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel.

  4. Sorption of atmospheric gases by bulk lithium metal

    SciTech Connect

    Hart, C. A.; Skinner, C. H.; Capece, A. M.; Koel, B. E.

    2016-01-01

    Lithium conditioning of plasma facing components has enhanced the performance of several fusion devices. Elemental lithium will react with air during maintenance activities and with residual gases (H2O, CO, CO2) in the vacuum vessel during operations. We have used a mass balance (microgram sensitivity) to measure the mass gain of lithium samples during exposure of a ~1 cm2 surface to ambient and dry synthetic air. For ambient air, we found an initial mass gain of several mg/h declining to less than 1 mg/h after an hour and decreasing by an order of magnitude after 24 h. A 9 mg sample achieved a final mass gain corresponding to complete conversion to Li2CO3 after 5 days. Exposure to dry air resulted in a 30 times lower initial rate of mass gain. The results have implications for the chemical state of lithium plasma facing surfaces and for safe handling of lithium coated components.

  5. Accurate, reliable control of process gases by mass flow controllers

    SciTech Connect

    Hardy, J.; McKnight, T.

    1997-02-01

    The thermal mass flow controller, or MFC, has become an instrument of choice for the monitoring and controlling of process gas flow throughout the materials processing industry. These MFCs are used on CVD processes, etching tools, and furnaces and, within the semiconductor industry, are used on 70% of the processing tools. Reliability and accuracy are major concerns for the users of the MFCs. Calibration and characterization technologies for the development and implementation of mass flow devices are described. A test facility is available to industry and universities to test and develop gas floe sensors and controllers and evaluate their performance related to environmental effects, reliability, reproducibility, and accuracy. Additional work has been conducted in the area of accuracy. A gravimetric calibrator was invented that allows flow sensors to be calibrated in corrosive, reactive gases to an accuracy of 0.3% of reading, at least an order of magnitude better than previously possible. Although MFCs are typically specified with accuracies of 1% of full scale, MFCs may often be implemented with unwarranted confidence due to the conventional use of surrogate gas factors. Surrogate gas factors are corrections applied to process flow indications when an MFC has been calibrated on a laboratory-safe surrogate gas, but is actually used on a toxic, or corrosive process gas. Previous studies have indicated that the use of these factors may cause process flow errors of typically 10%, but possibly as great as 40% of full scale. This paper will present possible sources of error in MFC process gas flow monitoring and control, and will present an overview of corrective measures which may be implemented with MFC use to significantly reduce these sources of error.

  6. Production of greenhouse gases in the former Soviet Union

    SciTech Connect

    Kolchugina, T.P.; Vinson, T.S. . Civil Engineering Dept.)

    1994-09-01

    The former Soviet Union (FSU) was the largest country in the world and was one of the greatest emitters of greenhouse gases to the atmosphere. At the end of the 1980s and the beginning of the 1990s the CO[sub 2] emissions for the FSU amounted to 1.46 Pg C yr[sup [minus]1] (Pg = 10[sup 15] g). Total CH[sub 4] emissions for the FSU were 55.8 Tg C yr[sup [minus]1] (Tg = 10[sup 12] g) or approximately one-third of the global CH[sub 4] emissions; 53% of the FSU CH[sub 4] emissions was contributed by peatlands. Emissions of CFCs were 67 Gg yr[sup [minus]1] (Gg = 10[sup 9] g) and comprised 12% of the global CFCs emissions. The forest sector was a net sink for 0.48 Pg C yr[sup [minus]1] of atmospheric carbon, offsetting approximately one-half of the CO[sub 2] emissions from industrial processes. FSU peatlands accumulated 52 Tg C yr[sup [minus]1], but overall they were a net source of 48 Tg C yr[sup [minus]1] to the atmosphere considering utilization of peat. The net CO[sub 2] emissions of the FSU were 0.68 Pg C yr[sup [minus]1]. The FSU and China shared the fifth and sixth places in the world ranking of net CO[sub 2] emissions. The FSU and European countries shared the fourth and fifth places in the world ranking of net CO[sub 2] emissions per capita.

  7. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  8. ACID GASES IN CO2-RICH SUBSURFACE GEOLOGIC ENVIRONMENTS

    SciTech Connect

    Chialvo, Ariel A; Vlcek, Lukas; Cole, David

    2013-01-01

    The analysis of species behavior involving dilute fluid environments has been crucial for the advance of modern solvation thermodynamics through molecular-based formalisms to guide the development of macroscopic regression tools in the description of fluid behavior and correlation of experimental data (Chialvo 2013). Dilute fluid environments involving geologic formations are of great theoretical and practical relevance regardless of the thermodynamic state conditions. The most challenging systems are those involving highly compressible and reactive confined environments, i.e., where small perturbations of pressure and/or temperature can trigger considerable density changes. This in turn can alter significantly the species solvation, their preferential solvation, and consequently, their reactivity with one another and with the surrounding mineral surfaces whose outcome is the modification of the substrate porosity and permeability, and ultimately, the integrity of the mineral substrates. Considering that changes in porosity and permeability resulting from dissolution and precipitation phenomena in confined environments are at the core of the aqueous CO2-mineral interactions, and that caprock integrity (e.g., sealing capacity) depends on these key parameters, it is imperative to gain fundamental understanding of the mineral-fluid interfacial phenomena and fluid-fluid equilibria under mineral confinement at subsurface conditions. In order to undertand the potential effects of acid gases as contaminants of supercritical CO2 streams, in the next section we will discuss the thermodynamic behavior of CO2 fluid systems by addressing two crucial issues in the context of carbon capture, utilization and sequestration (CCUS) technologies: (i) Why should we consider (acid gas) CO2 impurities? and (ii) Why are CO2 fluid - mineral interactions of paramount relevance?

  9. Methods for separating oxygen from oxygen-containing gases

    DOEpatents

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  10. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  11. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Oxide Emission Standards, Model Years 2017-2025 | Department of Energy 5: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025 Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025 The Environmental Protection Agency finalized Tier 3 emission standards in a rule issued in March 2014. One effect of the rule is a decrease in the combined amount of non-methane organic gases

  12. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect

    May, R.L.; Snow, N.J. Jr.

    1983-12-06

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a well-head; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; and separating LPG from gas vapors of the refrigerated natural gas. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for cooling the compressed gases therefrom; and a product separator downstream of the refrigeration unit for receiving cooled and compressed gases discharged from the refrigeration unit and separating LPG therein from gases remaining in vapor form.

