National Library of Energy BETA

Sample records for oxygenated reformulated total

  1. Process for conversion of lignin to reformulated, partially oxygenated gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    2001-01-09

    A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

  2. Reformulated Gasoline Complex Model

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Table 2. Statutory Baseline Fuel Compositions * Simple Model ... Related EIA Short-Term Forecast Analysis Products * RFG ... * Demand, Supply, and Price Outlook for Reformulated ...

  3. Reformulated diesel fuel

    DOE Patents [OSTI]

    McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

    2006-03-28

    Reformulated diesel fuels for automotive diesel engines which meet the requirements of ASTM 975-02 and provide significantly reduced emissions of nitrogen oxides (NO.sub.x) and particulate matter (PM) relative to commercially available diesel fuels.

  4. Device for measuring the total concentration of oxygen in gases

    DOE Patents [OSTI]

    Isaacs, Hugh S.; Romano, Anthony J.

    1977-01-01

    This invention provides a CO equilibrium in a device for measuring the total concentration of oxygen impurities in a fluid stream. To this end, the CO equilibrium is produced in an electrochemical measuring cell by the interaction of a carbon element in the cell with the chemically combined and uncombined oxygen in the fluid stream at an elevated temperature.

  5. Total

    U.S. Energy Information Administration (EIA) (indexed site)

    Product: Total Crude Oil Liquefied Petroleum Gases PropanePropylene Normal ButaneButylene Other Liquids Oxygenates Fuel Ethanol MTBE Other Oxygenates Biomass-based Diesel Fuel ...

  6. Reformulated gasoline quality issues

    SciTech Connect (OSTI)

    Gonzalez, R.G.; Felch, D.E.; Edgar, M.D.

    1995-11-01

    One year ago, a panel of industry experts were interviewed in the November/December 1994 issue of Fuel Reformulation (Vol. 4, No. 6). With the focus then and now on refinery investments, the panelists were asked to forecast which refining processes would grow in importance. It is apparent from their response, and from other articles and discussions throughout the year, that hydroprocessing and catalytic conversion processes are synergistic in the overall refinery design, with flexibility and process objectives varying on a unit-by-unit case. To an extent, future refinery investments in downstream petrochemicals, such as for paraxylene production, are based on available catalytic reforming feedstock. Just a importantly, hydroprocessing units (hydrotreating, hydrocracking) needed for clean fuel production (gasoline, diesel, aviation fuel), are heavily dependent on hydrogen production from the catalytic reformer. Catalytic reforming`s significant influence in the refinery hydrogen balance, as well as its status as a significant naphtha conversion route to higher-quality fuels, make this unit a high-priority issue for engineers and planners striving for flexibility.

  7. Total Imports

    U.S. Energy Information Administration (EIA) (indexed site)

    Data Series: Imports - Total Imports - Crude Oil Imports - Crude Oil, Commercial Imports - by SPR Imports - into SPR by Others Imports - Total Products Imports - Total Motor Gasoline Imports - Finished Motor Gasoline Imports - Reformulated Gasoline Imports - Reformulated Gasoline Blended w/ Fuel Ethanol Imports - Other Reformulated Gasoline Imports - Conventional Gasoline Imports - Conv. Gasoline Blended w/ Fuel Ethanol Imports - Conv. Gasoline Blended w/ Fuel Ethanol, Ed55 & < Imports -

  8. Areas Participating in the Reformulated Gasoline Program

    Gasoline and Diesel Fuel Update

    Reformulated Gasoline Program Contents * Introduction * Mandated RFG Program Areas o Table 1. Mandated RFG Program Areas * RFG Program Opt-In Areas o Table 2. RFG Program Opt-In Areas * RFG Program Opt-Out Procedures and Areas o Table 3. History of EPA Rulemaking on Opt-Out Procedures o Table 4. RFG Program Opt-Out Areas * State Programs o Table 5. State Reformulated Gasoline Programs * Endnotes Spreadsheets Referenced in this Article * Reformulated Gasoline Control Area Populations Related EIA

  9. Oxygenate Supply/Demand Balances

    Annual Energy Outlook

    Related EIA Short-Term Forecast Analysis Products * ... and Price Outlook for Reformulated Motor Gasoline, 1995 Introduction The blending of oxygenates, such as fuel ethanol ...

  10. Reformulated Gasoline Market Affected Refiners Differently, 1995

    Reports and Publications

    1996-01-01

    This article focuses on the costs of producing reformulated gasoline (RFG) as experienced by different types of refiners and on how these refiners fared this past summer, given the prices for RFG at the refinery gate.

  11. Energy and crude oil input requirements for the production of reformulated gasolines

    SciTech Connect (OSTI)

    Singh, M.; McNutt, B.

    1993-10-01

    The energy and crude oil requirements for the production of reformulated gasoline (RFG) are estimated. The scope of the study includes both the energy and crude oil embodied in the final product and the process energy required to manufacture the RFG and its components. The effects on energy and crude oil use of employing various oxygenates to meet the minimum oxygen-content level required by the Clean Air Act Amendments are evaluated. The analysis shows that production of RFG requires more total energy, but uses less crude oil, than that of conventional gasoline. The energy and crude oil use requirements of the different RFGs vary considerably. For the same emissions performance level, RFG with ethanol requires substantially more total energy and crude oil than does RFG with methyl tertiary butyl ether (MTBE) or ethyl tertiary butyl ether. A specific proposal by the US Environmental Protection Agency, designed to allow the use of ethanol in RFG, would increase the total energy required to produce RFG by 2% and the total crude oil required by 2.0 to 2.5% over the corresponding values for the base RFG with MTBE.

  12. Energy and crude oil input requirements for the production of reformulated gasolines

    SciTech Connect (OSTI)

    Singh, M.; McNutt, B.

    1993-11-01

    The energy and crude oil requirements for the production of reformulated gasolines (RFG) are estimated. Both the energy and crude oil embodied in the final product and the process energy required to manufacture the RFG and its components are included. The effects on energy and crude oil use of using various oxygenates to meet the minimum oxygen content level required by the Clean Air Act Amendments are evaluated. The analysis illustrates that production of RFG requires more total energy than that of conventional gasoline but uses less crude oil. The energy and crude oil use requirements of the different RFGs vary considerably. For the same emissions performance level, RFG with ethanol requires substantially more total energy and crude oil than RFG with MTBE or ETBE. A specific proposal by the EPA designed to allow the use of ethanol in RFG would increase the total energy required to produce RFG by 2% and the total crude oil required by 2.0 to 2.5% over that for the base RFG with MTBE.

  13. Reformulated diesel fuel and method

    DOE Patents [OSTI]

    McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

    2006-08-22

    A method for mathematically identifying at least one diesel fuel suitable for combustion in an automotive diesel engine with significantly reduced emissions and producible from known petroleum blendstocks using known refining processes, including the use of cetane additives (ignition improvers) and oxygenated compounds.

  14. Ionospheric total electron content, and far ultraviolet, near infrared oxygen emission

    SciTech Connect (OSTI)

    Aghanajafi, C.

    1988-01-01

    The purpose of this investigation is to calculate the total electron content and four oxygen emissions for solar cycle maximum at equinox season. The investigation shows that the total electron content reaches its maximum development at 2100 LT with the crest nearest to the equator being the greatest. This asymmetry reverses at 0200 LT when the crest farthest from the equator is smallest. In spite of the fact that while N{sub max} decreases at noon, and the layer becomes greater in altitude under the influence of the upward drift, the noon bite out occurs at the equator around 1200 Lt. The behavior of OI 6300 {angstrom}, the brightest dayglow source is investigated. The oxygen at 6300 {angstrom} is strongly a function of N{sub max} and h{sub max}. The data for the OI 6300 {angstrom} reveal that the latitudinal asymmetry is associated with the asymmetry in altitude of F{sub 2} peak. The maximum electron density height is strongly affected by vertical E {times} B drift velocity. The emission at 1356 {angstrom} and 7774 {angstrom} is calculated using the radiative recombination and ion-ion recombination processes. The ion-ion recombination has substantial effect in total emission rates. The intensity of OI 911 {angstrom} due to direct recombination to the ground state is obtained. These emissions can be used as a way of remotely sensing the F region and exosphere plasma properties, and the winds responsible for plasma transport.

  15. Reformulated gasoline deal with Venezuela draws heat

    SciTech Connect (OSTI)

    Begley, R.

    1994-04-06

    A fight is brewing in Congress over a deal to let Venezuela off the hook in complying with the Clean Air Act reformulated gasoline rule. When Venezuela threatened to call for a GATT panel to challenge the rule as a trade barrier, the Clinton Administration negotiated to alter the rule, a deal that members of Congress are characterizing as {open_quotes}secret{close_quotes} and {open_quotes}back door.{close_quotes}

  16. DOE Awarded Patent for Reformulated Diesel Fuel | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Awarded Patent for Reformulated Diesel Fuel DOE Awarded Patent for Reformulated Diesel Fuel May 19, 2006 - 10:46am Addthis Available free of Licensing Fees, Cleaner for the Environment WASHINGTON, DC - The U.S. Department of Energy today announced that it has developed, patented, and made commercially available reformulated diesel fuels which when used can reduce nitrogen oxides up to 10% and particulate matter up to 22% compared to those currently available. The diesel fuel formulations covered

  17. ,"U.S. Reformulated, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) (indexed site)

    ...www.eia.govdnavpetpetprirefmg2cnusepm0rdpgalm.htm" ,"Source:","Energy Information ... Reformulated Gasoline Retail Sales by Refiners (Dollars per ...

  18. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) (indexed site)

    Information AdministrationPetroleum Marketing Annual 1999 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and Selected States (Cents per...

  19. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) (indexed site)

    Information AdministrationPetroleum Marketing Annual 1998 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and Selected States (Cents per...

  20. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) (indexed site)

    Information Administration Petroleum Marketing Annual 1995 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  1. Total..........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.9 Q Q Q Heat Pump......7.7 0.3 Q Q Steam or Hot Water System......Census Division Total West Energy Information Administration ...

  2. Total..........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.9 Q Q Q Heat Pump......6.2 3.8 2.4 Steam or Hot Water System......Census Division Total Northeast Energy Information ...

  3. Total............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Total................................................................... 111.1 2,033 1,618 1,031 791 630 401 Total Floorspace (Square Feet) Fewer than 500............................................... 3.2 357 336 113 188 177 59 500 to 999....................................................... 23.8 733 667 308 343 312 144 1,000 to 1,499................................................. 20.8 1,157 1,086 625 435 409 235 1,500 to 1,999................................................. 15.4 1,592

  4. Efficient Conservative Reformulation Schemes for Lithium Intercalation

    SciTech Connect (OSTI)

    Urisanga, PC; Rife, D; De, S; Subramanian, VR

    2015-02-18

    Porous electrode theory coupled with transport and reaction mechanisms is a widely used technique to model Li-ion batteries employing an appropriate discretization or approximation for solid phase diffusion with electrode particles. One of the major difficulties in simulating Li-ion battery models is the need to account for solid phase diffusion in a second radial dimension r, which increases the computation time/cost to a great extent. Various methods that reduce the computational cost have been introduced to treat this phenomenon, but most of them do not guarantee mass conservation. The aim of this paper is to introduce an inherently mass conserving yet computationally efficient method for solid phase diffusion based on Lobatto III A quadrature. This paper also presents coupling of the new solid phase reformulation scheme with a macro-homogeneous porous electrode theory based pseudo 20 model for Li-ion battery. (C) The Author(s) 2015. Published by ECS. All rights reserved.

  5. Total

    U.S. Energy Information Administration (EIA) (indexed site)

    Total floor- space 1 Heated floor- space 2 Total floor- space 1 Cooled floor- space 2 Total floor- space 1 Lit floor- space 2 All buildings 87,093 80,078 70,053 79,294 60,998 83,569 68,729 Building floorspace (square feet) 1,001 to 5,000 8,041 6,699 5,833 6,124 4,916 7,130 5,590 5,001 to 10,000 8,900 7,590 6,316 7,304 5,327 8,152 6,288 10,001 to 25,000 14,105 12,744 10,540 12,357 8,840 13,250 10,251 25,001 to 50,000 11,917 10,911 9,638 10,813 7,968 11,542 9,329 50,001 to 100,000 13,918 13,114

  6. Total...................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    2,033 1,618 1,031 791 630 401 Total Floorspace (Square Feet) Fewer than 500............................................... 3.2 357 336 113 188 177 59 500 to 999....................................................... 23.8 733 667 308 343 312 144 1,000 to 1,499................................................. 20.8 1,157 1,086 625 435 409 235 1,500 to 1,999................................................. 15.4 1,592 1,441 906 595 539 339 2,000 to

  7. Total..........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    . 111.1 20.6 15.1 5.5 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.9 0.5 0.4 500 to 999........................................................... 23.8 4.6 3.6 1.1 1,000 to 1,499..................................................... 20.8 2.8 2.2 0.6 1,500 to 1,999..................................................... 15.4 1.9 1.4 0.5 2,000 to 2,499..................................................... 12.2 2.3 1.7 0.5 2,500 to

  8. Total..........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    5.6 17.7 7.9 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.5 0.3 Q 500 to 999........................................................... 23.8 3.9 2.4 1.5 1,000 to 1,499..................................................... 20.8 4.4 3.2 1.2 1,500 to 1,999..................................................... 15.4 3.5 2.4 1.1 2,000 to 2,499..................................................... 12.2 3.2 2.1 1.1 2,500 to

  9. Total..........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.7 21.7 6.9 12.1 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.9 0.6 Q Q 500 to 999........................................................... 23.8 9.0 4.2 1.5 3.2 1,000 to 1,499..................................................... 20.8 8.6 4.7 1.5 2.5 1,500 to 1,999..................................................... 15.4 6.0 2.9 1.2 1.9 2,000 to 2,499..................................................... 12.2 4.1 2.1 0.7

  10. Total..........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    4.2 7.6 16.6 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 1.0 0.2 0.8 500 to 999........................................................... 23.8 6.3 1.4 4.9 1,000 to 1,499..................................................... 20.8 5.0 1.6 3.4 1,500 to 1,999..................................................... 15.4 4.0 1.4 2.6 2,000 to 2,499..................................................... 12.2 2.6 0.9 1.7 2,500 to

  11. Total................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    .. 111.1 86.6 2,522 1,970 1,310 1,812 1,475 821 1,055 944 554 Total Floorspace (Square Feet) Fewer than 500............................. 3.2 0.9 261 336 162 Q Q Q 334 260 Q 500 to 999.................................... 23.8 9.4 670 683 320 705 666 274 811 721 363 1,000 to 1,499.............................. 20.8 15.0 1,121 1,083 622 1,129 1,052 535 1,228 1,090 676 1,500 to 1,999.............................. 15.4 14.4 1,574 1,450 945 1,628 1,327 629 1,712 1,489 808 2,000 to

  12. Total..........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    .. 111.1 24.5 1,090 902 341 872 780 441 Total Floorspace (Square Feet) Fewer than 500...................................... 3.1 2.3 403 360 165 366 348 93 500 to 999.............................................. 22.2 14.4 763 660 277 730 646 303 1,000 to 1,499........................................ 19.1 5.8 1,223 1,130 496 1,187 1,086 696 1,500 to 1,999........................................ 14.4 1.0 1,700 1,422 412 1,698 1,544 1,348 2,000 to 2,499........................................ 12.7

  13. Total...................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Floorspace (Square Feet) Total Floorspace 1 Fewer than 500............................................ 3.2 0.4 Q 0.6 1.7 0.4 500 to 999................................................... 23.8 4.8 1.4 4.2 10.2 3.2 1,000 to 1,499............................................. 20.8 10.6 1.8 1.8 4.0 2.6 1,500 to 1,999............................................. 15.4 12.4 1.5 0.5 0.5 0.4 2,000 to 2,499............................................. 12.2 10.7 1.0 0.2 Q Q 2,500 to

  14. Total.........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Floorspace (Square Feet) Total Floorspace 2 Fewer than 500.................................................. 3.2 Q 0.8 0.9 0.8 0.5 500 to 999.......................................................... 23.8 1.5 5.4 5.5 6.1 5.3 1,000 to 1,499.................................................... 20.8 1.4 4.0 5.2 5.0 5.2 1,500 to 1,999.................................................... 15.4 1.4 3.1 3.5 3.6 3.8 2,000 to 2,499.................................................... 12.2 1.4 3.2 3.0 2.3 2.3

  15. Total..........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    25.6 40.7 24.2 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.9 0.5 0.9 1.0 500 to 999........................................................... 23.8 4.6 3.9 9.0 6.3 1,000 to 1,499..................................................... 20.8 2.8 4.4 8.6 5.0 1,500 to 1,999..................................................... 15.4 1.9 3.5 6.0 4.0 2,000 to 2,499..................................................... 12.2 2.3 3.2 4.1

  16. Total..........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    7.1 7.0 8.0 12.1 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.4 Q Q 0.5 500 to 999........................................................... 23.8 2.5 1.5 2.1 3.7 1,000 to 1,499..................................................... 20.8 1.1 2.0 1.5 2.5 1,500 to 1,999..................................................... 15.4 0.5 1.2 1.2 1.9 2,000 to 2,499..................................................... 12.2 0.7 0.5 0.8 1.4

  17. Total...........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500.................................... 3.2 0.7 Q 0.3 0.3 0.7 0.6 0.3 Q 500 to 999........................................... 23.8 2.7 1.4 2.2 2.8 5.5 5.1 3.0 1.1 1,000 to 1,499..................................... 20.8 2.3 1.4 2.4 2.5 3.5 3.5 3.6 1.6 1,500 to 1,999..................................... 15.4 1.8 1.4 2.2 2.0 2.4 2.4 2.1 1.2 2,000 to 2,499..................................... 12.2 1.4 0.9

  18. Total...........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    26.7 28.8 20.6 13.1 22.0 16.6 38.6 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................... 3.2 1.9 0.9 Q Q Q 1.3 2.3 500 to 999........................................... 23.8 10.5 7.3 3.3 1.4 1.2 6.6 12.9 1,000 to 1,499..................................... 20.8 5.8 7.0 3.8 2.2 2.0 3.9 8.9 1,500 to 1,999..................................... 15.4 3.1 4.2 3.4 2.0 2.7 1.9 5.0 2,000 to 2,499..................................... 12.2 1.7 2.7 2.9 1.8 3.2 1.1 2.8

  19. Process for conversion of lignin to reformulated hydrocarbon gasoline

    SciTech Connect (OSTI)

    Shabtai, Joseph S.; Zmierczak, Wlodzimierz W.; Chornet, Esteban

    1999-09-28

    A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

  20. DOE Awarded Patent for Reformulated Diesel Fuel | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Awarded Patent for Reformulated Diesel Fuel May 19, 2006 - 10:46am Addthis Available free of Licensing Fees, Cleaner for the Environment WASHINGTON, DC - The U.S. Department of...

  1. Assessment of California reformulated gasoline impact on vehicle fuel economy

    SciTech Connect (OSTI)

    Aceves, S., LLNL

    1997-01-01

    Fuel economy data contained in the 1996 California Air Resources Board (CARB) report with respect to the introduction of California Reformulated Gasoline (CaRFG) has been examined and reanalyzed by two additional statistical methodologies. Additional data has also been analyzed by these two statistical approaches. Within the assumptions of the analysis, point estimates for the reduction in fuel economy using CaRFG as compared to conventional, non-reformulated gasoline were 2-4%, with a 95% upper confidence bound of 6%. Substantial variations in fuel economy are routine and inevitable due to additional factors which affect mileage, even if there is no change in fuel reformulation. This additional analysis confirms the conclusion reached by CARB with respect to the impact of CaRFG on fuel economy.

  2. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) (indexed site)

    61.5 70.8 92.7 90.7 81.5 72.8 - 78.0 See footnotes at end of table. 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 146 Energy Information...

  3. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) (indexed site)

    62.6 71.7 92.3 89.9 82.6 72.7 - 78.2 See footnotes at end of table. 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 146 Energy Information...

  4. Demand, Supply, and Price Outlook for Reformulated Motor Gasoline 1995

    Reports and Publications

    1994-01-01

    Provisions of the Clean Air Act Amendments of 1990 designed to reduce ground-level ozone will increase the demand for reformulated motor gasoline in a number of U.S. metropolitan areas. This article discusses the effects of the new regulations on the motor gasoline market and the refining industry.

  5. Structural evolution across the insulator-metal transition in oxygen-deficient BaTiO3-δ studied using neutron total scattering and Rietveld analysis

    DOE PAGES-Beta [OSTI]

    Jeong, I.-K.; Lee, Seunghun; Jeong, Se-Young; Won, C. J.; Hur, N.; Llobet, A.

    2011-08-29

    Oxygen-deficient BaTiO3-δ exhibits an insulator-metal transition with increasing δ. We performed neutron total scattering measurements to study structural evolution across an insulator-metal transition in BaTiO3-δ. Despite its significant impact on resistivity, slight oxygen reduction (δ=0.09) caused only a small disturbance on the local doublet splitting of Ti-O bond. This finding implies that local polarization is well preserved under marginal electric conduction. In the highly oxygen-deficient metallic state (δ=0.25), however, doublet splitting of the Ti-O bond became smeared. The smearing of the local Ti-O doublet is complemented with long-range structural analysis and demonstrates that the metallic conduction in the highly oxygen-reducedmore » BaTiO3-δ is due to the appearance of nonferroelectric cubic lattice.« less

  6. East Coast (PADD 1) Total Crude Oil and Petroleum Products Net Receipts by

    U.S. Energy Information Administration (EIA) (indexed site)

    Pipeline, Tanker, Barge and Rail Product: Total Crude Oil and Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Unfinished Oils Motor Gasoline Blend. Comp. (MGBC) MGBC - Reformulated MGBC - Reformulated RBOB MGBC - RBOB for Blending w/ Alcohol* MGBC - RBOB for Blending w/ Ether* MGBC - Reformulated GTAB* MGBC - Conventional MGBC - CBOB MGBC - Conventional GTAB MGBC - Conventional Other

  7. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H.

