National Library of Energy BETA

Sample records for oil distillation downstream

  1. Distillate Fuel Oil Sales for Residential Use

    Energy Information Administration (EIA) (indexed site)

    End Use/ Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate Commercial - No. 2 Distillate Commercial - No. 2 Fuel Oil Commercial - Ultra Low Sulfur Diesel Commercial - Low Sulfur Diesel Commercial - High Sulfur Diesel Commercial - No. 4 Fuel Oil Commercial - Residual Fuel Oil Commercial - Kerosene Industrial - Distillate Fuel Oil Industrial - No. 1 Distillate Industrial - No. 2

  2. Adjusted Distillate Fuel Oil Sales for Residential Use

    Energy Information Administration (EIA) (indexed site)

    End Use Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate ...

  3. Apparatus for distilling shale oil from oil shale

    SciTech Connect

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  4. Table 10.24 Reasons that Made Distillate Fuel Oil Unswitchable...

    Annual Energy Outlook

    4 Reasons that Made Distillate Fuel Oil Unswitchable, 2006; Level: National Data; Row: ... Combinations of NAICS Distillate Fuel Oil Unswitchable Distillate Capable of ...

  5. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  6. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Energy Information Administration (EIA) (indexed site)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  7. Crude oil steam distillation in steam flooding. Final report

    SciTech Connect

    Wu, C.H.; Elder, R.B.

    1980-08-01

    Steam distillation yields of sixteen crude oils from various parts of the United States have been determined at a saturated steam pressure of 200 psig. Study made to investigate the effect of steam pressure (200 to 500 psig) on steam distillation yields indicates that the maximum yields of a crude oil may be obtained at 200 psig. At a steam distillation correlation factor (V/sub w//V/sub oi/) of 15, the determined steam distillation yields range from 12 to 56% of initial oil volume for the sixteen crude oils with gravity ranging from 12 to 40/sup 0/API. Regression analysis of experimental steam distillation yields shows that the boiling temperature (simulated distillation temperature) at 20% simulated distillation yield can predict the steam distillation yields reasonably well: the standard error ranges from 2.8 to 3.5% (in yield) for V/sub w//V/sub oi/ < 5 and from 3.5 to 4.5% for V/sub w//V/sub oi/ > 5. The oil viscosity (cs) at 100/sup 0/F can predict the steam distillation yields with standard error from 3.1 to 4.3%. The API gravity can predict the steam distillation yields with standard error from 4.4 to 5.7%. Characterization factor is an unsatisfactory correlation independent variable for correlation purpose.

  8. Distillate Fuel Oil Assessment for Winter 1996-1997

    Reports and Publications

    1997-01-01

    This article describes findings of an analysis of the current low level of distillate stocks which are available to help meet the demand for heating fuel this winter, and presents a summary of the Energy Information Administration's distillate fuel oil outlook for the current heating season under two weather scenarios.

  9. East Coast (PADD 1) Distillate Fuel Oil Imports

    Gasoline and Diesel Fuel Update

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 942 1,260 1,471 1,990 2000's 2,114 1,896 1,914 1,969 2,258 2,132 2,118 1,955 1,695 1,237 2010's 1,471 2,114 2,970 2,608 3,801 4,282

    Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending

  10. Total Adjusted Sales of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series ...

  11. Total Sales of Distillate Fuel Oil

    Energy Information Administration (EIA) (indexed site)

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series ...

  12. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOEpatents

    Ignasiak, Teresa; Strausz, Otto; Ignasiak, Boleslaw; Janiak, Jerzy; Pawlak, Wanda; Szymocha, Kazimierz; Turak, Ali A.

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  13. Atmospheric Crude Oil Distillation Operable Capacity

    Gasoline and Diesel Fuel Update

    4 Arizona - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S3. Summary statistics for natural gas - Arizona, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 1 1 1 0 1 Gas Wells 5 R 4 R 3 R 6 6 Production (million cubic feet) Gross

  14. Distillate Fuel Oil Refinery, Bulk Terminal, and Natural Gas Plant Stocks

    Gasoline and Diesel Fuel Update

    Product: Finished Motor Gasoline Reformulated Gasoline Conventional Gasoline Motor Gasoline Blending Comp. (MGBC) MGBC - Reformulated MGBC - Conventional Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Greater 500 ppm Residual Fuel Oil Propane/Propylene Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources &

  15. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  16. U.S. Distillate Fuel Oil and Kerosene Sales by End Use

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Distillate Fuel Oil and Kerosene Sales by End Use (Thousand Gallons) Area: U.S. East Coast ... Residential Distillate Fuel Oil 4,103,881 3,930,517 3,625,747 3,473,310 3,536,111 ...

  17. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  18. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    Energy Information Administration (EIA) (indexed site)

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

  19. Recent hydrocarbon developments in Latin America: Key issues in the downstream oil sector

    SciTech Connect

    Wu, K.; Pezeshki, S.

    1995-03-01

    This report discusses the following: (1) An overview of major issues in the downstream oil sector, including oil demand and product export availability, the changing product consumption pattern, and refineries being due for major investment; (2) Recent upstream developments in the oil and gas sector in Argentina, Bolivia, Brazil, Chile, Colombia, Ecuador, Mexico, Peru, Trinidad and Tobago, and Venezuela; (3) Recent downstream developments in the oil and gas sector in Argentina, Chile, Colombia, Ecuador, Mexico, Peru, Cuba, and Venezuela; (4) Pipelines in Argentina, Bolivia, Brazil, Chile, and Mexico; and (5) Regional energy balance. 4 figs., 5 tabs.

  20. ,,,,"Reasons that Made Distillate Fuel Oil Unswitchable"

    Energy Information Administration (EIA) (indexed site)

    4 Relative Standard Errors for Table 10.24;" " Unit: Percents." ,,,,"Reasons that Made Distillate Fuel Oil Unswitchable" " "," ",,,,,,,,,,,,," " ,,"Total Amount of ","Total Amount of","Equipment is Not","Switching","Unavailable ",,"Long-Term","Unavailable",,"Combinations of " "NAICS"," ","Distillate Fuel Oil","Unswitchable

  1. ,"New Mexico Sales of Distillate Fuel Oil by End Use"

    Energy Information Administration (EIA) (indexed site)

    Sales of Distillate Fuel Oil by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Sales of Distillate Fuel Oil by End Use",13,"Annual",2014,"6/30/1984" ,"Release Date:","12/22/2015" ,"Next Release Date:","Last Week of November 2016" ,"Excel

  2. ,"U.S. Adjusted Sales of Distillate Fuel Oil by End Use"

    Energy Information Administration (EIA) (indexed site)

    Distillate Fuel Oil by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Adjusted Sales of Distillate Fuel Oil by End Use",13,"Annual",2014,"6/30/1984" ,"Release Date:","12/22/2015" ,"Next Release Date:","Last Week of November 2016" ,"Excel File

  3. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect

    Eaton, Scott J; Bunting, Bruce G; Lewis Sr, Samuel Arthur; Fairbridge, Craig

    2009-01-01

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  4. U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use

    Energy Information Administration (EIA) (indexed site)

    Show Data By: End Use Product Area 2009 2010 2011 2012 2013 2014 View History Residential Distillate Fuel Oil 4,328,840 3,897,937 3,713,883 3,223,851 3,714,150 4,041,766 1984-2014 ...

  5. DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate

    Office of Energy Efficiency and Renewable Energy (EERE)

    The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy said today.

  6. ,,"Distillate Fuel Oil",,,"Alternative Energy Sources(b)"

    Energy Information Administration (EIA) (indexed site)

    ...med(c)","Switchable","Switchable","Receipts(d)","Gas","Fuel Oil","Coal","LPG","Breeze","Other(e)" ,,"Total United States" 311,"Food",20,42,22,70,30,52,0,58,0,70 311221," Wet Corn ...

  7. ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)"

    Energy Information Administration (EIA) (indexed site)

    ...med(d)","Switchable","Switchable","Receipts(e)","Gas","Fuel Oil","Coal","LPG","Breeze","Other(f)" ,,"Total United States" 311,"Food",8,15,9,21,19,18,0,27,0,41 311221," Wet Corn ...

  8. ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)"

    Energy Information Administration (EIA) (indexed site)

    ...med(d)","Switchable","Switchable","Receipts(e)","Gas","Fuel Oil","Coal","LPG","Breeze","Other(f)" ,,"Total United States" 311,"Food",9,24,10.6,52.6,26.8,32,"X",28.4,"X",32.7 3112," ...

  9. Texas Sales of Distillate Fuel Oil by End Use

    Energy Information Administration (EIA) (indexed site)

    ,329,790 5,693,270 6,373,078 6,688,629 6,914,481 7,837,118 1984-2014 Residential 67 28 127 102 16 59 1984-2014 Commercial 136,419 100,886 184,312 173,303 142,268 132,601 1984-2014 Industrial 189,981 197,024 233,292 241,601 240,179 270,760 1984-2014 Oil Company 210,865 316,523 541,640 736,186 679,737 886,957 1984-2014 Farm 201,769 207,183 243,170 216,915 190,572 222,849 1984-2014 Electric Power 19,495 15,646 23,156 20,022 20,706 24,700 1984-2014 Railroad 429,026 467,128 498,006 483,096 504,823

  10. Louisiana Sales of Distillate Fuel Oil by End Use

    Energy Information Administration (EIA) (indexed site)

    514,474 1,744,771 1,873,769 1,488,986 1,405,392 1,375,580 1984-2014 Residential 1,036 140 34 53 84 89 1984-2014 Commercial 59,689 38,695 39,659 36,840 17,590 21,197 1984-2014 Industrial 21,826 26,063 20,770 33,052 31,744 33,670 1984-2014 Oil Company 243,789 319,394 364,261 245,303 183,801 178,810 1984-2014 Farm 42,624 44,027 49,985 48,462 40,785 46,134 1984-2014 Electric Power 4,321 4,775 5,464 2,733 4,610 4,826 1984-2014 Railroad 18,345 25,425 32,515 28,110 39,578 45,790 1984-2014 Vessel

  11. Mississippi Sales of Distillate Fuel Oil by End Use

    Energy Information Administration (EIA) (indexed site)

    835,855 800,065 771,577 830,756 806,396 819,763 1984-2014 Residential 5 5 4 7 7 8 1984-2014 Commercial 26,641 23,713 26,383 26,386 24,019 28,803 1984-2014 Industrial 21,853 18,362 15,450 20,153 21,186 19,595 1984-2014 Oil Company 3,955 4,262 4,058 6,226 7,450 6,419 1984-2014 Farm 41,080 57,087 52,559 81,878 84,753 79,443 1984-2014 Electric Power 3,796 3,393 2,019 1,674 2,223 1,921 1984-2014 Railroad 24,727 17,936 37,741 29,848 32,550 35,578 1984-2014 Vessel Bunkering 141,302 93,384 58,285 58,505

  12. ,"U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use"

    Energy Information Administration (EIA) (indexed site)

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Residential",4,"Annual",2014,"6/30/1984" ,"Data 2","Commercial",10,"Annual",2014,"6/30/1984" ,"Data

  13. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    Energy Information Administration (EIA) (indexed site)

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Residential",4,"Annual",2014,"6/30/1984" ,"Data 2","Commercial",10,"Annual",2014,"6/30/1984" ,"Data

  14. "Table A2. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    Energy Information Administration (EIA) (indexed site)

    . Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel" " Oil for Selected Purposes by Census Region, Industry Group, and Selected" " Industries, 1991" " (Estimates in Barrels per Day) " ,,,,," Input for Heat,",,," Primary" " ",," Consumption for All Purposes",,,"Power, and Generation of Electricity",,," Consumption for Nonfuel Purposes ",,,"RSE" "SIC",,"

  15. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some

  16. Downstream Petroleum Mergers and Acquisitions by U.S. Major Oil Companies

    Reports and Publications

    2009-01-01

    A summary presentation of mergers and acquisitions by U.S. major oil companies (including the U.S. affiliates of foreign major oil companies). The presentation focuses on petroleum refining over the last several years through late 2009.

  17. Vacuum Distillation

    Energy Information Administration (EIA) (indexed site)

    Thermal Cracking: OtherGas Oil Thermal Cracking: Coking (BarrelsCalendar Day) Catalytic Cracking Fresh Feed Catalytic Cracking Fresh Feed (BarrelsCalendar Day) Catalytic ...

  18. Catalytic distillation structure

    DOEpatents

    Smith, Jr., Lawrence A.

    1984-01-01

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  19. Stocks of Distillate Fuel Oil

    Energy Information Administration (EIA) (indexed site)

    156,972 155,732 152,378 150,550 148,602 148,912 1982-2016 PADD 1 67,073 66,391 64,764 65,721 64,801 64,939 1990-2016 New England 12,875 12,828 12,753 12,790 13,008 12,791 1990-2016 Central Atlantic 40,330 40,422 39,313 40,033 39,994 39,737 1990-2016 Lower Atlantic 13,868 13,141 12,699 12,898 11,800 12,411 1990-2016 PADD 2 33,149 31,751 32,827 32,393 31,107 30,589 1990-2016 PADD 3 38,605 40,303 38,538 37,081 37,451 38,580 1990-2016 PADD 4 3,830 3,492 3,151 3,304 3,676 3,687 1990-2016 PADD 5

  20. Imports of Distillate Fuel Oil

    Annual Energy Outlook

    175 90 207 126 118 52 1982-2016 East Coast (PADD 1) 173 81 199 120 107 48 2004-2016 Midwest (PADD 2) 2 1 2 3 2 1 2004-2016 Gulf Coast (PADD 3) 0 0 0 0 0 0 2004-2016 Rocky Mountain ...

  1. Catalytic distillation structure

    DOEpatents

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  2. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Energy Information Administration (EIA) (indexed site)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  3. Catalytic distillation process

    DOEpatents

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  4. Catalytic distillation process

    DOEpatents

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  5. Advanced Distillation Final Report

    SciTech Connect

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were

  6. Distillation Column Flooding Predictor

    SciTech Connect

    2002-02-01

    This factsheet describes a research project whose goal is to develop the flooding predictor, an advanced process control strategy, into a universally useable tool that will maximize the separation yield of a distillation column.

  7. Rocky Mountain (PADD 4) Total Crude Oil and Products Imports

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Conventional Gasoline Blend. Comp. Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm ...

  8. DISTILLATION OF CALCIUM

    DOEpatents

    Barton, J.

    1954-07-27

    This invention relates to an improvement in the process for the purification of caicium or magnesium containing an alkali metal as impurity, which comprises distiiling a batch of the mixture in two stages, the first stage distillation being carried out in the presence of an inert gas at an absolute pressure substantially greater than the vapor pressure of calcium or maguesium at the temperature of distillation, but less than the vaper pressure at that temperature of the alkali metal impurity so that only the alkali metal is vaporized and condensed on a condensing surface. A second stage distilso that substantially only the calcium or magnesium distills under its own vapor pressure only and condenses in solid form on a lower condensing surface.

  9. Correlations estimate volume distilled using gravity, boiling point

    SciTech Connect

    Moreno, A.; Consuelo Perez de Alba, M. del; Manriquez, L.; Guardia Mendoz, P. de la

    1995-10-23

    Mathematical nd graphic correlations have been developed for estimating cumulative volume distilled as a function of crude API gravity and true boiling point (TBP). The correlations can be used for crudes with gravities of 21--34{degree} API and boiling points of 150--540 C. In distillation predictions for several mexican and Iraqi crude oils, the correlations have exhibited accuracy comparable to that of laboratory measurements. The paper discusses the need for such a correlation and the testing of the correlation.

  10. Neutrino Factory Downstream Systems

    SciTech Connect

    Zisman, Michael S.

    2009-12-23

    We describe the Neutrino Factory accelerator systems downstream from the target and capture area. These include the bunching and phase rotation, cooling, acceleration, and decay ring systems. We also briefly discuss the R&D program under way to develop these systems, and indicate areas where help from CERN would be invaluable.

  11. "Characteristic(a)","Total","Fuel Oil","Fuel Oil(b)","Natural...

    Energy Information Administration (EIA) (indexed site)

    ... oil converted to residual and distillate fuel oils) are excluded." " NFNo applicable ... for any table cell, multiply the cell's" "corresponding RSE column and RSE row factors. ...

  12. "Characteristic(a)","Electricity","Fuel Oil","Fuel Oil(b)","Natural...

    Energy Information Administration (EIA) (indexed site)

    " Unit: Percents." " ",," "," ",," "," " "Economic",,"Residual","Distillate",,"LPG and" "Characteristic(a)","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal

  13. Catalytic hydroprocessing of petroleum and distillates

    SciTech Connect

    Oballa, M.C.; Shih, S.S.

    1994-12-31

    There is a strong push for the processing of heavy oils, bitumen and/or residue, which carries with it some problems. These are connected with obtaining state-of-the-art technologies at reasonable capital and operating costs to the refiner. Then there are problems associated with choosing the best catalyst--one specially designed to lower considerably the high content of heteroatoms (S, N, O) and metals (V, Ni, Fe). To address the above considerations, engineers and scientists working in the processing of petroleum and distillates from different parts of the world presented papers covering different facets of residue upgrading and distillate hydrotreating. This book is a compilation of most of the papers presented in the five sessions of the symposium. The editors have broadly classified the papers in terms of content into the following four categories: catalyst deactivation; upgrading of heavy oils and residue; hydrotreating of distillates; and general papers. All papers have been processed separately for inclusion on the data base.

  14. Crude Oil

    Energy Information Administration (EIA) (indexed site)

    Barrels) Product: Crude Oil Liquefied Petroleum Gases Distillate Fuel Oil Residual Fuel Oil Still Gas Petroleum Coke Marketable Petroleum Coke Catalyst Petroleum Coke Other Petroleum Products Natural Gas Coal Purchased Electricity Purchased Steam Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History U.S. 0 0 0 0 0 0 1986-2015 East Coast (PADD 1) 0 0 0 0

  15. Atmospheric Crude Oil Distillation Operable Capacity

    Annual Energy Outlook

    Charge Capacity (BSD) Catalytic Hydrotreating NaphthaReformer Feed Charge Cap (BSD) Catalytic Hydrotreating Gasoline Charge Capacity (BSD) Catalytic Hydrotreating...

  16. Product Supplied for Distillate Fuel Oil

    Gasoline and Diesel Fuel Update

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4.77 2.81 3.07 2.74 2.51 1990's 3.10 2.59 2.25 2.59 2.50 2.39 2.97 3.02 2.45 2.61 2000's 4.10 4.19 3.41 5.54 6.09 7.59 6.83 6.92 8.58 4.47 2010's 5.02 4.64 3.25 4.08 5.51 3.07

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1989 2.69 2.40 2.40 2.33 2.44 2.57 2.54 2.48 2.41 2.56 2.71 2.79 1990 3.11 2.94 2.42 2.95 2.51 2.75 2.95 2.79 2.82 2.71 2.74 4.23 1991 3.61 3.08 2.76 2.87 2.14 2.19 2.36 2.53 2.32 2.27

  17. Distillate Fuel Oil Days of Supply

    Gasoline and Diesel Fuel Update

    Changes to proved reserves of U.S. natural gas by source, 2013-14 trillion cubic feet Year-end 2013 2014 Year-end 2014 proved 2014 revisions and 2014 proved Source of natural gas reserves Discoveries other changes production reserves Coalbed methane 12.4 0.4 4.3 -1.4 15.7 Shale 159.1 37.8 16.2 -13.4 199.7 Other U.S. natural gas Lower 48 onshore 166.0 11.4 -8.4 -11.7 157.2 Lower 48 offshore 9.1 0.8 0.8 -1.3 9.4 Alaska 7.4 0.1 -0.4 -0.3 6.8 U.S. TOTAL 354.0 50.5 12.4 -28.1 388.8 Note: Lower 48

  18. Distillate Fuel Oil Sales for Military Use

    Gasoline and Diesel Fuel Update

    Maine 1,487 2,852 1,506 1,071 1,058 2,482 1984-2014 Massachusetts 500 343 3,101 466 329 453 1984-2014 New Hampshire 1,480 490 253 104 90 257 1984-2014 Rhode Island 1,643 903 900 ...

  19. Distillate Fuel Oil Sales for Residential Use

    Energy Information Administration (EIA) (indexed site)

    4,103,881 3,930,517 3,625,747 3,473,310 3,536,111 3,802,848 1984-2014 East Coast (PADD 1) 3,670,994 3,545,676 3,274,963 3,183,878 3,240,215 3,501,957 1984-2014 New England (PADD...

  20. Distillate Fuel Oil Sales for Farm Use

    Energy Information Administration (EIA) (indexed site)

    660,024 2,928,175 2,942,436 3,031,878 3,026,611 3,209,391 1984-2014 East Coast (PADD 1) 333,748 454,160 375,262 382,639 404,799 401,686 1984-2014 New England (PADD 1A) 13,909...

  1. Distillate Fuel Oil Sales for Railroad Use

    Energy Information Administration (EIA) (indexed site)

    2,759,140 2,974,641 3,121,150 3,118,150 3,369,781 3,670,338 1984-2014 East Coast (PADD 1) 459,324 482,929 514,418 492,156 460,066 480,024 1984-2014 New England (PADD 1A) 43,763...

  2. Distillate Fuel Oil Sales for Industrial Use

    Energy Information Administration (EIA) (indexed site)

    2,159,428 2,045,164 2,179,953 2,325,503 2,271,056 2,417,898 1984-2014 East Coast (PADD 1) 597,048 560,403 568,024 568,997 559,886 600,949 1984-2014 New England (PADD 1A) 60,994...

  3. Distillate Fuel Oil Sales for Commercial Use

    Energy Information Administration (EIA) (indexed site)

    785,246 2,738,304 2,715,335 2,557,543 2,471,897 2,543,778 1984-2014 East Coast (PADD 1) 1,565,353 1,528,778 1,433,828 1,286,053 1,295,125 1,348,704 1984-2014 New England (PADD 1A)...

  4. Oil

    Energy.gov [DOE]

    The Energy Department works to ensure domestic and global oil supplies are environmentally sustainable and invests in research and technology to make oil drilling cleaner and more efficient.

  5. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated...

  6. American Distillation Inc | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Distillation Inc Jump to: navigation, search Name: American Distillation Inc. Place: Leland, North Carolina Zip: 28451 Product: Biodiesel producer in North Carolina. References:...

  7. West Coast (PADD 5) Total Crude Oil and Products Imports

    Energy Information Administration (EIA) (indexed site)

    Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha for Petrochem. Feed. Use Other Oils for Petrochem. Feed.

  8. Distillation process using microchannel technology

    DOEpatents

    Tonkovich, Anna Lee; Simmons, Wayne W.; Silva, Laura J.; Qiu, Dongming; Perry, Steven T.; Yuschak, Thomas; Hickey, Thomas P.; Arora, Ravi; Smith, Amanda; Litt, Robert Dwayne; Neagle, Paul

    2009-11-03

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  9. Distillation Column Flooding Predictor

    SciTech Connect

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid

  10. Process for preparing lubricating oil from used waste lubricating oil

    DOEpatents

    Whisman, Marvin L.; Reynolds, James W.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

  11. "Code(a)","Subsector and Industry","Source(b)","Fuel Oil","Fuel...

    Energy Information Administration (EIA) (indexed site)

    ... oil converted to residual and distillate fuel oils) are excluded." " NFNo applicable ... for any table cell, multiply the cell's" "corresponding RSE column and RSE row factors. ...

  12. Omniphobic Membrane for Robust Membrane Distillation

    SciTech Connect

    Lin, SH; Nejati, S; Boo, C; Hu, YX; Osuji, CO; Ehmelech, M

    2014-11-01

    In this work, we fabricate an omniphobic microporous membrane for membrane distillation (MD) by modifying a hydrophilic glass fiber membrane with silica nanoparticles followed by surface fluorination and polymer coating. The modified glass fiber membrane exhibits an anti-wetting property not only against water but also against low surface tension organic solvents that easily wet a hydrophobic polytetrafluoroethylene (PTFE) membrane that is commonly used in MD applications. By comparing the performance of the PTFE and omniphobic membranes in direct contact MD experiments in the presence of a surfactant (sodium dodecyl sulfate, SDS), we show that SDS wets the hydrophobic PTFE membrane but not the omniphobic membrane. Our results suggest that omniphobic membranes are critical for MD applications with feed waters containing surface active species, such as oil and gas produced water, to prevent membrane pore wetting.

  13. Method for controlling boiling point distribution of coal liquefaction oil product

    DOEpatents

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  14. Method for controlling boiling point distribution of coal liquefaction oil product

    DOEpatents

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  15. Total Crude Oil and Products Imports from All Countries

    Energy Information Administration (EIA) (indexed site)

    Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha for Petrochem. Feed. Use Other

  16. Corrosion inhibition for distillation apparatus

    DOEpatents

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.; Schweighardt, Frank K.

    1985-01-01

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  17. Distillate Fuel Oil Sales for Oil Company Use

    Annual Energy Outlook

    Connecticut 12 2 0 3 4 0 1984-2014 Maine 0 438 238 0 0 0 1984-2014 Massachusetts 0 871 965 887 0 0 1984-2014 New Hampshire 0 997 0 2 0 27 1984-2014 Rhode Island 0 0 0 0 0 0 ...

  18. Method of removing polychlorinated biphenyl from oil

    DOEpatents

    Cook, Gus T.; Holshouser, Stephen K.; Coleman, Richard M.; Harless, Charles E.; Whinnery, III, Walter N.

    1983-01-01

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  19. Method of removing polychlorinated biphenyl from oil

    DOEpatents

    Cook, G.T.; Holshouser, S.K.; Coleman, R.M.; Harless, C.E.; Whinnery, W.N. III

    1982-03-17

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  20. Distributive Distillation Enabled by Microchannel Process Technology

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Distributive Distillation Enabled by Microchannel Process Technology Citation Details In-Document Search Title: Distributive Distillation Enabled by Microchannel Process Technology The application of microchannel technology for distributive distillation was studied to achieve the Grand Challenge goals of 25% energy savings and 10% return on investment. In Task 1, a detailed study was conducted and two distillation systems were identified that would meet

  1. SRC residual fuel oils

    SciTech Connect

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  2. SRC Residual fuel oils

    DOEpatents

    Tewari, Krishna C.; Foster, Edward P.

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  3. ITP Chemicals: Hybripd Separations/Distillation Technology. Research...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hybripd SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Chemicals: Hybripd SeparationsDistillation Technology. Research ...

  4. ITP Chemicals: Hybrid Separations/Distillation Technology. Research...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hybrid SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Chemicals: Hybrid SeparationsDistillation Technology. Research ...

  5. Distributive Distillation Enabled by Microchannel Process Technology

    SciTech Connect

    Arora, Ravi

    2013-01-22

    The application of microchannel technology for distributive distillation was studied to achieve the Grand Challenge goals of 25% energy savings and 10% return on investment. In Task 1, a detailed study was conducted and two distillation systems were identified that would meet the Grand Challenge goals if the microchannel distillation technology was used. Material and heat balance calculations were performed to develop process flow sheet designs for the two distillation systems in Task 2. The process designs were focused on two methods of integrating the microchannel technology 1) Integrating microchannel distillation to an existing conventional column, 2) Microchannel distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated as a manufacturing method for microchannel distillation units. However, it was found that a significant development work would be required to develop process parameters to use UAM for commercial distillation manufacturing. Two alternate manufacturing methods were explored. Both manufacturing approaches were experimentally tested to confirm their validity. The conceptual design of the microchannel distillation unit (Task 3) was combined with the manufacturing methods developed in Task 4 and flowsheet designs in Task 2 to estimate the cost of the microchannel distillation unit and this was compared to a conventional distillation column. The best results were for a methanol-water separation unit for the use in a biodiesel facility. For this application microchannel distillation was found to be more cost effective than conventional system and capable of meeting the DOE Grand Challenge performance requirements.

  6. Fuel Oil and Kerosene Sales

    Reports and Publications

    2015-01-01

    Provides information, illustrations and state-level statistical data on end-use sales of kerosene; No.1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off-highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses.

  7. Total Number of Operable Refineries

    Energy Information Administration (EIA) (indexed site)

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  8. The Influence of Molecular Structure of Distillate Fuels on HFRR...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity Presentation given at 2007 ...

  9. New Design Methods and Algorithms for Multi-component Distillation...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf (517.32 KB) ...

  10. Method for reclaiming waste lubricating oils

    DOEpatents

    Whisman, Marvin L.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A method for purifying and reclaiming used lubricating oils containing additives such as detergents, antioxidants, corrosion inhibitors, extreme pressure agents and the like and other solid and liquid contaminants by preferably first vacuum distilling the used oil to remove water and low-boiling contaminants, and treating the dried oil with a solvent mixture of butanol, isopropanol and methylethyl ketone which causes the separation of a layer of sludge containing contaminants, unspent additives and oxidation products. After solvent recovery, the desludged oil is then subjected to conventional lubricating oil refining steps such as distillation followed by decolorization and deodorization.

