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Sample records for oxide fuel cell

  1. Solid Oxide Fuel Cells FAQs

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Solid Oxide Fuel Cells FAQs faq-header-big.jpg SOLID OXIDE FUEL CELLS - BASICS Q: What is a fuel cell? A: A fuel cell is a power generation device that converts the chemical energy of a fuel and oxidant directly into electrical energy, with heat and water as byproducts. Since fuel cells produce electricity through an electrochemical reaction and not through a combustion process, they are inherently more efficient and environmentally friendly than conventional electric power generation processes.

  2. Solid oxide fuel cell generator

    DOEpatents

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  3. Solid oxide fuel cell generator

    DOEpatents

    Di Croce, A. Michael; Draper, Robert

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  4. NETL: Solid Oxide Fuel Cells

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Solid Oxide Fuel Cells Solid oxide fuel cells (SOFC) are electrochemical devices that convert chemical energy of a fuel and oxidant directly into electrical energy. Since SOFCs produce electricity through an electrochemical reaction and not through a combustion process, they are much more efficient and environmentally benign than conventional electric power generation processes. Their inherent characteristics make them uniquely suitable to address the environmental, climate change, and water

  5. Solid oxide fuel cell generator

    DOEpatents

    Draper, Robert; George, Raymond A.; Shockling, Larry A.

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  6. Solid oxide fuel cell generator

    DOEpatents

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  7. NETL: Solid Oxide Fuel Cells Publications

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Solid Oxide Fuel Cells Technology Program Plan January 2013 The Solid Oxide Fuel Cells Technology Development Program Plan describes the SOFC R&D efforts in 2013 and beyond. SOFC ...

  8. Interconnection of bundled solid oxide fuel cells

    DOEpatents

    Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

    2014-01-14

    A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

  9. Solid oxide fuel cell with monolithic core

    DOEpatents

    McPheeters, C.C.; Mrazek, F.C.

    1988-08-02

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

  10. Solid oxide fuel cell with monolithic core

    DOEpatents

    McPheeters, Charles C.; Mrazek, Franklin C.

    1988-01-01

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

  11. Interfacial material for solid oxide fuel cell

    DOEpatents

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  12. Nanocrystalline cerium oxide materials for solid fuel cell systems

    SciTech Connect

    Brinkman, Kyle S

    2015-05-05

    Disclosed are solid fuel cells, including solid oxide fuel cells and PEM fuel cells that include nanocrystalline cerium oxide materials as a component of the fuel cells. A solid oxide fuel cell can include nanocrystalline cerium oxide as a cathode component and microcrystalline cerium oxide as an electrolyte component, which can prevent mechanical failure and interdiffusion common in other fuel cells. A solid oxide fuel cell can also include nanocrystalline cerium oxide in the anode. A PEM fuel cell can include cerium oxide as a catalyst support in the cathode and optionally also in the anode.

  13. Sintered electrode for solid oxide fuel cells

    DOEpatents

    Ruka, Roswell J.; Warner, Kathryn A.

    1999-01-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

  14. Solid oxide MEMS-based fuel cells

    DOEpatents

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  15. Generator configuration for solid oxide fuel cells

    DOEpatents

    Reichner, Philip

    1989-01-01

    Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

  16. Tubular solid oxide fuel cell demonstration activities

    SciTech Connect

    Ray, E.R.; Veyo, S.E.

    1995-12-31

    This reports on a solid oxide fuel cell demonstration program in which utilities are provided fully integrated, automatically controlled, packaged solid oxide fuel cell power generation systems. These field units serve to demonstrate to customers first hand the beneficial attributes of the SOFC, to expose deficiencies through experience in order to guide continued development, and to garner real world feedback and data concerning not only cell and stack parameters, but also transportation, installation, permitting and licensing, start-up and shutdown, system alarming, fault detection, fault response, and operator interaction.

  17. Breakout Group 5: Solid Oxide Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5: Solid Oxide Fuel Cells PARTICIPANTS Name Organization Robert Ploessl Corning, Inc. Tim Armstrong Oak Ridge National Laboratory Barbara Heydorn SRI International Suresh Baskaran Pacific Northwest National Laboratory Michael Pambianchi Corning Inc. Fatih Dogan Missouri University of Science and Technology David Watkins Los Alamos National Laboratory Charles Vesely Cummins Power Generation Steven Sinsabaugh Lockheed Martin Brian Borglum Versa Power Robert Stokes Versa Power Joel Doyon FuelCell

  18. Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell (RSOFC), Dual Mode Operation with Low Degradation Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low Degradation Presented ...

  19. Tubular solid oxide fuel cell current collector

    DOEpatents

    Bischoff, Brian L.; Sutton, Theodore G.; Armstrong, Timothy R.

    2010-07-20

    An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

  20. Stability of solid oxide fuel cell materials

    SciTech Connect

    Armstrong, T.R.; Bates, J.L.; Chick, L.A.

    1996-04-01

    Interconnection materials in a solid oxide fuel cell are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. The thermal expansion characteristics of substituted lanthanum and yttrium chromite interconnect materials were evaluated by dilatometry as a function of oxygen partial pressures from 1 atm to 10{sup -18} atm, controlled using a carbon dioxide/hydrogen buffer.

  1. Breakout Group 5: Solid Oxide Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5: Solid Oxide Fuel Cells Breakout Group 5: Solid Oxide Fuel Cells Report from Breakout Group 5 of the Fuel Cell Pre-Solicitation Workshop, January 23-24, 2008 fc_pre-solicitation_workshop_sofc.pdf (49.47 KB) More Documents & Publications DOE Fuel Cell Pre-Solicitation Workshop Agenda, January 23-24, 2008, Golden, Colorado Breakout Group 2: Membrane Electrode Assemblies Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation)

  2. Sintered electrode for solid oxide fuel cells

    DOEpatents

    Ruka, R.J.; Warner, K.A.

    1999-06-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

  3. Open end protection for solid oxide fuel cells

    DOEpatents

    Zafred, Paolo R.; Dederer, Jeffrey T.; Tomlins, Gregory W.; Toms, James M.; Folser, George R.; Schmidt, Douglas S.; Singh, Prabhakar; Hager, Charles A.

    2001-01-01

    A solid oxide fuel cell (40) having a closed end (44) and an open end (42) operates in a fuel cell generator (10) where the fuel cell open end (42) of each fuel cell contains a sleeve (60, 64) fitted over the open end (42), where the sleeve (60, 64) extends beyond the open end (42) of the fuel cell (40) to prevent degradation of the interior air electrode of the fuel cell by fuel gas during operation of the generator (10).

  4. Solid Oxide Fuel Cell and Power System Development at PNNL

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Solid Oxide Fuel Cell and Power Solid Oxide Fuel Cell and Power S t D l t t PNNL S t D l t t PNNL System Development at PNNL System Development at PNNL Larry Chick Energy Materials ...

  5. Solid oxide fuel cell process and apparatus

    DOEpatents

    Cooper, Matthew Ellis; Bayless, David J.; Trembly, Jason P.

    2011-11-15

    Conveying gas containing sulfur through a sulfur tolerant planar solid oxide fuel cell (PSOFC) stack for sulfur scrubbing, followed by conveying the gas through a non-sulfur tolerant PSOFC stack. The sulfur tolerant PSOFC stack utilizes anode materials, such as LSV, that selectively convert H.sub.2S present in the fuel stream to other non-poisoning sulfur compounds. The remaining balance of gases remaining in the completely or near H.sub.2S-free exhaust fuel stream is then used as the fuel for the conventional PSOFC stack that is downstream of the sulfur-tolerant PSOFC. A broad range of fuels such as gasified coal, natural gas and reformed hydrocarbons are used to produce electricity.

  6. Electrocatalyst for alcohol oxidation in fuel cells

    DOEpatents

    Adzic, Radoslav R.; Marinkovic, Nebojsa S.

    2001-01-01

    Binary and ternary electrocatalysts are provided for oxidizing alcohol in a fuel cell. The binary electrocatalyst includes 1) a substrate selected from the group consisting of NiWO.sub.4 or CoWO.sub.4 or a combination thereof, and 2) Group VIII noble metal catalyst supported on the substrate. The ternary electrocatalyst includes 1) a substrate as described above, and 2) a catalyst comprising Group VIII noble metal, and ruthenium oxide or molybdenum oxide or a combination thereof, said catalyst being supported on said substrate.

  7. Solid Oxide Fuel Cells Operating on Alternative and Renewable Fuels

    SciTech Connect

    Wang, Xiaoxing; Quan, Wenying; Xiao, Jing; Peduzzi, Emanuela; Fujii, Mamoru; Sun, Funxia; Shalaby, Cigdem; Li, Yan; Xie, Chao; Ma, Xiaoliang; Johnson, David; Lee, Jeong; Fedkin, Mark; LaBarbera, Mark; Das, Debanjan; Thompson, David; Lvov, Serguei; Song, Chunshan

    2014-09-30

    This DOE project at the Pennsylvania State University (Penn State) initially involved Siemens Energy, Inc. to (1) develop new fuel processing approaches for using selected alternative and renewable fuels – anaerobic digester gas (ADG) and commercial diesel fuel (with 15 ppm sulfur) – in solid oxide fuel cell (SOFC) power generation systems; and (2) conduct integrated fuel processor – SOFC system tests to evaluate the performance of the fuel processors and overall systems. Siemens Energy Inc. was to provide SOFC system to Penn State for testing. The Siemens work was carried out at Siemens Energy Inc. in Pittsburgh, PA. The unexpected restructuring in Siemens organization, however, led to the elimination of the Siemens Stationary Fuel Cell Division within the company. Unfortunately, this led to the Siemens subcontract with Penn State ending on September 23rd, 2010. SOFC system was never delivered to Penn State. With the assistance of NETL project manager, the Penn State team has since developed a collaborative research with Delphi as the new subcontractor and this work involved the testing of a stack of planar solid oxide fuel cells from Delphi.

  8. National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies

    Energy.gov [DOE]

    A compilation of studies examining cathodes for solid oxide fuel cells is available on the Department of Energy’s National Energy Technology Laboratory website. The report, entitled Recent Solid Oxide Fuel Cell Cathode Studies, provides a concise, portfolio-wide synopsis of cathode research conducted under the Office of Fossil Energy’s Solid Oxide Fuel Cells Program.

  9. Solid Oxide Fuel Cell (SOFC) Technology for Greener Airplanes | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy (SOFC) Technology for Greener Airplanes Solid Oxide Fuel Cell (SOFC) Technology for Greener Airplanes Presentation by Larry Chick, Pacific Northwest National Laboratory, at the DOD-DOE Aircraft Petroleum Use Reduction Workshop, September 30, 2010, in Washington, DC. aircraft_9_chick.pdf (2.68 MB) More Documents & Publications Solid Oxide Fuel Cell and Power System Development at PNNL Electrical Generation for More-Electric Aircraft using Solid Oxide Fuel Cells Solid Oxide Fuel

  10. Fuel Transformer Solid Oxide Fuel Cell

    SciTech Connect

    Norman Bessette; Douglas S. Schmidt; Jolyon Rawson; Rhys Foster; Anthony Litka

    2006-07-27

    The following report documents the technical approach and conclusions made by Acumentrics Corporation during latest budget period toward the development of a low cost 10kW tubular SOFC power system. The present program, guided under direction from the National Energy Technology Laboratory of the US DOE, is a nine-year cost shared Cooperative Agreement totaling close to $74M funded both by the US DOE as well as Acumentrics Corporation and its partners. The latest budget period ran from January of 2006 through June 2006. Work focused on cell technology enhancements as well as BOP and power electronics improvements and overall system design. Significant progress was made in increasing cell power enhancements as well as decreasing material cost in a drive to meet the SECA cost targets. The following report documents these accomplishments in detail as well as the layout plans for further progress in next budget period.

  11. FUEL TRANSFORMER SOLID OXIDE FUEL CELL

    SciTech Connect

    Norman Bessette; Douglas S. Schmidt; Jolyon Rawson; Lars Allfather; Anthony Litka

    2005-03-24

    The following report documents the technical approach and conclusions made by Acumentrics Corporation during latest budget period toward the development of a low cost 10kW tubular SOFC power system. The present program, guided under direction from the National Energy Technology Laboratory of the US DOE, is a nine-year cost shared Cooperative Agreement totaling close to $74M funded both by the US DOE as well as Acumentrics Corporation and its partners. The latest budget period ran from July of 2004 through January 2004. Work was focused on cell technology enhancements as well as BOP and power electronics improvements and overall system design. Significant progress was made in increasing cell power enhancements as well as decreasing material cost in a drive to meet the SECA cost targets. The following report documents these accomplishments in detail as well as the lay out plans for further progress in next budget period.

  12. Fuel Transformer Solid Oxide Fuel Cell

    SciTech Connect

    Norman Bessette; Douglas S. Schmidt; Jolyon Rawson; Lars Allfather; Anthony Litka

    2005-08-01

    The following report documents the technical approach and conclusions made by Acumentrics Corporation during latest budget period toward the development of a low cost 10kW tubular SOFC power system. The present program, guided under direction from the National Energy Technology Laboratory of the US DOE, is a nine-year cost shared Cooperative Agreement totaling close to $74M funded both by the US DOE as well as Acumentrics Corporation and its partners. The latest budget period ran from January of 2005 through June 2005. Work focused on cell technology enhancements as well as BOP and power electronics improvements and overall system design. Significant progress was made in increasing cell power enhancements as well as decreasing material cost in a drive to meet the SECA cost targets. The following report documents these accomplishments in detail as well as the layout plans for further progress in next budget period.

  13. Solid oxide fuel cell having monolithic core

    DOEpatents

    Ackerman, J.P.; Young, J.E.

    1983-10-12

    A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

  14. Solid oxide fuel cell generator with removable modular fuel cell stack configurations

    DOEpatents

    Gillett, James E.; Dederer, Jeffrey T.; Zafred, Paolo R.; Collie, Jeffrey C.

    1998-01-01

    A high temperature solid oxide fuel cell generator produces electrical power from oxidation of hydrocarbon fuel gases such as natural gas, or conditioned fuel gases, such as carbon monoxide or hydrogen, with oxidant gases, such as air or oxygen. This electrochemical reaction occurs in a plurality of electrically connected solid oxide fuel cells bundled and arrayed in a unitary modular fuel cell stack disposed in a compartment in the generator container. The use of a unitary modular fuel cell stack in a generator is similar in concept to that of a removable battery. The fuel cell stack is provided in a pre-assembled self-supporting configuration where the fuel cells are mounted to a common structural base having surrounding side walls defining a chamber. Associated generator equipment may also be mounted to the fuel cell stack configuration to be integral therewith, such as a fuel and oxidant supply and distribution systems, fuel reformation systems, fuel cell support systems, combustion, exhaust and spent fuel recirculation systems, and the like. The pre-assembled self-supporting fuel cell stack arrangement allows for easier assembly, installation, maintenance, better structural support and longer life of the fuel cells contained in the fuel cell stack.

  15. Solid oxide fuel cell generator with removable modular fuel cell stack configurations

    DOEpatents

    Gillett, J.E.; Dederer, J.T.; Zafred, P.R.; Collie, J.C.

    1998-04-21

    A high temperature solid oxide fuel cell generator produces electrical power from oxidation of hydrocarbon fuel gases such as natural gas, or conditioned fuel gases, such as carbon monoxide or hydrogen, with oxidant gases, such as air or oxygen. This electrochemical reaction occurs in a plurality of electrically connected solid oxide fuel cells bundled and arrayed in a unitary modular fuel cell stack disposed in a compartment in the generator container. The use of a unitary modular fuel cell stack in a generator is similar in concept to that of a removable battery. The fuel cell stack is provided in a pre-assembled self-supporting configuration where the fuel cells are mounted to a common structural base having surrounding side walls defining a chamber. Associated generator equipment may also be mounted to the fuel cell stack configuration to be integral therewith, such as a fuel and oxidant supply and distribution systems, fuel reformation systems, fuel cell support systems, combustion, exhaust and spent fuel recirculation systems, and the like. The pre-assembled self-supporting fuel cell stack arrangement allows for easier assembly, installation, maintenance, better structural support and longer life of the fuel cells contained in the fuel cell stack. 8 figs.

  16. Tubular solid oxide fuel cell development program

    SciTech Connect

    Ray, E.R.; Cracraft, C.

    1995-12-31

    This paper presents an overview of the Westinghouse Solid Oxide Fuel Cell (SOFC) development activities and current program status. The Westinghouse goal is to develop a cost effective cell that can operate for 50,000 to 100,000 hours. Progress toward this goal will be discussed and test results presented for multiple single cell tests which have now successfully exceeded 56,000 hours of continuous power operation at temperature. Results of development efforts to reduce cost and increase power output of tubular SOFCs are described.

  17. Tubular solid oxide fuel cell developments

    SciTech Connect

    Bratton, R.J.; Singh, P.

    1995-08-01

    An overview of the tubular solid oxide fuel cell (SOFC) development at Westinghouse is presented in this paper. The basic operating principles of SOFCs, evolution in tubular cell design and performance improvement, selection criteria for cell component materials, and cell processing techniques are discussed. The commercial goal is to develop a cell that can operate for 5 to 10 years. Results of cell test operated for more than 50,000 hours are presented. Since 1986, significant progress has been made in the evolution of cells with higher power, lower cost and improved thermal cyclic capability. Also in this period, successively larger multi-kilowatt electrical generators systems have been built and successfully operated for more than 7000 hours.

  18. Solid oxide fuel cell having monolithic core

    DOEpatents

    Ackerman, John P.; Young, John E.

    1984-01-01

    A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween, and each interconnect wall consists of thin layers of the cathode and anode materials sandwiching a thin layer of interconnect material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick.

  19. Solid Oxide Fuel Cell Systems PVL Line

    SciTech Connect

    Susan Shearer - Stark State College; Gregory Rush - Rolls-Royce Fuel Cell Systems

    2012-05-01

    In July 2010, Stark State College (SSC), received Grant DE-EE0003229 from the U.S. Department of Energy (DOE), Golden Field Office, for the development of the electrical and control systems, and mechanical commissioning of a unique 20kW scale high-pressure, high temperature, natural gas fueled Stack Block Test System (SBTS). SSC worked closely with subcontractor, Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) over a 13 month period to successfully complete the project activities. This system will be utilized by RRFCS for pre-commercial technology development and training of SSC student interns. In the longer term, when RRFCS is producing commercial products, SSC will utilize the equipment for workforce training. In addition to DOE Hydrogen, Fuel Cells, and Infrastructure Technologies program funding, RRFCS internal funds, funds from the state of Ohio, and funding from the DOE Solid State Energy Conversion Alliance (SECA) program have been utilized to design, develop and commission this equipment. Construction of the SBTS (mechanical components) was performed under a Grant from the State of Ohio through Ohio's Third Frontier program (Grant TECH 08-053). This Ohio program supported development of a system that uses natural gas as a fuel. Funding was provided under the Department of Energy (DOE) Solid-state Energy Conversion Alliance (SECA) program for modifications required to test on coal synthesis gas. The subject DOE program provided funding for the electrical build, control system development and mechanical commissioning. Performance testing, which includes electrical commissioning, was subsequently performed under the DOE SECA program. Rolls-Royce Fuel Cell Systems is developing a megawatt-scale solid oxide fuel cell (SOFC) stationary power generation system. This system, based on RRFCS proprietary technology, is fueled with natural gas, and operates at elevated pressure. A critical success factor for development of the full scale system is the capability to

  20. Electrocatalysts for Alcohol Oxidation in Fuel Cells - Energy Innovation

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Portal Electrocatalysts for Alcohol Oxidation in Fuel Cells Brookhaven National Laboratory Contact BNL About This Technology <p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the best commercially available catalyst for methanol oxidation.</p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the

  1. Solid Oxide Fuel Cell Manufacturing Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Manufacturing Overview Solid Oxide Fuel Cell Manufacturing Overview Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, DC, August 11-12, 2011. Solid Oxide Fuel Cell Manufacturing Overview (1.16 MB) More Documents & Publications Progress on the Development of Reversible SOFC Stack Technology Reversible Fuel Cells Workshop Summary Report Materials and System Issues with Reversible SOFC

  2. Advanced materials for solid oxide fuel cells

    SciTech Connect

    Armstrong, T.; Stevenson, J.

    1995-12-31

    The purpose of this research is to improve the properties of the current state-of-the-art materials used for solid oxide fuel cells (SOFCs). The objectives are to: (1) develop materials based on modifications of the state-of-the-art materials; (2) minimize or eliminate stability problems in the cathode, anode, and interconnect; (3) Electrochemically evaluate (in reproducible and controlled laboratory tests) the current state-of-the-art air electrode materials and cathode/electrolyte interfacial properties; (4) Develop accelerated electrochemical test methods to evaluate the performance of SOFCs under controlled and reproducible conditions; and (5) Develop and test materials for use in low-temperature SOFCs.

  3. Solid oxide fuel cell matrix and modules

    DOEpatents

    Riley, B.

    1988-04-22

    Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs. 11 figs.

  4. Tubular screen electrical connection support for solid oxide fuel cells

    DOEpatents

    Tomlins, Gregory W.; Jaszcar, Michael P.

    2002-01-01

    A solid oxide fuel assembly is made of fuel cells (16, 16', 18, 24, 24', 26), each having an outer interconnection layer (36) and an outer electrode (28), which are disposed next to each other with rolled, porous, hollow, electrically conducting metal mesh conductors (20, 20') between the fuel cells, connecting the fuel cells at least in series along columns (15, 15') and where there are no metal felt connections between any fuel cells.

  5. Solid oxide fuel cell power system development

    SciTech Connect

    Kerr, Rick; Wall, Mark; Sullivan, Neal

    2015-06-26

    This report summarizes the progress made during this contractual period in achieving the goal of developing the solid oxide fuel cell (SOFC) cell and stack technology to be suitable for use in highly-efficient, economically-competitive, commercially deployed electrical power systems. Progress was made in further understanding cell and stack degradation mechanisms in order to increase stack reliability toward achieving a 4+ year lifetime, in cost reduction developments to meet the SECA stack cost target of $175/kW (in 2007 dollars), and in operating the SOFC technology in a multi-stack system in a real-world environment to understand the requirements for reliably designing and operating a large, stationary power system.

  6. Solid oxide fuel cell matrix and modules

    DOEpatents

    Riley, Brian (Willimantic, CT)

    1990-01-01

    Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). Each of the blocks includes a square center channel which forms a vertical shaft when the blocks are arranged in a stacked array. Positioned within the channel is a SOFC unit cell such that a plurality of such SOFC units disposed within a vertical shaft form a string of SOFC units coupled in series. A first pair of facing inner walls of each of the blocks each include an interconnecting channel hole cut horizontally and vertically into the block walls to form gas exit channels. A second pair of facing lateral walls of each block further include a pair of inner half circular grooves which form sleeves to accommodate anode fuel and cathode air tubes. The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs.

  7. Annual Solid Oxide Fuel Cell (SOFC) Workshop Accommodations

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    th Annual Solid Oxide Fuel Cell (SOFC) Workshop Accommodations Pittsburgh Airport Marriott 777 Aten Road Coraopolis, PA 15108 (412)788-8800 The Pittsburgh Airport Marriott Hotel is ...

  8. Solid Oxide Fuel Cell Technologies: Improved Electrode-Electrode...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Solid Oxide Fuel Cell Technologies: Improved Electrode-Electrode Structures for Solid State Electrochemical Devices Lawrence Berkeley National Laboratory Contact LBL About This ...

  9. Materials issues in solid oxide fuel cell systems

    SciTech Connect

    Ziomek-Moroz, M.

    2007-03-02

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). The presence of carbon oxides in the fuel can cause significant performance problems resulting in decreasing the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC below ~800 C may allow less expensive metallic materials to be used for interconnects. This presentation provides insight on the material performance of ferritic steels in fuels containing carbon oxides and seeks to quantify the extent of possible degradation due to carbon species in the gas stream.

  10. High power density solid oxide fuel cells

    DOEpatents

    Pham, Ai Quoc; Glass, Robert S.

    2004-10-12

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O (LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  11. Connections for solid oxide fuel cells

    DOEpatents

    Collie, Jeffrey C.

    1999-01-01

    A connection for fuel cell assemblies is disclosed. The connection includes compliant members connected to individual fuel cells and a rigid member connected to the compliant members. Adjacent bundles or modules of fuel cells are connected together by mechanically joining their rigid members. The compliant/rigid connection permits construction of generator fuel cell stacks from basic modular groups of cells of any desired size. The connections can be made prior to installation of the fuel cells in a generator, thereby eliminating the need for in-situ completion of the connections. In addition to allowing pre-fabrication, the compliant/rigid connections also simplify removal and replacement of sections of a generator fuel cell stack.

  12. Nanostructured Solid Oxide Fuel Cell Electrodes

    SciTech Connect

    Sholklapper, Tal Zvi

    2007-12-15

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  13. Solid oxide fuel cell operable over wide temperature range

    DOEpatents

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    2001-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  14. Stack configurations for tubular solid oxide fuel cells

    DOEpatents

    Armstrong, Timothy R.; Trammell, Michael P.; Marasco, Joseph A.

    2010-08-31

    A fuel cell unit includes an array of solid oxide fuel cell tubes having porous metallic exterior surfaces, interior fuel cell layers, and interior surfaces, each of the tubes having at least one open end; and, at least one header in operable communication with the array of solid oxide fuel cell tubes for directing a first reactive gas into contact with the porous metallic exterior surfaces and for directing a second reactive gas into contact with the interior surfaces, the header further including at least one busbar disposed in electrical contact with at least one surface selected from the group consisting of the porous metallic exterior surfaces and the interior surfaces.

  15. Solid Oxide Fuel Cells | Department of Energy

    Energy.gov [DOE] (indexed site)

    Fuel cells are an energy user's dream: an efficient, combustion-less, virtually pollution-free power source, capable of being sited in downtown urban areas or in remote regions ...

  16. NETL: Solid Oxide Fuel Cells Operating Principles

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    (Water-gas shift reactors for PEM and PAFC operate in the 200 to 350C ... will continue to flow as long as air flow, fuel flow, and cell temperature are maintained. ...

  17. Solid Oxide Fuel Cell Manufacturing Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R&D Workshop August 11-12, 2011 Washington, DC Mark Richards, Eric Tang, Randy Petri Copyright © 2011 Versa Power Systems. All Rights Reserved. 2 Contents  Manufacturing development dependencies  SOFC elements  Cell manufacturing processes - Materials - Forming - Conditioning  Stack assembly  Quality control and testing  VPS projected cost reductions in SECA Copyright © 2011 Versa Power Systems.

  18. Electrode electrolyte interlayers containing cerium oxide for electrochemical fuel cells

    DOEpatents

    Borglum, Brian P.; Bessette, Norman F.

    2000-01-01

    An electrochemical cell is made having a porous fuel electrode (16) and a porous air electrode (13), with solid oxide electrolyte (15) therebetween, where the air electrode surface opposing the electrolyte has a separate, attached, dense, continuous layer (14) of a material containing cerium oxide, and where electrolyte (16) contacts the continuous oxide layer (14), without contacting the air electrode (13).

  19. FY 2014 Solid Oxide Fuel Cell Project Selections

    Energy.gov [DOE]

    In FY 2014, nine research projects focused on advancing the reliability, robustness, and endurance of solid oxide fuel cells (SOFC) have been selected for funding by Office of Fossil Energy’s...

  20. Solid Oxide Fuel Cell Systems for APU Functions and Beyond |...

    Energy.gov [DOE] (indexed site)

    of FreedomCAR and Vehicle Technologies (OFCVT). deer07grieve.pdf (105.13 KB) More Documents & Publications Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs ...

  1. solid oxide fuel cells | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    solid oxide fuel cells sofc.jpg Imagine an efficient, combustion-less, virtually pollution-free power source capable of being sited in urban areas or in remote regions, running...

  2. Solid Oxide Fuel Cell and Power System Development at PNNL |...

    Energy.gov [DOE] (indexed site)

    Presented at the DOE-DOD Shipboard APU Workshop on March 29, 2011. apu20119chick.pdf (1.77 MB) More Documents & Publications Solid Oxide Fuel Cell (SOFC) Technology for Greener ...

  3. Fuel cell power supply with oxidant and fuel gas switching

    DOEpatents

    McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

    1987-04-14

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

  4. Fuel cell power supply with oxidant and fuel gas switching

    DOEpatents

    McElroy, James F.; Chludzinski, Paul J.; Dantowitz, Philip

    1987-01-01

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

  5. OXIDATION OF FUELS IN THE COOL FLAME REGIME FOR COMBUSTION AND REFORMING FOR FUEL CELLS.

    SciTech Connect

    NAIDJA,A.; KRISHNA,C.R.; BUTCHER,T.; MAHAJAN,D.

    2002-08-01

    THE REVIEW INTEGRATES RECENT INVESTIGATIONS ON AUTO OXIDATION OF FUEL OILS AND THEIR REFORMING INTO HYDROGEN RICH GAS THAT COULD SERVE AS A FEED FOR FUEL CELLS AND COMBUSTION SYSTEMS.

  6. Nondestructive characterization methods for monolithic solid oxide fuel cells

    SciTech Connect

    Ellingson, W.A.

    1993-01-01

    Monolithic solid oxide fuel cells (MSOFCS) represent a potential breakthrough in fuel cell technology, provided that reliable fabrication methods can be developed. Fabrication difficulties arise in several steps of the processing: First is the fabrication of uniform thin (305 {mu}m) single-layer and trilayer green tapes (the trilayer tapes of anode/electrolyte/cathode and anode/interconnect/cathode must have similar coefficients of thermal expansion to sinter uniformly and to have the necessary electrochemical properties); Second is the development of fuel and oxidant channels in which residual stresses are likely to develop in the tapes; Third is the fabrication of a ``complete`` cell for which the bond quality between layers and the quality of the trilayers must be established; and Last, attachment of fuel and oxidant manifolds and verification of seal integrity. Purpose of this report is to assess nondestructive characterization methods that could be developed for application to laboratory, prototype, and full-scale MSOFCs.

  7. Method of fabricating a monolithic solid oxide fuel cell

    DOEpatents

    Minh, N.Q.; Horne, C.R.

    1994-03-01

    In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array. 10 figures.

  8. Method of fabricating a monolithic solid oxide fuel cell

    DOEpatents

    Minh, Nguyen Q.; Horne, Craig R.

    1994-01-01

    In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array.

  9. Dynamic Modeling in Solid-Oxide Fuel Cells Controller Design

    SciTech Connect

    Lu, Ning; Li, Qinghe; Sun, Xin; Khaleel, Mohammad A.

    2007-06-28

    In this paper, a dynamic model of the solid-oxide fuel cell (SOFC) power unit is developed for the purpose of designing a controller to regulate fuel flow rate, fuel temperature, air flow rate, and air temperature to maintain the SOFC stack temperature, fuel utilization rate, and voltage within operation limits. A lumped model is used to consider the thermal dynamics and the electro-chemial dynamics inside an SOFC power unit. The fluid dynamics at the fuel and air inlets are considered by using the in-flow ramp-rates.

  10. Serially connected solid oxide fuel cells having monolithic cores

    DOEpatents

    Herceg, Joseph E. (Naperville, IL)

    1987-01-01

    A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

  11. Tubular solid oxide fuel cell prospect

    SciTech Connect

    Veyo, S.E.

    1996-05-01

    Driven by technological achievement and rational projection of commercial product cost, expectations for tubular SOFC commercialization are improving. Tubular SOFCs have surpassed 7 yrs operation and have recently demonstrated remarkable toughness in thermal cycling. Customer-owned systems with 25 kW stacks utilizing air electrode supported (AES) cells continue to operate directly on natural gas without degradation after multiple thermal cycles and over 4000 hrs operation. AES cell operation at elevated pressure corroborates theoretical estimates of performance gain without evidence of deleterious effect. Commercial class AES cell of 22 mm dia and 1500 mm length, is now in production for application to 100 kW, 50% efficient (ac/LHV), atmospheric pressure systems. This same cell applied to pressurized systems in combination with conventional turbo machinery (gas turbines) can yield an efficiency approaching 70% for power plants as small as 5 MW. Total installed system cost for commercial 5 MW SOFC/CT units for distributed power generation and on-site cogeneration should approach $1000/kW. A major challenge is formation of funded projects to demonstrate at the turn of the century prototype MW class SOFC/CT combined cycle power plants and to complete the development of commercial fuel cell manufacturing processes.

  12. LG Solid Oxide Fuel Cell (SOFC) Model Development

    SciTech Connect

    Haberman, Ben; Martinez-Baca, Carlos; Rush, Greg

    2013-05-31

    This report presents a summary of the work performed by LG Fuel Cell Systems Inc. during the project LG Solid Oxide Fuel Cell (SOFC) Model Development (DOE Award Number: DE-FE0000773) which commenced on October 1, 2009 and was completed on March 31, 2013. The aim of this project is for LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) to develop a multi-physics solid oxide fuel cell (SOFC) computer code (MPC) for performance calculations of the LGFCS fuel cell structure to support fuel cell product design and development. A summary of the initial stages of the project is provided which describes the MPC requirements that were developed and the selection of a candidate code, STAR-CCM+ (CD-adapco). This is followed by a detailed description of the subsequent work program including code enhancement and model verification and validation activities. Details of the code enhancements that were implemented to facilitate MPC SOFC simulations are provided along with a description of the models that were built using the MPC and validated against experimental data. The modeling work described in this report represents a level of calculation detail that has not been previously available within LGFCS.

  13. A Total Cost of Ownership Model for Solid Oxide Fuel Cells in...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    A Total Cost of Ownership Model for Solid Oxide Fuel Cells in Combined Heat and Power and ... Efficiency and Renewable Energy (EERE) Fuel Cells Technologies Office (FCTO) under ...

  14. The effect of chromium oxyhydroxide on solid oxide fuel cells.

    SciTech Connect

    Krumpelt, M.; Cruse, T. A.; Ingram, B. J.; Routbort, J. L.; Wang, S.; Salvador, P. A.; Chen, G.; Carnegie Mellon Univ.; NETL; Ohio Univ.

    2010-01-01

    Hexavalent chromium species like the oxyhydroxide, CrO{sub 2}(OH){sub 2}, or hexoxide, CrO{sub 3}, are electrochemically reduced to Cr{sub 2}O{sub 3} in solid oxide fuel cells and adversely affect the cell operating potentials. Using a narrowly focused beam from the Advanced Photon Source, such chromium oxide deposits were unequivocally identified in the active region of the cathode by X-ray diffraction, suggesting that the triple phase boundaries were partially blocked. Under fuel cell operating conditions, the reaction has an equilibrium potential of about 0.9 V and the rate of chromium oxide deposition is therefore dependent on the operating potential of the cell. It becomes diffusion limited after several hours of steady operation. At low operating potentials, lanthanum manganite cathodes begin to be reduced to MnO, which reacts with the chromium oxide to form the MnCr{sub 2}O{sub 4} spinel.

  15. The low-temperature partial oxidation reforming of fuels for transportation fuel cell systems

    SciTech Connect

    Kumar, R.; Ahmed, S.; Krumpelt, M.

    1996-12-31

    Argonne`s partial-oxidation reformer (APOR) is a compact, lightweight, rapid-start, and dynamically responsive device to convert liquid fuels to H{sub 2} for use in automotive fuel cells. An APOR catalyst for methanol has been developed and tested; catalysts for other fuels are being evaluated. Simple in design, operation, and control, the APOR can help develop efficient fuel cell propulsion systems.

  16. Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell

    DOEpatents

    Ruka, Roswell J.; Vora, Shailesh D.

    2001-01-01

    A fuel cell structure (2) is provided, having a pre-sintered nickel-zirconia fuel electrode (6) and an air electrode (4), with a ceramic electrolyte (5) disposed between the electrodes, where the pre-sintered fuel electrode (6) contains particles selected from the group consisting of nickel oxide, cobalt and cerium dioxide particles and mixtures thereof, and titanium dioxide particles, within a matrix of yttria-stabilized zirconia and spaced-apart filamentary nickel strings having a chain structure, and where the fuel electrode can be sintered to provide an active solid oxide fuel cell.

  17. Five Kilowatt Solid Oxide Fuel Cell/Diesel Reformer

    SciTech Connect

    Dennis Witmer; Thomas Johnson

    2008-12-31

    Reducing fossil fuel consumption both for energy security and for reduction in global greenhouse emissions has been a major goal of energy research in the US for many years. Fuel cells have been proposed as a technology that can address both these issues--as devices that convert the energy of a fuel directly into electrical energy, they offer low emissions and high efficiencies. These advantages are of particular interest to remote power users, where grid connected power is unavailable, and most electrical power comes from diesel electric generators. Diesel fuel is the fuel of choice because it can be easily transported and stored in quantities large enough to supply energy for small communities for extended periods of time. This projected aimed to demonstrate the operation of a solid oxide fuel cell on diesel fuel, and to measure the resulting efficiency. Results from this project have been somewhat encouraging, with a laboratory breadboard integration of a small scale diesel reformer and a Solid Oxide Fuel Cell demonstrated in the first 18 months of the project. This initial demonstration was conducted at INEEL in the spring of 2005 using a small scale diesel reformer provided by SOFCo and a fuel cell provided by Acumentrics. However, attempts to integrate and automate the available technology have not proved successful as yet. This is due both to the lack of movement on the fuel processing side as well as the rather poor stack lifetimes exhibited by the fuel cells. Commercial product is still unavailable, and precommercial devices are both extremely expensive and require extensive field support.

  18. Solid oxide fuel cell with single material for electrodes and interconnect

    DOEpatents

    McPheeters, Charles C.; Nelson, Paul A.; Dees, Dennis W.

    1994-01-01

    A solid oxide fuel cell having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed therebetween, and the anode, cathode and interconnect elements are comprised of substantially one material.

  19. Electrode Performance in Reversible Solid Oxide Fuel Cells

    SciTech Connect

    Marina, Olga A.; Pederson, Larry R.; Williams, Mark C.; Coffey, Greg W.; Meinhardt, Kerry D.; Nguyen, Carolyn D.; Thomsen, Ed C.