  13. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOEpatents

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  14. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOEpatents

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  15. Peru mitigation assessment of greenhouse gases: Sector -- Energy. Peru climate change country study; Final report

    SciTech Connect

    1996-08-01

    The aim of this study is to determine the Inventory and propose Greenhouse Gases Mitigation alternatives in order to face the future development of the country in a clean environmental setting without delaying the development process required to improve Peruvian standard of living. The main idea of this executive abstract is to show concisely the results of the Greenhouse Gases Mitigation for Peru in the period 1990--2015. The studies about mitigation for the Energy Sector are shown in this summary.

  16. Coherence and Clock Shifts in Ultracold Fermi Gases with Resonant Interactions

    SciTech Connect

    Baym, Gordon; Pethick, C. J.; Yu Zhenhua; Zwierlein, Martin W.

    2007-11-09

    Using arguments based on sum rules, we derive a general result for the average shifts of rf lines in Fermi gases in terms of interatomic interaction strengths and two-particle correlation functions. We show that near an interaction resonance shifts vary inversely with the atomic scattering length, rather than linearly as in dilute gases, thus accounting for the experimental observation that clock shifts remain finite at Feshbach resonances.

  17. Radon and helium in soil gases in the Phlegraean Fields, central Italy

    SciTech Connect

    Lombardi, S. ); Reimer, G.M. )

    1990-05-01

    The distribution and migration of radon and helium soil-gas concentrations in the Phlegraean Fields, Italy, are controlled by the tectonic features of the area. Radon is supplied from surficial sources and helium has both surficial and deep origins. There is no direct correlation between the two noble gases on a point-to-point basis but the areal distribution of both gases is similar, suggesting that the distribution is controlled primarily by fractures and movement of geothermal fluids.

  18. ARM Carbon Cycle Gases Flasks at SGP Site (Dataset) | Data Explorer

    Office of Scientific and Technical Information (OSTI)

    Carbon Cycle Gases Flasks at SGP Site Title: ARM Carbon Cycle Gases Flasks at SGP Site Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern Great Plains Site and analyzed by the National Oceanic and Atmospheric Administration NOAA, Earth System Research Laboratory ESRL. The SGP site is included in the NOAA Cooperative Global Air Sampling Network. The surface samples are collected from a 60 m tower at the ARM SGP Central Facility, usually once per week in

  19. Emissions of Greenhouse Gases in the United States 2009, DOE/EIA-0573(2009)

    Energy Information Administration (EIA) (indexed site)

    March 2011 www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Emissions of Greenhouse Gases in the United States 2009 ii Contacts This report, Emissions of Greenhouse Gases in the United States 2009, was prepared under the general direction of John Conti, Assistant Administrator for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. General questions concerning the content of this report may be directed to the Office of

  20. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOEpatents

    Natesan, Krishnamurti

    1992-01-01

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  1. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOEpatents

    Natesan, K.

    1992-11-17

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  2. Emissions of greenhouse gases in the United States, 1985--1990

    SciTech Connect

    Not Available

    1993-11-10

    The Earth`s capacity to support life depends on the moderating influences of gases that envelop the planet and warm its surface and protect it from harmful radiation. These gases are referred to as ``greenhouse gases.`` Their warming capacity, called ``the greenhouse effect,`` is essential to maintaining a climate hospitable to all plant, animal, and human life. In recent years, however, there has been increasing concern that human activity may be affecting the intricate balance between the Earth`s absorption of heat from the sun and its capacity to reradiate excess heat back into space. Emissions of greenhouse gases from human activities may be an important mechanism that affects global climate. Thus, research is intensifying to improve our understanding of the role human activities might play in influencing atmospheric concentrations of greenhouse gases. On the basis of scientific findings of the past few decades, the US Government and the international community at large are now taking steps toward stabilizing greenhouse gas emissions. This report contributes to that process. Mandated by Congress this report provides estimates of US emissions of the principal greenhouse gases--carbon dioxide, methane, nitrous oxide, chlorofluorcarbons, carbon monoxide, nitrogen oxides, and nonmethane volatile organic compounds. Estimates are for the period 1985 to 1990. Preliminary estimates for 1991 have also been included, whenever data were available.

  3. Recent advances in the speciation of selenium in petroleum refinery and municipal waste using ICP-MS and ICP-MS coupled with liquid chromatography

    SciTech Connect

    Roehl, R.

    1996-09-01

    An analytical scheme for the speciation of selenium in petroleum refinery waste waters reported at the 1994 Winter Plasma Conference included methods for the determination of total, dissolved, particulate and volatile selenium, as well as for the separate quantitation of dissolved selenite, selenate and selenocyanate. Several of those methods have been improved significantly. Determinations of total, dissolved, and particulate selenium are based on the ICP-MS quantitation of the {sup 82}Se isotope in waste water samples or sample fractions digested with hydrogen peroxide and nitric acid. These analyses now include corrections for potential isobaric interferences are minimized by monitoring the signals for Br{sup +} and m/z 79 and SO{sub 3}H{sup +} at m/z 83 and correcting the apparent {sup 82}Se{sup +} signal using appropriate equations with correction factors derived from the analysis of calibration solutions containing sulfate and bromide. The correction factors used in those equations relate ionic species of different composition to each other (e.g., Br{sup +} and HBr{sup +}). To help ensure that the relative rate of formation of those ions in the plasma is not sample dependent, high concentrations of sodium and other easily ionized elements are removed from the sample digests by cation-exchange.

  4. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  5. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  6. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOEpatents

    Walker, Richard J.

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  7. Emission of biogenic sulfur gases from Chinese paddy soil and rice plant

    SciTech Connect

    Zhen Yang [Nanjing Univ. of Science and Technology (China); Li Kong [Nanjing Agricultural Univ. (China)

    1996-12-31

    Biogenic sulfur gases emitted from terrestrial ecosystem may play in important role in global sulfur cycle and have a profound influence on global climate change. But very little is known concerning emissions from paddy soil and rice plant, which are abundant in many parts of the world. As a big agricultural country, this is about 33 million hectare rice planted in China. With laboratory incubation and closed chamber method in the field, the biogenic sulfur gases emitted from Chinese paddy soil and rice plant were detected in both conditions: hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), methyl mercaptan (MSH), carbon disulfide (CS{sub 2}), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Among which, DMS was predominant part of sulfur emission. Emission of sulfur gases from different paddy field exhibit high spatial and temporal variability. The application of fertilizer and organic manure, total sulfur content in wetland, air temperature were positively correlated to the emission of volatile sulfur gases from paddy soil. Diurnal and seasonal variation of total volatile sulfur gases and DMS indicate that their emissions were greatly influenced by the activity of the rice plant. The annual emission of total volatile sulfur gases, from Nanjing paddy field is ranged from 4.0 to 9.5 mg S m{sup -2}yr{sup -1}, that of DMS is ranged from 3.1 to 6.5 mg S m{sup -2}yr{sup -1}. Rice plant could absorb COS gas, that may be one of the sinks of COS.