  11. Fuel oil and kerosene sales 1997

    SciTech Connect

    1998-08-01

    The Fuel Oil and Kerosene Sales 1997 report provides information, illustrations and state-level statistical data on end-use sales of kerosene; No. 1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses. 24 tabs.

  12. Distillation: Still towering over other options

    SciTech Connect

    Kunesh, J.G.; Kister, H.Z.; Lockett, M.J.; Fair, J.R.

    1995-10-01

    Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

  13. "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural...

    Energy Information Administration (EIA) (indexed site)

    Errors for Table 5.8;" " Unit: Percents." ,,,"Distillate" ,,,"Fuel Oil",,,"Coal" ,"Net Demand","Residual","and",,"LPG and","(excluding Coal" "End Use","for ...

  14. "Code(a)","End Use","for Electricity(b)","Fuel Oil","Diesel Fuel...

    Energy Information Administration (EIA) (indexed site)

    Unit: Percents." " "," ",," ","Distillate"," "," " " "," ",,,"Fuel Oil",,,"Coal" "NAICS"," ","Net Demand","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End Use","for ...

  15. Minimizing corrosion in coal liquid distillation

    DOEpatents

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.

    1985-01-01

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  16. Controlling vanadium from high metals crude oils

    SciTech Connect

    Golden, S.W.; Martin, G.R.

    1995-09-01

    Processing heavier high metals crude oils continues to be an objective of many refiners. Refiners manage the vanadium and other contaminants with hydroprocessing and FCC catalysts that are more tolerant to metals. Although hydroprocessing and FCC catalyst formulations are critical and will be required for the bulk of the metals removal, many times primary distillation impacts on vanadium are ignored. Distillation system designs can significantly impact the metals content of the gas oil pool or the total gas yields for a targeted metals level. Commercial experience shows that total gas oil metals to the hydroprocessing unit can be reduced by 20 to 40% for a given gas yield or the total gas oil yield can be increased for a given metals target by optimizing primary distillation system performance. Total gas oil vanadium content has varied from 5 to 2 weight ppm depending on crude oil metals level, unit process design, distillation unit operation, and equipment design. An actual example using a 22.0 API Bochequero Field blend will be used to illustrate the points covered. The source of the vanadium in the various gas oil pool components will be evaluated and show potential gas oil quality improvements based on primary distillation system design and operation modifications. In the example, the refiner processes 145,000 bpd of crude oil through a conventional integrated atmospheric/vacuum unit and processes the vacuum residue in a delayed coker. The gas oil blend streams consists of atmospheric gas oil, light vacuum gas oil, and heavy vacuum gas oil from the crude unit and heavy coker gas oil from the delayed coker. All the modifications which will be discussed have been operating successfully for several years.

  17. Classic papers in Solar Energy: Solar distillation

    SciTech Connect

    Howe, E.D.

    1990-06-01

    The following Classic Paper was presented by Professor Howe at the first international Conference on Solar Energy at Tucson, Arizona, USA in 1955. That conference was sponsored by the Association of Applied solar Energy (AFASE), the precursor of ISES. Although this paper does not represent the many developments in solar distillation later applied by Professor Howe in the South Pacific, it is a classic paper because it presents Professor Howe's pioneering work in setting up the Seawater Conversion Laboratory in Richmond for the University of California at Berkeley, US. The research of Professor Howe and his colleagues at the Seawater Conversion Laboratory formed the foundation of contemporary solar energy desalination and distillation systems.

  18. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Energy Information Administration (EIA) (indexed site)

    3,856.4 26,071.0 56,502.9 1,351.8 60,057.4 April ... 1,030.8 157.5 20,855.8 21,528.9 3,655.2 25,184.0 46,039.8 817.2 48,045.3 May...

  19. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Energy Information Administration (EIA) (indexed site)

    165,833.6 February ... 7,190.5 4,192.4 55,685.0 76,234.8 22,030.8 98,265.6 153,950.6 2,265.8 167,599.4 March ... 3,741.4...

  20. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Energy Information Administration (EIA) (indexed site)

    December ... 3,872.6 4,684.1 35,790.4 88,601.0 20,217.6 108,818.6 144,609.0 1,089.2 154,255.0 1998 Average ... 2,643.4 1,854.8...

  1. Stocks of Distillate Fuel Oil 15 ppm Sulfur and Under

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    128,930 135,683 2004-2016 PADD 1 48,011 47,644 49,624 47,947 48,127 49,490 2004-2016 New England 3,841 4,379 4,534 4,438 5,029 5,888 2004-2016 Central Atlantic 31,859 30,793...

  2. Stocks of Distillate Fuel Oil Greater Than 500 ppm Sulfur

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    15,747 15,675 15,436 1993-2016 PADD 1 9,594 10,156 10,022 10,045 9,893 9,629 1993-2016 New England 3,108 3,131 2,948 3,290 3,055 3,284 1993-2016 Central Atlantic 5,474 5,933...

  3. Florida Sales of Distillate Fuel Oil by End Use

    Energy Information Administration (EIA) (indexed site)

    840,100 2,027,012 1,914,621 1,918,039 2,023,650 2,038,923 1984-2014 Residential 1,551 1,820 1,085 572 451 728 1984-2014 Commercial 126,292 113,313 100,791 104,860 113,873 110,082 ...

  4. New Mexico Sales of Distillate Fuel Oil by End Use

    Gasoline and Diesel Fuel Update

    Vessel Bunkering 0 0 0 0 0 0 1984-2014 On-Highway 432,794 472,924 495,600 495,026 484,394 504,615 1984-2014 Military 582 306 859 572 405 682 1984-2014 Off-Highway 5,729 24,907 ...

  5. Alabama Sales of Distillate Fuel Oil by End Use

    Gasoline and Diesel Fuel Update

    Vessel Bunkering 61,852 65,017 41,339 25,542 24,650 20,222 1984-2014 On-Highway 657,070 711,371 717,466 705,904 754,337 768,994 1984-2014 Military 2,014 2,203 2,135 1,649 1,326 ...

  6. Refiner and Blender Net Production of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update

    496 4,599 4,536 4,662 4,784 4,984 1982-2016 PADD 1 378 373 373 393 398 374 1990-2016 PADD 2 995 1,094 1,084 1,112 1,092 1,118 1990-2016 PADD 3 2,412 2,455 2,424 2,505 2,588 2,731 1990-2016 PADD 4 209 189 185 207 220 225 1990-2016 PADD 5 502 489 470 446 486 538 1990

  7. Gross Input to Atmospheric Crude Oil Distillation Units

    Energy Information Administration (EIA) (indexed site)

    Sep-15 Oct-15 Nov-15 Dec-15 Jan-16 Feb-16 View History U.S. 16,394 15,690 16,673 16,848 16,365 16,167 1985-2016 PADD 1 1,063 1,133 1,190 1,136 1,136 1,080 1985-2016 East Coast 965 ...

  8. "Table A10. Total Consumption of LPG, Distillate Fuel Oil...

    Energy Information Administration (EIA) (indexed site)

    ... Form EIA-846, '1991" "Manufacturing Energy Consumption Survey,' and the Bureau of the Census, Industry" "Division, data files for the '1991 Annual Survey of Manufactures.'

  9. Distillate Fuel Oil Sales for All Other Uses

    Gasoline and Diesel Fuel Update

    Connecticut 0 0 0 0 0 0 1984-2014 Maine 0 0 0 0 0 0 1984-2014 Massachusetts 0 0 0 0 0 0 1984-2014 New Hampshire 0 0 0 0 0 0 1984-2014 Rhode Island 0 0 0 0 0 0 1984-2014 Vermont 0 0 ...

  10. Distillate Fuel Oil Sales for Off-Highway Use

    Energy Information Administration (EIA) (indexed site)

    1,985,592 2,148,677 2,070,260 2,088,157 2,063,319 2,014,184 1984-2014 East Coast (PADD 1) 605,884 615,812 634,470 621,261 584,856 604,093 1984-2014 New England (PADD 1A) 81,453...

  11. Distillate Fuel Oil Sales for Vessel Bunkering Use

    Energy Information Administration (EIA) (indexed site)

    1,912,984 2,002,834 2,133,395 1,768,324 1,675,521 1,593,398 1984-2014 East Coast (PADD 1) 276,013 259,319 296,947 283,254 274,142 289,674 1984-2014 New England (PADD 1A) 45,147...

  12. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect

    Agrawal, Rakesh

    2013-11-21

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  13. Downstream extent of the N Reactor plume

    SciTech Connect

    Dauble, D.D.; Ecker, R.M.; Vail, L.W.; Neitzel, D.A.

    1987-09-01

    The downstream extent of the N Reactor thermal plume was studied to assess the potential for fisheries impacts downstream of N Reactor. The N Reactor plume, as defined by the 0.5/sup 0/F isotherm, will extend less than 10 miles downstream at river flows greater than or equal to annual average flows (120,000 cfs). Incremental temperature increases at the Oregon-Washington border are expected to be less than 0.5/sup 0/F during all Columbia River flows greater than the minimum regulated flows (36,000 cfs). The major physical factor affecting Columbia River temperatures in the Hanford Reach is solar radiation. Because the estimated temperature increase resulting from N Reactor operations is less than 0.3/sup 0/F under all flow scenarios, it is unlikely that Columbia River fish populations will be adversely impacted.

  14. Philippines' downstream sector poised for growth

    SciTech Connect

    Not Available

    1992-05-11

    This paper reports that the Philippines' downstream sector is poised for sharp growth. Despite a slip in refined products demand in recent years, Philippines products demand will rebound sharply by 2000, East-West Center (EWC), Honolulu, predicts. Philippines planned refinery expansions are expected to meet that added demand, EWC Director Fereidun Fesharaki says. Like the rest of the Asia-Pacific region, product specifications are changing, but major refiners in the area expect to meet the changes without major case outlays. At the same time, Fesharaki says, push toward deregulation will further bolster the outlook for the Philippines downstream sector.

  15. Refiner/marketer targets production of transportation fuels and distillates

    SciTech Connect

    Thompson, J.E.

    1997-01-01

    Citgo Petroleum Corp., the wholly owned subsidiary of Petroleos de Venezuela, S.A. (PDVSA), the Venezuelan national oil company, owns two gasoline producing refineries, a 305,000-b/d system in Lake Charles, La., and a 130,000-b/d facility in Corpus Christi, Texas. Each is considered a deep conversion facility capable of converting heavy, sour crudes into a high percentage of transportation fuels and distillates. Two smaller refineries, one in Paulsboro, N.J., and one in Savannah, GA., have the capacity to process 40,000 b/d and 28,000 b/d of crude, respectively, for asphalt products. In the past two years, Citgo`s light oils refineries operated safely and reliably with a minimum of unscheduled shutdowns. An ongoing emphasis to increase reliability has resulted in extended run lengths at the refineries. Citgo has invested $314 million at its facilities in 1995, much of this toward environmental and regulatory projects, such as the new waste water treatment unit at the Lake Charles refinery. Over the next few years, Citgo expects to complete $1.5 billion in capital spending for major processing units such as a 60,000-b/d FCC feed hydrotreater unit at the Lake Charles refinery and crude expansion at the Corpus Christi refinery. Product exchanges and expanded transport agreements are allowing Citgo to extend its marketing reach.

  16. Four different shale oils processed into jet fuel

    SciTech Connect

    Not Available

    1987-03-01

    Crude shale oils produced by (a) Geokinetics, (b) Occidental, (c) Paraho, and (d) Tosco II processes have each been catalytically hydroprocessed to produce jet fuel fractions. The shale oil hydroprocessing was performed at low, medium and high hydroprocessing severities. Hydroprocessing severity was changed mainly by varying the temperature. Full boiling range (121-300/sup 0/C) jet fuel was produced from the hydroprocessed product of the raw oil distillates boiling below 343/sup 0/C. This paper describes the shale oil properties and hydroprocessing, gives the results of sulfur removal and hydrogenated shale oil distillation, and lists the physical and chemical properties of the jet fuels. 2 figures, 3 tables.

  17. Fuel oil and kerosene sales 1996

    SciTech Connect

    1997-08-01

    The Fuel Oil and Kerosene Sales 1996 report provides information, illustrations and State-level statistical data on end-use sales of kerosene; No. 1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Fuel Oil and Kerosene Sales 1996. 24 tabs.

  18. Process for upgrading heavy hydrocarbonaceous oils

    SciTech Connect

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1981-10-13

    An integrated upgrading process is disclosed which can be used to lower the specific gravity, viscosity and boiling range of heavy, viscous hydrocarbonaceous oil . The process consists of fractionally distilling the oil, treating its residuum with a hydrogen donor material under hydrocracking conditions, fractionally distilling the effluent from the hydrocracking zone and rehydrogenating that portion boiling from about 180/sup 0/ C to 350/sup 0/ C for recycling to the hydrocracking zone. The liquid portion of the oil not recycled can be recombined into a reconstituted crude suitable for transporting by normal crude pipelines.

  19. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, E.M. Jr.

    1985-08-20

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  20. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, Jr., Edward M.

    1984-01-01

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  1. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, Jr., Edward M.

    1985-01-01

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  2. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, E.M. Jr.

    1984-03-27

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  3. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update

    distillate fuel oil with sulfur content 15 ppm and under due to product detail limitations in exports data received from the U.S. Census Bureau. LRG Liquefied Refinery Gas. ...

  4. Co-processing of carbonaceous solids and petroleum oil

    DOEpatents

    Gupta, Avinash; Greene, Marvin I.

    1992-01-01

    In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the thermal liquefaction heater. Coal may be co-processed with petroleum oil by adding pre-hydrogenated oil to the first stage or unhydrogenated oil to the second stage.

  5. Combined process for heavy oil, upgrading and synthetic fuel production

    SciTech Connect

    Polomski, R.E.

    1984-06-05

    A process for upgrading heavy oil to fuel products comprises deasphalting the heavy oil with an oxygenated solvent and simultaneously converting the oxygenated solvent and deasphalted oil over a ZSM-5 type catalyst to produce gasoline and distillate boiling range hydrocarbons.

  6. Conversion of LPG hydrocarbons into distillate fuels using an integral LPG dehydrogenation-MOGD process

    SciTech Connect

    Owen, H.; Zahner, J.C.

    1987-06-23

    This patent describes a process for converting lower paraffinic hydrocarbon feedstock comprising propane and/or butane into heavier hydrocarbons comprising gasoline and distillate, comprising the steps of: feeding the paraffinic feedstock to a dehydrogenation zone under conversion conditions for dehydrogenating at least a portion of the feedstock; recovering a first dehydrogenation gaseous effluent stream comprising propene and/or butene; contacting the first gaseous effluent steam with a liquid lean oil sorbent stream comprising C/sub 5//sup +/ hydrocarbons under sorption conditions to produce a C/sub 3//sup +/ rich liquid absorber stream and a light gas stream; sequentially pressurizing, heating and passing the C/sub 3//sup +/ rich liquid absorber stream to an oligomerization reactor zone at elevated temperature and pressure; contacting the C/sub 3//sup +/ rich stream with oligomerization catalyst in the oligomerization reactor zone for conversion of at least a portion of lower olefins to heavier hydrocarbons under oligomerization reaction conditions to provide a second reactor effluent stream comprising gasoline and distillate boiling range hydrocarbons; flash separating the second reactor effluent stream into a separator vapor stream comprising a major portion of the hydrocarbons which later form the lean oil stream, and a major portion of the C/sub 4//sup -/ hydrocarbons and a separator liquid stream comprising the gasoline and distillate boiling range materials produced in the oligomerization reactor zone; fractionating the separator liquid stream in a first product debutanizer tower into a first debutanizer overhead vapor stream comprising C/sub 4//sup -/ hydrocarbons and a product debutanizer liquid bottoms stream comprising C/sub 5//sup +/ gasoline and distillate boiling range hydrocarbons.

  7. Turbocharger with downstream pressure-gain combustor

    SciTech Connect

    Sherikar, S.V.

    1991-05-14

    This patent describes a turbocharger. It comprises: an internal combustion engine; a compressor located upstream of the internal combustion engine for increasing the inlet pressure of the internal combustion engine; a turbine located down stream of the internal combustion engine and mechanically coupled to the compressor for driving the compressor; and a pressure-gain combustor located downstream of the turbine for decreasing the outlet pressure of the internal combustion engineer and thus increasing the turbine power output and improving the starting characteristics of the turbocharger.

  8. Integrated hydroprocessing scheme for production of premium quality distillates and lubricants

    SciTech Connect

    Chen, N.Y.; LaPierre, R.B.; Partridge, R.D.; Wong, S.S.

    1989-07-25

    This patent describes a method of upgrading a gas oil hydrocarbon feedstock into a naphtha product and a distillate product having a boiling range above that of the naptha product and below that of the gas oil and also having content of iso-paraffins. The method comprises hydrocracking the gas oil feedstock over a large pore size, aromatic selective hydrocracking catalyst having acidic functionality and hydrogenation-deydrogenation functionality, at a hydrogen pressure up to about 10,000 kPa and at a conversion below 50 percent to 650{sup 0}F.-products, to effects a removal of aromatic components by hydrocracking and to form the naptha product and a product boiling above the naptha product which is enriched in paraffinic components; separating the naptha product from the product enriched in paraffinic components; and hydroprocessing the product enriched in paraffinic components over a hydroprocessing catalyst comprising zeolite beta as an acidic component and a hydrogenation-dehydrogenation component, to produce a distillate boiling range product having an enhanced content of isoparaffinic components.

  9. New Design Methods and Algorithms for Multi-component Distillation

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Processes | Department of Energy Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf (517.32 KB) More Documents & Publications Development of Method and Algorithms To Identify Easily Implementable Energy-Efficient Low-Cost Multicomponent Distillation Column Trains With Large Energy Savings For Wide Number of Separations CX-100137 Categorical Exclusion Determination ITP

  10. Increasing Distillate Production at U.S. Refineries

    Reports and Publications

    2010-01-01

    Paper explores the potential for U.S. refiners to create more distillate and less gasoline without major additional investments beyond those already planned.

  11. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect

    Gambert, G.

    1996-12-31

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  12. ,"U.S. Downstream Processing of Fresh Feed Input"

    Energy Information Administration (EIA) (indexed site)

    (Thousand Barrels per Day)","U.S. Downstream Processing of Fresh Feed Input by Catalytic Cracking Units (Thousand Barrels per Day)","U.S. Downstream Processing of Fresh Feed Input ...

  13. This Week In Petroleum Distillate Section

    Gasoline and Diesel Fuel Update

    Residential heating oil prices (dollars per gallon) Average Regional U.S. residential heating oil prices graph Regional residential heating oil prices graph Residential heating oil prices (dollars per gallon) more price data › Year ago Most recent 11/16/15 11/14/16 11/07/16 10/31/16 10/24/16 10/17/16 10/10/16 10/03/16 Average 2.398 2.375 2.386 2.399 2.394 2.380 2.366 2.301 East Coast (PADD 1) 2.402 2.382 2.393 2.404 2.399 2.385 2.370 2.306 New England (PADD 1A) 2.347 2.331 2.336 2.334 2.328

  14. Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction

    SciTech Connect

    Andile B. Mzinyati

    2007-09-15

    The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

  15. Northeast Home Heating Oil Reserve (NEHHOR) Guidelines for Release |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Heating Oil Reserve » Northeast Home Heating Oil Reserve (NEHHOR) Guidelines for Release Northeast Home Heating Oil Reserve (NEHHOR) Guidelines for Release The Energy Policy and Conservation Act, as amended, sets conditions for the release of the Northeast Home Heating Oil Reserve. The Secretary of Energy has the authority to sell, exchange, or otherwise dispose of petroleum distillate from the Reserve in order to maintain the quality or quantity of the petroleum

  16. Upgrading petroleum residues and heavy oils

    SciTech Connect

    Gray, M.R.

    1994-01-01

    Here is an in-depth look at current techniques for converting heavy oils and residues into more valuable distillates. It examines the chemistry of heavy hydrocarbon feeds and their properties which are important to engineering design, including phase behavior, reaction kinetics, and thermodynamic and transport characteristics.

  17. A Method to Distill Hydrogen Isotopes from Lithium | Princeton...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    to Distill Hydrogen Isotopes from Lithium This white paper outlines a method for the removal of tritium and deuterium from liquid lithium. The method is based on rapid or flash ...

  18. Membrane augmented distillation to separate solvents from water

    DOEpatents

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  19. Heat Integrated Distillation through Use of Microchannel Technology

    Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  20. Low Temperature Geothermal Resource Assessment for Membrane Distillation

    Office of Scientific and Technical Information (OSTI)

    Desalination in the United States: Preprint (Conference) | SciTech Connect Low Temperature Geothermal Resource Assessment for Membrane Distillation Desalination in the United States: Preprint Citation Details In-Document Search Title: Low Temperature Geothermal Resource Assessment for Membrane Distillation Desalination in the United States: Preprint Substantial drought and declines in potable groundwater in the United States over the last decade has increased the demand for fresh water.

  1. Fuel oil and kerosene sales 1994

    SciTech Connect

    1995-09-27

    This publication contains the 1994 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the sixth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA)for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1994 edition marks the 11th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Distillate and residual fuel oil sales continued to move in opposite directions during 1994. Distillate sales rose for the third year in a row, due to a growing economy. Residual fuel oil sales, on the other hand, declined for the sixth year in a row, due to competitive natural gas prices, and a warmer heating season than in 1993. Distillate fuel oil sales increased 4.4 percent while residual fuel oil sales declined 1.6 percent. Kerosene sales decreased 1.4 percent in 1994.

  2. Evaluation of Exxon donor solvent full-range distillate as a utility boiler fuel. Final report

    SciTech Connect

    Reese, J.; Folsom, B.; Jones, F.

    1984-03-01

    The use of Exxon Donor Solvent (EDS) as a utility boiler fuel was evaluated at Southern California Edison Company's Highgrove Unit 4, a Combustion Engineering 44.5 net Mw wall-fired boiler. The EDS evaluated was a full range solvent oil produced at the Exxon Coal-Liquefaction Pilot Plant in Baytown, Texas. This evaluation involved modifying the boiler equipment and operating procedures for EDS, and then firing 4500 barrels of EDS in the boiler. The resulting boiler performance and emissions with EDS were compared to those with a blended low-sulfur petroleum distillate similar to No. 4 fuel oil and with natural gas. The boiler was operated over a range of load and excess air conditions during the tests. The potential for NO/sub x/ reduction with a burner out of service (BOOS) was also evaluated. Boiler performance, including excess air requirements, maximum load, thermal efficiency and heat rate efficiency was similar to that with oil. The NO/sub x/ emissions with EDS were about 12 percent higher than with oil. NO/sub x/ reduction with BOOS was about 20 percent with both oil and EDS. EDS use did not result in an increase in particulate emissions. Submicron particulate, however, was increased with EDS. Required equipment modifications at Highgrove primarily involved material compatibility with EDS, fuel system capacity, and the burner nozzles. The use of EDS required the implementation of health and safety procedures due to the adverse health effects that could result from prolonged exposure to the fuel. The results of the evaluation demostrated that EDS can be used in a utility boiler designed for oil with only minor modifications.

  3. Deliveries of fuel oil and kerosene in 1980

    SciTech Connect

    Not Available

    1982-02-11

    This report contains numerical data on deliveries of distillate fuel oil, residual fuel oil, and kerosene which will be helpful to federal and state agencies, industry, and trade associations in trend analysis, policy/decision making, and forecasting. The data for 1979 and 1980 are tabulated under the following headings: all uses, residential, commercial, industrial, oil companies, electric utilities, transportation, military, and farm use. The appendix contains product and end-use descriptions. (DMC)

  4. Oil shale, tar sands, and related materials

    SciTech Connect

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  5. Specific heavy oil processing market study. Final report

    SciTech Connect

    Not Available

    1984-06-01

    The market potential for two not-yet-commercialized, proprietary processes for upgrading heavy oil was evaluated. Dynacracking (TM) of Hydrocarbon Research Inc. (HRI) and Aurabon of UOP Process Division (UOP), including an integrated commercial hydrotreating unit were the processes studied. The report concludes that while a large market for Heavy Oil Processing (HOP) units was originally forecast as the result of the shift to heavier crudes by US refiners under a given demand slate and refinery configuration, this market has either eroded due to massive demand shifts (both in volumetric and relative product mix terms) or largely been satisfied on an accelerated basis (due to downstream restructuring pressures) by units already constructed or under firm commitment utilizing other HOP technology. Dynacracking or Aurabon does not appear to offer the substantial economic advantage needed to replace other HOP units already committed. However, additional demands for HOP units couold arise, particularly on a regional basis, if significant additional foreign or domestic sources of heavy crude are introduced into the supply picture or the demand structure moves dramatically away from that currently foreseen by the EIA. Expected profit margins were calculated for both processes, allowing $2/barrel extra credit to the Aurabon products because of their higher quality. Both processes appear to produce about the same fraction of vacuum bottoms when processing the same crude. Dynacracking produces a higher proportion of naphtha and Aurabon produces substantially more heavy distillate. This report is not intended to serve as a basis of selecting either process for a particular installation. 10 references, 7 figures, 29 tables.

  6. FRACTIONAL DISTILLATION SEPARATION OF PLUTONIUM VALUES FROM LIGHT ELEMENT VALUES

    DOEpatents

    Cunningham, B.B.

    1957-12-17

    A process is described for removing light element impurities from plutonium. It has been found that plutonium contaminated with impurities may be purified by converting the plutonium to a halide and purifying the halide by a fractional distillation whereby impurities may be distilled from the plutonium halide. A particularly effective method includes the step of forming a lower halide such as the trior tetrahalide and distilling the halide under conditions such that no decomposition of the halide occurs. Molecular distillation methods are particularly suitable for this process. The apparatus may comprise an evaporation plate with means for heating it and a condenser surface with means for cooling it. The condenser surface is placed at a distance from the evaporating surface less than the mean free path of molecular travel of the material being distilled at the pressure and temperature used. The entire evaporating system is evacuated until the pressure is about 10/sup -4/ millimeters of mercury. A high temperuture method is presented for sealing porous materials such as carbon or graphite that may be used as a support or a moderator in a nuclear reactor. The carbon body is subjected to two surface heats simultaneously in an inert atmosphere; the surface to be sealed is heated to 1500 degrees centigrade; and another surface is heated to 300 degrees centigrade, whereupon the carbon vaporizes and flows to the cooler surface where it is deposited to seal that surface. This method may be used to seal a nuclear fuel in the carbon structure.

  7. Synthetic crude oils carcinogenicity screening tests. Progress report, September 15, 1979-March 15, 1980

    SciTech Connect

    Calkins, W.H.; Deye, J.F.; King, C.F.; Hartgrove, R.W.; Krahn, D.F.

    1980-01-01

    Four crude oils (H Coal-Fuel Oil Mode, Occidental in situ Shale Oil, Exxon Donor Solvent Liquid, and SRC II) which were distilled into four fractions (naphtha, mid-distillate, gas oil and residue) for analysis and biological screening testing during the last report period were tested for mutagenicity by the Ames test and for tumor initiating activity by an initiation/promotion (skin painting) test. Substantial agreement exists between Ames and skin painting results. Low boiling naphtha fractions of the 4 crude oils showed little or no mutagenicity or tumor initiating activity by the two tests used. The higher boiling fractions (gas oils and residues) and the crude oils themselves were mutagenic and exhibited tumor initiation activity. The coal derived fractions were more active by both tests than the shale oil fractions.

  8. Extraction of El-Lajjun oil shale

    SciTech Connect

    Anabtawi, M.Z.; Uysal, B.Z.

    1995-10-01

    Extraction of the bitumen fraction of El-Lajjun oil shale was carried out using 17 different solvents, pure and combined. Out of all the solvents used, toluene and chlorform were found to be the most efficient for extraction of the bitumen to perform the major part of the experiments. This selectivity was based on the quality and quantity of the yield and on the quantity of solvent recovered. Extraction was carried out using a Soxhlet extractor. For complete recovery of solvent the extract phase was subjected to two stages of distillation, simple distillation followed by fractional distillation, where different cuts of oil were obtained. It was found that an optimum shale size of 1.0 mm offered better solvent recovery. One hour was the optimum time needed for complete extraction. The yield of oil was determined from the material balance gained from fractional distillation after testing for the existence of any traces of solvent trapped in the different cuts by using a gas chromotography technique. When chloroform was used, it was found that the average amount of bitumen extracted was 0.037 g/g of shale, which corresponds to 98% of the actual bitumen trapped in the oil shale (by assuming the bitumen represents 15% of the organic matter) and 84.1% of solvent recovered. When toluene was used, it was found that the average amount of oil extracted was 0.0293 g/g/ of shale, which corresponds to 78% of the actual bitumen trapped in the oil shale (by assuming bitumen represents 15% of the organic matter) and 89.9% of solvent for extraction with toluene.

  9. ,"U.S. Downstream Charge Capacity of Operable Petroleum Refineries...

    Energy Information Administration (EIA) (indexed site)

    as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal Cracking Downstream Charge Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal ...