    2007-03-22

    The performance of several negative (fuel) and positive (air) electrode compositions for use in reversible solid oxide fuel cells (SOFC) that are capable of operating both as a fuel cell and as an electrolyzer was investigated in half-cell and full-cell tests. Negative electrode compositions studied were a nickel/zirconia cermet (Ni/YSZ) and lanthanum-substituted strontium titanate/ceria composite, whereas positive electrode compositions examined included mixed ion and electron-conducting lanthanum strontium ferrite (LSF), lanthanum strontium copper ferrite (LSCuF), lanthanum strontium cobalt ferrite (LSCoF), and lanthanum strontium manganite (LSM). While titanate/ceria and Ni/YSZ electrodes performed similarly in the fuel cell mode in half-cell tests, losses associated with electrolysis were lower for the titanate/ceria electrode. Positive electrodes all gave higher losses in the electrolysis mode when compared to the fuel cell mode. This behavior was most apparent for mixed-conducting LSF, LSCuF, and LSCoF electrodes, and discernible but smaller for LSM; observations are consistent with expected trends in the interfacial oxygen vacancy concentration under anodic and cathodic polarization. Full-cell tests conducted for cells with a thin electrolyte (7 um YSZ) similarly showed higher polarization losses in the electrolysis than fuel cell direction.

  20. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOEpatents

    Adzic, Radoslav; Kowal, Andrzej

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  1. Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation

    SciTech Connect

    David Deangelis; Rich Depuy; Debashis Dey; Georgia Karvountzi; Nguyen Minh; Max Peter; Faress Rahman; Pavel Sokolov; Deliang Yang

    2004-09-30

    This report summarizes the work performed by Hybrid Power Generation Systems, LLC (HPGS) during the April to October 2004 reporting period in Task 2.3 (SOFC Scaleup for Hybrid and Fuel Cell Systems) under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL), entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. This study analyzes the performance and economics of power generation systems for central power generation application based on Solid Oxide Fuel Cell (SOFC) technology and fueled by natural gas. The main objective of this task is to develop credible scale up strategies for large solid oxide fuel cell-gas turbine systems. System concepts that integrate a SOFC with a gas turbine were developed and analyzed for plant sizes in excess of 20 MW. A 25 MW plant configuration was selected with projected system efficiency of over 65% and a factory cost of under $400/kW. The plant design is modular and can be scaled to both higher and lower plant power ratings. Technology gaps and required engineering development efforts were identified and evaluated.

  2. Solid oxide fuel cell steam reforming power system

    DOEpatents

    Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

    2013-03-12

    The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

  3. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  4. Nanofiber Scaffold for Cathode of Solid Oxide Fuel Cell

    SciTech Connect

    Mingjia Zhi; Nicholas Mariani; Randall Gemmen; Kirk Gerdes; Nianqiang Wu

    2010-10-01

    A high performance solid oxide fuel cell cathode using the yttria-stabilized zirconia (YSZ) nanofibers scaffold with the infiltrated La1-xSrxMnO3 (LSM) shows an enhanced catalytic activity toward oxygen reduction. Such a cathode offers a continuous path for charge transport and an increased number of triple-phase boundary sites.

  5. Effects of Humidity on Solid Oxide Fuel Cell Cathodes

    SciTech Connect

    Hardy, John S.; Stevenson, Jeffry W.; Singh, Prabhakar; Mahapatra, Manoj K.; Wachsman, E. D.; Liu, Meilin; Gerdes, Kirk R.

    2015-03-17

    This report summarizes results from experimental studies performed by a team of researchers assembled on behalf of the Solid-state Energy Conversion Alliance (SECA) Core Technology Program. Team participants employed a variety of techniques to evaluate and mitigate the effects of humidity in solid oxide fuel cell (SOFC) cathode air streams on cathode chemistry, microstructure, and electrochemical performance.

  6. Solid-oxide fuel cell electrolyte

    DOEpatents

    Bloom, Ira D.; Hash, Mark C.; Krumpelt, Michael

    1993-01-01

    A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

  7. Digital Sofcell Shanghai ShenLi Goeta solid oxide fuel cell joint...

    OpenEI (Open Energy Information) [EERE & EIA]

    ShenLi Goeta solid oxide fuel cell joint venture Jump to: navigation, search Name: Digital Sofcell - Shanghai ShenLi - Goeta solid oxide fuel cell joint venture Place: China...

  8. Current status of Westinghouse tubular solid oxide fuel cell program

    SciTech Connect

    Parker, W.G.

    1996-04-01

    In the last ten years the solid oxide fuel cell (SOFC) development program at Westinghouse has evolved from a focus on basic material science to the engineering of fully integrated electric power systems. Our endurance for this cell is 5 to 10 years. To date we have successfully operated at power for over six years. For power plants it is our goal to have operated before the end of this decade a MW class power plant. Progress toward these goals is described.

  9. Electrical contact structures for solid oxide electrolyte fuel cell

    DOEpatents

    Isenberg, Arnold O.

    1984-01-01

    An improved electrical output connection means is provided for a high temperature solid oxide electrolyte type fuel cell generator. The electrical connection of the fuel cell electrodes to the electrical output bus, which is brought through the generator housing to be connected to an electrical load line maintains a highly uniform temperature distribution. The electrical connection means includes an electrode bus which is spaced parallel to the output bus with a plurality of symmetrically spaced transversely extending conductors extending between the electrode bus and the output bus, with thermal insulation means provided about the transverse conductors between the spaced apart buses. Single or plural stages of the insulated transversely extending conductors can be provided within the high temperatures regions of the fuel cell generator to provide highly homogeneous temperature distribution over the contacting surfaces.

  10. Santa Clara County Planar Solid Oxide Fuel Cell Demonstration Project

    SciTech Connect

    Fred Mitlitsky; Sara Mulhauser; David Chien; Deepak Shukla; David Weingaertner

    2009-11-14

    The Santa Clara County Planar Solid Oxide Fuel Cell (PSOFC) project demonstrated the technical viability of pre-commercial PSOFC technology at the County 911 Communications headquarters, as well as the input fuel flexibility of the PSOFC. PSOFC operation was demonstrated on natural gas and denatured ethanol. The Santa Clara County Planar Solid Oxide Fuel Cell (PSOFC) project goals were to acquire, site, and demonstrate the technical viability of a pre-commercial PSOFC technology at the County 911 Communications headquarters. Additional goals included educating local permit approval authorities, and other governmental entities about PSOFC technology, existing fuel cell standards and specific code requirements. The project demonstrated the Bloom Energy (BE) PSOFC technology in grid parallel mode, delivering a minimum 15 kW over 8760 operational hours. The PSOFC system demonstrated greater than 81% electricity availability and 41% electrical efficiency (LHV net AC), providing reliable, stable power to a critical, sensitive 911 communications system that serves geographical boundaries of the entire Santa Clara County. The project also demonstrated input fuel flexibility. BE developed and demonstrated the capability to run its prototype PSOFC system on ethanol. BE designed the hardware necessary to deliver ethanol into its existing PSOFC system. Operational parameters were determined for running the system on ethanol, natural gas (NG), and a combination of both. Required modeling was performed to determine viable operational regimes and regimes where coking could occur.

  11. Ionic conductors for solid oxide fuel cells

    DOEpatents

    Krumpelt, Michael; Bloom, Ira D.; Pullockaran, Jose D.; Myles, Kevin M.

    1993-01-01

    An electrolyte that operates at temperatures ranging from 600.degree. C. to 800.degree. C. is provided. The electrolyte conducts charge ionically as well as electronically. The ionic conductors include molecular framework structures having planes or channels large enough to transport oxides or hydrated protons and having net-positive or net-negative charges. Representative molecular framework structures include substituted aluminum phosphates, orthosilicates, silicoaluminates, cordierites, apatites, sodalites, and hollandites.

  12. Serially connected solid oxide fuel cells having monolithic cores

    DOEpatents

    Herceg, J.E.

    1985-05-20

    Disclosed is a solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output. The cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

  13. Iron aluminide alloy container for solid oxide fuel cells

    DOEpatents

    Judkins, Roddie Reagan; Singh, Prabhakar; Sikka, Vinod Kumar

    2000-01-01

    A container for fuel cells is made from an iron aluminide alloy. The container alloy preferably includes from about 13 to about 22 weight percent Al, from about 2 to about 8 weight percent Cr, from about 0.1 to about 4 weight percent M selected from Zr and Hf, from about 0.005 to about 0.5 weight percent B or from about 0.001 to about 1 weight percent C, and the balance Fe and incidental impurities. The iron aluminide container alloy is extremely resistant to corrosion and metal loss when exposed to dual reducing and oxidizing atmospheres at elevated temperatures. The alloy is particularly useful for containment vessels for solid oxide fuel cells, as a replacement for stainless steel alloys which are currently used.

  14. SOLID OXIDE FUEL CELL HYBRID SYSTEM FOR DISTRIBUTED POWER GENERATION

    SciTech Connect

    Kurt Montgomery; Nguyen Minh

    2003-08-01

    This report summarizes the work performed by Honeywell during the October 2001 to December 2001 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a turbogenerator. The conceptual and demonstration system designs were proposed and analyzed, and these systems have been modeled in Aspen Plus. Work has also started on the assembly of dynamic component models and the development of the top-level controls requirements for the system. SOFC stacks have been fabricated and performance mapping initiated.

  15. Method to fabricate high performance tubular solid oxide fuel cells

    DOEpatents

    Chen, Fanglin; Yang, Chenghao; Jin, Chao

    2013-06-18

    In accordance with the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes forming an asymmetric porous ceramic tube by using a phase inversion process. The method further includes forming an asymmetric porous ceramic layer on a surface of the asymmetric porous ceramic tube by using a phase inversion process. The tube is co-sintered to form a structure having a first porous layer, a second porous layer, and a dense layer positioned therebetween.

  16. The low-temperature partial-oxidation reforming of fuels for transportation fuel cell systems

    SciTech Connect

    Kumar, R.; Ahmed, S.; Krumpelt, M.

    1996-12-31

    Passenger cars powered by fuel cell propulsion systems with high efficiency offer superior fuel economy, very low to zero pollutant emissions, and the option to operate on alternative and/or renewable fuels. Although the fuel cell operates on hydrogen, a liquid fuel such as methanol or gasoline is more attractive for automotive use because of the convenience in handling and vehicle refueling. Such a liquid fuel must be dynamically converted (reformed) to hydrogen on board the vehicle in real time to meet fluctuating power demands. This paper describes the low-temperature Argonne partial-oxidation reformer (APOR) developed for this application. The APOR is a rapid-start, compact, lightweight, catalytic device that is efficient and dynamically responsive. The reformer is easily controlled by varying the feed rates of the fuel, water, and air to satisfy the rapidly changing system power demands during the vehicle`s driving cycle.

  17. DOE Selects Research Projects to Advance Solid Oxide Fuel Cell Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Research Projects to Advance Solid Oxide Fuel Cell Technology DOE Selects Research Projects to Advance Solid Oxide Fuel Cell Technology July 13, 2015 - 10:00am Addthis The Department of Energy's (DOE) National Energy Technology Laboratory (NETL) has selected for funding 16 solid oxide fuel cell (SOFC) technology research projects. Fuel cells are a modular, efficient, and virtually pollution-free power generation technology. In Fiscal Year (FY) 2015, NETL issued two

  18. Development of an External Fuel Processor for a Solid Oxide Fuel Cell

    SciTech Connect

    Daniel Birmingham; Crispin Debellis; Mark Perna; Anant Upadhyayula

    2008-02-28

    A 250 kW External Fuel Processor was developed and tested that will supply the gases needed by a pipeline natural gas fueled, solid oxide fuel cell during all modes of operation. The fuel processor consists of three major subsystems--a desulfurizer to remove fuel sulfur to an acceptable level, a synthesis gas generator to support plant heat-up and low load fuel cell operations, and a start gas generator to supply a non-flammable, reducing gas to the fuel cell during startup and shutdown operations. The desulfurization subsystem uses a selective catalytic sulfur oxidation process that was developed for operation at elevated pressure and removes the fuel sulfur to a total sulfur content of less than 80 ppbv. The synthesis gas generation subsystem uses a waterless, catalytic partial oxidation reactor to produce a hydrogen-rich mixture from the natural gas and air. An operating window was defined that allows carbon-free operation while maintaining catalyst temperatures that will ensure long-life of the reactor. The start gas subsystem generates an oxygen-free, reducing gas from the pipeline natural gas using a low-temperature combustion technique. These physically and thermally integrated subsystems comprise the 250 kW External Fuel Processor. The 250 kW External Fuel Processor was tested at the Rolls-Royce facility in North Canton, Ohio to verify process performance and for comparison with design specifications. A step wise operation of the automatic controls through the startup, normal operation and shutdown sequences allowed the control system to be tuned and verified. A fully automated system was achieved that brings the fuel processor through its startup procedure, and then await commands from the fuel cell generator module for fuel supply and shutdown. The fuel processor performance met all design specifications. The 250 kW External Fuel Processor was shipped to an American Electric Power site where it will be tested with a Rolls-Royce solid oxide fuel cell

  19. AlliedSignal solid oxide fuel cell technology

    SciTech Connect

    Minh, N.; Barr, K.; Kelly, P.; Montgomery, K.

    1996-12-31

    AlliedSignal has been developing high-performance, lightweight solid oxide fuel cell (SOFC) technology for a broad spectrum of electric power generation applications. This technology is well suited for use in a variety of power systems, ranging from commercial cogeneration to military mobile power sources. The AlliedSignal SOFC is based on stacking high-performance thin-electrolyte cells with lightweight metallic interconnect assemblies to form a compact structure. The fuel cell can be operated at reduced temperatures (600{degrees} to 800{degrees}C). SOFC stacks based on this design has the potential of producing 1 kW/kg and 1 ML. This paper summarizes the technical status of the design, manufacture, and operation of AlliedSignal SOFCs.

  20. Method and apparatus for assembling solid oxide fuel cells

    DOEpatents

    Szreders, B.E.; Campanella, N.

    1988-05-11

    This invention relates generally to solid oxide fuel power generators and is particularly directed to improvements in the assembly and coupling of solid oxide fuel cell modules. A plurality of jet air tubes are supported and maintained in a spaced matrix array by a positioning/insertion assembly for insertion in respective tubes of a solid oxide fuel cell (SOFC) in the assembly of an SOFC module. The positioning/insertion assembly includes a plurality of generally planar, elongated, linear vanes which are pivotally mounted at each end thereof to a support frame. A rectangular compression assembly of adjustable size is adapted to receive and squeeze a matrix of SOFC tubes so as to compress the inter-tube nickel felt conductive pads which provide series/parallel electrical connection between adjacent SOFCs, with a series of increasingly larger retainer frames used to maintain larger matrices of SOFC tubes in position. Expansion of the SOFC module housing at the high operating temperatures of the SOFC is accommodated by conductive, flexible, resilient expansion, connector bars which provide support and electrical coupling at the top and bottom of the SOFC module housing. 17 figs.

  1. SOLID STATE ENERGY CONVERSION ALLIANCE DELPHI SOLID OXIDE FUEL CELL

    SciTech Connect

    Steven Shaffer; Sean Kelly; Subhasish Mukerjee; David Schumann; Gail Geiger; Kevin Keegan; John Noetzel; Larry Chick

    2003-12-08

    The objective of Phase I under this project is to develop a 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. During Phase I, the following will be accomplished: Develop and demonstrate technology transfer efforts on a 5 kW stationary distributed power generation system that incorporates steam reforming of natural gas with the option of piped-in water (Demonstration System A). Initiate development of a 5 kW system for later mass-market automotive auxiliary power unit application, which will incorporate Catalytic Partial Oxidation (CPO) reforming of gasoline, with anode exhaust gas injected into an ultra-lean burn internal combustion engine. This technical progress report covers work performed by Delphi from January 1, 2003 to June 30, 2003, under Department of Energy Cooperative Agreement DE-FC-02NT41246. This report highlights technical results of the work performed under the following tasks: Task 1 System Design and Integration; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant (BOP) Components; Task 5 Manufacturing Development (Privately Funded); Task 6 System Fabrication; Task 7 System Testing; Task 8 Program Management; and Task 9 Stack Testing with Coal-Based Reformate.

  2. Gas Cleaning for Remote Solid Oxide Fuel Cell (SOFC) Applications

    Energy.gov [DOE] (indexed site)

    up for Fuel Cell Applications, Argonne National Lab Fuel (NG, LPG, LFG, ADG, APG, biodiesel) opportunities and impurity issues Gas Cleaning for Remote SOFC Applications Acumentrics ...

  3. Planar solid oxide fuel cell with staged indirect-internal air and fuel preheating and reformation

    DOEpatents

    2003-10-21

    A solid oxide fuel cell arrangement and method of use that provides internal preheating of both fuel and air in order to maintain the optimum operating temperature for the production of energy. The internal preheat passes are created by the addition of two plates, one on either side of the bipolar plate, such that these plates create additional passes through the fuel cell. This internal preheat fuel cell configuration and method reduce the requirements for external heat exchanger units and air compressors. Air or fuel may be added to the fuel cell as required to maintain the optimum operating temperature through a cathode control valve or an anode control valve, respectively. A control loop comprises a temperature sensing means within the preheat air and fuel passes, a means to compare the measured temperature to a set point temperature and a determination based on the comparison as to whether the control valves should allow additional air or fuel into the preheat or bypass manifolds of the fuel cell.

  4. Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur

    SciTech Connect

    Ziomek-Moroz, M.; Hawk, Jeffrey A.

    2005-01-01

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

  5. Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

    SciTech Connect

    Chen, Fanglin; Zhao, Fei; Liu, Qiang

    2015-10-06

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  6. Cost projections for planar solid oxide fuel cell systems

    SciTech Connect

    Krist, K.; Wright, J.D.; Romero, C.; Chen, Tan Ping

    1996-12-31

    The Gas Research Institute (GRI) is funding fundamental research on solid oxide fuel cells (SOFCs) that operate at reduced temperature. As part of this effort, we have carried out engineering analysis to determine what areas of research can have the greatest effect on the commercialization of SOFCs. Previous papers have evaluated the markets for SOFCs and the amount which a customer will be willing to pay for fuel cell systems or stacks in these markets, the contribution of materials costs to the total stack cost, and the benefits and design requirements associated with reduced temperature operation. In this paper, we describe the cost of fabricating SOFC stacks by different methods. The complete analysis is available in report form.

  7. Solid oxide fuel cell having a glass composite seal

    DOEpatents

    De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

    2013-04-16

    A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

  8. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOEpatents

    Brian, Riley; Szreders, Bernard E.

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  9. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOEpatents

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  10. Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Operation with Low Degradation | Department of Energy for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low Degradation Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low Degradation Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 petri_versa%20_power_kickoff.pdf (3.53 MB) More Documents & Publications Reversible Fuel Cells Workshop Summary Report Progress on the

  11. Fuel cell-fuel cell hybrid system

    DOEpatents

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  12. Air feed tube support system for a solid oxide fuel cell generator

    DOEpatents

    Doshi, Vinod B. (Monroeville, PA); Ruka, Roswell J. (Pittsburgh, PA); Hager, Charles A. (Zelienople, PA)

    2002-01-01

    A solid oxide fuel cell generator (12), containing tubular fuel cells (36) with interior air electrodes (18), where a supporting member (82) containing a plurality of holes (26) supports oxidant feed tubes (51), which pass from an oxidant plenum (52") into the center of the fuel cells, through the holes (26) in the supporting member (82), where a compliant gasket (86) around the top of the oxidant feed tubes and on top (28) of the supporting member (82) helps support the oxidant feed tubes and center them within the fuel cells, and loosen the tolerance for centering the air feed tubes.

  13. New Catalysts for Direct Methanol Oxidation Fuel Cells

    SciTech Connect

    Adzic, Radoslav

    1998-08-01

    A new class of efficient electrocatalytic materials based on platinum - metal oxide systems has been synthetized and characterized by several techniques. Best activity was found with NiWO{sub 4}-, CoWO{sub 4}-, and RuO{sub 2}- srpported platinum catalysts. A very similar activity at room temperature was observed with the electrodes prepared with the catalyst obtained from International Fuel Cells Inc. for the same Pt loading. Surprisingly, the two tungstates per se show a small activity for methanol oxidation without any Pt loading. Synthesis of NiWO{sub 4} and CoWO{sub 4} were carried out by solid-state reactions. FTIR spectroscopy shows that the tungstates contain a certain amount of physically adsorbed water even after heating samples at 200{degrees}C. A direct relationship between the activity for methanol oxidation and the amount of adsorbed water on those oxides has been found. The Ru(0001) single crystal shows a very small activity for CO adsorption and oxidation, in contrast to the behavior of polycrystalline Ru. In situ extended x-ray absorption fine structure spectroscopy (EXAFS) and x-ray absorption near edge spectroscopy (XANES) showed that the OH adsorption on Ru in the Pt-Ru alloy appears to be the limiting step in methanol oxidation. This does not occur for Pt-RuO{SUB 2} electrocatalyst, which explains its advantages over the Pt-Ru alloys. The IFCC electrocatalyst has the properties of the Pt-Ru alloy.

  14. Method for producing electricity from a fuel cell having solid-oxide ionic electrolyte

    DOEpatents

    Mason, David M.

    1984-01-01

    Stabilized quadrivalent cation oxide electrolytes are employed in fuel cells at elevated temperatures with a carbon and/or hydrogen containing fuel anode and an oxygen cathode. The fuel cell is operated at elevated temperatures with conductive metallic coatings as electrodes and desirably having the electrolyte surface blackened. Of particular interest as the quadrivalent oxide is zirconia.

  15. Solid oxide fuel cell having compound cross flow gas patterns

    DOEpatents

    Fraioli, Anthony V.

    1985-01-01

    A core construction for a fuel cell is disclosed having both parallel and cross flow passageways for the fuel and the oxidant gases. Each core passageway is defined by electrolyte and interconnect walls. Each electrolyte wall consists of cathode and anode materials sandwiching an electrolyte material. Each interconnect wall is formed as a sheet of inert support material having therein spaced small plugs of interconnect material, where cathode and anode materials are formed as layers on opposite sides of each sheet and are electrically connected together by the interconnect material plugs. Each interconnect wall in a wavy shape is connected along spaced generally parallel line-like contact areas between corresponding spaced pairs of generally parallel electrolyte walls, operable to define one tier of generally parallel flow passageways for the fuel and oxidant gases. Alternate tiers are arranged to have the passageways disposed normal to one another. Solid mechanical connection of the interconnect walls of adjacent tiers to the opposite sides of the common electrolyte wall therebetween is only at spaced point-like contact areas, 90 where the previously mentioned line-like contact areas cross one another.

  16. Solid oxide fuel cell having compound cross flow gas patterns

    DOEpatents

    Fraioli, A.V.

    1983-10-12

    A core construction for a fuel cell is disclosed having both parallel and cross flow passageways for the fuel and the oxidant gases. Each core passageway is defined by electrolyte and interconnect walls. Each electrolyte wall consists of cathode and anode materials sandwiching an electrolyte material. Each interconnect wall is formed as a sheet of inert support material having therein spaced small plugs of interconnect material, where cathode and anode materials are formed as layers on opposite sides of each sheet and are electrically connected together by the interconnect material plugs. Each interconnect wall in a wavy shape is connected along spaced generally parallel line-like contact areas between corresponding spaced pairs of generally parallel electrolyte walls, operable to define one tier of generally parallel flow passageways for the fuel and oxidant gases. Alternate tiers are arranged to have the passageways disposed normal to one another. Solid mechanical connection of the interconnect walls of adjacent tiers to the opposite sides of the common electrolyte wall therebetween is only at spaced point-like contact areas, 90 where the previously mentioned line-like contact areas cross one another.

  17. SOLID STATE ENERGY CONVERSION ALLIANCE DELPHI SOLID OXIDE FUEL CELL

    SciTech Connect

    Steven Shaffer; Sean Kelly; Subhasish Mukerjee; David Schumann; Gail Geiger; Kevin Keegan; Larry Chick

    2004-05-07

    The objective of this project is to develop a 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. During Phase I, the following will be accomplished: Develop and demonstrate technology transfer efforts on a 5 kW stationary distributed power generation system that incorporates steam reforming of natural gas with the option of piped-in water (Demonstration System A). Initiate development of a 5 kW system for later mass-market automotive auxiliary power unit application, which will incorporate Catalytic Partial Oxidation (CPO) reforming of gasoline, with anode exhaust gas injected into an ultra-lean burn internal combustion engine. This technical progress report covers work performed by Delphi from July 1, 2003 to December 31, 2003, under Department of Energy Cooperative Agreement DE-FC-02NT41246. This report highlights technical results of the work performed under the following tasks: Task 1 System Design and Integration; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant (BOP) Components; Task 5 Manufacturing Development (Privately Funded); Task 6 System Fabrication; Task 7 System Testing; Task 8 Program Management; Task 9 Stack Testing with Coal-Based Reformate; and Task 10 Technology Transfer from SECA CORE Technology Program. In this reporting period, unless otherwise noted Task 6--System Fabrication and Task 7--System Testing will be reported within Task 1 System Design and Integration. Task 8--Program Management, Task 9--Stack Testing with Coal Based Reformate, and Task 10--Technology Transfer from SECA CORE Technology Program will be reported on in the Executive Summary section of this report.

  18. Recent progress in tubular solid oxide fuel cell technology

    SciTech Connect

    Singhal, S.C.

    1997-12-31

    The tubular design of solid oxide fuel cells (SOFCs) and the materials used therein have been validated by successful, continuous electrical testing over 69,000 h of early technology cells built on a calcia-stabilized zirconia porous support tube (PST). In the latest technology cells, the PST has been eliminated and replaced by a doped lanthanum manganite air electrode tube. These air electrode supported (AES) cells have shown a power density increase of about 33% with a significantly improved performance stability over the previously used PST type cells. These cells have also demonstrated the ability to thermally cycle over 100 times without any mechanical damage or performance loss. In addition, recent changes in processes used to fabricate these cells have resulted in significant cost reduction. This paper reviews the fabrication and performance of the state-of-the-art AES tubular cells. It also describes the materials and processing studies that are underway to further reduce the cell cost, and summarizes the recently built power generation systems that employed state-of-the-art AES cells.

  19. Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Balance of Plant and Stack Component Integration Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration Presentation by Acumentrics Corporation for Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration March 16, 2010 fuelcell_pre-solicitation_wkshop_mar10_bessette.pdf (1.75 MB) More Documents & Publications The Micro-CHP Technologies Roadmap, December 2003 High Temperature BOP and Fuel Processing Ceramic Fuel Cells (SOFC)

  20. Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE for Further Development | Department of Energy Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by DOE for Further Development Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by DOE for Further Development July 27, 2012 - 1:00pm Addthis Washington, D.C. - Seven projects that will help develop low-cost solid oxide fuel cell (SOFC) technology for environmentally responsible central power generation from the Nation's abundant fossil energy

  1. Air electrode composition for solid oxide fuel cell

    DOEpatents

    Kuo, Lewis; Ruka, Roswell J.; Singhal, Subhash C.

    1999-01-01

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell.

  2. Air electrode composition for solid oxide fuel cell

    DOEpatents

    Kuo, L.; Ruka, R.J.; Singhal, S.C.

    1999-08-03

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO{sub 3}. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell. 3 figs.

  3. Glass-Ceramic Seal for Solid-Oxide Fuel Cells - Energy Innovation...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Contact PNNL About This Technology Scientists at PNNL are developing materials and techniques used to fabricate solid oxide fuel cells. Scientists at PNNL are developing...

  4. Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Presentation by Acumentrics Corporation for Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration March 16, 2010 fuelcellpre-solicitationwkshopmar10bessette.pd...

  5. Glass Fiber Mesh Method of Joining for Solid Oxide Fuel Cells...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Glass Fiber Mesh Method of Joining for Solid Oxide Fuel Cells Pacific Northwest National Laboratory Contact PNNL About This Technology A simple schematic shows the physical...

  6. Fuel Cells

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of 175 per kW, and ...

  7. Apparatus tube configuration and mounting for solid oxide fuel cells

    DOEpatents

    Zymboly, Gregory E. (Murrysville, PA)

    1993-01-01

    A generator apparatus (10) is made containing long, hollow, tubular, fuel cells containing an inner air electrode (64), an outer fuel electrode (56), and solid electrolyte (54) therebetween, placed between a fuel distribution board (29) and a board (32) which separates the combustion chamber (16) from the generating chamber (14), where each fuel cell has an insertable open end and in insertable, plugged, closed end (44), the plugged end being inserted into the fuel distribution board (29) and the open end being inserted through the separator board (32) where the plug (60) is completely within the fuel distribution board (29).

  8. Solid oxide fuel cell with single material for electrodes and interconnect

    DOEpatents

    McPheeters, C.C.; Nelson, P.A.; Dees, D.W.

    1994-07-19

    A solid oxide fuel cell is described having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed there between, and the anode, cathode and interconnect elements are comprised of substantially one material. 9 figs.

  9. Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)

    SciTech Connect

    Mark Perna; Anant Upadhyayula; Mark Scotto

    2012-11-05

    Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

  10. Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation) |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy System (SOFC) Technology R&D Needs (Presentation) Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation) Presented at the DOE Fuel Cell Pre-Solicitation Workshop held January 23-24, 2008 in Golden, Colorado. fuelcell_pre-solicitation_wkshop_jan08_delphi.pdf (1.7 MB) More Documents & Publications DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 3: HIGH TEMP (SOFC) SYSTEM AND BOP Breakout Group 5: Solid Oxide Fuel Cells DOE Fuel Cell

  11. Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    3 Path: 247 Reliability for Renewables: Source: Water The VPS Storage f Wind Fuel Cell f Solar Electrolyzer Continuous SOFC Intermittent Power Power In Out Air, Oxygen Hydrogen ...

  12. Cover and startup gas supply system for solid oxide fuel cell generator

    DOEpatents

    Singh, P.; George, R.A.

    1999-07-27

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

  13. Cover and startup gas supply system for solid oxide fuel cell generator

    DOEpatents

    Singh, Prabhakar; George, Raymond A.

    1999-01-01

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

  14. Probabilistic Based Design Methodology for Solid Oxide Fuel Cell Stacks

    SciTech Connect

    Sun, Xin; Tartakovsky, Alexandre M.; Khaleel, Mohammad A.

    2009-05-01

    A probabilistic-based component design methodology is developed for solid oxide fuel cell (SOFC) stack. This method takes into account the randomness in SOFC material properties as well as the stresses arising from different manufacturing and operating conditions. The purpose of this work is to provide the SOFC designers a design methodology such that desired level of component reliability can be achieved with deterministic design functions using an equivalent safety factor to account for the uncertainties in material properties and structural stresses. Multi-physics-based finite element analyses were used to predict the electrochemical and thermal mechanical responses of SOFC stacks with different geometric variations and under different operating conditions. Failures in the anode and the seal were used as design examples. The predicted maximum principal stresses in the anode and the seal were compared with the experimentally determined strength characteristics for the anode and the seal respectively. Component failure probabilities for the current design were then calculated under different operating conditions. It was found that anode failure probability is very low under all conditions examined. The seal failure probability is relatively high, particularly for high fuel utilization rate under low average cell temperature. Next, the procedures for calculating the equivalent safety factors for anode and seal were demonstrated such that uniform failure probability of the anode and seal can be achieved. Analysis procedures were also included for non-normal distributed random variables such that more realistic distributions of strength and stress can be analyzed using the proposed design methodology.

  15. 2016 Solid Oxide Fuel Cells Project Portfolio | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The mission of the Solid Oxide Fuel Cell Program is to enable the generation of efficient, low-cost electricity with intrinsic carbon capture capabilities for near-term solid oxide ...

  16. Testing of a Catalytic Partial Oxidation Diesel Reformer with a Solid Oxide Fuel Cell System

    SciTech Connect

    Lyman Frost; Bob Carrington; Rodger McKain; Dennis Witmer

    2005-03-01

    Rural Alaska currently uses diesel generator sets to produce much of its power. The high energy content of diesel (i.e. ~140,000 BTU per gallon) makes it the fuel of choice because this reduces the volume of fuel that must be transported, stored, and consumed in generating the power. There is an existing investment in infrastructure for the distribution and use of diesel fuel. Problems do exist, however, in that diesel generators are not very efficient in their use of diesel, maintenance levels can be rather high as systems age, and the environmental issues related to present diesel generators are of concern. The Arctic Energy Technology Development Laboratory at the University of Alaska -- Fairbanks is sponsoring a project to address the issues mentioned above. The project takes two successful systems, a diesel reformer and a tubular solid oxide fuel cell unit, and jointly tests those systems with the objective of producing a for-purpose diesel fueled solid oxide fuel cell system that can be deployed in rural Alaska. The reformer will convert the diesel to a mixture of carbon monoxide and hydrogen that can be used as a fuel by the fuel cell. The high temperature nature of the solid oxide fuel cell (SOFC is capable of using this mixture to generate electricity and provide usable heat with higher efficiency and lower emissions. The high temperature nature of the SOFC is more compatible with the arctic climate than are low temperature technologies such as the proton exchange membrane fuel cells. This paper will look at the interaction of a SOFC system that is designed to internally reform methane and a catalytic partial oxidation (CPOX) diesel reformer. The diesel reformer produces a reformate that is approximately 140 BTU per scf (after removal of much of the reformate water) as compared to a methane based reformate that is over twice that value in BTU content. The project also considers the effect of altitude since the test location will be at 4800 feet with the

  17. Diesel-fueled solid oxide fuel cell auxiliary power units for heavy-duty vehicles

    SciTech Connect

    Krause, T.; Kumar, R.; Krumpelt, M.

    2000-05-15

    This paper explores the potential of solid oxide fuel cells (SOFCS) as 3--10 kW auxiliary power units for trucks and military vehicles operating on diesel fuel. It discusses the requirements and specifications for such units, and the advantages, challenges, and development issues for SOFCS used in this application. Based on system design and analysis, such systems should achieve efficiencies approaching 40% (lower heating value), with a relatively simple system configuration. The major components of such a system are the fuel cell stack, a catalytic autothermal reformer, and a spent gas burner/air preheater. Building an SOFC-based auxiliary power unit is not straightforward, however, and the tasks needed to develop a 3--10 kW brassboard demonstration unit are outlined.

  18. Pressurized solid oxide fuel cell integral air accumular containment

    DOEpatents

    Gillett, James E.; Zafred, Paolo R.; Basel, Richard A.

    2004-02-10

    A fuel cell generator apparatus contains at least one fuel cell subassembly module in a module housing, where the housing is surrounded by a pressure vessel such that there is an air accumulator space, where the apparatus is associated with an air compressor of a turbine/generator/air compressor system, where pressurized air from the compressor passes into the space and occupies the space and then flows to the fuel cells in the subassembly module, where the air accumulation space provides an accumulator to control any unreacted fuel gas that might flow from the module.

  19. HIGH-TEMPERATURE TUBULAR SOLID OXIDE FUEL CELL GENERATOR DEVELOPMENT

    SciTech Connect

    S.E. Veyo

    1998-09-01

    During the Westinghouse/USDOE Cooperative Agreement period of November 1, 1990 through November 30, 1997, the Westinghouse solid oxide fuel cell has evolved from a 16 mm diameter, 50 cm length cell with a peak power of 1.27 watts/cm to the 22 mm diameter, 150 cm length dimensions of today's commercial prototype cell with a peak power of 1.40 watts/cm. Accompanying the increase in size and power density was the elimination of an expensive EVD step in the manufacturing process. Demonstrated performance of Westinghouse's tubular SOFC includes a lifetime cell test which ran for a period in excess of 69,000 hours, and a fully integrated 25 kWe-class system field test which operated for over 13,000 hours at 90% availability with less than 2% performance degradation over the entire period. Concluding the agreement period, a 100 kW SOFC system successfully passed its factory acceptance test in October 1997 and was delivered in November to its demonstration site in Westervoort, The Netherlands.

  20. PRESSURIZED SOLID OXIDE FUEL CELL/GAS TURBINE POWER SYSTEM

    SciTech Connect

    W.L. Lundberg; G.A. Israelson; R.R. Moritz; S.E. Veyo; R.A. Holmes; P.R. Zafred; J.E. King; R.E. Kothmann

    2000-02-01

    Power systems based on the simplest direct integration of a pressurized solid oxide fuel cell (SOFC) generator and a gas turbine (GT) are capable of converting natural gas fuel energy to electric power with efficiencies of approximately 60% (net AC/LHV), and more complex SOFC and gas turbine arrangements can be devised for achieving even higher efficiencies. The results of a project are discussed that focused on the development of a conceptual design for a pressurized SOFC/GT power system that was intended to generate 20 MWe with at least 70% efficiency. The power system operates baseloaded in a distributed-generation application. To achieve high efficiency, the system integrates an intercooled, recuperated, reheated gas turbine with two SOFC generator stages--one operating at high pressure, and generating power, as well as providing all heat needed by the high-pressure turbine, while the second SOFC generator operates at a lower pressure, generates power, and provides all heat for the low-pressure reheat turbine. The system cycle is described, major system components are sized, the system installed-cost is estimated, and the physical arrangement of system components is discussed. Estimates of system power output, efficiency, and emissions at the design point are also presented, and the system cost of electricity estimate is developed.

  1. Combination nickel foam expanded nickel screen electrical connection supports for solid oxide fuel cells

    DOEpatents

    Draper, Robert; Prevish, Thomas; Bronson, Angela; George, Raymond A.

    2007-01-02

    A solid oxide fuel assembly is made, wherein rows (14, 25) of fuel cells (17, 19, 21, 27, 29, 31), each having an outer interconnection (20) and an outer electrode (32), are disposed next to each other with corrugated, electrically conducting expanded metal mesh member (22) between each row of cells, the corrugated mesh (22) having top crown portions and bottom portions, where the top crown portion (40) have a top bonded open cell nickel foam (51) which contacts outer interconnections (20) of the fuel cells, said mesh and nickel foam electrically connecting each row of fuel cells, and where there are no more metal felt connections between any fuel cells.

  2. Automated brush plating process for solid oxide fuel cells

    DOEpatents

    Long, Jeffrey William

    2003-01-01

    A method of depositing a metal coating (28) on the interconnect (26) of a tubular, hollow fuel cell (10) contains the steps of providing the fuel cell (10) having an exposed interconnect surface (26); contacting the inside of the fuel cell (10) with a cathode (45) without use of any liquid materials; passing electrical current through a contacting applicator (46) which contains a metal electrolyte solution; passing the current from the applicator (46) to the cathode (45) and contacting the interconnect (26) with the applicator (46) and coating all of the exposed interconnect surface.

  3. Advanced materials for solid oxide fuel cells: Hafnium-Praseodymium-Indium Oxide System

    SciTech Connect

    Bates, J.L.; Griffin, C.W.; Weber, W.J.