  8. ARM - PI Product - ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ProductsARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases Data from ccg-flasks are sampled at the ARM SGP site and analyzed by the NOAA Earth System Research Laboratory (ESRL) as part of the NOAA Cooperative Global Air Sampling Network. Surface samples are collected from a 60m tower at the SGP Central

  9. Changing the Way We Fly: Renewable Jet Fuels Made from Waste Gases Reaching

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    New Heights with Airline Industry | Department of Energy Changing the Way We Fly: Renewable Jet Fuels Made from Waste Gases Reaching New Heights with Airline Industry Changing the Way We Fly: Renewable Jet Fuels Made from Waste Gases Reaching New Heights with Airline Industry August 11, 2016 - 10:45am Addthis In June 2015, United Airlines announced a partnership with biofuel company Fulcrum BioEnergy to invest in future commercial-scale aviation biofuel plants. The company’s innovative

  10. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOEpatents

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  11. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOEpatents

    Young, John E.; Jalan, Vinod M.

    1984-01-01

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  12. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOEpatents

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  13. EIA's Energy in Brief: What are greenhouse gases and how much are emitted

    Gasoline and Diesel Fuel Update

    by the United States? greenhouse gases and how much are emitted by the United States? Last Updated: January 20, 2016 Greenhouse gases trap heat from the sun and warm the planet's surface. Most U.S. greenhouse gas emissions are related to energy production and consumption. Most of those emissions are carbon dioxide (CO2) from the burning of fossil fuels. From 1990 to 2014, energy-related carbon dioxide emissions in the United States increased on average by about 0.3% per year. Because

  14. TABLE19.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update

    9. Percent Refinery Yield of Petroleum Products by PAD and Refining Districts, a January 1998 Liquefied Refinery Gases ...... 1.2 -0.3 1.1 3.4 ...

  15. untitled

    Gasoline and Diesel Fuel Update

    - - - - - -6 - - - Natural Gas Liquids and LRGs 306 120 93 26 - 37 95 15 398 Pentanes Plus 33 0 1 22 - 0 43 4 10 Liquefied Petroleum Gases 273 120 92 4 - 37 52 11 388 Ethane...

  16. untitled

    Gasoline and Diesel Fuel Update

    - - - - - 72 - - - Natural Gas Liquids and LRGs 240 66 147 149 - -293 176 8 710 Pentanes Plus 29 0 2 33 - -1 57 5 2 Liquefied Petroleum Gases 212 66 146 116 - -292 120 3 707...

  17. untitled

    Annual Energy Outlook

    - - - - - 14 - - - Natural Gas Liquids and LRGs 298 103 102 50 - -4 115 14 428 Pentanes Plus 33 0 1 25 - 0 48 4 7 Liquefied Petroleum Gases 265 103 101 25 - -4 68 9 420 Ethane...

  18. untitled

    Gasoline and Diesel Fuel Update

    - - - - - -68 - - - Natural Gas Liquids and LRGs 297 78 90 47 - -47 131 13 415 Pentanes Plus 37 0 1 26 - 0 58 3 4 Liquefied Petroleum Gases 260 78 89 20 - -47 74 10 411 Ethane...

  19. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook

    - - - - - 14 - - - Natural Gas Liquids and LRGs 298 105 110 47 - -5 118 14 433 Pentanes Plus 33 - 1 25 - 0 48 4 7 Liquefied Petroleum Gases 265 105 109 22 - -4 70 9 426 Ethane...

  20. Documentation for Emissions of Greenhouse Gases in the United States 2008

    Reports and Publications

    2011-01-01

    The Energy Policy Act of 1992 required the U.S. Energy Information Administration (EIA) to prepare an inventory of aggregate U.S. national emissions of greenhouse gases for the period 1987-1990, with annual updates thereafter. This report documents the methodology for the seventeenth annual inventory, covering national emissions over the period 1990-2008.

  1. Isotopic studies of rare gases in terrestrial samples and natural nucleosynthesis

    SciTech Connect

    Not Available

    1990-07-01

    This project is concerned with research in rare gas mass spectrometry. We read the natural record that isotopes of the rare gases provide. We study fluids using a system (RARGA) that is sometimes deployed in the field. In 1990 there was a strong effort to reduce the backlog of RARGA samples on hand, so that it was a year of intensive data gathering. Samples from five different areas in the western United States and samples from Guatemala and Australia were analyzed. In a collaborative study we also began analyzing noble gases from rocks associated with the fluids. An important objective, continuing in 1991, is to understand better the reasons for somewhat elevated {sup 3}He/{sup 4}He ratios in regions where there is no contemporary volcanism which could produce the effect by addition of mantle helium. Our helium data have given us and our collaborators some insights, which are to be followed up, into gold mineralization in geothermal regions. Our DOE work in calibrating a sensitive laser microprobe mass spectrometer for noble gases in fluid inclusions continues. Having completed a series of papers on noble gases in diamonds, we next will attempt to make precise isotopic measurements on xenon from mantle sources, in search of evidence for terrestrially elusive {sup 244}Pu decay.

  2. Greenhouse gases emission from municipal waste management: The role of separate collection

    SciTech Connect

    Calabro, Paolo S.

    2009-07-15

    The municipal solid waste management significantly contributes to the emission in the atmosphere of greenhouse gases (e.g. CO{sub 2}, CH{sub 4}, N{sub 2}O) and therefore the management process from collection to treatment and disposal has to be optimized in order to reduce these emissions. In this paper, starting from the average composition of undifferentiated municipal solid waste in Italy, the effect of separate collection on greenhouse gases emissions from municipal waste management has been assessed. Different combinations of separate collection scenarios and disposal options (i.e. landfilling and incineration) have been considered. The effect of energy recovery from waste both in landfills and incinerators has also been addressed. The results outline how a separate collection approach can have a significant effect on the emission of greenhouse gases and how wise municipal solid waste management, implying the adoption of Best Available Technologies (i.e. biogas recovery and exploitation system in landfills and energy recovery system in Waste to Energy plants), can not only significantly reduce greenhouse gases emissions but, in certain cases, can also make the overall process a carbon sink. Moreover it has been shown that separate collection of plastic is a major issue when dealing with global warming relevant emissions from municipal solid waste management.

  3. Evolution of Some Particle Detectors Based On the Discharge in Gases

    DOE R&D Accomplishments

    Charpak, G.

    1969-11-19

    Summary of the properties of some of the detectors that are commonly used in counter experiments to localize charged particles, and which are based on discharge in gases under the influence of electric fields and some basic facts of gaseous amplification in homogeneous and inhomogeneous fields.

  4. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOEpatents

    Judkins, Roddie R.; Burchell, Timothy D.

    1999-01-01

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known "pressure swing adsorption" technique utilizing the same sorption material.