  10. ,"No. 2 Distillate Sales to End Users Refiner Sales Volumes"

    Energy Information Administration (EIA) (indexed site)

    ... Refiners (Thousand Gallons per Day)","New Mexico No 2 Distillate Retail Sales by Refiners ...57.7,6018.7,64.6,101.5,691.5,1553.8,1576.9,2030.5,4320.3,1350.4,683.2,792.4,316.4,804.3,37...

  11. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOEpatents

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  12. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOEpatents

    Baker, E.G.; Elliott, D.C.

    1993-01-19

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  13. Characterization of DOE reference oil shales: Mahogany Zone, Parachute Creek Member, Green River Formation Oil Shale, and Clegg Creek Member, New Albany Shale

    SciTech Connect

    Miknis, F. P.; Robertson, R. E.

    1987-09-01

    Measurements have been made on the chemical and physical properties of two oil shales designated as reference oil shales by the Department of Energy. One oil shale is a Green River Formation, Parachute Creek Member, Mahogany Zone Colorado oil shale from the Exxon Colony mine and the other is a Clegg Creek Member, New Albany shale from Kentucky. Material balance Fischer assays, carbon aromaticities, thermal properties, and bulk mineralogic properties have been determined for the oil shales. Kerogen concentrates were prepared from both shales. The measured properties of the reference shales are comparable to results obtained from previous studies on similar shales. The western reference shale has a low carbon aromaticity, high Fischer assay conversion to oil, and a dominant carbonate mineralogy. The eastern reference shale has a high carbon aromaticity, low Fischer assay conversion to oil, and a dominant silicate mineralogy. Chemical and physical properties, including ASTM distillations, have been determined for shale oils produced from the reference shales. The distillation data were used in conjunction with API correlations to calculate a large number of shale oil properties that are required for computer models such as ASPEN. There was poor agreement between measured and calculated molecular weights for the total shale oil produced from each shale. However, measured and calculated molecular weights agreed reasonably well for true boiling point distillate fractions in the temperature range of 204 to 399/sup 0/C (400 to 750/sup 0/F). Similarly, measured and calculated viscosities of the total shale oils were in disagreement, whereas good agreement was obtained on distillate fractions for a boiling range up to 315/sup 0/C (600/sup 0/F). Thermal and dielectric properties were determined for the shales and shale oils. The dielectric properties of the reference shales and shale oils decreased with increasing frequency of the applied frequency. 42 refs., 34 figs., 24

  14. New Design Methods and Algorithms for Multi-component Distillation Processes

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Methods and Algorithms for Multi-component Distillation Processes Improved Energy Efficiency through the Determination of Optimal Distillation Configuration The ability to apply low-energy distillation confgurations can allow chemical manufacturers to reduce energy consumption of both existing and grassroots plants. However, the determina- tion of an appropriate confguration is limited by an incomplete knowledge of the 'search space' for a proper distillation network. Currently, no systematic

  15. Transition duct with divided upstream and downstream portions

    SciTech Connect

    McMahan, Kevin Weston; LeBegue, Jeffrey Scott; Maldonado, Jaime Javier; Dillard, Daniel Jackson; Flanagan, James Scott

    2015-07-14

    Turbine systems are provided. In one embodiment, a turbine system includes a transition duct comprising an inlet, an outlet, and a duct passage extending between the inlet and the outlet and defining a longitudinal axis, a radial axis, and a tangential axis. The outlet of the transition duct is offset from the inlet along the longitudinal axis and the tangential axis. The duct passage includes an upstream portion extending from the inlet and a downstream portion extending from the outlet. The turbine system further includes a rib extending from an outer surface of the duct passage, the rib dividing the upstream portion and the downstream portion.

  16. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  17. Too early to tell on $100 oil

    Energy Information Administration (EIA) (indexed site)

    Presentation to: April 8, 2008 Lehman Brothers oil outlook: Stronger signals of weaker prices Adam Robinson What's driving oil markets today? u Not the short run: Oil prices go up every time the US economy gets worse u It's tempting to argue that the rise in oil prices now is simply a continuation of past trends - The cost of F&D continues to march up - Demand in China growing faster with no signs of slowdown - Upstream and downstream supply bottlenecks are permanent u We think current price

  18. Integrated process of distillation with side reactors for synthesis of organic acid esters

    DOEpatents

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  19. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  20. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential

  1. Written Statement of Peggy Montana, Shell Downstream Quadrennial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    I am here today to discuss the resilience of the domestic oil and gas industry's infrastructure. Today, thanks to the innovation and entrepreneurial spirit of the men and women in ...

  2. Gulf Canada donor refined bitumen heavy oil upgrading process

    SciTech Connect

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1982-09-01

    The method is a moderate-pressure, noncatalytic alternative which has been shown to be applicable to a wide range of bitumens and heavy oils. It offers the potential of efficiency and reliability at a low capitalized investment and operating cost. The raw distillates are separated from the bitumen or heavy oil and the vacuum residuum is blended with an efficient hydrogen donor stream containing a high proportion of substituted tetralins, and is thermally cracking in the liquid phase. The exhausted donor is recovered from the middle distillate reactor product, reactivated by fixed bed hydrogenation before being recycled to the reactor. The process can be self-sufficient in donor and is independent of the metal content of the feed. The products are blanded with the raw distillates and further hydrogenated to high quality petroleum products. While the primary hydrogen consumption is low, the reconstituted naphtha, distillate and gas oil fractions require less hydrogen than the coker liquids to achieve acceptable refinery feed quality. 1 figure, 9 tables.

  3. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    Energy Information Administration (EIA) (indexed site)

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  4. Heavy oil upgrading using an integrated gasification process

    SciTech Connect

    Quintana, M.E.; Falsetti, J.S.

    1995-12-31

    The value of abundant, low-grade heavy crude oil reserves can be enhanced by appropriate upgrade processing at the production site to yield marketable refinery feedstocks or ultimate products. One of the upgrading process sequences most commonly considered involves vacuum distillation followed by a bottoms processing step such as solvent deasphalting or coking. These schemes can be further enhanced with the addition of a gasification step to convert the unsaleable, bottom-of-the-barrel residues into useful products, such as high-purity hydrogen for hydrotreating, electrical power, steam for enhanced oil recovery and distillation, etc. This paper describes the Texaco Gasification Process and the T-STARs hydrotreating process, and their application in an integrated upgrade processing scheme in which an optimal, virtually bottomless oil utilization can be achieved. Illustrative examples of this integration are provided with comparative economic information.

  5. Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.

    SciTech Connect

    Arora, S.; Wu, M.; Wang, M.; Energy Systems

    2011-02-01

    Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

  6. New Design Methods and Algorithms for Energy Efficient Multicomponent Distillation Column Trains

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Methods and Algorithms for Energy Efficient Multicomponent Distillation Column Trains Enabling optimal configurations for high volume chemical separations Distillation is a ubiquitous method in the chemical and petrochemical industries to separate mixtures into their individual components and accounts for a large percentage of all separations in chemical and petrochemical plants. A large fraction of the separations are mixtures containing four or more components requiring multiple distillation

  7. New Design Methods and Algorithms for Energy Efficient Multicomponent Distillation Column Trains

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Rakesh Agrawal, School of Chemical Engineering, Purdue University U.S. DOE Advanced Manufacturing Office Program Review Meeting Washington, D.C. June 14-15, 2016 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective Distillation: Essential to Meet Human Needs Courtesy: static.squarespace.com/ Courtesy: ths.talawanda.org Project Objective Distillation: Essential to Meet Human Needs  Multicomponent distillation: ubiquitous in

  8. DOE Awards Storage Contracts for Northeast Home Heating Oil Reserve |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Storage Contracts for Northeast Home Heating Oil Reserve DOE Awards Storage Contracts for Northeast Home Heating Oil Reserve August 18, 2011 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy (DOE) today announced that new contracts have been awarded for commercial storage of 650,000 barrels of ultra low sulfur distillate (ULSD) for the Northeast Home Heating Oil Reserve (NEHHOR). Awards were made to two companies for storage in New England--Hess Corporation

  9. Lime addition to heavy crude oils prior to coking

    SciTech Connect

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, or residua is decreased by the addition of slaked lime or calcium oxide to the heavy crude oil prior to coking. The presence of the slaked lime or calcium oxide leads to an increased yield of liquid distillates at coking temperatures of about 450/sup 0/ to about 500/sup 0/ C. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  10. Fractional distillation of C/sub 2//C/sub 3/ hydrocarbons at optimum pressures

    SciTech Connect

    Tedder, D.W.

    1984-08-07

    A method of recovering by distillation the separate components of a hydrocarbon gas mixture comprising ethylene, ethane, propylene and propane which comprises separating the ethylene and ethane as an overhead from a propylene and propane bottom in a first distillation tower at from about 400 to about 600 psia, separating ethylene and ethane as an ethylene overhead and an ethane bottom in a second distillation tower at from about 600 to about 700 psia, and separating propylene as an overhead from a propane bottom in a third distillation tower at from about 280 to about 300 psia is disclosed.

  11. T-534: Vulnerability in the PDF distiller of the BlackBerry Attachment...

    Energy.gov [DOE] (indexed site)

    PROBLEM: Vulnerability in the PDF distiller of the BlackBerry Attachment Service for the BlackBerry Enterprise Server. PLATFORM: * BlackBerry Enterprise Server Express version...

  12. Large-Scale Algal Cultivation, Harvesting and Downstream Processing Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    ATP3 (Algae Testbed Public-Private Partnership) is hosting the Large-Scale Algal Cultivation, Harvesting and Downstream Processing Workshop on November 2–6, 2015, at the Arizona Center for Algae Technology and Innovation in Mesa, Arizona. Topics will include practical applications of growing and managing microalgal cultures at production scale (such as methods for handling cultures, screening strains for desirable characteristics, identifying and mitigating contaminants, scaling up cultures for outdoor growth, harvesting and processing technologies, and the analysis of lipids, proteins, and carbohydrates). Related training will include hands-on laboratory and field opportunities.

  13. World oil trends

    SciTech Connect

    Anderson, A. )

    1991-01-01

    This book provides data on many facets of the world oil industry topics include; oil consumption; oils share of energy consumption; crude oil production; natural gas production; oil reserves; prices of oil; world refining capacity; and oil tankers.

  14. U.S. Adjusted Sales of Distillate Fuel Oil by End Use

    Energy Information Administration (EIA) (indexed site)

    Area: U.S. East Coast (PADD 1) New England (PADD 1A) Connecticut Maine Massachusetts New Hampshire Rhode Island Vermont Central Atlantic (PADD 1B) Delaware District of Columbia Maryland New Jersey New York Pennsylvania Lower Atlantic (PADD 1C) Florida Georgia North Carolina South Carolina Virginia West Virginia Midwest (PADD 2) Illinois Indiana Iowa Kansas Kentucky Michigan Minnesota Missouri Nebraska North Dakota Ohio Oklahoma South Dakota Tennessee Wisconsin Gulf Coast (PADD 3) Alabama

  15. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Energy Information Administration (EIA) (indexed site)

    October ... 14,752.6 69,758.6 7,217.1 15,271.7 21,969.7 85,030.3 3,137.2 25,623.2 25,106.9 110,653.4 November ... 14,904.2...

  16. Stocks of Distillate Fuel Oil Greater Than 15 ppm to 500 ppm...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    7,736 8,385 8,505 8,299 1993-2016 PADD 1 5,695 5,241 5,102 5,162 5,289 5,069 1993-2016 New England 3,839 3,354 3,250 3,424 3,460 3,335 1993-2016 Central Atlantic 1,426 1,524...

  17. ,"U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End...

    Energy Information Administration (EIA) (indexed site)

    worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Residential",4,"Annual",2013,"6301984" ,"Data...

  18. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook

    25,794.3 125,232.3 November ... 14,453.5 66,101.3 8,392.5 14,607.4 22,846.0 80,708.7 3,071.6 38,342.1 25,917.7 119,050.8 December ......

  19. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook

    I January ... 3,767.8 15,166.2 1,271.9 3,441.5 5,039.7 18,607.8 1,103.3 23,611.9 6,143.0 42,219.7 February ... 4,023.0 15,858.8...

  20. Refiner and Blender Net Production of Distillate Fuel Oil 15 ppm Sulfur and

    Gasoline and Diesel Fuel Update

    Under 4,159 4,271 4,245 4,219 4,421 4,654 2004-2016 PADD 1 331 323 347 299 363 349 2004-2016 PADD 2 1,017 1,110 1,101 1,109 1,099 1,111 2004-2016 PADD 3 2,131 2,182 2,158 2,205 2,287 2,465 2004-2016 PADD 4 211 189 186 203 209 224 2004-2016 PADD 5 469 468 454 403 462 505 2004

  1. Refiner and Blender Net Production of Distillate Fuel Oil > 15 pmm to 500

    Gasoline and Diesel Fuel Update

    ppm Sulfur 67 99 8 104 81 77 1993-2016 PADD 1 15 22 5 50 8 5 1993-2016 PADD 2 -9 -2 -4 -3 5 0 1993-2016 PADD 3 53 75 12 40 50 56 1993-2016 PADD 4 0 1 0 5 11 1 1993-2016 PADD 5 7 2 -5 13 7 15 1993

  2. Refiner and Blender Net Production of Distillate Fuel Oil > 500 ppm Sulfur

    Gasoline and Diesel Fuel Update

    Weekly 4-Week Average Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 10/07/16 10/14/16 10/21/16 10/28/16 11/04/16 11/11/16 View History U.S. 270 229 282 338 282 253 1993-2016 PADD 1 31 28 21 44 27 19 1993-2016 PADD 2 -13 -14 -12 6 -13 7 1993-2016 PADD 3 228 197 254 260 251 210 1993-2016 PADD 4 -2 -1 0 -1 -1 -1 1993-2016 PADD 5 26 19 20 29 18 18 1993

  3. U.S. Sales of Distillate Fuel Oil by End Use

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Area: U.S. East Coast (PADD 1) New England (PADD 1A) Connecticut Maine Massachusetts New Hampshire Rhode Island Vermont Central Atlantic (PADD 1B) Delaware District of Columbia ...

  4. Comparison of advanced distillation control methods. Third annual report

    SciTech Connect

    Riggs, J.B.

    1997-07-01

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls, feedforward from a feed composition analyzer, and decouplers. Auto Tune Variation (ATV) identification with on-line detuning for setpoint changes was used for tuning the diagonal proportional integral (PI) composition controls. In addition, robustness tests were conducted by inducting reboiler duty upsets. For single composition control, the (L, V) configuration was found to be best. For dual composition control, the optimum configuration changes from one column to another. Moreover, the use of analysis tools, such as RGA, appears to be of little value in identifying the optimum configuration for dual composition control. Using feedforward from a feed composition analyzer and using decouplers are shown to offer significant advantages for certain specific cases.

  5. Low capital implementation of distributed distillation in ethylene recovery

    DOEpatents

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  6. UV resonance Raman characterization of polycyclic aromatic hydrocarbons in coal liquid distillates

    SciTech Connect

    Rumelfanger, R.; Asher, S.A.; Perry, M.B.

    1988-02-01

    Ultraviolet resonance Raman spectroscopy has been used to characterize the polycyclic aromatic hydrocarbon composition of a series of distillates of coal-derived liquids. The UV Raman spectra easily monitor changes in the polycyclic aromatic hydrocarbon composition as a function of distillation temperature. Specific species, such as pyrene, can be determined by judicious choice of excitation wavelength.

  7. Crude oil and shale oil

    SciTech Connect

    Mehrotra, A.K.

    1995-06-15

    This year`s review on crude oil and shale oil has been prepared by classifying the references into the following main headings: Hydrocarbon Identification and Characterization, Trace Element Determination, Physical and Thermodynamic Properties, Viscosity, and Miscellaneous Topics. In the two-year review period, the references on shale oils were considerably less in number than those dealing with crude oils. Several new analytical methodologies and applications were reported for hydrocarbon characterization and trace element determination of crude oils and shale oils. Also included in this review are nine U.S., Canadian British and European patents. 12 refs.

  8. Kinetics of heavy oil/coal coprocessing

    SciTech Connect

    Szladow, A.J.; Chan, R.K. ); Foudu, S.; Kelly, J.F. )

    1988-06-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modelling of the CANMET coal/heavy oil coprocessing process. CANMET has been conducting research and process development work on coprocessing of Canadian heavy oil/bitumen and coal since 1979 including studies of the kinetics and mechanisms of coprocessing. As a continuation of the program, CANMET and Lobbe Technologies undertook a project on mathematical modelling of coprocessing kinetics with emphasis on the development of reaction engineering models for improved process performance and operation.

  9. The role of interruptible natural gas customers in New England heating oil markets: A preliminary examination of events in January-February 2000

    SciTech Connect

    2000-11-01

    This report provides an analysis of data collected from gas service providers and end-use customers in the six New England States and offers a preliminary assessment of the impact of interruptible gas customers on the distillate fuel oil market this past winter. Based on information collected and analyzed as of October 2000, the main findings areas follows: (1) For interruptible gas customers with distillate fuel oil as a backup fuel, their volume of interruptions was equivalent to about 1 to 2 percent of the total sales of distillate fuel oil in New England during January-February 2000. For the two peak weeks of gas supply interruptions, however, the equivalent volume of distillate fuel oil amounted to an estimated 3 to 6 percent of total sales in New England. There were no interruptions of the natural gas service during the 2-month period. (2) Purchases of distillate fuel oil by interruptible gas customers may have contributed somewhat to the spike in the price of distillate fuel oil in January-February 2000, especially during the peak weeks of gas interruptions. Nevertheless, other factors--a sudden drop in temperatures, low regional stocks of distillate fuels, and weather-related supply problems during a period of high customer demand--appear to have played a significant role in this price spike, as they have in previous spikes. (3) While this preliminary analysis suggests that interruptible natural gas service does not threaten the stability of the home heating oil market, several steps might be taken-without undermining the benefits of interruptible service--to reduce the potential adverse impacts of gas supply interruptions in times of market stress. Regardless of the magnitude of the impact of distillate fuel oil purchases by interruptible gas customers on Northeast heating oil markets, the threat of future heating oil price spikes and supply problems still remains. To help counter the threat, President Clinton in July 2000 directed Secretary Richardson to

  10. Corrosion impact of reductant on DWPF and downstream facilities

    SciTech Connect

    Mickalonis, J. I.; Imrich, K. J.; Jantzen, C. M.; Murphy, T. H.; Wilderman, J. E.

    2014-12-01

    Glycolic acid is being evaluated as an alternate reductant in the preparation of high level waste for the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS). During processing, the glycolic acid is not completely consumed and small quantities of the glycolate anion are carried forward to other high level waste (HLW) facilities. The impact of the glycolate anion on the corrosion of the materials of construction throughout the waste processing system has not been previously evaluated. A literature review had revealed that corrosion data in glycolate-bearing solution applicable to SRS systems were not available. Therefore, testing was recommended to evaluate the materials of construction of vessels, piping and components within DWPF and downstream facilities. The testing, conducted in non-radioactive simulants, consisted of both accelerated tests (electrochemical and hot-wall) with coupons in laboratory vessels and prototypical tests with coupons immersed in scale-up and mock-up test systems. Eight waste or process streams were identified in which the glycolate anion might impact the performance of the materials of construction. These streams were 70% glycolic acid (DWPF feed vessels and piping), SRAT/SME supernate (Chemical Processing Cell (CPC) vessels and piping), DWPF acidic recycle (DWPF condenser and recycle tanks and piping), basic concentrated recycle (HLW tanks, evaporators, and transfer lines), salt processing (ARP, MCU, and Saltstone tanks and piping), boric acid (MCU separators), and dilute waste (HLW evaporator condensate tanks and transfer line and ETF components). For each stream, high temperature limits and worst-case glycolate concentrations were identified for performing the recommended tests. Test solution chemistries were generally based on analytical results of actual waste samples taken from the various process facilities or of prototypical simulants produced in the laboratory. The materials of construction for most vessels

  11. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Energy Saver

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil)...

  12. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) ...

  13. Thermal oscillations downstream of an elbow in stratified pipe flow

    SciTech Connect

    Kuzay, T.M.; Kasza, K.E.

    1984-01-01

    In previously published papers, the test geometry, test methodology and the scope of the thermal transient induced pipe stratification studies at Argonne National Laboratory (ANL) were explained. In these prior studies, limited fluid temperature data from elbow inlet and exit plane thermocouples indicated the presence of large-amplitude thermal fluctuations for conditions in which the horizontal pipe upstream of the elbow developed stratified flow induced by a pipe entrant thermal transient. Under severe transient conditions, thermal oscillations of amplitude of almost 70 percent of the pipe inlet transient temperature change were observed in the bulk flow. TC data and accompanying flow visualization test results showed that the largest near wall thermal oscillations were located within and immediately downstream of the elbow. The thermal oscillations if they are of large enough amplitude, of the appropriate frequency, and of sufficiently long duration can cause thermal stripping and thermal-fatigue stress cracking in the elbow region. A specially instrumented test section was fabricated to study these thermal fluctuations.

  14. Venezuelan oil

    SciTech Connect

    Martinez, A.R. )

    1989-01-01

    Oil reserves have been known to exist in Venezuela since early historical records, however, it was not until the 20th century that the extensive search for new reserves began. The 1950's marked the height of oil exploration when 200 new oil fields were discovered, as well as over 60{percent} of proven reserves. Venezuela now produces one tone in seven of crude oil consumption and the country's abundant reserves such as the Bolivar Coastal field in the West of the country and the Orinoco Belt field in the East, will ensure it's continuing importance as an oil producer well into the 21st century. This book charts the historical development of Venezuela oil and provides a chronology of all the significant events which have shaped the oil industry of today. It covers all the technical, legal, economic and political factors which have contributed to the evolution of the industry and also gives information on current oil resources and production. Those events significant to the development of the industry, those which were influential in shaping future policy and those which precipitated further action are included. The book provides a source of reference to oil companies, oil economists and petroleum geologists.

  15. Kinetic and reactor models for HDT of middle distillates

    SciTech Connect

    Cotta, R.M.; Filho, R.M.

    1996-12-31

    Hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of middle distillates over a commercial Ni-Mo/y-Al{sub 2}O{sub 3} has been studied under wide operating conditions just as 340 to 380{degrees}C and 38 to 98 atm. A Power Law model was presented to each one of those reactions. The parameters of kinetic equations were estimated solving the ordinary differential equations by the 4 order Runge-Kutta-Gill algorithm and Marquardt method for searching of set of kinetic parameters (kinetic constants as well as the orders of reactions). An adiabatic diesel hydrotreating trickle-bed reactor packed with the same catalyst was simulated numerically in order to check up the behavior of this specific reaction system. One dimensional pseudo-homogeneous model was used in this work. For each feed, the mass and energy balance equations were integrated along the length of the catalytic bed using the 4th Runge-Kutta-Gill method. The performance of two industrial reactors was checked. 5 refs., 2 tabs.

  16. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  17. Use of extractive distillation to produce concentrated nitric acid

    SciTech Connect

    Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

    1981-04-01

    Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

  18. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect

    1996-11-01

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls. ATV identification with on-line detuning was used for tuning the diagonal PI composition controllers. Each configuration was evaluated with respect to steady-state RGA values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity), were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  19. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect

    Riggs, J.B.

    1996-11-01

    Detailed dynamic simulations of two industrial distillation columns (a propylene/propane splitter and a xylene/toluene column) have been used to study the issue of configuration selection for diagonal PI dual composition controls. Auto Tune Variation (ATV) identification with on-line detuning was used for tuning the diagonal proportional integral (PI) composition controls. Each configuration was evaluated with respect to steady-state relative gain array (RGA) values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity) were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  20. Distillation sequence for the purification and recovery of hydrocarbons

    DOEpatents

    Reyneke, Rian; Foral, Michael; Papadopoulos, Christos G.; Logsdon, Jeffrey S.; Eng, Wayne W. Y.; Lee, Guang-Chung; Sinclair, Ian

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  1. Fractional distillation as a strategy for reducing the genotoxic potential of SRC-II coal liquids: a status report

    SciTech Connect

    Pelroy, R.A.; Wilson, B.W.

    1981-09-01

    This report presents results of studies on the effects of fractional distillation on the genotoxic potential of Solvent Refined Coal (SRC-II) liquids. SRC-II source materials and distilled liquids were provided by Pittsburg and Midway Coal Mining Co. Fractional distillations were conducted on products from the P-99 process development unit operating under conditions approximating those anticipated at the SRC-II demonstration facility. Distillation cuts were subjected to chemical fractionation, in vitro bioassay and initial chemical analysis. Findings are discussed as they relate to the temperature at which various distillate cuts were produced. This document is the first of two status reports scheduled for 1981 describing these studies.

  2. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    Energy Information Administration (EIA) (indexed site)

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  3. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    Energy Information Administration (EIA) (indexed site)

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  4. U.S. Total No. 2 Distillate Prices by Sales Type

    Gasoline and Diesel Fuel Update

    2010 2011 2012 2013 2014 2015 View History No. 2 Distillate Sales to End Users, Average 2.449 - - - - - 1983-2015 Residential 2.798 - - - - - 1978-2015 CommercialInstitutional ...

  5. New Design Methods and Algorithms for Multi-component Distillation Processes

    SciTech Connect

    2009-02-01

    This factsheet describes a research project whose main goal is to develop methods and software tools for the identification and analysis of optimal multi-component distillation configurations for reduced energy consumption in industrial processes.

  6. A heat & mass integration approach to reduce capital and operating costs of a distillation configuration

    SciTech Connect

    Madenoor Ramapriya, Gautham; Jiang, Zheyu; Tawarmalani, Mohit; Agrawal, Rakesh

    2015-11-11

    We propose a general method to consolidate distillation columns of a distillation configuration using heat and mass integration. The proposed method encompasses all heat and mass integrations known till date, and includes many more. Each heat and mass integration eliminates a distillation column, a condenser, a reboiler and the heat duty associated with a reboiler. Thus, heat and mass integration can potentially offer significant capital and operating cost benefits. In this talk, we will study the various possible heat and mass integrations in detail, and demonstrate their benefits using case studies. This work will lay out a framework to synthesize an entire new class of useful configurations based on heat and mass integration of distillation columns.

  7. Do-it-yourself guideline for constructing a solar alcohol distillation system

    SciTech Connect

    Kennedy, B.W.

    1982-07-27

    The development and testing of a solar powered distillation system are described. The system consists of a parabolic dish collector, a two axis sun tracking stand, sun tracking solar cell system, condenser, fermentation tanks, and continuous distillation still. The assembly instructions for the parabolic dish are included as well as the basic steps to follow in mashing and fermenting of corn meal. 15 figures. (DMC)

  8. Quantum tomographic cryptography with Bell diagonal states: Nonequivalence of classical and quantum distillation protocols

    SciTech Connect

    Kaszlikowski, Dagomir; Lim, J.Y.; Willeboordse, Frederick H.; Oi, D.K.L.; Gopinathan, Ajay; Kwek, L.C.

    2005-01-01

    We present a generalized tomographic quantum key distribution protocol in which the two parties share a Bell diagonal mixed state of two qubits. We show that if an eavesdropper performs a coherent measurement on many quantum ancilla states simultaneously, classical methods of secure key distillation are less effective than quantum entanglement distillation protocols. We also show that certain classes of Bell diagonal states are resistant to any attempt at incoherent eavesdropping.

  9. Comparison of Advanced Distillation Control Methods, Final Technical Report

    SciTech Connect

    Dr. James B. Riggs

    2000-11-30

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to evaluate configuration selections for single-ended and dual-composition control, as well as to compare conventional and advanced control approaches. In addition, a simulator of a main fractionator was used to compare the control performance of conventional and advanced control. For each case considered, the controllers were tuned by using setpoint changes and tested using feed composition upsets. Proportional Integral (PI) control performance was used to evaluate the configuration selection problem. For single ended control, the energy balance configuration was found to yield the best performance. For dual composition control, nine configurations were considered. It was determined that the use of dynamic simulations is required in order to identify the optimum configuration from among the nine possible choices. The optimum configurations were used to evaluate the relative control performance of conventional PI controllers, MPC (Model Predictive Control), PMBC (Process Model-Based Control), and ANN (Artificial Neural Networks) control. It was determined that MPC works best when one product is much more important than the other, while PI was superior when both products were equally important. PMBC and ANN were not found to offer significant advantages over PI and MPC. MPC was found to outperform conventional PI control for the main fractionator. MPC was applied to three industrial columns: one at Phillips Petroleum and two at Union Carbide. In each case, MPC was found to significantly outperform PI controls. The major advantage of the MPC controller is its ability to effectively handle a complex set of constraints and control objectives.

  10. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect

    Pierce, R. A.; Pak, D. J.