    1988-06-01

    The HfO/sub 2/-PrO/sub 1.83/-In/sub 2/O/sub 3/ system has been studied at the Pacific Northwest Laboratory to develop alternative, highly electrically conducting oxides as electrode and interconnection materials for solid oxide fuel cells. A coprecipitation process was developed for synthesizing single-phase, mixed oxide powders necessary to fabricate powders and dense oxides. A ternary phase diagram was developed, and the phases and structures were related to electrical transport properties. Two new phases, an orthorhombic PrInO/sub 3/ and a rhombohedral Hf/sub 2/In/sub 2/O/sub 7/ phase, were identified. The highest electronic conductivity is related to the presence of a bcc, In/sub 2/O/sub 3/ solid solution (ss) containing HfO/sub 2/ and PrO/sub 1.83/. Compositions containing more than 35 mol % of the In/sub 2/O/sub 3/ ss have electrical conductivities greater than 10/sup /minus/1/ (ohm-cm)/sup /minus/1/, and the two or three phase structures that contain this phase appear to exhibit mixed electronic-ionic conduction. The high electrical conductivities and structures similar to the Y/sub 2/O/sub 3/-stabilized ZrO/sub 2/(HfO/sub 2/) electrolyte give these oxides potential for use as cathodes in solid oxide fuel cells. 21 refs.

  4. Integrating catalytic coal gasifiers with solid oxide fuel cells

    SciTech Connect

    Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

    2010-01-01

    A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

  5. Effect of Sulfur on Solid Oxide Fuel Cell (SOFC) Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Effect of Sulfur on SOFC Performance Using Diesel Reformate R. Kerr March 6-7, 2014 Workshop on Gas Cleanup for Fuel Cell Applications, ANL, March 6-7, 2014 Sulfur Poisoning Effect ...

  6. Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells

    SciTech Connect

    Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-07-01

    In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

  7. Silicon Based Solid Oxide Fuel Cell Chip for Portable Consumer Electronics -- Final Technical Report

    SciTech Connect

    Alan Ludwiszewski

    2009-06-29

    LSIs fuel cell uses efficient Solid Oxide Fuel Cell (SOFC) technology, is manufactured using Micro Electrical Mechanical System (MEMS) fabrication methods, and runs on high energy fuels, such as butane and ethanol. The companys Fuel Cell on a Chip technology enables a form-factor battery replacement for portable electronic devices that has the potential to provide an order-of-magnitude run-time improvement over current batteries. Further, the technology is clean and environmentally-friendly. This Department of Energy funded project focused on accelerating the commercialization and market introduction of this technology through improvements in fuel cell chip power output, lifetime, and manufacturability.

  8. Nanoparticle scaffolds for syngas-fed solid oxide fuel cells

    DOE PAGES [OSTI]

    Boldrin, Paul; Ruiz-Trejo, Enrique; Yu, Jingwen; Gruar, Robert I.; Tighe, Christopher J.; Chang, Kee-Chul; Ilavsky, Jan; Darr, Jawwad A.; Brandon, Nigel

    2014-12-17

    Incorporation of nanoparticles into devices such as solid oxide fuel cells (SOFCs) may provide benefits such as higher surface areas or finer control over microstructure. However, their use with traditional fabrication techniques such as screen-printing is problematic. Here, we show that mixing larger commercial particles with nanoparticles allows traditional ink formulation and screen-printing to be used while still providing benefits of nanoparticles such as increased porosity and lower sintering temperatures. SOFC anodes were produced by impregnating ceria–gadolinia (CGO) scaffolds with nickel nitrate solution. The scaffolds were produced from inks containing a mixture of hydrothermally-synthesised nanoparticle CGO, commercial CGO and polymericmore » pore formers. The scaffolds were heat-treated at either 1000 or 1300 °C, and were mechanically stable. In situ ultra-small X-ray scattering (USAXS) shows that the nanoparticles begin sintering around 900–1000 °C. Analysis by USAXS and scanning electron microscopy (SEM) revealed that the low temperature heat-treated scaffolds possessed higher porosity. Impregnated scaffolds were used to produce symmetrical cells, with the lower temperature heat-treated scaffolds showing improved gas diffusion, but poorer charge transfer. Using these scaffolds, lower temperature heat-treated cells of Ni–CGO/200 μm YSZ/CGO-LSCF performed better at 700 °C (and below) in hydrogen, and performed better at all temperatures using syngas, with power densities of up to 0.15 W cm-2 at 800 °C. This approach has the potential to allow the use of a wider range of materials and finer control over microstructure.« less

  9. Nanoparticle scaffolds for syngas-fed solid oxide fuel cells

    SciTech Connect

    Boldrin, Paul; Ruiz-Trejo, Enrique; Yu, Jingwen; Gruar, Robert I.; Tighe, Christopher J.; Chang, Kee-Chul; Ilavsky, Jan; Darr, Jawwad A.; Brandon, Nigel

    2014-12-17

    Incorporation of nanoparticles into devices such as solid oxide fuel cells (SOFCs) may provide benefits such as higher surface areas or finer control over microstructure. However, their use with traditional fabrication techniques such as screen-printing is problematic. Here, we show that mixing larger commercial particles with nanoparticles allows traditional ink formulation and screen-printing to be used while still providing benefits of nanoparticles such as increased porosity and lower sintering temperatures. SOFC anodes were produced by impregnating ceria–gadolinia (CGO) scaffolds with nickel nitrate solution. The scaffolds were produced from inks containing a mixture of hydrothermally-synthesised nanoparticle CGO, commercial CGO and polymeric pore formers. The scaffolds were heat-treated at either 1000 or 1300 °C, and were mechanically stable. In situ ultra-small X-ray scattering (USAXS) shows that the nanoparticles begin sintering around 900–1000 °C. Analysis by USAXS and scanning electron microscopy (SEM) revealed that the low temperature heat-treated scaffolds possessed higher porosity. Impregnated scaffolds were used to produce symmetrical cells, with the lower temperature heat-treated scaffolds showing improved gas diffusion, but poorer charge transfer. Using these scaffolds, lower temperature heat-treated cells of Ni–CGO/200 μm YSZ/CGO-LSCF performed better at 700 °C (and below) in hydrogen, and performed better at all temperatures using syngas, with power densities of up to 0.15 W cm-2 at 800 °C. This approach has the potential to allow the use of a wider range of materials and finer control over microstructure.

  10. Formation of thin walled ceramic solid oxide fuel cells

    DOEpatents

    Claar, Terry D.; Busch, Donald E.; Picciolo, John J.

    1989-01-01

    To reduce thermal stress and improve bonding in a high temperature monolithic solid oxide fuel cell (SOFC), intermediate layers are provided between the SOFC's electrodes and electrolyte which are of different compositions. The intermediate layers are comprised of a blend of some of the materials used in the electrode and electrolyte compositions. Particle size is controlled to reduce problems involving differential shrinkage rates of the various layers when the entire structure is fired at a single temperature, while pore formers are provided in the electrolyte layers to be removed during firing for the formation of desired pores in the electrode layers. Each layer includes a binder in the form of a thermosetting acrylic which during initial processing is cured to provide a self-supporting structure with the ceramic components in the green state. A self-supporting corrugated structure is thus formed prior to firing, which the organic components of the binder and plasticizer removed during firing to provide a high strength, high temperature resistant ceramic structure of low weight and density.

  11. Method and apparatus for assembling solid oxide fuel cells

    DOEpatents

    Szreders, Bernard E.; Campanella, Nicholas

    1989-01-01

    A plurality of jet air tubes are supported and maintained in a spaced matrix array by a positioning/insertion assembly for insertion in respective tubes of a solid oxide fuel cell (SOFC) in the assembly of an SOFC module. The positioning/insertion assembly includes a plurality of generally planar, elongated, linear vanes which are pivotally mounted at each end thereof to a support frame. The vanes, which each include a plurality of spaced slots along the facing edges thereof, may be pivotally displaced from a generally vertical orientation, wherein each jet air tube is positioned within and engaged by the aligned slots of a plurality of paired upper and lower vanes to facilitate their insertion in respective aligned SOFC tubes arranged in a matrix array, to an inclined orientation, wherein the jet air tubes may be removed from the positioning/insertion assembly after being inserted in the SOFC tubes. A rectangular compression assembly of adjustable size is adapted to receive and squeeze a matrix of SOFC tubes so as to compress the inter-tube nickel felt conductive pads which provide series/parallel electrical connection between adjacent SOFCs, with a series of increasingly larger retainer frames used to maintain larger matrices of SOFC tubes in position. Expansion of the SOFC module housing at the high operating temperatures of the SOFC is accommodated by conductive, flexible, resilient expansion, connector bars which provide support and electrical coupling at the top and bottom of the SOFC module housing.

  12. 17th Annual Solid Oxide Fuel Cell Project Review Meeting | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    17th Annual Solid Oxide Fuel Cell Project Review Meeting SOFC-logo Workshop Summary Additional materials will be added when they are received from the author. PRESENTATIONS Tuesday, July 19, 2016 NETL's Fuel Cell Program Overview Shailesh Vora, Technology Manager for Fuel Cells U.S. Department of Energy, National Energy Technology Laboratory ARPA-E's REBELS Program Overview Paul Albertus and Grigorii Soloveichik, Program Directors for REBELS U.S. Department of Energy, ARPA-E System Analysis of

  13. Solid oxide fuel cells for transportation: A clean, efficient alternative for propulsion

    SciTech Connect

    Kumar, R.; Krumpelt, M.; Myles, K.M.

    1993-04-01

    Fuel cells show great promise for providing clean and efficient transportation power. Of the fuel cell propulsion systems under investigation, the solid oxide fuel cell (SOFC) is particularly attractive for heavy duty transportation applications that have a relatively long duty cycle, such as locomotives, trucks, and barges. Advantages of the SOFC include a simple, compact system configuration; inherent fuel flexibility for hydrocarbon and alternative fuels; and minimal water management. The specific advantages of the SOFC for powering a railroad locomotive are examined. Feasibility, practicality, and safety concerns regarding SOFCs in transportation applications are discussed, as am the major R&D issues.

  14. Solid oxide fuel cells for transportation: A clean, efficient alternative for propulsion

    SciTech Connect

    Kumar, R.; Krumpelt, M.; Myles, K.M.

    1993-01-01

    Fuel cells show great promise for providing clean and efficient transportation power. Of the fuel cell propulsion systems under investigation, the solid oxide fuel cell (SOFC) is particularly attractive for heavy duty transportation applications that have a relatively long duty cycle, such as locomotives, trucks, and barges. Advantages of the SOFC include a simple, compact system configuration; inherent fuel flexibility for hydrocarbon and alternative fuels; and minimal water management. The specific advantages of the SOFC for powering a railroad locomotive are examined. Feasibility, practicality, and safety concerns regarding SOFCs in transportation applications are discussed, as am the major R D issues.

  15. Solid Oxide Fuel Cells (SOFC) as Military APU Replacements | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Cells (SOFC) as Military APU Replacements Solid Oxide Fuel Cells (SOFC) as Military APU Replacements Presentation by Thomas Reitz, Air Force Research Laboratory, at the DOD-DOE Aircraft Petroleum Use Reduction Workshop, September 30, 2010, in Washington, DC. aircraft_7_reitz.pdf (406.74 KB) More Documents & Publications Report of the DOE-DOE Workshop on Fuel Cells in Aviation: Workshop Summary and Action Plan Manufacturing Cost Analysis of 1 kW and 5 kW Solid Oxide Fuel Cell

  16. Operation of a solid oxide fuel cell on biodiesel with a partial oxidation reformer

    SciTech Connect

    Siefert, N, Shekhawat, D.; Gemmen, R.; Berry, D.

    2010-01-01

    The National Energy Technology Laboratory’s Office of Research & Development (NETL/ORD) has successfully demonstrated the operation of a solid oxide fuel cell (SOFC) using reformed biodiesel. The biodiesel for the project was produced and characterized by West Virginia State University (WVSU). This project had two main aspects: 1) demonstrate a catalyst formulation on monolith for biodiesel fuel reforming; and 2) establish SOFC stack test stand capabilities. Both aspects have been completed successfully. For the first aspect, in–house patented catalyst specifications were developed, fabricated and tested. Parametric reforming studies of biofuels provided data on fuel composition, catalyst degradation, syngas composition, and operating parameters required for successful reforming and integration with the SOFC test stand. For the second aspect, a stack test fixture (STF) for standardized testing, developed by Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) for the Solid Energy Conversion Alliance (SECA) Program, was engineered and constructed at NETL. To facilitate the demonstration of the STF, NETL employed H.C. Starck Ceramics GmbH & Co. (Germany) anode supported solid oxide cells. In addition, anode supported cells, SS441 end plates, and cell frames were transferred from PNNL to NETL. The stack assembly and conditioning procedures, including stack welding and sealing, contact paste application, binder burn-out, seal-setting, hot standby, and other stack assembly and conditioning methods were transferred to NETL. In the future, fuel cell stacks provided by SECA or other developers could be tested at the STF to validate SOFC performance on various fuels. The STF operated on hydrogen for over 1000 hrs before switching over to reformed biodiesel for 100 hrs of operation. Combining these first two aspects led to demonstrating the biodiesel syngas in the STF. A reformer was built and used to convert 0.5 ml/min of

  17. Sulfur-tolerant anode material for direct hydrocarbon solid oxide fuel cells

    DOEpatents

    Chen, Fanglin; Yang, Chenghao; Yang, Zhibin

    2016-08-02

    In one aspect, the present subject matter is directed to a composite anode for a hydrocarbon solid oxide fuel cell, the anode comprising a layered perovskite ceramic and a bi-metallic alloy.

  18. CRACK GROWTH ANALYSIS OF SOLID OXIDE FUEL CELL ELECTROLYTES

    SciTech Connect

    S. Bandopadhyay; N. Nagabhushana

    2003-10-01

    Defects and Flaws control the structural and functional property of ceramics. In determining the reliability and lifetime of ceramics structures it is very important to quantify the crack growth behavior of the ceramics. In addition, because of the high variability of the strength and the relatively low toughness of ceramics, a statistical design approach is necessary. The statistical nature of the strength of ceramics is currently well recognized, and is usually accounted for by utilizing Weibull or similar statistical distributions. Design tools such as CARES using a combination of strength measurements, stress analysis, and statistics are available and reasonably well developed. These design codes also incorporate material data such as elastic constants as well as flaw distributions and time-dependent properties. The fast fracture reliability for ceramics is often different from their time-dependent reliability. Further confounding the design complexity, the time-dependent reliability varies with the environment/temperature/stress combination. Therefore, it becomes important to be able to accurately determine the behavior of ceramics under simulated application conditions to provide a better prediction of the lifetime and reliability for a given component. In the present study, Yttria stabilized Zirconia (YSZ) of 9.6 mol% Yttria composition was procured in the form of tubes of length 100 mm. The composition is of interest as tubular electrolytes for Solid Oxide Fuel Cells. Rings cut from the tubes were characterized for microstructure, phase stability, mechanical strength (Weibull modulus) and fracture mechanisms. The strength at operating condition of SOFCs (1000 C) decreased to 95 MPa as compared to room temperature strength of 230 MPa. However, the Weibull modulus remains relatively unchanged. Slow crack growth (SCG) parameter, n = 17 evaluated at room temperature in air was representative of well studied brittle materials. Based on the results, further work

  19. Filled glass composites for sealing of solid oxide fuel cells.

    SciTech Connect

    Tandon, Rajan; Widgeon, Scarlett Joyce; Garino, Terry J.; Brochu, Mathieu; Gauntt, Bryan D.; Corral, Erica L.; Loehman, Ronald E.

    2009-04-01

    Glasses filled with ceramic or metallic powders have been developed for use as seals for solid oxide fuel cells (SOFC's) as part of the U.S. Department of Energy's Solid State Energy Conversion Alliance (SECA) Program. The composites of glass (alkaline earth-alumina-borate) and powders ({approx}20 vol% of yttria-stabilized zirconia or silver) were shown to form seals with SOFC materials at or below 900 C. The type and amount of powder were adjusted to optimize thermal expansion to match the SOFC materials and viscosity. Wetting studies indicated good wetting was achieved on the micro-scale and reaction studies indicated that the degree of reaction between the filled glasses and SOFC materials, including spinel-coated 441 stainless steel, at 750 C is acceptable. A test rig was developed for measuring strengths of seals cycled between room temperature and typical SOFC operating temperatures. Our measurements showed that many of the 410 SS to 410 SS seals, made using silver-filled glass composites, were hermetic at 0.2 MPa (2 atm.) of pressure and that seals that leaked could be resealed by briefly heating them to 900 C. Seal strength measurements at elevated temperature (up to 950 C), measured using a second apparatus that we developed, indicated that seals maintained 0.02 MPa (0.2 atm.) overpressures for 30 min at 750 C with no leakage. Finally, the volatility of the borate component of sealing glasses under SOFC operational conditions was studied using weight loss measurements and found by extrapolation to be less than 5% for the projected SOFC lifetime.

  20. Catalytic membranes for CO oxidation in fuel cells

    DOEpatents

    Sandi-Tapia, Giselle; Carrado Gregar, Kathleen; Kizilel, Riza

    2010-06-08

    A hydrogen permeable membrane, which includes a polymer stable at temperatures of about 200 C having clay impregnated with Pt or Au or Ru or Pd particles or mixtures thereof with average diameters of less than about 10 nanometers (nms) is disclosed. The membranes are useful in fuel cells or any device which requires hydrogen to be separated from carbon monoxide.

  1. Expanded nickel screen electrical connection supports for solid oxide fuel cells

    DOEpatents

    Draper, Robert; Antol, Ronald F.; Zafred, Paolo R.

    2002-01-01

    A solid oxide fuel assembly is made, wherein rows (14, 24) of fuel cells (16, 18, 20, 26, 28, 30), each having an outer interconnection (36) and an outer electrode (32), are disposed next to each other with corrugated, electrically conducting expanded metal mesh (22) between each row of cells, the corrugated mesh (22) having top crown portions (40) and bottom shoulder portions (42), where the top crown portion (40) contacts outer interconnections (36) of the fuel cells (16, 18, 20) in a first row (14), and the bottom shoulder portions (42) contacts outer electrodes (32) of the fuel cells in a second row (24), said mesh electrically connecting each row of fuel cells, and where there are no metal felt connections between any fuel cells.

  2. Method of improving fuel cell performance by removing at least one metal oxide contaminant from a fuel cell electrode

    DOEpatents

    Kim, Yu Seung; Choi, Jong-Ho; Zelenay, Piotr

    2009-08-18

    A method of removing contaminants from a fuel cell catalyst electrode. The method includes providing a getter electrode and a fuel cell catalyst electrode having at least one contaminant to a bath and applying a voltage sufficient to drive the contaminant from the fuel cell catalyst electrode to the getter electrode. Methods of removing contaminants from a membrane electrode assembly of a fuel cell and of improving performance of a fuel cell are also provided.

  3. Fuel Preprocessor (FPP) for a Solid Oxide Fuel Cell Auxiliary Power Unit

    SciTech Connect

    M. Namazian, S. Sethuraman and G. Venkataraman

    2004-12-31

    Auxiliary Power Units (APUs), driven by truck engines, consume over 800 million gallon of diesel fuel while idling. Use of separate SOFC based APUs are an excellent choice to reduce the cost and pollution associated with producing auxiliary power. However, diesel fuel is a challenging fuel to use in fuel cell systems because it has heavy hydrocarbons that can transform into carbon deposits and gums that can block passages and deactivate fuel reformer and fuel cell reactor elements. The work reported herein addresses the challenges associated with the diesel fuel sulfur and carbon producing contaminants in a Fuel Preprocessor (FPP). FPP processes the diesel fuel onboard and ahead of the reformer to reduce its carbon deposition tendency and its sulfur content, thus producing a fuel suitable for SOFC APU systems. The goal of this DOE supported Invention and Innovation program was to design, develop and test a prototype Fuel Preprocessor (FPP) that efficiently and safely converts the diesel fuel into a clean fuel suitable for a SOFC APU system. The goals were achieved. A 5 kWe FPP was designed, developed and tested. It was demonstrated that FPP removes over 80% of the fuel sulfur and over 90% of its carbon residues and it was demonstrated that FPP performance exceeds the original project goals.

  4. Generation and Solid Oxide Fuel Cell Carbon Sequestration in Northwest Indiana

    SciTech Connect

    Kevin Peavey; Norm Bessette

    2007-09-30

    The objective of the project is to develop the technology capable of capturing all carbon monoxide and carbon dioxide from natural gas fueled Solid Oxide Fuel Cell (SOFC) system. In addition, the technology to electrochemically oxidize any remaining carbon monoxide to carbon dioxide will be developed. Success of this R&D program would allow for the generation of electrical power and thermal power from a fossil fuel driven SOFC system without the carbon emissions resulting from any other fossil fueled power generationg system.

  5. Molten carbonate fuel cell cathode with mixed oxide coating

    DOEpatents

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  6. Direct hydrocarbon fuel cells

    DOEpatents

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  7. Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices

    DOEpatents

    Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

    2010-11-23

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

  8. Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices

    DOEpatents

    Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

    2010-03-02

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

  9. Copper-substituted perovskite compositions for solid oxide fuel cell cathodes and oxygen reduction electrodes in other electrochemical devices

    DOEpatents

    Rieke, Peter C.; Coffey, Gregory W.; Pederson, Larry R.; Marina, Olga A.; Hardy, John S.; Singh, Prabhaker; Thomsen, Edwin C.

    2010-07-20

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells. Also provided are electrochemical devices that include active oxygen reduction electrodes, such as solid oxide fuel cells, sensors, pumps and the like. The compositions comprises a copper-substituted ferrite perovskite material. The invention also provides novel methods for making and using the electrode compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having cathodes comprising the compositions.

  10. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    SciTech Connect

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  11. The Case for Natural Gas Fueled Solid Oxide Fuel Cell Power Systems for Distributed Generation

    SciTech Connect

    Chick, Lawrence A.; Weimar, Mark R.; Whyatt, Greg A.; Powell, Michael R.

    2015-02-01

    Natural-gas-fueled solid oxide fuel cell (NGSOFC) power systems yield electrical conversion efficiencies exceeding 60% and may become a viable alternative for distributed generation (DG) if stack life and manufacturing economies of scale can be realized. Currently, stacks last approximately 2 years and few systems are produced each year because of the relatively high cost of electricity from the systems. If mass manufacturing (10,000 units per year) and a stack life of 15 years can be reached, the cost of electricity from an NGSOFC system is estimated to be about 7.7 ¢/kWh, well within the price of commercial and residential retail prices at the national level (9.9-10¢/kWh and 11-12 ¢/kWh, respectively). With an additional 5 ¢/kWh in estimated additional benefits from DG, NGSOFC could be well positioned to replace the forecasted 59-77 gigawatts of capacity loss resulting from coal plant closures due to stricter emissions regulations and low natural gas prices.

  12. Generator module architecture for a large solid oxide fuel cell power plant

    DOEpatents

    Gillett, James E.; Zafred, Paolo R.; Riggle, Matthew W.; Litzinger, Kevin P.

    2013-06-11

    A solid oxide fuel cell module contains a plurality of integral bundle assemblies, the module containing a top portion with an inlet fuel plenum and a bottom portion receiving air inlet feed and containing a base support, the base supports dense, ceramic exhaust manifolds which are below and connect to air feed tubes located in a recuperator zone, the air feed tubes passing into the center of inverted, tubular, elongated, hollow electrically connected solid oxide fuel cells having an open end above a combustion zone into which the air feed tubes pass and a closed end near the inlet fuel plenum, where the fuel cells comprise a fuel cell stack bundle all surrounded within an outer module enclosure having top power leads to provide electrical output from the stack bundle, where the fuel cells operate in the fuel cell mode and where the base support and bottom ceramic air exhaust manifolds carry from 85% to all 100% of the weight of the stack, and each bundle assembly has its own control for vertical and horizontal thermal expansion control.

  13. High pressure operation of tubular solid oxide fuel cells and their intergration with gas turbines

    SciTech Connect

    Haynes, C.; Wepfer, W.J.

    1996-12-31

    Fossil fuels continue to be used at a rate greater than that of their natural formation, and the current byproducts from their use are believed to have a detrimental effect on the environment (e.g. global warming). There is thus a significant impetus to have cleaner, more efficient fuel consumption alternatives. Recent progress has led to renewed vigor in the development of fuel cell technology, which has been shown to be capable of producing high efficiencies with relatively benign exhaust products. The tubular solid oxide fuel cell developed by Westinghouse Electric Corporation has shown significant promise. Modeling efforts have been and are underway to optimize and better understand this fuel cell technology. Thus far, the bulk of modeling efforts has been for operation at atmospheric pressure. There is now interest in developing high-efficiency integrated gas turbine/solid oxide fuel cell systems. Such operation of fuel cells would obviously occur at higher pressures. The fuel cells have been successfully modeled under high pressure operation and further investigated as integrated components of an open loop gas turbine cycle.

  14. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOEpatents

    Jankowski, Alan F.; Makowiecki, Daniel M.; Rambach, Glenn D.; Randich, Erik

    1999-01-01

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

  15. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOEpatents

    Jankowski, A.F.; Makowiecki, D.M.; Rambach, G.D.; Randich, E.

    1998-05-19

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated. 8 figs.

  16. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOEpatents

    Jankowski, Alan F.; Makowiecki, Daniel M.; Rambach, Glenn D.; Randich, Erik

    1998-01-01

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

  17. Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SOFC Technology R& D Needs Steven Shaffer Chief Engineer - Fuel Cell Development DOE Pre-Solicitation Workshop January 23 &24, 2008 2 DOE Pre-Solicitation Workshop, Golden CO Field Office Solid Oxide Fuel Cell Market Opportunity US Stationary - APU & CHP Natural Gas, LPG European micro -CHP & CHCP Natural Gas Commercial Power Natural Gas FutureGen Powerplant Coal Gas Recreational Vehicles Diesel, LPG Heavy Duty Truck Diesel Truck and Trailer Refrigeration Diesel US Military JP-8

  18. Fuel cell generator

    DOEpatents

    Isenberg, Arnold O.

    1983-01-01

    High temperature solid oxide electrolyte fuel cell generators which allow controlled leakage among plural chambers in a sealed housing. Depleted oxidant and fuel are directly reacted in one chamber to combust remaining fuel and preheat incoming reactants. The cells are preferably electrically arranged in a series-parallel configuration.

  19. Synthesis and Stability of a Nanoparticle-Infiltrated Solid OxideFuel Cell Electrode

    SciTech Connect

    Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-11-20

    Nanoparticulate catalysts infiltrated into SOFC (Solid OxideFUel Cell) electrodes can significantly enhance the cell performance, butthe stability of these electrodes has been an open issue. An infiltrationprocedure is reported that leads to a stable scandia-stablized zirconia(SSZ) cathode electrode performance.

  20. Development of low temperature solid oxide fuel cells

    SciTech Connect

    Bakker, W.T.; Goldstein, R.

    1996-12-31

    The historical focus of the electric utility industry has been central station power plants. These plants are usually sited outside urban areas and electricity was delivered via high voltage transmission lines. Several things are beginning to change this historical precedent One is the popular concern with EMF as a health hazard. This has rendered the construction of new lines as well as upgrading old ones very difficult. Installation of power generating equipment near the customer enables the utility to better utilize existing transmission and distribution networks and defer investments. Power quality and lark of disturbances and interruptions is also becoming increasingly more important to many customers. Grid connected, but dedicated small power plants can greatly improve power quality. Finally the development of high efficiency, low emission, modular fuel cells promises near pollution free localized power generation with an efficiency equal to or exceeding that of even the most efficient central power stations.

  1. Innovative Seals for Solid Oxide Fuel Cells (SOFC)

    SciTech Connect

    Singh, Raj

    2008-06-30

    A functioning SOFC requires different type of seals such as metal-metal, metal-ceramic, and ceramic-ceramic. These seals must function at high temperatures between 600--900{sup o}C and in oxidizing and reducing environments of the fuels and air. Among the different type of seals, the metal-metal seals can be readily fabricated using metal joining, soldering, and brazing techniques. However, the metal-ceramic and ceramic-ceramic seals require significant research and development because the brittle nature of ceramics/glasses can lead to fracture and loss of seal integrity and functionality. Consequently, any seals involving ceramics/glasses require a significant attention and technology development for reliable SOFC operation. This final report is prepared to describe the progress made in the program on the needs, approaches, and performance of high temperature seals for SOFC. In particular, a new concept of self-healing glass seals is pursued for making seals between metal-ceramic material combinations, including some with a significant expansion mismatch.

  2. Pressurized solid oxide fuel cell/gas turbine combined cycle systems

    SciTech Connect

    George, R.A.

    1997-12-31

    Over the last 10 years, Westinghouse Electric Corporation has made great strides in advancing tubular solid oxide fuel cell (SOFC) technology towards commercialization by the year 2001. In 1993, Westinghouse initiated a program to develop pressurized solid oxide fuel cell/gas turbine (PSOFC/GT) combined cycle power systems because of the ultra-high electrical efficiencies, 60-75% (net AC/LHV CH4), inherent with these systems. This paper will discuss SOFC technology advancements in recent years, and the final phase development program which will focus on the development and demonstration of PSOFC/GT power systems for distributed power applications.

  3. Reforming of fuel inside fuel cell generator

    DOEpatents

    Grimble, R.E.

    1988-03-08

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream 1 and spent fuel stream 2. Spent fuel stream 1 is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream 1 and exhaust stream 2, and exhaust stream 1 is vented. Exhaust stream 2 is mixed with spent fuel stream 2 to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells. 1 fig.

  4. Reforming of fuel inside fuel cell generator

    DOEpatents

    Grimble, Ralph E.

    1988-01-01

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  5. Fuel cells and fuel cell catalysts

    DOEpatents

    Masel, Richard I.; Rice, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2006-11-07

    A direct organic fuel cell includes a formic acid fuel solution having between about 10% and about 95% formic acid. The formic acid is oxidized at an anode. The anode may include a Pt/Pd catalyst that promotes the direct oxidation of the formic acid via a direct reaction path that does not include formation of a CO intermediate.

  6. Final Technical Report, Oct 2004 - Nov. 2006, High Performance Flexible Reversible Solid Oxide Fuel Cell

    SciTech Connect

    Guan, Jie; Minh, Nguyen

    2007-02-21

    This report summarizes the work performed for the program entitled “High Performance Flexible Reversible Solid Oxide Fuel Cell” under Cooperative Agreement DE-FC36-04GO14351 for the U. S. Department of Energy. The overall objective of this project is to demonstrate a single modular stack that generates electricity from a variety of fuels (hydrogen and other fuels such as biomass, distributed natural gas, etc.) and when operated in the reverse mode, produces hydrogen from steam. This project has evaluated and selected baseline cell materials, developed a set of materials for oxygen and hydrogen electrodes, and optimized electrode microstructures for reversible solid oxide fuel cells (RSOFCs); and demonstrated the feasibility and operation of a RSOFC multi-cell stack. A 10-cell reversible SOFC stack was operated over 1000 hours alternating between fuel cell (with hydrogen and methane as fuel) and steam electrolysis modes. The stack ran very successfully with high power density of 480 mW/cm2 at 0.7V and 80% fuel utilization in fuel cell mode and >6 SLPM hydrogen production in steam electrolysis mode using about 1.1 kW electrical power. The hydrogen generation is equivalent to a specific capability of 2.59 Nm3/m2 with electrical energy demand of 3 kWh/Nm3. The performance stability in electrolysis mode was improved vastly during the program with a degradation rate reduction from 8000 to 200 mohm-cm2/1000 hrs. This was accomplished by increasing the activity and improving microstructure of the oxygen electrode. Both cost estimate and technology assessment were conducted. Besides the flexibility running under both fuel cell mode and electrolysis mode, the reversible SOFC system has the potentials for low cost and high efficient hydrogen production through steam electrolysis. The cost for hydrogen production at large scale was estimated at ~$2.7/kg H2, comparing favorably with other electrolysis techology.

  7. Iron-based perovskite cathodes for solid oxide fuel cells

    DOEpatents

    Ralph, James M.; Rossignol, Cecile C.R.; Vaughey, John T.

    2007-01-02

    An A and/or A' site deficient perovskite of general formula of (A.sub.1-xA'.sub.x).sub.1-yFeO.sub.3-.delta. or of general formula A.sub.1-x-yA'.sub.xFeO.sub.3-67, wherein A is La alone or with one or more of the rare earth metals or a rare earth metal other than Ce alone or a combination of rare earth metals and X is in the range of from 0 to about 1; A' is Sr or Ca or mixtures thereof and Y is in the range of from about 0.01 to about 0.3; .delta. represents the amount of compensating oxygen loss. If either A or A' is zero the remaining A or A' is deficient. A fuel cell incorporating the inventive perovskite as a cathode is disclosed as well as an oxygen separation membrane. The inventive perovskite is preferably single phase.

  8. Design and performance of tubular flat-plate solid oxide fuel cell

    SciTech Connect

    Matsushima, T.; Ikeda, D.; Kanagawa, H.

    1996-12-31

    With the growing interest in conserving the environmental conditions, much attention is being paid to Solid Oxide Fuel Cell (SOFC), which has high energy-conversion efficiency. Many organizations have conducted studies on tubular and flat type SOFCs. Nippon Telegraph and Telephone Corporation (NTT) has studied a combined tubular flat-plate SOFC, and already presented the I-V characteristics of a single cell. Here, we report the construction of a stack of this SOFC cell and successful generation tests results.

  9. Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in DOE-Sponsored Test

    Energy.gov [DOE]

    In a test sponsored by the U.S. Department of Energy, a Delphi auxiliary power unit employing a solid oxide fuel cell (SOFC) successfully operated the electrical system and air conditioning of a Peterbilt Model 386 truck under conditions simulating idling conditions for 10 hours.

  10. Solid oxide fuel cell systems with hot zones having improved reactant distribution

    DOEpatents

    Poshusta, Joseph C; Booten, Charles W; Martin, Jerry L

    2013-12-24

    A Solid Oxide Fuel Cell (SOFC) system having a hot zone with a center cathode air feed tube for improved reactant distribution, a CPOX reactor attached at the anode feed end of the hot zone with a tail gas combustor at the opposing end for more uniform heat distribution, and a counter-flow heat exchanger for efficient heat retention.

  11. Recovery Act. Solid Oxide Fuel Cell Diesel Auxilliary Power Unit Demonstration

    SciTech Connect

    Geiger, Gail E.

    2013-09-30

    Solid Oxide Fuel Cell Diesel Auxilliary Power Unit Demonstration Project. Summarizing development of Delphi’s next generation SOFC system as the core power plant to prove the viability of the market opportunity for a 3-5 kW diesel SOFC system. Report includes test and demonstration results from testing the diesel APU in a high visibility fleet customer vehicle application.

  12. Ceramic interconnectors for planar solid oxide fuel cells through tape casting of reaction sprayed powders

    SciTech Connect

    Stolten, D.; Kurbjuhn, M.; Wagner, W.

    1995-09-01

    A route to produce doped lanthanum-chromite interconnectors for application in solid oxide fuel cells is presented. Reaction spraying is applied to attain fine grained and homogeneous raw powder. A ceramic exhibiting a sintering density of 99% is attained via continuous calcination, milling, tape casting and subsequently sintering. Due to the high sintering density, gas tightness is achieved.

  13. Solid oxide fuel cell systems with hot zones having improved reactant distribution

    DOEpatents

    Poshusta, Joseph C.; Booten, Charles W.; Martin, Jerry L.

    2012-11-06

    A Solid Oxide Fuel Cell (SOFC) system having a hot zone with a center cathode air feed tube for improved reactant distribution, a CPOX reactor attached at the anode feed end of the hot zone with a tail gas combustor at the opposing end for more uniform heat distribution, and a counter-flow heat exchanger for efficient heat retention.

  14. Ni modified ceramic anodes for direct-methane solid oxide fuel cells

    DOEpatents

    Xiao, Guoliang; Chen, Fanglin

    2016-01-19

    In accordance with certain embodiments of the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes synthesizing a composition having a perovskite present therein. The method further includes applying the composition on an electrolyte support to form an anode and applying Ni to the composition on the anode.

  15. HIGH EFFICIENCY, LOW EMISSIONS, SOLID OXIDE FUEL CELL SYSTEMS FOR MULTIPLE APPLICATIONS

    SciTech Connect

    Sara Ward; Michael A. Petrik

    2004-07-28

    Technology Management Inc. (TMI), teamed with the Ohio Office of Energy Efficiency and Renewable Energy, has engineered, constructed, and demonstrated a stationary, low power, multi-module solid oxide fuel cell (SOFC) prototype system operating on propane and natural gas. Under Phase I, TMI successfully operated two systems in parallel, in conjunction with a single DC-AC inverter and battery bus, and produced net AC electricity. Phase II testing expanded to include alternative and renewable fuels typically available in rural regions of Ohio. The commercial system is expected to have ultra-low pollution, high efficiency, and low noise. The TMI SOFC uses a solid ceramic electrolyte operating at high temperature (800-1000 C) which electrochemically converts gaseous fuels (hydrogen or mixed gases) and oxygen into electricity. The TMI system design oxidizes fuel primarily via electrochemical reactions and uses no burners (which pollute and consume fuel)--resulting in extremely clean exhaust. The use of proprietary sulfur tolerant materials developed by TMI allows system operation without additional fuel pre-processing or sulfur removal. Further, the combination of high operating temperatures and solid state operation increases the potential for higher reliability and efficiencies compared to other types of fuel cells. Applications for the TMI SOFC system cover a wide range of transportation, building, industrial, and military market sectors. A generic technology, fuel cells have the potential to be embodied into multiple products specific to Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) program areas including: Fuel Cells and Microturbines, School Buildings, Transportation, and Bioenergy. This program focused on low power stationary applications using a multi-module system operating on a range of common fuels. By producing clean electricity more efficiently (thus using less fuel), fuel cells have the triple effect of cleaning up the

  16. FUEL CELLS Fuel Cell Cars

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    CELLS Fuel Cell Cars Power, performance, and pollution - free Only water from tailpipe More efficient than traditional combustion Only water and heat as byproducts Produce electricity without any combustion Scale up easily to meet many power needs Hydrogen in. Electricity, Heat and Water Out. Share the knowledge #FuelCellsNow #HydrogenNow Learn more: energy.gov/eere/fuelcells Most abundant element in universe Fuel Cell Cars Power, performance, and pollution - free Only water from tailpipe Fuel

  17. Manifold, bus support and coupling arrangement for solid oxide fuel cells

    DOEpatents

    Parry, G.W.