  5. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOEpatents

    Judkins, R.R.; Burchell, T.D.

    1999-07-20

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known pressure swing adsorption'' technique utilizing the same sorption material. 1 fig.

  6. Comment on "Radiative forcings for 28 potential Archean greenhouse gases" by Byrne and Goldblatt (2014)

    DOE PAGES [OSTI]

    Kochanov, R. V.; Gordon, I. E.; Rothman, L. S.; Sharpe, S. W.; Johnson, T. J.; Sams, R. L.

    2015-08-25

    In the recent article by Byrne and Goldblatt, "Radiative forcing for 28 potential Archean greenhouse gases", Clim. Past. 10, 1779–1801 (2014), the authors employ the HITRAN2012 spectroscopic database to evaluate the radiative forcing of 28 Archean gases. As part of the evaluation of the status of the spectroscopy of these gases in the selected spectral region (50–1800 cm-1), the cross sections generated from the HITRAN line-by-line parameters were compared with those of the PNNL database of experimental cross sections recorded at moderate resolution. The authors claimed that for NO2, HNO3, H2CO, H2O2, HCOOH, C2H4, CH3OH and CH3Br there exist largemore » or sometimes severe disagreements between the databases. In this work we show that for only three of these eight gases a modest discrepancy does exist between the two databases and we explain the origin of the differences. For the other five gases, the disagreements are not nearly at the scale suggested by the authors, while we explain some of the differences that do exist. In summary, the agreement between the HITRAN and PNNL databases is very good, although not perfect. Typically differences do not exceed 10 %, provided that HITRAN data exist for the bands/wavelengths of interest. It appears that a molecule-dependent combination of errors has affected the conclusions of the authors. In at least one case it appears that they did not take the correct file from PNNL (N2O4 (dimer)+ NO2 was used in place of the monomer). Finally, cross sections of HO2 from HITRAN (which do not have a PNNL counterpart) were not calculated correctly in BG, while in the case of HF misleading discussion was presented there based on the confusion by foreign or noise features in the experimental PNNL spectra.« less

  7. Results of the Independent Radiological Verification Survey of Remediation at Building 31, Former Linde Uranium Refinery, Tonawanda, New York (LI001V)

    SciTech Connect

    McKenzie, S.P.; Uziel, M.S.

    1998-11-01

    As part of the Formerly Utilized Sites Remedial Action Progmq a team from Oak Ridge National Laboratory (ORNL) conducted a radiological veriihtion survey of Building 31 at the former Linde Uranium Refinery, Tonawau& New York. The purpose of the survey was to ver@ that remedial action completed by the project management contractor had reduced contamination levels to within authorized limits. Prior to remediatioq tied radioactive material was prevalent throughout the building and in some of the ductwork Decontaminadon consisted of removing surfhce contamination from floors, baseboards, and overhead areas; removing some air ducts; and vacuuming dust. Building 31 at the former Linde site in TonawandA New Yorlq was thoroughly investigated inside and outside for radionuclide residues. The verification team discovered previously undetected contaminadon beneath the concrete pad on the first floor and underneath floor tiles on the second floor. All suspect floor tiles were removed and any contamination beneath them cleaned to below guideline levels. The verification team also discovered elevated radiation levels associated with overhead air lines that led to the eventual removal of the entire air lige and a complete investigation of the history of all process piping in the building. Final verification surveys showed that residual surface beta-gamma activity levels were slightly elevated in some places but below U.S. Department of Energy applicable guidelines for protection against radiation (Table 1). Similarly, removable radioactive contamination was also below applicable guidelines. Exposure rates within the building were at typical background levels, and no consistently elevated indoor radon concentrations were measured. However, radionuclide analysis of subsurface soil from beneath the concrete floor on the ground level showed concentrations of `*U and'% that exceeded applicable guidelines. At the time of this survey, there was no measured exposure pathway for this

  8. Outlook for Refinery Outages and Available Refinery Capacity...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    of gasoline and distillate, and to include a more detailed consideration of the impact of unexpected outages on product supplies. This report reviews the potential...

  9. Improved Laser Induced Breakdown Spectroscopy (LIBS) Elemental Composition Detection System: A device to measure subsurface gases, liquids, and solids at subsurface conditions

    Energy Innovation Portal

    2016-02-23

    This device can measure subsurface gases, liquids, and solids at subsurface conditions. Atomic identification and concentration measurements can be made on solids, liquids, and gases at down hole pressure and temperature conditions....

  10. Refinery Capacity Report - Explanatory Notes

    Energy Information Administration (EIA) (indexed site)

    ... Office, or other Federal agencies authorized by law to receive such information. ... purposes such as administrative, regulatory, law enforcement, or adjudicatory purposes. ...

  11. Reformulated Gasoline Foreign Refinery Rules

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    1995 Introduction On August 27, 1997, the EPA promulgated revised the rules that allow ... Notice Citation (1) Date Final Rule by EPA allows foreign refiners to establish ...

  12. U.S. Refinery Yield

    Energy Information Administration (EIA) (indexed site)

    Special Naphthas 0.2 0.2 0.3 0.3 0.3 0.2 1993-2015 Lubricants 1.1 1.1 1.0 1.0 1.0 1.1 1993-2015 Waxes 0.1 0.1 0.1 0.1 0.0 0.0 1993-2015 Petroleum Coke 5.3 5.5 5.5 5.5 5.4 5.3 ...

  13. Integrated Forest Products Refinery (IFPR)

    SciTech Connect

    van Heiningen, Adriaan R. P.