    2012-09-11

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  11. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  12. Kinetics of heavy oil/coal coprocessing

    SciTech Connect

    Szladow, A.J.; Chan, R.K.; Fouda, S.; Kelly, J.F. )

    1988-01-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modeling of the CANMET coal/heavy oil coprocessing process. A number of reaction networks were evaluated for CANMET coprocessing. The final choice of model was a parallel model with some sequential characteristics. The model explained 90.0 percent of the total variance, which was considered satisfactory in view of the difficulties of modeling preasphaltenes. The models which were evaluated showed that the kinetic approach successfully applied to coal liquefaction and heavy oil upgrading can be also applied to coprocessing. The coal conversion networks and heavy oil upgrading networks are interrelated via the forward reaction paths of preasphaltenes, asphaltenes, and THFI and via the reverse kinetic paths of an adduct formation between preasphaltenes and heavy oil.

  13. Collisionless relaxation of downstream ion distributions in low-Mach number shocks

    SciTech Connect

    Gedalin, M.; Friedman, Y.; Balikhin, M.

    2015-07-15

    Collisionlessly formed downstream distributions of ions in low-Mach number shocks are studied. General expressions for the asymptotic value of the ion density and pressure are derived for the directly transmitted ions. An analytical approximation for the overshoot strength is suggested for the low-β case. Spatial damping scale of the downstream magnetic oscillations is estimated.

  14. Formation of coke from heavy crude oils in the presence of calcium carbonate

    SciTech Connect

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, and residua, is decreased by the addition of calcium carbonate, preferably in the form of limestone, to the heavy crude oil prior to coking. The presence of the limestone leads to an increased yield of liquid distillates from the coking process under preferred coking conditions. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  15. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  16. Experimental investigation on hydrogen cryogenic distillation equipped with package made by ICIT

    SciTech Connect

    Bornea, A.; Zamfirache, M.; Stefan, L.; Stefanescu, I.; Preda, A.

    2015-03-15

    ICIT (Institute for Cryogenics and Isotopic Technologies) has used its experience in cryogenic water distillation process to propose a similar process for hydrogen distillation that can be used in detritiation technologies. This process relies on the same packages but a stainless filling is tested instead of the phosphorous bronze filling used for water distillation. This paper presents two types of packages developed for hydrogen distillation, both have a stainless filling but it differs in terms of density, exchange surface and specific volume. Performance data have been obtained on laboratory scale. In order to determine the characteristics of the package, the installation was operated in the total reflux mode, for different flow rate for the liquid. There were made several experiments considering different operating conditions. Samples extracted at the top and bottom of cryogenic distillation column allowed mathematical processing to determine the separation performance. The experiments show a better efficiency for the package whose exchange surface was higher and there were no relevant differences between both packages as the operating pressure of the cryogenic column was increasing. For a complete characterization of the packages, future experiments will be considered to determine performance at various velocities in the column and their correlation with the pressure in the column. We plan further experiments to separate tritium from the mixture of isotopes DT, having in view that our goal is to apply this results to a detritiation plant.

  17. Investigation and development of alternative methods for shale oil processing and analysis. Final technical report, October 1979--April 1983

    SciTech Connect

    Evans, R.A.

    1998-06-01

    Oil shale, a carbonaceous rock which occurs abundantly in the earth`s crust, has been investigated for many years as an alternate source of fuel oil. The insoluble organic matter contained in such shales is termed {open_quotes}Kerogen{close_quotes} from the Greek meaning oil or oil forming. The kerogen in oil shale breaks down into oil-like products when subjected to conditions simulating destructive distillation. These products have been the subject of extensive investigations by several researchers and many of the constituents of shale oil have been identified. (1) Forsman (2) estimates that the kerogen content of the earth is roughly 3 {times} 10{sup 15} tons as compared to total coal reserves of about 5 {times} 10{sup 12}. Although the current cost per barrel estimate for commercial production of shale oil is higher than that of fossil oil, as our oil reserves continue to dwindle, shale oil technology will become more and more important. When oil shale is heated, kerogen is said to undergo chemical transformation to usable oil in two steps (3): Kerogen (in oil shale) 300-500{degrees}C bitumen. Crude shale oil and other products. The crude shale oil so obtained differs from fossil oil in that: (1) kerogen is thought to have been produced from the aging of plant matter over many years; (2) shale oil has a higher nitrogen content than fossil oil; (3) non-hydrocarbons are present to a much greater extent in shale oil; and (4) the hydrocarbons in shale oil are much more unsaturated than those in fossil oil (petroleum).

  18. ,"Total Fuel Oil Expenditures

    Energy Information Administration (EIA) (indexed site)

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  19. ,"Total Fuel Oil Consumption

    Energy Information Administration (EIA) (indexed site)

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  20. ,"Total Fuel Oil Expenditures

    Energy Information Administration (EIA) (indexed site)

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  1. ,"Total Fuel Oil Expenditures

    Energy Information Administration (EIA) (indexed site)

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  2. ,"Total Fuel Oil Consumption

    Energy Information Administration (EIA) (indexed site)

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  3. Measurement of velocity deficit at the downstream of a 1:10 axial hydrokinetic turbine model

    SciTech Connect

    Gunawan, Budi; Neary, Vincent S; Hill, Craig; Chamorro, Leonardo

    2012-01-01

    Wake recovery constrains the downstream spacing and density of turbines that can be deployed in turbine farms and limits the amount of energy that can be produced at a hydrokinetic energy site. This study investigates the wake recovery at the downstream of a 1:10 axial flow turbine model using a pulse-to-pulse coherent Acoustic Doppler Profiler (ADP). In addition, turbine inflow and outflow velocities were measured for calculating the thrust on the turbine. The result shows that the depth-averaged longitudinal velocity recovers to 97% of the inflow velocity at 35 turbine diameter (D) downstream of the turbine.

  4. Bitumen and heavy oil upgrading in Canada

    SciTech Connect

    Chrones, J. ); Germain, R.R. )

    1989-01-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulphur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional projects, also based on hydrogenation, will use ebullated bed catalyst systems; the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  5. Bitumen and heavy oil upgrading in Canada

    SciTech Connect

    Chrones, J.

    1988-06-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulfur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader, now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional products, also based on hydrogenation, will use ebullated bed catalyst systems: the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  6. Low-temperature distillation plants: a comparison with seawater reverse osmosis

    SciTech Connect

    Hoffman, D.

    1981-07-01

    Low-temperature distillation plants using large aluminum-alloy heat-transfer surfaces have reduced energy requirements to levels projected today for second-generation seawater reverse-osmosis (SWRO) plants. Less sensitive to feed contamination, and totally free from maintenance associated with a complex and critical feed-pretreatment system and periodic membrane replacements, the low-temperature distillation plants out-perform SWRO plants also by their higher-quality product, 2-10 ppM TDS versus 300 to 1000 ppM TDS. Energy requirements and operating costs for Low Temperature Vapor Compression (LT-VC) and Multi-Effect-Distillation (LT-MED) plants, in dual-purpose and various waste-heat-utilization schemes, are compared with those of SWRO plants. 10 references, 14 figures, 8 tables.

  7. Global optimization of multicomponent distillation configurations: 2. Enumeration based global minimization algorithm

    DOE PAGES [OSTI]

    Nallasivam, Ulaganathan; Shah, Vishesh H.; Shenvi, Anirudh A.; Huff, Joshua; Tawarmalani, Mohit; Agrawal, Rakesh

    2016-02-10

    We present a general Global Minimization Algorithm (GMA) to identify basic or thermally coupled distillation configurations that require the least vapor duty under minimum reflux conditions for separating any ideal or near-ideal multicomponent mixture into a desired number of product streams. In this algorithm, global optimality is guaranteed by modeling the system using Underwood equations and reformulating the resulting constraints to bilinear inequalities. The speed of convergence to the globally optimal solution is increased by using appropriate feasibility and optimality based variable-range reduction techniques and by developing valid inequalities. As a result, the GMA can be coupled with already developedmore » techniques that enumerate basic and thermally coupled distillation configurations, to provide for the first time, a global optimization based rank-list of distillation configurations.« less

  8. Conversion of lpg hydrocarbons to distillate fuels or lubes using integration of lpg dehydrogenation and mogdl

    SciTech Connect

    Chang, C. D.; Penick, J. E.; Socha, R. F.

    1985-09-17

    Disclosed is a method and apparatus for producing distillate and/or lubes which employ integrating catalytic (or thermal) dehydrogenation of paraffins with MOGDL. The process feeds the product from a low temperature propane and/or butane dehydrogenation zone into a first catalytic reactor zone, which operates at low pressure and contains zeolite oligomerization catalysts, where the low molecular weight olefins are reacted to primarily gasoline range materials. These gasoline range materials can then be pressurized to the pressure required for reacting to distillate in a second catalytic reactor zone operating at high pressure and containing a zeolite oligomerization catalyst. The distillate is subsequently sent to a hydrotreating unit and product separation zone to form lubes and other finished products.

  9. Source book for planning nuclear dual-purpose electric/distillation desalination plants

    SciTech Connect

    Reed, S.A.

    1981-02-01

    A source book on nuclear dual-purpose electric/distillation desalination plants was prepared to assist government and other planners in preparing broad evaluations of proposed applications of dual-purpose plants. The document is divided into five major sections. Section 1 presents general discussions relating to the benefits of dual-purpose plants, and spectrum for water-to-power ratios. Section 2 presents information on commercial nuclear plants manufactured by US manufacturers. Section 3 gives information on distillation desalting processes and equipment. Section 4 presents a discussion on feedwater pretreatment and scale control. Section 5 deals with methods for coupling the distillation and electrical generating plants to operate in the dual mode.

  10. Systems and methods for reactive distillation with recirculation of light components

    DOEpatents

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  11. Maximize revenue by analyzing crude oil treating parameters

    SciTech Connect

    Pellegrino, V.L.; Crane, T.L.; Heiman, M.S.; Pantermuhl, L.

    1983-10-01

    In the past the Chemshare Design 2000 program has been utilized to model gas processing plant streams. This paper describes how the Chemshare Design 2000 program may be used to maximize lease revenues by modeling a crude oil treating system and presents a technique of recombining an ASTM Distillation and a gas sample to arrive at the original composition of the inlet oil stream for use with the Chemshare Program. Next the treating facility operations are evaluated in order to maximize revenues which depending on the crude could mean an increase or decrease in the treating temperatures and pressures. For a lease producing 21,000 BOPD the losses can easily surpass $2 MM per year due to oil shrinkage and gravity differential.

  12. Maximize revenue by analyzing crude oil treating parameters

    SciTech Connect

    Heiman, M.S.; Pellegrino, V.L.; Pantermuehl, L.A.; Crane, T.L.

    1983-01-01

    In the past, the Chemshare Design 2000 program has been utilized to model gas processing plant streams. This study describes how the Chemshare Design 2000 program may be used to maximize lease revenues by modeling a crude oil treating system and presents a technique of recombining an ASTM distillation and a gas sample to arrive at the original composition of the inlet oil stream for use with the Chemshare Program. Next the treating facility operations are evaluated in order to maximize revenues which, depending on the crude, could mean an increase or decrease in the treating temperatures and pressures. For a lease producing 21,000 bopd the losses can easily surpass $2.0 MM/yr due to oil shrinkage and gravity differential.

  13. Oil products distribution in Iran: a planning approach

    SciTech Connect

    Abrishami, H.

    1986-01-01

    The significance of this study is that it examines the functions of the most important element in the public sector of the economy of Iran - the Ministry of Oil. Oil is the main source of Iran's foreign earnings and the commodity most crucial to the country's economy as its prime export. Furthermore, it plays a vital role in meeting domestic energy demands. The distribution of oil products affects, on the one hand, households, small businesses, and larger industries while, on the other, it affects the allocation, in general of other national resources. Accordingly, the effects of the Ministry of Oil's policies with regard to its production-distribution system cannot be overemphasized. The research entailed has elicited certain factors: The Ministry of Oil's present system suffers from a number of weaknesses in its production-distribution design. These deficiencies involved, among others, terminal location, number of terminals, assignment of terminals to customers, substitution of other major sources of energy for major oil products, the middle distillates problem, and an outmoded distribution method and techniques. This dissertation addresses alternatives that will eliminate faults in the present system. The approach and conclusions of this research have the potential of application to any type of industry in Iran - oil or otherwise, whether in the private or public sector - that has a similar intricate distribution-system design subject to similar variables.

  14. Comparison between continuous stirred tank reactor extractor and soxhlet extractor for extraction of El-Lajjun oil shale

    SciTech Connect

    Anabtawi, M.Z.

    1996-02-01

    Extraction on El-Lajjun oil shale in a continuous stirred tank reactor extractor (CSTRE) and a Soxhlet extractor was carried out using toluene and chloroform as solvents. Solvents were recovered using two distillation stages, a simple distillation followed by a fractional distillation. Gas chromotography was used to test for the existence of trapped solvent in the yield. It was found that extraction using a CSTRE gave a 12% increase in yield on average compared with the Soxhlet extractor, and an optimum shale size of 1.0mm offered a better yield and solvent recovery for both techniques. It was also found that an optimum ratio of solvent to oil shale of 2:1 gave the best oil yield. The Soxhlet extractor was found to offer an extraction rate of 1 hour to complete extraction compared with 4 hours in a CSTRE. The yield in a CSTRE was found to increase on increase of stirring. When extraction was carried out at the boiling point of the solvents in a CSTRE, the yield was found to increase by 30% on average compared to that of extraction when the solvent was at room temperature. When toluene was used for extraction, the average amount of bitumen extracted was 0.032 g/g of oil shale and 76.4% of the solvent recovered, compared with 0.037 g/g of oil shale and 84.1% of the solvent recovered using a Soxhlet extractor.

  15. Corrosion and protection of mild steel in petroleum distillates electrolyte mixtures

    SciTech Connect

    Groysman, A.; Erdman, N.

    1999-11-01

    The purpose of this study is to examine the influence of water and salts present on the corrosion process in petroleum distillate electrolyte mixtures and evaluation of inorganic inhibitors efficiency for protection of mild steel in these mixtures. Most of the research in this area until now was done with hydrocarbon water mixtures with relatively high concentrations of water (above 5 % volume). This study was conducted using mixtures of light petroleum distillates (naphtha and gasoline) and water with water concentrations in the mixture below 5% volume. The study confirmed the electrochemical origin of the corrosion mechanism and showed that the main cause of the corrosion in the petroleum distillate water mixtures is the presence of water and dissolved oxygen. Critical added water concentrations were evaluated for naphtha-water and gasoline-water mixtures. The most efficient concentrations of inorganic inhibitors were determined and the inhibition mechanism was confirmed. Valuable data regarding different types of corrosion attack (pitting or uniform corrosion) on mild steel in petroleum distillate electrolyte mixtures was acquired during the study.

  16. Hybrid Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction

    SciTech Connect

    Eldridge, R. Bruce; Seibert, A. Frank; Robinson, Sharon; Rogers, Jo

    2005-04-01

    This report focuses on improving the existing separations systems for the two largest energy-consuming sectors: the chemicals and petroleum refining industries. It identifies the technical challenges and research needs for improving the efficiency of distillation systems. Areas of growth are also highlighted.

  17. Conversion of LPG hydrocarbons to distillate fuels or lubes using integration of LPG dehydrogenation and mogdl

    SciTech Connect

    Chang, C.D.; Penick, J.E.; Socha, R.F.

    1987-07-07

    This patent describes an apparatus for producing distillates of lubes from paraffins, which comprise: (a) a dehydrogenation reactor including means for passing a paraffinic feedstock stream into a dehydrogenation zone at conditions of pressure and temperature selected to convert the paraffins to an olefin rich effluent stream comprising at least one of the group consisting of propylene and butylene; (b) a low pressure oligomerization catalytic reactor including means for contacting the olefin rich effluent stream in a low pressure oligomerization catalytic reactor zone with a crystalline zeolite oligomerization catalyst at conditions of pressure and temperature selected to convert olefins to a first reactor effluent stream rich in liquid olefinic gasoline range hydrocarbons; (c) a first means for separating the first reactor effluent stream to form a substantially liquid C/sub 5/+ rich stream and a C/sub 4/- rich stream; (d) means for passing the C/sub 5/+ rich stream to a high pressure oligomerization catalytic reactor zone; (e) a high pressure oligomerization catalytic reactor including means for contacting the substantially liquid C/sub 5/+ rich stream in the high pressure oligomerization catalytic reactor zone with a crystalline zeolite oligomerization catalyst at conditions of temperature and pressure selected to produce a second reactor effluent stream which is rich in distillate; (f) second means for separating the second reactor effluent stream to recover an olefinic gasoline stream and a distillate stream; and (g) a hydrotreating reactor including means for contacting the distillate stream with hydrogen in a hydrotreating unit to produce a hydrotreated distillate stream comprising lube range hydrocarbons.

  18. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    SciTech Connect

    Carbognani, L.; Hazos, M.; Sanchez, V. ); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  19. FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds Breakout Session 2: Frontiers and Horizons ...

  20. Chemistry of hydrotreating heavy crudes: II. Detailed analysis of polar compounds in Wilmington 650-1000 degree F distillate and hydrotreated products

    SciTech Connect

    Sturm, G.P. Jr.; Green, J.B.; Tang, S.Y.; Reynolds, J.W.; Yu, S.K.T. )

    1987-04-01

    Notwithstanding the current oversupply of crude oil, the future importance of heavy crude as a primary energy resource is widely recognized. In addition, with the market for resid declining, refiners are facing an increasing challenge to convert more of the bottom of the barrel to transportation fuels. The problems that have been predicted for refinery products made from heavier feedstocks are now beginning to surface. State-of-the-art upgrading procedures have proven to be inadequate for removal of many of the chemical compound types that cause problems in the processing sequence or adversely affect the quality of the end products. These problems include instability or incompatibility of process streams or products, corrosiveness and catalyst poisoning. Before new approaches can be intelligently developed to remove the problem components, it is necessary to know what compound types are causing the observed problems. This study is focused on determination of polar compounds in the feedstock and products from hydrotreating a distillate of a representative heavy crude, Wilmington. The ultimate objective is to acquire an understanding of the compound types and reaction mechanisms contributing to instability, incompatibility, corrosiveness, catalyst poisoning and other problems exhibited by some crude oil feedstocks, intermediate process streams and final products resulting from the processing of lower quality fossil fuel feedstocks.

  1. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect

    Pierce, R.; Pak, D.

    2011-08-10

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current

  2. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study

  3. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    Energy Information Administration (EIA) (indexed site)

    . Total Fuel Oil Consumption and Expenditures for Non-Mall Buildings, 2003" ,"All Buildings* Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  4. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    Energy Information Administration (EIA) (indexed site)

    A. Total Fuel Oil Consumption and Expenditures for All Buildings, 2003" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  5. Residuum and heavy oil upgrading with the CANMET hydrocracking process

    SciTech Connect

    Patmore, D.J.; Khulbe, C.P.; Belinko, K.

    1981-03-01

    The advantages of the CANMET hydrocracking process are: Feed Flexibility - high levels of the main feed contaminants, sulfur, nitrogen and metals do not have a deleterious effect on the process. Hence, a wide range of feedstocks can be upgraded by this process including residuum from conventional crudes; Operability - extended runs indicate that the process will operate continuously with little sensitivity to operational problems even with difficult feedstocks such as Cold Lake and Boscan heavy oil. During extended operation nearly constant pitch conversion and product yields and qualities are obtained; High Distillate Yields - the CANMET Process can produce over 100 vol % distillate, compared to 83 vol % for coking process; Flexibility of Operation - the amount of pitch converted can easily be controlled by adjusting reactor temperature and liquid feed rate. Thus, the required product slate can be obtained by simply changing the operating conditions; Thermal Stability - because the process does not employ an active catalyst, the potential for thermal run-away and development of hot spots is considerably reduced; High Pitch Conversion - the CANMET additive permits sustained controlled and repeatable operation at pitch conversions higher than 90 wt % on a wide range of feedstocks; Reduced Operating Pressure - the action of the additive as a processing aid allows substantial reduction in operating pressure below that for competitive commercial technology; and Efficient Hydrogen Utilization - Since CANMET does not employ an active desulfurizing catalyst, overall hydrogen consumption for a given conversion is low. Almost all of the hydrogen goes to distillate product.

  6. ,"Catalytic Reforming Downstream Processing of Fresh Feed Input"

    Energy Information Administration (EIA) (indexed site)

    Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","8/2016","1/15/2010" ,"Release Date:","10/31/2016" ,"Next Release

  7. VEBA-cracking-processes for upgrading heavy oils and refinery residues

    SciTech Connect

    Graeser, U.; Niemann, K.

    1983-03-01

    More than 20 different heavy oils and residues have been processed by the VEBA-Combi-Cracking and VEBA-LQ-Cracking high pressure hydrocracking processes, in a bench scale unit. Conversions up to 99 wt % of to a syncrude, consisting of naphtha middle distillate and vacuum gas oil were obtained. Conversions correlate with space velocity at a given temperature and product pattern depends upon degree of conversion. The VEBA-LQ-Cracking process produces a stable syncrude whereas the products of the VEBA-Combi process are very low in sulfur and nitrogen.

  8. Hydrofining of Athabasca derived heavy gas oil over Ni-W and Co-Mo catalysts

    SciTech Connect

    Mann, R.S.; Diaz-real, R.

    1987-01-01

    The hydrotreatment of heavy gas oil derived from Athabasca bitumen was studied in a trickle bed reactor over Ni-W and Co-Mo zeolite catalyst at 350-425/sup 0/C, 3.55 to 10.44 MPa, and LHSV of 1-4. The effects of temperature and liquid flow rates on the product were investigated. ASTM distillation, aniline point, viscosities and densities of the product oil were measured and correlated with various parameters. Activity of the catalysts for hydrodenitrogenation is compared.

  9. Sludge formation during heavy oil upgrading

    SciTech Connect

    Storm, D.A.; Decanio, S.J.; Edwards, J.C.

    1995-12-31

    A soft coke-like substance often forms in the liquid product of visbreaking and hydrocracking processes for upgrading vacuum residue of heavy crude oil. This material usually limits the severity or conversion of the process because it accumulates in downstream equipment. Although the amount of such material produced depends on the crude oil, it has not been possible to correlate its production rate to chemical characteristics of the vacuum residue in a quantitative manner In this work we show that the amount of sludge produced per unit weight of vacuum residue feed in laboratory hydrotreating experiments can be correlated with four chemical characteristic of the vacuum residue: the degree of condensed polynuclear aromaticity, the average number of alkyl-groups substituting the polynuclear aromatics, the ratio of heptane insolubles to pentane insoluble-heptane solubles, and the H/C ratio of the latter fraction. The correlation coefficient is 0.95.

  10. Crude Oil | NISAC

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    NISACCrude Oil content top National Transportation Fuels Model Posted by tmanzan on Oct 3, ... by the network model (see figure) spans from oil fields to fuel distribution terminals. ...

  11. Oil Security Metrics Model

    SciTech Connect

    Greene, David L.; Leiby, Paul N.

    2005-03-06

    A presentation to the IWG GPRA USDOE, March 6, 2005, Washington, DC. OSMM estimates oil security benefits of changes in the U.S. oil market.

  12. Crude Oil Domestic Production

    Energy Information Administration (EIA) (indexed site)

    Data Series: Crude Oil Domestic Production Refinery Crude Oil Inputs Refinery Gross Inputs Refinery Operable Capacity (Calendar Day) Refinery Percent Operable Utilization Net ...

  13. Oil and Gas

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Oil and Gas Oil and Gas R&D focus on the use of conventional and unconventional fossil fuels, including associated environmental challenges Contact thumbnail of Business ...

  14. NETL: Oil & Gas

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Oil & Gas Efficient recovery of our nation's fossil fuel resources in an environmentally ... and challenging locations of many of our remaining oil and natural gas accumulations. ...

  15. Biochemically enhanced oil recovery and oil treatment

    DOEpatents

    Premuzic, Eugene T.; Lin, Mow

    1994-01-01

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  16. Biochemically enhanced oil recovery and oil treatment

    DOEpatents

    Premuzic, E.T.; Lin, M.

    1994-03-29

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  17. Composition-explicit distillation curves of aviation fuel JP-8 and a coal-based jet fuel

    SciTech Connect

    Beverly L. Smith; Thomas J. Bruno

    2007-09-15

    We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications to the classical measurement provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements that are true thermodynamic state points; (3) temperature, volume, and pressure measurements of low uncertainty suitable for an equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; (6) a trace chemical analysis of each distillate fraction; and (7) a corrosivity assessment of each distillate fraction. The most significant modification is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to the measurement of rocket propellant, gasoline, and jet fuels. In this paper, we present the application of the technique to representative batches of the military aviation fuel JP-8, and also to a coal-derived fuel developed as a potential substitute. We present not only the distillation curves but also a chemical characterization of each fraction and discuss the contrasts between the two fluids. 26 refs., 5 figs., 6 tabs.

  18. Crude oil and finished fuel storage stability: An annotated review

    SciTech Connect

    Whisman, M.L.; Anderson, R.P.; Woodward, P.W.; Giles, H.N.

    1991-01-01

    A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by all the citations for that category.

  19. A new hydrocracking catalyst for heavy oil upgrading

    SciTech Connect

    Itoh, T. )

    1987-04-01

    In comparison with ordinary oil, tar sands bitumen and vacuum residue contain large quantities of impurities such as asphaltene, heavy metal compounds, sulfur, and nitrogen, which are obstacles to upgrading the refining process. Therefore, these types of materials are extremely difficult to treat with existing refining technologies. In order to upgrade oil feedstocks that are of poor quality, such as tar sands bitumen, new upgrading technologies must be established. In this paper, the author discusses first, the results of catalyst screening, second, the factors of the active catalyst, and finally, the performance of a semi-industrially produced catalyst. The catalyst has high middle-distillate yield, coke plus gum (coke precursors) suppressing ability, low hydrogen consumption and mechanical strength and high temperature stability in slurry reactors.

  20. Oil Production

    Energy Science and Technology Software Center

    1989-07-01

    A horizontal and slanted well model was developed and incorporated into BOAST, a black oil simulator, to predict the potential production rates for such wells. The HORIZONTAL/SLANTED WELL MODEL can be used to calculate the productivity index, based on the length and location of the wellbore within the block, for each reservoir grid block penetrated by the horizontal/slanted wellbore. The well model can be run under either pressure or rate constraints in which wellbore pressuresmore » can be calculated as an option of infinite-conductivity. The model can simulate the performance of multiple horizontal/slanted wells in any geometric combination within reservoirs.« less

  1. World Crude Oil Prices

    Energy Information Administration (EIA) (indexed site)

    World Crude Oil Prices (Dollars per Barrel) The data on this page are no longer available.

  2. Eco Oil 4

    SciTech Connect

    Brett Earl; Brenda Clark

    2009-10-26

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  3. Report to Congress on the feasibility of establishing a heating oil component to the Strategic Petroleum Reserve. Volume 2: Appendices

    SciTech Connect

    1998-06-01

    Nine appendices to the main report are included in this volume. They are: Northeastern US distillate supply systems; New England fuel oil storage capacities and inventories; Characteristics of the northeast natural gas market; Documentation of statistical models and calculation of benefits; Regional product reserve study; Other countries` experience with refined product storage; Global refining supply demand appraisal; Summary of federal authorities relevant to the establishment of petroleum product reserves; Product stability and turnover requirements.

  4. Sluiceway Operations for Adult Steelhead Downstream Passage at The Dalles Dam, Columbia River, USA

    SciTech Connect

    Khan, Fenton; Royer, Ida M.; Johnson, Gary E.; Tackley, Sean C.

    2013-10-01

    This study evaluated adult steelhead (Oncorhynchus mykiss; fallbacks and kelts) downstream passage at The Dalles Dam in the Columbia River, USA, during the late fall, winter, and early spring months between 2008 and 2011. The purpose of the study was to determine the efficacy of operating the dam’s ice-and-trash sluiceway during non-spill months to provide a relatively safe, non-turbine, surface outlet for overwintering steelhead fallbacks and downstream migrating steelhead kelts. We applied the fixed-location hydroacoustic technique to estimate fish passage rates at the sluiceway and turbines of the dam. The spillway was closed during our sampling periods, which generally occurred in late fall, winter, and early spring. The sluiceway was highly used by adult steelhead (91–99% of total fish sampled passing the dam) during all sampling periods. Turbine passage was low when the sluiceway was not operated. This implies that lack of a sluiceway route did not result in increased turbine passage. However, when the sluiceway was open, adult steelhead used it to pass through the dam. The sluiceway may be operated during late fall, winter, and early spring to provide an optimal, non-turbine route for adult steelhead (fallbacks and kelts) downstream passage at The Dalles Dam.

