National Library of Energy BETA

Sample records for oxygen pro cess

  1. Genie Pro

    Energy Science and Technology Software Center

    2004-05-15

    Genie Pro is a general purpose, interactive, adaptive tool for automatically labeling regions and finding objects in large amounts of image data. Genie Pro uses supervised learning techniques to search for spatio-spectral algorithms that are best able to match exaple labels provided by a user during a training session. After Genie Pro has discovered a useful algorithm, this algorith can then be applied to other similar types of image data, to label regions and objectsmore » similar to those provided during the training session. Genie Pro was originally developed for analyzing multispectral satellite data, but it works equally well with panchromatic (grayscale) and hyperspectral satellite data, aerial imagery, and various kinds of medical imagery. AS a rough guideline, Genie Pro can work with any imagery where the scene being imaged is all approximately at a constant distance fromt he imaging device, and so the scale of imagery is fixed. Applications for Genie Pro include: Crop and terrain type mapping, Road and river network mapping, Broad area search for vehicles and buildings, and Cancer identification in histological images.« less

  2. AL PRO | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: AL-PRO Place: Grossheide, Lower Saxony, Germany Zip: 26532 Sector: Wind energy Product: AL-PRO is an inndependent expert office for wind forecasts, wind...

  3. HyPRO Model

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    HyPRO Model (Strategic Analysis, Inc.) Objectives Provide a modeling tool to develop an understanding of how the hydrogen production infrastructure might evolve in the United States and determine the factors that will drive infrastructure development. Key Attributes & Strengths HyPRO provides a transparent enumeration of production, delivery and dispensing costs for comparison of different options. It also provides a graphical projection of production, delivery and dispensing infrastructure

  4. ProMat

    Energy Science and Technology Software Center

    2008-06-12

    ProMAT is a software tool for statistically analyzing data from enzyme-linked immunosorbent assay microarray experiments. The software estimates standard curves, sample protein concentrations and their uncertainties for multiple assays. ProMAT generates a set of comprehensive figures for assessing results and diagnosing process quality. The tool is available for Windows or Mac, and is distributed as open-source Java and R code

  5. Word Pro - S3

    Energy Information Administration (EIA) (indexed site)

    Crude Oil a Distillate Fuel Oil f Jet Fuel g LPG b Motor Gasoline i Residual Fuel Oil ... finished motor gasoline and motor gasoline blending components; excludes oxygenates. ...

  6. Energy Pro USA | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Pro USA Jump to: navigation, search Name: Energy Pro USA Place: Chesterfield, Missouri Zip: MO 63017 Product: Energy Pro funds and implements demand side energy savings programs to...

  7. Re-evaluating Network Onload vs. Offload for the Many-Core Era

    Office of Scientific and Technical Information (OSTI)

    As a result, the performance and power costs of host network protocol pro- cessing ... AMD equivalent core, to network pro- cessing has thus far been an acceptable compromise. ...

  8. Word Pro - Untitled1

    Energy Information Administration (EIA) (indexed site)

    chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group: CH 3 -(CH 2 )n-OH (e.g., metha- nol, ethanol, and tertiary butyl alcohol). See Fuel Ethanol. Alternative Fuel: Alternative fuels, for transportation applications, include the following: methanol; denatured ethanol, and other alcohols; fuel mixtures contain- ing 85 percent or more by volume of methanol, denatured ethanol, and other

  9. Word Pro - Untitled1

    Energy Information Administration (EIA) (indexed site)

    1 Table 10.5 Estimated Number of Alternative-Fueled Vehicles in Use and Fuel Consumption, 1992-2010 Year Alternative and Replacement Fuels 1 Liquefied Petroleum Gases Compressed Natural Gas Liquefied Natural Gas Methanol, 85 Percent (M85) 3 Methanol, Neat (M100) 4 Ethanol, 85 Percent (E85) 3,5 Ethanol, 95 Percent (E95) 3 Elec- tricity 6 Hydro- gen Other Fuels 7 Subtotal Oxygenates 2 Bio- diesel 10 Total Methyl Tertiary Butyl Ether 8 Ethanol in Gasohol 9 Total Alternative-Fueled Vehicles in Use

  10. Word Pro - Untitled1

    Energy Information Administration (EIA) (indexed site)

    3 All Sellers Sales Prices for Selected Petroleum Products, 2010 Motor Gasoline, Selected Grades Distillate Fuel Oil, Residual Fuel Oil, and Propane 170 U.S. Energy Information Administration / Annual Energy Review 2011 1 Prices are not adjusted for inflation. See "Nominal Dollars" in Glossary. 2 Includes oxygenated motor gasoline. 3 > 15 and <= 500 parts per million. 4 > 500 parts per million. - - = Not applicable. Note: Data are preliminary. Source: Table 5.23. 2.32 2.29

  11. Word Pro - Untitled1

    Gasoline and Diesel Fuel Update

    1 Table 5.1b Petroleum Overview, Selected Years, 1949-2011 (Thousand Barrels per Day) Year Field Production 1 Renewable Fuels and Oxygenates 5 Processing Gain 6 Trade Stock Change 8,10 Adjust- ments 11 Petroleum Products Supplied 8 Crude Oil 2 Natural Gas Plant Liquids 4 Total Imports 7,8 Exports Net Imports 8,9 48 States 3 Alaska Total 1949 5,046 0 5,046 430 5,477 NA -2 645 327 318 -8 -38 5,763 1950 5,407 0 5,407 499 5,906 NA 2 850 305 545 -56 -51 6,458 1955 6,807 0 6,807 771 7,578 NA 34 1,248

  12. DC Pro Software Tool Suite

    SciTech Connect

    2009-04-01

    This fact sheet describes how DOE's Data Center Energy Profiler (DC Pro) Software Tool Suite and other resources can help U.S. companies identify ways to improve the efficiency of their data centers.

  13. Oxygen analyzer

    DOEpatents

    Benner, William H.

    1986-01-01

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  14. Oxygen analyzer

    DOEpatents

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  15. AgPro | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: AgPro Place: Massena, New York Product: Operator of biodiesel plant based on soy. References: AgPro1 This article is a stub. You can help OpenEI...

  16. Si Pro AS | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Pro AS Jump to: navigation, search Name: Si Pro AS Place: Glomfjord, Norway Zip: 8161 Product: Silicon recycler with facility in Singapore. Coordinates: 66.807991, 13.97315...

  17. PIA - Savannah River Nuclear Solution SRNS ProRad Environment...

    Office of Environmental Management (EM)

    SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management ...

  18. Collateral Duties for Program Records Official (PRO) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Program Records Official (PRO) Collateral Duties for Program Records Official (PRO) GUIDANCE - Collateral Duties for PRO FINAL 141224.pdf (222.88 KB) More Documents & Publications ...

  19. ProPortal: A Database for Prochlorococcus

    DOE Data Explorer

    Huang, Katherine [Chisholm lab, MIT

    Prochlorococcus is a marine cyanobacterium that numerically dominates the mid-latitude oceans, and is the smallest known oxygenic phototroph. All isolates described thus far can be assigned to either a tightly clustered high-light (HL) adapted clade, or a more divergent low-light (LL) adapted group. They are closely related to, but distinct from, marine Synechococcus. The genomes of 12 strains have been sequenced and they range in size from 1.6 to 2.6 Mbp. They represent diverse lineages, spanning the rRNA diversity (97 to 99.93% similarity) of cultured representatives of this group. Our analyses of these genomes inform our understanding of how adaptation occurs in the oceans along gradients of light, nutrients, and other environmental factors, providing essential context for interpreting rapidly expanding metagenomic datasets. [Copied from http://proportal.mit.edu/project/prochlorococcus/] ProPortal allows users to browse and search genome date for not only Prochlorococcus, but Cyanophage and Synechococcus. Microarray data, environmental cell concentration data, and metagenome information are also available.

  20. Pro Corn LLC | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Pro-Corn LLC Place: Preston, Minnesota Zip: 55965 Product: Minnesotan farmer owned bioethanol production company. Coordinates: 47.526531, -121.936019 Show Map Loading map......

  1. Pro Ventum International | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: Pro Ventum International Place: Forchheim, Germany Zip: 79362 Sector: Wind energy Product: German-based developer of wind power...

  2. ProEco Energy | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Place: South Dakota Product: US South Dakota-based company specializing ethanol refinery project development. References: ProEco Energy1 This article is a stub. You can...

  3. Win pro energy group | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    energy group Place: Berlin, Berlin, Germany Zip: 12165 Sector: Renewable Energy, Solar, Wind energy Product: Win:pro offers location search, development, implementation,...

  4. ProForm | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Spreadsheet ComplexityEase of Use: Simple Website: poet.lbl.govProform Cost: Free References: ProForm1 Related Tools General Equilibrium Modeling Package (GEMPACK)...

  5. ProLogis | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Name: ProLogis Place: Aurora, Colorado Zip: 80011 Sector: Services Product: Provider of distribution facilities and services. Coordinates: 39.325162, -79.54975 Show Map...

  6. BERLinPro Booster Cavity Design, Fabrication and Test Plans ...

    Office of Scientific and Technical Information (OSTI)

    BERLinPro Booster Cavity Design, Fabrication and Test Plans Citation Details In-Document Search Title: BERLinPro Booster Cavity Design, Fabrication and Test Plans The bERLinPro ...

  7. ProLogis France IX EURL | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ProLogis France IX EURL Jump to: navigation, search Name: ProLogis France IX EURL Place: Aulnay-Sous-Bois Cedex, France Zip: 93614 Product: French subsidiary of ProLogis, a...

  8. EA-155 ProMark | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-155 ProMark Order authorizing ProMark Energy, Inc to export electric energy to Canada. EA-155 ProMark (46.89 KB) More Documents & Publications EA-196-A Minnesota Power, Sales ...

  9. Pro Sol Energia SA | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Sol Energia SA Jump to: navigation, search Name: Pro Sol Energia SA Place: Algarrobo-Costa (Malaga), Spain Zip: E-29750 Sector: Solar Product: Develops and builds solar power...

  10. Thermodynamic assessment of the Pr-O system

    SciTech Connect

    McMurray, Jake W.

    2015-12-24

    We found that the Calphad method was used to perform a thermodynamic assessment of the Pr–O system. Compound energy formalism representations were developed for the fluorite α-PrO 2–x and bixbyite σ-Pr 3 O 5 ± x solid solutions while the two-sublattice liquid model was used to describe the binary melt. The series of phases between Pr 2 O 3 and PrO 2 were taken to be stoichiometric. Moreover, the equilibrium oxygen pressure, phase equilibria, and enthalpy data were used to optimize the adjustable parameters of the models for a self-consistent representation of the thermodynamic behavior of the Pr–O system from 298 K to melting.

  11. Thermodynamic assessment of the Pr-O system

    DOE PAGES [OSTI]

    McMurray, Jake W.

    2015-12-24

    We found that the Calphad method was used to perform a thermodynamic assessment of the Pr–O system. Compound energy formalism representations were developed for the fluorite α-PrO 2–x and bixbyite σ-Pr 3 O 5 ± x solid solutions while the two-sublattice liquid model was used to describe the binary melt. The series of phases between Pr 2 O 3 and PrO 2 were taken to be stoichiometric. Moreover, the equilibrium oxygen pressure, phase equilibria, and enthalpy data were used to optimize the adjustable parameters of the models for a self-consistent representation of the thermodynamic behavior of the Pr–O system frommore » 298 K to melting.« less

  12. Home Performance Contractor Pro Forma | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Home Performance Contractor Pro Forma, with program HR, assumptions, marketing actuals and costs, and more, as posted on the U.S. Department of Energy's Better Buildings Neighborhood Program website. Home Performance Contractor Pro Forma (1.18 MB

  13. Artificial oxygen transport protein

    DOEpatents

    Dutton, P. Leslie

    2014-09-30

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  14. Cryogenic system for BERLinPro

    SciTech Connect

    Anders, W.; Hellwig, A.; Knobloch, J.; Pflückhahn, D.; Rotterdam, S.

    2014-01-29

    In 2010 Helmholtz-Zentrum Berlin (HZB) received funding to design and build the Berlin Energy Recovery Linac Project BERLinPro. The goal of this compact Energy recovery linac (ERL) is to develop the accelerator physics and technology required to generate and accelerate a 100-mA, 1-mm mrad emittance electron beam. The BERLinPro know-how can then be transferred to various ERL-based applications. All accelerating RF cavities including the electron source are based on superconducting technology operated at 1.8 K. A Linde L700 helium liquefier is supplying 4.5 K helium. The subatmospheric pressure of 16 mbar of the helium bath of the cavities will be achieved by pumping with a set of cold compressors and warm vacuum pumps. While the L700 is already in operating, the 1.8 K system and the helium transfer system are in design phase.

  15. HyPro: Modeling the Hydrogen Transition

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    HyPro: Modeling the H 2 Transition Brian James Directed Technologies, Inc. 9 May 2007 This presentation does not contain any proprietary, confidential, or otherwise restricted information Directed Technologies, Inc. 09 May 2007 2 Outline Model Overview Results Summary Cost & Methodology Assumptions Directed Technologies, Inc. 09 May 2007 3 Project Objectives Overall Create a tool robust enough to test the impact of different assumptions on the development of hydrogen infrastructure and

  16. Perl Embedded in PTC's Pro/ENGINEER, Version 1

    Energy Science and Technology Software Center

    2003-12-22

    Pro-PERL (AKA Pro/PERL) is a Perl extension to the PTC Pro/TOOLKIT API to the PTC Pro/ENGINEER CAD application including an embedded interpreter. It can be used to automate and customize Pro/ENGINEER, create Vendor Neutral Archive (VNA) format files and re-create CAD models from the VNA files. This has applications in sanitizing classified CAD models created in a classified environment for transfer to an open environment, creating template models for modification to finished models by non-expertmore » users, and transfer of design intent data to other modeling technologies.« less

  17. Solid state oxygen sensor

    DOEpatents

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  18. Solid state oxygen sensor

    DOEpatents

    Garzon, Fernando H.; Chung, Brandon W.; Raistrick, Ian D.; Brosha, Eric L.

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  19. Solid state oxygen sensor

    DOEpatents

    Garzon, Fernando H.; Brosha, Eric L.

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  20. Oxygen partial pressure sensor

    DOEpatents

    Dees, D.W.

    1994-09-06

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  1. Oxygen partial pressure sensor

    DOEpatents

    Dees, Dennis W.

    1994-01-01

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured.

  2. Pro Solar Solarstrom GmbH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    GmbH Jump to: navigation, search Name: Pro Solar Solarstrom GmbH Place: Ravensburg, Germany Zip: 88214 Sector: Solar Product: Distributor of PV modules, including Canadian...

  3. Home Performance Contractor Pro Forma | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Home Performance Contractor Pro Forma, with program HR, assumptions, marketing actuals and costs, and more, as posted on the U.S. Department of Energy's Better Buildings ...

  4. SolarPro Energy International | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Place: Granite Bay, California Zip: 95746 Sector: Solar Product: SolarPro Energy installs solar power systems using PV panels for residential and commercial properties. References:...

  5. A Variational Pro jection Operator for Mapping of Internal Variables...

    Office of Scientific and Technical Information (OSTI)

    Title: A Variational Pro jection Operator for Mapping of Internal Variables. Authors: Mota, Alejandro ; Sun, WaiChing ; Ostien, Jakob ; Foulk, James W., III ; Long, Kevin...

  6. BatPRO: Battery Manufacturing Cost Estimation | Argonne National Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    BatPRO: Battery Manufacturing Cost Estimation BatPRO models a stiff prismatic pouch-type cell battery pack with cells linked in series. BatPRO models a stiff prismatic pouch-type cell battery pack with cells linked in series. BatPRO is the user-friendly, Windows-based version of BatPaC, a software modeling tool designed for policymakers and researchers who are interested in estimating the cost of lithium-ion batteries after they have reached a mature state of development and are being

  7. Integrated turbomachine oxygen plant

    SciTech Connect

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  8. Oxygen ion conducting materials

    DOEpatents

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  9. Oxygen ion conducting materials

    DOEpatents

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  10. Oxygen ion conducting materials

    DOEpatents

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  11. Oxygen-Enriched Combustion

    Energy.gov [DOE]

    This tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency.

  12. Solid state oxygen sensor

    DOEpatents

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  13. Pro Isomerization in MLL1 PHD3-Bromo Cassette Connects H3K4me...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Pro ... Citation Details In-Document Search Title: Pro Isomerization ... Here, we report on structure-function studies that elucidate ...

  14. High Selectivity Oxygen Delignification

    SciTech Connect

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  15. Pro2 Anlagentechnik GmbH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zip: 47877 Product: Pro2 delivers turn-key plants for utilisation of biogas, sewage, natural gas and landfill gas in the range from 100 to 3,600 kWe. Coordinates: 51.26439,...

  16. Home Performance Contractor Pro Forma | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Excel sheet for program model, expenses, HR, and marketing, as posted on the U.S. Department of Energy's Better Buildings Neighborhood Program website. Home Performance Contractor Pro Forma (1022.61 KB

  17. Pennsylvania's Comprehensive, Statewide, Pro-Active Industrial Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Efficiency (E2) Program | Department of Energy Pennsylvania's Comprehensive, Statewide, Pro-Active Industrial Energy Efficiency (E2) Program Pennsylvania's Comprehensive, Statewide, Pro-Active Industrial Energy Efficiency (E2) Program Pennsylvania The U.S. Department of Energy's (DOE's) Advanced Manufacturing Office (AMO; formerly the Industrial Technologies Program) has developed multiple resources and a best practices suite of tools to help industrial manufacturers reduce their energy

  18. Optical oxygen concentration monitor

    DOEpatents

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  19. Monolithic solid electrolyte oxygen pump

    DOEpatents

    Fee, Darrell C.; Poeppel, Roger B.; Easler, Timothy E.; Dees, Dennis W.

    1989-01-01

    A multi-layer oxygen pump having a one-piece, monolithic ceramic structure affords high oxygen production per unit weight and volume and is thus particularly adapted for use as a portable oxygen supply. The oxygen pump is comprised of a large number of small cells on the order of 1-2 millimeters in diameter which form the walls of the pump and which are comprised of thin, i.e., 25-50 micrometers, ceramic layers of cell components. The cell components include an air electrode, an oxygen electrode, an electrolyte and interconnection materials. The cell walls form the passages for input air and for exhausting the oxygen which is transferred from a relatively dilute gaseous mixture to a higher concentration by applying a DC voltage across the electrodes so as to ionize the oxygen at the air electrode, whereupon the ionized oxygen travels through the electrolyte and is converted to oxygen gas at the oxygen electrode.

  20. GeoPro: Technology to Enable Scientific Modeling

    SciTech Connect

    C. Juan

    2004-02-09

    Development of the ground-water flow model for the Death Valley Regional Groundwater Flow System (DVRFS) required integration of numerous supporting hydrogeologic investigations. The results from recharge, discharge, hydraulic properties, water level, pumping, model boundaries, and geologic studies were integrated to develop the required conceptual and 3-D framework models, and the flow model itself. To support the complex modeling process and the needs of the multidisciplinary DVRFS team, a hardware and software system called GeoPro (Geoscience Knowledge Integration Protocol) was developed. A primary function of GeoPro is to manage the large volume of disparate data compiled for the 100,000-square-kilometer area of southern Nevada and California. The data are primarily from previous investigations and regional flow models developed for the Nevada Test Site and Yucca Mountain projects. GeoPro utilizes relational database technology (Microsoft SQL Server{trademark}) to store and manage these tabular point data, groundwater flow model ASCII data, 3-D hydrogeologic framework data, 2-D and 2.5-D GIS data, and text documents. Data management consists of versioning, tracking, and reporting data changes as multiple users access the centralized database. GeoPro also supports the modeling process by automating the routine data transformations required to integrate project software. This automation is also crucial to streamlining pre- and post-processing of model data during model calibration. Another function of GeoPro is to facilitate the dissemination and use of the model data and results through web-based documents by linking and allowing access to the underlying database and analysis tools. The intent is to convey to end-users the complex flow model product in a manner that is simple, flexible, and relevant to their needs. GeoPro is evolving from a prototype system to a production-level product. Currently the DVRFS pre- and post-processing modeling tools are being re

  1. Optical oxygen concentration monitor

    DOEpatents

    Kebabian, Paul

    1997-01-01

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  2. High pressure oxygen furnace

    DOEpatents

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  3. High pressure oxygen furnace

    DOEpatents

    Morris, Donald E.

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  4. Fuel cell oxygen electrode

    DOEpatents

    Shanks, H.R.; Bevolo, A.J.; Danielson, G.C.; Weber, M.F.

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A/sub x/WO/sub 3/ where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt/sub y/WO/sub 3/ where y is at least 0.8.

  5. Fuel cell oxygen electrode

    DOEpatents

    Shanks, Howard R.; Bevolo, Albert J.; Danielson, Gordon C.; Weber, Michael F.

    1980-11-04

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

  6. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  7. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  8. MEMS Pro Design Kit - Parts A, B, and C

    Energy Science and Technology Software Center

    2006-06-15

    Part A: SUMMiT V design Kit components for use with MEMS Pro from SoftMEMS Part B: SUMMiT V remote DRC and gear generator source code for use with autocad visual basic Part C: SUMMiT V DRC rules source and test cases for Calibre DRC engine

  9. Oxygen Transport Membranes

    SciTech Connect

    S. Bandopadhyay

    2008-08-30

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the

  10. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients

  11. VWA-0015- In the Matter of Am-Pro Protective Services, Inc.

    Office of Energy Efficiency and Renewable Energy (EERE)

    This Initial Agency Decision concerns a whistleblower complaint filed by Barry Stutts, a former security officer for Am-Pro Protective Services, Inc. (Am-Pro). It is undisputed that: Mr. Stutts and...

  12. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  13. Composite oxygen transport membrane

    DOEpatents

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  14. High Selectivity Oxygen Delignification

    SciTech Connect

    Arthur J. Ragauskas Lucian A. Lucia Hasan Jameel

    2005-09-30

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in

  15. PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management (3.45 MB) More Documents & Publications PIA - Savannah River Nuclear Solutions (SRNS) Human Resource Management System (HRMS) PIA - Savannah River Nuclear Solution (SRNS) Procurement Cycle System (PCS) PIA - Savannah

  16. Researchers Directly Observe Oxygen Signature in the Oxygen-evolving

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Complex of Photosynthesis Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the

  17. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report

  18. Oxygenates from synthesis gas

    SciTech Connect

    Falter, W.; Keim, W.

    1994-12-31

    The direct synthesis of oxygenates starting from synthesis gas is feasible by homogeneous and heterogeneous catalysis. Homogeneous Rh and Ru based catalysts yielding methyl formate and alcohols will be presented. Interestingly, modified heterogeneous catalysts based on {open_quotes}Isobutyl Oel{close_quotes} catalysis, practized in Germany (BRD) up to 1952 and in the former DDR until recently, yield isobutanol in addition to methanol. These {open_quotes}Isobutyl Oel{close_quotes} catalysts are obtained by adding a base such as Li < Na < K < Cs to a Zn-Cr{sub 2}O{sub 3} methanol catalyst. Isobutanol is obtained in up to 15% yield. Our best catalyst a Zr-Zn-Mn-Li-Pd catalyst produced isobotanol up to 60% at a rate of 740g isobutanol per liter catalyst and hour.

  19. Oxygen-reducing catalyst layer

    DOEpatents

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; Yang, Ruizhi; Easton, E. Bradley; Dahn, Jeffrey R.; O'Neill, David G.

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  20. EIA-819, Monthly Oxygenate Report ...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    (EIA) Form EIA-819, "Monthly Biofuel and Oxygenate Report," is used to collect data on ethanol production capacity, as well as stocks, receipts, inputs, production, and blending of...

  1. Oxygenate Supply/Demand Balances

    Annual Energy Outlook

    Related EIA Short-Term Forecast Analysis Products * ... and Price Outlook for Reformulated Motor Gasoline, 1995 Introduction The blending of oxygenates, such as fuel ethanol ...

  2. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-10-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  3. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

  4. Oxygen detection using evanescent fields

    DOEpatents

    Duan, Yixiang; Cao, Weenqing

    2007-08-28

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  5. Rotation Manager Pro Version 1.0b1

    Energy Science and Technology Software Center

    2002-02-01

    The Rotation Manager Pro Package maintains databases of instructions to replicate plate tectonic movements. The instructions are in the standard of tectonic plate rotations, including plate identification and location and angle of the rotation pole. Each database is accompanied by various metadata, including information about each rotation pole and the database itself. The package provides a range of tools to actively manage the database using methods specifically required for rotations: rotation pole addition and subtraction,more » viewing of a rotation chain through the rotation hierarchy, and the rotation of data points.« less

  6. Mixed oxygen ion/electron-conducting ceramics for oxygen separation

    SciTech Connect

    Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

    1995-05-01

    Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

  7. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-11-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

  8. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  9. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

    2003-11-01

    The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with

  10. A lithium oxygen secondary battery

    SciTech Connect

    Semkow, K.W.; Sammells, A.F.