    1986-01-01

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  8. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) (indexed site)

    3.3 3.4 7.9 3.3 W 11.3 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  9. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) (indexed site)

    92.8 92.5 84.0 72.5 W 80.7 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  10. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) (indexed site)

    92.4 92.1 83.7 74.1 W 80.9 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  11. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) (indexed site)

    3.6 3.7 7.9 3.1 W 11.0 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  12. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  13. Defining the politics changing markets of fuel reformulation: A perspective from Washington

    SciTech Connect (OSTI)

    Potter, F.L. )

    1994-01-01

    On the specific issue of RFG and US motor fuel policy, 1993 NPRA Annual meeting keynote speaker Daniel Yergin said it best, once the refining industry proved it could compete on an environmental basis with alternative fuels through the introduction of ARCO's EC-1, the challenge of economic competitiveness once again became the burden of proof for the alternative fuels industry. This economic need for turning the wheels of public policy change, along with the new tax revenue requirements to fulfill the president's campaign promises, created the policy foundation for President Clinton's original Btu tax proposal. Through the leadership of the NPRA and the chief executive officers of the major oil companies, the petroleum industry turned back the Btu tax. This was accomplished by emphasizing the importance of jobs and cost-effective public policy. The increase in the Btu tax proposal was eventually replaced by a modest increase in the gasoline excise tax. The see-saw battle of economic versus environmental-benefit claims continues in Washington today. No case study is as insightful as the battle over RFG and EPA's newly proposed renewable oxygenate standard (ROS). EPA's proposed ROS offers US petroleum refiners certain benefits not now well understood. The paper discusses the US public policy and economics of the petroleum industry; possible benefits to US refiners from EPA's ROS; public policy formation and campaign contributions; American agriculture and the politics of productivity; how US petroleum refiners can seize public policy initiative; and the choice of foreign methanol and MTBE or ROS and US hydrocarbons. Appendices contain three articles from recent journals, two related to reformulated gasoline and the third about ethanol processing and the federal budget impact.

  14. Impact of California Phase 2 reformulated gasoline on atmospheric reactivity of exhaust and evaporative emissions

    SciTech Connect (OSTI)

    Kirchstetter, T.W.; Singer, B.C.; Harley, R.A.; Kendall, G.R.; Traverse, M.

    1997-12-31

    Phase 2 of California`s reformulated gasoline (RFG) program took effect statewide in the first half of 1996. Changes to gasoline composition required by Phase 2 specifications included: lower vapor pressure; lower olefin, aromatic, benzene, and sulfur content; lower T50 and T90; and a minimum oxygen content. In this paper, impacts of Phase 2 RFG on the atmospheric reactivity of motor vehicle exhaust and evaporative emissions are described. Volatile organic compounds in motor vehicle exhaust were measured at the Caldecott tunnel in summer 1995 and 1996. Aggregate emissions of greater than 8000 vehicles were measured each day. Regular and premium grade gasoline samples were collected from service stations in Berkeley concurrently with tunnel measurements both summers. Liquid gasoline samples and their headspace vapors were analyzed to determine detailed chemical composition. Normalized reactivity was calculated for exhaust and evaporative emissions by applying maximum incremental reactivity values to the detailed speciation profiles. Results indicate that the composition of gasoline in 1996 differed markedly from that of 1995. Changes in liquid gasoline composition led to corresponding changes in the speciation of vehicle exhaust and of gasoline headspace vapors. Benzene concentration in liquid gasoline decreased from 2.0 to 0.6 wt%, which contributed to a 70 and 37% reduction in benzene weight fraction in headspace vapors and vehicle exhaust, respectively. Addition of MTBE and reduction of olefins and aromatics in gasoline led to significant reductions in the atmospheric reactivity of unburned gasoline and gasoline headspace vapors. The normalized reactivity of liquid gasoline and headspace vapors decreased by 23 and 19%, respectively, between 1995 and 1996. The normalized reactivity of non-methane organic compounds in vehicle exhaust decreased by about 8%, but the uncertainty in this change was large.

  15. A Simply Constrained Optimization Reformulation of KKT Systems Arising from Variational Inequalities

    SciTech Connect (OSTI)

    Facchinei, F. Fischer, A. Kanzow, C. Peng, J.-M.

    1999-01-15

    The Karush-Kuhn-Tucker (KKT) conditions can be regarded as optimality conditions for both variational inequalities and constrained optimization problems. In order to overcome some drawbacks of recently proposed reformulations of KKT systems, we propose casting KKT systems as a minimization problem with nonnegativity constraints on some of the variables. We prove that, under fairly mild assumptions, every stationary point of this constrained minimization problem is a solution of the KKT conditions. Based on this reformulation, a new algorithm for the solution of the KKT conditions is suggested and shown to have some strong global and local convergence properties.

  16. Fuel cycle evaluations of biomass-ethanol and reformulated gasoline. Volume 1

    SciTech Connect (OSTI)

    Tyson, K.S.

    1993-11-01

    The US Department of Energy (DOE) is using the total fuel cycle analysis (TFCA) methodology to evaluate energy choices. The National Energy Strategy (NES) identifies TFCA as a tool to describe and quantify the environmental, social, and economic costs and benefits associated with energy alternatives. A TFCA should quantify inputs and outputs, their impacts on society, and the value of those impacts that occur from each activity involved in producing and using fuels, cradle-to-grave. New fuels and energy technologies can be consistently evaluated and compared using TFCA, providing a sound basis for ranking policy options that expand the fuel choices available to consumers. This study is limited to creating an inventory of inputs and outputs for three transportation fuels: (1) reformulated gasoline (RFG) that meets the standards of the Clean Air Act Amendments of 1990 (CAAA) using methyl tertiary butyl ether (MTBE); (2) gasohol (E10), a mixture of 10% ethanol made from municipal solid waste (MSW) and 90% gasoline; and (3) E95, a mixture of 5% gasoline and 95% ethanol made from energy crops such as grasses and trees. The ethanol referred to in this study is produced from lignocellulosic material-trees, grass, and organic wastes -- called biomass. The biomass is converted to ethanol using an experimental technology described in more detail later. Corn-ethanol is not discussed in this report. This study is limited to estimating an inventory of inputs and outputs for each fuel cycle, similar to a mass balance study, for several reasons: (1) to manage the size of the project; (2) to provide the data required for others to conduct site-specific impact analysis on a case-by-case basis; (3) to reduce data requirements associated with projecting future environmental baselines and other variables that require an internally consistent scenario.

  17. U.S. Reformulated Gasoline Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) (indexed site)

    8,999.7 9,201.2 9,316.6 9,664.1 9,351.8 9,453.6 1994-2016 Through Retail Outlets 8,975.9 9,175.7 9,291.9 9,637.8 9,331.5 9,427.9 1994-2016 Sales for Resale, Total NA NA NA NA NA NA 1994-2016 DTW 18,390.2 18,584.8 18,492.9 18,354.8 18,204.6 18,684.5 1994-2016 Rack 74,336.9 76,465.1 76,955.7 79,301.3 77,485.9 78,619.2 1994-2016 Bulk 3,422.9 2,916.2 4,005.0 4,319.8 3,976.6 3,10

  18. Estimating Impacts of Diesel Fuel Reformulation with Vector-based Blending

    SciTech Connect (OSTI)

    Hadder, G.R.

    2003-01-23

    The Oak Ridge National Laboratory Refinery Yield Model has been used to study the refining cost, investment, and operating impacts of specifications for reformulated diesel fuel (RFD) produced in refineries of the U.S. Midwest in summer of year 2010. The study evaluates different diesel fuel reformulation investment pathways. The study also determines whether there are refinery economic benefits for producing an emissions reduction RFD (with flexibility for individual property values) compared to a vehicle performance RFD (with inflexible recipe values for individual properties). Results show that refining costs are lower with early notice of requirements for RFD. While advanced desulfurization technologies (with low hydrogen consumption and little effect on cetane quality and aromatics content) reduce the cost of ultra low sulfur diesel fuel, these technologies contribute to the increased costs of a delayed notice investment pathway compared to an early notice investment pathway for diesel fuel reformulation. With challenging RFD specifications, there is little refining benefit from producing emissions reduction RFD compared to vehicle performance RFD. As specifications become tighter, processing becomes more difficult, blendstock choices become more limited, and refinery benefits vanish for emissions reduction relative to vehicle performance specifications. Conversely, the emissions reduction specifications show increasing refinery benefits over vehicle performance specifications as specifications are relaxed, and alternative processing routes and blendstocks become available. In sensitivity cases, the refinery model is also used to examine the impact of RFD specifications on the economics of using Canadian synthetic crude oil. There is a sizeable increase in synthetic crude demand as ultra low sulfur diesel fuel displaces low sulfur diesel fuel, but this demand increase would be reversed by requirements for diesel fuel reformulation.

  19. U.S. Sales for Resale, Total Refiner Motor Gasoline Sales Volumes

    U.S. Energy Information Administration (EIA) (indexed site)

    NA NA NA NA NA NA 1983-2016 by Grade Regular NA NA NA NA NA NA 1983-2016 Midgrade NA NA NA NA NA NA 1988-2016 Premium NA NA NA NA NA NA 1983-2016 by Formulation Conventional NA NA NA NA NA NA 1994-2016 Oxygenated - - - - - - 1994-2016 Reformulated NA NA NA NA NA NA

  20. The Energy Information Administration`s assessment of reformulated gasoline. Volume 2

    SciTech Connect (OSTI)

    1994-09-29

    This report is divided into two volumes. This first volume contains EIA`s findings and analyses on reformulated gasoline as it affects the petroleum industry. The data contained herein should assist members of the Congress, Federal, State and local governments, analysts, researchers, the media and academia to understand the RFG program and the current status of implementation. The second volume contains 10 appendices that include letter from Congressman Dingell, survey results, survey forms, and historical summary data. A glossary and a list of acronyms and abbreviations are printed in Volumes 1 and 2.

  1. The Energy Information Administration`s assessment of reformulated gasoline. Volume 1

    SciTech Connect (OSTI)

    1994-09-28

    This report is divided into two volumes. The first volume contains EIA`s findings and analyses on reformulated gasoline as it affects the petroleum industry. The data contained herein should assist members of the Congress, Federal, State and local governments, analysts, researchers, the media and academia to understand the RFG program and the current status of implementation. This second volume contains 10 appendices that include letter from Congressman Dingell, survey results, survey forms, and historical summary data. A glossary and a list of acronyms and abbreviations are printed in Volumes 1 and 2.

  2. EPA`s proposed renewable oxygenate requirement (ROR): Pros and cons

    SciTech Connect (OSTI)

    Czeskleba, H.M.

    1995-12-31

    In December 1993, the US Environmental Protection Agency (EPA) released its final rule that sets for the details for requirements to sell reformulated gasoline (RFG) in certain ozone non-attainment areas. At the same time, EPA also issued a proposed rule to require that 30% of the oxygen required in RFG be based on a renewable oxygenate. Renewables include ethanol and its ether derivatives such as ethyl tertiary butyl ether (ETBE). The RFG rule is a final rule, while the Renewable Oxygenate Requirement (ROR) rule is a proposed rule yet to be finalized and subject to revision. Included in this paper are brief reviews of Ashland petroleum Company`s ethanol usage, oxygenated fuel and reformulated gasoline blending economics, and some comments on the EPA proposed renewable oxygenate requirement.

  3. Impact of oxygenates on petroleum refining part 2: Future outlook

    SciTech Connect (OSTI)

    Unzelman, G.H.

    1995-07-01

    With the move to a more conservative political outlook in the U.S. in 1995, some have voiced the opinion there may be resistance to the Clean Air Act and specifically to reformulated gasoline (RFG). There has been some evidence that substantiates early resistance to RFG, brought about by price hikes as high as 10 cents/gal at the pump. Pennsylvania, Maine, New York and Wisconsin have elected to {open_quotes}opt out{close_quotes} about 200,000 b/d of RFG. Certainly a move of this nature may slow the {open_quotes}opt in{close_quotes} movement in other areas of the U.S. On the other hand, the basic RFG program for nine critical areas in the U.S. will remain in place, and as air-quality limits are exceeded in other regions, they will be forced into the program. The movement toward cleaner air is worldwide, and the U.S. has been a leader in fuel reformulation for the past 25 years. While the movement may falter for various reasons, and fine tuning of regulations is inevitable, the ultimate result will be a U.S. gasoline pool that is largely reformulated - and the presence of oxygenates is fundamental to reformulation.

  4. Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)

    Reports and Publications

    1998-01-01

    The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

  5. Efficient simulation and model reformulation of two-dimensional electrochemical thermal behavior of lithium-ion batteries

    DOE PAGES-Beta [OSTI]

    Northrop, Paul W. C.; Pathak, Manan; Rife, Derek; De, Sumitava; Santhanagopalan, Shriram; Subramanian, Venkat R.

    2015-03-09

    Lithium-ion batteries are an important technology to facilitate efficient energy storage and enable a shift from petroleum based energy to more environmentally benign sources. Such systems can be utilized most efficiently if good understanding of performance can be achieved for a range of operating conditions. Mathematical models can be useful to predict battery behavior to allow for optimization of design and control. An analytical solution is ideally preferred to solve the equations of a mathematical model, as it eliminates the error that arises when using numerical techniques and is usually computationally cheap. An analytical solution provides insight into the behaviormore » of the system and also explicitly shows the effects of different parameters on the behavior. However, most engineering models, including the majority of battery models, cannot be solved analytically due to non-linearities in the equations and state dependent transport and kinetic parameters. The numerical method used to solve the system of equations describing a battery operation can have a significant impact on the computational cost of the simulation. In this paper, a model reformulation of the porous electrode pseudo three dimensional (P3D) which significantly reduces the computational cost of lithium ion battery simulation, while maintaining high accuracy, is discussed. This reformulation enables the use of the P3D model into applications that would otherwise be too computationally expensive to justify its use, such as online control, optimization, and parameter estimation. Furthermore, the P3D model has proven to be robust enough to allow for the inclusion of additional physical phenomena as understanding improves. In this study, the reformulated model is used to allow for more complicated physical phenomena to be considered for study, including thermal effects.« less

  6. Efficient simulation and model reformulation of two-dimensional electrochemical thermal behavior of lithium-ion batteries

    SciTech Connect (OSTI)

    Northrop, Paul W. C.; Pathak, Manan; Rife, Derek; De, Sumitava; Santhanagopalan, Shriram; Subramanian, Venkat R.

    2015-03-09

    Lithium-ion batteries are an important technology to facilitate efficient energy storage and enable a shift from petroleum based energy to more environmentally benign sources. Such systems can be utilized most efficiently if good understanding of performance can be achieved for a range of operating conditions. Mathematical models can be useful to predict battery behavior to allow for optimization of design and control. An analytical solution is ideally preferred to solve the equations of a mathematical model, as it eliminates the error that arises when using numerical techniques and is usually computationally cheap. An analytical solution provides insight into the behavior of the system and also explicitly shows the effects of different parameters on the behavior. However, most engineering models, including the majority of battery models, cannot be solved analytically due to non-linearities in the equations and state dependent transport and kinetic parameters. The numerical method used to solve the system of equations describing a battery operation can have a significant impact on the computational cost of the simulation. In this paper, a model reformulation of the porous electrode pseudo three dimensional (P3D) which significantly reduces the computational cost of lithium ion battery simulation, while maintaining high accuracy, is discussed. This reformulation enables the use of the P3D model into applications that would otherwise be too computationally expensive to justify its use, such as online control, optimization, and parameter estimation. Furthermore, the P3D model has proven to be robust enough to allow for the inclusion of additional physical phenomena as understanding improves. In this study, the reformulated model is used to allow for more complicated physical phenomena to be considered for study, including thermal effects.

  7. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) (indexed site)

    retail outlets, e.g., sales to agricultural customers, commercial sales, and industrial sales. Note: Totals may not equal the sum of the components due to rounding....

  8. MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)

    Reports and Publications

    1999-01-01

    The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

  9. Reformulation of Density Functional Theory for N-Representable Densities and the Resolution of the v-Representability Problem

    DOE PAGES-Beta [OSTI]

    Gonis, A.; Zhang, X. G.; Stocks, G. M.; Nicholson, D. M.

    2015-10-23

    Density functional theory for the case of general, N-representable densities is reformulated in terms of density functional derivatives of expectation values of operators evaluated with wave functions leading to a density, making no reference to the concept of potential. The developments provide a complete solution of the v-representability problem by establishing a mathematical procedure that determines whether a density is v-representable and in the case of an affirmative answer determines the potential (within an additive constant) as a derivative with respect to the density of a constrained search functional. It also establishes the existence of an energy functional of themore » density that, for v-representable densities, assumes its minimum value at the density describing the ground state of an interacting many-particle system. The theorems of Hohenberg and Kohn emerge as special cases of the formalism.« less

  10. Reformulation of Density Functional Theory for N-Representable Densities and the Resolution of the v-Representability Problem

    SciTech Connect (OSTI)

    Gonis, A.; Zhang, X. G.; Stocks, G. M.; Nicholson, D. M.

    2015-10-23

    Density functional theory for the case of general, N-representable densities is reformulated in terms of density functional derivatives of expectation values of operators evaluated with wave functions leading to a density, making no reference to the concept of potential. The developments provide a complete solution of the v-representability problem by establishing a mathematical procedure that determines whether a density is v-representable and in the case of an affirmative answer determines the potential (within an additive constant) as a derivative with respect to the density of a constrained search functional. It also establishes the existence of an energy functional of the density that, for v-representable densities, assumes its minimum value at the density describing the ground state of an interacting many-particle system. The theorems of Hohenberg and Kohn emerge as special cases of the formalism.

  11. Total Crude Oil and Petroleum Products Exports

    U.S. Energy Information Administration (EIA) (indexed site)

    Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter

  12. Stocks of Reformulated Gasoline

    Annual Energy Outlook

    40 33 35 42 37 35 1993-2015 PADD 1 25 19 19 23 23 18 1993-2015 PADD 2 0 0 0 0 0 0 1993-2015 PADD 3 0 0 0 0 0 0 1993-2015 PADD 4 0 0 0 0 0 0 1993-2015 PADD 5 15 14 16 19 14 17 1993...

  13. Impact of oxygenates on petroleum refining, review and forecast

    SciTech Connect (OSTI)

    Unzelman, G.H.

    1995-09-01

    During the coming decade, oxygenates will continue to impact light oil processing and will steadily change the composition of the US gasoline pool. There are several major driving forces that will sustain the gradual influx of oxygen to US gasoline toward the regulatory limits: (1) the positive environmental characteristics of oxygenated compounds, (2) the high-octane quality of ethers that promote elimination of less desirable hydrocarbons and (3) the competitive need for ultra-clean gasoline to compete with alternatives. From 1995 forward, conventional gasoline will gradually shift to RFG (reformulated gasoline) containing a minimum of 2 wt% oxygen and less aromatics. As a result some processing changes, already in motion in the refining industry, will continue. For example, less severe naphtha reforming and cracking innovations to yield more feed for etherification and alkylation. While alternative fuel and vehicle technology will continue to develop, oxygenates in US gasoline will contribute the major alternative dimension to transportation fuel in the foreseeable future. With RFG, internal-combustion engine emissions will be progressively less toxic and lower in photochemical reactivity. The oxygenate mix will favor methyl ethers in spite of the recent methanol price spike. Ethyl ethers will be used on a more limited basis for specific situations where lower volatility and feedstock economics are an advantage. Downstream blending of ethanol will supplement ethers blended at the refinery in situations where economics are more favorable than refinery ethers. Long-range survival of ethanol, as a direct blending agent or feedstock for refinery ethers, depends on one or more of several factors: future crude oil costs, longevity of subsidies and/or mandates, and new production technology based on cellulose yielding ethanol economically competitive with hydrocarbons.

  14. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  15. Barge Truck Total

    Annual Energy Outlook

    Barge Truck Total delivered cost per short ton Shipments with transportation rates over total shipments Total delivered cost per short ton Shipments with transportation rates over...

  16. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  17. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H.; Chung, Brandon W.; Raistrick, Ian D.; Brosha, Eric L.

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  18. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H.; Brosha, Eric L.

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  19. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report

  20. Total Crude by Pipeline

    U.S. Energy Information Administration (EIA) (indexed site)

    Product: Total Crude by All Transport Methods Domestic Crude by All Transport Methods Foreign Crude by All Transport Methods Total Crude by Pipeline Domestic Crude by Pipeline Foreign Crude by Pipeline Total Crude by Tanker Domestic Crude by Tanker Foreign Crude by Tanker Total Crude by Barge Domestic Crude by Barge Foreign Crude by Barge Total Crude by Tank Cars (Rail) Domestic Crude by Tank Cars (Rail) Foreign Crude by Tank Cars (Rail) Total Crude by Trucks Domestic Crude by Trucks Foreign

  1. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) (indexed site)

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  2. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  3. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, Dennis W.

    1994-01-01

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured.

  4. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  5. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  6. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  7. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  8. Oxygen-Enriched Combustion

    Energy.gov [DOE]

    This tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency.

  9. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  10. untitled

    U.S. Energy Information Administration (EIA) (indexed site)

    Commodity Motor Gasoline Motor Gasoline Blending Components Kerosene Reformulated Conventional Total Reformulated Conventional Total PAD District 1 ......

  11. Efficient Reformulation of Solid Phase Diffusion in Electrochemical-Mechanical Coupled Models for Lithium-Ion Batteries: Effect of Intercalation Induced Stresses

    SciTech Connect (OSTI)

    De, S; Suthar, B; Rife, D; Sikha, G; Subramanian, VR

    2013-07-23

    Lithium-ion batteries are typically modeled using porous electrode theory coupled with various transport and reaction mechanisms with an appropriate discretization or approximation for the solid phase diffusion within the electrode particle. One of the major difficulties in simulating Li-ion battery models is the need for simulating solid-phase diffusion in the second radial dimension r within the particle. It increases the complexity of the model as well as the computation time/cost to a great extent. This is Particularly true for the inclusion of pressure induced diffusion inside particles experiencing volume change. A computationally efficient representation for solid-phase diffusion is discussed in this paper. The operating condition has a significant effect on the validity, accuracy, and efficiency of various approximations for the solid-phase transport governed by pressure induced diffusion. This paper introduces efficient methods for solid phase reformulation - (1) parabolic profile approach and (2) a mixed order finite difference method for approximating/representing solid-phase concentration variations within the active materials of porous electrodes for macroscopic models for lithium-ion batteries. (C) 2013 The Electrochemical Society. All rights reserved.

  12. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) (indexed site)

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  13. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) (indexed site)

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  14. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) (indexed site)

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  15. Total Space Heat-

    Gasoline and Diesel Fuel Update

    Commercial Buildings Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration...

  16. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) (indexed site)

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  17. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) (indexed site)

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  18. Total Space Heat-

    Gasoline and Diesel Fuel Update

    Revised: December, 2008 Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other All Buildings...