  5. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    Energy Information Administration (EIA) (indexed site)

    A. Fuel Oil Consumption (Btu) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy Intensity (thousand Btu...

  6. Oil coking propensity under hydroprocessing conditions

    SciTech Connect

    Kriz, J.F. )

    1991-01-01

    If the processability of heavy or residual oil is assessed in terms of conversion to distillate oils, the tendency to form carbonaceous (coke) deposits in the reactor would impose limits on the operating conditions, since any significant coke accumulation on a continuing basis would be prohibitive. Experimentally, one can evaluate the feedstock coking propensity in a bench-scale reactor for a set of typical hydroprocessing conditions by varying the temperature near the threshold of coking. For a number of different feedstocks examined by this method, an empirical function can be found correlating the coking propensity with some of the characteristic properties determined by routine analyses. The present approach used a combination of physical and chemical properties including density and contents of Conradson Carbon residue, pentane and toluene insolubles, fraction of high-boiling pitch, and carbon, hydrogen, nitrogen, sulfur and ash. Feedstocks were chosen to cover a wide but practical range of properties to establish their impact on the coking propensity. Although these relationships apply to thermal hydroprocessing, the role of catalysts is also indicated.

  7. International oil companies in the Far East

    SciTech Connect

    Mlotok, P.

    1984-10-01

    All of the major international oil companies have extensive operations in the Far East, and in most cases, these operations account for a significant part of their worldwide earnings. In the refining and marketing end of the business, near-term profitability could be hampered by problems in the Singapore refining center. An expansion of Indonesian refining capacity has reduced profits from processing arrangements, and new Saudi product exports will enter Singapore starting this year. Longer term, however, the strong economic growth in the region renders it a highly attractive area in which to operate. On the producing end, rising output will boost profits for the international oil companies in Indonesia and Malaysia. Caltex (a 50/50 joint venture between Chevron and Texaco) is one of the largest marketers in the Far East. It will not initially be affected greatly by the Singapore refinery problem, as its production from this area goes directly into its own marketing system rather than into the open market. Exxon is a medium-size marketer with especially strong positions in Japan, Malaysia and Thailand. However, the company could be vulnerable to near-term problems in Singapore. Mobil, another medium-size marketer, has a very strong position in Japan but problems in Australia. As those problems are corrected, earnings should grow over time. The Royal Dutch Shell Group is one of the largest marketers in the Far East, with good positions in Singapore, Malaysia and Australia. Shell will have difficulty adjusting to the changing conditions in Singapore, but once this is complete, downstream earnings growth should resume. British Petroleum (BP) has a smaller upstream and downstream presence than the other international oils. Estimated 1983 Far East earnings are tabulated for these five companies. 5 figures.

  8. "Economic","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal"

    Energy Information Administration (EIA) (indexed site)

    4 Relative Standard Errors for Table 7.4;" " Unit: Percents." " ",," "," ",," "," " ,,"Residual","Distillate",,"LPG and" "Economic","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal" "Characteristic(a)","(kWh)","(gallons)","(gallons)","(1000 cu

  9. Synthesis of zeolite from Italian coal fly ash: Differences in crystallization temperature using seawater instead of distilled water

    SciTech Connect

    Belviso, Claudia; Cavalcante, Francesco; Fiore, Saverio

    2010-05-15

    In this study Italian coal fly ash was converted into several types of zeolite in laboratory experiments with temperatures of crystallization ranging from 35 up to 90 deg. C. Distilled and seawater were used during the hydrothermal synthesis process in separate experiments, after a pre-treatment fusion with NaOH. The results indicate that zeolites could be formed from different kind of Italian coal fly ash at low temperature of crystallization using both distilled and seawater. SEM data and the powder patterns of X-ray diffraction analysis show that faujasite, zeolite ZK-5 and sodalite were synthesized when using both distilled and seawater; zeolite A crystallized only using distilled water. In particular the experiments indicate that the synthesis of zeolite X and zeolite ZK-5 takes place at lower temperatures when using seawater (35 and 45 deg. C, respectively). The formation of sodalite is always competitive with zeolite X which shows a metastable behaviour at higher temperatures (70-90 deg. C). The chemical composition of the fly ash source could be responsible of the differences on the starting time of synthesized zeolite with distilled water, in any case our data show that the formation of specific zeolites takes place always at lower temperatures when using seawater.

  10. Catalytic deoxygenation of microalgae oil to green hydrocarbons

    SciTech Connect

    Zhao, Chen; Bruck, Thomas; Lercher, Johannes A.

    2013-05-14

    Microalgae are high potential raw biomass material for triglyceride feedstock, due to their high oil content and rapid growth rate, and because algae cultivation does not compete with edible food on arable land. This review addresses first the microalgae cultivation with an overview of the productivity and growth of microalgae, the recovery of lipids from the microalgae, and chemical compositions of microalgae biomass and microalgal oil. Second, three basic approaches are discussed to downstream processing for the production of green gasoline and diesel hydrocarbons from microalgae oil, including cracking with zeolite, hydrotreating with supported sulfided catalysts and hydrodeoxygenation with non-sulfide metal catalysts. For the triglyceride derived bio-fuels, only “drop-in” gasoline and diesel range components are discussed in this review.

  11. Report to Congress on the feasibility of establishing a heating oil component to the Strategic Petroleum Reserve. Volume 1

    SciTech Connect

    1998-06-01

    In the Autumn of 1996, consumers and Members of Congress from the Northeast expressed concern about high prices for heating oil and historically low levels of inventories. Some Members of Congress advocated building a Federal inventory of heating oil as part of the Strategic Petroleum Reserve (SPR). Regional reserves are authorized as part of the SPR for import dependent regions by the Energy Policy and Conservation Act. In response, the Department of Energy (DOE) proposed a series of studies related to heating fuels, including a study of the desirability, feasibility, and cost of creating a Federal reserve containing distillate fuel. This report documents that study.

  12. Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle

    DOEpatents

    Butcher, Thomas A.; Celebi, Yusuf; Fisher, Leonard

    2000-09-15

    The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

  13. Conceptual design and optimization for JET water detritiation system cryo-distillation facility

    SciTech Connect

    Lefebvre, X.; Hollingsworth, A.; Parracho, A.; Dalgliesh, P.; Butler, B.; Smith, R.

    2015-03-15

    The aim of the Exhaust Detritiation System (EDS) of the JET Active Gas Handling System (AGHS) is to convert all Q-based species (Q{sub 2}, Q-hydrocarbons) into Q{sub 2}O (Q being indifferently H, D or T) which is then trapped on molecular sieve beds (MSB). Regenerating the saturated MSBs leads to the production of tritiated water which is stored in Briggs drums. An alternative disposal solution to offsite shipping, is to process the tritiated water onsite via the implementation of a Water Detritiation System (WDS) based, in part, on the combination of an electrolyser and a cryo-distillation (CD) facility. The CD system will separate a Q{sub 2} mixture into a de-tritiated hydrogen stream for safe release and a tritiated stream for further processing on existing AGHS subsystems. A sensitivity study of the Souers' model using the simulation program ProSimPlus (edited by ProSim S.A.) has then been undertaken in order to perform an optimised dimensioning of the cryo-distillation system in terms of available cooling technologies, cost of investment, cost of operations, process performance and safety. (authors)

  14. Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles

    SciTech Connect

    Haihua Zhao; Per F. Peterson

    2012-10-01

    Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

  15. Crude Oil Characteristics Research

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SAE Plan June 29, 2015 Page 1 Crude Oil Characteristics Research Sampling, Analysis and Experiment (SAE) Plan The U.S. is experiencing a renaissance in oil and gas production. The Energy Information Administration projects that U.S. oil production will reach 9.3 million barrels per day in 2015 - the highest annual average level of oil production since 1972. This domestic energy boom is due primarily to new unconventional production of light sweet crude oil from tight-oil formations like the

  16. Oil supply increase due in 1996`s second half

    SciTech Connect

    Beck, R.J.

    1996-07-29

    The crucial oil-market issue for this year`s second half is new supply. Production will increase again outside the Organization of Petroleum Exporting Countries. And Iraq has general approval to resume exports under limits set by the United Nations, although start of the exports has been delayed by at least 60 days. The big question is the market`s ability to absorb the supply gains. As usual, the market`s need for oil in the second half will depend on economies. So far in 1996, economic growth has pushed consumption to levels unexpected a year ago. Demand the rest of the year depends heavily on economic performances of the industrialized nations that make up the organization for Economic Cooperation and Development (OECD) and the rapidly growing nations of the Asia-Pacific region. Growth in countries elsewhere in the developing world, especially Latin America, remains a wild card. The paper discusses the worldwide outlook, crude oil prices, US product prices, natural gas prices, US economy, US energy demand, natural gas in the US, US oil demand, gasoline prices, distillate gains, resid slumps, LPG, ethane, US supply, production patterns, rise in refinery capacity, imports, stocks, and stock coverage.

  17. Fuel Oil Use in Manufacturing

    Energy Information Administration (EIA) (indexed site)

    logo Return to: Manufacturing Home Page Fuel Oil Facts Oil Price Effect Fuel Switching Actual Fuel Switching Storage Capacity Fuel Oil Use in Manufacturing Why Look at Fuel Oil?...

  18. Thermal striping downstream of a horizontal elbow under thermally stratified transient flow conditions

    SciTech Connect

    Kuzay, T.M.; Kasza, K.E.

    1984-06-01

    A thermally stratified flow produced by a thermal transient passing through a horizontal elbow gives rise to large thermal fluctuations on the inner curvature wall of the downstream piping. These fluctuations were measured in a specially instrumented horizontal pipe and elbow system on a test set-up using water in the Mixing Components Technology Facility. This study is part of a larger program which is studying the influence of thermal buoyancy on general reactor component performance. This paper discusses the influence of pipe flow generated thermal oscillations on the structured thermal stresses induced in the pipe walls.

  19. Sound Oil Company

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... Ward Oil Co., 24 DOE 81,002 (1994); see also Belcher Oil Co., 15 DOE 81,018 (1987) ... months relief because of flood); Utilities Bd. of Citronelle-Gas, 4 DOE 81,205 (1979) ...

  20. South American oil

    SciTech Connect

    Not Available

    1992-06-01

    GAO reviewed the petroleum industries of the following eight South American Countries that produce petroleum but are not major exporters: Argentina, Bolivia, Brazil, Chile, Colombia, Ecuador, Peru, and Trinidad and Tobago. This report discusses the amount of crude oil the United States imports from the eight countries, expected crude oil production for these countries through the year 2010, and investment reforms that these countries have recently made in their petroleum industries. In general, although the United States imports some oil from these countries, as a group, the eight countries are currently net oil importers because combined domestic oil consumption exceeds oil production. Furthermore, the net oil imports are expected to continue to increase through the year 2010, making it unlikely that the United States will obtain increased oil shipments from these countries.

  1. Enhanced Oil Recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Enhanced Oil Recovery As much as two-thirds of conventional crude oil discovered in U.S. fields remains unproduced, left behind due to the physics of fluid flow. In addition, ...

  2. Table 5.15 Fuel Oil and Kerosene Sales, 1984-2010 (Thousand Gallons)

    Energy Information Administration (EIA) (indexed site)

    5 Fuel Oil and Kerosene Sales, 1984-2010 (Thousand Gallons) Year Distillate Fuel Oil Residential Commercial Industrial Oil Company Farm Electric Power 1 Railroad Vessel Bunkering On-Highway Diesel Military Off-Highway Diesel Other Total 1984 8,215,722 5,538,184 2,555,898 848,083 3,201,600 648,665 2,944,694 1,763,782 16,797,423 700,788 1,756,077 700,864 45,671,779 1985 7,728,057 4,463,226 2,440,661 684,227 3,102,106 523,010 2,786,479 1,698,985 17,279,650 661,644 1,522,041 168,625 43,058,711 1986

  3. A Study of the Use of Jatropha Oil Blends in Boilers

    SciTech Connect

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic

  4. Vegetable oils for tractors

    SciTech Connect

    Moroney, M.

    1981-11-14

    Preliminary tests by the Agricultural Institute, show that tractors can be run on a 50:50 rape oil-diesel mixture or on pure rape oil. In fact, engine power actually increased slightly with the 50:50 blend but decreased fractionally with pure rape oil. Research at the North Dakota State University on using sunflower oil as an alternative to diesel fuel is also noted.

  5. Oil-futures markets

    SciTech Connect

    Prast, W.G.; Lax, H.L.

    1983-01-01

    This book on oil futures trading takes a look at a market and its various hedging strategies. Growing interest in trading of commodity futures has spread to petroleum, including crude oil, and key refined products such as gasoline and heating oil. This book describes how the international petroleum trade is structured, examines the working of oil futures markets in the United States and the United Kingdom, and assesses the possible courses of further developments.

  6. Biochemical upgrading of oils

    DOEpatents

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing in organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed.

  7. Biochemical upgrading of oils

    DOEpatents

    Premuzic, E.T.; Lin, M.S.

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  8. Evaluating lignocellulosic biomass, its derivatives, and downstream products with Raman spectroscopy

    SciTech Connect

    Lupoi, Jason S.; Gjersing, Erica; Davis, Mark F.

    2015-04-20

    The creation of fuels, chemicals, and materials from plants can aid in replacing products fabricated from non-renewable energy sources. Before using biomass in downstream applications, it must be characterized to assess chemical traits, such as cellulose, lignin, or lignin monomer content, or the sugars released following an acid or enzymatic hydrolysis. The measurement of these traits allows researchers to gage the recalcitrance of the plants and develop efficient deconstruction strategies to maximize yields. Standard methods for assessing biomass phenotypes often have experimental protocols that limit their use for screening sizeable numbers of plant species. Raman spectroscopy, a non-destructive, non-invasive vibrational spectroscopy technique, is capable of providing qualitative, structural information and quantitative measurements. Applications of Raman spectroscopy have aided in alleviating the constraints of standard methods by coupling spectral data with multivariate analysis to construct models capable of predicting analytes. Hydrolysis and fermentation products, such as glucose and ethanol, can be quantified off-, at-, or on-line. Raman imaging has enabled researchers to develop a visual understanding of reactions, such as different pretreatment strategies, in real-time, while also providing integral chemical information. Finally, this review provides an overview of what Raman spectroscopy is, and how it has been applied to the analysis of whole lignocellulosic biomass, its derivatives, and downstream process monitoring.

  9. Downstream plasma transport and metal ionization in a high-powered pulsed-plasma magnetron

    SciTech Connect

    Meng, Liang; Szott, Matthew M.; McLain, Jake T.; Ruzic, David N.; Yu, He

    2014-06-14

    Downstream plasma transport and ionization processes in a high-powered pulsed-plasma magnetron were studied. The temporal evolution and spatial distribution of electron density (n{sub e}) and temperature (T{sub e}) were characterized with a 3D scanning triple Langmuir probe. Plasma expanded from the racetrack region into the downstream region, where a high n{sub e} peak was formed some time into the pulse-off period. The expansion speed and directionality towards the substrate increased with a stronger magnetic field (B), largely as a consequence of a larger potential drop in the bulk plasma region during a relatively slower sheath formation. The fraction of Cu ions in the deposition flux was measured on the substrate using a gridded energy analyzer. It increased with higher pulse voltage. With increased B field from 200 to 800 Gauss above racetrack, n{sub e} increased but the Cu ion fraction decreased from 42% to 16%. A comprehensive model was built, including the diffusion of as-sputtered Cu flux, the Cu ionization in the entire plasma region using the mapped n{sub e} and T{sub e} data, and ion extraction efficiency based on the measured plasma potential (V{sub p}) distribution. The calculations matched the measurements and indicated the main causes of lower Cu ion fractions in stronger B fields to be the lower T{sub e} and inefficient ion extraction in a larger pre-sheath potential.

  10. Electromagnetic energy conversion in downstream fronts from three dimensional kinetic reconnection

    SciTech Connect

    Lapenta, Giovanni [Departement Wiskunde, KU Leuven, Universiteit Leuven (Belgium)] [Departement Wiskunde, KU Leuven, Universiteit Leuven (Belgium); Goldman, Martin; Newman, David [University of Colorado, Colorado 80309 (United States)] [University of Colorado, Colorado 80309 (United States); Markidis, Stefano [High Performance Computing and Visualization (HPCViz) Department, KTH Royal Institute of Technology, Stockholm (Sweden)] [High Performance Computing and Visualization (HPCViz) Department, KTH Royal Institute of Technology, Stockholm (Sweden); Divin, Andrey [Swedish Institute of Space Physics, Uppsala (Sweden)] [Swedish Institute of Space Physics, Uppsala (Sweden)

    2014-05-15

    The electromagnetic energy equation is analyzed term by term in a 3D simulation of kinetic reconnection previously reported by Vapirev et al. [J. Geophys. Res.: Space Phys. 118, 1435 (2013)]. The evolution presents the usual 2D-like topological structures caused by an initial perturbation independent of the third dimension. However, downstream of the reconnection site, where the jetting plasma encounters the yet unperturbed pre-existing plasma, a downstream front is formed and made unstable by the strong density gradient and the unfavorable local acceleration field. The energy exchange between plasma and fields is most intense at the instability, reaching several pW/m{sup 3}, alternating between load (energy going from fields to particles) and generator (energy going from particles to fields) regions. Energy exchange is instead purely that of a load at the reconnection site itself in a region focused around the x-line and elongated along the separatrix surfaces. Poynting fluxes are generated at all energy exchange regions and travel away from the reconnection site transporting an energy signal of the order of about S?10{sup ?3}W/m{sup 2}.

  11. Evaluating lignocellulosic biomass, its derivatives, and downstream products with Raman spectroscopy

    DOE PAGES [OSTI]

    Lupoi, Jason S.; Gjersing, Erica; Davis, Mark F.

    2015-04-20

    The creation of fuels, chemicals, and materials from plants can aid in replacing products fabricated from non-renewable energy sources. Before using biomass in downstream applications, it must be characterized to assess chemical traits, such as cellulose, lignin, or lignin monomer content, or the sugars released following an acid or enzymatic hydrolysis. The measurement of these traits allows researchers to gage the recalcitrance of the plants and develop efficient deconstruction strategies to maximize yields. Standard methods for assessing biomass phenotypes often have experimental protocols that limit their use for screening sizeable numbers of plant species. Raman spectroscopy, a non-destructive, non-invasive vibrationalmore » spectroscopy technique, is capable of providing qualitative, structural information and quantitative measurements. Applications of Raman spectroscopy have aided in alleviating the constraints of standard methods by coupling spectral data with multivariate analysis to construct models capable of predicting analytes. Hydrolysis and fermentation products, such as glucose and ethanol, can be quantified off-, at-, or on-line. Raman imaging has enabled researchers to develop a visual understanding of reactions, such as different pretreatment strategies, in real-time, while also providing integral chemical information. Finally, this review provides an overview of what Raman spectroscopy is, and how it has been applied to the analysis of whole lignocellulosic biomass, its derivatives, and downstream process monitoring.« less

  12. Refinery Capacity Report

    Energy Information Administration (EIA) (indexed site)

    Vacuum State/Refiner/Location Barrels per Atmospheric Crude Oil Distillation Capacity Barrels per Operating Idle Operating Idle Downstream Charge Capacity Thermal Cracking Delayed Fluid Coking Visbreaking Other/Gas Calendar Day Stream Day Distillation Coking Oil Table 3. Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) ......................................................... Alabama 131,675 0 140,500 0 47,000 32,000 0 0 0

  13. Utah Heavy Oil Program

    SciTech Connect

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  14. European oil companies struggle to meet the challenge of an uncertain future

    SciTech Connect

    Reed, P.

    1996-07-01

    Oil companies have traditionally favored vertical integration, controlling the flow of oil from the drilling rig through refineries to the gasoline pump. The development of the downstream infrastructure has largely been driven by the retail market, with other fuels often treated as {open_quotes}marginal{close_quotes} businesses that leverage the retail distribution infrastructure. High-margin niche business such as lubricants and bitumen exist, but their volumes are typically small compared to the retail market. Other high-volume businesses such as aviation and heating fuels are closely tied to traded markets and generally have small market margins. Price levels at the retail site are crucial to the profitability of the downstream business. Price levels at European retail stations have historically been high when compared with North American prices, owing to government taxation. Despite the efforts of the oil companies to educate the consumer on what is the real cause of high prices, the oil majors are blamed when fuel prices fall, the consumer often feels as though lower prices had to be forced on the oil companies. Therefore, European consumers are more price sensitive than consumers elsewhere, and in markets which are deregulated on price, oil companies are losing market share to hypermarkets and supermarkets. In the U.S., increases in fuel tax levels are likely to result in a heightened price awareness for the average American, increasing the probability that hypermarkets will also enter the U.S fuels market.

  15. Distillation efficiencies of an industrial-scale i-butane/n-butane fractionator

    SciTech Connect

    Klemola, K.T.; Ilme, J.K.

    1996-12-01

    Rarely published industrial-scale distillation efficiency data are presented. The Murphree tray efficiencies are determined from the i-butane/n-butane fractionator performance data. Point efficiencies, numbers of overall vapor phase transfer units, numbers of vapor and liquid phase transfer units, and liquid phase resistances of mass transfer are backcalculated from the Murphree tray efficiencies. Various efficiency prediction and scale-up methods have been tested against experimental results. A new model for the prediction of the numbers of vapor and liquid phase transfer units has been developed. The model can be applied to hydrocarbon systems at high pressure. The influence of the mass-transfer coefficients, the interfacial area, and the vapor and liquid residence times on mass transfer has been analyzed separately, and as a result the NTU correlations for vapor and liquid phases are obtained. The constants of the model can be obtained by fitting the model to experimental efficiency data from a similar system.

  16. US Crude oil exports

    Gasoline and Diesel Fuel Update

    2014 EIA Energy Conference U.S. Crude Oil Exports July 14, 2014 By Lynn D. Westfall U.S. Energy Information Administration U.S. crude oil production has grown by almost 50% since 2008 and is up by 1.0 million b/d (14%) since April of 2013 U.S. crude oil production million barrels of oil per day Source: U.S. Energy Information Administration Lynn Westfall, 2014 EIA Energy Conference, U.S. Crude Oil Exports, July 14, 2014 2 0 2 4 6 8 10 12 1970 1972 1974 1976 1978 1980 1982 1984 1986 1988 1990

  17. Performance of ESPs operating downstream from spray-drying desulphurisation units

    SciTech Connect

    Ollero, P.; Canadas, L.; Salvador, L.

    1995-06-01

    This paper summarizes data from a Spray Dryer/ESP pilot plant located at the Los Barrios Coal Power Plant (Cadiz, Spain). A series of tests has been conducted to evaluate the performance of an existing ESP operating downstream from a spray dryer in a retrofit application. A factorial design of experiments with two SO{sub 2} levels, two flyash load levels, three Ca/S ratios and three sulfur removal efficiencies, was run during a six-month experimental programme. A global and a field-by-field analysis of the performance of the pilot ESP has shown that the desulphurisation unit enhances ESP efficiency and reduces the emission level. No evidence of electrical dust reentrainment has been found.

  18. Use of Bone Scan During Initial Prostate Cancer Workup, Downstream Procedures, and Associated Medicare Costs

    SciTech Connect

    Falchook, Aaron D.; Salloum, Ramzi G.; Hendrix, Laura H.; Chen, Ronald C.

    2014-06-01

    Purpose: For patients with a high likelihood of having metastatic disease (high-risk prostate cancer), bone scan is the standard, guideline-recommended test to look for bony metastasis. We quantified the use of bone scans and downstream procedures, along with associated costs, in patients with high-risk prostate cancer, and their use in low- and intermediate-risk patients for whom these tests are not recommended. Methods and Materials: Patients in the Surveillance, Epidemiology, and End Results (SEER)-Medicare database diagnosed with prostate cancer from 2004 to 2007 were included. Prostate specific antigen (PSA), Gleason score, and clinical T stage were used to define D'Amico risk categories. We report use of bone scans from the date of diagnosis to the earlier of treatment or 6 months. In patients who underwent bone scans, we report use of bone-specific x-ray, computed tomography (CT), and magnetic resonance imaging (MRI) scans, and bone biopsy within 3 months after bone scan. Costs were estimated using 2012 Medicare reimbursement rates. Results: In all, 31% and 48% of patients with apparent low- and intermediate-risk prostate cancer underwent a bone scan; of these patients, 21% underwent subsequent x-rays, 7% CT, and 3% MRI scans. Bone biopsies were uncommon. Overall, <1% of low- and intermediate-risk patients were found to have metastatic disease. The annual estimated Medicare cost for bone scans and downstream procedures was $11,300,000 for low- and intermediate-risk patients. For patients with apparent high-risk disease, only 62% received a bone scan, of whom 14% were found to have metastasis. Conclusions: There is overuse of bone scans in patients with low- and intermediate-risk prostate cancers, which is unlikely to yield clinically actionable information and results in a potential Medicare waste. However, there is underuse of bone scans in high-risk patients for whom metastasis is likely.

  19. Crude Oil Analysis Database

    DOE Data Explorer

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  20. From upstream to downstream: Megatrends and latest developments in Latin America`s hydrocarbons sector

    SciTech Connect

    Wu, Kang; Pezeshki, S.; McMahon, J.

    1995-08-01

    In recent years, Latin America`s hydrocarbons sector has been characterized by reorganization, revitalization, regional cooperation, environmental awakening, and steady expansion. The pattern of these changes, which appear to be the megatrends of the region`s hydrocarbons sector development, will continue during the rest of the 1990s. To further study the current situation and future prospects of Latin America`s hydrocarbons sector, we critically summarize in this short article the key issues in the region`s oil and gas development. These megatrends in Latin America`s hydrocarbons sector development will impact not only the future energy demand and supply in the region, but also global oil flows in the North American market and across the Pacific Ocean. Each country is individually discussed; pipelines to be constructed are discussed also.

  1. Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils

    DOEpatents

    Agblevor, Foster A.; Besler-Guran, Serpil

    2001-01-01

    A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous layer with ethyl acetate, and discarding the ethyl acetate fraction to obtain a brown-colored solution not susceptible to gelling or solidification upon heating; i) heating the solution to distill off water and other light components and concentrating a bottoms fraction comprising hydroxyacetaldehyde and other non-volatile components having high boiling points; and j) decolorizing the stabilized brown solution with activated carbon to obtain a colorless solution.

  2. Compatibility Assessment of Fuel System Elastomers with Bio-oil and Diesel Fuel

    DOE PAGES [OSTI]

    Kass, Michael D.; Janke, Christopher J.; Connatser, Raynella M.; Lewis, Samuel A.; Keiser, James R.; Gaston, Katherine

    2016-07-12

    Here we report that bio-oil derived via fast pyrolysis is being developed as a renewable fuel option for petroleum distillates. The compatibility of neat bio-oil with six elastomer types was evaluated against the elastomer performance in neat diesel fuel, which served as the baseline. The elastomers included two fluorocarbons, six acrylonitrile butadiene rubbers (NBRs), and one type each of fluorosilicone, silicone, styrene butadiene rubber (SBR), polyurethane, and neoprene. Specimens of each material were exposed to the liquid and gaseous phases of the test fuels for 4 weeks at 60 °C, and properties in the wetted and dried states were measured.more » Exposure to bio-oil produced significant volume expansion in the fluorocarbons, NBRs, and fluorosilicone; however, excessive swelling (over 80%) was only observed for the two fluorocarbons and two NBR grades. The polyurethane specimens were completely degraded by the bio-oil. In contrast, both silicone and SBR exhibited lower swelling levels in bio-oil compared to neat diesel fuel. The implication is that, while polyurethane and fluorocarbon may not be acceptable seal materials for bio-oils, silicone may offer a lower cost alternative.« less

  3. Dynacracking process first commerical application for upgrading heavy oils

    SciTech Connect

    Dawson, F.N. Jr.

    1981-01-01

    The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in the product mix, product quality, and economics.

  4. New noncatalytic heavy-oil process developed in Canada

    SciTech Connect

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1982-11-22

    Describes Gulf Canada's hydrogen addition upgrading process, named Donor Refined Bitumen (DRB), which involves the pyrolysis of the residuum portion of the bitumen or heavy oil in the presence of an efficient hydrogen donor that stabilizes the intermediates from the pyrolyzing bitumen. Advantages are high operability and reliability, low capital and operating costs, high yields and good product quality, feedstock and independence, the use of conventional refinery equipment, and ready availability of high quality donor. Presents a schematic flow sheet of the DRB process showing how bitumen is upgraded sufficiently to allow easy pipelining to a central major upgrading plant. Tables give comparative compositional data on middle distillates; naptha compositions and qualities; and operating costs.

  5. Thermally-enhanced oil recovery method and apparatus

    DOEpatents

    Stahl, Charles R.; Gibson, Michael A.; Knudsen, Christian W.

    1987-01-01

    A thermally-enhanced oil recovery method and apparatus for exploiting deep well reservoirs utilizes electric downhole steam generators to provide supplemental heat to generate high quality steam from hot pressurized water which is heated at the surface. A downhole electric heater placed within a well bore for local heating of the pressurized liquid water into steam is powered by electricity from the above-ground gas turbine-driven electric generators fueled by any clean fuel such as natural gas, distillate or some crude oils, or may come from the field being stimulated. Heat recovered from the turbine exhaust is used to provide the hot pressurized water. Electrical power may be cogenerated and sold to an electric utility to provide immediate cash flow and improved economics. During the cogeneration period (no electrical power to some or all of the downhole units), the oil field can continue to be stimulated by injecting hot pressurized water, which will flash into lower quality steam at reservoir conditions. The heater includes electrical heating elements supplied with three-phase alternating current or direct current. The injection fluid flows through the heater elements to generate high quality steam to exit at the bottom of the heater assembly into the reservoir. The injection tube is closed at the bottom and has radial orifices for expanding the injection fluid to reservoir pressure.