    1987-08-01

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  11. V-210: HP LaserJet Pro Printer Bug Lets Remote Users Access Data

    Energy.gov [DOE]

    A potential security vulnerability has been identified with certain HP LaserJet Pro printers. The vulnerability could be exploited remotely to gain unauthorized access to data.

  12. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01

    the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  13. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19, ...

  14. Oxygen Transport Ceramic Membranes

    SciTech Connect

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-05-01

    been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  15. EVALUATING AN INNOVATIVE OXYGEN SENSOR FOR REMOTE SUBSURFACE OXYGEN MEASUREMENTS

    SciTech Connect

    Millings, M; Brian Riha, B; Warren Hyde, W; Karen Vangelas, K; Brian02 Looney, B

    2006-10-12

    Oxygen is a primary indicator of whether anaerobic reductive dechlorination and similar redox based processes contribute to natural attenuation remedies at chlorinated solvent contaminated sites. Thus, oxygen is a viable indicator parameter for documenting that a system is being sustained in an anaerobic condition. A team of researchers investigated the adaptation of an optical sensor that was developed for oceanographic applications. The optical sensor, because of its design and operating principle, has potential for extended deployment and sensitivity at the low oxygen levels relevant to natural attenuation. The results of the research indicate this tool will be useful for in situ long-term monitoring applications, but that the traditional characterization tools continue to be appropriate for characterization activities.

  16. BERLinPro Booster Cavity Design, Fabrication and Test Plans

    SciTech Connect

    Burrill, Andrew; Anders, W; Frahm, A.; Knobloch, Jens; Neumann, Axel; Ciovati, Gianluigi; Kneisel, Peter K.; Turlington, Larry D.

    2014-12-01

    The bERLinPro project, a 100 mA, 50 MeV superconducting RF (SRF) Energy Recovery Linac (ERL) is under construction at Helmholtz-Zentrum Berlin for the purpose of studying the technical challenges and physics of operating a high current, c.w., 1.3 GHz ERL. This machine will utilize three unique SRF cryomodules for the injector, booster and linac module respectively. The booster cryomodule will contain three 2-cell SRF cavities, based on the original design by Cornell University, and will be equipped with twin 115 kW RF power couplers in order to provide the appropriate acceleration to the high current electron beam. This paper will review the status of the fabrication of the 4 booster cavities that have been built for this project by Jefferson Laboratory and look at the challenges presented by the incorporation of fundamental power couplers capable of delivering 115 kW. The test plan for the cavities and couplers will be given along with a brief overview of the cryomodule design.

  17. Methods for separating oxygen from oxygen-containing gases

    DOEpatents

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  18. Catalyst containing oxygen transport membrane

    DOEpatents

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  19. Composite oxygen ion transport element

    DOEpatents

    Chen, Jack C.; Besecker, Charles J.; Chen, Hancun; Robinson, Earil T.

    2007-06-12

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  20. DC Pro Software Tool Suite, Data Center Fact Sheet, Industrial Technologies Program

    SciTech Connect

    Not Available

    2009-04-01

    This fact sheet describes how DOE's Data Center Energy Profiler (DC Pro) Software Tool Suite and other resources can help U.S. companies identify ways to improve the efficiency of their data centers.

  1. VWA-0015- Deputy Secretary Decision- In the Matter of Am-Pro Protective Services, Inc.

    Energy.gov [DOE]

    Barry Stutts, Complainant v. Am-Pro Protective Agency, Inc., Respondent, OHA Case No. VWA-0015 DECISION DENYING REVIEW OF INITIAL AGENCY DECISION This is a request for review by Complainant Barry...

  2. ProForce marks 65 years protecting Sandia resources, facilities, people |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) ProForce marks 65 years protecting Sandia resources, facilities, people Monday, October 26, 2015 - 12:00am NNSA Blog Current and former members of the Lab's Protective Force gathered to reflect on and recognize the contributions ProForce has made to securing Sandia National Laboratory's resources, facilities, and people. Over the past 65 years, the force has changed in size and structure but its mission has remained the same: To ensure the

  3. Oxygen permeation and coal-gas-assisted hydrogen production using...

    Office of Scientific and Technical Information (OSTI)

    Oxygen permeation and coal-gas-assisted hydrogen production using oxygen transport membranes Citation Details In-Document Search Title: Oxygen permeation and coal-gas-assisted ...

  4. The mechanisms of oxygen reduction and evolution reactions in...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    and evolution reactions in nonaqueous lithium-oxygen batteries A mechanistic understanding of the oxygen reductionevolution reaction in non-aqueous lithium-oxygen batteries. ...

  5. Single-Column Modeling R. D. Cess Marine Sciences Research Center

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    by dry-plains agricultural land typical of the adjoining several hundred square kilometers ranging to the east (Cessetal. 1991). These insolation measurements are provided as...

  6. Cancer Associated Fibroblasts express pro-inflammatory factors in human breast and ovarian tumors

    SciTech Connect

    Erez, Neta; Glanz, Sarah; Raz, Yael; Avivi, Camilla; Barshack, Iris

    2013-08-02

    Highlights: •CAFs in human breast and ovarian tumors express pro-inflammatory factors. •Expression of pro-inflammatory factors correlates with tumor invasiveness. •Expression of pro-inflammatory factors is associated with NF-κb activation in CAFs. -- Abstract: Inflammation has been established in recent years as a hallmark of cancer. Cancer Associated Fibroblasts (CAFs) support tumorigenesis by stimulating angiogenesis, cancer cell proliferation and invasion. We previously demonstrated that CAFs also mediate tumor-enhancing inflammation in a mouse model of skin carcinoma. Breast and ovarian carcinomas are amongst the leading causes of cancer-related mortality in women and cancer-related inflammation is linked with both these tumor types. However, the role of CAFs in mediating inflammation in these malignancies remains obscure. Here we show that CAFs in human breast and ovarian tumors express high levels of the pro-inflammatory factors IL-6, COX-2 and CXCL1, previously identified to be part of a CAF pro-inflammatory gene signature. Moreover, we show that both pro-inflammatory signaling by CAFs and leukocyte infiltration of tumors are enhanced in invasive ductal carcinoma as compared with ductal carcinoma in situ. The pro-inflammatory genes expressed by CAFs are known NF-κB targets and we show that NF-κB is up-regulated in breast and ovarian CAFs. Our data imply that CAFs mediate tumor-promoting inflammation in human breast and ovarian tumors and thus may be an attractive target for stromal-directed therapeutics.

  7. Oxygen ion-beam microlithography

    DOEpatents

    Tsuo, Y. Simon

    1991-01-01

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  8. Oxygen ion-beam microlithography

    DOEpatents

    Tsuo, Y.S.

    1991-08-20

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  9. Device and method for separating oxygen isotopes

    DOEpatents

    Rockwood, Stephen D.; Sander, Robert K.

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  10. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    High-Stability-Low-Cost Supports | Department of Energy Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 adzic_bnl_kickoff.pdf (4.62 MB) More Documents & Publications Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

  11. Oxygen electrocatalysis on (001)-oriented manganese perovskite...

    Office of Scientific and Technical Information (OSTI)

    the nanoscale Citation Details In-Document Search Title: Oxygen electrocatalysis on (001)-oriented manganese perovskite films: Mn valency and charge transfer at the nanoscale ...

  12. Jupiter Oxygen Corporation | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Place: Schiller Park, Illinois Zip: 60176 Product: Illinois-based oxy-fuel combustion company involved in the capture of CO2. References: Jupiter Oxygen Corporation1...

  13. Homogeneously dispersed, multimetal oxygen-evolving catalysts...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Homogeneously dispersed, multimetal oxygen-evolving catalysts Citation ... Publication Date: 2016-03-24 OSTI Identifier: 1245398 Report ...

  14. DEVICE FOR CONTROL OF OXYGEN PARTIAL PRESSURE

    DOEpatents

    Bradner, H.; Gordon, H.S.

    1957-12-24

    A device is described that can sense changes in oxygen partial pressure and cause a corresponding mechanical displacement sufficient to actuate meters, valves and similar devices. A piston and cylinder arrangement contains a charge of crystalline metal chelate pellets which have the peculiar property of responding to variations in the oxygen content of the ambient atmosphere by undergoing a change in dimension. A lever system amplifies the relative displacement of the piston in the cylinder, and actuates the controlled valving device. This partial pressure oxygen sensing device is useful in controlled chemical reactions or in respiratory devices such as the oxygen demand meters for high altitude aircraft.

  15. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    More Documents & Publications Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Advanced Materials and Concepts for Portable Power Fuel Cells Catalysis Working ...

  16. Identification of an Archean marine oxygen oasis

    SciTech Connect

    Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

    2014-01-01

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  17. Sandia National Laboratories: News: Publications: Lab News

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    properties. Looking ahead The researchers want the model to handle both forging and welding because in some ways the two pro-cesses work against one another. Forging steel gives...

  18. Structure of RheniumContaining Sodium Borosilicate Glass

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    not problem- atic in evaporation and drying processes but does creates trouble in high temperature molten glass pro- cessing from either liquid or dried feed. 2 Other sources of 99...

  19. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  20. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  1. Oxygen ion-conducting dense ceramic

    DOEpatents

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1996-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  2. Oxygen ion-conducting dense ceramic

    DOEpatents

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1997-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  3. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this

  4. Selective photooxidation of hydrocarbons in zeolites by oxygen

    DOEpatents

    Frei, Heinz; Blatter, Fritz; Sun, Hai

    1998-01-01

    A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

  5. Microstructure design for fast oxygen conduction

    DOE PAGES [OSTI]

    Aidhy, Dilpuneet S.; Weber, William J.

    2015-11-11

    Research from the last decade has shown that in designing fast oxygen conducting materials for electrochemical applications has largely shifted to microstructural features, in contrast to material-bulk. In particular, understanding oxygen energetics in heterointerface materials is currently at the forefront, where interfacial tensile strain is being considered as the key parameter in lowering oxygen migration barriers. Nanocrystalline materials with high densities of grain boundaries have also gathered interest that could possibly allow leverage over excess volume at grain boundaries, providing fast oxygen diffusion channels similar to those previously observed in metals. In addition, near-interface phase transformations and misfit dislocations aremore » other microstructural phenomenon/features that are being explored to provide faster diffusion. In this review, the current understanding on oxygen energetics, i.e., thermodynamics and kinetics, originating from these microstructural features is discussed. Moreover, our experimental observations, theoretical predictions and novel atomistic mechanisms relevant to oxygen transport are highlighted. In addition, the interaction of dopants with oxygen vacancies in the presence of these new microstructural features, and their future role in the design of future fast-ion conductors, is outlined.« less

  6. A mutation in the mitochondrial protein UQCRB promotes angiogenesis through the generation of mitochondrial reactive oxygen species

    SciTech Connect

    Chang, Junghwa; Jung, Hye Jin; Jeong, Seung Hun; Kim, Hyoung Kyu; Han, Jin; Kwon, Ho Jeong

    2014-12-12

    Highlights: • We constructed mitochondrial protein UQCRB mutant stable cell lines on the basis of a human case report. • These mutant cell lines exhibit pro-angiogenic activity with enhanced VEGF expression. • Proliferation of mutant cell lines was regulated by UQCRB inhibitors. • UQCRB may have a functional role in angiogenesis. - Abstract: Ubiquinol-cytochrome c reductase binding protein (UQCRB) is one of the subunits of mitochondrial complex III and is a target protein of the natural anti-angiogenic small molecule terpestacin. Previously, the biological role of UQCRB was thought to be limited to the maintenance of complex III. However, the identification and validation of UQCRB as a target protein of terpestacin enabled the role of UQCRB in oxygen sensing and angiogenesis to be elucidated. To explore the biological role of this protein further, UQCRB mutant stable cell lines were generated on the basis of a human case report. We demonstrated that these cell lines exhibited glycolytic and pro-angiogenic activities via mitochondrial reactive oxygen species (mROS)-mediated HIF1 signal transduction. Furthermore, a morphological abnormality in mitochondria was detected in UQCRB mutant stable cell lines. In addition, the proliferative effect of the UQCRB mutants was significantly regulated by the UQCRB inhibitors terpestacin and A1938. Collectively, these results provide a molecular basis for UQCRB-related biological processes and reveal potential key roles of UQCRB in angiogenesis and mitochondria-mediated metabolic disorders.

  7. Petrochemical feedstock from basic oxygen steel furnace

    SciTech Connect

    Greenwood, C.W.; Hardwick, W.E.

    1983-10-01

    Iron bath gasification in which coal, lime, steam and oxygen are injected into a bath of molten iron for the production of a medium-Btu gas is described. The process has its origin in basic oxygen steelmaking. It operates at high temperatures and is thus not restrictive on the type of coal used. The ash is retained in the slag. The process is also very efficient. The authors suggest that in the present economic climate in the iron and steel industry, such a plant could be sited where existing coal-handling, oxygen and steelmaking equipment are available.

  8. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  9. Oxygen ion-conducting dense ceramic

    DOEpatents

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1998-01-01

    Preparation, structure, and properties of mixed metal oxide compositions and their uses are described. Mixed metal oxide compositions of the invention have stratified crystalline structure identifiable by means of powder X-ray diffraction patterns. In the form of dense ceramic membranes, the present compositions demonstrate an ability to separate oxygen selectively from a gaseous mixture containing oxygen and one or more other volatile components by means of ionic conductivities.

  10. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-01-01

    This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

  11. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

  12. Magnetism in LithiumOxygen Discharge Product

    SciTech Connect

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13

    Nonaqueous lithiumoxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithiumoxygen batteries. We demonstrate that the major discharge product formed in the lithiumoxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  13. Facile oxygen intercalation between full layer graphene and Ru...

    Office of Scientific and Technical Information (OSTI)

    Facile oxygen intercalation between full layer graphene and Ru(0001) under ambient ... Title: Facile oxygen intercalation between full layer graphene and Ru(0001) under ambient ...

  14. Webinar: Testing Oxygen Reduction Reaction Activity with the...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Above is the video recording for the webinar, "Testing Oxygen Reduction Reaction ...

  15. Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite...

    Office of Scientific and Technical Information (OSTI)

    Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films Citation Details In-Document Search Title: Strain Control of Oxygen Vacancies in Epitaxial Strontium ...

  16. Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency & ...

  17. Pt3Re alloy nanoparticles as electrocatalysts for the oxygen...

    Office of Scientific and Technical Information (OSTI)

    Pt3Re alloy nanoparticles as electrocatalysts for the oxygen reduction reaction Citation ... on March 24, 2018 Title: Pt3Re alloy nanoparticles as electrocatalysts for the oxygen ...

  18. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers ... technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for ...

  19. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for ...

  20. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    OpenEI (Open Energy Information) [EERE & EIA]

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  1. Artificial oxygen transport protein (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Artificial oxygen transport protein Citation Details In-Document Search Title: Artificial oxygen transport protein This invention provides heme-containing peptides capable...

  2. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-07-01

    Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance

  3. Direct Observation of the Oxygenated Species during Oxygen Reduction on a

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Platinum Fuel Cell Cathode | Stanford Synchrotron Radiation Lightsource Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell

  4. Oxygen generator for medical applications (USIC)

    SciTech Connect

    Staiger, C. L.

    2012-03-01

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible

  5. HyPro: A Financial Tool for Simulating Hydrogen Infrastructure Development, Final Report

    SciTech Connect

    Brian D. James, Peter O. Schmidt, Julie Perez

    2008-12-01

    This report summarizes a multi-year Directed Technologies Inc. (DTI) project to study the build-out of hydrogen production facilities during the transition from gasoline internal combustion engine vehicle to hydrogen fuel cell vehicles. The primary objectives of the project are to develop an enhanced understanding of hydrogen production issues during the transition period (out to 2050) and to develop recommendations for the DOE on areas of further study. These objectives are achieved by conducting economic and scenario analysis to predict how industry would provide the hydrogen production, delivery and dispensing capabilities necessary to satisfy increased hydrogen demand. The primary tool used for the analysis is a custom created MatLab simulation tool entitled HyPro (short for Hydrogen Production). This report describes the calculation methodology used in HyPro, the baseline assumptions, the results of the baseline analysis and several corollary studies. The appendices of this report included a complete listing of model assumptions (capital costs, efficiencies, feedstock prices, delivery distances, etc.) and a step-by-step manual on the specific operation of the HyPro program. This study was made possible with funding from the U.S. Department of Energy (DOE).

  6. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect

    Wolfe, R.

    1995-12-31

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  7. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-02-01

    This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

  8. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  9. Absorption process for producing oxygen and nitrogen and solution therefor

    DOEpatents

    Roman, I.C.; Baker, R.W.

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

  10. Absorption process for producing oxygen and nitrogen and solution therefor

    DOEpatents

    Roman, Ian C. [Wilmington, DE; Baker, Richard W. [Palo Alto, CA

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

  11. Absorption process for producing oxygen and nitrogen and solution therefor

    DOEpatents

    Roman, Ian C.

    1984-01-01

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

  12. Novel Membranes and Processes for Oxygen Enrichment

    SciTech Connect

    Lin, Haiqing

    2011-11-15

    The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a

  13. Oxygen reduction reaction: A framework for success

    DOE PAGES [OSTI]

    Allendorf, Mark D.

    2016-05-06

    Oxygen reduction at the cathode of fuel cells typically requires a platinum-based material to catalyse the reaction, but lower-cost, more stable catalysts are sought. Here, an intrinsically conductive metal–organic framework based on cheaper elements is shown to be a durable, structurally well-defined catalyst for this reaction.

  14. Ammonia producing engine utilizing oxygen separation

    DOEpatents

    Easley, Jr., William Lanier; Coleman, Gerald Nelson; Robel, Wade James

    2008-12-16

    A power system is provided having a power source, a first power source section with a first intake passage and a first exhaust passage, a second power source section with a second intake passage and a second exhaust passage, and an oxygen separator. The second intake passage may be fluidly isolated from the first intake passage.

  15. Oxygen-exchange Pathways in Aluminum Polyoxocations

    SciTech Connect

    Rustad, James R.; Loring, J. S.; Casey, William H.

    2004-07-15

    Using molecular dynamics simulations and electronic structure methods, we postulate a mechanism to explain the complicated reactivity trends that are observed for oxygen isotope exchange reactions between sites in aluminum polyoxocations of the E-Keggin type and bulk solution. Experimentally, the molecules have four nonequivalent oxygens that differ considerably in reactivity both within a molecule, and between molecules in the series: Al13, GaAl12, and GeAl12 [MO4Al12(OH)24(H2O)12 n*(aq); with M=Al(III) for Al13, n=7; M=Ga(III) for GaAl12, n=7; M=Ge(IV) for GeAl12, n=8]. We find that a partly dissociated, metastable intermediate molecule of expanded volume is necessary for exchange of both sets of u2-OH and that the steady-state concentration of this intermediate reflects the bond strengths between the central metal and the u4-O. Thus the central metal exerts extraordinary control over reactions at hydroxyl bridges, although these are three bonds away. This mechanism not only explains the reactivity trends for oxygen isotope exchange in u2-OH and u-OH2 sites in the E-Keggin aluminum molecules, but also explains the observation that the reactivities of minerals tend to reflect the presence of highly coordinated oxygens, such as the u4-O in boehmite, a-, and y-Al2O3 and their Fe(III) analogs. The partial dissociation of these highly coordinated oxygens, coupled with simultaneous activation and displacement of neighboring metal centers, may be a fundamental process by which metals atoms undergo ligand exchanges at mineral surfaces.

  16. Influence of Pro-Qura-generated Plans on Postimplant Dosimetric Quality: A Review of a Multi-Institutional Database

    SciTech Connect

    Allen, Zachariah |||; Merrick, Gregory S. ||| Grimm, Peter; Blasko, John; Sylvester, John; Butler, Wayne; Chaudry, Usman-Ul-Haq; Sitter, Michael |||

    2008-10-01

    The influence of Pro-Qura-generated plans vs. community-generated plans on postprostate brachytherapy dosimetric quality was compared. In the Pro-Qura database, 2933 postplans were evaluated from 57 institutions. A total of 1803 plans were generated by Pro-Qura and 1130 by community institutions. Iodine-125 ({sup 125}I) plans outnumbered Palladium 103 ({sup 103}Pd) plans by a ratio of 3:1. Postimplant dosimetry was performed in a standardized fashion by overlapping the preimplant ultrasound and the postimplant computed tomography (CT). In this analysis, adequacy was defined as a V{sub 100} > 80% and a D{sub 90} of 90% to 140% for both isotopes along with a V{sub 150} < 60% for {sup 125}I and < 75% for {sup 103}Pd. The mean postimplant V{sub 100} and D{sub 90} were 88.6% and 101.6% vs. 89.3% and 102.3% for Pro-Qura and community plans, respectively. When analyzed in terms of the first 8 sequence groups (10 patients/sequence group) for each institution, Pro-Qura planning resulted in less postimplant variability for V{sub 100} (86.2-89.5%) and for D{sub 90} (97.4-103.2%) while community-generated plans had greater V{sub 100} (85.3-91.2%) and D{sub 90} (95.9-105.2%) ranges. In terms of sequence groups, postimplant dosimetry was deemed 'too cool' in 11% to 30% of cases and 'too hot' in 12% to 27%. On average, no clinically significant postimplant dosimetric differences were discerned between Pro-Qura and community-based planning. However, substantially greater variability was identified in the community-based plan cohort. It is possible that the Pro-Qura plan and/or the routine postimplant dosimetric evaluation may have influenced dosimetric outcomes at community-based centers.

  17. Oxygen-producing inert anodes for SOM process

    SciTech Connect

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  18. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-10-01

    This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

  19. Excess Oxygen Defects in Layered Cuprates

    DOE R&D Accomplishments

    Lightfoot, P.; Pei, S. Y.; Jorgensen, J. D.; Manthiram, A.; Tang, X. X.; Goodenough, J. B.

    1990-09-01

    Neutron powder diffraction has been used to study the oxygen defect chemistry of two non-superconducting layered cuprates, La{sub 1. 25}Dy{sub 0.75}Cu{sub 3.75}F{sub 0.5}, having a T{sup {asterisk}}- related structure, and La{sub 1.85}Sr{sub 1.15}Cu{sub 2}O{sub 6.25}, having a structure related to that of the newly discovered double-layer superconductor La{sub 2-x}Sr{sub x}CaCu{sub 2}O{sub 6}. The role played by oxygen defects in determining the superconducting properties of layered cuprates is discussed.

  20. Electrical insulator assembly with oxygen permeation barrier

    DOEpatents

    Van Der Beck, Roland R.; Bond, James A.

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  1. Electrical insulator assembly with oxygen permeation barrier

    DOEpatents

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  2. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Radoslav Adzic Co-workers: Jia Wang, Miomir Vukmirovic, Kotaro Sasaki, Stoyan Bliznakov, Yun Cai, Yu Zhang, Kurian Kuttiyiel, Kuanping Gong, YongMan Choi, Ping Liu, Hideo Naohara 1 Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973 1 Toyota Motor Corporation, Susono, Japan Webinar June 19, 2012 Outline - Introduction on fuel cells, electrocatalysis, existing developments and remaining obstacles to

  3. A miniature inexpensive, oxygen sensing element

    SciTech Connect

    Arenz, R.W.

    1991-10-07

    An exhaustive study was conducted to determine the feasibility of Nernst-type oxygen sensors based on ceramics containing Bi{sub 2}O{sub 3}. The basic sensor design consisted of a ceramic sensing module sealed into a metal tube. The module accommodated an internal heater and thermocouple. Thermal-expansion-matched metals, adhesives, and seals were researched and developed, consistent with sequential firings during sensor assembly. Significant effort was devoted to heater design/testing and to materials' compatibility with Pt electrodes. A systematic approach was taken to develop all sensor components which led to several design modifications. Prototype sensors were constructed and exhaustively tested. It is concluded that development of Nerst-type oxygen sensors based on Bi{sub 2}O{sub 3} will require much further effort and application of specialized technologies. However, during the course of this 3-year program much progress was reported in the literature on amperometric-type oxygen sensors, and a minor effort was devoted here to this type of sensor based on Bi{sub 2}O{sub 3}. These studies were made on Bi{sub 2}O{sub 3}-based ceramic samples in a multilayer-capacitor-type geometry and amperometric-type oxygen sensing was demonstrated at very low temperatures ({approximately} 160{degree}C). A central advantage here is that these types of sensors can be mass-produced very inexpensively ({approximately} 20--50 cents per unit). Research is needed, however, to develop an optimum diffusion-limiting barrier coating. In summary, the original goals of this program were not achieved due to unforeseen problems with Bi{sub 2}O{sub 3}-based Nernst sensors. However, a miniature amperometric sensor base on Bi{sub 2}O{sub 3} was demonstrated in this program, and it is now seen that this latter sensor is far superior to the originally proposed Nernst sensor. 6 refs., 24 figs.