    2010-05-29

    Pre-extraction–kraft studies of hardwoods showed that when extracting about 10% of the wood, the final kraft pulp yield and physical properties could only be maintained at a level similar to that of regular kraft pulp when the final extract pH was close to neutral. This so-called “near neutral” pre-extraction condition at a level of 10% wood dissolution was achieved by contacting the wood chips with green liquor (GL) at a charge of about 3% (as Na2O on wood) at 160 °C for almost 2 hours (or an H-factor of about 800 hrs.). During subsequent kraft cooking of the pre-extracted hardwood chips the effective alkali charge could be reduced by about 3% (as Na2O on wood) and the cooking time shortened relative to that during regular kraft cooking, while still producing the same bleachable grade kappa number as the kraft control pulp. For softwood, no extraction conditions were discovered in the present investigation whereby both the final kraft pulp yield and physical properties could be maintained at a level similar to that of regular softwood kraft pulp. Therefore for hardwoods the “near- neutral green liquor pre-extraction conditions do meet the requirements of the IFPR concept, while for softwood, no extraction conditions were discovered which do meet these requirements. Application of simulated industrial GL at an extraction H-factor of about 800 hrs and 3% GL charge in a recirculating digester produced an hardwood extract containing about 4% (on wood) of total anhydro-sugars, 2% of acetic acid, and 1.3% of lignin. Xylan comprised of 80% of the sugars of which about 85% is oligomeric. Since only polymeric hemicelluloses and lignin may be adsorbed on pulp (produced at a yield of about 50% from the original wood), the maximum theoretical yield increase due to adsorption may be estimated as 10% on pulp (or 5% on wood). However, direct application of raw GL hardwood extract for hemicelluloses adsorption onto hardwood kraft pulp led to a yield increase of only about 1% (on pulp). By using the wet-end retention aid guar gum during the adsorption process at a charge of 0.5% on pulp the yield gain may be increased to about 5%. Unfortunately, most of this yield increase is lost during subsequent alkaline treatments in the pulp bleach plant. It was found that by performing the adsorption at alkaline conditions the adsorption loss during alkaline treatment in the bleach plant is mostly avoided. Thus a permanent adsorption yield of about 3 and 1.5% (on pulp) was obtained with addition of guar gum at a charge of 0.5 and 0.1% respectively during adsorption of GL hardwood extract on pre-extracted kraft pulp at optimal conditions of pH 11.5, 90 C for 60 minutes at 5% consistency. The beatability of the adsorbed kraft pulps was improved. Also, significant physical strength improvements were achieved. Further study is needed to determine whether the improvements in pulp yield and paper properties make this an economic IFPR concept. Application of the wood solids of a hot water extract of Acer rubrum wood strands as a substitute for polystyrene used for production of SMC maintained the water adsorption properties of the final product. Further work on the physical properties of the hemicellulose containing SMCs need to be completed to determine the potential of wood extracts for the production of partially renewable SMCs. The discovery of the “near-neutral” green liquor extraction process for hardwood was formed the basis for a commercial Integrated Biorefinery that will extract hemicelluloses from wood chips to make biofuels and other specialty chemicals. The pulp production process will be maintained as is proposed in the present researched IFBR concept. This Integrated Biorefinery will be constructed by Red Shield Acquisition LLC (RSA) at the Old Town kraft pulp mill in Maine. RSA in collaboration with the University of Maine will develop and commercialize the hemicellulose extraction process, the conversion of the hemicellulose sugars into butanol by fermentation, and the separation of specialty chemicals such as acetic acid from the extract. When operating the facility will produce 1.5 million gallons per year of butanol and create 16 new “green collar” jobs. Previously, a spare pulp digester was converted to a new extractor, and in 2009 it was demonstrated that a good hemicellulose extract could be produced, while simultaneously producing market pulp. Since then more than 250 hours of operational experience has been acquired by the mill generating a hemicellulose extract while simultaneously producing market pulp at a scale of 1000 tonnes (OD)/day of mixed northern hardwood chips.

  14. PSM implementation at a refinery

    SciTech Connect

    Nahale, T.

    1995-12-31

    Prior to the promulgation of the OSHA Standard on Process Safety Management (PSM), the petroleum industry had a precursor developed by the American Petroleum Institute titled Recommended Practice 750, Management of Process Hazards. This Recommended Practice, though not identical with the OSHA regulation, provided the industry with a voluntary standard prior to May, 1992, when PSM went into effect. In formulating a PSM implementation strategy, one of the first decisions encountered at a facility is whether to utilize a separate group dedicated full-time to PSM issues, or to develop the program using key individuals who continue to perform their regulator job duties. Although a PSM manager may prefer one strategy over the other, this staffing decisions is normally made by senior management at the facility.

  15. U.S. Refinery Stocks

    Energy Information Administration (EIA) (indexed site)

    Area: U.S. PADD 1 East Coast Appalachian No. 1 PADD 2 Ind., Ill. and Ky. Minn., Wis., N. Dak., S. Dak. Okla., Kans., Mo. PADD 3 Texas Inland Texas Gulf Coast La. Gulf Coast N. La., Ark New Mexico PADD 4 PADD 5 Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History Crude Oil and Petroleum

  16. Motiva Refinery | Department of Energy

    Energy.gov [DOE] (indexed site)

    per hour and coastal wave surges 20 to 30 feet high. there are limits on what we can do. ... parties to ensure that improved communication and coordination will lead to a better ...

  17. Refinery Outages: First Half 2015

    Gasoline and Diesel Fuel Update

    to increase by 820,000 bbld in 2015. While global oil supply growth has been strong, economic growth outside of the United States has been slow, particularly in Russia and...

  18. Process for removal of ammonia and acid gases from contaminated waters

    DOEpatents

    King, C.J.; Mackenzie, P.D.

    1982-09-03

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  19. Process for removal of ammonia and acid gases from contaminated waters

    DOEpatents

    King, C. Judson; MacKenzie, Patricia D.

    1985-01-01

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  20. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gasesHe, Ne, and Aras additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  1. Membranes, methods of making membranes, and methods of separating gases using membranes

    DOEpatents

    Ho, W. S. Winston

    2012-10-02

    Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO.sub.2, H.sub.2S, and HCl with one side of a nonporous and at least one of CO.sub.2, H.sub.2S, and HCl selectively permeable membrane such that at least one of CO.sub.2, H.sub.2S, and HCl is selectively transported through the membrane.

  2. A comprehensive study of different gases in inductively coupled plasma torch operating at one atmosphere

    SciTech Connect

    Punjabi, Sangeeta B.; Joshi, N. K.; Mangalvedekar, H. A.; Lande, B. K.; Das, A. K.; Kothari, D. C.

    2012-01-15

    A numerical study is done to understand the possible operating regimes of RF-ICP torch (3 MHz, 50 kW) using different gases for plasma formation at atmospheric pressure. A two dimensional numerical simulation of RF-ICP torch using argon, nitrogen, oxygen, and air as plasma gas has been investigated using computational fluid dynamic (CFD) software fluent{sup (c)}. The operating parameters varied here are central gas flow, sheath gas flow, RF-power dissipated in plasma, and plasma gas. The temperature contours, flow field, axial, and radial velocity profiles were investigated under different operating conditions. The plasma resistance, inductance of the torch, and the heat distribution for various plasma gases have also been investigated. The plasma impedance of ICP torch varies with different operating parameters and plays an important role for RF oscillator design and power coupling. These studies will be useful to decide the design criteria for ICP torches required for different material processing applications.

  3. Simultaneous removal of nitrogen oxides and sulfur oxides from combustion gases

    DOEpatents

    Clay, David T.; Lynn, Scott

    1976-10-19

    A process for the simultaneous removal of sulfur oxides and nitrogen oxides from power plant stack gases comprising contacting the stack gases with a supported iron oxide catalyst/absorbent in the presence of sufficient reducing agent selected from the group consisting of carbon monoxide, hydrogen, and mixtures thereof, to provide a net reducing atmosphere in the SO.sub.x /NO.sub.x removal zone. The sulfur oxides are removed by absorption substantially as iron sulfide, and nitrogen oxides are removed by catalytic reduction to nitrogen and ammonia. The spent iron oxide catalyst/absorbent is regenerated by oxidation and is recycled to the contacting zone. Sulfur dioxide is also produced during regeneration and can be utilized in the production of sulfuric acid and/or sulfur.