    1988-04-21

    Individual, tubular solid oxide fuel cells (SOFCs) are assembled into bundles called a module within a housing, with a plurality of modules arranged end-to-end in a linear, stacked configuration called a string. A common set of piping comprised of a suitable high temperature resistant material (1) provides fuel and air to each module housing, (2) serves as electrically conducting buses, and (3) provides structural support for a string of SOFC modules. Ceramic collars are used to connect fuel and air inlet piping to each of the electrodes in an SOFC module and provide (1) electrical insulation for the current carrying bus bars and gas manifolds, (2) damping for the fuel and air inlet piping, and (3) proper spacing between the fuel and air inlet piping to prevent contact between these tubes and possible damage to the SOFC. 11 figs.

  18. Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects

    SciTech Connect

    Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

    2011-01-10

    Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

  19. Modified cermet fuel electrodes for solid oxide electrochemical cells

    DOEpatents

    Ruka, Roswell J.; Spengler, Charles J.

    1991-01-01

    An exterior porous electrode (10), bonded to a solid oxygen ion conducting electrolyte (13) which is in contact with an interior electrode (14), contains coarse metal particles (12) of nickel and/or cobalt, having diameters from 3 micrometers to 35 micrometers, where the coarse particles are coated with a separate, porous, multiphase layer (17) containing fine metal particles of nickel and/or cobalt (18), having diameters from 0.05 micrometers to 1.75 micrometers and conductive oxide (19) selected from cerium oxide, doped cerium oxide, strontium titanate, doped strontium titanate and mixtures thereof.

  20. Solid oxide fuel cell with transitioned cross-section for improved anode gas management at the open end

    DOEpatents

    Zafred, Paolo R.; Draper, Robert

    2012-01-17

    A solid oxide fuel cell (400) is made having a tubular, elongated, hollow, active section (445) which has a cross-section containing an air electrode (452) a fuel electrode (454) and solid oxide electrolyte (456) between them, where the fuel cell transitions into at least one inactive section (460) with a flattened parallel sided cross-section (462, 468) each cross-section having channels (472, 474, 476) in them which smoothly communicate with each other at an interface section (458).

  1. FUNDAMENTAL STUDIES OF THE DURABILITY OF MATERIALS FOR INTERCONNECTS IN SOLID OXIDE FUEL CELLS

    SciTech Connect

    Frederick S. Pettit; Gerald H. Meier

    2003-06-30

    This report describes the result of the first eight months of effort on a project directed at improving metallic interconnect materials for solid oxide fuel cells (SOFCs). The results include cyclic oxidation studies of a group of ferritic alloys, which are candidate interconnect materials. The exposures have been carried out in simulated fuel cell atmospheres. The oxidation morphologies have been characterized and the ASR has been measured for the oxide scales. The effect of fuel cell electric current density on chromia growth rates has been considered The thermomechanical behavior of the scales has been investigated by stress measurements using x-ray diffraction and interfacial fracture toughness measurements using indentation. The ultimate goal of this thrust is to use knowledge of changes in oxide thickness, stress and adhesion to develop accelerated testing methods for evaluating SOFC interconnect alloys. Finally a theoretical assessment of the potential for use of ''new'' metallic materials as interconnect materials has been conducted and is presented in this report. Alloys being considered include materials based on pure nickel, materials based on the ''Invar'' concept, and coated materials to optimize properties in both the anode and cathode gases.

  2. Stationary market applications potential of solid oxide and solid polymer fuel cell systems

    SciTech Connect

    Baker, J.N.; Fletcher, W.H.

    1996-12-31

    The UK DTI`s Advanced Fuel Cells Programme currently focuses on two main fuel cell technologies, namely the solid oxide and solid polymer systems (SOFC and SPFC), respectively. The provision of accurate and timely market data is regarded as an important part of the overall programme objectives, such as to assist both Government and industry in their appraisals of the technologies. The present study was therefore commissioned against this background, with a complementary study addressing transportation and mobile applications. The results reported herein relate to the stationary market applications potential of both SOFC and SPFC systems.

  3. Solid oxide fuel cell power plant with an anode recycle loop turbocharger

    SciTech Connect

    Saito, Kazuo; Skiba, Tommy; Patel, Kirtikumar H.

    2015-07-14

    An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

  4. Fuel cell arrangement

    DOEpatents

    Isenberg, A.O.

    1987-05-12

    A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber. 3 figs.

  5. Fuel cell arrangement

    DOEpatents

    Isenberg, Arnold O.

    1987-05-12

    A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

  6. Micro fuel cell

    SciTech Connect

    Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

    1998-12-31

    An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

  7. Tubular solid oxide fuel cells with porous metal supports and ceramic interconnections

    DOEpatents

    Huang, Kevin; Ruka, Roswell J.

    2012-05-08

    An intermediate temperature solid oxide fuel cell structure capable of operating at from 600.degree. C. to 800.degree. C. having a very thin porous hollow elongated metallic support tube having a thickness from 0.10 mm to 1.0 mm, preferably 0.10 mm to 0.35 mm, a porosity of from 25 vol. % to 50 vol. % and a tensile strength from 700 GPa to 900 GPa, which metallic tube supports a reduced thickness air electrode having a thickness from 0.010 mm to 0.2 mm, a solid oxide electrolyte, a cermet fuel electrode, a ceramic interconnection and an electrically conductive cell to cell contact layer.

  8. FY 2014 Solid Oxide Fuel Cell Project Selections | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    The project will include fabrication and testing of cells, modeling the thermodynamics and ... and evaluate their performance in comparison to more established cathode materials. ...

  9. Development of planar solid oxide fuel cells for power generation applications

    SciTech Connect

    Minh, N.Q.

    1996-04-01

    Planar solid oxide fuel cells (SOFCs) are presently being developed for a variety of electric power generation application. The planar design offers simple cell geometry, high power density, and multiple fabrication and gas manifolding options. Planar SOFC technology has received much attention recently, and significant progress has been made in this area. Recent effort at AlliedSignal has focused on the development of high-performance, lightweight planar SOFCs, having thin-electrolyte films, that can be operated efficiently at reduced temperatures (< 1000{degrees}C). The advantages of reduced-temperature operation include wider material choice (including use of metallic interconnects), expected longer cell life, reduced thermal stress, improved reliability, and reduced fuel cell cost. The key aspect in the development of thin-film SIFCs is to incorporate the thin electrolyte layer into the desired structure of cells in a manner that yields the required characteristics. AlliedSignal has developed a simple and cost-effective method based on tape calendering for the fabrication of thin-electrolyte SOFCs. Thin-electrolyte cells made by tape calendering have shown extraordinary performance, e.g., producing more than 500mW/cm{sup 2} at 700{degrees}C and 800mW/cm{sup 2} at 800{degrees}C with hydrogen as fuel and air is oxidant. thin-electrolyte single cells have been incorporated into a compliant metallic stack structure and operated at reduced and operated at reduced-temperature conditions.

  10. Advances in tubular solid oxide fuel cell technology

    SciTech Connect

    Singhal, S.C.

    1996-12-31

    The design, materials and fabrication processes for the earlier technology Westinghouse tubular geometry cell have been described in detail previously. In that design, the active cell components were deposited in the form of thin layers on a ceramic porous support tube (PST). The tubular design of these cells and the materials used therein have been validated by successful electrical testing for over 65,000 h (>7 years). In these early technology PST cells, the support tube, although sufficiently porous, presented an inherent impedance to air flow toward air electrode. In order to reduce such impedance to air flow, the wall thickness of the PST was first decreased from the original 2 mm (the thick-wall PST) to 1.2 mm (the thin-wall PST). The calcia-stabilized zirconia support tube has now been completely eliminated and replaced by a doped lanthanum manganite tube in state-of-the-art SOFCs. This doped lanthanum manganite tube is extruded and sintered to about 30 to 35 percent porosity, and serves as the air electrode onto which the other cell components are fabricated in thin layer form. These latest technology cells are designated as air electrode supported (AES) cells.

  11. High Temperature Solid Oxide Fuel Cell Generator Development

    SciTech Connect

    Joseph Pierre

    2007-09-30

    This report describes the results of the tubular SOFC development program from August 22, 1997 to September 30, 2007 under the Siemens/U.S. Department of Energy Cooperative Agreement. The technical areas discussed include cell manufacturing development, cell power enhancement, SOFC module and system cost reduction and technology advancement, and our field unit test program. Whereas significant progress has been made toward commercialization, significant effort remains to achieve our cost, performance and reliability targets for successful commercialization.

  12. Solid oxide fuel cells, and air electrode and electrical interconnection materials therefor

    DOEpatents

    Bates, J. Lambert

    1992-01-01

    In one aspect of the invention, an air electrode material for a solid oxide fuel cell comprises Y.sub.1-a Q.sub.a MnO.sub.3, where "Q" is selected from the group consisting of Ca and Sr or mixtures thereof and "a" is from 0.1 to 0.8. Preferably, "a" is from 0.4 to 0.7. In another aspect of the invention, an electrical interconnection material for a solid oxide fuel cell comprises Y.sub.1-b Ca.sub.b Cr.sub.1-c Al.sub.c O.sub.3, where "b" is from 0.1 to 0.6 and "c" is from 0 to 9.3. Preferably, "b" is from 0.3 to 0.5 and "c" is from 0.05 to 0.1. A composite solid oxide electrochemical fuel cell incorporating these materials comprises: a solid oxide air electrode and an adjacent solid oxide electrical interconnection which commonly include the cation Y, the air electrode comprising Y.sub.1-a Q.sub.a MnO.sub.3, where "Q" is selected from the group consisting of Ca and Sr or mixtures thereof and "a" is from 0.1 to 0.8, the electrical interconnection comprising Y.sub.1-b Ca.sub.b Cr.sub.1-c Al.sub.c O.sub.3, where "b" is from 0.1 to 0.6 and "c" is from 0.0 to 0.3; a yttrium stabilized solid electrolyte comprising (1-d)ZrO.sub.2 -(d)Y.sub.2 O.sub.3 where "d" is from 0.06 to 0.5; and a solid fuel electrode comprising X-ZrO.sub.2, where "X" is an elemental metal.

  13. Solid oxide fuel cells, and air electrode and electrical interconnection materials therefor

    DOEpatents

    Bates, J.L.

    1992-09-01

    In one aspect of the invention, an air electrode material for a solid oxide fuel cell comprises Y[sub 1[minus]a]Q[sub a]MnO[sub 3], where Q is selected from the group consisting of Ca and Sr or mixtures thereof and a' is from 0.1 to 0.8. Preferably, a' is from 0.4 to 0.7. In another aspect of the invention, an electrical interconnection material for a solid oxide fuel cell comprises Y[sub 1[minus]b]Ca[sub b]Cr[sub 1[minus]c]Al[sub c]O[sub 3], where b' is from 0.1 to 0.6 and c' is from 0 to 9.3. Preferably, b' is from 0.3 to 0.5 and c' is from 0.05 to 0.1. A composite solid oxide electrochemical fuel cell incorporating these materials comprises: a solid oxide air electrode and an adjacent solid oxide electrical interconnection which commonly include the cation Y, the air electrode comprising Y[sub 1[minus]a]Q[sub a]MnO[sub 3], where Q is selected from the group consisting of Ca and Sr or mixtures thereof and a' is from 0.1 to 0.8, the electrical interconnection comprising Y[sub 1[minus]b]Ca[sub b]Cr[sub 1[minus]c]Al[sub c]O[sub 3], where b' is from 0.1 to 0.6 and c' is from 0.0 to 0.3; a yttrium stabilized solid electrolyte comprising (1[minus]d)ZrO[sub 2]-(d)Y[sub 2]O[sub 3] where d' is from 0.06 to 0.5; and a solid fuel electrode comprising X-ZrO[sub 2], where X' is an elemental metal. 5 figs.

  14. Characterization of Solid Oxide Fuel Cell Components Using Electromagnetic Model-Based Sensors

    SciTech Connect

    Zilberstein, Vladimir; Craven, Chris; Goldfine, Neil

    2004-12-28

    In this Phase I SBIR, the contractor demonstrated a number of capabilities of model-based sensors such as MWM sensors and MWM-Arrays. The key results include (1) porosity/microstructure characterization for anodes, (2) potential for cathode material characterization, (3) stress measurements in nickel and cobalt, and (4) potential for stress measurements in non-magnetic materials with a ferromagnetic layer. In addition, potential applications for manufacturing quality control of nonconductive layers using interdigitated electrode dielectrometers have been identified. The results indicate that JENTEK's MWM technology can be used to significantly reduce solid oxide fuel cell production and operating costs in a number of ways. Preliminary investigations of solid oxide fuel cell health monitoring and scale-up issues to address industry needs have also been performed.

  15. DEVELOPMENT OF LOW-COST MANUFACTURING PROCESSES FOR PLANAR, MULTILAYER SOLID OXIDE FUEL CELL ELEMENTS

    SciTech Connect

    Scott Swartz; Matthew Seabaugh; William Dawson; Harlan Anderson; Tim Armstrong; Michael Cobb; Kirby Meacham; James Stephan; Russell Bennett; Bob Remick; Chuck Sishtla; Scott Barnett; John Lannutti

    2004-06-12

    This report summarizes the results of a four-year project, entitled, ''Low-Cost Manufacturing Of Multilayer Ceramic Fuel Cells'', jointly funded by the U.S. Department of Energy, the State of Ohio, and by project participants. The project was led by NexTech Materials, Ltd., with subcontracting support provided by University of Missouri-Rolla, Michael A. Cobb & Co., Advanced Materials Technologies, Inc., Edison Materials Technology Center, Gas Technology Institute, Northwestern University, and The Ohio State University. Oak Ridge National Laboratory, though not formally a subcontractor on the program, supported the effort with separate DOE funding. The objective of the program was to develop advanced manufacturing technologies for making solid oxide fuel cell components that are more economical and reliable for a variety of applications. The program was carried out in three phases. In the Phase I effort, several manufacturing approaches were considered and subjected to detailed assessments of manufacturability and development risk. Estimated manufacturing costs for 5-kW stacks were in the range of $139/kW to $179/kW. The risk assessment identified a number of technical issues that would need to be considered during development. Phase II development work focused on development of planar solid oxide fuel cell elements, using a number of ceramic manufacturing methods, including tape casting, colloidal-spray deposition, screen printing, spin-coating, and sintering. Several processes were successfully established for fabrication of anode-supported, thin-film electrolyte cells, with performance levels at or near the state-of-the-art. The work in Phase III involved scale-up of cell manufacturing methods, development of non-destructive evaluation methods, and comprehensive electrical and electrochemical testing of solid oxide fuel cell materials and components.

  16. Oxygen reduction and transportation mechanisms in solid oxide fuel cell cathodes

    SciTech Connect

    Li YH, Gemmen R, Liu XB

    2010-06-01

    In recent years, various models have been developed for describing the reaction mechanisms in solid oxide fuel cell (SOFC) especially for the cathode electrode. However, many fundamental issues regarding the transport of oxygen and electrode kinetics have not been fully understood. This review tried to summarize the present status of the SOFC cathode modeling efforts, and associated experimental approaches on this topic. In addition, unsolved problems and possible future research directions for SOFC cathode kinetics had been discussed

  17. Solid oxide fuel cell with multi-unit construction and prismatic design

    DOEpatents

    McPheeters, Charles C.; Dees, Dennis W.; Myles, Kevin M.

    1999-01-01

    A single cell unit of a solid oxide fuel cell that is individually fabricated and sintered prior to being connected to adjacent cells to form a solid oxide fuel cell. The single cell unit is comprised of a shaped anode sheet positioned between a flat anode sheet and an anode-electrolyte-cathode (A/E/C) sheet, and a shaped cathode sheet positioned between the A/E/C sheet and a cathode-interconnect-anode (C/I/A) sheet. An alternate embodiment comprises a shaped cathode sheet positioned between an A/E/C sheet and a C/I/A sheet. The shaped sheets form channels for conducting reactant gases. Each single cell unit is individually sintered to form a finished sub-assembly. The finished sub-assemblies are connected in electrical series by interposing connective material between the end surfaces of adjacent cells, whereby individual cells may be inspected for defects and interchanged with non-defective single cell units.

  18. Solid oxide fuel cell with multi-unit construction and prismatic design

    DOEpatents

    McPheeters, C.C.; Dees, D.W.; Myles, K.M.

    1999-03-16

    A single cell unit of a solid oxide fuel cell is described that is individually fabricated and sintered prior to being connected to adjacent cells to form a solid oxide fuel cell. The single cell unit is comprised of a shaped anode sheet positioned between a flat anode sheet and an anode-electrolyte-cathode (A/E/C) sheet, and a shaped cathode sheet positioned between the A/E/C sheet and a cathode-interconnect-anode (C/I/A) sheet. An alternate embodiment comprises a shaped cathode sheet positioned between an A/E/C sheet and a C/I/A sheet. The shaped sheets form channels for conducting reactant gases. Each single cell unit is individually sintered to form a finished sub-assembly. The finished sub-assemblies are connected in electrical series by interposing connective material between the end surfaces of adjacent cells, whereby individual cells may be inspected for defects and interchanged with non-defective single cell units. 7 figs.

  19. Composite electrolyte with proton conductivity for low-temperature solid oxide fuel cell

    SciTech Connect

    Raza, Rizwan; Ahmed, Akhlaq; Akram, Nadeem; Saleem, Muhammad; Niaz Akhtar, Majid; Ajmal Khan, M.; Abbas, Ghazanfar; Alvi, Farah; Yasir Rafique, M.; Sherazi, Tauqir A.; Shakir, Imran; Mohsin, Munazza; Javed, Muhammad Sufyan; Zhu, Bin E-mail: zhubin@hubu.edu.cn

    2015-11-02

    In the present work, cost-effective nanocomposite electrolyte (Ba-SDC) oxide is developed for efficient low-temperature solid oxide fuel cells (LTSOFCs). Analysis has shown that dual phase conduction of O{sup −2} (oxygen ions) and H{sup +} (protons) plays a significant role in the development of advanced LTSOFCs. Comparatively high proton ion conductivity (0.19 s/cm) for LTSOFCs was achieved at low temperature (460 °C). In this article, the ionic conduction behaviour of LTSOFCs is explained by carrying out electrochemical impedance spectroscopy measurements. Further, the phase and structure analysis are investigated by X-ray diffraction and scanning electron microscopy techniques. Finally, we achieved an ionic transport number of the composite electrolyte for LTSOFCs as high as 0.95 and energy and power density of 90% and 550 mW/cm{sup 2}, respectively, after sintering the composite electrolyte at 800 °C for 4 h, which is promising. Our current effort toward the development of an efficient, green, low-temperature solid oxide fuel cell with the incorporation of high proton conductivity composite electrolyte may open frontiers in the fields of energy and fuel cell technology.

  20. Solid Oxide Fuel Cell (SOFC) Technology for Greener Airplanes

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Cell (SOFC) Technology for Greener Airplanes Larry Chick/Mike Rinker Energy Materials Group Pacific Northwest National Laboratory September 30, 2010 2 2 SOFC Technology Development at PNNL PNNL has been active in SOFC development since 1987. Major participant in SECA Core Technology Program since 2000. SOFC stack electrochemical- thermal modeling Development of electrically conductive coatings to prevent Cr volatility from SS Glycine - nitrate powder synthesis of La 0.7 Ca 0.31 CrO 3 3

  1. Basic properties of a liquidt in anode solid oxide fuel cell

    SciTech Connect

    Harry Abernathy; RandallGemmen; KirkGerdes; Mark Koslowske; ThomasTao

    2010-12-17

    An unconventional high temperature fuel cell system, the liquidt in anode solid oxide fuel cell(LTA-SOFC), is discussed. A thermodynamic analysis of a solid oxide fuel cell with a liquid metal anode is developed. Pertinent thermo chemical and thermo physical properties of liquid tin in particular are detailed. An experimental setup for analysis of LTA-SOFC anode kinetics is described, and data for a planar cell under hydrogen indicated an effective oxygen diffusion coefficient of 5.310?5 cm2 s?1 at 800 ?C and 8.910?5 cm2 s?1 at 900 ?C. This value is similar to previously reported literature values for liquid tin. The oxygen conductivity through the tin, calculated from measured diffusion coefficients and theoretical oxygen solubility limits, is found to be on the same order of thatofyttria-stabilizedzirconia(YSZ), a traditional SOFC electrolyte material. As such,the ohmicloss due to oxygen transport through the tin layer must be considered in practical system cell design since the tin layer will usually be at least as thick as the electrolyte.

  2. Compliant sealants for solid oxide fuel cells and other ceramics

    DOEpatents

    Bloom, I.D.; Ley, K.L.

    1995-09-26

    A glass or glass-ceramic sealant is described for a SOFC having a coefficient of thermal expansion in the range of from about 8 to about 13{times}10{sup {minus}6}/C and a viscosity of at least 10{sup 3}Pa-s at cell operating temperature. The sealant has a composition of SrO present in the range of from about 5 to about 60 mole percent, La{sub 2}O{sub 3} present in the range of from 0 to about 45 mole percent, Al{sub 2}O{sub 3} present in the range from 0 to about 15 mole percent, B{sub 2}O{sub 3} present in the range of from about 15 mole percent to about 80 mole percent, and SiO{sub 2} present in the range of from 0 to about 40 mole percent, wherein the material is a viscous fluid at cell operating temperatures of from about 600 C to about 1000 C. The sealant may also be compounds of CaO present in the range of from 0 to about 35 mole percent, Al{sub 2}O{sub 3} present in the range from 0 to about 15 mole percent, B{sub 2}O{sub 3} present in the range of from about 35 mole percent to about 85 mole percent, and SiO{sub 2} present in the range of from 0 to about 30 mole percent. 2 figs.

  3. Compliant sealants for solid oxide fuel cells and other ceramics

    DOEpatents

    Bloom, Ira D.; Ley, Kevin L.

    1995-01-01

    A glass or glass-ceramic sealant for a SOFC having a coefficient of thermal expansion in the range of from about 8 to about 13.times.10.sup.-6 /.degree.C. and a viscosity of at least 10.sup.3 Pa-s at cell operating temperature. The sealant has a composition of SrO present in the range of from about 5 to about 60 mole percent, La.sub.2 O.sub.3 present in the range of from 0 to about 45 mole percent, Al.sub.2 O.sub.3 present in the range from 0 to about 15 mole percent, B.sub.2 O.sub.3 present in the range of from about 15 mole percent to about 80 mole percent, and SiO.sub.2 present in the range of from 0 to about 40 mole percent, wherein the material is a viscous fluid at cell operating temperatures of from about 600.degree. C. to about 1000.degree. C. The sealant may also be compounds of CaO present in the range of from 0 to about 35 mole percent, Al.sub.2 O.sub.3 present in the range from 0 to about 15 mole percent, B.sub.2 O.sub.3 present in the range of from about 35 mole percent to about 85 mole percent, and SiO.sub.2 present in the range of from 0 to about 30 mole percent.

  4. Functionally Graded Cathodes for Solid Oxide Fuel Cells

    SciTech Connect

    Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

    2008-04-30

    The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts

  5. Structure{leftrightarrow}property relationships in solid oxide fuel cells

    SciTech Connect

    Huebner, W.; Reed, D.M.; Anderson, H.U.

    1996-12-31

    The electrode reactions are a major cause of the energy losses in SOFC`s, and limit their use to higher temperatures, typically 800-1000{degrees}C. The electrode reactions have received much attention aimed at better understanding the electrode kinetics and mechanisms, but are still very primitive in their basic understanding. The electrode microstructure and its corresponding reactivity has commonly been studied by DC and AC impedance techniques. A common method of examining electrode reactions employs surface-mounted reference electrodes, although this technique often limits the experiment to examination of one electrode. In this study a new technique has been developed of utilizing a Pt voltage probe placed internally into the electrolyte to measure the IN and impedance spectra of both electrodes operating under cell conditions. Unlike surface mounted electrodes which need to be concerned with distance and dimensions of reference electrodes with respect to working and counter electrodes the internal Pt voltage probe is centered internally at a known depth within the electrolyte and between corresponding electrodes.

  6. Cost Study for Manufacturing of Solid Oxide Fuel Cell Power Systems

    SciTech Connect

    Weimar, Mark R.; Chick, Lawrence A.; Gotthold, David W.; Whyatt, Greg A.

    2013-09-30

    Solid oxide fuel cell (SOFC) power systems can be designed to produce electricity from fossil fuels at extremely high net efficiencies, approaching 70%. However, in order to penetrate commercial markets to an extent that significantly impacts world fuel consumption, their cost will need to be competitive with alternative generating systems, such as gas turbines. This report discusses a cost model developed at PNNL to estimate the manufacturing cost of SOFC power systems sized for ground-based distributed generation. The power system design was developed at PNNL in a study on the feasibility of using SOFC power systems on more electric aircraft to replace the main engine-mounted electrical generators [Whyatt and Chick, 2012]. We chose to study that design because the projected efficiency was high (70%) and the generating capacity was suitable for ground-based distributed generation (270 kW).

  7. Manifold, bus support and coupling arrangement for solid oxide fuel cells

    DOEpatents

    Parry, Gareth W.

    1989-01-01

    Individual, tubular solid oxide fuel cells (SOFCs) are assembled into bundles called a module within a housing, with a plurality of modules arranged end-to-end in a linear, stacked configuration called a string. A common set of piping comprised of a suitable high temperture resistant material (1) provides fuel and air to each module housing, (2) serves as electrically conducting buses, and (3) provides structural support for a string of SOFC modules. The piping thus forms a manfold for directing fuel and air to each module in a string and makes electrical contact with the module's anode and cathode to conduct the DC power generated by the SOFC. The piping also provides structureal support for each individual module and maintains each string of modules as a structurally integral unit for ensuring high strength in a large 3-dimensional array of SOFC modules. Ceramic collars are used to connect fuel and air inlet piping to each of the electrodes in an SOFC module and provide (1) electrical insulation for the current carrying bus bars and gas manifolds, (2) damping for the fuel and air inlet piping, and (3) proper spacing between the fuel and air inlet piping to prevent contact between these tubes and possible damage to the SOFC.

  8. Cassettes for solid-oxide fuel cell stacks and methods of making the same

    DOEpatents

    Weil, K. Scott; Meinhardt, Kerry D; Sprenkle, Vincent L

    2012-10-23

    Solid-oxide fuel cell (SOFC) stack assembly designs are consistently investigated to develop an assembly that provides optimal performance, and durability, within desired cost parameters. A new design includes a repeat unit having a SOFC cassette and being characterized by a three-component construct. The three components include an oxidation-resistant, metal window frame hermetically joined to an electrolyte layer of a multi-layer, anode-supported ceramic cell and a pre-cassette including a separator plate having a plurality of vias that provide electrical contact between an anode-side collector within the pre-cassette and a cathode-side current collector of an adjacent cell. The third component is a cathode-side seal, which includes a standoff that supports a cathode channel spacing between each of the cassettes in a stack. Cassettes are formed by joining the pre-cassette and the window frame.

  9. Development of a hydrogen generator for fuel cells based on the partial oxidation of methane

    SciTech Connect

    Recupero, V.; Torre, T.; Saija, G.; Fiordano, N.

    1996-12-31

    As well known, the most acknowledged process for generation of hydrogen for fuel cells is based upon the steam reforming of methane or natural gas (SRM). The reaction is endothermic ({Delta}H{sub 298}= 206 kJ/mole) and high H{sub 2}O/CH{sub 4} ratios are required in order to limit coke formation at T higher than 1000 K. Moreover, it is a common practice that the process`s fuel economy is highly sensitive to proper heat fluxes and reactor design (tubular type) and to operational conditions. Efficient heat recovery can be accomplished only on large scale units (> 40,000 Nm{sup 3}/h), far from the range of interest of {open_quotes}on-site{close_quotes} fuel cells. Even if, to fit the needs of the fuel cell technology, medium sized external reforming units (50-200 Nm{sup 3} H{sub 2}/h) have been developed and/or planned for integration with both the first and the second generation fuel cells, amelioration in their heat recovery and efficiency is at the expense of an increased sophistication and therefore at higher per unit costs. In all cases, SRM requires an extra {open_quotes}fuel{close_quotes} supply (to substain the endothermicity of the reaction) in addition to stoichiometric requirements ({open_quotes}feed{close_quotes} gas). A valid alternative could be a process based on catalytic partial oxidation of CH{sub 4} (CSPOM), since the process is mildly exothermic ({Delta}H{sub 298}= -35.6 kJ/mole) and therefore not energy intensive. Consequently, great interest is expected from conversion of methane into syngas, if an autothermal, low energy intensive, compact and reliable process could be developed.

  10. Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Power - Combat Proven Take Almost Any Generator Plug into Clean Power Provided by ... Fuel desulfurizer JP JP- -8 Fueled 10kW Generator 8 Fueled 10kW Generator 108 cell Cathode ...

  11. Fuel cell stack arrangements

    DOEpatents

    Kothmann, Richard E.; Somers, Edward V.

    1982-01-01

    Arrangements of stacks of fuel cells and ducts, for fuel cells operating with separate fuel, oxidant and coolant streams. An even number of stacks are arranged generally end-to-end in a loop. Ducts located at the juncture of consecutive stacks of the loop feed oxidant or fuel to or from the two consecutive stacks, each individual duct communicating with two stacks. A coolant fluid flows from outside the loop, into and through cooling channels of the stack, and is discharged into an enclosure duct formed within the loop by the stacks and seals at the junctures at the stacks.

  12. Molten carbonate fuel cell

    DOEpatents

    Kaun, Thomas D.; Smith, James L.

    1987-01-01

    A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  13. Molten carbonate fuel cell

    DOEpatents

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  14. Fundamental Studies of the Durability of Materials for Interconnects in Solid Oxide Fuel Cells

    SciTech Connect

    Frederick S. Pettit; Gerald H. Meier

    2006-06-30

    Ferritic stainless steels are a leading candidate material for use as an SOFC interconnect, but have the problem of forming volatile chromia species that lead to cathode poisoning. This project has focused both on optimization of ferritic alloys for SOFC applications and evaluating the possibility of using alternative materials. The initial efforts involved studying the oxidation behavior of a variety of chromia-forming ferritic stainless steels in the temperature range 700-900 C in atmospheres relevant to solid oxide fuel cell operation. The alloys exhibited a wide variety of oxidation behavior based on composition. A method for reducing the vaporization is to add alloying elements that lead to the formation of a thermally grown oxide layer over the protective chromia. Several commercial steels form manganese chromate on the surface. This same approach, combined with observations of TiO{sub 2} overlayer formation on the chromia forming, Ni-based superalloy IN 738, has resulted in the development of a series of Fe-22 Cr-X Ti alloys (X=0-4 wt%). Oxidation testing has indicated that this approach results in significant reduction in chromia evaporation. Unfortunately, the Ti also results in accelerated chromia scale growth. Fundamental thermo-mechanical aspects of the durability of solid oxide fuel cell (SOFC) interconnect alloys have also been investigated. A key failure mechanism for interconnects is the spallation of the chromia scale that forms on the alloy, as it is exposed to fuel cell environments. Indentation testing methods to measure the critical energy release rate (Gc) associated with the spallation of chromia scale/alloy systems have been evaluated. This approach has been used to evaluate the thermomechanical stability of chromia films as a function of oxidation exposure. The oxidation of pure nickel in SOFC environments was evaluated using thermogravimetric analysis (TGA) to determine the NiO scaling kinetics and a four-point probe was used to measure

  15. Short time proton dynamics in bulk ice and in porous anode solid oxide fuel cell materials

    SciTech Connect

    Basoli, Francesco; Senesi, Roberto; Kolesnikov, Alexander I; Licoccia, Silvia

    2014-01-01

    Oxygen reduction and incorporation into solid electrolytes and the reverse reaction of oxygen evolution play a cru-cial role in Solid Oxide Fuel Cell (SOFC) applications. However a detailed un derstanding of the kinetics of the cor-responding reactions, i.e. on reaction mechanisms, rate limiting steps, reaction paths, electrocatalytic role of materials, is still missing. These include a thorough characterization of the binding potentials experienced by protons in the lattice. We report results of Inelastic Neutron Scattering (INS) measurements of the vibrational state of the protons in Ni- YSZ highly porous composites (75% to 90% ), a ceramic-metal material showing a high electrical conductivity and ther mal stability, which is known to be most effectively used as anodes for solid ox ide fuel cells. The results are compared with INS and Deep Inelastic Neutron Scattering (DINS) experiments on the proton binding states in bulk ice.

  16. Performance of solid oxide fuel cells approaching the two-dimensional limit

    SciTech Connect

    Kerman, K. Ramanathan, S.

    2014-05-07

    We model electrochemical kinetics and physical conduction mechanisms for carrier transport in electrolyte membranes to determine the limits of dimensionality reduction (down to 1?nm) on maximum power output of solid oxide fuel cells with symmetric Pt electrodes. Using Y-doped ZrO{sub 2}, we find a minimum thickness of ?6?nm to realize near ideal chemical potential in such fuel cells, which is limited by electronic breakdown when approaching the dielectric breakdown strength. For larger electrolyte thicknesses, the greatest source of electronic leakage influencing power loss is from Ohmic transport of minority carriers and emission of trapped carriers. For porous metallic electrodes, an ideal microstructure with the particle size comparable to particle spacing dimensions is found to accurately model experimental results. The role of electronic trap states in the electrolyte band gap on power density characteristics is highlighted.

  17. Mixed Oxide Fuel Fabrication Facility

    National Nuclear Security Administration (NNSA)

    0%2A en Mixed Oxide (MOX) Fuel Fabrication Facility http:nnsa.energy.govfieldofficessavannah-river-field-officemixed-oxide-mox-fuel-fabrication-facility

  18. Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program

    SciTech Connect

    Nguyen Minh

    2006-07-31

    This report summarizes the work performed for Phase I (October 2001 - August 2006) under Cooperative Agreement DE-FC26-01NT41245 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled 'Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program'. The program focuses on the development of a low-cost, high-performance 3-to-10-kW solid oxide fuel cell (SOFC) system suitable for a broad spectrum of power-generation applications. During Phase I of the program significant progress has been made in the area of SOFC technology. A high-efficiency low-cost system was designed and supporting technology developed such as fuel processing, controls, thermal management, and power electronics. Phase I culminated in the successful demonstration of a prototype system that achieved a peak efficiency of 41%, a high-volume cost of $724/kW, a peak power of 5.4 kW, and a degradation rate of 1.8% per 500 hours. . An improved prototype system was designed, assembled, and delivered to DOE/NETL at the end of the program. This prototype achieved an extraordinary peak efficiency of 49.6%.

  19. A Total Cost of Ownership Model for Solid Oxide Fuel Cells in...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    a total cost of ownership model for emerging applications in stationary fuel cell systems. ... A Total Cost of Ownership Model for Low Temperature PEM Fuel Cells in Combined Heat ...

  20. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOEpatents

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  1. Methods for using novel cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    DOEpatents

    Jacobson, Allan J.; Wang, Shuangyan; Kim, Gun Tae

    2016-01-12

    Methods using novel cathode, electrolyte and oxygen separation materials operating at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes include oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  2. Optimization design of electrodes for anode-supported solid oxide fuel cells via genetic algorithm

    SciTech Connect

    Shi, J.; Xue, X.

    2011-01-01

    Porous electrode is the critical component of solid-oxide fuel cells (SOFCs) and provides a functional material backbone for multi-physicochemical processes. Model based electrode designs could significantly improve SOFC performance. This task is usually performed via parameter studies for simple case and assumed property distributions for graded electrodes. When nonlinearly coupled multiparameters of electrodes are considered, it could be very difficult for the model based parameter study method to effectively and systematically search the design space. In this research, the optimization approach with a genetic algorithm is demonstrated for this purpose. An anode-supported proton conducting SOFC integrated with a fuel supply system is utilized as a physical base for the model development and the optimization design. The optimization results are presented, which are difficult to obtain for parametric study method.

  3. Electrical Generation for More-Electric Aircraft Using Solid Oxide Fuel Cells

    SciTech Connect

    Whyatt, Greg A.; Chick, Lawrence A.

    2012-04-01

    This report examines the potential for Solid-Oxide Fuel Cells (SOFC) to provide electrical generation on-board commercial aircraft. Unlike a turbine-based auxiliary power unit (APU) a solid oxide fuel cell power unit (SOFCPU) would be more efficient than using the main engine generators to generate electricity and would operate continuously during flight. The focus of this study is on more-electric aircraft which minimize bleed air extraction from the engines and instead use electrical power obtained from generators driven by the main engines to satisfy all major loads. The increased electrical generation increases the potential fuel savings obtainable through more efficient electrical generation using a SOFCPU. However, the weight added to the aircraft by the SOFCPU impacts the main engine fuel consumption which reduces the potential fuel savings. To investigate these relationships the Boeing 787­8 was used as a case study. The potential performance of the SOFCPU was determined by coupling flowsheet modeling using ChemCAD software with a stack performance algorithm. For a given stack operating condition (cell voltage, anode utilization, stack pressure, target cell exit temperature), ChemCAD software was used to determine the cathode air rate to provide stack thermal balance, the heat exchanger duties, the gross power output for a given fuel rate, the parasitic power for the anode recycle blower and net power obtained from (or required by) the compressor/expander. The SOFC is based on the Gen4 Delphi planar SOFC with assumed modifications to tailor it to this application. The size of the stack needed to satisfy the specified condition was assessed using an empirically-based algorithm. The algorithm predicts stack power density based on the pressure, inlet temperature, cell voltage and anode and cathode inlet flows and compositions. The algorithm was developed by enhancing a model for a well-established material set operating at atmospheric pressure to reflect the

  4. 2007 Fuel Cell Technologies Market Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline...

  5. Fuel cell market applications

    SciTech Connect

    Williams, M.C.

    1995-12-31

    This is a review of the US (and international) fuel cell development for the stationary power generation market. Besides DOE, GRI, and EPRI sponsorship, the US fuel cell program has over 40% cost-sharing from the private sector. Support is provided by user groups with over 75 utility and other end-user members. Objectives are to develop and demonstrate cost-effective fuel cell power generation which can initially be commercialized into various market applications using natural gas fuel by the year 2000. Types of fuel cells being developed include PAFC (phosphoric acid), MCFC (molten carbonate), and SOFC (solid oxide); status of each is reported. Potential international applications are reviewed also. Fuel cells are viewed as a force in dispersed power generation, distributed power, cogeneration, and deregulated industry. Specific fuel cell attributes are discussed: Fuel cells promise to be one of the most reliable power sources; they are now being used in critical uninterruptible power systems. They need hydrogen which can be generated internally from natural gas, coal gas, methanol landfill gas, or other fuels containing hydrocarbons. Finally, fuel cell development and market applications in Japan are reviewed briefly.