  19. Total Space Heat-

    Gasoline and Diesel Fuel Update

    Released: September, 2008 Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other All Buildings*...

  20. Parallel Total Energy

    Energy Science and Technology Software Center (OSTI)

    2004-10-21

    This is a total energy electronic structure code using Local Density Approximation (LDA) of the density funtional theory. It uses the plane wave as the wave function basis set. It can sue both the norm conserving pseudopotentials and the ultra soft pseudopotentials. It can relax the atomic positions according to the total energy. It is a parallel code using MP1.

  1. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  2. Summary Max Total Units

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Summary Max Total Units *If All Splits, No Rack Units **If Only FW, AC Splits 1000 52 28 28 2000 87 59 35 3000 61 33 15 4000 61 33 15 Totals 261 153 93 ***Costs $1,957,500.00 $1,147,500.00 $697,500.00 Notes: added several refrigerants removed bins from analysis removed R-22 from list 1000lb, no Glycol, CO2 or ammonia Seawater R-404A only * includes seawater units ** no seawater units included *** Costs = (total units) X (estimate of $7500 per unit) 1000lb, air cooled split systems, fresh water

  3. Total Space Heat-

    Gasoline and Diesel Fuel Update

    Survey: Energy End-Use Consumption Tables Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other...

  4. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

    2003-11-01

    The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with

  5. ARM - Measurement - Total carbon

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    carbon ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total carbon The total concentration of carbon in all its organic and non-organic forms. Categories Atmospheric Carbon, Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  6. Total Blender Net Input of Petroleum Products

    U.S. Energy Information Administration (EIA) (indexed site)

    Normal Butane Isobutane Other Liquids OxygenatesRenewables Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol...

  7. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  8. Total DOE/NNSA

    National Nuclear Security Administration (NNSA)

    8 Actuals 2009 Actuals 2010 Actuals 2011 Actuals 2012 Actuals 2013 Actuals 2014 Actuals 2015 Actuals Total DOE/NNSA 4,385 4,151 4,240 4,862 5,154 5,476 7,170 7,593 Total non-NNSA 3,925 4,017 4,005 3,821 3,875 3,974 3,826 3765 Total Facility 8,310 8,168 8,245 8,683 9,029 9,450 10,996 11,358 non-NNSA includes DOE offices and Strategic Parternship Projects (SPP) employees NNSA M&O Employee Reporting

  9. Monolithic solid electrolyte oxygen pump

    DOE Patents [OSTI]

    Fee, Darrell C.; Poeppel, Roger B.; Easler, Timothy E.; Dees, Dennis W.

    1989-01-01

    A multi-layer oxygen pump having a one-piece, monolithic ceramic structure affords high oxygen production per unit weight and volume and is thus particularly adapted for use as a portable oxygen supply. The oxygen pump is comprised of a large number of small cells on the order of 1-2 millimeters in diameter which form the walls of the pump and which are comprised of thin, i.e., 25-50 micrometers, ceramic layers of cell components. The cell components include an air electrode, an oxygen electrode, an electrolyte and interconnection materials. The cell walls form the passages for input air and for exhausting the oxygen which is transferred from a relatively dilute gaseous mixture to a higher concentration by applying a DC voltage across the electrodes so as to ionize the oxygen at the air electrode, whereupon the ionized oxygen travels through the electrolyte and is converted to oxygen gas at the oxygen electrode.

  10. Reformulated Gasoline Foreign Refinery Rules

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1995 Introduction On August 27, 1997, the EPA promulgated revised the rules that allow ... Notice Citation (1) Date Final Rule by EPA allows foreign refiners to establish ...

  11. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul

    1997-01-01

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  12. 21 briefing pages total

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    briefing pages total p. 1 Reservist Differential Briefing U.S. Office of Personnel Management December 11, 2009 p. 2 Agenda - Introduction of Speakers - Background - References/Tools - Overview of Reservist Differential Authority - Qualifying Active Duty Service and Military Orders - Understanding Military Leave and Earnings Statements p. 3 Background 5 U.S.C. 5538 (Section 751 of the Omnibus Appropriations Act, 2009, March 11, 2009) (Public Law 111-8) Law requires OPM to consult with DOD Law

  13. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  14. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E.

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  15. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, H.R.; Bevolo, A.J.; Danielson, G.C.; Weber, M.F.

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A/sub x/WO/sub 3/ where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt/sub y/WO/sub 3/ where y is at least 0.8.

  16. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, Howard R.; Bevolo, Albert J.; Danielson, Gordon C.; Weber, Michael F.

    1980-11-04

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

  17. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  18. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  19. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update

    Refinery, Bulk Terminal, and Natural Gas Plant Stocks by State Definitions Key Terms Definition Bulk Terminal A facility used primarily for the storage and/or marketing of petroleum products which has a total bulk storage capacity of 50,000 barrels or more and/or receives petroleum products by tanker, barge, or pipeline. Conventional Gasoline Finished motor gasoline not included in the oxygenated or reformulated gasoline categories. Excludes reformulated gasoline blendstock for oxygenate

  20. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the

  1. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients

  2. U.S. Total Stocks

    U.S. Energy Information Administration (EIA) (indexed site)

    Fuel Ethanol) 731 1,085 836 695 1,070 927 2009-2015 MTBE 561 871 605 452 770 829 1993-2015 Other Oxygenates 170 214 231 243 300 98 1993-2015 Renewables (including Fuel Ethanol) ...

  3. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  4. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  5. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas Lucian A. Lucia Hasan Jameel

    2005-09-30

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in

  6. Researchers Directly Observe Oxygen Signature in the Oxygen-evolving

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Complex of Photosynthesis Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the

  7. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  8. Oxygenates from synthesis gas

    SciTech Connect (OSTI)

    Falter, W.; Keim, W.

    1994-12-31

    The direct synthesis of oxygenates starting from synthesis gas is feasible by homogeneous and heterogeneous catalysis. Homogeneous Rh and Ru based catalysts yielding methyl formate and alcohols will be presented. Interestingly, modified heterogeneous catalysts based on {open_quotes}Isobutyl Oel{close_quotes} catalysis, practized in Germany (BRD) up to 1952 and in the former DDR until recently, yield isobutanol in addition to methanol. These {open_quotes}Isobutyl Oel{close_quotes} catalysts are obtained by adding a base such as Li < Na < K < Cs to a Zn-Cr{sub 2}O{sub 3} methanol catalyst. Isobutanol is obtained in up to 15% yield. Our best catalyst a Zr-Zn-Mn-Li-Pd catalyst produced isobotanol up to 60% at a rate of 740g isobutanol per liter catalyst and hour.

  9. Total Crude Oil and Petroleum Products Imports by Area of Entry

    U.S. Energy Information Administration (EIA) (indexed site)

    by Area of Entry Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel

  10. U.S. Total Exports

    U.S. Energy Information Administration (EIA) (indexed site)

    Total To Barbados Total To Brazil Freeport, TX Sabine Pass, LA Total to Canada Eastport, ID Calais, ME Detroit, MI Marysville, MI Port Huron, MI Crosby, ND Portal, ND Sault St. Marie, MI St. Clair, MI Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Morgan, MT Sherwood, ND Pittsburg, NH Buffalo, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Sweetgrass, MT Total to Chile Sabine Pass, LA Total to China Kenai, AK Sabine Pass, LA Total to Egypt Freeport, TX Total to

  11. U.S. Total Exports

    U.S. Energy Information Administration (EIA) (indexed site)

    Sabine Pass, LA Total To Barbados Miami, FL Total To Brazil Freeport, TX Sabine Pass, LA Total to Canada Eastport, ID Calais, ME Detroit, MI Marysville, MI Port Huron, MI Portal, ND Sault St. Marie, MI St. Clair, MI Noyes, MN Babb, MT Havre, MT Port of Morgan, MT Sherwood, ND Pittsburg, NH Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Sweetgrass, MT Total to Chile Sabine Pass, LA Total to China Kenai, AK Sabine Pass, LA Total to Dominican Republic Sabine Pass, LA Total

  12. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; Yang, Ruizhi; Easton, E. Bradley; Dahn, Jeffrey R.; O'Neill, David G.

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  13. EIA-819, Monthly Oxygenate Report ...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    (EIA) Form EIA-819, "Monthly Biofuel and Oxygenate Report," is used to collect data on ethanol production capacity, as well as stocks, receipts, inputs, production, and blending of...

  14. U.S. Sales to End Users, Total Refiner Motor Gasoline Sales Volumes

    U.S. Energy Information Administration (EIA) (indexed site)

    25,220.5 25,860.0 25,967.6 26,711.1 26,333.6 26,532.9 1983-2016 by Grade Regular 20,698.8 21,263.3 21,331.0 21,940.6 21,587.4 21,748.3 1983-2016 Midgrade 1,790.7 1,828.0 1,842.8 1,898.9 1,887.9 1,899.4 1988-2016 Premium 2,731.0 2,768.7 2,793.8 2,871.6 2,858.4 2,885.3 1983-2016 by Formulation Conventional 16,220.8 16,658.8 16,651.0 17,047.0 16,981.8 17,079.3 1994-2016 Oxygenated - - - - - - 1994-2016 Reformulated 8,999.7 9,201.2 9,316.6 9,664.1 9,351.8 9,453.6

  15. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-10-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  16. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

  17. Total Eolica | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Eolica Jump to: navigation, search Name: Total Eolica Place: Spain Product: Project developer References: Total Eolica1 This article is a stub. You can help OpenEI by expanding...

  18. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang; Cao, Weenqing

    2007-08-28

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  19. Total

    U.S. Energy Information Administration (EIA) (indexed site)

    1,001 to 5,000 2,777 8,041 10,232 2.9 786 56 5,001 to 10,000 1,229 8,900 9,225 7.2 965 62 10,001 to 25,000 884 14,105 14,189 16.0 994 65 25,001 to 50,000 332 11,917 11,327 35.9 1,052 72 50,001 to 100,000 199 13,918 12,345 69.9 1,127 80 100,001 to 200,000 90 12,415 11,310 137.9 1,098 89 200,001 to 500,000 38 10,724 10,356 284.2 1,035 99 Over 500,000 8 7,074 9,196 885.0 769 117 Principal building activity Education 389 12,239 10,885 31.5 1,124 53 Food sales 177 1,252 1,172 7.1 1,067 121 Food

  20. Total

    U.S. Energy Information Administration (EIA) (indexed site)

    1,001 to 5,000 2,777 8,041 10,232 2.9 786 56 5,001 to 10,000 1,229 8,900 9,225 7.2 965 62 10,001 to 25,000 884 14,105 14,189 16.0 994 65 25,001 to 50,000 332 11,917 11,327 35.9 1,052 72 50,001 to 100,000 199 13,918 12,345 69.9 1,127 80 100,001 to 200,000 90 12,415 11,310 137.9 1,098 89 200,001 to 500,000 38 10,724 10,356 284.2 1,035 99 Over 500,000 8 7,074 9,196 885.0 769 117 Principal building activity Education 389 12,239 10,885 31.5 1,124 53 Food sales 177 1,252 1,172 7.1 1,067 121 Food

  1. Total

    U.S. Energy Information Administration (EIA) (indexed site)

    Median square feet per building (thousand) Median square feet per worker Median operating hours per week Median age of buildings (years) All buildings 5,557 87,093 88,182 5.0 1,029 50 32 Building floorspace (square feet) 1,001 to 5,000 2,777 8,041 10,232 2.8 821 49 37 5,001 to 10,000 1,229 8,900 9,225 7.0 1,167 50 31 10,001 to 25,000 884 14,105 14,189 15.0 1,444 56 32 25,001 to 50,000 332 11,917 11,327 35.0 1,461 60 29 50,001 to 100,000 199 13,918 12,345 67.0 1,442 60 26 100,001 to 200,000 90

  2. Total

    Gasoline and Diesel Fuel Update

    Fuel Oil, Greater than 500 ppm Sulfur Residual Fuel Oil Lubricants Asphalt and Road Oil Other Products Period: Annual (as of January 1) Download Series History Download ...

  3. Total

    Gasoline and Diesel Fuel Update

    of photovoltaic module shipments, 2015 (peak kilowatts) Source Disposition Source: U.S. Energy Information Administration, Form EIA-63B, 'Annual Photovoltaic CellModule ...

  4. Total..........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    ... Housing Units (millions) UrbanRural Location (as Self-Reported) Living Space ... Housing Units (millions) UrbanRural Location (as Self-Reported) Living Space ...

  5. Total..........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    ... Housing Units (millions) UrbanRural Location (as Self-Reported) City Town Suburbs Rural ... Housing Units (millions) UrbanRural Location (as Self-Reported) City Town Suburbs Rural ...

  6. Total..........................................................

    Annual Energy Outlook

    Living Space Characteristics Detached Attached Energy Information Administration 2005 Residential Energy Consumption Survey: Preliminary Housing Characteristics Tables Table HC3.2 ...

  7. Total..........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    ... 111.1 20.6 15.1 5.5 Do Not Have Cooling Equipment...... 17.8 4.0 2.4 1.7 Have Cooling Equipment...... 93.3 ...

  8. Total..........................................................

    Annual Energy Outlook

    ... Average Square Feet per Apartment in a -- Apartments (millions) Major Outside Wall Construction Siding (Aluminum, Vinyl, Steel)...... 35.3 3.5 1,286 1,090 325 852 786 461 ...

  9. Total

    Gasoline and Diesel Fuel Update

    ... District heat 48 5,964 8,230 124.9 725 87 District chilled water 54 4,608 5,742 85.4 803 ... Natural gas 12 732 1,048 61.5 699 67 District chilled water 54 4,608 5,742 85.4 803 87 ...

  10. Total..............................................

    U.S. Energy Information Administration (EIA) (indexed site)

    111.1 86.6 2,720 1,970 1,310 1,941 1,475 821 1,059 944 554 Census Region and Division Northeast.................................... 20.6 13.9 3,224 2,173 836 2,219 1,619 583 903 830 Q New England.......................... 5.5 3.6 3,365 2,154 313 2,634 1,826 Q 951 940 Q Middle Atlantic........................ 15.1 10.3 3,167 2,181 1,049 2,188 1,603 582 Q Q Q Midwest...................................... 25.6 21.0 2,823 2,239 1,624 2,356 1,669 1,336 1,081 961 778 East North

  11. Total...........................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Q Million U.S. Housing Units Renter- Occupied Housing Units (millions) Type of Renter-Occupied Housing Unit U.S. Housing Units (millions Single-Family Units Apartments in Buildings With-- Living Space Characteristics Detached Attached Table HC4.2 Living Space Characteristics by Renter-Occupied Housing Units, 2005 2 to 4 Units 5 or More Units Mobile Homes Energy Information Administration 2005 Residential Energy Consumption Survey: Preliminary Housing Characteristics Tables Million U.S. Housing

  12. Total............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

  13. Total.............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    26.7 28.8 20.6 13.1 22.0 16.6 38.6 Personal Computers Do Not Use a Personal Computer........... 35.5 17.1 10.8 4.2 1.8 1.6 10.3 20.6 Use a Personal Computer....................... 75.6 9.6 18.0 16.4 11.3 20.3 6.4 17.9 Most-Used Personal Computer Type of PC Desk-top Model.................................. 58.6 7.6 14.2 13.1 9.2 14.6 5.0 14.5 Laptop Model...................................... 16.9 2.0 3.8 3.3 2.1 5.7 1.3 3.5 Hours Turned on Per Week Less than 2 Hours..............................

  14. Total..............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    ,171 1,618 1,031 845 630 401 Census Region and Division Northeast................................................... 20.6 2,334 1,664 562 911 649 220 New England.......................................... 5.5 2,472 1,680 265 1,057 719 113 Middle Atlantic........................................ 15.1 2,284 1,658 670 864 627 254 Midwest...................................................... 25.6 2,421 1,927 1,360 981 781 551 East North Central.................................. 17.7 2,483 1,926 1,269

  15. Total..............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment................ 17.8 5.3 4.7 2.8 1.9 3.1 3.6 7.5 Have Cooling Equipment............................. 93.3 21.5 24.1 17.8 11.2 18.8 13.0 31.1 Use Cooling Equipment.............................. 91.4 21.0 23.5 17.4 11.0 18.6 12.6 30.3 Have Equipment But Do Not Use it............. 1.9 0.5 0.6 0.4 Q Q 0.5 0.8 Type of Air-Conditioning Equipment 1, 2 Central System.......................................... 65.9 11.0 16.5 13.5 8.7 16.1 6.4 17.2 Without a Heat

  16. Total...............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    20.6 25.6 40.7 24.2 Personal Computers Do Not Use a Personal Computer ........... 35.5 6.9 8.1 14.2 6.4 Use a Personal Computer......................... 75.6 13.7 17.5 26.6 17.8 Number of Desktop PCs 1.......................................................... 50.3 9.3 11.9 18.2 11.0 2.......................................................... 16.2 2.9 3.5 5.5 4.4 3 or More............................................. 9.0 1.5 2.1 2.9 2.5 Number of Laptop PCs

  17. Total...............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.7 21.7 6.9 12.1 Personal Computers Do Not Use a Personal Computer ........... 35.5 14.2 7.2 2.8 4.2 Use a Personal Computer......................... 75.6 26.6 14.5 4.1 7.9 Number of Desktop PCs 1.......................................................... 50.3 18.2 10.0 2.9 5.3 2.......................................................... 16.2 5.5 3.0 0.7 1.8 3 or More............................................. 9.0 2.9 1.5 0.5 0.8 Number of Laptop PCs

  18. Total...............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    26.7 28.8 20.6 13.1 22.0 16.6 38.6 Personal Computers Do Not Use a Personal Computer ........... 35.5 17.1 10.8 4.2 1.8 1.6 10.3 20.6 Use a Personal Computer......................... 75.6 9.6 18.0 16.4 11.3 20.3 6.4 17.9 Number of Desktop PCs 1.......................................................... 50.3 8.3 14.2 11.4 7.2 9.2 5.3 14.2 2.......................................................... 16.2 0.9 2.6 3.7 2.9 6.2 0.8 2.6 3 or More............................................. 9.0 0.4 1.2

  19. Total...............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment................. 17.8 5.3 4.7 2.8 1.9 3.1 3.6 7.5 Have Cooling Equipment.............................. 93.3 21.5 24.1 17.8 11.2 18.8 13.0 31.1 Use Cooling Equipment............................... 91.4 21.0 23.5 17.4 11.0 18.6 12.6 30.3 Have Equipment But Do Not Use it............. 1.9 0.5 0.6 0.4 Q Q 0.5 0.8 Air-Conditioning Equipment 1, 2 Central System............................................ 65.9 11.0 16.5 13.5 8.7 16.1 6.4 17.2 Without a Heat

  20. Total...............................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    47.1 19.0 22.7 22.3 Personal Computers Do Not Use a Personal Computer ........... 35.5 16.9 6.5 4.6 7.6 Use a Personal Computer......................... 75.6 30.3 12.5 18.1 14.7 Number of Desktop PCs 1.......................................................... 50.3 21.1 8.3 10.7 10.1 2.......................................................... 16.2 6.2 2.8 4.1 3.0 3 or More............................................. 9.0 2.9 1.4 3.2 1.6 Number of Laptop PCs

  1. Total................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    111.1 26.7 28.8 20.6 13.1 22.0 16.6 38.6 Do Not Have Space Heating Equipment....... 1.2 0.5 0.3 0.2 Q 0.2 0.3 0.6 Have Main Space Heating Equipment.......... 109.8 26.2 28.5 20.4 13.0 21.8 16.3 37.9 Use Main Space Heating Equipment............ 109.1 25.9 28.1 20.3 12.9 21.8 16.0 37.3 Have Equipment But Do Not Use It.............. 0.8 0.3 0.3 Q Q N 0.4 0.6 Main Heating Fuel and Equipment Natural Gas.................................................. 58.2 12.2 14.4 11.3 7.1 13.2 7.6 18.3 Central

  2. Total.................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    49.2 15.1 15.6 11.1 7.0 5.2 8.0 Have Cooling Equipment............................... 93.3 31.3 15.1 15.6 11.1 7.0 5.2 8.0 Use Cooling Equipment................................ 91.4 30.4 14.6 15.4 11.1 6.9 5.2 7.9 Have Equipment But Do Not Use it............... 1.9 1.0 0.5 Q Q Q Q Q Do Not Have Cooling Equipment................... 17.8 17.8 N N N N N N Air-Conditioning Equipment 1, 2 Central System............................................. 65.9 3.9 15.1 15.6 11.1 7.0 5.2 8.0 Without a Heat

  3. Total.................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Do Not Have Space Heating Equipment........ 1.2 N Q Q 0.2 0.4 0.2 0.2 Q Have Main Space Heating Equipment........... 109.8 14.7 7.4 12.4 12.2 18.5 18.3 17.1 9.2 Use Main Space Heating Equipment............. 109.1 14.6 7.3 12.4 12.2 18.2 18.2 17.1 9.1 Have Equipment But Do Not Use It............... 0.8 Q Q Q Q 0.3 Q N Q Main Heating Fuel and Equipment Natural Gas................................................... 58.2 9.2 4.9 7.8 7.1 8.8 8.4 7.8 4.2 Central

  4. Total.................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    26.7 28.8 20.6 13.1 22.0 16.6 38.6 Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day.............................. 8.2 2.9 2.5 1.3 0.5 1.0 2.4 4.6 2 Times A Day........................................... 24.6 6.5 7.0 4.3 3.2 3.6 4.8 10.3 Once a Day................................................ 42.3 8.8 9.8 8.7 5.1 10.0 5.0 12.9 A Few Times Each Week........................... 27.2 5.6 7.2 4.7 3.3 6.3 3.2 7.5 About Once a Week................................... 3.9 1.1 1.1

  5. Total..................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    78.1 64.1 4.2 1.8 2.3 5.7 Do Not Have Cooling Equipment..................... 17.8 11.3 9.3 0.6 Q 0.4 0.9 Have Cooling Equipment................................. 93.3 66.8 54.7 3.6 1.7 1.9 4.8 Use Cooling Equipment.................................. 91.4 65.8 54.0 3.6 1.7 1.9 4.7 Have Equipment But Do Not Use it................. 1.9 1.1 0.8 Q N Q Q Type of Air-Conditioning Equipment 1, 2 Central System.............................................. 65.9 51.7 43.9 2.5 0.7 1.6 3.1 Without a Heat