  4. Oxygen stabilized zirconium vanadium intermetallic compound

    DOEpatents

    Mendelsohn, Marshall H.; Gruen, Dieter M.

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  5. Hydrogen (H2) Production by Oxygenic Phototrophs

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical

  6. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

  7. DME-to-oxygenates process studies

    SciTech Connect

    Tartamella, T.L.; Sardesai, A.; Lee, S.; Kulik, C.J.

    1994-12-31

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  8. Oxygen Catalysis: The Other Half of the Equation

    SciTech Connect

    Turner, J.

    2008-10-01

    Artificial photosynthesis--splitting water with light--is an attractive way to make hydrogen, but what happens to the oxygen? A catalyst that aids in the efficient production of gaseous oxygen improves the viability of this approach.

  9. Impact of interstitial oxygen on the electronic and magnetic...

    Office of Scientific and Technical Information (OSTI)

    interstitial oxygen on the electronic and magnetic structure in superconducting Fe 1 + y Te O x thin films Citation Details In-Document Search Title: Impact of interstitial oxygen...

  10. Oxygen-Enriched Combustion for Military Diesel Engine Generators

    Energy.gov [DOE]

    Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion

  11. Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films Citation Details In-Document Search Title: Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films The ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the

  12. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect

    Riley, M.F.

    2003-04-30

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations

  13. Chemical diffusion of oxygen in tin dioxide: Effects of dopants and oxygen partial pressure

    SciTech Connect

    Kamp, B.; Merkle, R. . E-mail: s.weiglein@fkf.mpg.de; Lauck, R.; Maier, J.

    2005-10-15

    Tin dioxide SnO{sub 2-{delta}} is a pronounced n-type electron conductor due to its oxygen deficiency. This study investigates the rate of chemical diffusion of oxygen in SnO{sub 2-{delta}} single crystals, which is a crucial step in the overall stoichiometry change of the material. The chemical diffusion coefficient D{sup {delta}} was determined from conductivity- and EPR-relaxation methods. The temperature dependence was found to be D{sup {delta}}=exp(-4+/-2)cm{sup 2}s{sup -1}exp(-(1.1+/-0.3)eV/kT). The dependence on crystal orientation, dopant content and oxygen partial pressure was below experimental error. The latter observation leads to the conclusion that the chemical diffusion coefficient is close to the diffusion coefficient of oxygen vacancies. Along with the relaxation process resulting from the chemical diffusion of oxygen, additional processes were observed. One of these was attributed to complications in the defect chemistry of the material. The relevance of the results for the kinetics of drift processes of Taguchi sensors is discussed.

  14. CHARACTERIZATION OF Pro-Beam LOW VOLTAGE ELECTRON BEAM WELDING MACHINE

    SciTech Connect

    Burgardt, Paul; Pierce, Stanley W.

    2015-02-18

    The purpose of this paper is to present and discuss data related to the performance of a newly acquired low voltage electron beam welding machine. The machine was made by Pro-Beam AG &Co. KGaA of Germany. This machine was recently installed at LANL in building SM -39; a companion machine was installed in the production facility. The PB machine is substantially different than the EBW machines typically used at LANL and therefore, it is important to understand its characteristics as well as possible. Our basic purpose in this paper is to present basic machine performance data and to compare those with similar results from the existing EBW machines. It is hoped that this data will provide a historical record of this machine’s characteristics as well as possibly being helpful for transferring welding processes from the old EBW machines to the PB machine or comparable machines that may be purchased in the future.

  15. Towards a 100mA Superconducting RF Photoinjector for BERLinPro

    SciTech Connect

    Neumann, Axel; Anders, W.; Burrill, Andrew; Jankowiak, Andreas; Kamps, T.; Knobloch, Jens; Kugeler, Oliver; Lauinger, P.; Matveenko, A.N.; Schmeisser, M.; Volker, J.; Ciovati, Gianluigi; Kneisel, Peter; Nietubyc, R.; Schubert, S.G.; Smedley, John; Sekutowicz, Jacek; Volkov, V.; Will, I.; Zaplatin, Evgeny

    2013-09-01

    For BERLinPro, a 100 mA CW-driven SRF energy recovery linac demonstrator facility, HZB needs to develop a photo-injector superconducting cavity which delivers a at least 1mm*mr emittance beam at high average current. To address these challenges of producing a high peak brightness beam at high repetition rate, at first HZB tested a fully superconducting injector with a lead cathode*,followed now by the design of a SC cavity allowing operation up to 4 mA using CW-modified TTF-III couplers and inserting a normal conducting high quantum efficiency cathode using the HZDR-style insert scheme. This talk will present the latest results and an overview of the measurements with the lead cathode cavity and will describe the design and optimization process, the first production results of the current design and an outlook to the further development steps towards the full power version.

  16. Mechanism of singlet oxygen deactivation in an electric discharge oxygen – iodine laser

    SciTech Connect

    Azyazov, V N; Mikheyev, P A; Torbin, A P; Pershin, A A; Heaven, M C

    2014-12-31

    We have determined the influence of the reaction of molecular singlet oxygen with a vibrationally excited ozone molecule O{sub 2}(a {sup 1}Δ) + O{sub 3}(ν) → 2O{sub 2} + O on the removal rate of O{sub 2}(a {sup 1}Δ) in an electric-discharge-driven oxygen – iodine laser. This reaction has been shown to be a major channel of O{sub 2}(a {sup 1}Δ) loss at the output of an electric-discharge singlet oxygen generator. In addition, it can also contribute significantly to the loss of O{sub 2}(a {sup 1}Δ) in the discharge region of the generator. (lasers)

  17. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE PAGES [OSTI]

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore » a new strategy of developing the catalyst for oxygen evolution reaction.« less

  18. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithiumoxygen batteries

    SciTech Connect

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  19. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    SciTech Connect

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  20. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltn; Horvth, Attila [Institute of Chemistry, Etvs Lornd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsr, Zoltn [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mssbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mssbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mssbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  1. Cathode architectures for alkali metal / oxygen batteries

    SciTech Connect

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  2. Oxygen stabilized zirconium-vanadium-iron alloy

    DOEpatents

    Mendelsohn, Marshall H.; Gruen, Dieter M.

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  3. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-01

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  4. Instabilities in a capacitively coupled oxygen plasma

    SciTech Connect

    Küllig, C. Wegner, Th. Meichsner, J.

    2015-04-15

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species (O{sub 2}{sup +}, e, O{sup −}, O{sub 2}{sup −}) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  5. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect

    Carter, J. D. Noble, J.

    2009-10-01

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily

  6. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

  7. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

  8. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable

  9. Efficiency evaluation of oxygen enrichment in energy conversion processes

    SciTech Connect

    Bomelburg, H.J.

    1983-12-01

    The extent to which energy conversion efficiencies can be increased by using oxygen or oxygen-enriched air for combustion was studied. Combustion of most fuels with oxygen instead of air was found to have five advantages: increases combustion temperature and efficiency, improves heat transfer at high temperatures, reduces nitrous oxide emissions, permits a high ration of exhaust gas recirculation and allows combustion of certain materials not combustible in air. The same advantages, although to a lesser degree, are apparent with oxygen-enriched air. The cost-effectiveness of the process must necessarily be improved by about 10% when using oxygen instead of air before such use could become justifiable on purely economic terms. Although such a modest increase appears to be attainable in real situations, this study ascertained that it is not possible to generally assess the economic gains. Rather, each case requires its own evaluation. For certain processes industry has already proven that the use of oxygen leads to more efficient plant operation. Several ideas for essentially new applications are described. Specifically, when oxygen is used with exhaust gas recirculation in external or internal combustion engines. It appears also that the advantages of pulse combustion can be amplified further if oxygen is used. When burning wet fuels with oxygen, direct steam generation becomes possible. Oxygen combustion could also improve processes for in situ gasification of coals, oil shales, peats, and other wet fuels. Enhanced oil recovery by fire flooding methods might also become more effective if oxygen is used. The cold energy contained in liquid oxygen can be substantially recovered in the low end of certain thermodynamic cycles. Further efforts to develop certain schemes for using oxygen for combustion appear to be justified from both the technical and economic viewpoints.

  10. Preliminary Study of Oxygen-Enhanced Longitudinal Relaxation in MRI: A Potential Novel Biomarker of Oxygenation Changes in Solid Tumors

    SciTech Connect

    O'Connor, James P.B.; Naish, Josephine H.; Parker, Geoff J.M.; Waterton, John C.; Watson, Yvonne; Jayson, Gordon C.; Buonaccorsi, Giovanni A.; Cheung, Sue; Buckley, David L.; McGrath, Deirdre M.; West, Catharine M.L.; Davidson, Susan E.; Roberts, Caleb; Mills, Samantha J.; Mitchell, Claire L.; Hope, Lynn; Ton, N. Chan; Jackson, Alan

    2009-11-15

    Purpose: There is considerable interest in developing non-invasive methods of mapping tumor hypoxia. Changes in tissue oxygen concentration produce proportional changes in the magnetic resonance imaging (MRI) longitudinal relaxation rate (R{sub 1}). This technique has been used previously to evaluate oxygen delivery to healthy tissues and is distinct from blood oxygenation level-dependent (BOLD) imaging. Here we report application of this method to detect alteration in tumor oxygenation status. Methods and materials: Ten patients with advanced cancer of the abdomen and pelvis underwent serial measurement of tumor R{sub 1} while breathing medical air (21% oxygen) followed by 100% oxygen (oxygen-enhanced MRI). Gadolinium-based dynamic contrast-enhanced MRI was then performed to compare the spatial distribution of perfusion with that of oxygen-induced DELTAR{sub 1}. Results: DELTAR{sub 1} showed significant increases of 0.021 to 0.058 s{sup -1} in eight patients with either locally recurrent tumor from cervical and hepatocellular carcinomas or metastases from ovarian and colorectal carcinomas. In general, there was congruency between perfusion and oxygen concentration. However, regional mismatch was observed in some tumor cores. Here, moderate gadolinium uptake (consistent with moderate perfusion) was associated with low area under the DELTAR{sub 1} curve (consistent with minimal increase in oxygen concentration). Conclusions: These results provide evidence that oxygen-enhanced longitudinal relaxation can monitor changes in tumor oxygen concentration. The technique shows promise in identifying hypoxic regions within tumors and may enable spatial mapping of change in tumor oxygen concentration.

  11. METHOD OF COMBINING HYDROGEN AND OXYGEN

    DOEpatents

    McBride, J.P.

    1962-02-27

    A method is given for the catalytic recombination of radiolytic hydrogen and/or deulerium and oxygen resulting from the subjection or an aqueous thorium oxide or thorium oxide-uranium oxide slurry to ionizing radiation. An improved catalyst is prepared by providing paliadium nitrate in an aqueous thorium oxide sol at a concentration of at least 0.05 grams per gram of thorium oxide and contacting the sol with gaseous hydrogen to form flocculated solids. The solids are then recovered and added to the slurry to provide a palladium concentration of 100 to 1000 parts per million. Recombination is effected by the calalyst at a rate sufficient to support high nuclear reactor power densities. (AEC)

  12. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect

    Timothy L. Ward

    2002-07-01

    Mixed-conducting ceramics have the ability to conduct oxygen with perfect selectivity at elevated temperatures, making them extremely attractive as membrane materials for oxygen separation and membrane reactor applications. While the conductivity of these materials can be quite high at elevated temperatures (typically 800-1000 C), much higher oxygen fluxes, or, alternatively, equivalent fluxes at lower temperatures, could be provided by supported thin or thick film membrane layers. Based on that motivation, the objective of this project was to explore the use of ultrafine aerosol-derived powder of a mixed-conducting ceramic material for fabrication of supported thick-film dense membranes. The project focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} (SCFO) because of the desirable permeability and stability of that material, as reported in the literature. Appropriate conditions to produce the submicron SrCo{sub 0.5}FeO{sub x} powder using aerosol pyrolysis were determined. Porous supports of the same composition were produced by partial sintering of a commercially obtained powder that possessed significantly larger particle size than the aerosol-derived powder. The effects of sintering conditions (temperature, atmosphere) on the porosity and microstructure of the porous discs were studied, and a standard support fabrication procedure was adopted. Subsequently, a variety of paste and slurry formulations were explored utilizing the aerosol-derived SCFO powder. These formulations were applied to the porous SCFO support by a doctor blade or spin coating procedure. Sintering of the supported membrane layer was then conducted, and additional layers were deposited and sintered in some cases. The primary characterization methods were X-ray diffraction and scanning electron microscopy, and room-temperature nitrogen permeation was used to assess defect status of the membranes.We found that non-aqueous paste/slurry formulations incorporating

  13. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect

    Riley, Michael F.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  14. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect

    Riley, M.F.; Ryan, H.M.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  15. Oxygen detected in atmosphere of Saturn's moon Dione

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of molecular oxygen ions in the upper-most atmosphere of Dione. March 3, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics

  16. Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity | The Ames

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Laboratory Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity Oxygen is one of the most ubiquitous elements in chemistry and materials science, yet one of the most elusive elements for spectroscopic investigation by solid-state Nuclear Magnetic Resonance (SSNMR). Used to determine the structure of materials and chemicals on the atomic scale, SSNMR requires nuclei that have magnetic moments. Yet, less than four of every 10,000 oxygen nuclei are 17O, the only NMR-active isotope of

  17. Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Technique | Department of Energy Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Presentation slides from the Fuel Cell Technologies Office webinar, "Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique," held March 12, 2013. Presenters were Shyam S. Kocha, National Renewable Energy Laboratory; Yannick Garsany, Naval Research

  18. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) ...

  19. Strain control of oxygen vacancies in epitaxial strontium cobaltite...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Strain control of oxygen vacancies in epitaxial strontium cobaltite films ... This content will become publicly available on January 25, 2017 Title: Strain control of ...

  20. Hybrid System for Separating Oxygen from Air - Energy Innovation...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate...

  1. New Oxygen-Production Technology Proving Successful | Department...

    Energy.gov [DOE] (indexed site)

    ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also ...

  2. Catalytic reduction system for oxygen-rich exhaust

    DOEpatents

    Vogtlin, George E.; Merritt, Bernard T.; Hsiao, Mark C.; Wallman, P. Henrik; Penetrante, Bernardino M.

    1999-01-01

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.

  3. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen...

    Energy Saver

    Review 2015: Intake Air Oxygen Sensor Vehicle Technologies Office Merit Review 2014: Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  4. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen...

    Energy Saver

    Office Merit Review 2014: Intake Air Oxygen Sensor Bosch Powertrain Technologies Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  5. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Energy Information Administration (EIA) (indexed site)

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  6. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Energy Information Administration (EIA) (indexed site)

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  7. Catalytic reduction system for oxygen-rich exhaust

    DOEpatents

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  8. Role of strain and conductivity in oxygen electrocatalysis on...

    Office of Scientific and Technical Information (OSTI)

    The slow kinetics of the oxygen reduction and evolution reactions (ORR, OER) hinder energy conversion and storage in alkaline fuel cells and electrolyzers employing abundant ...

  9. The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl...

    Office of Scientific and Technical Information (OSTI)

    Title: The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl Impurity Defects on Titanium Dioxide (110) Surface Introducing a charge into a solid such as a metal oxide ...

  10. Strain control of oxygen vacancies in epitaxial strontium cobaltite films

    DOE PAGES [OSTI]

    Jeen, Hyoung Jeen; Choi, Woo Seok; Reboredo, Fernando A.; Freeland, John W.; Eres, Gyula; Lee, Ho Nyung; Petrie, Jonathan R.; Mitra, Chandrima; Meyer, Tricia L.

    2016-01-25

    In this study, the ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the deliberate control of important defects, oxygen vacancies. Here, strontium cobaltite (SrCoOx) is used to demonstrate that epitaxial strain is a powerful tool for manipulating the oxygen vacancy concentration even under highly oxidizing environments and at annealing temperatures as low as 300 °C. By applying a small biaxial tensile strain (2%), the oxygen activation energy barrier decreases by ≈30%, resulting inmore » a tunable oxygen deficient steady-state under conditions that would normally fully oxidize unstrained cobaltite. These strain-induced changes in oxygen stoichiometry drive the cobaltite from a ferromagnetic metal towards an antiferromagnetic insulator. The ability to decouple the oxygen vacancy concentration from its typical dependence on the operational environment is useful for effectively designing oxides materials with a specific oxygen stoichiometry.« less

  11. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Energy.gov [DOE] (indexed site)

    (196.85 KB) More Documents & Publications Development Methodology for Power-Dense Military Diesel Engine Oxygen-Enriched Combustion Emission Control Strategy for Downsized ...

  12. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock ...

  13. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an ...

  14. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: ...

  15. Discovery of oxygen in atmosphere could mean life for Saturn...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  16. Oxygen detected in atmosphere of Saturn's moon Dione

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  17. Electrocatalyst for Oxygen Reduction with Reduced Platinum Oxidation...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates The invention relates to platinum-metal oxide composite particles and their use as...

  18. Probing oxygen vacancy concentration and homogeneity in solid...

    Office of Scientific and Technical Information (OSTI)

    Here, we develop an approach for direct mapping of oxygen vacancy concentrations based on local lattice parameter measurements by scanning transmission electron microscopy. The ...

  19. Oxidation State and Interfacial Effects on Oxygen Vacancies in...

    Office of Scientific and Technical Information (OSTI)

    Oxygen Vacancies in Tantalum Pentoxide. Abstract not provided. Authors: Bondi, Robert James ; Marinella, Matthew Publication Date: 2014-10-01 OSTI Identifier: 1184499 Report...

  20. Processing and Testing of the SRF Photoinjector Cavity for BERLinPro

    SciTech Connect

    Burrill, Andrew; Anders, W.; Frahm, A.; Knobloch, Jens; Neumann, Axel; Ciovati, Gianluigi; Clemens, William; Kneisel, Peter; Turlington, Larry; Zaplatin, Evgeny

    2014-07-01

    The BERLinPro project is a compact, c.w. SRF energy recovery linac (ERL) that is being built to develop the accelerator physics and technology required to operate the next generation of high current ERLs. The machine is designed to produce a 50 MeV 100 mA beam, with better than 1 mm-mrad emittance. The electron source for the ERL will be a SRF photoinjector equipped with a multi-alkali photocathode. In order to produce a SRF photoinjector to operate reliably at this beam current HZB has undertaken a 3 stage photoinjector development program to study the operation of SRF photoinjectors in detail. The 1.4 cell cavity being reported on here is the second stage of this development, and represents the first cavity designed by HZB for use with a high quantum efficiency multi-alkali photocathode. This paper will describe the work done to prepare the cavity for RF testing in the vertical testing dewar at Jefferson Laboratory as well as the results of these RF tests.

  1. Oxygen diffusion of anodic surface oxide film on titanium studied by Auger electron spectroscopy. [Oxygen diffusivity

    SciTech Connect

    Wang, P.S.; Wittberg, T.N.; Keil, R.G.

    1982-01-01

    TiO/sub 2/ films of about 1000 A were grown onto titanium foils anodically under galvanostatic conditions at 20 mA/cm/sup 2/ in saturated aqueous solutions of ammonium tetraborate. The samples were then aged at 450, 500, and 550/sup 0/C, and oxygen diffusion was observed by Auger electron spectroscopy (AES) profilings. The oxygen diffusivities were calculated by Fick's Second Law, using the Boltzmann-Matano solution, to be 9.4 x 10/sup -17/, 2.6 x 10/sup -16/, and 1.2 x 10/sup -15/ cm/sup 2//sec at 450, 500, and 550/sup 0/C, respectively. The diffusivities obtained by this method were also compared with those obtained using an exact solution to Fick's Second Law. The activation energy was calculated to be 30 kcal/mole.

  2. Salicylic acid induces apoptosis in colon carcinoma cells grown in-vitro: Influence of oxygen and salicylic acid concentration

    SciTech Connect

    Zitta, Karina; Meybohm, Patrick; Bein, Berthold; Huang, Ying; Heinrich, Christin; Scholz, Jens; Steinfath, Markus; Albrecht, Martin

    2012-04-15

    In solid tumors the hypoxic environment can promote tumor progression and resistance to therapy. Recently, acetylsalicylic acid a major component of analgesic drugs and its metabolite salicylic acid (SA) have been shown to reduce the risk of colon cancer, but the mechanisms of action remain still unclear. Here we elucidate the effects of physiologically relevant concentrations of SA on colon carcinoma cells (CaCo-2) grown under normoxic and hypoxic conditions. Western blotting, caspase-3/7 apoptosis assays, MTS cell-proliferation assays, LDH cytotoxicity assays and hydrogen peroxide measurements were performed to investigate the effects of 1 and 10 {mu}M SA on CaCo-2 cells grown under normoxic conditions and cells exposed to hypoxia. Under normoxic conditions, SA did not influence cell proliferation or LDH release of CaCo-2 cells. However, caspase-3/7 activity was significantly increased. Under hypoxia, cell proliferation was reduced and LDH release and caspase-3/7 activities were increased. None of these parameters was altered by the addition of SA under hypoxic conditions. Hypoxia increased hydrogen peroxide concentrations 300-fold and SA significantly augmented the release of hydrogen peroxide under normoxic, but not under hypoxic conditions. Phosphorylation of the pro-survival kinases akt and erk1/2 was not changed by SA under hypoxic conditions, whereas under normoxia SA reduced phosphorylation of erk1/2 after 2 hours. We conclude that in colon carcinoma cells effects of SA on apoptosis and cellular signaling are dependent on the availability of oxygen. -- Highlights: Black-Right-Pointing-Pointer Effects of salicylic acid on colon carcinoma cells grown under normoxic and hypoxic conditions Black-Right-Pointing-Pointer Salicylic acid increases caspase-3/7 activity and hydrogen peroxide release under normoxia Black-Right-Pointing-Pointer Salicylic acid decreases pro-survival erk-1/2 phosphorylation under normoxia Black-Right-Pointing-Pointer Salicylic acid does

  3. Low NOx combustion using cogenerated oxygen and nitrogen streams

    DOEpatents

    Kobayashi, Hisashi; Bool, Lawrence E.; Snyder, William J.

    2009-02-03

    Combustion of hydrocarbon fuel is achieved with less formation of NOx by feeding the fuel into a slightly oxygen-enriched atmosphere, and separating air into oxygen-rich and nitrogen-rich streams which are fed separately into the combustion device.

  4. Effects of oxygen and catalyst on tetraphenylborate decomposition rate

    SciTech Connect

    Walker, D.D.

    1999-12-15

    Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.

  5. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOEpatents

    Adzic, Radoslav; Huang, Tao

    2009-12-15

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  6. Device for measuring the total concentration of oxygen in gases

    DOEpatents

    Isaacs, Hugh S.; Romano, Anthony J.

    1977-01-01

    This invention provides a CO equilibrium in a device for measuring the total concentration of oxygen impurities in a fluid stream. To this end, the CO equilibrium is produced in an electrochemical measuring cell by the interaction of a carbon element in the cell with the chemically combined and uncombined oxygen in the fluid stream at an elevated temperature.

  7. Homogeneously dispersed, multimetal oxygen-evolving catalysts

    DOE PAGES [OSTI]

    Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; et al

    2016-03-24

    Earth-abundant first-row (3d) transition-metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials significantly above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing near-optimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxy-hydroxide materials with an atomically homogeneous metal distribution. These gelled FeCoW oxy-hydroxide exhibits the lowest overpotential (191 mV) reported at 10 mA per square centimeter in alkaline electrolyte. Here, the catalyst shows no evidence of degradation following more than 500 hours of operation. X-ray absorption and computationalmore » studies reveal a synergistic interplay between W, Fe and Co in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.« less

  8. Nanoparticulate-catalyzed oxygen transfer processes

    DOEpatents

    Hunt, Andrew T.; Breitkopf, Richard C.

    2009-12-01

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  9. Willamette Oxygen Supplementation Studies : Annual Report 1994.

    SciTech Connect

    Ewing, R.D.; Ewing, S.K.; Sheahan, J.E.

    1994-09-01

    Hydropower development and operations in the Columbia River basin have caused the loss of 5 million to 11 million salmonids. An interim goal of the Northwest Power Planning Council is to reestablish these historical numbers by doubling the present runs from 2.5 million adult fish to 5.0 million adult fish. This increase in production will be accomplished through comprehensive management of both wild and hatchery fish, but artificial propagation will play a major role in the augmentation process. The current husbandry techniques in existing hatcheries require improvements that may include changes in rearing densities, addition of oxygen, removal of excess nitrogen, and improvement in raceway design. Emphasis will be placed on the ability to increase the number of fish released from hatcheries that survive to return as adults. Rearing density is one of the most important elements in fish culture. Fish culturists have attempted to rear fish in hatchery ponds at densities that most efficiently use the rearing space available. Such efficiency studies require a knowledge of cost of rearing and the return of adults to the fisheries and to the hatchery.