  6. Fuel Cell Power Plant Experience Naval Applications

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy/ Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC March 29, 2011 FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. *FuelCell Energy, Inc. *Renewable and Liquid Fuels Experience *HTPEM Fuel Cell Stack for Shipboard APU *Solid Oxide Experience and Applications DOE-ONR Workshop FuelCell Energy, the FuelCell

  7. Zero Emission Power Plants Using Solid Oxide Fuel Cells and Oxygen Transport Membranes

    SciTech Connect

    Shockling, Larry A.; Huang, Keqin; Gilboy, Thomas E.; Christie, G. Maxwell; Raybold, Troy M.

    2001-11-06

    Siemens Westinghouse Power Corp. (SWPC) is engaged in the development of Solid Oxide Fuel Cell stationary power systems. SWPC has combined DOE Developmental funds with commercial customer funding to establish a record of successful SOFC field demonstration power systems of increasing size. SWPC will soon deploy the first unit of a newly developed 250 kWe Combined Heat Power System. It will generate electrical power at greater than 45% electrical efficiency. The SWPC SOFC power systems are equipped to operate on lower number hydrocarbon fuels such as pipeline natural gas, which is desulfurized within the SOFC power system. Because the system operates with a relatively high electrical efficiency, the CO2 emissions, {approx}1.0 lb CO2/ kW-hr, are low. Within the SOFC module the desulfurized fuel is utilized electrochemically and oxidized below the temperature for NOx generation. Therefore the NOx and SOx emissions for the SOFC power generation system are near negligible. The byproducts of the power generation from hydrocarbon fuels that are released into the environment are CO2 and water vapor. This forward looking DOE sponsored Vision 21 program is supporting the development of methods to capture and sequester the CO2, resulting in a Zero Emission power generation system. To accomplish this, SWPC is developing a SOFC module design, to be demonstrated in operating hardware, that will maintain separation of the fuel cell anode gas, consisting of H2, CO, H2O and CO2, from the vitiated air. That anode gas, the depleted fuel stream, containing less than 18% (H2 + CO), will be directed to an Oxygen Transport Membrane (OTM) Afterburner that is being developed by Praxair, Inc.. The OTM is supplied air and the depleted fuel. The OTM will selectively transport oxygen across the membrane to oxidize the remaining H2 and CO. The water vapor is then condensed from the totally 1.5.DOC oxidized fuel stream exiting the afterburner, leaving only the CO2 in gaseous form. That CO2 can

  8. A solid oxide fuel cell power system: 1992--1993 field operation

    SciTech Connect

    Veyo, S.E.; Kusunoki, A.; Takeuchi, S.; Kaneko, S.; Yokoyama, H.

    1994-05-01

    Westinghouse has deployed fully integrated, automatically controlled, packaged solid oxide fuel cell (SOFC) power generation systems in order to obtain useful customer feedback. Recently, Westinghouse has deployed 20 kW class natural gas fueled SOFC generator modules integrated into two 25 kW SOFC systems, the first with The UTILITIES, a Japanese consortium. The UTILITIES 25 kW SOFC system is the focus of this paper. The unit was shipped to the Rokko Island Test Center for Advanced Energy Systems (near Kobe, Japan) operated by Kansai Electric Power Co.; testing was initiated February 1992. Module A operated for 2601 hours at an ave output 16.6 kW dc; final shutdown was induced by current stability problems with dissipator (restart not possible because of damaged cells). Module B operated for 1579 hours at ave output 17.8 kWdc. The unit was damaged by operation at excessively high fuel utilization > 91%. It was rebuilt and returned to Rokko Island. This module B2 operated for 1843 hours on PNG; shutdown was cuased by air supply failure. After a new blower and motor were installed July 1993, the system was restarted August 5, 1993 and operated continuously until November 10, 1993, when an automatic shutdown was induced as part of a MITI licensing inspection. After restart, the unit passed 6000 hours of operation on desulfurized PNG on January 25, 1994. Westinghouse`s future plans are outlined.

  9. Optimization and Demonstration of a Solid Oxide Regenerative Fuel Cell System

    SciTech Connect

    James F. McElroy; Darren B. Hickey; Fred Mitlitsky

    2006-09-30

    Single cell solid oxide regenerative fuel cells (SORFCs) have been demonstrated for over 1000 hours of operation at degradation rates as low as 0.5% per thousand hours for current densities as high as 300mA/cm{sup 2}. Efficiency levels (fuel cell power out vs. electrolysis power in) have been demonstrated in excess of 80% at 100mA/cm{sup 2}. All testing has been performed with metallic based interconnects and non-noble metal electrodes in order to limit fabrication costs for commercial considerations. The SORFC cell technology will be scaled up to a 1kW sized stack which will be demonstrated in Year 2 of the program. A self contained SORFC system requires efficient thermal management in order to maintain operating temperatures during exothermic and endothermic operational modes. The use of LiF as a phase change material (PCM) was selected as the optimum thermal storage medium by virtue of its superior thermal energy density by volume. Thermal storage experiments were performed using LiF and a simulated SORFC stack. The thermal storage concept was deemed to be technically viable for larger well insulated systems, although it would not enable a high efficiency thermally self-sufficient SORFC system at the 1 kW level.

  10. Program of scientific investigations and development of solid-oxide fuel cells (SOFC) in VIITF proposals on scientific and technical collaboration and SOFC commercialization

    SciTech Connect

    Kleschev, Yu.N.; Chulharev, V.F.

    1996-04-01

    Investigations being performed at VNIITF covers the whole cycle of solid oxide fuel cell manufacturing. This report describes the main directions of investigations in materials, technologies, and commercialization.

  11. Fuel cell system with interconnect

    DOEpatents

    Liu, Zhien; Goettler, Richard; Delaforce, Philip Mark

    2016-03-08

    The present invention includes a fuel cell system having an interconnect that reduces or eliminates diffusion (leakage) of fuel and oxidant by providing an increased densification, by forming the interconnect as a ceramic/metal composite.

  12. Method of Fabrication of High Power Density Solid Oxide Fuel Cells

    DOEpatents

    Pham, Ai Quoc; Glass, Robert S.

    2008-09-09

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O(LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  13. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell ...

  14. Composite solid oxide fuel cell anode based on ceria and strontium titanate

    DOEpatents

    Marina, Olga A.; Pederson, Larry R.

    2008-12-23

    An anode and method of making the same wherein the anode consists of two separate phases, one consisting of a doped strontium titanate phase and one consisting of a doped cerium oxide phase. The strontium titanate phase consists of Sr.sub.1-xM.sub.xTiO.sub.3-.delta., where M is either yttrium (Y), scandium (Sc), or lanthanum (La), where "x" may vary typically from about 0.01 to about 0.5, and where .delta. is indicative of some degree of oxygen non-stoichiometry. A small quantity of cerium may also substitute for titanium in the strontium titanate lattice. The cerium oxide consists of N.sub.yCe.sub.1-yO.sub.2-.delta., where N is either niobium (Nb), vanadium (V), antimony (Sb) or tantalum (Ta) and where "y" may vary typically from about 0.001 to about 0.1 and wherein the ratio of Ti in said first phase to the sum of Ce and N in the second phase is between about 0.2 to about 0.75. Small quantities of strontium, yttrium, and/or lanthanum may additionally substitute into the cerium oxide lattice. The combination of these two phases results in better performance than either phase used separately as an anode for solid oxide fuel cell or other electrochemical device.

  15. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Seminar Orlando, FL Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 1112011 2 | Fuel Cell Technologies Program Source: US ...

  16. Method of fabricating a monolithic core for a solid oxide fuel cell

    DOEpatents

    Zwick, Stanley A.; Ackerman, John P.

    1985-01-01

    A method is disclosed for forming a core for use in a solid oxide fuel cell that electrochemically combines fuel and oxidant for generating galvanic output. The core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support consisting instead only of the active anode, cathode, electrolyte and interconnect materials. Each electrolyte wall consists of cathode and anode materials sandwiching electrolyte material therebetween, and each interconnect wall consists of the cathode and anode materials sandwiching interconnect material therebetween. The electrolyte and interconnect walls define a plurality of substantially parallel core passageways alternately having respectively the inside faces thereof with only the anode material or with only the cathode material exposed. In the wall structure, the electrolyte and interconnect materials are only 0.002-0.01 cm thick; and the cathode and anode materials are only 0.002-0.05 cm thick. The method consists of building up the electrolyte and interconnect walls by depositing each material on individually and endwise of the wall itself, where each material deposit is sequentially applied for one cycle; and where the depositing cycle is repeated many times until the material buildup is sufficient to formulate the core. The core is heat cured to become dimensionally and structurally stable.

  17. The Modeling of a Standalone Solid-Oxide Fuel Cell Auxiliary Power Unit

    SciTech Connect

    Lu, Ning; Li, Qinghe; Sun, Xin; Khaleel, Mohammad A.

    2006-10-27

    In this research, a Simulink model of a standalone vehicular solid-oxide fuel cell (SOFC) auxiliary power unit (APU) is developed. The SOFC APU model consists of three major components: a controller model; a power electronics system model; and an SOFC plant model, including an SOFC stack module; two heat exchanger modules; and a combustor module. This paper discusses the development of the nonlinear dynamic models for the SOFC stacks, the heat exchangers and the combustors. When coupling with a controller model and a power electronic circuit model, the developed SOFC plant model is able to model the thermal dynamics and the electrochemical dynamics inside the SOFC APU components as well as the transient responses to the electric loading changes. It has been shown that having such a model for the SOFC APU will benefit design engineers to adjust design parameters to optimize the performance. The modeling results of the heat-up stage of an SOFC APU and the output voltage response to a sudden load change are presented in the paper. The fuel flow regulation based on fuel utilization is also briefly discussed.

  18. Bipolar fuel cell

    DOEpatents

    McElroy, James F.

    1989-01-01

    The present invention discloses an improved fuel cell utilizing an ion transporting membrane having a catalytic anode and a catalytic cathode bonded to opposite sides of the membrane, a wet-proofed carbon sheet in contact with the cathode surface opposite that bonded to the membrane and a bipolar separator positioned in electrical contact with the carbon sheet and the anode of the adjacent fuel cell. Said bipolar separator and carbon sheet forming an oxidant flowpath, wherein the improvement comprises an electrically conductive screen between and in contact with the wet-proofed carbon sheet and the bipolar separator improving the product water removal system of the fuel cell.

  19. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell ...

  20. Fuel cell water transport

    DOEpatents

    Vanderborgh, Nicholas E.; Hedstrom, James C.

    1990-01-01

    The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

  1. Global Failure Criteria for Positive/Electrolyte/Negative Structure of Planar Solid Oxide Fuel Cell

    SciTech Connect

    Liu, Wenning N.; Sun, Xin; Khaleel, Mohammad A.; Qu, Jianmin

    2009-07-15

    Due to mismatch of the coefficients of thermal expansion of various layers in the positive/electrolyte/negative (PEN) structures of solid oxide fuel cells (SOFC), thermal stresses and warpage on the PEN are unavoidable due to the temperature changes from the stress-free sintering temperature to room temperature during the PEN manufacturing process. In the meantime, additional mechanical stresses will also be created by mechanical flattening during the stack assembly process. In order to ensure the structural integrity of the cell and stack of SOFC, it is necessary to develop failure criteria for SOFC PEN structures based on the initial flaws occurred during cell sintering and stack assembly. In this paper, the global relationship between the critical energy release rate and critical curvature and maximum displacement of the warped cells caused by the temperature changes as well as mechanical flattening process is established so that possible failure of SOFC PEN structures may be predicted deterministically by the measurement of the curvature and displacement of the warped cells.

  2. 1986 fuel cell seminar: Program and abstracts

    SciTech Connect

    1986-10-01

    Ninety nine brief papers are arranged under the following session headings: gas industry's 40 kw program, solid oxide fuel cell technology, phosphoric acid fuel cell technology, molten carbonate fuel cell technology, phosphoric acid fuel cell systems, power plants technology, fuel cell power plant designs, unconventional fuels, fuel cell application and economic assessments, and plans for commerical development. The papers are processed separately for the data base. (DLC)

  3. Fuel Cells at NASCAR

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation slides from the DOE Fuel Cell Technologies Office webinar "Fuel Cells at NASCAR" held on April 17, 2014.

  4. Fuel cell generator with fuel electrodes that control on-cell fuel reformation

    DOEpatents

    Ruka, Roswell J.; Basel, Richard A.; Zhang, Gong

    2011-10-25

    A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

  5. Co-flow anode/cathode supply heat exchanger for a solid-oxide fuel cell assembly

    SciTech Connect

    Haltiner, Jr., Karl J.; Kelly, Sean M.

    2005-11-22

    In a solid-oxide fuel cell assembly, a co-flow heat exchanger is provided in the flow paths of the reformate gas and the cathode air ahead of the fuel cell stack, the reformate gas being on one side of the exchanger and the cathode air being on the other. The reformate gas is at a substantially higher temperature than is desired in the stack, and the cathode gas is substantially cooler than desired. In the co-flow heat exchanger, the temperatures of the reformate and cathode streams converge to nearly the same temperature at the outlet of the exchanger. Preferably, the heat exchanger is formed within an integrated component manifold (ICM) for a solid-oxide fuel cell assembly.

  6. Advanced technologies in the fuel cell program

    SciTech Connect

    Smotrov, N.V.; Kleschev, Y.N.; Chukharev, V.F.

    1996-04-01

    This document consist of photos and abstracts describing the solid oxide fuel cell technology program at the VNIITF.

  7. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  8. Mixed oxide fuel development

    SciTech Connect

    Leggett, R.D.; Omberg, R.P.

    1987-05-08

    This paper describes the success of the ongoing mixed-oxide fuel development program in the United States aimed at qualifying an economical fuel system for liquid metal cooled reactors. This development has been the cornerstone of the US program for the past 20 years and has proceeded in a deliberate and highly disciplined fashion with high emphasis on fuel reliability and operational safety as major features of an economical fuel system. The program progresses from feature testing in EBR-II to qualifying full size components in FFTF under fully prototypic conditions to establish a basis for extending allowable lifetimes. The development program started with the one year (300 EFPD) core, which is the FFTF driver fuel, continued with the demonstration of a two year (600 EFPD) core and is presently evaluating a three year (900 EFPD) fuel system. All three of these systems, consistent with other LMR fuel programs around the world, use fuel pellets gas bonded to a cladding tube that is assembled into a bundle and fitted into a wrapper tube or duct for ease of insertion into a core. The materials of construction progressed from austenitic CW 316 SS to lower swelling austenitic D9 to non swelling ferritic/martensitic HT9. 6 figs., 2 tabs.

  9. Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

    SciTech Connect

    Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

    2012-01-01

    Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  10. A reduced temperature solid oxide fuel cell with three-dimensionally ordered macroporous cathode

    SciTech Connect

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-01-01

    Three-dimensionally ordered macroporous cathode was fabricated for a zirconia based micro-tubular solid oxide fuel cells (SOFCs). Three different cathodes (cathode A, no pore former; cathode B, with pore former (1.5 {micro}m in diameter); cathode C, with pore former (0.8 {micro}m in diameter)) were compared to investigate how the microstructure of it affected the cell performance at various operating temperatures. Micro-sized pores were well distributed within cathode B and C. The total porosity of cathode A is 35%, while it respectively reached 42 and 50% for cathodes B and C. At the same time, the specific surface area of them was 28.8 and 52.0% larger than that of the cathode A. As a result, the peak power density of the zirconia based cell, with cathode C, was 0.25 and 0.56 W cm{sup -2} at 550 and 600 C, while the respective value was just 0.11 and 0.30 W cm{sup -2} for the cell with cathode A. Thus, optimizing microstructure of cathode should be one of the best approaches for lowering the operating temperature for SOFCs.

  11. Fuel cell system configurations

    DOEpatents

    Kothmann, Richard E.; Cyphers, Joseph A.

    1981-01-01

    Fuel cell stack configurations having elongated polygonal cross-sectional shapes and gaskets at the peripheral faces to which flow manifolds are sealingly affixed. Process channels convey a fuel and an oxidant through longer channels, and a cooling fluid is conveyed through relatively shorter cooling passages. The polygonal structure preferably includes at least two right angles, and the faces of the stack are arranged in opposite parallel pairs.

  12. Exergy & Economic Analysis of Catalytic Coal Gasifiers Coupled with Solid Oxide Fuel Cells

    SciTech Connect

    Siefert, Nicholas; Litster, Shawn

    2012-01-01

    The National Energy Technology Laboratory (NETL) has undertaken a review of coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide. One way to achieve an overall system efficiency of greater than 60% is in a power plant in which a catalytic coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis and this is sent to a SOFC, with CO{sub 2} capture occurring either before or after the SOFC. Integration of a catalytic gasifier with a SOFC, as opposed to a conventional entrained flow gasifier, is improved due to (a) decreased exergy destruction inside a catalytic, steam-coal gasifier producing a high-methane content syngas, and (b) decreased exergy destruction in the SOFC due to the ability to operate at lower air stoichiometric flow ratios. For example, thermal management of the SOFC is greatly improved due to the steam-methane reforming in the anode of the fuel cell. This paper has two main goals. First, we converted the levelized cost of electricity (LCOE) estimates of various research groups into an average internal rate of return on investment (IRR) in order to make comparisons between their results, and to underscore the increased rate of return on investment for advanced integrated gasification fuel cell systems with carbon capture & sequestration (IGFC-CCS) compared with conventional integrated gasification combined cycle (IGCC-CCS) systems and pulverized coal combustion (PCC-CCS) systems. Using capital, labor, and fuel costs from previous researchers and using an average price of baseload electricity generation of $61.50 / MW-hr, we calculated inflation-adjusted IRR values of up to 13%/yr for catalytic gasification with pressurized fuel cell and carbon dioxide capture and storage (CCS), whereas we calculate an IRR of ∼4%/yr and ∼2%/yr for new, conventional IGCC-CCS and PCC-CCS, respectively. If

  13. Combined Theoretical and Experimental Analysis of Processes Determining Cathode Performance in Solid Oxide Fuel Cells

    SciTech Connect

    Kukla, Maija M.; Kotomin, Eugene Alexej; Merkle, R.; Mastrikov, Yuri; Maier, J.

    2013-02-11

    Solid oxide fuel cells (SOFC) are under intensive investigation since the 1980s as these devices open the way for ecologically clean direct conversion of the chemical energy into electricity, avoiding the efficiency limitation by Carnots cycle for thermochemical conversion. However, the practical development of SOFC faces a number of unresolved fundamental problems, in particular concerning the kinetics of the electrode reactions, especially oxygen reduction reaction. We review recent experimental and theoretical achievements in the current understanding of the cathode performance by exploring and comparing mostly three materials: (La,Sr)MnO3 (LSM), (La,Sr)(Co,Fe)O3 (LSCF) and (Ba,Sr)(Co,Fe)O3 (BSCF). Special attention is paid to a critical evaluation of advantages and disadvantages of BSCF, which shows the best cathode kinetics known so far for oxides. We demonstrate that it is the combined experimental and theoretical analysis of all major elementary steps of the oxygen reduction reaction which allows us to predict the rate determining steps for a given material under specific operational conditions and thus control and improve SOFC performance.

  14. Solid oxide fuel cell having monolithic cross flow core and manifolding

    DOEpatents

    Poeppel, R.B.; Dusek, J.T.

    1983-10-12

    This invention discloses a monolithic core construction having the flow passageways for the fuel and for the oxidant gases extended transverse to one another, whereby full face core manifolding can be achieved for these gases and their reaction products. The core construction provides that only anode material surround each fuel passageway and only cathode material surround each oxidant passageway, each anode and each cathode further sandwiching at spaced opposing sides electrolyte and interconnect materials to define electrolyte and interconnect walls. Webs of the cathode and anode material hold the electrolyte and interconnect walls spaced apart to define the flow passages. The composite anode and cathode wall structures are further alternately stacked on one another (with the separating electrolyte or interconnect material typically being a single common layer) whereby the fuel passageways and the oxidant passageways are disposed transverse to one another.

  15. Solid oxide fuel cell having monolithic cross flow core and manifolding

    DOEpatents

    Poeppel, Roger B.; Dusek, Joseph T.

    1984-01-01

    This invention discloses a monolithic core construction having the flow passageways for the fuel and for the oxidant gases extended transverse to one another, whereby full face core manifolding can be achieved for these gases and their reaction products. The core construction provides that only anode material surround each fuel passageway and only cathode material surround each oxidant passageway, each anode and each cathode further sandwiching at spaced opposing sides electrolyte and interconnect materials to define electrolyte and interconnect walls. Webs of the cathode and anode material hold the electrolyte and interconnect walls spaced apart to define the flow passages. The composite anode and cathode wall structures are further alternately stacked on one another (with the separating electrolyte or interconnect material typically being a single common layer) whereby the fuel passageway and the oxidant passageways are disposed transverse to one another.

  16. Low circumferential voltage gradient self supporting electrode for solid oxide fuel cells

    DOEpatents

    Reichner, Philip

    1989-01-01

    The porous, self-supporting, elongated electrode is made, having at least two chambers through its axial length, the chambers separated by an electronically conductive member. This electrode can be an air electrode of a fuel cell, having a superimposed solid electrolyte and fuel electrode.

  17. Microbial fuel cell treatment of fuel process wastewater (Patent) |

    Office of Scientific and Technical Information (OSTI)

    DOEPatents Microbial fuel cell treatment of fuel process wastewater Title: Microbial fuel cell treatment of fuel process wastewater The present invention is directed to a method for cleansing fuel processing effluent containing carbonaceous compounds and inorganic salts, the method comprising contacting the fuel processing effluent with an anode of a microbial fuel ell, the anode containing microbes thereon which oxidatively degrade one or more of the carbonaceous compounds while producing

  18. Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation...

    Energy.gov [DOE] (indexed site)

    Presented at the DOE Fuel Cell Pre-Solicitation Workshop held January 23-24, 2008 in Golden, Colorado. fuelcellpre-solicitationwkshopjan08delphi.pdf (1.7 MB) More Documents & ...

  19. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Technologies Overview Flow Cell Workshop Washington, DC Dr. Sunita Satyapal & Dr. Dimitrios Papageorgopoulos U.S. Department of Energy Fuel Cell Technologies Program 37...

  20. Catalysts compositions for use in fuel cells

    SciTech Connect

    Chuang, Steven S.C.

    2015-12-01

    The present invention generally relates to the generation of electrical energy from a solid-state fuel. In one embodiment, the present invention relates to a solid-oxide fuel cell for generating electrical energy from a carbon-based fuel, and to catalysts for use in a solid-oxide fuel cell.

  1. Catalysts compositions for use in fuel cells

    SciTech Connect

    Chuang, Steven S.C.

    2015-12-02

    The present invention generally relates to the generation of electrical energy from a solid-state fuel. In one embodiment, the present invention relates to a solid-oxide fuel cell for generating electrical energy from a carbon-based fuel, and to catalysts for use in a solid-oxide fuel cell.

  2. Fuel Cells Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel cells are the most energy efficient devices for extracting power from fuels. Capable of running on a variety of fuels, including hydrogen, natural gas, and biogas, fuel cells ...

  3. NREL: Hydrogen and Fuel Cells Research - Stationary Fuel Cell Systems

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Analysis Stationary Fuel Cell Systems Analysis NREL's technology validation team analyzes the performance of stationary fuel cell systems operating in real-world conditions and reports on the technology's performance, progress, and challenges. This analysis includes multiple fuel cell types-proton exchange membrane, solid oxide, phosphoric acid, and molten carbonate-with system sizes ranging from 5 kW to 2.8 MW. Overview Composite Data Products Publications Learn More Contacts Photo of

  4. Innovative Self-Healing Seals for Solid Oxide Fuel Cells (SOFC)

    SciTech Connect

    Raj Singh

    2012-06-30

    Solid oxide fuel cell (SOFC) technology is critical to several national initiatives. Solid State Energy Conversion Alliance (SECA) addresses the technology needs through its comprehensive programs on SOFC. A reliable and cost-effective seal that works at high temperatures is essential to the long-term performance of the SOFC for 40,000 hours at 800°C. Consequently, seals remain an area of highest priority for the SECA program and its industry teams. An innovative concept based on self-healing glasses was advanced and successfully demonstrated through seal tests for 3000 hours and 300 thermal cycles to minimize internal stresses under both steady state and thermal transients for making reliable seals for the SECA program. The self-healing concept requires glasses with low viscosity at the SOFC operating temperature of 800°C but this requirement may lead to excessive flow of the glass in areas forming the seal. To address this challenge, a modification to glass properties by addition of particulate fillers is pursued in the project. The underlying idea is that a non-reactive ceramic particulate filler is expected to form glass-ceramic composite and increase the seal viscosity thereby increasing the creep resistance of the glass-composite seals under load. The objectives of the program are to select appropriate filler materials for making glass-composite, fabricate glass-composites, measure thermal expansion behaviors, and determine stability of the glass-composites in air and fuel environments of a SOFC. Self-healing glass-YSZ composites are further developed and tested over a longer time periods under conditions typical of the SOFCs to validate the long-term stability up to 2000 hours. The new concepts of glass-composite seals, developed and nurtured in this program, are expected to be cost-effective as these are based on conventional processing approaches and use of the inexpensive materials.

  5. Multivariable Robust Control of a Simulated Hybrid Solid Oxide Fuel Cell Gas Turbine Plant

    SciTech Connect

    Tsai, Alex; Banta, Larry; Tucker, D.A.; Gemmen, R.S.

    2008-06-01

    This paper presents a systematic approach to the multivariable robust control of a hybrid fuel cell gas turbine plant. The hybrid configuration under investigation comprises a physical simulation of a 300kW fuel cell coupled to a 120kW auxiliary power unit single spool gas turbine. The facility provides for the testing and simulation of different fuel cell models that in turn help identify the key issues encountered in the transient operation of such systems. An empirical model of the facility consisting of a simulated fuel cell cathode volume and balance of plant components is derived via frequency response data. Through the modulation of various airflow bypass valves within the hybrid configuration, Bode plots are used to derive key input/output interactions in Transfer Function format. A multivariate system is then built from individual transfer functions, creating a matrix that serves as the nominal plant in an H-Infinity robust control algorithm. The controller’s main objective is to track and maintain hybrid operational constraints in the fuel cell’s cathode airflow, and the turbo machinery states of temperature and speed, under transient disturbances. This algorithm is then tested on a Simulink/MatLab platform for various perturbations of load and fuel cell heat effluence.

  6. Electrocatalytic Activity of Transition Metal Oxide-Carbon Composites for Oxygen Reduction in Alkaline Batteries and Fuel Cells

    SciTech Connect

    Malkhandi, S; Trinh, P; Manohar, AK; Jayachandrababu, KC; Kindler, A; Prakash, GKS; Narayanan, SR

    2013-06-07

    Conductive transition metal oxides (perovskites, spinels and pyrochlores) are attractive as catalysts for the air electrode in alkaline rechargeable metal-air batteries and fuel cells. We have found that conductive carbon materials when added to transition metal oxides such as calcium-doped lanthanum cobalt oxide, nickel cobalt oxide and calcium-doped lanthanum manganese cobalt oxide increase the electrocatalytic activity of the oxide for oxygen reduction by a factor of five to ten. We have studied rotating ring-disk electrodes coated with (a) various mass ratios of carbon and transition metal oxide, (b) different types of carbon additives and (c) different types of transition metal oxides. Our experiments and analysis establish that in such composite catalysts, carbon is the primary electro- catalyst for the two-electron electro-reduction of oxygen to hydroperoxide while the transition metal oxide decomposes the hydroperoxide to generate additional oxygen that enhances the observed current resulting in an apparent four-electron process. These findings are significant in that they change the way we interpret previous reports in the scientific literature on the electrocatalytic activity of various transition metal oxide- carbon composites for oxygen reduction, especially where carbon is assumed to be an additive that just enhances the electronic conductivity of the oxide catalyst. (C) 2013 The Electrochemical Society. All rights reserved.

  7. Solid oxide fuel cell processing using plasma arc spray deposition techniques. Final report

    SciTech Connect

    Ray, E.R.; Spengler, C.J.; Herman, H.

    1991-07-01

    The Westinghouse Electric Corporation, in conjunction with the Thermal Spray Laboratory of the State University of New York, Stony Brook, investigated the fabrication of a gas-tight interconnect layer on a tubular solid oxide fuel cell with plasma arc spray deposition. The principal objective was to determine the process variables for the plasma spray deposition of an interconnect with adequate electrical conductivity and other desired properties. Plasma arc spray deposition is a process where the coating material in powder form is heated to or above its melting temperature, while being accelerated by a carrier gas stream through a high power electric arc. The molten powder particles are directed at the substrate, and on impact, form a coating consisting of many layers of overlapping, thin, lenticular particles or splats. The variables investigated were gun power, spray distance, powder feed rate, plasma gas flow rates, number of gun passes, powder size distribution, injection angle of powder into the plasma plume, vacuum or atmospheric plasma spraying, and substrate heating. Typically, coatings produced by both systems showed bands of lanthanum rich material and cracking with the coating. Preheating the substrate reduced but did not eliminate internal coating cracking. A uniformly thick, dense, adherent interconnect of the desired chemistry was finally achieved with sufficient gas- tightness to allow fabrication of cells and samples for measurement of physical and electrical properties. A cell was tested successfully at 1000{degree}C for over 1,000 hours demonstrating the mechanical, electrical, and chemical stability of a plasma-arc sprayed interconnect layer.

  8. Solid oxide fuel cell processing using plasma arc spray deposition techniques

    SciTech Connect

    Ray, E.R.; Spengler, C.J.; Herman, H.

    1991-07-01

    The Westinghouse Electric Corporation, in conjunction with the Thermal Spray Laboratory of the State University of New York, Stony Brook, investigated the fabrication of a gas-tight interconnect layer on a tubular solid oxide fuel cell with plasma arc spray deposition. The principal objective was to determine the process variables for the plasma spray deposition of an interconnect with adequate electrical conductivity and other desired properties. Plasma arc spray deposition is a process where the coating material in powder form is heated to or above its melting temperature, while being accelerated by a carrier gas stream through a high power electric arc. The molten powder particles are directed at the substrate, and on impact, form a coating consisting of many layers of overlapping, thin, lenticular particles or splats. The variables investigated were gun power, spray distance, powder feed rate, plasma gas flow rates, number of gun passes, powder size distribution, injection angle of powder into the plasma plume, vacuum or atmospheric plasma spraying, and substrate heating. Typically, coatings produced by both systems showed bands of lanthanum rich material and cracking with the coating. Preheating the substrate reduced but did not eliminate internal coating cracking. A uniformly thick, dense, adherent interconnect of the desired chemistry was finally achieved with sufficient gas- tightness to allow fabrication of cells and samples for measurement of physical and electrical properties. A cell was tested successfully at 1000{degree}C for over 1,000 hours demonstrating the mechanical, electrical, and chemical stability of a plasma-arc sprayed interconnect layer.

  9. Exploration of alloy 441 chemistry for solid oxide fuel cell interconnect application

    SciTech Connect

    Paul D. Jablonski; Christopher J. Cowen; John S. Sears

    2010-02-01

    Alloy 441 stainless steel (UNS S 44100) is being considered for application as an SOFC interconnect material. There are several advantages to the selection of this alloy over other iron-based or nickel-based alloys: first and foremost alloy 441ss is a production alloy which is both low in cost and readily available. Second, the coefficient of thermal expansion (CTE) more closely matches the CTE of the adjoining ceramic components of the fuel cell. Third, this alloy forms the Laves phase at typical SOFC operating temperatures of 600800 C. It is thought that the Laves phase preferentially consumes the Si present in the alloy microstructure. As a result it has been postulated that the long-term area specific resistance (ASR) performance degradation often seen with other ferritic stainless steels, which is associated with the formation of electrically resistive Si-rich oxide subscales, may be avoidable with alloy 441ss. In this paper we explore the physical metallurgy of alloy 441, combining computational thermodynamics with experimental verification, and discuss the results with regards to Laves phase formation under SOFC operating conditions. We show that the incorporation of the Laves phase into the microstructure cannot in itself remove sufficient Si from the ferritic matrix in order to completely avoid the formation of Si-rich oxide subscales. However, the thickness, morphology, and continuity of the Si-rich subscale that forms in this alloy is modified in comparison to non-Laves forming ferritic stainless steel alloys and therefore may not be as detrimental to long-term SOFC performance.

  10. Exploration of alloy 441 chemistry for solid oxide fuel cell interconnect application

    SciTech Connect

    Jablonski PD, Cowen CJ, Sears JS

    2010-02-01

    Alloy 441 stainless steel (UNS S 44100) is being considered for application as an SOFC interconnect material. There are several advantages to the selection of this alloy over other iron-based or nickel-based alloys: first and foremost alloy 441ss is a production alloy which is both low in cost and readily available. Second, the coefficient of thermal expansion (CTE) more closely matches the CTE of the adjoining ceramic components of the fuel cell. Third, this alloy forms the Laves phase at typical SOFC operating temperatures of 600800 ?C. It is thought that the Laves phase preferentially consumes the Si present in the alloy microstructure. As a result it has been postulated that the long-term area specific resistance (ASR) performance degradation often seen with other ferritic stainless steels, which is associated with the formation of electrically resistive Si-rich oxide subscales, may be avoidable with alloy 441ss. In this paper we explore the physical metallurgy of alloy 441, combining computational thermodynamics with experimental verification, and discuss the results with regards to Laves phase formation under SOFC operating conditions. We show that the incorporation of the Laves phase into the microstructure cannot in itself remove sufficient Si from the ferritic matrix in order to completely avoid the formation of Si-rich oxide subscales. However, the thickness, morphology, and continuity of the Si-rich subscale that forms in this alloy is modified in comparison to non-Laves forming ferritic stainless steel alloys and therefore may not be as detrimental to long-term SOFC performance

  11. DOE 2010 Fuel Cell Pre-Solicitation Workshop Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    - Chris Ainscough, Nuvera Fuel Cells 3:15 Fuel Processor RD&D Needs - Pinakin Patel, FuelCell Energy 3:45 Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration - ...

  12. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOEpatents

    Ruka, R.J.; Kuo, L.; Li, B.

    1999-06-29

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO[sub 3]. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La[sub w]Ca[sub x]Ln[sub y]Ce[sub z]MnO[sub 3], wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics. 10 figs.

  13. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOEpatents

    Ruka, Roswell J.; Kuo, Lewis; Li, Baozhen

    1999-01-01

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La.sub.w Ca.sub.x Ln.sub.y Ce.sub.z MnO.sub.3, wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics.

  14. Novel Electrode Materials for Low-Temperature Solid-Oxide Fuel Cells

    SciTech Connect

    Shaowu Zha; Meilin Liu

    2005-03-23

    Composites electrodes consisting of silver and bismuth vanadates exhibit remarkable catalytic activity for oxygen reduction at 500-550 C and greatly reduce the cathode-electrolyte (doped ceria) resistances of low temperature SOFCs, down to about 0.53 {omega}cm{sup 2} at 500 C and 0.21 {omega}cm{sup 2} at 550 C. The observed power densities of 231, 332, and 443 mWcm-2 at 500, 525 and 550 C, respectively, make it possible to operate SOFCs at temperatures about 500 C. Fuel cell performance depends strongly on the anode microstructure, which is determined by the anode compositions and fabrication conditions. Four types of anodes with two kinds of NiO and GDC powders were investigated. By carefully adjusting the anode microstructure, the GDC electrolyte/anode interfacial polarization resistances reduced dramatically. The interfacial resistance at 600 C decreased from 1.61 {omega} cm{sup 2} for the anodes prepared using commercially available powders to 0.06 {omega} cm{sup 2} for those prepared using powders derived from a glycine-nitrate process. Although steam reforming or partial oxidation is effective in avoiding carbon deposition of hydrocarbon fuels, it increases the operating cost and reduces the energy efficiency. Anode-supported SOFCs with an electrolyte of 20 {micro}m-thick Gd-doped ceria (GDC) were fabricated by co-pressing. A catalyst (1 %wt Pt dispersed on porous Gd-doped ceria) for pre-reforming of propane was developed with relatively low steam to carbon (S/C) ratio ({approx}0.5), coupled with direct utilization of the reformate in low-temperature SOFCs. Propane was converted to smaller molecules during pre-reforming, including H{sub 2}, CH{sub 4}, CO, and CO{sub 2}. A peak power density of 247 mW/cm{sup 2} was observed when pre-reformed propane was directly fed to an SOFC operated at 600 C. No carbon deposition was observed in the fuel cell for a continuous operation of 10 hours at 600 C. The ability of producing vastly different microstructures and

  15. Analysis of Actual Operating Conditions of an Off-grid Solid Oxide Fuel Cell

    SciTech Connect

    Dennis Witmer; Thomas Johnson; Jack Schmid

    2008-12-31

    Fuel cells have been proposed as ideal replacements for other technologies in remote locations such as Rural Alaska. A number of suppliers have developed systems that might be applicable in these locations, but there are several requirements that must be met before they can be deployed: they must be able to operate on portable fuels, and be able to operate with little operator assistance for long periods of time. This project was intended to demonstrate the operation of a 5 kW fuel cell on propane at a remote site (defined as one without access to grid power, internet, or cell phone, but on the road system). A fuel cell was purchased by the National Park Service for installation in their newly constructed visitor center at Exit Glacier in the Kenai Fjords National Park. The DOE participation in this project as initially scoped was for independent verification of the operation of this demonstration. This project met with mixed success. The fuel cell has operated over 6 seasons at the facility with varying degrees of success, with one very good run of about 1049 hours late in the summer of 2006, but in general the operation has been below expectations. There have been numerous stack failures, the efficiency of electrical generation has been lower than expected, and the field support effort required has been far higher than expected. Based on the results to date, it appears that this technology has not developed to the point where demonstrations in off road sites are justified.

  16. Variable area fuel cell process channels

    DOEpatents

    Kothmann, Richard E.

    1981-01-01

    A fuel cell arrangement having a non-uniform distribution of fuel and oxidant flow paths, on opposite sides of an electrolyte matrix, sized and positioned to provide approximately uniform fuel and oxidant utilization rates, and cell conditions, across the entire cell.