  4. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOEpatents

    Mollot, Darren J.; Bonk, Donald L.; Dowdy, Thomas E.

    1998-01-01

    Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

  5. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOEpatents

    Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

    1998-01-13

    Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

  6. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect

    Steinberg, M.; Fallon, P.T.

    1982-06-01

    The rapid or flash pyrolysis of wood biomass is being studied in a 1'' downflow entrained tubular reactor with a capacity of approximately 1 lb/hr of wood. The process chemistry data is being obtained with the view of building a data base and ascertaining the value of producing synthetic fuels and chemical feedstocks by the flash pyrolysis method. Data is being obtained on the effect of non-reactive pyrolyzing gases and the effect of reactive gases, hydrogen for the flash hydropyrolysis of wood and methane for flash methanolysis of wood. Preliminary process design and analysis has been made. The yield of ethylene and benzene is especially attractive for the production of chemical feedstocks from the reaction of methane and wood in a flash methanolysis process.

  7. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOEpatents

    Gaddy, J.L.

    1998-09-15

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

  8. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOEpatents

    Gaddy, James L.

    1998-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  9. OSTIblog Articles in the greenhouse gases Topic | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information greenhouse gases Topic Carbon Sequestration - Helping to Save Our Beautiful World by Kathy Chambers 17 Apr, 2014 in 17081 Goose-BNL.jpg Carbon Sequestration - Helping to Save Our Beautiful World Read more about 17081 Warmer winters are changing bird migratory patterns, warmer seawater is linked to coral reef bleaching in the Florida Keys and Puerto Rico, and more extreme climate events are affecting society and ecosystems. According to the

  10. Nonlinear spectroscopic effects in quantum gases induced by atom-atom interactions

    SciTech Connect

    Safonov, A. I. Safonova, I. I.; Yasnikov, I. S.

    2013-05-15

    We consider nonlinear spectroscopic effects-interaction-enhanced double resonance and spectrum instability-that appear in ultracold quantum gases owing to collisional frequency shift of atomic transitions and, consequently, due to the dependence of the frequencies on the population of various internal states of the particles. Special emphasis is put to two simplest cases, (a) the gas of two-level atoms and (b) double resonance in a gas of three-level bosons, in which the probe transition frequency remains constant.

  11. Boron Boosts Graphene's Sensitivity to Noxious Gases | U.S. DOE Office of

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Science (SC) Boron Boosts Graphene's Sensitivity to Noxious Gases Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 07.20.16 Boron Boosts

  12. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOEpatents

    Ayala, Raul E.

    1993-01-01

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  13. Effect of different carrier gases and their flow rates on the growth of carbon nanotubes

    SciTech Connect

    Tewari, Aarti; Sharma, Suresh C.

    2015-04-15

    The present paper examines the effect of different carrier gases and their flow rates on the growth of carbon nanotubes (CNTs). A theoretical model is developed incorporating the charging rate of the carbon nanotube, kinetics of all the plasma species, and the growth rate of the CNTs because of diffusion and accretion of ions on the catalyst nanoparticle. The three different carrier gases, i.e., argon (Ar), ammonia, and nitrogen, are considered in the present investigation, and flow rates of all the three carrier gases are varied individually (keeping the flow rates of hydrocarbon and hydrogen gas constant) to investigate the variations in the number densities of hydrocarbon and hydrogen ions in the plasma and their consequent effects on the height and radius of CNT. Based on the results obtained, it is concluded that Ar favors the formation of CNTs with larger height and radius whereas ammonia contributes to better height of CNT but decreases the radius of CNT, and nitrogen impedes both the height and radius of CNT. The present work can serve to the better understanding of process parameters during growth of CNTs by a plasma enhanced chemical vapor deposition process.

  14. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect

    1995-09-25

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  15. Comment on "Radiative forcings for 28 potential Archean greenhouse gases" by Byrne and Goldblatt (2014)

    SciTech Connect

    Kochanov, R. V.; Gordon, I. E.; Rothman, L. S.; Sharpe, S. W.; Johnson, T. J.; Sams, R. L.

    2015-08-25

    In the recent article by Byrne and Goldblatt, "Radiative forcing for 28 potential Archean greenhouse gases", Clim. Past. 10, 1779–1801 (2014), the authors employ the HITRAN2012 spectroscopic database to evaluate the radiative forcing of 28 Archean gases. As part of the evaluation of the status of the spectroscopy of these gases in the selected spectral region (50–1800 cm-1), the cross sections generated from the HITRAN line-by-line parameters were compared with those of the PNNL database of experimental cross sections recorded at moderate resolution. The authors claimed that for NO2, HNO3, H2CO, H2O2, HCOOH, C2H4, CH3OH and CH3Br there exist large or sometimes severe disagreements between the databases. In this work we show that for only three of these eight gases a modest discrepancy does exist between the two databases and we explain the origin of the differences. For the other five gases, the disagreements are not nearly at the scale suggested by the authors, while we explain some of the differences that do exist. In summary, the agreement between the HITRAN and PNNL databases is very good, although not perfect. Typically differences do not exceed 10 %, provided that HITRAN data exist for the bands/wavelengths of interest. It appears that a molecule-dependent combination of errors has affected the conclusions of the authors. In at least one case it appears that they did not take the correct file from PNNL (N2O4 (dimer)+ NO2 was used in place of the monomer). Finally, cross sections of HO2 from HITRAN (which do not have a PNNL counterpart) were not calculated correctly in BG, while in the case of HF misleading discussion was presented there based on the confusion by foreign or noise features in the experimental PNNL spectra.

  16. EIA-815

    Energy Information Administration (EIA) (indexed site)

    Other Oxygenates 445 Natural Gas Plant Liquids and Liquefied Refinery Gases, TOTAL 242 EthaneEthylene, TOTAL 108 Ethylene 631 PropanePropylene, TOTAL 246 Propylene (nonfuel use) ...

  17. EIA-800

    Energy Information Administration (EIA) (indexed site)

    ... Other Oxygenates 445 Natural Gas Plant Liquids (NGPL) and Liquefied Refinery Gases (LRG): EthaneEthylene, TOTAL 108 Ethane - LRG 641 Ethylene 631 PropanePropylene, TOTAL 246 ...

  18. EIA-800

    Energy Information Administration (EIA) (indexed site)

    ... Liquids (NGPL) and Liquefied Refinery Gases (LRG):" "EthaneEthylene, TOTAL",108,,,... "Ethane - LRG",641 "Ethylene",631 "PropanePropylene, TOTAL",246,,,... "Propane - ...