  6. Total..................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    33.0 8.0 3.4 5.9 14.4 1.2 Do Not Have Cooling Equipment..................... 17.8 6.5 1.6 0.9 1.3 2.4 0.2 Have Cooling Equipment................................. 93.3 26.5 6.5 2.5 4.6 12.0 1.0 Use Cooling Equipment.................................. 91.4 25.7 6.3 2.5 4.4 11.7 0.8 Have Equipment But Do Not Use it................. 1.9 0.8 Q Q 0.2 0.3 Q Type of Air-Conditioning Equipment 1, 2 Central System.............................................. 65.9 14.1 3.6 1.5 2.1 6.4 0.6 Without a Heat

  7. Total..................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    . 111.1 14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Do Not Have Cooling Equipment..................... 17.8 3.9 1.8 2.2 2.1 3.1 2.6 1.7 0.4 Have Cooling Equipment................................. 93.3 10.8 5.6 10.3 10.4 15.8 16.0 15.6 8.8 Use Cooling Equipment.................................. 91.4 10.6 5.5 10.3 10.3 15.3 15.7 15.3 8.6 Have Equipment But Do Not Use it................. 1.9 Q Q Q Q 0.6 0.4 0.3 Q Type of Air-Conditioning Equipment 1, 2 Central

  8. Total...................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    15.2 7.8 1.0 1.2 3.3 1.9 For Two Housing Units............................. 0.9 Q N Q 0.6 N Heat Pump.................................................. 9.2 7.4 0.3 Q 0.7 0.5 Portable Electric Heater............................... 1.6 0.8 Q Q Q 0.3 Other Equipment......................................... 1.9 0.7 Q Q 0.7 Q Fuel Oil........................................................... 7.7 5.5 0.4 0.8 0.9 0.2 Steam or Hot Water System........................ 4.7 2.9 Q 0.7 0.8 N For One Housing

  9. Total...................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Air-Conditioning Equipment 1, 2 Central System............................................... 65.9 47.5 4.0 2.8 7.9 3.7 Without a Heat Pump.................................. 53.5 37.8 3.4 2.2 7.0 3.1 With a Heat Pump....................................... 12.3 9.7 0.6 0.5 1.0 0.6 Window/Wall Units.......................................... 28.9 14.9 2.3 3.5 6.0 2.1 1 Unit........................................................... 14.5 6.6 1.0 1.6 4.2 1.2 2

  10. Total...................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Type of Air-Conditioning Equipment 1, 2 Central System.............................................. 65.9 47.5 4.0 2.8 7.9 3.7 Without a Heat Pump.................................. 53.5 37.8 3.4 2.2 7.0 3.1 With a Heat Pump....................................... 12.3 9.7 0.6 0.5 1.0 0.6 Window/Wall Units........................................ 28.9 14.9 2.3 3.5 6.0 2.1 1 Unit........................................................... 14.5 6.6 1.0 1.6 4.2 1.2 2

  11. Total....................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Household Size 1 Person.......................................................... 30.0 4.6 2.5 3.7 3.2 5.4 5.5 3.7 1.6 2 Persons......................................................... 34.8 4.3 1.9 4.4 4.1 5.9 5.3 5.5 3.4 3 Persons......................................................... 18.4 2.5 1.3 1.7 1.9 2.9 3.5 2.8 1.6 4 Persons......................................................... 15.9 1.9 0.8 1.5 1.6 3.0 2.5 3.1 1.4 5

  12. Total.......................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.6 15.1 5.5 Personal Computers Do Not Use a Personal Computer ................... 35.5 6.9 5.3 1.6 Use a Personal Computer................................ 75.6 13.7 9.8 3.9 Number of Desktop PCs 1.................................................................. 50.3 9.3 6.8 2.5 2.................................................................. 16.2 2.9 1.9 1.0 3 or More..................................................... 9.0 1.5 1.1 0.4 Number of Laptop PCs

  13. Total.......................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    5.6 17.7 7.9 Personal Computers Do Not Use a Personal Computer ................... 35.5 8.1 5.6 2.5 Use a Personal Computer................................ 75.6 17.5 12.1 5.4 Number of Desktop PCs 1.................................................................. 50.3 11.9 8.4 3.4 2.................................................................. 16.2 3.5 2.2 1.3 3 or More..................................................... 9.0 2.1 1.5 0.6 Number of Laptop PCs

  14. Total.......................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    4.2 7.6 16.6 Personal Computers Do Not Use a Personal Computer ................... 35.5 6.4 2.2 4.2 Use a Personal Computer................................ 75.6 17.8 5.3 12.5 Number of Desktop PCs 1.................................................................. 50.3 11.0 3.4 7.6 2.................................................................. 16.2 4.4 1.3 3.1 3 or More..................................................... 9.0 2.5 0.7 1.8 Number of Laptop PCs

  15. Total........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    25.6 40.7 24.2 Do Not Have Space Heating Equipment............... 1.2 Q Q Q 0.7 Have Main Space Heating Equipment.................. 109.8 20.5 25.6 40.3 23.4 Use Main Space Heating Equipment.................... 109.1 20.5 25.6 40.1 22.9 Have Equipment But Do Not Use It...................... 0.8 N N Q 0.6 Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 11.4 18.4 13.6 14.7 Central Warm-Air Furnace................................ 44.7 6.1

  16. Total........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    5.6 17.7 7.9 Do Not Have Space Heating Equipment............... 1.2 Q Q N Have Main Space Heating Equipment.................. 109.8 25.6 17.7 7.9 Use Main Space Heating Equipment.................... 109.1 25.6 17.7 7.9 Have Equipment But Do Not Use It...................... 0.8 N N N Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 18.4 13.1 5.3 Central Warm-Air Furnace................................ 44.7 16.2 11.6 4.7 For One Housing

  17. Total........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.7 21.7 6.9 12.1 Do Not Have Space Heating Equipment............... 1.2 Q Q N Q Have Main Space Heating Equipment.................. 109.8 40.3 21.4 6.9 12.0 Use Main Space Heating Equipment.................... 109.1 40.1 21.2 6.9 12.0 Have Equipment But Do Not Use It...................... 0.8 Q Q N N Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 13.6 5.6 2.3 5.7 Central Warm-Air Furnace................................ 44.7 11.0 4.4

  18. Total........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    7.1 7.0 8.0 12.1 Do Not Have Space Heating Equipment............... 1.2 Q Q Q 0.2 Have Main Space Heating Equipment.................. 109.8 7.1 6.8 7.9 11.9 Use Main Space Heating Equipment.................... 109.1 7.1 6.6 7.9 11.4 Have Equipment But Do Not Use It...................... 0.8 N Q N 0.5 Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 3.8 0.4 3.8 8.4 Central Warm-Air Furnace................................ 44.7 1.8 Q 3.1 6.0

  19. Total...........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.6 15.1 5.5 Do Not Have Cooling Equipment............................. 17.8 4.0 2.4 1.7 Have Cooling Equipment.......................................... 93.3 16.5 12.8 3.8 Use Cooling Equipment........................................... 91.4 16.3 12.6 3.7 Have Equipment But Do Not Use it.......................... 1.9 0.3 Q Q Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 6.0 5.2 0.8 Without a Heat

  20. Total...........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    5.6 17.7 7.9 Do Not Have Cooling Equipment............................. 17.8 2.1 1.8 0.3 Have Cooling Equipment.......................................... 93.3 23.5 16.0 7.5 Use Cooling Equipment........................................... 91.4 23.4 15.9 7.5 Have Equipment But Do Not Use it.......................... 1.9 Q Q Q Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 17.3 11.3 6.0 Without a Heat

  1. Total...........................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    4.2 7.6 16.6 Do Not Have Cooling Equipment............................. 17.8 10.3 3.1 7.3 Have Cooling Equipment.......................................... 93.3 13.9 4.5 9.4 Use Cooling Equipment........................................... 91.4 12.9 4.3 8.5 Have Equipment But Do Not Use it.......................... 1.9 1.0 Q 0.8 Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 10.5 3.9 6.5 Without a Heat

  2. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment............................... 17.8 4.0 2.1 1.4 10.3 Have Cooling Equipment............................................ 93.3 16.5 23.5 39.3 13.9 Use Cooling Equipment............................................. 91.4 16.3 23.4 38.9 12.9 Have Equipment But Do Not Use it............................ 1.9 0.3 Q 0.5 1.0 Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 6.0 17.3 32.1 10.5 Without a Heat

  3. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day......................................... 8.2 1.2 1.0 0.2 2 Times A Day...................................................... 24.6 4.0 2.7 1.2 Once a Day........................................................... 42.3 7.9 5.4 2.5 A Few Times Each Week...................................... 27.2 6.0 4.8 1.2 About Once a Week.............................................. 3.9 0.6 0.5 Q Less Than Once a

  4. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day......................................... 8.2 1.4 1.0 0.4 2 Times A Day...................................................... 24.6 5.8 3.5 2.3 Once a Day........................................................... 42.3 10.7 7.8 2.9 A Few Times Each Week...................................... 27.2 5.6 4.0 1.6 About Once a Week.............................................. 3.9 0.9 0.6 0.3 Less Than Once a

  5. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment............................... 17.8 2.1 1.8 0.3 Have Cooling Equipment............................................ 93.3 23.5 16.0 7.5 Use Cooling Equipment............................................. 91.4 23.4 15.9 7.5 Have Equipment But Do Not Use it............................ 1.9 Q Q Q Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 17.3 11.3 6.0 Without a Heat

  6. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment............................... 17.8 1.4 0.8 0.2 0.3 Have Cooling Equipment............................................ 93.3 39.3 20.9 6.7 11.8 Use Cooling Equipment............................................. 91.4 38.9 20.7 6.6 11.7 Have Equipment But Do Not Use it............................ 1.9 0.5 Q Q Q Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 32.1 17.6 5.2 9.3 Without a Heat

  7. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day......................................... 8.2 2.6 0.7 1.9 2 Times A Day...................................................... 24.6 6.6 2.0 4.6 Once a Day........................................................... 42.3 8.8 2.9 5.8 A Few Times Each Week...................................... 27.2 4.7 1.5 3.1 About Once a Week.............................................. 3.9 0.7 Q 0.6 Less Than Once a

  8. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment............................... 17.8 10.3 3.1 7.3 Have Cooling Equipment............................................ 93.3 13.9 4.5 9.4 Use Cooling Equipment............................................. 91.4 12.9 4.3 8.5 Have Equipment But Do Not Use it............................ 1.9 1.0 Q 0.8 Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 10.5 3.9 6.5 Without a Heat

  9. Total.............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Do Not Have Cooling Equipment............................... 17.8 8.5 2.7 2.6 4.0 Have Cooling Equipment............................................ 93.3 38.6 16.2 20.1 18.4 Use Cooling Equipment............................................. 91.4 37.8 15.9 19.8 18.0 Have Equipment But Do Not Use it............................ 1.9 0.9 0.3 0.3 0.4 Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 25.8 10.9 16.6 12.5 Without a Heat

  10. Total..............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    20.6 25.6 40.7 24.2 Do Not Have Cooling Equipment................................ 17.8 4.0 2.1 1.4 10.3 Have Cooling Equipment............................................. 93.3 16.5 23.5 39.3 13.9 Use Cooling Equipment.............................................. 91.4 16.3 23.4 38.9 12.9 Have Equipment But Do Not Use it............................. 1.9 0.3 Q 0.5 1.0 Air-Conditioning Equipment 1, 2 Central System........................................................... 65.9 6.0 17.3 32.1 10.5

  11. Total..............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    0.7 21.7 6.9 12.1 Do Not Have Cooling Equipment................................ 17.8 1.4 0.8 0.2 0.3 Have Cooling Equipment............................................. 93.3 39.3 20.9 6.7 11.8 Use Cooling Equipment.............................................. 91.4 38.9 20.7 6.6 11.7 Have Equipment But Do Not Use it............................. 1.9 0.5 Q Q Q Air-Conditioning Equipment 1, 2 Central System........................................................... 65.9 32.1 17.6 5.2 9.3 Without a

  12. Total..............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    111.1 7.1 7.0 8.0 12.1 Personal Computers Do Not Use a Personal Computer .......................... 35.5 3.0 2.0 2.7 3.1 Use a Personal Computer....................................... 75.6 4.2 5.0 5.3 9.0 Number of Desktop PCs 1......................................................................... 50.3 3.1 3.4 3.4 5.4 2......................................................................... 16.2 0.7 1.1 1.2 2.2 3 or More............................................................ 9.0 0.3

  13. Total..............................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    7.1 19.0 22.7 22.3 Do Not Have Cooling Equipment................................ 17.8 8.5 2.7 2.6 4.0 Have Cooling Equipment............................................. 93.3 38.6 16.2 20.1 18.4 Use Cooling Equipment.............................................. 91.4 37.8 15.9 19.8 18.0 Have Equipment But Do Not Use it............................. 1.9 0.9 0.3 0.3 0.4 Air-Conditioning Equipment 1, 2 Central System........................................................... 65.9 25.8 10.9 16.6 12.5

  14. Total.................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    7.1 7.0 8.0 12.1 Do Not Have Cooling Equipment................................... 17.8 1.8 Q Q 4.9 Have Cooling Equipment................................................ 93.3 5.3 7.0 7.8 7.2 Use Cooling Equipment................................................. 91.4 5.3 7.0 7.7 6.6 Have Equipment But Do Not Use it............................... 1.9 Q N Q 0.6 Air-Conditioning Equipment 1, 2 Central System.............................................................. 65.9 1.1 6.4 6.4 5.4 Without a

  15. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    25.6 40.7 24.2 Personal Computers Do Not Use a Personal Computer.................................. 35.5 6.9 8.1 14.2 6.4 Use a Personal Computer.............................................. 75.6 13.7 17.5 26.6 17.8 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 10.4 14.1 20.5 13.7 Laptop Model............................................................. 16.9 3.3 3.4 6.1 4.1 Hours Turned on Per Week Less than 2

  16. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    5.6 17.7 7.9 Personal Computers Do Not Use a Personal Computer.................................. 35.5 8.1 5.6 2.5 Use a Personal Computer.............................................. 75.6 17.5 12.1 5.4 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 14.1 10.0 4.0 Laptop Model............................................................. 16.9 3.4 2.1 1.3 Hours Turned on Per Week Less than 2

  17. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day................................................. 8.2 3.0 1.6 0.3 1.1 2 Times A Day.............................................................. 24.6 8.3 4.2 1.3 2.7 Once a Day................................................................... 42.3 15.0 8.1 2.7 4.2 A Few Times Each Week............................................. 27.2 10.9 6.0 1.8 3.1 About Once a Week..................................................... 3.9

  18. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Personal Computers Do Not Use a Personal Computer.................................. 35.5 14.2 7.2 2.8 4.2 Use a Personal Computer.............................................. 75.6 26.6 14.5 4.1 7.9 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 20.5 11.0 3.4 6.1 Laptop Model............................................................. 16.9 6.1 3.5 0.7 1.9 Hours Turned on Per Week Less than 2

  19. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    4.2 7.6 16.6 Personal Computers Do Not Use a Personal Computer.................................. 35.5 6.4 2.2 4.2 Use a Personal Computer.............................................. 75.6 17.8 5.3 12.5 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 13.7 4.2 9.5 Laptop Model............................................................. 16.9 4.1 1.1 3.0 Hours Turned on Per Week Less than 2

  20. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day................................................. 8.2 3.7 1.6 1.4 1.5 2 Times A Day.............................................................. 24.6 10.8 4.1 4.3 5.5 Once a Day................................................................... 42.3 17.0 7.2 8.7 9.3 A Few Times Each Week............................................. 27.2 11.4 4.7 6.4 4.8 About Once a Week.....................................................

  1. Total....................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    111.1 47.1 19.0 22.7 22.3 Personal Computers Do Not Use a Personal Computer.................................. 35.5 16.9 6.5 4.6 7.6 Use a Personal Computer.............................................. 75.6 30.3 12.5 18.1 14.7 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 22.9 9.8 14.1 11.9 Laptop Model............................................................. 16.9 7.4 2.7 4.0 2.9 Hours Turned on Per Week Less than 2

  2. Total.........................................................................................

    U.S. Energy Information Administration (EIA) (indexed site)

    ..... 111.1 7.1 7.0 8.0 12.1 Personal Computers Do Not Use a Personal Computer...................................... 35.5 3.0 2.0 2.7 3.1 Use a Personal Computer.................................................. 75.6 4.2 5.0 5.3 9.0 Most-Used Personal Computer Type of PC Desk-top Model............................................................. 58.6 3.2 3.9 4.0 6.7 Laptop Model................................................................. 16.9 1.0 1.1 1.3 2.4 Hours Turned on Per Week Less

  3. Mixed oxygen ion/electron-conducting ceramics for oxygen separation

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

    1995-05-01

    Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

  4. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-11-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

  5. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  6. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  7. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01

    the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  8. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19, ...

  9. Country Total Percent of U.S. Total Canada

    Annual Energy Outlook

    Taiwan 60,155 1% Vietnam 361,184 4% All others 1,861,971 19% Total 9,755,831 100% Table 7 . Photovoltaic module import shipments by country, 2015 Note: All Others includes Czech ...

  10. Determination of Total Solids in Biomass and Total Dissolved...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... The published moisture loss on drying for sodium tartrate is 15.62% (84.38% total solids). 14.6 Sample size: Determined by sample matrix. 14.7 Sample storage: Samples should be ...

  11. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-05-01

    been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  12. EVALUATING AN INNOVATIVE OXYGEN SENSOR FOR REMOTE SUBSURFACE OXYGEN MEASUREMENTS

    SciTech Connect (OSTI)

    Millings, M; Brian Riha, B; Warren Hyde, W; Karen Vangelas, K; Brian02 Looney, B

    2006-10-12

    Oxygen is a primary indicator of whether anaerobic reductive dechlorination and similar redox based processes contribute to natural attenuation remedies at chlorinated solvent contaminated sites. Thus, oxygen is a viable indicator parameter for documenting that a system is being sustained in an anaerobic condition. A team of researchers investigated the adaptation of an optical sensor that was developed for oceanographic applications. The optical sensor, because of its design and operating principle, has potential for extended deployment and sensitivity at the low oxygen levels relevant to natural attenuation. The results of the research indicate this tool will be useful for in situ long-term monitoring applications, but that the traditional characterization tools continue to be appropriate for characterization activities.

  13. TotalView Training 2015

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    TotalView Training 2015 TotalView Training 2015 NERSC will host an in-depth training course on TotalView, a graphical parallel debugger developed by Rogue Wave Software, on Thursday, March 26, 2015. This will be provided by Rogue Wave Software staff members. The training will include a lecture and demo sessions in the morning, followed by a hands-on parallel debugging session in the afternoon. Location This event will be presented online using WebEx technology and in person at NERSC Oakland

  14. Characteristics RSE Column Factor: Total

    U.S. Energy Information Administration (EIA) (indexed site)

    and 1994 Vehicle Characteristics RSE Column Factor: Total 1993 Family Income Below Poverty Line Eli- gible for Fed- eral Assist- ance 1 RSE Row Factor: Less than 5,000 5,000...

  15. ARM - Measurement - Total cloud water

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    cloud water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total cloud water The total concentration (mass/vol) of ice and liquid water particles in a cloud; this includes condensed water content (CWC). Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a

  16. Development of a Supersonic Atomic Oxygen Nozzle Beam Source for Crossed Beam Scattering Experiments

    DOE R&D Accomplishments [OSTI]

    Sibener, S. J.; Buss, R. J.; Lee, Y. T.

    1978-05-01

    A high pressure, supersonic, radio frequency discharge nozzle beam source was developed for the production of intense beams of ground state oxygen atoms. An efficient impedance matching scheme was devised for coupling the radio frequency power to the plasma as a function of both gas pressure and composition. Techniques for localizing the discharge directly behind the orifice of a water-cooled quartz nozzle were also developed. The above combine to yield an atomic oxygen beam source which produces high molecular dissociation in oxygen seeded rare gas mixtures at total pressures up to 200 torr: 80 to 90% dissociation for oxygen/argon mixtures and 60 to 70% for oxygen/helium mixtures. Atomic oxygen intensities are found to be greater than 10{sup 17} atom sr{sup -1} sec{sup -1}. A brief discussion of the reaction dynamics of 0 + IC1 ..-->.. I0 + C1 is also presented.

  17. CATEGORY Total Procurement Total Small Business Small Disadvantaged

    National Nuclear Security Administration (NNSA)

    CATEGORY Total Procurement Total Small Business Small Disadvantaged Business Woman Owned Small Business HubZone Small Business Veteran-Owned Small Business Service Disabled Veteran Owned Small Business FY 2013 Dollars Accomplished $1,049,087,940 $562,676,028 $136,485,766 $106,515,229 $12,080,258 $63,473,852 $28,080,960 FY 2013 % Accomplishment 54.40% 13.00% 10.20% 1.20% 6.60% 2.70% FY 2014 Dollars Accomplished $868,961,755 $443,711,175 $92,478,522 $88,633,031 $29,867,820 $43,719,452 $26,826,374

  18. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  19. Million Cu. Feet Percent of National Total

    Annual Energy Outlook

    Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: ...

  20. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 New Hampshire - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle ...

  1. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) (indexed site)

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  2. Catalyst containing oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  3. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C.; Besecker, Charles J.; Chen, Hancun; Robinson, Earil T.

    2007-06-12

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  4. Design Storm for Total Retention.pdf

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Title: Design Storm for "Total Retention" under Individual Permit, Poster, Individual ... International. Environmental Programs Design Storm for "Total Retention" under ...