  17. Ohio Fuel Cell Initiative

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Top 5 Fuel Cell States: Why Local Policies Mean Green Growth Jun 21 st , 2011 2 * Ohio Fuel Cell Initiative * Ohio Fuel Cell Coalition * Accomplishments * Ohio Successes Discussion Areas 3 Ohio's Fuel Cell Initiative * Announced on 5/9/02 * Part of Ohio Third Frontier Initiative * $85 million investment to date * Core focus areas: 1) Expand the state's research capabilities; 2) Participate in demonstration projects; and 3) Expand the fuel cell industry in Ohio 4 OHIO'S FUEL CELL INITIATIVE

  18. Bio-inspired surfactant assisted nano-catalyst impregnation of Solid-Oxide Fuel Cell (SOFC) electrodes

    SciTech Connect

    Ozmen, Ozcan; Zondlo, John W.; Lee, Shiwoo; Sabolsky, Edward M.

    2015-11-02

    A bio-inspired surfactant was utilized to assist in the efficient impregnation of a nano-CeO₂ catalyst throughout both porous Solid Oxide Fuel Cells (SOFC’s) electrodes simultaneously. The process included the initial modification of electrode pore walls with a polydopamine film. The cell was then submersed into a cerium salt solution. The amount of nano-CeO₂ deposited per impregnation step increased by 3.5 times by utilizing this two-step protocol in comparison to a conventional drip impregnation method. The impregnated cells exhibited a 20% higher power density than a baseline cell without the nano-catalyst at 750°C (using humid H₂ fuel).

  19. Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by Sunita Satyapal at the 2010 Fuel ...

  20. Fuel Cell Case Study

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Building & Energy Initiatives * Solar 20 new; 30 total, ... * Alternative Energy-Fuel Cells, waste to electricity, ... History of Fuel Cell Contemplation * Back in 2006, UTC Power ...

  1. Hydrogen Fuel Cell Demonstration ...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Hydrogen fuel cells have a long track record of supplying efficient, emissions-free power ... power, by demonstrating a hydrogen fuel cell deployment in a commercial port setting. ...

  2. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    States Energy Advisory Board (STEAB) Washington, DC Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 3142012 2 | Fuel Cell ...

  3. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Technologies Overview States Energy Advisory Board (STEAB) Washington, DC Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 3...

  4. Fuel Cell Development Status

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    60% of Sales are in building technologies Transportation Stationary Fuel Cells Space & Defense * Fuel cell technology leader since 1958 * 550 employees * 768+ Active U.S. ...

  5. A Total Cost of Ownership Model for Solid Oxide Fuel Cells in Combined Heat and Power and Power-Only Applications

    Energy.gov [DOE]

    This report prepared by Lawrence Berkeley National Laboratory describes a total cost of ownership model for emerging applications in stationary fuel cell systems. Solid oxide fuel cell systems (SOFC) for use in combined heat and power (CHP) and power-only applications from 1 to 250 kilowatts-electric are considered.

  6. California Fuel Cell Partnership: Alternative Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Partnership - Alternative Fuels Research TNS Automotive Chris White Communications Director cwhite@cafcp.org 2 TNS Automotive for California Fuel Cell Partnership ...

  7. Fuel cell with internal flow control

    DOEpatents

    Haltiner, Jr., Karl J.; Venkiteswaran, Arun

    2012-06-12

    A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

  8. Project proposals on the creation of Russian-American joint enterprise for investigation, development and manufacture of power plants on the basis of solid oxide fuel cells

    SciTech Connect

    Smotrov, N.V.; Kleschev, Yu.N.

    1996-04-01

    This paper describes a proposal for a joint Russian-American enterprise for performing scientific investigations, development, and manufacture of fuel cell power plants on the basis of the solid oxide fuel cell. RASOFCo. Russian-American Solid Oxide Fuel Cells Company. RASOFCo will provide the series output of the electrochemical generator (ECG) of 1kW power, then of 5kW and 10kW as well as the development and the output of 10kW power plant with the subsequent output of a power plant of greater power. An ECG based on solid oxide fuel cells uses methane as a fuel. Predicted technical characteristics, market analysis, assessment of potential demands for power plants of low power for Tyumentransgas, participants of the joint enterprise and their founding contributions, strategy for manufacture and financing, and management of RASOFCo are discussed.

  9. Fuel Cell Handbook, Fifth Edition

    SciTech Connect

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed

  10. Multivariable Robust Control of a Simulated Hybrid Solid Oxide Fuel Cell Gas Turbine Plant

    SciTech Connect

    Tsai, Alex; Banta, Larry; Tucker, David; Gemmen, Randall

    2010-08-01

    This work presents a systematic approach to the multivariable robust control of a hybrid fuel cell gas turbine plant. The hybrid configuration under investigation built by the National Energy Technology Laboratory comprises a physical simulation of a 300kW fuel cell coupled to a 120kW auxiliary power unit single spool gas turbine. The public facility provides for the testing and simulation of different fuel cell models that in turn help identify the key difficulties encountered in the transient operation of such systems. An empirical model of the built facility comprising a simulated fuel cell cathode volume and balance of plant components is derived via frequency response data. Through the modulation of various airflow bypass valves within the hybrid configuration, Bode plots are used to derive key input/output interactions in transfer function format. A multivariate system is then built from individual transfer functions, creating a matrix that serves as the nominal plant in an H{sub {infinity}} robust control algorithm. The controller’s main objective is to track and maintain hybrid operational constraints in the fuel cell’s cathode airflow, and the turbo machinery states of temperature and speed, under transient disturbances. This algorithm is then tested on a Simulink/MatLab platform for various perturbations of load and fuel cell heat effluence. As a complementary tool to the aforementioned empirical plant, a nonlinear analytical model faithful to the existing process and instrumentation arrangement is evaluated and designed in the Simulink environment. This parallel task intends to serve as a building block to scalable hybrid configurations that might require a more detailed nonlinear representation for a wide variety of controller schemes and hardware implementations.

  11. Effect of pre-oxidation and environmental aging on the seal strength of a novel high-temperature solid oxide fuel cell (SOFC) sealing glass with metallic interconnect

    SciTech Connect

    Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

    2008-09-15

    A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two ferritic stainless steel coupons for strength evaluation. The steel coupons were pre-oxidized at elevated temperatures to promote thick oxide layers to simulate long-term exposure conditions. In addition, seals to as-received metal coupons were also tested after aging in oxidizing or reducing environments to simulate the actual SOFC environment. Room temperature tensile testing showed strength degradation when using pre-oxidized coupons, and more extensive degradation after aging in air. Fracture surface and microstructural analysis confirmed that the cause of degradation was formation of SrCrO4 at the outer sealing edges exposed to air.

  12. Program of scientific investigations and development of solid-oxide fuel cells (SOFC) in VNIITF. Proposals on scientific and technical collaboration and SOFC commercialization

    SciTech Connect

    Kleschev, Yu.N.; Chukharev, V.F.

    1996-04-01

    This paper describes proposals on scientific and technical collaborations pertaining to solid oxide fuel cell commercialization. Topics included for discussion are: materials research and manufacture; market estimation and cost; directions of collaboration; and project of proposals on joint enterprise creation.

  13. Sintering behavior of lanthanide-containing glass-ceramic sealants for solid oxide fuel cells

    SciTech Connect

    Goel, Ashutosh; Reddy, Allu Amarnath; Pascual, Maria J.; Gremillard, Laurent; Malchere, Annie; Ferreira, Jose M.

    2012-05-01

    This article reports on the influence of different lanthanides (La, Nd, Gd and Yb) on sintering behavior of alkaline-earth aluminosilicate glass-ceramics sealants for their application in solid oxide fuel cells (SOFC). All the glasses have been prepared by melt-quench technique. The in situ follow up of sintering behavior of glass powders has been done by high temperature - environmental scanning electron microscope (HT-ESEM) and hot-stage microscope (HSM) while the crystalline phase evolution and assemblage has been analyzed by x-ray diffraction (XRD) and scanning electron microscopy (SEM). All the glass compositions exhibit a glass-in-glass phase separation followed by two stage sintering resulting in well sintered glass powder compacts after heat treatment at 850 C for 1 h. Diopside (CaMgSi{sub 2}O{sub 6}) based phases constituted the major crystalline part in glass-ceramics followed by some minor phases. The increase in lanthanide content in glasses suppressed their tendency towards devitrification, thus, resulting in glass-ceramics with high amount of residual glassy phase (50-96 wt.%) which is expected to facilitate their self-healing behavior during SOFC operation. The electrical conductivity of the investigated glass-ceramics varied between (1.19 and 7.33) x 10{sup -7} S cm{sup -1} (750-800 C), and depended on the ionic field strength of lanthanide cations. Further experimentation with respect to the long term thermal and chemical stability of residual glassy phase under SOFC operation conditions along with high temperature viscosity measurements will be required in order to elucidate the potential of these glass-ceramics as self-healing sealants.

  14. Development of planar geometry solid oxide fuel cell technology. Phase II-C. Final report, May 1991-April 1992

    SciTech Connect

    Khandkar, A.; Elangovan, S.; Hartvigsen, J.; Prouse, D.; Milliken, C.

    1992-08-01

    The report describes the progress made in planar solid oxide fuel cell stack technology. The work builds on the technology developed in the earlier phases where the feasibility of low cost ceramics fabrication technology to fabricate stacks was established. The effort focused on three technology areas: qualification of the advanced interconnection material in stack tests, stack performance diagnostics, and manifold design and seal development. Long term testing of single cells and stacks were conducted. Additionally, progress was made in electrode optimization. This resulted in demonstration of high fuel utilization (80%) in single cells. A rigorous quality improvement approach was undertaken in all aspects of Solid Oxide Fuel Cell (SOFC) development in recognition of the need to scale up technology for the eventual commercial manufacture of SOFC stacks and systems. Manufacturing tolerances were studied and, via a statistical design of experiments approach, methods defined to improve tolerances and process yields. Finally, as a result of the stack and module engineering design activity, advancements have been made to seal and module manifold development. Seal tests conducted on new manifold concepts have shown a 100 fold decrease in reactant gas leak rates at temperature, pointing to the possibility of developing high efficiency planar SOFC stacks.

  15. 1990 fuel cell seminar: Program and abstracts

    SciTech Connect

    Not Available

    1990-12-31

    This volume contains author prepared short resumes of the presentations at the 1990 Fuel Cell Seminar held November 25-28, 1990 in Phoenix, Arizona. Contained herein are 134 short descriptions organized into topic areas entitled An Environmental Overview, Transportation Applications, Technology Advancements for Molten Carbonate Fuel Cells, Technology Advancements for Solid Fuel Cells, Component Technologies and Systems Analysis, Stationary Power Applications, Marine and Space Applications, Technology Advancements for Acid Type Fuel Cells, and Technology Advancement for Solid Oxide Fuel Cells.

  16. Compact fuel cell

    DOEpatents

    Jacobson, Craig; DeJonghe, Lutgard C.; Lu, Chun

    2010-10-19

    A novel electrochemical cell which may be a solid oxide fuel cell (SOFC) is disclosed where the cathodes (144, 140) may be exposed to the air and open to the ambient atmosphere without further housing. Current collector (145) extends through a first cathode on one side of a unit and over the unit through the cathode on the other side of the unit and is in electrical contact via lead (146) with housing unit (122 and 124). Electrical insulator (170) prevents electrical contact between two units. Fuel inlet manifold (134) allows fuel to communicate with internal space (138) between the anodes (154 and 156). Electrically insulating members (164 and 166) prevent the current collector from being in electrical contact with the anode.

  17. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell Technologies Program describing hydrogen fuel cell technology. Fuel Cells Fact Sheet (545.14 KB) More Documents & Publications Comparison of Fuel Cell Technologies: Fact Sheet Fuel Cells Fact Sheet 2011 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies

  18. Optimized cell configurations for stable LSCF-based solid oxide fuel cells

    DOEpatents

    Kim, Jin Yong; Sprenkle, Vincent L.; Canfield, Nathan L.; Meinhardt, Kerry D.; WA, Chick, Lawrence A.

    2012-05-22

    Lanthanum strontium cobalt iron oxides (La(1-x)SrxCoyFe1-yO3-f; (LSCF) have excellent power density (>500 mW/cm2 at 750.degree. C.). When covered with a metallization layer, LSCF cathodes have demonstrated increased durability and stability. Other modifications, such as the thickening of the cathode, the preparation of the device by utilizing a firing temperature in a designated range, and the use of a pore former paste having designated characteristics and combinations of these features provide a device with enhanced capabilities.

  19. Effects of surface chemistry and microstructure of electrolyte on oxygen reduction kinetics of solid oxide fuel cells

    SciTech Connect

    Park, Joong Sun; An, Jihwan; Lee, Min Hwan; Prinz, Friedrich B.; Lee, Wonyoung

    2015-07-10

    In this study, we report systematic investigation of the surface properties of yttria-stabilized zirconia (YSZ) electrolytes with the control of the grain boundary (GB) density at the surface, and its effects on electrochemical activities. The GB density of thin surface layers deposited on single crystal YSZ substrates is controlled by changing the annealing temperature (750-1450 °C). Higher oxygen reduction reactions (ORR) kinetics is observed in samples annealed at lower temperatures. The higher ORR activity is ascribed to the higher GB density at the YSZ surface where 'mobile' oxide ion vacancies are more populated. Meanwhile, oxide ion vacancies concurrently created with yttrium segregation at the surface at the higher annealing temperature are considered inactive to oxygen incorporation reactions. Our results provide additional insight into the interplay between the surface chemistry, microstructures, and electrochemical activity. They potentially provide important guidelines for engineering the electrolyte electrode interfaces of solid oxide fuel cells for higher electrochemical performance.

  20. Fuel cell system for transportation applications

    DOEpatents

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1993-09-28

    A propulsion system is described for a vehicle having pairs of front and rear wheels and a fuel tank. An electrically driven motor having an output shaft operatively connected to at least one of said pair of wheels is connected to a fuel cell having a positive electrode and a negative electrode separated by an electrolyte for producing dc power to operate the motor. A partial oxidation reformer is connected both to the fuel tank and to the fuel cell and receives hydrogen-containing fuel from the fuel tank and uses water and air for partially oxidizing and reforming the fuel in the presence of an oxidizing catalyst and a reforming catalyst to produce a hydrogen-containing gas. The hydrogen-containing gas is sent from the partial oxidation reformer to the fuel cell negative electrode while air is transported to the fuel cell positive electrode to produce dc power for operating the electric motor. 3 figures.

  1. Fuel cell system for transportation applications

    DOEpatents

    Kumar, Romesh; Ahmed, Shabbir; Krumpelt, Michael; Myles, Kevin M.

    1993-01-01

    A propulsion system for a vehicle having pairs of front and rear wheels and a fuel tank. An electrically driven motor having an output shaft operatively connected to at least one of said pair of wheels is connected to a fuel cell having a positive electrode and a negative electrode separated by an electrolyte for producing dc power to operate the motor. A partial oxidation reformer is connected both to the fuel tank and to the fuel cell receives hydrogen-containing fuel from the fuel tank and water and air and for partially oxidizing and reforming the fuel with water and air in the presence of an oxidizing catalyst and a reforming catalyst to produce a hydrogen-containing gas. The hydrogen-containing gas is sent from the partial oxidation reformer to the fuel cell negative electrode while air is transported to the fuel cell positive electrode to produce dc power for operating the electric motor.

  2. Fuel Cell 101

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Don Hoffman Ship Systems & Engineering Research Division March 2011 Distribution Statement A: Approved for public release; distribution is unlimited. Fuel Cell Operation * A Fuel ...

  3. Manufacturing Cost Analysis of 100 and 250 kW Fuel Cell Systems...

    Energy.gov [DOE] (indexed site)

    Both polymer electrolyte membrane (PEM) fuel cell stacks and solid oxide fuel cell (SOFC) ... kW Direct Hydrogen Polymer Electrolyte Membrane (PEM) Fuel Cell for Material Handling ...

  4. Fuel cell membrane humidification

    DOEpatents

    Wilson, Mahlon S.

    1999-01-01

    A polymer electrolyte membrane fuel cell assembly has an anode side and a cathode side separated by the membrane and generating electrical current by electrochemical reactions between a fuel gas and an oxidant. The anode side comprises a hydrophobic gas diffusion backing contacting one side of the membrane and having hydrophilic areas therein for providing liquid water directly to the one side of the membrane through the hydrophilic areas of the gas diffusion backing. In a preferred embodiment, the hydrophilic areas of the gas diffusion backing are formed by sewing a hydrophilic thread through the backing. Liquid water is distributed over the gas diffusion backing in distribution channels that are separate from the fuel distribution channels.

  5. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Y.; Meng, W.J.; Swathirajan, S.; Harris, S.J.; Doll, G.L.

    1997-04-29

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell`s operating environment. Stainless steels rich in Cr, Ni, and Mo are particularly effective protective interlayers. 6 figs.

  6. High-efficiency intermediate temperature solid oxide electrolyzer cells for the conversion of carbon dioxide to fuels

    SciTech Connect

    Yan , Jingbo; Chen, Hao; Dogdibegovic, Emir; Stevenson, Jeffry W.; Cheng, Mojie; Zhou, Xiao-Dong

    2014-04-15

    Electrochemical reduction of carbon dioxide in the intermediate temperature region was investigated by utilizing a reversible solid oxide electrolysis cell (SOEC). The current potential (i-V) curve exhibited a nonlinear characteristic at low current density. Differentiation of i-V curves revealed that the cell area specific resistance (ASR) was current-dependent and had its maximum in electrolysis mode and minimum in fuel cell mode. Impedance measurements were performed under different current densities and gas compositions, and the results were analyzed by calculating the distribution of relaxation times. The ASR variation resulted from the difference in electrochemical reactions occurring on the Ni-YSZ electrode, i.e., Ni-YSZ is a better electrode for CO oxidation than for CO2 reduction. Coke formation on Ni-YSZ played a crucial role in affecting its electrolysis performance in the intermediate temperature region. The ASR apex was associated with a decrease in cell temperature during electrolysis due to the endothermic nature of CO2 reduction reaction. It was postulated that such a decrease in temperature and rise in CO concentration led to coke formation. As a consequence, higher temperature (>700 degrees C), higher CO2 concentration (>50%), and the presence of hydrogen or steam are recommended for efficient CO2 reduction in solid oxide electrochemical cells. (C) 2013 Elsevier B.V. All rights reserved

  7. Fuel cell electric power production

    DOEpatents

    Hwang, Herng-Shinn; Heck, Ronald M.; Yarrington, Robert M.

    1985-01-01

    A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

  8. MATERIAL AND PROCESS DEVELOPMENT LEADING TO ECONOMICAL HIGH-PERFORMANCE THIN-FILM SOLID OXIDE FUEL CELLS

    SciTech Connect

    Jie Guan; Atul Verma; Nguyen Minh

    2003-04-01

    This document summarizes the technical progress from September 2002 to March 2003 for the program, Material and Process Development Leading to Economical High-Performance Thin-Film Solid Oxide Fuel Cells, contract number DE-AC26-00NT40711. The causes have been identified for the unstable open circuit voltage (OCV) and low performance exhibited by the anode-supported lanthanum gallate based cells from the earlier development. Promising results have been obtained in the area of synthesis of electrolyte and cathode powders, which showed excellent sintering and densification at low temperatures. The fabrication of cells using tapecalendering process for anode-supported thin lanthanum gallate electrolyte cells and their performance optimization is in progress.

  9. Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...

    Energy.gov [DOE] (indexed site)

    Fuel Cell Seminar on November 1, 2011. Fuel Cell Technologies Overview (4.38 MB) More Documents & Publications Fuel Cell Technologies Overview: March 2012 State Energy Advisory ...

  10. DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...

    Energy.gov [DOE] (indexed site)

    Overview of DOE's Fuel Cell Technologies Office presented by Sunita Satyapal at the 2013 Fuel Cell Seminar and Energy Exposition in Columbus, Ohio. DOE Fuel Cell Technologies ...

  11. Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined...

    Energy.gov [DOE] (indexed site)

    smith.pdf (0 B) More Documents & Publications Fuel Cells at Supermarkets: NYSERDA's Perspective Fuel Cell Case Study Hydrogen Production and Storage for Fuel Cells: Current Status

  12. Fuel Cells

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Cells - Sandia Energy Energy Search Icon Sandia Home ... Energy Conversion Efficiency Solar Energy Wind Energy Water ... EnergyWater Nexus EnergyWater History Water Monitoring & ...

  13. Experimental characterization of glass-ceramic seal properties and their constitutive implementation in solid oxide fuel cell stack models

    SciTech Connect

    Stephens, Elizabeth V.; Vetrano, John S.; Koeppel, Brian J.; Chou, Y. S.; Sun, Xin; Khaleel, Mohammad A.

    2009-09-05

    This paper discusses experimental determination of solid oxide fuel cell (SOFC) glass-ceramic seal material properties and seal/interconnect interfacial properties to support development and optimization of SOFC designs through modeling. Material property experiments such as dynamic resonance, dilatometry, flexure, creep, tensile, and shear tests were performed on PNNLs glass-ceramic sealant material, designated as G18, to obtain property data essential to constitutive and numerical model development. Characterization methods for the physical, mechanical, and interfacial properties of the sealing material, results, and their application to the constitutive implementation in SOFC stack modeling are described.

  14. Fuel cell CO sensor

    DOEpatents

    Grot, Stephen Andreas; Meltser, Mark Alexander; Gutowski, Stanley; Neutzler, Jay Kevin; Borup, Rodney Lynn; Weisbrod, Kirk

    1999-12-14

    The CO concentration in the H.sub.2 feed stream to a PEM fuel cell stack is monitored by measuring current and/or voltage behavior patterns from a PEM-probe communicating with the reformate feed stream. Pattern recognition software may be used to compare the current and voltage patterns from the PEM-probe to current and voltage telltale outputs determined from a reference cell similar to the PEM-probe and operated under controlled conditions over a wide range of CO concentrations in the H.sub.2 fuel stream. A CO sensor includes the PEM-probe, an electrical discharge circuit for discharging the PEM-probe to monitor the CO concentration, and an electrical purging circuit to intermittently raise the anode potential of the PEM-probe's anode to at least about 0.8 V (RHE) to electrochemically oxidize any CO adsorbed on the probe's anode catalyst.

  15. National Energy Technology Laboratory Publishes Solid Oxide Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    as quickly as possible. The NETL-managed program is currently developing solid oxide fuel cells for large power plants. The same technology is also likely to find...

  16. Fuel cell development for transportation: Catalyst development

    SciTech Connect

    Doddapaneni, N.

    1996-04-01

    Fuel cells are being considered as alternate power sources for transportation and stationary applications. With proton exchange membrane (PEM) fuel cells the fuel crossover to cathodes causes severe thermal management and cell voltage drop due to oxidation of fuel at the platinized cathodes. The main goal of this project was to design, synthesize, and evaluate stable and inexpensive transition metal macrocyclic catalysts for the reduction of oxygen and be electrochemically inert towards anode fuels such as hydrogen and methanol.

  17. Effect of Creep of Ferritic Interconnect on Long-Term Performance of Solid Oxide Fuel Cell Stacks

    SciTech Connect

    Liu, Wenning N.; Sun, Xin; Khaleel, Mohammad A.

    2010-08-01

    High-temperature ferritic alloys are potential candidates as interconnect (IC) materials and spacers due to their low cost and coefficient of thermal expansion (CTE) compatibility with other components for most of the solid oxide fuel cells (SOFCs) . However, creep deformation becomes relevant for a material when the operating temperature exceeds or even is less than half of its melting temperature (in degrees of Kelvin). The operating temperatures for most of the SOFCs under development are around 1,073 K. With around 1,800 K of the melting temperature for most stainless steel, possible creep deformation of ferritic IC under the typical cell operating temperature should not be neglected. In this paper, the effects of IC creep behavior on stack geometry change and the stress redistribution of different cell components are predicted and summarized. The goal of the study is to investigate the performance of the fuel cell stack by obtaining the changes in fuel- and air-channel geometry due to creep of the ferritic stainless steel IC, therefore indicating possible changes in SOFC performance under long-term operations. The ferritic IC creep model was incorporated into software SOFC-MP and Mentat-FC, and finite element analyses were performed to quantify the deformed configuration of the SOFC stack under the long-term steady-state operating temperature. It was found that the creep behavior of the ferritic stainless steel IC contributes to narrowing of both the fuel- and the air-flow channels. In addition, stress re-distribution of the cell components suggests the need for a compliant sealing material that also relaxes at operating temperature.

  18. Improvement of the long term stability in the high temperature solid oxide fuel cell using functional layers

    SciTech Connect

    Brueckner, B.; Guenther, C.; Ruckdaeschel, R.

    1996-12-31

    In the planar Siemens design of the solid oxide fuel cell a metallic interconnector is used to seperate the ceramic single cells. A disadvantage of the metallic bipolar plate which consists of a chromium alloy is the formation of high volatile Cr-oxides and hydroxides at the surface at the cathode side. The reaction products evaporate and are reduced at the cathode/electrolyte interface to form new crystalline phases. This process gives rise to long term cell degradation. Protective coatings might be successful in preventing the chromium oxide evaporation. The required properties of the protective layers are (I) high electrical conductivity, (II) similar coefficients of thermal expansion to the bipolar plate (III), chemical compatibility to the bipolar plate and cathode material, (IV) a low diffusion coefficient of Cr and (V) chemical stability up to 1223K under oxygen atmosphere. Furthermore, during operation at 1223K an electrical contact between the metallic plate and the electrodes has to be maintained. This problem could be solved using ceramic layer between the metallic plate and the single cells.

  19. Fuel Cells in the States

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    in the Fuel Cells in the States States State and Regional State and Regional Initiatives ... Jennifer Gangi Jennifer Gangi Program Director Program Director Fuel Cells 2000 Fuel Cells ...

  20. EERE Fuel Cell Technologies Program

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AudienceEvent Date EERE Fuel Cell Technologies Program Sunita Satyapal Acting Program Manager U.S. Department of Energy Fuel Cell Technologies Program Fuel Cell Project Kickoff ...

  1. DOE Fuel Cell Technologies Office

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE Fuel Cell Technologies Office Fuel Cell Seminar & Energy Exposition Columbus, Ohio Dr. Sunita Satyapal Director Fuel Cell Technologies Office Energy Efficiency and Renewable ...

  2. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen Joel; Doll, Gary Lynn

    2001-07-17

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  3. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen J.; Doll, Gary L.

    1997-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  4. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen Joel; Doll, Gary Lynn

    2002-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  5. Fuel Cell Bus Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ec o o es o a Energy Efficiency & Renewable Energy Fuel Cell Bus Workshop Overview and Purp pose Dimitrios Papageorgopoulos Fuel Cell Technolog gies Prog gram DOE and DOT Joint ...

  6. ZERO EMISSION POWER PLANTS USING SOLID OXIDE FUEL CELLS AND OXYGEN TRANSPORT MEMBRANES

    SciTech Connect

    G. Maxwell Christie; Troy M. Raybold

    2003-06-10

    Over 16,700 hours of operational experience was gained for the Oxygen Transport Membrane (OTM) elements of the proposed SOFC/OTM zero-emission power generation concept. It was repeatedly demonstrated that OTMs with no additional oxidation catalysts were able to completely oxidize the remaining depleted fuel in a simulated SOFC anode exhaust at an O{sub 2} flux that met initial targets. In such cases, neither residual CO nor H{sub 2} were detected to the limits of the gas chromatograph (<10 ppm). Dried OTM afterburner exhaust streams contained up to 99.5% CO{sub 2}. Oxygen flux through modified OTMs was double or even triple that of the standard OTMs used for the majority of testing purposes. Both the standard and modified membranes in laboratory-scale and demonstration-sized formats exhibited stable performance over extended periods (2300 to 3500 hours or 3 to 5 months). Reactor contaminants, were determined to negatively impact OTM performance stability. A method of preventing OTM performance degradation was developed and proven to be effective. Information concerning OTM and seal reliability over extended periods and through various chemical and thermal shocks and cycles was also obtained. These findings were used to develop several conceptual designs for pilot (10 kWe) and commercial-scale (250 kWe) SOFC/OTM zero emission power generation systems.

  7. Fuel cell having dual electrode anode or cathode

    DOEpatents

    Findl, Eugene

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  8. Fuel cell having dual electrode anode or cathode

    DOEpatents

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  9. Development and optimization of planar-geometry solid-oxide fuel cells. Annual report, December 1990-December 1991

    SciTech Connect

    Timper, M.; Parrish, M.; Milliken, C.; Elangovan, S.; Khandkar, A.

    1992-02-01

    The main focus of the work is to develop solid oxide fuel cell electrolytes that operate in the 600-800 C range. The first phase of the work focused on the development of composite Bi2O3-ZrO2 electrolytes which showed the promise of high conductivity and stability towards fuel. Kinetic stabilization of Bi2O3 compositions which resist phase transformation was also demonstrated. Work on two layer composite electrolytes with a thin ZrO2 protective layer was continued. Initial sputter coating trials on CeO2 electrolytes exhibited thin cracks in the ZrO2 layer due to mismatch in thermal expansion coefficients. Development of an EVD process for coating of a thin layer appears to be a viable technique. Single cell tests using uncoated CeO2 electrolytes using tubular cells showed a performance of about 100mA/sq cm at 0.4 V at approximately 800 C while the performance of planar cells is about 250mA/sq cm at 0.4 V. The main challenge is to fabricate composite electrolytes without causing either delamination or microcracking. Vacuum sputter deposition was chosen as the first process and alternate techniques such as EVD and plasma spraying are also being considered. The transport properties are then evaluated and electrodes are optimized for testing and evaluation as SOFCs.

  10. Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells Presented at the DOE-DOD Shipboard APU Workshop on March 29, 2011. apu2011_6_roychoudhury.pdf (4.83 MB) More Documents & Publications System Design - Lessons Learned, Generic Concepts, Characteristics & Impacts Fuel Cells For Transportation - 1999 Annual Progress Report Energy Conversion Team Fuel Cell Systems Annual Progress Report

  11. Fuel Cells & Alternative Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Cells & Alternative Fuels Fuel Cells & Alternative Fuels Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and ...

  12. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  13. Microbial fuel cells

    DOEpatents

    Nealson, Kenneth H; Pirbazari, Massoud; Hsu, Lewis

    2013-04-09

    A microbial fuel cell includes an anode compartment with an anode and an anode biocatalyst and a cathode compartment with a cathode and a cathode biocatalyst, with a membrane positioned between the anode compartment and the cathode compartment, and an electrical pathway between the anode and the cathode. The anode biocatalyst is capable of catalyzing oxidation of an organic substance, and the cathode biocatalyst is capable of catalyzing reduction of an inorganic substance. The reduced organic substance can form a precipitate, thereby removing the inorganic substance from solution. In some cases, the anode biocatalyst is capable of catalyzing oxidation of an inorganic substance, and the cathode biocatalyst is capable of catalyzing reduction of an organic or inorganic substance.

  14. Combined Theoretical and Experimental Investigation and Design of H2S Tolerant Anode for Solid Oxide Fuel Cells

    SciTech Connect

    Gerardine G. Botte; Damilola Daramola; Madhivanan Muthuvel

    2009-01-07

    A solid oxide fuel cell (SOFC) is a high temperature fuel cell and it normally operates in the range of 850 to 1000 C. Coal syngas has been considered for use in SOFC systems to produce electric power, due to its high temperature and high hydrogen and carbon monoxide content. However, coal syngas also has contaminants like carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). Among these contaminants, H{sub 2}S is detrimental to electrode material in SOFC. Commonly used anode material in SOFC system is nickel-yttria stabilized zirconia (Ni-YSZ). The presence of H{sub 2}S in the hydrogen stream will damage the Ni anode and hinder the performance of SOFC. In the present study, an attempt was made to understand the mechanism of anode (Ni-YSZ) deterioration by H{sub 2}S. The study used computation methods such as quantum chemistry calculations and molecular dynamics to predict the model for anode destruction by H{sub 2}S. This was done using binding energies to predict the thermodynamics and Raman spectroscopy to predict molecular vibrations and surface interactions. On the experimental side, a test stand has been built with the ability to analyze button cells at high temperature under syngas conditions.

  15. Pore Scale Modeling of the Reactive Transport of Chromium in the Cathode of a Solid Oxide Fuel Cell

    SciTech Connect

    Ryan, Emily M.; Tartakovsky, Alexandre M.; Recknagle, Kurtis P.; Khaleel, Mohammad A.; Amon, Cristina

    2011-01-01

    We present a pore scale model of a solid oxide fuel cell (SOFC) cathode. Volatile chromium species are known to migrate from the current collector of the SOFC into the cathode where over time they decrease the voltage output of the fuel cell. A pore scale model is used to investigate the reactive transport of chromium species in the cathode and to study the driving forces of chromium poisoning. A multi-scale modeling approach is proposed which uses a cell level model of the cathode, air channel and current collector to determine the boundary conditions for a pore scale model of a section of the cathode. The pore scale model uses a discrete representation of the cathode to explicitly model the surface reactions of oxygen and chromium with a cathode material. The pore scale model is used to study the reaction mechanisms of chromium by considering the effects of reaction rates, diffusion coefficients, chromium vaporization, and oxygen consumption on chromiums deposition in the cathode. The study shows that chromium poisoning is most significantly affected by the chromium reaction rates in the cathode and that the reaction rates are a function of the local current density in the cathode.

  16. DOE Fuel Cell Subprogram (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    most relevant fuel cell research, development, and ... available at www.hydrogen.energy.gov) Product Non-purpose * ... c Fuel Cell Seminar Abstracts, 2004, p. 290. 13 Fuel ...

  17. Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation

    SciTech Connect

    Powell, Michael R.; Meinhardt, Kerry D.; Sprenkle, Vincent L.; Chick, Lawrence A.; Mcvay, Gary L.

    2012-05-01

    Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

  18. Calculation of contact angles at triple phase boundary in solid oxide fuel cell anode using the level set method

    SciTech Connect

    Sun, Xiaojun; Hasegawa, Yosuke; Kohno, Haruhiko; Jiao, Zhenjun; Hayakawa, Koji; Okita, Kohei; Shikazono, Naoki

    2014-10-15

    A level set method is applied to characterize the three dimensional structures of nickel, yttria stabilized zirconia and pore phases in solid oxide fuel cell anode reconstructed by focused ion beam-scanning electron microscope. A numerical algorithm is developed to evaluate the contact angles at the triple phase boundary based on interfacial normal vectors which can be calculated from the signed distance functions defined for each of the three phases. Furthermore, surface tension force is estimated from the contact angles by assuming the interfacial force balance at the triple phase boundary. The average contact angle values of nickel, yttria stabilized zirconia and pore are found to be 143156, 83138 and 82123, respectively. The mean contact angles remained nearly unchanged after 100 hour operation. However, the contact angles just after reduction are different for the cells with different sintering temperatures. In addition, standard deviations of the contact angles are very large especially for yttria stabilized zirconia and pore phases. The calculated surface tension forces from mean contact angles were close to the experimental values found in the literature. Slight increase of surface tensions of nickel/pore and nickel/yttria stabilized zirconia were observed after operation. Present data are expected to be used not only for the understanding of the degradation mechanism, but also for the quantitative prediction of the microstructural temporal evolution of solid oxide fuel cell anode. - Highlights: A level set method is applied to characterize the 3D structures of SOFC anode. A numerical algorithm is developed to evaluate the contact angles at the TPB. Surface tension force is estimated from the contact angles. The average contact angle values are found to be 143o-156o, 83o-138o and 82o-123o. Present data are expected to understand degradation and predict evolution of SOFC.

  19. TESTING AND PERFORMANCE ANALYSIS OF NASA 5 CM BY 5 CM BI-SUPPORTED SOLID OXIDE ELECTROLYSIS CELLS OPERATED IN BOTH FUEL CELL AND STEAM ELECTROLYSIS MODES

    SciTech Connect

    R. C. O'Brien; J. E. O'Brien; C. M. Stoots; X. Zhang; S. C. Farmer; T. L. Cable; J. A. Setlock

    2011-11-01

    A series of 5 cm by 5 cm bi-supported Solid Oxide Electrolysis Cells (SOEC) were produced by NASA for the Idaho National Laboratory (INL) and tested under the INL High Temperature Steam Electrolysis program. The results from the experimental demonstration of cell operation for both hydrogen production and operation as fuel cells is presented. An overview of the cell technology, test apparatus and performance analysis is also provided. The INL High Temperature Steam Electrolysis laboratory has developed significant test infrastructure in support of single cell and stack performance analyses. An overview of the single cell test apparatus is presented. The test data presented in this paper is representative of a first batch of NASA's prototypic 5 cm by 5 cm SOEC single cells. Clearly a significant relationship between the operational current density and cell degradation rate is evident. While the performance of these cells was lower than anticipated, in-house testing at NASA Glenn has yielded significantly higher performance and lower degradation rates with subsequent production batches of cells. Current post-test microstructure analyses of the cells tested at INL will be published in a future paper. Modification to cell compositions and cell reduction techniques will be altered in the next series of cells to be delivered to INL with the aim to decrease the cell degradation rate while allowing for higher operational current densities to be sustained. Results from the testing of new batches of single cells will be presented in a future paper.

  20. California Fuel Cell Partnership: Alternative Fuels Research...

    Energy.gov [DOE] (indexed site)

    This presentation by Chris White of the California Fuel Cell Partnership provides information about alternative fuels research. cafcpinitiativescall.pdf (133.97 KB) More ...

  1. Microbial fuel cell treatment of fuel process wastewater

    DOEpatents

    Borole, Abhijeet P; Tsouris, Constantino

    2013-12-03

    The present invention is directed to a method for cleansing fuel processing effluent containing carbonaceous compounds and inorganic salts, the method comprising contacting the fuel processing effluent with an anode of a microbial fuel ell, the anode containing microbes thereon which oxidatively degrade one or more of the carbonaceous compounds while producing electrical energy from the oxidative degradation, and directing the produced electrical energy to drive an electrosorption mechanism that operates to reduce the concentration of one or more inorganic salts in the fuel processing effluent, wherein the anode is in electrical communication with a cathode of the microbial fuel cell. The invention is also directed to an apparatus for practicing the method.