  19. EIA-817

    Energy Information Administration (EIA) (indexed site)

    Fuel 205 Other Renewable Fuels 207 Liquefied Petroleum and Refinery Gases: EthaneEthylene 108 PropanePropylene 246 Normal ButaneButylene 244 IsobutaneIsobutylene 245 ...

  20. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook

    change by sulfur content may not equal total residual fuel oil ending stocks and stock change. LRG Liquefied Refinery Gases. - Not Applicable. Notes: Totals may not equal...

  1. The terrestrial biosphere as a net source of greenhouse gases to the atmosphere

    DOE PAGES [OSTI]

    Tian, Hanqin; Lu, Chaoqun; Ciais, Philippe; Michalak, Anna M.; Canadell, Josep G.; Saikawa, Eri; Huntzinger, Deborah N.; Gurney, Kevin R; Sitch, Stephen; Zhang, Bowen; et al

    2016-03-09

    The terrestrial biosphere can release or absorb the greenhouse gases, carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O), and therefore has an important role in regulating atmospheric composition and climate1. Anthropogenic activities such as land-use change, agriculture and waste management have altered terrestrial biogenic greenhouse gas fluxes, and the resulting increases in methane and nitrous oxide emissions in particular can contribute to climate change2, 3. The terrestrial biogenic fluxes of individual greenhouse gases have been studied extensively4, 5, 6, but the net biogenic greenhouse gas balance resulting from anthropogenic activities and its effect on the climate system remains uncertain.more » Here we use bottom-up (inventory, statistical extrapolation of local flux measurements, and process-based modelling) and top-down (atmospheric inversions) approaches to quantify the global net biogenic greenhouse gas balance between 1981 and 2010 resulting from anthropogenic activities and its effect on the climate system. We find that the cumulative warming capacity of concurrent biogenic methane and nitrous oxide emissions is a factor of about two larger than the cooling effect resulting from the global land carbon dioxide uptake from 2001 to 2010. This results in a net positive cumulative impact of the three greenhouse gases on the planetary energy budget, with a best estimate (in petagrams of CO2 equivalent per year) of 3.9 ± 3.8 (top down) and 5.4 ± 4.8 (bottom up) based on the GWP100 metric (global warming potential on a 100-year time horizon). Lastly, our findings suggest that a reduction in agricultural methane and nitrous oxide emissions, particularly in Southern Asia, may help mitigate climate change.« less

  2. The Marginal Damage Costs of Different Greenhouse Gases: An Application of FUND

    SciTech Connect

    Waldhoff, Stephanie T.; Anthoff, David; Rose, Steven K.; Tol, Richard

    2014-01-01

    We use FUND 3.8 to estimate the social cost of four greenhouse gases: carbon dioxide, methane, nitrous oxide, and sulphur hexafluoride emissions. The damage potential for each gas—the ratio of the social cost of the non-carbon dioxide greenhouse gas to the social cost of carbon dioxide—is also estimated. The damage potentials are compared to several metrics, focusing in particular on the global warming potentials, which are frequently used to measure the trade-off between gases in the form of carbon dioxide equivalents. We find that damage potentials could be significantly higher than global warming potentials. This finding implies that previous papers have underestimated the relative importance of reducing non-carbon dioxide greenhouse gas emissions from an economic damage perspective. We show results for a range of sensitivity analyses: carbon dioxide fertilization on agriculture productivity, terrestrial feedbacks, climate sensitivity, discounting, equity weighting, and socioeconomic and emissions scenarios. The sensitivity of the results to carbon dioxide fertilization is a primary focus as it is an important element of climate change that has not been considered in much of the previous literature. We estimate that carbon dioxide fertilization has a large positive impact that reduces the social cost of carbon dioxide with a much smaller effect on the other greenhouse gases. As a result, our estimates of the damage potentials of methane and nitrous oxide are much higher compared to estimates that ignore carbon dioxide fertilization. As a result, our base estimates of the damage potential for methane and nitrous oxide that include carbon dioxide fertilization are twice their respective global warming potentials. Our base estimate of the damage potential of sulphur hexafluoride is similar to the one previous estimate, both almost three times the global warming potential.

  3. Unconventional states and geometric effects in mesoscopic systems of ultra-cold atomic Fermi gases

    SciTech Connect

    Bolech, C. J.

    2014-10-15

    During the last decade, experiments all over the world started to test the superconducting state of matter using a newly developed mesoscopic tunable system: trapped ultra-cold atomic gases. Theorists and experimentalists hand-in-hand are now able to advance our understanding of the superconducting state by asking new questions that probe further into the physical mechanisms underlying the phenomenon and the door is open to the exploration of exotic unconventional superconducting states. In particular, a series of experiments on systems of trapped cold atomic gases were aimed at studying the effects of polarization on superconducting pairing. Two different experimental groups encountered surprising qualitative and quantitative discrepancies which seemed to be a function of the confining geometry and the cooling protocol. Our numerical studies demonstrate a tendency towards metastability and suggest an explanation for the observed discrepancy. From our calculations, the most likely solution which is consistent with the experiments supports a state strikingly similar to the so called FFLO state (after Ferrell, Fulde, Larkin and Ovchinnikov), which had been theorized long ago but eluded detection so far. Moreover, the three-dimensional scenario described above is reminiscent of predictions for one-dimensional systems of dilute polarized attractive gases and another set of ultra-cold-atom experiments incorporates optical lattices to study this reduced-dimensionality setting. The measurements are in quantitative agreement with theoretical calculations (using a wide array of numerical and analytic techniques) in which a partially polarized phase is found to be the one-dimensional analogue of the FFLO state. Moreover, exploring the dimensional-crossover regime, our latest findings indicate that the mesoscopic nature of these quasi-one-dimensional systems favors the appearance of a new type of Mott phase transition involving an emergent pair-superfluid of equal

  4. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    SciTech Connect

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  5. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE PAGES [OSTI]

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmore » functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.« less

  6. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect

    LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

    2000-07-21

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

  7. Electric-field enhanced performance in catalysis and solid-state devices involving gases

    SciTech Connect

    Blackburn, Bryan M.; Wachsman, Eric D.; Van Assche, IV, Frederick Martin

    2015-05-19

    Electrode configurations for electric-field enhanced performance in catalysis and solid-state devices involving gases are provided. According to an embodiment, electric-field electrodes can be incorporated in devices such as gas sensors and fuel cells to shape an electric field provided with respect to sensing electrodes for the gas sensors and surfaces of the fuel cells. The shaped electric fields can alter surface dynamics, system thermodynamics, reaction kinetics, and adsorption/desorption processes. In one embodiment, ring-shaped electric-field electrodes can be provided around sensing electrodes of a planar gas sensor.