  10. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect

    Riley, M.F.

    1996-12-31

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  11. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect

    Zawierucha, R.; McIlroy, K.; Million, J.F.

    1995-12-31

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  12. Enhancing perovskite electrocatalysis through strain tuning of oxygen deficiency

    DOE PAGES [OSTI]

    Barron, Sara C.; Lee, Ho Nyung; Petrie, Jonathan R.; Jeen, Hyoungjeen; Meyer, Tricia L.

    2016-05-27

    Oxygen vacancies in transition-metal oxides facilitate catalysis critical for energy storage and generation. However, promoting vacancies at the lower temperatures required for operation in devices such as metal–air batteries and portable fuel cells has proven elusive. Here we used thin films of perovskite-based strontium cobaltite (SrCoOx) to show that epitaxial strain is a powerful tool for manipulating the oxygen content under conditions consistent with the oxygen evolution reaction, yielding increasingly oxygen-deficient states in an environment where the cobaltite would normally be fully oxidized. The additional oxygen vacancies created through tensile strain enhance the cobaltite’s catalytic activity toward this important reactionmore » by over an order of magnitude, equaling that of precious-metal catalysts, including IrO2. Lastly, our findings demonstrate that strain in these oxides can dictate the oxygen stoichiometry independent of ambient conditions, allowing unprecedented control over oxygen vacancies essential in catalysis near room temperature.« less

  13. Noble metal-free bifunctional oxygen evolution and oxygen reduction acidic media electro-catalysts

    DOE PAGES [OSTI]

    Patel, Prasad Prakash; Datta, Moni Kanchan; Velikokhatnyi, Oleg I.; Kuruba, Ramalinga; Damodaran, Krishnan; Jampani, Prashanth; Gattu, Bharat; Shanthi, Pavithra Murugavel; Damle, Sameer S.; Kumta, Prashant N.

    2016-07-06

    We report that identification of low cost, highly active, durable completely noble metal-free electro-catalyst for oxygen reduction reaction (ORR) in proton exchange membrane (PEM) fuel cells, oxygen evolution reaction (OER) in PEM based water electrolysis and metal air batteries remains one of the major unfulfilled scientific and technological challenges of PEM based acid mediated electro-catalysts. In contrast, several non-noble metals based electro-catalysts have been identified for alkaline and neutral medium water electrolysis and fuel cells. Furthermore, we report for the very first time, F doped Cu1.5Mn1.5O4, identified by exploiting theoretical first principles calculations for ORR and OER in PEM basedmore » systems. The identified novel noble metal-free electro-catalyst showed similar onset potential (1.43 V for OER and 1 V for ORR vs RHE) to that of IrO2 and Pt/C, respectively. The system also displayed excellent electrochemical activity comparable to IrO2 for OER and Pt/C for ORR, respectively, along with remarkable long term stability for 6000 cycles in acidic media validating theory, while also displaying superior methanol tolerance and yielding recommended power densities in full cell configurations.« less

  14. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  15. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOEpatents

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  16. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect

    Yi, Min; Shen, Zhigang; Zhao, Xiaohu; Liang, Shuaishuai; Liu, Lei

    2014-04-07

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  17. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOEpatents

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  18. Modelling oxygen self-diffusion in UO2 under pressure

    DOE PAGES [OSTI]

    Cooper, Michael William D.; Grimes, R. W.; Fitzpatrick, M. E.; Chroneos, A.

    2015-10-22

    Access to values for oxygen self-diffusion over a range of temperatures and pressures in UO2 is important to nuclear fuel applications. Here, elastic and expansivity data are used in the framework of a thermodynamic model, the cBΩ model, to derive the oxygen self-diffusion coefficient in UO2 over a range of pressures (0–10 GPa) and temperatures (300–1900 K). Furthermore, the significant reduction in oxygen self-diffusion as a function of increasing hydrostatic pressure, and the associated increase in activation energy, is identified.

  19. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect

    Kojda, Danny [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universitt Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  20. Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report

    SciTech Connect

    Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

    1994-08-01

    The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

  1. In-situ generation of oxygen-releasing metal peroxides

    DOEpatents

    Looney, Brian B.; Denham, Miles E.

    2007-01-09

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  2. IMPACT OF OXYGEN CONCENTRATION ON ZEBRA MUSSEL MORTALITY

    SciTech Connect

    Daniel P. Molloy

    2003-01-27

    These tests have indicated that the bacterium Pseudomonas fluorescens strain CL0145A is effective at killing zebra mussels in environments having dissolved oxygen (DO) concentrations ranging from very low to very high. The results suggest that the highest mussel kill can be achieved in moderately to highly aerated environments, while kill may be 0-20% lower under conditions of very low oxygen. For example, under highly oxygenated conditions 97% kill was achieved while conditions having low DO produced 79% mussel kill. Service water measured in a local power plant indicated that DO concentrations were in the range of 8-9 ppm (e.g., highly aerated) within their pipes. Therefore, we will not expect to see decreases in the efficacy of CL0145A treatments due to oxygen levels within such power plant pipes.

  3. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  4. STUDY OF USING OXYGEN-ENRICHED COMBUSTION AIR FOR LOCOMOTIVE...

    Office of Scientific and Technical Information (OSTI)

    ... Evaluation o f Polymeric Membranes for Oxygen-Enrichment of Air, DOEAD- 127 10- 1, U S . ... fLom Gas Turbine Engines, Atmospheric Pollution by Aircraft Engines, AGARD CP-125, Paper ...

  5. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    OpenEI (Open Energy Information) [EERE & EIA]

    Silicates In The Larderello Geothermal Field, Italy Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The...

  6. Hybrid membrane--PSA system for separating oxygen from air

    DOEpatents

    Staiger, Chad L.; Vaughn, Mark R.; Miller, A. Keith; Cornelius, Christopher J.

    2011-01-25

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  7. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Armstrong, M R; Zaug, J M; Grant, C D; Crowhurst, J C; Bastea, S 75...

  8. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR ...

  9. Oxygen Control of Atomic Structure and Physical Properties of...

    Office of Scientific and Technical Information (OSTI)

    Properties of SrRuO3 Surfaces Citation Details In-Document Search Title: Oxygen Control of Atomic Structure and Physical Properties of SrRuO3 Surfaces Authors: Tselev, ...

  10. Enhancing SNCR-aided combustion with oxygen addition

    DOEpatents

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool, III, Lawrence E.

    2004-03-09

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  11. Role of an Oxygen Vacancy Nanostructure on the Switchable Photovoltaic...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Role of an Oxygen Vacancy Nanostructure on the Switchable Photovoltaic Effect in BiFeO3 ... Moreover, a switchable photovoltaic effect and its diode effect have been demonstrated.2 ...

  12. Sensor Rapidly Measures the Concentration of Oxygen in Fluids...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Compared to current sensor technology, such as universal exhaust gas oxygen sensors and ... mixture inside the intake manifold of an engine, to a transducer via a fiber optic cable. ...

  13. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen Sensor

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Robert Bosch at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensor.

  14. Hydrogen (H2) Production by Oxygenic Phototrophs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Oxygenic Phototrophs Hydrogen (H2) Production by Oxygenic Phototrophs Presentation by Eric Hegg, Michigan State University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. bio_h2_workshop_hegg.pdf (1.07 MB) More Documents & Publications Renewable Hydrogen Production from Biological Systems Autofermentative Biological Hydrogen Production by Cyanobacteria 2013 Biological Hydrogen Production Workshop

  15. NETL Advances Copper-Hybrid Oxygen Carrier for Chemical Looping |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Advances Copper-Hybrid Oxygen Carrier for Chemical Looping NETL Advances Copper-Hybrid Oxygen Carrier for Chemical Looping November 4, 2016 - 12:18pm Addthis NETL’s Chemical Looping Reactor Pilot-Scale Test Facility NETL's Chemical Looping Reactor Pilot-Scale Test Facility Back in February, we shared that DOE's National Energy Technology Laboratory (NETL) researchers were exploring the potential of using copper in a process known as chemical looping to capture

  16. Oxygen enhanced switching to combustion of lower rank fuels

    DOEpatents

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  17. Method for making oxygen-reducing catalyst layers

    DOEpatents

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

    2010-06-22

    Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  18. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Transport Membrane (OTM) (Presentation) | Department of Energy Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. 11_anl_distributed_reforming_using_otm.pdf (809.59 KB) More Documents & Publications Cost

  19. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Authors: Armstrong, M R ; Zaug, J M ; Grant, C D ; Crowhurst, J C ; Bastea, S Publication Date: 2014-06-24 OSTI Identifier: 1149544 Report Number(s):

  20. Oxygen-permeable ceramic membranes for gas separation

    SciTech Connect

    Balachandran, U.; Ma, B.; Maiya, P.S.; Dusek, J.T.; Mieville, R.L.; Picciolo, J.J.

    1998-02-01

    Mixed-conducting oxides have a wide range of applications, including fuel cells, gas separation systems, sensors, and electrocatalytic equipment. Dense ceramic membranes made of mixed-conducting oxides are particularly attractive for gas separation and methane conversion processes. Membranes made of Sr-Fe-Co oxide, which exhibits high combined electronic and oxygen ionic conductivities, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, i.e., CO + H{sub 2}). The authors have fabricated tubular Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes and tested them (some for more than 1,000 h) in a methane conversion reactor that was operating at 850--950 C. An oxygen permeation flux of {approx} 10 scc/cm{sup 2} {center_dot} min was obtained at 900 C in a tubular membrane with a wall thickness of 0.75 mm. Using a gas-tight electrochemical cell, the authors have also measured the steady-state oxygen permeability of flat Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes as a function of temperature and oxygen partial pressure(pO{sub 2}). Steady-state oxygen permeability increases with increasing temperature and with the difference in pO{sub 2} on the two sides of the membrane. At 900 C, an oxygen permeability of {approx} 2.5 scc/cm{sup 2} {center_dot} min was obtained in a 2.9-mm-thick membrane. This value agrees with that obtained in methane conversion reactor experiments. Current-voltage (I-V) characteristics determined in the gas-tight cell indicate that bulk effect, rather than surface exchange effect, is the main limiting factor for oxygen permeation of {approx} 1-mm-thick Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes at elevated temperatures (> 650 C).

  1. Electrochemical transfer of oxygen during direct current arc welding

    SciTech Connect

    Kim, J.H.; Frost, R.H.; Olson, D.L.

    1994-12-31

    Weld metal oxygen content is important for control of weld metal microstructure and notch toughness. Low oxygen contents promote low toughness bainitic structures. Moderate oxygen levels favor a tough acicular ferrite structure, and high oxygen levels promote lower toughness grain boundary and Widmanstaetten side plate structures. The objective of this research was to examine electrochemical oxygen transfer as a function of welding process variables, polarity, and the relative importance of conduction across plasma-metal and slag-metal interfaces for: submerged arc welding (SAW), shielded metal arc welding (SMAW), and gas tungsten arc welding (GTAW) processes. SAW and SMAW were made in DCEN and DCEP polarities on structural steel and copper substrates. GTAW were made on steel substrates in DCEN polarity. The experimental results show that both thermochemical and electrochemical reactions are important for oxygen transfer, and that there are differences in the electrochemical reactions at slag-metal and plasma-metal interfaces. Both electrochemical and thermochemical reactions are significant for direct current arc welding processes. The arc plasma acts as an electrolyte for arc welding processes and electrochemical reactions occur at the plasma-metal interface have chemical effects opposite to those at the slag metal interface. This is caused by the fact that only positive ions exist in the arc plasma in large concentrations.

  2. Interaction of light with the ZnO surface: Photon induced oxygen breathing, oxygen vacancies, persistent photoconductivity, and persistent photovoltage

    SciTech Connect

    Gurwitz, Ron; Cohen, Rotem; Shalish, Ilan

    2014-01-21

    ZnO surfaces adsorb oxygen in the dark and emit CO{sub 2} when exposed to white light, reminiscent of the lungs of living creatures. We find that this exchange of oxygen with the ambient affects the integrity of the ZnO surface. Thus, it forms a basis for several interesting surface phenomena in ZnO, such as photoconductivity, photovoltage, and gas sensing, and has a role in ZnO electrical conduction. Using x-ray photoelectron spectroscopy on ZnO nanowires, we observed a decomposition of ZnO under white light and formation of oxygen-depleted surface, which explains photoconductivity by the electron donation of oxygen vacancies. Our findings suggest that the observed decomposition of the ZnO lattice may only take place due to photon-induced reduction of ZnO by carbon containing molecules (or carbo-photonic reduction), possibly from the ambient gas, accounting in a consistent way for both the reduced demands on the energy required for decomposition and for the observed emission of lattice oxygen in the form of CO{sub 2}. The formation of oxygen-vacancy rich surface is suggested to induce surface delta doping, causing accumulation of electrons at the surface, which accounts for both the increase in conductivity and the flattening of the energy bands. Using surface photovoltage spectroscopy in ultra high vacuum, we monitored changes in the deep level spectrum. We observe a wide optical transition from a deep acceptor to the conduction band, which energy position coincides with the position of the so called green luminescence in ZnO. This green transition disappears with the formation of surface oxygen vacancies. Since the oxygen vacancies are donors, while the green transition involves surface acceptors, the results suggest that the initial emission of oxygen originates at the defect sites of the latter, thereby eliminating each other. This suggests that the green transition originates at surface Zn vacancy acceptors. Removing an oxygen atom from a Zn vacancy

  3. Constitutive NF-?B activation and tumor-growth promotion by Romo1-mediated reactive oxygen species production

    SciTech Connect

    Chung, Jin Sil; Lee, Sora; Yoo, Young Do

    2014-08-08

    Highlights: Romo1 expression is required for constitutive nuclear DNA-binding activity of NF-?B. Romo1 depletion suppresses tumor growth in vivo. Romo1 presents a potential therapeutic target for diseases. - Abstract: Deregulation of nuclear factor-?B (NF-?B) and related pathways contribute to tumor cell proliferation and invasion. Mechanisms for constitutive NF-?B activation are not fully explained; however, the underlying defects appear to generate and maintain pro-oxidative conditions. In hepatocellular carcinoma (HCC) tissues, up-regulation of reactive oxygen species modulator 1 (Romo1) correlates positively with tumor size. In the present study, we showed that Romo1 expression is required to maintain constitutive nuclear DNA-binding activity of NF-?B and transcriptional activity through constitutive I?B? phosphorylation. Overexpression of Romo1 promoted p65 nuclear translocation and DNA-binding activity. We also show that Romo1 depletion suppressed anchorage-independent colony formation by HCC cells and suppressed tumor growth in vivo. Based on these findings, Romo1 may be a principal regulatory factor in the maintenance of constitutive NF-?B activation in tumor cells. In the interest of anti-proliferative treatments for cancer, Romo1 may also present a productive target for drug development.

  4. Acute Toxicity of Radiochemotherapy in Rectal Cancer Patients: A Risk Particularly for Carriers of the TGFB1 Pro25 variant

    SciTech Connect

    Schirmer, Markus Anton; Mergler, Caroline Patricia Nadine; Rave-Fraenk, Margret; Herrmann, Markus Karl; Hennies, Steffen; Gaedcke, Jochen; Conradi, Lena-Christin; Jo, Peter; Beissbarth, Tim; Hess, Clemens Friedrich; Becker, Heinz; Ghadimi, Michael; Brockmoeller, Juergen; Christiansen, Hans; Wolff, Hendrik Andreas

    2012-05-01

    Purpose: Transforming growth factor-beta1 is related to adverse events in radiochemotherapy. We investigated TGFB1 genetic variability in relation to quality of life-impairing acute organ toxicity (QAOT) of neoadjuvant radiochemotherapy under clinical trial conditions. Methods and Materials: Two independent patient cohorts (n = 88 and n = 75) diagnosed with International Union Against Cancer stage II/III rectal cancer received neoadjuvant radiation doses of 50.4 Gy combined with 5-fluorouracil-based chemotherapy. Toxicity was monitored according to Common Terminology Criteria for Adverse Events. QAOT was defined as a CTCAE grade {>=}2 for at least one case of enteritis, proctitis, cystitis, or dermatitis. Nine germline polymorphisms covering the common genetic diversity in the TGFB1 gene were genotyped. Results: In both cohorts, all patients carrying the TGFB1 Pro25 variant experienced QAOT (positive predictive value of 100%, adjusted p = 0.0006). In a multivariate logistic regression model, gender, age, body mass index, type of chemotherapy, or disease state had no significant impact on QAOT. Conclusion: The TGFB1 Pro25 variant could be a relevant marker for individual treatment stratification and carriers may benefit from adaptive clinical care or specific radiation techniques.

  5. Surface control of epitaxial manganite films via oxygen pressure

    DOE PAGES [OSTI]

    Tselev, Alexander; Vasudevan, Rama K.; Gianfrancesco, Anthony G.; Qiao, Liang; Ganesh, Panchapakesan; Meyer, Tricia L.; Lee, Ho Nyung; Biegalski, Michael D.; Baddorf, Arthur P.; Kalinin, Sergei

    2015-03-11

    The trend to reduce device dimensions demands increasing attention to atomic-scale details of structure of thin films as well as to pathways to control it. We found that this is of special importance in the systems with multiple competing interactions. We have used in situ scanning tunneling microscopy to image surfaces of La5/8Ca3/8MnO3 films grown by pulsed laser deposition. The atomically resolved imaging was combined with in situ angle-resolved X-ray photoelectron spectroscopy. We find a strong effect of the background oxygen pressure during deposition on structural and chemical features of the film surface. Deposition at 50 mTorr of O2 leadsmore » to mixed-terminated film surfaces, with B-site (MnO2) termination being structurally imperfect at the atomic scale. Moreover, a relatively small reduction of the oxygen pressure to 20 mTorr results in a dramatic change of the surface structure leading to a nearly perfectly ordered B-site terminated surface with only a small fraction of A-site (La,Ca)O termination. This is accompanied, however, by surface roughening at a mesoscopic length scale. The results suggest that oxygen has a strong link to the adatom mobility during growth. The effect of the oxygen pressure on dopant surface segregation is also pronounced: Ca surface segregation is decreased with oxygen pressure reduction.« less

  6. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    SciTech Connect

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  7. High fidelity modeling of thermal relaxation and dissociation of oxygen

    SciTech Connect

    Andrienko, Daniil A. Boyd, Iain D.

    2015-11-15

    A master equation study of vibrational relaxation and dissociation of oxygen is conducted using state-specific O{sub 2}–O transition rates, generated by extensive trajectory simulations. Both O{sub 2}–O and O{sub 2}–O{sub 2} collisions are concurrently simulated in the evolving nonequilibrium gas system under constant heat bath conditions. The forced harmonic oscillator model is incorporated to simulate the state-to-state relaxation of oxygen in O{sub 2}–O{sub 2} collisions. The system of master equations is solved to simulate heating and cooling flows. The present study demonstrates the importance of atom-diatom collisions due to the extremely efficient energy randomization in the intermediate O{sub 3} complex. It is shown that the presence of atomic oxygen has a significant impact on vibrational relaxation time at temperatures observed in hypersonic flow. The population of highly-excited O{sub 2} vibrational states is affected by the amount of atomic oxygen when modeling the relaxation under constant heat bath conditions. A model of coupled state-to-state vibrational relaxation and dissociation of oxygen is also discussed.

  8. Surface control of epitaxial manganite films via oxygen pressure

    SciTech Connect

    Tselev, Alexander; Vasudevan, Rama K.; Gianfrancesco, Anthony G.; Qiao, Liang; Ganesh, Panchapakesan; Meyer, Tricia L.; Lee, Ho Nyung; Biegalski, Michael D.; Baddorf, Arthur P.; Kalinin, Sergei

    2015-03-11

    The trend to reduce device dimensions demands increasing attention to atomic-scale details of structure of thin films as well as to pathways to control it. We found that this is of special importance in the systems with multiple competing interactions. We have used in situ scanning tunneling microscopy to image surfaces of La5/8Ca3/8MnO3 films grown by pulsed laser deposition. The atomically resolved imaging was combined with in situ angle-resolved X-ray photoelectron spectroscopy. We find a strong effect of the background oxygen pressure during deposition on structural and chemical features of the film surface. Deposition at 50 mTorr of O2 leads to mixed-terminated film surfaces, with B-site (MnO2) termination being structurally imperfect at the atomic scale. Moreover, a relatively small reduction of the oxygen pressure to 20 mTorr results in a dramatic change of the surface structure leading to a nearly perfectly ordered B-site terminated surface with only a small fraction of A-site (La,Ca)O termination. This is accompanied, however, by surface roughening at a mesoscopic length scale. The results suggest that oxygen has a strong link to the adatom mobility during growth. The effect of the oxygen pressure on dopant surface segregation is also pronounced: Ca surface segregation is decreased with oxygen pressure reduction.

  9. Oxygen electrode reaction in molten carbonate fuel cells

    SciTech Connect

    Appleby, A.J.; White, R.E.

    1992-07-07

    Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

  10. Method and apparatus for producing oxygenates from hydrocarbons

    DOEpatents

    Kong, Peter C.; Lessing, Paul A.

    1995-01-01

    A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.

  11. Method and apparatus for producing oxygenates from hydrocarbons

    DOEpatents

    Kong, P.C.; Lessing, P.A.

    1995-06-27

    A chemical reactor for oxygenating hydrocarbons includes: (a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; (b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; (c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and (d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed. 4 figs.

  12. Fuel and oxygen addition for metal smelting or refining process

    DOEpatents

    Schlichting, Mark R.

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  13. Fuel and oxygen addition for metal smelting or refining process

    DOEpatents

    Schlichting, M.R.

    1994-11-22

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  14. CRADA Final Report: Ionically Conductive Membranes Oxygen Separation

    SciTech Connect

    Visco, Steven J.

    2001-10-29

    Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

  15. Impact of oxygenates on petroleum refining, review and forecast

    SciTech Connect

    Unzelman, G.H.

    1995-09-01

    During the coming decade, oxygenates will continue to impact light oil processing and will steadily change the composition of the US gasoline pool. There are several major driving forces that will sustain the gradual influx of oxygen to US gasoline toward the regulatory limits: (1) the positive environmental characteristics of oxygenated compounds, (2) the high-octane quality of ethers that promote elimination of less desirable hydrocarbons and (3) the competitive need for ultra-clean gasoline to compete with alternatives. From 1995 forward, conventional gasoline will gradually shift to RFG (reformulated gasoline) containing a minimum of 2 wt% oxygen and less aromatics. As a result some processing changes, already in motion in the refining industry, will continue. For example, less severe naphtha reforming and cracking innovations to yield more feed for etherification and alkylation. While alternative fuel and vehicle technology will continue to develop, oxygenates in US gasoline will contribute the major alternative dimension to transportation fuel in the foreseeable future. With RFG, internal-combustion engine emissions will be progressively less toxic and lower in photochemical reactivity. The oxygenate mix will favor methyl ethers in spite of the recent methanol price spike. Ethyl ethers will be used on a more limited basis for specific situations where lower volatility and feedstock economics are an advantage. Downstream blending of ethanol will supplement ethers blended at the refinery in situations where economics are more favorable than refinery ethers. Long-range survival of ethanol, as a direct blending agent or feedstock for refinery ethers, depends on one or more of several factors: future crude oil costs, longevity of subsidies and/or mandates, and new production technology based on cellulose yielding ethanol economically competitive with hydrocarbons.

  16. Properties of reactive oxygen species by quantum Monte Carlo

    SciTech Connect

    Zen, Andrea; Trout, Bernhardt L.; Guidoni, Leonardo

    2014-07-07

    The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of chemistry, biology, and atmospheric science. Nevertheless, the electronic structure of such species is a challenge for ab initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution, and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular, we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as N{sup 3} ? N{sup 4}, where N is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

  17. Evaluation of the effect of organic pro-degradant concentration in polypropylene exposed to the natural ageing

    SciTech Connect

    Montagna, L. S. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Catto, A. L. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Rossini, K. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Forte, M. M. C. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Santana, R. M. C. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com

    2014-05-15

    The production and consumption of plastics in the last decade has recorded a remarkable increase in the scientific and industrial interest in environmentally degradable polymer (EDPs). Polymers wastes are deposited improperly, such as dumps, landfills, rivers and seas, causing a serious problem by the accumulation in the environment. The abiotic processes, like the photodegradation, are the most efficient occurring in the open environmental, where the polymers undergo degradation from the action of sunlight that result from direct exposure to solar radiation, however depend of the type of chemical ageing, which is the principal component of climatic ageing. The subject of this work is to study the influence of concentration of organic pro-degradant (1, 2 and 3 % w/w) in the polypropylene (PP) exposed in natural ageing. PP samples with and without the additive were processed in plates square form, obtained by thermal compression molding (TCM) using a press at 200C under 2 tons for 5 min, and then were exposed at natural ageing during 120 days. The presence of organic additive influenced on PP degradability, this fact was assessed by changes in the thermal and morphology properties of the samples after 120 days of natural ageing. Scanning Electronic Microscopy (SEM) results of the morphological surface of the modified PP samples showed greater degradation photochemical oxidative when compared to neat PP, due to increase of rugosity and formation of microvoids. PP samples with different pro-degradant concentration under natural ageing presented a degree of crystallinity, obtained by Differential Scanning Calorimeter (DSC) increases in comparing the neat PP.