  2. Effects of surface chemistry and microstructure of electrolyte on oxygen reduction kinetics of solid oxide fuel cells

    DOE PAGES [OSTI]

    Park, Joong Sun; An, Jihwan; Lee, Min Hwan; Prinz, Friedrich B.; Lee, Wonyoung

    2015-07-10

    In this study, we report systematic investigation of the surface properties of yttria-stabilized zirconia (YSZ) electrolytes with the control of the grain boundary (GB) density at the surface, and its effects on electrochemical activities. The GB density of thin surface layers deposited on single crystal YSZ substrates is controlled by changing the annealing temperature (750-1450 °C). Higher oxygen reduction reactions (ORR) kinetics is observed in samples annealed at lower temperatures. The higher ORR activity is ascribed to the higher GB density at the YSZ surface where 'mobile' oxide ion vacancies are more populated. Meanwhile, oxide ion vacancies concurrently created withmore » yttrium segregation at the surface at the higher annealing temperature are considered inactive to oxygen incorporation reactions. Our results provide additional insight into the interplay between the surface chemistry, microstructures, and electrochemical activity. They potentially provide important guidelines for engineering the electrolyte electrode interfaces of solid oxide fuel cells for higher electrochemical performance.« less

  3. Electrical Stability of a Novel Refractory Sealing Glass in a Dual Environment for Solid Oxide Fuel Cell Applications

    SciTech Connect

    Chou, Y. S.; Stevenson, Jeffry W.; Meinhardt, Kerry D.

    2010-03-01

    A novel refractory alkaline-earth silicate (Sr-Ca-Y-B-Si) sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was sealed between two metallic interconnect plates and tested for electrical stability at elevated temperatures and duel environments under DC loading. The isothermal aging results showed very stable electrical resistivity with values 5-9 orders of magnititudes higher than typical SOFC function materials at 850 degrees C for ~700 hr. For comparison, the state-of-the-art sealing glass (G18, Ba-Ca-Al-B-Si) was also evaluated in a similar condition and showed less stable in accelerated tests at 830 degrees C for ~100 hr. Interfacial microstruicture was characterized and possible reactions were discussed.

  4. Heating subsurface formations by oxidizing fuel on a fuel carrier

    DOEpatents

    Costello, Michael; Vinegar, Harold J.

    2012-10-02

    A method of heating a portion of a subsurface formation includes drawing fuel on a fuel carrier through an opening formed in the formation. Oxidant is supplied to the fuel at one or more locations in the opening. The fuel is combusted with the oxidant to provide heat to the formation.

  5. Preventing CO poisoning in fuel cells

    DOEpatents

    Gottesfeld, Shimshon

    1990-01-01

    Proton exchange membrane (PEM) fuel cell performance with CO contamination of the H.sub.2 fuel stream is substantially improved by injecting O.sub.2 into the fuel stream ahead of the fuel cell. It is found that a surface reaction occurs even at PEM operating temperatures below about 100.degree. C. to oxidatively remove the CO and restore electrode surface area for the H.sub.2 reaction to generate current. Using an O.sub.2 injection, a suitable fuel stream for a PEM fuel cell can be formed from a methanol source using conventional reforming processes for producing H.sub.2.

  6. Fuel Cell Technologies Budget

    SciTech Connect

    EERE

    2012-03-16

    The Fuel Cell Technologies Office receives appropriations from Energy and Water Development. The offices's major activities and budget are outlined in this Web page.

  7. Opportunities with Fuel Cells

    Reports and Publications

    1994-01-01

    The concept for fuel cells was discovered in the nineteenth century. Today, units incorporating this technology are becoming commercially available for cogeneration applications.

  8. Fuel Cell Case Study

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Fuel Cells for Supermarkets, April 4, 2011.

  9. Hydrogen Fuel Cells

    Publication and Product Library

    The fuel cell an energy conversion device that can efficiently capture and use the power of hydrogen is the key to making it happen.

  10. Hydrogen Fuel Cells

    Publication and Product Library

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  11. Fuel Cell Demonstration Program

    SciTech Connect

    Gerald Brun

    2006-09-15

    In an effort to promote clean energy projects and aid in the commercialization of new fuel cell technologies the Long Island Power Authority (LIPA) initiated a Fuel Cell Demonstration Program in 1999 with six month deployments of Proton Exchange Membrane (PEM) non-commercial Beta model systems at partnering sites throughout Long Island. These projects facilitated significant developments in the technology, providing operating experience that allowed the manufacturer to produce fuel cells that were half the size of the Beta units and suitable for outdoor installations. In 2001, LIPA embarked on a large-scale effort to identify and develop measures that could improve the reliability and performance of future fuel cell technologies for electric utility applications and the concept to establish a fuel cell farm (Farm) of 75 units was developed. By the end of October of 2001, 75 Lorax 2.0 fuel cells had been installed at the West Babylon substation on Long Island, making it the first fuel cell demonstration of its kind and size anywhere in the world at the time. Designed to help LIPA study the feasibility of using fuel cells to operate in parallel with LIPA's electric grid system, the Farm operated 120 fuel cells over its lifetime of over 3 years including 3 generations of Plug Power fuel cells (Lorax 2.0, Lorax 3.0, Lorax 4.5). Of these 120 fuel cells, 20 Lorax 3.0 units operated under this Award from June 2002 to September 2004. In parallel with the operation of the Farm, LIPA recruited government and commercial/industrial customers to demonstrate fuel cells as on-site distributed generation. From December 2002 to February 2005, 17 fuel cells were tested and monitored at various customer sites throughout Long Island. The 37 fuel cells operated under this Award produced a total of 712,635 kWh. As fuel cell technology became more mature, performance improvements included a 1% increase in system efficiency. Including equipment, design, fuel, maintenance, installation

  12. Solid oxide fuel cell with internal reforming, catalyzed interconnect for use therewith, and methods

    DOEpatents

    Liu, Di-Jia; Guan, Jie; Minh, Nguyen

    2010-06-08

    A catalyzed interconnect for an SOFC electrically connects an anode and an anodic current collector and comprises a metallic substrate, which provides space between the anode and anodic current collector for fuel gas flow over at least a portion of the anode, and a catalytic coating on the metallic substrate comprising a catalyst for catalyzing hydrocarbon fuel in the fuel gas to hydrogen rich reformate. An SOFC including the catalyzed anodic inter-connect, a method for operating an SOFC, and a method for making a catalyzed anodic interconnect are also disclosed.

  13. 2007 Fuel Cell Technologies Market Report

    SciTech Connect

    McMurphy, K.

    2009-07-01

    The fuel cell industry, which has experienced continued increases in sales, is an emerging clean energy industry with the potential for significant growth in the stationary, portable, and transportation sectors. Fuel cells produce electricity in a highly efficient electrochemical process from a variety of fuels with low to zero emissions. This report describes data compiled in 2008 on trends in the fuel cell industry for 2007 with some comparison to two previous years. The report begins with a discussion of worldwide trends in units shipped and financing for the fuel cell industry for 2007. It continues by focusing on the North American and U.S. markets. After providing this industry-wide overview, the report identifies trends for each of the major fuel cell applications -- stationary power, portable power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline fuel cell (AFC), molten carbonate fuel cell (MCFC), phosphoric acid fuel cell (PAFC), and direct-methanol fuel cell (DMFC) -- used for these applications.

  14. Miniature ceramic fuel cell

    DOEpatents

    Lessing, Paul A.; Zuppero, Anthony C.

    1997-06-24

    A miniature power source assembly capable of providing portable electricity is provided. A preferred embodiment of the power source assembly employing a fuel tank, fuel pump and control, air pump, heat management system, power chamber, power conditioning and power storage. The power chamber utilizes a ceramic fuel cell to produce the electricity. Incoming hydro carbon fuel is automatically reformed within the power chamber. Electrochemical combustion of hydrogen then produces electricity.

  15. Microstructural and chemical evolution near anode triple phase boundary in Ni/YSZ solid oxide fuel cells

    SciTech Connect

    Chen, Yun; Chen, Song; Hackett, Gregory; Finklea, Harry; Song, Xueyan; Gerdes, Kirk

    2011-12-12

    In this study, we report the micro-structural and chemical evolution of anode grain boundaries and triple phase boundary (TPB) junctions of Ni/YSZ anode supported solid oxide fuel cells. A NiO phase was found to develop along the Ni/YSZ interfaces extending to TPBs in the operated cells. The thickness of the NiO ribbon phase remains constant at ~ 5 nm in hydrogen for operating durations up to 540 h. When operating on synthesis gas, an increase in interphase thickness was observed from ~ 11 nm for 24 h of operation to ~ 51 nm for 550 h of operation. YSZ phases are observed to be stable in H{sub 2} over 540 h of operation. However, for the cell operated in syngas for 550 h, a 510 nm tetragonal YSZ (t-YSZ) interfacial layer was identified that originated from the Ni/YSZ interfaces. Yttrium species seem to segregate to the interfaces during operation, leading to the formation of t-YSZ in the Y-depleted regions.

  16. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  17. Characterization and Quantification of Electronic and Ionic Ohmic Overpotential and Heat Generation in a Solid Oxide Fuel Cell Anode

    SciTech Connect

    Grew, Kyle N.; Izzo, Jr., John R.; Chiu, W. K. S.

    2011-01-01

    The development of a solid oxide fuel cell (SOFC) with a higher efficiency and power density requires an improved understanding and treatment of the irreversibilities. Losses due to the electronic and ionic resistances, which are also known as ohmic losses in the form of Joule heating, can hinder the SOFCs performance. Ohmic losses can result from the bulk material resistivities as well as the complexities introduced by the cells microstructure. In this work, two-dimensional (2D), electronic and ionic transport models are used to develop a method of quantification of the ohmic losses within the SOFC anode microstructure. This quantification is completed as a function of properties determined from a detailed microstructure characterization, namely, the tortuosity of the electronic and ionic phases, phase volume fraction, contiguity, and mean free path. A direct modeling approach at the level of the pore-scale microstructure is achieved through the use of a representative volume element (RVE) method. The correlation of these ohmic losses with the quantification of the SOFC anode microstructure are examined. It is found with this analysis that the contributions of the SOFC anode microstructure on ohmic losses can be correlated with the volume fraction, contiguity, and mean free path.

  18. Tilted fuel cell apparatus

    DOEpatents

    Cooper, John F.; Cherepy, Nerine; Krueger, Roger L.

    2005-04-12

    Bipolar, tilted embodiments of high temperature, molten electrolyte electrochemical cells capable of directly converting carbon fuel to electrical energy are disclosed herein. The bipolar, tilted configurations minimize the electrical resistance between one cell and others connected in electrical series. The tilted configuration also allows continuous refueling of carbon fuel.

  19. Direct Internal Reformation and Mass Transport in the Solid Oxide Fuel Cell Anode: A Pore-Scale Lattice Boltzmann Study with Detailed Reaction Kinetics

    SciTech Connect

    Grew, Kyle N.; Joshi, Abhijit S.; Chiu, W. K. S.

    2010-11-30

    The solid oxide fuel cell (SOFC) allows the conversion of chemical energy that is stored in a given fuel, including light hydrocarbons, to electrical power. Hydrocarbon fuels, such as methane, are logistically favourable and provide high energy densities. However, the use of these fuels often results in a decreased efficiency and life. An improved understanding of the reactive flow in the SOFC anode can help address these issues. In this study, the transport and heterogeneous internal reformation of a methane based fuel is addressed. The effect of the SOFC anode's complex structure on transport and reactions is shown to exhibit a complicated interplay between the local molar concentrations and the anode structure. Strong coupling between the phenomenological microstructures and local reformation reaction rates are recognised in this study, suggesting the extension to actual microstructures may provide new insights into the reformation processes.

  20. NREL: Hydrogen and Fuel Cells Research - Early Fuel Cell Market

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Demonstrations Early Fuel Cell Market Demonstrations Photo of fuel cell backup power system in outdoor setting. Photo of fuel cell forklifts in warehouse setting. Fuel cell backup power systems offer longer continuous runtimes and greater durability than traditional batteries in harsh outdoor environments. For specialty vehicles such as forklifts, fuel cells can be a cost-competitive alternative to traditional lead-acid batteries. Learn More Subscribe to the biannual Fuel Cell and Hydrogen

  1. Fuel Cells Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen fuel cell technology. Fuel Cells More Documents & Publications Hydrogen and Fuel Cell...

  2. Method of making straight fuel cell tubes

    DOEpatents

    Borglum, Brian P. (Edgewood, PA)

    2001-01-01

    A method and an apparatus for making straight fuel cell tubes are disclosed. Extruded tubes comprising powders of fuel cell material and a solvent are dried by rotating the extruded tubes. The rotation process provides uniform circumferential drying which results in uniform linear shrinkage of the tubes. The resultant dried tubes are very straight, thereby eliminating subsequent straightening steps required with conventional processes. The method is particularly useful for forming inner air electrode tubes of solid oxide fuel cells.

  3. Multi-stage fuel cell system method and apparatus

    DOEpatents

    George, Thomas J.; Smith, William C.

    2000-01-01

    A high efficiency, multi-stage fuel cell system method and apparatus is provided. The fuel cell system is comprised of multiple fuel cell stages, whereby the temperatures of the fuel and oxidant gas streams and the percentage of fuel consumed in each stage are controlled to optimize fuel cell system efficiency. The stages are connected in a serial, flow-through arrangement such that the oxidant gas and fuel gas flowing through an upstream stage is conducted directly into the next adjacent downstream stage. The fuel cell stages are further arranged such that unspent fuel and oxidant laden gases too hot to continue within an upstream stage because of material constraints are conducted into a subsequent downstream stage which comprises a similar cell configuration, however, which is constructed from materials having a higher heat tolerance and designed to meet higher thermal demands. In addition, fuel is underutilized in each stage, resulting in a higher overall fuel cell system efficiency.

  4. EA-0510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator Development Project (METC), Churchill, Pennsylvania

    Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to enter into a 5-year cooperative agreement with the Westinghouse Electric Corporation for the development of high-temperature solid oxide...

  5. Fuel Cell Animation- Fuel Cell Stack (Text Version)

    Energy.gov [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

  6. Fuel Cell Animation- Fuel Cell Components (Text Version)

    Energy.gov [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

  7. DOE Fuel Cell Technologies Office Record 14014: Fuel Cell System...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    14014 Date: September 25, 2014 Title: Fuel Cell System Cost - 2014 Update to: Record 14012 ... polymer electrolyte membrane (PEM) fuel cell system based on next-generation ...

  8. NREL: Hydrogen and Fuel Cells Research - Stationary Fuel Cell...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Stationary Fuel Cell Units Greater Than 100 kW Achieve 2015 Target for Electrical ... Center (NFCTEC) has validated the electrical efficiency of stationary fuel cells for ...

  9. Microbial fuel cell treatment of fuel process wastewater (Patent...

    Office of Scientific and Technical Information (OSTI)

    Microbial fuel cell treatment of fuel process wastewater Title: Microbial fuel cell treatment of fuel process wastewater The present invention is directed to a method for cleansing ...

  10. Microbial fuel cell treatment of fuel process wastewater (Patent...

    Office of Scientific and Technical Information (OSTI)

    Microbial fuel cell treatment of fuel process wastewater Title: Microbial fuel cell treatment of fuel process wastewater You are accessing a document from the Department of ...

  11. Hydrogen Fueling for Current and Anticipated Fuel Cell Electric...

    Energy.gov [DOE] (indexed site)

    Hydrogen Fueling for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs)" held on June 24, 2014. Hydrogen Fueling for Current and Anticipated Fuel Cell Electric Vehicles ...

  12. The Orientation Distributions of Lines, Surfaces, and Interfaces Around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes

    SciTech Connect

    Dillon, Shen; Helmick, Lam; Miller, Herbert M.; Johnson, Christopher; Wilson, Lane; Gemmen, Randall; Petrova, Rumyana; Barmak, Katayun; Gerdes, Kirk; Rohrer, Gregory S.; Salvador, Paul A.

    2011-11-01

    Three-dimensional electron backscatter diffraction was used to measure the crystallographic distribution of the electrochemically relevant triple phase boundary lines and surfaces near them in SOFC cathodes made up of a porous mixture of yttria-stabilized zirconia and lanthanum strontium manganese oxide, both before and after mild electrochemical loading. All distributions were observed to be nearly isotropic, but non-random textures above the detection threshold were observed. The distributions differ between the two cells, as do the phase fractions and the electrochemical history. The different distributions are interpreted as evidence that steady-state distributions vary locally with phase fractions or that they evolve during the initial operation of the fuel cell. The rates at which triple lines, pore surfaces, and interface boundaries in the porous mixture approach a steady-state value appear to decrease with the average amount of mass transport required to reorient that specific feature. This work provides initial insights into the crystallography of interfaces in a multiphase ceramic material.

  13. Characterization and Quantification of Electronic and Ionic Ohmic Overpotential and Heat Generation in a Solid Oxide Fuel Cell Anode

    SciTech Connect

    Grew, Kyle N.; Izzo, John R.; Chiu, Wilson K.S.

    2011-08-16

    The development of a solid oxide fuel cell (SOFC) with a higher efficiency and power density requires an improved understanding and treatment of the irreversibilities. Losses due to the electronic and ionic resistances, which are also known as ohmic losses in the form of Joule heating, can hinder the SOFC's performance. Ohmic losses can result from the bulk material resistivities as well as the complexities introduced by the cell's microstructure. In this work, two-dimensional (2D), electronic and ionic transport models are used to develop a method of quantification of the ohmic losses within the SOFC anode microstructure. This quantification is completed as a function of properties determined from a detailed microstructure characterization, namely, the tortuosity of the electronic and ionic phases, phase volume fraction, contiguity, and mean free path. A direct modeling approach at the level of the pore-scale microstructure is achieved through the use of a representative volume element (RVE) method. The correlation of these ohmic losses with the quantification of the SOFC anode microstructure are examined. It is found with this analysis that the contributions of the SOFC anode microstructure on ohmic losses can be correlated with the volume fraction, contiguity, and mean free path.

  14. The main directions in technology investigation of soid oxide fuel cell in Russian Federal Research Center Institute of Physics & Power Engineering (IPPE)

    SciTech Connect

    Ievleva, J.I.; Kolesnikov, V.P.; Mezhertisky, G.S.

    1996-04-01

    The main direction of science investigations for creation of efficient solid oxide fuel cells (SOFC) in IPPE are considered in this work. The development program of planar SOFC with thin-film electrolyte is shown. General design schemes of experimental SOFC units are presented. The flow design schemes of processes for initial materials and electrodes fabrication are shown. The results of investigations for creation thin-film solid oxide electrolyte at porous cathode by magnetron sputtering from complex metal target in oxidative environment are presented.

  15. DOE Hydrogen & Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    t t 1 | Fuel Cell Technologies Program eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U S D f E Overview U.S. ...

  16. Microbial Fuel Cell Technologies--MxCs: Can They Scale?

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Microbial Fuel Cell Technologies-- MxCs: Can they scale? (Yes!) Bruce E. Logan Penn State University Engineering Energy & Environmental Institute MFCs Anode Fuel (wastes) Oxidation products (CO 2 ) Bacteria that make electrical current Electrical power generation in a Microbial Fuel Cell (MFC) using exoelectrogenic microorganisms load e - e - Cathode Oxidant (O 2 ) Reduced oxidant (H 2 O) Liu e t al. (2004) Environ. Sci. Technol. H + 2 3 Scaling up MFCs & MECs MFCs= fuel cells, make

  17. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    CSD Workshop Washington, DC Fuel Cell Technologies Program Overview Dr. Sunita Satyapal Director, Fuel Cell Technologies Office Energy Efficiency and Renewable Energy U.S. Department of Energy 3/20/2012 2 | Fuel Cell Technologies Program eere.energy.gov Overview Fuel Cells - An Emerging Global Industry Clean Energy Patent Growth Index [1] shows that fuel cell patents lead in the clean energy field with over 950 fuel cell patents issued in 2011. * Nearly double the second place holder, solar,

  18. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Non-Metallic Materials Meeting Washington, DC Fuel Cell Technologies Program Overview Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 10/17/2012 2 | Fuel Cell Technologies Program eere.energy.gov Overview Fuel Cells - An Emerging Global Industry Clean Energy Patent Growth Index [1] shows that fuel cell patents lead in the clean energy field with over 950 fuel cell patents issued in 2011. * Nearly double the second place holder, solar, which has ~540

  19. Solid Oxide Fuel Cell Development for Auxiliary Power in Heavy Duty Vehicle Applications

    SciTech Connect

    Daniel T. Hennessy

    2010-06-15

    Changing economic and environmental needs of the trucking industry is driving the use of auxiliary power unit (APU) technology for over the road haul trucks. The trucking industry in the United States remains the key to the economy of the nation and one of the major changes affecting the trucking industry is the reduction of engine idling. Delphi Automotive Systems, LLC (Delphi) teamed with heavy-duty truck Original Equipment Manufacturers (OEMs) PACCAR Incorporated (PACCAR), and Volvo Trucks North America (VTNA) to define system level requirements and develop an SOFC based APU. The project defines system level requirements, and subsequently designs and implements an optimized system architecture using an SOFC APU to demonstrate and validate that the APU will meet system level goals. The primary focus is on APUs in the range of 3-5 kW for truck idling reduction. Fuels utilized were derived from low-sulfur diesel fuel. Key areas of study and development included sulfur remediation with reformer operation; stack sensitivity testing; testing of catalyst carbon plugging and combustion start plugging; system pre-combustion; and overall system and electrical integration. This development, once fully implemented and commercialized, has the potential to significantly reduce the fuel idling Class 7/8 trucks consume. In addition, the significant amounts of NOx, CO2 and PM that are produced under these engine idling conditions will be virtually eliminated, inclusive of the noise pollution. The environmental impact will be significant with the added benefit of fuel savings and payback for the vehicle operators / owners.

  20. Internet Fuel Cells Forum

    SciTech Connect

    Sudhoff, Frederick A.

    1996-08-01

    The rapid development and integration of the Internet into the mainstream of professional life provides the fuel cell industry with the opportunity to share new ideas with unprecedented capabilities. The U.S. Department of Energy's (DOE's) Morgantown Energy Technology Center (METC) has undertaken the task to maintain a Fuel Cell Forum on the Internet. Here, members can exchange ideas and information pertaining to fuel cell technologies. The purpose of this forum is to promote a better understanding of fuel cell concepts, terminology, processes, and issues relating to commercialization of fuel cell power technology. The Forum was developed by METC to provide those interested with fuel cell conference information for its current concept of exchanging ideas and information pertaining to fuel cells. Last August, the Forum expanded to an on-line and world-wide network. There are 250 members, and membership is growing at a rate of several new subscribers per week. The forum currently provides updated conference information and interactive information exchange. Forum membership is encouraged from utilities, industry, universities, and government. Because of the public nature of the internet, business sensitive, confidential, or proprietary information should not be placed on this system. The Forum is unmoderated; therefore, the views and opinions of authors expressed in the forum do not necessarily state or reflect those of the U.S. government or METC.

  1. Manufacturing Fuel Cell Manhattan Project

    Office of Energy Efficiency and Renewable Energy (EERE)

    This document communicates the major fuel cell manufacturing cost drivers, gaps, and industry best practices, as well as recommends manufacturing projects to advance fuel cell manufacturing.

  2. Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Activities Mr. Pete Devlin U.S. Department of Energy Fuel Cell Technologies Program Market Transformation Manager Stationary Fuel Cell Applications First National Bank of Omaha...

  3. Fuel Cell Technologies Office: Publications

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Technologies Office EERE Fuel Cell Technologies Office Share this resource Publications Advanced Search Browse by Topic Mail Requests Help Feature featured product...

  4. Comparison of Fuel Cell Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    More Information More information on the Fuel Cell Technologies Offce is available at http:www.hydrogenandfuelcells.energy.gov. Fuel Cell Type Common Electrolyte Operating ...

  5. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    IEA HIA Hydrogen Safety Stakeholder Workshop Bethesda, Maryland Fuel Cell Technologies Program Overview Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program ...

  6. Manufacturing Fuel Cell Manhattan Project

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Manufacturing Fuel Cell Manhattan Project Presented by the Benchmarking and Best Practices ... in providing valued information on affordable and implementable fuel cell technology. ...

  7. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    The Administration's Clean Energy Goals 2 3 Fuel Cells Address Our Key Energy Challenges Increasing Energy Efficiency and Resource Diversity Fuel cells offer a highly efficient ...

  8. DOE Fuel Cell Technology Office

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Fuel Cell Technology Office - Sandia Energy Energy Search Icon Sandia Home Locations ... SunShot Grand Challenge: Regional Test Centers DOE Fuel Cell Technology Office Home...

  9. Long-term evaluation of solid oxide fuel cell candidate materials in a 3-cell generic short stack fixture, Part II: sealing glass stability, microstructure and interfacial reactions.

    SciTech Connect

    Chou, Y. S.; Stevenson, Jeffry W.; Choi, Jung-Pyung

    2014-03-15

    A generic solid oxide fuel cell stack test fixture was developed to evaluate candidate materials and processing methods under realistic conditions. Part I of the work addressed the stack fixture, seal system and cell performance of a 3-cell short stack tested at 800oC for 6000h. Commercial NiO-YSZ anode-supported thin YSZ electrolyte cells with LSM cathodes were used for assessment and were tested in constant current mode with dilute (~50% H2) fuel versus air. Part II of the work examined the sealing glass stability, microstructure development, interfacial reactions, and volatility issues. Part III of the work investigated the stability of Ce-(Mn,Co) spinel coating, AISI441 metallic interconnect, alumina coating, and cell degradation. After 6000h of testing, the refractory sealing glass YSO77 (Ba-Sr-Y-B-Si) showed desirable chemical compatibility with YSZ electrolyte in that no discernable interfacial reaction was identified, consistent with thermodynamic calculations. In addition, no glass penetration into the thin electrolyte was observed. At the aluminized AISI441 interface, the protective alumina coating appeared to be corroded by the sealing glass. Air side interactions appeared to be more severe than fuel side interactions. Metal species such as Cr, Mn, and Fe were detected in the glass, but were limited to the vicinity of the interface. No alkaline earth chromates were found at the air side. Volatility was also studied in a similar glass and weight loss in a wet reducing environment was determined. Using the steady-state volatility data, the life time (40,000h) weight loss of refractory sealing glass YSO77 was estimated to be less than 0.1 wt%.

  10. Modular fuel-cell stack assembly

    SciTech Connect

    Patel, Pinakin; Urko, Willam

    2008-01-29

    A modular multi-stack fuel-cell assembly in which the fuel-cell stacks are situated within a containment structure and in which a gas distributor is provided in the structure and distributes received fuel and oxidant gases to the stacks and receives exhausted fuel and oxidant gas from the stacks so as to realize a desired gas flow distribution and gas pressure differential through the stacks. The gas distributor is centrally and symmetrically arranged relative to the stacks so that it itself promotes realization of the desired gas flow distribution and pressure differential.

  11. Anode protection system for shutdown of solid oxide fuel cell system

    DOEpatents

    Li, Bob X; Grieves, Malcolm J; Kelly, Sean M

    2014-12-30

    An Anode Protection Systems for a SOFC system, having a Reductant Supply and safety subsystem, a SOFC anode protection subsystem, and a Post Combustion and slip stream control subsystem. The Reductant Supply and safety subsystem includes means for generating a reducing gas or vapor to prevent re-oxidation of the Ni in the anode layer during the course of shut down of the SOFC stack. The underlying ammonia or hydrogen based material used to generate a reducing gas or vapor to prevent the re-oxidation of the Ni can be in either a solid or liquid stored inside a portable container. The SOFC anode protection subsystem provides an internal pressure of 0.2 to 10 kPa to prevent air from entering into the SOFC system. The Post Combustion and slip stream control subsystem provides a catalyst converter configured to treat any residual reducing gas in the slip stream gas exiting from SOFC stack.

  12. Single module pressurized fuel cell turbine generator system

    DOEpatents

    George, Raymond A.; Veyo, Stephen E.; Dederer, Jeffrey T.

    2001-01-01

    A pressurized fuel cell system (10), operates within a common pressure vessel (12) where the system contains fuel cells (22), a turbine (26) and a generator (98) where preferably, associated oxidant inlet valve (52), fuel inlet valve (56) and fuel cell exhaust valve (42) are outside the pressure vessel.

  13. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  14. Multilayered YSZ/GZO films with greatly enhanced ionic conduction for low temperature solid oxide fuel cells

    SciTech Connect

    Li, Bin; Zhang, Jiaming; Kaspar, Tiffany C.; Shutthanandan, V.; Ewing, Rodney C.; Lian, Jie

    2013-01-01

    Strain confinement in heterostructured films significantly affects ionic conductivity of the electrolytes for solid oxide fuel cells based on a multi-layered design strategy. Nearly ideal tensile strain can be achieved by a dedicated manipulation of the lattice mismatch between adjacent layers and fine control of the layer thicknesses to minimize the formation of dislocations and thus to achieve optimized ionic conduction. This strategy was demonstrated by a model system of multilayered 8 mol%Y2O3 stabilized ZrO2 (YSZ) with Gd2Zr2O7 (GZO) films, which were epitaxially grown on Al2O3 (0001) substrates by pulsed laser deposition (PLD) with the {111} planes of YSZ/GZO along the Al2O3 [0 1 ?1 0] direction. The tensile strain (3%) resulting from the lattice mismatch can be confined in individual YSZ layers with the formation of a coherent, dislocation-free interface upon the manipulation of the layer thickness below a critical value, e.g., down to 5 nm. The strained heterostructure displays a two order-of-magnitude increase in oxide-ion conductivity as compared with bulk YSZ, and a high ionic conductivity of 0.01 S cm?1 at 475 C can be achieved, five times greater than that of Gd-doped ceria/zirconia. The approach of strain confinement by fine control of lattice mismatch and layer thickness represents a promising strategy in developing advanced electrolytes enabling the miniaturization of solid-state ionic devices that can be operated at low temperatures below 500 C.

  15. Fuel cell generator energy dissipator

    DOEpatents

    Veyo, Stephen Emery; Dederer, Jeffrey Todd; Gordon, John Thomas; Shockling, Larry Anthony

    2000-01-01

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a fuel cell generator when the electrical power output of the fuel cell generator is terminated. During a generator shut down condition, electrically resistive elements are automatically connected across the fuel cell generator terminals in order to draw current, thereby depleting the fuel

  16. Creep Behavior of Glass/Ceramic Sealant and its Effect on Long-term Performance of Solid Oxide Fuel Cells

    SciTech Connect

    Liu, Wenning N.; Sun, Xin; Koeppel, Brian J.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2009-10-14

    The creep behavior of glass or glass-ceramic sealant materials used in solid oxide fuel cells (SOFCs) becomes relevant under SOFC operating temperatures. In this paper, the creep of glass-ceramic sealants was experimentally examined, and a standard linear solid model was applied to capture the creep behavior of glass ceramic sealant materials developed for planar SOFCs at high temperatures. The parameters of this model were determined based on the creep test results. Furthermore, the creep model was incorporated into finite-element software programs SOFC-MP and Mentat-FC developed at Pacific Northwest National Laboratory for multi-physics simulation of SOFCs. The effect of creep of glass ceramic sealant materials on the long-term performance of SOFC stacks was investigated by studying the stability of the flow channels and the stress redistribution in the glass seal and on the various interfaces of the glass seal with other layers. Finite element analyses were performed to quantify the stresses in various parts. The stresses in glass seals were released because of creep behavior during operations.

  17. Development of Ni1-xCoxO as the cathode/interconnect contact for solid oxide fuel cells

    SciTech Connect

    Lu, Zigui; Xia, Guanguang; Templeton, Joshua D.; Li, Xiaohong S.; Nie, Zimin; Yang, Zhenguo; Stevenson, Jeffry W.

    2011-06-01

    A new type of material, Ni1-xCoxO, was developed for solid oxide fuel cell (SOFC) cathode/interconnect contact applications. The phase structure, coefficient of thermal expansion, sintering behavior, electrical property, and mechanical bonding strength of these materials were evaluated against the requirements of the SOFC cathode/interconnect contact. A dense cathode/interconnect contact layer was developed through reaction sintering from Ni and Co metal powders. An area specific resistance (ASR) as low as 5.5 mohm.cm2 was observed after 1000 h exposure in air at 800 C for the LSM/Ni0.33Co0.67O/AISI441 assembly. Average mechanical strengths of 6.8 and 5.0 MPa were obtained for the cathode/contact/cathode and interconnect/contact/interconnect structures, respectively. The significantly low ASR was probably due to the dense structure and therefore improved electrical conductivity of the Ni0.33Co0.67O contact and the good bonding of the interfaces between the contact and the cathode, and between the contact and the interconnect.

  18. Characterization of Cr poisoning in a solid oxide fuel cell cathode using a high-energy x-ray microbeam.

    SciTech Connect

    Liu, D. J.; Almer, J.; Cruse, T.

    2010-01-01

    A key feature of planar solid oxide fuel cells (SOFCs) is the feasibility of using metallic interconnects made of high temperature ferritic stainless steels, which reduce system cost while providing excellent electric conductivity. Such interconnects, however, contain high levels of chromium, which has been found to be associated with SOFC cathode performance degradation at SOFC operating temperatures; a phenomenon known as Cr poisoning. Here, we demonstrate an accurate measurement of the phase and concentration distributions of Cr species in a degraded SOFC, as well as related properties including deviatoric strain, integrated porosity, and lattice parameter variation, using high energy microbeam X-ray diffraction and radiography. We unambiguously identify (MnCr){sub 3}O{sub 4} and Cr{sub 2}O{sub 3} as the two main contaminant phases and find that their concentrations correlate strongly with the cathode layer composition. Cr{sub 2}O{sub 3} deposition within the active cathode region reduces porosity and produces compressive residual strains, which hinders the reactant gas percolation and can cause structural breakdown of the SOFC cathode. The information obtained through this study can be used to better understand the Cr-poisoning mechanism and improve SOFC design.

  19. Three-dimensional microstructural changes in the NiYSZ solid oxide fuel cell anode during operation

    SciTech Connect

    Nelson G. J.; Chu Y.; Grew, K.N.; Izzo Jr. J.R.; Lombardo, J.J.; Harris, W.M.; Faes, A.; Hessler-Wyser, A.; Van herle, J.; Wang, S.; Virkar, A.V.; Chiu, W.K.S.

    2012-04-07

    Microstructural evolution in solid oxide fuel cell (SOFC) cermet anodes has been investigated using X-ray nanotomography along with differential absorption imaging. SOFC anode supports composed of Ni and yttria-stabilized zirconia (YSZ) were subjected to extended operation and selected regions were imaged using a transmission X-ray microscope. X-ray nanotomography provides unique insight into microstructure changes of all three phases (Ni, YSZ, pore) in three spatial dimensions, and its relation to performance degradation. Statistically significant 3D microstructural changes were observed in the anode Ni phase over a range of operational times, including phase size growth and changes in connectivity, interfacial contact area and contiguous triple-phase boundary length. These observations support microstructural evolution correlated to SOFC performance. We find that Ni coarsening is driven by particle curvature as indicated by the dihedral angles between the Ni, YSZ and pore phases, and hypothesize that growth occurs primarily by means of diffusion and particle agglomeration constrained by a pinning mechanism related to the YSZ phase. The decrease in Ni phase size after extended periods of time may be the result of a second process connected to a mobility-induced decrease in the YSZ phase size or non-uniform curvature resulting in a net decrease in Ni phase size.

  20. Soft X-Ray Spectroscopic Study of Dense Strontium-Doped Lanthanum Manganite Cathodes for Solid Oxide Fuel Cell Applications

    SciTech Connect

    L Piper; A Preston; S Cho; A DeMasi; J Laverock; K Smith; L Miara; J Davis; S Basu; et al.

    2011-12-31

    The evolution of the Mn charge state, chemical composition, and electronic structure of La{sub 0.8}Sr{sub 0.2}MnO{sub 3} (LSMO) cathodes during the catalytic activation of solid oxide fuel cell (SOFC) has been studies using X-ray spectroscopy of as-processed, exposed, and activated dense thin LSMO films. Comparison of O K-edge and Mn L{sub 3,2}-edge X-ray absorption spectra from the different stages of LSMO cathodes revealed that the largest change after the activation occurred in the Mn charge state with little change in the oxygen environment. Core-level X-ray photoemission spectroscopy and Mn L{sub 3} resonant photoemission spectroscopy studies of exposed and as-processed LSMO determined that the SOFC environment (800 C ambient pressure of O{sub 2}) alone results in La deficiency (severest near the surface with Sr doping >0.55) and a stronger Mn{sup 4+} contribution, leading to the increased insulating character of the cathode prior to activation. Meanwhile, O K-edge X-ray absorption measurements support Sr/La enrichment nearer the surface, along with the formation of mixed Sr{sub x}Mn{sub y}O{sub z} and/or passive MnO{sub x} and SrO species.

  1. Long-term oxidation behavior of spinel-coated ferritic stainless steel for solid oxide fuel cell interconnect applications

    SciTech Connect

    Stevenson, Jeffry W.; Yang, Zhenguo; Xia, Guanguang; Nie, Zimin; Templeton, Joshua D.

    2013-06-01

    Long-term tests (>8,000 hours) indicate that AISI 441 ferritic stainless steel coated with a Mn-Co spinel protection layer is a promising candidate material system for IT-SOFC interconnect applications. While uncoated AISI 441 showed a substantial increase in area-specific electrical resistance (ASR), spinel-coated AISI 441 exhibited much lower ASR values (11-13 mOhm-cm2). Formation of an insulating silica sublayer beneath the native chromia-based scale was not observed, and the spinel coatings reduced the oxide scale growth rate and blocked outward diffusion of Cr from the alloy substrate. The structure of the scale formed under the spinel coatings during the long term tests differed from that typically observed on ferritic stainless steels after short term oxidation tests. While short term tests typically indicate a dual layer scale structure consisting of a chromia layer covered by a layer of Mn-Cr spinel, the scale grown during the long term tests consisted of a chromia matrix with discrete regions of Mn-Cr spinel distributed throughout the matrix. The presence of Ti in the chromia scale matrix and/or the presence of regions of Mn-Cr spinel within the scale may have increased the scale electrical conductivity, which would explain the fact that the observed ASR in the tests was lower than would be expected if the scale consisted of pure chromia.

  2. DOE Fuel Cell Technologies Program Record, Record # 11003, Fuel...

    Energy Saver

    Program Record, Record 11003, Fuel Cell Stack Durability DOE Fuel Cell Technologies Program Record, Record 11003, Fuel Cell Stack Durability Dated May 3, 2012, this program ...

  3. Fuel cell system with combustor-heated reformer

    DOEpatents

    Pettit, William Henry

    2000-01-01

    A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

  4. Hydrogen Fuel Cell Demonstration ...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Brothers, Ltd., at their facility in the Port of Honolulu. The pilot hydrogen fuel cell unit will be used in place of a diesel generator currently used to provide power for...