  6. Fuel quality issues in the oil heat industry

    SciTech Connect

    Litzke, Wai-Lin

    1992-12-01

    The quality of fuel oil plays an essential role in combustion performance and efficient operation of residential heating equipment. With the present concerns by the oil-heat industry of declining fuel-oil quality, a study was initiated to identify the factors that have brought about changes in the quality of distillate fuel. A background of information will be provided to the industry, which is necessary to deal with the problems relating to the fuel. The high needs for servicing heating equipment are usually the result of the poor handling characteristics of the fuel during cold weather, the buildup of dirt and water in storage tanks, and microbial growth. A discussion of how to deal with these problems is presented in this paper. The effectiveness of fuel additives to control these problems of quality is also covered to help users better understand the functions and limitations of chemical treatment. Test data have been collected which measure and compare changes in the properties of fuel using selected additives.

  7. Shale oil dearsenation process

    SciTech Connect

    Brickman, F.E.; Degnan, T.F.; Weiss, C.S.

    1984-10-29

    This invention relates to processing shale oil and in particular to processing shale oil to reduce the arsenic content. Specifically, the invention relates to treating shale oil by a combination of processes - coking and water washing. Many shale oils produced by conventional retorting processes contain inorganic materials, such as arsenic, which interfere with subsequent refining or catalytic hydroprocessing operations. Examples of these hydroprocessing operations are hydrogenation, denitrogenation, and desulfurization. From an environmental standpoint, removal of such contaminants may be desirable even if the shale oil is to be used directly as a fuel. Hence, it is desirable that contaminants such as arsenic be removed, or reduced to low levels, prior to further processing of the shale oil or prior to its use as a fuel.

  8. Upgrading heavy oil using slurry processes

    SciTech Connect

    Del Bianco, A.; Panariti, N.; Marchionna, M.

    1995-11-01

    There is a growing interest in processes capable of converting heavy feedstocks (petroleum residues and heavy oils) into lower boiling products of high quality. The operational problems of upgrading heavy feeds relate to the presence of sulfur, nitrogen, metals, and considerable amounts of Conradson carbon residue. An efficient residue conversion process must be able to reduce the molecular weight of the feedstocks to material with boiling points below 550 C, increase the H-to-C ratio of the refined product, and remove heteroatoms and metals. Whereas the molecular weight reduction is normally achieved by C-C bond cracking above 400 C, often in the presence of acid catalysts, a higher H-to-C ratio can be obtained by either the rejection of carbon (as in coking) or the addition of hydrogen (as in hydrogenation processes). Slurry processes combine the flexibility of the carbon rejection with the high performance of the hydrogen addition processes. The origin of slurry processes is the Bergius-Pier technology (1920--1930) for the conversion of heavy oils and coal into distillates. Whereas the original Bergius-Pier technology did not use a catalyst, small amounts of inexpensive additives or finely dispersed hydrogenation catalysts can be used to increase the rates of the desired reactions. Catalysts can also inhibit coke formation by physically interfering with the coalescence of mesophase, which is the precursor of solid coke. Catalysts are used to reduce the severity of the process and to improve the quality of the products. Most of the research carried out in the past decade in the field of slurry processes has dealt with the identification of more effective and/or less expensive catalysts and the technological problems related to their use. Here the authors discuss both subjects, describing the path from the fundamental chemistry of dispersed catalytic systems to the development and initial commercialization of slurry processes.

  9. Residential heating oil price

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 7.6 cents from a week ago to $2.97 per gallon. That's down $1.05 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.94 per gallon, down 6.7 cents from last week, and down $1.07

  10. Residential heating oil price

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 6.3 cents from a week ago to $2.91 per gallon. That's down $1.10 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.88 per gallon, down 6.8 cents from last week, and down $1.13

  11. Residential heating oil price

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 7.5 cents from a week ago to $2.84 per gallon. That's down $1.22 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.80 per gallon, down 7.4 cents from last week, and down $1.23

  12. Residential heating oil price

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 4.1 cents from a week ago to $2.89 per gallon, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.84 per gallon, down 5.4 cents from last week

  13. Residential heating oil price

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 3.6 cents from a week ago to $3.04 per gallon. That's down 99.4 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.01 per gallon, down 3.6 cents from last week, and down $1.01

  14. Hot Oiling Spreadsheet

    Energy Science and Technology Software Center

    1993-10-22

    One of the most common oil-field treatments is hot oiling to remove paraffin from wells. Even though the practice is common, the thermal effectiveness of the process is not commonly understood. In order for producers to easily understand the thermodynamics of hot oiling, a simple tool is needed for estimating downhole temperatures. Such a tool has been developed that can be distributed as a compiled spreadsheet.

  15. Vegetable oil fuel

    SciTech Connect

    Bartholomew, D.

    1981-04-01

    In this article, the future role of renewable agricultural resources in providing fuel is discussed. it was only during this century that U.S. farmers began to use petroleum as a fuel for tractors as opposed to forage crop as fuel for work animals. Now farmers may again turn to crops as fuel for agricultural production - the possible use of sunflower oil, soybean oil and rapeseed oil as substitutes for diesel fuel is discussed.

  16. Characterization of heavy oil by capillary supercritical fluid chromatography

    SciTech Connect

    Fuhr, B.J.; Holloway, L.R.; Reichert, C.

    1988-06-01

    The characterization of heavy oils and bitumen produced by thermal recovery methods may aid in bringing about the following benefits: improved recovery methods, promotion of upgrading in the reservoir, improved emulsion treatment and optimized use of diluent for transportation. Because of the high proportion of nonvolatile compounds in heavy oils, gas chromatography (GC) is not particularly useful for characterization purposes. High performance liquid chromatography, while capable of analyzing a larger proportion of the nonvolatiles, possesses considerably less resolution than GC. By utilizing mobile phases in their supercritical region it is possible to study compounds that cannot be vaporized for GC analysis, yet still attain the resolution approaching that of GC. Another advantage of supercritical fluid chromatography (SFC) with the commonly used mobile phase CO/sub 2/, is the ability to employ the flame ionization detector (FID) which provides a uniform response over a wide range of compound types. SFC methods used on packed columns are excellent for low resolution separations into hydrocarbon group types and can produce data in about 5 to 15 min. A number of workers have described the use of packed silica columns for the separation and quantitation of saturate and aromatic component types in gasolines and middle distillate fuels, and of saturates, aromatics and polars in high boiling residues. In these studies the mobile phase was CO/sub 2/ and the detector was the FID. Campbell and Lee reported a semi-preparative SFC method using a packed, amino-modified silica column for the separation of aromatics according to the number of rings in a coal tar and a solved refined coal heavy distillate.

  17. Oil & Gas Research

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Oil & Gas Research Unconventional Resources NETL's onsite research in unconventional resources is focused on developing the data and modeling tools needed to predict and quantify ...

  18. Crude Oil Production

    Gasoline and Diesel Fuel Update

    Notes: Year-to-date totals include revised monthly production estimates by state published in Petroleum Navigator. Crude oil production quantities are estimated by state and summed ...

  19. Crude Oil Production

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Notes: Year-to-date totals include revised monthly production estimates by state published in Petroleum Navigator. Crude oil production quantities are estimated by state and summed ...

  20. Crude Oil Prices

    Energy Information Administration (EIA) (indexed site)

    Information AdministrationPetroleum Marketing Annual 2001 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  1. Crude Oil Prices

    Energy Information Administration (EIA) (indexed site)

    Information AdministrationPetroleum Marketing Annual 1998 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  2. Crude Oil Prices

    Energy Information Administration (EIA) (indexed site)

    Information AdministrationPetroleum Marketing Annual 1999 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  3. Upgrading heavy gas oils

    SciTech Connect

    Ferguson, S.; Reese, D.D.

    1986-05-20

    A method is described of neutralizing the organic acidity in heavy gas oils to produce a neutralization number less than 1.0 whereby they are rendered suitable as lube oil feed stocks which consists essentially of treating the heavy gas oils with a neutralizing amount of monoethanolamine to form an amine salt with the organic acids and then heating the thus-neutralized heavy gas oil at a temperature at least about 25/sup 0/F greater than the boiling point of water and for a time sufficient to convert the amine salts to amides.

  4. ,"for Electricity(a)","Fuel Oil","Diesel Fuel(b)","(billion","NGL(d)","(million"

    Energy Information Administration (EIA) (indexed site)

    7 Relative Standard Errors for Table 5.7;" " Unit: Percents." ,,,"Distillate",,,"Coal" ,,,"Fuel Oil",,,"(excluding Coal" ,"Net Demand","Residual","and","Natural Gas(c)","LPG and","Coke and Breeze)" ,"for Electricity(a)","Fuel Oil","Diesel Fuel(b)","(billion","NGL(d)","(million" "End Use","(million

  5. Oil Shale and Oil Sands Development Robert Keiter; John Ruple...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Robert Keiter; John Ruple; Heather Tanana; Rebecca Holt 29 ENERGY...

  6. Oil shale technology

    SciTech Connect

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  7. Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

    SciTech Connect

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

  8. Balancing oil and environment... responsibly.

    SciTech Connect

    Weimer, Walter C.; Teske, Lisa

    2007-01-25

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  9. oil and gas portfolio reports

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Natural Gas & Oil Program Research Portfolio Reports The Office of Fossil Energy (FE)... focus areas: Unconventional Oil & Gas Resources; Ultra-Deepwater; and Small Producers. ...

  10. Oil Refund Decisions

    Office of Energy Efficiency and Renewable Energy (EERE)

    During the period 1973 through 1981, the Federal government imposed price and allocation controls of crude oil and refined petroleum products, such as gasoline and heating oil. During that period and for many years afterwards, the DOE had an enforcement program. When a firm was found to have overcharged, the DOE generally required the firm to make refunds to its customers.

  11. Vegetable oil as fuel

    SciTech Connect

    Not Available

    1980-11-01

    A review is presented of various experiments undertaken over the past few years in the U.S. to test the performance of vegetable oils in diesel engines, mainly with a view to on-farm energy self-sufficiency. The USDA Northern Regional Research Center in Peoria, Illinois, is screening native U.S. plant species as potential fuel oil sources.

  12. Catalytic hydroprocessing of SRC-II heavy distillate fractions. 4. Hydrodeoxygenation of phenolic compounds in the acidic fractions

    SciTech Connect

    Li, C.L.

    1985-01-01

    Heavy distillate obtained by hydroliquefaction of Powhatan No.5 coal was separated into 9 fractions by liquid chromatography. The very-weak-acid and weak-acid fractions were used as feeds in hydroprocessing experiments with sulphided Ni-Mo/Al/sub 2/O/sub 3/ catalyst at 350 C and 120 atm. The hydrodeoxygenation of the acidic compounds was shown to be rapid in comparison with other hydroprocessing reactions of coal liquids, including hydrogenation of aromatics, hydrodesulphurisation and hydrodenitrogenation.

  13. Corrosivity Of Pyrolysis Oils

    SciTech Connect

    Keiser, James R; Bestor, Michael A; Lewis Sr, Samuel Arthur; Storey, John Morse

    2011-01-01

    Pyrolysis oils from several sources have been analyzed and used in corrosion studies which have consisted of exposing corrosion coupons and stress corrosion cracking U-bend samples. The chemical analyses have identified the carboxylic acid compounds as well as the other organic components which are primarily aromatic hydrocarbons. The corrosion studies have shown that raw pyrolysis oil is very corrosive to carbon steel and other alloys with relatively low chromium content. Stress corrosion cracking samples of carbon steel and several low alloy steels developed through-wall cracks after a few hundred hours of exposure at 50 C. Thermochemical processing of biomass can produce solid, liquid and/or gaseous products depending on the temperature and exposure time used for processing. The liquid product, known as pyrolysis oil or bio-oil, as produced contains a significant amount of oxygen, primarily as components of water, carboxylic acids, phenols, ketones and aldehydes. As a result of these constituents, these oils are generally quite acidic with a Total Acid Number (TAN) that can be around 100. Because of this acidity, bio-oil is reported to be corrosive to many common structural materials. Despite this corrosive nature, these oils have the potential to replace some imported petroleum. If the more acidic components can be removed from this bio-oil, it is expected that the oil could be blended with crude oil and then processed in existing petroleum refineries. The refinery products could be transported using customary routes - pipelines, barges, tanker trucks and rail cars - without a need for modification of existing hardware or construction of new infrastructure components - a feature not shared by ethanol.

  14. Cryogenic distillation: a fuel enrichment system for near-term tokamak-type D-T fusion reactors

    SciTech Connect

    Misra, B.; Davis, J.F.

    1980-02-01

    The successful operation and economic viability of deuterium-tritium- (D-T-) fueled tokamak-type commercial power fusion reactors will depend to a large extent on the development of reliable tritium-containment and fuel-recycle systems. Of the many operating steps in the fuel recycle scheme, separation or enrichment of the isotropic species of hydrogen by cryogenic distillation is one of the most important. A parametric investigation was carried out to study the effects of the various operating conditions and the composition of the spent fuel on the degree of separation. A computer program was developed for the design and analysis of a system of interconnected distillation columns for isotopic separation such that the requirements of near-term D-T-fueled reactors are met. The analytical results show that a distillation cascade consisting of four columns is capable of reprocessing spent fuel varying over a wide range of compositions to yield reinjection-grade fuel with essentially unlimited D/T ratio.

  15. Policy Analysis of Water Availability and Use Issues for Domestic Oil Shale and Oil Sands Development

    SciTech Connect

    Ruple, John; Keiter, Robert

    2010-12-31

    Oil shale and oil sands resources located within the intermountain west represent a vast, and as of yet, commercially untapped source of energy. Development will require water, and demand for scarce water resources stands at the front of a long list of barriers to commercialization. Water requirements and the consequences of commercial development will depend on the number, size, and location of facilities, as well as the technologies employed to develop these unconventional fuels. While the details remain unclear, the implication is not – unconventional fuel development will increase demand for water in an arid region where demand for water often exceeds supply. Water demands in excess of supplies have long been the norm in the west, and for more than a century water has been apportioned on a first-come, first-served basis. Unconventional fuel developers who have not already secured water rights stand at the back of a long line and will need to obtain water from willing water purveyors. However, uncertainty regarding the nature and extent of some senior water claims combine with indeterminate interstate river management to cast a cloud over water resource allocation and management. Quantitative and qualitative water requirements associated with Endangered Species protection also stand as barriers to significant water development, and complex water quality regulations will apply to unconventional fuel development. Legal and political decisions can give shape to an indeterminate landscape. Settlement of Northern Ute reserved rights claims would help clarify the worth of existing water rights and viability of alternative sources of supply. Interstate apportionment of the White River would go a long way towards resolving water availability in downstream Utah. And energy policy clarification will help determine the role oil shale and oil sands will play in our nation’s future.

  16. New short contact time processes upgrade residual oils and heavy crudes

    SciTech Connect

    Not Available

    1991-08-12

    This paper reports on new short contact time carbon rejection technology developed for upgrading residual oils and converting heavier crudes into high-quality synthetic crudes. The process, called discriminatory destructive distillation, or 3D, has been demonstrated in a Kansas refinery on feedstocks ranging from 13.5 to 30.6{degrees} API. For the past year, Coastal Derby Refining Co. has been operating a revolutionary, according to Bartholic, circulating fluid solids processing apparatus that can be run as either a 3D process unit, to virtually eliminate the residual oil component of crude, or as an MSCC process unit, to upgrade VGO residual oils. Because both of these processes circulate a fluid solid in a manner similar to the well known and commercially accepted fluid catalytic cracking (FCC) process, existing FCC-type units can be easily and economically converted to either 3D or MSCC operation. The 3D process is a low-pressure, carbon-rejection residual oil treating process for preparation of gas oils for fluid catalytic cracking (or MSCC), hydrotreating, mild hydrocracking, or full hydrocracking, says Bartholic. The process is also applicable, he says to upgrading heavy crudes or tar sands bitumen to high-quality reconstituted crudes for world markets.

  17. China shows increasing interest in heavy oil and oil sands

    SciTech Connect

    Not Available

    1986-12-01

    China and Canadian and US groups are cooperating in several areas to develop the heavy oil, asphalt, and oil sand deposits of China. The agreements dealing with exploration and upgrading are briefly described. The majority of the paper describes the occurrences of heavy oil, asphalt, and oil sands in China. 1 figure.

  18. Oil program implementation plan FY 1996--2000

    SciTech Connect

    1995-04-01

    This document reaffirms the US Department of Energy (DOE) Office of Fossil Energy commitment to implement the National Oil Research Program in a way to maximize assurance of energy security, economic growth, environmental protection, jobs, improved economic competitiveness, and improved US balance of trade. There are two sections and an appendix in this document. Section 1 is background information that guided its formulation and a summary of the Oil Program Implementation Plan. This summary includes mission statements, major program drivers, oil issues and trends, budget issues, customers/stakeholders, technology transfer, measures of program effectiveness, and benefits. Section 2 contains more detailed program descriptions for the eight technical areas and the NIPER infrastructure. The eight technical areas are reservoir characterization; extraction research; exploration, drilling, and risk-based decision management; analysis and planning; technology transfer; field demonstration projects; oil downstream operations; and environmental research. Each description contains an overview of the program, descriptions on main areas, a discussion of stakeholders, impacts, planned budget projections, projected schedules with Gantt charts, and measures of effectiveness. The appendix is a summary of comments from industry on an earlier draft of the plan. Although changes were made in response to the comments, many of the suggestions will be used as guidance for the FY 1997--2001 plan.

  19. Oil shale research in China

    SciTech Connect

    Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

    1989-01-01

    There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

  20. Crude Oil Prices

    Energy Information Administration (EIA) (indexed site)

    20.86 20.67 20.47 20.24 20.32 19.57 See footnotes at end of table. 21. Domestic Crude Oil First Purchase Prices Energy Information Administration Petroleum Marketing Annual...

  1. Oil & Natural Gas Technology

    Office of Scientific and Technical Information (OSTI)

    IN SITU THERMAL PROCESSING OF OIL SHALESANDS Authors: Michal Hradisky and Philip J. Smith DOE Award No.: DE-FE0001243 Reporting Period: October 1, 2009 - September 30, 2011 ...

  2. Hydroprocessing hydrocarbon oils

    SciTech Connect

    Simpson, H.D.; Borgens, P.B.

    1990-07-10

    This patent describes a catalytic hydroprocess of a hydrocarbon oil containing nitrogen or sulfur. It comprises: contacting a catalytic composition with the hydrocarbon oil under hydroprocessing conditions so as to produce a product hydrocarbon oil containing less nitrogen or sulfur than the hydrocarbon oil, the catalytic composition prepared by the method comprising the steps of impregnating porous refractory support particles with an aqueous impregnating solution comprising one or more Group VIB metal components, one or more phosphorus components and citric acid, the citric acid in a mole ratio to the Group VIB metal components calculated as the Group VIB metal trioxide of less than 1 to 1. The solution has a pH less than 1.0 and calcining the impregnated support particles to produce a catalytic composition containing a Group VIB metal component and a phosphorous component on the porous refractory oxide support.

  3. Oil Market Assessment

    Reports and Publications

    2001-01-01

    Based on Energy Information Administration (EIA) contacts and trade press reports, overall U.S. and global oil supplies appear to have been minimally impacted by yesterday's terrorist attacks on the World Trade Center and the Pentagon.

  4. enhanced_oil_current_proj | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Enhanced Oil Recovery and Other Oil Resources Enhanced Oil Recovery and Other Oil Resources CO2 EOR | Other EOR & Oil Resources | Environmental | Completed Project Number Project ...

  5. Oil & Gas Research

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Oil & Gas Research Unconventional Resources NETL's onsite research in unconventional resources is focused on developing the data and modeling tools needed to predict and quantify potential risks associated with oil and gas resources in shale reservoirs that require hydraulic fracturing or other engineering measures to produce. Fugitive Emissions | Produced Water Management | Subsurface Fluid & Gas Migration | Induced Seismicity Offshore Resources Building the scientific understanding and

  6. Oil/gas collector/separator for underwater oil leaks

    DOEpatents

    Henning, Carl D.

    1993-01-01

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  7. Finding Hidden Oil and Gas Reserves

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Finding Hidden Oil and Gas Reserves Finding Hidden Oil and Gas Reserves Key Challenges: Seismic imaging methods, vital in our continuing search for deep offshore oil and gas...

  8. Microsoft Word - Heating Oil Season.docx

    Energy.gov [DOE] (indexed site)

    4-2015 Heating Oil Season Northeast Home Heating Oil Reserve Trigger Mechanism (Cents per Gallon, Except Where Noted) Week Residential Heating Oil Price Average Brent Spot Price ...

  9. Deepwater Oil & Gas Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to...

  10. Deepwater Oil & Gas Resources | Department of Energy

    Office of Environmental Management (EM)

    Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to ...

  11. Heating Oil Reserve History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Heating Oil Reserve History Heating Oil Reserve History Creation of an emergency reserve of heating oil was directed by President Clinton on July 10, 2000, when he directed ...

  12. United Oil Company | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Oil Company Jump to: navigation, search Name: United Oil Company Place: Pittsburgh, Pennsylvania Product: Vegetable-Oil producer Biodiesel producer based in Pittsburgh, PA...

  13. STEO December 2012 - oil production

    Energy Information Administration (EIA) (indexed site)

    Rise in 2012 U.S. oil production largest since 1859, output in 2013 seen topping 7 million bpd U.S. crude oil production is now expected to rise by about 760,000 barrels per day in 2012, the biggest annual increase in oil output since U.S. commercial crude oil production began in 1859. American oil producers are expected to pump a daily average of 6.4 million barrels of crude oil this year, according to the U.S. Energy Information Administrator's new monthly energy forecast. The annual increase

  14. Going Global: Tight Oil Production

    Gasoline and Diesel Fuel Update

    GOING GLOBAL: TIGHT OIL PRODUCTION Leaping out of North America and onto the World Stage JULY 2014 GOING GLOBAL: TIGHT OIL PRODUCTION Jamie Webster, Senior Director Global Oil Markets Jamie.webster@ihs.com 1 GOING GLOBAL: TIGHT OIL PRODUCTION Key Message: Tight Oil Will Have Unconventional Effects Tight Oil Production will change in the coming decades. It will be:  More global, as it leaps out of North America  More inclusive, as companies come to the US for experience and US companies go

  15. Abandoned Texas oil fields

    SciTech Connect

    Not Available

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  16. Enhanced Oil Recovery to Fuel Future Oil Demands | GE Global...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Enhanced Oil Recovery to Fuel Future Oil Demands Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) ...

  17. International Oil and Gas Board International Oil and Gas Board...

    OpenEI (Open Energy Information) [EERE & EIA]

    Petroleum Company Syrian Petroleum Company Damascus Syria Syria http www spc sy com en production activities1 en php Yemen Ministry of Oil and Minerals Yemen Ministry of Oil and...

  18. History of western oil shale

    SciTech Connect

    Russell, P.L.

    1980-01-01

    The history of oil shale in the United States since the early 1900's is detailed. Research on western oil shale probably began with the work of Robert Catlin in 1915. During the next 15 years there was considerable interest in the oil shales, and oil shale claims were located, and a few recovery plants were erected in Colorado, Nevada, Utah, Wyoming, and Montana. Little shale soil was produced, however, and the major oil companies showed little interest in producing shale oil. The early boom in shale oil saw less than 15 plants produce a total of less than 15,000 barrels of shale oil, all but about 500 barrels of which was produced by the Catlin Operation in Nevada and by the US Bureau of Mines Rulison, Colorado operation. Between 1930 and 1944 plentiful petroleum supplies at reasonable prices prevent any significant interest in shale oil, but oil shortages during World War II caused a resurgence of interest in oil shale. Between 1940 and 1969, the first large-scale mining and retorting operations in soil shale, and the first attempts at true in situ recovery of shale oil began. Only 75,000 barrels of shale oil were produced, but major advancements were made in developing mine designs and technology, and in retort design and technology. The oil embargo of 1973 together with a new offering of oil shale leases by the Government in 1974 resulted in the most concentrated efforts for shale oil production to date. These efforts and the future prospects for shale oil as an energy source in the US are discussed.

  19. Completed Enhanced Oil Recovery and Other Oil Resoureces Projects

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Completed Enhanced Oil Recovery and Other Oil Resoureces Projects Active | Completed Projects Completed Enhanced Oil Recovery and Other Oil Resources Projects Project Number Project Name Primary Performer 10122-39 Novel Engineered Osmosis Technology: A Comprehensive Approach to the Treatment and Reuse of Produced Water and Drilling Wastewater Colorado School of Mines 11123-03 Cost-Effective Treatment of Produced Water Using Co-Produced Energy Sources - Phase II: Field Scale Demo and

  20. Oil production history in Albania oil fields and their perspective

    SciTech Connect

    Marko, D.; Moci, A.

    1995-12-31

    In this paper we will make a general presentation for oil fields in Albania, actual state, and their perspective.

  1. The Use of TaBoRR as a Heavy Oil Upgrader

    SciTech Connect

    Lee Brecher; Charles Mones

    2009-02-05

    Preliminary testing has shown that Western Research Institute's (WRI) Tank Bottom Recovery and Remediation (TaBoRR{reg_sign}) technology shows promise for heavy oil upgrading. Approximately 70 to 75 wt% of a Canadian Cold Lake bitumen feed was converted to a partially upgraded overhead product that could be transported directly by pipeline or blended with the parent bitumen to produce transportable crude. TaBoRR{reg_sign} was originally developed to remediate tank bottom wastes by producing a distillate product and solid waste. TaBoRR{reg_sign}'s processing steps include breaking a water-oil emulsion, recovering a light hydrocarbon fraction by distillation in a stripper unit, and pyrolyzing the residua reducing it to additional overhead and a benign coke for disposal. Cold Lake bitumen was tested in WRI's bench-scale equipment to evaluate the potential use of TaBoRR{reg_sign} technology for heavy oil upgrading to produce a stable, partially (or fully) upgraded product that will allow diluent-reduced or diluent-free transportation of bitumen or ultra-heavy crudes to market. Runs were conducted at temperatures of low, intermediate and high severity in the stripper to produce stripper overhead and bottoms. The bottoms from each of these runs were processed further in a 6-inch screw pyrolyzer to produce pyrolyzer overhead for blending with the corresponding stripper overheads. Proceeding in this fashion yielded three partially upgraded crudes. The products from TaBoRR{reg_sign} processing, the parent bitumen, and bitumen blends were subjected to stability and compatibility testing at the National Centre for Upgrading Technology (NCUT). Chemical analyses of the overhead product blends have met pipeline specifications for viscosity and density; however the bromine number does not, which might indicate the need for mild hydrotreating. Storage stability tests showed the blends to be stable. The blends were also soluble and compatible with most other Alberta crudes.

  2. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    SciTech Connect

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2

  3. Hollow Fibers Structured Packings in Olefin/Paraffin Distillation: Apparatus Scale-Up and Long-Term Stability

    DOE PAGES [OSTI]

    Yang, Dali; Le, Loan; Martinez, Ronald; Morrison, Malcolm

    2013-06-21

    Following the conceptual demonstration of high separation efficiency and column capacity obtained in olefin/paraffin distillation using hollow fiber structured packings (HFSPs) in a bench scale (J. Membr. Sci.2006, 2007, and 2010), we scaled-up this process with a 10-fold increase in the internal flow rate and a 3-fold increase in the module length. We confirmed that the HFSPs technology gives high separation efficiency and column capacity in iso-/n-butane distillation for 18 months. We systematically investigated the effects of packing density, concentration of light component, reflux ratio, and module age on the separation efficiency and operating stability. The comprehensive characterizations using scanningmore » electron microscopy (SEM), Brunauer–Emmett–Teller (BET), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) were carried out to probe the changes in the morphological, thermal, and mechanical properties of polypropylene (PP) hollow fibers over the aging process. Our results suggest that after a long-term exposure to light hydrocarbon environments at ≤70 °C the morphological and mechanical properties of the PP polymer do not degrade significantly in a propane/propylene and iso-/n-butane environment.« less

  4. Hollow Fibers Structured Packings in Olefin/Paraffin Distillation: Apparatus Scale-Up and Long-Term Stability

    SciTech Connect

    Yang, Dali; Le, Loan; Martinez, Ronald; Morrison, Malcolm

    2013-06-21

    Following the conceptual demonstration of high separation efficiency and column capacity obtained in olefin/paraffin distillation using hollow fiber structured packings (HFSPs) in a bench scale (J. Membr. Sci.2006, 2007, and 2010), we scaled-up this process with a 10-fold increase in the internal flow rate and a 3-fold increase in the module length. We confirmed that the HFSPs technology gives high separation efficiency and column capacity in iso-/n-butane distillation for 18 months. We systematically investigated the effects of packing density, concentration of light component, reflux ratio, and module age on the separation efficiency and operating stability. The comprehensive characterizations using scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) were carried out to probe the changes in the morphological, thermal, and mechanical properties of polypropylene (PP) hollow fibers over the aging process. Our results suggest that after a long-term exposure to light hydrocarbon environments at ≤70 °C the morphological and mechanical properties of the PP polymer do not degrade significantly in a propane/propylene and iso-/n-butane environment.