  5. U.S. Total Imports

    U.S. Energy Information Administration (EIA) (indexed site)

    St. Clair, MI International Falls, MN Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Del Bonita, MT Port of Morgan, MT Sweetgrass, MT Whitlash, MT Portal, ND Sherwood, ND Pittsburg, NH Champlain, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Highgate Springs, VT North Troy, VT U.S. Pipeline Total from Mexico Ogilby, CA Otay Mesa, CA Alamo, TX El Paso, TX Galvan Ranch, TX Hidalgo, TX McAllen, TX Penitas, TX LNG Imports from Algeria Cove Point, MD Everett, MA Lake

  6. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect (OSTI)

    Riley, Michael F.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  7. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect (OSTI)

    Riley, M.F.; Ryan, H.M.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  8. Solar total energy project Shenandoah

    SciTech Connect (OSTI)

    1980-01-10

    This document presents the description of the final design for the Solar Total Energy System (STES) to be installed at the Shenandoah, Georgia, site for utilization by the Bleyle knitwear plant. The system is a fully cascaded total energy system design featuring high temperature paraboloidal dish solar collectors with a 235 concentration ratio, a steam Rankine cycle power conversion system capable of supplying 100 to 400 kW(e) output with an intermediate process steam take-off point, and a back pressure condenser for heating and cooling. The design also includes an integrated control system employing the supervisory control concept to allow maximum experimental flexibility. The system design criteria and requirements are presented including the performance criteria and operating requirements, environmental conditions of operation; interface requirements with the Bleyle plant and the Georgia Power Company lines; maintenance, reliability, and testing requirements; health and safety requirements; and other applicable ordinances and codes. The major subsystems of the STES are described including the Solar Collection Subysystem (SCS), the Power Conversion Subsystem (PCS), the Thermal Utilization Subsystem (TUS), the Control and Instrumentation Subsystem (CAIS), and the Electrical Subsystem (ES). Each of these sections include design criteria and operational requirements specific to the subsystem, including interface requirements with the other subsystems, maintenance and reliability requirements, and testing and acceptance criteria. (WHK)

  9. Oxygen permeation and coal-gas-assisted hydrogen production using...

    Office of Scientific and Technical Information (OSTI)

    Oxygen permeation and coal-gas-assisted hydrogen production using oxygen transport membranes Citation Details In-Document Search Title: Oxygen permeation and coal-gas-assisted ...

  10. The mechanisms of oxygen reduction and evolution reactions in...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    and evolution reactions in nonaqueous lithium-oxygen batteries A mechanistic understanding of the oxygen reductionevolution reaction in non-aqueous lithium-oxygen batteries. ...

  11. Reformulated Gasoline Sales to End Users Prices

    Gasoline and Diesel Fuel Update

    394 - - - - - 1994-2015 East Coast (PADD 1) 2.347 - - - - - 1994-2015 New England (PADD 1A) 2.374 - - - - - 1994-2015 Connecticut 2.415 - - - - - 1994-2015 Maine - - - - - - ...

  12. Retail Prices for Regular Gasoline - Reformulated Areas

    Gasoline and Diesel Fuel Update

    2.017 1.961 1994-2016 East Coast (PADD1) 1.997 1.975 1.906 1.880 1.850 1.806 1994-2016 New England (PADD 1A) 2.025 1.988 1.934 1.904 1.875 1.827 1994-2016 Central Atlantic (PADD...

  13. Reformulated Gasoline Sales to End Users Prices

    U.S. Energy Information Administration (EIA) (indexed site)

    Connecticut - - - - - - 1994-2016 Maine - - - - - - 1994-2016 Massachusetts - - - - - - 1994-2016 New Hampshire - - - - - - 1994-2016 Rhode Island - - - - - - 1994-2016 Vermont - - ...

  14. Total quality management implementation guidelines

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    These Guidelines were designed by the Energy Quality Council to help managers and supervisors in the Department of Energy Complex bring Total Quality Management to their organizations. Because the Department is composed of a rich mixture of diverse organizations, each with its own distinctive culture and quality history, these Guidelines are intended to be adapted by users to meet the particular needs of their organizations. For example, for organizations that are well along on their quality journeys and may already have achieved quality results, these Guidelines will provide a consistent methodology and terminology reference to foster their alignment with the overall Energy quality initiative. For organizations that are just beginning their quality journeys, these Guidelines will serve as a startup manual on quality principles applied in the Energy context.

  15. Total Imports of Residual Fuel

    U.S. Energy Information Administration (EIA) (indexed site)

    2010 2011 2012 2013 2014 2015 View History U.S. Total 133,646 119,888 93,672 82,173 63,294 69,914 1936-2015 PAD District 1 88,999 79,188 59,594 33,566 30,944 34,524 1981-2015 Connecticut 220 129 1995-2015 Delaware 748 1,704 510 1,604 2,479 1995-2015 Florida 15,713 11,654 10,589 8,331 5,055 7,198 1995-2015 Georgia 5,648 7,668 6,370 4,038 2,037 1,629 1995-2015 Maine 1,304 651 419 75 317 135 1995-2015 Maryland 3,638 1,779 1,238 433 938 589 1995-2015 Massachusetts 123 50 78 542 88 1995-2015 New

  16. Total Imports of Residual Fuel

    U.S. Energy Information Administration (EIA) (indexed site)

    Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 View History U.S. Total 8,596 6,340 4,707 8,092 8,512 8,017 1936-2016 PAD District 1 2,694 1,250 1,327 2,980 2,074 3,566 1981-2016 Connecticut 1995-2015 Delaware 280 231 385 1995-2016 Florida 800 200 531 499 765 1995-2016 Georgia 149 106 1995-2016 Maine 1995-2015 Maryland 84 66 1995-2016 Massachusetts 1995-2015 New Hampshire 1995-2015 New Jersey 1,073 734 355 1,984 399 1,501 1995-2016 New York 210 196 175 1,223 653 1995-2016 North Carolina 1995-2011

  17. Total quality management program planning

    SciTech Connect (OSTI)

    Thornton, P.T.; Spence, K.

    1994-05-01

    As government funding grows scarce, competition between the national laboratories is increasing dramatically. In this era of tougher competition, there is no for resistance to change. There must instead be a uniform commitment to improving the overall quality of our products (research and technology) and an increased focus on our customers` needs. There has been an ongoing effort to bring the principles of total quality management (TQM) to all Energy Systems employees to help them better prepare for future changes while responding to the pressures on federal budgets. The need exists for instituting a vigorous program of education and training to an understanding of the techniques needed to improve and initiate a change in organizational culture. The TQM facilitator is responsible for educating the work force on the benefits of self-managed work teams, designing a program of instruction for implementation, and thus getting TQM off the ground at the worker and first-line supervisory levels so that the benefits can flow back up. This program plan presents a conceptual model for TQM in the form of a hot air balloon. In this model, there are numerous factors which can individually and collectively impede the progress of TQM within the division and the Laboratory. When these factors are addressed and corrected, the benefits of TQM become more visible. As this occurs, it is hoped that workers and management alike will grasp the ``total quality`` concept as an acceptable agent for change and continual improvement. TQM can then rise to the occasion and take its rightful place as an integral and valid step in the Laboratory`s formula for survival.

  18. Total-derivative supersymmetry breaking

    SciTech Connect (OSTI)

    Haba, Naoyuki; Uekusa, Nobuhiro

    2010-05-15

    On an interval compactification in supersymmetric theory, boundary conditions for bulk fields must be treated carefully. If they are taken arbitrarily following the requirement that a theory is supersymmetric, the conditions could give redundant constraints on the theory. We construct a supersymmetric action integral on an interval by introducing brane interactions with which total-derivative terms under the supersymmetry transformation become zero due to a cancellation. The variational principle leads equations of motion and also boundary conditions for bulk fields, which determine boundary values of bulk fields. By estimating mass spectrum, spontaneous supersymmetry breaking in this simple setup can be realized in a new framework. This supersymmetry breaking does not induce a massless R axion, which is favorable for phenomenology. It is worth noting that fermions in hyper-multiplet, gauge bosons, and the fifth-dimensional component of gauge bosons can have zero-modes (while the other components are all massive as Kaluza-Klein modes), which fits the gauge-Higgs unification scenarios.

  19. The effect of plutonium dioxide water surface coverage on the generation of hydrogen and oxygen

    SciTech Connect (OSTI)

    Veirs, Douglas K.; Berg, John M.; Crowder, Mark L.

    2012-06-20

    The conditions for the production of oxygen during radiolysis of water adsorbed onto plutonium dioxide powder are discussed. Studies in the literature investigating the radiolysis of water show that both oxygen and hydrogen can be generated from water adsorbed on high-purity plutonium dioxide powder. These studies indicate that there is a threshold in the amount of water below which oxygen is not generated. The threshold is associated with the number of monolayers of adsorbed water and is shown to occur at approximately two monolayers of molecularly adsorbed water. Material in equilibrium with 50% relative humidity (RH) will be at the threshold for oxygen generation. Using two monolayers of molecularly adsorbed water as the threshold for oxygen production, the total pressure under various conditions is calculated assuming stoichiometric production of hydrogen and oxygen. The specific surface area of the oxide has a strong effect on the final partial pressure. The specific surface areas resulting in the highest pressures within a 3013 container are evaluated. The potential for oxygen generation is mitigated by reduced relative humidity, and hence moisture adsorption, at the oxide surface which occurs if the oxide is warmer than the ambient air. The potential for oxygen generation approaches zero as the temperature difference between the ambient air and the material approaches 6 C.

  20. Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion

    SciTech Connect (OSTI)

    Bhavsar, Saurabh; Veser, Goetz

    2013-11-06

    The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

  1. ,"West Virginia Natural Gas Total Consumption (MMcf)"

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","West Virginia Natural Gas Total Consumption ... AM" "Back to Contents","Data 1: West Virginia Natural Gas Total Consumption (MMcf)" ...

  2. ,"Total Crude Oil and Petroleum Products Exports"

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Total Crude Oil and Petroleum Products ... "Back to Contents","Data 1: Total Crude Oil and Petroleum Products Exports" ...

  3. Total Space Heating Water Heating Cook-

    Annual Energy Outlook

    Commercial Buildings Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing...

  4. Total Natural Gas Underground Storage Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Working Gas Capacity Total Number of Existing Fields Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources ...

  5. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 1,870 1,276...

  6. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update

    Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All...

  7. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 1,602 1,397...

  8. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings ... 2,037...

  9. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon

    1991-01-01

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  10. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  11. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D.; Sander, Robert K.

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  12. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    High-Stability-Low-Cost Supports | Department of Energy Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 adzic_bnl_kickoff.pdf (4.62 MB) More Documents & Publications Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

  13. Oxygen electrocatalysis on (001)-oriented manganese perovskite...

    Office of Scientific and Technical Information (OSTI)

    the nanoscale Citation Details In-Document Search Title: Oxygen electrocatalysis on (001)-oriented manganese perovskite films: Mn valency and charge transfer at the nanoscale ...

  14. Jupiter Oxygen Corporation | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Place: Schiller Park, Illinois Zip: 60176 Product: Illinois-based oxy-fuel combustion company involved in the capture of CO2. References: Jupiter Oxygen Corporation1...

  15. Homogeneously dispersed, multimetal oxygen-evolving catalysts...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Homogeneously dispersed, multimetal oxygen-evolving catalysts Citation ... Publication Date: 2016-03-24 OSTI Identifier: 1245398 Report ...

  16. DEVICE FOR CONTROL OF OXYGEN PARTIAL PRESSURE

    DOE Patents [OSTI]

    Bradner, H.; Gordon, H.S.

    1957-12-24

    A device is described that can sense changes in oxygen partial pressure and cause a corresponding mechanical displacement sufficient to actuate meters, valves and similar devices. A piston and cylinder arrangement contains a charge of crystalline metal chelate pellets which have the peculiar property of responding to variations in the oxygen content of the ambient atmosphere by undergoing a change in dimension. A lever system amplifies the relative displacement of the piston in the cylinder, and actuates the controlled valving device. This partial pressure oxygen sensing device is useful in controlled chemical reactions or in respiratory devices such as the oxygen demand meters for high altitude aircraft.

  17. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    More Documents & Publications Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Advanced Materials and Concepts for Portable Power Fuel Cells Catalysis Working ...

  18. Identification of an Archean marine oxygen oasis

    SciTech Connect (OSTI)

    Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

    2014-01-01

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  19. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  20. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  1. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1996-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  2. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1997-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  3. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this

  4. Total Space Heating Water Heating Cook-

    Annual Energy Outlook

    Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 634 578 46 1 Q 116.4 106.3...

  5. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Delaware - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S8. Summary statistics for natural gas - Delaware, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals

  6. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Massachusetts - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S23. Summary statistics for natural gas - Massachusetts, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross

  7. Total System Performance Assessment Peer Review Panel

    Office of Energy Efficiency and Renewable Energy (EERE)

    Total System Performance Assessment (TSPA) Peer Review Panel for predicting the performance of a repository at Yucca Mountain.

  8. Selective photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz; Blatter, Fritz; Sun, Hai

    1998-01-01

    A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

  9. Microstructure design for fast oxygen conduction

    DOE PAGES-Beta [OSTI]

    Aidhy, Dilpuneet S.; Weber, William J.

    2015-11-11

    Research from the last decade has shown that in designing fast oxygen conducting materials for electrochemical applications has largely shifted to microstructural features, in contrast to material-bulk. In particular, understanding oxygen energetics in heterointerface materials is currently at the forefront, where interfacial tensile strain is being considered as the key parameter in lowering oxygen migration barriers. Nanocrystalline materials with high densities of grain boundaries have also gathered interest that could possibly allow leverage over excess volume at grain boundaries, providing fast oxygen diffusion channels similar to those previously observed in metals. In addition, near-interface phase transformations and misfit dislocations aremore » other microstructural phenomenon/features that are being explored to provide faster diffusion. In this review, the current understanding on oxygen energetics, i.e., thermodynamics and kinetics, originating from these microstructural features is discussed. Moreover, our experimental observations, theoretical predictions and novel atomistic mechanisms relevant to oxygen transport are highlighted. In addition, the interaction of dopants with oxygen vacancies in the presence of these new microstructural features, and their future role in the design of future fast-ion conductors, is outlined.« less

  10. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Cao, Yan

    2012-11-30

    Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improves the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of oxygen

  11. Oxygen disorder, a way to accommodate large epitaxial strains in oxides

    DOE PAGES-Beta [OSTI]

    Zhang, Yu Yang; Mishra, Rohan; Pennycook, Timothy J.; Borisevich, Albina Y.; Pennycook, Stephen J.; Pantelides, Sokrates T.

    2015-09-22

    Density-functional calculations (total-energy comparisons) and checks for negative-frequency phonon modes are employed as a stability indicator to show that, in rutile- and fluorite-structure oxides, e.g., zirconia strained by a strontium titanate substrate, oxygen-sublattice disorder can be the energetically preferred way to accommodate strain.

  12. Petrochemical feedstock from basic oxygen steel furnace

    SciTech Connect (OSTI)

    Greenwood, C.W.; Hardwick, W.E.

    1983-10-01

    Iron bath gasification in which coal, lime, steam and oxygen are injected into a bath of molten iron for the production of a medium-Btu gas is described. The process has its origin in basic oxygen steelmaking. It operates at high temperatures and is thus not restrictive on the type of coal used. The ash is retained in the slag. The process is also very efficient. The authors suggest that in the present economic climate in the iron and steel industry, such a plant could be sited where existing coal-handling, oxygen and steelmaking equipment are available.

  13. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  14. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1998-01-01

    Preparation, structure, and properties of mixed metal oxide compositions and their uses are described. Mixed metal oxide compositions of the invention have stratified crystalline structure identifiable by means of powder X-ray diffraction patterns. In the form of dense ceramic membranes, the present compositions demonstrate an ability to separate oxygen selectively from a gaseous mixture containing oxygen and one or more other volatile components by means of ionic conductivities.

  15. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-01-01

    This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

  16. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

  17. Magnetism in LithiumOxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13

    Nonaqueous lithiumoxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithiumoxygen batteries. We demonstrate that the major discharge product formed in the lithiumoxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  18. Facile oxygen intercalation between full layer graphene and Ru...

    Office of Scientific and Technical Information (OSTI)

    Facile oxygen intercalation between full layer graphene and Ru(0001) under ambient ... Title: Facile oxygen intercalation between full layer graphene and Ru(0001) under ambient ...

  19. Webinar: Testing Oxygen Reduction Reaction Activity with the...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Above is the video recording for the webinar, "Testing Oxygen Reduction Reaction ...

  20. Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite...

    Office of Scientific and Technical Information (OSTI)

    Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films Citation Details In-Document Search Title: Strain Control of Oxygen Vacancies in Epitaxial Strontium ...

  1. Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency & ...

  2. Pt3Re alloy nanoparticles as electrocatalysts for the oxygen...

    Office of Scientific and Technical Information (OSTI)

    Pt3Re alloy nanoparticles as electrocatalysts for the oxygen reduction reaction Citation ... on March 24, 2018 Title: Pt3Re alloy nanoparticles as electrocatalysts for the oxygen ...

  3. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers ... technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for ...

  4. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for ...

  5. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Information (Open El) [EERE & EIA]

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  6. Artificial oxygen transport protein (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Artificial oxygen transport protein Citation Details In-Document Search Title: Artificial oxygen transport protein This invention provides heme-containing peptides capable...

  7. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-07-01

    Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance

  8. Direct Observation of the Oxygenated Species during Oxygen Reduction on a

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Platinum Fuel Cell Cathode | Stanford Synchrotron Radiation Lightsource Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell

  9. TOKIO: Total Knowledge of I/O

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    TOKIO: Total Knowledge of I/O TOKIO: Total Knowledge of I/O The Total Knowledge of I/O (TOKIO) project is developing algorithms and a software framework that collects and correlates I/O workload data from production HPC resources at multiple system levels to provide a dramatically clearer view of system behavior, and the causes of behavior, to application scientists, facility operators and computer science researchers in the field. TOKIO is a collaboration between the Lawrence Berkeley and

  10. Total Adjusted Sales of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series ...

  11. Total Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) (indexed site)

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series ...

  12. Total Natural Gas Underground Storage Capacity

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Storage Capacity Salt Caverns Storage Capacity Aquifers Storage Capacity Depleted Fields Storage Capacity Total Working Gas Capacity Working Gas Capacity of Salt Caverns Working...

  13. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Alabama - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S1. Summary statistics for natural gas - Alabama, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 346 367 402 436 414 Gas Wells R 6,243 R 6,203 R 6,174 R 6,117 6,044 Production

  14. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    2 Alaska - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S2. Summary statistics for natural gas - Alaska, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 2,040 1,981 2,006 2,042 2,096 Gas Wells R 274 R 281 R 300 R 338 329 Production

  15. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Colorado - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S6. Summary statistics for natural gas - Colorado, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 5,963 6,456 6,799 7,771 7,733 Gas Wells R 43,792 R 46,141 R 46,883 R 46,876

  16. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 District of Columbia - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S9. Summary statistics for natural gas - District of Columbia, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic

  17. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Hawaii - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S13. Summary statistics for natural gas - Hawaii, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From

  18. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 Idaho - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S14. Summary statistics for natural gas - Idaho, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From

  19. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    20 Maine - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S21. Summary statistics for natural gas - Maine, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From

  20. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Mississippi - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S26. Summary statistics for natural gas - Mississippi, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 561 618 581 540 501 Gas Wells R 1,703 R 1,666 R 1,632 R 1,594 1,560

  1. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Montana - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S28. Summary statistics for natural gas - Montana, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 1,956 2,147 2,268 2,377 2,277 Gas Wells R 6,615 R 6,366 R 5,870 R 5,682 5,655

  2. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 New Mexico - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S33. Summary statistics for natural gas - New Mexico, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 12,887 13,791 14,171 14,814 14,580 Gas Wells R 40,231 R 40,441 R 40,119 R

  3. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 New York - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S34. Summary statistics for natural gas - New York, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 988 1,170 1,589 1,731 1,697 Gas Wells R 7,372 R 7,731 R 7,553 R 7,619 7,605

  4. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 North Dakota - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S36. Summary statistics for natural gas - North Dakota, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 5,561 7,379 9,363 11,532 12,799 Gas Wells R 526 R 451 R 423 R 398 462

  5. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    2 Ohio - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S37. Summary statistics for natural gas - Ohio, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 6,775 6,745 7,038 7,257 5,941 Gas Wells R 31,966 R 31,647 R 30,804 R 31,060 26,599

  6. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Oklahoma - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S38. Summary statistics for natural gas - Oklahoma, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 6,723 7,360 8,744 7,105 8,368 Gas Wells R 51,712 R 51,472 R 50,606 R 50,044

  7. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 Oregon - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S39. Summary statistics for natural gas - Oregon, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells R 28 R 24 R 24 R 12 14 Production (million cubic feet) Gross

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    8 Pennsylvania - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S40. Summary statistics for natural gas - Pennsylvania, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 7,046 7,627 7,164 8,481 7,557 Gas Wells R 61,815 R 62,922 R 61,838 R

  9. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 Tennessee - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S44. Summary statistics for natural gas - Tennessee, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 52 75 NA NA NA Gas Wells R 1,027 R 1,027 1,089 NA NA Production (million cubic

  10. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    8 Texas - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S45. Summary statistics for natural gas - Texas, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 85,030 94,203 96,949 104,205 105,159 Gas Wells R 139,368 R 140,087 R 140,964 R 142,292

  11. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Utah - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S46. Summary statistics for natural gas - Utah, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 3,119 3,520 3,946 4,249 3,966 Gas Wells R 7,603 R 8,121 R 8,300 R 8,537 8,739 Production

  12. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Virginia - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S48. Summary statistics for natural gas - Virginia, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 2 1 1 2 2 Gas Wells R 7,781 R 7,874 7,956 R 8,061 8,111 Production (million

  13. Oxygen generator for medical applications (USIC)

    SciTech Connect (OSTI)

    Staiger, C. L.

    2012-03-01

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible

  14. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect (OSTI)

    Wolfe, R.

    1995-12-31

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  15. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-02-01

    This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

  16. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  17. Oxygen vacancy ordering within anion-deficient Ceria

    SciTech Connect (OSTI)

    Hull, S.; Norberg, S.T.; Ahmed, I.; Eriksson, S.G.; Marrocchelli, D.; Madden, P.A.

    2009-10-15

    The structural properties of anion deficient ceria, CeO{sub 2-{delta}}, have been studied as a function of oxygen partial pressure, p(O{sub 2}), over the range 0>=log{sub 10p}(O{sub 2})>=-18.9 at 1273(2) K using the neutron powder diffraction technique. Rietveld refinement of the diffraction data collected on decreasing p(O{sub 2}) showed increases in the cubic lattice parameter, a, the oxygen nonstoichiometry, delta, and the isotropic thermal vibration parameters, u{sub Ce} and u{sub O}, starting at log{sub 10p}(O{sub 2}){approx}-11. The increases are continuous, but show a distinct kink at log{sub 10p}(O{sub 2}){approx}-14.5. Analysis of the total scattering (Bragg plus diffuse components) using reverse Monte Carlo (RMC) modelling indicates that the O{sup 2-} vacancies preferentially align as pairs in the <111> cubic directions as the degree of nonstoichiometry increases. This behaviour is discussed with reference to the chemical crystallography of the CeO{sub 2}-Ce{sub 2}O{sub 3} system at ambient temperature and, in particular, to the nature of the long-range ordering of O{sup 2-} vacancies within the crystal structure of Ce{sub 7}O{sub 12}. - Graphical abstract: Partial radial distribution function for oxygen vacancies within CeO{sub 1.710} at 1273 K (solid line) showing the increased tendency for local ordering in <111> directions compared to a random distribution (dashed line).