  5. Small-Scale Low Cost Solid Oxide Fuel Cell Power Systems

    SciTech Connect

    S.D. Vora

    2005-09-30

    Tasks carried out during the reporting period March 2005-August 2005 are summarized. During this reporting period, the primary focus was on tasks leading to the fabrication of a proof-of-concept (POC) unit with HPD5R1 cells. Assembly of the POC unit was completed and the initial operation was started. Optimization of HPD cell design, investigation of scandia doped zirconia and low temperature operation of YSZ electrolyte based cells continued. Development of seal to be used in a ''once-thru'' design or an ''up-down'' design was started. Attachment 1 describes the progress in cell development and Attachments 2 and 3 deal with status of generator and BOP design. Operation of POC is summarized in Attachment 4. Plans for future work are summarized in Attachment 5.

  6. BCA Perspective on Fuel Cell APUs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    BCA Perspective on Fuel Cell APUs BCA Perspective on Fuel Cell APUs Presentation at DOE-DOE Aircraft Petroleum Use Reduction Workshop, September 30, 2010 aircraft_6_breit.pdf (1.55 MB) More Documents & Publications Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board Commercial Airplanes Report of the DOE-DOE Workshop on Fuel Cells in Aviation: Workshop Summary and Action Plan Electrical Generation for More-Electric Aircraft using Solid Oxide Fuel Cells

  7. Rapidly refuelable fuel cell

    DOEpatents

    Joy, Richard W. (Santa Clara, CA)

    1983-01-01

    This invention is directed to a metal-air fuel cell where the consumable metal anode is movably positioned in the cell and an expandable enclosure, or bladder, is used to press the anode into contact with separating spacers between the cell electrodes. The bladder may be depressurized to allow replacement of the anode when consumed.

  8. Ceramic Fuel Cells (SOFC)

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    H2/FC Manufacturing R&D Workshop J. David Carter, PhD Chemical Sciences and Engineering Argonne National Laboratory Thursday, August 11, 2011 Ceramic Fuel Cells (SOFC) Manufacturing Fuel Cell Manhattan Project: * Joe Bonadies - Delphi * Rick Kerr - Delphi * David Carter - Argonne * Aaron Crumm - AMI * Randy Petri - Versa Power * Jolyon Rawson - Acumentrics * Marc Gietter - Army-CERDEC * Scott Swartz - NexTech Materials * Eric Stanfield - NIST * Mike Ulsh - NREL / DOE * Matt Steinbroner -

  9. Financing Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    organized by: ◦ US Department of Energy Fuel Cell Technologies Program ◦ Clean Energy States Alliance ◦ Technology Transition Corporation  Also briefing papers and materials for state policymakers and others on the Hydrogen and Fuel Cells Project page at www.cleanenergystates.org 2  A nonprofit coalition of state and sub-national clean energy funds and programs working together to develop and promote clean energy technologies and markets. www.cleanenergystates.org 3  For more

  10. Fuel Cells at NASCAR

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cells at NASCAR Ned Stetson U.S. Department of Energy Fuel Cell Technologies Office Catherine Kummer - NASCAR Green Norm Bessette - Acumentrics Question and Answer * Please type your question into the question box hydrogenandfuelcells.energy.gov 3 Selected Milestone Accomplishments * 5 years of NASCAR Green with now most impactful sustainability platform in history of U.S. based on numbers; most impactful in sports * 75% of avid NASCAR fans are now aware of NASCAR green and believe the

  11. Fuel Cells in Telecommunications

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cells Simply Powerful Fuel Cells in Telecommunications J. Blanchard December 2011 - ~ ReliOn Overview Markets Backup, grid supplement, and off grid power systems for critical communications infrastructure spanning telecom, transportation, government, utility, and OEM customers throughout the world. Products Purpose designed product portfolio of 175W to 2.5kW building blocks providing solutions up to 30kW for target markets. Broad range of hydrogen storage solutions supported by major

  12. Compliant fuel cell system

    DOEpatents

    Bourgeois, Richard Scott; Gudlavalleti, Sauri

    2009-12-15

    A fuel cell assembly comprising at least one metallic component, at least one ceramic component and a structure disposed between the metallic component and the ceramic component. The structure is configured to have a lower stiffness compared to at least one of the metallic component and the ceramic component, to accommodate a difference in strain between the metallic component and the ceramic component of the fuel cell assembly.

  13. Composite fuel cell membranes

    DOEpatents

    Plowman, Keith R. (Lake Jackson, TX); Rehg, Timothy J. (Lake Jackson, TX); Davis, Larry W. (West Columbia, TX); Carl, William P. (Marble Falls, TX); Cisar, Alan J. (Cypress, TX); Eastland, Charles S. (West Columbia, TX)

    1997-01-01

    A bilayer or trilayer composite ion exchange membrane suitable for use in a fuel cell. The composite membrane has a high equivalent weight thick layer in order to provide sufficient strength and low equivalent weight surface layers for improved electrical performance in a fuel cell. In use, the composite membrane is provided with electrode surface layers. The composite membrane can be composed of a sulfonic fluoropolymer in both core and surface layers.

  14. Composite fuel cell membranes

    DOEpatents

    Plowman, K.R.; Rehg, T.J.; Davis, L.W.; Carl, W.P.; Cisar, A.J.; Eastland, C.S.

    1997-08-05

    A bilayer or trilayer composite ion exchange membrane is described suitable for use in a fuel cell. The composite membrane has a high equivalent weight thick layer in order to provide sufficient strength and low equivalent weight surface layers for improved electrical performance in a fuel cell. In use, the composite membrane is provided with electrode surface layers. The composite membrane can be composed of a sulfonic fluoropolymer in both core and surface layers.

  15. Iridium−Ruthenium Alloyed Nanoparticles for the Ethanol Oxidation Fuel Cell Reactions

    SciTech Connect

    Su D.; Du, W.; Deskins, N.A.; Teng, X.

    2012-06-01

    In this study, carbon supported Ir-Ru nanoparticles with average sizes ranging from 2.9 to 3.7 nm were prepared using a polyol method. The combined characterization techniques, that is, scanning transmission electron microscopy equipped with electron energy loss spectroscopy, high resolution transmission electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction, were used to determine an Ir-Ru alloy nanostructure. Both cyclic voltammetry and chronoamperometry (CA) results demonstrate that Ir{sub 77}Ru{sub 23}/C bears superior catalytic activities for the ethanol oxidation reaction compared to Ir/C and commercial Pt/C catalysts. In particular, the Ir{sub 77}Ru{sub 23}/C catalyst shows more than 21 times higher mass current density than that of Pt/C after 2 h reaction at a potential of 0.2 V vs Ag/AgCl in CA measurement. Density functional theory simulations also demonstrate the superiority of Ir-Ru alloys compared to Ir for the ethanol oxidation reaction.

  16. Maritime Hydrogen Fuel Cell project

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... SunShot Grand Challenge: Regional Test Centers Maritime Hydrogen Fuel Cell project HomeTag:Maritime Hydrogen Fuel Cell project - Pete Devlin, of the Department of Energy's Fuel ...

  17. Energy conversion with solid oxide fuel cell systems: A review of concepts amd outlooks for the short- and long-term

    SciTech Connect

    Adams, II, Thomas A.; Nease, Jake; Tucker, David; Barton, Paul I.

    2013-01-01

    A review of energy conversion systems which use solid oxide fuel cells (SOFCs) as their primary electricity generation component is presented. The systems reviewed are largely geared for development and use in the short- and long-term future. These include systems for bulk power generation, distributed power generation, and systems integrated with other forms of energy conversion such as fuel production. The potential incorporation of CO{sub 2} capture and sequestration technologies and the influences of potential government policies are also discussed.

  18. Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cells Fuel Cells A fuel cell uses the chemical energy of hydrogen or another fuel to cleanly and efficiently produce electricity. If hydrogen is the fuel, electricity, water, and heat are the only products. Fuel cells are unique in terms of the variety of their potential applications; they can provide power for systems as large as a utility power station and as small as a laptop computer. Why Study Fuel Cells Fuel cells can be used in a wide range of applications, including transportation,

  19. Fuel dissipater for pressurized fuel cell generators

    DOEpatents

    Basel, Richard A.; King, John E.

    2003-11-04

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a pressurized fuel cell generator (10) when the electrical power output of the fuel cell generator is terminated during transient operation, such as a shutdown; where, two electrically resistive elements (two of 28, 53, 54, 55) at least one of which is connected in parallel, in association with contactors (26, 57, 58, 59), a multi-point settable sensor relay (23) and a circuit breaker (24), are automatically connected across the fuel cell generator terminals (21, 22) at two or more contact points, in order to draw current, thereby depleting the fuel inventory in the generator.

  20. Fuel Cells and Renewable Gaseous Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cells and Renewable Gaseous Fuels Fuel Cells and Renewable Gaseous Fuels Breakout Session 3-C: Renewable Gaseous Fuels Fuel Cells and Renewable Gaseous Fuels Sarah Studer, ORISE Fellow-Fuel Cell Technologies Office, U.S. Department of Energy studer_bioenergy_2015.pdf (2 MB) More Documents & Publications Workshop on Gas Clean-Up for Fuel Cell Applications U.S Department of Energy Fuel Cell Technologies Office Overview: 2015 Smithsonian Science Education Academies for Teachers Novel

  1. DEVELOPMENT OF ELECTROCHEMICAL REDUCTION TECHNOLOGY FOR SPENT OXIDE FUELS

    SciTech Connect

    Hur, Jin-Mok; Seo, Chung-Seok; Kim, Ik-Soo; Hong, Sun-Seok; Kang, Dae-Seung; Park, Seong-Won

    2003-02-27

    The Advanced Spent Fuel Conditioning Process (ACP) has been under development at Korea Atomic Energy Research Institute (KAERI) since 1997. The concept is to convert spent oxide fuel into metallic form and to remove high heat-load fission products such as Cs and Sr from the spent fuel. The heat power, volume, and radioactivity of spent fuel can decrease by a factor of a quarter via this process. For the realization of ACP, a concept of electrochemical reduction of spent oxide fuel in Li2O-LiCl molten salt was proposed and several cold tests using fresh uranium oxides have been carried out. In this new electrochemical reduction process, electrolysis of Li2O and reduction of uranium oxide are taking place simultaneously at the cathode part of electrolysis cell. The conversion of uranium oxide to uranium metal can reach more than 99% ensuring the feasibility of this process.

  2. Fuel cell anode configuration for CO tolerance

    DOEpatents

    Uribe, Francisco A.; Zawodzinski, Thomas A.

    2004-11-16

    A polymer electrolyte fuel cell (PEFC) is designed to operate on a reformate fuel stream containing oxygen and diluted hydrogen fuel with CO impurities. A polymer electrolyte membrane has an electrocatalytic surface formed from an electrocatalyst mixed with the polymer and bonded on an anode side of the membrane. An anode backing is formed of a porous electrically conductive material and has a first surface abutting the electrocatalytic surface and a second surface facing away from the membrane. The second surface has an oxidation catalyst layer effective to catalyze the oxidation of CO by oxygen present in the fuel stream where at least the layer of oxidation catalyst is formed of a non-precious metal oxidation catalyst selected from the group consisting of Cu, Fe, Co, Tb, W, Mo, Sn, and oxides thereof, and other metals having at least two low oxidation states.

  3. 2009 Fuel Cell Market Report

    SciTech Connect

    Vincent, Bill; Gangi, Jennifer; Curtin, Sandra; Delmont, Elizabeth

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  4. Seventh Edition Fuel Cell Handbook

    SciTech Connect

    NETL

    2004-11-01

    Provides an overview of fuel cell technology and research projects. Discusses the basic workings of fuel cells and their system components, main fuel cell types, their characteristics, and their development status, as well as a discussion of potential fuel cell applications.

  5. Breakthrough Vehicle Development - Fuel Cells

    Publication and Product Library

    Document describing research and development program for fuel cell power systems for transportation applications.

  6. SOFC cells and stacks for complex fuels

    SciTech Connect

    Edward M. Sabolsky; Matthew Seabaugh; Katarzyna Sabolsky; Sergio A. Ibanez; Zhimin Zhong

    2007-07-01

    Reformed hydrocarbon and coal (syngas) fuels present an opportunity to integrate solid oxide fuel cells into the existing fuel infrastructure. However, these fuels often contain impurities or additives that may lead to cell degradation through sulfur poisoning or coking. Achieving high performance and sulfur tolerance in SOFCs operating on these fuels would simplify system balance of plant and sequestration of anode tail gas. NexTech Materials, Ltd., has developed a suite of materials and components (cells, seals, interconnects) designed for operation in sulfur-containing syngas fuels. These materials and component technologies have been integrated into an SOFC stack for testing on simulated propane, logistic fuel reformates and coal syngas. Details of the technical approach, cell and stack performance is reported.

  7. Performance of Anode-Supported Solid Oxide Fuel Cell with Thin Bi-Layer Electrolyte by Pulsed Laser Deposition

    SciTech Connect

    Lu, Zigui; Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.; Fisher, Daniel; Wu, Naijuan; Ignatiev, Alex

    2012-07-15

    Anode-supported yttria stabilized zirconia (YSZ)/samaria doped ceria (SDC) bi-layer electrolytes with uniform thickness and high density were fabricated by pulsed laser deposition at 1000 degrees C. Fuel cells with such bi-layer electrolytes were fabricated and tested, yielding open circuit voltages from 0.94 to 1.0 V at 600-700 degrees C. Power densities from 0.4 to 1.0 W cm{sup -2} at 0.7 V were achieved in air at temperatures of 600-700 degrees C. Cell performance was improved in flowing oxygen, with an estimated peak power density of over 2 W cm{sup -2} at 650 degrees C, assuming the same overall resistance over the entire range of current density. The high cell performance was attributed to the very low ohmic resistance of the fuel cell, owing to the small thickness of the electrolyte. Stable performance was also demonstrated in that the voltage of the fuel cell showed very little change at a constant current density of 1 A cm{sup -2} during more than 400 hours of operation at 650 degrees C in flowing oxygen. SEM analysis of the fuel cell after testing showed that the bi-layer electrolyte had retained its chemical and mechanical integrity.

  8. Fuel Processors for PEM Fuel Cells

    SciTech Connect

    Levi T. Thompson

    2008-08-08

    Fuel cells are being developed to power cleaner, more fuel efficient automobiles. The fuel cell technology favored by many automobile manufacturers is PEM fuel cells operating with H2 from liquid fuels like gasoline and diesel. A key challenge to the commercialization of PEM fuel cell based powertrains is the lack of sufficiently small and inexpensive fuel processors. Improving the performance and cost of the fuel processor will require the development of better performing catalysts, new reactor designs and better integration of the various fuel processing components. These components and systems could also find use in natural gas fuel processing for stationary, distributed generation applications. Prototype fuel processors were produced, and evaluated against the Department of Energy technical targets. Significant advances were made by integrating low-cost microreactor systems, high activity catalysts, π-complexation adsorbents, and high efficiency microcombustor/microvaporizers developed at the University of Michigan. The microreactor system allowed (1) more efficient thermal coupling of the fuel processor operations thereby minimizing heat exchanger requirements, (2) improved catalyst performance due to optimal reactor temperature profiles and increased heat and mass transport rates, and (3) better cold-start and transient responses.

  9. Supporting electrodes for solid oxide fuel cells and other electrochemical devices

    DOEpatents

    Sprenkle, Vincent L. (Richland, WA); Canfield, Nathan L. (Kennewick, WA); Meinhardt, Kerry (Kennewick, WA); Stevenson, Jeffry W. (Richland, WA)

    2008-04-01

    An electrode supported electrolyte membrane includes an electrode layer 630 facing an electrolyte layer 620. The opposing side of the electrode layer 630 includes a backing layer 640 of a material with a thermal expansion coefficient approximately equal to the thermal expansion coefficient of the electrolyte layer 620. The backing layer 640 is in a two dimensional pattern that covers only a portion of the electrolyte layer 630. An electrochemical cell such as a SOFC is formed by providing a cathode layer 610 on an opposing side of the electrolyte layer 620.

  10. Fuel Cell Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Cells » Fuel Cell Systems Fuel Cell Systems The design of fuel cell systems is complex, and can vary significantly depending upon fuel cell type and application. However, several basic components are found in many fuel cell systems: Fuel cell stack Fuel processor Power conditioners Air compressors Humidifiers Fuel Cell Stack The fuel cell stack is the heart of a fuel cell power system. It generates electricity in the form of direct current (DC) from electro-chemical reactions that take place in

  11. Fuel cell system

    DOEpatents

    Early, Jack; Kaufman, Arthur; Stawsky, Alfred

    1982-01-01

    A fuel cell system is comprised of a fuel cell module including sub-stacks of series-connected fuel cells, the sub-stacks being held together in a stacked arrangement with cold plates of a cooling means located between the sub-stacks to function as electrical terminals. The anode and cathode terminals of the sub-stacks are connected in parallel by means of the coolant manifolds which electrically connect selected cold plates. The system may comprise a plurality of the fuel cell modules connected in series. The sub-stacks are designed to provide a voltage output equivalent to the desired voltage demand of a low voltage, high current DC load such as an electrolytic cell to be driven by the fuel cell system. This arrangement in conjunction with switching means can be used to drive a DC electrical load with a total voltage output selected to match that of the load being driven. This arrangement eliminates the need for expensive voltage regulation equipment.

  12. Fuel processor for fuel cell power system

    DOEpatents

    Vanderborgh, Nicholas E.; Springer, Thomas E.; Huff, James R.

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  13. Fuel cell development for transportation: Catalyst development

    SciTech Connect

    Doddapaneni, N.; Ingersoll, D.

    1996-12-31

    Fuel cells are being considered as alternative power sources for transportation and stationary applications. The degradation of commonly used electrode catalysts (e.g. Pt, Ag, and others) and corrosion of carbon substrates are making commercialization of fuel cells incorporating present day technologies economically problematic. Furthermore, due to the instability of the Pt catalyst, the performance of fuel cells declines on long-term operation. When methanol is used as the fuel, a voltage drop, as well as significant thermal management problems can be encountered, the later being due to chemical oxidation of methanol at the platinized carbon at the cathode. Though extensive work was conducted on platinized electrodes for both the oxidation and reduction reactions, due to the problems mentioned above, fuel cells have not been fully developed for widespread commercial use. Several investigators have previously evaluated metal macrocyclic complexes as alternative catalysts to Pt and Pt/Ru in fuel cells. Unfortunately, though they have demonstrated catalytic activity, these materials were found to be unstable on long term use in the fuel cell environment. In order to improve the long-term stability of metal macrocyclic complexes, we have chemically bonded these complexes to the carbon substrate, thereby enhancing their catalytic activity as well as their chemical stability in the fuel cell environment. We have designed, synthesized, and evaluated these catalysts for O{sub 2} reduction, H{sub 2} oxidation, and direct methanol oxidation in Proton Exchange Membrane (PEM) and aqueous carbonate fuel cells. These catalysts exhibited good catalytic activity and long-term stability. In this paper we confine our discussion to the initial performance results of some of these catalysts in H{sub 2}/O{sub 2} PEM fuel cells, including their long-term performance characteristics as well as CO poisoning effects on these catalysts.

  14. NREL: Hydrogen and Fuel Cells Research - Fuel Cells

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Cells Photo of scientific equipment in a laboratory setting. NREL scientist applies catalyst layer to a fuel cell through a spray process that delivers a more even distribution of material, improving performance. Photo by Dennis Schroeder, NREL What is a fuel cell? A single fuel cell consists of an electrolyte sandwiched between two electrodes. Bipolar plates on either side of the cell help distribute gases and serve as current collectors. Depending on the application, a fuel cell stack may

  15. Solid polymer MEMS-based fuel cells

    DOEpatents

    Jankowski, Alan F.; Morse, Jeffrey D.

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  16. Energy 101: Fuel Cell Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Technology Energy 101: Fuel Cell Technology

  17. Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells

    SciTech Connect

    Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

    2011-12-11

    A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

  18. Fuel cell membranes and crossover prevention

    DOEpatents

    Masel, Richard I.; York, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2009-08-04

    A membrane electrode assembly for use with a direct organic fuel cell containing a formic acid fuel includes a solid polymer electrolyte having first and second surfaces, an anode on the first surface and a cathode on the second surface and electrically linked to the anode. The solid polymer electrolyte has a thickness t:.gtoreq..times..times..times..times. ##EQU00001## where C.sub.f is the formic acid fuel concentration over the anode, D.sub.f is the effective diffusivity of the fuel in the solid polymer electrolyte, K.sub.f is the equilibrium constant for partition coefficient for the fuel into the solid polymer electrolyte membrane, I is Faraday's constant n.sub.f is the number of electrons released when 1 molecule of the fuel is oxidized, and j.sub.f.sup.c is an empirically determined crossover rate of fuel above which the fuel cell does not operate.

  19. Fuel cell system combustor

    DOEpatents

    Pettit, William Henry

    2001-01-01

    A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode and cathode effluents. The combustor includes a turbulator section at its input end for intimately mixing the anode and cathode effluents before they contact the combustors primary catalyst bed. The turbulator comprises at least one porous bed of mixing media that provides a tortuous path therethrough for creating turbulent flow and intimate mixing of the anode and cathode effluents therein.

  20. DOE Hydrogen & Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    20 active fuel cell buses 60 fueling stations In the U.S., there are currently: 9 ... NAS study, "Transitions to Alternative Transportation Technologies: A Focus ...

  1. Fuel quality issues in stationary fuel cell systems.

    SciTech Connect

    Papadias, D.; Ahmed, S.; Kumar, R.

    2012-02-07

    Fuel cell systems are being deployed in stationary applications for the generation of electricity, heat, and hydrogen. These systems use a variety of fuel cell types, ranging from the low temperature polymer electrolyte fuel cell (PEFC) to the high temperature solid oxide fuel cell (SOFC). Depending on the application and location, these systems are being designed to operate on reformate or syngas produced from various fuels that include natural gas, biogas, coal gas, etc. All of these fuels contain species that can potentially damage the fuel cell anode or other unit operations and processes that precede the fuel cell stack. These detrimental effects include loss in performance or durability, and attenuating these effects requires additional components to reduce the impurity concentrations to tolerable levels, if not eliminate the impurity entirely. These impurity management components increase the complexity of the fuel cell system, and they add to the system's capital and operating costs (such as regeneration, replacement and disposal of spent material and maintenance). This project reviewed the public domain information available on the impurities encountered in stationary fuel cell systems, and the effects of the impurities on the fuel cells. A database has been set up that classifies the impurities, especially in renewable fuels, such as landfill gas and anaerobic digester gas. It documents the known deleterious effects on fuel cells, and the maximum allowable concentrations of select impurities suggested by manufacturers and researchers. The literature review helped to identify the impurity removal strategies that are available, and their effectiveness, capacity, and cost. A generic model of a stationary fuel-cell based power plant operating on digester and landfill gas has been developed; it includes a gas processing unit, followed by a fuel cell system. The model includes the key impurity removal steps to enable predictions of impurity breakthrough

  2. Fuel cell systems program plan, Fiscal year 1994

    SciTech Connect

    Not Available

    1994-07-01

    Goal of the fuel cell program is to increase energy efficiency and economic effectiveness through development and commercialization of fuel cell systems which operate on fossil fuels in multiple end use sectors. DOE is participating with the private sector in sponsoring development of molten carbonate fuel cells and solid oxide fuel cells for application in the utility, commercial, and industrial sectors. Commercialization of phosphoric acid fuel cells is well underway. Besides the introduction, this document is divided into: goal/objectives, program strategy, technology description, technical status, program description/implementation, coordinated fuel cell activities, and international activities.

  3. Internal reforming fuel cell assembly with simplified fuel feed

    SciTech Connect

    Farooque, Mohammad; Novacco, Lawrence J.; Allen, Jeffrey P.

    2001-01-01

    A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

  4. Development of PEM fuel cell technology at international fuel cells

    SciTech Connect

    Wheeler, D.J.

    1996-04-01

    The PEM technology has not developed to the level of phosphoric acid fuel cells. Several factors have held the technology development back such as high membrane cost, sensitivity of PEM fuel cells to low level of carbon monoxide impurities, the requirement to maintain full humidification of the cell, and the need to pressurize the fuel cell in order to achieve the performance targets. International Fuel Cells has identified a hydrogen fueled PEM fuel cell concept that leverages recent research advances to overcome major economic and technical obstacles.

  5. Careers in Fuel Cell Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Careers In Fuel Cell Technologies Existing and emerging fuel cell applications hold large job growth potential. Fuel cells are among the promising technologies that are expected to transform our energy sector. They represent highly efficient and fuel- flexible technologies that offer diverse benefits. For example, fuel cells can be used in a wide range of applications- from portable electronics, to combined heat and power (CHP) units used for distributed electricity generation, to passenger

  6. Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells

    SciTech Connect

    Lee, You-Kee; Kim, Jung-Yeul; Lee, Young-Ki; Kim, Insoo; Moon, Hee-Soo; Park, Jong-Wan; Jacobson, Craig P.; Visco, Steven J.

    2002-12-06

    Composite cathodes of 50/50 vol percent LSM-YSZ (La1-xSrxMnO3-yttria stabilized zirconia) were deposited onto dense YSZ electrolytes by a colloidal deposition technique. The cathode characteristics were then examined by scanning electron microscopy (SEM) and studied by an impedance spectroscopy (IS). Conditioning effects of the LSM-YSZ cathodes were seen, and remedies for these effects were proposed for improving the performance of a solid oxide fuel cell (SOFC). LSM surface contamination and modification, cathode bonding to the YSZ electrolyte, changing Pt electrode and bonding paste, and curvature of sintered YSZ electrolytes led to some changes in microstructure and variability in cell performances.

  7. California Fuel Cell Partnership: Alternative Fuels Research | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Fuel Cell Partnership: Alternative Fuels Research California Fuel Cell Partnership: Alternative Fuels Research This presentation by Chris White of the California Fuel Cell Partnership provides information about alternative fuels research. cafcp_initiatives_call.pdf (133.97 KB) More Documents & Publications The Department of Energy Hydrogen and Fuel Cells Program Plan Vehicle Technologies Office Merit Review 2015: Alternative Fuel Station Locator Fuel Cell Buses in U.S. Transit

  8. Fuel Cells Go Live

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    green h y d r o g e n f u e l i n g POWer Fuel Cells Go live A closer look at the requirements to create a hydrogen-based warehouse M anagers of distribution centers are always on the lookout for new ways to gain competitive advantage through increased operational efficiency, productivity and worker safety. Around North America, some are finding success by integrating commercially available hydrogen fuel cell systems into their lift truck fleets. For operations with large fleets of electric lift

  9. Treatment of Fuel Process Wastewater Using Fuel Cells - Energy...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Treatment of Fuel Process Wastewater Using Fuel Cells Oak Ridge National Laboratory Contact ORNL ...

  10. Cathode preparation method for molten carbonate fuel cell

    DOEpatents

    Smith, James L.; Sim, James W.; Kucera, Eugenia H.

    1988-01-01

    A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

  11. Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5/2011 eere.energy.gov 5 th International Conference on Polymer Batteries & Fuel Cells Argonne, Illinois Hydrogen and Fuel Cell Activities Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager August 4, 2011 2 | Fuel Cell Technologies Program Source: US DOE 8/5/2011 eere.energy.gov Fuel Cells: Benefits & Market Potential The Role of Fuel Cells Key Benefits Very High Efficiency Reduced CO 2 Emissions * 35-50%+ reductions for CHP systems (>80% with

  12. Performance of Ni-Fe/gadolinium-doped CeO{sub2} anode supported tubular solid oxide fuel cells using steam reforming of methane

    SciTech Connect

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-03-15

    Iron nanoparticles (Fe{sub 2}O{sub 3}) were added to NiO/gadolinium-doped CeO{sub 2} (GDC) anode supported solid oxide fuel cell (SOFC) for the direct methane-water fuel operation. The cell was co-sintered at 1400 C, and the anode porosity is 31.8%. The main size corresponding to peak volume is around 1.5 {mu}m. When steam and methane directly fed to the cell, the power density is about 0.57 W cm{sup -2} at 650 C. It is the familiar performance for H{sub 2} operation (4 times of flow rate) with same fuel utilization. Compare with the testing temperature of 600 and 650 C, there is almost no carbon fiber deposition at 700 C with steam/methane (S/C) of 5. At the same time, fuel operation of high value of S/C (=3.3) resulted in fiber-like deposition and degradation of power performance based on loading test results.

  13. Palladium-based electrocatalysts and fuel cells employing such electrocatalysts

    DOEpatents

    Masel; Richard I. , Zhu; Yimin , Larsen; Robert T.

    2010-08-31

    A direct organic fuel cell includes a fluid fuel comprising formic acid, an anode having an electrocatalyst comprising palladium nanoparticles, a fluid oxidant, a cathode electrically connected to the anode, and an electrolyte interposed between the anode and the cathode.

  14. Gore Fuel Cell Technologies | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Gore Fuel Cell Technologies Jump to: navigation, search Name: Gore Fuel Cell Technologies Place: Elkton, Maryland Zip: 21922-1488 Product: Gore Fuel Cell Technologies supplies the...

  15. Hydra Fuel Cell Corporation | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Fuel Cell Corporation Jump to: navigation, search Name: Hydra Fuel Cell Corporation Place: Beaverton, Oregon Product: Holding company for American Security Resources' fuel cell...

  16. Cornell Fuel Cell Institute | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Cornell Fuel Cell Institute Jump to: navigation, search Name: Cornell Fuel Cell Institute Place: Ithaca, New York Zip: 14850 Product: The Cornell Fuel Cell Institute (CFCI)...

  17. Fuel Cell Power | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Fuel Cell Power Place: United Kingdom Product: Information provider of fuel cells and their supporting infrastructure. References: Fuel Cell Power1 This article is a stub. You...

  18. US Fuel Cell Council | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    US Fuel Cell Council Place: Washington DC, Washington, DC Zip: Washington Product: US Fuel Cell Council is a membership association of fuel cell industry dedicated to fostering the...

  19. Cabot Fuel Cells | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Cabot Fuel Cells Jump to: navigation, search Name: Cabot Fuel Cells Place: Albuquerque, New Mexico Zip: 87113 Product: Cabot develops and manufactures advanced fuel cell...

  20. Hydrogen and Fuel Cells Success Stories

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    71 Hydrogen and Fuel Cells Success Stories en Doosan Fuel Cell Takes Closed Plant to Full Production http:energy.goveeresuccess-storiesarticlesdoosan-fuel-cell-takes-closed-p...

  1. Financing Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cells Financing Fuel Cells Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Financing Fuel Cell Installations, August 30, 2011. ...

  2. Canadian Fuel Cell Commercialization Roadmap Update: Progress...

    OpenEI (Open Energy Information) [EERE & EIA]

    Fuel Cell Commercialization Roadmap Update: Progress of Canada's Hydrogen and Fuel Cell Industry Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Canadian Fuel Cell...

  3. DOE Hydrogen and Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U.S. Department of Energy Fuel Cell Technologies Program January 5, 2011 2 | ...

  4. DOE Hydrogen and Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U.S. Department of Energy Fuel Cell Technologies Program DOECESATTC Hydrogen and Fuel Cells Webinar December ...

  5. Overview of Hydrogen & Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Source: US DOE 2252011 eere.energy.gov Overview of Hydrogen & Fuel Cell Activities FUEL CELL TECHNOLOGIES PROGRAM IPHE - Stationary Fuel Cell Workshop Rick Farmer U.S. ...

  6. Methods of conditioning direct methanol fuel cells

    DOEpatents

    Rice, Cynthia; Ren, Xiaoming; Gottesfeld, Shimshon

    2005-11-08

    Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode assembly. In a second method, methanol is supplied to an anode surface of the membrane electrode assembly, allowed to cross over the polymer electrolyte membrane of the membrane electrode assembly to a cathode surface of the membrane electrode assembly, and an electrical current of polarity opposite to that in a functioning direct methanol fuel cell is drawn through the membrane electrode assembly, wherein methanol is oxidized at the cathode surface of the membrane electrode assembly while the catalyst on the anode surface is reduced. Surface oxides on the direct methanol fuel cell anode catalyst of the membrane electrode assembly are thereby reduced.

  7. Air Breathing Direct Methanol Fuel Cell

    DOEpatents

    Ren; Xiaoming

    2003-07-22

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  8. Fuel cell generator

    DOEpatents

    Makiel, Joseph M.

    1985-01-01

    A high temperature solid electrolyte fuel cell generator comprising a housing means defining a plurality of chambers including a generator chamber and a combustion products chamber, a porous barrier separating the generator and combustion product chambers, a plurality of elongated annular fuel cells each having a closed end and an open end with the open ends disposed within the combustion product chamber, the cells extending from the open end through the porous barrier and into the generator chamber, a conduit for each cell, each conduit extending into a portion of each cell disposed within the generator chamber, each conduit having means for discharging a first gaseous reactant within each fuel cell, exhaust means for exhausting the combustion product chamber, manifolding means for supplying the first gaseous reactant to the conduits with the manifolding means disposed within the combustion product chamber between the porous barrier and the exhaust means and the manifolding means further comprising support and bypass means for providing support of the manifolding means within the housing while allowing combustion products from the first and a second gaseous reactant to flow past the manifolding means to the exhaust means, and means for flowing the second gaseous reactant into the generator chamber.

  9. Fuel cell tubes and method of making same

    DOEpatents

    Borglum, Brian P.

    1999-11-30

    A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost. A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost.

  10. Organic fuel cells and fuel cell conducting sheets

    DOEpatents

    Masel, Richard I.; Ha, Su; Adams, Brian

    2007-10-16

    A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

  11. Fuel Cell Projects Kickoff Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Nancy Garland Acting Fuel Cells Team Leader DOE Hydrogen Program nancy.garland@ee.doe.gov February 13-14, 2007 Washington, DC Overview 9 Key Personnel 9 Fuel Cell Program 9 Key ...

  12. Fuel Cells & Renewable Portfolio Standards

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    by 2025. o Non solar renewable energy - 12% o Solar energy - 0.5% o Advanced energy - 12.5% History of Ohio RPS Why fuel cells and RPS * Ohio's robust fuel cell industry in 2008 ...

  13. 2009 Fuel Cell Market Report

    Publication and Product Library

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  14. Fuel Cell Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hydrogen Storage Technologies Roadmap Fuel Cell Technical Team Roadmap June 2013 This ... The Fuel Cell Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose ...

  15. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel Cell Technologies Program Overview Program Overview Richard Farmer Richard Farmer ... 2 t t F l ll ff hi hl ffi i di f l d Fuel Cells Address Our Key Energy Challenges ...

  16. Fuel Cell Technical Team Roadmap

    SciTech Connect

    2013-06-01

    The Fuel Cell Technical Team promotes the development of a fuel cell power system for an automotive powertrain that meets the U.S. DRIVE Partnership (United States Driving Research and Innovation for Vehicle efficiency and Energy sustainability) goals.

  17. Integrated gasification fuel cell (IGFC) demonstration test

    SciTech Connect

    Steinfeld, G.; Ghezel-Ayagh, H.; Sanderson, R.; Abens, S.

    2000-07-01

    As concern about the environment generates interest in ultra-clean energy plants, fuel cell power plants can respond to the challenge. Fuel cells convert hydrocarbon fuels to electricity at efficiencies exceeding conventional heat engine technologies while generating extremely low emissions. Emissions of SOx and NOx are expected to be well below current and anticipated future standards. Nitrogen oxides, a product of combustion, will be extremely low in this power plant because power is produced electrochemically rather than by combustion. Due to its higher efficiencies, a fuel cell power plant also produces less carbon dioxide. Fuel cells in combination with coal gasification, are an efficient and environmentally acceptable means to utilize the abundant coal reserves both in the US and around the world. To demonstrate this technology, FuelCell Energy, Inc. (FCE), is planning to build and test a 2-MW Fuel Cell Power Plant for operation on coal derived gas. This power plant is based on Direct Fuel Cell (DFC{trademark}) technology and will be part of a Clean Coal V IGCC project supported by the US DOE. A British Gas Lurgi (BGL) slagging fixed-bed gasification system with cold gas clean up is planned as part of a 400 MW IGCC power plant to provide a fuel gas slip stream to the fuel cell. The IGFC power plant will be built by Kentucky Pioneer Energy, A subsidiary of Global Energy, in Clark County, KY. This demonstration will result in the world's largest fuel cell power plant operating on coal derived gas. The objective of this test is to demonstrate fuel cell operation on coal derived gas at a commercial scale and to verify the efficiency and environmental benefits.

  18. Manufacturing Fuel Cell Manhattan Project

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    to DOE Fuel Cell Manufacturing Workshop 2011 John Christensen, PE NREL Consultant DOE Fuel Cell Market Transformation Support August 11, 2011 Manufacturing Fuel Cell Manhattan Project √ Identify manufacturing cost drivers to achieve affordability √ Identify best practices in fuel cell manufacturing technology √ Identify manufacturing technology gaps √ Identify FC projects to address these gaps MFCMP Objectives Completed Final Report due out Nov 2010 B2PCOE Montana Tech SME's Industry

  19. Hydrogen & Fuel Cells Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE)

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Joint Plenary

  20. Investigation into the effects of trace coal syn gas species on the performance of solid oxide fuel cell anodes, PhD. thesis, Russ College of Engineering and Technology of Ohio University

    SciTech Connect

    Trembly, J. P.

    2007-06-01

    Coal is the United States’ most widely used fossil fuel for the production of electric power. Coal’s availability and cost dictates that it will be used for many years to come in the United States for power production. As a result of the environmental impact of burning coal for power production more efficient and environmentally benign power production processes using coal are sought. Solid oxide fuel cells (SOFCs) combined with gasification technologies represent a potential methodology to produce electric power using coal in a much more efficient and cleaner manner. It has been shown in the past that trace species contained in coal, such as sulfur, severely degrade the performance of solid oxide fuel cells rendering them useless. Coal derived syngas cleanup technologies have been developed that efficiently remove sulfur to levels that do not cause any performance losses in solid oxide fuel cells. The ability of these systems to clean other trace species contained in syngas is not known nor is the effect of these trace species on the performance of solid oxide fuel cells. This works presents the thermodynamic and diffusion transport simulations that were combined with experimental testing to evaluate the effects of the trace species on the performance of solid oxide fuel cells. The results show that some trace species contained in coal will interact with the SOFC anode. In addition to the transport and thermodynamic simulations that were completed experimental tests were completed investigating the effect of HCl and AsH3 on the performance of SOFCs.