  18. Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2

    DOE PAGES [OSTI]

    Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis; Sun, Lei; Surendranath, Yogesh; Dinca, Mircea

    2016-03-08

    Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni3(HITP)2 (HITP=2, 3, 6, 7, 10, 11-hexaiminotriphenylene) as an intrinsically conductive metal-organic framework which functions as a well-defined, tunable oxygen reduction electrocatalyst in alkaline solution. Ni3(HITP)2 exhibits oxygen reduction activity competitive with the most active non-platinum group metal electrocatalysts and stability during extended polarization. The square planar Ni-N4 sites are structurally reminiscent of the highly active and widely studied non-platinum group metal electrocatalysts containing M-N4 units.more » Ni3(HITP)2 and analogues thereof combine the high crystallinity of metal-organic frameworks, the physical durability and electrical conductivity of graphitic materials, and the diverse yet well-controlled synthetic accessibility of molecular species. As a result, such properties may enable the targeted synthesis and systematic optimization of oxygen reduction electrocatalysts as components of fuel cells and electrolysers for renewable energy applications.« less

  19. Blood storage device and method for oxygen removal

    DOEpatents

    Bitensky, Mark W.; Yoshida, Tatsuro

    2000-01-01

    The present invention relates to a storage device and method for the long-term storage of blood and, more particularly, to a blood storage device and method capable of removing oxygen from the stored blood and thereby prolonging the storage life of the deoxygenated blood.

  20. High-temperature potentiometric oxygen sensor with internal reference

    DOEpatents

    Routbort, Jules L.; Singh, Dileep; Dutta, Prabir K.; Ramasamy, Ramamoorthy; Spirig, John V.; Akbar, Sheikh

    2011-11-15

    A compact oxygen sensor is provided, comprising a mixture of metal and metal oxide an enclosure containing said mixture, said enclosure capable of isolating said mixture from an environment external of said enclosure, and a first wire having a first end residing within the enclosure and having a second end exposed to the environment. Also provided is a method for the fabrication of an oxygen sensor, the method comprising confining a metal-metal oxide solid mixture to a container which consists of a single material permeable to oxygen ions, supplying an electrical conductor having a first end and a second end, whereby the first end resides inside the container as a reference (PO.sub.2).sup.ref, and the second end resides outside the container in the atmosphere where oxygen partial pressure (PO.sub.2).sup.ext is to be measured, and sealing the container with additional single material such that grain boundary sliding occurs between grains of the single material and grains of the additional single material.

  1. Process for conversion of lignin to reformulated, partially oxygenated gasoline

    DOEpatents

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    2001-01-09

    A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

  2. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  3. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect

    Kelly, Sen; Turner, Miles M.

    2013-09-28

    A plasma needle is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  4. Materials and methods for the separation of oxygen from air

    DOEpatents

    MacKay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2003-07-15

    Metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes having the formula: O.sub.5+z where: x and x' are greater than 0; y and y' are greater than 0; x+x' is equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides, Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof and B" is Co or Mg, with the exception that when B" is Mg, A' and A" are not Mg. The metal oxides are useful for preparation of dense membranes which may be formed from dense thin films of the mixed metal oxide on a porous metal oxide element. The invention also provides methods and catalytic reactors for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula.

  5. Chemistry - Oxygen Vacancies and Catalysis on Ceria Surfaces

    SciTech Connect

    Campbell, Charles T.; Peden, Charles HF.

    2005-07-29

    Chemistry occurring at the surface of metal oxides is critical in a variety of industrial applications including catalysis and photocatalysis, optical display technology, solar energy devices and corrosion prevention. Defects have long been recognized to be the most reactive sites on the surfaces of many oxide materials. The most common types of defects present on the surfaces of metal oxides are oxygen vacancies and step edges. The nature of surface oxygen vacancies, and their number, distribution and diffusion across the surface of oxides, are thus issues of major scientific importance. One of the most interesting oxides in this respect is CeO2, since oxygen vacancies play the key role in giving this material it's industrially important ''oxygen-storage capacity''. This capacity makes modern automotive exhaust treatment catalysts containing CeO2 much more effective than their predecessors without CeO2. Ceria is also well known as a support which enhances the performance of transition metal catalysts, relative to other oxide supports, in a variety of other reactions including water-gas shift, steam reforming of oxygenates and PROX 1-7, all of which hold promise for enabling a hydrogen economy 1. Related to ceria's facile redox capacity (ability to rapidly form and eliminate oxygen vacancy defects) is the poorly understood observation that some less reducible oxides, such as zirconia (ZrO2), are used as additives that actually enhance this ''oxygen storage'' property of CeO2. In this issue, Esch and coworkers in Trieste, Italy report an exciting study that for the first time clearly elucidates the structure, distribution and formation of oxygen vacancies on a cerium oxide surface 8. They have elegantly combined beautiful, atomic-resolution imaging using scanning-tunneling microscopy (STM) on a ceria surface with state-of-the-art quantum mechanical calculations using Density Functional Theory (DFT) to raise our understanding of CeO2 surfaces to a much higher level

  6. Subtask 3.12 - Oxygen-Fired CFBC

    SciTech Connect

    Douglas Hajicek; Mark Musich; Ann Henderson

    2007-02-28

    Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize

  7. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOEpatents

    Erickson, Donald C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power.

  8. Oxygen assisted interconnection of silver nanoparticles with femtosecond laser radiation

    SciTech Connect

    Huang, H.; Zhou, Y.; Duley, W. W.

    2015-12-14

    Ablation of silver (Ag) nanoparticles in the direction of laser polarization is achieved by utilizing femtosecond laser irradiation in air at laser fluence ranging from ∼2 mJ/cm{sup 2} to ∼14 mJ/cm{sup 2}. This directional ablation is attributed to localized surface plasmon induced localized electric field enhancement. Scanning electron microscopy observations of the irradiated particles in different gases and at different pressures indicate that the ablation is further enhanced by oxygen in the air. This may be due to the external heating via the reactions of its dissociation product, atomic oxygen, with the surface of Ag particles, while the ablated Ag is not oxidized. Further experimental observations show that the ablated material re-deposits near the irradiated particles and results in the extension of the particles in laser polarization direction, facilitating the interconnection of two well-separated nanoparticles.

  9. Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion

    SciTech Connect

    Bhavsar, Saurabh; Veser, Goetz

    2013-11-06

    The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

  10. Residual Oxygen on Nb Heated to 500 C

    SciTech Connect

    Kirby, R.; King, F.K.; Padamsee, H.; /Cornell U., LEPP

    2005-06-10

    The superconducting accelerating cavities for the International Linear Collider will be constructed of high-residual resistivity ratio (RRR) niobium sheet. Excessive oxygen within the skin depth (several microns) will reduce the RRR and increase resistive losses. We measure the thickness of this oxide layer, following bakeout simulation, to be about 0.5 nm thick. The results suggest that this layer will very slowly disappear from the top five nm at 500 C.

  11. Excited states in the active media of oxygen - iodine lasers

    SciTech Connect

    Azyazov, V N

    2009-11-30

    A review of investigations of kinetic processes in active media oxygen - iodine lasers (OILs) performed in the last decade is presented. The mechanisms of pumping and quenching of electronically and vibrationally excited O{sub 2} and I{sub 2} molecules are considered, and dissociation mechanisms of I{sub 2} in the active medium of the OIL are analysed. The values of kinetic constants of processes proceeding in the active media of OILs are recommended. (review)

  12. Real Space Mapping of Oxygen Vacancy Diffusion and Electrochemical

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Transformations by Hysteretic Current Reversal Curve Measurements - Energy Innovation Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Real Space Mapping of Oxygen Vacancy Diffusion and Electrochemical Transformations by Hysteretic Current Reversal Curve Measurements Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryElectrochemical energy storage and conversion systems based on

  13. K-shell auger decay of atomic oxygen

    SciTech Connect

    Stolte, W.C.; Lu, Y.; Samson, J.A.R.

    1997-04-01

    The aim of the present research is to understand the interaction between the ejected photoelectron and Auger electron produced by the Auger decay of a 1s hole in atomic oxygen, and to understand the influence this interaction has on the shape of the ionization cross sections. To accomplish this the authors have measured the relative ion yields (ion/photon) in the vicinity of the oxygen K-shell (525 - 533 eV) for O{sup +} and O{sup 2+}. The measurements were performed at the ALS on beamline, 6.3.2. The atomic oxygen was produced by passing molecular oxygen through a microwave-driven discharge. A Rydberg analysis of the two series leading to the [1s]2s{sup 2}2p{sup 4}({sup 4}P) and [1s]2s{sup 2}2p{sup 4}({sup 2}P) limits were obtained. This analysis shows some differences to the recently published results by Menzel et al. The energy position of the main 1s{sup 1}2s{sup 2}2p{sup 5}({sup 3}P) resonance differs by approximately 1 eV from the authors value, all members of the ({sup 2}P)np series differ by 0.3 eV, but the members of the ({sup 4}P)np series agree. The molecular resonance at 530.5 eV and those between 539 eV and 543 eV, measured with the microwave discharge off show identical results in both experiments.

  14. Observing Oxygen Atoms Move during Information Storage in Tantalum Oxide

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Memristors | Stanford Synchrotron Radiation Lightsource Observing Oxygen Atoms Move during Information Storage in Tantalum Oxide Memristors Saturday, April 30, 2016 Memristor technology, or resistive random access memory (RRAM), is a frontrunner for next generation computer memory, owing to the promise of long endurance, low power, nanoscale device size and fast operation.1 Memristor devices are typically made of a transition metal oxide sandwiched between two metallic electrodes, and

  15. Electrocatalyst for Oxygen Reduction with Reduced Platinum Oxidation and

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Dissolution Rates - Energy Innovation Portal Oxygen Reduction with Reduced Platinum Oxidation and Dissolution Rates Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Electrodeposition of Pt onto RuO2 (110) Single-Crystal Surface (437 KB) <p> Results of a density functional theory calculation of atomic positions of platinum on an oxide surface, showing good agreement with experimental results.</p> Results of a density

  16. Atomically Precise Electrocatalyst for Oxygen Evolution Reaction | Stanford

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Synchrotron Radiation Lightsource Atomically Precise Electrocatalyst for Oxygen Evolution Reaction Thursday, March 31, 2016 Traditional heterogeneous catalysts contain a range of particles sizes, crystallographic faces, and surface structures. This heterogeneity makes catalysts design a challenge because the active sites responsible for catalytic activity are simply not known. An emerging class of "atomically-precise" nanocatalysts can help alleviate this problem because they form

  17. Controllable positive exchange bias via redox-driven oxygen migration

    DOE PAGES [OSTI]

    Gilbert, Dustin A.; Olamit, Justin; Dumas, Randy K.; Kirby, B. J.; Grutter, Alexander J.; Maranville, Brian B.; Arenholz, Elke; Borchers, Julie A.; Liu, Kai

    2016-03-21

    We report that ionic transport in metal/oxide heterostructures offers a highly effective means to tailor material properties via modification of the interfacial characteristics. However, direct observation of ionic motion under buried interfaces and demonstration of its correlation with physical properties has been challenging. Using the strong oxygen affinity of gadolinium, we design a model system of GdxFe1-x/NiCoO bilayer films, where the oxygen migration is observed and manifested in a controlled positive exchange bias over a relatively small cooling field range. The exchange bias characteristics are shown to be the result of an interfacial layer of elemental nickel and cobalt, amore » few nanometres in thickness, whose moments are larger than expected from uncompensated NiCoO moments. This interface layer is attributed to a redox-driven oxygen migration from NiCoO to the gadolinium, during growth or soon after. Ultimately, these results demonstrate an effective path to tailoring the interfacial characteristics and interlayer exchange coupling in metal/oxide heterostructures.« less

  18. Taguchi methods applied to oxygen-enriched diesel engine experiments

    SciTech Connect

    Marr, W.W.; Sekar, R.R.; Cole, R.L.; Marciniak, T.J.; Longman, D.E.

    1992-12-01

    This paper describes a test series conducted on a six-cylinder diesel engine to study the impacts of controlled factors (i.e., oxygen content of the combustion air, water content of the fuel, fuel rate, and fuel-injection timing) on engine emissions using Taguchi methods. Three levels of each factor were used in the tests. Only the main effects of the factors were examined; no attempt was made to analyze the interactions among the factors. It was found that, as in the case of the single-cylinder engine tests, oxygen in the combustion air was very effective in reducing particulate and smoke emissions. Increases in NO{sub x} due to the oxygen enrichment observed in the single-cylinder tests also occurred in the present six-cylinder tests. Water in the emulsified fuel was found to be much less effective in decreasing NO{sub x} emissions for the six-cylinder engine than it was for the single-cylinder engine.

  19. Taguchi methods applied to oxygen-enriched diesel engine experiments

    SciTech Connect

    Marr, W.W.; Sekar, R.R.; Cole, R.L.; Marciniak, T.J. ); Longman, D.E. )

    1992-01-01

    This paper describes a test series conducted on a six-cylinder diesel engine to study the impacts of controlled factors (i.e., oxygen content of the combustion air, water content of the fuel, fuel rate, and fuel-injection timing) on engine emissions using Taguchi methods. Three levels of each factor were used in the tests. Only the main effects of the factors were examined; no attempt was made to analyze the interactions among the factors. It was found that, as in the case of the single-cylinder engine tests, oxygen in the combustion air was very effective in reducing particulate and smoke emissions. Increases in NO[sub x] due to the oxygen enrichment observed in the single-cylinder tests also occurred in the present six-cylinder tests. Water in the emulsified fuel was found to be much less effective in decreasing NO[sub x] emissions for the six-cylinder engine than it was for the single-cylinder engine.

  20. How a weird Mars rock may be solid proof of an ancient oxygen...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Weird Mars rock may be solid proof of ancient oxygen atmosphere How a weird Mars rock may be solid proof of an ancient oxygen atmosphere When researchers found a compound that ...

  1. Growth control of oxygen stoichiometry in homoepitaxial SrTiO3...

    Office of Scientific and Technical Information (OSTI)

    Growth control of oxygen stoichiometry in homoepitaxial SrTiO3 films by pulsed laser epitaxy in high vacuum Prev Next Title: Growth control of oxygen stoichiometry in ...

  2. Selectivity of Chemisorbed Oxygen in C-H Bond Activation and...

    Office of Scientific and Technical Information (OSTI)

    Selectivity of Chemisorbed Oxygen in C-H Bond Activation and CO Oxidation and Kinetic ... Title: Selectivity of Chemisorbed Oxygen in C-H Bond Activation and CO Oxidation and ...

  3. SYSTEM DESIGN AND ANALYSIS FOR CONCEPTUAL DESIGN OF OXYGEN-BASED...

    Office of Scientific and Technical Information (OSTI)

    DESIGN OF OXYGEN-BASED PC BOILER Citation Details In-Document Search Title: SYSTEM DESIGN AND ANALYSIS FOR CONCEPTUAL DESIGN OF OXYGEN-BASED PC BOILER The objective of the system ...

  4. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Impact of ethanol and butanol as oxygenates on SIDI engine ...

  5. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  6. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOEpatents

    Cassano, Anthony A.

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  7. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOEpatents

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  8. Method and apparatus for producing oxygen and nitrogen and membrane therefor

    DOEpatents

    Roman, Ian C.; Baker, Richard W.

    1985-01-01

    Process and apparatus for the separation and purification of oxygen and nitrogen as well as a novel membrane useful therein are disclosed. The process utilizes novel facilitated transport membranes to selectively transport oxygen from one gaseous stream to another, leaving nitrogen as a byproduct. In the method, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a polar organic membrane which separates a gaseous feed stream such as atmospheric air and a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form at the interface of the feed stream with the membrane, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form at the interface of the product stream with the membrane. In an alternate mode of operation, the feed stream is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form at the interface of the feed stream with the membrane and the product stream is maintained at a sufficiently high temperature to keep the carrier in its deoxygenated form at the interface of the product stream with the membrane. Under such conditions, the carrier acts as a shuttle, picking up oxygen at the feed side of the membrane, diffusing across the membrane as the oxygenated complex, releasing oxygen to the product stream, and then diffusing back to the feed side to repeat the process. Exceptionally and unexpectedly high O.sub.2 /N.sub.2 selectivity, on the order of 10 to 30, is obtained, as well as exceptionally high oxygen permeability, on the order of 6 to 15.times.10.sup.-8 cm.sup.3 -cm/cm.sup.2 -sec-cmHg, as well as a long membrane life of in excess of 3 months, making the process commercially feasible.

  9. Method and apparatus for producing oxygen and nitrogen and membrane therefor

    DOEpatents

    Roman, I.C.; Baker, R.W.

    1985-09-17

    Process and apparatus for the separation and purification of oxygen and nitrogen as well as a novel membrane useful therein are disclosed. The process utilizes novel facilitated transport membranes to selectively transport oxygen from one gaseous stream to another, leaving nitrogen as a byproduct. In the method, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a polar organic membrane which separates a gaseous feed stream such as atmospheric air and a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form at the interface of the feed stream with the membrane, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form at the interface of the product stream with the membrane. In an alternate mode of operation, the feed stream is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form at the interface of the feed stream with the membrane and the product stream is maintained at a sufficiently high temperature to keep the carrier in its deoxygenated form at the interface of the product stream with the membrane. Under such conditions, the carrier acts as a shuttle, picking up oxygen at the feed side of the membrane, diffusing across the membrane as the oxygenated complex, releasing oxygen to the product stream, and then diffusing back to the feed side to repeat the process. Exceptionally and unexpectedly high O[sub 2]/N[sub 2] selectivity, on the order of 10 to 30, is obtained, as well as exceptionally high oxygen permeability, on the order of 6 to 15 [times] 10[sup [minus]8] cm[sup 3]-cm/cm[sup 2]-sec-cmHg, as well as a long membrane life of in excess of 3 months, making the process commercially feasible. 2 figs.

  10. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia

    SciTech Connect

    Edmondson, P. D.; Weber, William J.; Namavar, Fereydoon; Zhang, Yanwen

    2011-07-13

    The oxygen ion conductivity, attributed to an oxygen vacancy mechanism, of yttria-stabilized zirconia membranes used in solid oxide fuel cells is restricted due to trapping limitations. In this work, a high concentration of oxygen vacancies has been deliberately introduced into nanocrystalline stabilizer-free zirconia through ion-irradiation. Oxygen vacancies with different charge states can be produced by varying irradiation temperatures. Due to the reduced trapping sites and high oxygen vacancy concentration, this work suggests that the efficiency of solid oxide fuel cells can be improved.

  11. Oxygen vacancy ordering within anion-deficient Ceria

    SciTech Connect

    Hull, S.; Norberg, S.T.; Ahmed, I.; Eriksson, S.G.; Marrocchelli, D.; Madden, P.A.

    2009-10-15

    The structural properties of anion deficient ceria, CeO{sub 2-{delta}}, have been studied as a function of oxygen partial pressure, p(O{sub 2}), over the range 0>=log{sub 10p}(O{sub 2})>=-18.9 at 1273(2) K using the neutron powder diffraction technique. Rietveld refinement of the diffraction data collected on decreasing p(O{sub 2}) showed increases in the cubic lattice parameter, a, the oxygen nonstoichiometry, delta, and the isotropic thermal vibration parameters, u{sub Ce} and u{sub O}, starting at log{sub 10p}(O{sub 2}){approx}-11. The increases are continuous, but show a distinct kink at log{sub 10p}(O{sub 2}){approx}-14.5. Analysis of the total scattering (Bragg plus diffuse components) using reverse Monte Carlo (RMC) modelling indicates that the O{sup 2-} vacancies preferentially align as pairs in the <111> cubic directions as the degree of nonstoichiometry increases. This behaviour is discussed with reference to the chemical crystallography of the CeO{sub 2}-Ce{sub 2}O{sub 3} system at ambient temperature and, in particular, to the nature of the long-range ordering of O{sup 2-} vacancies within the crystal structure of Ce{sub 7}O{sub 12}. - Graphical abstract: Partial radial distribution function for oxygen vacancies within CeO{sub 1.710} at 1273 K (solid line) showing the increased tendency for local ordering in <111> directions compared to a random distribution (dashed line).

  12. Oxygen transport in off-stoichiometric uranium dioxide mediated by defect clustering dynamics

    SciTech Connect

    Yu, Jianguo; Bai, Xian -Ming; El-Azab, Anter; Allen, Todd R.

    2015-03-05

    In this study, oxygen transport is central to many properties of oxides such as stoichiometric changes, phase transformation and ionic conductivity. In this paper, we report a mechanism for oxygen transport in uranium dioxide (UO2) in which the kinetics is mediated by defect clustering dynamics. In particular, the kinetic Monte Carlo (KMC) method has been used to investigate the kinetics of oxygen transport in UO2 under the condition of creation and annihilation of oxygen vacancies and interstitials as well as oxygen interstitial clustering, with variable offstoichiometry and temperature conditions. It is found that in hypo-stoichiometric UO2-x, oxygen transport is well described by the vacancy diffusion mechanism while in hyper-stoichiometric UO2+x, oxygen interstitial cluster diffusion contributes significantly to oxygen transport kinetics, particularly at high temperatures and high off-stoichiometry levels. It is also found that diinterstitial clusters and single interstitials play dominant roles in oxygen diffusion while other larger clusters have negligible contributions. However, the formation, coalescence and dissociation of these larger clusters indirectly affects the overall oxygen diffusion due to their interactions with mono and di-interstitials, thus providing a explanation of the experimental observation of saturation or even drop of oxygen diffusivity at high off-stoichiometry.

  13. Oxygen transport in off-stoichiometric uranium dioxide mediated by defect clustering dynamics

    SciTech Connect

    Yu, Jianguo Bai, Xian-Ming; El-Azab, Anter; Allen, Todd R.

    2015-03-07

    Oxygen transport is central to many properties of oxides such as stoichiometric changes, phase transformation, and ionic conductivity. In this paper, we report a mechanism for oxygen transport in uranium dioxide (UO{sub 2}) in which the kinetics is mediated by defect clustering dynamics. In particular, the kinetic Monte Carlo method has been used to investigate the kinetics of oxygen transport in UO{sub 2} under the condition of creation and annihilation of oxygen vacancies and interstitials as well as oxygen interstitial clustering, with variable off-stoichiometry and temperature conditions. It is found that in hypo-stoichiometric UO{sub 2?x}, oxygen transport is well described by the vacancy diffusion mechanism while in hyper-stoichiometric UO{sub 2+x}, oxygen interstitial cluster diffusion contributes significantly to oxygen transport kinetics, particularly at high temperatures and high off-stoichiometry levels. It is also found that di-interstitial clusters and single interstitials play dominant roles in oxygen diffusion while other larger clusters have negligible contributions. However, the formation, coalescence, and dissociation of these larger clusters indirectly affects the overall oxygen diffusion due to their interactions with mono and di-interstitials, thus providing an explanation of the experimental observation of saturation or even drop of oxygen diffusivity at high off-stoichiometry.

  14. Oxygen transport in off-stoichiometric uranium dioxide mediated by defect clustering dynamics

    DOE PAGES [OSTI]

    Yu, Jianguo; Bai, Xian -Ming; El-Azab, Anter; Allen, Todd R.

    2015-03-05

    In this study, oxygen transport is central to many properties of oxides such as stoichiometric changes, phase transformation and ionic conductivity. In this paper, we report a mechanism for oxygen transport in uranium dioxide (UO2) in which the kinetics is mediated by defect clustering dynamics. In particular, the kinetic Monte Carlo (KMC) method has been used to investigate the kinetics of oxygen transport in UO2 under the condition of creation and annihilation of oxygen vacancies and interstitials as well as oxygen interstitial clustering, with variable offstoichiometry and temperature conditions. It is found that in hypo-stoichiometric UO2-x, oxygen transport is wellmore » described by the vacancy diffusion mechanism while in hyper-stoichiometric UO2+x, oxygen interstitial cluster diffusion contributes significantly to oxygen transport kinetics, particularly at high temperatures and high off-stoichiometry levels. It is also found that diinterstitial clusters and single interstitials play dominant roles in oxygen diffusion while other larger clusters have negligible contributions. However, the formation, coalescence and dissociation of these larger clusters indirectly affects the overall oxygen diffusion due to their interactions with mono and di-interstitials, thus providing a explanation of the experimental observation of saturation or even drop of oxygen diffusivity at high off-stoichiometry.« less

  15. Hydrogen and oxygen concentrations in IXCs: A compilation

    SciTech Connect

    Liljegren, L.M.; Terrones, G.T.; Melethil, P.K.