  18. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, I.C.; Baker, R.W.

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

  19. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, Ian C. [Wilmington, DE; Baker, Richard W. [Palo Alto, CA

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

  20. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, Ian C.

    1984-01-01

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

  1. 2009 Total Energy Production by State | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Total Energy Production by State 2009 Total Energy Production by State 2009 Total Energy Production by State...

  2. TotalView Parallel Debugger at NERSC

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    The performance of the GUI can be greatly improved if used in conjunction with free NX software. The TotalView documentation web page is a good resource for learning more...

  3. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    -3,826 Total Supply 854,673 908,380 892,923 R 900,232 828,785 See footnotes at end of ... Gas Annual 165 Table S43. Summary statistics for natural gas - South Dakota, ...

  4. EQUUS Total Return Inc | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jump to: navigation, search Name: EQUUS Total Return Inc Place: Houston, Texas Product: A business development company and VC investor that trades as a closed-end fund. EQUUS is...

  5. Million Cu. Feet Percent of National Total

    Annual Energy Outlook

    as known volumes of natural gas that were the result of leaks, damage, accidents, migration, andor blow down. Notes: Totals may not add due to independent rounding. Prices are...

  6. Total Ore Processing Integration and Management

    SciTech Connect (OSTI)

    Leslie Gertsch; Richard Gertsch

    2004-06-30

    This report outlines the technical progress achieved for project DE-FC26-03NT41785 (Total Ore Processing Integration and Management) during the period 01 April through 30 June of 2004.

  7. ARM - Measurement - Net broadband total irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    govMeasurementsNet broadband total irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Net broadband total irradiance The difference between upwelling and downwelling, covering longwave and shortwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  8. ARM - Measurement - Shortwave broadband total downwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total downwelling irradiance The total diffuse and direct radiant energy that comes from some continuous range of directions, at wavelengths between 0.4 and 4 {mu}m, that is being emitted downwards. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  9. Orbital reconstruction in a self-assembled oxygen vacancy nanostructure

    DOE PAGES-Beta [OSTI]

    Jang, H.; Kerr, G.; Lim, J. S.; Yang, C. -H.; Kao, C. -C.; Lee, J. -S.

    2015-07-27

    We demonstrate the microscopic role of oxygen vacancies spatially confined within nanometer inter-spacing (about 1nm) in BiFeO₃, using resonant soft X-ray scattering techniques and soft X-ray spectroscopy measurements. Such vacancy confinements and total number of vacancy are controlled by substitution of Ca²⁺ for Bi³⁺ cation. We found that by increasing the substitution, the in-plane orbital bands of Fe³⁺ cations are reconstructed without any redox reaction. It leads to a reduction of the hopping between Fe atoms, forming a localized valence band, in particular Fe 3d-electronic structure, around the Fermi level. This band localization causes to decrease the conductivity of themore » doped BiFeO₃ system.« less

  10. Orbital reconstruction in a self-assembled oxygen vacancy nanostructure

    SciTech Connect (OSTI)

    Jang, H.; Kerr, G.; Lim, J. S.; Yang, C. -H.; Kao, C. -C.; Lee, J. -S.

    2015-07-27

    We demonstrate the microscopic role of oxygen vacancies spatially confined within nanometer inter-spacing (about 1nm) in BiFeO₃, using resonant soft X-ray scattering techniques and soft X-ray spectroscopy measurements. Such vacancy confinements and total number of vacancy are controlled by substitution of Ca²⁺ for Bi³⁺ cation. We found that by increasing the substitution, the in-plane orbital bands of Fe³⁺ cations are reconstructed without any redox reaction. It leads to a reduction of the hopping between Fe atoms, forming a localized valence band, in particular Fe 3d-electronic structure, around the Fermi level. This band localization causes to decrease the conductivity of the doped BiFeO₃ system.

  11. Novel Membranes and Processes for Oxygen Enrichment

    SciTech Connect (OSTI)

    Lin, Haiqing

    2011-11-15

    The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a

  12. Oxygen reduction reaction: A framework for success

    DOE PAGES-Beta [OSTI]

    Allendorf, Mark D.

    2016-05-06

    Oxygen reduction at the cathode of fuel cells typically requires a platinum-based material to catalyse the reaction, but lower-cost, more stable catalysts are sought. Here, an intrinsically conductive metal–organic framework based on cheaper elements is shown to be a durable, structurally well-defined catalyst for this reaction.

  13. Ammonia producing engine utilizing oxygen separation

    DOE Patents [OSTI]

    Easley, Jr., William Lanier; Coleman, Gerald Nelson; Robel, Wade James

    2008-12-16

    A power system is provided having a power source, a first power source section with a first intake passage and a first exhaust passage, a second power source section with a second intake passage and a second exhaust passage, and an oxygen separator. The second intake passage may be fluidly isolated from the first intake passage.

  14. AISI/DOE Technology Roadmap Program Hot Oxygen Injection Into The Blast Furnace

    SciTech Connect (OSTI)

    Michael F. Riley

    2002-10-21

    Increased levels of blast furnace coal injection are needed to further lower coke requirements and provide more flexibility in furnace productivity. The direct injection of high temperature oxygen with coal in the blast furnace blowpipe and tuyere offers better coal dispersion at high local oxygen concentrations, optimizing the use of oxygen in the blast furnace. Based on pilot scale tests, coal injection can be increased by 75 pounds per ton of hot metal (lb/thm), yielding net savings of $0.84/tm. Potential productivity increases of 15 percent would yield another $1.95/thm. In this project, commercial-scale hot oxygen injection from a ''thermal nozzle'' system, patented by Praxair, Inc., has been developed, integrated into, and demonstrated on two tuyeres of the U.S. Steel Gary Works no. 6 blast furnace. The goals were to evaluate heat load on furnace components from hot oxygen injection, demonstrate a safe and reliable lance and flow control design, and qualitatively observe hot oxygen-coal interaction. All three goals have been successfully met. Heat load on the blowpipe is essentially unchanged with hot oxygen. Total heat load on the tuyere increases about 10% and heat load on the tuyere tip increases about 50%. Bosh temperatures remained within the usual operating range. Performance in all these areas is acceptable. Lance performance was improved during testing by changes to lance materials and operating practices. The lance fuel tip was changed from copper to a nickel alloy to eliminate oxidation problems that severely limited tip life. Ignition flow rates and oxygen-fuel ratios were changed to counter the effects of blowpipe pressure fluctuations caused by natural resonance and by coal/coke combustion in the tuyere and raceway. Lances can now be reliably ignited using the hot blast as the ignition source. Blowpipe pressures were analyzed to evaluate ht oxygen-coal interactions. The data suggest that hot oxygen increases coal combustion in the blow pipe and

  15. Oxygen-exchange Pathways in Aluminum Polyoxocations

    SciTech Connect (OSTI)

    Rustad, James R.; Loring, J. S.; Casey, William H.

    2004-07-15

    Using molecular dynamics simulations and electronic structure methods, we postulate a mechanism to explain the complicated reactivity trends that are observed for oxygen isotope exchange reactions between sites in aluminum polyoxocations of the E-Keggin type and bulk solution. Experimentally, the molecules have four nonequivalent oxygens that differ considerably in reactivity both within a molecule, and between molecules in the series: Al13, GaAl12, and GeAl12 [MO4Al12(OH)24(H2O)12 n*(aq); with M=Al(III) for Al13, n=7; M=Ga(III) for GaAl12, n=7; M=Ge(IV) for GeAl12, n=8]. We find that a partly dissociated, metastable intermediate molecule of expanded volume is necessary for exchange of both sets of u2-OH and that the steady-state concentration of this intermediate reflects the bond strengths between the central metal and the u4-O. Thus the central metal exerts extraordinary control over reactions at hydroxyl bridges, although these are three bonds away. This mechanism not only explains the reactivity trends for oxygen isotope exchange in u2-OH and u-OH2 sites in the E-Keggin aluminum molecules, but also explains the observation that the reactivities of minerals tend to reflect the presence of highly coordinated oxygens, such as the u4-O in boehmite, a-, and y-Al2O3 and their Fe(III) analogs. The partial dissociation of these highly coordinated oxygens, coupled with simultaneous activation and displacement of neighboring metal centers, may be a fundamental process by which metals atoms undergo ligand exchanges at mineral surfaces.

  16. ARM - Measurement - Shortwave spectral total downwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    total downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral total downwelling irradiance The rate at which radiant energy, at specrally-resolved wavelengths between 0.4 and 4 {mu}m, is being emitted upwards and downwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments

  17. Oxygen-producing inert anodes for SOM process

    SciTech Connect (OSTI)

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  18. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    From Gas Wells 0 0 0 0 0 From Oil Wells 0 0 0 0 0 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 0 0 0 0 0 Repressuring 0 0 0 0 0 Vented and Flared 0 0 0 0 0 ...

  19. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Oil Wells 120,880 67,065 69,839 R 70,475 66,065 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 94,349 87,854 94,268 R 107,577 107,964 Total 279,130 246,822 252,310 R 238,988 ...

  20. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    8,814 7,938 6,616 7,250 From Oil Wells 0 0 0 0 0 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 9,075 8,814 7,938 6,616 7,250 Repressuring NA NA NA NA NA Vented ...

  1. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Gas Wells 34 44 32 20 27 From Oil Wells 0 0 0 0 0 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 34 44 32 20 27 Repressuring 0 0 0 0 0 Vented and Flared 0 0 0 0 ...

  2. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    2,887 R 1,929 2,080 From Oil Wells 7 0 0 0 0 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 2,121 2,125 2,887 R 1,929 2,080 Repressuring 0 0 0 NA NA Vented ...

  3. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Oil Wells 68,505 49,380 51,948 R 50,722 44,748 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 2,088,306 2,130,551 1,534,372 R 1,197,480 1,120,806 Total 3,040,523 2,955,437 ...

  4. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    R 93,091 85,775 From Oil Wells 1,665 0 0 0 0 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 124,243 106,122 94,665 R 93,091 85,775 Repressuring 0 0 0 NA NA ...

  5. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Wells 37,194 0 0 0 0 From Coalbed Wells 35,924 31,689 28,244 R 25,387 23,359 From Shale Gas Wells 0 0 0 0 0 Total 309,952 296,299 292,467 R 286,480 285,236 Repressuring 521 NA NA ...

  6. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Gas Wells 0 0 8 R 3 1 From Oil Wells 0 0 1 * 0 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 0 0 9 R 3 1 Repressuring 0 0 0 0 0 Vented and Flared 0 0 0 0 0 ...

  7. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1,027 R 353 399 From Oil Wells 126 11 5 R 63 78 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 1,980 1,328 1,032 R 417 477 Repressuring 0 0 0 0 0 Vented and ...

  8. Million Cu. Feet Percent of National Total

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    From Gas Wells 0 0 0 * 1 From Oil Wells 3 4 3 3 3 From Coalbed Wells 0 0 0 0 0 From Shale Gas Wells 0 0 0 0 0 Total 3 4 3 3 3 Repressuring 0 0 0 0 0 Vented and Flared 0 0 0 0 0 ...

  9. Total pressing Indonesian gas development, exports

    SciTech Connect (OSTI)

    Not Available

    1994-01-24

    Total is on track to become Indonesia's leading gas exporter by the turn of the century. Total's aggressive development of its Mahakam Delta acreage in East Kalimantan is intended to keep pace with growing liquefied natural gas demand, mainly from Japan but also increasingly from South Korea and Taiwan. A frantic scramble is under way among natural gas suppliers in the Pacific Rim region, particularly those with current LNG export facilities, to accommodate projections of soaring natural gas demand in the region. Accordingly, Total's Indonesian gas production goal is the centerpiece of a larger strategy to become a major player in the Far East Asia gas scene. Its goals also fall in line with Indonesia's. Facing flat or declining oil production while domestic oil demand continues to soar along with a rapidly growing economy, Indonesia is heeding some studies that project the country could become a net oil importer by the turn of the century. The paper describes Total's Far East strategy, the Mahakam acreage which it operates, the shift to gas development, added discoveries, future development, project spending levels, and LNG export capacity.

  10. Total internal reflection laser tools and methods

    DOE Patents [OSTI]

    Zediker, Mark S.; Faircloth, Brian O.; Kolachalam, Sharath K.; Grubb, Daryl L.

    2016-02-02

    There is provided high power laser tools and laser heads that utilize total internal reflection ("TIR") structures to direct the laser beam along a laser beam path within the TIR structure. The TIR structures may be a TIR prism having its hypotenuse as a TIR surface.

  11. The Leica TCRA1105 Reflectorless Total Station

    SciTech Connect (OSTI)

    Gaudreault, F.

    2005-09-06

    This poster provides an overview of SLAC's TCRA1105 reflectorless total station for the Alignment Engineering Group. This instrument has shown itself to be very useful for planning new construction and providing quick measurements to difficult to reach or inaccessible surfaces.

  12. Product Supplied for Total Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update

    EthaneEthylene PropanePropylene Normal ButaneButylene IsobutaneIsobutylene Other Liquids HydrogenOxygenatesRenewablesOther Hydrocarbons Unfinished Oils Motor Gasoline Blend. ...

  13. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-10-01

    This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

  14. Excess Oxygen Defects in Layered Cuprates

    DOE R&D Accomplishments [OSTI]

    Lightfoot, P.; Pei, S. Y.; Jorgensen, J. D.; Manthiram, A.; Tang, X. X.; Goodenough, J. B.

    1990-09-01

    Neutron powder diffraction has been used to study the oxygen defect chemistry of two non-superconducting layered cuprates, La{sub 1. 25}Dy{sub 0.75}Cu{sub 3.75}F{sub 0.5}, having a T{sup {asterisk}}- related structure, and La{sub 1.85}Sr{sub 1.15}Cu{sub 2}O{sub 6.25}, having a structure related to that of the newly discovered double-layer superconductor La{sub 2-x}Sr{sub x}CaCu{sub 2}O{sub 6}. The role played by oxygen defects in determining the superconducting properties of layered cuprates is discussed.

  15. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R.; Bond, James A.

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  16. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  17. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Radoslav Adzic Co-workers: Jia Wang, Miomir Vukmirovic, Kotaro Sasaki, Stoyan Bliznakov, Yun Cai, Yu Zhang, Kurian Kuttiyiel, Kuanping Gong, YongMan Choi, Ping Liu, Hideo Naohara 1 Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973 1 Toyota Motor Corporation, Susono, Japan Webinar June 19, 2012 Outline - Introduction on fuel cells, electrocatalysis, existing developments and remaining obstacles to

  18. A miniature inexpensive, oxygen sensing element

    SciTech Connect (OSTI)

    Arenz, R.W.

    1991-10-07

    An exhaustive study was conducted to determine the feasibility of Nernst-type oxygen sensors based on ceramics containing Bi{sub 2}O{sub 3}. The basic sensor design consisted of a ceramic sensing module sealed into a metal tube. The module accommodated an internal heater and thermocouple. Thermal-expansion-matched metals, adhesives, and seals were researched and developed, consistent with sequential firings during sensor assembly. Significant effort was devoted to heater design/testing and to materials' compatibility with Pt electrodes. A systematic approach was taken to develop all sensor components which led to several design modifications. Prototype sensors were constructed and exhaustively tested. It is concluded that development of Nerst-type oxygen sensors based on Bi{sub 2}O{sub 3} will require much further effort and application of specialized technologies. However, during the course of this 3-year program much progress was reported in the literature on amperometric-type oxygen sensors, and a minor effort was devoted here to this type of sensor based on Bi{sub 2}O{sub 3}. These studies were made on Bi{sub 2}O{sub 3}-based ceramic samples in a multilayer-capacitor-type geometry and amperometric-type oxygen sensing was demonstrated at very low temperatures ({approximately} 160{degree}C). A central advantage here is that these types of sensors can be mass-produced very inexpensively ({approximately} 20--50 cents per unit). Research is needed, however, to develop an optimum diffusion-limiting barrier coating. In summary, the original goals of this program were not achieved due to unforeseen problems with Bi{sub 2}O{sub 3}-based Nernst sensors. However, a miniature amperometric sensor base on Bi{sub 2}O{sub 3} was demonstrated in this program, and it is now seen that this latter sensor is far superior to the originally proposed Nernst sensor. 6 refs., 24 figs.

  19. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H.; Gruen, Dieter M.

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  20. Hydrogen (H2) Production by Oxygenic Phototrophs

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical

  1. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

  2. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S.; Kulik, C.J.

    1994-12-31

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  3. Oxygen Catalysis: The Other Half of the Equation

    SciTech Connect (OSTI)

    Turner, J.

    2008-10-01

    Artificial photosynthesis--splitting water with light--is an attractive way to make hydrogen, but what happens to the oxygen? A catalyst that aids in the efficient production of gaseous oxygen improves the viability of this approach.

  4. Impact of interstitial oxygen on the electronic and magnetic...

    Office of Scientific and Technical Information (OSTI)

    interstitial oxygen on the electronic and magnetic structure in superconducting Fe 1 + y Te O x thin films Citation Details In-Document Search Title: Impact of interstitial oxygen...

  5. Frustrated total internal reflection acoustic field sensor

    DOE Patents [OSTI]

    Kallman, Jeffrey S.

    2000-01-01

    A frustrated total internal reflection acoustic field sensor which allows the acquisition of the acoustic field over an entire plane, all at once. The sensor finds use in acoustic holography and acoustic diffraction tomography. For example, the sensor may be produced by a transparent plate with transparent support members tall enough to support one or more flexible membranes at an appropriate height for frustrated total internal reflection to occur. An acoustic wave causes the membrane to deflect away from its quiescent position and thus changes the amount of light that tunnels through the gap formed by the support members and into the membrane, and so changes the amount of light reflected by the membrane. The sensor(s) is illuminated by a uniform tight field, and the reflection from the sensor yields acoustic wave amplitude and phase information which can be picked up electronically or otherwise.

  6. Fractionated total body irradiation for metastatic neuroblastoma

    SciTech Connect (OSTI)

    Kun, L.E.; Casper, J.T.; Kline, R.W.; Piaskowski, V.D.

    1981-11-01

    Twelve patients over one year old with neuroblastoma (NBL) metastatic to bone and bone marrow entered a study of adjuvant low-dose, fractionated total body irradiation (TBI). Six children who achieved a ''complete clinical response'' following chemotherapy (cyclophosphamide and adriamycin) and surgical resection of the abdominal primary received TBI (10 rad/fraction to totals of 100-120 rad/10-12 fx/12-25 days). Two children received concurrent local irradiation for residual abdominal tumor. The intervals from cessation of chemotherapy to documented progression ranged from 2-16 months, not substatially different from patients receiving similar chemotherapy and surgery without TBI. Three additional children with progressive NBL received similar TBI (80-120 rad/8-12 fx) without objective response.

  7. Florida Natural Gas Total Consumption (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Consumption (Million Cubic Feet) Florida Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption Florida Natural Gas Consumption by End Use Total ...

  8. Million Cu. Feet Percent of National Total Million Cu. Feet...

    Annual Energy Outlook

    Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: ...

  9. Million Cu. Feet Percent of National Total Million Cu. Feet...

    Annual Energy Outlook

    Feet Percent of National Total Total Net Movements: -1,159,080 - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total ...

  10. Million Cu. Feet Percent of National Total Million Cu. Feet...

    Gasoline and Diesel Fuel Update

    Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: 0 Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: ...

  11. Oxygen-Enriched Combustion for Military Diesel Engine Generators

    Energy.gov [DOE]

    Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion

  12. Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films Citation Details In-Document Search Title: Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films The ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the

  13. ARM - Measurement - Shortwave broadband total net irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    net irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total net irradiance The difference between upwelling and downwelling broadband shortwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  14. ARM - Measurement - Shortwave narrowband total downwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband total downwelling irradiance The rate at which radiant energy, in narrow bands of wavelengths shorter than approximately 4 {mu}m, passes through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  15. ARM - Measurement - Shortwave narrowband total upwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband total upwelling irradiance The rate at which radiant energy, in narrow bands of wavelengths shorter than approximately 4 {mu}m, passes through a horizontal unit area in an upward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments.

  16. Notices Total Estimated Number of Annual

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    372 Federal Register / Vol. 78, No. 181 / Wednesday, September 18, 2013 / Notices Total Estimated Number of Annual Burden Hours: 10,128. Abstract: Enrollment in the Federal Student Aid (FSA) Student Aid Internet Gateway (SAIG) allows eligible entities to securely exchange Title IV, Higher Education Act (HEA) assistance programs data electronically with the Department of Education processors. Organizations establish Destination Point Administrators (DPAs) to transmit, receive, view and update

  17. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect (OSTI)

    Riley, M.F.

    2003-04-30

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations

  18. Chemical diffusion of oxygen in tin dioxide: Effects of dopants and oxygen partial pressure

    SciTech Connect (OSTI)

    Kamp, B.; Merkle, R. . E-mail: s.weiglein@fkf.mpg.de; Lauck, R.; Maier, J.

    2005-10-15

    Tin dioxide SnO{sub 2-{delta}} is a pronounced n-type electron conductor due to its oxygen deficiency. This study investigates the rate of chemical diffusion of oxygen in SnO{sub 2-{delta}} single crystals, which is a crucial step in the overall stoichiometry change of the material. The chemical diffusion coefficient D{sup {delta}} was determined from conductivity- and EPR-relaxation methods. The temperature dependence was found to be D{sup {delta}}=exp(-4+/-2)cm{sup 2}s{sup -1}exp(-(1.1+/-0.3)eV/kT). The dependence on crystal orientation, dopant content and oxygen partial pressure was below experimental error. The latter observation leads to the conclusion that the chemical diffusion coefficient is close to the diffusion coefficient of oxygen vacancies. Along with the relaxation process resulting from the chemical diffusion of oxygen, additional processes were observed. One of these was attributed to complications in the defect chemistry of the material. The relevance of the results for the kinetics of drift processes of Taguchi sensors is discussed.

  19. Table 6a. Total Electricity Consumption per Effective Occupied...

    U.S. Energy Information Administration (EIA) (indexed site)

    a. Total Electricity Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using Electricity (thousand) Total Electricity Consumption...