  5. Distributed Bio-Oil Reforming

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Distributed Bio-Oil Reforming R. Evans, S. Czernik, R. French, M. Ratcliff National ... GAS 7 BIOMASS BIO-OIL CHAR For reactor or export Gas recycle For fluidization or export ...

  6. Assessment of heavy oil conversion

    SciTech Connect

    Gleim, W.T.K.

    1983-08-01

    Removal of benzene insoluble asphaltene components greatly facilitates and improves the subsequent upgrading of residual oils, the desulfurization in particular. For the upgrading of Venezualean oils, the Aurobon process is still the only feasible solution.

  7. AEO Early Release 2013 - oil

    Energy Information Administration (EIA) (indexed site)

    Growing U.S. oil output and rising vehicle fuel economy to cut U.S. reliance on foreign oil The United States is expected to continue cutting its dependence on petroleum and liquid ...

  8. Oil and Gas

    Energy Saver

    RD&D Leases in the United States Oil Shale RD&D Leases in the United States This paper describes the original plans, progress and accomplishments, and future plans for nine oil shale research, development and demonstration (RD&D) projects on six existing RD&D leases awarded in 2006 and 2007 by the United States Department of the Interior, Bureau of Land Management (BLM) to Shell, Chevron, EGL (now AMSO), and OSEC (now Enefit American, respectively); as well as three pending

  9. Explaining EIA Crude Oil and Petroleum Product Price Data and Comparing with Other U.S. Government Data Sources, 2001 to 2010

    Reports and Publications

    2012-01-01

    This article describes the sampling frames and basic data collection methods for petroleum price data reported by Energy Information Administration (EIA) and other Government agencies. In addition, it compares and contrasts annual average prices reported by EIA with comparable prices from the Bureau of Labor Statistics (BLS) CPI (Consumer Price Indexes) for the retail prices of residential No. 2 distillate, on-highway diesel fuel and motor gasoline (all grades.) Further, it compares refiner wholesale/resale prices for No. 2 fuel oil, No. 2 diesel fuel, motor gasoline (all grades,) kerosene-type jet fuel and residual fuel oil reported by EIA with comparable prices from the BLS PPI (Producer Price Index.) A discussion of the various crude oil prices and spot/futures prices published by EIA and other Government agencies is also included in the article.

  10. Nineteenth oil shale symposium proceedings

    SciTech Connect

    Gary, J.H.

    1986-01-01

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  11. Heating Oil and Propane Update

    Annual Energy Outlook

    Maps of states participating in Winter Fuels Survey Residential propane PADD map Residential heating oil PADD map

  12. Residential heating oil prices available

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil prices available The average retail price for home heating oil is $2.30 per gallon, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region currently average $2.23

  13. Residential heating oil prices available

    Energy Information Administration (EIA) (indexed site)

    heating oil prices available The average retail price for home heating oil is $2.41 per gallon, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region currently average $2.35 per gallon. This is Marcela Rourk with EIA, in Washington.

  14. Oil shale: Technology status report

    SciTech Connect

    Not Available

    1986-10-01

    This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

  15. Phase Behavior, Solid Organic Precipitation, and Mobility Characterization Studies in Support of Enhanced Heavy Oil Recovery on the Alaska North Slope

    SciTech Connect

    Shirish Patil; Abhijit Dandekar; Santanu Khataniar

    2008-12-31

    The medium-heavy oil (viscous oil) resources in the Alaska North Slope are estimated at 20 to 25 billion barrels. These oils are viscous, flow sluggishly in the formations, and are difficult to recover. Recovery of this viscous oil requires carefully designed enhanced oil recovery processes. Success of these recovery processes is critically dependent on accurate knowledge of the phase behavior and fluid properties, especially viscosity, of these oils under variety of pressure and temperature conditions. This project focused on predicting phase behavior and viscosity of viscous oils using equations of state and semi-empirical correlations. An experimental study was conducted to quantify the phase behavior and physical properties of viscous oils from the Alaska North Slope oil field. The oil samples were compositionally characterized by the simulated distillation technique. Constant composition expansion and differential liberation tests were conducted on viscous oil samples. Experiment results for phase behavior and reservoir fluid properties were used to tune the Peng-Robinson equation of state and predict the phase behavior accurately. A comprehensive literature search was carried out to compile available compositional viscosity models and their modifications, for application to heavy or viscous oils. With the help of meticulously amassed new medium-heavy oil viscosity data from experiments, a comparative study was conducted to evaluate the potential of various models. The widely used corresponding state viscosity model predictions deteriorate when applied to heavy oil systems. Hence, a semi-empirical approach (the Lindeloff model) was adopted for modeling the viscosity behavior. Based on the analysis, appropriate adjustments have been suggested: the major one is the division of the pressure-viscosity profile into three distinct regions. New modifications have improved the overall fit, including the saturated viscosities at low pressures. However, with the limited

  16. Method and apparatus for converting and removing organosulfur and other oxidizable compounds from distillate fuels, and compositions obtained thereby

    DOEpatents

    D'Alessandro, Robert N.; Tarabocchia, John; Jones, Jerald Andrew; Bonde, Steven E.; Leininger, Stefan

    2010-10-26

    The present disclosure is directed to a multi-stage system and a process utilizing said system with the design of reducing the sulfur-content in a liquid comprising hydrocarbons and organosulfur compounds. The process comprising at least one of the following states: (1) an oxidation stage; (2) an extraction state; (3) a raffinate washing stage; (4) a raffinate polishing stage; (5) a solvent recovery stage; (6) a solvent purification stage; and (7) a hydrocarbon recovery stage. The process for removing sulfur-containing hydrocarbons from gas oil, which comprises oxidizing gas oil comprising hydrocarbons and organosulfur compounds to obtain a product gas oil.

  17. Salinity, temperature, oil composition, and oil recovery by waterflooding

    SciTech Connect

    Tang, G.Q.; Morrow, N.R.

    1997-11-01

    The effect of aging and displacement temperatures and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea sandstone with three crude oils and three reservoir brines (RB`s). Salinity was varied by changing the concentration of total dissolved solids (TDS`s) of the synthetic brine in proportion. Salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the RB with dilution of both the initial (connate) and invading brine or dilution of either. Aging and displacement temperatures were varied independently. For all crude oils, water wetness and oil recovery increased with increase in displacement temperature. Removal of light components from the crude oil resulted in increased water wetness. Addition of alkanes to the crude oil reduced the water wetness, and increased oil recovery. Relationships between waterflood recovery and rate and extent of oil recovery by spontaneous imbibition are summarized.

  18. Dying for oil

    SciTech Connect

    Sachs, A.

    1996-05-01

    This article discusses the fight and execution of Ken Saro-Wiwa, the Ogoni leader who defended his people`s land on the Niger delta against oil development encouraged by the government and persued by the Royal/Dutch Shell Co. Political reprocussions and heightened vigilance of environmental activists are discussed at length.

  19. African oil plays

    SciTech Connect

    Clifford, A.J. )

    1989-09-01

    The vast continent of Africa hosts over eight sedimentary basins, covering approximately half its total area. Of these basins, only 82% have entered a mature exploration phase, 9% have had little or no exploration at all. Since oil was first discovered in Africa during the mid-1950s, old play concepts continue to bear fruit, for example in Egypt and Nigeria, while new play concepts promise to become more important, such as in Algeria, Angola, Chad, Egypt, Gabon, and Sudan. The most exciting developments of recent years in African oil exploration are: (1) the Gamba/Dentale play, onshore Gabon; (2) the Pinda play, offshore Angola; (3) the Lucula/Toca play, offshore Cabinda; (4) the Metlaoui play, offshore Libya/Tunisia; (5) the mid-Cretaceous sand play, Chad/Sudan; and (6) the TAG-I/F6 play, onshore Algeria. Examples of these plays are illustrated along with some of the more traditional oil plays. Where are the future oil plays likely to develop No doubt, the Saharan basins of Algeria and Libya will feature strongly, also the presalt of Equatorial West Africa, the Central African Rift System and, more speculatively, offshore Ethiopia and Namibia, and onshore Madagascar, Mozambique, and Tanzania.

  20. World Oil Transit Chokepoints

    Reports and Publications

    2012-01-01

    Chokepoints are narrow channels along widely used global sea routes, some so narrow that restrictions are placed on the size of vessel that can navigate through them. They are a critical part of global energy security due to the high volume of oil traded through their narrow straits.

  1. Structural Oil Pan With Integrated Oil Filtration And Cooling System

    DOEpatents

    Freese, V, Charles Edwin

    2000-05-09

    An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

  2. State of Terengganu: A development plan for the petrochemical industry and its associated downstream industries. Final report

    SciTech Connect

    Not Available

    1987-01-08

    This study, conducted by Chem Systems, Inc., was funded by the U.S. Trade and Development Agency on behalf of Terengganu's State Economic Planning Unit. The main objectives of the report are to: (1) Identify and list all medium stream and downstream activities, including services in petrochemical industries, using natural gas-derived ethane, propane, and butane as main feedstock and other linkages; (2) List the various enterprises noted above that can be economically and viably established in Terengganu; (3) Identify and locate the various sites for the projects identified. This is volume 1 of 2 and it contains the Final Report.

  3. State of Terengganu: A development plan for the petrochemical industry and its associated downstream industries. Appendix. Export trade information

    SciTech Connect

    Not Available

    1987-02-01

    The study, conducted by Chem Systems, Inc., was funded by the U.S. Trade and Development Agency on behalf of Terengganu's State Economic Planning Unit. The main objectives of the report are to: (1) Identify and list all medium stream and downstream activities, including services in petrochemical industries, using natural gas-derived ethane, propane, and butane as main feedstock and other linkages; (2) List the various enterprises noted above that can be economically and viably established in Terengganu; (3) Identify and locate the various sites for the projects identified. This is volume 2 of 2 and it contains the Appendix.

  4. Process for upgrading heavy oils

    SciTech Connect

    LePage, J.F.; Marlino, G.

    1983-07-05

    The viscosity of heavy oils is reduced in order to facilitate pipe line transportation thereof. A fraction of the heavy oil is deasphalted in the presence of C/sub 5/-C/sub 7/ hydrocarbons, a portion of the separated asphalt is converted to synthesis gas, at least a portion of said gas is used to manufacture an alcohol mixture including methanol and C/sub 2/ to C/sub 10/ alcohols, which mixture is admixed with the heavy oil before transportation thereof. This procedure is more beneficial to the transported heavy oil than the prior processes which do not comprise the conversion of the asphalt fraction of the heavy oil.

  5. Heavy oil/plastic co-processing - subtask 4.1. Topical report, February 1, 1994--February 1, 1995

    SciTech Connect

    1998-12-31

    Western Research Institute (WRI) is developing a low-temperature thermal decomposition process to alleviate the problems associated with disposal of waste plastics and at the same time generate a product stream in the gasoline boiling range for use in the refining and petrochemical industries. The technology being developed by WRI is significantly different from conventional thermal decomposition processes used to recover distillates from waste plastics. The key to this difference is the application of a decomposition initiator concept that allows operation of the process at temperatures below those used in other thermal decomposition processes. The WRI technology utilizes the decomposition initiator to enhance thermal decomposition of waste plastics in the presence of a low-value heavy oil at temperatures below those normally used for thermal decomposition. Operation of the process at lower temperatures produces higher yields of distillate product and lower yields of gaseous and char products than conventional processes. The activity of the initiator was identified in earlier research studying the thermal decomposition of polymers. This activity was observed to result in a decrease in the temperature required to thermally decompose plastics in the presence of a heavy oil. These early experiments indicated that the initiator was native to the plastics matrix, but the identity and possible mode of action were not determined. This study was undertaken to identify the active initiator in the plastics matrix and define its activity. The experiments performed in this study were conducted in a batch-type reactor. The particular elements of the activity that were addressed included: (1) the kinetics of the reaction, (2) the effects of diluting the plastics with the heavy oil, and (3) the effects of using different types of heavy oil.

  6. Aerobic microbial enhanced oil recovery

    SciTech Connect

    Torsvik, T.; Gilje, E.; Sunde, E.

    1995-12-31

    In aerobic MEOR, the ability of oil-degrading bacteria to mobilize oil is used to increase oil recovery. In this process, oxygen and mineral nutrients are injected into the oil reservoir in order to stimulate growth of aerobic oil-degrading bacteria in the reservoir. Experiments carried out in a model sandstone with stock tank oil and bacteria isolated from offshore wells showed that residual oil saturation was lowered from 27% to 3%. The process was time dependent, not pore volume dependent. During MEOR flooding, the relative permeability of water was lowered. Oxygen and active bacteria were needed for the process to take place. Maximum efficiency was reached at low oxygen concentrations, approximately 1 mg O{sub 2}/liter.

  7. Unconventional Oil and Gas Resources

    SciTech Connect

    2006-09-15

    World oil use is projected to grow to 98 million b/d in 2015 and 118 million b/d in 2030. Total world natural gas consumption is projected to rise to 134 Tcf in 2015 and 182 Tcf in 2030. In an era of declining production and increasing demand, economically producing oil and gas from unconventional sources is a key challenge to maintaining global economic growth. Some unconventional hydrocarbon sources are already being developed, including gas shales, tight gas sands, heavy oil, oil sands, and coal bed methane. Roughly 20 years ago, gas production from tight sands, shales, and coals was considered uneconomic. Today, these resources provide 25% of the U.S. gas supply and that number is likely to increase. Venezuela has over 300 billion barrels of unproven extra-heavy oil reserves which would give it the largest reserves of any country in the world. It is currently producing over 550,000 b/d of heavy oil. Unconventional oil is also being produced in Canada from the Athabasca oil sands. 1.6 trillion barrels of oil are locked in the sands of which 175 billion barrels are proven reserves that can be recovered using current technology. Production from 29 companies now operating there exceeds 1 million barrels per day. The report provides an overview of continuous petroleum sources and gives a concise overview of the current status of varying types of unconventional oil and gas resources. Topics covered in the report include: an overview of the history of Oil and Natural Gas; an analysis of the Oil and Natural Gas industries, including current and future production, consumption, and reserves; a detailed description of the different types of unconventional oil and gas resources; an analysis of the key business factors that are driving the increased interest in unconventional resources; an analysis of the barriers that are hindering the development of unconventional resources; profiles of key producing regions; and, profiles of key unconventional oil and gas producers.

  8. Benthic invertebrate metals exposure, accumulation, and community-level effects downstream from a hard-rock mine site

    SciTech Connect

    Beltman, D.J.; Lipton, J.; Cacela, D.; Clements, W.H.

    1999-02-01

    This study quantitatively evaluated the relationships among As, Co, and Cu concentrations in exposure media (surface water, sediment, and aufwuchs), As, Co, and Cu concentrations in aquatic macroinvertebrates, and invertebrate community structure in a mine-affected stream. Concentrations of As, Co, and Cu were significantly elevated in both exposure media and invertebrate tissue downstream from the mine. Copper in invertebrates was significantly correlated only with Cu in aufwuchs, and Co in invertebrates was significantly correlated only with dissolved Co in water, suggesting different mechanisms of invertebrate accumulation for these two metals. The invertebrate community was severely affected downstream from the mine, with a loss of metals-sensitive species and reductions in both total biomass and number of species. Total abundance was not affected. Principal components analysis was performed on the invertebrate community data to develop a simplified description of community response to mine inputs. Based on this index, metal concentrations in invertebrates were poor predictors of community structure. Copper concentrations in water, combined with an estimate of invertebrate drift from clean tributaries, were statistically significant predictors of community structure.

  9. Mercury in Fish Collected Upstream and Downstream of Los Alamos National Laboratory, New Mexico: 1991--2004.

    SciTech Connect

    P.R. Fresquez

    2004-10-15

    Small amounts of mercury (Hg) may exist in some canyon drainage systems within Los Alamos National Laboratory lands as a result of past discharges of untreated effluents. This paper reports on the concentrations of Hg in muscle (fillets) of various types of fish species collected downstream of LANL's influence from 1991 through 2004. The mean Hg concentration in fish from Cochiti reservoir (0.22 {micro}g/g wet weight), which is located downstream of LANL, was similar to fish collected from a reservoir upstream of LANL (Abiquiu) (0.26 {micro}g/g wet weight). Mercury concentrations in fish collected from both reservoirs exhibited significantly (Abiquiu = p < 0.05 and Cochiti = p < 0.10) decreasing trends over time. Predator fish like the northern pike (Esox lucius) contained significantly higher concentrations of Hg (0.39 {micro}g/g wet weight) than bottom-feeding fish like the white sucker (Catostomus commersoni) (0.10 {micro}g/g wet weight).

  10. A characterization and evaluation of coal liquefaction process streams. The kinetics of coal liquefaction distillation resid conversion

    SciTech Connect

    Klein, M.T.; Calkins, W.H.; Huang, H.; Wang, S.; Campbell, D.

    1998-03-01

    Under subcontract from CONSOL Inc., the University of Delaware studied the mechanism and kinetics of coal liquefaction resid conversion. The program at Delaware was conducted between August 15, 1994, and April 30, 1997. It consisted of two primary tasks. The first task was to develop an empirical test to measure the reactivity toward hydrocracking of coal-derived distillation resids. The second task was to formulate a computer model to represent the structure of the resids and a kinetic and mechanistic model of resid reactivity based on the structural representations. An introduction and Summary of the project authored by CONSOL and a report of the program findings authored by the University of Delaware researchers are presented here.

  11. Weekly Petroleum Status Report

    Energy Information Administration (EIA) (indexed site)

    9 Distillate Stocks Figure 3. Stocks of Distillate Fuel Oil by PAD District, January 2015 to Present

  12. Strategic Significance of Americas Oil Shale Resource

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Early products de- rived from shale oil included kerosene and lamp oil, paraffin, fuel oil, lubricating oil and grease, naphtha, illuminating gas, and ammonium sulfate fertilizer. ...

  13. Florida Natural Gas Number of Oil Wells (Number of Elements)

    Energy Information Administration (EIA) (indexed site)

    Oil Wells (Number of Elements) Florida Natural Gas Number of Oil Wells (Number of ... Number of Gas Producing Oil Wells Number of Gas Producing Oil Wells (Summary) Florida ...

  14. About the Oil and Gas Field Code Master List

    Annual Energy Outlook

    ... Oil and Gas Board of Alabama Alaska Alaska Oil and Gas Conservation Commission Arizona Arizona Oil and Gas Conservation Commission Arkansas Arkansas Oil and Gas Commission ...

  15. Louisiana - North Crude Oil + Lease Condensate Proved Reserves...

    Energy Information Administration (EIA) (indexed site)

    Crude Oil + Lease Condensate Proved Reserves (Million Barrels) Louisiana - North Crude Oil ... Crude Oil plus Lease Condensate Proved Reserves, as of Dec. 31 North Louisiana Crude Oil ...

  16. Crude Oil and Petroleum Products Total Stocks Stocks by Type

    Energy Information Administration (EIA) (indexed site)

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases EthaneEthylene PropanePropylene Normal ButaneButylene ...

  17. Oil taxation and risks

    SciTech Connect

    Rodriguez-Padilla, V. )

    1992-01-01

    The relationship between the taxation system and the division of risks between the host country governments and the international companies is discussed. The analysis underscores the effect of taxation on the geological and political risks. These two cases are evaluated in two West-African oil-producing countries. It emerges from this that too heavy and regressive taxes greatly increase the risks supported by the two partners. The progressive character of the taxation is a necessary but not a sufficient condition for the reduction of public and private risks. A taxation burden well-balanced among small and large deposits is the best way to reduce the risk due to taxation. The oil-producing countries of this region had made great advances in developing neutral taxation systems but in most cases they must progress further. 15 refs., 3 figs., 1 tab.

  18. Shale oil recovery process

    DOEpatents

    Zerga, Daniel P.

    1980-01-01

    A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

  19. Oil shale retort apparatus

    DOEpatents

    Reeves, Adam A.; Mast, Earl L.; Greaves, Melvin J.

    1990-01-01

    A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

  20. Enhanced oil recovery

    SciTech Connect

    Fisher, W.G.

    1982-01-01

    The principal enhanced recovery technique is waterflooding, because water generally is inexpensive to obtain and inject into the reservoir and it works. With the shortage of conventional oil in Canada there is greater emphasis being placed on other recovery schemes in addition to or in place of waterflooding. Tertiary recovery is applicable to many of the existing projects and engineers must recognize those fields that are candidates for tertiary recovery applications. The application of tertiary recovery techniques to a specific reservoir requires consideration of all methods developed to select the one most suitable. A thorough understanding of waterflooding and the factors that affect recovery is necessary before a tertiary process is considered. Factors that affect oil recovery under waterflooding are areal and vertical sweep efficiency, contact factor and displacement efficiency.

  1. Genome Sequences of Industrially Relevant Saccharomyces cerevisiae Strain M3707, Isolated from a Sample of Distillers Yeast and Four Haploid Derivatives

    SciTech Connect

    Brown, Steven D.; Klingeman, Dawn M.; Johnson, Courtney M.; Clum, Alicia; Aerts, Andrea; Salamov, Asaf; Sharma, Aditi; Zane, Matthew; Barry, Kerrie; Grigoriev, Igor V.; Davison, Brian H.; Lynd, Lee R.; Gilna, Paul; Hau, Heidi; Hogsett, David A.; Froehlich, Allan C.

    2013-04-19

    Saccharomyces cerevisiae strain M3707 was isolated from a sample of commercial distillers yeast, and its genome sequence together with the genome sequences for the four derived haploid strains M3836, M3837, M3838, and M3839 has been determined. Yeasts have potential for consolidated bioprocessing (CBP) for biofuel production, and access to these genome sequences will facilitate their development.

  2. T-534: Vulnerability in the PDF distiller of the BlackBerry Attachment Service for the BlackBerry Enterprise Server

    Energy.gov [DOE]

    BlackBerry advisory describes a security issue that the BlackBerry Attachment Service component of the BlackBerry Enterprise Server is susceptible to. The issue relates to a known vulnerability in the PDF distiller component of the BlackBerry Attachment Service that affects how the BlackBerry Attachment Service processes PDF files.

  3. Emulsified industrial oils recycling

    SciTech Connect

    Gabris, T.

    1982-04-01

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  4. Retrofitting heavy oil processes

    SciTech Connect

    Hamilton, G.L.; Fitzgerald, M.; D'Amico, V.

    1986-01-01

    Refiners, faced with the need to process the bottom end of the heavy high sulfur crude oil barrel in today's uncertain economic environment, are reluctant to commit large amounts of money to expensive upgrading processes. In order to conserve scarce capital while improving operating margins, additional valuable products can be produced by retrofits such as conversion of an idle crude unit to visbreaking, delayed coking or deasphalting service, or conversion of hydrodesulfurizers to mild hydrocracking.

  5. Oil Price Volatility

    Gasoline and Diesel Fuel Update

    Speculation and Oil Price Volatility Robert J. Weiner Robert J. Weiner Professor of International Business, Public Policy & Professor of International Business, Public Policy & Public Administration, and International Affairs Public Administration, and International Affairs George Washington University; George Washington University; Membre Associ Membre Associ é é , GREEN, Universit , GREEN, Universit é é Laval Laval EIA Annual Conference Washington Washington 7 April 2009 7 April

  6. Geothermal Energy Market Study on the Atlantic Coastal Plain: Technical Feasibility of use of Eastern Geothermal Energy in Vacuum Distillation of Ethanol Fuel

    SciTech Connect

    1981-04-01

    The DOE is studying availability, economics, and uses of geothermal energy. These studies are being conducted to assure maximum cost-effective use of geothermal resources. The DOE is also aiding development of a viable ethanol fuel industry. One important point of the ethanol program is to encourage use of non-fossil fuels, such as geothermal energy, as process heat to manufacture ethanol. Geothermal waters available in the eastern US tend to be lower in temperature (180 F or less) than those available in the western states (above 250 F). Technically feasible use of eastern geothermal energy for ethanol process heat requires use of technology that lowers ethanol process temperature requirements. Vacuum (subatmospheric) distillation is one such technology. This study, then, addresses technical feasibility of use of geothermal energy to provide process heat to ethanol distillation units operated at vacuum pressures. They conducted this study by performing energy balances on conventional and vacuum ethanol processes of ten million gallons per year size. Energy and temperature requirements for these processes were obtained from the literature or were estimated (for process units or technologies not covered in available literature). Data on available temperature and energy of eastern geothermal resources was obtained from the literature. These data were compared to ethanol process requirements, assuming a 150 F geothermal resource temperature. Conventional ethanol processes require temperatures of 221 F for mash cooking to 240 F for stripping. Fermentation, conducted at 90 F, is exothermic and requires no process heat. All temperature requirements except those for fermentation exceed assumed geothermal temperatures of 150 F. They assumed a 130 millimeter distillation pressure for the vacuum process. It requires temperatures of 221 F for mash cooking and 140 F for distillation. Data indicate lower energy requirements for the vacuum ethanol process (30 million BTUs per

  7. High oil production continues to cut U.S. oil imports

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    High oil production continues to cut U.S. oil imports High U.S. crude oil production will help further reduce America's reliance on oil imports during the next two years. In its ...

  8. U.S. oil imports to decline with rising oil production through...

    Gasoline and Diesel Fuel Update

    oil imports to decline with rising oil production through 2014 The United States will need fewer oil imports over the next two years because of rising U.S. oil production. The new ...

  9. Crude Oil Movements of Crude Oil by Rail

    Gasoline and Diesel Fuel Update

    Product: Crude Oil Fuel Ethanol Biodiesel Period-Unit: Monthly-Thousand Barrels Annual-Thousand Barrels Download Series History Download Series History Definitions, Sources & Notes ...

  10. Crude Oil Prices Table 21. Domestic Crude Oil First Purchase...

    Energy Information Administration (EIA) (indexed site)

    Information Administration Petroleum Marketing Annual 1995 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  11. Michigan residential heating oil and propane price survey: 1995--1996 heating season. Final report

    SciTech Connect

    Moriarty, C.

    1996-05-01

    This report summarizes the results of a survey of residential No. 2 distillate fuel (home heating oil) and liquefied petroleum gas (propane) prices over the 1995--1996 heating season in Michigan. The Michigan`s Public Service Commission (MPSC) conducted the survey under a cooperative agreement with the US Department of Energy`s (DOE) Energy Information Administration (EIA). This survey was funded in part by a grant from the DOE. From October 1995 through March 1996, the MPSC surveyed participating distributors by telephone for current residential retail home heating oil and propane prices. The MPSC transmitted the data via a computer modem to the EIA using the Petroleum Electronic Data Reporting Option (PEDRO). Survey results were published in aggregate on the MPSC World Wide Web site at http://ermisweb.state.mi.us/shopp. The page was updated with both residential and wholesale prices immediately following the transmission of the data to the EIA. The EIA constructed the survey using a sample of Michigan home heating oil and propane retailers. The sample accounts for different sales volumes, geographic location, and sources of primary supply.

  12. Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids

    SciTech Connect

    Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert

    2009-09-15

    Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

  13. Method of operating an oil shale kiln

    DOEpatents

    Reeves, Adam A.

    1978-05-23

    Continuously determining the bulk density of raw and retorted oil shale, the specific gravity of the raw oil shale and the richness of the raw oil shale provides accurate means to control process variables of the retorting of oil shale, predicting oil production, determining mining strategy, and aids in controlling shale placement in the kiln for the retorting.

  14. The twentieth oil shale symposium proceedings

    SciTech Connect

    Gary, J.H.

    1987-01-01

    This book contains 20 selections. Some of the titles are: The technical contributions of John Ward Smith in oil shale research; Oil shale rubble fires: ignition and extinguishment; Fragmentation of eastern oil shale for in situ recovery; A study of thermal properties of Chinese oil shale; and Natural invasion of native plants on retorted oil shale.