  8. Method and apparatus for detecting and measuring trace impurities in flowing gases

    DOEpatents

    Taylor, Gene W.; Dowdy, Edward J.

    1979-01-01

    Trace impurities in flowing gases may be detected and measured by a dynamic atomic molecular emission spectrograph utilizing as its energy source the energy transfer reactions of metastable species, atomic or molecular, with the impurities in the flowing gas. An electronically metastable species which maintains a stable afterglow is formed and mixed with the flowing gas in a region downstream from and separate from the region in which the metastable species is formed. Impurity levels are determined quantitatively by the measurement of line and/or band intensity as a function of concentration employing emission spectroscopic techniques.

  9. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOEpatents

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  10. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect

    Atallah, S.; Janardhan, A.

    1996-02-01

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  11. Molecular dynamics of gases and vapors in nanoporous solids. Final LDRD project report

    SciTech Connect

    Pohl, P.I.

    1996-08-01

    This report provides a study of gases in microporous solids using molecular modeling. The theory of gas transport in porous materials as well as the molecular modeling literature is briefly reviewed. Work complete is described and analyzed with retard to the prevailing theory. The work covers two simple subjects, construction of porous solid models and diffusion of He, H{sub 2}, Ar and CH{sub 4} down a pressure gradient across the material models as in typical membrane permeation experiments. The broader objective is to enhance our capability to efficiently and accurately develop, produce and apply microporous materials.

  12. Novel Material for Efficient and Low-cost Separation of Gases for Fuels and Plastics

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Novel Material for Efficient and Low-Cost Separation of Gases for Fuels and Plastics Work was performed at University of California and supported by the Center for Gas Separations Relevant to Clean Energy Technologies EFRC. Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown, C. M.; Long, J. R. Science 2012, 335, 1606-1610 Left: Crystal structure of Fe 2 (dobdc)-ethylene showing Fe (orange), O(red), C(gray), and D(blue) atoms. The view along the [001] direction shows an ethylene

  13. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  14. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  15. Sampling and analysis of hydrocarbons in combustion gases. Annual report, October 1979-September 1980

    SciTech Connect

    Johnson, I.; Myles, K.M.; Siczek, A.A.

    1981-04-01

    The purpose of these studies is to develop a method for the chemical analysis of ultratrace levels of polycyclic organic compounds in the flue gases from fluidized-bed combustors. Methods which have the potential for real time analysis have been studied. Two methods, double mass spectrometry and laser ionization mass spectrometry, appear to be promising. A brief review of current analytical methods has been made. A brief examination of fly ash from fluidized-bed combustion revealed no carcinogenic species although samples collected during fluidized-bed combustor startup were found to be mutagenic.

  16. Fundamental Understanding of the Interaction of Acid Gases with CeO2 : From Surface Science to Practical Catalysis

    DOE PAGES [OSTI]

    Tumuluri, Uma; Rother, Gernot; Wu, Zili

    2016-03-21

    Acid gases including CO2, SO2, and NOx are ubiquitous in large-scale energy applications including heterogeneous catalysis. The adverse environmental and health effects of these acid gases have resulted in high interest in the research and development of technologies to remove or convert these acid gases. The main challenge for the development of these technologies is to develop catalysts that are highly efficient, stable, and cost-effective, and many catalysts have been reported in this regard. CeO2 and CeO2-based catalysts have gained prominence in the removal and conversion of CO2, SO2, and NOx because of their structural robustness and redox and acid–basemore » properties. In this article, we provide a brief overview of the application of CeO2 and CeO2-based catalysts for the removal of CO2, SO2, and NOx gases with an emphasis on the fundamental understanding of the interactions of these acid gases with CeO2. The studies summarized in this review range from surface science using single crystals and thin films with precise crystallographic planes to practical catalysis applications of nanocrystalline and polycrystalline CeO2 materials with defects and dopants. After an introduction to the properties of CeO2 surfaces, their catalytic properties for conversions of different acid gases are reviewed and discussed. Lastly, we find that the surface atomic structure, oxygen vacancies, and surface acid–base properties of CeO2 play vital roles in the surface chemistry and structure evolution during the interactions of acid gases with CeO2 and CeO2-based catalysts.« less

  17. Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases. Final report

    SciTech Connect

    Prather, Michael J.; Hsu, Juno; Nicolau, Alex; Veidenbaum, Alex; Smith, Philip Cameron; Bergmann, Dan

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  18. Fluctuations of the number of particles within a given volume in cold quantum gases

    SciTech Connect

    Astrakharchik, G. E.; Combescot, R.; Pitaevskii, L. P.

    2007-12-15

    In ultracold gases many experiments use atom imaging as a basic observable. The resulting image is averaged over a number of realizations and mostly only this average is used. Only recently the noise has been measured to extract physical information. In the present paper we investigate the quantum noise arising in these gases at zero temperature. We restrict ourselves to the homogeneous situation and study the fluctuations in particle number found within a given volume in the gas, and more specifically inside a sphere of radius R. We show that zero-temperature fluctuations are not extensive and the leading term scales with sphere radius R as R{sup 2} ln R (or ln R) in three- (or one-) dimensional systems. We calculate systematically the next term beyond this leading order. We consider first the generic case of a compressible superfluid. Then we investigate the whole Bose-Einstein-condensation (BEC) -BCS crossover, and in particular the limiting cases of the weakly interacting Bose gas and of the free Fermi gas.

  19. The Effect of Diluent Gases In The Shock Tube and Rapid Compression Machine

    SciTech Connect

    Silke, E; W?rmel, J; O?Conaire, M; Simmie, J; Curran, H

    2007-02-09

    Studying the details of hydrocarbon chemistry in an internal combustion engine is not straightforward. A number of factors, including varying conditions of temperature and pressure, complex fluid motions, as well as variation in the composition of gasoline, render a meaningful characterization of the combusting system difficult. Some simplified experimental laboratory devices offer an alternative to complex engine environments: they remove some of the complexities that exist in real engines but retain the ability to work under engine-relevant conditions. The choice of simplified experimental devices is limited by the range of temperature and pressure at which they can operate; only the shock tube and rapid compression machine (RCM) can reach engine-relevant temperatures and pressures quickly enough and yet withstand the high pressures that occur after the ignition event. Both devices, however, suffer a common drawback: the use of inert diluent gases has been shown to affect the measured ignition delay time under some experimental conditions. Interestingly, this effect appears to be opposite in the shock tube and RCM: in the comparative study of the carrier gases argon and nitrogen, argon decreases the ignition delay time in the shock tube, but increases it in the RCM. This observation is investigated in more detail in this study.

  20. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect

    Dennis Laudal

    2008-09-30

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.