    1996-06-01

    This paper contains four reports and two internal letters that address the estimation of hydrogen and oxygen concentrations in ion exchange columns that treat the water of the K-East and K-West Basins at Hanford. The concern is the flammability of this mixture of gases and planning for safe transport during decommissioning. A transient will occur when the hydrogen filter is temporarily blocked by a sandbag. Analyses are provided for steady-state, transients, and for both wet and dry resins.

  16. Oxygen-stabilized zirconium-vanadium intermetallic compound

    DOEpatents

    Mendelsohn, M.H.; Gruen, D.M.

    1981-10-06

    An oxygen stabilized intermetallic compound having the formula Zr/sub x/OV/sub y/ where x = 0.7 to 2.0 and y = 0.18 to 0.33 is described. The compound is capable of reversibly sorbing hydrogen at temperatures from - 196/sup 0/C to 450/sup 0/C at pressures down to 10/sup -6/ Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO/sub 2/.

  17. Device for measuring oxygen activity in liquid sodium

    DOEpatents

    Roy, P.; Young, R.S.

    1973-12-01

    A composite ceramic electrolyte in a configuration (such as a closed end tube or a plate) suitable to separate liquid sodium from a reference electrode with a high impedance voltmeter connected to measure EMF between the sodium and the reference electrode as a measure of oxygen activity in the sodium is described. The composite electrolyte consists of zirconiacalcia with a bonded layer of thoria-yttria. The device is used with a gaseous reference electrode on the zirconia-calcia side and liquid sodium on the thoria-yttria side of the electrolyte. (Official Gazette)

  18. Thermochemical generation of hydrogen and oxygen from water

    DOEpatents

    Robinson, Paul R.; Bamberger, Carlos E.

    1982-01-01

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  19. Thermochemical generation of hydrogen and oxygen from water

    DOEpatents

    Robinson, Paul R.; Bamberger, Carlos E.

    1981-01-01

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  20. Method for providing oxygen ion vacancies in lanthanide oxides

    DOEpatents

    Kay, D. Alan R.; Wilson, William G.

    1989-12-05

    A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

  1. Recent advances in the kinetics of oxygen reduction

    SciTech Connect

    Adzic, R.

    1996-07-01

    Oxygen reduction is considered an important electrocatalytic reaction; the most notable need remains improvement of the catalytic activity of existing metal electrocatalysts and development of new ones. A review is given of new advances in the understanding of reaction kinetics and improvements of the electrocatalytic properties of some surfaces, with focus on recent studies of relationship of the surface properties to its activity and reaction kinetics. The urgent need is to improve catalytic activity of Pt and synthesize new, possibly non- noble metal catalysts. New experimental techniques for obtaining new level of information include various {ital in situ} spectroscopies and scanning probes, some involving synchrotron radiation. 138 refs, 18 figs, 2 tabs.

  2. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology

  3. Electrode Interface Dictates Oxygen Evolution from Lithium Peroxide in

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Li-O2 Batteries - Joint Center for Energy Storage Research December 16, 2014, Research Highlights Electrode Interface Dictates Oxygen Evolution from Lithium Peroxide in Li-O2 Batteries Isolation of the charge reaction from the discharge in Li-O2 cells by utilizing electrodes prefilled with commercial lithium peroxide provides a unique method to understand interfacial properties. OER is very facile on TiC, which lacks a significant oxide film and occurs at a much lower overpotential relative

  4. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOEpatents

    Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

    2014-01-07

    A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

  5. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOEpatents

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

    2016-01-19

    A method and apparatus for producing heat used in a synthesis gas production process is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the steam reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5

  6. Word Pro - Untitled1

    Energy Information Administration (EIA) (indexed site)

    degree-days are deviations above the mean daily temperature of 65 F. For example, a weather station recording a mean daily temperature of 78 F would report 13 cooling...

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    Energy Consumption and Expenditures Indicators Estimates Energy Consumption, 1949-2011 Energy Expenditures, 1970-2010 Energy Consumption per Real Dollar of Gross Domestic...

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    Monthly Value (Year of Record) 2010- 2011 Heating Season 30-Year Monthly Normal Record Low Monthly Value (Year of Record) 260 (1981) (1985) 1 Based on calculations of data from...

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    Energy Information Administration (EIA) (indexed site)

    High Monthly Value (Year of Record) 2011 Cooling Season 30-Year Monthly Normal Record Low Monthly Value (Year of Record) 83 (1963) 118 (1967) 27 (1976) 268 (1950) 147 (1991) 228...

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    Energy Information Administration (EIA) (indexed site)

    7 a Exact conversion. b Calculated by the U.S. Energy Information Administration. Web Page: http://www.eia.gov/totalenergy/data/monthly/#appendices. Source: U.S. Department of Commerce, National Institute of Standards and Technology, Specifications, Tolerances, and Other Techni- cal Requirements for Weighing and Measuring Devices, NIST Handbook 44, 1994 Edition (Washington, DC, October 1993), pp. B-10, C-17, and C-21. cubic feet (ft 3 ) 128 a = 1 cord (cd) shorts tons 1.25 b = 1 cord (cd) Wood

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    9 Appendix C Table C1. Population, U.S. Gross Domestic Product, and U.S. Gross Output Population U.S. Gross Domestic Product U.S. Gross Output a United States b World United States as Share of World Billion Nominal Dollars d Billion Chained (2009) Dollars e Implicit Price Deflator c (2009 = 1.00000) Billion Nominal Dollars d Million People Percent 1950 .............. 152.3 2,557.6 6.0 300.2 2,184.0 0.13745 NA 1955 .............. 165.9 2,782.1 6.0 426.2 2,739.0 .15559 NA 1960 .............. 180.7

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    Energy Information Administration (EIA) (indexed site)

    ec 192 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table A2. Approximate Heat Content of Petroleum Production, Imports, and Exports (Million Btu per Barrel) Production Imports Exports Crude Oil a Petroleum Products Total Crude Oil a Petroleum Products Total Crude Oil a Natural Gas Plant Liquids Motor Gasoline b Total Products Motor Gasoline c Total Products 1950 ...................... 5.800 4.522 5.943 5.253 6.263 6.080 5.800 5.253 5.751 5.766 1955

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    Energy Information Administration (EIA) (indexed site)

    1 Appendix D Table D1. Estimated Primary Energy Consumption in the United States, Selected Years, 1635-1945 (Quadrillion Btu) Fossil Fuels Renewable Energy Electricity Net Imports b Total Coal Natural Gas Petroleum Total Conventional Hydroelectric Power Biomass Total Wood a 1635 .............. NA - - - - NA - - (s) (s) - - (s) 1645 .............. NA - - - - NA - - 0.001 0.001 - - 0.001 1655 .............. NA - - - - NA - - .002 .002 - - .002 1665 .............. NA - - - - NA - - .005 .005 - -

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    Energy Information Administration (EIA) (indexed site)

    Note. Geographic Coverage of Statistics for 1635-1945. Table D1 presents estimates of U.S. energy consumption by energy source for a period that begins a century and a half before the original 13 colonies formed a political union and continues through the decades during which the United States was still expanding territorially. The question thus arises, what exactly is meant by "U.S. consumption" of an energy source for those years when the United States did not formally exist or

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    195 Table A5. Approximate Heat Content of Coal and Coal Coke (Million Btu per Short Ton) Coal Coal Coke Production a Waste Coal Supplied b Consumption Imports Exports Imports and Exports Residential and Commercial Sectors c Industrial Sector Electric Power Sector e,f Total Coke Plants Other d 1950 ........................ 25.090 NA 24.461 26.798 24.820 23.937 24.989 25.020 26.788 24.800 1955 ........................ 25.201 NA 24.373 26.794 24.821 24.056 24.982 25.000 26.907 24.800 1960

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    6 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table A6. Approximate Heat Rates for Electricity, and Heat Content of Electricity (Btu per Kilowatthour) Approximate Heat Rates a for Electricity Net Generation Heat Content j of Electricity k Fossil Fuels b Nuclear h Noncombustible Renewable Energy g,i Coal c Petroleum d Natural Gas e Total Fossil Fuels f,g 1950 .............................. NA NA NA 14,030 - - 14,030 3,412 1955 .............................. NA NA

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    Consumption by Sector 1. Energy Overview Figure 1.1 Primary Energy Overview (Quadrillion Btu) Overview, 1949-2015 Overview, Monthly Overview, July 2016 Net Imports, January-July Web Page: http://www.eia.gov/totalenergy/data/monthly/#summary. Source: Table 1.1. 2 U.S. Energy Information Administration / Monthly Energy Review October 2016 6.515 6.443 6.944 2014 2015 2016 0 2 4 6 8 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 20 40 60 80 100 120 Consumption Production

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    Monthly Energy Review October 2016 Table 1.4a Primary Energy Imports by Source (Quadrillion Btu) Imports Coal Coal Coke Natural Gas Petroleum Biofuels c Electricity Total Crude Oil a Petroleum Products b Total 1950 Total ...................... 0.009 0.011 0.000 1.056 0.830 1.886 NA 0.007 1.913 1955 Total ...................... .008 .003 .011 1.691 1.061 2.752 NA .016 2.790 1960 Total ...................... .007 .003 .161 2.196 1.802 3.999 NA .018 4.188 1965 Total ...................... .005 .002

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    Energy Information Administration (EIA) (indexed site)

    5 Merchandise Trade Value (Billion Dollars a ) Imports and Exports, 1974-2015 Imports and Exports, Monthly Trade Balance, 1974-2015 Trade Balance, Monthly a Prices are not adjusted for inflation. S ee "Nominal Dollars" in Glossary. http://www.eia.gov/totalenergy/data/monthly/#summary. Source: Table 1.5. 12 U.S. Energy Information Administration / Monthly Energy Review October 2016 Energy Exports 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 500 1,000 1,500 2,000 2,500 J F MA M J J A S

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    Energy Information Administration (EIA) (indexed site)

    Table 1.5 Merchandise Trade Value (Million Dollars a ) Petroleum b Energy c Non- Energy Balance Total Merchandise Exports Imports Balance Exports Imports Balance Exports Imports Balance 1974 Total ................ 792 24,668 -23,876 3,444 25,454 -22,010 18,126 99,437 103,321 -3,884 1975 Total ................ 907 25,197 -24,289 4,470 26,476 -22,006 31,557 108,856 99,305 9,551 1980 Total ................ 2,833 78,637 -75,803 7,982 82,924 -74,942 55,246 225,566 245,262 -19,696 1985 Total

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    Energy Information Administration (EIA) (indexed site)

    7 Primary Energy Consumption and Energy Expenditures Indicators Energy Consumption per Capita, 1949-2015 Primary Energy Consumption per Real Dollar a of Gross Domestic Product, 1949-2015 Energy Expenditures as Share of Gross Domestic Product and Gross Output, b 1987-2013 16 U.S. Energy Information Administration / Monthly Energy Review October 2016 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 100 200 300 400 Million Btu Thousand Btu per Chained (2009) Dollar a 1950

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    Table 1.7 Primary Energy Consumption, Energy Expenditures, and Carbon Dioxide Emissions Indicators Primary Energy Consumption a Energy Expenditures b Carbon Dioxide Emissions c Consump- tion Consump- tion per Capita Consumption per Real Dollar d of GDP e Expendi- tures Expendi- tures per Capita Expenditures as Share of GDP e Expenditures as Share of Gross Output f Emissions Emissions per Capita Emissions per Real Dollar d of GDP e Quadrillion Btu Million Btu Thousand Btu per Chained (2009)

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    Energy Information Administration (EIA) (indexed site)

    Monthly Energy Review October 2016 Table 1.9 Heating Degree Days by Census Division New England a Middle Atlantic b East North Central c West North Central d South Atlantic e East South Central f West South Central g Mountain h Pacific i United States 1950 Total .................... 6,794 6,324 7,027 7,455 3,521 3,547 2,277 6,341 3,906 5,367 1955 Total .................... 6,872 6,231 6,486 6,912 3,508 3,513 2,294 6,704 4,320 5,246 1960 Total .................... 6,828 6,391 6,908 7,184 3,780

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    Table 1.10 Cooling Degree Days by Census Division New England a Middle Atlantic b East North Central c West North Central d South Atlantic e East South Central f West South Central g Mountain h Pacific i United States 1950 Total .................... 295 401 505 647 1,414 1,420 2,282 682 629 871 1955 Total .................... 532 761 922 1,139 1,636 1,674 2,508 780 558 1,144 1960 Total .................... 318 487 626 871 1,583 1,532 2,367 974 796 1,000 1965 Total .................... 310 498

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    3 Table 1.1 Primary Energy Overview (Quadrillion Btu) Production Trade Stock Change and Other d Consumption Fossil Fuels a Nuclear Electric Power Renew- able Energy b Total Imports Exports Net Imports c Fossil Fuels e Nuclear Electric Power Renew- able Energy b Total f 1950 Total .................... 32.563 0.000 2.978 35.540 1.913 1.465 0.448 -1.372 31.632 0.000 2.978 34.616 1955 Total .................... 37.364 .000 2.784 40.148 2.790 2.286 .504 -.444 37.410 .000 2.784 40.208 1960 Total

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    2 Primary Energy Production (Quadrillion Btu) By Source, 1949-2015 By Source, Monthly Total, January-July By Source, July 2016 a Natural gas plant liquids. Web Page: http://www.eia.gov/totalenergy/data/monthly/#summary. Source: Table 1.2. 4 U.S. Energy Information Administration / Monthly Energy Review October 2016 2014 2015 2016 Renewable Energy Crude Oil and NGPL a Nuclear Electric Power Coal Natural Gas Crude Oil and NGPL a Renewable Energy Nuclear Electric Power 1950 1955 1960 1965 1970 1975

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    Table 1.2 Primary Energy Production by Source (Quadrillion Btu) Fossil Fuels Nuclear Electric Power Renewable Energy a Total Coal b Natural Gas (Dry) Crude Oil c NGPL d Total Hydro- electric Power e Geo- thermal Solar Wind Bio- mass Total 1950 Total .................. 14.060 6.233 11.447 0.823 32.563 0.000 1.415 NA NA NA 1.562 2.978 35.540 1955 Total .................. 12.370 9.345 14.410 1.240 37.364 .000 1.360 NA NA NA 1.424 2.784 40.148 1960 Total .................. 10.817 12.656 14.935

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    3 Primary Energy Consumption (Quadrillion Btu) By Source, a 1949-2015 By Source, a Monthly Total, January-July By Source, a July 2016 a Small quantities of net imports of coal coke and electricity are not shown. Web Page: http://www.eia.gov/totalenergy/data/monthly/#summary. Source: Table 1.3. 6 U.S. Energy Information Administration / Monthly Energy Review October 2016 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 15 30 45 Petroleum Natural Gas Coal Nuclear Electric

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    7 Table 1.3 Primary Energy Consumption by Source (Quadrillion Btu) Fossil Fuels Nuclear Electric Power Renewable Energy a Total f Coal Natural Gas b Petro- leum c Total d Hydro- electric Power e Geo- thermal Solar Wind Bio- mass Total 1950 Total .................... 12.347 5.968 13.315 31.632 0.000 1.415 NA NA NA 1.562 2.978 34.616 1955 Total .................... 11.167 8.998 17.255 37.410 .000 1.360 NA NA NA 1.424 2.784 40.208 1960 Total .................... 9.838 12.385 19.919 42.137 .006

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    Energy Information Administration (EIA) (indexed site)

    a Primary Energy Imports and Exports (Quadrillion Btu) Imports by Source, 1949-2015 Exports by Source, 1949-2015 Imports by Source, Monthly Exports by Major Source, Monthly a Coal, coal coke, biofuels, and electricity. Web Page: http://www.eia.gov/totalenergy/data/monthly/#summary. b Includes coal coke. Sources: Tables 1.4a and 1.4b. 8 U.S. Energy Information Administration / Monthly Energy Review October 2016 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 5 10 15 20 25

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    b Primary Energy Net Imports (Quadrillion Btu) Total, 1949-2015 By Major Source, 1949-2015 Total, Monthly By Major Source, Monthly U.S. Energy Information Administration / Monthly Energy Review October 2016 9 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 -5 0 5 10 15 20 25 30 35 Natural Gas Crude Oil a Petroleum Products b Coal Crude Oil a 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 -5 0 5 10 15 20 25 0 -5 Petroleum Products b Coal Natural Gas J

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    Energy Information Administration (EIA) (indexed site)

    . Renewable Energy Figure 10.1 Renewable Energy Consumption (Quadrillion Btu) Major Sources, 1949-2015 By Source, 2015 By Sector, 2015 Compared With Other Resources, 1949-2015 150 U.S. Energy Information Administration / Monthly Energy Review October 2016 Solar a Hydroelectric Power b Wind a Renewable Energy a See Table 10.1 for definition. b Conventional hydroelectric power. Web Page: http://www.eia.gov/totalenergy/data/monthly/#renewable. Sources: Tables 1.3 and 10.1-10.2c. Power fuels a

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    8 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 10.6 Solar Electricity Net Generation (Million Kilowatthours) Distributed a Solar Generation b Utility-Scale c Solar Generation b Total Residential Sector Commercial Sector Industrial Sector Total Commercial Sector d Industrial Sector e Electric Power Sector f Total 1985 Total ...................... NA NA NA NA NA NA 11 11 11 1990 Total ...................... 10 14 3 27 - - 367 367 394 1995 Total

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    Energy Information Administration (EIA) (indexed site)

    1 Renewable Energy Consumption (Quadrillion Btu) Major Sources, 1949-2015 By Source, 2015 By Sector, 2015 Compared With Other Resources, 1949-2015 150 U.S. Energy Information Administration / Monthly Energy Review October 2016 Solar a Hydroelectric Power b Wind a Renewable Energy a See Table 10.1 for definition. b Conventional hydroelectric power. Web Page: http://www.eia.gov/totalenergy/data/monthly/#renewable. Sources: Tables 1.3 and 10.1-10.2c. Power fuels a Fossil Fuels Biomass a Nuclear

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    2 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 10.2a Renewable Energy Consumption: Residential and Commercial Sectors (Trillion Btu) Residential Sector Commercial Sector a Geo- thermal b Solar c Biomass Total Hydro- electric Power e Geo- thermal b Solar f Wind g Biomass Total Wood d Wood d Waste h Fuel Ethanol i Total 1950 Total .................... NA NA 1,006 1,006 NA NA NA NA 19 NA NA 19 19 1955 Total .................... NA NA 775 775 NA NA NA NA 15 NA NA

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    4 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 10.2c Renewable Energy Consumption: Electric Power Sector (Trillion Btu) Hydro- electric Power a Geo- thermal b Solar c Wind d Biomass Total Wood e Waste f Total 1950 Total .................... 1,346 NA NA NA 5 NA 5 1,351 1955 Total .................... 1,322 NA NA NA 3 NA 3 1,325 1960 Total .................... 1,569 (s) NA NA 2 NA 2 1,571 1965 Total .................... 2,026 2 NA NA 3 NA 3 2,031 1970 Total

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    U.S. Energy Information Administration / Monthly Energy Review October 2016 157 Table 10.5 Solar Energy Consumption (Trillion Btu) Distributed a Solar Energy b Utility-Scale c Solar Energy b Total k Heat f Electricity d Total g Electricity e Residential Sector Commercial Sector Industrial Sector Total Commercial Sector h Industrial Sector i Electric Power Sector j Total 1985 Total ...................... NA NA NA NA NA NA NA NA (s) (s) (s) 1990 Total ...................... 55 (s) (s) (s) (s) 55 -

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    Energy Information Administration (EIA) (indexed site)

    Energy Note. Renewable Energy Production and Consumption. In Tables 1.1, 1.3, and 10.1, renewable energy consumption consists of: conventional hydroelectricity net generation (converted to Btu by multiplying by the total fossil fuels heat rate factors in Table A6); geothermal electricity net generation (converted to Btu by multiplying by the total fossil fuels heat rate factors in Table A6), and geothermal heat pump and geothermal direct use energy; solar thermal and photovoltaic electricity net

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    . International Petroleum Figure 11.1a World Crude Oil Production Overview (Million Barrels per Day) World Production, 1973-2015 World Production, Monthly Selected Producers, 1973-2015 Selected Producers, Monthly 168 U.S. Energy Information Administration / Monthly Energy Review October 2016 United States 2014 2015 2016 2014 2015 2016 Non-OPEC J F MA M J J A S O N D J F MA M J J A S O N D J F MA M J J A S O N D 0 20 40 60 80 100 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 30 60 90 Non-OPEC

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    a World Crude Oil Production Overview (Million Barrels per Day) World Production, 1973-2015 World Production, Monthly Selected Producers, 1973-2015 Selected Producers, Monthly 168 U.S. Energy Information Administration / Monthly Energy Review October 2016 United States 2014 2015 2016 2014 2015 2016 Non-OPEC J F MA M J J A S O N D J F MA M J J A S O N D J F MA M J J A S O N D 0 20 40 60 80 100 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 30 60 90 Non-OPEC World 1975 1980 1985 1990 1995 2000

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    b World Crude Oil Production by Selected Countries (Million Barrels per Day) U.S. Energy Information Administration / Monthly Energy Review October 2016 169 3.652 3.938 0.482 2.193 1.763 10.254 0.970 8.685 1.320 1.876 0.545 0.845 4.130 4.415 2.570 0.310 1.880 1.537 10.670 2.840 2.220 3.821 4.263 0.524 2.308 1.611 10.213 0.839 9.418 1.370 1.890 0.538 0.772 3.300 4.325 2.550 0.400 2.245 1.537 10.400 2.820 2.500 Canada China Egypt Mexico Norway Russia United Kingdom United States Algeria Angola

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    Energy Information Administration (EIA) (indexed site)

    70 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 11.1a World Crude Oil Production: Selected OPEC Members (Thousand Barrels per Day) Algeria Angola Ecuador Indo- nesia Iran Iraq Kuwait a Libya Nigeria Qatar Saudi Arabia a United Arab Emirates Vene- zuela Total OPEC b 1973 Average ................ 1,097 162 209 1,339 5,861 2,018 3,020 2,175 2,054 570 7,596 1,533 3,366 R 31,150 1975 Average ................ 983 165 161 1,307 5,350 2,262 2,084 1,480 1,783 438

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    1 Table 11.1b World Crude Oil Production: Persian Gulf Nations, Non-OPEC, and World (Thousand Barrels per Day) Persian Gulf Nations b Selected Non-OPEC a Producers Total Non- OPEC a World Canada China Egypt Mexico Norway Former U.S.S.R. Russia United Kingdom United States 1973 Average .................... 20,668 1,798 1,090 165 465 32 8,324 NA 2 9,208 R 24,529 55,679 1975 Average .................... 18,934 1,430 1,490 235 705 189 9,523 NA 12 8,375 R 25,509 52,828 1980 Average

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    3 Table 11.2 Petroleum Consumption in OECD Countries (Thousand Barrels per Day) France Germany a Italy United Kingdom OECD Europe b Canada Japan South Korea United States Other OECD c OECD d World 1973 Average .................... 2,601 3,324 2,068 2,341 15,879 1,729 4,949 281 17,308 1,768 41,913 57,237 1975 Average .................... 2,252 2,957 1,855 1,911 14,314 1,779 4,621 311 16,322 1,885 39,232 56,198 1980 Average .................... 2,256 3,082 1,934 1,725 14,995 1,873 4,960 537 17,056

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    Energy Information Administration (EIA) (indexed site)

    5 Table 11.3 Petroleum Stocks in OECD Countries (Million Barrels) France Germany a Italy United Kingdom OECD Europe b Canada Japan South Korea United States Other OECD c OECD d 1973 Year ......................... 201 181 152 156 1,070 140 303 NA 1,008 67 2,588 1975 Year ......................... 225 187 143 165 1,154 174 375 NA 1,133 67 2,903 1980 Year ......................... 243 319 170 168 1,464 164 495 NA 1,392 72 3,587 1985 Year ......................... 139 277 156 131 1,154 112 500 13

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    6 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 12.7 Carbon Dioxide Emissions From Biomass Energy Consumption (Million Metric Tons of Carbon Dioxide a ) By Source By Sector Wood b Biomass Waste c Fuel Ethanol d Bio- diesel Total Resi- dential Com- mercial e Indus- trial f Trans- portation Electric Power g Total 1973 Total ...................... 143 (s) NA NA 143 33 1 109 NA (s) 143 1975 Total ...................... 140 (s) NA NA 141 40 1 100 NA (s) 141 1980

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    Energy Information Administration (EIA) (indexed site)

    2 Carbon Dioxide Emissions From Energy Consumption by Sector (Million Metric Tons of Carbon Dioxide) Total a by End-Use Sector, b 1973-2015 Residential Sector by Major Source, 1973-2015 Commercial Sector by Major Source, 1973-2015 Industrial Sector by Major Source, 1973-2015 Transportation Sector by Major Source, 1973-2015 Electric Power Sector by Major Source, 1973-2015 180 U.S. Energy Information Administration / Monthly Energy Review October 2016 1975 1980 1985 1990 1995 2000 2005 2010 2015 0

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    Energy Information Administration (EIA) (indexed site)

    4 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 12.5 Carbon Dioxide Emissions From Energy Consumption: Transportation Sector (Million Metric Tons of Carbon Dioxide a ) Coal Natural Gas b Petroleum Retail Elec- tricity f Total g Aviation Gasoline Distillate Fuel Oil c Jet Fuel LPG d Lubri- cants Motor Gasoline e Residual Fuel Oil Total 1973 Total ........................ (s) 39 6 163 152 3 6 886 57 1,273 2 1,315 1975 Total ........................ (s) 32 5 155

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    Energy Information Administration (EIA) (indexed site)

    2. Energy Consumption by Sector Figure 2.1 Energy Consumption by Sector (Quadrillion Btu) Total Consumption by End-Use Sector, 1949-2015 Total Consumption by End-Use Sector, Monthly By Sector, July 2016 28 U.S. Energy Information Administration / Monthly Energy Review October 2016 Transportation Residential 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 10 20 30 40 Industrial Transportation Residential Commercial J F M A M J J A S O N D J F M A M J J A S O N D J F M A M

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    Energy Information Administration (EIA) (indexed site)

    Transportation Sector Energy Consumption (Quadrillion Btu) By Major Source, 1949-2015 By Major Source, Monthly Total, January-July Total, Monthly . 36 U.S. Energy Information Administration / Monthly Energy Review October 2016 2014 2015 2016 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 5 10 15 20 25 30 Petroleum Natural Gas Renewable Energy J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Petroleum Natural Gas

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    Energy Information Administration (EIA) (indexed site)

    Electric Power Sector Energy Consumption (Quadrillion Btu) By Major Source, 1949-2015 By Major Source, Monthly Total, January-July By Major Source, July 2016 . 38 U.S. Energy Information Administration / Monthly Energy Review October 2016 2014 2015 2016 Nuclear Electric Power Natural Gas Petroleum Renewable Energy Coal Renewable Energy Natural Gas 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 4 8 12 16 20 24 J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J

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    Energy Information Administration (EIA) (indexed site)

    9 Table 2.6 Electric Power Sector Energy Consumption (Trillion Btu) Primary Consumption a Fossil Fuels Nuclear Electric Power Renewable Energy b Elec- tricity Net Imports f Total Primary Coal Natural Gas c Petro- leum Total Hydro- electric Power d Geo- thermal Solar e Wind Bio- mass Total 1950 Total ...................... 2,199 651 472 3,322 0 1,346 NA NA NA 5 1,351 6 4,679 1955 Total ...................... 3,458 1,194 471 5,123 0 1,322 NA NA NA 3 1,325 14 6,461 1960 Total ......................