  20. ARM - Measurement - Shortwave broadband total upwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total upwelling irradiance The rate at which radiant energy, at a wavelength between 0.4 and 4 {mu}m, is being emitted upwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments The above measurement is considered

  1. Total-variation regularization with bound constraints

    SciTech Connect (OSTI)

    Chartrand, Rick; Wohlberg, Brendt

    2009-01-01

    We present a new algorithm for bound-constrained total-variation (TV) regularization that in comparison with its predecessors is simple, fast, and flexible. We use a splitting approach to decouple TV minimization from enforcing the constraints. Consequently, existing TV solvers can be employed with minimal alteration. This also makes the approach straightforward to generalize to any situation where TV can be applied. We consider deblurring of images with Gaussian or salt-and-pepper noise, as well as Abel inversion of radiographs with Poisson noise. We incorporate previous iterative reweighting algorithms to solve the TV portion.

  2. Mechanism of singlet oxygen deactivation in an electric discharge oxygen – iodine laser

    SciTech Connect (OSTI)

    Azyazov, V N; Mikheyev, P A; Torbin, A P; Pershin, A A; Heaven, M C

    2014-12-31

    We have determined the influence of the reaction of molecular singlet oxygen with a vibrationally excited ozone molecule O{sub 2}(a {sup 1}Δ) + O{sub 3}(ν) → 2O{sub 2} + O on the removal rate of O{sub 2}(a {sup 1}Δ) in an electric-discharge-driven oxygen – iodine laser. This reaction has been shown to be a major channel of O{sub 2}(a {sup 1}Δ) loss at the output of an electric-discharge singlet oxygen generator. In addition, it can also contribute significantly to the loss of O{sub 2}(a {sup 1}Δ) in the discharge region of the generator. (lasers)

  3. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE PAGES-Beta [OSTI]

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore » a new strategy of developing the catalyst for oxygen evolution reaction.« less

  4. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithiumoxygen batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  5. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  6. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltn; Horvth, Attila [Institute of Chemistry, Etvs Lornd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsr, Zoltn [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mssbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mssbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mssbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  7. Cathode architectures for alkali metal / oxygen batteries

    SciTech Connect (OSTI)

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  8. Oxygen stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, Marshall H.; Gruen, Dieter M.

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  9. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-01

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  10. Total Ore Processing Integration and Management

    SciTech Connect (OSTI)

    Leslie Gertsch

    2006-01-30

    This report outlines the technical progress achieved for project DE-FC26-03NT41785 (Total Ore Processing Integration and Management) during the period 01 October through 31 December of 2005. Graphical analysis of blast patterns according to drill monitor data is continuing. Multiple linear regression analysis of 16 mine and mill variables (powder factor, two modeled size fractions, liberation index, predicted grind, total crude Fe, Satmagan Fe, sat ratio, DSC, geologic blend, ambient temperature, cobbing hours, feeder plugs, and percent feeder run time-of-mill time) indicates that December variations in plant performance are generally predictable (Figure 1). The outlier on December 28th coincides with low cobbing availability and equipment downtime. Mill productivity appeared to be most influenced, as usual, by ore quality as indicated by the liberation index--the higher the liberation index, the lower the throughput. The upcoming quarter will be concerned with wrapping up the work in progress, such as the detailed statistical analyses, and writing a final report. Hibtac Mine engineers are evaluating neural network software to determine its utility for modeling, and eventually predicting, mill throughput.

  11. Atomic oxygen interaction with nickel multilayer and antimony oxide doped MoS{sub 2} films

    SciTech Connect (OSTI)

    Dugger, M.T.

    1994-12-31

    Sputtered MoS{sub 2} is a solid lubricant capable of ultralow friction coefficients (below 0.05) load-bearing capacity. Since it exhibits low friction in vacuum, low outgassing rate, is non-migrating and lacks organic binders, this material is an attractive lubricant for space mechanisms. To exploit these new materials to their fullest potential, designers of space-based motion systems require data on the effects of atomic oxygen exposure on dense, sputtered MoS{sub 2}. This paper describes the effects of atomic oxygen in low earth orbit on the friction and surface composition of sputtered MoS{sub 2} films. Sputtered multilayer films of MoS{sub 2} with nickel (0.7 nm Ni per 10 nm MoS{sub 2}, for 1 {mu}m total film thickness), and MoS{sub 2} cosputtered with antimony oxide (nominally 2 {mu}m thick) were exposed to 2.2 to 2.5 x 10{sup 20} oxygen/cm{sup 2} over a period of 42.25 hours in earth orbit on the United States space shuttle. Identical specimens were kept as controls in desiccated storage for the duration of the mission, and another set was exposed to an equivalent fluence of atomic oxygen in the laboratory. The friction coefficient in air and vacuum, and the composition of worn surfaces, were determined prior to the shuttle flight and again after the shuttle flight. Results are described.

  12. Country/Continent Total Percent of U.S. Total Canada

    Annual Energy Outlook

    SouthCentral America 17,753 9% Europe 31,843 17% Africa 3,034 2% Asia 124,282 66% Australia and Oceania 609 0% Total 188,003 100% Table 8. Destination of photovoltaic module ...

  13. Instabilities in a capacitively coupled oxygen plasma

    SciTech Connect (OSTI)

    Küllig, C. Wegner, Th. Meichsner, J.

    2015-04-15

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species (O{sub 2}{sup +}, e, O{sup −}, O{sub 2}{sup −}) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  14. Total Ore Processing Integration and Management

    SciTech Connect (OSTI)

    Leslie Gertsch; Richard Gertsch

    2006-01-30

    This report outlines the technical progress achieved for project DE-FC26-03NT41785 (Total Ore Processing Integration and Management) during the period 01 July through 30 September of 2005. This ninth quarterly report discusses the activities of the project team during the period 1 July through 30 September 2005. Richard Gertsch's unexpected death due to natural causes while in Minnesota to work on this project has temporarily slowed progress. Statistical analysis of the Minntac Mine data set for late 2004 is continuing. Preliminary results raised several questions that could be amenable to further study. Detailed geotechnical characterization is being applied to improve the predictability of mill and agglomerator performance at Hibtac Mine.

  15. 2015 Retail Power Marketers Sales- Total

    U.S. Energy Information Administration (EIA) (indexed site)

    Total (Data from form EIA-861 schedule 4B) Entity State Ownership Customers (Count) Sales (Megawatthours) Revenues (Thousands Dollars) Average Price (cents/kWh) 3 Phases Renewables CA Power Marketer 447 410,148 24,961.2 6.09 Calpine Power America LLC CA Power Marketer 1 1,069,832 57,737.7 5.40 City of Cerritos - (CA) CA Municipal 303 80,466 5,882.9 7.31 City of Corona - (CA) CA Municipal 975 68,598 5,759.7 8.40 Commerce Energy, Inc. CA Power Marketer 10,977 337,263 23,998.8 7.12 Constellation

  16. Total Supplemental Supply of Natural Gas

    U.S. Energy Information Administration (EIA) (indexed site)

    Product: Total Supplemental Supply Synthetic Propane-Air Refinery Gas Biomass Other Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History U.S. 64,575 60,088 61,366 54,650 59,642 58,625 1980-2015 Alabama 0 0 0 0 0 0 1967-2015 Alaska 0 0 0 0 0 0 2004-2015 Arizona 0 0 0 0 0 0 1967-2015 Arkansas 0 0 0 0 0 0 1967-2015 Colorado 5,148 4,268 4,412 4,077

  17. Total energy study of the microscopic structure and electronic properties of tetragonal perovskite SrTiO{sub 3}

    SciTech Connect (OSTI)

    Rubio-Ponce, A.; Olgun, D.

    2014-05-15

    To study the structural and electronic properties of cubic perovskite SrTiO{sub 3} and its stress-induced tetragonal phase, we have performed total energy calculations and studied the effect of oxygen vacancies on the electronic properties of tetragonal perovskite SrTiO{sub 3}. The method used was the relativistic full-potential linearized augmented plane wave (FLAPW) method. To obtain the geometry that minimizes the total energy, we relaxed the internal atomic sites of the tetragonal cell. As a result of this procedure, we have found that the titanium atoms move toward the plane of the vacancy by 0.03 , and the apical oxygen atoms move to the same plane by approximately 0.14 . These results are discussed in comparison with experimental data.

  18. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D. Noble, J.

    2009-10-01

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily

  19. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

  20. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

  1. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable

  2. Efficiency evaluation of oxygen enrichment in energy conversion processes

    SciTech Connect (OSTI)

    Bomelburg, H.J.

    1983-12-01

    The extent to which energy conversion efficiencies can be increased by using oxygen or oxygen-enriched air for combustion was studied. Combustion of most fuels with oxygen instead of air was found to have five advantages: increases combustion temperature and efficiency, improves heat transfer at high temperatures, reduces nitrous oxide emissions, permits a high ration of exhaust gas recirculation and allows combustion of certain materials not combustible in air. The same advantages, although to a lesser degree, are apparent with oxygen-enriched air. The cost-effectiveness of the process must necessarily be improved by about 10% when using oxygen instead of air before such use could become justifiable on purely economic terms. Although such a modest increase appears to be attainable in real situations, this study ascertained that it is not possible to generally assess the economic gains. Rather, each case requires its own evaluation. For certain processes industry has already proven that the use of oxygen leads to more efficient plant operation. Several ideas for essentially new applications are described. Specifically, when oxygen is used with exhaust gas recirculation in external or internal combustion engines. It appears also that the advantages of pulse combustion can be amplified further if oxygen is used. When burning wet fuels with oxygen, direct steam generation becomes possible. Oxygen combustion could also improve processes for in situ gasification of coals, oil shales, peats, and other wet fuels. Enhanced oil recovery by fire flooding methods might also become more effective if oxygen is used. The cold energy contained in liquid oxygen can be substantially recovered in the low end of certain thermodynamic cycles. Further efforts to develop certain schemes for using oxygen for combustion appear to be justified from both the technical and economic viewpoints.

  3. Total least squares for anomalous change detection

    SciTech Connect (OSTI)

    Theiler, James P; Matsekh, Anna M

    2010-01-01

    A family of difference-based anomalous change detection algorithms is derived from a total least squares (TLSQ) framework. This provides an alternative to the well-known chronochrome algorithm, which is derived from ordinary least squares. In both cases, the most anomalous changes are identified with the pixels that exhibit the largest residuals with respect to the regression of the two images against each other. The family of TLSQ-based anomalous change detectors is shown to be equivalent to the subspace RX formulation for straight anomaly detection, but applied to the stacked space. However, this family is not invariant to linear coordinate transforms. On the other hand, whitened TLSQ is coordinate invariant, and furthermore it is shown to be equivalent to the optimized covariance equalization algorithm. What whitened TLSQ offers, in addition to connecting with a common language the derivations of two of the most popular anomalous change detection algorithms - chronochrome and covariance equalization - is a generalization of these algorithms with the potential for better performance.

  4. Preliminary Study of Oxygen-Enhanced Longitudinal Relaxation in MRI: A Potential Novel Biomarker of Oxygenation Changes in Solid Tumors

    SciTech Connect (OSTI)

    O'Connor, James P.B.; Naish, Josephine H.; Parker, Geoff J.M.; Waterton, John C.; Watson, Yvonne; Jayson, Gordon C.; Buonaccorsi, Giovanni A.; Cheung, Sue; Buckley, David L.; McGrath, Deirdre M.; West, Catharine M.L.; Davidson, Susan E.; Roberts, Caleb; Mills, Samantha J.; Mitchell, Claire L.; Hope, Lynn; Ton, N. Chan; Jackson, Alan

    2009-11-15

    Purpose: There is considerable interest in developing non-invasive methods of mapping tumor hypoxia. Changes in tissue oxygen concentration produce proportional changes in the magnetic resonance imaging (MRI) longitudinal relaxation rate (R{sub 1}). This technique has been used previously to evaluate oxygen delivery to healthy tissues and is distinct from blood oxygenation level-dependent (BOLD) imaging. Here we report application of this method to detect alteration in tumor oxygenation status. Methods and materials: Ten patients with advanced cancer of the abdomen and pelvis underwent serial measurement of tumor R{sub 1} while breathing medical air (21% oxygen) followed by 100% oxygen (oxygen-enhanced MRI). Gadolinium-based dynamic contrast-enhanced MRI was then performed to compare the spatial distribution of perfusion with that of oxygen-induced DELTAR{sub 1}. Results: DELTAR{sub 1} showed significant increases of 0.021 to 0.058 s{sup -1} in eight patients with either locally recurrent tumor from cervical and hepatocellular carcinomas or metastases from ovarian and colorectal carcinomas. In general, there was congruency between perfusion and oxygen concentration. However, regional mismatch was observed in some tumor cores. Here, moderate gadolinium uptake (consistent with moderate perfusion) was associated with low area under the DELTAR{sub 1} curve (consistent with minimal increase in oxygen concentration). Conclusions: These results provide evidence that oxygen-enhanced longitudinal relaxation can monitor changes in tumor oxygen concentration. The technique shows promise in identifying hypoxic regions within tumors and may enable spatial mapping of change in tumor oxygen concentration.

  5. METHOD OF COMBINING HYDROGEN AND OXYGEN

    DOE Patents [OSTI]

    McBride, J.P.

    1962-02-27

    A method is given for the catalytic recombination of radiolytic hydrogen and/or deulerium and oxygen resulting from the subjection or an aqueous thorium oxide or thorium oxide-uranium oxide slurry to ionizing radiation. An improved catalyst is prepared by providing paliadium nitrate in an aqueous thorium oxide sol at a concentration of at least 0.05 grams per gram of thorium oxide and contacting the sol with gaseous hydrogen to form flocculated solids. The solids are then recovered and added to the slurry to provide a palladium concentration of 100 to 1000 parts per million. Recombination is effected by the calalyst at a rate sufficient to support high nuclear reactor power densities. (AEC)

  6. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2002-07-01

    Mixed-conducting ceramics have the ability to conduct oxygen with perfect selectivity at elevated temperatures, making them extremely attractive as membrane materials for oxygen separation and membrane reactor applications. While the conductivity of these materials can be quite high at elevated temperatures (typically 800-1000 C), much higher oxygen fluxes, or, alternatively, equivalent fluxes at lower temperatures, could be provided by supported thin or thick film membrane layers. Based on that motivation, the objective of this project was to explore the use of ultrafine aerosol-derived powder of a mixed-conducting ceramic material for fabrication of supported thick-film dense membranes. The project focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} (SCFO) because of the desirable permeability and stability of that material, as reported in the literature. Appropriate conditions to produce the submicron SrCo{sub 0.5}FeO{sub x} powder using aerosol pyrolysis were determined. Porous supports of the same composition were produced by partial sintering of a commercially obtained powder that possessed significantly larger particle size than the aerosol-derived powder. The effects of sintering conditions (temperature, atmosphere) on the porosity and microstructure of the porous discs were studied, and a standard support fabrication procedure was adopted. Subsequently, a variety of paste and slurry formulations were explored utilizing the aerosol-derived SCFO powder. These formulations were applied to the porous SCFO support by a doctor blade or spin coating procedure. Sintering of the supported membrane layer was then conducted, and additional layers were deposited and sintered in some cases. The primary characterization methods were X-ray diffraction and scanning electron microscopy, and room-temperature nitrogen permeation was used to assess defect status of the membranes.We found that non-aqueous paste/slurry formulations incorporating

  7. Apparatus and method for quantitatively evaluating total fissile and total fertile nuclide content in samples

    DOE Patents [OSTI]

    Caldwell, John T.; Kunz, Walter E.; Cates, Michael R.; Franks, Larry A.

    1985-01-01

    Simultaneous photon and neutron interrogation of samples for the quantitative determination of total fissile nuclide and total fertile nuclide material present is made possible by the use of an electron accelerator. Prompt and delayed neutrons produced from resulting induced fissions are counted using a single detection system and allow the resolution of the contributions from each interrogating flux leading in turn to the quantitative determination sought. Detection limits for .sup.239 Pu are estimated to be about 3 mg using prompt fission neutrons and about 6 mg using delayed neutrons.

  8. Oxygen detected in atmosphere of Saturn's moon Dione

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of molecular oxygen ions in the upper-most atmosphere of Dione. March 3, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics

  9. Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity | The Ames

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Laboratory Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity Oxygen is one of the most ubiquitous elements in chemistry and materials science, yet one of the most elusive elements for spectroscopic investigation by solid-state Nuclear Magnetic Resonance (SSNMR). Used to determine the structure of materials and chemicals on the atomic scale, SSNMR requires nuclei that have magnetic moments. Yet, less than four of every 10,000 oxygen nuclei are 17O, the only NMR-active isotope of

  10. Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Technique | Department of Energy Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Presentation slides from the Fuel Cell Technologies Office webinar, "Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique," held March 12, 2013. Presenters were Shyam S. Kocha, National Renewable Energy Laboratory; Yannick Garsany, Naval Research

  11. Nevada Natural Gas % of Total Residential Deliveries (Percent...

    Annual Energy Outlook

    Nevada Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 Year-2 ... Share of Total U.S. Natural Gas Residential Deliveries Nevada Share of Total U.S. Natural ...

  12. Texas Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update

    Texas Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 Year-2 ... Share of Total U.S. Natural Gas Residential Deliveries Texas Share of Total U.S. Natural ...

  13. Oklahoma Natural Gas % of Total Residential Deliveries (Percent...

    Annual Energy Outlook

    Oklahoma Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries Oklahoma Share of Total U.S. ...

  14. New York Natural Gas % of Total Residential Deliveries (Percent...

    Annual Energy Outlook

    New York Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries New York Share of Total U.S. ...

  15. New Mexico Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update

    New Mexico Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries New Mexico Share of Total U.S. ...

  16. New Jersey Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update

    New Jersey Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries New Jersey Share of Total U.S. ...

  17. Minnesota Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update

    Minnesota Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries Minnesota Share of Total U.S. ...

  18. On the dynamics of the damage growth in 5 MeV oxygen-implanted lithium niobate

    SciTech Connect (OSTI)

    Bianconi, M.; Argiolas, N.; Bazzan, M.; Bentini, G.G.; Chiarini, M.; Cerutti, A.; Mazzoldi, P.; Pennestri, G.; Sada, C.

    2005-08-15

    The damage induced by 5 MeV oxygen ion implantation in x-cut congruent LiNbO{sub 3} has been investigated by Rutherford backscattering spectrometry channeling technique. The dynamics of the damage growth has been described by an analytical formula considering the separate contributions of nuclear and electronic energy deposition. It has been hypothesized that the nuclear damage provides the localization of the energy released to the electronic subsystem necessary for the conversion into atomic displacements. The strong influence of the preexisting defects on the damage pileup, foreseen by the analytical formula, has been experimentally verified by pre-implanting the samples with 500 keV oxygen ions. It has been shown that a subsequent 5 MeV oxygen implantation step gives rise to an impressive damage accumulation, eventually leading to the total amorphization of the surface, even at moderate fluences.

  19. Total lymphoid irradiation for multiple sclerosis

    SciTech Connect (OSTI)

    Devereux, C.K.; Vidaver, R.; Hafstein, M.P.; Zito, G.; Troiano, R.; Dowling, P.C.; Cook, S.D.

    1988-01-01

    Although chemical immunosuppression has been shown to benefit patients with chronic progressive multiple sclerosis (MS), it appears that chemotherapy has an appreciable oncogenic potential in patients with multiple sclerosis. Accordingly, we developed a modified total lymphoid irradiation (TLI) regimen designed to reduce toxicity and applied it to a randomized double blind trial of TLI or sham irradiation in MS. Standard TLI regimens were modified to reduce dose to 1,980 rad, lowering the superior mantle margin to midway between the thyroid cartilage and angle of the mandible (to avert xerostomia) and the lower margin of the mantle field to the inferior margin of L1 (to reduce gastrointestinal toxicity by dividing abdominal radiation between mantle and inverted Y), limiting spinal cord dose to 1,000 rad by custom-made spine blocks in the mantle and upper 2 cm of inverted Y fields, and also protecting the left kidney even if part of the spleen were shielded. Clinical efficacy was documented by the less frequent functional scale deterioration of 20 TLI treated patients with chronic progressive MS compared to to 20 sham-irradiated progressive MS patients after 12 months (16% versus 55%, p less than 0.03), 18 months (28% versus 63%, p less than 0.03), and 24 months (44% versus 74%, N.S.). Therapeutic benefit during 3 years follow-up was related to the reduction in lymphocyte count 3 months post-irradiation (p less than 0.02). Toxicity was generally mild and transient, with no instance of xerostomia, pericarditis, herpes zoster, or need to terminate treatment in TLI patients. However, menopause was induced in 2 patients and staphylococcal pneumonia in one.

  20. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) ...

  1. Strain control of oxygen vacancies in epitaxial strontium cobaltite...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Strain control of oxygen vacancies in epitaxial strontium cobaltite films ... This content will become publicly available on January 25, 2017 Title: Strain control of ...

  2. Hybrid System for Separating Oxygen from Air - Energy Innovation...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate...

  3. New Oxygen-Production Technology Proving Successful | Department...

    Energy.gov (indexed) [DOE]

    ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also ...

  4. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, George E.; Merritt, Bernard T.; Hsiao, Mark C.; Wallman, P. Henrik; Penetrante, Bernardino M.

    1999-01-01

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.

  5. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen...

    Energy Savers

    Review 2015: Intake Air Oxygen Sensor Vehicle Technologies Office Merit Review 2014: Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  6. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen...

    Energy Savers

    Office Merit Review 2014: Intake Air Oxygen Sensor Bosch Powertrain Technologies Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  7. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) (indexed site)

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  8. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) (indexed site)

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  9. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  10. Role of strain and conductivity in oxygen electrocatalysis on...

    Office of Scientific and Technical Information (OSTI)

    The slow kinetics of the oxygen reduction and evolution reactions (ORR, OER) hinder energy conversion and storage in alkaline fuel cells and electrolyzers employing abundant ...

  11. The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl...

    Office of Scientific and Technical Information (OSTI)

    Title: The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl Impurity Defects on Titanium Dioxide (110) Surface Introducing a charge into a solid such as a metal oxide ...

  12. Strain control of oxygen vacancies in epitaxial strontium cobaltite films

    DOE PAGES-Beta [OSTI]

    Jeen, Hyoung Jeen; Choi, Woo Seok; Reboredo, Fernando A.; Freeland, John W.; Eres, Gyula; Lee, Ho Nyung; Petrie, Jonathan R.; Mitra, Chandrima; Meyer, Tricia L.