  15. International Oil Supplies and Demands

    SciTech Connect

    Not Available

    1992-04-01

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--1990 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  16. International Oil Supplies and Demands

    SciTech Connect

    Not Available

    1991-09-01

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--90 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  17. Residential heating oil price decrease

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price decrease The average retail price for home heating oil fell 1.4 cents from a week ago to $2.39 per gallon. That's down 4.4 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.33 per gallon, down 4-tenths of a cent from last week, and down 4.4

  18. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price increases The average retail price for home heating oil rose 6-tenths of a cent from a week ago to $2.18 per gallon. That's down 79 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.13 per gallon, unchanged from last week, and down 88

  19. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 1.9 cents from a week ago to $2.16 per gallon. That's down 75 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.11 per gallon, down 2.8 cents from last week, and down 77

  20. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 5.1 cents from a week ago to $2.11 per gallon. That's down 72 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.05 per gallon, down 5.3 cents from last week, and down 75

  1. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 5 cents from a week ago to $2.06 per gallon. That's down 75 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.01 per gallon, down 4.1 cents from last week, and down 78

  2. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 1.8 cents from a week ago to $2.82 per gallon. That's down $1.36 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.79 per gallon, down 1.5 cents from last week, and down $1.34

  3. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price increases The average retail price for home heating oil rose 1.8 cents from a week ago to $2.08 per gallon. That's down 72 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.02 per gallon, up 3-tenths of a cent from last week, and down 76

  4. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 1.9 cents from a week ago to $2.80 per gallon. That's down $1.44 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.78 per gallon, down 1.2 cents from last week, and down $1.40

  5. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price increases The average retail price for home heating oil rose 1 cent from a week ago to $2.09 per gallon. That's down 82 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.02 per gallon, up 8-tenths of a cent from last week, and down 85

  6. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price increases The average retail price for home heating oil rose 1.1 cents from a week ago to $2.10 per gallon. That's down 94 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.04 per gallon, up 2.3 cents from last week, and down 95

  7. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price decreases The average retail price for home heating oil fell 9-tenths of a cent from a week ago to $2.09 per gallon. That's down $1.09 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.04 per gallon, down 1-tenth of a cent from last week, and down $1.11

  8. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price decreases The average retail price for home heating oil fell 5-tenths of a cent from a week ago to $2.09 per gallon. That's down $1.20 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.03 per gallon, down 9-tenths of a cent from last week, and down $1.22

  9. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price increases The average retail price for home heating oil rose 6-tenths of a cent from a week ago to $2.10 per gallon. That's down $1.11 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.04 per gallon, up 5-tenths of a cent from last week, and down $1.14

  10. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price increases The average retail price for home heating oil rose 2.6 cents from a week ago to $2.12 per gallon. That's down 91 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.06 per gallon, up 2.1 cents from last week, and down 94

  11. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price increases The average retail price for home heating oil rose 1 cent from a week ago to $2.13 per gallon. That's down 80 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $2.07 per gallon, up 9-tenths of a cent from last week, and down 83

  12. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 10.5 cents from a week ago to $2.93 per gallon, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.90 per gallon, down 10.4 cents from last week. This is Marcela Rourk

  13. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price decreases The average retail price for home heating oil fell 1.1 cents from a week ago to $2.38 per gallon. That's down 2.3 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.33 per gallon, down 5-tenths of a cent from last week, and down 1.6

  14. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 2.3 cents from a week ago to $2.38 per gallon. That's down 99 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.32 per gallon, down 3.1 cents from last week, and down $1.00

  15. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 1.5 cents from a week ago to $2.36 per gallon. That's down 97 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.31 per gallon, down 2-tenths of a cent from last week, and down 96

  16. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 3 cents from a week ago to $2.33 per gallon. That's down 89 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.28 per gallon, down 3.5 cents from last week, and down 9

  17. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 7.6 cents from a week ago to $2.26 per gallon. That's down 89 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.19 per gallon, down 8.9 cents from last week, and down 92

  18. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 4.5 cents from a week ago to $2.21 per gallon. That's down 87 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.15 per gallon, down 3.6 cents from last week, and down 89

  19. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 3.5 cents from a week ago to $2.18 per gallon. That's down 87 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.13 per gallon, down 2.2 cents from last week, and down 88

  20. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    5, 2014 Residential heating oil price decreases The average retail price for home heating oil fell 1.9 cents from a week ago to $3.43 per gallon. That's down 39 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.38 per gallon, down 2.6 cents from last week, and down 38.7

  1. Residential heating oil price decreases

    Energy Information Administration (EIA) (indexed site)

    7, 2014 Residential heating oil price decreases The average retail price for home heating oil fell 7.8 cents from a week ago to $3.14 per gallon. That's down 81.1 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.12 per gallon, down 6.5 cents from last week, and down 79.9

  2. Residential heating oil price increases

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price increases The average retail price for home heating oil rose 1.4 cents from a week ago to $2.38 per gallon. That's down 4.9 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose to $2.32 per gallon, up 3 cents from last week, and down 5.2 cents

  3. Residential heating oil prices available

    Energy Information Administration (EIA) (indexed site)

    Residential heating oil price increases The average retail price for home heating oil rose half of a cent from a week ago to $2.40 per gallon. That's down 2.6 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose to $2.33 per gallon, up 6-tenths of a cent from last week, and down 3.4

  4. Residential heating oil prices available

    Energy Information Administration (EIA) (indexed site)

    heating oil prices available The average retail price for home heating oil is $3.52 per gallon. That's down 32.7 cents from a year ago, based on the U.S. Energy Information Administration's weekly residential heating fuel price survey. Heating oil prices in the New England region are at $3.48 per gallon, down 29.1 cents from a year ago. This is Marcela Rourk, with EIA, in Washington

  5. Residential heating oil prices decline

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 2 cents from a week ago to $3.36 per gallon. That's down 52.5 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.31 per gallon, down 1.3 cents from last week, and down 52.6

  6. Residential heating oil prices decline

    Energy Information Administration (EIA) (indexed site)

    heating oil price decreases The average retail price for home heating oil fell 6.3 cents from a week ago to $3.08 per gallon. That's down 90.3 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.05 per gallon, down 6.8 cents from last week, and down 91.6

  7. Residential heating oil prices decline

    Energy Information Administration (EIA) (indexed site)

    2, 2014 Residential heating oil prices decline The average retail price for home heating oil is $3.48 per gallon. That's down 4.5 cents from a week ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are at $3.43 per gallon, down 5.7 cents from last week. This is Amerine Woodyard

  8. Residential heating oil prices decrease

    Energy Information Administration (EIA) (indexed site)

    heating oil prices decrease The average retail price for home heating oil fell 1.7 cents from a week ago to $4.02 per gallon. That's up 1.7 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to 4.01 per gallon, down 6-tenths of a cent from last week, and up 5.8

  9. Residential heating oil prices decrease

    Energy Information Administration (EIA) (indexed site)

    9, 2014 Residential heating oil price decreases The average retail price for home heating oil fell 2.9 cents from a week ago to $3.45 per gallon. That's down 36.6 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.41 per gallon, down 3 cents from last week, and down 35

  10. Residential heating oil prices increase

    Energy Information Administration (EIA) (indexed site)

    heating oil prices increase The average retail price for home heating oil rose 5.4 cents from a week ago to $4.04 per gallon. That's up 4.9 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose to 4.02 per gallon, up 5.6 cents from last week, and up 8

  11. Residential heating oil prices increase

    Energy Information Administration (EIA) (indexed site)

    3, 2014 Residential heating oil prices increase The average retail price for home heating oil rose 4.4 cents from a week ago to $4.06 per gallon. That's up 4.1 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose to 4.03 per gallon, up 2.5 cents from last week, and up 6

  12. Residential heating oil prices increase

    Energy Information Administration (EIA) (indexed site)

    heating oil prices increase The average retail price for home heating oil rose 12 cents from a week ago to $4.18 per gallon. That's up 13 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose to 4.13 per gallon, up 9.8 cents from last week, and up 12.9 cents from a

  13. Residential heating oil prices increase

    Energy Information Administration (EIA) (indexed site)

    heating oil prices increase The average retail price for home heating oil rose 3.9 cents last week to $3.96 per gallon. That's down 2.6 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. The price for heating oil in the New England region averaged 3.92 per gallon, up 5.2 cents from last week, and 1.7

  14. Residential heating oil prices increase

    Energy Information Administration (EIA) (indexed site)

    heating oil prices increase The average retail price for home heating oil rose 2.9 cents from a week ago to $3.98 per gallon. That's up 6-tenths of a penny from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose to 3.96 per gallon, up 4.1 cents from last week, and up 4.8

  15. Estimating Adult Chinook Salmon Exposure to Dissolved Gas Supersaturation Downstream of Hydroelectric Dams Using Telemetry and Hydrodynamic Models

    SciTech Connect

    Johnson, Eric L.; Clabough, Tami S.; Peery, Christopher A.; Bennett, David H.; bjornn, Theodore C.; Caudill, Christopher C.; Richmond, Marshall C.

    2007-11-01

    Gas bubble disease (GBD) has been recognized for years as a potential problem for fishes in the Columbia River basin. GBD results from exposure to gas supersaturated water created by discharge over dam spillways. Spill typically creates a downstream plume of water with high total dissolved gas supersaturation (TDGS) that may be positioned along either shore or mid-channel, depending on dam operations. We obtained spatial data on fish migration paths and migration depths for 228 adult spring and summer Chinook salmon, Oncorhynchus tshawytscha, during 2000. Migration paths were compared to output from a two-dimensional hydrodynamic and dissolved gas model to estimate the potential for GBD expression and to test for behavioral avoidance of the high TDGS plume in unrestrained fish migrating under field conditions. Consistent with our previous estimates using single-location estimates of TDGS, we observed salmon swam sufficiently deep in the water column to receive complete hydrostatic compensation 95.9% of time spent in the Bonneville tailrace and 88.1% of the time in the Ice Harbor tailrace. The majority of depth uncompensated exposure occurred at TDGS levels > 115%. Adult spring and summer Chinook salmon tended to migrate near the shoreline. Adults moved into the high dissolved gas plume as often as they moved out of it downstream of Bonneville Dam, providing no evidence that adults moved laterally to avoid areas with elevated dissolved gas levels. The strong influence of dam operations on the position of the high-TDGS plume and shoreline-orientation behaviors of adults suggest that exposure of adult salmonids to high-TDGS conditions may be minimized using operational conditions that direct the plume mid-channel, particularly during periods of high discharge and spill. More generally, our approach illustrates the potential for combined field and modeling efforts to estimate the fine-scale environmental conditions encountered by fishes in natural and regulated rivers.

  16. STEO September 2012 - oil production

    Energy Information Administration (EIA) (indexed site)

    oil production forecast to rise almost 700,000 bpd this year, help cut U.S. petroleum imports U.S. crude oil production is expected to average 6.3 million barrels per day in 2012. That's up nearly 700,000 barrels per day from last year and the highest annual oil output since 1997 says the U.S. Energy Information Administration in its new monthly short-term energy outlook for September. EIA analyst Sam Gorgen explains: "Higher oil supplies, especially from North Dakota and Texas, boosted

  17. Brushing up on oil recovery

    SciTech Connect

    Mackey, J.

    1995-12-01

    To be prepared for a range of oil spills, emergency response organizations must have an arsenal of powerful and adaptable equipment. Around the coastal United States, a network of oil spill cooperatives and emergency response organizations stand ready with the technology and the know-how to respond to the first sign of an oil spill. When the telephone rings, they may be required to mop up 200 gallons of oil that leaked off the deck of a ship or to contain and skim 2,000 gallons of oil from a broken hose at a loading terminal. In a few cases each year, they may find themselves responding to a major pollution incident, one that involves hundreds of people and tons of equipment. To clean an oil spill at a New Jersey marine terminal, the local cooperative used the Lundin Oil Recovery Inc. (LORI) skimming system to separate the oil and water and the lift the oil out of the river. The LORI skimming technology is based on sound principles of fluid management - using the natural movement of water instead of trying to fight against it. A natural feeding mechanism delivers oily water through the separation process, and a simple mechanical separation and recovery device - a brush conveyor - removes the pollutants from the water.

  18. Oil cooled, hermetic refrigerant compressor

    DOEpatents

    English, William A.; Young, Robert R.

    1985-01-01

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler 18 and is then delivered through the shell to the top of the motor rotor 24 where most of it is flung radially outwardly within the confined space provided by the cap 50 which channels the flow of most of the oil around the top of the stator 26 and then out to a multiplicity of holes 52 to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber 58 to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole 62 also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator 68 from which the suction gas passes by a confined path in pipe 66 to the suction plenum 64 and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum 64.

  19. Oil cooled, hermetic refrigerant compressor

    DOEpatents

    English, W.A.; Young, R.R.

    1985-05-14

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler and is then delivered through the shell to the top of the motor rotor where most of it is flung radially outwardly within the confined space provided by the cap which channels the flow of most of the oil around the top of the stator and then out to a multiplicity of holes to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator from which the suction gas passes by a confined path in pipe to the suction plenum and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum. 3 figs.

  20. Solar retorting of oil shale

    DOEpatents

    Gregg, David W.

    1983-01-01

    An apparatus and method for retorting oil shale using solar radiation. Oil shale is introduced into a first retorting chamber having a solar focus zone. There the oil shale is exposed to solar radiation and rapidly brought to a predetermined retorting temperature. Once the shale has reached this temperature, it is removed from the solar focus zone and transferred to a second retorting chamber where it is heated. In a second chamber, the oil shale is maintained at the retorting temperature, without direct exposure to solar radiation, until the retorting is complete.

  1. Heating Oil and Propane Update

    Gasoline and Diesel Fuel Update

    The Federal forms below are required for State Energy Officials participating in the State Heating Oil and Propane Program (SHOPP) to execute their cooperative agreements with the ...

  2. Heating Oil and Propane Update

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Holiday Release Schedule The Heating Oil and Propane Update is produced during the winter heating season, which extends from October through March of each year. The standard ...

  3. Oil market outlook and drivers

    Gasoline and Diesel Fuel Update

    Oil inventories in industrialized countries to reach record high at end of 2015 The amount of year-end oil inventories held in industrialized countries is expected to be the highest on record in 2015. In its monthly forecast, the U.S. Energy Information Administration said it expects commercial oil inventories in the United States and other industrialized countries to total 2.83 billion barrels at the end of this year almost 90 million barrels more than at the end of 2014. Global oil production

  4. "Code(a)","End Use","Total","Electricity(b)","Fuel Oil","Diesel Fuel(c)","Natural Gas(d)","NGL(e)","Coke and Breeze)","Other(f)"

    Energy Information Administration (EIA) (indexed site)

    2 Relative Standard Errors for Table 5.2;" " Unit: Percents." ,,,,,"Distillate" ,,,,,"Fuel Oil",,,"Coal" "NAICS",,,"Net","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End Use","Total","Electricity(b)","Fuel Oil","Diesel Fuel(c)","Natural Gas(d)","NGL(e)","Coke and Breeze)&

  5. "End Use","Total","Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural Gas(c)","NGL(d)","Coke and Breeze)","Other(e)"

    Energy Information Administration (EIA) (indexed site)

    6 Relative Standard Errors for Table 5.6;" " Unit: Percents." " "," ",," ","Distillate"," "," ",," " " ",,,,"Fuel Oil",,,"Coal" " "," ","Net","Residual","and",,"LPG and","(excluding Coal"," " "End Use","Total","Electricity(a)","Fuel Oil","Diesel

  6. heavy_oil | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Much of America's heavy oil is produced via a costly steam injection enhanced oil recovery (EOR) method to produce a crude oil grade that is lower in quality and thus sells for ...

  7. ,"U.S. Crude Oil Imports"

    Energy Information Administration (EIA) (indexed site)

    ... Imports from Ghana of Crude Oil (Thousand Barrels per Day)","U.S. Imports from Guatemala of Crude Oil (Thousand Barrels per Day)","U.S. Imports from Guinea of Crude Oil ...

  8. ,"U.S. Crude Oil Imports"

    Energy Information Administration (EIA) (indexed site)

    ... Imports from Ghana of Crude Oil (Thousand Barrels)","U.S. Imports from Guatemala of Crude Oil (Thousand Barrels)","U.S. Imports from Guinea of Crude Oil (Thousand ...

  9. Oman Oil Company | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Oil Company (S.A.O.C.) Name: Oman Oil Company (S.A.O.C.) Place: Muscat, Oman Product: Oil exploration and production Year Founded: 1966 Phone Number: + 968 - 2457 3100 Website:...

  10. Compare All CBECS Activities: Fuel Oil Use

    Gasoline and Diesel Fuel Update

    Fuel Oil Use Compare Activities by ... Fuel Oil Use Total Fuel Oil Consumption by Building Type Commercial buildings in the U.S. used a total of approximately 1.3 billion gallons...

  11. ,"U.S. Crude Oil Imports"

    Energy Information Administration (EIA) (indexed site)

    ... Imports from Oman of Crude Oil (Thousand Barrels)","U.S. Imports from Papua New Guinea of Crude Oil (Thousand Barrels)","U.S. Imports from Peru of Crude Oil (Thousand ...

  12. heavy_oil | netl.doe.gov

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Heavy Oil Heavy oil is a vast U.S. oil resource that is underexploited because its highly viscous nature renders it difficult to produce and to refine. As higher-gravity crudes ...

  13. Iran Oil and Gas | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Iran Oil and Gas Jump to: navigation, search Logo: Iran Oil and Gas Name: Iran Oil and Gas Address: Unit 16, 3rd Fl., Bldg. No. 2, 9th Narenjestan St., North Pasdaran Ave. Place:...

  14. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what

  15. Upgrading residual oil

    SciTech Connect

    Angevine, P.J.; Stein, T.R.

    1982-04-13

    Residual oil fractions are upgraded in that Conradson Carbon Residue (CCR) is selectively removed without undue hydrogen consumption by hydroprocessing with a catalyst comprising a single metal such as molybdenum, tungsten, nickel, iron or palladium or multimetallic combination of such metals, excluding, however, active desulfurization compositions such as nickel molybdenum and nickel-tungsten. Said catalyst is characterized as having greater than about 50% of its pore volume contribution in pores having diameters in the range of between about 100 and 200 angstroms. The product of such hydroprocessing is a particularly preferable feedstock for coking to give more liquid yield and less coke make.

  16. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields while simultaneously maximizing oil production. January 8, 2014 Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery. Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery.

  17. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields while simultaneously maximizing oil production. January 8, 2014 Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery. Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery.

  18. Enhanced Oil Recovery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Enhanced Oil Recovery Enhanced Oil Recovery Cross-section illustrating how carbon dioxide and water can be used to flush residual oil from a subsurface rock formation between wells. Cross-section illustrating how carbon dioxide and water can be used to flush residual oil from a subsurface rock formation between wells. Crude oil development and production in U.S. oil reservoirs can include up to three distinct phases: primary, secondary, and tertiary (or enhanced) recovery. During primary

  19. Perspective: Towards environmentally acceptable criteria for downstream fish passage through mini hydro and irrigation infrastructure in the Lower Mekong River Basin

    SciTech Connect

    Baumgartner, Lee J.; Deng, Zhiqun; Thorncraft, Garry; Boys, Craig A.; Brown, Richard S.; Singhanouvong, Douangkham; Phonekhampeng, Oudom

    2014-02-26

    Tropical rivers have high annual discharges optimal for hydropower and irrigation development. The Mekong River is one of the largest tropical river systems, supporting a unique mega-diverse fish community. Fish are an important commodity in the Mekong, contributing a large proportion of calcium, protein, and essential nutrients to the diet of the local people and providing a critical source of income for rural households. Many of these fish migrate not only upstream and downstream within main-channel habitats but also laterally into highly productive floodplain habitat to both feed and spawn. Most work to date has focused on providing for upstream fish passage, but downstream movement is an equally important process to protect. Expansion of hydropower and irrigation weirs can disrupt downstream migrations and it is important to ensure that passage through regulators or mini hydro systems is not harmful or fatal. Many new infrastructure projects (<6 m head) are proposed for the thousands of tributary streams throughout the Lower Mekong Basin and it is important that designs incorporate the best available science to protect downstream migrants. Recent advances in technology have provided new techniques which could be applied to Mekong fish species to obtain design criteria that can facilitate safe downstream passage. Obtaining and applying this knowledge to new infrastructure projects is essential in order to produce outcomes that are more favorable to local ecosystems and fisheries.

  20. Oil & Gas Research | Department of Energy

    Energy Saver

    DOE is conducting groundbreaking research to unlock the energy potential of gas hydrates. Read more Unconventional Oil and Natural Gas Unconventional Oil and Natural Gas DOE ...

  1. ,"Total Crude Oil and Petroleum Products Exports"

    Energy Information Administration (EIA) (indexed site)

    Data for" ,"Data 1","Total Crude Oil and Petroleum Products ... "Back to Contents","Data 1: Total Crude Oil and Petroleum Products Exports" ...

  2. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate ...

  3. Biomass Derivatives Competitive with Heating Oil Costs.

    Energy Saver

    Biomass Derivatives Competitive with Heating Oil Costs Transportation fuel Heat or electricity * Data are from literature, except heating oil is adjusted from 2011 winter average * ...

  4. SciTech Connect: "oil shale"

    Office of Scientific and Technical Information (OSTI)

    oil shale" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "oil shale" Semantic Semantic Term Title: Full Text: Bibliographic Data: Creator ...

  5. Oil and Gas Gateway | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    States, oil and gas boards and commissions are the place for finding data related to oil and gas activities. These activities include well records, permitting, and production...

  6. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  7. Oil and Gas Research| GE Global Research

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Oil & Gas We're balancing the increasing demand for finite resources with technology that ensures access to energy for generations to come. Home > Innovation > Oil & Gas ...

  8. Measuring Dependence on Imported Oil

    Reports and Publications

    1995-01-01

    U.S. dependence on imported oil can be measured in at least two ways. The differences hinge largely on whether oil imports are defined as net imports (total imports minus exports) or as total imports. EIA introduces a revised table that expresses dependence on imports in terms of both measures.

  9. Conversion of heavy hydrocarbon oils

    SciTech Connect

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  10. Finished Motor Gasoline Net Production

    Gasoline and Diesel Fuel Update

    Adjustment Kerosene-Type Jet Fuel Kerosene-Type Jet, Commercial Kerosene-Type Jet, Military Distillate Fuel Oil Distillate Fuel Oil, 15 ppm Sulfur and Under Distillate Fuel Oil ...

  11. Heavy oil transportation by pipeline

    SciTech Connect

    Gerez, J.M.; Pick, A.R.

    1996-12-31

    Worldwide there are a number of pipelines used to transport heavy crude oils. The operations are facilitated in a variety of ways. For example, the Alyeska pipeline is an insulated pipeline transporting warm oil over 800 miles. This 48-inch line experiences limited heat loss due to the insulation, volume of oil contained, and heat gain due to friction and pumping. Some European trunk lines periodically handle heavy and waxy crudes. This is achieved by proper sizing of batches, following waxy crudes with non-waxy crudes, and increased use of scrapers. In a former Soviet republic, the transportation of heavy crude oil by pipeline has been facilitated by blending with a lighter Siberian crude. The paper describes the pipeline transport of heavy crudes by Interprovincial Pipe Line Inc. The paper describes enhancing heavy oil transportation by emulsion formation, droplet suspension, dilution, drag reducing agents, and heating.

  12. Process for oil shale retorting

    DOEpatents

    Jones, John B.; Kunchal, S. Kumar

    1981-10-27

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  13. Sources of Mercury to East Fork Poplar Creek Downstream from the Y-12 National Security Complex: Inventories and Export Rates

    SciTech Connect

    Southworth, George R; Greeley Jr, Mark Stephen; Peterson, Mark J; Lowe, Kenneth Alan; Ketelle, Richard H; Floyd, Stephanie B

    2010-02-01

    sediments by more than 2000-fold) in the 1980s, mercury concentrations in EFPC fish exceeded those in fish from regional reference sites by only a little more than 10-fold. This apparent low bioavailability of mercury in EFPC, coupled with a downstream pattern of mercury in fish in which mercury decreased in proportion to dilution of the upstream source, lead to the assumption that mercury in fish would respond to decreased inputs of dissolved mercury to the stream's headwaters. However, during the past two decades when mercury inputs were decreasing, mercury concentrations in fish in Lower EFPC (LEFPC) downstream of Y-12 increased while those in Upper EFPC (UEFPC) decreased. The key assumption of the ongoing cleanup efforts, and concentration goal for waterborne mercury were both called into question by the long-term monitoring data. The large inventory of mercury within the watershed downstream presents a concern that the successful treatment of sources in the headwaters may not be sufficient to reduce mercury bioaccumulation within the system to desired levels. The relative importance of headwater versus floodplain mercury sources in contributing to mercury bioaccumulation in EFPC is unknown. A mercury transport study conducted by the Tennessee Valley Authority (TVA) in 1984 estimated that floodplain sources contributed about 80% of the total annual mercury export from the EFPC system (ORTF 1985). Most of the floodplain inputs were associated with wet weather, high flow events, while much of the headwater flux occurred under baseflow conditions. Thus, day-to-day exposure of biota to waterborne mercury was assumed to be primarily determined by the Y-12 source. The objective of this study was to evaluate the results of recent studies and monitoring within the EFPC drainage with a focus on discerning the magnitude of floodplain mercury sources and how long these sources might continue to contaminate the system after headwater sources are eliminated or greatly reduced.

  14. DOE - Fossil Energy: Squeezing Oil Out of Rock

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2-Squeezing Out Oil An Energy Lesson Looking Down an Oil Well Looking Down an Oil Well Squeezing Oil out of Rocks Imagine trying to force oil through a rock. Can't be done, you ...

  15. Fuel oil quality task force

    SciTech Connect

    Laisy, J.; Turk, V.

    1997-09-01

    In April, 1996, the R.W. Beckett Corporation became aware of a series of apparently unrelated symptoms that made the leadership of the company concerned that there could be a fuel oil quality problem. A task force of company employees and industry consultants was convened to address the topic of current No. 2 heating oil quality and its effect on burner performance. The task force studied changes in fuel oil specifications and trends in properties that have occurred over the past few years. Experiments were performed at Beckett and Brookhaven National Laboratory to understand the effect of changes in some fuel oil properties. Studies by other groups were reviewed, and field installations were inspected to gain information about the performance of fuel oil that is currently being used in the U.S. and Canada. There was a special concern about the use of red dye in heating oils and the impact of sulfur levels due to the October, 1993 requirement of low sulfur (<0.05%) for on-highway diesel fuel. The results of the task force`s efforts were published in July, 1996. The primary conclusion of the task force was that there is not a crisis or widespread general problem with fuel oil quality. Localized problems that were seen may have been related to refinery practices and/or non-traditional fuel sources. System cleanliness is very important and the cause of many oil burner system problems. Finally, heating oil quality should get ongoing careful attention by Beckett engineering personnel and heating oil industry groups.

  16. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    SciTech Connect

    Anthony R. Kovscek; William E. Brigham

    1999-06-01

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  17. Oil Stop Valve : Oil Spill Containment Research and Development Project.

    SciTech Connect

    Bourn, Robert D.

    1982-07-01

    This report summarizes the research and development project conducted by the Civil Engineering Section, Division of Substation and Control Engineering, to determine the effectiveness of the oil stop valve for use in the Bonneville Power Administration's Oil Spill Containment and Countermeasure Program. The most attractive alternative to lagoons and separator tanks was found in the oil stop valve manufactured by AFL/Clark Industries of Riviera Beach, Florida. This small, direct-acting and relatively inexpensive valve requires little maintenance and can either be employed independently, using existing drain lines for effluent storage, or in conjunction with oil separator tanks and lagoon systems. The AFL/Clark valve requires no power and has only one moving part, a ballasted float having a specific gravity between that of oil and water. In water, the float rides above the throat of the discharge pipe allowing water to flow out. When oil enters the water the float begins losing its relative bouyancy and sinks until it seats itself over the throat of the outlet, closing the valve. Usually installed in a manhole within a typical storm drainage system, the valve backs spilled oil into drainways and contains it for temporary storage within the switchyard.

  18. DOE to Purchase Heating Oil for the Northeast Home Heating Oil Reserve |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Purchase Heating Oil for the Northeast Home Heating Oil Reserve DOE to Purchase Heating Oil for the Northeast Home Heating Oil Reserve June 23, 2008 - 1:29pm Addthis WASHINGTON, DC -The U.S. Department of Energy (DOE) today issued a solicitation seeking to purchase heating oil for the Northeast Home Heating Oil Reserve (NEHHOR) using $3 million in appropriated funds. The Northeast Home Heating Oil Reserve provides an important safety cushion for millions of Americans

  19. Shale oil deemed best near-term synfuel for unmodified diesels and gas turbines. [More consistent properties, better H/C ratios

    SciTech Connect

    Not Available

    1980-06-16

    Among synthetic fuels expected to be developed in the next decade, shale oil appears to be the prime near-term candidate for use in conventional diesel engines and gas turbines. Its superiority is suggested in assessments of economic feasibility, environmental impacts, development lead times and compatibility with commercially available combustion systems, according to a report by the Exxon Research and Engineering Co. Other studies were conducted by the Westinghouse Electric Corp., the General Motors Corp., the General Electric Co. and the Mobil Oil Co. Coal-derived liquids and gases also make excellent fuel substitutes for petroleum distillates and natural gas, these studies indicate, but probably will be economic only for gas turbines. Cost of upgrading the coal-derived fuels for use in diesels significantly reduces economic attractiveness. Methane, hydrogen and alcohols also are suitable for turbines but not for unmodified diesels. The Department of Energy supports studies examining the suitability of medium-speed diesels for adaptation to such fuels.

  20. Water issues associated with heavy oil production.

    SciTech Connect

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.