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    0 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 2.7 U.S. Government Energy Consumption by Agency, Fiscal Years (Trillion Btu) Fiscal Year a Agri- culture Defense Energy GSA b HHS c Interior Justice NASA d Postal Service Trans- portation Veterans Affairs Other e Total 1975 .............. 9.5 1,360.2 50.4 22.3 6.5 9.4 5.9 13.4 30.5 19.3 27.1 10.5 1,565.0 1976 .............. 9.3 1,183.3 50.3 20.6 6.7 9.4 5.7 12.4 30.0 19.5 25.0 11.2 1,383.4 1977 ..............

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    Energy Information Administration (EIA) (indexed site)

    1 Table 2.8 U.S. Government Energy Consumption by Source, Fiscal Years (Trillion Btu) Fiscal Year a Coal Natural Gas b Petroleum Other Mobility Fuels f Elec- tricity Purchased Steam and Other g Total Aviation Gasoline Fuel Oil c Jet Fuel LPG d Motor Gasoline e Total 1975 .............. 77.9 166.2 22.0 376.0 707.4 5.6 63.2 1,174.2 0.0 141.5 5.1 1,565.0 1976 .............. 71.3 151.8 11.6 329.7 610.0 4.7 60.4 1,016.4 .0 139.3 4.6 1,383.4 1977 .............. 68.4 141.2 8.8 348.5 619.2 4.1 61.4

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    Energy Information Administration (EIA) (indexed site)

    2.1 Energy Consumption by Sector (Quadrillion Btu) Total Consumption by End-Use Sector, 1949-2015 Total Consumption by End-Use Sector, Monthly By Sector, July 2016 28 U.S. Energy Information Administration / Monthly Energy Review October 2016 Transportation Residential 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 10 20 30 40 Industrial Transportation Residential Commercial J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D 0 1 2 3 4 Industrial

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    Energy Information Administration (EIA) (indexed site)

    1 Table 2.2 Residential Sector Energy Consumption (Trillion Btu) Primary Consumption a Electricity Retail Sales e Electrical System Energy Losses f Total Fossil Fuels Renewable Energy b Total Primary Coal Natural Gas c Petro- leum Total Geo- thermal Solar d Bio- mass Total 1950 Total .................... 1,261 1,240 1,322 3,824 NA NA 1,006 1,006 4,829 246 913 5,989 1955 Total .................... 867 2,198 1,767 4,833 NA NA 775 775 5,608 438 1,232 7,278 1960 Total .................... 585 3,212

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    Energy Information Administration (EIA) (indexed site)

    Commercial Sector Energy Consumption (Quadrillion Btu) By Major Source, 1949-2015 By Major Source, Monthly Total, January-July By Major Source, July 2016 32 U.S. Energy Information Administration / Monthly Energy Review October 2016 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 1 2 3 4 5 Electricity a Natural Gas Petroleum Coal Renewable Energy 2014 2015 2016 J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D 0.0 0.2 0.4 0.6 0.8 Natural Gas

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    Energy Information Administration (EIA) (indexed site)

    3 Table 2.3 Commercial Sector Energy Consumption (Trillion Btu) Primary Consumption a Elec- tricity Retail Sales g Electrical System Energy Losses h Total Fossil Fuels Renewable Energy b Total Primary Coal Natural Gas c Petro- leum d Total Hydro- electric Power e Geo- thermal Solar f Wind Bio- mass Total 1950 Total .................... 1,542 401 872 2,815 NA NA NA NA 19 19 2,834 225 834 3,893 1955 Total .................... 801 651 1,095 2,547 NA NA NA NA 15 15 2,561 350 984 3,895 1960 Total

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    Industrial Sector Energy Consumption (Quadrillion Btu) By Major Source, 1949-2015 By Major Source, Monthly Total, January-July By Major Source, July 2016 34 U.S. Energy Information Administration / Monthly Energy Review October 2016 Coal 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 3 6 9 12 Natural Gas Petroleum Electricity a Renewable Energy J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D 0.0 0.2 0.4 0.6 0.8 1.0 Natural Gas Petroleum

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    Energy Information Administration (EIA) (indexed site)

    5 Table 2.4 Industrial Sector Energy Consumption (Trillion Btu) Primary Consumption a Elec- tricity Retail Sales h Electrical System Energy Losses i Total e Fossil Fuels Renewable Energy b Total Primary Coal Natural Gas c Petro- leum d Total e Hydro- electric Power f Geo- thermal Solar g Wind Bio- mass Total 1950 Total .................... 5,781 3,546 3,960 13,288 69 NA NA NA 532 602 13,890 500 1,852 16,241 1955 Total .................... 5,620 4,701 5,123 15,434 38 NA NA NA 631 669 16,103 887

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    Energy Information Administration (EIA) (indexed site)

    Consumption by Sector Note 1. Electrical System Energy Losses. Electrical system energy losses are calculated as the difference between total primary consumption by the electric power sector (see Table 2.6) and the total energy content of electricity retail sales (see Tables 7.6 and A6). Most of these losses occur at steam- electric power plants (conventional and nuclear) in the conver- sion of heat energy into mechanical energy to turn electric generators. The loss is a thermodynamically

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    6 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 3.3c Petroleum Trade: Imports From OPEC Countries (Thousand Barrels per Day) Algeria a Angola b Ecuador c Iraq Kuwait d Libya e Nigeria f Saudi Arabia d Vene- zuela Other g Total OPEC 1960 Average ...................... a ( ) b ( ) c ( ) 22 182 e ( ) f ( ) 84 911 34 1,233 1965 Average ...................... a ( ) b ( ) c ( ) 16 74 42 f ( ) 158 994 155 1,439 1970 Average ...................... 8 b ( ) c ( ) - 48

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    Energy Information Administration (EIA) (indexed site)

    7 Table 3.3d Petroleum Trade: Imports From Non-OPEC Countries (Thousand Barrels per Day) Brazil Canada Colombia Mexico Nether- lands Norway Russia a United Kingdom U.S. Virgin Islands Other Total Non-OPEC 1960 Average ...................... 1 120 42 16 NA NA - (s) NA NA 581 1965 Average ...................... - 323 51 48 1 - - (s) - 606 1,029 1970 Average ...................... 2 766 46 42 39 - 3 11 189 1,027 2,126 1975 Average ...................... 5 846 9 71 19 17 14 14 406 1,052 2,454 1980

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    Energy Information Administration (EIA) (indexed site)

    3 Table 3.6 Heat Content of Petroleum Products Supplied by Type (Trillion Btu) Asphalt and Road Oil Aviation Gasoline Distillate Fuel Oil b Jet Fuel c Kero- sene LPG a Lubri- cants Motor Gasoline e Petro- leum Coke Residual Fuel Oil Other f Total Propane d Total 1950 Total ...................... 435 199 2,300 c ( ) 668 NA 343 236 5,015 90 3,482 546 13,315 1955 Total ...................... 615 354 3,385 301 662 NA 592 258 6,640 147 3,502 798 17,255 1960 Total ...................... 734 298 3,992

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    Energy Information Administration (EIA) (indexed site)

    5 Table 3.7a Petroleum Consumption: Residential and Commercial Sectors (Thousand Barrels per Day) Residential Sector Commercial Sector a Distillate Fuel Oil Kero- sene Liquefied Petroleum Gases Total Distillate Fuel Oil Kero- sene Liquefied Petroleum Gases Motor Gasoline b Petro- leum Coke Residual Fuel Oil Total 1950 Average .................... 390 168 104 662 123 23 28 52 NA 185 411 1955 Average .................... 562 179 144 885 177 24 38 69 NA 209 519 1960 Average .................... 736

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    Energy Information Administration (EIA) (indexed site)

    6 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 3.7b Petroleum Consumption: Industrial Sector (Thousand Barrels per Day) Industrial Sector a Asphalt and Road Oil Distillate Fuel Oil Kerosene Liquefied Petroleum Gases Lubricants Motor Gasoline b Petroleum Coke Residual Fuel Oil Other c Total 1950 Average .................... 180 328 132 100 43 131 41 617 250 1,822 1955 Average .................... 254 466 116 212 47 173 67 686 366 2,387 1960 Average

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    Energy Information Administration (EIA) (indexed site)

    0 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 3.8a Heat Content of Petroleum Consumption: Residential and Commercial Sectors (Trillion Btu) Residential Sector Commercial Sector a Distillate Fuel Oil Kerosene Liquefied Petroleum Gases Total Distillate Fuel Oil Kerosene Liquefied Petroleum Gases Motor Gasoline b Petroleum Coke Residual Fuel Oil Total 1950 Total ........................ 829 347 146 1,322 262 47 39 100 NA 424 872 1955 Total

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    Energy Information Administration (EIA) (indexed site)

    1 Table 3.8b Heat Content of Petroleum Consumption: Industrial Sector (Trillion Btu) Industrial Sector a Asphalt and Road Oil Distillate Fuel Oil Kerosene Liquefied Petroleum Gases Lubricants Motor Gasoline b Petroleum Coke Residual Fuel Oil Other c Total 1950 Total ........................ 435 698 274 156 94 251 90 1,416 546 3,960 1955 Total ........................ 615 991 241 323 103 332 147 1,573 798 5,123 1960 Total ........................ 734 1,016 161 507 107 381 328 1,584 947 5,766 1965

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    Energy Information Administration (EIA) (indexed site)

    U.S. Energy Information Administration / Monthly Energy Review October 2016 53 Table 3.3a Petroleum Trade: Overview Imports From Persian Gulf a Imports From OPEC b Imports Exports Net Imports Products Supplied As Share of Products Supplied As Share of Total Imports Imports From Persian Gulf a Imports From OPEC b Imports Net Imports Imports From Persian Gulf a Imports From OPEC b Thousand Barrels per Day Percent 1950 Average .................... NA NA 850 305 545 6,458 NA NA 13.2 8.4 NA NA 1955

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    Energy Information Administration (EIA) (indexed site)

    U.S. Energy Information Administration / Monthly Energy Review October 2016 55 Table 3.3b Petroleum Trade: Imports and Exports by Type (Thousand Barrels per Day) Imports Exports Crude Oil a Distillate Fuel Oil Jet Fuel d LPG b Motor Gasoline f Residual Fuel Oil Other g Total Crude Oil a Petroleum Products Total SPR c Total Propane e Total 1950 Average ................ - - 487 7 d ( ) - - (s) 329 27 850 95 210 305 1955 Average ................ - - 782 12 d ( ) - - 13 417 24 1,248 32 336 368 1960

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    Energy Information Administration (EIA) (indexed site)

    Gas Resource Development . 4. Natural Gas Figure 4.1 Natural Gas (Trillion Cubic Feet) Overview, 1949-2015 Consumption by Sector, 1949-2015 Overview, Monthly Consumption by Sector, Monthly Web Page: http://www.eia.gov/totalenergy/data/monthly/#naturalgas. Sources: Tables 4.1 and 4.3. 82 U.S. Energy Information Administration / Monthly Energy Review October 2016 Commercial Electric Power Industrial Industrial Trans- portation Transportation 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000

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    Energy Information Administration (EIA) (indexed site)

    3 Table 4.1 Natural Gas Overview (Billion Cubic Feet) Gross With- drawals a Marketed Production (Wet) b NGPL Production c Dry Gas Production d Supple- mental Gaseous Fuels e Trade Net Storage With- drawals f Balancing Item g Consump- tion h Imports Exports Net Imports 1950 Total .................... 8,480 i 6,282 260 i 6,022 NA 0 26 -26 -54 -175 5,767 1955 Total .................... 11,720 i 9,405 377 i 9,029 NA 11 31 -20 -68 -247 8,694 1960 Total .................... 15,088 i 12,771 543 i

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    Energy Information Administration (EIA) (indexed site)

    4 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 4.2 Natural Gas Trade by Country (Billion Cubic Feet) Imports Exports a Algeria b Canada c Egypt b Mexico c Nigeria b Qatar b Trinidad and Tobago b Other b,d Total Canada c Japan b Mexico c Other b,e Total 1950 Total .................... 0 0 0 0 0 0 0 0 0 3 0 23 0 26 1955 Total .................... 0 11 0 (s) 0 0 0 0 11 11 0 20 0 31 1960 Total .................... 0 109 0 47 0 0 0 0 156 6 0 6 0 11 1965 Total

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    Energy Information Administration (EIA) (indexed site)

    6 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 4.4 Natural Gas in Underground Storage (Volumes in Billion Cubic Feet) Natural Gas in Underground Storage, End of Period Change in Working Gas From Same Period Previous Year Storage Activity Base Gas Working Gas Total a Volume Percent Withdrawals Injections Net b,c 1950 Total .................... NA NA NA NA NA 175 230 -54 1955 Total .................... 863 505 1,368 40 8.7 437 505 -68 1960 Total

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    . Crude Oil and Natural Gas Resource Development Figure 5.1 Crude Oil and Natural Gas Resource Development Indicators Rotary Rigs in Operation by Type, 1949-2015 Rotary Rigs in Operation by Type, Monthly Active Well Service Rig Count, Monthly Total Wells Drilled by Type, 1949-2010 . 90 U.S. Energy Information Administration / Monthly Energy Review October 2016 Total 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 1 2 3 4 Thousand Rigs 1950 1955 1960 1965 1970 1975 1980

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    Energy Information Administration (EIA) (indexed site)

    1 Crude Oil and Natural Gas Resource Development Indicators Rotary Rigs in Operation by Type, 1949-2015 Rotary Rigs in Operation by Type, Monthly Active Well Service Rig Count, Monthly Total Wells Drilled by Type, 1949-2010 . 90 U.S. Energy Information Administration / Monthly Energy Review October 2016 Total 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 1 2 3 4 Thousand Rigs 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 0 10 20 30 40 50 Thousand

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    Energy Information Administration (EIA) (indexed site)

    91 Table 5.1 Crude Oil and Natural Gas Drilling Activity Measurements (Number of Rigs) Rotary Rigs in Operation a Active Well Service Rig Count c By Site By Type Total b Onshore Offshore Crude Oil Natural Gas 1950 Average ........................ NA NA NA NA 2,154 NA 1955 Average ........................ NA NA NA NA 2,686 NA 1960 Average ........................ NA NA NA NA 1,748 NA 1965 Average ........................ NA NA NA NA 1,388 NA 1970 Average ........................ NA NA NA NA 1,028

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    Energy Information Administration (EIA) (indexed site)

    . Coal Figure 6.1 Coal (Million Short Tons) Overview, 1949-2015 Consumption by Sector, 1949-2015 Overview, Monthly Electric Power Sector Consumption, Monthly 96 U.S. Energy Information Administration / Monthly Energy Review October 2016 2014 20 15 2016 Electric Power Consumption J F MA M J J A S O N D J F MA M J J A S O N D J F MA M J J A S O N D 0 20 40 60 80 100 Net Exports 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 200 400 600 800 1,000 1,200 a Includes

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    1 Coal (Million Short Tons) Overview, 1949-2015 Consumption by Sector, 1949-2015 Overview, Monthly Electric Power Sector Consumption, Monthly 96 U.S. Energy Information Administration / Monthly Energy Review October 2016 2014 20 15 2016 Electric Power Consumption J F MA M J J A S O N D J F MA M J J A S O N D J F MA M J J A S O N D 0 20 40 60 80 100 Net Exports 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 200 400 600 800 1,000 1,200 a Includes combined-heat-and-power

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    Energy Information Administration (EIA) (indexed site)

    7 Table 6.1 Coal Overview (Thousand Short Tons) Production a Waste Coal Supplied b Trade Stock Change d,e Losses and Unaccounted for e,f Consumption Imports Exports Net Imports c 1950 Total .................... 560,388 NA 365 29,360 -28,995 27,829 9,462 494,102 1955 Total .................... 490,838 NA 337 54,429 -54,092 -3,974 -6,292 447,012 1960 Total .................... 434,329 NA 262 37,981 -37,719 -3,194 1,722 398,081 1965 Total .................... 526,954 NA 184 51,032 -50,848 1,897

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    Energy Information Administration (EIA) (indexed site)

    8 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 6.2 Coal Consumption by Sector (Thousand Short Tons) End-Use Sectors Electric Power Sector e,f Total Resi- dential Commercial Industrial Trans- portation CHP a Other b Total Coke Plants Other Industrial Total CHP c Non-CHP d Total 1950 Total .................... 51,562 g ( ) 63,021 63,021 104,014 h ( ) 120,623 120,623 224,637 63,011 91,871 494,102 1955 Total .................... 35,590 g ( ) 32,852 32,852 107,743

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    Energy Information Administration (EIA) (indexed site)

    9 Table 6.3 Coal Stocks by Sector (Thousand Short Tons) Producers and Distributors End-Use Sectors Electric Power Sector c,d Total Residential a and Commercial Industrial Total Coke Plants Other b Total 1950 Year ..................... NA 2,462 16,809 26,182 42,991 45,453 31,842 77,295 1955 Year ..................... NA 998 13,422 15,880 29,302 30,300 41,391 71,691 1960 Year ..................... NA 666 11,122 11,637 22,759 23,425 51,735 75,160 1965 Year ..................... NA 353 10,640 13,122

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    Energy Information Administration (EIA) (indexed site)

    4 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 7.3b Consumption of Combustible Fuels for Electricity Generation: Electric Power Sector (Subset of Table 7.3a) Coal a Petroleum Natural Gas f Other Gases g Biomass Other j Distillate Fuel Oil b Residual Fuel Oil c Other Liquids d Petroleum Coke e Total e Wood h Waste i Thousand Short Tons Thousand Barrels Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu 1950 Total .................... 91,871

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    Energy Information Administration (EIA) (indexed site)

    5 Table 7.3c Consumption of Selected Combustible Fuels for Electricity Generation: Commercial and Industrial Sectors (Subset of Table 7.3a) Commercial Sector a Industrial Sector b Coal c Petroleum d Natural Gas e Biomass Coal c Petroleum d Natural Gas e Other Gases g Biomass Other i Waste f Wood h Waste f Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu 1990 Total .................... 417 953 28 15 10,740

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    Energy Information Administration (EIA) (indexed site)

    7 Table 7.4a Consumption of Combustible Fuels for Electricity Generation and Useful Thermal Output: Total (All Sectors) (Sum of Tables 7.4b and 7.4c) Coal a Petroleum Natural Gas f Other Gases g Biomass Other j Distillate Fuel Oil b Residual Fuel Oil c Other Liquids d Petroleum Coke e Total e Wood h Waste i Thousand Short Tons Thousand Barrels Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu 1950 Total .................... 91,871 5,423 69,998 NA NA 75,421 629 NA 5 NA NA 1955

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    Energy Information Administration (EIA) (indexed site)

    8 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 7.4b Consumption of Combustible Fuels for Electricity Generation and Useful Thermal Output: Electric Power Sector (Subset of Table 7.4a) Coal a Petroleum Natural Gas f Other Gases g Biomass Other j Distillate Fuel Oil b Residual Fuel Oil c Other Liquids d Petroleum Coke e Total e Wood h Waste i Thousand Short Tons Thousand Barrels Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu 1950 Total

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    Energy Information Administration (EIA) (indexed site)

    19 Table 7.4c Consumption of Selected Combustible Fuels for Electricity Generation and Useful Thermal Output: Commercial and Industrial Sectors (Subset of Table 7.4a) Commercial Sector a Industrial Sector b Coal c Petroleum d Natural Gas e Biomass Coal c Petroleum d Natural Gas e Other Gases g Biomass Other i Waste f Wood h Waste f Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu 1990 Total

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    Energy Information Administration (EIA) (indexed site)

    21 Table 7.5 Stocks of Coal and Petroleum: Electric Power Sector Coal a Petroleum Distillate Fuel Oil b Residual Fuel Oil c Other Liquids d Petroleum Coke e Total e,f Thousand Short Tons Thousand Barrels Thousand Short Tons Thousand Barrels 1950 Year ............................. 31,842 NA NA NA NA 10,201 1955 Year ............................. 41,391 NA NA NA NA 13,671 1960 Year ............................. 51,735 NA NA NA NA 19,572 1965 Year ............................. 54,525 NA NA NA NA

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    Energy Information Administration (EIA) (indexed site)

    23 Table 7.6 Electricity End Use (Million Kilowatthours) Retail Sales a Direct Use f Total End Use g Residential Commercial b Industrial c Transpor- tation d Total Retail Sales e 1950 Total .................... 72,200 E 65,971 146,479 E 6,793 291,443 NA 291,443 1955 Total .................... 128,401 E 102,547 259,974 E 5,826 496,748 NA 496,748 1960 Total .................... 201,463 E 159,144 324,402 E 3,066 688,075 NA 688,075 1965 Total .................... 291,013 E 231,126 428,727 E 2,923

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    Energy Information Administration (EIA) (indexed site)

    7 Table 7.1 Electricity Overview (Billion Kilowatthours) Net Generation a Trade T&D Losses f and Unaccounted for g End Use Electric Power Sector b Com- mercial Sector c Indus- trial Sector d Total Imports e Exports e Net Imports e Retail Sales h Direct Use i Total 1950 Total .................... 329 NA 5 334 2 (s) 2 44 291 NA 291 1955 Total .................... 547 NA 3 550 5 (s) 4 58 497 NA 497 1960 Total .................... 756 NA 4 759 5 1 5 76 688 NA 688 1965 Total ....................