    2016-01-25

    In this study, the ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the deliberate control of important defects, oxygen vacancies. Here, strontium cobaltite (SrCoOx) is used to demonstrate that epitaxial strain is a powerful tool for manipulating the oxygen vacancy concentration even under highly oxidizing environments and at annealing temperatures as low as 300 °C. By applying a small biaxial tensile strain (2%), the oxygen activation energy barrier decreases by ≈30%, resulting inmore » a tunable oxygen deficient steady-state under conditions that would normally fully oxidize unstrained cobaltite. These strain-induced changes in oxygen stoichiometry drive the cobaltite from a ferromagnetic metal towards an antiferromagnetic insulator. The ability to decouple the oxygen vacancy concentration from its typical dependence on the operational environment is useful for effectively designing oxides materials with a specific oxygen stoichiometry.« less

  13. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Energy.gov (indexed) [DOE]

    (196.85 KB) More Documents & Publications Development Methodology for Power-Dense Military Diesel Engine Oxygen-Enriched Combustion Emission Control Strategy for Downsized ...

  14. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock ...

  15. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an ...

  16. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: ...

  17. Discovery of oxygen in atmosphere could mean life for Saturn...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  18. Oxygen detected in atmosphere of Saturn's moon Dione

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  19. Electrocatalyst for Oxygen Reduction with Reduced Platinum Oxidation...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates The invention relates to platinum-metal oxide composite particles and their use as...

  20. Probing oxygen vacancy concentration and homogeneity in solid...

    Office of Scientific and Technical Information (OSTI)

    Here, we develop an approach for direct mapping of oxygen vacancy concentrations based on local lattice parameter measurements by scanning transmission electron microscopy. The ...

  1. Oxidation State and Interfacial Effects on Oxygen Vacancies in...

    Office of Scientific and Technical Information (OSTI)

    Oxygen Vacancies in Tantalum Pentoxide. Abstract not provided. Authors: Bondi, Robert James ; Marinella, Matthew Publication Date: 2014-10-01 OSTI Identifier: 1184499 Report...

  2. West Virginia Natural Gas Total Consumption (Million Cubic Feet...

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Consumption (Million Cubic Feet) West Virginia Natural Gas Total Consumption ... Referring Pages: Natural Gas Consumption West Virginia Natural Gas Consumption by End Use ...

  3. Virginia Natural Gas Total Consumption (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Consumption (Million Cubic Feet) Virginia Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption Virginia Natural Gas Consumption by End Use ...

  4. ,"Alaska (with Total Offshore) Natural Gas Liquids Lease Condensate...

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Alaska (with Total Offshore) Natural Gas Liquids Lease Condensate, ... to Contents","Data 1: Alaska (with Total Offshore) Natural Gas Liquids Lease Condensate, ...

  5. ,"Alaska (with Total Offshore) Coalbed Methane Proved Reserves...

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Alaska (with Total Offshore) Coalbed Methane Proved Reserves ... to Contents","Data 1: Alaska (with Total Offshore) Coalbed Methane Proved Reserves ...

  6. ,"Alaska (with Total Offshore) Natural Gas Plant Liquids, Expected...

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Alaska (with Total Offshore) Natural Gas Plant Liquids, Expected ... to Contents","Data 1: Alaska (with Total Offshore) Natural Gas Plant Liquids, Expected ...

  7. ,"Alaska (with Total Offshore) Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Alaska (with Total Offshore) Shale Proved Reserves (Billion Cubic ... to Contents","Data 1: Alaska (with Total Offshore) Shale Proved Reserves (Billion Cubic ...

  8. ARM: GRAMS: data from the total direct diffuse radiometer (TDDR...

    Office of Scientific and Technical Information (OSTI)

    direct diffuse radiometer (TDDR) Title: ARM: GRAMS: data from the total direct diffuse radiometer (TDDR) GRAMS: data from the total direct diffuse radiometer (TDDR) Authors: ...

  9. Total Energy Facilities Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Energy Facilities Biomass Facility Jump to: navigation, search Name Total Energy Facilities Biomass Facility Facility Total Energy Facilities Sector Biomass Facility Type...

  10. Nevada Natural Gas Total Consumption (Million Cubic Feet)

    Annual Energy Outlook

    Total Consumption (Million Cubic Feet) Nevada Natural Gas Total Consumption (Million Cubic ... Referring Pages: Natural Gas Consumption Nevada Natural Gas Consumption by End Use ...

  11. Price of Lake Charles, LA Liquefied Natural Gas Total Imports...

    Gasoline and Diesel Fuel Update

    Liquefied Natural Gas Total Imports (Dollars per Thousand Cubic Feet) Price of Lake Charles, LA Liquefied Natural Gas Total Imports (Dollars per Thousand Cubic Feet) Decade Year-0 ...

  12. Table 6b. Relative Standard Errors for Total Electricity Consumption...

    U.S. Energy Information Administration (EIA) (indexed site)

    b. Relative Standard Errors for Total Electricity Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using Electricity (thousand) Total...

  13. Webtrends Archives by Fiscal Year — EERE Totals

    Office of Energy Efficiency and Renewable Energy (EERE)

    Historical EERE office total reports include only Webtrends archives by fiscal year. EERE total reports dating after FY11 can be accessed in EERE's Google Analytics account.

  14. Table 5a. Total District Heat Consumption per Effective Occupied...

    U.S. Energy Information Administration (EIA) (indexed site)

    a. Total District Heat Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using District Heat (thousand) Total District Heat Consumption...

  15. NREL: Building America Total Quality Management - 2015 Peer Review...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    NREL: Building America Total Quality Management - 2015 Peer Review NREL: Building America Total Quality Management - 2015 Peer Review Presenter: Stacey Rothgeb, NREL View the ...

  16. Kansas Natural Gas Total Consumption (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Consumption (Million Cubic Feet) Kansas Natural Gas Total Consumption (Million Cubic ... Referring Pages: Natural Gas Consumption Kansas Natural Gas Consumption by End Use Natural ...

  17. ARM: GRAMS: data from the total solar broadband radiometer (TBBR...

    Office of Scientific and Technical Information (OSTI)

    solar broadband radiometer (TBBR) Title: ARM: GRAMS: data from the total solar broadband radiometer (TBBR) GRAMS: data from the total solar broadband radiometer (TBBR) Authors: ...

  18. ARM: GRAMS: calibration information for the total solar broadband...

    Office of Scientific and Technical Information (OSTI)

    solar broadband radiometer (TBBR) Title: ARM: GRAMS: calibration information for the total solar broadband radiometer (TBBR) GRAMS: calibration information for the total solar ...

  19. ,"Total District Heat Consumption (trillion Btu)",,,,,"District...

    U.S. Energy Information Administration (EIA) (indexed site)

    Heat Consumption (trillion Btu)",,,,,"District Heat Energy Intensity (thousand Btusquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  20. ,"Total Natural Gas Consumption (trillion Btu)",,,,,"Natural...

    U.S. Energy Information Administration (EIA) (indexed site)

    Gas Consumption (trillion Btu)",,,,,"Natural Gas Energy Intensity (thousand Btusquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  1. New Jersey Natural Gas Total Consumption (Million Cubic Feet...

    Gasoline and Diesel Fuel Update

    Total Consumption (Million Cubic Feet) New Jersey Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption New Jersey Natural Gas Consumption by End Use ...

  2. New York Natural Gas Total Consumption (Million Cubic Feet)

    Annual Energy Outlook

    Total Consumption (Million Cubic Feet) New York Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption New York Natural Gas Consumption by End Use ...

  3. New Mexico Natural Gas Total Consumption (Million Cubic Feet...

    Gasoline and Diesel Fuel Update

    Total Consumption (Million Cubic Feet) New Mexico Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption New Mexico Natural Gas Consumption by End Use ...

  4. North Carolina Natural Gas Total Consumption (Million Cubic Feet...

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Consumption (Million Cubic Feet) North Carolina Natural Gas Total Consumption ... Referring Pages: Natural Gas Consumption North Carolina Natural Gas Consumption by End Use ...

  5. North Dakota Natural Gas Total Consumption (Million Cubic Feet...

    U.S. Energy Information Administration (EIA) (indexed site)

    Total Consumption (Million Cubic Feet) North Dakota Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption North Dakota Natural Gas Consumption by End Use ...

  6. ,"Crude Oil and Petroleum Products Total Stocks Stocks by Type...

    U.S. Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Crude Oil and Petroleum Products Total Stocks Stocks ... PM" "Back to Contents","Data 1: Crude Oil and Petroleum Products Total Stocks Stocks ...

  7. Estimation of Anisotoropy from Total Cross Section and Optical...

    Office of Scientific and Technical Information (OSTI)

    Conference: Estimation of Anisotoropy from Total Cross Section and Optical Model Citation Details In-Document Search Title: Estimation of Anisotoropy from Total Cross Section and ...

  8. Minnesota Natural Gas Total Consumption (Million Cubic Feet)

    Gasoline and Diesel Fuel Update

    Total Consumption (Million Cubic Feet) Minnesota Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption Minnesota Natural Gas Consumption by End Use ...

  9. Oxygen diffusion of anodic surface oxide film on titanium studied by Auger electron spectroscopy. [Oxygen diffusivity

    SciTech Connect (OSTI)

    Wang, P.S.; Wittberg, T.N.; Keil, R.G.

    1982-01-01

    TiO/sub 2/ films of about 1000 A were grown onto titanium foils anodically under galvanostatic conditions at 20 mA/cm/sup 2/ in saturated aqueous solutions of ammonium tetraborate. The samples were then aged at 450, 500, and 550/sup 0/C, and oxygen diffusion was observed by Auger electron spectroscopy (AES) profilings. The oxygen diffusivities were calculated by Fick's Second Law, using the Boltzmann-Matano solution, to be 9.4 x 10/sup -17/, 2.6 x 10/sup -16/, and 1.2 x 10/sup -15/ cm/sup 2//sec at 450, 500, and 550/sup 0/C, respectively. The diffusivities obtained by this method were also compared with those obtained using an exact solution to Fick's Second Law. The activation energy was calculated to be 30 kcal/mole.

  10. Low NOx combustion using cogenerated oxygen and nitrogen streams

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, Lawrence E.; Snyder, William J.

    2009-02-03

    Combustion of hydrocarbon fuel is achieved with less formation of NOx by feeding the fuel into a slightly oxygen-enriched atmosphere, and separating air into oxygen-rich and nitrogen-rich streams which are fed separately into the combustion device.

  11. Effects of oxygen and catalyst on tetraphenylborate decomposition rate

    SciTech Connect (OSTI)

    Walker, D.D.

    1999-12-15

    Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.

  12. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav; Huang, Tao

    2009-12-15

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  13. Homogeneously dispersed, multimetal oxygen-evolving catalysts

    DOE PAGES-Beta [OSTI]

    Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; et al

    2016-03-24

    Earth-abundant first-row (3d) transition-metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials significantly above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing near-optimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxy-hydroxide materials with an atomically homogeneous metal distribution. These gelled FeCoW oxy-hydroxide exhibits the lowest overpotential (191 mV) reported at 10 mA per square centimeter in alkaline electrolyte. Here, the catalyst shows no evidence of degradation following more than 500 hours of operation. X-ray absorption and computationalmore » studies reveal a synergistic interplay between W, Fe and Co in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.« less

  14. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T.; Breitkopf, Richard C.

    2009-12-01

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  15. Willamette Oxygen Supplementation Studies : Annual Report 1994.

    SciTech Connect (OSTI)

    Ewing, R.D.; Ewing, S.K.; Sheahan, J.E.

    1994-09-01

    Hydropower development and operations in the Columbia River basin have caused the loss of 5 million to 11 million salmonids. An interim goal of the Northwest Power Planning Council is to reestablish these historical numbers by doubling the present runs from 2.5 million adult fish to 5.0 million adult fish. This increase in production will be accomplished through comprehensive management of both wild and hatchery fish, but artificial propagation will play a major role in the augmentation process. The current husbandry techniques in existing hatcheries require improvements that may include changes in rearing densities, addition of oxygen, removal of excess nitrogen, and improvement in raceway design. Emphasis will be placed on the ability to increase the number of fish released from hatcheries that survive to return as adults. Rearing density is one of the most important elements in fish culture. Fish culturists have attempted to rear fish in hatchery ponds at densities that most efficiently use the rearing space available. Such efficiency studies require a knowledge of cost of rearing and the return of adults to the fisheries and to the hatchery.

  16. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect (OSTI)

    Riley, M.F.

    1996-12-31

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  17. ,"U.S. Reformulated Gasoline Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) (indexed site)

    Sales Volumes",6,"Monthly","22016","1151994" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefmgcnusepm0rmgalpdm.xls" ...

  18. 0101,"SPRAGUE ENERGY CORP",1,150,"MOGAS, REFORMULATED",0131,...

    U.S. Energy Information Administration (EIA) (indexed site)

    REFG & MKTG INC",2,152,"MOGAS, OTHER FINISHED",4908,"PONCE, PR","PR",600,830,"SPAIN",230,0,0 0101,"TEXACO REFG & MKTG INC",3,152,"MOGAS, OTHER FINISHED",1003,"NEWARK,...

  19. Reformulated Gasoline Use Under the 8-Hour Ozone Rule

    Reports and Publications

    2002-01-01

    This paper focuses on the impact on gasoline price and supply when additional ozone non-attainment areas come under the new 8-hour ozone standard.

  20. Refiner and Blender Net Production of Reformulated Gasoline

    Gasoline and Diesel Fuel Update

    3,225 3,240 3,261 3,264 3,266 3,189 1993-2016 PADD 1 1,271 1,277 1,307 1,300 1,319 1,253 1993-2016 PADD 2 355 357 368 365 365 361 1993-2016 PADD 3 467 474 477 475 482 471 1993-2016 PADD 4 0 0 0 0 0 0 1993-2016 PADD 5 1,132 1,132 1,109 1,124 1,100 1,103 1993

  1. ,"U.S. Reformulated, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) (indexed site)

    File Name:","petprirefmg2cnusepm0rdpgalm.xls" ,"Available from Web Page:","http:www.eia.govdnavpetpetprirefmg2cnusepm0rdpgalm.htm" ,"Source:","Energy ...

  2. Demand and Price Outlook for Phase 2 Reformulated Gasoline, 2000

    Gasoline and Diesel Fuel Update

    78-2005 Citygate 5.67 9.03 7.19 5.67 5.54 5.87 1984-2015 Residential 15.12 15.38 15.24 13.65 13.21 12.62 1967-2015 Commercial 13.26 13.58 13.31 11.78 11.42 10.70 1967-2015 Industrial 10.18 11.69 11.61 11.24 10.95 10.11 1997-2015 Vehicle Fuel 24.55 28.76 30.97 1995-2012 Electric Power W W -- -- -- -- 1997-2015 Underground Storage (Million Cubic Feet) Injections 1967-1975 Withdrawals 1967-1975 Net Withdrawals 1967-1975 Liquefied Natural Gas Storage (Million Cubic Feet) Additions 73 64 117 63 157

  3. U.S. Reformulated, Average Refiner Gasoline Prices

    U.S. Energy Information Administration (EIA) (indexed site)

    736 1.921 2.011 2.078 1.998 1.885 1994-2016 Through Retail Outlets 1.737 1.921 2.012 2.079 1.999 1.885 1994-2016 Sales for Resale, Average 1.463 1.601 1.694 1.740 1.574 1.553 1994-2016 DTW 1.783 1.895 1.917 1.983 1.884 1.732 1994-2016 Rack 1.388 1.533 1.645 1.690 1.504 1.513 1994-2016 Bulk 1.377 1.514 1.602 1.619 1.524 1.479

  4. Oxygen transport pathways in Ruddlesden–Popper structured oxides revealed via in situ neutron diffraction

    DOE PAGES-Beta [OSTI]

    Tomkiewicz, Alex C.; Tamimi, Mazin; Huq, Ashfia; McIntosh, Steven

    2015-09-21

    Ruddlesden-Popper structured oxides, general form An+1BnO3n+1, consist of n-layers of the perovskite structure stacked in between rock-salt layers, and have potential application in solid oxide electrochemical cells and ion transport membrane reactors. Three materials with constant Co/Fe ratio, LaSrCo0.5Fe0.5O4-δ (n = 1), La0.3Sr2.7CoFeO7-δ (n = 2), and LaSr3Co1.5Fe1.5O10-δ (n = 3) were synthesized and studied via in situ neutron powder diffraction between 765 K and 1070 K at a pO2 of 10-1 atm. Then, the structures were fit to a tetragonal I4/mmm space group, and were found to have increased total oxygen vacancy concentration in the order La0.3Sr2.7CoFeO7-δ > LaSr3Co1.5Fe1.5O10-δmore » > LaSrCo0.5Fe0.5O4-δ, following the trend predicted for charge compensation upon increasing Sr2+/La3+ ratio. The oxygen vacancies within the material were almost exclusively located within the perovskite layers for all of the crystal structures with only minimal vacancy formation in the rock-salt layer. Finally, analysis of the concentration of these vacancies at each distinct crystallographic site and the anisotropic atomic displacement parameters for the oxygen sites reveals potential preferred oxygen transport pathways through the perovskite layers.« less

  5. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect (OSTI)

    Zawierucha, R.; McIlroy, K.; Million, J.F.

    1995-12-31

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  6. Enhancing perovskite electrocatalysis through strain tuning of oxygen deficiency

    DOE PAGES-Beta [OSTI]

    Barron, Sara C.; Lee, Ho Nyung; Petrie, Jonathan R.; Jeen, Hyoungjeen; Meyer, Tricia L.

    2016-05-27

    Oxygen vacancies in transition-metal oxides facilitate catalysis critical for energy storage and generation. However, promoting vacancies at the lower temperatures required for operation in devices such as metal–air batteries and portable fuel cells has proven elusive. Here we used thin films of perovskite-based strontium cobaltite (SrCoOx) to show that epitaxial strain is a powerful tool for manipulating the oxygen content under conditions consistent with the oxygen evolution reaction, yielding increasingly oxygen-deficient states in an environment where the cobaltite would normally be fully oxidized. The additional oxygen vacancies created through tensile strain enhance the cobaltite’s catalytic activity toward this important reactionmore » by over an order of magnitude, equaling that of precious-metal catalysts, including IrO2. Lastly, our findings demonstrate that strain in these oxides can dictate the oxygen stoichiometry independent of ambient conditions, allowing unprecedented control over oxygen vacancies essential in catalysis near room temperature.« less

  7. Noble metal-free bifunctional oxygen evolution and oxygen reduction acidic media electro-catalysts

    DOE PAGES-Beta [OSTI]

    Patel, Prasad Prakash; Datta, Moni Kanchan; Velikokhatnyi, Oleg I.; Kuruba, Ramalinga; Damodaran, Krishnan; Jampani, Prashanth; Gattu, Bharat; Shanthi, Pavithra Murugavel; Damle, Sameer S.; Kumta, Prashant N.

    2016-07-06

    We report that identification of low cost, highly active, durable completely noble metal-free electro-catalyst for oxygen reduction reaction (ORR) in proton exchange membrane (PEM) fuel cells, oxygen evolution reaction (OER) in PEM based water electrolysis and metal air batteries remains one of the major unfulfilled scientific and technological challenges of PEM based acid mediated electro-catalysts. In contrast, several non-noble metals based electro-catalysts have been identified for alkaline and neutral medium water electrolysis and fuel cells. Furthermore, we report for the very first time, F doped Cu1.5Mn1.5O4, identified by exploiting theoretical first principles calculations for ORR and OER in PEM basedmore » systems. The identified novel noble metal-free electro-catalyst showed similar onset potential (1.43 V for OER and 1 V for ORR vs RHE) to that of IrO2 and Pt/C, respectively. The system also displayed excellent electrochemical activity comparable to IrO2 for OER and Pt/C for ORR, respectively, along with remarkable long term stability for 6000 cycles in acidic media validating theory, while also displaying superior methanol tolerance and yielding recommended power densities in full cell configurations.« less

  8. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  9. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  10. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min; Shen, Zhigang; Zhao, Xiaohu; Liang, Shuaishuai; Liu, Lei

    2014-04-07

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  11. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  12. Modelling oxygen self-diffusion in UO2 under pressure

    DOE PAGES-Beta [OSTI]

    Cooper, Michael William D.; Grimes, R. W.; Fitzpatrick, M. E.; Chroneos, A.

    2015-10-22

    Access to values for oxygen self-diffusion over a range of temperatures and pressures in UO2 is important to nuclear fuel applications. Here, elastic and expansivity data are used in the framework of a thermodynamic model, the cBΩ model, to derive the oxygen self-diffusion coefficient in UO2 over a range of pressures (0–10 GPa) and temperatures (300–1900 K). Furthermore, the significant reduction in oxygen self-diffusion as a function of increasing hydrostatic pressure, and the associated increase in activation energy, is identified.

  13. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universitt Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  14. Delaware Total Electric Power Industry Net Generation, by Energy...

    U.S. Energy Information Administration (EIA) (indexed site)

    ...e","-","-","-","-","-" "Other","-","-",11,6,"-" "Total",7182,8534,7524,4842,5628 " " "s Value is less than 0.5 of the table metric, but value is included in any associated total.

  15. Maine Natural Gas Total Consumption (Million Cubic Feet)

    Annual Energy Outlook

    Total Consumption (Million Cubic Feet) Maine Natural Gas Total Consumption (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's...

  16. Maine Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update

    % of Total Residential Deliveries (Percent) Maine Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

  17. Project Functions and Activities Definitions for Total Project Cost

    Directives, Delegations, and Requirements [Office of Management (MA)]

    1997-03-28

    This chapter provides guidelines developed to define the obvious disparity of opinions and practices with regard to what exactly is included in total estimated cost (TEC) and total project cost (TPC).

  18. Total China Investment Co Ltd | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    China Investment Co Ltd Jump to: navigation, search Name: Total (China) Investment Co. Ltd. Place: Beijing, China Zip: 100004 Product: Total has been present in China for about 30...

  19. Washington Natural Gas % of Total Residential Deliveries (Percent...

    Annual Energy Outlook

    % of Total Residential Deliveries (Percent) Washington Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

  20. Washington Natural Gas Total Consumption (Million Cubic Feet...

    Annual Energy Outlook

    Total Consumption (Million Cubic Feet) Washington Natural Gas Total Consumption (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9...