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    Energy Information Administration (EIA) (indexed site)

    9 Table 7.2a Electricity Net Generation: Total (All Sectors) (Sum of Tables 7.2b and 7.2c; Million Kilowatthours) Fossil Fuels Nuclear Electric Power Hydro- electric Pumped Storage e Renewable Energy Total j Coal a Petro- leum b Natural Gas c Other Gases d Conven- tional Hydro- electric Power f Biomass Geo- thermal Solar i Wind Wood g Waste h 1950 Total .............. 154,520 33,734 44,559 NA 0 f ( ) 100,885 390 NA NA NA NA 334,088 1955 Total .............. 301,363 37,138 95,285 NA 0 f ( )

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    Energy Information Administration (EIA) (indexed site)

    3 Consumption of Selected Combustible Fuels for Electricity Generation Coal by Sector, 1989-2015 Petroleum by Sector, 1989-2015 Natural Gas by Sector, 1989-2015 Other Gases b by Sector, 1989-2015 Wood by Sector, 1989-2015 Waste by Sector, 1989-2015 112 U.S. Energy Information Administration / Monthly Energy Review October 2016 Commercial Industrial Electric Power Electric Power Industrial Industrial Total a Total a 1990 1995 2000 2005 2010 2015 0.0 0.3 0.6 0.9 1.2 Billion Short Tons Total a

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    Energy Information Administration (EIA) (indexed site)

    3 Table 7.3a Consumption of Combustible Fuels for Electricity Generation: Total (All Sectors) (Sum of Tables 7.3b and 7.3c) Coal a Petroleum Natural Gas f Other Gases g Biomass Other j Distillate Fuel Oil b Residual Fuel Oil c Other Liquids d Petroleum Coke e Total e Wood h Waste i Thousand Short Tons Thousand Barrels Thousand Short Tons Thousand Barrels Billion Cubic Feet Trillion Btu 1950 Total .................... 91,871 5,423 69,998 NA NA 75,421 629 NA 5 NA NA 1955 Total ....................

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    Energy Information Administration (EIA) (indexed site)

    8. Nuclear Energy Figure 8.1 Nuclear Energy Overview Electricity Net Generation, 1957-2015 Nuclear Share of Electricity Net Generation, 1957-2015 Nuclear Electricity Net Generation Capacity Factor, Monthly 128 U.S. Energy Information Administration / Monthly Energy Review October 2016 Web Page: http://www.eia.gov/totalenergy/data/monthly/#nuclear. Sources: Tables 7.2a and 8.1. 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 1 2 3 4 5 Trillion Kilowatthours Nuclear Electric Power

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    Energy Information Administration (EIA) (indexed site)

    Nuclear Energy Overview Electricity Net Generation, 1957-2015 Nuclear Share of Electricity Net Generation, 1957-2015 Nuclear Electricity Net Generation Capacity Factor, Monthly 128 U.S. Energy Information Administration / Monthly Energy Review October 2016 Web Page: http://www.eia.gov/totalenergy/data/monthly/#nuclear. Sources: Tables 7.2a and 8.1. 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 1 2 3 4 5 Trillion Kilowatthours Nuclear Electric Power Total 1960 1965 1970 1975 1980

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    Energy Information Administration (EIA) (indexed site)

    U .S. Energy Information Administration / Monthly Energy Review October 2016 129 Table 8.1 Nuclear Energy Overview Total Operable Units a,b Net Summer Capacity of Operable Units b,c Nuclear Electricity Net Generation Nuclear Share of Electricity Net Generation Capacity Factor d Number Million Kilowatts Million Kilowatthours Percent 1957 Total .......................... 1 0.055 10 (s) NA 1960 Total .......................... 3 .411 518 .1 NA 1965 Total .......................... 13 .793 3,657 .3

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    Energy Information Administration (EIA) (indexed site)

    Nuclear Energy Note 1. Operable Nuclear Reactors. A reactor is generally defined as operable while it possessed a full-power license from the Nuclear Regulatory Commission or its predecessor the Atomic Energy Commission, or equivalent permission to operate, at the end of the year or month shown. The definition is liberal in that it does not exclude units retaining full-power licenses during long, non-routine shutdowns that for a time rendered them unable to generate electricity. Examples are:

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    Energy Information Administration (EIA) (indexed site)

    9. Energy Prices Figure 9.1 Petroleum Prices Crude Oil Prices, 1949-2015 Composite Refiner Acquisition Cost, Monthly Refiner Prices to End Users: Selected Products, July 2016 132 U.S. Energy Information Administration / Monthly Energy Review October 2016 a Prices are not adjusted for inflation. See "Nominal Dollars" in Glossary. Web Page: http://www.eia.gov/totalenergy/data/monthly/#prices. Sources: Tables 9.1, 9.5, and 9.7. 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005

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    Energy Information Administration (EIA) (indexed site)

    3 Table 9.9 Cost of Fossil-Fuel Receipts at Electric Generating Plants (Dollars a per Million Btu, Including Taxes) Coal Petroleum Natural Gas e All Fossil Fuels f Residual Fuel Oil b Distillate Fuel Oil c Petroleum Coke Total d 1973 Average .................... 0.41 0.79 NA NA 0.80 0.34 0.48 1975 Average .................... .81 2.01 NA NA 2.02 .75 1.04 1980 Average .................... 1.35 4.27 NA NA 4.35 2.20 1.93 1985 Average .................... 1.65 4.24 NA NA 4.32 3.44 2.09 1990 Average

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    Energy Information Administration (EIA) (indexed site)

    Petroleum Prices Crude Oil Prices, 1949-2015 Composite Refiner Acquisition Cost, Monthly Refiner Prices to End Users: Selected Products, July 2016 132 U.S. Energy Information Administration / Monthly Energy Review October 2016 a Prices are not adjusted for inflation. See "Nominal Dollars" in Glossary. Web Page: http://www.eia.gov/totalenergy/data/monthly/#prices. Sources: Tables 9.1, 9.5, and 9.7. 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 0 20 40 60 80 100

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    Energy Information Administration (EIA) (indexed site)

    3 Table 9.1 Crude Oil Price Summary (Dollars a per Barrel) Domestic First Purchase Price c F.O.B. Cost of Imports d Landed Cost of Imports e Refiner Acquisition Cost b Domestic Imported Composite 1950 Average .................. 2.51 NA NA NA NA NA 1955 Average .................. 2.77 NA NA NA NA NA 1960 Average .................. 2.88 NA NA NA NA NA 1965 Average .................. 2.86 NA NA NA NA NA 1970 Average .................. 3.18 NA NA E 3.46 E 2.96 E 3.40 1975 Average ..................

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    Energy Information Administration (EIA) (indexed site)

    34 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 9.2 F.O.B. Costs of Crude Oil Imports From Selected Countries (Dollars a per Barrel) Selected Countries Persian Gulf Nations b Total OPEC c Total Non-OPEC c Angola Colombia Mexico Nigeria Saudi Arabia United Kingdom Venezuela 1973 Average d ................. W W - 7.81 3.25 - 5.39 3.68 5.43 4.80 1975 Average .................. 10.97 - 11.44 11.82 10.87 - 11.04 10.88 11.34 10.62 1980 Average ..................

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    Energy Information Administration (EIA) (indexed site)

    5 Table 9.3 Landed Costs of Crude Oil Imports From Selected Countries (Dollars a per Barrel) Selected Countries Persian Gulf Nations b Total OPEC c Total Non-OPEC c Angola Canada Colombia Mexico Nigeria Saudi Arabia United Kingdom Venezuela 1973 Average d ............... W 5.33 W - 9.08 5.37 - 5.99 5.91 6.85 5.64 1975 Average ................ 11.81 12.84 - 12.61 12.70 12.50 - 12.36 12.64 12.70 12.70 1980 Average ................ 34.76 30.11 W 31.77 37.15 29.80 35.68 25.92 30.59 33.56 33.99 1985

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    Energy Information Administration (EIA) (indexed site)

    6 U.S. Energy Information Administration / Monthly Energy Review October 2016 Table 9.4 Retail Motor Gasoline and On-Highway Diesel Fuel Prices (Dollars a per Gallon, Including Taxes) Platt's / Bureau of Labor Statistics Data U.S. Energy Information Administration Data Motor Gasoline by Grade Regular Motor Gasoline by Area Type On-Highway Diesel Fuel Leaded Regular Unleaded Regular Unleaded Premium b All Grades c Conventional Gasoline Areas d Reformulated Gasoline Areas e All Areas 1950 Average

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    Energy Information Administration (EIA) (indexed site)

    7 Table 9.5 Refiner Prices of Residual Fuel Oil (Dollars a per Gallon, Excluding Taxes) Residual Fuel Oil Sulfur Content Less Than or Equal to 1% Residual Fuel Oil Sulfur Content Greater Than 1% Average Sales for Resale Sales to End Users Sales for Resale Sales to End Users Sales for Resale Sales to End Users 1978 Average ...................... 0.293 0.314 0.245 0.275 0.263 0.298 1980 Average ...................... .608 .675 .479 .523 .528 .607 1985 Average ...................... .610 .644 .560

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    Energy Information Administration (EIA) (indexed site)

    Table A3. Approximate Heat Content of Petroleum Consumption and Fuel Ethanol (Million Btu ... renewable diesel fuel (including biodiesel) blended into distillate fuel oil. d ...

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    Energy Information Administration (EIA) (indexed site)

    ... fuel oil, excluding biodiesel. d Liquefied petroleum gases. e Finished motor gasoline, excluding fuel ethanol. f Emissions from energy consumption (for electricity and a ...

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    Energy Information Administration (EIA) (indexed site)

    ... fuels. d Distillate fuel oil, excluding biodiesel. e Liquefied petroleum gases. f Finished ... See Table 12.6. i Excludes emissions from biomass energy consumption. See Table 12.7. ...

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    Energy Information Administration (EIA) (indexed site)

    ... renewable diesel fuel (including biodiesel) blended into distillate fuel oil. c ... Notes: * Petroleum products supplied is an approximation of petroleum consumption and is ...

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    Gasoline and Diesel Fuel Update

    ... fuels. c Distillate fuel oil, excluding biodiesel. d Liquefied petroleum gases. e Finished ... products. g Emissions from energy consumption (for electricity and a small amount of ...

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    Energy Information Administration (EIA) (indexed site)

    ... renewable diesel fuel (including biodiesel) blended into distillate fuel oil. c ... * For total heat content of petroleum consumption by all sectors, see data for heat ...

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    ... renewable diesel fuel (including biodiesel) blended into distillate fuel oil. c ... Notes: * Transportation sector data are estimates. * For total petroleum consumption by ...

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    Energy Information Administration (EIA) (indexed site)

    Consumer Price Index, All Urban Consumers a Motor Gasoline b Residential Heating Oil c Residential Natural Gas b Residential Electricity b Index 1982-1984100 Dollars per Gallon ...

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    Energy Information Administration (EIA) (indexed site)

    2 Average Retail Prices of Electricity (Cents a per Kilowatthour) By Sector, 1960-2015 By ... See "Nominal Price" in Glossary. b Public street and highway lighting, interdepartmental ...

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    Energy Information Administration (EIA) (indexed site)

    Crude Oil d NGPL e Other Liquids f Total Distillate Fuel Oil g Jet Fuel h LPG c Motor ... Beginning in 1981, also includes aviation and motor gasoline blending components (net). ...

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    Energy Information Administration (EIA) (indexed site)

    Finished Motor Gasoline b Finished Aviation Gasoline Kerosene- Type Jet Fuel Kerosene No. ... See "Nominal Dollars" in Glossary. b See Note 5, "Motor Gasoline Prices," at end of ...

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    Energy Information Administration (EIA) (indexed site)

    a per Gallon, Excluding Taxes) Finished Motor Gasoline b Finished Aviation Gasoline ... See "Nominal Dollars" in Glossary. b See Note 5, "Motor Gasoline Prices," at end of ...

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    Energy Information Administration (EIA) (indexed site)

    Table 1.8 Motor Vehicle Mileage, Fuel Consumption, and Fuel Economy Light-Duty Vehicles, Short Wheelbase a Light-Duty Vehicles, Long Wheelbase b Heavy-Duty Trucks c All Motor ...

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    Energy Information Administration (EIA) (indexed site)

    ... Revenue may not correspond to sales for a particular month because of energy service provider billing and accounting procedures. That lack of correspondence could result in ...

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    the residential, commercial, and industrial sectors and "Primary Energy Total Consumption" are due, in whole or in part, to the incorporation of new distributed solar energy data. ...

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    used to convert nominal dollars to chained (2005) dollars. RRevised. NANot available. Web Pages: * See http:www.eia.govtotalenergydataannualappendices for all data...

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    Gasoline and Diesel Fuel Update

    ... Beginning in 2009, also includes renewable diesel fuel (including biodiesel). g Beginning in 2009, includes renewable diesel fuel (including biodiesel) blended into distillate fuel ...

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    ... Natural gas, excluding supplemental gaseous fuels. c Distillate fuel oil, excluding biodiesel. d Liquefied petroleum gases. e Emissions from energy consumption (for electricity ...

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    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Table 10.4 Biodiesel and Other Renewable Fuels Overview Biodiesel Other Renew- able Fuels f Feed- stock a Losses and Co- prod- ucts b Production Trade Stocks d Stock Change e ...

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    Energy Information Administration (EIA) (indexed site)

    ... of fuel ethanol and biodiesel. c Wood and wood-derived fuels, biomass waste, and total biomass inputs to the production of fuel ethanol and biodiesel. d Hydroelectric power, ...

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    Gasoline and Diesel Fuel Update

    ... fuels. d Distillate fuel oil, excluding biodiesel. e Liquefied petroleum gases. f Finished ... fuels. c Distillate fuel oil, excluding biodiesel. d Liquefied petroleum gases. e ...

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    Gasoline and Diesel Fuel Update

    ... renewable diesel fuel (including biodiesel) blended into distillate fuel oil. d ... renewable diesel fuel (including biodiesel) blended into distillate fuel oil. g ...

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    Annual Energy Outlook

    ... of fuel ethanol and biodiesel. Does not include natural gas, electricity, and other non-biomass energy used in the production of fuel ethanol and biodiesel-these are included in ...

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    Gasoline and Diesel Fuel Update

    Jet Fuel c Residual Fuel Oil a Beginning in 1993, includes fuel ethanol blended into motor gasoline. b Beginning in 2009, includes renewable diesel fuel (including biodiesel) ...

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    Gasoline and Diesel Fuel Update

    Index 1949100 0.186 0.073 0.043 0.008 Wood Fuel Ethanol Waste Biodiesel 0.00 0.05 0.10 ... fuels. 5 Distillate fuel oil, excluding biodiesel. 6 Liquefied petroleum gases. 7 Finished ...

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    Annual Energy Outlook

    Includes fuel ethanol blended into motor gasoline. d Includes renewable diesel fuel (including biodiesel) blended into distillate fuel oil. e Includes kerosene-type jet fuel only. ...

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    Annual Energy Outlook

    ... converted to Btu by multiplying by the biodiesel heat content factor in Table A1; for ... converted to Btu by multiplying by the biodiesel heat content factor in Table A1; for ...

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    Energy Information Administration (EIA) (indexed site)

    ... be 5.359 million Btu per barrel or equal to the thermal conversion factor for Biodiesel. ... Approximate Heat Content of Biofuels Biodiesel. EIA estimated the thermal conversion ...

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    Energy Information Administration (EIA) (indexed site)

    Asphalt Aviation Distillate Jet Kerosene Liquefied Lubricants Motor Petroleum Residual Other 0.0 0.6 1.2 1.8 Quadrillion Btu a Includes renewable diesel fuel (including biodiesel) ...

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    Gasoline and Diesel Fuel Update

    ... 1244. b Natural gas, excluding supplemental gaseous fuels. c Distillate fuel oil, excluding biodiesel. d Municipal solid waste from non-biogenic sources, and tire-derived fuels. ...

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    Gasoline and Diesel Fuel Update

    ... converted to Btu by multiplying by the biodiesel 22 U.S. Energy Information ... converted to Btu by multiplying by the biodiesel heat content factor in Table A1; for ...

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    Energy Information Administration (EIA) (indexed site)

    ... Does not include biofuels. d Through 2010, data are for biodiesel only. Beginning in 2011, data are for fuel ethanol (minus denaturant) and biodiesel. RRevised. NANot available. ...

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    Gasoline and Diesel Fuel Update

    5 Table 10.3 Fuel Ethanol Overview Feed- stock a Losses and Co- products b Dena- turant c ... used for fuel ethanol. b Losses and co-products from the production of fuel ethanol. ...

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    Annual Energy Outlook

    7 Table 10.3 Fuel Ethanol Overview, 1981-2011 Year Feed- stock 1 Losses and Co- products 2 ... used for fuel ethanol. 2 Losses and co-products from the production of fuel ethanol. ...

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    Gasoline and Diesel Fuel Update

    Gas Note 1. Natural Gas Production. Final annual data are from the U.S. Energy Information Administration's (EIA) Natural Gas Annual (NGA). Data for the two most recent months ...

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    Fossil Fuels Nuclear Electric Power Hydro- electric Pumped Storage e Renewable Energy ... generation from solar thermal and photovoltaic (PV) energy at utility-scale facilities. ...

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    Gasoline and Diesel Fuel Update

    Coal 1,344 1,241 797 516 27 Coal Natural Nuclear Renewable Petro- 0 500 1,000 1,500 J F MA ... Note: Data are for utility-scale facilities. Web Page: http:www.eia.govtotalenergy...

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    Energy Information Administration (EIA) (indexed site)

    ... Coal 1,344 1,241 797 516 27 Coal Natural Nuclear Renewable Petro- 0 500 1,000 1,500 J F MA ... Note: Data are for utility-scale facilities. Web Page: http:www.eia.govtotalenergy...

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    Gasoline and Diesel Fuel Update

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141 10.4 Biodiesel Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ....

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    Annual Energy Outlook

    Primary Consumption a Electricity Retail Sales e Electrical System Energy Losses f Total ... See Note 1, "Electrical System Energy Losses," at end of section. g Beginning in 1978, the ...

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    Energy Information Administration (EIA) (indexed site)

    Publications 330, 811, and 814. * American National Standards InstituteInstitute of Electrical and Electronic Engineers, ANSIIEEE Std 268-1992, pp. 28 and 29. degrees Celsius ...

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    ... "Annual Report of International Electrical ExportImport Data." 1989: DOE, Fossil Energy, Form FE-781R, "Annual Report of International Electrical ExportImport Data." 1990-2000: ...

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    0 U.S. Energy Information Administration Monthly Energy Review June 2016 Table A4. Approximate Heat Content of Natural Gas (Btu per Cubic Foot) Production Consumption a Imports ...

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    Energy Information Administration (EIA) (indexed site)

    EIA, International Energy Statistics Database, June 2016. All Other Countries and ... EIA, International Energy Statistics Database, June 2016. 172 U.S. Energy Information ...

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    Gasoline and Diesel Fuel Update

    Power Sector. . . . . . . . . . . . . . . . 165 12.7 Carbon Dioxide Emissions From Biomass Energy Consumption . . . . . . . . . . . . . . . . . . . . . . . . . . . 166...

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    in the United States, Selected Years, 1635-1945 (Quadrillion Btu) Year Fossil Fuels Renewable Energy Electricity Net Imports Total Coal Natural Gas Petroleum Total...

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    Gasoline and Diesel Fuel Update

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128 9.10 Cost of Fossil-Fuel Receipts at Electric Generating Plants. . . . . . . . . . . . . . . . . . . . . . . ....

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    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127 9.9 Cost of Fossil-Fuel Receipts at Electric Generating Plants. . . . . . . . . . . . . . . . . . . . . . . ....

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    Gasoline and Diesel Fuel Update

    Btu of coal coke net imports. 4 Conventional hydroelectric power, geothermal, solarphotovoltaic, wind, and biomass. 5 Includes industrial combined-heat-and-power (CHP)...

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    Annual Energy Outlook

    Gas 3 Other Gases 4 Total Conventional Hydroelectric Power 6 Biomass Geo- thermal SolarPV 9 Wind Total Wood 7 Waste 8 1949 135.5 28.5 37.0 NA 201.0 0.0 6 ( ) 89.7 0.4 NA NA...

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    2 Natural gas plant liquids. 3 Conventional hydroelectric power, biomass, geothermal, solarphotovoltaic, and wind. 4 Crude oil and petroleum products. Includes imports into the...

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    Gasoline and Diesel Fuel Update

    1,000 2,000 3,000 4,000 5,000 6,000 Degree-Days 30-Year Normal 1 Excludes Alaska and Hawaii. 2 Based on calculations of data from 1971 through 2000. Note: See Appendix C for map...

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    2005 2010 0 500 1,000 1,500 2,000 Degree-Days 30-Year Normal 1 Excludes Alaska and Hawaii. 2 Based on calculations of data from 1971 through 2000. Note: See Appendix C for map...

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    Gasoline and Diesel Fuel Update

    Manufacturing Energy Consumption for All Purposes, 2006 By Energy Source By North American Industry Classification System (NAICS) Code 6 46 U.S. Energy Information Administration / Annual Energy Review 2011 1 Liquefied petroleum gases. 2 Natural gas liquids. 3 See "Breeze" in Glossary. 4 Includes all other types of energy that respondents indicated were consumed or allocated. 5 Energy sources produced onsite from the use of other energy sources but sold or trans- ferred to another

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    Gasoline and Diesel Fuel Update

    2 Natural Gas Production Gross Withdrawals and Dry Gas Production, 1949-2011 Production Flow, 2011 (Trillion Cubic Feet) Gross Withdrawals by Well Type, 2011 180 U.S. Energy Information Administration / Annual Energy Review 2011 Dry Gas Production 1 Volume reduction resulting from the removal of natural gas plant liquids, which are trans- ferred to petroleum supply. 2 Includes natural gas gross withdrawals from coalbed wells and shale gas wells. Source: Table 6.2. Gross Withdrawals 1950 1960

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    Gasoline and Diesel Fuel Update

    7 Coal Mining Productivity Total, 1949-2011 By Mining Method, 2011 By Location, 2011 By Mining Method, 1 1949-2011 By Region and Mining Method, 2011 210 U.S. Energy Information Administration / Annual Energy Review 2011 Mississippi 1 For 1979 forward, includes all coal; prior to 1979, excludes anthracite. Note: Beginning in 2001, surface mining includes a small amount of refuse recovery. Source: Table 7.7. 2.68 15.98 East of the West of the 0 5 10 15 20 Short Tons per Employee Hour 1950 1960

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    Annual Energy Outlook

    Energy GSA 1 HHS 2 Interior Justice NASA 3 Postal Service Trans- portation Veterans Affairs Other 4 Total 1975 9.5 1,360.2 50.4 22.3 6.5 9.4 5.9 13.4 30.5 19.3 27.1 10.5...

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    Energy Information Administration (EIA) (indexed site)

    2 U.S. Energy Information Administration Annual Energy Review 2011 Table A2. Approximate Heat Content of Petroleum Production, Imports, and Exports, Selected Years, 1949-2011...

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    Energy Information Administration (EIA) (indexed site)

    Energy Review 2011 Jet Fuel 1 Distillate fuel oil and residual fuel oil. 2 Includes ethanol blended into motor gasoline. Note: U.S. Government's fiscal year was October 1...

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    Transportation Sector Electric Power Sector 2 Total CHP 3 Other 4 Total Coke Plants Other Industrial Total Electricity Only CHP Total CHP 5 Non-CHP 6 Total 1949 52.4 7 ( ) 64.1 ...

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    Gasoline and Diesel Fuel Update

    historical energy statistics. Included are statistics on total energy production, consumption, trade, and energy prices; overviews of petroleum, natural gas, coal, electricity,...

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    Annual Energy Outlook

    retail sales to ultimate customers by electric utilities and, beginning in 1996, other energy service providers. 8 Use of electricity that is 1) self-generated, 2)...

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    Annual Energy Outlook

    Year Residential Sector Commercial Sector 1 Geo- thermal 2 SolarPV 3 Biomass Total Hydro- electric Power 5 Geo- thermal 2 SolarPV 6 Wind 7 Biomass Total Wood 4 Wood 4 Waste 8 ...

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    Annual Energy Outlook

    Year Hydroelectric Power 1 Geothermal 2 SolarPV 3 Wind 4 Biomass Total Wood 5 Waste 6 ... fossil-fuels heat rate-see Table A6). 3 Solar thermal and photovoltaic (PV) electricity ...

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    Annual Energy Outlook

    Biomass Total Renewable Energy 4 Hydro- electric Power 5 Geo- thermal 6 SolarPV 7 Wind 8 ... 4 Hydroelectric power, geothermal, solar thermalphotovoltaic, wind, and biomass. 5 ...

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    Energy Information Administration (EIA) (indexed site)

    3 Table 1.10 Cooling Degree-Days by Census Division, Selected Years, 1949-2011 Year New England Middle Atlantic East North Central West North Central South Atlantic East South...

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    Annual Energy Outlook

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    Annual Energy Outlook

    (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride-that are transparent to solar (short- wave) radiation but opaque to long-wave (infrared) radiation, thus...

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    Energy Information Administration (EIA) (indexed site)

    Census divisions and the national average. * See Appendix C for map of Census divisions. Web Pages: * See http:www.eia.govtotalenergydataannualsummary for all data...

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    Energy Information Administration (EIA) (indexed site)

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    U.S. Department of Energy (DOE) - all webpages (Extended Search)

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